SCIENTIFIC ABSTRACT KREYN, O. YE. - KREYN, S. E.

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• Collection: Scientific Abstracts
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• Document Release Date: July 31, 2000
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KUYN, O.Ye.; KOWHIM, L.P..
\-
Comparative economic evaluation of methods of preparing molytAlonur,
dioulfide. Izv. vys, ucheb, zav.; tsvet. met. 2 no-3:130-134 159.
O-IIRA 12:9)
1.Moskovskiy institut tavetnykh motallov i zolota, Kafedra notallurgii
reak-ikh metallov.
(Molybdenum oulfides-Costs)

ABASHIN, Georgiy Ivanovich; FOGOSTAN, Grigoriy *aradovich; _,qHjW,_ O.re. ,
retsenzent; BELTATATSKATA, L.Y., rateenzent; SINTAKOV, A.Y.,
retsenzent, red.; XAKAIWA, O.M., red.izd-va; XARASEV, A.I.,
tekhn.red.
[Tungsten and molybdenum production processes] Takhnologiia polu-
chaniia vollframa i molibdena. Koskvs, Gos.nauchno-tskhn.i%d-vo
lit-ry po"'chernoi-i tsvetno~.metallurgii, 1960. 259 p.
(MIRA 13:10)
(Tungsten-46tallurgy) (Molybdemu~--Metallurgy)

=,L- 6 ~5 V,3
S/078
,/60/005/05/30/037
B004/BO16
AUTHORSs Meyerson, G. A., Kreyn, 0. Ye.
TITLEs Preparation of Hafnium Carbide 'Vi
PERIODICALt Zhurnal neorganioheekoy khimiij 1960, Vol- 5, No. 5, PP- 1164 - 1167
TEXTs The authors deal with this problem because HfC might be of interest for
reactox/7enRineering, since it is a substance with a high melting point and a
high neutron absorption coefficient. They treated pure HfO 2with lampblack at
0
0 2, 1, and 5 torr and temperatures of between 1,800 - 2,200 .Table 1 shows that
c;mpounds free from oxygen were obtained which, however, contained less C than
corresponds to the formula HfC. A carbide forms with defective lattice and re-
duced period. In experiments with carbon excess (Table 2) a carbide with nearly
stoichiometric ratio between Hf and C was obtained. Fig. 1 indicates that a low
pressure of CO in the reaction vessel (of the order of some torr) supports the
formation of cc plete HfC. The lattice constants of three samples with 4.61,
4.62, and 4-63 1 were determined by X-ray analysis (Fig. 2). These values were in
close agreement with the data available in publications. There are 2 figures,
Card 1/2

440'P3 -K
Preparation of Hafnium Carbide
2 tablesp and 9 references, 4 of which are Soviet.
SUBMITTEDt JulY 1, 1959
3/078/60/005/05/30/037
B004/BO16
Card 2/2

83122
S/078/60/005/009/001/017
2 20U B015/Bo64
AUTHORS: Meyerson, G. A., Kroyn, 0. Ye.
TITLE: Study of thtr- Conditions of Synthasizing Vanadium CarvidoAn
Vacuum
PERIODICAL- Zhurnal neorganicheskoy khimii, 1960, Vol. 5, No. 9,
PPO 1924-1930
TEXT: It has alroady been found (Ref. 6) that in reducing V 203 Nitn car-
bon at atmospheric pressure the amount of carbon bound in VC did not r,!.Rch
the theoretical value of 19-05%, and that below 2500 0C also in th- -,4.btv~n~,,o
of oxygen there were still vacancies in the carbide lattice (Tabl.! 1).
The present investigation deals vith the proguotion of vanadium carbide
at 0.1-10 torr and temperatures of 150OP-1600 C by reduction o** V 20
(65-3~~ X) with carbon (carbon black) in a vacuum furnace. To determine the
temperature range in which carbide formation took place, the proce-na
manometrically analyzed (Fig. 1). In the substitution of oxygen by ccrboll,
0
however, part of the sites occupied by oxygen remain vacant. At 11)(,0 C' at"(1
Card 1/2

