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SCIENTIFIC ABSTRACT FR:KOTELNIKOVA, A.V. TO:KOTELNIKOVA, V.P.

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CIA-RDP86-00513R000825300013-6
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U
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99
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November 2, 2016
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13
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Publication Date: 
December 31, 1967
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SCIENTIFIC ABSTR
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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 savJ2a-~?a-~.-52/5a Separation of Adsnylatkinase and Nucleos:lde Monophosphatkinase From the Prater-soluble Fraction of the Live~~ experimental methods were the same ae in reference 1. The fol- lowing oonolusions may be drawn froca the investigations. Thf~ enzymes adenylatkinase anil Numoki could be completely sep- arated by fractionating the aqueoum liver extract of rab6it~~ by means of alcohol. Adenylatki.naee is contained in the frac- tion of a-2a~ at~d Numoki j.n the fraction of 4a-5a~ oi: alcohol. It pas for the first time that these enzymes could be separated. Adenylatkinase catalyzes the phosphate transference only among adenine nueleotidse. Numoki apparently catalyzes this reaction betpeen nucleoside tripho~-phate and nucleoside monaphosphatel under the ti~lloring conditions 1) Nucleotides of every coulllr~ have to contain different bases; ~) one part of every nucleotide couple has to be an adenine nucleotide. Enzyme preparations from hog kidney (Ref 4) and calf kidney (Ref 5} showed the obligatory participation of adenine nucleotides in the numoki reaction. The diets found prove these conclusions also pith regard to water soluble Numoki from rabbit kidney. There are 3 figures, 3 tables, and 5 references, 3 of which Card 2~ 3 are Sovie t APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 17(3} ~OV/Za~~ze~~~-yz/5c~ AUTIiORS: Dovedova, Ye. Lo, Kotel'nikova, A. V. TITLE: Separation of Adenyl;~tkinase and Nucleoside P~~onol5hosphatki:xa~3e Froru the Water-soluble Fraction of the i,iver PEItTODICAL: Doklady Akademii nauk SS;iR, 1g5y, Vol 125, Nr 1, pp 1~~~19'j (USSit) ABSTRACT: The present paper gives clata on the preparative separation of the enzymes mentioned in the title. The reparation was cau>rjed by fractionating aqueous liver solutions by means of alcohc-I. 'i'he substrates u�ed were; adenar~intriphosphate (ATP) and adenosin-5'-phosphate (AF'P), purified in rectifying columns from commercial ATP by means of anionites AV-16 or AV-17; uridin-5~-phosphate (UFy), produced from yeast and purified by means of AU-16, as tivell a,~e imported; inasinw~~ ~phoaphF~te ~IFI'~, guanosin-5~-phosphate (Gl='P), uridintriphos~hate (UTk) - im- ported goods for sale; inoaintriphoaphate (ITF'), made available by V. Z. Gorkin of the In.stitut biologicheskoy i meditsinsk.oy khimii AA~N SSSR (Institute of Biological and ~~edical Chemistry AMS USSR). The reaotion to nucleoside monophoaphatkinase Card 1/3 (numoki) wF~s mainly investigated by means of UFP and ATP. The APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 On the Specificity of the Water Soluble "Adenylata" SOV~2G-123-2-33/50 Kinase From the Liver showed any activity. It nigy be ooncluded from these results that in aqueous extracts #'rom the rabbit liver the "adenylat~e" kinase (speoifio for adenine nuoleotid�s) as w�ll as the numoki are contained. There are 3 figures and 12 referenos$, 