SCIENTIFIC ABSTRACT KORSHAK,V.V. - KORSHAK,V.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000824930007-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ACCESSION NRs AP4037282
'treated with tart-butyl peroxide to form a polymort
C14:
ILI
.06
Cris +
H `H
The 3bove polymer structure was confirmed by IR and elemental
analysis. In case 2, 'a mixture of two nitriles was treated with;'
I tert-butyl peroxides/ malonitrile and adiponitrile. &--tolunitr I Is
or diphenylmethane;'methyl 2-cyangacetate and a-tolunitrile or
f
malonitrile. All the copolymers produced contained a system
of conjugated C-N bonds in the backbone 9 gave mn EPR signalg and k-
had high decomposition temperatures (300-600C)&, but showed
i1o elasticity# As a rule# they were soluble in dimethylfor"amide,
and cresol only, and exhib-ited semiconducting properties, The
temperature dependence of conductivity obeyed an exponential. law.,,-,'
J
2/3,

V-ACCESSION URI AP40372 62

Conductivity measured in vacuum (about 10-3 a Hg) at 293K
ranged from 3.35elO-22 to 9.33-10-11 ohm" c:- but at
225-300C it reached 10-11ohn-t cu"I. This research was done at thc
institute of Organoele ftental Compounds of the Academy of
-USSR* Oriss art* hoes 2 figures, 3 tables. and 6 formula@*
ASSOCIATION# Instit
i Igmentoorganichoskikh soyedinenly AN
:
.15SR (Institute oV0 g
oolomentatO
:
o Compounds,,AN SSSR)

UBMITTEDI O5Jun63

ATE ACQ t 09 n 0,
89CLI 0
Ju

UB CODE g ]a .0

RZF-SOVI 00 7,'~ - OTHSI s 09
t

A

:C,,d 3/3

.R
1 WE - 11
WON
- ,

NR: Ap4o37285 S/0190/64/006/005/09M/090
'AUTHORSs Korshaks Vo Vo I'Frumej T, No; 1%yoneyevs A. Ael Shishkina., To o
ITITLEt Synthesis of polymero bjr the polycrolization reactions 4, Synthesis of
polyamidobomimidozolon, from 301-diaminobenzidines hemathylon-aaamb-00 and
diphanylaebacate
SOURCE: Vy*sokomoleku1yarnr4y9 soyedineniyaVy, 6. no. 5s 1964, 901-905
TOPIC TAGSt: polymer polycyclization reaction, mixed polyamidobanximidar-olop
diaminobenaidine hexamebhylenediamine diphenylsebacates polyamidization reaction
i
-ABSTRACT: The nation of 301-diaminobemidine (DAB)s h~xawthylene
polyconder
!diamine (HKD) and diphenylsebacate (DFS) vas.conducted 0 a current of nitrogenj
and the products were heated in a 1 um vacuum and a 10-J vacuum* The proportion of'I
ined mixed polyamidobansisidazoles variedp depending on the ratio of the,
the obta
issuirg materiales the temperatures and the duration of the polymerisation MaGt1w
but all of than contained blodrs of the.structure-
1/3

OV
I. V
Cheralead transfoination Of POlYmer5- 18. -Qed.
n0.6:994'-996 Je 164 01-1,1.-R,~ 18,2)

ACCESSION Nit: Ap4o4o487' S/0190/64/006/006/1078/lW
AUTHORS: Korshak., V. V.j Krongauzo Ye. S.; Berlin., A. M.
TITLEs Synthesis ~f polymers by the polycyclization reaction. Polypyrazoles
SOURCE: Vy*sokomolekulyarrMe soyedineniyaq ve 6., no, 6. 1964; 1078-106
TOPIC TAGS: polycyclization reaction., branched diketone., adipic acid dihydrazide's
keto enol tautomerism., polypyra~ole., polylVdrazone
ABSTRACT: This is a continuation of an earlier work by the authors and P. N.
Gribkova (Doki. AN SSSR 149 602,1953 CAbstracter's notei 1963 on the inter-
.0 !7)
action of bis-( 0-diketonesi with the dibydrazide of adipio acid (DAA). The
present investigation differed from the previous one in that instead of linear
diketones it involved branched diketones of the type
CHI CHI
O=C C/- 0
H,-,R.-CH
1 0 4~ Cj- 0
\bH
Card 1/3 CHI

ACCESSION XR: APW40487
where the R is either absent or represents CH
22 GH&H,~H GH~Ce 0 H CH or
2 4 6 4 20
02G6HO04CH The synthesis of these monomers with DAA was conducted by heating
2*
equimolecular quantities of the reactants either in absolute ethanol or in a melt
for periods up to 10 hours at 80-170C, The obtained polyhydrazones or polypyrazoles
were analyzed and their malting point, viscosity (in cresol or sulfuric acid), and
infrared spectra were recorded. It was found that the reaction of tetraacetyldi-
ethylbenzol- of 4 41-bis-(211,211-diacetoethyl)ciiphenyl-, am of 4,41-bis-(21,02'e-
j
diacetoethyl~diphe;~rloxide with DAA yielded polypiperazoles, while the other
diketones produced polyhydrazones, In the opinion of the authors, the composition
oreactivity of the and product of the~reaction is determined by the k6to-enol
.tautomerism of the original dikotones and by their cis- or trans-configuration.
.The keto form led directly to polypyrazoles,, the trans-onol configuration yielded
only polyhydrazones, while the cis-onol form yielded polypyrazoles through the Poly.!
.hydrazone intermediate atage. V. E. Sheina supplied the tetraacetylpropane #rA
carried out its purification, Orig, arto hass 3 tables and 4 fonwlas.
'ASSOOIATIONs Institut- elementoor"nI&Ookikh soyedineMy AN 9M. (lutitute of
Card 2/3

