SCIENTIFIC ABSTRACT KOSSOWSKI, S. - KOST, A.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000825130010-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

S tan islaw; G I EI, D A I Jerz-1 - 7, 1
Senile doafness und Ue u,,i,3 (.)f wit%min
Fol. 18 no.3.'335-340 I U.
I . Z Kl i 1- 1. C-to I aryxi gol o g i c. v, n e j Aji 'I d em 11 M e a yZ?~ 'w 1~a wl I,
7 Zalk ll--~ J~J Tt,, Z
(Kierovmik: prof. dr. W. Janku.,%O-t
AkadeTaii Medycmej wo 11-1roclawiu (KJ

I KMSOWSKI, Stan4slaw; AGOPSOW-ICZ, Gr7ecc;~i;,,, ."c-
1- ~.~ -,7~ 1
Use of Polyester fabri cs in Eyrie~ t operti-ti, on. -, --- ". .- -
18 no.3.,433-434 16.1.
1. Z Khniki Oto1CLI.'Yr.9olr-,9iCZnej Ak.hcklaIi ~:c-
law-Ju. (Kierownik: prof. dr. W. Jarikowsk-.Q.

KOSSOWSKI. Stanisl GIELDANOWSKI, Jer,,,,y; ZIFMKI, Zbigniew
.
Aging of the organ of hearing ,:tcc,,)rding to the WrocIM moclification
of Feldmann's test. Otolaryng. Pol. 18 no.109-46 164.
1. Z Kliniki Otolax7ngologicznej Akademii Medyczriej we Wroclawlu
(Kierownikr Prof. dr W. Jankownki) i z Zakladu Farmakologii
Akademii Medycznej we Wroclawiv (Kierownik: prof. dr J. Hano).

KOSSOWSKI, S.; AGOPS(VICZ, G.
The Importance of tho antJbiolirwn In illnefivorn caused by
Klebsiella. Cesk. otolaryng. 14 no.L.'40-44 F165.
I. Otolaryn,-ologicka klir-lkn A.1,!. vo Wroclawi (predno.,-,ta:
Prof. dr. 1-1. Jankowski). I.

KOSSOWSKI, Stanislaw; GIEWANOUSKIO Jerzy; ZILMKI, Zbigniev
Audiometric localization of injuries of the central auditory
tracts. Otolaryng. Pol. 19 no.2t163-168 165.
1. Z Kliniki Otolaryngologicznej Akademii Medycznej we Vroc-
lawiu (Kierowniks prof. dr. V. Jankcewski) i z Zakladu Far-
makologii Akademli Medycznej we Wroclawiu (Kierowniks prof.
dr. J. Hano).

PILOCIENNIK, Zygmunt, inz.;_KOSS,OWSKI, Wladyslaw, inz.
Transportable apparatus for testing and controlling installations
of central heating during the summer. Gosp paliw 11 Special
issue no.(95):5-8 Ja 163.
1. Ministerstwo Gospodarki Komunalnej, I%Tydzial Ci(-plowni3twa,
Warszawa (for Plociennik). 2. MiejskiEt Przedslebiorstwo
Instalacyjne, Warszawa (for Kossowski).

WOJEWSKI, Alfons; KOSSOWSKI, Wcjciech
&kperlmontal urinary calculi, Fol. tygr. lek. 18 noo46:1717-
1720 11 N163
1. Z Kliniki Urologicznej FM w Szczecinie; kierowniki doc.
dr. A. Wojewski,

KOSSOT, A.
Nature and role of cooperation during the period of the transition
from capitalism to socialism. Vop. ekon. no.2t82-92 F 163.
(MIFLA 160)
(Cooperat;ion)
I I
I

Is it a proper way to interpret Important theorL-tic pr*1ems
("Main problems of the political. economy of socialism in V-1.
Lenin's work by N.D. Koleaw and others. Reviewed by k. K-)ssoi).
Vop. ekin. no.8:142-146 Ag 161., 04IRA 14:7)
(Economics) (Lenin, Vladimir Wich, 18?0-1924)
(Kolesov, N.D.) (Grigor"ev P.G.) (Feshekhonov, V.A.)
(Pliner, M.D.) (Raud, V.M.~ (Fedorova, L.P.)
M~Iykov:5kaia, E.A.)

aGADKOV, I.A., doktor ekon.nsuk;.K0SSqj,ji,J.,. kand.ekon.nauk; GORBUNOV,
R.P., nauchnyy sotrudnik; YAKOTTSET-1WIT, T.N., kand.ekon.nauk;
ORLOV, B.P., kand.ekon.nauk; DIKHTYAR, G.A., kand.ekon.nauk;
DITACHMO, V.P.; PAVLOV, K.P.. kanft.ekoninauk; CHEBOTARET, V.A*o
nauchnyy sotrudnik; BAKOVETSKATA, V.S., red.itd-va; GOLUB', S.P.,
tekhn.red..
[The Soviet national economy, 1991-1.9251 Sovetskoe narodnoe kho-
ziaistvo v 1921-1923 gg. Moskva, 1()60. 558 p. (MMA 13:3)
1. Akademiya nauk SSSR. Institut skonomiki. 2. Chlen-korrespondent
AN SSSR (for D'yachenko).
(Russia-3conomio condi*V*ions)

GLADEOV, I.A., doktor ekon. nauh; KQZSOT., Aj., kand. ekon. nauk;
VIDOEOVIV S.S., nauchn. sotr.; SNMOYLOVA, I.D., naucIm. sotr.;
GOR13111-4-OV, E.P., kand. elor. naWc; HAMMY, I.V., doktor
ekonov. nvWqCHBIkTAI(E,V.A.j kandt. okon. nauk; KAIAUSHER,
L.N., nauchn. sotr.; STROYEVA, Z.N., nauchn. sotr.; FOMDA,
L.V., nauchn. sotr.; VOLZOBIYEV, Yu.F., kand. ekon. nauk;
KRAYEV, M.A., doktor elcon. 'nauk; KAT'LINSKIY, Ye.M., kand.
elcon. nau1c; LAPINA, S.N., nauchn. sotr.; YAKOV'TSEVSKIY, V.N.~
kand. ekon. nauk; OHLOV, B.P., Icand, okon. nauk; DIKITTYAR,
G.A., doktor ekon. nauk Ideceaged],- PWITIMOV, K.11.;
MALIKOVA, A.I., nauchn. sotr.; TOV1110SYMI, MYe., red.iza-va;
POLYAKOVA) T.V.) tekhn. red.
[Socialist national economy of the U.S.S.R. in 1933 to 19401
Sot siali stiche skoe narodnoe kho ziais-wo SSSR v 1933-1940 gg.
Moskva, Izd-vo AN SSSR, 1963. 663 p. (MA 16:12)
1. Akader.iya nauk SSSR. Institut ekonomiki. 2. Sektor istori-i
narodnogo khozyaystva Instituta ekonoriki AR SSSR (for
Stroyeka Fomina, Kaplinskiy, Lapina). 3. Chlen-korrespondent
A24 SSSR ~for Plotnikov).
(Russia-Economic conditions)

KOSSOY, AX ~
"Problems of state capitaliam during the transition period from
capitalism to,aocialism" by A.4.Seid-Gu9einov,-,"- State capitalism
in the U.S.S.R. durirg the transition period from capitalism to
socialism" by I,D.Brin. Reviewed by AJossoi. Top. ekCn. no,12:
121-130 D 160. (MIRA 13:3.2)
(Comaninist countries-3conomic policy)
(Brin. 1.D.)

USSR/Chemical Technology Chemical Products and 'Their Application.
Products. Cellulose and. Its Manufacture.
Abst Journal: Referat Zhur - Xhimiya, No 19, 1956, 63369
Author: Kossoy, A. S.-
Institution: None
Wood Chemistry
Paper, 1-23
Title: Water Hydrolysis of Wood as the Preliminary Stage of Sulfate Cooking
of Birch Wood Viscose Cellulose
OrJg inal
Periodical: Tr. Leningr. tekhnol. in-ta im. V. M. Molotova, 1955, No 3, 44-53
Abstract: As optimal conditions of preliminary hydrolysis which ensure maximum
preservation of cellulose (C) with concomitant passing into solution
of greatest possible amount of hemicelluloses (EC), is recommended a
treatment of chips with water at 1800 for 15-30 minutes. On such a
treatment more than 13% of pentosan (P) are removed, while losses of
C amount to 3.6% of the weight of the wood. Bleached C obtained after
preliminary hydrolysis contains (in %%): a-cellulose 94,5-94-7. P
3.6-4.14, lignin 0.35-0-38, ash 0.16-0-30; yield of bleached C
Card 1/2
,USSR/Chemical Technology - Chemical Products and Their Application. Wood Chemistry
Products. Cellulose and Its Manufacture. Paper, 1-23
Abst Journal: Referat Zhur - Xhimiya, No 19, 1956, 63369
Abstract: 33.2-33.5%. After addttional invernion the hydrolyzate contains
-15% HC on the basis of initial wood or,-0.45 t per one t of C, and
can be used for the production of food or feed yeast.
Card 2/2

KOSSOY, A.S., kand. tekhn. nauk
Chemical woodpulp for newsprint and hanging paper. Bum. prom.
37 no.7:3-7 J1162. (MIRA 17:2)
1. Leningradskiy tekhnologichaskiy institut tsellyulozno-
bumazhnoy pronyshlennosti.

XOSSOY, A.b/.,"kand.tekhn.uauk, dots.
Ch6mfical pulp from wood chips* Buri.prom. 33 no.10:6-9 0 '58.
(MIRA 11:11)
1, Le aIingradakiy tekhnologichsakij, inatitut.
(Woodpulp)

GUBERNSKAYA, L.T., red.; KOSSGY, I.S., red.; EYDLIN, I.Ya.,
red.; YAKUBOVICH, S.Z.j red.
[New developments in woodpulp and paper production; from
reports delivered by British and knerican experi,3 on
January 26 1962 in the State Committee of the Council of
Ministers of the U.S.S.R. on Research Coordination] 1`0voe
v tselliulozno-bwvazhnom prciizvodstve; po dokladar,
angliiskikh i amerikanskikb spetsiE.listov 26 ianvaria
1962 g. v Gosudarstvennom komitete Sovete Ministrov SSSR
po koordinatsii nauchno-issledovatc,11skikh rabot. Moskva,
1962. 89 p. (MIRA 17:9)
1. Moscow. TSentrallnyy institut tokhnicbeekay informatsii
i okonomicheskikh issledovaniy po leancy, bumazhno7 i do-
revoobrabatyvayushchey promyshlennosti.

JOSSOY, A.S., kand.tekhn.nauk
Use of lumbering wastes for the manufacture of fibrous semi-
finished products. Bam.prom. 38 no.lt29-30 Ja 163. (MIRA 16:2)
1. Leningradakiy tekhnologicheskiy institut tsellyulozno-
bumazhnoy promyshlennosti.
(Woodpulp) (Lumbering)

BRMOVSKIKH.S.M.Ereviewerl; VIYNBIRG, K.L.; XOSSOY, B.S.; NOLIKEN, M.P,;
RIMIIKOV, M-1. [authors].
Useful manual ("Glass manufacturing plant equipment.' K.L.Veinberg,
B.S.Kossoi. M.P,Nollken, M,I,,Reznikov. Reviewed b7 S.M.Brekhovskikh).
Stek.i ker. 10 no.12:27-29 D 153. (nRA 6:11)
(Glass nunufacture) (Vainberg. K.L.) (Kossoi, B.S.)

