SCIENTIFIC ABSTRACT KRASULA, R. - KRASUSKI, T.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000826220003-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 31, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KRASULA, Rudolf, inz.
-
Ten years of experience with glued sleepers. Drevo 19 no.7:
251-253 JI '64.
1. Research Institute of Transportation, Bratislava.

G
,IYZIN, I., inzh.; KRASULIN, I., inzh.
The P'rVL universal measitring instrument. Radio no.1:45-46 Ja 165.
(MIRA 18:4)

KRASLILIE, I.D., in-.h.
UsIng electric resisLance ten5c-r~rztcr~. t--, 'nv-tzi-tfa
effects of tho cour.I.Ings of atcol
357 '63.

FRASTJLTNP T.D.
Stressed state and the cArrying capacity of -1-jointe. Stroi, truboprcrv.
9 no.10v21-25 0 164. (MJRA 180)

.- obl..'Al)
Induo'vrii~l dire ci,ccws. Pozh. dolo 7 no. 2:2') '~ 1,~
'l.
(,. r
. . 14: -')
i,rov.L!-,cc--v'.Lc Lori c:3 --Fj I-uj -."; .,,) pro'i,,: i ion)
u

KRASUINO 11.
Shortcomings in the milling system of the milling combine being
bvdIt in Vologda, M&. elev. prom. 23 no.12:19 D 157. (MIRA 1112)
1. Glavnyy takhnoiog Yaroolvaskogo oblastnogo upravleniya khlebopro-
duktov.
(Vologda--71our mills-9quipment aiad supplies)

KISEM, , I. (Minsk); KPLASULIN. H. (Taroalavll); MBL'NIKOV, P. (Leningrad)
A u9oful measure. Muk-clevepromo 25 no-1:31 Ja '59. (MIRA 12:3)
(Grain milling)

DUROV, I.S.; KRASULIN, N.N.; IONIN:, S.11.
Experimental study of panels for apartment 'irujy JjTj 11,7:
11-16 163. OMIRA 17'.3)
0

KRASULIN., 11.11,; P"VELKO, V.L.
Experiment in uzing fv-rwring method,- and Inst-ruments for atudying
defects in structural elements. Trudy rTI 147:27-29 163.
(MIRA 17:3)

KFLASULIN, IN.N.
Re.,fl-stance of wood tO VOMI,rC't' :31-on a(~rt)33 the fil.,-,r3 as related to
its structure. Trudy NPI 147:37-54 163.
Exporimantal study of shoar vxonjen, of wood aloni., tile borders be-
tween the annual rings. lbirt.05 -t-,O 0-11PUI 1',%3)

KRASULIN, N.P. (g.f-ashkina - Moskva); MISHIM, S.A. (g.Pushkino - Moskva).
",
Scales for determining transpiration by weighing twigs. Bot.zhur.
41 no.8:1145-1150 Ag 156. NLRA 9:12)
(Scales (Weighing instruments)) (Plants--Transpiration)

K 1214,~ A f P I k, , P,
USSRIFe,re-Ary .- Forest Cultur-co. K.
Abs Jour Rcf Mur - Biol., '11) 21, 1953, 95836
Author KruouLiii, V.P.
L'st All-u'lio'n Scientific-Rescarch Institute of Forestry mid
Machanizntion of Forestry.
Titlo Value of Or[pnic and Mincral Fertilizers for Raisin:.-
Slcm-GrowinC Scedlinr_s of Forest Speciec;.
Ori~,,?, Pub Byul. aauchno-tclei.-.. inforri. Vscs. in-t lesov-D'Astva
i r'CWI--liz- loon- ldl-vn, 1957, iiA, 38-41-
Abstract Emparinents oa fertilization of sccdlin:,5 were establislicd
ia the sprin(; of 1932 at tho IvaAuy(.,vsIeiy Pursery of the
AMIFM (All-Miton Sciontific-Rescarcl: Dstitute of Fores-
try and Mccha'Amtion of F:)jL-estry) )a poftolic,
Lovl.T.,.d turf,
amdra~;c clayey unfortile sjil wit'! PH 4-3.
applied in the sprin.~~ fron a calculation of 100 t/11a,
Card 112

USSR/MyeioloMr of Plants - Water Re[;ime.
Abe Jour : Rof Mur - Biol., Na 15, 1958, 67828
Author : Krasulin N P Pankratova, N.M.
Tnst : All-Union Sientific. Research Institute of Forest Economy.
Title : Transpiration as an Index of Water Absorption by the Root
Systems of Tree Species.
Orig Pub : Dokl. AN SSBRI 1957, 1.13) zio 4~ 927-929
Abstract : Duri"G the summer of 1951 the transpiration intensity of
23-year old trees of an oah-ash plantation in Sallskaya
Dacha (R03t0V8kaya, Oblast') was determined using the
weiGhinG method of L.A. Ivanov. Transpiration dropped with
the onset of the dry season; the process was more marked
in the ash than in the oak, and it was also more marked in
the areas of more severe natural conditions. PAin caused
a sharp rise in tranapiration in the ash) followed by a
Card 1/2
- 14 -

KONOPLYAATSIW, A.A., redaktor; MUSULM V.S f r6daktor; SHIROKOV, A.S.,
redaktor; KOLOSIOVA. M.177"Fiffif8i;Rfatellotya; OMOVA. O.A..
tekhnichaskiy rodaktor
Eikparience in using geophysical methods of prospecting in hydro-
geological. engineering and geological research) Opyt primenanila
geofisicheskikh matodov raevadki i gidrogeologichookikh i inzhanerno-
goologicheakikh iseledovaniyakh. Pod red. A.A.Konopliantseva, V.S.
Krasulina i A.S.Shirokova. Koskva, Goa. nauchno-tekhn. izd-vo lit-
ry po geol. t okhrane nedr, 1955. 74 p. (MLRA 9:8)
1. Russia (1923- U.S.S.R.) Hinisteratvo geologii i okhrany nedr.
Tekhaicheskiy sovet.
(Prospecting-Geophysical methods)

ARM Arvela magnetometer. Razved.1 okh.nedr 21 no.6:59
N-D 155. (MLRA 9:12)
(Magnetometer)
I-N, ".

~,., KRAS
Meeting Of geoPhYsicifts of the Ministry of Geolog7 and the Conserv-
ation of Mineral Resources. Isv.AN SSSR Ser.gsofiz. n0-10:1234-1236
0 156, (M1RA 10:1)
(Rrospecting-Geophysical methods)

J~WULIII,-V-Z~---
"Atlas of theoretical curves for interpreting magnetic and
gravitational anomalies." D.S. Mikov. Reviewed by V.S.Krasulin.
Razved.1 okhr.nedr 22 no.5:63 my '56. (MLRA 9:9)
1. Ministerstvo geologii I okbrany nedr.
(Prospecting-Geopbysical methods) (Mikov, D.S.)