AccEssioN NR.- Apho4o487
Elenientooreanic Go"undes AN SM)
sommiED: j,,,, 63 DATF, AcQ, o6jul64 ML 00
SUB CODEs GG NO REF SOVs 003 OTMI 008
Card 3/3

JXCESSION Nfti APho4o488
5/0l9O/6h/0O6/0O6Ao67Aoq1
AUTHORS: Korshakp Ve V.; Krongauzs Yee So; Berlins A. M.; Travnikova, A. P.
TITLE: Synthesis of polymers by the po%veyclization reaction, 6, Polypyrazoles
SOURCE: Vy*sokomolekulyarny" soyedineniya, v. 6s no. 6p 1964p 1087-1091
TOPIC TAGS: polycyclization reactions polypryazole., bipyrazole polycondensations
dicarbo.Vlic acid chloride, dikefone polycyclization, dicarboxylic acid d1hydrazido
ABSrRACT t T lie investigators atteVtod. to synthesize polypyrazoles from coupounds
containing pyrazole cycles@ The desired results were achieved by po3jvorA&nxati*fi
of bipyrazoles with the chlorides of dicarboWlic acids according to the r"atim
X 0 0
R J-R
r
'.Card 1/3

.ACCESSION N
R, AMA88
-Hc--c
RG N N CR
+2HCI,'
\N/ C Y-G-
0 0
whe
re X Cell, (C112) 2CsH4; CsHj0C6ll&;- CH2Ca1ljCH2; (CH2)e; RMs. CeHs;
Y (CI12)4, CGHI-
:A total of 8 bypyrazoles were synthesized. Seven of them were now and re-Presenteds
,4,41-bis-(5-methylpyrazolyl-3)diplienyloxide 4 hl-bis-(3,5-dimethylpyrazolyl-4)
xylilene, 4,41-bis--53,,5-dimethylpyrazolyl-t)m'etIV17diphenyloxide, 4,L'-bis-j3.*5-
.4phenyl, 1,8 di-(5-phenyl-pyr di-(3s5-
dimethylpyrazolyl-WinethY17 -azolyl-3)octane,
dimethylpyrazolyl-4), and 4,41-bis-(5-methylpyrazolyl-j)diphenyldisulfide, The
procedure was started by mixing 30-40 ml of pyridine with 0.1 mole quantities of
one of the bypyrazoles. To these mixtures were added (dropwiso) 0.1 mole amounts
of adipic, terephthalic, or isophthalic acid chloride, dissolved in 20 ml of
'xylene. The contents of the flasks were stirred and cooled for several hours.
~They were then heated for a long time to 100-125C,, and were &1lowed to stand over.
;night. The po2ypyrazoles so produced were identical with the polvpyrazoles ob-
;,Card 2/3

Accwww NR v Ap4o4o488
tained by polycyclization of bis-( -diketones) with the
dihydrazides of the corresponding dicarbwW3.ic acids. The latter eroup was
described in an earlier publication by the authors and P. N. Gritkova (Dokl. AN
SMS 31482 6020 1963). Orig, art, has 1 3 table3 and 1 formula*
AsSOCIATIoN j Institut elsmentoorganichakikh soyedinerdy AN WSR (Institute of
'Elementoorganic Compounds# AN SSSR)
SUBKITTED3 3ljul63 DATE ACO 06Jul64 ENCL: 00
:SUB COM GG ND MW SOVI (mm, oo6
card 313

!ACCESSION NRt AP4042185 S/0190/64/006/007/1195/1202.~,-.;
AUTHORs Kor f_4 V Berlin, As He; Smirnovaq
sh Krongaus, Yee So;
To Yao
TITLE: Synthesis of polymers by polycyclization. Polypyrazoles.
SOURCE: Vy*sokomolakulyarny*ye soyedinenlya, v. 6, no. 7, 1964,
1195-1202
TOPIC TAGS: polypyrazole, polycyclization reaction, bLs-(0-4iketone)
dihydrazine, hexamethytenehydrazine dihydrochl 'orido, p-phenylene-
hydrazine dihydrochloride, polypyrazole property
ABSTRACT: The authors have synthesized polypyrazoles (up.. 200-3000
by polycylizatlon of linear and branched bin-(O-dLketones) with di-
,ly-
hydrazides of dicarboxylic acids. In an attempt to develop pa
pyrazoles with a higher heat resistance, d1hydrazides were replaced
with dihydrazine, or aside groups were introduced in the polymers to 1~
form hydrogen bonds. Polycyclization of bis-(0-diketones) with
Ihexamethylons- or p-phonylonehydrazine dihydrochlorides in boiling
jalcohol with alkali added to separate and bind HCI, or beating equi-~
Imolar amounts of the Initial materials in pyridine, yielded
L~#rd _.I /2., ........