NEYEBERG, K.L.; KOSSOYJ B.S NOLIKEN# M.P.; DEZNIXOV, M.I.; KADANER'P N.I.,
f
red. iM--Va:, N.I., tekhn. red,
[Equipment for gliss plants] Oborudovemie stakollrykh zavodov. Pod
red. H.I.Reznikova. lzd.2.p ispr. i dop. Moskvat Gos. izd-vo Ut-
ry po stroit.# arkhit. i stroit. materialam, 1961. 618 pi, -
(MIU' 14:8)
(Glass manufacture-Equipment and supplies)

har.-.
1J r ~ian .Lcce3 Aons,
,10,thi-, M-2,t of of'

311.141611GOG100310011002
ElC4/E235
AUTHOR: Kossoy, 1-1. S., Engineer
TITLE- Expe-rience of Introducing the Process of Electrical
Heat Treatment of t4elded Joints on Steam Piping in
the Cherepet' GRES
PERIODIICAL: Energomashinootroyeniye, 1961, Fo. 3, pp, 28-31
TEXT: In 1958 T 'sMITMASh developed a process for the high-
teiaDerature austenization o,[' weld5 on sLeam pipinL~; under erection
and reoair conditions using induction heating at a frequency of
2 500 cls. The new proces.~,, has considerable advanta,~3es over
heatin.- with electrical muffle furnaces and the even heatin- that
it produced gave very c,,ood metallurGical results. The invo,,,t*.'L[,")a-
tion also showed that power, frequency a..c. has advantages for pipe
weld heating as no special high-frequency convertor is required
and -the welds may be heated by solerivik.1 type inductors operating
at 220 or 370 V. The high frequency portable equipment chat was
used in the Cherepet' GRES is then described. It was based on the
packaged heating equipment Type MP3-1C1(MGZ-l02) of -he
U -1 1 U
Elektropech' Trust tmd consists of a fc-equency changer, a control
Card 1/4

i j/114/61/000/00 VOO)JU02
E194/1i;235
Experience of Introducin- the Process of' Electrical Heat Treatment
of idelded. joints on Steam Piping in the Cherepet' G-U-S
0
kiosk and control panel, a flexible inductor cable and appropriate
extension cables, The frequency changer is Type TTBC-)DO C1500-1
(PVS-100/2500-1) with an output of 100 kW and frequency of 2500
c/s. A number of base plates are provided at different places in
the station on which the frequency chani,;er can be installed. The
flexible conductor is built up of two cores of bare copper laires
grade /Irr(MGG) of 150 Bull cross section contained in a standard
linen fire hose of 51 mia diameter. The inductor is 7.5 M long.
The conductors are clipped together at intervals of about 650 mm.
The extension cables are of similar construction but use rubberized
hose. They are used to connect the inductors to the, control Panel
whon this cannoti be put the job, 111eat insulation consis-
ting of sheet asbestos 15-20 mi." thick i~~l wrapped rourld the Joint
to be heated and the inO-uctor is wound on -this. The inductor and
extension cables are water-cooled. Nuiierous minoc dcsisn foatures
of the equipment are described. Heat treatment wu; first tried on
welds in main pipework in the Turbine roo-u. The internal diameter
Card 2/4

S/114/61/000/003/001/002
E194/E235
Experience of Introducing the Process of Electrical Heat Treatment
of Welded Joints on Steam Piping in the Cherepet' GRES
of the ' e 27 mm and the external 219 mm, the grade of steel
wasIXI& I (lKhl8Nl2T), the heating temperature was 1 075 1 25*G,
the mean rate of heating was 20-22*C per minute, the welds were
maintained at the maximum temperature for one hour and were then
cooled at an average rate of 6-?*C per ninute. Six turns of the
inductor were wound round the weld. The weld temperature was
checked with a thermo-couple. The powe:v consumption was 75-80 kW
during the heating period and maximum temperature was maintained
with an output of 40-45 kW. Immediately after heat treatment the
welds were inspected and found satisfactory. During erection of
the main pipework of bne boiler 75 welded joints were treated~
The station now has a portable high-frequency set which is used
for electrical treatment of steam pipe welds in various parts of
the station during major overhauls. It is possible to treat 2-3
welds per shift. Measurements were made of the bending of steam
pipes during heat treatment of welds. The method of measuring the
pipe displacement is explained and test results are given.
Card 3/4

S/114/61/000/003/001/002
E194/E235
Experience of Introducing the Process of Electrical Heat Treatment
of Welded Joints on Stemi Piping in the Cherepet' GRES
Analysis of the results shows that induction heat treatment of
pipework welds has negligible effects. However, under certain
circumstances additional bending stresses may be set up in the
pipework during the heating process and it would be best to make
the welds whilst the pipework is mounted. on spring type suspensions.
For successful heat treatment the welds should be at a distance of
not less than 1 metre from heavy parts such as flanges, valves and
the like. There are 7 figures and 4 tables.
Card 4/4

inzh.
Experience in using the thermoelectric treatment for the welded
joints of steampipes in the Cherepet Hydroelectric Power Plant.
Energomashinostroenia 7 no.3t28-31 Mr 161. (MrRA 16:8)
.(Induction harderaing)
(Cherepet Hydroelectric Power Station--Steampipes)

KOSSOT. YU. M.11 (Qp:r.Ikiy)
With the railroad workers of an automobile plant. Pat' i put. khoz.
no.3:36-37 Mr 157. (MIRA 10:5)
(Gorkly-Automobile industry)

:~- .- :, S , *- ". (-,-,I
- i /,,-'
I ~, - ,, z
KOSSOY, Yu.H. (g. Gorlkiy).
Automobile chassis for mobile power gem)rators. Pat' i put. khoz,.
no.l:-20 Ja 158. (MIRA UZI)
1. Nachallnik sluzbby Gor1kovskogo avtozavoda.
(Vehicles) (Blectric generators)

XOSSOYs Yu.M, inzh.(Gorlkly)
Characteristics of track mintenance and mpair in industrial
transportation. Zhql.dor.transpe 41 no.12:49-52 D '59-
(MMA 13:4)
(Railroads, Indumtrial)

KOSSOY, Yu.M., inzh.
Industrial railroad transportation should be provided with high
quality equipment and personnel. Zhel.dor.transp. 42 no.10-63-66
0 160, (MIRA 13:10)
1. Sekretart partbyuro zheleznodorozhnogo tsekha Gor1kovskogo avto-
zavoda, g.Gorlkiy,
(Railroads. Industrial)

KOSSOY Yu M inzh. (Gorfkiy)
Organization of track operation, maint(mance and repair of the
induatrial transportation. Zhel. dor. transp. 47 no.1:77-
78 Ja 165. OaRA 18:3)

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A. 11. Terent'ev (Mow" Wait Unir.). Ckm.
06
(U.SS.R.) 17, 1054(1947)(in Russian):. cf. C.A. 41.
IORIA -in unpublislied work of Longinov and Filipptw
19M) it was found that when the No uvd lur
of irsters contains eveti as little a-
'he redi-aiou
0.01% of X the vields of the ales. .]fit, 11 . 111V -00
y
tilt Tellarilon o(NCII(C(hut), Ilse yirld is me *then tilt
No contains 0.1% K. It-Myer. it the atilt. of K is ill.
Clessed. the Viddit riv again " beenine rortrud wilh V;
~91111, 43 K. This is important sincie No Is usuaU:r contaminated
withtracesolK. This study was extendtl to the reduc.
nepropionitn e
tion of Et.NCIIrCH.CN and I-piperidi . . 'I in ,zoo
BuOll by the method of Suter and Ifolfelt (C.A. 28,
Tech. No Pvc 38-M% of the dixtinitic. iture No
51-M% while tech. No with the addn. of V10 K gave
65.9-70k diamine. In the case of HtlNCIIjCHrCS. d
With the piperidyl compd. the yieJds were 42-M%,
48.9-57.2%0 and 48--57%, resp., thus indirAting a sinij.
Wily to tbg results obtained in ester toductiou. The
hish-K No pvc reproducilsk yWds and tended to give
snudIrr anito. of hiSher-builing prioducti (presumably a 00
secondary amines). The Rupe! tochniqtie (Imintediate
steam disin.) gave sloillar results, but was inconvenient zoo
because of the low votatility of the products. G.NLK.
::so
. rM
'A.pil 3
_k tit too
U 5 two 0 vlffjw*"0~20
or It 0 tt It opfit dittitIl man ltxwn 14

0 0 o
X-M
r. 11 R A-A 0-tv- y jo,
4
-00
Syntheses with actrylonittile. V. Preparation of ure-
tham o! I -Wothykmlw-3 4Lmilsoprop gas. A. 11. Ter-
-00
ent'ev and A. N. Kcnt (161mrow State lyniv.). J. Gea.
A. 41. moic) in 30 tv.
f
it() Wall Mated with I/ai toole istm-ij. K'CO" followlA
IPY wltcf unin a 1%mv It-ortned (-ilxmil I..*,,v.). The 111W.,
%-,%tied with kv, wav tn-At"I A.1.1y 111 t/. F,j._
VCI (of On"ally R('#.CCI) in ~Io c,. ststu'lills
At 1`00111 IMP. 14-20 he,. I he m x. 14y" will let' I., t Ike all.
larm extd. with Rto anti tile ofg. m)II q. d '61, to ruch"
The foLlowins esters of (3.di~jkyja p1, ifj"P'-'P)0rdF&1 pus. "Do
:0 Ofid (1-Jidhy14MiM0-J-r,'Pax$ uletka-if) were 1"Ilt]. iii
0 this WAY: EJ 11, 130'. mil, 1.45tkj; 11, i?,
Ih-4 I;rJ-3'. IAIA21, ill., .1,,*
:0 OAAM?' Ho (42 A"'), 4513, t1:' il.IKLI 1:
:,.Ogg
.W (b' 3"' olla I 412N n1a 1.4,577 1--
A 0-91m; ;~W)4 Ill,$ I' I
(M-7 I - 4 7 2-%
1.47&2. dil 0,97dil: 2.mdkyj(ytj,,Aexyj
b, I-
011? 1.4603, at? 1.4723, d:*
I" "fivoth)i f--i.2-1), b;
3'. mV 1.4719. d.10 0.9482. cry%td. 01, manding and in.
31' (froin McOff). C.- M. K'~Aujx'ff Z* 0
to 0
Qj
Ic i :; I - -
li~i I " '. 1 A I M . I L A at I AL k LR6K AL L1T1R4T1,kj~-kS%WKAj N
%soy imoll..
VL &V to Li 'T
in " (v .1 of M j( It it Iq u " In n it vi mD n 1 1.
0 0 0 0 o;* * 0 0 0 0 0 0 0 *.* 0 0 0 0 0 *10 0
*a*** Oi0o a so oie 9 0 0 0 0

