SCIENTIFIC ABSTRACT KRAUS, J. - KRAUS, M.

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SCIENTIFIC ABSTRACT
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KRAUS, J., inze) C.So. I Moderni2+tion of our railroad tracks; discussion. Zel dop tech 10 no.10:310 162. KRAUS, Josef, inz. CSc.; KUBICEK, Bobumil, inz. 11 Using complex mechanized work trains for the repair of rail- road tunnels. Inz stavby 12 no. 3: Supplement:Mechanizace no. 3:35-39 164. 4 1. Research Institute of Transportation, Prague (for Kraus). 2. ZeleznIcni stavitelstvi) Prague (for Kubicek). n7. -1. ze, of ru!IT'oud b~'(-,. A na ra t1lod of laying f w 12 no.lOt261-264 164. KRAUS, Josef . ing. Railroad technology in the world. Rev cailor far 13 no.1:39-46 Ja 165. KRAUs, Josef, in,.1 KUBICEK, Bohumil, inz. Fconomic aspect of the naw methods of railroad Ledding consolidation. Doprava 6 no.6:415-418 164. Jearo., Inv, i ri,.,, 1:,0 1 1,:;,- 1 3eparntf? concreLlriE of uored pi. 3 59 F '65, 1. 3tavby sltnic a !rcr I Mare a) 2 . ~~Fl n!trch Iw;tltlitfi Kralm) KRAUS, J. Research in drainage and consolidation of soils under railroad tracks by means of electroosmosis. p. 74. ZELEZNICNI DOPRAVA A TECHNIKA. (Ministerstvo dopruvy) Praha, Czechoslovakia Vol. 7, no. 3. 1959. Monthly List of East European Accessions (EEAI) LC, Vol. 8, No. U. Nov. 1959 Uncl, KRAUSI J., inz., C.3c.; KUBICE*, B., inz. Mechanized deep jointing of stone masonry. 1,,,z stavby 9 no.9: 334-337 S 161. 1. Vyzkymny uatav dopravni, Praha (for Kraus) 2. Zeleznicni stavitelstvi, Praha (for Kublcek). XPAUS Josef, inz., C. Se.; NEDFLA, VIM., inz. lncreamin~r the bear!nv capacity rf rail-wny tracks by earth stabilizaticn. Zpl dcT) t-ch 10 no. D12-14 162. XRAUS, -J., --in%,y-G.Sc. W--- - Consolldatien of muddy ground under the rail joints. Zel dop tech 10 no. 3:85-86. 162, - KILOS, Joscf,--Y.Z., ';.5c.; 11LICEK, Eohumil, ir;z. Gun sprayed plasters froo aerated concrete mortar. Inz stavby 10 no.4:133-137. AP 162, 1. Vyzkumny ustav dopravni, Praha (for Kraus). 2. Zeleznicni stavitelstvi, Praha (for Kubicek). MLY Vilem, inz.,- KUICEK, Bohimil, inz.; KRAUS, Jose-f, inz., C.Sc. Experience with machinery used in the Aarocam method. Inz stavby 10 no.7: 2uffil Xo6bWdA#Ae no*.7877-,80 162. 1, Zeleznicni, stavitelstvi,, Rraha (for Jugl and Kubieek). 2. Vyzku=V ustav dopravni, Praha (for Kraus). KRAUS Josef, inz., C.Sc. New methods of improving the road slope stability. Siln doprava 11 no.2s6-8 F 163. 1. Vyziumny ustav dopravnip Praha. JIMS, Josoft inz., c.Sc,; KUBICEK, Bobumil, inz. Aeroconcrete grout in water-construction engineering. Vodni hoop 13 no.2:72-74 163. 1. Vyzkumny ustav dopravni, Praha; Zeleznieni stavitelstvi,, Praha, MUS, Jo*f inzop ScC.; KMCEX, Bohumil,, Inz. , . m- wNo"W w;,;` Lifting of the q#ftled concrete pavement by injection. Inz stavbv 11 no.5:110--173 My 163. 1. Vyzkumny ustav dopravnip Praha (for Kraus). 2, Zelemicni staviteletvii. Praha (for Kubicek). KRAUS, Josef, ipz., C.Sc.; KUBIGEK, Bolv.Lidl, inz. Stabilization of sl1pping ambwikwnts by injection. Inz otavby 11 no-/.:i5l-155 Ap 163. 1. Vyzkumny ustav dopravni, Praha (for Kraus) 2. Zeleznicni stavitalstvi, Praha (for Kubicek) HUBACEK, Josef, promovany ekonom; KRAUS, Josef, inz. Nsw trends in the production and use of industrial fertilizers in the world. Vest ust zemedel 11 no.6:231-237 164. 1. In3titute of Szientific and TechnolcgJcal information, Ministry Of Agriculture, Forestry and Water Resources Management, Prague. fflja~CEK' Josef, promovany ekonom; MX3, Josef, Inz. Scientific research and consultant activities in the United States agriculture. Vest uat zemedel 11 no.10:3 of cover - 4 of cover 164. 1. Inatitute of Scientific and Technological information, Ministry of Agriculture, Forestry and Water Resources. KRAUS, Josef, inz., CSc. Protection of rock cuttings by concrete mixture coating. Zal dop tech 12 no.ls20-22 164. KRAIMP Jomlf, inz, CSP.; TYC, Potr, don. Inz. C:3c. Construction of drain ducts with porous pipes. Zel dop tech 13 no.2:38-39 165. Mimi K. Braking of induction motors* pe 363e (Elektrotechnicky Obzore Vol& 46y no* 70 JulY 1957- Praha, Czechoslovakia) I SO: Monthly List of East European Accessions (EEAL) LC, Vol. 6, no. 10, October 1957. Uncle U'AUS, K. "The method of Inverted transformation." p. 547 (Elektrotechnicky Gbzor) Vol. 46, no. 10, Oct. 1957 