SCIENTIFIC ABSTRACT KOZLOV, V.S. - KOZLOV, V.V.

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SCIENTIFIC ABSTRACT
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LO 9 e)4E,-.i ?4k:,l~, m MIXH, Takov Moisayevich, kand.ekonom.nauk; KOZIoOT. Vladimir Sergeyevich, kand.ekonom.naule; GOLIJIBERG. Abram Mikhaylovich, Btarshiy prepo- davatell; PRIVkUHTSWA, A.G., red.; PTATAKOYA, N.D., takhn.red. LStatistical atudy of labor productivity in industry; based on materials of the Odessa Economic Council] Statisticheskoe izuchenle proizvoditellnosti truda v promyBhlennoBti; po Mats- rialam predpriiatii Odesskogo sovnarkhoza. Moskva, Gos.stat. izd-vo, 59. 129 p. (KIRA 13:2) 70deses Province--Productivity accounting) -1 K940Y, V.S., dotaent; ZAKTAROV, F.M. Methods for eliminating sterility In cows on a state farm. Vaterinarila 40 no.5:43-44 My '63, (MIRA 1731) 1. Alma,-Atinskiy zooveterinarnyy in3titut (for Kazlov). 2. Glavnyy vaterinarnyy vrach sovkhoza, "Aksay". Alma-Atinskoy oblasti. (for Zakha- rov). DENISOV, L.A.j KOZLOVt V.S. Determining the magnetization force necessary, for magneto- graphic control. Stroi. truboprov, 8 no.-9:19-20 'S 163. (MM 16: 11) 1. Gosudarstvennyy montazhnyy trest Glavsantekhmontazha Ministerstva stroitellstva SSSR, Minsk. DOLGUSHEVSKIY, F.G., dote.; JMZIDV,--v_S_,-dots.; PANCHENKO, V.P., as- sistent; POLUSHIN, P.I., starshiy prepodavatell; POSTNIKOVA, G.V., kand. ekon. naukj EPJ,IKH, Ya.M., dots.; SHENTSIS, Ye.M., red.; ILIIUSEENKOVA, T.P., tekhn. red. (Statistical study of labor productivity and the uncovering of its potentials in agriculture]Nekotoi-ye voprosy statistichaskogo izucheniia i vyiavleniia rezervov proizvoditellnosti truda v sell- skom khoziaistve. [By]F.G.Dolgushevoki4i i dr. Moskva,, Gosstat- izdat, 1962. 189 p. (MIRA 16:1) 1. Prepodavateli Cdesskogo kreditno-ekonomicheskogo institute. (for all except Shentsis, Illyushenkova). (Odessa Province-Agriculture-Labor productivity) DOLGUSHEVSKIY, F.G., dots.; GOLIDBERG, A.M., dots.; XOZLOV. V, dots.; PANCHENKO, V.P., assistent; POLUSHIN, P.I., at. prepod.; ERLIKH, Ya.M., dots.; TRUKHANOVA, A.N., red.; ILIYUSHENKOVA, T.P., tekhn. red. [Problems in economic statistics] Sbornik zadach po ekono- micheskoi statistike. (By] F.G.Dolgushevskii i dr. Moskva, Gosstatizdat, 1963. 311 p. (MIRA 16:9) (Statistics-'-Problems, exercises, etc.) DENISOV$ L.S., inzh.1-KOZLOV V.S inzh. 01~ecking the quality of welding in the construction of municipal gad'lines in the White Russian S.S.R. Stroi. trub?provo 8 no.ls 20-21 Ja 163. (MIRA 160) 1. Treat No.24 Goaudarstvannogo montazhnogo treata, Glaveantakhmontaaha MiniBterstva stroitel'stva SSSR, Minsk. (White Russia--Gas pipes-Welding) (Ga=a i i-Industrial, applications) PAVLOV, I.M.; BELOSE91CH,, V.K.; Prininali uchastiye: WHAKOV, W.V., inzh.; KO ~ ;4P, V.S., 3Aborant Investigating the relationBhip between the friotion coefficient and speed and pressure on a special unit. Trudy Inst.met. no.9:139-146 162. OMU 16:5) (Friction) KOZLOV, V.S. Now 5th series transformer stations of the State Institute for the Design and Planning of Electric Power Systems. Prom. energ. lF no.7: 14-45 Jl '63. (MIRA 16:9) 1. Kazgiprotsvetmet. (Electric substations) KOZLOV, Vasiliy 5ergeyevich; DOfJRONLVSKIY, Ye.D., nauchn. r,~d. (Black and white electron-beam tubes and externa_1 auxiliary devices] Cherno--belye elektronrio:Luchevye trub- ki i vneshnie vapomogatellnye ustroistva. Moskva, TSenti nauchno-issl. in-t patentnol informatsi! i tokhniko-ekon. 1881.J1 1964. 40 P. (1,11U. 18: 1) .1 -- KOZLOVP V.S. (Minsk) Increasing the reliability of the MD-11 defectoscope. Stroi. truboprov. 10 no.2129 F 165, (MIRA 1815) ~-O~z (go ahimkont) A Atplifted moth6d tf d6termining the maximm power oonsumption of agrIcultural owitimeiij, triergigtik 13 llo,8:17-18 Ag 165. (141RA AM DENISOV, T.S.q In'Ais- y ~ -- -, -k- , ~' -2 -- . rl-! c ':, ~:, i .: , r! -. -i. - -;-z r. prr. * zv. me~hcd o" - r ~ t,,- - 7 1 i r! v ~-; ~., 1. -L - ~ I - n,).7:1 -~,-18 E. t65- KOZLOV, V-Sh., inzh. Precaot reinforced concrete sectional girdere. Prom. strol. i inzh. soor. l,no.1:29-32 0 '59. (MIRA 13:12) 1 (GL-dere) GUTW, G.I., inzh.; KOZIOV, V.Sh.. inzh.-. SYTIJIK, V.I.. inzh. Open standard crane trestles. Prom.otrol. 38 no.1:25-27 16o. (14IRA 13:5) (Cranes, derrickop otc.) (Trestles) KOZLOV V.Sh.; SVESIINIKOV,, G.V. Uperimental construction of &baiMing from machine-cast elements. Prom.stroi. 39 no.805-40 'Ca. (MIRA 14&9) (Kiev-Precast concrete construction) LIBrRMAN, A.D., kand.tekhn.nauk; KOZLOV, V-Sh., inz~.; SVESHNIKOV, G.V., inzh. Design and construction of a mechanically assembled building for an automatic macbine-too3 plant. Prom. stroi. 39 no.10:42-47 0 161. (MIIIA 14: 10) 1. Nauchno-issledovatel.'skiy institut stroitellnykll. konstruktsil Akademii stroitel'stva i arkbitektury USSR (for liberman). 2. Kiyevskiy Promstroyproyekt (for Koziov). 3. Kiyevskiy sovnar- khoz Zfor Sveshnikov) ' (Kiev--Precast concrete construction) -KOZLOV, Vladimir Shalavinh; DYKIiOVICHNYY, Aleksandr Aleksandrovich; GORCH&R, A.S., red.; BERGER, K.V., red.; YEREMINA, I.A., tekhn. red-. I [Deoign of reinforced-conarete elemental mechanical methodal Raschet zhelezobetonnykh konstruktaii; mekhanizirovannye me- tody. Kiev, Goaatroiizdat USSR, 1963. 493 P. (MIRA 16:4) (Calculating machinea) (Precaat concrete) DENISOV, L.S.; KOZLOV, V.S. Possibilities for uoing puloe maGnetization in magaitopaphic control of city gas mains. Stroi. truboprov. 0, no.5:23-26 Hy 164. (Muk 17:9) 1. Trest No.24 Santaklmontazli, Uin:-)k.. KORSHUNOV, D.A., inzh.; KOZLOV, V.Sh., inzh. Standard elements for precast monolithAc short shells. Stroi. kon.qtr. no.20-14 165, (MIRA 18: 32) 1. Nauchno-lssledovatell3kiy institut stroitelinykh konstruktoiy SSSR, Kiyev (for Korahunov). 2. Kiye7skly Gosudarstvennyy proyektnyy Institut ro obshchestroiteltnomu i sanitarno- tekhnicheakomu proyektirovaniyu prim7shlennykh predpriyatiy Gasstroya SSSR (for Kozlov). ~OZIIOV,.V.Sh., inzh.; SA14OLETOV, M.V., inzh.; KfIAPITONOV, I.G., inzh.; KORSHUNOV, D.A., kand. tekJm. nauk Standardization of open c,antry cranes. Prom. strol. 42 no.6: 20-23 165. (MIRA 18:12) 1. Kiyevskiy gosudars-Lvennyy proyektnyy institut po obshchesI.roi- tellnomu i sanitarno-tekhnicheskomu proyektirovaniyy promyshlennyk1- predpriyatiy Goss-troya SSSR (for all except Korshunov). 2. Nauchno.. issledovatellskiy institut stroitelInykh konstruktaly Gosstroya SSSR (for Korshunov). 124-57-1-1077 Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 1, p 150 (USSR) AUTHOR: Kozlov, V. T. TITLE: Torsion of Compound Beams Made of Rolled Angle Irons (Krucheniye sostavnykh sterzhney iz prokatnykh ugolkov) - PERIODICAL: Nauch. zap, Odessk. potitekhn. in-ta, 1956, Vol 9, pp 105-110 ABSTRACT: Bibliographic entry 1, Beams-Stresses-Bibliography Card 1/1 K r-, Z 1 6-1 / V.-F AUNORS: Koz1ov, V. T., and Dorogostayskiy, Z. E. TITLE: Instrument for Determining Transverse Deformation of Rod Specimens (Pribor dlya opredeleniya poperechnoy deformatsii sterzhnevykh obraztsov) PERIODICAL: Zavodskaya Laboratcriya, 1957, Vol. 23, No. 1, pp. 103-104 ABSTRACT: The article describes an instrument proposed by Prof. A. P. Korobav for determining the transverse deformation where a rod is either stretched or compressed longitudinally. It is based on the application of a transmitting, double-knee lever device clamped on the piece that is being tested. A dial indicator is included in the circuit of the instru- ment. A diagram showing the principle of the instrument is presented. The instrument is of simple construction, port- able and reliable in its functioning. ASSOCIATION: Odessa Polytechnical Institute (Odesskiy politekhnicheskiy institut) PRESENTED BY: Card 1/2 Instrument for Determining Transverse Deformation of Rod Specimens SUBMITTED: AVAILAEU: Card 2/2 --KOZLOV. V.T.,--- Experimental investigation of deformations of noncircular rods Bubjected t45 free and hindered torsion. Nauch.zap.0d.politekh.inst.14: C5-95 t59. (MIRA 14:3) (Elastic rods and wires) L 43o8o-.66 EWP(k)/EWT(ml//T/EW-?(w)/EWP(-.)/ETI IJP(c') jD/-iW ACC hIR: AR6014374 (P'A SOURCE CODE: UR/0l37A5/0OO/0ll/D0O5/DOO5 AUTHORS; Kozlov, V. T.;...KY-sochin, V. D. -111-3i 11 TITIE: ImprovemGnt of fatigue properties of wire cable by means of elastic- plastic elongation SOURCE: Ref. zh. 14~tallurgiya, Abs. 1ID30 REF SOURCE: Sb. Stalln. kanaty. Vyp. 2. Kiyov, Tekhnika, 1965, 425-427 TOPIC TAGS: wire, wire product.. fatigue strongth,QA0 ABSTRACT: Results of investigations show that elastic-plastic elongation changes tho character of the distribution of residual tensions. The fatigue properties of w:L-e cables are notably improved by the proper choice of drawing technology and elongation stresses. 3 illustrations., 2 tables. L. Kochenova LTransliltion of abstrac3t Card 1 qj UDC: 621.771.001. 1 912-0 // =1o AUTHORS: TITLE: 66295 ZZ051 lLto3,1136 s/igo/60/002/Ooa/007/017 B004/BO54 Tarasova, Z. N., Kaplunov, M. Ya., Kozlov, V. T., Klauzen. N. A., Dogadkin. B. A. Interaction of Sulfur With Natural Rubber Under the Action of Ionizing Radiation PERIODICAL.: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 8, pp. 1201-1206 TEXT: The authors study the problem of production of radiation-resisting rubbers, the conditions for a common vulcanization of irradiated and sulfurated rubbers, and the modification of rubbers treated with radiation. The present paper gives the first informative results of investigation of the effect of radiation by Covjon rubber in the presence of sulfur. A considerable sulfur addition occurred at 25 OC, and was accelerated by an increase in the radiation dose and temperature, Particularly by addition of hexane chloro ethane. In thermal vulcanizationt the admixture of chloro derivatives showed no effect on sulfur addition. The presence of sulfur delays the structuration as compared with rubber without sulfur admixture. Card 1/3 96295 Interaction of Sulfur With Natural Rubber Under S/190/60/002/008/007/017 the Action of Ionizing Radiation B000054 But structuration increases also here between -800C and +1000C with increas- ing temperature. Pure rubber showed at 500C a reversion of the structura- tion process, which was not observed in the presence of sulfur in the tem- perature range investigated. A study of the infrared spectra in argon of irradiated rubbers with and without sulfur showed a decrease in intensity of the 840 cm-1 band due to a reduced degree of nonsaturation. This effect was more intense in the presence of sulfur. The decrease in intensity of the 2940 and 1450 cm-1 bands due to a reduced number of CH 2 groups or ring v formation was, however, more intense0in the presence of sulfur. An in esti gation of the sulfur exchange at 120 C in Irradiated rubber tagged wish radioactive sulfur, carried out by a method described in Ref. 7, showed that about 40~6 of sulfur is exchangeable. This amount does not depend on the radiation dose (up to 100 megaroentgens). The high degree of exchange- ability is ascribed to a formation of polysulfide groups. Sulfurous rub- bers with addition of hexachloro ethane showed, on irradiation