3 of whioh era Soviet. ASSOCIATTQN: Laboratoriya fiziologiehaskoy khimii Akademii Weak SSSR (Laboratory of physiological Chemistry of the Academy of Saienoes, USSR) PRESENTED: SUBMITTED: Card 3~3 July 2, 1958, by A. I. Opa.rin, Aoademioian June 26, 1958 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 On the Specificity of the Water Soluble "Adenylate" SOY~20-123_2-33/ 5a Kinase From th� Liver (like numoki). With the yeast enzyme it was proved that numoki is different from adenylate kinase. With liver enzymes this proble>!m remains unsolved. The authors investigated tl'ais problem in aqueous extracts from rabbit liver according to the method given in reference 1. Figures 1 and 2 give the expeximental results of the activity determination of the "adenylate'" kinase and numoki in one and the same liver extract (treated with FiCI). The reaction products were separated by paper chromatography and quantitatively determined. From the results may be seen that the watex� soluble liver 1'adenylat�" kinase is, like the myakinase, a specific "adenine" enzym� and differs from numoki. Figure 3 gives the results of the activity determination of numoki after the heating ofd the dialyzed aqueous liver extracts for 2 minutes at 60 and at pg '] (R�#' 12), The numoki reaction was clearly shown. The negative numoki reaction in �xtraat� treat�d Kith HCI were explained by the higher re$istanae of the numoki to heating in ~leutral medium compared with that Card 2 of tho "ader~ylate" kinase� On a heating of the extracts up ~3 to 80 for 2 minutes at phi 7 neither of the two ferments APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 17(3) AUTHORS: Kotelfnikova, A. V. Dovedova, Xe. L. S4V/24-123-2-33~'Sp TITLE: 4n the Speoifioity of the Water Soluble "Adenylate" Kinase Fxom the Liver (0 spetaifichnosti vodorastvorimoy adenilatkiraazy iz pecheni) PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 123, Nr 2, pp 327 334 (USSR) ABSTRACTS In earlier papers of the first mentioned author it was proved that th� animal liver contains the farm+ant (phoaphomutase ADF) mentioned in the title, which highly differs from that from the muscles (myokinaee) (Ref 1). Since in living organisms free nualeotide~s were found together with others, as adenine, purine and py:rimidine bases (Ref 2), in animal tissues and in yeast enzytnea (Rafe 3, q) were found that were called nuoleoside-~mo~aaphosphate kinases (abbravis,;tedi numoki). They catalyzed the phosphate transfer from nucleoside triphosphate to nucleoside monaphosphate, haweve;r, with different purine- or pyrimidine bases. In this con- nection the question arosE- if the water soluble liver "ader~yiate" kinase ie a e~>eoifia "adenine" enzyme (lik� the Card 1/3 myokinase, Ref 3) or if it is specific within a wider range APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 USSR; Human and Atlimal Physiology .. 2~~~tabalista. - T ' Abs Jour Rif Zhur Biol . , 1Vo 3, :959, 12531 which possessed a hig~i s3pectfic radioactiivity. Hy a studf of the propertieES of this substance it was es- tablisiled that it CpntLtined $--Sgroups ui~d the proper- ty of coenzyme A ~t'~e e~bility to catalyze acetylized anino-a7.obellzene. ~a~he recovered substance was different from phospha>"yl coenzyme A 111 that it did not vie a po- sitive reaction on the free SH-groups after treatment with alkali and had a Ciefinite Mobility with paper crlror:.atography t~sitig N-propanol--NH3--H2O as the solvent. -- V.I. RosPt~gart Card 2~2 . 21 - APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 USSR/'Hw:gal: aid .Lli:~i~a. !