Prague, Czechoslovakia SO: Monthly Index of East European Accessions (ELAI) LC. Vol. 7, no. 4, April 1958 Z/037/62/000/004/oo8/oo8 E197/E335 '111UTHOR: KrauB, K. (Ejpovice,near Pilsen) TITLE: 'Measurement of the thermal conductivity of ferrites PERIODICAL: Ceskoslovensk~ 'easopis pro fysiku, no. 4, 1962, 382 - 386 TEXT: The author evaluates the thermal conductivity X by m,easuring the thermal diffusion a , using the formula a = X/sc in which s isdensity and- c the specific heat. Two equal assem.blies, each comprising a known standard anil the ferrite under test, are used. The two assemblies are heated to different teraperatures, then pressed together to achieve intimate contact and the change in temperature at the boundary between standard and ferrite is measured. By specifying the initial. conditions and using the known formulae for the exponential change of tempera- ture with time, the author derives an expression for the tempera-. ture of the boundary and thus also the coefficient of thermal dif fusion. For the measurement, the author uses a two-tharmistor Card 1/'~ Z/037/62/000/004/008/008 Measurement of .... E197/E335 bridge, in which the difference in the temperature-resistance slope of the thermistor is compensated by an ohmic resistance. The dimensions of the standard (copper) were 60 mm dia., 80 mm long and the length of the ferrite specimen was 5 min. The temperature difference of'the two assemblies prior to test was about 15 OC. In the single experimental example quoted, procisely'the same thermal-conductivity value was obtained as is published in the literature. The advantages of the method are: short duration of the test (2 minutes); only small temperature differences are needed; the temperature has to be in one place only. There are 2 figures. SUBMITTED: February 15, 1962 Card 2/2 mus, K. (Ejpovice u Plzne) Preparation of colloidal magnetic iron oxide. Cs cas fys 12 no.l: 66-;87 - 62. WM=Y/Chemical. Technology - Fermentation in Industry. H. Abs Jour : Ref Zhur - Khimiya, No 16, 1958, 55457 Author : Kraus, Kanich Tnst Title A New Method for Preparing Fusel Oil during Purification of Alcohol~ Orig Pub Elem. ipar4, 1955, 9, 110 5, 146-148 Abstract A New method for purification of alcohol is described, providing the yield of fusel oils in an increased con- centration ( ;;180%). Card 1/1 ACCESSION NR: AP4016078 AUTHOR: Kraus, Kamil TLTLE: Analysis of magnetothermal affects Z/0037/64/000/001/0005/0016 SOURM Ceekool. casopLo pro fysiku, no. 1, 1964t 5-16 TOPIC TAGS: magnetothermal effects, Stoner-Rhodes theory, Teale-Rowlands theory energy changes, reversible processes, irreversible processes, Bloch's wall, SL-Fe single crystals ABSTRACT: The author evaluates theories used an a basis for the analyses of maget- othermal phenomena. The purpose of the study was to find shortcomings distorting the objective evaluation of experimental results. Theories of Stoner and Rhodes, and Teale and Rowlands are deacrLbed, and their limits of validity discussed. 11w_ shortcomings of both methods is that they apply only to magnetic changes due to reversible processes, but not to changes due to irreversible processes. It would be an advantage to evaluate individual processes from the point of view of energy changes characteristic of each process, in direct connection with the hysteresia.loop. A possible approach is to follow.changes in magnetothermal phenomena accompanying the movement of Bloch's wall on Si-Fe single crystals in the,~shape of frames prepared according to Williams; the author is at prevent Card 1/2 ACCWSION NR: AP4016078 engaged in experimental work in this field. Orig. art. boo: I figure. 63 equations. ASSOCIA71ON: SPS Strojnicka, Plxon (Secondary School for Mechanical Engineering) SUBMITrED: l4Peb63 DATE ACQ: l4Ptb64 ENCL%.00 SUB CODE: PH, GE NO REP SOVt 000. 01m: 018 Card 2/2 ACCESSIONARI AP4022282 Z/0037/64/000/002/0100/0104 AUTHORi Kraus, KamLl TITLE: Sensitive measurement of small temperature changes SOURCEt Cookoolovenaky caoopia pro fysiku, no. 2, 1964, 100-104 TOPIC TAGS: temperature measurement, thermistor, magnetothe,.rmal effect ABSTRAM An apparatus for measureme-,t of amdll temperature changes is described. The usual thermocouplea arc replaced by a thermistor (0.1 mm in diameter) with a low time constant, connected on a Wheatscone bridge fed by a circuit of 500 cps a-c. The a-c amplifier operates at the same frequency. The apparatus has been uned for measurenents of temperature changes an the order of 10-3C with an accuracy of up to 5%, Orias art, hast 6 figures. I table, and 5 .formulas. ASSOCIATION: none Card nt Of :ien3ltiv (:klekbosl f j,,,, zhurnql r of ! Iii K-iu-JTS, Karel., Inz- treatment in .