with 20 megaroentgens, maximum values of tensile strength (about 130 kg/cm2) aq of elongation. When irradiating pure rubber, a maximum (about 100 kg/cm~f) is only attained at 50-70 megaroentgens. Sulfurous irradiated vulcanizates showed a faster stress relaxation than irradiated vulcanizates free from Card 2/3 86295' Interaction of Sulfur With Natural Rubber Under S/190/60/002/008/007/017 the Action of Ionizing Radiation B004/BO54 sulfur. The authors assume that sulfur addition leads to a more homogeneous and regular structure since secondary reactions causing chain ramification are inhibited. There are 7 figures and 7 references: 3 Soviet, 3 US, and I British. ASSOCIATION: Nauchno-issledovatel'skiy institut shinnoy promyshlennosti (scientific Research Institute of the Tire Industry) SUBMITTED: March 24, 1960 Card 3/3 S/844/62/000/000/095/129 D204/D307 AUTHORS: Dogadkin, B. A., Tarasova, Z. No, Kaplunov, M. Ya.,.Koz- lov, V. To, Klauzen, I. A. and Matveyev, V. So TITLE: The interactions of sulfur with polym6ra under the action or irradiation SOURCE: Trudy II Vsesoyuznogo soveshchanly"a po radiatsionnoy khi-! mii. Ed. by L. So Polak. Mosc'ow, Izd-vo AN SSSR$ 1962, 554-562 TEXT: The interactions of S with natural-rubber, 1,4-cis-polybu- tadiene, butadiene-styrene and butyl rubber was studied, under ir- radiation from a Co 60 source. S added bn to natural rubber at.25 - ~/ 10000 and to butadiene-styrene rubber and polyethylene at 250C, un- der argon, in amounts increasing with the dose (0 - 120 Mr), the rate of addition being faster at higher temperatures. At room tem- perature the amount of 6 added on is independent of the initial S- content in the starting mixture (1 - 10% by weight). The addition Card 1/3 : t-, I S/844/, 62/000/000/095/129 The interactions of ... D204/ 307 was promoted by C Cl The presence of 8 hindered the development 2 6' 1 of structurization, which.~-;au, however, promoted by raising the temperature from -80 to 1609C. Pure natural~ru'bber developed cross- linking only up to -5L)oCq :above which temperature the process was reversed; this reversal wqs, not observed in,the presence. of 2cv' S, i1 (SKS-30AM) bu- up to 10000. The pre~;ence :.of 1 - 45' S inr tadiene-styrene rubber led only to a slight reduction in the de- gree of cross-linking on irradiation. The loss of unsaturation and _CH 2- groups on irradiAtion was studied (by ir ~;jectroscopy) on natural rubber both in ~he presence and aboence of 8, and was found to be greater in the latter case. The ~~ adds on in a form capable of isotopic exchange with elemental sulfur. Initially 70ri of th& C~ added sulfur may be exchanged in natural cand butadiene-styrend rubbers; this value falls with irradiation to a constant 40% at 50 - 120 Mr. Radiational vulcanizates of.natural rubber exhibit in- creased tensile strength when the polymer contains 2% S, particu- larly at 10000; in general', the strength increases with the dose -of irradiation. The best strengths were obtained for a mixture of Card 2/3 The interactions of ... S/844/62/000/000/095/129 D204/D307 natural rubber, S, and C 016 The sulfur is believed to interact with the polymeric radic3le ~formed on irradiation by C-C fission) to form polysulfides which (a) lower the thermomechanical stabili- ty, and (b) prevent recombination reactions and reactions of radi- cale formed with C=C, thus hindering the development of branched structures. There are 12 figures. ASSOCIATION: NII shinnoy promyshlennost'i dustry) (NII of the Tire In- --Card 3/3 S/1~0/62/004/0108/01o/o16 B101/B180 AUTHORS: Tarasova, Z. N., Fogellson, IM. Kashlinskiy, A. I., Kaplunov, M. Ya., Dogadkin, B. A. TITLE: Ep3~ study of the radiation vulcanization of rubber in the preeez)ce of sulfur and hexachlor ethane ?F,RIODIC.%L; Vysokomolekuly~arnyye soyedineniyaj v. 4, no. 8, 19621 1204-1209 TEXT: Records 'd epr spectra were used to study the formation of free radicals during the radiation polymerization of natural rubber (11R) and mixtures of INR with 2wt.V.' sulfur or iowt.-~ C,Cl,,. /0 Zrradiation was, 0 6o I . ,!onducted at -196 - +20 C witn cc at a dose of 6 - 11 Mr. Results: (1) Lon~;-lived radicals with an initial concentration of (1-2-5).101 4mg- form in UR and its mixtures with S or C Cl at 200C and 6-8'Ar.* 2 6 (2) Radicals of different lives form with irradiation at -11960C. Their initiL concentrations in NR, NR + C 2C16 and in Nil + S are Card 1/3 s/19o/62/004'008/010/010' Bpr study of the radiation ... B101/-180 4 7-9-i-O-*1015mg-1, (11+2).1015 mg- 1, and (2-.6+o.6)-1o1-5 mg-1 , respectively. ( Inhibitinn, o? delocaliza-tion Tne effect S is due to of an electron-in 0 the S ring. (3) If the NR + C Cl sample irradiated at -1960C is slowly 2 6 brou.-ht to room temperature, structuration occurs near the vitrification temperature (-70()C). Short-lived radicals disappear and the concentration of free radicals approaches the room temperature level. (4) Gradual heatin6 of the NR + S sample yields new short-lived radicals with a factor of 2.027 + 0-003 which is typical of 3 radicals. The radicals whose concentration reaches a maximum of approximately 1, S-1014- -1 00 are formed by reaction between IM and S, the S ring mg at -50 a A .being ruptured. (5) After irradiationtarystalline C 1.1 ahowed an 2 6 --ntensive epr signal, from which it is assumed that various types of r4didal %ru formed. The form4tion or 401 radicals was confirmed by tho 3 . . analytical detection of chloroform. (6) Structuration of NR irradiated at low temperatures is supported by C2Cl 6 and impeded by S which increases Card 2/3 s11901621004100810101016 Epr,study of the radiation ... B101/B180 the static strength of the radiation vulcanizate. (7) crystalline S showed only a weak epr signal. There are 5 figures- ASSOCIAMOIT: ilauchno-issladovatellskiy institut shinncy promyshlennosti (Scientific Research Institute of the Tire Industry) SM:ITTED: May 12, 1961 Card 3/3 I TARASOVA, 2". N.; LWADKIDI, B. A.; LYKIN, A. S.; KAPLUNOV, M. 'ia.; KHGZAK, V. K., KOZLOV, V. T.; SOBOLEV, V. S.; EIMZEN, N. A. "Struktura i nvoystva vLLlkanizatov, POILichennykin karnhim."Lrovannyv. cleystvilem sery I ion i-ziruyushchikh izluchenly. It report sdomitted for 35th Intl Cong, Industriai Cloemistri. Warzaw, Sep 64. Nauchno-issledovatel'skiy institut shinnoy promyslKlennostl, Moscow. YANSHIN, A.L., akademik; YAKOVLEV, Yu.Ya. (Moskva); PLOTKIN, S.Ya., kand.beekhn. nauk (Moskva); GVOZDETSKIY H.A., prof.; NOVIK, I.B. (Moskva); SVINTSITSKIY, V.N. (Moskva~; KOZLOV, V.V. (Moskva); SULIDI-KONDRATIYEV, Ye.D. (Moskva); BELOV, S.V. (Lenirlgiaid)' Books. Priroda 54 no.7:56-57; 71; 104-111 Jl 165. - (111IR-k 18:7) 1. Moskovskiy gosudarstvennyy universitet in. I.I.V.kmonosova (for Gvozde tskiy). KOZLOV, Vadirr, Valentinovich Legal-medical si,~,nificance of Gunsmith Lubricants concerning Bullet Wounds (experimental research) Dis5ertation for candidate of a Medical Science deFree. Chair of Legal M'edicines (bead, Asst. Prof. I.V. Skopin) Sariltov Medical Lnstitute, 1q57 XOZLOV, V.V. ':/ a".11" Vkbl~~0'~J V Significance of the Impregnation of skin nerve fibers with silver for the diagnosis of intravital, injuries. Bad,-med.ekspert. 3 no.l: 18-21 Ja-* 160. (MIRA 13:5) 1, XELfedra sudebuoy meditsiny (zav, - dotsent I.V. Skopin [deceased)) Saratovskogo meditsinskogo instituta. (WOUNDS AND IRMISS) (SXIN--INMVATION) KOZWT, V.V. We are improving the remote control of deep wells. Neftainik 3 no,4z 26 Ap 158. (MIRA 13:0) 1. Ispolnyayushchi7 obyazannosti nachalinika konstruktorskogo by-t=o elektromontazhnogo toekha nefteproqrslovogo iTravleniya Starogrosueft'. (Oil wells) (Remote control) AFANASIYE;V, FIM.,, inzh.; BORMICH, M.K., Inzh,j DOLGOV, V.A., inzh.; KOZLOV V.V. inzh, 1knufacture of wire-reinforced concrete articles on the TP-906 unit in Krasnodar* Bet.i zhel.-bet. no.6:254-257 Je 161. (KIRA 14:7) (Krasnodar-Prestressed conorete) BORODICH, M.K., nauchnyy sotrudnik; AFAIMIYEV, P.M., nauchnyy sotrudnik.; MUCV, V.Y. Tensioning station of very simple design. Bet. i zhel.-bet. 8 no.61276 Je 162. (~aRA 15:7) 1. Krasnodarskiy filial Nauchno-issledovateliskogo instituta po stroitellstvu 14inisterstva stroitellstva RSFSR (for Borodich, Afanaslyov). 2. Glavnyy inzhener zavoda No.3 Krasnodarskogo sovnarkhoza (for Kozlov). (Prestressed concrete) KOZLOV Vasiliy Vasillyevich,- BEDRAK, T.V., red.; DATRIYEVA, Ye.U., '-tekhn. red. (on multinational collective farm] V mnogonatsionallnom kolkhoze. Ordzhonikidze, Severo-osetinskoe knizhnoe izd-vo 1959. 18 p. (MIRA 16:7~ (Collective farms) KOZLOV, V.V. (Moskva); snIDI-KONDRATIYEV, Ye.D. (Moskva) ------- Before the flight into the unknown; collection of papers "flew discoveries about the moon." Reviewed by V. V. Kozlov, E. D. Sulidi-Kondratley. Priroda 53 no.4:1.18 164. (MIRA 17:4) KOZLOVP V.V.0 kand.med.nauk Unusual transpositions of internal organs in automobile accident injuries. Sud. - med. ekspert. 6 no-3:51-52 R-S'63. (MIRA 16%10) 1. Kafedra, kriminalistiki (zav. - dotsent D.P.Rasseykin) Sara- tovsko o yuridicheskogo instituta. fTRAFFIC ACCIDENT 11WESTIGATION) (TRAUMATISM) a Al -30 b IV's 12 U 11 0 is 11 4 1 V a) a ago It I-V 1~111 - - * . .1 s - 0 A& -01 CC OR U48-1 1 t lit 4.0 j.D 040100~ A mineral dY" 08 W001 &bar tf!~M MVWOUS MUSPOUGMU& M. A TO V .KOIWV. J. R&JL PhYS.-C". SOC. WV OIWIJ(RO)).~7U obkt I" to study the adborptim ol.mincral dyes (1%.0, (1-bero.),pb(oft), 00 ultramarine) on woolen latick which bas been technically washed with soda and amp sohu. When woolen cloth is pond through an sq. mpention of mine-ai dm the .441 latter settle on the fiber in an even layer. Tht rractim is completed In the cold in 2-10 it min. The resultant dytingissubstantiallyfutto water. The particularobjrctal the to study quant. the staseis of adsorption a functions of the coam.. temp.. :g elLp"MUn. as well as adsorption an addified cloth. the effect of eki"rulytm and the dt-ir" of evvirsibifily ut the P.Dise For the quant. studies. air-dried MyCr(]~ (0.37% ell lfO) wu employed and a cloth of 11.62% inasturv (ev.). For the qual. studies the 00 E 01 her substances were employed. Adsorption proceeds better In ordinary 11.0 than in =00 111sid. 11#0. 71w pitmiKe a( inherrid salts In ordinary water makes the adsorption c,,tnpk-te and siv" the dyeing a brighter shade. The adisorptiou isiefra" rapidly with 0 we time at first, but XTadually appruaches a cocist. value; It shows a typk-Al curve. As the 00 j, cimm. hxTrnm-*, the wt. adsorbed incrtam linearly and rapidly at fim up to a cirtain Point; then further increase abruptly cram and the cum becomes gat. As temp. rim, roe as u the advarptiou lam-aws but slightly. As cotics, of elemalytes hicreastro, adigirption first decreaws, then incrvasta, thra again decreases. As the diln. inervean. the WL of ff adsorbed decream but slowly. =lc washing the cloth retamed 60% = dyestuff initially adsorbed. As the " inerraws, the cluantity of acid adsorbed by the labric ins:rcaxa up to a certain value. whetru" it becomes const- .00 0 The dyed acidified labirk at cam &bows an increase of 13 to 23% in adsorbed wt. of dye 640 0 over non-ar,4dified fabric. However. as quantity ol add adsorbed Increases. the wt. of Ago dyvstuff adsorbed does not himase -.,M rapidly. D. IL 'A '00 11: *11TALLUNGICAL LITERATL49 CLASSWICATION 0 0 J, 'I-so., s I., I o. 0 it I :E!