0 0
so*- *-9 0
A, I a X L 0 a a Ira I u
IN 30 At n 33 26 'S 36 3? X 39 40 41 0 43 M
ti" Vito -L-A-A-
4-11Z
Q 1,111wivVIIII 1.31surtilva V~a
HIS EF:4
it
so?!
so.-)
0 O:r
so=
so.
r
j 00
so
so-! x,~ Alt. .83- A so
If.?. r cc
In so
I-E-F EX=
log g%~~j FA pff
Joao O.Ow
-T
t- i-t If 0:
11 ca
00
000 a 0 0 00 0 0, Ire,

hi a it a
*tl
it, LAA-1
A V
with* assibils, Vd., 'NsirlIX'Xityl. i-,_ the filtirme'eva P-1j_j__Xd'_;e_Ji.~ g. Orpkhaliwulo.
41100. 0 OFID111111111 Ud NOW# of Its 4011trativirs. A. P. 7- tit. JW$74"j (Iosa'm F1011). Thi% 1,
7WW"i IV. A. N. KtAt, RINI V, M. I,tA&lw)v (Missiew 8fillit -suirdillithOcc. 2111,1. JfCJ 11 hr%., (vuled, filttict jr ) te
0* ~i Vill-). Jr-GO"11101-01N. (U.S.S.R.) 18, N2-410M)On IWItatt'01mrYof C41II(COOVIrellulip), the Otratervapd.
60 Rusilian); d. C.A. 42, 2Wild.-In it systirmalk, study of its somp at 60', thi, dry rc4dup extd. %tilt full all,. Ittoll,
the best metim conditions for Cll#:CtICN (1) and Ph- the cooled rat. tilturd, the Qtralc again rvapd. too WIMP,
00 NEtH interaction, it was founif that the best yields YR aand the tor.Mue &asolved. tit ti parts of Moll, tit. 011111'
06 attained with an exreus of 1, 1 be mill. being hral~ d IN)
hirs. on a steam bath In the presence of AO and hy&o- W. almost (me 44 Inorg. Impurities. Flithalimide (14.7, -00
4-QuIrone. HiShm trinp*. lead to tar. Fe or Ni %tit& &I. X.) hftted to tQ'L Witt treated with g. h).dr"_ 1 -00
if most do not affect the yield, while Cu Ix)wglvr actually quinotic and 6 cc. of MeallbNOll soln., The stimd mixt, .00
09 lowen It; in the presence of EtONa and in the atincrice of it treated over 10-1 !1 M44 wfth W cv~ file serylate and a few
mtsilyst the reaction doc% not proceed at all. use of a little cry~stal& of Isydrequinotiv, sitnuhauctiusly ittith 10- 0, cc.
0 116SOO at IlW fives a vay jXX* yield. HCI is not a of fiftaIRIIN011 soln.. tw&ttd to W-115'20 inins. after com- zoo
satidactory catsilyst as it Sim volatile N Wts which are plete soln. took place. filterW box. and cvupd. at 40-W
09 4~dlfficuktorexxswve. PassareoliondPlINEtifov"AIA the irtsidluid oil wilidified on itandiriz, to 1a-CJMCO).N-
9400 or glasis wool al 200-41W failed to produce reaction. C11lC11jCO$A1*, at. 05-7P. 91-3% yirlil; the purr prod-
FMWY dw. 111WHO11 (W.6 8.). Ac*O uct, in. 73-4* (from RtOll, then train liensent). 1-e of
00 43 Ict. amlate sillialmly gave Ot em"pimitfilig 1-:1 Owrr r/ too
(0-2 . I he me ester (35 S .) and a 00
Oev be*ted. In the Prentice of a trace of hydratfultione, in tit.- .
awalled tube 100 b". on a steans bath, giving 707~ N- 70 cc. 20% JJCI boiled 9 lurs., cooled, filtered, and the I
etkW-.,-*P.)i-s-amisopropi"itrik (11), be 15.1-W ; no filtrate evapd. tilt a steam bath and dried in a desiccator, too
oft rtdOln.. it bt 158'. bit 104-5', freezes to a glan at -40'. yiCmed 7U-839, 0-alaidne-110, tit. 116-20' (from 967,
alt IXM, d." 1,0200; 11C).sall, hygrostiopk: mm; the EtOlf). Ffft A-6141111111C WLS obtained by mixing 10 j. of
_rO 9i jt4yak and styp4mak are oill- the emplting ptidsid with 's the HCI Wt with 30 g. Ilb oxide and 50 cc. IftO, boiling a
I id i i9a. ow. min., irvalig. to dryness, drying the residue 3 his. tit W-
dl ~j diazod" jo4anjite ar is a timis solid - *
e
ja V yell Z111119
"j~'i green &q. soln.. turning to brown on a W. eitts. with but 11,0, treating The ext. with IIA
I Oust; the
All a (00#111i prialowl with diarodied p-11jNCJj.NOj is red_ evapil., and drying over CaCl. to give 6.15 S. kee
brown. mini. In water, 1,043mistill' b"sidf'no con Lne (M.P. of sti'mcs4ve fractions: 193-4.5".
Pit- -Y P-aldul
slowly in sew gmng a red-violet awn, which turns 97-W). This (LI-A a.) in a little H.0 trrotrd
- soln. 11 (14 tj. 2() g. jCOIf. no hot th an r-acta of fresh hydrated CuO. bodied Pc 1
YtMw in rieutrad or alk all Vera
iad. ILO. and 70 nil. 81011 were mauled 15 hrs. scidIfied tuin- filtcred, and coned. gave the blue Cu bait of abinine
by JfCl. and "td. veith 6o.HuOH; addit. of Ri'*5 to the f0 the te'"'hydrs'It- liculing 4 it. 0-alanine and 7 it.
tit. gave phthalic atthydri& to 17W 15 min. Pve pAlka
Rill, sit
w
l'ItOlmt.
XA W 8 -1 W ft s C. a 3 a I "X'
UxiAlOPOLSIP to tilt OR atit R
4
ID 006 0000

1944"(640m
n
r
vb also from
thi
)

0 '
.
s
"u
ii
.
'I
~z
with 3-rorthyl
M and
ridinat In 34% )PIeld
1 0 0 0 T 0
A
h

0 _
.
py
hill tire 64%of the bensylident analog. m. 166'. 1141 9.
r..
I ml. tabs. HIM, re used I
Vd:ea
. Vt? refluxing continued MI min.. the 111"tt
*

0

00 refloated I hr. with 60 nal. IlrO, gim 93% AcCHsN -
.
L)
' /7b-
laydrornsied (1-3 fact.) rarer NI j. Raney Ni at 1(10
,
84
Video. m. 214-
M*
1 (Xl&tm., load the crude II()mtrr hydrolysed With 00
00 1.5
). 1 0 ff.), refloated 2 hre. with IOD ml. she. NtOll,
Slyral A flualit. Yklfl of ArCII(CC1,HONJIlls, It. 150-110-4 II fit. gives N"P, V (on Imaak of hipilurk 664); 1 he ester b -
1101/10-0 man. avid partially ervati.. the ("Itiefs bring
09
00
o0 1
mnl- (5-10% reCtRiversion to 1) (smicilirbaftisar, m. 172-3*
(airctimpri.,notcor.)). hIeCII(NIIBx)CO#Ns (6g.) and
100'
7
5
l
A
O
h
t
d 5
1
l
8
2
b
l4
1 used to s"d the crude eater.
-ether, allotmal to %land 3 days at 0'. givet, IN (38'r
m"
An m- m-

00
00 -
.
m
ea
-p
.
c,
e
m
n. at
ve
.
eny
.
it.
, g
b
i
l
w
d I
I .
bassed an U) nt.-N-brosaviollAr-lof N oil"
l
N
-
e"Inist
o
san
a
-
-
. -
ow-
mild &tit, hydrolv%is giv" SKV~ in -
so
00 be,-. P.Se relleivir, N__._ 116-
3o
, Sojilailobro, Painit (IX). m. 1-47 *. I'h;,Mhetvv%ItUir.tryit4d.
00 4-valmsmv, pale yellow, M. 199- ")
("alt lva.)); in a 2W
ellit
thetelinill I min
at I(XV)
there rmlttd a mmpd. 108 g. of a YeBow oll.awhich Orlital NI K. 081';~ on basis of
of
dwimijan
W-21
4
d 00
-
.
,
* .
t (in,
.
"1 Q
11) of the ACHICIII ' 00
es C.11,~%Nv, In. 225-6
(drivinpra., " ca,), U colital Which glees 13'r,, DL-N-bC111.0y1threonitw (on lasis of 11)
00 not be reduced in sq. soin. with fit oxide at Small quaratitlear
I-A
f R
Cr
11 (2
20
l
0
8 N N
f
d 4
) I and (with 11110 atiout 121", of t.a.-thrtonine. VIn (4240
1
02 1111 IS
09 o
aney
.
.
.
n
m
a
i
an
g.
g.
Rainey NI, slaekkeas 20 hr.. with if at to= temp. said &ran.
11
4
l
A
CII
Oll
If
b
l
i
i
N g.
, treated with 1
-1.) in Will aid. dry C.H.Nat - 10
IrC.11~%O,Ll J3.% turs.) awl I.,uml Into 1.21. -m"1. It 00

00
00 ).
wr~uris (
ma
e.
bor
it
vv
e
4.
O
%
(
), lt
23g.96
showed
CII(NII
m
mierobillf
Sim
)COII (V) arid 2.4 kil. im, gives :171% 1.
,
0
o
h
00 .
.
t
.
;
y
that thiv containard about 7. L-thrrovallie (Vt). U (10
"
( r
er)
(frula liett. et
CIA-4
oukPirmallf Ej aijer (1). all. 1
148.541.5' (front ArONt-petar. ether); 270 ff. crude X, so
00 0.) in 110 M I
hydropeostral over IND S.
A. 138 g. AcOK, and 950 mi. anhyd. RiOll. reflaied 2.5 bars.. so
Raney N1 until I atom H was absterbod pve
(63% on be lin-
Im.
Chan
ed 11 and 2
6 give 1017. (on t"t 4 11) of tq_t,dw,,4~44ellv
v_
CI
CH 00
9s .
a.
g
m. =al
(devomp". ; further L
(
0-Y14-pitailkyal-al-oartiatilivii, (XI). WIr 00
reduction in N N%Oli over Raney I ~ PVT 70
V
II
2D
8NN
b
t
i
2W
I
O
OH
d A
Rt).N:CI'11.0. b. I(W/10-1 man.; j4rratf. m. 17741%

0
so -
-
-
R&
e
U
m
s
(
,
kirs.) over g. Raney NI at M-W 4/1 Ir.1tor and the
V
rat. 117.5-18"; IN) .. XI and NO ml. 23%. H8r,
JICJ eak
00
11110, Led~ Proda" (7.6 exild. witit is 03. HOO, give, as ,
refitaxed 4 lars. and the adrupy residue ditmaivrd in 760 ml. so
00 saddle. tit Jw ml. hot
: to the filtr.t,. a . v;
now hot HtOll and a slight excess of om%~d- N11.011. give
la on hassals of.11) of Vt. VUI (20 IMA.
(26510 x.) anat - I .

o
00
00 (4-2 g.). rrYsId.,
repeatedly lroma AcOlf.
me
G'
w
z
top.. gi- I,,) (he.
SCICI, kelit I hr. at room tar aird on 11)
the IICI salt, on artandlotin
00
a
j ro
(
231-2% reduct an at
arm. gi,. only
V11 (I
.)
7 mi
Ill
d 0
17 the sk. absoarbe 11,0 and thft EJ
"
11
140
l1
i
i
h
l 00
.
.
, an
.
r
p. heated a fact. at
111"),
V .1
.
ow, m.
ar
rrato.
t ye
167
g
; p

0
0 ,
INNI- ,
(4ft-mn Vbittyrk ", an.
r, tn. 211-
6, (d na.-Allothr native, lam no effra-t mi the growth ci
joicalistratirearprarlenavorahtirwolyl. Nif.1fir's
00
ec"nalm.
the and
w cont-val-saw id
-t of crude samplev of the anduo me
0*
as prepd, also ill
1
"air hyl)-
t
1Y1i!`ki
-Ine and I'tCjjBU"_
~
without e0ret on the growth tit the melsollarra. The total
th
b
30
i

9
,
4
A
CH(
- - Ilz (22D raut
s a
e
Orinw-all yitM of Vt from hippuric add
%,
greaten las bring incurred ditring the wpn. of the 110

L 0 0 0 0 0 0 0 0 0 0 0 see 00 0 j
e 0 0 0 fiffees **see 00000 t*P- W W 0 W . . . . . . CJ. West, 9