- dl conlerl-nce on metal working and metal heat I fa t i o"I " Odesa, 1960. Hut listy 16 no.1-.62-63 Ta 161. - - - -. . ~'- ., -. I - M KRAUS, Karel# inz. Heat treatment of construction steel. Hut listy 16 no,5:3681vy 1619 KAIrLCKI, Karol; KRAUS, Karol Haah.imotols struma lymphomatona changed to Riedel's fibrous goiter. Pol. przegl. chir. 34 no.9029-933 162. 1. Z Zakladu Anatmii Patolog~oznej we WrocLawiu, Kierownik: prof. dr Z. Albert i z Oddzialu Chirargioznego III Szpitala Miejskiogo im. L. Ryxlygiera we Wrocalwiu Ordvnator: dr K. Kraus. (THYROIDIS LYMPMtATOUS5 (GOITER) KRAUS, L. KRAUS, L. Defective bricks in construction in the Ostrava region. p. 57 Vol. 34. no. 2, Feb. 1956 STAVIVO TECOOLOGY Prahap Czechoslovakia Sot East European Accession Vol. 6. no. 2, 1957 z BAUICR, J.; MUS, L. Problem of fracture healing in the distal third portion of the hmerus, Roshl. chir. 36 no.8:540-546 Alig 57. 1. ChIrargicka kliniks, UK v Kosiciach, prednosta prof, Jan Knazovicky traumatologioke oddelanis KUNZ Kosice, prednosta Jan Bauer. Orthopedicka klinika UK v Bratislava, prednosta prof. Jan Carvezansk7. (HUMUS, fract. distal third, hog ing (Cz)) BAUIR, J.;KRAUS, L. Primary suture of injured tendons. Rozhl. chir. 39 no.1:39-43 ja l6o 1. Ghlrurgicka klinikR UK v Kosiciach, prednosta prof. MUDr. Jan Knazovicky Traumatologioke oddelenia XMZ - Kosice, prednbsta MUDr. Jan Bauer. (TINDONS, wds. & W.) KRAUS,41 VEPROVSYA, E. Use of thin layer chromatography in the analysis of dispensed suppositories. Cesk. farm. 12 no.101515 W63 1. Statni ustay pro kontrolu leciv, Praha., a Krajska kontrolni laborator, Ostrava* KRAUSt L. Disdagulshfil =een a ~Oovv MvEnfi tn.! Ohemir,al Abstreate i0m and Podop y emnKPOK. I Cost Cab., ). V01- 48 NO- 5 -'IM -SCI lCfCbCr-SCbQlFnO. NO PRM BPOtS Of MOR 501n. Of Mar. log 1954 !podophyllin, the resin of Padophyllum pcUatum, show yellow Inmu:rnce in ultmviolet light, while spots of the resin of P.. D. Hubl! BiologiCal Gb(148trY nre s _jrr XRAUS. Lj. Determination of anthraquinone derivatives In drugs; rhisoma rhel and cortex fragulas. Cesk. farm. 3 no.5:171-174 )~r 154. 1. Z uutradnich technicko-kontrolnich laboratori Sanitass, Praha. (ANTHRAqUINONE, determination, *in various drugs) ZADINA. R.; KRAUS, Lj. pha.rm&COlogy of Vincotoxiam officluale Hoonch. Cook. farm. 3 no.7:235-238 Sept 54. 1. Z Vyzkumnsho ustayu lecivych rostlin a z Ustrednich technicko- kontrolnich laboratori Sanitas, N.P., v Praza. (Plains, Tincontoilcm officinals, pharmacol.) V KKA u 'S-, ~- 4 - CZECHOSLOVAKV,,/Chmdcal Technology - Chejaical Products and H-17 Their Applicationo Hedicinals. Vitamins. Antibiotics. Abs Jour Ref Zhur - Xhimiye... No 8., 1958, 26182 Author Inst Title Now Modification of Borntmogerts Reaction in Testing Folia Sennae Orig Pub Ceskosl. farmac., 1956, 5, No 7, 41o-43.1 Abstract In view of the fact that Barntraeger's reaction does not yield satisfactory results in the testing of senna leaves (Alexandria leave6), which is due to insufficient cleava- ge on hydrolysis of glucoside derivatives of anthraquino- ne., the fo3.lo*iu(S modification of this reaction has been worked out; 0.3 g of comminuted plant raw material are heated for I minute with 10 ml 0.5 11 K(XI toGether with 1 ml of H202 solution, The warm solution iu filtered Card 1/2 CZECHOSL4DVAM / Chemical Technology; Cbomical Products and Their B-25 Application. Fats arxi Oils. Waxes. Soap and Detergents. Flotation Agents. Abe Jnur Rof Zhur - Khimiyaj No 5, 1959, No- 17o94 Author Vesely., P.; Zadina, R. Inat Not given Title oil from Cytisus Lab%wnuu Soods Orig Pub Cookoal. farmos, 19571 6; No 8Y 448J~49 Abstract Oil was extracted with potroloum, ethar from CYtisus laburnum soods vith the yield of 11.4. The oil is dark yellow in color., of slightly burning tgto, it giyqs an acid reaction to lithL=, it has n D = 1.4739, d4~~o , o.qi4o, 190-7 saponification number, 119.2 iodino and nwabor, 0*5 acid nuwbor 87.0 Gennor number. The unna onifiod portimn .53~) yielded crystalline atcarine (24T C27H440 eko with 115 - U70 molting point, vhich vas tentatively namod "cytiaostoarim". -- A. Vavllovii Card 1/1 COUNTRY Czechoslovakia I "'A f 11.IGOH A113. MP. iiZ:~h-L*.M. 87(05 Kraus, Lj, "IL'ITUP Determination of Anthraquinone Derivatives In Pharmaceutical Preparations. I. Photometric Determination of Frangulaemodin in Cholagol. 