~Yaysi.a~.c~gy - Metabalisl:t. T � ~ Aar Jour Rei X~hur Riot.., era 3, 1;~5~, 12531 Author : Kotel'nikova, A.V. . ~~ Fast ; A5 USSR Tittle Role of Metabolites of F"senzi~ A in Phosphorus MQtabai.siri of Liver of Ar3ir~aly , Orig Pub V sb.: ]:z~~ch. zhivotn. organizr~~a. M., AN SSSR, 195, 83-95 Abstract ; Rats were in,~ectcd With phosphate P~2; after 15 3a riita~:t~.s the an~,m~1F were sr~cri-(iced, the livers were rerwved, and After prec~lpitat~i.on off' the protein with trichloracetic acid the fra~ctio~r of Ba-no~~-soluble phospharus co~ipoalds wa;otel'aliknva ;Anri V, U~ aPYr'$se in Po A 1s!ly~Aknd llydrtk'�~~~~.5;~ ., ~, 5aiornatinn. Duk� cnncerr~ccl a~ith trlrrtsf~ttls,itat g~~rl ~acle -~it hhosphu~to,~, ttuttteiy (tnYro~; un,t Irt~Ic) pllu~~shrlt~lfic, wei~ , t ttti~crls nt ~urlau~ vur,etli~s o! tidttltges,.. A ntntt, in the terem~e Irt the ~nayrttic nctivltiex nt ~. ectaeki~ruble dU~ taitgti, lnclicatLig A` l~ptieuiar! ~`ttrictlea studio was ucttvtty ut the sitr ~' itnportunt mk M apYrnsa' sh~rch xyn hesi~ tsk~ iiu~r r ~evrtgpraent at winch intefta;ive i . Cen~ tasJl~j the Y~rietles with lase s~itrc~h tttertt hav~iaw apyt~se act vlty, starch turttla shviv ~! illb'}j activit o whlk the high. A htttas> ttttivIt it/A3 Y l the entyme, ~ vim; y es~entittlly the $ame lp 6111 i ~; ~ !,+:: APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 ~ttTFL!pIR~Vd, ~. ~. r i ah~�~,aa~~ Ab~~. a3,a~.pgiaal. 41~mi a ter j: 1~ ~ puadoa aaa propett[~~ a ~~ ~ir~-~ ~r~~ xe, ~ vat ~xts , in thg a-1t118 v~ai. m ne, ~n ra41 nau. no etreet do tha t~tivity o~ li, ~~'he ttoi115ed p~"ocedurd aiforda a 12-I~�foid putificatiat accompanied ~y ~ a 2~-~2-foicf'ccnwen, itt tht activity df the I. Unlike the nc~a� pttritlecl pct. the ptirlliod I is anatabie_in mcdltt ~ acid dnd neutral ccactlojn~ and i:E mote cagily insctixatett` by CCi~. C~al~t. Tits tttability of I in ndnpudtjal recta, is d Rprclfla ataltill:er- a>ut not to tuty atruc~tttcal dli'F ~>.+ i-~ta activptrn I up td OU-96~. B� 8. Imo' i~ 1:, APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 KbI'EL ~ N'~K4VA ~ A. V, tiSSR/Biology {Agrizculture) -Starch From Potatae8 Sep/Oct ~, ~~Starah and xta Formation in Fotataes,n B. N. 5teparienko, Ye. L, Rosenfeld, A. N, Petrova, A. V. Kotel~rikava, Moscow '~t)spekh Sovrem Biol~+ Vol XXXII, No ~ pp 193-'31 Potatoes are s very important crop in the USSR; 7.7 million hectares were planted uru~er potatoes before World War IT and the acreage was ~~ higher in 1850, Yield from 1 hectare corresponds to 1,600 liters of alc, which may serve as raw material far synthe- tic rubber, While yields were raised by 21$ during the past 10 yrs, the starch content i.s often inadequate. A number of interesting investigations on starch formation in potatoes was carried out at the Inst of Biochem imsni $akh, Acad Sci U5SR. This wank and other data will help in raising the starch content. Reviews in detail the present status of the problem of phytochem starch formation. 198T1 p APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 ~Oi'KOYA d. P. -_~--w--~-..~,.~..,..~_.