IDASMIN, V. a.
Conference of geophysicists of the Xiuletr7 of Geology and
Conservation of Kineral.Resources of the U.S.S.R. Razved.i
okh.nedr 22 no-7:62-64 J'l '56. MAL 9: 11)
1. Hinisterstvo geologli i okhrany nedr SSSR.
(Prospecting-Geophysical methods)

New American geophymical instruments, Razved. i okh.nedr. 22
no.11:59-62 N 1569' (MLRA 10:1)
1. Glavgeofizika Ministerstva geologii i okhrany nedr SSSR.
(Geophysics) (Mrsical instruments)

AUTHORSt --Krasulin, V.S., and Fedyuk, V.I. 132-11-7/7
TITLE: 40 Years of Soviet Progpecting Geophysicar (Sorok let sovetskol
razvedochnoy geofiziki)
PERIODICALs Razvedka i okhrana nedr, 1957, No 11, PP 50-62 (USSR)
ABSTRACTt Geophysical prospecting methods were first applied by the
Special Committee for the Study of the Kursk Magnetic Anomalies
(Osobaya komissiya po izucheniyu Kurskikh magnitnykh anomaliy-
OKKMA) during 1919-1927. During subsequent years the methods
of induction, electric coring and magnetism were perfected for
prospecting minerals, oil deposits and water resources. The
method of aeromagnetic surveying aided in discovering deposits
located in areas of poor accessibility. Perfection of the
aeromagnetometer "AM-49" by a group of specialists under the
supervision of G.S. Smirnov enabled to establish the crystal-
line structure of areas covered by thick sediments, the con-
tours of basic geologic formations, tectonic changes besides
locating mineral, oil, and gas deposits. More than half of the
territory of the USSR has been surveyed with this instrument
at the present time. Gravimetric surveying started in 1932,
was conducted by uniform methods and according to a uniform
Card 1/5 government plan. UP to 1939, foreign made gravimeters were

40 Years of Soviet Prospecting Geophysics
132-11-7/7
used in the USSR. During subsequent years, the following
gravimeters were constructed: "N[1-2", "rKFIM-3", "ri-A-511
-CH-311-, 11rKA", ,rKom,, and ITAK-3M11 . Parallel with
gravimetrio surveying on the surface, were conducted studies
of gravity on the bottom of water reservoirs. Used were the
gravimetere ,,arm,,, ,ArA", the automatic altimeters "BA-481,
andl,rB-5211 9 the bottom gravimeters,wriEll and adapted gravi-
meters ,rAH-M". This method aided essentially in surveying
the Kursk Magnetic Anomaly, the Krivoy Rog iron ore rayon,
the chromium deposits of the Ural, the Volga-Ural and Ural-
Emba oil districts, the depressions of the Bashkir Ural region,
aouth-eastern Caucasus, Azerbaydzhan, and the Dnepro-Doneta
basin, several districts of the Turkmen SSR, and other areas.
In connection with the exploration of northern permafrost
aeras, the ondometric device NIA-6" was constructed by A.A.
Petrovskiy and V.V. Alekseyev. Operating on direct current,
the potentiometer nn-v, was manufactured in aeries since
1934- In 19359 seismometers were used for prospecting for oil
deposits on a large scale. Construction of multi-ohannel
aeismic stations was started in 19479 and seismography became
one of the most important methods of geophysical prospecting
Card 2/5 operations. At presentp domestic industry manufactures 26-

40 Years of Soviet Prospecting Geophy3ics 132-11-7/7
channel seismic stations "CC-26-51-A" , 60-channel seismic
stations "CC-60" and small seized instruments "CC-30/60-56"
Soviet industry met the requirements of seismic expeditions by
manufacturing seismographs of the types "CII-1611 and 110-160.
The radiometric method gained great importance in the USSR for
geophysical purposes. The latest types ("AM-*25", " ACrM-3811
were issued in conjunction with the aeromagnetometer IIAM-1111
by which the geologic efficiency of each instrument was in-
creased. Beginning in 1939, a group of specialists under the
supervision of G.A. Gamburtsev applied the correlation method
of refracted waves ("KMPBII)p which method was further develop-
ed to the method of deflected wavesp which remained the basic
method for prospecting for oil deposits, and establishing the
complex structures of the earth. With the aid of this method,
the Buzovninskaya deposit on the Apsheron peninsula was dis-
covered in 1940, and further important results were obtained
on southern Embal which lead to discoveries at Narmundanakq
southern Koshkarq Tentyaksor and other deposits. Parallel
with core sampling by electric means were developed other
methods of examining drill holes, such as resistivometry, in-
clinometry, cavernometry, inclinometry. From the semi-auto-
Card 3/5 matic stations 'IrIKC-200011 and 1111KC-120011 were developed

40 Years of Soviet Prospecting Qeop~qsic& 132-11-7/7
the automatic stations "A3KC-52 11 and "OKC-52" with electronic
electronic potentiometers"IIACK" or with photorecordere
"(PP-411. In 1948, gas sampling by electric means was widely
applied with the aid of the semi automatic station of the type
11m1, , and lately with the automatic gas sampling station
"ArKO-5611 combined with the chromatic gas analyzer tirOT-211
Research is conducted at the present time to improve the
method of core sampling by ma6metic means (11 M-10*1). During
the past years radioactive gamma core sampling has been develop-
ed, together with several new modificationst such as neutronic
core sampling, gamma-gamma core sampling, by the activation
and isotope methods, The Soviet industry has developed up-to-
date devices for radioactive core sampling (" A3KC-7-5511)
Of special importance are methods of complex geologic-geo-
physical research, developed by Soviet geophysicists, applic-
able for separate regions and industrial districts. Examples
of complex prospecting are the Kursk Magnetic Anomaly and the
Turgayekaya deprersion. An eastern geophysical expedition
has successfully applied aeromagnetic, surface-magnetic and
gravimotric methods at prospeoting for diamonds in kimberlite
layers in the Yakutsk ASSR. Switching to a lt50#OOO scale at
Card 4/5 aeromagnetic surveying in connection with limited surface

40 Years of Soviet Prospecting Geophysics 132-11-7/7
magnetic surveying resulted in the discovery of numerous iron
ore deposits. Rational application of electric prospecting
for solving of hydro-geologic problems Is of great importance.
As to the future, Soviet scientists are facing the task to
further develop the physico-mathematical basis of research as
well as further develop the methods of interpreting the re-
sults of geophysical surveying. Soviet geophisicists and de-
signers have constructed new types of geophysical devices,
among which are automatic electronic compensators "3AK-211
electronic needle compensators "30K-111 electronic computing
compensators "KCP-211 and numerous other instruments for geo-
physical prospecting.
ASSOCIATION: Winistrv of Geology and Conservation of Natural Resources ofifis
(Minist,prstvo geologii i okhrany nedr SSSR)
AVAILABLEi Library of Congress
Card 5/5

AUPHOR: Krasul 132-58-4-17/17
TIM: Aeaders' Conference (Chitatellskaya konferentsiya)
?L'.h1Qjj1GAL: siazvedka i Okhrana Nedr, 1958, Nr 4, PP 63-64 (USSH)
ABSPRACT4 A readers, conference, called by the Gosgeoltekhizdat, took
place in I)Iooeow on 28 February 1950, where both achievements
and shortcomings of printing methods in the USSR were discussed.
Al')SOCIATION3 GoDeeoltekhizdat
AVAILABLEi Library of Congresu
Card 1/1 1. Printing-USSR
USCOMI-DC-5476o

KRASULB, Veniamin Semenovich
[Simplest methods of determining minerals upder the
conditions of a geological field trip] Frosteishie me-
tody opredeleniia mineralov v usloviiakh geologicheskogo
pokhoda. Moskva, Nedra, 1965. 83 P. WIPA 18,3)

paru-ci in it -,rt wi ti,
tnyrol-I cylana- Kllmrt7iJa .,Ll T I
~. I'l P A18:2)
1. Fakul'totsk~i,,,a khir-.;rFi,7~,qs.,L%ya Vl.,nA,t -.1-ditsinskogo
1 n.;! tu ta,

S113516010001GO910OV015
A006/AO02
AUTHORS: Krasulin, Yu. L. and Sagalovich, V. V., Engineers
Tl=- Welding With Consumable Electrodes of Thin Stainless Steel Sheets
In a Mixture of Carbon Dioxide and Argon
PERIODICAL: Svarochnoye proizvodstvo, 1960, No. 9, pp. 10-11
TEXT: In gas-electric welding with consumable electrodes the shielding
gas must ensure the lowest possible value of the critical current density,
required for the jetlike or fine-dropped transition of the metal in the are,
providing for a stable are discharge. Differing from single-atom Inert gases,
such as helium or argon, carbon dioxide dissociates in the high-temperature zone
of the are, forming carbon monoxide and oxygen. As a result exothermic reactions
occur in the welding pool producing additional heat which has a positive effect
on the formation of the seam. Satisfactory penetration and a smooth outline of
the seams welded in carbon dioxide approach them to those welded in helium. The
authors developed a method for gas-electric welding with consumable electrode
on a standard machine and a wire of over 1.0 mm, using a mixture of carbon
dioxide and argon (CO 2 - 70 ~ 50%; Ar - 30 1 50%). This mixture reduces the
Card 1/2