0 R 1- - Ceskosl. farmac., 1959, 8, No 2, 83-B4 A 13 T RA C T A new method was developed for determination of frangulaemodin in the prc-paration Cholagol, w)ijcjj is based on Borntraeger's reaction. Analysis Is conducted In Pulfrich photometer, with 351 filter, in 5-m1 cells. On the basis of tbe results thus obtained a graph was plotted showing depencence of extinction on concentration of the frangulaemodin. -- From authorts summary. C--ZID: GSSII 'Lu lccj-~-V), )lo I:ontro .1sti,11to for DluC Control Otatni 113t' Bratis?-tvaj FarmncouticlZr Obzor, iio 1, 1963, pp 20-25 "GuXIJAVO Iferbo and PossibiliticS of t1jair Use in 11-odorn Tilorapy" (1) .KRAUS -ik~ ; NADHMp J& i Fharmaco-anatomical study ol the leaves of the fgmily Daueaceae. II. Apioideae - Scandicinaeo Cesk. farm. 13 no.0173-178 97164 KRAUS, L.; PERLRYI, F. Determination of azuIene in thr,, oil of milfoil mille- folium) by thin-layer chromatography. Cesk. fari;i. 1;, no.8:4;!3- 14,21, 0 165. 1. Statni ustal, pro kontrolu leciv, Frahn, Far--aceuticka fak-alta Univerzity Komenskeho, Bratislava. Submitted ',,Iaj, 16, 1965. KRAUS, Lavoslav, sanite-taki pukovnik, dr. On the role and place of health education in military medicine in the Yugoslavian Army. Vojnosanit. pregI. 19 no-4:272-276 Ap 162. (MILITARY MEDICINE) (HEALTH EDUCATION) KRAUS. Lavoslay, Pukovnik dr. Hygienic cultural and People's Araq. Voj. Jan-Fab 57, educational activity in the Tugoslav an. pregl., Beogr. 14 no.1-2:61-64 (HYGIENS, adue. in Yugool. People's Army (Bar)) KRAUS, Lyubomir Quantitative determination of cytiaine in ampules by means of paper chromatography. Apt.delo 8 no.2186-87 Mr-Ap 159. (MIRA 12:5) 1. Iz Gonudaratvennogo instituta kontrolya lekarstvennykh preparatov v Prage (Chekhoslovakiya) (CYTISINE) (PAPER CHROMATOGRAPHY) KRAUS, Lyubomir (Praga) ~~erials. Apt. delo-9 Paper oR;j~togrsphy of anthraquinon.a raw (KORA 13: 1~) noo6:64-70 N-D.'60* 1. GooudarotvenW kontrollnyy institut lekaratmennykh paratov. 13) ... HRAQUINO (CHROMTOGRAPHIC ANALIS (ANT (BGTUYI MEDIGAL) j ISHCHEIIKO, Aleksey Vladimirovich; KLDIOVy Boris Grigorlyevich; KODYK, Gri- goriy Trofimovieb; KOWTOVA, Irina Savellyevna; KRAUS, 14onid An- dreyevichj,ABR&OV., V.Ly otv. red.; SABITOV, A., tekbn. red. [Inspecting and adjusting hoists) Reviziia i naladka pod*emrWkh usta- novok. By A.V.Ishchanko i dr. Moskva, Gos. nauchno-tekhn. izd-vo lit- ry po gornomu delu, 1961. 81 p. (MIRA 2J,:.10) (Mine hoisting) TFRENTIYEV, Boris Petrovichy prej)od.; KITAYEV, Valentin Yevgenlyevich, prepod.; 0011BOVITSM, Roman t-'tirkovich, prepod.; ~~" Rs- --AOR _~Ljd4 prepod.; FUTIMU, Iya Nikolayevna, Lyu g_!y&R :~jLo prepod.; PrInImaln uchastip- LYATKOVSKAYA, A.D., inzli.; LYUBSKIY, G.S., otv. red.; VOLOWLISKAYA, Me., red. [Power systerz of cormunication enterprises] Energetika pred- priiatii sviazi. Mlonkva, Sviazi, 1965. 614 p. (MIAA 16:9) 1. I-loskovskiy elektrotekhnicheskiy inst--tut svyazi (for all except Lyubskiy, Volodarskaya). VIGAIM,_A.G.., inzh.; YJUUS#,, L.A., inzh.; ArZKHIN, AD,. Use of a multiple position relay control of tho asy*hronow engine for the automation of mine hoists. Ugoll 37 no.5:35-39 MY 62. ~ (MIRA 15:6) 1. Giprouglegormash i trost Oktyabrlugoll. (Mine hoistiog) (Automatic control) I A "h II ("I"..,. EMI~POWSKIY, Isny Il'ich- KRAUS L,A., red.; IARIONOV, G.Te., tekhn.red. - - [Power supply for radio installtional Elektropitanie radio- ustroistv. Moekvn, Gos.energ.12d-vo, 1957. 310 P. (MIRA 11:1) (Radio--Apparatue and supplies) BELOPOLISKIY, Isay Illich; KRAUS, L.A.9 kand. tekhn.naukp rpi. (Electric power supply of radio systems] Elektropitanie radionstroistv. Izd.2.p perer. Yoskvag Energlla~ 1965, 317 p. (MIRA 180) KHAUS, K.; HAHN, P. Effect of hypoxia on heart rate in young rats in ontogenesis in high environmental temperature. Cesk. fYaiol. 7 no-3:211-212 May 58. L J~rsiologlcky ustay GGAY, Praha, (ANOXIA, effects, on heart rate in young rats exposed to beat (CZ)) (E3AP 2 physiol. ;ate, eff. of anoxia in young rats exposed to heat 02)) (HZAT,effects, on heart rate in young rate exposed to anoxia (Cz)) IMAUS, M.; SKODA, J. Rpading on publishing. Pt.10. Chem listy 57 no.9.