83122
Study of the Conditions of Synthesizing Vanadium S/078/60/005/009/001/017
Carbide in Vacuum B015/BO64
above, oxygen can be completely removed from the solid phase In vacuut,
under the formation of a oolJd VC_V solution (Table 2). Three sample mix-
tureB were made to determine the influence exerted by the amount of carbon
on the carbide formation (Table 3). It was found tnat at 15000C asid
0.1-1.0 torr also in the presence of free carbon VC-V "as formed, and not
0 0
1500 1800 C and 0.1-1.0 torr it is possible to obtt.11
VC (Table 4). At -A
oxygen-free carbide with a maximum carbon content of 15.5fa to 17.61.t (in-
f
stead of 19-05'/o). The experiments on the influence of temperature and pr"a-
sure on the composition of the product (Table 5), the dgpendcrce of' the
amount of bound carbon on the reaction duration at 17 00 C (Table 6), and
the composition of vanadium carbide obtaine9 from a mixture with increased
carbon content (Table 7), show that at 1700 -18000C and 1-1.0 torr the
maximum saturation of vanadium carbide with carbon amounting to 17.6- '0
is reachod within two hours. M. A. Gurovich and B. P. Ormont are mentiorod
in the paper. There are 4 figures, 7 tablon, and 8 roferences: 4
I French, 2 Japanese, I US, and I Gorman.
SUBMITUD, , June 18, 1959
Card 2/2

5.2000,15-05600 771" 99
SOV/80-33-1-8/49
AUTHORS: Zelikman, A. N., Kreyn, 0. Ye.
TITLE: Preparation of Molybden*wn Disulfide for Lubrication
Purposes
PERIODICAL: Zhurnal prikladnoy khimii, 1960, Vol 33, Nr 1, pp 49-55
(USSR)
ABSTRACT: The lubricating properties of natural MoS 2 (molybdenite),
supplied by the Sobin Refining Plant, and of synthetic
Mos , were compared by testing both materials in oil
suspension in TsNIIMASH and VIAM friction testing
machines. The lubricating properties of both additives
were practically equal. Synthetic MoS 2 was obt-ained:
(1) on fusing MoO 3 with sulfur and sodium carbonate;
optimum conditions: sulfur in 15% excess, temperature
7000 C, time of reaction 1 hr; (2) on fusing CaMoo 4
Card 1/2 with sulfur and sodium carbonate; optimum conditions:

Preparation of Molybden= Disulfide 77499
for Lubrication Purposes SOV/80-33-1-8/49
SIUBMITTED:
sulfur in 60% excess, temperature 600-700 0 C, time
of reaction 1 hr. There are 5 figures; 5 tables; and
7 references, 2 U.S., 1 French, 3 German, 1 Soviet.
The U.S. references are: R. E. Bell, R. E. Herfert, J.
Am. Chem. Soc., 79, 13 3351 (1957); R. L. Graham,
L. G. Hepfer, ibid.' 76; X, 19, 4846 (1956).
January 19, 1959
Card 2/2

IL411 15' 5 Z) S/070/61/0101VO,03/003/009
0 0 E021/E435
AUTHORS: Zelikman, A.N., Chistyakov. Yu.D., Indenbaum. G.V. and
Kreyn. O.Ye.
TITLE. Study of the crystal structure of molybdenum disulvhide
prepared by different methods
PERIODICALt Kristallografiya, 1961, Vol.6, No.3, PP-389-394
TEXT: The crystal structure of powdered MoS2 prepared by five
different methods has been investigated by X-ray analysis.
Sample one was formed by the interaction of molybdenum trioxide
with sulphur in fused soda; sample two by the interaction of
calcium molybdenatewith sulphur in fused soda; sample three by the
interaction of molybdenum pentachloride with hydrogen sulphide;
sample four by the interaction of molybdenum trioxide with sulphur
vapour and sample five by the interaction of molybdenum with
sulphur vapour. Further samples were also tested - sample six
obtained by the thermal dissociation of molybdenum trisulphide and
sample seven obtained by the interaction of molybdenum and sulphur
and hot-pressed at 1200 to 13000C. The X-ray photographs of these
samples show that the structure of all the synthetic samples is a
Card 1/4