'(03T) A. ,w.
U33H/Chumistr,-T - Propianitrih, Beta
(N-Piparidyl)
S.,
Cher.-Listry - Ynthusis
1948
ItSynt'nesis Ath thc: ilid of Nitrile Acrylic Acid. VIH. l- ( 11 -P -i pt; rid-, 1) - c)
and Itt Urethan Derivatives," A. P. Tlercntlyuv, A. .,'. il.-ost, Lab Or. ~iw-m
Acadeadoix-i N. D. Zelinskiy, "o3cow Xate U, 5 do
ItZhur Obshca 1"him" VQJ ',~%IITIJ WU~"), 1,10 3
Piperidine and --crylonitrile w~.;re used to product beta- (N-piperi d-,-1) -pro pionitr Ll,,;.
Latter was reduced b.,- sodiu.,n potassium alloys to produce I- (I I -pipe ridj-1) -3- a.,ftno-pro pane
Article describes properties of some eight new cor(ipoundt:. 3ubmitted 24 Feb 1947.
PA 62T79

synthiials of I 0n& S alacyclubdane it N k"'l. A 11
I livoVey, and V t" ya-looAll. Ve't"?k
No, 41. Set, Fit.-Alue, v File,t. Samill No 4
Coodesmation of Cli,-.CIICN an-I 11001,01'eN .till
gave KS.7%
und NMI, nlxms prulofigi-if stram
ktil., Acidification of tile ol6fillate, evalat . and treat.
lent 'Ailb mAid Naoll. travir 3'.!A% evebe
~11*4111%'W' hit, PIT-s". tile Owl 2*. d"' I W`v'o. qtjo I. I~Ixs'
uhich (S'a&%illett apprtlx~ the rolterl n1iij "f 1.14.- It '.
11.111.4 by (k(711 ('11, 1he 11~t' hwil
1.111411tv li'l COO .41111 111111" ill or It- MI W. I % lit
x1oll Olov; po fate. Ill, W, ! tit I I.' Is
decoull'. I ill,(hom ll-(o; Ill... jlvhhn,j!e
all(] twnentsmYt,mamide dr,irs. ate oils. Tilt- mot. ;4 NII,
liburalvil 411tring tile miorfloo apvroximmv, the tit-H 4
the cwhe anlim. (12 "'; of tw.ll N' if 111-boomirl

5T
0 1 P. (V
9
CIW%f9CI ill FttO at ttstaut Icuip W Ctl,:CIICN
's-it.in-u. ..r nintiom ts.1l, 4 tij,
.1 P117V )jr1l td Pill, FAWIll, vv~ll at -Ht ;J1114.1 ill't.111-
fAmImAy. ne IwAylls". .111-1 wAlhis J13.1 ppill (l.ml
pirrillilleby IF'O. i'.4 fighl y0to" ~Ihl' ,I its pylodmc. i-
A ml )Av, a lid Nit No,. .4t'-fling at I fit ~Iq Ril't 11"l1 ttf
")."It Olk), MOAD"
ev. it Att r Ijkl Itf, At
/0

KOST, A.N., SHVEMGEYMP-li, G.A.
Amines
Preparation of sorte N-derivativea of cyclopentylamine. Vest, Mosk. un., 5, No. 9, 1950-
9. monthly List of Russian Accessions, Library of Congress, October, 195i2ift Unclassified.

KOST, A. N.
A. P. Terent'ev, K. I. Chursina, and A. N. Kost - "syntheses with acrylonitrile.
IX. The reaction of acrylonitrile with ammonia and the formation of trimethylene
diamine." (p. 1073)
SO: J2=al of General ChemIgtr , (Zhurnal Obshchei Khimii), 1950, Vol. 20, No. 6.

dof
-~"theaea with acrylonitrile. XI. CyanuivithyLshou of
ethylenediamine. A. 1'. l',irsit'vv A N. kmi (NI-
!cNlW State I'lliYA Zhur . ONA'Airl Akin. ( 1. (ieu. Cht-111.)
120, --NxAi--, 1 (lit,'W; Cl. CA 42. %~17f. 44, !U III/. Albin.
-.I J5 9. dly CII, ClIC', .1111 onimp. .4.1d g-1 e-I ... K 1"
".10 x. ky (CII,NII,]li in W nd Ft,41 it 1:. 1-
-iming 2 lim. dald Wtwx %1.i ... I all
g,ive Ih C. (JU.Se, '? Il,.Nj
if," Li7'17, unit M.] If.
CII.C.V.4. 1".. 174% Lt.. fill'. d:' I.Ir-1.4. iii,' 1.47,93.
The fortuet Vields an oily picratir and tilom-41: dettv., nhile
its HO sdis is it very hvLtitwopoc uiliil. the dit-v.m,wthyIA
~11141 jullifild Imills an vlIv 1-1, 'O.If 'Ind .1 110 all, .1.1 mill,
, t1luln ,
I N-1 7, lit. NIC011).
Ap

A lanitrue as a Starting mraterhilJor Mthvffs
Ie7!2 ~_
t
Rl
l
U4
-
- -
M
zdpiski Uask
NO l31_JU-U#tLUo(Jj; Cf. G-A. 4L. l MO gis
777
70
Wjn;. *4
J
,
DiS-kft;QiO" at the Ijai.TMIItY_ (IM) %vith complete. exqtL
.~a details'and bibliolzriphyW. 1001 rcfCrcjIctm~':A labM
l
C
C 0
fk

~t
id 100 0. SUCIS was added 30 g. 2n dust

~
'
3
tirri -and after completion orreAction. the alixt, 'wip,
"ng
~

'
'~
~-_
allowed t6siand2fir3, decanted, washed with-10%ACOU
k, ,,
crAzincl,.ovcrnicht with 60 ml. 80--00% Acell ;filaW
K-4sft2d ivith. ItIO until neutral, and washed Avith

~r L be-,
-,tS4);,gIving 30-3-5 g.-Sn 6st. Mtira~ ofZn:mus
rernoved for goW rrsolts with thii catalyst- Ifeating ZWk
frocir,cir.c.,v witi, s,g. of theubove So dust ln,zAistii

below 1tv,
app. xvith chilted mcciverso that vapor temp. is
I
yieldi it 2-lw~vr distillate; the upper la~W af* dr 9. th,
n
V
, Sew.
CaCIJLYiOld~ up t6 90% 11 It coox;~
I
tthylenc o%i a is, d
'

te pr be,coft-
in, the prepti.. of the cyanoby(trin, il ad 'Ct
6 inated with
In ; CHCN, HA and ~4frrrtl. 4Z i

fied hV J~-ID MI=Ic=_, rat Willi PiON and =i(b,. ~
en acuvat-A Q
R axing the-cyntwhydrin with silica g4

'gave vut "0%
'
over A130i at 206-:20
gave but 18-20% 1. , To 950 mLlaq-
'
N"'Olt(satfl. in
thetotd) was added 05 C. I'drjVwiSjwftb
coolinp over 2 hn. so that the mba- remainedL a-
after 30 min. at room tezr~.p, dista. gav~e 5G%Ai2VC#2I
CAV, ~ bl, 77-8% bsj SD*. nV 1.4390, cis 0.9584. which polpm~
merized in several davt in a sealed ampul even to darkat"I.
Distre. of Vic bigher-ImWnIr residue gim 47,96' HN(CS.~:
CIT-ACN)2. LY14 1 bn 209-11% nV 1.46W. kilo 4.01W.
HO jaft, ~ m. 147-8* (Ftow MeOff); N-Bs c4triv..~ im. US'
d(fr*mAfe0J.T). The fteeaminegeneratedby adcb.o(rO%"-
=MeNII to solid MaOll was W into 106 z. I *ith
ivg over C-8 hm., and the mixt., distd. after 2 bm: St
i room tesup. yielding 80--;1% AfetAVCH$CAVsCN,,byw 1711:-~*-
rilt 1.42M, d,.OAMS, pierafg, tij

'
ti!imi MCKLYI). Ur!z4L ~440 g. NtliCiff and 26-5 g. I lgavtaw 7.
t
Aiighl beat evolution after &-10 min.; refluxed on a st-
bnth 2 hrs. (vellow color) and di$td., It yielded S"SV-
lf_th-e~ li~eatinri% dorni 4irw.
d

r
130 01VI 45 3-iso-Pr oular, Q

4q 5% h M
tne r
AM,; cl,;~ (1.0334; CsUal' vila., 0.3,6o.
4 1A.528. n. jr~ I A571,A-s- 0.91W; - eydohrpyl lit, ;Itl.5
6~4 1644% n3,A, 1,4725i nl~ L4752,
cy'do4W ctkrl 91.574. b, 177" nl~ 1 4bik3j
' d,.
1
W. 173%
.. L11
,101
-
WI
Ac-
04
l 76T 141 t 0;
r5
er
Wer, -40.40?

4 4 th 1 _0 It 1.4 ~-d.. om-m;-
tiler, 0.8,ol'th 146
136.5-7 1 1-
AMU;
jO-A) eiter, 66.2 1,471 740; ~_C.Ifp
-2 2713' 0"
"sler, d 9.350 1

d
ow~

NwOm W knisam"s with cashisayl compoetaft im On
mi"91 ul*W. A. N. Kagr A. P. Terrat'ry
Vr ~G"A!f arthis
M,hurr
Ab". Seek S.S.S. ., twtq. KUM. Nistilt 1931, W-W.-
The reactim of 11COSM11 with cashottyl catipb. is ac-
cri-AtId bY The licturpee of bydivigmalim mubFK& (NJ.
Co. P1, Pd, etc.), mod the Umit of active tnvp. Is bruremel by
2D-W*. Particularly eff"ve at such substanceii In rcee-
fie-solaiii0thmiemmptly. Tficuscolestalystsimproves
the *14 of primary arnitirs. The results Indicatt that the
bamblim of the reactim is much the sub-i
"&"am bert Uttk he"ins on It UW the true tatchunham MAY
proceed by adda. of IIOCNnt to Rco I. Ow meamof addis.
of tbr 1110C and KII,(or NRI) frmp~ftts affoss The CO link
afthetwisrinyl: the imaging RMN"'or N)WOCII0111st"
1114,11*11P. into Covarms 'bitanduc ReCHNII,(or NTR,). 7U
above mentioned catalysts give 2-6% better ykkisof RNH%
at I 104W in cisemparimon with the 180' required without a
cutW". The. Sicatalyst was pfrpd. bytrestinS Nicarbots-
&Is irlib excese JIC(h1I 10-12 bra. at tow. temp,. filiedar
The NI %mate. stid therumally demnpg. the requisite istat.
Witt before aw after inuistminS with a little 11MTI; the
inilm don b a ordinary bumer. Typical r-
W"
tim with 6),W. the reaction of fd% IIC'OJ1
HCORNYI
-with (NlW~M Ibliaterd by --) follow- liestit's 60
r 1, 1 x Ni cxtair~ft wid 24A it, NIMCO 00 bro. at 90* and
firs, ej IN'. thu's hydrolysis by holling 2 firs. with IOD ml.
cooed. )ICI. gnvv fil^ hip 014'. joirruto,
W. &mi larly 60 4. 1 simi X) it. mehCO wil b I X,
hi pvc 431% 3-ami"tamt, bm W91'. 110 sell. m.
W (from MOB). To 60 jr. I and I a. Ni in a Claimen
Auk heated to 1:10, was slowly (0.5 ht.) 1kddW 23 ~I, Et-
PrCO and tk* nd~tt. heated 7 hirs. at 125-M, with reicycling
at the dktd, hox"it. y1thfini; 32.9 lim
IW221. 110 jA, m, Z15'. a2buly MeAmCO raire
55.1% bm 140-31; 110 ask m. 133*-
hWtn2RtI2G-A'4br*.j&vv%40%Tkm. S91a;i;ATCO
after 8 km. at 140 taire 63.8% +4w bra
UCI ask, Uk. 244-1' (WM RtOfti_=
.1 330"4' the is
61.4 when t In = of the ketaut Is hIXVVtT I
ff~ WW 48,1. C4 pre in 2 hm at iris-MI
MA )s4mfiw*ft*N bm 164-71; HC1 ask. m. 83.69 (fmm
. Hudtg 120 g. 1. 2 g. N1, NW 34J 1. imc~pr"