- a AT .0 LO At IT 0 0 * 0 41 0 0 0 0 0 0 Ms-vir-few WT 40 I I I is 11 a) u W is L6 it 14 Is a 11 it a SO is u Sd 13 a v a 44 hi 0 a a it I R .1-4 A A--L JL A-1-AA -N A Do U4 k 1 4 0 Koil;,v and T. 1). XvIrduva. I miliol.,j"Isoik 0 Pro" 3 91 V IMI). -in The prvi'd of W'.11111K vilmlorwe. III$. N-41 rrAull, w"M laitirti lily -imill!Ancooi mill-mation d VOI, will, Itaming 41 with fti-cl oil, 1-41-AmOlf and N)I( (Itrit, Inji, f'. 1. .11, filfl), wflrrrl,v a W3161 prothwt "'tild IV Isolatell only with (ta.-I '111. th" PC-Alict 1--'. pkial wV16111 .641 and entul,l(vul ptuprtilvi, and itt tivring of cotton and "IwAsIly td av%ul fail#" lsrt,- d Mrs very le%vl vilrets. Chas. Illanc 00 1' Af of .4$0 00 =0 0 0 S . - s L a .1TALLLWGICAL UTIRAT"t CtSl1fPK#TWN RZ two. 'A L 03 of er ft 1, 49 4 of if 7e, m"se. 004#60044064000 Oc At 1~ a of 111 V ld 5 a OF 0 a 4111 it 41 a 4W 4 is u la Is. 1_1L, -0 - a #--a- OV 4q!L- 'm so of so played by the in~lbilitv ,I th' ACid- -It CjI. C.11. w give u,*h 111.4 luk. .. awl Aioht%qtkiwqKu11,mw A,W, pt,%Ikh, thiln rite j:: Msts.1104intliftilto COMP1411 COMP"Adt 61 MMAII11061C Inch, -,-[ 01 AlON1 A11-4 Aml "dr,%jivamowe j-, . acids of ampilthalme and benzene. N, 14. Vorushusiv Acid, .4 C.Ils MOVt, .4. Nil, woli'l, is. Nqnr doolso. if -~iz and X-jL-fjoll"v. J. Gets. CAM. W. S. S. R.) S. Arlifi, %urh a, 000 of IAffauffunic scists NA-hit. wonw 0-ititumulfouic wylo (2,1- And 2.4.9.) arml 00 "t C'.11, &nit CJ1. will, 4'1. N11. 1. *Jns. .1 Cat And Ni 1.3- mild m-mull,ka tusrxi;X6 (11) --pk% Sit. runtpOs. 1111* wta. or lit, l"Wlis the A. Cis anti NI malm of thster achis 00 with all. %11&. 11wrt %Vft- Pistil. Isom, tvyst. frictalul- With Ni Al"I Co Aft.%. Wit I.I.Alie'd 11tv insist, Cu cunt1*110. as 0 anunisin cnni-k-% illsOl. ol' newly Invil. ill HP 1-he I'Willatiml '11 untie far tAllo-d trullitio conlidexes wim Allj t,"111114mi mX. -,ivrut,~ M. Ephraim. C. .1. 14. UM); the mullonic acid. .4 is so highly wusitiv cloill *17:1. 17, ll12). The %truclurr, of thiew MHOCIrs that the rraction can tic tmA for detertion wisit dertil. 00 CII(N110. R" LL1141 N0,1614 RI, (ri. Chustary, CU 01141 Xi and flillsiffillibilliC OCKIS. M COMPICIL C(Ant9l"k L* Wmseir. fl 4.). Th" -91"lits' '01 -%(),- and balogess- prej-1. 10%C Onne Nil, at rall trulp. alid all the NIL At see UlAtittited .,"If,mor At id% to give %uch colill4est cmlpd3- 110'. by mulAtitutinif AroniAtic Aild aliphatk- amiricts -it '14ritt hw Nil, ill the tractum, therv were olitaitscd litsu. of the te a is astrilivil to th"If iliefl, lots, character. Fhr go 0 d ability of 1'*2-()l%'C'Jl.4-X*h1I (1) to give mint eAtily ults of the cum~j-odills and millsille, '00 these rmplt.%r.% shown the influeoce of the o-Imissition of five front Cu and M. BY addii, -4 NflCI or so* the NO. anti 80111 Kwur in the rius. (cf. C. A. 27, 2444)). to a ImAll. of Cis ult of an-(hNC.11,.~XMI or OsNC,Il.. The Illnurrice of Its, mOrtiorg, rudiests L% fistritheir dis- Sooll there were o6tained utyNt., *4. Anti fing" ppits. '06 ly1m C -1 of the V110,80i CuRt 0 - G -Kraut, 114od. buirk aisopl. Chem. S. 87110. The wimitivirneu of the woo folkywitif reaction,, i%(tyen ill Isatts of Cis, Ni at Cal I" too -a parts 11.0. 4 1.2. NC,.IISOs~.Cu(.Vffs), 21flO, sit. zoo siss nt I d.ICC- W,-11, I-T Isla" oil ONT old 41141111 u is Alf As 'd It I I -ss~w I I A OW 0 is 0 1 it 14 0 A I I 1 401111 Ia. eta 1. 'T 0 0 41 see a 00 a so* 00 10 00 0 0 0 0 0 # 0 0 0 0 6 0 0 0, 0 1 9 is 09 00 0o *0 00 00 1 0v 00 00 00 of es a 11 v 31 bi a 1611 mod 411 42430MAO Ito .1. D=coatrol of P-aaphthol product[ois at th4 Latim &IoX and A. A. Chff- Frult" woo V..P kankil. Amilix0hrasockx4yis jImm.4. A setwral mtthotl of anslysb k dm-ribed. C. H. :31 4 U w is 16 v a 0 a 6m 4!~ -40 -00 moo Zoo roe r.* 0 go 0 Cloo go 0 t:94 Us 0 "to ILA AITAI,L(O CICAL UtTRATLOR CLAIIWKAYIGP Do 0 77-- Aid., 11.1411 .34. goo felava &l, Q.T 4*1 SlAill OK a., is. A . . I I , ; I A 0 U n IT so to a 19 it OP K 9 a I " a ig it r, I I.. Pill so 040 willwilmsa 0 0 0 4 6, 0 0 0 :1$ 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 o 04'es ,TOO::::: :100*0,00 000004004-09 000069 0 ego 06 0000000900e 4000*00*40000 off#*: . a- VIA- m o00 0 0 0 0 e 0 0 0 0 0 0 03 11 A Is b Ina WX A M U U M n b V j6 P. Ar Q 63 41 to 1. &A. 0 p a 0 1 f .211 A I AA a k I a A I I 4 .-1** Lj&.(&d b"k dy" with beteraWY -P-ds (ragW1444). V-V-AAkMV- AXWX0kFdJ0CA"aYu "row' S, )H0-92(1935) 19M, 1. '21443. S~' Top" diwuwgd Wu& Lb"c"mPt' szeUmn"i'lle prel"t. of I" 0 ail dyn (rum cumpigs pho%pholungstic, phMplumn(Avimlic mukatuagsik WW6 of Row" auLnul.. tests W the siped bxh in thr famnem to light of tbt plgrswnts so tA)t i .00 pugr farin and an caniers. (At gets, tle.93.. kmAin), snd 00 11 -magions at to I twif uW.. W. A. Mmor -0 0 90 z 00 00 00 coo 00 --0 0 00 r; 40 0 0 18=2 ::Zoo 00 f 00 0 00 A 0 es to 0 00 L* 0 *0 f Is L4 0 Of Wo - - ------------ -It 04 u #A I I a W a 0 -1 v P I- a 04 It is K 0 of c[ it It of suo A I ~14 oo::Sooooooooooooooooooo0400000000000: 4Y : : : : : .: 0 0 Ogg a 0 0 0 006 go * 0i0 Ogg 0 09 oe 0 0 0 0 0 0 0 0 0 OA A 00 a ,~ qq a e 4 0 4t : 004 *0 12 00 13 4.6 0 470 6 IF* -06-0 6-0 oo**oooo**ooo UNSIX hVIN0041 one WhOW OF DYI UALYSISo lo AN"7818 OF qUINOHOID DUS BY TIM TITANNU XXTUV9 V* 19"ov (j . Appl. 93 TIC13 or OWS4 Rule,# 1935j, 8. 1416-141'1~ TL2 (So4)3 solutions ch" tMir titvo by 0.00=4 N per dsqs th* oxidised solutions can be periodically ro- generated tW adding Zme Tbe d3va are best titrated in 201 120-stoil contalrAnt lot' or N& I tartrato AM approx. IS of 4yes the resvits tend to be high, by;~. 2.5~* Titration with.CrOU lin place of U013 does -flot Sive Satisfactory resullso swift to the indefinite mid point and to the slootwas of the reastion with certain dyes. (Ple-vioUts surudness, rhodamines)i the most reudily red,joad are oxasins and thissirs dyes. R. T. lee .00 0*0 -00 -00 .00 40041 nool VA 6 see see 8,4001 400 So 0 we 165 Us All-ILA r--r J-w e a a:& 41410400,00000000000000 0 A-0- 0-41 0 0 0 0 0 0 0 0 0 0 0 le 0 0 0~9 0 * 0 0 0 0 0 * 0 0 0 0 0 6 004 * 0 - s- 6 0 0 606600006 0 0 0 0 * 0** 0 0 0 0 0 00 0 0 0 so 00, 4. 000 0 41 0 0 0 0 0 0 0 0 0 03 1 0 111 to 11 1) m16 U " " " a " " V C * , , 0 -- - -L--L--L-AA *,.C 0 ' as S. V. W W - 00 sof Scal details f(w the utp. (4 ;m , -90 py'VIu it with HCI p in. of Mn(OH)s by NaOfl and ax t of the Mot Of with Cis oto live 1110~ of hisks ox pown we 1. M. Lcocester itoed 06 1~ 3 60 1 ~ 90 =0 9 --.0 0 so =o of -0 : c:00 go 0 00 r0 0 96 goo 00 zoo 00 j .40 00 -00 06 cz, t:O 00 '0 0 ~ r ' " 0 'l Is w 11!C , , " " ;A A 141 m i w I wn IRA K . A 4" 0o0040000000-000 o ;O ooooolsoo o ot '6 'a 1 00 0 111 0 0 0 0 0 0 0 0 gio 0 0 0 0 0 0 0 0 0 0 9 q 0 4 1 0 0 0 0 0 0 0 0 0 off* g ?900000 0 000000 Alt 00 A via Mal" 1-00 ^0 Oec W A 0 .00 bo .00 O ' w j ids k i." (a) 000 mod Ismans awo zoo dya DWI* 2 rVin, by we4W &W ppL. but .000 1 im Im is Ma cam of b~iAo dye& I O PP . r 000 OOW L IMLO(al "b"odwapies"dwoomi. I I I , a T on coo Ap whi" Is dtmUd O t II by WW 0(60h AM A IL 1J6 rAL Of it" r4iMW$*4TOmL n %% i f * w wt W s != of 11-ft AAd r6 d m s L ft , x6o Al Wuua*m No* I in OA gh)ft :to* t i ~ The a II T . 610.2LA &I . a A TtL IM It 4". -dat *A ~ftr It. 0 ar so AS T A' a ad a 0 a I If of 9 dB a 3 a I pop a K ~ 4 1 Is 16 I 161 0 0 0 4 0 0 0 0 * 0 a 0 00 a see 4 0 0 0 W 0-0-0--0-O 0 0 0 * 0 0 00 61 900000 0 0 a * 4 a 0 0 : 0 0 411: 0 0 0 '0 ~0660 I I I ]a 11 if is m is m )its "Alin 83911110)1?0 wit Uss m 1% m u 0 H LI 'I A a A L J. m U" J"(, Jw; Stable preparation% of diato cormliounds. lium. bl,?RW. sqfl. .91. IWI',. Ali, -k-111's, ilf '4111% air fival"I woll lulcl- th"i" mill if" of F d S'. r A 0 I'll's k; 1h e ~ . 00 . fie., L A *,I -t,o Wfwto( c% awri(wit. too is if If It '.4 ~.4.) 'I o14 0 0 0 a Ole 0 0 0 f 0 0 0 0 0 0 0 0 0 4 0 *--* 0 0-0 0-9 40 0 * 000 0 0 0 40 0 o 4 4 g 0 0 0 0 0 0 0 0 w Ir 14 0 0 6*00 __o* so ova W~e x It a IS w Is A, I-11.1 IIJ 1. a. is a is v XT 36 it 00 #A 1 -&- 4 00 rr~ too ANCI st! "q -00 PROCISIOS five P660191111 moth ~ VIL Us roduction of 1,641- ' 00 pitionaphthaMs. N. N. Vowtuht., .,.I V. V, KadoV. i j - J. (;ex. Chow. (V. S. S. k.) 7. 73"21 IWO); 0. C. ii 30, MW~ -Cam. 1,15-C"(2400t; k1l was fromed Gain Shc %O . jirjusmee (U) by dimolving it in W parts of 100% H, , and filtering at W-90% thm roofing the solm. to IS 30 fStso 11. TU fitteste was pmvd into vx" orwer, mW the pitt., after wasthing to twu" reacticto and drvnjr~ 00 c l. In. lm 70'. A cm- was reffymd. from Calls, sivind watI effmited by 112% from In. 215' m Iet se of 1 *a ot . . , c m. . p a rapid cooling of the enrichtc! I in AcvO. IA-Ctoll,- jP41f;)j, nt, tirrulted in 77% yield when HvS. to- orso coudoct"I f d till k i h stream o a wea s, grthcr w t rr into ID g, I in RX) g. I'hNHs lot 1(0,1' for 2,-A firs., (of- lowed by diatc. ad of the I'liNH, and crymig. frotto ILA) The jame reaction at W multed In the furmation of c*9 timphthaleme-pai-dibuinc, III, 110, yield, 0.621 x. frout A g. Of Chas. Hham- cI*# 00 j no 0 . AIR-ILA WALLURGOCAL U1644f"I CLAS111FKATION oz- fig., U BAY POAS" 1 1 ZA 0 i# ' 1 L Im a a I I m 111 0 AS " a or Ir N X a x a x a It 41 , a a a a 0 0 0 a # a 0 0 0 0 9 0 0 0 [4 . 00 00 a* a 009 0 00 a 0 0 a S 4 t A bd it U Ij M 11, 1. o is, Al,nj, .A I f 1% d ii w hi m I 0 0 t 1 00 al * 0 o 0 IT : of IP UIF aa Al a is A 20 A, 1. V UIN Vm0 A. .1 V N, A, go I Z kA go CC DD a A -2. Coolly, 0 I(XIIS81, ..D -II(Vtor'll -400 -00 oa Ditto totizatloo 0i amiymo$ in the WW I DIM -00 *,Me of vale:i r an "Its. V--.V,-KQLIQX J Gr*. tin. 1 p- I of the benzene rld C.14, " k", which are umally Wt to dimatize. can be diszeltited qtrkkfy and n"r- B i h K I W f i t a y w n (be prelmence o n neutral or SnC], h -09 d volfts. Whtn this "It Is, present. every I-aminin-2- iroxy4-cyanomplithalene, whkh century he dfarmiml let ord;Tyary cooditions, reacts without difficulty. The bilitlyof thediazotized moln. is Iftcrealyrd by the prm, Wh S C HM i en excess a h. s prmnt rmrpling reac. h rm with diazoalum salts often give tars and by-producti. lit wAn. contains SySCII, suchside reactiyrn are entirely Ifirr-misvil and very pure prcAu,-t% tire Mitained frenn the 0 lillng. Smlts(d bivalent My anel Fi- &Ivy thow this tx,. 0 rW. If. %I my W zoo 00 00 A AD S t 62ITALLUV(,KAL LiTERAT01 CLASSIFICATION 00 1101. ~1- ill. 7,. ono sm ma Ica a tt it Of 'w n All I -f IN 6 g 0 0 0 0 0 0 0 0 0 * 0 0 0 000 0 a 0 0:0 0 * G. 0 0go go 0 0 0 0 q 0 1 NNW! 6 4 4 0 a * 0 0-4 0 a * 0 Of t 0, of ow got oil oil ON 'PU a It v a m a b v m 0 it a a w 420 r 7v1xv A- L-A- a it i I v ~ Y, L-L-I-L- M A QL U44 A-4 A-B tit 140. "Via$ .14 .