-1004-1008 S 163. BERAVEK,4; KRAUS,M.; BAZANT.,V. I Catalytic dealkylation of alkyl aromatic compounde. Pt.7. Coll Cz Chem 29 no,lt239-250 Jat6/, 1. Institut fur theoretisobe Grundlagen der chemischen Technik, Tachechoolowakische Jkademie der Wissenschaften, Prag. KRAUS, M.; SKODA, J. On publishing. Part 8: Experimental part of a scientific publication. Chem listy 56 no.11:1376-1379 N 162. KRAUS,, M.11 SKODAp J. Scientific p, Part 9. Chem listy 57 ~blications; discuasion. nool:93-95 A 163. JEKLER,Jej BOREK,Z.1 VANEGKOVApO.;_)WUSp~,!. Remote results of the surgical treatment of achalasia. Cas.lek. cesk. 103 no,13t329-334 V Mr'64 1. II.chirurgicka klinika fakulty vseobocneho lekarstv:i KU v Praze; prednosta: prof.dr. J.Lhotka. BLANA, K.; GTITY J.; KORYTA, J.; Czocho,ilo-rak !h~tmistry in thr~ y;-,,,.i*2 Chem li5!ty 59 no.5:521-532 Yly 165- unt, 0" in IIM of rats. 0-1 'r, TUGAINMISKI, Witold Charigen of thf~, blo-clectric ncti-v-.; in in-I 7t?iiial flb'~rs of 11 lionirt. Actn physiol. Pol. 1 n, .. Z 7,F)-kIlidu Fi 7,jol ngil. S I rz:'r 1 h A VI 11 k : d C . d-, . M . DLOUIIIA, H.; KRMS,,M.; KU,,CEf,,J.; PLISKA,V. Ser:sItivity of rats to vasopressin in the vewiir~,g period. I'Iiy.,;iol. Boheva031OV. 14 ro.3:217-224 165. 1. Tnatitute of Physiology and Tristitute of Organic Chemistry and Biochemintry, Czechoslovak Acadm,.y nC Sciqnces, Prargue. KBAUSZ~-Miaaxynlaw* doe. dr.; VORBRODT# Cndrzajp doe. dr.; KMWISZM, Henryka; TAWS , Jozef. AttmTt of histochemical localization of catecholamines In the metencephalon. Acta physiol. Pol. 16 no.1:1-7 Ja-F'65. I* Zbklad Plzjologii (Kierownik: doe* dre M. Krause); Wlad Histologil. i Ibbrioloei Ogolnej (Kierovnikt doe. dr, A. Vor- brodt) oram Taklad Amatomii Pravidlowej Slaskiej Akadenii Medyoznej v Ubrzu-Rokitnicy (Kierowniki prof. dr. St. Kohmann). KRAU', Mail, Jti(,., cerecetator atiintific - .--- ------- -.- I . A valuable fodder plant, the hybrid ,,,orghLun. St --I Teti Puc 17 no.3:3P-39 Mr 165. 1. T.C.C.P.T., Rmdulen. C. WMAM", aM4r4ftl liceyl actute (1) 11-AteA in 4 q~jtz tube at 220,30' fit .Licli a rutio that the! pl-tiA prmur 11 i9 12 nim. avil Nit jwriA of oc"Ilt.1 0,13 a 010"T, onivershill ~kolf -1 7.5.5'-7, vh-141 ol C-1 m sample colkeol"Pt v rti Arl Pl. I A Urzmpk So' oil. Lrascd ca tht rl'6~ "~ drscribed arA rattd tmd as ;i gaa bld~~r Czechoelovakia/Organic ChemistrY - Synthetic Organic Chemistry, B-2 Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 797 Author: Kraus M and Bazhant, V. 66" Institution: None Title: Dienes by the Pyrolysis of Cyclic Compounds. I!. Preparation off Butadiene by the Pyrolysis of Cyclohexanol Original Periodical: Sb. chekhosl. khim. rabot, 1956, Vol 21, No 2, 363-367 (German summary) Abstract: See Referat Zhur - Xhimiya, 1956, 46830 Card 1/1 -:"~Cbeud'~Sd; Journa ljczechbalovakia) 'Vol 50 (80) Ito. 4, April, 1950, Pyrolytic Froparatioa of Uenvin fma C11clic Oompour.(10.111.9 Kine-tics of Fission ol" C'iC_EO_17x_cnp and Qyc1ghgxy2:_,&QOtmtO. The kinetics of ryrolycis of cycloberene to butadiene wid ethYieno Liet"1004 938 - 1018"' (; arid the xyl aoctato to cyclobeyone aud uootlo acid botteon 'G23,-,773 G WoM iinveottealed. Ootlh reactions are homoCencouo ahd-~ of -the --f int-ordar,- valucIty uanstaitts were caloulated.. By 114 *1e_raabT!.VavruaJ.-,a 4; ............_ clip MMONS i14 E NN -'A 78 I act Vitt -1-461na -y S. Ooln "d dr In (PPA , PeedIng AD S. cm" to a hftter sit a rate 0.11 it -wiTwm. .8,7~6.F, Yet space together with H (0.12 molelmin.) and passing the wartned mixt. at it rate 13.8 mole/hr. through 4 teactze tube-, 480' t 80 t d l i h 9 m , ca eate to a g. condensate: yvt jives 7 j, " wh" yields on dista.: 13.3 X., b. 1, 0-M I (phenol); 10.8f -98, =1), 04.7 1., b. 108-2M, (ffl-ctexol);~ 7 203- ( le ta b d 8 0 di id l ) . no . s . res ue. , su g. s xy x L. UrbAmr1r 01 KRAUS.,--ji.. ? VAVRIM-KAP M. : BAZANT, V. "Detection of dienes by means of the pyrolysis of cyclic compounds. III Kinetics of the decomposition of cyclohexene and cyclohexylacetate. In German." P. 484 (COLLECTION OF CZECHOSLOVAK CHEKICAL COMUNICATIONS. SBORNIK CHECKSHOSOLVATSKIKH KW.IICHESKIKH RABOT. -- Praha, Czechosloval..