TERENTOYEV, A.P.; KOST -, A.N*; GOVICH. S.M.
Condensation of acrylonitrile with some dieaes. Vestnik Moskov.
Univ. 6, No.12, Ser. Fiz.-Mat. i EstestvDn. Nank No.8, 79-83 151.
(CA 47 no.14:6877 '53)

gles'pWanarlonih-fle. ]CIL Preparation of some
a r0 M 41 and spennidint. A. P. Tcietittv,
,rt.and K. 1. Chutsina Mo."m State Uni 1.
,,; I Khim. (J. Gen. Cbeni.) 21. 24114-7(kiiiAli:
cl. C.A. 44. WI-Ifff; 45. M22e.-To 14.9 g. II.N(Cllj~,Nll,
was added with cooling 10.6 K. Clio: C11C.1; and the M,[".
I-A, ried slowly to 40-5'. then 2 Im. no a sit-jut Kith. aoit
Tarpid y disid. in 4L N atm. to give W1% 11,A*(C11,),N11-
C11,C11,CN, 111 200-10', and atiout :1 g. dicyatioetliviallon
product. lo, 230-70*: when 2 inali-s Cll,:CIIC.N: is U"I.
70% mona4l) and 2.1% diryanmkjkliax (11) preOucts art
formed. 1, th 2f)3-fl*. b. 214-18% nil 1.47112. df 0-972-%
forms a cryst. di-110 sail. dirLenific at 11,00: 1.
1), 2,113 !,*. 14 271.51.
ovV 1.4100. d1l LOIGR. Rediulim q,f IL,j K, I hor 15 C.
Na added to a suln. in 251) nil. litiOl I A PW noff otimin
-dbtn. t125-35-) gave W21%
tit. 270 (front aq. MeOlf): dipicralp onenek 'ubair. deminp.
226'. Similar reduction of t1 gave 12% #V.JN"-kj(J-amixgo-
pr*pyN:h**edia=ixe-4l1C7.11iO, darkening at IW. a
irb"Wine "Ojos. G. M. Knsoialwiff
Ile

.L
Tj 17.
V-1 tnm ~ n B
t 51
llcll~mthenirl vsith the PO o' "I eNlitrilr-~ of Awl(i. XIV. prCyrrz!'it'll C, o
Dinltrilv of ~'mcinic A. 11. Tercntl-(-~ L. ?T. F
Ac-c N. D. Llo!~covi 34-- to ii
ll~',Ilur N-'z:hmh Khim" Vol XXI, 110 10, pp
Describes pr~pn of d3i-ii,rile ol m~ccinic -cid (yic-10 FO-F'~%, b,,- L~ction of nc-73on-i'L.1,11r, rm
- 1, . I ' - k, -n serve rs ntn t'm- --.!~tcriivl for
sAd Pr, -oln of KCIT ,nrl l,',,'O rho einii-'rile c i
'C r' of
ol rni I to putresmne (stv,2-t1tw -nt,irltil fo -n
Ivittmin Blor cm be re,'- I
ibers and u-sed in prepn of series of co"nds '.-:ith high ph:7s!cl. activity, i. spert~l~e
Results ef mixt of I~C,.T, and M-',04 rr,,lns in rrm, crres nF~ for
hy6roc'-,-anic acid.
PA 1~4T35

KOST, A. N., YASHUNS M , V. G.
Chemists
A. N. Vyshnegradskiy. Vest. hosk. un., 7, No. 2. 1952.6
9. Monthly List of Russian Accessions, Library of Congress, October, 1952MOM Unclassified. I

VIT
Aleksel Nikolaevith Vlahnegridaldl. &_N,.XgjCind
V t1 Yalb, n*U Uspikhi Khim. 21, 26"(1932).-Briet
summary of adentific work (1851-18M) of Vysbnegradekff
with 22 refertnees, *.G. M. Ko solapoff --J
'19

Vc,].. 48 No, 5
'
V. Prep ation of 3-
T 'h ud A. 1'.~
fle.
10I 195-'~
Organic Chcaistry C.A. 47, 2759h~

Pil,

A
wfcjl~

XOST, A~ -Y4ST4NSlJY, V. G.
.:~roplonitriluu, llvahne,~~radclr:iy Reaction
Anomaloas behavior of ~6- cubstititted propicnitriles
J, t, I-
n 'lie Vyclinegradskii reaction. Dokl. All SSM 83 no. 1, 195"
SO: Month List of Russian Accessions, Library of Congress, 9j_t Uncl.

z
37 WIMM-W
jV1,

'A
A
~
a.-
U
-
121-
estmov, NOW

Afg;- I
We. 4,
44
1095 -7T0 2-3 9- Of Ifillyl OMMe ( )MAS FAICd 5
et h ti
Af
p (CIJXU
t
~,
8 hrs. at 120* the ruixt;
dissolved Its hot- Us%
with 0.5 cc. of 0.2N ram-ed 4 hm, AbOll distd, U
and the $011, treated vIth_BMC(h-Oiv.85.%AOIICCtIr
MhBa (11) McOll).. Since intcmedWe oduct A
"7-
Be
On
l
=
l
OCH.Cli
n. (presence indlkated by d
lk
.g
bl
ra
ej
to cafty out the hydrolysis rapidly, poke t of u1-,
ativitik is Thente
Iodation ims cartled
ocrot
l "t 41,
10hro
.
.
1
Q
y
at 160* hl a sealed tube It jpvc 3st, Iftlese(CHO)SO6111114

added 8.8 V. of dioxane and.4.3 g. of 1. kept vold-O hml
*then tvapd. on a water bath 8 bts.. 5 cc. 1120. in 2 portlo
added I and treated with BaCOil to )ield 25% IM; ~ To a siml,
lar dioxane-S% iced mixt. I X~ of bD Z"te was.,'.
-
'
-
dd
d
h
i
ld 67
i
i
D
i
%- .
a
rk
O,
e
w
t
st
e
ns
to y
MO.
( 111104S)I
ClHgCH2CHO (C.A. 44, MM) was sultonated with m I
VJH(hCCHjSOj)kBi' instead. of the,,
(CHsCl~tu give 41~
td 19i which In d jAvi- off.
COx.aod.'dJd not forni
,
salt3 with S-(p-n;kphthy))lbikkronhtm chlorlide (M).
=
To 212 g. of I was added *hl)e coolng W g. of dimme
dlbrwnidc In Portioni 1, RW the juvrer I yer
washed with ice H.O. dried ever C*Clv~ dissidjp rama pm
);bzkl0l-40
-C
~ lf
lil
i
A
2W
d

vn
.
t
n,
i 9,
),
t
mq added 3 j.'NaiSCh In 25 hil. HmO, Itentrd Ondrr rdox
er
Mwa, -salt
toding -t added and the no,
,
~ 01, the
Idintificlal6h
'n I
1-
m
i draplified by, the fact that the WU v cook"
a
1.
m.p. at 2W-4*.

M
&I. 'La. T~ I- - -
.; Mltlt IIZV, V. 6.
Nitrilas
Anomalous reduction of -substituted propionitriles, according to Vyf;hne-radskiy. Zhur.
U
ob. khim. 23t No. Zt 1953.
SO. Mont List of Russian Accessions, Library of Congress, - June 1953, Uncl.

-Reaction of mobile amino, group It. Excben OIPW[no,
g~Topp in
A NT
e7 SM. -
T4
-si w__a!"' Jili':i
Mrs, JMW 1 0. to ejNCHICHICN Ih Citif Suve
the quaternary salt (I , ,netdIcs'(from MeOll), which,
heated to 120% begins to decomp. (at 20D* the reaction Is
rapid) Into CHI: CHCN and Mc4N. The former to obtained
in 70% yield. Similar pyrolysis of the Bts$O4 salt at 180-
200*1gave 80% CHj;CIICN and avers low yield olMeM4N.
Is. 66-0* (plerate, m. 184!). Pyrolysis'in the presence of
solid KOH nt 100-2009 gave 88% CHj:CHCN. Addn.
of 44.9 CICII,Cl-I,CN dropwise jo, 23 g. KOH and 10 g.
WIN heated to 1200 pvi a distillate contg. 76-80% M,11:-
Na d I-,,d
CIICN. 1(02g.)refluxed4br9. with 4.6 g. VX
In -60 Mi. McOIJ gave WIN and 21 % MeOCI IsCHAW,
lism 164-5*, nV 1.4031, die 0.9488. -Refluxing 24.g. Nie-
NCHsCH-CN.h1e1 with 6.6 g. KOH its 74 g. BuOll 6 Ins,
gave 73.790' MOCHICH2CN. ba. 80-20. d2c O.M1, . 0.0'
1.4174.- Healing 13.4 ii.-MINCIIsCHICN.Alel wit%4,11 g.1
KCN in 50 mi. H,0 In an autoctave 0 hrs. at, I g"
!after acidification. 6f'the.wolled mixt th Elz:~
$3(1% MH.C0-143;. In. IS20. G. M. X0361apdy

xcthi~d V
%: -
fj 7
!rT*
CN ift 1,`:~
-A. 47. 8.M G a.;
I illvll~cizll!
iihi
ton ims 4 g.
tb
-10%19
n4dibn au d.: Into Cl,' elld tho steam
-.11441 - Wtya ylildin
it 13
Under Et.
_40N M. ~ CH,,
lo TD
,e a
bo
io,:Ai~ii:00 c 350
Jjj 110 Ot 4 -
Aa, "mi aad
WAbe N
-VZWXi wd'
!kid
Int TA5
it