*cf$.1qt -4. UIV-stualtive mitre comptinds N~ Ole, (J,- /"./ -1 . h -N 11 1 4. a in-vi'm pubim-dwitt, .1411 11-4,tl-l Aml d"K.Usmuts Lilt l"dw Ell to 0 04 coo 00 of I of 'goo X00 two 0 PiTALLURGICAL LITCRAILMIll CLAWFICATION 92-- jc* 0 100 1. SQ4., 0- dal IV 10 Is rp J. 1 0 Od 0 &Fps it u n it v4 4n ~00*001000000,,;;Of 0* 00000004joe 0 0 0 00 of 00 000 S TION Ou 60*6,6 *as a a a 00 0 000000 00 016 0 q6*OOO6oOOOO:::::1 It IL I a I It L is' Air, 00 Ali - I o* Eve 004 of j 04111 00 'a 00 g oo 8 &44 :J jW ti WA0111:! g~lj t I 1.1111:111-missiti" nitro tompomile. till. met*-N*M- tbmceo~MODOGWI*nlc acids. N. Varmbitov at", 64i'l ChOm- t'~ '4' " 71 27, 2440*, Tho Iterm. of tell-thris- 1107); .4 4a1 use :=;1~9 vic 11) hy t thosit of Ithintillst seat ,Jfohvts~ -I; 1% A 18, ZMI 11091~lklt Stac"t'd St"" 'he I., kept at lit-1h, durinq allet6m. I maussigg be by .1icialition of ttw tritrossimbrimiceme. all" Only milirsterLmulne I. formed. Treatment Of I with 'let and 11100, give, a dit-h4whir which Is ovidisird by C10; in inven, - Title shingsk that I ItAll tile mein. ell, mws:.-Ilsm of I with Zn And Rt~W% give" 1114 smine. When #h1t 14 dintaillnirl "d heal rd .,orripiustriftiF t ajfn,,. 11. IM-91, willielt Is hy- wish Poct. If Si- a - topontleranol-l-sulforsk-mcid, That. itrolyted bY NaOll ~mcrne-I-4uIf(jniC em. Itts, Ne. Ca. Cu. fit', Im. M, As and feelic "allm aulgonle " Ill) mritt RIM10 me Nimmanthraeftil-2 Ivy The grapthod of ff. anif %f- .1muled during 11% PrtPll. tim ion of anthracene.d-sulfanyl s It cannot lie forrsiti. by ill As, Inv and ferrovii; %All* air (le- chlorldi It- Cis- lie.,, 't-tilsed Whru I lio~t it$ light. it rilt'"i" a dar-Ir in,. 11 while ,ajer the mine condilk &%m.lLA &A IS At 40 11 0 1 0 0 0 0 0 ST44000000 11TALL11116KAL L171RATM CLASSWICATION Vis D It stall MAINIC Man Ital o n 0 0 0 a 0 0 0 0 r0 0 0e000040900900906 ..*1@ 0 sa 4 _IL__4. aA The action of 110t an Witter solutions at m ddo and an their eWor on w" and lb". lot-lik4- sap. o( l-"it""-nsph1ha=gfM m-id 41) in ail toin. am autswaimavocauv redn.vit liv light Viiiiatkne,itmIS, i0ossins. than in "Is. The Ifit itall 1. entire imilvir lb" 11W Na -411 ot free I. The flainge twvmr- lietrer wbft The mill 6 dritualittil an wool then Oil -0k nr cation. T1h*s=e:(tnk1anh hassillm thrieution. and h"" it goes N, or M atm. - The I jLk%,mer iq inner tivethlirr in flight than ivi 1.2- or 1.7-Itimem In res"111. comptIm. in whi'll Mh and N)jIf are etmw%t (I ruch Oliver are The nawo 'I'milltr Whril the %uhiliftwelit are In the quitiogrnie i I,', ond 1,7.) the je,61 I, it-" %russ. Iive than whets thity ate in the rimi-quitiogrinic (1.0i anti 10pusilk"m Amont I fie dinlirmilpheityl tikulfidev and d nitrodinaplighyl dirul6de-i anti the nlinkentenisti4ifortir acids the o4"tm% are the mint wit-ith-r. but none we as arfl%-r at 1. When P41wr qKmkf%l In fileati faill"I. end t*%ptw,l to light It rin hwil,wilh dil. NatCrt0t *Qm, the colum err wt N-livr I ail I r4ur H,0 k isted. Tl;e %411% of the. tvipi-natilithelene cvv"ipdq. desverewitise Al"r rmul. [I. moke c*O coo coo or* 0 1400 800 AS411411 WOO ago no woo 61'sill &A 4%w its 11MA Sabha "Vitritiona')vy 16 0 0 o 0 0 o 0 q 0 0 0 0 0 0 0 Q4oQ46oW9o*oooo I of It U Is Is 4 *--Y- IL 11.1 A 61 6.t to Sokol to .00. L11111111-66"Ivo mitre Gavinvous". V. TU Santo of ::9 NK $.a -A- I A Jwf. - 0 b Q#Gk 00 2 0 00 0 0* 90 06 3 0 Um prodaft of dw cdou at snuonic add. N. it, twv and V. V. Koatuv. 1. 6*0. CAew. M. S. S. R.) 7, 1610~13(1037);* eh C. A. 31, M4tIt-t-%'hcn I -CoalG( NEMS(hif P.4fk.. are tril-,l 1-1 'unlight, it dayeppl. omirs d-iwn, 11 it probably I- dillino-H (it -nitro- I -tutplithylsulluoyl) -2-ti4phtlwl, t4l IlkuXb It'May bc an Isomer conig. another of( gionp all.l. anNOinsteadolaNOsmp. When the Mit %alt ,I tit, wame acid Is extiosed to sunlight for 33 his., tire dark pp whichremsholiprolably lbecyvfic M;xidt 42-hydrmt 1,1'-azonaphihakite-8,8'-di$Wanic acid. Ifthoexritnut, lasts 1.0~1.5 yrs., a dark, in-A. polymffic rnoduct is ol. tained. H. NI. Leimtti zq AS&-ILA drtTALLURrKAL LitairaTLAIR CLASIAPKATIGO Too., 90.01~ 'PC.. 0-09 flitSIM.9 it , V--j-r_T__rw__ a ad 0 Or 0 '1 Of 0 3 U 19 to III; . It it "a f, to 0 9 It 0 0 0 0 0 0 C 0 gi 0 0 0 0 0 0 0 0 0 6 0 0 0 a 0 0 0 01 4 sorill, a** 7 1*0 soill see ,00 .04111, *:o * 0 0 0 0 0 0 0 0 0 0 0 6 4, 0 0 0 )o 0 0 0 * 0 0 0 * 0 0 0 0 0 6 4 0 40 9 0 00 0 0 0 0 0 0 0 0 0 0 0 S 6 1 1 4 Zo 11 u It Al is IS it 4 1 TI u a m J$ At 11 a h a It 11 13 m a At I? a 10 A; At a 41 a CC 0 .1 V 9 A J-1 .,V JAUL-A-1-1 #A Is M PMP U 6 f..$ A A Ii t) 1-0 09 F, 00 1-00 00 2 Analysis *I dyes. V. Analysis of Illsolultle iuo dyes .00 a&4 colair lacqum. V. V. Kozlov and A. V. 14manov, 00 A skaya. J. Applied CUW. -(11: S. S. k.) to. cm %I Go F b M)(1937); c(. C. 4. it, ~=4,. oxxis. -00 A =Lwm am amlywd hv the UnIlwerhi tue-thoul (Off. lik3&MOK111)) of by the (latictihinskaya mrohmi if 1~!l -00 (c. A. To suslyrr intmol. out ilyr t,*K. pig. Incull) 0.1 $- Was di$NAVVd Ift 25 cr, 44 11,FA). (d. 1.J44 t by heed waW bath for 30 On. The tmiting "I. i was Wwalth 400 cc. of water and, after all air in tim. coo fiask was clisplaced by CCt,. was Itreted with 44) 70 cc. ofSnCJvfpr45mIn.to2hrs.uutd therewa%atilwpchang, Of COW whik lKsting on a Wding vlairr ljclh. The o %- CC1111 Of the reducing M=t was back-litrated in the UUMI OC z *0 uuLu-. TiCh and TV80,11a can he used as the ruilucing ts Ingeld of SaCts, but the rumilts are lem. wcurpit, 25*0 0 4 with S"ClI. Mats are NFWYAII in the valne way, sincgthcolidonnul inteffrewith 16&tudyl,. "k00 w0 A. A, INOVwIly Igoe Tj boo voo flo 0 be* SIVALLURCICAL LIURATUAll CLAISIFICATION C-zrr - -- * Ila.. Sa.01, x1lift-i-iii~4JI.- ~77: too Mallt) it a-- O-C lllkljl~ll aliTli UFO- 11i U 35 At 10 411; tt 1, 1; AAA INOWD ".1mims'a v OWL- PT KW I's a 0 :10 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 !1* 0 0 0 0 0 * 0 o 0 4 0 0 0 0 0 0 0 4 le~ p : : : : 0 A 0 0 0 0 a 9 0 0 0 0 0 * 0 0 0 0 0 0 0 0 0 * 0 0 0 N 0 0 a * 0 0 0000*0000000*00040 ~ V00 pro w go 0 0 00000000 0 's its is if 41 111 0 0 O'S'l I its s to tolititil'! 16111,11 ir 0 a _x I f.-T A * Ill T (w voqta~ 0 v Cie,Iis~ .0 014, Pill f #I 00 00 o-Antlinquizoamitanyl chIM4#. V V Killh.V AIM IL G. Fionsiva. fill.%. ati~ :11, PAS Awhi- .9 quitione is ttrA(cif With ChWiriAll (mlicip't'll its flit- A 0 tit sulflit" of itictatli,d the first and tilt, m,,,tid Ki.,up ,( Ow j peritlilic q9twi. rx of sails tit $-Alit hrailitintirtirmillotitt, see strill m Its malltmil. =00 00 is CID 0 66 j *9 041110 too -.0 00 AITALLURGICAL LITINATtilif CLASSWKATM" It 1--- 0 --- --------- .&I CNI cog gills, &I i ; " ;i "t I I I T.-I ... V171- - n at I W A I a 0 u lot AT 10 -4 ww a I I xx T I ir 0; old: 0 0 Ste 0 0 0 0 0 0 0 Ole 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 Ole 9 o 0 0 0 0 0 0 0 0 * 4 0 Ole 4 0 a a 0 0 0 0 q 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * a 0 0 0 0 0 0 0 0 *10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 * 0 4 0 0 0 a 0 0 0 Ij I a 1 4 P 0 4 N 1, 11 11 M Ib 16 11 4 OP a'11 V a 14 a JS V 8 P 6 33 L' U 36 a b V a 0 41 Q LI M 4 A :0 T k t A 94 Lacquer pigments. N. V. Vqw-uht-, Jr.. 00 SumnovAava and A. T. rroshchenko. Ruv%. ?ttatvh 31, 19M. Azo dy,-i ,btaint4l bY miPling 00 -4 P-hyd%P'Iv't4j'hC"yI with &%J.- 4,41,14N. firr o# "it 1,00 fur kith 1.1"tIAIC -UCh &A Al- "WIT11116 ItImI7 -00 IIA , 00 a f0 -00 00 j NO* 06 .3':~ :10 0 00 0 0 coo *0 so* 0 o "0 * oir -. 0 ~. ZOO OW i !100 1 1g00 &ITINAIIAR UOO 8; WOO V-4 --i-4-1-T - j- It I da 4 3 2 v go it n 41 og Q n I * 0 0 0 a a 0 0 0 0 0 0 0 # 0 0:0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 Z 0 0 0 0 0:0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Ole 0 0 0 0 * 0 * * 0 0 * 0 0 0 0 0 1~~ Ve 0 0 '0 0 m M _n ! 4 a U., . ~11! 1 oil a a 0 it It 4 2 1 Al 1 0 W 11 0 0 11 1 Is P I 1 1.1 41 It 42 1, 00 . - 1.0 ..0 00 .00 09 a As* dy**. V. V. K,utl.v. RU-. M.M. )%dy * -00 .00 0 Mg 1 Nuall anIto:Ut i.J6iA Ilk-tals that All be o%WU%-d hi 0 a ithrr stage, C. S., AIIIIIIIIJ114, fV110111 to IlLaUKAIRMS 0 .00 *411s, air added to diato *An%. tsefutc empling with the 0 Imial conlj~nctsts. : 00 0 3 -00 'O'b goo '00 ICAL tlygeATUR9 CLASIMPKATION all. slow VIWIII two 141431 ~v oil 0 Igmailo sit 0" (369 10 J 4 a 'T, 0 0 0 0 r 0 0 a 0 a 0 a 00000 0 -0 0 0 0 0 : 9 0 0 00 4 4 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 Ole 0 0 0 0 0 0 0 4 0 6 0 9 4 0 A 0:0 w 1:1 0 We W0,676"We 4,910 0 0 0 0 - -1wr d as 4 LLLLL U-1 --11.11'lill--~ 0e4 -00 MmUff Ale "Mrsfacs MoNo 000 -00 00-4 -00 0*4 p c-, .00 soc 0 00 a 0 00 ~00 004Z 000 fee -40 ooz 0* 0 sea Tfig-c6i~FL of d." mArgaw is detftvdwd coWd. nifteivaly. Nut of aw hae"kaft Iola got 40* cat ~74 tic"" *lWask.. SOA466 Nit Owv 411 on 40,I 00 A I a u 40 10 0 ir is ii 4 2 0 460000000*00*0090 o0000000#41000000 see* 00000000000000000*000o 090960C06#640 of 00000000*0090000 0 *w, 01.61, ~0161- 00.1 ~04--" 0l 0 00 1.4 0 0 0 0 000 0 m No Cc W U A. I "I 1., 01-*1 Ul 1. V -U~w -A 00 00 00 00 I-so so 1-00 00 .0 *0 90 km. lestbarm, ate- pe 0 U-- KIM. 1hmmlics 31; JWp' Tho dyq" effecird with 1.3. 1.7, 1,8-, and(cw)* 2."ihrtwxy. 0 -3 -Vhih&kiws w th~, mixt r4 0 01 1 j.4_C,j4(Njj.)" 00 e. lho Fwrwtwel4 all olillitinj coo 99 go * 0 0 00 Too boo to 0 boo S L a METALLWMICAL LITIRATUNE CLAISWKA?" '3460 .4s q%V 044 3 4 AV so a 09*0000000000 OTION 0 0 0 0 0 000000 0000 J"AL&A-Mi let 1 *4 T 00 **1* 00000101 0 0.. 0 its 41 u &1 41 41t0 IL- A- -11- L A 11-11 tt M -4--, 4-1- - 00 A ! Fr7 oo 00 -00 of Al '00 0o 4' 00 00 --oo &&%n C"thm- oft, V. V, K to u u . 7= . - KIM. Ike. St. UNW. 'DIV V,. '00 talned by oxictittion of a mixt. of 2.6- or 2.7-dibydr my. naphilaskme atW 0-tihenyknedismine, c. x.. with 11sot. go me 0 ""Do C00 .91ALt VROIC~L Uttit 41441 CLAH 0KAMN r. Zia". si"WaLl. aftv del M-- &V go is It M 14 166 0 it a I v 49 if it 41 0 * a 6 0 0 0 0 V 0 0 0_40 0 0- 0 0- 0 0- 0 0- 0 0 0 0 of 0 0 0 0 0 4 0 0 0 0 0 0 000, tP o o 0 a 0 o a o 6 o o o 0 a 096 I AS Ij " 1 11 i"OH11 USA us asu astrieSlade 46 dii~v 0 A I C _11"J rXIT is I I A I v a 8 1 A : W I I mail 11-9-11 A W. AV -00 09 1 gain* derive. 1.00 Light-ovaisitivis nitro compounds, V lives of with o- and "viblibluents can. sallser. N,N.Voajhiit,%v 1-00 60 st I IL U, J. Gets. Ckirm, W. S. R.) 9. 6121 bi likil)j; .00 cf. C. A. 32. 49W.-O-Nitircs-0-ruiplithybunine (1) is to. by n1irriiiici .4 amt-d-naphitsd6le. Wht,n -A%, to the 14v,. 00 =gms The va"irm issith I "" .,# II'S(X. it At,.- ill), in. 119.5*. It IICI is owil inot-All ill ll*S). in lilts ttvictiurs, ilic product ii atid. :Ile its. *3",.1*. U is nictiltrattly lialst-tirnutivir. Nittaltim" 00 givr. a likisif ~ .4 the Ll- and 4 111tio .00 0 0 drilvis These our [WAS ftlkl, by JW%%l%ind lilt 11110. its Go* it% K611, ddig.. ridilinx lite pla. toils v I'hNA 1, Qlhl Im- 00,1 iikq in a stfranicA dry IICL Urkh-r ills- 1.4. : S:1110, 09. trittamplithylatittide L4 tiljlahw4~ Ity cite Gattefirtisifut tv- "Clims this lim orld. ill. "I "'go: 132.111" which it ulkli" by 116(h its ths. Clirl"Ixill,fitia is 0411 -iflionis: SAM. Both thrse ackla are weakly witAitivv to See light. dd k/ IS tMrSld. IIT I lie 00 91 Sunditteyrt reartkin fitsit 1'z 0 richl. It is a hyjtivscvpk- yellow lx,wd" whiter Its. I-e !50 !zip NI. 00 A A."'-W YN.