___., 6529� RCOTBLNIKOPA A. P. Machan~isd oP transfer et the adenylic system of high-anerg~- phosphates in yeasts Dckladi /Yade~aii Hiwk SSSx, Nesaaw 1950, 69/6 (83q-840) Tables 3 '.Pwe pssslble traneperting aechaaisns �f high-oa-ergy phosphates in yeasts: (a) A phasphemutae� ~' be sup}�sed to ecL kb) an en ~ utilise adea~pliq acid (i~aatdad et ADP ar ATP); t~yme system, stiXl unknown, ~ exist in the yeast sell, ade~rlic acid playing the role of a phosphate aoaeptor and dDP that ~-f a phosphate decor. d phosphemutasa ~~ould require the presence �f hexekinaee to 11u-ctien as an ensyme system; direct aaperimontal evidence ter a phosphomataae-transporting mechanism was obtained by eepa- ration at the two enzymes in a ;~eaet extract, by 3 minutes' boiling of the neutralised solution, which reduced hezokin+sae activity to ~ of the �riginal value, whereas the X-hosphoa~ntasa activity was redu~aed only to 61~. The tact that yl~ast entracte could split phosphate e!P ADP in pros,�nae of myosin m>ay be regarded as further evidesoe In tavour of a phosphomutaee system since purified myelin splits only one equivalent of phosphate from ATP and does not split ADP at all. Magnesium ions were toned to eat as efteators et yeast phosphamntaea. Zagreb S0: I~xcerpta Modica, Sectiea II, Pel III, l~0 12 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 t ':}~ ~~ a '' rr~y a ',;9C 7 f ~;-..y. ~.~ 51~d. # . ~ ~ , . , i 2d ~..sdek y~ {~{ ' , ~ _.. o- r , t- ~ _ ~ c 1 ,*.." 7 i T � ~ ~ 1 .. ~ 4 < ;* ~~� ~ ~ ' - sj y h ~ i ~ t t_'~ . # f L `~ - f _ ~ i r. ' .rt;... i ' J' ~ - r - ~ ~. i ~ !. r. ,. ~. ~ i ~~I S~ ` ~ ~ .. ~ ~ ~ ' i i ~ ", f t .. .. ,. . ' . APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 i ~ ; t 1 ~ 1 ~ + i r ~r a; tt t! !t ~t ErE t~ N H ~ ;r ~ it 1d ~ ?~ >i .~~ ~ ` x, tt t: u w a r ~ ig r� a: .c e: ti a is E; � A 1 .C .A..C-.,I .3'e....$_.1,. ~,, f. .+! ~ M fi R 3 T ,,.~?. ii 2..; ~ ~_.M NA {~ GU KE' y t e. t l a t ~ - + � r r + ..~`:+� (lf �� rif' ~ ~._._.. _ i:9 ::s� tit: [:rt:4isy r~ . r,- , ~~� R1 p..~ .-.. ._ r'kCr~Ntt�t.AK4' ~RERFilitt fy~~:At - =+~r� i ,,/~r~~ ~ t !� .~; 'Chn p~oopkamrixq at ndeao~fa+edlpha~fp~hal~ ttcfd fn u�~ �� ` rAAldgrl dl~Y~ti, ,~ .. tiI fltrnkMltnfytt 11, �,�� t 144-t~1(IU4Sj. tif.� . ,, ~~i~wiektutt) ft~t~kur, �� ~.. C'.~i. J . ~1~itl6N:-{I'6aephtxnutua~r (t) tat myc>kiuusr u~ `�p i� >>~ tirsi~ttatett by otl:rrttj of atlenonunctiiplt,~lth:ttc 1. vtt+lefy } a diRtnhutcd ht the animal orEnutsnt, ra>cc�iully in thtti;r ; ~~� � � � >f ~~ ti.xnc~t invnivrtt in un iutenxr rnec~y nu�tnlK+ti~ur tmu~~lr, ~ ~ ~. �� t~f liver, ltrgrt, kitlurya, crytttra�}�+ir+>, The arltr,~ih~ r>t I ~ ~ -�� :1 Ir Juat uF >errnt in Ihr rxtn. ~d Ihe~u auiluul ti>,sur. ;t~ iu ~ I � � ~! y nutx�Ie extrr. Un treatment Mwh IICI, the ,u�ur�tty ul l ; ~�� ` itt the e1it~. is retuittetl, wltctrctq tree ndruusinrJrfrhrKtrLu- ' ; �� ~ , ::�� ~+':~~� �� ~~ turf tu�tiMity Is r,~atupletrly dr*tTr~yrd. 1'he urttritY n( 1 � � J ` ix utxt minined by bnllln~ the ezt, In unit wdn trw a nht,t+ ~ - ~ '"� � � � ~~ Nntc. E{olllttt In ttcalral medium rantpletrly dr+tru-r ihr ! ~i ~�� activity p1 I in trytbracytcs and liver, nnrl mo,t rt( the � � a artivi[y in the heart and kidney:r. I!. I'rirxtler~ ! , ~ �� �. 3~~'_ p i ~ u~ 1~~ ~ � + ~e� R;A ~ a �� ~~ ~ ~ ,� � ~~i i~' v -sr ~i + �trA: ,. n. at f�~,ctra~t .tatsrttt4tiuis c; "r�� iff~tf~ ~ ` L.:UM; �,r i.i � s i ~�. 7 u t1 A'- ttr! o f~ r 6 1 w � - ~ t r., t i ~ t i 1~ ~ ~ `: 1 A r l t 4 M r ~ r r w P". ;7 9 ) M t ~, Ir u n n !t ;- ^- et to tt yt tt K tt tt tt tr {~t# ^ l t. ~ � � i � � �;� � � � � � � � � ~- � � � � � �+� � � � � � � � � � � � � � � � � � � � � APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 RO~~NI~O~'A, ~. V.. Yi~1:7/4i7rrFtAl~a ~~~ 1:iZ ~~ ~x ~ ~rN~o ~'~~cm~ ~~~~~~~ ~~m~-~~ ~~~~ ~~ ~~~~~~ y ~ ~ ~b'iD ~~~~ ~'~ M~~a~~ ~~'~"~ � ~ ~ ~ ~ ~ ~ ~ ~~~ C1' ~ IYI Cf' ~! ~y C.i. ,q ,y, m ~ ~. `t?' ~~ ~~ rime ~+K ~ ~~� a4 ~,~` ~ +~ ~-, ~~~ r Nh w m t~ .~~' c~: ~' m m ~ ~ . ~ a~ ~ ~ M ~ ~ ~ m -' b ~ ~ -~i N ' ~ ~ v ~ ~, ~ ,~- ~ ~ A` ~ ~~ mm~ ~ ~ W ~ ~~ ~ b CD O CF W wa~+ ~ a a~~ ~~ ' ~' ~s ;~'"- ~ }'' : ,~,. tx~;. a tAl 0 N H O (v P~ 3b/~49~ ~~ ~+ ~~ ~~~ ~~~~ ~i ~ ~~~ ~~m N ~~~ a~$ ~~~ b7 F~ ~~ a~ ~~ a ~ ~~ ~ ~4 ,~~,M~ m ~ c,~ ~~~~ a .