-a.) Vol. 22J No. 2., April 1957 SO: Monthly Index of East E-oropean Accession (EEAI) Lr,, Vol. 7, No. 5 May 1958 -KRAUS,jA,- "V. Ettel's Orranicka tachnolovie (Organte Technolo ); a book review. In German." p. 1074 (Collection of Czechoslovak Chemical Communications. Sbornik Chekhoslovatakikh Khimichaskikh Rabot.) Vol. 22, no. 1, June 1957 Prague, Czechoslovakia SO: Monthly Index of East European Accessions (EEAI) LC. Vol. 7, no. 4, April 1958 CZECHOSLGVAKIA/Orpnic Chenistry. Synthetic OrgnnicChemistry. G Abs Jour: Ref Zhur-Khim., No 2, 1959, W41. Author Kochloefl, K., Kraus, M., and Bazant, V. Inst Title Isonerization and Disproportionation of Cresols. Orig Pub: Chen Listy, 51, No 12, 2295-2303 (1957) (in Czech). Abstract: The isomrization and the disproportionation of cresolo in the liquid phase and in the gas phase on acid catalysts have been investigated. The starting material used consisted of the m- and p-cresol frac- tions obtained during the semicoking of brown coal after renoval of basic and sulfur-containing compounds. As a result of isomerization the m-cresol content was found to increase from an initial value of 3% to 60%. The results obtained from liquid phase isomerizations Card 1h 14 CZECIIOSLOVAXIA/Organic CherAstry. Syntlietic Organic Cherdstry. G Abs jour: Ref Zhur-Khim., No 2, 1959, 4641. carried out with AlGIj as a catalyst at 1401 are similar to those described earlier (G. Baddeley, J Cheri Soc, !243. 1. P. Yoiasner and F. E. , 527; ' French) J Amer Chen Soc) y4, 1000~ 1952)). Gas phase experimnts have been carried out using a variety of oxide catalysts and catalysts containing fluorine; anong the latter best results were obtained with A1(13F*)s on J' -A140j, calculated at 24. In the isomrization experinerts the cresols were diluted with hydrogen in the ratio 1 : I in order to reduce carbon deposition on the cataly8ts. The effect of teaperature was investigated in the range 380-500c and the space velocity was varied between 15-and 75 mls/hr per liter catalyst. Using pure coppo- nents (o-, n-, and p-cresol as well as various Card 2/3 CZECHOSLOVAKIA/Organic Chemistry. Synthetic Organic Chemistry. G Abs Jour: Ref Zhar-Kh1m., Ito 2, 1959, 4641. xylols) the reactivity of the various isoners was investigated. The effect of various catalyst poi- soning agents has also been investigated. Nitrogen- containing substances (pyridine mid quinoline) in small amounts have a negative effect on the isomeri- zation process and in large amounts also inhibit the disproportionation, process. Sulfur conpo=ds, on the other hani, inhibit only isomerization reactions and have no effect on the disproportio- nation reaction. Apparently the two reactions take place at different active centers. Values are given for the equilibrium constants for the isaneerization and for the disproportionation reactions of all three cresols. The heats of reactions are also given. -- K. Setinek. Card 3/3 15 DiGtr: 4E3d /Obtdining Rk~~ and cresols from xylt:nol fractions. ~%rau%T-K-uucl KochhwP, and VI -a,lipjjr" WLUIL 9,056. Apr. 15, IONT x',lenol 1ructimis coutg. approx. 2070 ethylphimob evapd. in a sticam tit 11 (Ifx) 111 1. 11/g.). the mixt. passed itt U)O' over r-afalyst contg. 200/,) AI(BF,), on -I-alumina nt I kg, fractiwi/lir./L catalylic hPUCC 91VC:; a 11(plid prodoct kuotg. 1110 21.7. mixt. of Cil, arid I'lihie 2.0. PhOll 25.4, o-cresol 6.3, mitt. of M- and p- cresol 25.5, mixt. of xylcuots 23.8. nod distit. tesidue 14.3%. L. J. UrtAuv4- A(~, COUNTRY : CZ1.1' ~'i i 0 SLOWLI, IA CATEGORY : 01,ganic Clicniotnj. Synthr!tlc O.-:!~,inic Chr-rilstry ABS. JOUR. : RZKhims) No. 1 196o, No. 1160 A.7 TFj)F. Kocilloc "1 114; PJ'IZI?.rt, V. T ITLE Iso'norization tend Disproportlom..tion of -,rcsols 10-Rlr-. PUB. : Col.Icct. Czl-chosl. Chem. Corwiuns, 1959, 2~., 1;0 3, 958-967 :ABSTRACT : Flo nh2tvact "Scol AI~2i]Lkl. lia 2, 19,59, Eo LL6--hi. VAcIdIty and activity of fluntabof ate ca'al at$ M Krnus K. Kochloeff, K & r 9. a a d V. a. PRI"t : II.-'N.Wo nib CGWZ too Czechollov. Chi~t. Con tis. 24, 1188- 93(1059).