&I COW UAS44 %AMJ. CA All. $1, It LIAGK LITEIAIL411 CLAWOKA11010 .'r". . As is er TV. U vt AV M3 "jo 0 tv 1. a Is if ill a 11 M it a n I a so 11 43 a 3 1 V 0 1101 a 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 111 0 4 0 0 o c a 0 0 443 Cc 't I ki it 1: 14 it is It p :1 u A30A XvxJ0 lot) JIM Jon by Sjov it wood,** "Pil", 00 pacc#9111 AW 01CO10141, .Lot r- naphthylamint mad its Irsaidormation into an suo dyo. 9;_ Vomilmov and V_X. Kuduv, J. Grpo. Chem. 00 S. R. 1 9. .1 - - -- K. U(110W 31. 5.ilml A mWit6m ot nh -w 61.4). m ns 11-111,4 lit.111 alt.. m NIUM l1w:.61"I alk. u4n. Kivv, a dop lift,wit-1.12.1, (Ill, ii ppid. WW1 40A. Th.. IV'.. Illwlitnhh- ;I, ml =00 00 .3 !.1111111valm, Klvr, % 1110-n-mt -it, Ill -md, 00, fwm.mud N;1.011 o, mwi-r-fidly ill-plall w 111w, of .1114 1 ago 1611OR10111f, J1141 Of 9- Athl f john Lival coo so a ago so SOO s!00 see 41*111. 00 04, .j tie o "'o A S a S L A Of TAWAG)CAL Lilft#7601 CLASSIFICA110 1 1 t3vo so sic Ito., 10.", l1re* -Z T 2;' -"L- An- -i- a AV 10 is 0 IV so 0 a ew 0 10 0 1 v IN 5 a a 0g of a it If It 91 it It K kW n I : 14 0 gio 0 0 0 *go* 4 so*@ *00 *00 000 4 00 600699066* so a It ;to 11 v F1 m I's lot v w a 4 61 A; Al apo I v I - i r I A k AA a u II I .00 ChowAstry of naphlbalone derivativec f ReActiOll A) Joe anic acids with alkali chlorates -00 of paphtweammewaff so and D. 6. Talybov. J. Gto - C". I I'. S~ S R -M -WO10)).-The mrtion of I RCI whb KCI(h m the luviting trllnk~. I%vf ch-4-11v -00 1.6-C OC14 and Smuc I.S, I.X- Aml '.!- 40 C,4H a uudcr thew 411ndillow, x"%, 0.411 AV% -.IL, Clifw The mactions mV act1mvp1mini bv lum.11 .%i. .04 Tf the di-Cl mmpdI. to datik;~ - -00 Of nme,m.,106-70. ; . lakr. plzr~ at low f temps.. fm fW). Chad. 111,4", 00 j 00 00.1 300 Noe 91 :2.", ::$so RL*41ACtl 'r LAI. ("I U~It IIktUMAAA;W C"~ 9d.. 1%4J' , AT '1 .1 . A%- % I z : I I we* J#1 --04 go a--4 a I IF 04 1 0 00000 0 0 0 0 0 0 0 4 090 0*0000 00 0 0 0 0 0 0 0 * 0 0*00000~1roo:::*9* 0 9;4 0 a 0 e 41 # 0 0 0 0 0 0 4 a 0 go 0, -000000600 :Zile 0 0 0 0 00 0 0 0 0 0 0 4 *0*0000090 00000 I j a 1 4 1 a0 4 as 11 It w Is 4 it a It j0 HT a311 V'x "loll 161111 us me mostalou"aace A -a "9- I., "as i P&OCISSIS AstO POCIstial-11 Oil cApadtj col wj~nk p4p-ont-a and %*-%',K41Alcov;al%1A. Simanco"kaya. dw 1039.*N-ci. 10. :111) 42; skkim~ Risferal. boor. 1040. No, it, 119, cf. C. A, $4, 36M.-C-mipervallarar slots moo- pte-writ 4111 tkir ml empAcity 4wf "volli, orol. joloolivelitt Aild varlifth" ii,arol ht the lx4yrsophl, indmitar. Fsaar -0 0 letit. ail tod rairwity (hr mrth,%l't,( bsamig a, SwArtli'l 1" 111"'ar.4 A110.4 th-Ses. umearch 11too .4 w w VAMill'141 4111il Pioclalttll~; it lit MOM I'Sliki. .11asViltille ILMI sanail Slimat ttt,r(mltjcibk- arratillat. ZOO Lee 00 zoo a* o so lose t:e 0 1:311110 A 1 0. 1 L A AITAI LUIRGICAL LITINATIAt CLASUPKAIICU so It! _14-1501 -a Jac -1 0-0 S 1 or So 11, 611 is 10 us AV so 11 T I', 41"t 1 1: g a 0 11 : : ON a '01 ; g' : 9~ 06 : : : : : :: : 6 166:09:090:0000 0000-00000 4411164116606*~ fig d CLAUOKATIN .0 V. W Wo 0, now page! Ms. dy" od : d thi , w .ag w > book 41e ~j 200 0*0 go* too go* age 90* wee no* woo At -00 "Ji 1; 'A it a it'it i il it a itra a -i IV, Ol 0 0 0 00 0 000*0000000 tislw& 9W 1 11,6.00 W a- ~ -vw W.W0.0 w0 0 0 a 0 a e & 0 a & a 0 a 00 go 00 r 0 a to 0600 000000 0 it a a so a ft. VJX It 0 SO 0 4A 0 4 I AS a __L_j L At__" 2*0 _J_!t_"ptq -00 .00 --Of Sit 000 d6fiVativ*s as oxidation dyes for fuM. = Am And D. S. ZhUk_ 1. APP(W (. - (U. S. V2 V .0 IMI-12(in French. 1313)(1030).-The ability A 0 halcurs to dye fun dc"cases in the of the dihydroiyrA&Pht mdre 1,2-. 1.4-, 1.6", 1,7-, 1,3-, 2.(1-. 2.7,. Ifi-. IA- zoo y1jprocedutcladescribedindclail. coo 1,4-Naphthyletiedfamims and 1.2- and 1.4-amin-Ph- lbols, also were stud[W. Richer colors are obtained with 6 these diarninci, than with those of the benicne series, too urnbiuations ul these dyes in fur dyeing art stmi dixuucd. c Nhydrozynaphthalents can he combimA with other oxi- Iatkm dyes of lbt usphthakist series as well as of the betmene scrin, The fastum of the dye an the fur* is not infetlix, and in wxnc instances It LL supetioc. to that ub- It l isined from licantic "Ys. 22 referroces. A. A. D. ose le 0 '00 '09 -i go it I t i~ 'At flow* go v1srm9aq3#.,x 0 000 q *1 0 0 m 0 e a 0 0 0 0 9 6 0 0 S'o 0 0 0 0 0 0 0 4s 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 a O o 0 0 0 & 0 MP f N ' jolt lin lots ismassal UU a F F d old 60 A '.r. *0 1 PSOCISMAS AMC ..A the cleavage of the lIctert"lly " and the foruistwork of I Nato compounds. The-Istasoctlooic d d1iiii Coom. corresponding phrools. Thus, the derivs. of *-(NNC4H#- 00 j 1 Note wltl~ complex hotel polly acids. Xr,,L?, Kodo, and Nil, and ol-anisidine gare resp 4417a #-C~.NCX4011 and ru . Arkill IV M% Conflict so Ge". CArria. (U. S. S. R.) 10, CM -06 09 OW). cf.pl-. A-j31, 85171.-Pteviously It was shown etiodlounines with heteropolly adds and certain dy" as- (Rum. put. 51.808. C. A. 33, QMI) that Monistic di- rfrood fmm them. V. V. Koziov. D. N. Arkhlpuy and 09 Azoniurn suits tract with betero" adds ound their salts A. V. SArnaraivskays. Ibid. 697-77N.-The isomeric as0i free front F to form water-husol. Coulplex dL-ml CJLfNH.) reset in IICI IkAn. with heteropoly acids to 01111 11 polls. ljj~ Addill. data show that the scheme of the closest. reaction give splitingly Vol. complex salts of the type: jC.H.- A with pho%phontulybdic acid (1) (&M with bosphot [C4IIl(Nff1)IjS-jIIlP1,WA)IjI on (NI10118-111 acid is: 3 j .14,X + I-Moto - JArN,jlgP(b'foA nic and IC4II4(NIIl)ejj.II.S4(W,00~. The complex -who, -1- ivrd foro~tn .. a I t-i-nrt.. raft -lift NaN(S in IlCl 9 + 3 fix. Silicottimptic at-id tract, with 4 11 Z AtN.X. Ube "nuplex diarn or"otnp&., derived from i-o- .4". To of" 'j lbor tvt-~ I in" it' 0! k- it rividlinra, tolulditirs and ardsidinors. are inxil: And Iff.NC.- In coulnum Ms. sulwnts and are =1. in cold amtin, dd If NaN(% is used in excess of I eC0. --row morodiazo products bcconw 0 itlycitiol and ILI70 NaQH and in hot ca4N and m tnol.. the yellow or paile I'licy show greater stabili ty than the common diontelcompils. dilcolored by partial decompti. Analytical aw, extod. '31 to the action of elevated temps. (""). .evidence showed that only I Nil. vuup In "IUNII.1, Prolonced V ::i Stomlle (over I yew) and shock by blow. They burn in a Is diazatiied. Thus, the drcurrini. of the diato products ! free narne without a flash. Then "us. (freshly prrpool. Willi Wiling dil. IlpS04 and the treatment to( the drvtonipri. 1 or third) react in an sq. m%pornsiclin with azu components irs.idue with LN)"'o NaOil jpvr no reulorcinal anti hydro- i;. togivr dyrzol the manic color and tinctorial strength as the ~nnonc, r"p.. but the corresponding m- and p-IIINC#11.- L-Punding simple diazonium salts. Cu and Its salts 1, Identified as di-lit derivs. In ully. and stability catalyze the decoinfou. of the complex diam toolupois. with these itionodinin eximpo1q. air Rilinitoor too the curriales duali MOCO 00 . .00 I-94 *0 ! -90 -00 00 age 300 coo ee if nIpoll. dcft-l ibell in Pat I I I AlMVr. Wile" coupled a it h no W-,.. A: I I A tl1LL1,kQkAj LITtItAltollf rtA%jltKAljC* TS AT 00 111; n :0 It op 04 N 2-C.ol IrOl 1. 1 hey Ilive lilt t it oil lit town &sit dvort o it gi kxI Nat)II he !ago se dye. f.14tiless. %%Illrll treated With N are decontiod.: + ~060 PiNaOlf - 3 ll,NC4114NICI61froll + alfro + NAIPOI + NaiNliAh (d. C. .4. 31. ROW). o-C4II4(NII,)e rVACt11 slu) with hett-m4tilly itridg. but the resulting cryst. ewnplex Vodioi foorill Willi IIN(h Monte o."llpkol C.11111"ll. Ill.-lipal's, of timpling reartitm with ara "mulwincins, anti ~Wbly ts Ides of the ly too, 1C.H.N.I.M.M siv" Analvoils rmitktin*. C. U. C. ;o AA I S 10 a 0 1 11' 14 1 Ah if of it K I to 0* 0 07 10 0. 0. a v u jd a 36 u a P 4 41 a a &AS A 00 A POOCISS116 -4 1# Soriat. it. 'i -don of a salt of Wd'I'Uto a "It of I-nsphthyl- If. V. Agistow, A. 1. Itaryshev and M. F. F-61614Y."' J. Gr*. Owoo. (U. !1, S, R.) 10. ?A4-1Xk1(1WO1. O-L C. .1. 31. 71731.-Tbe translotutatkm o1 the No %sit (1) of 1,4- ILNCIJ (U) into the No ult (III) W 2,01M.) an heating with %Wd or CJI, in the ptes. ewe of Sk proceeds vk the No sot (v) u( I-ftphthyl- -*G Suffatak NW (VI). slace 2"All amis. of 1-naphthylaraine from VI can be detected in the reaction mist. and V yields -00 0, IU on ::'%onOdntQkv)t 1. as moneously stated by Beritcu. see J: hdm m (C. A. 33, 13(W) for the cme- spondLug N14 salt. The K, AfS and Ba salts of It tcact =00 in an analogous manner as 1. and the X and NIL salts of r0 0 V1 react like V. 11 is not rearranged an heating. The 00 yield of M 6 particularly high (73.77%) when 1 is boil,,l IN ith QUitIOUTIC. Gertrude B~xcnd too 002 U09 400 rkeOCOW UUAU.r't4- rh.,~ A I a I L A Of ULtVP.GK4 LOP.P&TIVE CLASSWK411016 lorm, a a u U AV ;0 UTf A 19 09 U tt It K KW *to o 0 o o a 0 0 0 0 0 o 6 1 0 0 01 :_OIL.*~ O.AJ19-0-A ke a q a o a o 0 0 o : : 0 a SIA 10 0 0 0 o o to q o a *.6 41 If 4" Fi, a ' a is 4 is V is of 0 a a i'll a, 517 if 111 It APO it 4:4) rio , 1 1 , N , !t 0 MIT 1 1 r". 4'2o A 00 A B . " . . . or " . . " a a I It 6 V 1 1 . 1 b __!l' -A^* - _'-. -. 0 *#a 1,1101:11011 Alai 0,1104,11MIt Dr. 00 The MUnWorat series. 1. Tblatithromor-.1 sulfamok 00 shor"Iyaka". J. (;Va. C is"o. C. S. S. R.) 10. fit'- -M -00 60 a Cell. still AtClj give 744 A% lidantfurne 0i Which it "Xidued by CI(4 lot orI46at 110A, to givr 93'e, thiAnthircite disullum oil, tit. 321'. rills is very incirt 0 t toward Plillonatins &sorcil-, and only When brat"I lot I hill. at 140' with a large curols of 012% OICUM in a scalcd I tubc does it give "A`4 Ili a moplei"Ifomoo: 41fid, isolated as the Z 1. K mh (11). No othri coonjxl%~ can be obtained. The f' two 0 , Nil.. %Is. Nil. K. Ca. 114. /it. Al. Fr, )'It still AS -wit, 00 131 I 1, 1 Ati, Jewlilit'd. 11i'llm It it Iriluml low 5 lit-. Willi 111.1. .00 00.3. A( Iftil, ill file litclenvor 44 a Hill, Ill 10'. it Ill.,-, ,I Ifte *0 irildir kill), drN.o%j.-. IUV, When Ill il k1f. in a walord to1w. it givrot a vvty o I J ll i Nil l 1 00 ll! volfr ' oil J.F ll"" . sl%v t Mollie grit and . too 'jaoj4#. Ill. 17n". whro 11 in Rf'ound Willi 14:4 and agne 04F a 1v - 11twis and livalrd Ila .5 tits. at 110" 1 78% of a 000 00 z Culinal will$ id "I. 12W. which f. by oxidiling Willi the cow 1. prepod P 00 j. IlOAc. tr~iun of 11 with NaOll gives PhOll, CV01 I. feiroudnol and p-110C.U.S6411, Thrmor facts Voter! thAt 'Allicination of I occuts in 1114? j1-1001ifiUll. I M. L. A ; ifllilll to 0 0 too# A 1 6 - 1 1. A -1 fILLUJIGICIL 1.118001149 CLA111FICATION cc- 58 too smicaj all 049 cog AP)MIC"t ~11:1' . - - - . ___ -ei"i, 211-n09" I" " 0 .9 1 14 L 9 1 old 0 a a I w st s a 4-3 4 V aill it : : : : 0 0 0 N 00 0 * 0 0 0 0 0 0 * 0 . : : '0 1 dm** **,O*o 0 Olo **Go 4 00 00 0:0,4 0, is 00 *0 ol 0 0 0 0 0 o 0 0* 0 0 0 0 0 0 w1Mw,,YTL",A IWO It 12 11 All atiomp*411000 41~0 A-A PROCISM11 &"a P110011 tilts Dim grpo#M. IV. Us Wuncs of p*bydrw ed n th d1awdutle of mes 0- i4 o e s auddlawbe. V. V, Kailloy and fl. 1. Stepamir. jl!rx. CkM. (U. S. 8-,R-.t1O.-T5I0-23(l940); cf. pfc- 00 vdln lotr.-Thtinflut=ofaddn.o(glyccrol,niannifol. , xlurwe. nialtow, latc-nale and (CIIA d= raffulose ou izAtion Of IN-C&IIAN110i (1) wrA Investigated. Tbe ykM of biowlistso clatupd. famed Was found to incrtax with the itilmloing vilA. -1 110 gmps In the will. of the added substacim. It &Lw in. creased with tht rovicn. of the added sub%tfinCT In boll). It "s altit found that the addith"i iJ sly(vtol inct tawd tilt, age lited of the stso-coupling wcactim. %% rUrvint. 