;ACCESSION MR: AP4042185
;polypyrazoles - powders with a up of 80-263C and a molecular
!weight of 5000. Polypyrazoles.containing amide groups in the back-
!bone were synthesized by reacting dipyrazoles with diisocyanates in
;chlorobenzene or by melting the initial materials in nitrogen. These
polymers are white powders with a up of 208-276C and a molecular
1weight of up to 10,000t. IR'spectra indicate that they do not contain'.
1hydrogen bonds. Thus,,the attempt to synthesize heat-resistant Poly-F,
1pyrozoles failed. The presence of heavy pyrazole rings upsets the
;symmetry and loosens the packing density of the polymer ch4LnS, andg.-
as a result, prevents the formation of hydrogen bonds* Orige art&
has: 1 figure and 2 table.*.
ASSOCIATIONS Instit'ut slamentoorganichaskikh soyedinonLy AN SSSR
(Institute of Organoolesental Compounds,AN SSSR)
SUBMITTEDo llJul63 ATD PRZSSs 3068 ENCLS 00
SUB CODES OC 00 NO RZY SOVI 009 OTNIRI 00.3
,,Card 2/2

POI, Irecombina,-Lon of
pe, C.)t .-P
1oil
j n a e 0

institut elementoorganicbpqkikh soyedinaniy AN gi'w-S? inf," '..jtp of
AY SSSR',
ETICL: 00 SIT3 OODE: Oc ',C
OTIfER: Oll s

L 119799-65 W(m)/EPF(0!)/E0WA-,~'*-"
ACCEssioN NR: Ap5w%og Y 9/0190/0!
AUTHOR. Sosin, S. L~jjiorozgva~ -Y~~ M.1, Korsbak, V. V.
TITLE: Production of high-molecular compounds on the basis of ii-4,ljderivativas
~!'.thod of
polyrecombij=tion
SOURCE: Vysokomolekulyarnyye Medineniya, v. 6. no. 7, 1964. i.228-123,,x
TOPIC TAGS: polymerization, maciN66ol6cular chemidty
ABSTRACT: Polymers were syntMeLzed by the reaction of polyrecombintion.-
utfil,--ing those factors that normally prevent radical V--!XmFfT~PtiOny i,e-
P, a 11 yl rod ica I , wh L c h I a I ac a,-) a' : e ~)F
recombtriation, and the ease c,f i~om-D.XtLc stri~p-;ng
A,~oms of the methyliane group. The methc-d of ,;ynthetLzLng
yrecom'l inat ton r"ctions is oas~d on ~-e rc-~~f tbA
-y jL-ip-;Ing the labiie hydrogen stcms -,)v
'~Ccozapo3ltLon 0C lnlux~dau -t r1w; ~m-Dna,.,on
-.r, con(lqcted at 2000, using ttts man-mer and
'-utyl~ perox.Lde &a t~%a source of fre
e radLcala. A poly%war was,
Gard 1/2

.L 19799-65
ACCESSION MR: AP5W3W
-obtained, in which- the double bohda- wefts preserved. ~-Tha polywir,poaseased
molecular weight of 5-106 and malted at 3000. it was ahgwn Ihat polymer
Lonazz&Lioa proceeda In two steps, namely by preliminary conversion of ally-
a;. ~.ac.~a to an o1 i~orzmar with molecular. weighp-" 400a thmuvh tk.ex- _nol
'binat waimW isnpre_mqw. IF
LSS I'' N: t 0-
.SS -AN., ZSSI
Hetercc~,rgsnic Compounds, AN a=)
SuBmi i ED: 22jui63 rocu'. OD.:.. SUB CODE: 00,1 GC'
NO R~2 SOV i _0Q6. amot _,JM7-
Lfcl
L

ACCESSION NRs AP4042186 S/0190/64/006/00711251/1255;
;AUTHOR: Korshak, Vo Ve; Frunze, T.-M.; Kurashev, V. V.;
LopatLna, G
;TITLEs- Synthesis of certain polybenzimidazoles with a single or
!mixed single component, and study of their properties
ISOURCE: Vy'*sokomolekulyarny*ye soyedineniyag vo 6, no* 7. 1964g
-1255
1
251
!TOPIC TAGS: copolymer- polybenzim'idazole, Lnfusiblo copolymer,
'insoluble copolymer, heat resistant copolymbr
iABSTRACT: New polybenzimidaz6les with a single-or mixed second
1component. have been-synthesized, and their properties have been.
;studied. These organic-copolymers have an unusually high heat r
a i s t a n c e .PolybenzimLdazoles with a single second component wer:
prepared by polycondensatLon of'3,31-dLaminobenzidine (DAD) with
Idiphenyl eaters of Lsophthalic acid, terephthalic acid,or bis(p- j
The first two polybenzimidazoles
proved to.be infusible and insoluble, The P-containing po~4enzlmLdarole
TF .... ...

ACCESSION NRs AP4042186
N N 0
is also infusible, but dissolves in formic and sulfuric acids, An
attempt to synthesize an F-containing copolymer by polycondensation
,of DAB with the diphanyl aster of perfluoroterephthalic acid failed
as a result of the docomposition of the polycondensation product.
'The thermomechanical curves 'of the synthesized products are given
fin Fig.la of the Enclosure. Polybenzim~dazoles with a mixed second
'compcnentwem prepared from DAB and mixtures of diphanyl este-rs of
il) terephthalic and is.ophthalic acids,'2). sebacic. and isophthalic
.acids, and 3) sebacic and terephth6lic acids. The thermomechanical
curves of some of the products are given in Fig. lb. Polybenzimidazoles
.containing mixed aromatic second components are infusible and ar
. e
~soluble'only with dLfficulty';',their solubility depends on the-compo-
sition ok the'initial mixtures.-'Polybenzimidazoles con'taining.both
aromatic and aliphatic,groups exhibit a better solubility, which
creases with an increase in aliphatic component content*. Prig, art,
has: I figure and 4 tables.#,
4
Ccfr
d

ACCESSION NRz AP4042186*
I!ASSOCIATIONs Inatitui elementoorganicheskikh soyedineniy AN-SSSR7
(Ipstitute of Organoelemental Compounds, AN SSSR),
A
~SUBMITTEDt 25Jul63 ATD PRESS: 3054 ENCL: 01
.;SUB CODEt 00 'NO'REF SOVi 001 OTHERt 004
Card 3/4