-The study of the Isomerhation of o- to w- and P-xylene, of P--resol, and of the disproportionatiou of xylene, cumene, and v4so-PrC4H40R on catalptirej. by Im reanating ralumina with AI(BP.h (1) (CA. 5 1, 8h) InTicates that the catalyst actlylil, is ptopoctional to the abundance of acid centax and that catalysts i3 caused by a new Compd. tomied from alumina and I which contains d -.4.1lu IkkSL T. U KRAUZ -Miloah--[ Kraus M.); Kokhlefl'. Karel (Kochloafl, K.]; BAZU", V~--~Zxlv V-1 Fluoborate catalyst for the isomeri2azion of cresols. Probl. kin. i kat. 1.0079-384 160. (MIM 14:5) 1. Khimicheakiy institut, Chakhoolovatakoy Akademii nauk, Praga. (Creool) (Aluminum fluoborate) BERANEK, L.; KRAUS, M.; KOCHLOEFL, K.; BAZANT, V. Mechanism for dehydrating secondary alcohols by means of aluminum oxide. I. Relation between the dehydration of alcohols and the iso- merization of olefins. Coll Cz chem 25 no.10:2513-2521 0 160. (ELU lo: 9) 1. Institut fur theoretische Grundlagen der chemischen Technik, Tochachoslowakische Akademie der Wissenschaften, Prag. (Alcohols) (Aluminum oxide) (Olefins) (Dehydration) JOKLIK, J.;_2TIUS, M.; BAZANT, V. Silicon organic compounds. XXIII. Kinetics of the reaction of methyl chloride with chomical3,v pure silicon in a catalysis with copper. Coll Cz chem 26 no.2:427-435 F 161. (EFAI 10:9) 1. Institut fur theoretische Grundlagen der chemischen Technik, - TBohachoolowakisohe Akademie der Wiesenschaften, Prag. (Organic compounds) (Chloromethane)- (Silicon) (copper) (Catalysis) t, KADLEC, M.; KRAUS, M.; BAZANT, V. - r--~ Silicon organio compounds. XXIV. Kinetics of a direct synthesis of metbyl chlorosilane under increased pressure. Coll Cz chem 26 no.2: 436-441 F 161. (EEAI 10:9) 1. Institut fur theoretische Grundlagen der chemischen Technik, Tachechoolowakiache Akademia der Wissenschaften, Prag. (Organic compounds) (Silicon) (Chloromethylsilane) SCHNEIDER, P.; _F!~USp M.; BAZANT, V. Catalytic dealkylation of alkylaromatic compounds. III. Reaction Of kinetics of etbylphenole over an acidic catalyst. Coll Cz chem 26 no.6tl636-1645 Je 161. 1. Institute for Chemical Process Fundamentals, Czechoslovak Academy of Sciences Prague. (Alkyl group) (Etbylphenol) AYZIKOVICHI M.A.; BORISOVA, L.A.; ZUBKOV, B.I.; -KRAUS, M. Order of the addition of ethyl alcohol to &symmetric methyl- phenylethylene oxide. Trudy LTI no.59t22-33 161. (MIRA l7r9) h1743 6/081/62/000/019/018/053 B144/BI80 TlTLI',': ur[anosiIicup cn~;ipourias. A.AVIll. Direct synthesis of ethyl chlorosik.ncs 1SIIujIC,,.Lj Refara!ivny~- zhurnal. . -Khi,Aya , no. 1,~, 1962, 22.5, abstract 19ZI:245 (Collect. Ozechoul. Chcm.,r,omm,jns,, v. 26, no'. 8, 1961, 20213 - N 34' [Ger. j zu;i,%iary in Rd3 T~'-:,~T: The kinetics of -C,,Ii..Cl Iriteracti6n with Si was a*tu(Aied in the pres'ence of a copper catal."t (ratio b;- we!Cht ji.Cu 90) in a flov.--throuCh renc- o r -, t 2 00 - 3 2 00 C. All the eti,yl chloroailane6 are forimed simultaneously. The zplittine of C h 01 with fQrma-tion of COH and fiCl is not a secondary 2 5 4 4 reaction. ilt~ncc, the forixition of C 2H5SiUC1. munt be attributed to oecond- :,ry reactiona takinr pl,,.,ce at the copper surface. The effect of the temperature and partial (,'2H5Cl ~re,-.-,ure on the course of the reaction %as studied. The experimental octui bird procedure are de:-,cribed. Report "VII Ca*rd 1/2 S/081/62//000/019/018/053 Orf,anosilicon compounda. ... BI-14/BlcO see Nh?,hiia, 1962, 15=2j"). [Abztracter's note: Complete translation.] Citrd 2/1, 8/081J62/000/024/039/073 B101[B186 AUTHORS: Ayzikovich, M. A., Borisova, L. A., Zubkov, B. I., Lr~ TITLE: Ethyl' alcohol addition to the oxide of asymmetric methyl- phanyl ethylene PERIODICAL: Refera,tivnyy zhurnal. Xhimiya, no. 24, 1962, 316, abstract 24Zhi6i (Tr- Leningr. tekhnol. in-ta, im. Lensoveta, no- 59, 1961, 22-32) TEXT: This is a study on the addition of C 2H 5OH to the asymmetric methyl- phenyl ethylene oxide (1) in its dependence on the catalyst used in the presence of C H ONa and the (C H -BF, c~omplex. Dehydration of dimethyl- 2 5 2 5)20 phenyl carbinol yielded C 6H5C(CH3)-CH2 (11), b.p. 164-166OC/760 Mth Hg. A solution of monochloro urea converts Il into C6 5 3 2 H C(CH )(OH)CH Ci (III), b.p. 99-1020C/9 mm H�. Stirring of M with 2V1* NaOH at room temperature yieldej, b.p. 84-86 C/16 mm, Hg. Heating of 8 g I and'60 ml 0 2H5 Oil containing 1 g metallic Na in a sealed.tube (1000C, 24 hre), distillation Card 1/3 s/081/62/000/'024/039/073 Ethyl alcohol addition to the B101 M6 of the alcohol I extraction wiih ether, and fractionation in vacuo yields 44.2,o (with respect to I) C 4H~C( C'13 )(011) C"20C2H5(IV), b.p. .0 20 20 114-115 C/10 = Hg, n 1.5062, d 1.0172. The structure of IV was D 4 confirmed by the