S/135/60/000/009/003/015
A0061AO02
Welding With Consumable Electrodes of Thin Stainless Steel Sheets in a Mixture
of Carbon Dioxide and Argon
oritical density of the current, stabilizing the burning of the arc and enguring
the fine-dropped metal transition at a current density of about 60 amps/mm~! in
welding on reversed polarity and of 40 amps/mmF in welding on straight- polarity.
The formation of the bead built-up with a consumable electrode in an Ar-CO
mixture is similar to that formed in carbon dioxide, Grade "lXl%?T" (1 ~QN9T)14
steel of 2.5 mm thickness welded with a "OX18H9" (OKh 18N9) wire of 1.2 mm in
diameter, was subjected to mechanical tests, which showed high mcchanical and
anti-corrosion properties of the steel. The authors used an "AAC-1000-2"
(ADS-1000-2) automatic machine with a nozzle designed by TsNIITMASh. An
3dditional controllable resistance in the form of a 240-oh;-n slide rheostat was
used for the accelerated electrode feed. The gas conduct system is illustrated
in Figure 2. The carbon dioxide gas was dehydrated in a drying device des!gned
by VNIIAVTOGEN, filled with roasted blue vitriol. A generator with rigid
characteristics Is recommended as a feed source. There are 2 figures and
I table.
Card 2/2

84634
S/135/60/000/0 11/008/0 16
A006,/AOOl
Lqlibo-ol ~~g
AUMCIR; Krasulin, Yu.L., Engineer
TITLEF Welding of MetaI6 by No Indirect Are-,\,
FEY-,-.TODICAL,- Svarochnoye pr-:1zvodrEtvo, 1960, Nc. 11, pp. 29-30
TM,,, Trie author suggests a methcd of metal welding with two Indirect
ar,T~~ using the advantages of both a dir-~-;t'and indirect arc. The heat source
for, heating and melting ths base metal and txe consumable electrode con-sicts of
ar:,s, one of which is burning betwesn two unconeumable vingsten ele:~trodes, V~
tte o'her c-ne beNeer. the consumable eleetrcde an,2 sne of the tungsten electrodes.
F,:-wer for former arc. is eupplie'. by a transformer wit!, a t-f C~:~illatDr, for
~b,~ I a*.4.er ty a d-.:! generator. Prg:n, a!FZuring stable arc di5c.-arge, !a used as
a ~--e-lding ga.z. --L-,, between '%hA ele,~tr~dz:s is ex3-lted with the aid
,f --e cs-,Illalcr --r by 5nort-,ircul,ing sn grap~"Ite, the electrode feed Is
awi~hed on, and ~ne se~-ond ar3 is ex:ited. Tne trermal effect of two indir
ar-t- Is grea','~-r than thal. cf one dlre~t, arc. The C-le--trode turn-off rate 4.6
az nigh as in welding with a c--.~nTumable electrode. lrh,~, iretal transfer i5
regula-,ed from irop 1,c a-pray type. The --on5umable ele-:,trode vibrates
Card 112

84634
8/135/60/000/011/008/'016
Wldlrg of Metali by Tlwc Indirect. Arcs AOo6/Aooi
w;,~n freqiiency whi,h improves the weii .-hap,% ',e weld azd -the
.t-lrg tle4ween -rhc weld and tne take me-al. P, a---- reducez -he C-Ir"ren+
--d f~r ar ay_'.y]:~- Tne dezrl--ed ~-a*_ z
7 r s ir a.? -
-,o-:,4r on w~tn -a galvar,!^ '!~-T-
wet ::pp-.- ..-n and
and ni~kal. --all.Ing YrIcicns). Tnc- wire may ts s-,ipplid t,
a-, cr at a -rall- angle w=l'i W,_-rk. f1-51 mod.- is rec,,r.
m~n::=d f-r we~laing, th& s--,cnd cne f-r hardfac'ng. Ti-e-e are 4 fj,izAre~
-a-

L 10303-63 MP(k)/EWP(q)/EWT(m)/BDS--AFFTC/
ACCESSION M AP3001114 S/0125/63/000/007/0001/0007
AUTHOR: Krasulin, Yu. L.; Shorshorov, M. Kh.
TITLE: Wedge test for evaluating t~e effect of cooling rate on the polygonization
of single-phase-struoture welds
SOURCE; Avtomaticheskaya svarka. no. 7, 1963, 1-7
TOPIC TAGS: welding wedge test,.EI868 alloy, polygoni~zation of welds
ABSTRACT: A weld-testing wedge made from OKhl8N9T Itenitic steel was used to
determine the critical rate of cooling at ;hich the polygonization of.EM68 ~'
M25MOB15) heat-resisting nickel anory is suppressed. The alloy was welded on
by an Indepeindent double-electrode are, with a 1.6-mm welding wire. EI868 alloy
is a single-phase solid solution strengthened by (about 16 per cant of) tungsten.-
Metallographic studies revealed that at the cooling rate of over 100 or 176T -per
see. the polygonization boundaries in the welded-on metal disappear. Five micro-
photographs are presented. Additional all of per cent Me (Mo-wire added in
the welding am) resulted in reduoing ~he cozoin'19 ra to 40C per see. The critical
rate of deformation, which determines the hot-orack~iesistance of the welded-on
metal, was found to be 2.8 and 7-3 mm per min. Fo-rEI868 and EI868 plus Me
Card 1/2
.........

L 10303-63
ACCESSION NR: AP3ooU14
respectively. Orig. art. has: figures, 4 forunlas, and 1 table.
ASSOCIATION: Institut metallurgii im. A. A. Baykova (Institue of Metallurgy)
SUBMITTED: l0J&n63 DATE ACQD: 02Aug63 ENCL: 00
SUB CODE: 00 NO REF SOV: 010 OTHM: 000
~wd 2/2

KRASULIN, Yu.L., itzh.; SHOFOHOROV, M.Kh., kand. tekhn. nauk
Regulating heat and diffuvion processes in the metal fusion
zone during welding fuid hard facing. Svar. proizv. no.8:13-
3.6 Ag 163. (MIRA 17:1)
1. Institut metallurgii imeni A.A. Bay1rova.

Yd'~ASIJLIN, Yu. L. (Engincer) MMET)
Reported on control thermal and diffusion processes 1r, th,~, of alloylnw
during we.1ding, or ,etras- "Wedge-shaped weldinF test for appraisal of Influence of speed
of cooling on polygonization of seams with aingle-phase structure".
Report. presented nt the re~nilar conference of the Moscow etty administration N71)
Masliprovi, April l')f,)3.
(Reported in Avtomaticheskays Svarka, No. 8., August 1-1163, PP 93-95, M. M. Popekiiin)
JPRS24,651 - 19 may 64

N_ tq1X*M ato
i7
1, 34066-65, E4 s bb)4/
r7
/WKV 6,11 ..t f-l -4 Pi t- b-10
T ':/rq -L-~ ~.rr a
W-AV&PM-4,76.
ACCESSION NR: N-AP5007604 S/03631651001100110029/0036
AUTHOR: Rykalin, N.-N Shorshorov, M. Kh Krasu
2 _tj lin. Yu. L.__
TITM Physical and chemlical,problems of joining differaot Mat2riAln
S011RCE: AN SSSR. Izvestiyai Neorganicheskiye materialy, v. 1, no. 1 1965, 29-36
TOPIC TAGS: velding.'welding energy, weldingtheory, ceramic weldtng glass weld-
'ing, radiation welding
-iew--of ~~the authors examine the theoreti-.
1 ABSTRACT Ina general,rev
of dfff.e4 nt solf.dR by welding t )ujzh a
V E_Q~
VA Ue_. Oca as
'!~i_ -6f=P I I I it 0
elastic- def -the ng- two'-d
ormation,--and'.t tinie 6 -radiationd rocess-_of--j6ini tr-7. -
'.ferent materials is divid nib 2 - princ,-ipa
ed. A stIL, es. - In case of joining-different
materials, one of which ii. In.: the mQlten_stjtteJthe relaxation period of the inter-;-
phase energy,, during which the diffusion is retarded, mus~_be considevo Farticu-1
lar attention Is paid to the welding of metals with glasPor ceramicsLre.g., Alvith~
silica) and the -welding of -solid Ti with liquid A) - The alithors conclude that
these proceises require'.a. regulatable energy source to control the type.of bond
Cord 1/2
a.