-AtCESSION NRI AP4042186 RINCLOSURE: 01
Fig. 1. Thermomachanical properties of:
Ia) polybenzimidazoles prepared- fr-om 3.3'-
diaminobenzidine and diphenyl'eaters of
inophthalic (1) and tore.phthalic (2)' acids
-p-carboxyphenyl)methylphosphine ox-
or bis(
ide
'(3); b) polybenzimidazoles, prepared.
from 3,3-diaminobenzidine and diphenyl'es-
ters of sebacic and terephthalic acids
!Molar ratio of diphenyl aster of sebacie
acid to diphenyl ester of Laophthalic acidt
f
f 1 ?-1.0.-0.0; 2 - 0.8:0.2; 3 - 0.6:0.4;
0.5:0.5; 5 0'.4:0.6; 6'- 0.2o.0.8;,
.4
W" armI I
7 0 0: 1. 0.
Temperature, IC
-4/ 4*
Caed

i
ACCESSION NR: A P4043775 8/0190/84/006/008/1394/1397
AUTHOR- Korshak.. V-.V., Manucharova, I. F., Frunts, T. M., Xurstahev, V. V.
TITLE: Investigation of the thermal stability of some homogeneous and mixed polybes-
zimidazoles by the method of differential thermal analysis
SOURCE: Vy*sokomo1ekulyarny*ye soyefteniya, v. 6, no. 8, 1964, ~394-2397
TOPIC TAGS: thermal stability, polybenzimidazole, differential thermal. analysis, mizad
polymer, thermogram,
ABSTRACT: Using the gravimetric method described in an earlier paper, the authors
investigated the thermal stability at ten polyboazimidazoles prepared from 3, 3 1-diamino-
the diphenylesters of either bio-(p-carboxyphenyl) methy1pbosphine oxide or
benzidine and
terephthalic, Isophthalic and sebacto acid. The weight lose of the polymers, heated In a,
stream of nitrogen to 560, 600 and 850C, the temperature of Incipient decomposition and
the temperature of ateep weight loss are tabulated. As shown by Fig. 1. in the Enclosule,
all these polymers, especially those of homogenewscompogition, exhibited a hI& degree d
thermal resistance, showing the first signs of decomposition at temperatures between. 400
and 520C. The relationships botwom thermal behavior and polymer oompositim "are
or

ACCESSION NR: AP4043775
discussed at length. Orig. art. has: I table and 2 figures.
ASSOCIATION: Affiliation: . Institut elementoorianicheskikh moyedinedy AN SM (Institute
of Organometallic Compounds, AN SSSR); Institut obah6hey i neorganiolmiskoy kbimff
imeni Kurnakova AN SSSR (Institute of General and Inorganic Chemistry, AN SSSR)
SUBMITTED: 25JuI63 ENCL: 01
OTIMRs 001
SUB CODE: OC NO REF SOV: 003'
213

ACCESSION-NR.-AP4043775--
F-A
a
Aciars
cc
d
time
1. nerinogram for polybenzimidazole abWned trom 3,31-'diaminobanxidine
./3 sW the diphanyl aster of.- a. sebaclo acid; b. lsophUiallo aold; c. torephthaHe
add; d. bis-(p-alLr~xypbmyl)-mothylphosphine oidde.
ENCLOSURE: 01

ACCESSION NR: AP4043776 S/0190/64/006/008/1398/1402
AUTHOR: Sladkov, A. M., Korshak, V. V. , Makhsumov, A. G.
TITLE: Synthesis and Investigation of the properties of polyesters containing triple
boWs in the chain. Polycondensation of acetylene glycols with dicarboxylic acids
SOURCE: Vy*sokomoWwIyarny*ye soyedinentya, v. 6, no. 8, 1964, 1398-1A02
TOPIC TAGS:. polyester, acetylene, polyacetylene, acetylene glycol, dicarboxylic acid,
polycondensation, polyrrier physical property
I
ABSTRACT: Polyhexadfeneisophthal ate, polybutenephthalate, polybutynephilial ate. polyp
butyncisophthalate, poly:iexadioneterophthalate, polybutynomalcato, polybut(!nemaleate,
polybutenesuceinate, polybutynesuccinate, and polybutenefumarate were prepared by the
classical condensation of acetylene glycols with the chloroanhydrides of dicarboxylic acids,
to supplement the results of a previous study in which similar polymers were obtained by
polydehydrocondensation with oxidation. The melting point, yield, molecular weight,
solubility, empirical formula of the monomer and elemental analysis, found ve calculated,
are tabulated, as well as the infrared spectra of the polymers. The synthevis of 2,4-
hexadienediol-1, 6 and the polycondensation of butynediol with succinic anhydride, butynediol
Card 1/2

ACCESSION NR: AP4043776
with isophthalylehlorlds. 2, 4-hexadienediol-1. 6 with isophthalylehloride and
butenediol-1,4 with fumaric acid are d(iscribed In detail. Thermomechanical curves
(relative elongation vs. temperature) of the polymers are presented and discussed.
Orig. art. has: 3 tables and 1 figure
ASSOCIATION: Institut elementoorganicheakikh noyedineniy AN SSSR (Institute Of
Organometallic Compounds, AN SSSR).
SUBMIWED: 08Aug63
NO ]REP SOV: 001
Card2/2