following dyhthesis: a three-fold excess of CH M91 was 3 0 20 caused to act on C 2If 5OCII2 COC6H 5(V), b.p. 94-96 C/2-3 mm fig, nD 1-5302, 61'~", of which had been obtained by reaction of C H MgBr'with C H OCH CIT, 6 5 2 5 2 b.p. 133-134'C. The latter was obtained with a 46-6;'7 yield from P20 5' 0 reacting witf, C 2H 5OCH2CONH 21 m'P' 81-03 C, 72,,/o of,which had been synthesized from a 281,e, solution of NH OH and C if OCH COOC H The latter 4 2 5 2 2 5* was obtained from the corresponding acid synthesized from C 2 H5ONa and CICH2 COOII. Reaction of C 2H5PN& with 5-3 9 1 in 100 ml absolute C 2H5 OH in the presence of 0;5-1 ml (C. H 5)2 O*BF, yielded 3 '6% (calculated. with respect to I (VI), b.p. 120-1210C mm Hg, n 20 1-51571 ) CUAP(CVOC2HOCH.20H D Card 2/3 S/081/62/000/024/039/073 Ethyl alcohol addition to the ... B101/B186 d20 1.0289. The resulting data show that I reacts with C H OH in the 4 2 5 presence of C2H5ONa yielding mainly IV (according to V. V. Markovnikov's rule), whereas in the preoenco of boron fluoride, mainly VI is obtained (q;ainst this rule). [Abstracter's note: Complete translation.] T Card 313 EMS. Milga; KOCH14ML, Karel; SETINEK, Karel; BERANEK, Ludvik; _--'i ~6i, Milosiav; BLUNT, Vladimir The course of potassium phthalate rearrangement to potassium terephthalate. Chem pr= 12 no.10:529-534 0 162. 1. Ustav teoretickych zakladu chemicke techniky, Ceskoslovenska akademie ved, Praha. KRAUS Milos; BERA=, ladvik; KOCHIDEFL, Karel; BAZAIr,', Vhii,,i 'I.. Vapor tension of some benzenecarboxylic acids atAd their derivatives. i Chem prum 3.2 no.12:649-652 D 162. 19 Ustav teoretickych 2akladu chemicke techrdky, Ceskoslovenska akademie ved, Praha@ ga v 3-AN I lgi if e ?Pj ;44 lip ~jt S/os 11/63/000/004/013/051 - AUTHORSs Joklikt J., Kraus# U## B41ant, Vo TITLEt Silicones. XXIX. Kinetics of the direct synthesis of mothyl- bromosilane PERIODICALs Referativnyy zhuinal. Khimiya, no- 4, 1963, 212, abstract 4Zh27 (Collect. Czechoal. Communs, Y. 27, no. 4, 1962# 974-978 LGer.j summary in Rusa.3) TEXTt The reaction rate is studied of CH3Dr with pure Big catolyzed with Cu, in a static installation at 100 - 1,000 mm Hg and 240 - 28000. 'The results are correlated by means of the relation derived earlier for CH 3Cl. It was found that the reaction of 08 1 with Sig using a Cu or AS tatalysto at 280-3500 gives tetraiodoollene instead of methylbromosilane. Apparently the methylbromosilane which in formed decomposes and the decomposition products block the active aurface of the contact nasal howevorg it is also possible that the C11 31 decomposes., The reactions of Cu and AS halides with Si were also studied. The &uthor considers that the reaction of alkyl Card 1/2 S/081,(63/000/004/013/031 Silicones. XXIX. Kinetica of the... B166/Bie6 halides with Si takes place during adsorption associated with dissociation, in which case the alkyl to adsorbed on the copper and the halide on the Si. Bromine atoms lower the electron density of Si less than chlorine atoms, which to a great extent promotes substitution of the electrophilie CH group at the Si, This process agrees with the results of kinetic measurements. For communication XXVIII see RZhKhial 1962, no. 19, IqZh245- (Abstracter's notes Complete translation.3 Card 2/2 KOCHLOFFL, K.; KRAUS-t M.L-CHOU CHIN-SHEN: BERANEK, L.; BAZANT, V. Un the mechanism of dehydration of secondary alcohols over alumina catalyst, Part 21 Effect of structure on rate. Coll Ca Chem 27 no.5sll99-lX9 My 162. 1. Institute of Chemical Process Yundanentals, Czechoslovak Academy of Sciences, Prague, 2. On the leave of absence from the Institute of Applied Chemistry, Chang-chun, China (for Chou Chin-Shen). .f5 A .1 V. DO 32 -7 14 PK saya e l M A v 14 tj 0 KRAUS, Milos; SETINEK, Kar,"; JOST, Frantisek; BAUNT, Vladimir Some properties of catalysts tar rearrangement of potassium phthalate into potassium terephthalate. Chem prum 13 no.2:67-70 F 63. 1. Ustav teoretickyoh sakladu chemicke technikyp Ceskoslovenska akademie ved, Praha. C ZEC i MLOVAIKIA __,_M; BAZU'Do V. K~AUS Institute of Chemical Process Fundamentals Czechoslovak Academy of Sciences, Pra~rue (for both~ CD Prague, Collection of Czectioslovak Cho,-.,iical Communications, No 7, 1963, pp lb77-lb84 "Catalytic Dealkylation of Alkylaromatic Compounds. VI. Reactions of Dialkylphenols Over an Acidic Catalyst."