RYKALIN, N.N.; KRASULIN, Yu.L.
Estination of the eriergy parameters of welding metals b7 laser light.
beams. Dokl. AN SSSR 163 no.107-90 JI 165. (MIRA 180)
1. Institut metallurgil in. A.A.Baykova, 2. Chlon-korrespondent AN
SSSR (for Ryka]Lin).

)/E-WP(v EWP(t F,'/P(~ '.'/A (h)/Ef/A
L 4022-66 SVT(d)1EVrr(l)A1VT(m)AWP(W I VE (C) ,
UR / O'P 9(
ACCESSION NR: AP5022258 IJPW 1 6~/65/001) J/007 1 90/1097
JD/H%/t?.I/AT 537.311.334546.3
AUTHOR: Krasulin, Yu. L.-,- Ivanov, V. D. .; Kruglovg L. H..
55,TJ -594 55?"l
TITIZ:- Role of dislocations in the f&m&tLon of jointa during pressure welding
with heating of the metal and semiconductor (f (0 61' /T
SOURCE: AN SSSR, Izvestiya. Reorganicheakiye materialy, v. 1. no. 7,19651
1090-1097
TOPIC TAGS: pressure welding, crystal ftelocation, semiconductor device
ABSTRACT: Metal conductors were welded to silicAingle crystals I onto which a
e
pyrex plunger was press~t~ simulate pressure welding. It is found that during
pressure welding involv the heating of the metal conductors with the semi-
conductort dislocations re formed on the surface of the semiconductor in the
r
area of its contact wi h the metal. Chemical bonds between the metal and tho
semiconductor are formed at points where the dislocations emerge to the surface
of the semiconductor. The number of dislocations formed in the surface layer
of the semiconductor depends on the welding parameters: temperature) pressure#
and duration, At low temperatures and short durations lasting less than the
incubation periodl the weld joint between metal conductors and semiconductors is
Card 1/2.

---L 4022-66
ACCESSION NR: APS022258
ell
f ormed owing to adhesive. forces (van der. Waals and mechanical bonding), Orig.
art. has: 6 figures's.
A
SSOCIMON: none

SUBMTTED*- 22HAr65 ENCM 00 SUB CODE:
Ss
NO REP SOVr 013

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2/2
.. .........

-------

L 3836-66 ma (k)/FBD/EWT(l)/EPA(s)-2/WT (m)/E2C (k) -2/00(v)/T/04P (t)/EWP(k)/
of1pt /n/HM
~b)1&A(M)-21A&(h)1FA4A(C) 3CTB/IJrF(c) Irn
ACCESSION HRI AP5018079
AUTRORs ftkalinj K- ff:qCorreqmnding hember AN GSSR); Kraculln! qq
I
TITLES Estimate of the energy parameters of metal weldinA by a 1_aaer_g6~ be"
SOME: AN.SSSR* Dokle4p v, 163.. no* lp 1965p 8T-go
TOPIC TACWs metal weldIngo copper Zoer beam, laser application
ABSTRACT: The authors first point t that all experimental evidence indicates
t
that successful welding by meane of a laser beam calls for exact knowledge of the
distribution of the beam energy over the surface of the welded material. To this
end, they estimate the total maximum beam power an well as the power In each splke.t
The problem Is solved for the case of interaction between the light beam and the
surface of a semi-infinite therma.11y conducting body,, assuming a Gaussian distrlbu-!
tion of the heat developed on the metal surface along the radius of the focused
spot. Approximate formulas are derived for the heat and temperature distribution
r-
produced by a normally-incident circular laser-beam spot and for the maximum pe
unit heat flux* The latter makes It possible to estimate the dimensions of the
spot of molten metal on the surface of the welded body and the depth of the weld.
The approximate lIght-beam, parameters required for welding thick copper @beets WA
the dimensions of the welding zone are calculated by way of an example. Methods
Card 112

L 3836-66
ACCESSION KHt AP50IW79
of eatimUns the laser beam power required to produce a weld of given dimnsions
are also Indicated, It In stated in the conclusion that more accurate calculations
call for the knowledge of the spatial and time distribution of the racUation an the
end of the laser rods and an the distribution of the encW In the focused spot.
Orig. wt. hast 2 -figwesp Tforwmlasp and 2 tables@
ASSOCIATIONt Institut metallutg1l Id., A6 A, BMAM Institutp) YV
BMWTTED t 25Feb65 ENCLe 00 M CODEt ZE
IR PXF BOWS 001 0Tmt 005
card

2M~~ - FAA th)/E-WP(k)IERT(l),(En'km)/'r/P,4P'tv)/EWP(t) JD/hN
ACC NRt AP6010145 SOURCE CODE: UR/0125/66/000/003/0664r6O 6
AUTHOR: Krasul!!. Yu. L (14oscow); Nikitin, V. G. (14oscow); Kus'min, V. I. (Hoscow)
ORG: none
TITLE: Welding of integrated circuits with indirect pulse heating
SOURCE: Avtomaticheskaya svarka, no. 3, 1966, 64-66
TOPIC TAGS: integrated circuit, circuit element, circuit microelement, microelement
welding, circuit welding . .
ABSTRACT: A method for pressure welding the microelements of integrated circuits is
suggested. In this method the microelements to be welded are heated to the required
temperature indirectly by the punch (see Fig. 1) through which a short a-c or d-c
pulse is passed. This power pulse brings the temperature in the contact point betwee
the punch and element to be welded to 400-560C, at which only a small pressure Is
required to achieve a perfect bond. The method was successfully used for bonding
aluminum, copper, and gold sigrowires 0.03-41 mm in diameter to aluminum, copper, or
Card 1/2 UDC: 621.791.89

ACIC. W AP6010145
Fig. 1. Layout of the welding unit.
1 - Table; 2 - welding head with interchangeable
punch; 3 - pressure producing mechanism;
4 microwire feeding mechanism
gold films on sital substrates or gold films on silicon or kovar substrates. and to
printed circuits on sital- substrates. The weld strength was roughly equal to the
strength of the microwire. Orig. art. has: 4 figures and 1 table. JDVJ
SUB; CODE: 13 SUBH DATE: 14Aug65/ ORIG REF: 004/ OTH REF: 002/ ATD PRESS:

-L 37002-66, EW'~- (m)/T/EWP(v),.1`,;;P r 1.)Ar,14P(k),/:-,T r
ACC NRs AP6021487 SOURCE CODEt UR/0413/66/ooo/oil/0.129/0129
INVENTOR: Krasulin, Yu, L.; Kut'aing V. 1.1 Nikitin, V. 0.
ORG: none
TITLEs Method of pressure welding microscopic parts with Indirect
heat input. Clame 490 No. 162490 115h,
SOURCEi lz*4b*%t*nil**, promyshlennyye obraztey, tovarnyye zn&ki,
no. 11, 19669 129 t
TOPIC TAGSa voldLugg micropart velding, pressure velding
f4 ?, 11&1(1 -013 Ohl'
ABSTRACT: This Author Certificate introduces a method of pressure
velding microparts vith indirect heat input supplied by an electrically
heated punch. To preserve the initial properties of one of the velded
materials, to T&%1L1:1t%te the velding of lov-ductility materials, and
to increase the efficiency of the process, the punch is heated by a
current pulse, (ND)
SUB CODE: 13/ SUBH DATE: 3oj&n64/ ATD PRESSti-0316
UDCt 621.791.66