ACCESSION NR: AP4043777 S/0190/64/006,(008/1403/1406
AUTHOR: Vinogradova, S. V., Korshak, V. V., Salazldn, S. N., Bereza, S. V.
TITLE: Heterocyclic polyesters. LX. Polyarylates based on Phonolphtlialein anilido
SOURCE: Vy*sokomolekulyarny*yo soyedineniya, v. 6, no. 8i 1964, 1403-1406
'OPIC TAGS: polyester, polyaryla to, phenolphthalein, phenolpbthaloin anflide, heterocyclic,
polyester
ABSTRACT: Using their method of equilibrium condensation described in Vy"ookomolcitu-
lyarny*ye soyedineniya 4, 339, 1962, with chlorodiphonyl In place or ditoly1methano as the
solvent, the auth6rs prepared polyarylates 6f 4,41-diplionyldlbarboxylic, torephth.-dic,
isophthalic, diphenic, fumario and sebaclo acids with phenolphtlialcin anilide as the base.
The phenolphthalein anilide was prepared by a procedure described by Albert [Berichte der
deutschen chemischen Gesellschaft, 26, 3077, 1893); and technique of interphaso polycon- i
densation, which was also employed consisted of 1. adding a 0. 1 benzene tolution of chloro-"
anhydride of the dicarboxylic acid to a 0. 1 al7kallne solutlon of phenolphthalein anillde,
containing 0. 9-1. 0% of nekal, 2. thoroughly mixing-for 20 min, and 3. precipitating the
polymer with methanol, washing with methanol and hot water and drying in a vacuum at 80C,
Cardl/2

m=a 10'a
r7v~,. S, V, Korsha:K, V.
.-iAk7iu~.;jjaw p-i~msWrs. XLI- SV11thCE3i!3 d T)h-Tl1ll~-)llf"-flfM j, iliric' Dolv~rrvllafpm
d,
M,

~-M;' Egg
ga'M
'71

2
I 4a af polyethers
iby oxidative polydehydracondenga-
o ro o a rq vil ct a 1 9
-vnmcleKtj~ varnylkye govvdineni
jotyether, dipropargyl acetal, nxld;3t~ve rclyleh7drocon-
ABSTPAC': Communication IV of the series "Synthests and s:udy of
of polymera with acetylenic bonds in the backbone"
--.a~ certAin new dipropargyl aCetals have Veen and
~l n evt Vve of polyether, c e i rt v-i I ve d
e

L 2 13 3 G-W, 5-
A C r--E S ~7 10 N 14 R - AP40454:13
and the monopropargyl neet al Acid cata I-is tz we -P u,~ied Th e
F~ r e
con F1 rmed by clamental Anal vq I , -L, .4 q "n
:)r. .:F 'lie ul-IsCaLalti vio2e JA 0'ubld
,. L qopp plex form,,
__~r com Or( iz rt
rm u Ia s
..Atitut elementaorganicheskikh
4 1) R F F 9 CIV

'K
--p-.er x P.
'A -.,- T-. -3
-=jlex pi-cpargy i uenzc ate,
mr-t~. d~-,henvxylilexs-diyne, acetylenic polyestter
q ild v 2 s h ovn t h P p o;t A j;7a n
L e eopp-er complexeG, these CoMpOuDds vere 9-ftleettd to oxidsti'ie
on b-f t re D t me n t f

E aber
a n;i rerl!ixing of the mixture for 3--5. nr. Dark-brovin
-~5c~ Li Lroducts containirg
T he i r
typic.%!_ )-bound copper vith no
narrov Siznal In any- case. TR spectra vere
7 aa made-

FdT(I )/EPA (s)-2/EWG(k)/EVfT(m)/EPF !/T Pr --A -6/pr 4 lp~c_
P 4 0 42 15
Sonin, ;I
Inlydispersi-y and chain structure of polyphenyliethylene
VY69okomolekulyjrny*ye soyedinaniya, v. 6, no. 0, 1964,
&ad top half of insert facing p. 1850
,TOPIC TAGSt polydisps ity, chain structure, polyphenylitethylane,
samiconductoi,vKractionation. molecular weight, ntrinstc
a2miconducting polymer
A study hits been made of the fractional compo!ition of
1 ne rhy I ene ,* PF,i) and o f the re 1. a ti oils t, i p 'D c ,we e; che mo Ile-
(M) and the intrinsic viscosit-I [,I) of ~rac a t 0 d
d Ib n, v ~I
'),-19 P re V a re d PPM va 9 f r aonC
!,-Jd~,ion of' a nonsolvenc. The in t r1
-i ; gn[ were- determined for aazh L J L C
a howed cont iderab 1e polydisperai ty when Llr- Mw/?ii r a t I op

n 'I - 3. 9 3 10 M
a Ac
the exponent of M r i~
in loose macromoleculaz- oa:ktng,
was assumed to result
0 a f irmad by x-iay pa tterng 3nd a the rmnme ~-han I ca c,-i re
~ , -- ". MI.

N R AP4047215
che absencis of crystallivity and high-ela~tic deftrmation,
it. hasi 4 figures, 1 table, and 3 formutasi
:,351:CIAIIORI Inatitut elementoorganicheskikh aoyedineniy V SSSR
of Organaelamental Compounda, AN 889P.).
i L3Dec63 ATD PRESSt 3119 e M C L T00
m0 REV "A"
'LCQ0

j
i(Y~p YOV
in ber7jjjkm fc,].ys.3jxt.,?Y"
6 nooUtj~)8,7.~i,~
K 18:21)
In 8 e lezn ar toorgwn 1 oh eak lkh ,,oyeci jre.11 All

I
TD10FEYEVAP G.I.) DUBROMA, L,Vv; KORSHAK, V.V.; PAVLOVA, S,A,
~ ~ ~'! -
VIscosimetric properties of polyarylates. Vyaokom. soed. 6
no.UM08-2010 N 164 (MIRA 2W)
MolecUar weight clistribution of polyarylates, lbideaZOU-201-lo.
1. Thstitut elementoorganicheakillch soyadinenly AN SSSF.