~ � � ~ ~~ ~~ CI Kb is F4 k~ �� ~ ~ ~~ O CG .~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 t 1 ~! 1 t! t M tt tJ !1 M h N !t ft' 18 ! �� ~ ~. -........�h,_,..._.ti-�..............R-.�._.,._,.,...,...,:....~-.~~..RrKflAbrl 4ap.pMllBliatrlSyt4utt ..~ t~. � � w #ii ~� ~ V � � +~ a iA�iiiiiii�iiii+;~ tin#! uu,,,>a>su>.a~ru~t+lu~bi~�. Rl.f.+t....l.:.z..:at e~rr,~.,r i ~� ~xu~.~stt .R, r .~ __~...,,,,r.�! -., t ._ .. ~� ~~. , � � 1 ".: ~p~omutrse of Itdenotinedipdosyhltte hom ttte W, Htrer. A, ~~~~�,lik~~~., Unk+'ady :Ikud .look ~ � l a ~ .`.S.S.1(."84; , r --, !`I-~fTi -'" ~incc� myukin~rro iti aidrly � ~ ~) ~ diatributlYi, thr Hume Ai3i~-Mu�phonluhl.c� i. pnrTx>5cr1 ~ it wtt~ frntnd in the liver cst, of the rtl,bit (h�rhniyuc �� , ~ `' similar to iROlation from the olusrlc tixtiuc) x�ith cxtn door ~ ~ v i by water or tl.l .1/ KCI, us vrril as in 11.1 .1! I:CI ext of rabbit hlcxxi (slightly Irx~ active) The principal diffrr- � � S rntr of the eneyule ~Irrlnt hu~n liver nt from nnnrlr tir~un, �� u Grc in str-bility to welling tr,ttrr, !hr ln�rl rllr~'lue II++r: UrglWly III li Itllll., Ihr m11 v41c 1'Ilf 1'Illr i�c Itll,l tfrr(t�tl, � � 7 sucltlnrly it i~ Irss stahlr to trirhlotruu�i�ue arid. �.� t (: 41 F~rnulapnff r~~ 1 ~f ;~; ..`._. ��; 1~�4'N ~,a, ~; ;,; '' w 1,. _ - _ ~~ i~1 A;A SlA YETAIIURGI[Al LITERATURE CLA1flfICATWN ~~ ~;~ _..,~. ~..n_.. - -- _. . M111~lANtc Xi SL At+ 10 p i . , . . . r y t r . t . + ~--i----~- 11 a t- tt rt u a K a it a ~r hart tr ~ � ~ � � � �~� � � � � � � � � � ~ � � i � ar� ' ��� ~~�# ~ ~�~' i t~�s~ i -�� � +�� as� � ~~� U � � ~, "'��/ ~~ `. � � !ri! ~~Ir�� ~ '~ � z~� Id� � ~~�� y t:S � � ._ . _. . i04r e?w Inc _ ~..... _.. ( ~� � a n i ~ ~ "" i s -r_ a ti ~il ` ~ i ii it t- ~i i �~��������������i������ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 ~. *:; ~ir�ir��i�~r~^s.~ ;;~ ~.~:;:~ ~�~ ~ r i� r r r r r� r r r� i r;~ . r ~;#~:l~ ~..i~ ~_r:r.-~ ~ ~ ~i. aa u xt~~at~u ~*~ri ~ ~~~~~~ii~ ~~ ~ � aor u!! ~~ N i! M I ~ ` ee i~qN ~yy~ ^~ wa>w ~� * IR ...~-.~..e.t.~a rM tlk t ~ . ...~..r. ++ ^~V_. o~ ~ o fi ._~ ~~ ~: . M �+W i ..V . . I~r ~ s ,,,,..,.,,,..,.......�...... _ - �sa~t~-rut ~1vu ~,.._...,~.....~.. ~N ~soctlztt ~ ~ ~ .. . w_...., ..,._ ".__.._. ~rr ~~ it ~ ~ rr # ~ ~~ ~ . ; -rr ,fir a i ~ "rrj ' ~~r ~ i ~ ~~ . ~ r! * ~ ` i ~ ~ of �drnogine~l n[ is .cla isp ~ aon+>d*~~t.Al(w� ut ~1# 1 ti r d ;~ A ~ I h Mrr 'fir' i r 1r~ ~ yI + e r+ ra . taleruN, ~,A.r~,1r;.~~.''n-::; . ' rr � wi " t 4 ~ 4 row). NaakA-Nt/rii 13, iitl iblitNK). .',t.�ta)luig lu 11.utR:i tiG.A, 41, 1300x), there cxistg in tuurclr an eniyme ahirh r, .~+ ~~ � ~ I ' ~ rft4iytes the tran~azmatican of adrncrsinec#iphosyhoric . e H � r r S ~ i ~ , siyd p) Iato na isomer, which ~ti{Icrb frntn the originui in .~ of iwmeric form, rn 'fh � f ~~ � '~ r d ~ ~ ; ; ` ; ; + e prcs its relat#on to ensylmea. al' I h~ aat #xea Lnafinnrd. !#. Priestley ~ ar ~ � � ~ r ` ( ` ' err ~r , " =rr 'rr ~ `' ~ ` err rr ~ ;i m rrr ~ ~ ~e � sa > _~ r ~~ifi "` I=r+t ~~iJ{ 1 ~~ Is - ,_ _ -.... _. ...,~ ~ , arr ~~l e.� ~.. .~.. .. r ' '~ ~~"'~ ~ '~ ~ A ! [ . ! L A [tTJ~LLUR4N:Al Llltk~4411t ~[LA111t'iCA11QN ~ - .~ - ) tna~ saNt~r ~[ ~ f t sotx t i *. r ~ i Y ~ �__._-__,.~.-.._.....a.�...~..-..-..-..........,. ,.... - . + t t ! ~ twi ati v 1 t t _. .~�i ~jr ~ i-#-?~' t..w�-~-++-^~-_~ ~ iM i.t i:) rN1 ONY 0~[ M17 t11 Mt~ -. - - ~,,~,~�~.,..:,..~., r ~ .. �;.. ~ , ~ _. _~. _ ~ .t_._ ~ ...~.,...