22792
S/07o/61/oo6/003/003/009
Study of the crystal E021/E435
new type different from both hexagonal a-Z~IOS2 and rhombohedral
P-MOS2. Fig.3 is a comparison of the results of X-ray studies for
the three types of structure (a - M-MOS2, 6 - P-MOS2, Ej and 2
new structural type). Since the Interplanar distance is the same
in going from one form to another, It can be assumed that the
layered lattice and the disposition of the sulphur atoms around
the molybdenum Is retained. It Is proposed that the new form is
hexagonal with c greater than in the lattice of O-MoS2.
Changes can be seen In the new structure depending on its method of
preparation. This is explained by statistical interchanging of
hexagonal and rhombohedral packing. The lubricating properties of
the Artificial MOS2 are not different from those of natural MoS2-
There are 3 figures, 1 table and 11 references: 2 Soviet-bloc and
9 non-Soviet-bloc. The two references to English language
publications read as follows: S.S.Berzollus, Pogg. Ann., 7, 261,
1826; R.E.Bell, R.Herfert, J.Amer.Chem.Soc., 19, 13, 3351, 1957.
ASSOCIATIONi Krasnoyarskly institut
(Krasnoyarsk Institute
SUBMITTED: September 5, 1960
Card 2,'4
tsvetnykh metallov im.M.IAalintna
of Non-Ferrous Metals Imeni
M.I.Kalinina)

Study of the crytt-61
Card
;,2792
S/070/61/906/()o'-
E021/E435 -,/003/009

227-9 2
V070/61/oo6/003/003/009
Study Of the crystal ... E021/1"1435
I
a
9
Fig.
3
Card 3/4 1 " I'* - ,
i~ P,,-, w
k f A, 4"

2, 1 '~ 0
ic-, 2 2- 0 0
27074
S/080/61/034/oo3/oi6/o17
A057/A129
AUTHORSt Zelikman, A. W., Gorovits, N. N.
TITLEt Purification of molybdenum trioxide from tungsten and admixturis of
some other elements
PEHIODICAL: Zhurnal prikladnoy kh1mii, v. 34, no, 3, 1961, 679 - 682
TEXTt A preparative purification method for molybdenum trioxide fr,)m tungsten
and other Impurities is described. The method in based on distill-atia-'I of mKlyb-
denum oxychloride by heating a mixture of molybdenum trioxide and sodium chlnrld'l.
Thus the tung�ten content can be decreased from an initial content of 0.01 to 1%
W down to 10- t - 10-3% W. The present method was already published by A. N. Zelik-
man [Soviet patent no. 1131145 (1957)j and developed as a result of prior tnvesti-
gations (Ref. 1i ZhOKh, 24, 1916 (1954)]. Previous experiments demonstrated tl,.e
reaction of MoO5 with NaCl at 5000 - 7000C resulting in format-ion of sodluir. molyb-
date and dioxychloride. The latter evaporates at this temperature. On the other
hand it was observed that at 5000 - 6500C tungsten trioxide does not react wW%
sodium chloride forming volatile compounds. Tests for the present metbod were car-
ried out with M003 + W03 m'rt"res varying the ratio of W/(Mo + W) from I to 29%.
card 1/4

27074
3/080/61/034/oo3/ol6/017
Purification of molybdenum trioxide from... A057/A129
The mixtures were obtained by mixing an ammonium molybdate solution with at=or,'utm
tungstate solution with subsequent evaporation of the liquid and calcination.
(5500 - 6000C) of the residue. The latter was then thoroughly mixed with ftnely
ground sodium chloride, placed In a horizontal tubular oven and heated by passing
air (about 10 I/hr). Molybdenum oxychloride sublimated, was dissolved and molybde.-
num and tungsten were determined. The latter was first determined colorimetrically
by the method of the Vsesoyuznyy institut tverdykh splavov (All-Union Lnstitute of
Solid Alloys), but since this msth:~d was insuffioient in further experiments a
spectral method, developed in the DUU (Moscow State University) by N. I. Tarasevi3h
et al. [Ref. 4: n, 8 (1959)] was applied. The obtained results (Table 1) demon-
strate that the sublimates contain a maximum of about 0.001% W/(Mo + W),, and inde-
pendently of the composItion cf th!, mixture about 20% of molybdenum sublimates.
Further tests were made with a quartz t1ibular oven (length 1 m, diameter 45 mm),
using 200 g samples, passing air at a 20 1/hr rate, and heating to 6500 - 7000C for
30 minutes. Thus a 20 - 22% ertraction of molybdenum was effected. For tungsten
contents of 0.004, 0.01, 0.03 arA 1.035% in the initial material (Mo03 from ammo-
nium paramolyVate., m4lybdeni4 acid, or contaminated with WO ) final products con-
taining 8-10- , 8-10- , 6-10- , and 1.5-10"3% respectively o? tungsten were obtaino~.
Card 2,14