7
V, V: nc~radova, S L a v Y'. A.,
-does in the -ield of coordinat- on- ?c T;w s 22. 7. v,2 z-.s 1 c Ie
c -: P,,~ I yTne r i (-- i)eryllium compexes w s L e .5 So L I C, r.
'ysokomoIekuiyarnyye soyed~nen;-ya, v.
coordination polymer, ~e_U1,1.,L-n ~ommp,ex, compound,
'e"Ic Del,
0 "Y-T y' lium intracomple.--cas w,~.'. t y, ) d 1111 e r'. y
-_tw
c, r i c a' -)repar,~G Iby a
I a
0 )c
e ?'D!yT'Icr3 Werr',! I
7. 70
r,:i,: n ae t-n a ne
M for 6 _.-.i a r a -Tra
-G W~ ch GOI 13" e
C U y a r n yy esoyedinineniya v. 6, ;2~,. 4e': sc.-Iama ZO,

L 2'2"g-65
ACCES~10N IMP: AP5001479
:.-.e -versible formatior of cyclic oligomers from intracomplex ber 11.1lium Polymers
OrIg. art. has: 3 tables, 5 figures and 3 for-m-i-as.
-,N,: 7-nsti -,ut Eilementoorganicheski& soyed"nenj7 AN SSSR -rstitute for
ganic Compounds, AS SSSR)
7: ED: 06Feb64 ENCL: GO S'~*B OGDZ OC
NO RE--- SOV: 003 OTHER: 001
Corc 2/2

?c-V?r-L
AP5001482 s/o,Lgo/64 'o,,)611,-, 2/2174/2.7T
Korshak V. V.- Vinoeradova, S. V.; Antonova-Ant.pova, 1. Po
tj
t, ~' - ;- z c L e r-, zr, e,-- ia rb -
---C-~ed polysiryl carbonatesi!based on
oxyiic acid
SOURCE: Vysokomolakulyarayye 6oyed~reniya, v. 6, no. 12, 1964, 2IT4-
21T7
TOPIC -AGS: polyaryl carbonate, colored polyaryl carbona-;e,homo-
polLymeric polyaryl carbonate, mixed polyaryl carbonate
7: Colored pol.yaryl esters based on 4,4'-azcberzen?dicarboxy!ic
q,m-A hrtve been prepared by equilibrium or by interfacal D.clycon-
Homopolymeric polyaryl esters were syrthes'.zel from
b'spne-io., A, -,ydrc-
-7,zenedicarbonyl h1oride and phenolpht", .
-I zed -T
r resorc i no.'. .Mixed polyary! esters vire syntre., I rom
HOMOP617M
Card 1/2

ACCESSION NR: AP5001482
chloride and bisphenol A or resorcinol were crystniline. All other
c1imeric and mixed poly&ryl esters were araorr~hous. omopo I ymeric
and mixed polyaryl esters based an phenolphthalein have hJgh softening
T 7 a tr e 6 ( 2 5 0 - 3 5 0Some p.31yary' esters based on azo-
-arboxyll'c actd, phenolphthalein, and
.5*n.c,) had a softening point of UUC ne, disqo,ve
n organic solvents and form strong-cr, lore-! ',rans;arent 11--ris
Orig. art. has: 4 tables.
-.)ye~i-eniy AN SSSR
N: institut elementoorgnnicheukik~
of I'leteroorganic CompoundE,0AN SSSF
2' Feb64 ENCL: 00 C-
~cv 007 OTHEP: 002 ATD PPFSS 3171
Card 2/2

S/0061/64/0001007/12'8111288
A.CCESSION NR-. AP4042675
AUTHOR: Korshq~#,_Yo Kr6n9'4U9j 8, Berlin,, A,, H.; GribkovAq
She na, Y
P. N.; eq
~iTITLEt 'Synthesis-of polymers fdr the.polycyclization reaction.
.i Communication 1* ~Polypyr.azoles
SOURCE:- AN 555R. Izvestiya,, Seriya khimicheskaya, no. 7j 1964#
J. 1281-1288
'TOPIC TAGS; polymer, heat res-Is.tant polymer,'polyhydrazone,*poly-
.
.pyrazole. bis-(0-diketone), dicarboxylic acid dihydrazide, poly-.,
cyclization reaction, pplypyrazole. stru'cture polypyrazole prope ~ty
,ABSTRACTt Polymers containing-pyrazole rings have been synthesized'
Jn an attempt to produce.new-polyme~ric materials with improved heat
cal stability. Polypyrlazoles were syuth
-resistance and che mi eaLzed
from bia-0-diketones) of.the R'C0C112M-,R-C0CH2C0R' type and dihydra-'
zides of dicarboxylic acids& The reaction, designated as polycycliza-
tion, proceeds Lu two stepus', formation of polyhydrazones by the
reaction o-f the c,arbonyl oxyjdn'..,of.~he katone'vith the and amine.
Cc.-rd* I I if 3'