Pr
C
ACC NRi
- CA) SOURCE CODE: UR/0125/66/000/009/0011/0015
1U36032551
J/
AUTHOR: Krasulin, Yu. L.; Kulagin,_I. D.
ORG: Institute of Metallurgy im. Baykov (Institut Metallurgii)
_plasma-arc
TITLE: Controlling the temperature of the melting pool in metal
i deposition
SOURCE: Avtomaticheskaya svarka, no. 9, 1966, 11-15
TOPIC TAGS: pt=nw are welding, plasma arc )metal deposition
ABSTRACT: The temperature of the melting pool in plasma arc welding can be controlled
by employing a current carrying filler wire (see Fig. 1)-.--Ine 'source of heat in this
system is the indirect double arc. One arc is between tungsten electrode 1 and
nozzle 2, and the other is between the electrode and current-carrying filler wire 6.
The are between the tungsten electrode and the filler wire produces a plasma jet
with a drop transfer of molten filler wire metal. The intensity of this jet can be

L 02965-67
ACC NRt AP6032551
Fig. 1. Plasma-arc metal deposition
with current-carrying filler wire
1 - Tungsten electrode; 2 water-
cooled nozzle; 3 - water; - RB-3oO
ballast rheostat; 5 - PS-50011generator;
6 - filler -vire-OT - plasma stream;
8 - plasma flare with molten filler
wire; 9 - plasma-forming gas.
filler wire. Thus, the temperature of molten
i be regulated in a very wide range. Orig.
ORIG REF: 009/ OTH REF: 001/

iACC NR, AP7001931 SOURCE CODE: IIR/0125/66/000/012/oo6o/oo6i--I
AUTHOR: Krasulin, Yu L Kozheynikov, A# P Kuzlmin V.
*A
ORG: none
iTITLE: Ultrasonic welding of microcircuits with indirect heating of
elements
SOURCE: Avtomaticheskaya avarka, no. 12, 1966, 60-61
iTOPIC TAGS: ml-"eeiiLeoit we4~d~g, ultrasonic welding',
-ABSTRACT: A method has been developed for.-welding elements of micro-
circuits made of dissimilar materials, for instance gold or aluminum
welded to silicon or thin films deposited on a semiconductor or ceramic
iubstrate. The method combines ultrasonic welding with simultaneous
indirect preheating of the welded parts done by passing a current pulse
through a section of the welding tool (See Fig. 1) Experiments showed
that the timing of the application of ultrasound depends on the wire
material. The beat results in welding aluminum wire 0.1 mm in diameter
to gallium arsenide and silicon, or gold, tantalum or aluminum films
were achievedvith ultrasound applied 0.3-0.4 see prior to heat applica-
tion. In the case of copper wire and gold film, ultrasound must be
1/2

Fig. 1
Layout of ultrasonic welder with indirect
heating of welded elements.
1. Transducer; 2. waveguide; 3. welding
NII-j tool; 4. heater;' 5. ultrasonic generator
applied 0.2 sac after the heat application, Orig. art.1has: 3 figures
and 1 table.
SUB CODE: 13
,P9,-I~UBM DATE: 04Mar66/ ORIG RZF: oo4
Rt AP7001931

ACC NR-AP7005676 (41) SOURCE CODE: -UR/0-~1^5/67/OOO/OO2-/Ol-48/Ol-4EI
IINVENTOR: Kraculin., Yu, L.; Kozhevnikov, A. P.; Kuztmin, V. I.
;ORG: none
TITLE: A method of ultrasonic welding with heating of the parts being
welded. ClasG 49, 190763
i
SOURCE: Izobreteniya, promynhlennyye obraztsy, tovarnyye znaki, no. 2,
1967, 148
V%FaW*-v*MM'
TOPIC TAGS: ultrasonic welding, Wd;9xx?M w el d i ng
ABSTRACT: This Author Certificate introduces a method of ultrasonic welding with
heating of the parts being welded. To improVe the quality of the joints in
welding miniature parts, the parts are heated indirectly Fhrough heat
transfer from the electrically heated welding tool.
SUB CODE:
Card 1
9613/ SUBM DATE: WQ 4Y1 ATD PRESS: 5117
Do: 621-791.16

BYSTROV, 1. V.; SHALIMOV, A. P.1 KWULINA,, A. K.
.........
Use of alag crusts of AN-20 and AN-348A fluxes. Avtome ever,
16 no.3:93 Mr 163. (MIRA 16:4)
(Electric welding) (Slag)

USSR/Cultivated Plants - SuIbt.--,)ica1 and Tropical. M-0
Abs Jour Rtif Lhur - Eiol., No 3, 1958, 11093
luthor Zhilina, T.S., Krasulina, D.Y.
Dint ------------
Title The Sweet DLq in Kuban'
Orig Pub Sad i ogorod, 1957, No 8, 71-72
Abstract A 8Weet bay bed has been planted on the Kuban' operallio-
nal, base of the Sochi Experimental Station of Subtropi-
cal Grops Yaykop).
Card 1/1

BYSTROV, A.V.; KRASULINA, A.K.
Automatic hard facing of auction-type coal dredge Avtom.
ovar. 18 no.10:60-62 0 165. (MTW~ 18:12)
1. Kuzzintnkiy meta I.turgicheski y kombinat,

t~_, -Z--
Study at dto alrectuit *1 C21-
-V
H with 6 moks cif'o at
nIA. wt. 350-400 was mixgd with x% hmmethyleaemm. 1
-Inc (1) U MOR, tile said. was -Pd. mad the residue cm.
PrOfted tQ Is tWet. The InCrUse j, the de(*CMWjt* ot
tht!)e tableft with (cmp.
was napid at x < 2%. I.e_ reams
coa,",
eo. t 1e I bomme ASCOVEAS(k at hj&fW &.Mpg. (e.g,
while the dcv~ty cg veds with
deVended an teinp~ betwteu LOV sad 20DI. P'll"t"'Y
Ue,
pwtkk= Of the, "in'.
4=sat'm of PhOU-CH-0 CtOns with 1. liaeO ob,fn
e4,
With Unfrevent Cross fink2go f0m; th am
OW141 Of IL"OFAIM, C.
"till,
WAfprm2n r -!j
FdYmc? S~i, it, 4
-19les. pmod. by Potrmnt~"
-Creool. gnu psa"d, gap" WOf hL' ftidkattd.
with phenol,
ne a*-lab wl- trandmated into
UM Melling 0 by a relatively mild b ilre hrhm-
9-606 OWS, 20 atm.) b b wt of Nl*-Cu
~7 U-1cahr caulot. it col he expected Ut`& treat.,
Inent do" dot atter the gtmctuml frme of the bloll. pmm:
tdtf"te OAIYIU and VbyL malft. of the flydromboni
m4a" were made " to the dructure of the novollbj
Thty a',- cescat.
lideof U-moptasts; no extra rings am
J. =11

-Aw

tottmornechmikAt stntly of the procvsw of font;Wd~Arid
of the str*cW* of 40d ta$Wuwo
del ev rvilr-t- It,"N, - Krasulml. w2
I h4r
I MAC of 2 mW,1 P-cre-501 taid I rwde .1 WWI hukd ;I t~n r
of AL-114Y stac of W: after mciiing VIP tciio witk- 2Z (.c
,N', Twise to 00' mid I-XV., mp. A&h. of
(1) to tbc.pWaic maee with M-
;
l
d
ICHANN. Uwml r to 140* while PAda. ot 2r;r,, I t~uv
In the aptletyAme --( a Ma"Wtic -,tate txtwern 170* area
220'; &md Ada, of mrc I had the vm.~ t4tet rt pluitkiters
orAmacphou I I Ir .1 MCI ~ . Durinit the reartion 0 rtsin
with (C11.1"N'. 1, xt-,& tgally Incarvic-d twtil R ti%id~v;f rri~
Mct~,tl itin tholohe v4c%,~Jly tA tit" tich
tk-v. stopped tuA tl!e cr-mvn mr O-e rmlf I-
fmicn.-

OP71"