7i

n
Chemical Abst.
Vol. 48 No. 8
Apr. 25p 1954
organic Chemiotry
Soioaltfo~ anil traltowt.icida of scidophobic substancei.
of
F"
MAU-MOV.). Millka Ak 23, Tirp~4-
cf. (CefA C4 17O.-HeAting 6 9. 2517. t6oin. 01,C111:010
,I lt;t
in and 0 g. pyridine-80i Its an ainpul 1.5-2 firs.
at 170', soln. in 140, neutralization with B&CO., stearn
~distn. of the pyridine, filtmtion of the residue, treatment of
the filtrate with C,conen.,addii.of hicOll, and extit.of the
product with hot MR 1cr 3 days gave 59; (UCVCII,-
S06)1ifla (1). formed apparently front the prinviry proiluct
6H,.CIiCI.O.M.O.Da.OA3j. Similar reaction of h1cC:-
C1111tr ve after 6 In. at I to* M% Ba salt cif 3-sulfoijo.
butyro1rhyde (11), which reduces ammoniaral A%N%-,
A salt, -utup; salt. itmi. in 11,0. Cif,:CIIOBu(2g.).
3.2 g. pyridin"t and 0 ml. (01,171), heated 9 firs. at 70-
00' anti treated as above. gave 30% 1. forriing a moni;-
At nae Oil rf On. front HID; I-CMIX1119 file MU71111IN 1-1
hm. gives A. .6% i0d; ult. of dk)XFII1ctii% itives -12%. 1
wit ~-2-naphthylt.Kiurcmluvi chloride gave die S-!-itajA-
A saroithim jaft. m. 202-1* (from C.14). CIt::CJ1OAe
an pyridin in (MiCI); gave, after 8 firs. at 1290*
an the tunial treatment. 81.% 1; ifioxanc-M gave 62%.
For better Wation of the ImIuct and ren-oval of AcOlf
the product bt best irtfluxeti I firs. with 0.2N I 1,SO. Wore
itcatment with DnC(*h. ll,(':CAlt-OAc(Ig.),itl(le(ltplg.
Sot, 0 mi. (CHICOt. and 0.6 g. diaxane witl~ ice ccmflag
gave 67% Ba acdoirejullonaft wonith)t1rale. 11ciluxing -9q.81
jr.iso-PrCHO, 61 g. AcOand 6 g. KOAc 10 firs. gave3G.5 g.
MeX.CHOAr, him 1214% nlt?~ 1.4100, which, ficaleA with
P3,7WItie-SOi 10 hrx. at 150" in an attilml, gave 357V 11.
clifirciticito beatett with 30, it% (CII,CI), 12 hm. on n,
stewn bath. tteated with It ,0. tm-W of ligsAlt-twith Mi.
and nentralized with BaM. gave 41% At suffikitelair
monohydrate (from 11.0). Aildn. of dioi,aut: difiromide
(112 g.) to 21.2 g. ClItt-CHOAc with miling gave .501,`t, Br-
(7111CUBrO.01C. b. 101-3% it' 'I LFAW7. if-, 1.0170, vibich.
(2.5g.)mfluxed I hr. with3 g. Na.,1;0~ iii 25 ml. 11-0. canc-d.,
treated with BaCCit. filtered, evapit. anti irratcAl with S-2-

FD-1511
USSR/Chemistry.
Card 1/1 : Pub. 129-14/18
Author : Kost, A. N.; Kamernitskiy, A. Y.; Gurvich., S. M.
V
Title Synthesis of 2,2-pentamethylenepyrolydine
Periodical Vest. Mosk. un., Ser. fizikomat i yest. nnuk, 9, No 6, 115-118, Sep 54
Abstract Describes synthesis of the above new spirfine. Synthesis consists of
reducing the cyanoethylated nitrocyclohextine. Gives a convenient
method for the preparation of gammalgamma.-dicyanopimelonitrile. Eight
references(Three USSR)
Institution : Chair of Organic Chemistry
Submitted : January 7, 1954

TFM,NTIYLFV, A.P.; KCST A.N.- TSUKMMH, A.M.: JPOTAFOV. V.M.;
SERGMV, P. ., -ro ssor, redaktor; STRUGHKOV, Tu.T.,
redaktor; MOSKVICIISVA, N.I., tekhnicheakiy rodaktor.
[Nomenclature of organic compounds; survey, criticism,
proposals] Nomanklatura organicheBkikh soodinanii;
obzor, kritika, predlozhenta. Mnakva, lzd-vo Akademii
nauk SSSR, 1955. 302 p. (MLRA 8:12)
(Chemistry, Organic--Nomenclature)

- Nomenclature FD-1683
)< tj -
CVT/1 : Pub. 129-8/25
Author : Terentlyev, A. P.; Kost, A. N.; Tsukerman, A. M.
Title : A new system of numbering atoms In condensed cyclic structures
Periodical : Vest. Mosk. un., Ser. fizikomt. i yest. nauk, Vol. 10 69-76. Feb 1955
Abstract : Proposes a new system for numbering condensed cyclic molecules which
depends on the structure of the compound and therefore can be used for
both carbo- and heterocyclic structures. The atoms in the condensed
cyclic structures are divided into four classes depending on whether
they are non-junctional, junctional, junctiona3 with three structural
atoms, or junctional with four structural atoms. Diagrams; eight
references (one USSR).
Institution : Chair of Organic Chemistry
Submitted : April 14, 1954

KOST. A.N.; YMHOV, V.V.
Reactions of hydrazine derivatives. Part 3. 3-aryl-pyrazolines.
Vest.14ook. un.10 no.12:115.-117 D '55. (MLHA 9:5)
1. Kafedra organicheakoy khImii.
(Hydrazine) (Pyrazoline)

GRMBERG, I.I.; KOST, A.H.
~-Wft hrm O=W a ~bwxmbwj W t
Reactions of hydrazine derivatives. Part 4. Now synthesis of
benzy1hydrazine. Vest-Moak. un-10 no.12:119-120 D 155.
(MLRh 9:5)
1. Kafedra organicheskoy khimai.
(Hydrazine)

Wt
.,
4",

trislv~ui;O~ei;, A~:N

1Vmfke-A& A7"r37Mr1`Tff zz -77
d hNHj uttd Jso-~B%~OCH-.CH

X
'
2
'gen.' Gl-rm
UZ.S-R; rt),i
-1
b
f 2
h
f
48
C
A
13M
S
l
- -
0 M~ at li4
pvc 74 ~qo crude 2 &dime-thvi minmimm, m.
*
t
iU'
t
61
i
l6j
V
b
~
~
p
.-
-met
ese3 o
M~
,q) pu
t
.
.
.
ynt
.
y
~
d
l
ib
9
hi
d
d
d
T
ii
~ .
-
,
,
nc
rm.
are pre
cm wit
: puy
,
,
%
i
~d
A
O
t
di
O
-
r-.
o
c
v
uT
ints are
escr
.
, 1.
et
rs wi
e
.
,A
cam
gp
jw
g
- a
y
t sw:r4 Vbe-3ield;, Ibc U~c of Etocll --clh zwe a 3451~
amd !L2 m3 uddud droplyil;c.ut -93-1 ----7 '--tt--ad A~c,
Ilit~a.tng'.~1.4k,f-lifewl,zvjl,. lug. Ptioc-rfxf!"
Q.5 S. 60 ;!IL d4mallf t% hr~l, at
'Die Sallie
n t
PlOdllcq, -Thik t~c e 9t
Br3O, was umd instead vi 1%N1151cl, ii. Ykid ..;L3 4 ZAP%; pideptiAnct. Ill 1(13_44 T,, !-2 3
b 9- t-MCOC4711MIR, 0-5 9. Of i15 HO Stltt. and m! ~w%
10 g~ l3u0CH:CH,. 0.5 g. PliNTH1.14CL and 40 ml. xylent ane rr"addM sicwly alreffax O-e~ 2 hX56. itj -b- 1SW-)ch,&P1
%veTe htattd 25 Ills, or. a -team bath. thta acldMed~ stea-m and the mixt. mfluxed 16-18 I-,m te ri%e
distd. toremove am solvent azA BuOR, and the r!.-Idve madtk, --methcp" ta 4t e T-64
alk. and str= disio. apin, thtre vms zbtalue46391 drom f i"Wsb"x dli-,nne uo mcibu tt:iA -krt~
- ,
"llon yltwedt 01ta 25 1.1s. at IM, Vcl
c

P? mi~ y;-l . -- DO.
Z7w; purVicAthis WM U.Ch z1vo ,

, ~
an
WOW DWItte Y!6-1"but wa~jt Abe SOW;* -
equirmaar prnilcwttan of mwts-
t
I
s
uk~l,
a,
Ve yk zu-2bix
U
1 L-
iN
v
Ht to
Ina, Lb.. auL

g,
8-9 9. P),Tuvic p6d
419 ;n
n, U
nbs
MOB
-
.
,
, a
rotillizzi In 'Ogorfms reaction, V~
;wL lewkw~l
POOAU after refluxing Ill brl. the mixtum vjej~!.d W%
-
(.. -?
acid, Ill, 2 u N'r. f,
1 PO

i9,

aW and metilanism 61 the LeuiCari reactift cailrartone
M-07 .4cT - I
5-"
(XfOe&L% ur.
UMIJUjIL3. . ~
H
i
~9
9
M
H
M l g~ 85% MC0,11. and 0.6 Z. Raney N1 heated 3 hrs. to 11
while 20 g. IICOH was. "g added, gave 84,870 dicy,ick-

IM
0
Catalyst
.
k
T, r
Y, L C::
0
i
`"Yl~l~line bai 13TV (HCI salt, ta.335*). To a tefluxiog
Prewnird of )4aney Ni accelerate the Leuckart reacti
i"
direct the mictioll t& the f urilla (loll of It fixi
112.1, 18,% g. 11CONill, 47.7 g. AtIO. andO.5 X. Hativy Ni

unlincs. 'Itt
Ck' WLL-. Added Ovct 20 tni". 01 g. cycloiltXYLunirm, brAtzil 40

rtactkat goes thcough the step 4ut dk,utq~ of
1ICONl1,,, tin allit, And treAted Vrith NUGH yielding 74% acesyl6yclArsyl.
,
-
: I -
the Ist product Is net tile Amilic but its fornlyl deniv. Online, fit, 102-3
; no formyleyclohexylantiaz iva4 detected,
, If Ac2O is omitted, the Ionnyl deriv. funned in 32% yield.
ed teLtiniques for formation of amines are &-s"iled beo
,
l
lo
50
T
i
6
N This'withNattudeirgisO weapawdery.Nattiolateofthc
f
l
l
i
tI
0
h
h
o
w
xt. COMR.
C. m
mo
q HCON
, and 2.6
A a
ormy
am
ne, %Y
ch wit
cxy
Rtl gave 22,8% cibyl.
ey
Inoles 11CO'll fillf-pt); by felssilli; 1411. into 8511% )ION)i or baii M-50 (pict-Ate, ni. 132') Aft,~r the
addax 11ji to tile Acid. 10110Ive4l by d6til. to batill- hapon: of the intermediate formyl &riv. witis 51/0 Naoll at
temp. I
the residue Was heard until tilt pot tunip; rc*e idlult. In the Leackairt Yeaction the adda. 0 tilt ketone

to 175-
j lien tile mixt. w distd. its Vacuo to yield at to the hot 11CON11. teods to,raie tile yield ckf
colupolle
1
if 0 . W a I q. ney i, tile inixt. licacd to the prijaury antioe. it HCON1101CO-11 is addeil to ex-i
I 4nadirk-litc ovtr1'6hrjO.'vlitlIV tilluousditil"with
J cesb ketouti the jitcoadary Mmille is jilainly fill 114M but Plot
1 9, 'VYVA t
tout" aittr 1.6 hill.- furiht!r hratiiig triii AddnANifieMtatLithCMAV_. . I
mix&; was, trealcil,wIth 300 vd. 50% NaOll, dpeanted. aiid'~ tion by ~wcelemtcd decompo. of IICOJI and decline of
-tile I-Pt. treated with hot 1410; tile sepa. oil lVag Vikelt Ilp, acidityulthesuediam. Inuixtbiesula. (pytidine, Nfl,, Na
io HtA) unil di.:Id.. yieldifig Ills or It= baj..s) the, reaction g,les Very unerg,firAly. EXcess
153-4% bw 2011 74% in. 1-171, ti'", 1.4131Y2, dy IMM, To acid ithall)-st Pievellis tile furillatiull of -~rvuljdary lonille.
Mu g. suixt. was adtkA 100 S. 85% Also in J. Get&. Chita. U.S.S.R. 25, 1377 81(106)(Hold,
over-1,61irs.
3r trauslatiou). Al. Kosuhl~lf..'
by 48 g. cyclullexanone; idiur 2.5 lirs-It 116.
, "apli. With
5M IoL Wned. 110, tn'110jeal witil XOII alid distil. tllvre~
8;).21;~l t imitw, lzu&ted as. tla~ 11C1
AW.