Lnr)gr&dova, S. V vili, !~Fir-g
p, I P, 1, - T. ~W~ ly vn 1 'A te,9
yu I l2e8-1292
Li ClIa g k&
khir , no, 7,
;-,~ymidoarjlaUe, structum, pbospborus
al
-7~1 t,-- bLc~(,k-, polyamide 'block,
!ne stT-acture of polyamidourylatea prepax d fnum bls(p-caxbwq~,I)-
antine ox-ids or sebacic acid v-itb diane and (1:0-5:0-
The viocosity Ln tricresol
e pol-y-cor.,lensation cbaugeed on heattoLA,
~1' L~~ -V!ll el~A rrkpid ly ','A rtn-~~ ti-eatiag, then
~n vrrlimgv-.d vere flruvn.
"Itri

ripe Ap4o42876
IN ned. -iluBl ?olzaryla"a obt&J,-,-d b7 lrt,~-PtL3be pollcondensatim
ta L
wleaular
.1g, az'-. hag: 2 figurea and
3
i'nstftut 11--mentoorganicbeakikh Akp-Amii anuk 88a
L: Oo

S
ACCESSICIN NH: AP"28n
AVMOR*. Norshak# V, Vej Vinograftyap' So Vo; Wu, Vang-yuan
TITIE: Heterochain polyesters Commmication 51s Folymidoarylates and pollaryl
iatea based on the chloraubldride of bia(p-carboxy&enyl)methylpbosphine oxidee
SOURCE: AN SSSR. Izventiya. Sorlya- khimiabeaksya, no. Tp 1964, 1292-1295
-TOPIC TAGS: Beterochain polyeatei~s polyamid6arylatep polyw7late, phosphorus
'containing polyestert synthesist Interphase polycondensation, solution polyconde4- A
cation.. thermally reactive polyarylatat softening temperaturej viscosity.. crystaU-'
Iluity, lincar polymerj, self ext shing polymer
-carboxyphenyl
'ABSTRACT-. Polyamidow7lateD based oia the chloranhydride of bia(p
methylphoaphine oxidle,, diatomid phenols (diane j reeorcinolp, dially1diane) and
i diaminea (hexamethylenediaminej m-phanylenediamine.. p4perazine) were syntbenited
lp~by the interpluwa polycondensation method* rolyaz7latea based on the chlorwhy
-drides of bis(p-cartoxyphenyl -matbylphoophlne oxide# of terephthaliej, isophthalic
or sebacic acids and phenola diane$- resortinolp hydroquinone) wore aypt~wsized by:
equilibrium. polycondennation in bi& boiling colywto A themaUy reactim
[Ca,d 1/2
- - -------------I------
Card

'I'T'P/T P'-' ipr
N R A 1 4 0 4 0 0 C) 0 r! '0 0 2 q f 13 0 2
Vinograd-ova, S. V. K
d hlc_~r pa!ya_Eylates
"O!vegters C~')Olk
f :70xv' J,
-ne ;~xde, dihydric L~i e 7d i ~t'
I
--%Arides
AN SSSR. lzvt:siya. 64, 1296-13U2
)xide, dihydric
DO
tr,.-thyiene gly-
'11~ dH_)O-%I
A C- T Wxed block polyarylates tliasp.j ~r-, po E- x 14e 4 P E 0) 0 f d I f -
p ~r xelghr,:~ (,)r rh- or triethvlene diane, !~~droqumone,
fti~11.1'~Jj.%":Iic~.7 --tnd ~,ie 1, qnEl- ~alic or tere h-
L
220C for 7 nouL's, precipitatmg
Card 3

3 11-10 49 7 8
ing anU4 Q y n a T- rea c t i on
17f, d The erfect of structure and z7a,~u
001 va rv late werp qtudied The hvdroquil -one-terepiitfia-
ternperaturc (even witki 30-45im'
c.,.d 2/3

L 16664-65
ACCESSION NR: AP4042878
thc. 1~irqpr th earnount of PFO that rr. A vh.~ ~:,it
!.-If. Pj-r duct Still does !lot Mp"t t3. .-P Q-mme weight
-he melting ternperiturc~ at .)u, 18o (jr
brig a rt. haR 3 fiqij -F- Q
Institut ekimentoorvanicheskikh sove-i"r"-niv SSS R
Zr~e- ,,A ~,ZQW
ri-metallic Compounds, Acadernv
'~T i~MTTTED- 12Dec62 ENCL- 00
SUB CODE: GCj OG NO REF SOV: 001 OTHER: 0('0
Card 3/3

ACCESSION NR: AP40~8153 S/0291/64/000/001/0067/0070
.AUTHOR. Korshak. V. V.; Sladkov, A. M.; Makhsumov, A. G.
TITLE: Synthesis and investigation of properties of polyesters containing -triple:
bonds in the chain. Communication 2. Production of polyesters by the,
oxidative dehydropolycondensation reaction
SOURCE: Uzbekskiy khimicheskiy zhurn no. 1, 1964,,67-70
TOPIC TAGS: dipropargyl eater,,' dipropargyl polyester, ace~ylenic
polyester, dipropargyi isophthalate, dipropargyl succinate, dipropargyl maleatel,
IR spectra, mpitincr Doint. softening temperature, heat iisistance, oxida-
tive hydropolycondens at Lon
ABSTRACT: Several new dipropargyl esters and polyesters were iynthesized.
Dipropargyl terephthalate, oxalate, isophthalate, succinate and maleate (the
last thr'ee compounds have not been reported in the literature) were prepared by
reaction of propargyl alcohol and the appropriaie acid anhydride. The dipropar-,
LTV1
were, then prepared by oxidative dehydropolycondensation in' the