V~ -4
zi
Kbie-tics af
_L 4
iw~ 1*1 ?K,,vcf3r(-Au 0
no
Irit) h
I&I like olvemb cql is
ni'mramina.
IM V ft.
am AkajTMU
t3.
Retults -of thammumhantcal ~Iudlrm in th pv~f-ncv u! wi~F!el
Pt additjvrs whit 14 c-an act i~j donor; of Jlxo

86291
3/190/60/002/008/002/017
~1 0t B004/BO54
AUTHORS: Igonin, L. A., Yeliseyev, Yu. A., Dyurgerov, 0. A.,
,~,rasulina, N. A.
TITLE: Formation of Stable Free Radicals in the Process of Harden-
ing and Thermal Destruction of Phenol Formaldehyde Resins
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 8,
pp. 1167-1170
TEXT: The ob3ect of the present paper is the proof that in the hardening
process of phenol formaldehyde resins not only dense-network polymers are
formed but also thermal destruction processes are taking place. The shear
stress of some resins as a function of time at rising temperature was de-
termined by an I. F. Kanavets plastometer (Ref. 2). Samples used were:
Novolac resin of the type K-18 (K-18) with 4~6 by weight of hexamethylene
tetramine and 30% of dibutyl phthalate; poly-oxybenzylamine from p-cresol,
and the aame compound made of tricres8l. Fig. 2 shows the shear stress as
a function of temperature. At 150-170 C, poly-oxybenzylamine behaved like
amorphous linear polymers with poorly marked network. At higher temperatuis
Card 1/3

86291
Formation of Stable Free Radicals in the S/190/60/002/008/002/017
Process of Hardening and Thermal Destruction B004/BO54
of Phenol Formaldehyde Resins
the network was destroyed; above 2000C, however, a dense network was form-
ed which is revealed by an increase in shear stress. This is explained
by recombination of macroradicals which had formed during thermal destruc-
tion. This assumption was checked by electron paramagnetic resonance (epr)
spectra. The epr spectra were taken by a spectrometer designed by the
Institut khimicheskoy fiziki AN SSSR (Institute of Chemical Physics of the
AS USSR).A concentration of 1o14 paramagnetic particles/cm3 was found for
Novolac, and of 5-105 for poly-oxybenzylamines. The epr spectra remained
unchanged after storing the samples for months. Origin and structure of
these very stable free radicals require further investigation. The authors
thank V. V. Voyevodskiy for taking the epr spectra in his laboratory, and
V. A. Kargin for a discussion. There are 3 figures and 4 references:
3 Soviet and 1 British.
ASSOCIATION: Nauchno-issledovatel'skiy institut plasticheskikh mass
(Scientific Research Institute of Plastics)
SUBMITTED: March 15, 1960
Card 2/3

86 291
S/190J60/0~2`1'00,5/00P/017
IB004/BO54
Le'e~d'to Fig. 2: Ch.~.nc-,- of the lizil
.shear stress during the hardening
PrOCCS3 of phenol formaldehyde resins.
1: I'ovolnc r'coin X-10 v;ith W, of
nlasticizer and 4'~~' of hexamethylene
letr
amine; 2: poly-oxybenzylamine
frorn --Crccoi; 3: poly-oxybenzyl-
f Ic

-5-- 2.P 2,z 68847
AUTHORS% Igonin, L. A.# Gintsbarg, E. G.? ,q1/076/60/034/02/006/044
Krasulina, ff. A., Basss So I*# BO1O/BO15

TITLEt Investigation of Oxybonsylamines Obtained From Phenol and Its
Mononuclear Derivatives
PERIODICALi Zhurnal fizicheskoy khimii, 1960, Vol 34, Nr 2, PP 287-294 (USSR)
ABSTRACT: On the basis of publication data it may be assumed that o;ybenzyl-
amines form as intermediates in the hardening of jovolackfphenol
formaldehyde resins with hexamethylenetatramins. In oxybenzyl-
aminest the phenol nuclei are connected by dimethylamine- or tri-
methylamine bridges. At high temperatures, these bridges are trans-
formed into methylene- or azomethine bridges. In the present case,
a series of oxybenzylamines, obtained from phenol and its mono-
nuclear derivatives, were investigated thermomechanically as wall
as by spectral analysis. The absorption spectra were taken by the
IKS-11 speetrograph, and are given for 2,2'_dioxY-3,5,3',5'-tetra-
methyldibensylamine and the corresponding tribenzylamine (Fig I).
The absorption bands observed at 11-84/4 in dibenzylamine and at
11.92,A in tribenzylamine are traced back to the dimethylenamine-
C'ard 1/3 jLnd trimethylenamine bridges between the phenol nuclei. This

68847
Investigation of Oxybenzylamines Obtained From S/076/60/034/02/006/044
Phenol and Its Mononuclear Derivatives BO1O/BO15
assumption is confirmed by the absorption spectra (Fig 2) of the
multinuclear oxybentylamines. The latter were prepared by a method
described earlier (Table 1, preparation conditions). All spectra of
the oxybenzylamines obtained from phenol and its para-substituted
derivatives show the 11-84/j., band whereas with oxybenzylamine ob-
tained from o-chlorophenol this band lies at 11.92#_ Thus, it can
be seen that it is the reaction between hexamethylenetetramine and
the mononuclear phenols in a diphenyl solution that leads to the
formation of the polymeric oxybenzylaminee (Table 2, suggested
structural formulas of polymerm). The polyoxybentylamines obtained
from phenol and its par&-substituted derivatives &re amorphous
linear polymers reticulated by individual arose bindings. The poly-
mers have very strong chains whose T value lies above their thermal
stability. The o-substituted derivatfvea form strongly ramified and
reticulated polymers. The polyoxybenzylamines obtained from phenol
reticulate under the offset of heat, and pass over into a non-
meltable and insoluble state whereas polybenzylamines obtained from
o- and p-substituttd derivatives of phenol are thermally instable,
and decompose at a temperature above 160*C forming low-molecular
Card 2/3 products. There are 6 figures, 2 tables, and 6 references, 1 of

6880
Investigation of Oxyboncylamines Obtained From S/076/60/034/02/006/044
Phenol and Its Mononuclear Derivatives B010/B015
which is Soviet.
ASSOCIATION: lauchno-inaledovatellskiy inatitut plastichookikh mass 41"
(Scientific Research Institute of Plastics)
SUBMITTEDi April 3, 1958
~Iard 3/3

KRASULDIA, T.P. (Leningrad)
Note on some stochastic approximation processes. Teor.veroiat.i
ee prim. 7 no.lsU3-118 162. (MM 15:3)
(Chance)(Approximate computation)

Transactiona,of-the Sixth,Conference.(Pont.)
71.- Oladkovo B. V. Some-Problems In the Tabulation of the Bete-
Distributioim 385':
-.-72. D'yachefiko,,.z. No of a.aamma-Typ~3 Distribution 389
73.- Kag4ns A. M. _Some Properties'of the Estimates of Maxim=
Likelihood. -
397
74, Chentsov* H. H. On the Asymptotlo Effectiveness of an
Estimate of - Maxl= Likelihood (co=ent on A. M. Kagan' a'..
Ples-of,the Ratimtes of Maxim=
report ."Some Propex
Likelihood") 399
oahastio Approximation 403
75* - ~On St
76. Manlya.,-G.-M. Quadratic Estimation of the DIsorepanoy of
the Densitlea'of -it Normal Two-Dimansional PlatrIbution
From Swpllng Data 40T.
6-1ah Co:l,:. on ProbabiUty Th_-ory'ctA_ %Xathimatical Statis--ics a.-A
in rali
",Oziura on D.-Iztrib-atio- Sp=os b3ld in Vilinyus
sop 060, vjj#rqw Gm.zpolil~izzdat. Lit, SSRX 1962. 493 p. 2506 c rinted

1
C
t Armt
-
U
.
*
h
ft
TIP71 ethors. S. P. V,
r ff9prnek
'XiiF
N
TIf
I
.
la, and 1" 13. TrulchmannVa (Inst.
~-XIW-M, JUM-9.-Study of