27074
S/080/61/03,'t/003/016/017
Purification of molybdenum trioxide from... A057/AY29
The purification degree in relation to other impurities is shown in Table There
are 3 tables, 1 figure and 4 Soviet-bloc references.
SUMMED- May 27, 1960
11118 !1
'I k ,
B peurt

Table 1. Purification degree
coinall CUCCH

.) + W
X;iojjttpo
- ~

of molybdenum trioxide M a IIC-
0.) VIUPUA

)uritics,
from tungcten im
t
in experiments with 2 - 3 g
0 1.113
2
batches. Temperature 600
C,
Mo0j + I%IVOj + NnC1
1,19 45
11.Sl; _3 1
'.98
~
duration of the experiments 1.19 GO ".19).10-3 19 ti-,

I hr 5.90 3o
- 1.93. W-1 21-JA
. MoO3 + 50,1,,NVO3 + NuCt 5.W)
1 )
4 U.91 - Iii-A

Legend: (1) ocinposition of the
5.90
0)
0.91 Ili
1
2I.j3
mixture, (2) ratio V1/(1.1o + W) 28.80
f 31) _;1 -if) 0 1
(% in the initial mixture), M,)03 + 25%1V03 + NaCI 28-sO
l 1.01 10-3 11.-
(3) time of ohlorination (min), 28.W 1.1)1 It)- p"9
(11) ratio VV(Mo + W) in the
oxychloride (%), (5) extraction
of molybdenum in the oxychloride (%), (6) traces.
Card 3/4

S/828/62/000/0QU/Ul6/Ul7
EU71/El3j
AUTHUR6, Ze I ikwan, A. N. , Nis el I soil, L.A. ,
Gorovits, N.N., and Ivanova, Z.1-
TITLL; Separation of tungsten and molybdenum by utilising tile
difference in volatility of the.ir chlorides and
oxychiorides
SOURCE: Razdeleniyc blizkilth po svoystvan redkikh metAllov.
T,',czhvuz. konfer. po inetodam-razdel. blizkikh po svoyst.
red. metallov. '11.!oscow, 1-!etallurgizdat, 19U2, i0b-197,
TEXT: A method of separating tungsten from inolybdenut-ii, based
on evaporation of ~IOOOC12 on heating of molybdenum trichloride
with bodium chloride ~o a temijerature of 600-700 OC, WaO StUdiUd.
With contents of 0.01 to 0.16 and 1-035'1'~ IV in the starting
inolybdenum trioxide tile purified product contained less than
(6 to 9) x 10- and 1.5 x 1o-3,. 14 respectively. l t was established
that it is possible to separate tungsten and inolybdenuin by
rectification of' their Liiglier chlorides. WC1(, and MoCl-
(rectification column data: diameter 30 mm, height WO mmi,
1.5 sieve plates, with 115 holes of I win diameter).
Card 1/2

Separation of tungsten and molybdenum... S/828/62/UOO/000/016/017
E071/EI35
Frow, tungsten sexquichloride containing about 51,, VoC15, and from
i~;olybdcnum pentachlorice containing about 51,o WC16, purified
chlorides containing below 0.01',,, of admixture of molybdenurr, or
tungsten respectively with yields of the main fractions of
70-605"i were obtained.
There are 6 figures and 7 tables.
Card 2/2

~':"/OUCO/62/035/007/004/013
D267/i;307
L.N., Krcyn. O.Yc. , Nisel'son, L.A. and
va-, I o va
oZ tu-k,.,rs-Lea -,.oIy'bdc-,Ium by the rccti-
o-- zheir chlorides
-,~r;,-Iadnoy khimii, v. 35, no. 7, 1962,
67 - 47 2-1
-:'u" 1.0015 were obtai-,:~d fro-m -purc -metals by
distilled in a-l-L ar:~on atmo SpIrlere to separ-
5c,~ ,%,,ocl5 or vice
-L LL with abou;-
w:vc.. C) -ftcr I-fr,4c' ,:1016
LL
o-a ~-I -,Io-tc c lumn. it w,~s f und that the
vcrsa -!crc 0 -0
o-f -Chc -)ur'ified chloride is less than 0.015'/o, and
t*aat t'.1c y1cla 0- 'L:'.-.c ----cctifLicd chloride is 70-80%, of theoretical.
arc 3 tables.
X-
2-:., '--961
Card l/L