# ~..... ~ ~ t M - s r nr a M' , ; r ii ~ ri ~~ a ~ s ' ono. u 1n Ar ro t! ~ a n n n v o- w rt n +t st K p tt it o! n ~~ zr r ��~rrrr~~�sis` ii~iiiiiiis~i~~iiiiiii~oiiliisiri~ r.r~rr ~___-- APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 1C0'Pl"sL ~ rJTKUiI~, A . V. ~~ ~�~~, ~~~ ~~~~ � �~ ~ ~ ~' m a~. ~, . a $~ ~~~ . +a ~~ ~,: 0 .. f'' ~~ ~~ ;~~~ `~ , ~. ~. ..~...... ~h ~.d~K ~~ ~~~ a :~ ~ ~~~'~~ ~~~ '`~~~ ~~ ~ ~~~~ N' N n ~F s ~ y: ~ ~, ~ ~ ~ $ ~ ~ ~ � ~ ow `~ ~ a~ H ~ ' f 7 A ~~ � ~ ~'~~' ~~ ~~ ~, ~ ~ y ~ ~~ i ~a ~~~ ~` N ~ ~ � ~ ~ ~~~ ~`~~ n@ a.~~ ~. ~ ~ ~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE: 06/23/11: CIA-R~P86-005138000825300013-6 ~+. ~,,,..~a. ,~ i _ .~,....,......... ` Nx r R Th 11 ~tiW~} i 1 e#l ~ i ~~ � .~ i n Yn r , ~4 , - ~ r rli trir a ~ urelt is h~liiul~tk r+lptr, xlith i~r.>trtt-� t~ ~ t! tulw kacrwn of cltttrfllt ~ ewapiry taint. ud pltlAev>t~th ~ r ti 4 PNliytita'U. fytr~lae tart 4t{ittlllt trrrr luratrti is yta-�t in rtiCUt ui the uir~t t tl k ~ t ~ ~ ; ryp - ge s t gtaltntiti~ tai� P* ~ ~ l .i ~ ~ latt~n~t, t-ttw't'xut taait~u a-~is, liter pnntittr tali pttetl+lalar, .rrtr h~in11>rtlr~l l-ai>! with lttiii+~aitir. � il! ~~;;, it:~ptti. wlth e~L~t. tc~dxl rrfih cr~rill~ r'linla �IINi airYtllt Nii~l Nlt~ tI1-r t~- (hr t Y ' ih kll h l ~, r~ ~ ~ ~ t il P li! Bttt~l 11~-ft l A9' NAl l d ' tu ly iUlpt~tilct+ tit!cittttAttagto t {~,da. ~~, tt~At11 � ! ~ ~ ~ ~ ~` trim 111 d the tYn ftwa re-+e~r~t ~i ,,, f~a- riiuw 1=nx ti~{lkrptlxn w~Y i~trtAl�tvl t N~ traa e~k+tb- � ~ ~ , . arK +all>� ttx~lt 6t>rta Na tm i~fti ww+ t~lrtltCtt tlxan Itny -+i � tli +~ ~ + ~ tli~r pr-Nei�w, - ti 1'tkst~ ~~~ ! t t)] r'u , ~!'t r :'~4 KJ~ Wi wl Q i ''-:'Fl : A ' E t ~} .~.^ir.'~ i ~ l .'. !~J :�i , I a4 to ~( A 1 Y S 4 A Y11Al4UROKAI i IttllAttr'1?E CIASI~'ICAtIgN e ~ ~ _ .$ ~ ~-.:""'-'""'-- ~ 1M lUYJ 11l! UMW dYE Y1l t,lnr~sla ~ - 11 tt Art !D It � ~ !- t1 t/ N Al k M tt X 91Z N p 1t It it ~i1 ~ ~~M~~~ ~l/~ ~`i] ~tlr~~r !] >: ~ M ~ ~ ~ ~ ~ ~ tt At ~ N a~ ~�~--- - i .~ !~ iiiAle -- -+ nliil7 Awt pNS lii R 1. lu ~I~~iflii+~ ~ ~~ ~ ~iit*~~~~~~~ 1 w~~ *~~ ~~'#i ~'~ V i~ t~ t *~~ w it ~: ~~~ ~~:. ~, :''~~~~ t: ~ ~~� a~i ~wf ~~li~ i Ai ~; ~~i! ~>+~� t3 i~ ~~~ t~is ~ Syys ~ .e.~ i~ ~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 7~n,3_~...~a~~8 Inveratigatian of the Campl~ex Compounds of Bivalent Rhenium . compounds of other valence t'rie a xtraotian method from aqueou~~ hydrochloric solutions witr~ organic solvents was ~tsed4 In this it wag :Pound that the best extraction of Re '" Can be carried out'with such orgaa~ic solvents in which C 0 occurs(; logo pinacol;iney aoetophenone,, methylacrylate~ dimethyl= phthalate and otherso Some bivalent rhenium compounds were isolated with methyl alcoholo ~n the reaction of H2ReC1 e 2 H2O in glacial acetic acid solution the followin~4compounds form on addi" tion of methyl alcohols .. Recl2 0 4 cH;scooH ReCl2 0 2 CH.~COOHoH2O ReC12 o CH3C()OH o H2Q ReCl2 4 CH~COO~i On the action of ReCl2 ~ CIt COH with pyr~din� ~: ao11d sut,... stance of the following cora~osition is formedR ReC12oCH3 COL~H.py, Card 3~4 'rhe thermogxaphi.o investigat~ione of the derivatives of APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 Inveati~ation of the Complex Compounds of Bivalent Rhenium of ternperatt~re it dscompaeea fo~ming oxidation products,: ReC~.~ o ~ Hi?Q on heating; to 1~0 C oleo looses 2 mol water forming ReC:[ n2 H 0~ In theaQ two compounds the water can.., based on thE:2experimental .resutts4 be regarded as coordi~~ natively bound, 'She formula is given as follows: ~~ReC12 n(H2Q)2 l a 2 H,,Q and ~.Recl~ (~i2a)2 H ReC12 ~ 2 H2O undergoes some intermediate compounds with the beginning of hydrolysis; these intermediate com~ounds .