114 table. and 17 Wertifirvs %-.v given, jahlro J, Hi-fitill Zo 0 MA, fig* ..e -Makw- l-, zioi il -V. a - i-, i- -11 V, U n AT PO r T A a ip to ft ty it ~11` $9 Olt xx 0119t. :*:iooo 0 0 04111, 00 00 0 00 KOZLOV, V. V.; ARKRIPOV, B. N.; SIMANOVSKAYA, A. V. "Investigations in the Field of Diazo Compound--III. On the Complex Diazo Compounds of Phenylene Diamenes With Heteropoly Acids and some Pigments From Them". Zhur. Obahch.aim. 10 No. 8, 1940. Lnb. of Dyestuffs, Mo6cow Chemico-Technol. Inst. imeni Mendeleyev. Received 13 Oct- 1939. Report U-1627, 11 Jen. 52 9 w4 ~Waj , 00 A 60 009 son 004 so& 00 ova 00.2 so OOM ii 0 so Mil ii! 4, 0*000*060000000 a Is 4 a 9 a 0 0 al 4 a 411 Way 4144w: /d g certain nuirdants and in -'-t-. with 05~i=dnym The colors were clatividembly Inure Its Ilion these of ordinary dyes of the bentrate wics, The IA-, 2.0-. varld 2.74movacra can InteSSUY the vol-w in a mixt. with other oxidizing drgs. Dihydr*XY- n4ilithAam caa be used (at the synthesis of vathWlle IMMIS In payfftephy. . W. R. He"ll Chem. Ab., V01- 38, March 10, 1944. &ITALLU46KAL LfftRA1k1d1 CLASWKAtCO 440 aw 684 filial cave I filial Oftv All Ig AV 00 Ail; 0 a 0 1 1 , - f r- I S a ew 0 N v I W IN 9 3 ang man -.1y"AlA 00000 logos a go 00 & 0.000000 :190 * *000 see 0000000.90 .00 .00 1104140 2 -0 ago 0*0 go* 000 so* 400 #so 4040 boo ti is of NTT WAS old* .. I i Y1 so 00 A wo wim X. kwb~Wg Y- ja -00 90 V. 'I ; A W : di y -00 ater v. . u p. O t$ - d. C-1. A it "m AMIM "1120*6 , with uddike. ul b -day" =fo ! ~ i~ -00 so WWAWOAA t lk l.-- YkkU W* %Mtj kk = -00 *-8 o act, to tb Ii! of .00 ... mtbF to the (H-011 -pd.. t at Zk)+P* lovisal the Imestiesults. Thembotsel- 0 u rwisdat amill l1kd WM hydrimulAt" "it Und" 4hd aban cuu- AO a J 3 F J4(S(h11) it W U g . j~Wj chtkmu cauM be aL., to fog of R"bthmt~W- age 0*-0 clad. 0'. Mw &w =.pnxhwt w. L7444 do*,, M. . d'*Or"O de"p. 0. with too g ~ 001 ?bNVQ tin pwduct yWd# -P ws-4u"- 40muff- goo 0 6. Lt. KOW11puff X*d woo 11*0 00 A t ONT q" 94 w 14 w) t *$'0 1 Olt 4NO 426 * -~-4 4 I - F - t AV 00 All; ; AM I fm a a I I IN 04 11 A 4 3 1 V v is, Or At n A x It K a a It 0 * go e 0 0 00 0-0 **A*** **a* goes 009 *11`1 lei lieu 1:11 a It 0 41 W IS M a a It a IT 0 to a As a ape IF d It I If to K,IL,-j I- d- 2-1-6 00 A A- -00 o*P i 0 a VIC I S 14, 11tianthrous series. U. ill dtoulfoost. 2-HydroxythlitAthrmodWisifeav. V.V.Koi- a Wit anti N. I,.*akhov4Aya (Moscow Clicin. Te-M-N4.T.- -Prem. Chose. I I Hk-2D(JM)(in Ruslan); et. C.A. 35, 4100.-N3 2-thLitathrenesulfunate 3.10-di- At NjOlf. 0.M g. %'4%*(h. anti 20 -60 th,c C~O tewti-i "t4y be psittiAlly c0d, with EtO. CIICISI i %vh-ne fituit the vallitial reaction mist . but. due to its great ~~Jy. ill wiver. the mother liquors still tire the Above- I** inentionel ilye. It was poqiitxlc to lsobte only 23-M70 .00 Z-hydiaxylbiaouArtive 5.10-disulfitim (U), m. 160' (dr- go -E sp: con pit.) (from EtOll), in a state of comparative punty; 41440 it xMill a brown color with FcChp a btack ppt. with NH.- 00 Ax'No,, a white ppt. with Cacil, and a Yellow ppt. with A ljr wlter. 11 wa3 acttylated only with difficulty on be-jl- 0 ing to M* with Ac4O in the presence a( a little 11,SO,; coo (1) Ac deriv. tn. above 30)' (front F'tOlf); treatment with 1 It its AcOll Save a dib-rowde. CojjsO.SHrj, in. 150.5* 0 vc. witcr were livalvi In in jutocLive 5 lirs. to 19U'. ifroinAcOllorPtOll). T'licatono-Oll conapd.z=7 also ',I-** the mist. 4cii,lifivi to Congo red with 11C], evapd. to be obtained in 17% yield by conducting the aut"vv aryne", and ext.l. with UtOlf to give 0.5 g. I.Jt4iky- reaction with 1.27 C. Na sullonAte, 2 C. N&OH, and 20 2.1,00 ~j! droxWhijaArems 5,10-disuffoxe, a Alce -yellow man, tn. cc. water5lus.at M-90% with isolation of the product by z0 9 197 di-,Vs sail. yellow needles (from dil. HIM); Pb =it, HIM citn. of the evapd., acidified reactlim mist. Alto yellow gt*in% (Irml HIM 1); tbeK. C4,,;.'*, Cot Nit and M. Kowupoff IL.'x jalb arc reatfily tiol. in water and 111011. The Ag oft see IMMOrly ". In Witter. Tho above expi. was Micated. ing 2 j. Na Nill and 2 g. CaO In 2) cc. water U hirs. ac age U, t:* IM) 11" .. ('Zwed by "ifimtion With 11CI to Coope red; it ji the "a. ~ thtu coadenied withl P-Ditrisantline In :41 ;' % ?C 4.%L4 WALtIONGKAL LIVIERATU01 CLASIVICATION I rZoo IM lot 0 U a AT 10 W tit It q, it K It X is 41tte, tftUon ,,AAA A S 41two '14 larilloa 0 3 i .00 V41 0 0 0 41 0 Si 0 0 0 0 0 000 see* oe 0 0iA *,0 0-0 0 0 0 11) ,C4 1**. 000 0 0 0 0 0 0 I OIJ 4. 1 4 A h I 004 no P-JI AND 01CO11114% ~01, 1 go - ...... Tke naph"ette series. XI, Reartatipmeat of the no)(st of I-seAllool-4-sultook acid Into the salts of I 6 Xplik"-2-nifectic add. V-V~ and ?,I. A: 11tatwC (Mainjim, Chem' :6 J. Von, C". (11.8-4-R.) '16. am ozoll. Cf. C-1 - JO, 27441. - The rea"Angriftelif c4 salts of 1-114phthol,l-mmunic " Into the salto ot I-Asphthol-2- so 4u)ftmk- iscid was fttudkd In reopect to the c1lect Ld trisill. 00 wid Ouse, the restills, were mnptrtrl)r min"out Iti thoac 00 tet-atird eviller (Voroahttov, ef s), V.A. 33, 4:17.0) Its comorvitom, with the forination of saltsof 1-naphthyllamine. 004 2-stalloode acid. The r"Wrancense"t apilarently J*txVcdx 00,3 throtigh the ittlersurcliste fornsatim of a I-itaphthol sulfate esict; the reaction I!& clortijiletely Inhibited by CaCj. Tbc_ '%,, with ittax. duratifitl 0( 000 felop, range h-Aled was JW-2 f] his. in a typical exist., 3.23 g. IN& I-olophthol-f-sul- 90.3 14mante ami 21) It. mand we" heated to VW 3 bn. to give I.ttaphth,44- and 63.47, Na 1-nmph1h,A.2-.uJf- -Late. The the productik was effevit4l thiotish the 0e K smIU; saltin4out with KCI pptd. ottly the K I-na fithut. 2-Sulfanatt, the 44so.mrr retuaining Its u4n. G. boil. K. A j L a atfALLUR4KAL L111441401 CLASPOKA1101# IF 0 1, p to o`I W, I it to m a to it 49 a I III 0 0 o * 9 0 W a 0,04 0 An A Is 0 ad a 01 W Me n I m a 4 9 W 0 0 & 0 0 0 -Zoo 0 00 -0 is -00 000 ago COO coo too 99*0 44 400 rdp-- 0 -- I t 1 4 to if Is if 11 M JA Is is 9 At to a of 41 Ollw 4 led -A-A- b t, P Q A 1 -1 _u ~c W-ju., J- 1 9 - .-t- CA v 111-1 A 4 4 t V V K h - ,4 t , Dane. . raqu I-IlydFosyant -Xf,- - I-Amho , 1917 :IiP 68 MO S R U S r . . . r. . , . , . I;g,wov 4. , 'ill ilmor'lliflulk. arl.1 I% actol u1""1 by Ile I'llrdil. 11",A). ill ' 1-99 so . ll,.Wll Z0111 -,Qo so 0o to as 0 00 zoo 00 00 0 0 ho 0 1.90 floe I'K 9~1 tj it "I 0 0, 0 0 e wla 0 0 0 0 0 0 o, 0 * 0 0 1 0 0 0 0 0 e 0 0 6 0 0 0 0 0 0 0 0 o 0 0 0 so 0 *go 0 0 0 0,40 0 0 0 0 0 0 * 0 0 lo 9 e 0 IS * 49 0 0 0 **( KOZLOV, V. V- PA 15T46 TY902AChemistry - Anthraquinone Feb 1947 Chemistry - Sulfonic acid "Investigation of the Anthraquinone Series: 1., The Study of 1.,4-Anthraquinone Disulfonir, Acid," V. V. Kozlov) 10 pp it Zhur Obshch Khim" Vol XVII, No 2 Synthesis of the subject acid, and studies of its salts with metals and amines. 15T46 KCZLkiv, V. V. PA i5TO I IU13M/Chamistry - Anthraquinone Feb lq'7 Chemistry - Sulfonic acid "Investigation of the Anthraquinone Series: 2,1. Chloro-4-Anthraquinone Sulfonic Acid," V. V. Kozlov, 5 pp "Zhur CYbahch Yhi?n" Vol XVII, No 2 Subject acid obtained by action of chlorine on 1,4- anthraquinone clioulfonic acid (see above) during its evolution. 3-5T47 a- I I I Ask O= ina~ M 4 4 0 But". TV. l. ell of, "Itwitaw = . Vk'V.xGW"WWK-I'KL4kl1-VW .so "Cl,1101,41 )".'Wit, Tech. Init. J.41 F. ~ d I he i h h 00.4 Ahq. I, S.R.) 17, 302-01(1047). cd- it 41I T f h 1 It i stuAw an raqu (KI nt a V " to ou"1011YOrate In"afts ranging front MVV t C so., .- reattwat o ant rmane ( ) w t of , higher couch. "is to significant amts. of ox t . . 4 showed that at -U4)" oil to 21)':(' AlIthlAtillillOSIC I% -1blAill- 00 C wta, principality anthraquisione and d1hyd laut je~ TZ able, while at 70" this ti". to M'16; at hill' igililKwit a l milli% an olklation of I under thm Mulition, are stints. of C am funnni will lhk4 Is the limitills; trolls. fur it, -Ole of tile CulkstivIr cti ims e ti d lli l b I ee AIM In corves, showing the effect of tcrop. find of the . t ( ve al a a i on r r i . 9 courts., and knit. of 11,s0, tmril. it 1A M..'sunittl that Ithr 4kV The ititht el. reactivity it( 1, no smittloation (Akm Isl ~ ' 0: 014latlaso t*krz 3 lislelwildent cossirlin *Idcb least, r"p" to dressin. cWtil is uilloile and &JIls elff w mlil 4111hra r lle Isw '4 Iftlive alklAtive M(st, (it 11,14 1. i4 tO W.". I His" ok-unt IUA-hr, r"tril4m) siv" imitir rrssuti% ill dult 00 u u ir ous t v , y , q throw. Pure I wa% pstro. front ant brallubustut by rittkic. o4lailon 6 the stilly strat'li-s, oh C 1-mousis 1wisix lion with At dust at 30-10" It% 1140 140 In 1147 yield omcwhat inore lisrusiousivol, (0, Orion Wid, 1.1 C list - 90 4- a (ortimit, in. M-40"), followed by purification, which is tuition even at.2t)'. Whets Its licated tirls, m thwrrtmd (or um ifr t f 10% h l *0 43 Initially the most dilfictilt operation, by cmtn. from -%fclr 4 " hi di 144 CO h i l i ld hil 1 2 o o e ng ismill. o wit Increas mooloullonation to a 5-fold most.) the sunt, Of utWh4n&"1 sol) - mme ate e s c . in - e more . w . w y y crystals. give the pure Droduct. M. fat-a". I (I g.) wait I rapictly drops from HUq- to 61)1,'0; wiIh2?I)`~.r%rrxvoIruuA ' 00,3 added Vnisdually to 15.cc. JIT504.11[sO with tirdng at 300 ,~ 01CUM CX- ,sit 100' 50% of the I is carbotoral, white 4 60 ' and kW 2.6 hn.; at ter posurinf; Into 75-11 1 cc. Ifso, the gives 40% 1, 3S 5% dihydrulUti(hione, and cen at OG-70 13.5% anthraquitione. Addo. Of 1011311 AIIII.S. Of Ni[,Vth crude prosittisrt **A Wiclul Olfe wwlstd thollo4hly with 'Or NJI96044sties rotcAu-cibesulloIL-ttioilfvActiolI totAke wattere and driell t NJ*; yjVI,I 0.147 S.; ritylills. froth Mer- , Plactit, tat sonsewhat rftfucrt the client of the oxi'Wissa, at N114VOI of At du%t sitoln (he oxidatiw;u almoTt 00-70* 11 CO Pee IK4 g. I asid 1).45 g- mixt, of aojhrkqsAj,,,4. . coospktdy. Attila. of SIC], IL&s a simiLor effects only 10% ALAL. hYdrodixothrow, its. The wi.n. of the prwlucts n clo-c Of mixts tvnt of C wi,, dow dilsydrofiallithroce being formed undtir conditious which . g. by tits. with C'114' an'llyzing the ext. arcording; to the normally yieM 20,17. anthr4quinow. HgSO, promotes idccrea~l! of t anits i ifi i b method given In Part Ill, anti Sept. it 1"103 ivincipalcons. is by extu. with cil, (witich lesivet; tehind the bulk . can on y s gn tbt oxidation react urift"ed1by,50%). Na'SO. promotes the formation &4 =dilAydro,fialithrour),essapo.of the t. anticryurt. dilsydrodiandirosse but hindtTs tile formation of antliza- * , (Ma Mc%CO (which vitra"t incM at 1); when the t. mdlifi~ the eilect~ of itchisone. Raising the temp. to 100 w tile ukilit ~ initiall exid ont in d much 1 with ki~~ AH Addidvell. G- Sf - KfWAADOff . c a e w . , y NlcrCO. Air-1,lowing of I x. I in 15 cc. 95.61,'o HsSOm 12 JIM. at 20' jave ahtsM a quint. yickl of tilbysiraWan. a throw, in. 1130 . When I C. I in 10 cc. 95.6% lf'SO4 was kept at IOV 2.05 he%- in A %WW Stream Of COr, there WAIX milli, lac "V Lt, obtained 0.:., 0. 