- I &~_,
of chlovo
rev-- with Lto-PrOCH:-
ernalslon
p
M
CITS with reductior-oxRL-don

m
syst as the inItiator showed t1git cDpo!ywcrizatjU.j C-Murs
readI
a preftminstrg iti titz noduct,
1(,tnd that chbWopren
1
2'
ha
e
d
diff
-
c
an
ng
Pn. at
erent temN.
400). In mass-cupolymcrizatfon studied. with fUjO, (fie
-the radical foute; the ether
rOet dmi not proceed by
component predomfiiales in the prodtict, find the compn. of
the prodtict Is incomtnnt4 [hus contati with air increnm
the content 6f thit, ether ynxer, while uuder Nt the
chloroptene,cmponent - P" The use of bL-azeso-
butyrouitrite gave the atue result. - The product of &tiortk
copolym~rizatkiu pri~domlnatcs in all oa&ft. Tt,-. cpopoty-
rners were fmctkid_-tvd:aud tool. v ets. up to COA)D--VOQW
'It. readily obtalaM~ The canits. of the milical copoly-
~meritatian aret jr, 0.164, aa&t2 RA5, wbich vialuts lud"te,
the ewsidemble Muenm of tht radimt of the c1lacr, (q
C43ntrut to its tAmVtor vrith other mvmNniv, Tbt
compa- 'at tmitsion eojiolyners agym with Up4mted valuLs
fitim radical

~-:j
Ins-
2" Ja::_2

tAbicit bi vichl.'t up to 11.5%, in C--ii
M~ mtctban
jIafaMJfu iLr. wat. uf ROCH.-CF% -,~ddcfi tc, th.~- d;
-rt~ th 2 Z,(3, an, a
~rS% C(:4
f6fz-;.f3 Ln 2.6 L-rs.,
lbt 5),-if v... .. Q` P-".VI- In INY)
wlqIvi~zd m tile uJalpt.
The 't'jilopf .I U;0A;Ljl!! uraitl
di=p la thC b-Zit4i 4y~t~M VLt aM hi(ff-~ t.
p;tsvsiv~
9.1

. :-.. ;.: " ..~ .
I . . . .1 z .. : , : I ~ ~ ~
- r'- -~ - r.~- , -, _- ~ -

I'

USHAKOV, S.N.; MITSENGMLER, S.P.; KRASULINA, V.N.
Copolymerization of diethylene hydrocarbons with vinylalkyl ethers.
Report No.2~ Copolymerization of divinyl with vinvlallql ethers
in emulsion at low temperatures. Izv.AN BSSR Otd.khim.nauk no.4:490-43
Ap '57. (MIRA 10:11)
1. Institut vysokomolekulyarnvkh soyedineniy AN SSSR.
(Polymerization) (Ethers)

KOROTKOV, A.A.; MITSMIGENDLER, S.Po; KRASULIMA, Vollo; VOLKOVA, L.A.
Syntheoie of polymethyl methaorylato of regular etructure. V7soV-omo
soad. I no.9:1319-1326 S '59. (MMA 13-3)
1.Institut v7sokomolakulyarnvkh soyedineniy AN SSSR.
(Methaerylic acid)

of ri-, 11,
L 6, V
c
7 .
03 i
U 1 1 C
]

-6g Id

13 14
. 933 to a

n
.8 o

I

.1 el
:lug
Vi j
Ag
ItH
8,- d
ft ,u

MERKULOV, V.A., kand.tekhn.nauk; K~~UYISEV,_Ye.M.,, inzh.;
ARAKELIYANTS, A.K. Jq inzh.
Effect of the ventilation systeia on the temperature conditions
in the working face of blind workings. Trudy Sem.po gor.
teplotekh. no-4:106-112 162. (MIRA 15:8)
1. Shakhtinskly nauchno-issledovatellskiy i proyektno-konstruktorskiy
ugolinyy institut.
(Mine ventilation)

KRASUNTSEV Ye., inzh. (g.Shakhty)
Transistorized electric thermometers. Radio no.4:47-48 Ap 165.
(MIRA 18:5)

~EFKULCV, V.A., kand.tekhn.nauk; ARAKELIYANTS, A.K., inzh.; RJUSUNTSEV,
Ye.K., inzh.
Improving the climatic conditions in stopes of Artem Mine No.2.
Trudy Sem.po gor.teplotek~. no-4:136-140 162. Off-RA 15:8)
1. Shakhtinskiy nauchno-issledovatellskiy i proyektno-konstraktorskiy
ugollnyy institut.
(Donets Basin-Mine ventilation)

KRASUSKA , Wanda
Causes of deaths in Warsaw from 1882 to 1962. Zdrow. publiczne
no.4/5:139-146 Ap-yq 165.
1. Z Zakladu Higieny Ogolnej AM w Wars2awie (Kisrownik: prof.
dr. M. Kacprzak).

AUTHORS: Ve I., SOV/62-58-7-24/126
Knunyants.
1. L., Mysov
,
,
Krasuskaya, M. P.
TITLE: The Catalytic Hydra n of the (p.-Olefines (Kataliticheskoye
gidrirovaniye y-olefinov)
PERIODICAL: Izyestiya Akadqmii nauk SSSR, Otdeleniye khimicheskikh nauk,
1958, Nr 7, pp 906 - 907 (USSR)
ABSTRACT: The investigation of the catalytic hydration of the y-olefines
besides its practical importance is also interesting because
it is directly connected with important problems concerning the
theory of heterogeneGus catalysis. The rate of hydration depends
on the state of the n-bond of the olefines. It increases with
the decrease of the electron density of the bond, if the removal
of the electrons from the catalyst latti,3e by the olefine
molecule Is the primary phencmenon in this process. The authors
of the present paper showed that T-ethylene, ip-propylene, T-
isobutylene, and other T-olefines may be easily hydrated with
molecular hydrogen on a palladium and nickel cata'Ayst. The
enclosed table gives the furmulae of the initial olefine, the
Card 1/2 name of the catalyst, the hydration temperatures, the hydration

The Catalytic Hydration of the q.-Oleftnes
SOV/62-58-7-24/26
products etc. Based on the observations made it may be assumed
with great probability that the property of easy hydration of
the olefine series increases from m-ethylene to q-isobutylene.
There are I table and Mfe:7=-Zz8-
ASSOCIATION: Institut eln-n-)~,rganicheskikh soyedineniy Akademii nauk 3SSR
F.- U.-*.' AS USSR)
-It
SUBMITTED: May 12, 1958
Card 2/2

k) 0
AUTHORS-;
82692
$106216010001008100610!2
13004/13054
Knunyants, 1. L., Krasuskaya, M. P., and Mysov, Ye. 1.
TITLE: Reactions of Fluoro Olefinso 13- Catalytic Hydrogenation
of Perfluoro Olefins I
PER 10 b TC A L: Izvestiya Akademii nauk SSS:-,., Otdolenlye khtmicheskikh nauk,
1960, No. 8, pp 1412-1418
TEXT: In previous papers (Refs. 3, 4) the authors had been dealing with
the hydrogenation of fluoro olefize, which easily proceeds on a palladium-,
or nickel catalyst. In the present paper they report on the hydrogenation
of tetrafluorot. and trifluoro ethylene as well as on the fact, that the
products of hydrogrenation of some hydrocarbon fluorides easily split 04,
hy*rogen fluoride under the action of alkali; here, fluoro olefins are
formed which cannotq or can only with great difficulty, be produced by
means of the usual methods of hazlogenation, In Wits connection, ,he author.-
give the followin,,, renotJon chains: Perfluoro i:30hutylene is hydr,gqn~ito6
to lsl,3,3s3--pentafluoro-2-trifluoromethyI propane (I), Which in 'tqflecus
alkali Lolution easily yields HF~ and forms 1;3,,3,3-tetrafluora-2-trifiuarri-
methylpropene-I (Ii) the structure of which was established by oxidation
Card 1/3