TZRMIYXV, A.P.; XOST, A.N.; BERLIN, A.M.
Syntheses with the aid of acrylic acid nitrile. Part 22. Now method
for the synthesis of pyrrolines. Zhur. ob.khim. 25 no.8:1613-1616
Ag (K[aA 9:2)
I.Mookovskiy gosudarstvennyy univereitet.
(PYrroline) (Nitriles)

KOST, A.N.; GRANDBIMG, I.I.
Reduction by means of formic acid and of itB derivatives. Part 1.
Reduction of azines and hydrazones. Zhur.ob.khim. 25 no.9:1719-1723
S '55. (MLRA 9:2)
l.Moskovekly goeudaretvenny7 univeraltat.
(Reduction, Chemical) (Azinee) (Hydrazones)

L

d

4-
And
watmuia iwilb "I Its. defivall VW a-
b
ductiou of 4tilaolifi
,
-Zh pnd L. C. - A'ndin (mm'y

'
100% 11CW11, 264 M g. IJ'C%Nsj III hrs,
~vrith stirring,
I
,adding FtO and ofem 30% NaOff, cs tx.. n
itb EW,~and
'
diog. tile ext.
-gave 85%
*
145-'
m
3S
5
(hum Ft
t
t
t
I
)
-
-
.
#
.
.
refluxed I hr with coned. HCI gave 04.4 r
t. t
.
b
drequilnoffne, bs-4 95~4% W 1 -051, it,* I AA DO, 110 sa 1.
m. IFQ*;~ PhNCO deriv., in. 98% Bi drriD~. ui
rn f
~ 74% pic t
tn. 140'. Quinoline (12.9 g.), OX g. 11COW 32i and 2A g
IqO% 11COJ1 -refluxed, three 6~&g. ~'Ortiflfls; FWded at I
hr. Intervals (tota the mixt, Mid. with
NnoWaml "Id. witli M.0, the ext. eviiiid.' 11111 tile

A.
A

7
-
Synthesis sin
IyAtbotab with atrylonitrile. 10
glifts- 14ndMepriplopic ocids.
elh_ - Me
Arx
1059- W,
v;6 jhbwjj jti~t tlw- 2-c)-zntik11YI pAinp tiin tm! clitaved Ito'
Anx 0 it Is acttktl In 1.19Y51tioll. the Snol. Is st-abi
9 thr, tioup Is 6 iml rdi~t. of I. I,
0.3-PoAtion. TO a 41
Its tit
)(do,- 10.6 Z. ( CfIC-N (Iii), find so tid. CGHO Was
111,
T
)A Kull
I
Isrs'..-thi plixt. was filturt-A,andAistd. yielding 9517p
1-indalekopionitrile, Its 169-80'. in.,47. Ittfluxed With
"'pioxk and (I); in
10% Koji 3 ties. it juve 05% 1-irdalep
(cm-tc),.nj. 9()-1& (from aq, EtOll-11CM
cytintilly
intlok. H:R
KOH In 100 kt;t. 05% Ftoll in auto6tv Z
ve 62% 1- NaOll gave a 41 % *W*' tht best Yield Was
94
90% -amit;d- with KOIV Ili 6 1w$-- a
t,
attit4i using EtOCIjjCIJtCN, kave a 47% Yielil In 6 hrs- 2
d was obtitined
CsHionlY 9L 12%yiel - - The.
Ruinchve maction as tititive of intlok and Jjt~Is1CU3CHtCN,:
~ve 53% 1., only 15%~was_
i,.jjh ;.Ikl )Coll in 05% EtOH
,3.1)g
61)m1h" -Ili rtfluxibi; xyluit. - Wtirrint
d6le, 3.4 g. IA. 0.2 g. Ix)wd. KOH and 15 10,Anj I-bri c
.7%
rom temp. and I hr. at rellux pvc
propionitrile. m. Bali b,17()-80% hydrolysis With KOH Sam
-12*~ Similar reae-
rid m
2-mrs6yi-i-indolepropimic a
U *ith
tionof 34 g. 3-infliAp"ripic, 1
il 1.3
powd. KOJI. in Cill. lr~ -%,
97%,
6 Moll), hydrolysis
Of-7 Im
-9' (crude
(JU)im. 88 ude), in, ( 3
d Ca "U"
~_*Oth 10% YCOJI pVe t4c fret i
idir condf- of 2-imdo -34n,lolt wfk.
k)UjtfijC~',. !tit IA - Wive j:j %
P1
.r ;
fit -i M-1 14
(firmn Etoff). ivilica .1ve I
it:
acid. jo;~j_ks- (fi-ofil jf~o; - V) - f
DW.Ae (4-8 F ) I ~ L-
' I I '. C 16; Wid W3 9. poWd, Oil filisr-d
t. I
rOM t1mli. fit 2 fit
15 Jul. C,1 14~ t -it mfluxi~j 2 Ili S. rztvc '10%
Ef -5f)"
.1,j glq, 35 wl,kitil-uve Ow fmc -,cm,
this ch.,xvO with StipcUlit"ittil zlx,111, Io ittlicAo.
_.Sln1itjrh%:; 1,34mictlebi5propl,01ije acid %rjtjA
~teaiu tit save 16d. llt,ating 111'
-:16th A little hydroquinorm utider N V, 250' gare 92%
In.
-94i'; refluxing I Ivith 50% Koff 8 hrs. in Mil
- StrOm 91M UO it1dole Witt unrly -~ll ucid it-nit mc,)vm-d.
jigirever ~6'iinilar treniniclit of 1-indak-limpionittile gave
abcatt 10tli hitlole and 80% 1. XXIL New metbod of ayn~
-thesis of gyrrollnes. A. P. TerefiCeV. A. 9. KMt. anti A.
bl. Berlin -Ibid. 1013-M.-To 91.2 y. lso-PtiCO and MO-
a f). Ilk I0 Itil. E1011), lleaWd oil a Staftin bilth, was Y
MIXt. aftej neumlization with II.Wj gave 40% y-mdhY--r-_
bjs1yr>4iiilrroni1ri1e, b& 106-S'. b7 it
jr 1.4132,
dn 0.9*.M1j! thi- (15 C.) In 300 in). 3%11..0,3 tul. ON NaW
s 101,1~ I
nd,-r 16 (Orin A clear saln. it
-as hcatW 0 hrs. at W-W*
netitralizOl and evittid. yietdirij 89%
m
vdsramW 90' (from CH.)-~ Sunilar
tion of Wqx4tyrophenont gave
efonf.
'trik b..6 1 li"I% rJU I.M. d~ 1.0469, which hydrof
as above to 03.5% -t-mrJhjW-7-Unsoy1vdkrarride (U), m..
* itficiii
145 iiHO). To23g.XaOH1u3WtnJ.IIjOat-3'
was added 5 Z raI. Br followed by 14.2 11. 1 und aftex 2 firs,
on a steam
bath and addn. of NaOH them was Isolated 70%'
.. .
$34 bi& 11SZ40, m1V 1.4471.
da. 0.8340~ ! which cams beadacbra on labalation aW eye
uptat (in; -decomp. ISO';- slyphnale, in, 184*;.-
N-Unwrtesulfos34 dcri~, ca;
carbansi* frri; CjsHjjNjO, rp,: 2D3*, I Similarly IT rave
b, 110-21'. NIJ 1.5440.
d.W
pkWit, M. I Xpkzi~

R,
q
eai AtrinUrgs. S)M;hesls 0
'
41be and,
nt
t
bic
UNK
I
M
TOA
,
.
a
eno
O
.
P.11M
)C
p
I
M Ift RtilW Nn N'.
_Q
27
1
7el
-cf.
.
.
2
-
3
0
eye oltexam -ie
2430, LW~ 156 1
10
ld
f I I
t7
l) ~r Ri
n o
'11'0 L, 70 ml.:HiO a

Wt 91'erni It Ofti
Mi. Mi% tht mixt. Wa~ ill 100
s t

yer! ~vas svpd. nnd
In
nil. H:0 rind 160 mi. Et-O.'the or
Astd.;
'
a'
~ Thi
tirrin
%vj
h
d
t
S
s
r
:
goo
.
1.52
, m 34
g
] it 70-5* ntidcr
lth'49
btAt 6
Cd
ttr
(COOI)i and
5
.
-
K.
,
w
y
oled snass with un soln. of 87
CO.; tMatident of the cL
fli CoTmh IijO and extri. with Cjllj~pve 6 fimn.,
under _N .100X'70~-taslly oxidizahk 8;4-4clljr?telhy!enr-5,r,-
(I)- 16"ICR54'

~Iiowevtr;
AF
-/o at~ htai6l 3 bm
wue ttuted'vvithlll ff. 100~
01-1
v
and t`jtd
ith C
li
t
t
d
ith
Z41J
th
0
.
riz-a
At '10-6
v
e"
e
w
.
s,
.
,
o
%
vm% oloalnNI rind 28.1 U; Niform-d dcrir, of
A041W', in,73'i-whivii hydfulyud w i-110 Is

- Imm"Im

III ~-M JOS, to 1. 1 (lit; g.) -.1m) g-1,4A I jw;a,A w, :I,, :,ir

aud 30 jjj j ICO,I I I Clot with 'Na,

73".
!JS
0 1.49;2, ti. A 57.9
'Id 1s Obtaim-d QAtCd all Cyclolij.
"
i Xannite) without kI-

oti, tesi.
tion of tile ubove inith -1 -.1
a 316t Ivact
1
With
TzO.11, btr4jud %vith S to 2 10* it gii Ii 44.6% lIb3. 11 With
pi.
394* (tmde), mu 400 Irom Me01W4eCb); -tile bruingle
%
ellh, gn-w-C Di I-C vC1Ojjtxy1,Cy1C~
htbLtcd .0
he~rne-; biiui 2361, tjV 1.49,tR;-d-. OX40, whicis tmatVil with
dry HCI in AcOll pve- 10%
aim. sn~ 30.51, also lonned from 11 md 110 in ACC;ll:- tile
Okfin with 1111r' gave the ab~)ve b
t S"
I
~f
H
20 da
0
i
4 romide, 11 Milt
I 50~01
d
U
j
- vve (
.
ys a
n
-)i
j(
--of unk-nown strueture:whickI contains txonti).
.
.
U J(*% not rVact
-a 2
A K, X

4
uted
-A Oslo Ai
!-,
a I-
-~-Reacdom 61:53 CH,:CIICN,-nnd =0 -j. licCH,CChlit-
*ith HtONa in RWH in 48 hTsi gave 50",V~ -,~iIIYMhOx

93CO0.5 IITL gave 7W0 4-oxacmaxilriN~ bLi JOS-9*, mV
1,4403. -This(JQg.)aad34 C., III OANarcfloxiid 10th 23 C
'"
d
d dfld
I(M
HMIT
tbt
rd
i
i
h m
6
e
i an
rmi
w
-~
a
A
,
t
oo
t
t&~ NaOll Ove.68% $51, wiliell
r ultd 3 hm with wned. Ila oM-&4WIROi4prOiC 4CI'lf-
-
6
. ~
A 24-hr.; maktica cit-20-8 g. (H.: CHUN
80, mu 1404
Vith 173 hleStCO in the pre3ence of PtON-u hi M01-1 jave
-
l ,
90 ra"ed N &~
) N 3O.'5 i
Wi 1COtNti ipid 20,8
in
HODR, CoUwwtd by 17.1'g. CHj~ CJICN -"d
t t Ve after nrutildirct-
and, btatlas O'W. bu I
'
'
'
I'
'
i
i!
W
c
00i
W" AOM -
a
rJ
S
46%
(1). bt I
Y
To 3D g. AcCII III W0,111 t and 4 in) - 10,
~a-MOH was nd%W at 10-12* IA 145 nsin. W g. c1fi:-
RIO.
CHCN; aftet 4 him, the Sol". was acitlika withAwil 4jul
dlstd~ I j0dizig 71 1h,
1044.6 . aj? AAW-). d,# 1.0518. Which YcAuxed ~j lim. with
aq, Mm.CO, pvt 21% 1. ba 142-3*-. 1 (11 1.) i~fiuxvd 40
bro. -Y," 18.41g. HCOjlI mid 27.1 g. IIC(),Na VIM M-AttAl
with 4-2 t, HCOJI itud rejIuxed 23 In, give titer utual
tftbllent,50% I-MdkYI4-4YI-6-PiPeridm*, bit' 1142-5%