14 S.'Othit, OjEkjajtDgk U 0 AT $0 . I ~ 0 9 1 1 V is S 413 it It IF OF #4 IF zt IF 1 1 An L N 0 v R)l IT 0 T*16 004 4111t0 0 & 40 0 0 0 0 o 0 00 0 4111, 0 00 00 0 0 a 0 0 0 a 0 0 0 0 a "41110 *00 -06 '00 Aloo Zoe I;o o 000 Ice 0 Oleo 40 00 18309 No 0 0 UOO kee :: * U U 14 U if to 4 ubwoo "riots. V. ms-Salfaisic adol of an- OOA .0 i, raw V, XorJoy Mendeleev Chem. Tech. Inst., M ). ' , DKMW Liles. Ckonoo, (U.SS,R,) 17, 747-U(1947) (in Ru"ian); cf. C.A. 4Z, 561g-Anthront (1) with Itrual okum or MR0,11 gives ws-axiArants4sook I a). V g.) In 2) cc. Acoll, treated otw 13-30 mist. ' at with 3 g. 007e ofeurn, heated 6 hn. at IOD . oes l"red Into 7&-Ino cc. HsO, and filtered. gave 0.5 C. U" vroduct com osed of 80% anthra and M% uitione p i , q Mited dihydroanthrone, anthrone, and C. Concn. of 09 the filtrate to &.8 cc. gave 0.15 g. (lack product (11), which was purified by charoaf In hot sq. HtOlf; It forms l minute jorisms. which have no m.p. and which bydrWyw j e9 tws heating the aq, soln.; I (I g.) and 10 g. C1190,11f 00 lot-Ated 3 bit. at IM " and treated as above gave UA5 jr. crude insol. product, which on brief boiling with IftO 04 0 gave 0.46 g, Insol. solid mitt. similar to that described show, whike concro. of the sq. solot. gave 0.3 g. Buffonic h h d h h It at abishIr t Plenf)cal wit wit okam. C antes W-150* S 7 h i ll d t I f f i f i in is. or oo e o rnm rom t me emp. , chingr The result, higher temp. merely Unno Ing the amdativr reactions. The sulfonk arid on boiling 4 his. with water gave U.90. and 1. Its well as trac" of anthra- 'j, 0 1 4 A 1 -quinone and bianthrone. The sulfonie " (ormt; the : ~ [Alawing salts: N4 64hydratc), yellow needles (from rill. 1 4i 131,011) which Juse 211,0 on stowage ever Ifs'Wh: di-Nor, yrilt,w-torren 14-11" Mm" all. P1011): CO irtilawIlre" ' nrefle% (hom 11%0), difficulily -4. in W4 11,0; Afg a smAir, lf'~" Pb. plAt", Ulmnal Insol. III 11P, 14011, i1c Amil, 11W 4flol 0144 ASSigneti 1111P 31111117~ -71t 7 F4 T 01, -V-" --- 11 - -P- U sor or a it or at at K 4 or x it cc It It it W ~UM o,,dyds, 0 00 0 :*0010 IN W a 0 ;1* 0*009*0* 009 9 if A j6 V 2 30 4 40 a a a *k 0 - -coot 111 4P of uu.&4tWoO,,Voak on the beals 011 eltmen'sory Anthr""O'se -00 M, 's sis P-bIc'*- and ev"It'lloo Zi al d b = r Y in y outol biant dustuc 11011011r3j'. change Uf the YT'kw go 00 "Ime , to- CO&M of the mor N*as4ll tot ,,ter has an o-quinnooid the Latt tow, indicates that 1 . t-ff G. %I across the a 0 0 gtrcwture a** Coo Is 0 7 -co- I - L'~;V l 10 * W a W I I It 14 5 41 4 2 1 if 1 1 Iq 0 114- A 0 14 4, Jj 00 A, 000 00 A 00- 0* C 0611 0o 0 :0 0* 00.3 OOV :a 00 04POOOTOO I I 4 it 0 00600000009000 a Is 9 a 6 0 At a a 0 tt M-M krdwatiminonit Swiss. V1. ictwe 4 dAwomwmk add on anthraquiume. V. V. "&v IMUWM Chrm- Tft*nol. Inst.). J. Ap*arMir. (US.&R-) 20. Srt- ucncr -980947)(in Ru%%L4n); cf. C.. 1. 42, 1231f.-Tbe Intl of exce" CISUM. time. alml troull, Oil the rmtkwt of CM)%II with anthmijuirione (1) w-AL Intcalgatiml. The reaction p"Krr4ls in it complex manner and at 1.15* yirldi the -%ulbi (U). 2-chlexosalluetyl (111), following defivs. of 1: 2 2-chkwo (IV), dichlorn IV). br1rox7 derivs. plus anthra- cene derivs.. w1ducts of Cl and IICI to 1. as well as un- changed 1. The yield of M as the chkl pmduct can be obtained in 3 brs. at 135* with jo moks CIS%ll or with 18 moles CISO'll and I mote 0070 olcum or WWI sulfate. Sullonstion In the presence of fig doft not lead to I -sutfo derivs.; almost all the I Ig sublimes in the form of IIICI,. Srpn. of I and 1111 is best done by ligroin, but fractional crysto. of these substances Is not very salis- any factory: hence. in view of the rather low content of Itc- ondary lwodycts. the analysis of the mixb. was best done by sublimation of resicluji I (temp. is not given); M is esid. by difictruce. 1 (tn.8 g.) was added over 04 hr. at to= temp. to 11.7 At. CLSOall, &IW which the mixt. was heated 3 hys. at IW-3'; after cooling and Pouting on let, the inixt. was m ly boiled. filtered at 80'. and the filtrute stul Aq. wasrigs were heated to the b-p- and treated with.10 ml. tl)% Xa,80.; the salted out Na Salt of H Me") is filterrd off in 15 bts. and rect"d. from IM). Z At*.SL41 -tIAL~Lllk.AL LIRSAV641 CLAWPICA110M conv"wxl.,( this to the a deeiv. $IVTSSfv 1, M. 24-6-, thus showing that the primary product if. 'rho ppe. ("Minell ffl-111 the naiginal resctim Edit. asul Ilet) UUWIV m. *U--8* and M Sublimation gives I (M.8- 0; crystn. from solvents (unqwctfird) Permits 603111110111 of 5" 1 . - U. 111- Will' (from ligroin); no ember products stem ISO- fated. The use of excess Ci&)Jf gave addni, prorlocts, summarized Wallows: Na salt of 11, 2U.2% Ul. 1.5% IV, 2..5% V, 1.5,; brlrmv firriv. of 1. 2.0% hydroxy detirs' of qulfiwnihraquinont~ ivl),3.5~tanthracrizedttin.,un(ill.151 adductsoiCito 1. (2)12mok-sCISOJJ: 40.0,2.6,39-6.2-3.3-5.2Ati.o. 5.6. and 0.21'. frsp.; (3) 19 moles CLSOJI: I I.S. 0.0, U-5. 4.01 7.5 6-0, 1.5. 2-0. Arid (1-155. r"p.; (4) .0) moh~ asmil 80.0'i. tram. 7.0. 9.0, 2.5. 2.5, - Mle V referred to represents be mist. obtabird on trt-&t' inent of the motlu-r liquor, after wpn. of 11. with byl 1~- chlorite. it is aplarrotly a mixt. ul the 2.jj- and .1 known. IV was estd. by Cl nalysi. of the th....k;; washed ppt. after ice treatment and by fractional c!yxin. (it the sublimate from AcOli. 11 as by adsorptixi ot AIA from PhMe "n. The as we VI wen detected by the mkw change of the mother liquor an neutralization by the mother liquor with hypochkxitrs at III), gAvv a crude hydroxy chloro deriv., m. 2.%-M'. while crystn. from AcOll gave COLOVOlfh, m. 2D4'; although the stnw- ture Of these COM-f-li- Was nOt ftlablilb9d. the cotot change to red an twulralizatino Indk-Ates a 2-011 deriv. Crude III on bettling in sto 111410CIAVI! With little gave Kj-, -41114111 -4110 .00 1-00 .00 -06 moo =00 1;0 0 ;, C*0 ro 0 4,1111111 Z;O 0 1940 300 moo C200 Tb*uWottationo(2.J'-dinaphthyltutione. V.V.kq,iIus -0 1111. S. TuIlv-.tn%k.4yu ~ Mrodclivv luxt.. ;-J, .044. Nauk S S N.H. $10, '-"1:; sit 11474% Client. 7rodr. lo4g. 11, _n". is. rhr W fla, Action of on air rItirnirly Iliffivoll I., millonalt' illulty nor- m4l runditionst- The avid onist Ili- 4nird, lilid nird Ili Urge r%cm. Ile min. roncit. mquired is, litudoce slow %ulf(init. linti tit 100' %hrit Itself in an e%r"% equal Iii M times the thrtwrtit-ul aint. "a% A like rilsrr~ of Wr; livid ,ullonatni the xtillmir m I.`- L1.1)" is ithin oil hour. A SO!' is vii"- of lite (oth-J. on innaostallana t Ion) slid not produce stull-mallon tit ', Inv. even at l(W. Nn bet- ter resilill were I,bt;4jn,,J bY Irratiox lite bulfolne In JfOAc with 20 Wce nicnin it br, at 15'. The adifts, of I0% NRr So. Well. oil the ~Ilrotl. . the traction some- ,' II,It HICAUW --f Ills no I, III lite 2 naphthalene an. Oc-1, the J Ow its-itt 1" 404". I's file 'Hitibaritultril pt,wincl I, vIr,v xbxhs. R~liwi Issisduct, lepts(Int are' 0- f7.2_IItNSCa,If.h (If!, last tellil". lAw,url the fissimown,4 I and 111; at A1.1111 IVW the 6,11111- tioat of III was already thitht, while at I&V the munii-I product wim 11. The ill comr.14. were tint brominAted 1,v while the mons; comild. took up 2 Bt atoms. All 3 sulfouir j4-id4 %hoierd weralz surface activity (ensulsifying porrerl, Alkali hiflimi. rJ the dioutfametand- yiekirtl di-1111 ilerivIs. whwh couhl br useif as new aso d.~ romposlesh. fixpll,: 3--(i r. (2-Coll,VS(h, in. 11W, Wd% heated with 30 times the theoretical amt. of conril. INS is, the PtodIII-1 Jklini'd intill I(W)-*-Xlfl rr~ Water. filtered Oft; the tanchangesl ultone witshril tint, the itasibef liquor tind %&Sh Water liCtItIldift1l 'A ith IIACOs. atIll the filtrate from the Ittit cmird. Ms. It's firit. the" the- ILI 'All of 1. 1110 1,111r.lit. was rVAINI. to thyllem Just ritid. will) W."', ale. Th.- rt'idur was 81111'.1 Islar 1; It w4s obtAlled front The Alc-~ Vxt. lirrivm. ill U lite Ila %dt with jlSAJI, yieLIC41 fnv 1. a,( it hy1r.-K-,,jAs: nza-. tit. 64'. The its ult with VC4 ~i Ili,. A[ IM' vi,,hIiii lite dirblurille. -nocti"(1-us C.U.. xvicur. and IIIIAO, tit. =', :llls7~ hi drolyled ill 6 lirs. by bralling wilb W.I" ,1 ]IN)'. "sulpittrIT hydrnlyged by aq. IIOAc and aq- ak-.. fnerned esters with anbyd. "~ Missif,,ndmade, ptatirkto Innis MrANO MeOll. ru~ 21W; di-miloffaxilid,. ptattlects f",nt PhXf I/ C.116, its. 'rig'. 'no Ila $aft. CSIfoO.SIiA,AjI,0 vlv.W~ front wairr an mimbedrons, C.11ol)"Ba-0140 111,111 "Ale, as ilmod.,brilrons. C.11,043,11a.711,13 front I'll. ak' l-1 ~Imfrtpla; P& oak. plairict. Imot 11~0)e; 1 1OAr. in-A. let water aml 14011. Cu imill, greenlidi or"Ib., Ca nit. thin ureslin; Pr ' ' '. Ni * I '. a ','It. pl..t, trip; till salt. granular, insol. tit water; Na. K. Mll. tit, alld fig milit. readily pol. in water; axilime salt. C01ir "A W . AXNtIsPh)*,4IIP0, medIrs from water, In- 17..*,, bloffiilfimol Jab, Imm W., In 2W. NOVA. *,I It. M.'WAP144. IAN frtint L L&I )WAr. tit. C110. vrov .4. In 0,11. .4trill, and 143% ty'd"roly" by floating *till notti 6 loo A III) '' still otherwise anAkWou., ill the aichlothle of 1; dijullem- W940, Allt CIV*tAI4 ffllnl NIWII, to INX% ill%olr ill VdWt, Vill.. %virne, mild C14-o"14, A-ITS-m.; dijulfe"d a dow,, ope lips foAo MrOlI.C.11a, *-,)14c umiles from Ilk.; nic.: btausdiw Sak. obtaint.1 as Jill ody fraillor. 'I be %.1l, 14 other metals and of triany andn" were very all. it, Ila'--- I~Vl. with the a& gult of Ill gave the salf,,syl 4hl,,,d,. 11milro (fill" C.1101. tit. Ifill 7* and froto this Ifir xmpAIAwhxi,, in. Ill . and 1.6-du him omaphl4olt pit, Ill. III*, o 0 4 0 0 00 C 0o 4 0o *0 of x -3 Poo 0 Anthraquitiono series. Vil. Suppression ON the Cat- f alytic effect of ntatcury in the sulfitattlort of an"al- nano. V. V. KoLlov. /Ato'. V&S44401 KAIM. tj. CWn. evolved on sofit. of llxt*l,. III, I~Alfftotl t~ JIJJ(*J J. ! -60 Chem.) It. RuWatt); d. C.A. 42 d ;i , ll&)s + Sk), ~ IIjS,). + 2 SAIIIIICI, 'I*llr ext"t of the ation 72wk, anti follitaing abstr.-Ill victor of The eluci reverse reuction, is insulficient to cnuirv wtcquAte removid the nature of lite %wil-known anlicVktalYtic effect Of N2CI- of Jig by sublimatiota tit IJCCIl. I,ht,,, 4,1&1. (d 111IC4 CWntVfAcq1llg lite j_%IlIIon.1tjl11 effect of lilt atill thus . husilluch As it is colivrri"I Into has the %ante ' _1111141111 Ivermitting of atithraquitione (11 to vioro- - ll the bo h t H id i i :141ft"MAWIF "AlAlYlk elTmA A- other lilt ctuillw1ok. This r a c lo le pfrW114 irvt1l ll f fullu"Ic.'r s, h l d i i t "C" IS Cry" "Wrly 4 "o"(101-Wint M4 IMIIV 61 NACI bill al%l r so n e different Jig comildt. tit sullottat on, an t y. by other antiraiAly.ts. Thus, in The sjjllowl~on W :bM C Oltum. virre investifilited, In the rilowsulfonatiou of I . I In 160 g. 40% olcutti, with 2 it. lIgO 3 5 btl At 136' in the prescnccul cotiiderable mints. tit flit, 1160 OrJINSO.. h . , ih, ajntq. of Of- anti of a~adfotlic aci4is were, ;jIh n ~i~ a y the un. -4 fix (culctf. its ligO) bound ( - s m h 4 1 r ! ' I in NACI 45 an.) 551!. *jih I C; NJCI, fix? 