82692
Reactions of Fluoro Olefins. 13- CatalYtic s/o62/6o/ooo/oo8/006/012
Hydrogenation of Perfluoro Olefins B004/BO54
to hexafluoro acetone. Hydrogenation of (11) yielded 1,3,3,3-tetrafluoro-
2-trifluoromethyl propane (III). Hexatluoro isobutylene (IV) --esulted
therefrom by giving off UF Hydrogenation of (IV) produced ;,5;3-trifluoro-,
2--trifluoromethyl propane iV), and from the latter 1,1.1,3,_.Tontafluoro--
2---~ethglpropeae-i '(vi) was obtained by,passing it thr".g 90~. molten KOH
-.
'70 C. The auth6rs performed a similar successive series ofreactions
a
with Derfluoro propylene:
CF.,-CF-CF H 2 CPH-CF H -=9 CF -CF;CFH H2 CF -CPH-CFH - HF CF -CF
1 2 Fd-* CF3,_(VII) 2 3 (VI I) F"', I (X) 2-VOW 3(XII)
-CH "ompound VIII is isomeric with the known 1,1,3,3,3-pentafluoropropens-
2'
1 (IX) but shows a different spectrum of nucleax magnetic resonance. Be-
sideaq the hydrogenation and HF-release of IX ,,iolds products with other
boiling points:
CF CH.CF H2 CF -CH -CF H _HP CF -CH-CFH . 2,3,3,3-tetrafluoro propane
3- 2 Wd 3 2 2 _r0H' 3
(IX) 0 (XI) (XI:T)
boiling at -1 C was obtained as a by-produot of hydrogenation of VITI. The
Card 2/3

82692
Reactions of Fluoro Olefins. 13, Catalytic S/062/60/000/006/006/012
Hydrogenation of Perfluoro Olefins B004/BO54
hydrogenation of perfluoro butadiene yielded 1,192,3,4,4-hexafluoro butane
*hich, with one mole of UP in 2,3-position splitting off, was transformed
to CF 2- CF-CH-CP2H. A table shows the boiling points of the oompcunds
obtained. In the experimental part of the paper, the authors indicate 1he
production of the Pd- and Ni catalystq and the reactions performed, as well
as the physical data and analyses of the compounds obtained. There are
1 table and 16 references: 3 Soviet, 5 US, 6 British, 1 Canadian, and
I ~German.
ASSOCIATION: Inatitut elementoorganicheskikh ioyedineniy Akademli nauk
SSSR (Institute of Elemental-organic Compounds of the
Academy of Sclences~-USSRT
SUBMITTED: March 3, 1959
Card 3/3

43309
S/06 62/000/012/004/007
B1 17YB1 01
A ORS; Knunyanto, I. L., Kracuskayal M. P., Mysav, Ye. I., and
'UTH
i.-.ukhtarov, I. A.
TITLEt Reactions of flucro olefins. Communication 15. CatalYtic
hydrogunation of Vurfluoro cyclAutene
PERI-JIMCAL: Akadeiniya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, Iu. 12, 1962, 2141-2145
TEM A Pd catal,7st ~Tras ujed for Ue hydrogenatiin of purfluoro cyclu-
~.utene at room temperaiture. A mixture containinG two isomers of 1,2-di-
hydroperfluoro cyclobutane was found to form: one (approximately 9C~X)
with a boiling point or 630C (d2G 1.5760;.n20*1.2985) and the other (less
4 1 D 15
than with a b,,ilint; Foint of 270C (d 4 1.5580; nD 1.2970). Radio-
apectroscopic studies were made to determine the confiGuration of the
isomers separated bj di.;tiiIation. jlr,, analysis o'f tl-.e rotational band,; in
microwave ab~;orption spectra showed the isomer with the higher Wiling point
to have a cis-confi6-uratiun and that with the lower boilint; point to have a
trana-confieuration. Dehydrofluorination converted both isomers into
Card 112

5/062/62/000/012/004/'007
Reactions of fluoro ulLfins ... B117/B161
1-hydropQz,fluuro cyclobutene, b.p. 260C. Oxidation of tle latter yielded
tetrafluoro succinic ucid ir,.p ~0' 15-1200C k) 1,1,2-trihydroperfluoro cyclo-
butane (6'4'~, h.;- 50-520(;j d 1.441; n 1.3025) was obtained by
,li 4 D
hydroL:,!natin6 1-1,y(froperfluoro cyclcbutone on a Pd catalyst. It was then
deh,ydrofluorinated into 1,2-dihydroperfluoro cyclobutene, b.P. 53-i)4'C,
and dibromide, b.p. 117-11,600, and dehydrobromated into 1-.hromo-2-hydro-
tetrafluoro cyclobutene, b.p. 72-74 0C. 1,1,2,2-tetrahydrupvrfluoro cyclo-
butane, b-P . 500c,n2J 1.~038, was obtained by hydro-enating 1,2-dihy~dro'-
D
perfluoro c~clubutune on Fd/Al 2 U3at 60-700C-
ASSOCIA'A101:s Institut elemuntoorZar,ichesl ikh soyedireriy Akademii ,-.auk SSSR
(In3titute of Elemental Organic Coopounds of the Academy of
Sciences U.'.SR)
SUBMITTEDi April 12, 1962
Card 2112

S10621631000100110211025
B101/B186
AUTHOR3t Knunyants, I. L., and
TITLE: Derivatives of perfluoro dicarboxylic acids
PERIODICALt Akademiya nauk SSSR. izvestiya. Otdeleniye khimicheskikh
nauk, no. 1, 1963, 190 - 192
TEXT: The synthesis of 1~ perfluoro adipic ac id M, perfluoro sebacic acid(3%
and perfluoro dodecamethylenic acid (III) by oxidation of the corresponding
4,1.j-perfluoro diolefins has boon described in a previous paper (Izv. JON
SSSR, Otd. khim. n. 1961, no. 8, 1462). The tollowing substances were
synthesized in the present studyt (1) Diethyl eater of I, yield 9(rh, b.p.
0 20 20
96-97 C/7 mm Hg, n D 1.35411 d 4 1-426; diethyl ester of II, yield
b.p. 118-120 0C/5 mm H9, n20 1.3424, d 20 1.576; and diethyl eater of III,
0 D 28 20
yield NA, b.p. 142-143 C/5 mm K9. n 1.3406, d 1.686, by reaction of I,,
1) 4
II, and III, respectively, with absolute ethanol in the presence of fluosul-~
fonic acid; (2) dichloride of-I, yield 706, b.p.-110-1320C, n 20 1.3484;
D
Card 1/3

S/062/63/000/001/021/025
Derivatives of perfluoro ... I B101/B186
dichloride of I'I,'yi-dld 78%t b.p. 115-117OC/40 mm.Hg m.p. 29-30 0C; and
, 0
dichloride of III, yield 74',., b.p. lul C, m.p. 92-95 C, by reaction with
SOCI 2; (3) diamid-e of I, m.p.-255-2-')BOC, diamide'of II, m.p. 238-239 0C, and
diamide of III, m.p. 242-24490, were obtained in 95-Wo yields from the di-
ethyl esters of 1, 11, and 111, by reaction with NH 3 gas in absolute ether;
(4) dinitrile of 1, b.p. 630,C, yield 77t~,, dinitrile of,II, yield 80~~, b.p.
147-1480C, n20 1.3039, d - 1.673, and dinitrile of III, b.p. 115-120 0C/10 mm
D
Hg, m.P. 78 0 C (from acetone), were obtained from the diamides of 1 6 11, and
III by reaction with P 205 at 100-300OC; (5) amidine of I, m.p. 154 C,
amidine of II, m.p. 173-175 OC (with decomposition), and amidine of III, m.p.
167-1900C (with decomposition) were obtained in 96-99% yields from the di-
nir~lea of 1, 11, and III by reaction with liquid NH ;. (6) 41, tj t.,-tetra-
03 67-6&q
hydroperfluoro hexane diol, yield 80~,, b.p. 118-120 C/11 mm Hg' m P6
whose phenyl urethane complex, crystallized from M 4, has m.'p. 14 C1
,