ACCESSION NR: AP4028153
presence of copper acetate in pyridine and methanol solutionsby tow
'I f lu)dng for 20 hours*- Pouring-* the product Into cold water, and filtering
the black polymer, which 'is formed according to the reactions
cut,
nHC=C %C-0-0-R-~~O-CHI-CmCH--`-,
0 0
-o- [-7CmC-.tCH2-0.-C-R-.C-0-CH2-~-CpaCis
0 0
IR spectra of the polymers show C- C, C-0, C=O and C-O-C groups and the
absence,of the aC-H group. The polymers have high softening temperatures and!
high thermal stability (fig. 1). Orig. art. has: 2 tables, I figure and I equation
ASSOGIAT
SSRICKi Institut khimii polymerov AN UzSSR (Institute of po~jmer Cheid t
AN Uz
1 SUB=EDs 24MaY63 DAT3 AGQs '29Apr64 WeLs 01
SUB GMSs OC NO RM SOVs 003 mrall 005
L5~rd. 2/3 ATD PR=t 3o44

ACCESSION NRt AP4028153 9NCLOSURgs 01
.7
too
JV - 4
Ivo a .509' -.Vo-
Fige I* Synthesis and'investigation of poly4~ster properties-
1 - Dipropaigyloxalate polymer; 2'- dipropargylmalesto poly-
mer; 3 - dipropargyltordphthalate polymer;,4 - dipropargyl-
soccinate polymeiz; S.- dioropargy1isophthalato polymer-
Card 3/3*

s, "s v A r P,
phooph ine-borane complex, Py re-, 1-711 -1
S 'S S R z-.-e si y a S e ri ya kh Am i C h a &'k Ot v an n t 1541-
plienylphosphine borane complex, (phenylphosphino)borane a
fiorFtant c polymer , boron contain ing pol y-ete phosphorous
PC, I Y"'V r
a " re p a re a homn R e n e o u z tr 1 no n 9 ion n I ne t -
MP I e W, .1 1
d
pheny I v -I i lie
f h i 9 prob a Iv ii i~ e& t. i i j
t s 0 h 6
I
wr t h a awoun to i
1 in d t h e I fne 6 r I r ga er i~ Ti a
c c o zr, &,n i '. db vd eFOP d5 t n n -
2

L ~-14 N R AP4044710
!creases vith ton-Paratum, i"-wfitch re-ivAti in the SpIttting dff,bf
;nd the form&tlolp of of
in qtr, The pyrolvato in asgumal !0 ir5caed as follOwSt
1 fnr%,jlj2 and I table.
k, L ix ffi i. n t &I
T

K~3711 11 F), -i.V,., "U."VP, TI.Ye.; GOGUfiJ)'AE?
?p To' . A, . - FC),',,'] N , A ~ 7 .
Stabilizition of water-logged by means of suat-lal copolymers
cf tl-~o --ir7r.vlin series. Plast.massy, no-10:40-44 t64.
(MIRA 1793.0)
I

4
Kcrsn.,kK
AR SSSR lzvestiya. S e r i y a k hn i c h csn,
TOPIC TAGS- poly e the r.-, - Aip~toipar gyl-~ -eth e r, oxidative polp-
hvdrocondensation
New dipropargyl etbers of
1- )X rl
thalene, alizarin, and quin'Larin nave -Been 5vnthesized
.:v mer sprepared therefrom by oxidative pccly'Lhycrocondennation
c fco-oper saits. e a
r:z,. n 1~ V
a g', h e ~i r c x
c c: 0 r.QH at 70-80C. The aioncc-nerG were identified by
Card 1/2

ACCESSION 11R: AP4047407
-7, --troscony anic4 elemental analys i!i 0 1 r F1 -1 CS e
9 e x e c t e I
ontain complex-, r-z r
t rl,~ than t~ e other two pc lye ig a r t .1i u
and I figire,
~.--SOCIATION: Institut elementoorganicheakikh soyedineriy Akademit
SSSR (Institute of Organoelemental Com?otL ~df; A c-a c Smy o
- e S S S -S -i T .- - - -
I T T E D05Mar64
SUB CODE: OC, GC
ATD PRESS: 3 125
NO REF SOV: 004
EN C 00
OTHER: 000
Card 2/2

7 4 C, 7408 ;o. Q r~
77, -1 v t 9 e V~ YU-_, P._: ~1-adknv, A. r s n k
e v d e h d T c c- n e r. -1
e 11 C e 0 f
z v
e X,
i c v v a e v a q a r r 1, 0 i:j
n 13 1 c a s e a the p -9 u a ~.ic
Cord 1 2

~ - - e -71 -.
ACCZSSION NR: AP4047408
were the end groups t
C EE C - C m C- C C C m C A.
the cace c-f acetylene and p-nitrrphe-nyl acetylene only
ro~i-1hen . 01.) t a I lie T*,-.1 f
1 b i..i tad i ene'lv aq
r -n 1) 1 A 9
goyedineniN Akademii
-.1014: Institut elementoorganicheskikh
T r q t i tu te o f Organoe I emen t a I Co oun d s , A ca de"T v 0 f
SLIBMT7-ED: 09Mar64 ATD PRESS: 3126 ENCI go
NO REF SOV: 003 001
F GC OTHE R
ca,d 2 2

~7
I /EPF (c /ZFR/FWP (j /T VPt-in Rn
S /0 062 16 41 C C /C I 11 Oh 21 o6
Frunze, T. M.; 1 zy *neyev
.,Yc,,,cA' i zat ion react ions r t,)e
e r. zm i d a z o I ee s t c r e C r 5
S O'~; PL AN SSSR Izvestiya Seriyl khimichesKaya, nu.
21OL-2io6
T 0 P IC TA G 5polyesterification, polycyclization , copolymer, mixed
copolymer
-STFA -olyesterificat~on and polycyclization 7,ave beer. used si-
r,~.Altane,-,us -'y for the -,rrparation of poly( benzimi dazole ester I ) and
poly(beLLimidazole ami,i,7i ~II). Copolymer I
N
(CHI)ICO