'not ()q; 'ith- , coo 3 It); of Ito; wt., 17% in the casir of MOO.. in ( 1 u T u c 1 u l With Jig, IIlj0.,.r IfflSO., trams of flit begin tuatIlwar If' hlxCl". Ilk, .,,,I i 91 Allot 97,; oait~ I PT; with 1% CACI, h 2"' '" PO l r " I i l 7 too Z lc mut. of the Ill (us 1100) the sulfunAted pftXIUCt when 0 1 f 1 II C I Z l- a . w ' 2 , l , PCI.- Of -110 11 ; '. with 1. 2. A , , nd V!,, Nalit, I) isn.1 fix), IA..i Anti X1,3. M'f. Allot ms:! 0 - ,6 (rewive to the wt. o ). 6 about 4 4. s %. I1 h h d i ~ KCN li,-v4 a weak anti~4talytjc ell"t. thu%. witll:l;lnd rja,,, e n- owever, II er 1 v.; also directs lite sulfunatiun to t KCN. 46 Quit 54. .54.2 still 47.8%. NaSo.. -,,I tki to 5% 111[ch, the unreacted I bindi only up to 0.75% - C 1l b1 f th l il f Il o , Va p b, e no R"tiC3tAIVtjV VaeCt at all. The foffi)Willg i e - era or amt. o e ; it con its wt. o g s sublimeoi, anti conticeLsors on the walls. At 1330. the Wy. ' facts are quot"I as evidem, that tile atill,mat"k 8,,, consi4to in supplying IICJ for the ~cjjou So + IICI - v olrism is very slight And no CV Ions ire of JfgCI# in 3.61,~ ' ' " , SWIClo which convert% the hulk tit the fig or fig conllxI _1 J.h", v olcuin, one detects cqWv. units. of, detectable; in . into nollioIjAcd IJSCJ,, thus ensuring The removal of fig N Jig** and of CI-. but. on cooling, 111W4 Crrtmill"M In- . frM the reaction illixt. through sublimation. Pre- o 0 C 1 t stead of llgCll. Con~rqurntly. In oleum. I M 's #4 f limingry boiling 'it Prior - onitfoilattion L t with HCJ too 1 oo 1 i 1 compd. Into IISS04.+ 211CI; in strong okum, . boo A 14 1 A al IALL to06Kill. L 1111 AIUNI CL A tWKAVIU 0 9 8 14 41; old., 411.411 WOO Q_ ON IF &;*WfW*;: 1 ::1141341 9 9 r 0 At a Of AM Z 0 Is I ; WI ~111- trip 0 0 0 0 000000 e 0 0 0 & 0 0 0 090000*900000 0 0000*000*00-000000*00o 0 0 0 ooo 0 oooooolooo ::::::::Oo Soo $00000 : 0*0 000 00 so so 00 suffonation to 0; while with equiv. amts. Cie Hgs(), and Naa in cotled. HM~. preliminarily heated to 100- 110'. the product Is a; with a mixt. of lIgCh or lilso, 0 ith 2 CqWv2. of N&CI In 25% oleum. bewiftl as before. ; 00 I -sutfoole ac4d Is obtained. II;CIs alone In 211% olcum, preliminarily heated, gives a. but with an addn. of 1% 80 liCl it Ives onl S bli 0 i f H 00 a . u mat on o g gClt brXins y ottlyafters time lag of about 30 min., itscribed to formation 00 1 .01 the complex 80,HCI.HgClg. The rutchanism of the 00 anticatalytic effect of NaC1 con thus be sumnsarit"I In the 010 scheme: 3 NaCl + 3 11.90, - 3 NaIIS0. + 3 IICI; 3 IIC1 + 3 5% - 3 SCOICI; 1100. + 2 S(MfCI - 00 "It" + II.So. + 2 M: 1-11C), + S%IICI - IICC6.S0V- - N 90 11 1 irclaxAllcl - SOXCI + HgCI, (sublimes); the global readies: Is 3 MACI + 2 H*SO. + S0s + If&). - 3 Nalm + Its" + MIMI. 11W effect of KCN is .explained in a similar wap b6 formation U the equally noulonlred but less stable s( Nh- N. Thon 00 go 00 *0 00 0 0 a 0 0 0 0 0 0 0 * a 0 0 0 Ole 0 0 0 0 0 0 0 0 0 a * 0 Olo 0 0 0 0 0 0 0 0 CA 0S.U.ni, .,ids V It K!Clly~,Jf OA."At'11,:=.'l 4701%, 111 -tech. M, slilrl- Inst., 26ftmicow). Pokkidy Akad. S4.k S.S.S.R. S7, P17-70011,47); Chrm. Zemir. (RtiViUn bine FA.) 1043, 11, Imill-1; cf. C.A. U.NIN Omluryw dAtA ill the lita., Ittiv, I-alakraq X14-4. mid (1) :Alt IN, hirdli-lys"ll mitladquitiour ill) I,v lmV, III t1w Ill bAli*. Thc ficill of lt~ Sa -Al 11C.It'll bolt SO.,. 11,410, luldvir aliont, A 11h)-jNI, fol Ii h" tit XK" 11. 1 ydro)Ysiii of the tm,I,r t--m Ill 161101.1". 11"itv%er, II.-Millit till, A. I'l .tilt %%,Itrr At ;ilwr /"I Ii llf~~ K.4%v MIV it' , 11 1 %A ht-Itt'l it- NO t, Ml-. %lith vIt"Id 14N 01 1~ it, tw1clitt'll [[j; m1t. tlw hOwl"., ..I if,, I .1IlItWfIIIV lillt Of I--- ~Alli .1111 111. ~! leould lia-hydrulyr.-d withh:", 11"SA).Al 1111i ;11 all 01.11 V.-wl or oith '181. act'l :41 yidd ill H. iNK; , Tip- I, %,-fv 't"wh ,vicrat-I fly the 14-111V A 119, itith .1 119 MK- 01MI-1 tl~ms (kit Itird. I wAtc4l "ith "At.1 At 1,41 ithl I (IIII. tit ltoi% Ow tv.Illlml liquid Wil-Is ifiL 11,141, , , %Ij_q U,i.l, ill,- irl"I'l of Ill 'Ir.rea-d 114 Willi Im oil grmill. V%ull 01,11 if..- ~At- A Ill, 16-1 kNA. K. Nit., Ill C.-I illft %k_l, tit, sidd ill Ill A." It ki'llid N. Illl-- d I., -w. if .'.' , JJ,s4 I, "'th the NA ..It t,f I ,ml h-lillit it :. 0 'i.11 I... I-' I, I". I(rittills I %tit it 'Aaw, lit lhu ptv- lit, .4 l1w 7jej,f ,11 ut; 18 111 It I 1,"A 0. U-1 -tl~ It %ij. obtaill"d, i% IN-li J.z anth'aqwq 1) .)'Noit" 'o. ~'l %%AOIC.11441 Willi 11,S41,111 lit' p1r,,two 4 fix -ifl,,poly lit,- I allmit, i,id %,-it, .- - 41"1 it. J, .,,I,i w" It'irlmd. %V c., NLxt, KOZLOV) V. V. USS/Chends-try - Antbraqulnona Apr 48 Chemistry - Anthronet Ybrourization of "Studies In the Field of the Anthraquinone Series," V. V, Kozlov, IAb of Ibres, Moscow Chemlootech Inst Imeni D. 1. Ylendeleyev, 10 pp 'Zhur Obshoh Xhle Vol XVIII (L=)., No 4 PA 8/49751 Describes mercurization of anthrone. using mercury acetate and sulfate. Products are dthydrodian- throne, anthraquinone) blanthrone, and mercury organic ccupounds. Submitted 13 Feb 1947. 00 a at 00 *a 00 00 009 *0 .3 as 00 3 00, 00 0.0 Id.0 0 11111" goo so a as goo** AlliLl- 00006000000:::!* T, _rl *'100 Tt'o 0 O'NOCE ISO IA.0 0-~112141 M~l7ll' I .-a* 0 !-*a sturfrig. VIU. Merestrattillia -01 am- If Zhur. ObsAwW Mar. (J. Gen. C Chem.) 18, 707-M(IM);, c(. C.A. 42,12W. and pre. ~66 ceding abstf.-Anthrone (0.58 a.) still 0 Raw ligo In 30 nil. AcOll a-, rvilulted 4 lits. V-41tered but, 00 Ills 0.27, a. of a black solid, which on treatment with IINOv tA hrv. at nvom teinp.ww% treed of metallic Ila -00 save 0.2 a. (11.41!;) yellow atuarphous, (Ijoill'(Wit :a prullably blj(P.10 - d4hydre - 10-rure -0 wilompy. The ma~kir product tw6ted by cv*Un was 10.10'.bianthrone (U), m 2561 (fnxn AeOll then C C611a) (0.47 c.). and anud] am*s. of unreacted antiltme. 00 As the reaction time Is Incfft= in 12 her. tire amt. of the 1.4tter drops to 14.4%, the "black prolfuct" locrewws to '0 OM a., anti It inctet6wit it) 0.42 a. 1, Ititurviled with it ills) 0 little "fiRdlin 4q1 "lilt Ivivilell with ittilling with romit. MI 3 1 hm.. SAvr IIKCI, and 1111; 1 (0.2 1.) 1 6 mi. 5% olvilill I fir., a-',S I. It. 1.1 a. anthr-ponone, 0.15 a. Ila, anti roe treated with CI (lot 45 min. at 1.5 , thrn poiarTil Into fre O.K.5 X. 1; 4 fir, 4 M, tr4cr, 0-07. 0 Od. mp.; adlin. of water, I.Ivr 0.1 a. la, 131.1$- smoir At du%t in '~e Lilt rx;,t. K.1ve 11 IS. 0.1. I ;wellali 41A a. Mov"ed lin I Illulle. 0- 00 ((fom (111. F1011). Ilthilinx 11) a. anthrotte. tog. 111CO, u anti 2W nil, AvOll hi'll. 2111411 411111%. of 1,111ILilit, W CA ithydiule and j,h.,L tile Ill, which after extri. with ble,C and crystri. were alw i%olAtnt, Uthrour (0.5 1.) In 10 nil. llio... from AcOll gavro.15 a. midue. does not in. up to 300- IGO treated with 0.5 a. Its %ultAte in to mi. IjpSo#.jIto, "41110 and on reduction by Zn-AcOlf save 10.10'-W-9-anthrol. heated 2 firs. at "". then pourcil Jilt., water, C.1ve .... -- , Indicating that the original product "us Ila. 0.61 ff. Solid. which after earn, will% ClIC4 X'lvv 0.15 ff. 'age When a a. antlif one. 5 it. lit(OAc)#. and 2W mi. AcOll Rick frlifilur. Cj.11,,0&S11f (HD. which ii, In.A. fit the i be 0 were fluxed file rniinwins pinijucts werv I %jUtr4I: usual volmh and it,," not int-11; it is probably 11 JuValf; the ClIC4 e%t. save 0.31 a. 1:* 0 m. 11.07, a. mixt. of anthraquinone "ith U, En. 2,"'. and OAS a. anthraquirtrate-imili t in "we mix ', " METALLURGICAL LITEA&7441_CLASUPKAIICN 170.4 ". (The.nif it higher truip, (70-lit)") incm1w, tire -SW OF v An & U IV 00 it 1, a fW 0 M 0 1 W IN 9 its a 3 It 11 0 luo n I 0 a 0 0 a 0 0 a 0 0 0 0 0 0 a a 0 0 0 0 0 0 0 0 a a 0 6 a a 0 0 0 0 0 a 0 00 go 00 410 so 00 so 00 as *0 00 so 90 difficulty t4 limitations oil III becauxe tif C intonation. 111 idthCrOt in HIS% at M' 1 hr. Save anthrosquillow 185%); y Into who. of M in U.S06.H.0 at W-00" gave the same product Kati U; tu catud vri,.h a ,little Sl 0l and ACOII and treated hot with coned. IICI band K 'A pre mathraquintine sold III realized with KI in dil. RtOlf In the :Zsenct rof a Wife slizann nil throne, It. milli a NO H -liv., pvrtan a tit 01001. In OWN. stalven 0. whkh on treAtment with H.W), kws S. but retains Hit. analysis giving r-,tH,Atfg (rW. wt. in HoSO.. W); it is up "rently Moratival with 1. Iffillinp O.A 1. 11 "fill 0.5 g. VIOSO. I" MI loll. 111,10o'. 1110 3 firm. at fAV-Gtl* with litining gave 0.2 ff. anthraqui. "Oni, and 0.3 S. 114; no Its iferiv. was twitlated. IX Action of satfoomating agents Do do W somthrone. lbod. SU t--&-The actiou of sid- =ing agents on netio-He derivv. of anthrone giv" it Clitliples traw 40 a result of direct exrhaple of the fig 'rolue (for the 11011f 111111p, 01thialivir redtflons, and oildt freelit,aA. M-Aritlutiltylill"cury Oullotle (IV) (0.3 1.) 411,12, rid. lls%.11.011"Iml I hr. lot IOU* seat theta poured into 8 nit. WaICT girr a ppt. cmtg. 0.20 g. Misittal He .]"IV.: no sulfonic acid IsdetrCtetl in the filtrate; traces -1 anthrmquincine unit 0A1 It. 11, tit. 284'. are found in the ppt. The Its detiv. (14 g.) and 5 a. W% toltuou after 3 041 hrm.at~oo* veOllit.13and 0.021. anthrequinowle, while the all". xtz nw, tratinticia. tiltration. and xcidiek~atinrt 0* 0.33 it. ac*i M (vi, K.. Ran 00 C.A. U 1254f). Monitor holoothis low 3 fire. at 1:1.'6' save h V i 0 . traces of as, atit ntintsultanic avid. anti 0.04 g. rilqu 0 0 0.6 'Of. U, so 'Well as tracts of 114 and C. Heiiiing WS g. V th 6 S. 20% olliturn 3 hr%. at 135' IaIW to yield any. . 00 thing twin an elk. ext. brilkles, 0.03 it. ch1cwtainthru. IS 0 quincine. in. 202' (cobtatiml by treatment tit the nitrate with HOCD. the In". Imikin pire MIA 1. anthrloquin,wor 09 anilO.3a.11. IV 0.6j.) *nil bit. OSAMI heAlM3 hroo. I.# * 0 0 133 few* unrov If and O.W I. V. as well as IM" S. I . 0 tolanne. be 1gdtr1v.*tU t2o; all - I hr. at 70*, filtered hot after 0 pdni Wa~irloter, P" on sellindimatim Othe oil. u4n.. filtraflact, and a. V. while HOCIadded to the filtrate care a true@ of I-chlorilmonthmclitirmone, tn. ' INLA ; the tolsin ppt. (1.3 if.) on extiv. with CHC4 kit 4.3 a. itimal. residue ciatite. S and Its and camsponding in- 00 comilln. to IV; the CH" ext. gave 0.7 a. U and 0.12 or. antiumquinone. G. xf. Koft-Ulu'll 00 0 0 0 0 0 o a 0 0 0 0 0 0 0 0 f 0 0 o 0 o 0 0 0 111, C-4 101 J-A USW/ChemistrZ - AnthrCaO may Chemletry - Dyes, Antbraquinane "Studies of the Pnthraquincne Parie;~YIX," V. V. rozlov, Iab of Dyes, Moscow Chemicotooh Inst imen:t D. 1. Mendeleyev, 4 3/4 PP 02b= Obahch Xhim" Vol XVIII (T No 5 Devoted to action of sulfurizing agents an mercury caMounds of anthrcae. Vith.the meso-mercury com- p=ds, a coMlex mi3fture is formed as-the result.or direct replacement of the - cury by a sulfo group., *- 9xidiiing oonqensatlon =d similar process. Mie .aation of oleum (700) on meso-morcury-oulfate or an', d1bydroquinone-mercury results In the formatiom 8149T6j USR/ChemIstr7 - Anthrme (Con+A) gLntbrcn8 M080-thio0arbonate and dibydroantbrone as basic products. At 1350, the main product is dibydrodianthrone. When chlorosulfuric acid (1350) reacts with anthrone-maso-mercury-sulfate, the main product Is enthrone meso-thiocarbcnate. Submitted 18 Mar 1947. MOscov Chemico-tech. inst. im. I). I. Mendeleyev. 8AW62