~ were also i;~olatedin solid forma Hz~Re(OH)3C1~ H2~Re(OH) J ~. 4 ReCl2 ~~ 4 H2Q and ReC12 ~ 2 H2Oo A1eo some ac;idous salts were isolated in solid forma KHReCIQ� o H2O9 KHReC14~ NH~HReC14 ~ H2Q and NFi~HReCl~b (PyH)HReC14o In the treai;ment of H ReC1 �Q 2 H2O PyH HReCl!~ forma with pyridine in cidous e~iumo4This compound can 2asilY be con�- vented into ~Re02Py C1 in the evaporation in air Re�II transforming ~.nto R �~=V on this occasiono Card 2~4 For the purpose of separating bivalent rhenium from rl~ienium. APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 7~..3~~_3q~3~ AIITiiORSs Kote1�nikova9 Aa Sr.g Tronev, V~ Gp TI~~L~s' ~ igatio;n of the Ca-uplex Gompounda o,f Aivnlent Rhenium (Issledovani;y~e kompleksnykti aoyedineni y dvukhvalentnogo reniya) Y~RIODICALs ZYiurnal Ne~organicheskoy Kh:Lmii~l~ja,Vola3,I7r ~,ppo100S~~10?j (USSR) AIISti'RACTa The Complex compounds of rl~enium-II were produced and invest:i�- gateda From the experimental material followss ths,t by the reduction of KReO in concentrated hydrochloric acid solurv tion with gaseo us4hydrogen and under a pressure of from 100 ~ 110 atmospheric excess pressure and at 300�C solutions can be produced in which rhenium exists in a bivalent form From the hydrochloric acid solutions of ~ enium-II with acetone solution the following products were isolated by crystallizations ReC12~q.H2O and H2ReCl 02 H20~ Thermographic analyses were carried ou~ with these compound s ReCl2 b 4 H2O has two endothermal effects at 150�C and 398oC~ Card 1~4 H2ReC1~ 0 2 H2O 1c, ses wat~ex at 15OoC and with a further rise APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 f i i j( !f I 1 1 AP603341g ._._._.__.._._____-------~.,__~.__.~.,.__.. ~_-.._._..... __... _.__- difforent opQrating conditions: the dust ~ ...__~__�_..._ .._.__.~._ _._.__.~.~,~ _._.~____.__ _....~ the magnetic field strength rant ian of thc.~ discharge was 12 ' varied from fi bed from 12 to 25 kOQ� �r 20 millisec� x 10`5 the initial h ~_ to 4 x 10"~ torr, and Cho linear tempei'atuz�a wasrvurn pressure 20 And 500� C. Some of the data are Irz�egent;ed r , the aid of the l~zaphicall a ied between matQrial balance equation a y nd are discussed, lifetime of an ion in the ~ teclu:iquo is clQyelopod fox� deriving`ViChe measurements of plasma densitymandrradius ofs pr�s5ura measurements assumed cross s�etions i'or cl~argQ exchnrtgo andhioniznLa filament a' th'a usua? the plasma. The ion lifetimes was found to i ion of atoms andtmoleicule c-r strength and to be vc ncreasc With sin ry sensitive to other characteristicsnof ethcng magnetic field gation of these relationshi s eomowhat less than the durationso~eing continued. Plasma. Invosti- conditions, and the plasma densit w The ion lifetime was found to be j plasma confit1ement under all the investigated ion lifetime and the lifetime of an absorbed atom aAb~ut equall 3 formulae and 10 figures. Y determined by tht; ho linear. Orig. art. bees SUB CODE; 20 Card 2~2 SUBM AATI~: 1~Nov65 ORIG. REF: 010 0TH REF: 007 ~' ~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 t ' ~~ r` r i i' f I E r t ~ ACC ~NR-~ApG033419 ~~==-'-- _...... _.:.~~~:..~.:~.:.,~~. ww.~. SOURCDs 'COpK: Un/0057/kiG/(}3G/k)10/1$.~ /1&1:1 s E AUt'll0i~: Garbunov,Yo. p. ; Kot,el ~ nikov,Yu.N. ; Kutukav,G~ p, ; Simoncv,V,A. ._.m...