Ramps-mum;
- ------- -- -
P;
lot, ~Alll -4- bkw~lic v'c 10~ .
I I I -I"'
- 4-
4-4-14 rid,
ne
1
741h
to
th
v 50
3
ar
p.
ln
,
g,%t
~
,
%,
p
)
Ili tal g. In"(IIII -11lid ;M$ R. 11CO'Na Rave 721~ji!
h j-dro."Ifijirdene, lij.- lfill-.. no (.qIr%Iiydro,;Ieflv. i~-41
faritted tr6h 11CIAII: 01111C.: Velluxilig. the firlithiel -willi I
concd~ 110 5 In. ji~ aeidoi
IICI jit -1734'. 6in which
i
MCV
In. Nvot hy Arl Ion n

To 10 X. I Ill: 31A, 11mi Allid 2 Ill , 1
lxell*CIJ~,*Ni M i I ON'
'
. wlileW
*011 Ams uddrd oiiinigh- Violl tn- Form it skilvt,
-nt &HP!, yleldW Ufter Cbric". Rod ilejitftlj~
heated 5 firs.
45% BzC11.C1IC0Xff,.*w. 125'. a 30%:jrield tt,,'
'
i-
1
f
nj,the n1fAe J ned,
1i.S0i 2 Firs. Thq
n Co I
f
oni k:Xi
9.) re uxed-40- hM-with 10.2 c. HC(hNm And 7,
&V
fter nf t
und M
e a
ar
S
Coped, NuOll, 4 te-i6:qm Ilia" which 11CAted btlefly
mrtdidvym~qni 108.
110 ave -30% 2-pAj~~YJ,6.p
Lf
lf) his. With coticil, JICI gave -"milr
acid-Ira, to. tw.
conditions gives Wj - ji- very-_. poor ~idd 61 (tie
lid
W
to f
r
f
h
i
t
ro
one u
.,
ti
litat
on o
ur.
RS
inuc
bin-APrOP1021itrile, Vith IICONH, amd it little
Ghoi- At 18D* gave a -m-d mlid, dc,~xxnp. 2W-,

KOST, A.N.; YUDIN, L.G.: SHIPOV, A.S.
Reduction by formic acid and its derivatives, Part 4: Reduction
of N-alkylpyridinium salts. Vest.Hosk.vm. Ser.mat.,mekh.,astron.,
fiz.,khim. 11 no.1:209-212 '56. (MIRA 10:12)
1. Kafedra organicheskoy khimii Moskovskogo universiteta.
(Reduction. Chemical) (PYriclinium comnounds)
ra-of -CH--20R---Uo -i= rins -crr- -15n=
Abstract: The ultraviolet absorption spe acel2dehyde) butYl-)
following compounds were studied: a)
isobutyl- and isovale-ziadehyde azines; b) azines of acetone
I), methylethylketone, me,thylpropylketoney CYClOhexanOne
RI)azines and mixed I and 11 azine (III); a) substituted Pyra-
:01ines and their hydrodblOrides: 5-CH 1-cHo-5 cH. 4 CH,
(&') 5 iao:c k,- ~-C&
5-cg~-, 4-isO-CP7-5-i,30-04%~ 4,4 A o- 1.4,4-
4,4-(CH3)2-5-isO-C3 H7-, i-ck o-4,4-01131~:5-iSO431~
V3 -9-
W' ---6ijfJ'j;66d'p it-was
under 225 M as c
I, absorb in the range Of about 230 M,"A (II'
exception Of IIn,,). it wae established that the majority of
absorbs at 230 p abOO379-tjon, bands: 225 tO 230 (log
the studied pyrazOline" hav(~ (ioga'- = 1 to 2) and thet, the ch-aTac-
3 to 5) and 320 to 330 m," ; depends litl;le on the substltlateu;
ter of the absorption C11111tmaition to bydrochlolldes is little
the spectrum change at the -idenecyclopentalione (V) was By-'Ithe-
-characteristic - CYcloPenty' cyclopfant
,anone L,.nd 96 g of
tized by the reaction of 197 9 Of Wt 119 to 3-2e
-is boiling), yield boiling Po:
CaCo (two hour . l.ol6q) n;-'UD = 1-5209-
at 1-4 mm, 136 to 1370 at P-5 M, d4F
Card 2/3 -10-

TIRW'YEV, A.P.; KOST, A.N.; SMXT, V.A.
Synthesis with the aid of acrylic acid nitrile. Part 25.
Cyanoethylation of indole. Zhur.ob.khim. 26 no.2:557-559 F '56.
(K4U 9:8)
1. Moskovsk1y gosudar8tvanVy universitet.
(Cyanoethylation) (Indole) (Acrylonitrile)

Win

4A.VA,
jPc-4M
Z~
lidrimel
. ............. .
lie POA
al.
it, -
Ill
~!14-71~~ *S.~ Afier
fWd
'All
IIJ 1wid,
Ifg.
7s Now
14~
RN
ITWASAM- ma~ ~ ..
VT1,
v-
It,rl
rlvp
v.
J,2

USSR/Organic Chemistry. Synthetic Organic Choriiatry. E-2
Abs Jour: Rof '"hur-Khimiya, Ile 6, 1957, 19206.
Author Kest A. N., Grandborg I. I.
Inst
Title Roactions of Hydrazino Derivatives. V. Synthesis of 3,
5,5-trialkylpyrazolonon.
Orig Pub: Zh. obshch. khimiyip iq%~ 26, iio 61 1717-1720-
Abstract, With the intontion of widening the possibilition of the
synthosia of' 3,505-trialkylpyrazolanas (TAP) tho rogroup-
ing of azinou oP anym3trical lcotonos, obtainod from the
hydrazono, hydrate of oyclohoxanono (1) by tho action of
is invo-stivated. With the
anhydrous HCOOH and (COOH)2 0
hol of the synthesis of 5-motlwl-3,5-diothylprazolono
(II~ by isomorization of the azino of mothylothylkctono
(III), and tho action of 96% hydrazinohydrato (IV) on
~-mothylhopton-~-ono-5 (V), the assumption of Curtius
Card 1/5
mixed azinc of acetone an(i 1~ Ik 'i I L I113 IJ L) tU A A A I .j
addition of aectono (Ijjjj~ in drop-. at 500 to II (left
rtanding 1; hours at 50-55 and adding potassiuv. carbonate
and other). yield of VII 59.5;'J, b.p. 96-970/8-9 Em,
Card 2/5
USSR/Organic Choraistry. Syntliotic Organic Chemistry. E-2
Abs Jour: Rof 2"hur-11(himiyal No 6, 1957, !01206.
n20D 1-14938 1 d4200-91"79. 3itaultanoottaly aro obtainod
16 g. of azino of acotono (IX) and ," 1 g. of azzino VI.
Fron 2 M0100 laothylothyllcotono (X) and I nolo IV ( looo
2 hours) is syntliosizod Mp yield 39.5,4,, b.p. 108-1100/1,25
r,m. Analogically are obtained LX, yio Id b.pe
129-132/753 rm, n2OD 1 45'3 d 200 .8434, and azino of
mothylpro ~ (~l
ylkotono XI )660 A hours), yiold 79 8%t
b. go 9 722 mo 100~/25 m, 1300/81 rm, n20D 1.4~65,
d4 m4oi, 3,3,5-trimathylpyrazolono (XII) is obtained
by tho addition in drops of I mole of IX to 1,1 Mole of
anhydrous (11000) and by heating (1000, It hours).
Oxalato X11 is d9composod with a avrpluo of 4M, solu-
tion of KOH; tho yield in XII 78%, b.?. 52-50/15 rm,
n20D 1-4573t d4200.9025.3-raothyl-51.5-pontcL,-iothylano-
pyrazolono (XIII) is synthosizod avillogically fron 60
F. 'Fol, yield 5051tj b.p. 125-1320/21-:.',.2 =a, n2OD 1.4975,
di, 00.9830. The acotyl derivative is XIII, m.p. 860

butyl--(v1I1)--5'5'5-trD1c ntlIC3ir, according tO ~jzhiic:r
in datjrmin,d by counter s7 o A-urc
and hydrazinc hYdrat'-; otrucL
fi-OLI 1107,itYlOXId' also accom-
bonzYlRtion VI. Tho cyclization of I is
0 ar d 1/3
USSFt/Organic chordstry. Synthetic Organic Ohomi-stry. E-2
Abs Jour: Rof Zhur-XhiniYm, No 69 1957t 19207
piiihod by hoating (2 hours, 100o) with the hydrochloride
VI (VIa). To 11.2 g. of I is gradually addod an oqui-
nolocular amount 11, the nixturc is loft. standing 1-2
hours at 200 and 5-2 g. hydro.brorAdo VI, D-P- 1700 (from
ale.) is soparatca; tho rest is hoat,A I hour at 1000
boiled 2-3 hours with 100-150 cc 21-1 1101, and alkalizoa
and oxtracted with othor VI, yiold .2 g., b.-p. 65-69119 rm,
n20D 1.4571; picrate, ra.p. 134.5 and VII, yield 18%, b.p.
77--8CP/19Ivm, n20D 1,4676, di,20 O.i:~957; picrato, n.p.
86-370 (from ale.). Analogically f-roll III is obtaincd
VIa' y1old 1 g. m.p . 171-1720 (from ale.); VI, goncral
Ylold 51ri'o, and VII, yiold lg'/"3; from 22.4 a.. I and 2,7.5
g. IV (hoating 46 hours at 90-1001)--VI (traces.) and
/2 b.p. 700/6 nn n-C)D 1.4551. d 20
VIII, yield 38.7, 4
11 ~ - T -A ip.6 -?. 11(hoating 2 hours at

KOST, A.N.; GRANDBERG, I.I.- GOLUBIVA, G.A.
2
f
Reactions of hydrazine derivativea. Part 8. Cyclization of
aldazines by alkyl balides. Zhur.ob.khim, 26 no.9:Z604-2607
S 156. (HLRA 9:11)
1. Moskov eki osudarstvennyy universitat.
(A21nSB~ ~Oycllzation) (Alkyl'halides)

rc)3 T, ,v, A,-
TARICNTOW, A,Po; KOST, A.H.; SALTYKOVA, Yu.V.; Y=11OV, V.V.
S.lrnthesis with help of acrylic acid nitril. Part 29: Cyanoothylation
of norm ketones. Zhur. ob, khim. 26 no,10:2925-2928 0 156.
(MIRA 1113)
1. Hookovskiy Gosudarstvennyy universitet.
(Ethylation) (Ketoneu)

WOW mad WAA
07, j*MHQ
3ho
1-3
CH
goU

ts
bdow =-=j6vbb-AtWkT bw
bad i'mat
,
al

t i

i., I-
, (' I j pi
) 'I
" _,;, / )CLIF~MSVYA, . GRA~MRG, 1. 1.
Reactions of hvdrazine derivatives, Part 10. Absorption apectra of
maines and pyrazolines. Zhur.ob.khim.26 no-1133135-3138 N 156.
(HIBA 10:1)
1. Hookovskly Gosudarstvennyy universitat,
(Piridine-4pectra) (P~razoline-Spectrpk)