~u.Q~- OitG: none TITI.K: Investigation of the material balance betwaan tha plasma :filament and tbo gaseous shall in the Tokamak-3 toroidal machine SOURCK: Zhurnal tekhnicheskoy Sizilti, v. Ski, na. 10, lAGki, 1f~31-�1841 TOPIC TAGS: hydrogen plasmas plasma confinE:ment, gas pressure, ionization gage, gas absorption, ion lifetime ADSTRAGT: The authors have employed specially designed ionization gages to record the pressure of the neutral ryas surrounding the plasma filament duz�iiig operation oP the Tolcama}c-3 machine, and with the aid of the data thus obtained they discuss tt-e exchange of material between the plasmn, the surrounding gas, and the stainless steel linear of the toroidal discharge chamber. The electron beam of the ionization gaga was modulated to make it pos;,ible to distinguish the ionization gage signal agair-st the noise background from th~~ main discharge. Kash instrument consisted of two identical ionization gages in a single envelope; one gags of the pair was usually operated with a cold cathode and its signal was subtracted from that of the normE-lly operated gage to reduce the noise background. Entrance of charged particles intc- the ionization gage was prevented by an electrostatic trap. Data were recorded undez� Card 1/'2 UDC: 533.9 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 I i I ~' ~...._......_. .o r ~ g m ro ~ +~ X ~a o+ ,a n ro ~' t'.~') ~~ ~~ ~~ ~n n~ ~~ Ir~ ~ ~ "fi 1 /73ii iii M 9 U q ~' ~ ` A .� / r a r ( ~' ~ t ~, ! ~ ( ~ ~ ~+ ~ . N 1 .r ~� OI i7 {~ p i. t~ tf P� ;; ., ~ ~.r i ~ ~ r 6 ~ .. .. ~; ~ , it ~I a r u" pi ~ ~ tr ,prT .. is I u E~ i. ~ ~ p~ f ~ i% U p ~/ :1 h! / ~~ i~ h ~ 0 ~p~ P t~+ P ~l~ p b ~~ o ci r ~ IhJ r 0 G ~o i~ {o H k H t~ ~ li m o.r n n ~ r N o~ h ~ N a m w 0 H d ~r ,rYl E( N qhq r ry rti P R " ~ ~ Cp r 0 '" ; n O �f ~1 ni x 'F '~ N . a 41~ s~ 1 1~ 1~ t. f ~' ~ ~ rl ~� :~ n n 0 0 m n v N b ey l(L] N W W r~ n r ir~} APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 The Isotopic Effect in the goV~~56-59-26/48 ethylamine Mutual Solubility of ~Yater and Tri- with the measuring results. An isotopic exchange occurs in solutions of triethylamine and heavy water Under exlaerimental conditions (concentration of triethylamine 35`~ by weight) 1 y 1.5~ of the deuterium atoms passed over into triothylamine. There are 1 figure, 1 tablla, and 3 references, t of which is soviet. PRESENTED B7Cs� Kafedra teoretioheskoy khimii Ural'akogo palitekhni instituta im. S. l~1. Kirova eheskogo (Chair of Thr~oretical Cherai.stry, Ural Polytecl~nic Institute imeni S. M. Kirov) sUBMTTTEfl: SQptember 22, 1y~8 Card 2~2 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 21(1) 5(4) ~ov/~5~-~59-2~6/4e gOTHORS: Kotel'nikavg .,'V,_,_vV., Skripov, V. P. TITLE: The Isotopic Effect in the i~iutual Solubility of Water and Triethylamine (Izotopnyy effekt vo vzaimnoy rastvori,tsl~nosti vody ~. t;ristilumina) PERiODICgL: Nauehnyys doglady vysshey ;~hkaly, Rhf.miya i khimicheskaya tekhnologiya, 1959, Nr 2, pp 248-249 (USSR) ABSl'BACT; The solubility in the systlams (C2H5)3N - D20 and (C2H5)~1P- H,~4 is investigated. A diagram (Fig 1) chows tha experimental results. Tha solubility is reduced in Y~savy ~vatex, the oritioal tearperaturea amaurit to 1'x.86 for H2O and to 14.05� for D20; thus the difference is negative. For dif- ferent deuterium content off' the water the change of the critioal temperature in the aria of an equal concentration of Height of triethylamine is calculated in the falla~ing xay: tx ~ tH~O w o.x(tH2O .. tD20) (tFi20 9 tD20 denote the ~. temperature :limit values at 100 H2O and D20, respectively). Card 1/2 6 table gives the values for cx. They are in good agreement APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138000825300013-6