t 4
ADC'ErZION UR Am5ol2945 BWK M'PLOITrI ION UR/I
Abram Ifatmovich; y~na; SamsonS'VL_~rigoriy
Valentinovich
tire metals (Hstallurgiya radkikh metallov)2d ad., rev. and enl'.
etalllwU 0 f -4r
tillurglya, 64. -056P, p, illus., btblio. Textbook for-tech-
Va
1400cowr Z&
Dical schools of nott farrous twtallurU. Errmtm slip ineGrted. 4,185 copiec
printed.
_ysical
TOPIC TAGS: rare earth mat*l, trace metallurgical process,ph
tantallu, niobium~i!t
13 tungr
MetfAll',Lra, Metal _PF2pery fte a r0
1..Arconi=, d i L, thallIum, rhaniuz~ berylllun, lithitm
I rupd"I'VE AND GOWM(E., The,book offers.a. description of production processes of
the most important rexe metale, such as tungsten, moijlodenum', rherlitm, tantalua
and nlobiura, zirconium, titanim, rare-carth metals, galli=-, indium., thallium,
berylli jrlithiua. The discussion of ca h metal includes a dea-
UZ
cription of its physical and mechanical propertioa, applications, basic methods
of obtaining chemical compounds fron varloue typos of new material and the P__o_
diwtion technology of urs metqls.(!vThe book is int-onded en a textbook Cor
too cal schools and may- serve an an alld ror engineer- i
i students of metalltuwr c
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1=11ritnethattr
-7
00 type we lam rff"wv. 1
) Armnatic omimls. boving
kmg (mmid.) A& Chaim of nowevial -froclum and 0i h,w
0 C%uwn*, poolltivaill do not Impruw the onliax6limhut

of 14"Worthre 14 o"Athrmd. Isad vv"I fucrodw the Ittulow-T
of amphtheaft to oxidiss. (9) r1w Iwooducts tit owamm,
0 of 4mmtic byeleam am of be env of piollos i-a
COVAIMmallon Pndwcb wbkb we sam "vv as ow.
osidben and tkw rotard thwe promm W odelatim.
00 A. A. Itorbelitimil
00
00
00
00
0 0 0
0
00
00
00
00
00
00
00
so
00
so
00
00
00
00
0
00
0
0 0

A000 0 0 0 00 0 0 00 6 41 gTo 0A 0 6 0 w a - w
AAL L L J I L I m F 9 1 1 9 T F I I AA 14 w 11
'Ir
.-so
The exida" of We. N. 1. Cbernoibulkov and S. F. .00
,#W CACM. (U. S. s. R.) 8, 2.11 41M in
Krdg, 1. AV
so ir (19U) - Translation In Fmitim Poroleum
00 --'0. 12144(im); 2, 21-38. 3D410(19M. .00
A lubrimting oU consisting
L.A. 27. 61 j8; 20, 6211.
tit maphthgm and at kvm WWT, of arminatic bydrom- .00
lKims with paraft d& chains formts no ppt. on o%Watim ~4411
00 Me acid conlent iiscreamrst twmuse the side chains err
00 oftidised. Tbecourwoltheo"timisthesanwasintht .04
00 Z abscom cd meplitheames. In the presewt of 1c." than 10% -00
of aronatic hydrocubow with " chains the oxidatkm
00 W tk as" as that of purt, "PlItbrocs. fl a naphthene ~44
oil contains " much as 5% of hydic
lenated
b drombous. & ppi. Is lonmed (m ox, tkm. consistinS
00 '3 :fhydrww acids, aWlesitcom and carbews. At higher .00
V; mum. of hydrolenatIrd stormatic hydrocarbons, the lip. ~00
coutelam chkfiy hydrury acids. Arotmatir (arry suh-
staccem do not affect the oxidation: !wXifthenc-like far -00
00 accelcralts It. A rochilingk
6 WO!
f
00
A S 2L A&(f&LI.VP(,KAL LIT(IOL&I CLAWPICAIM"
0 # 9 AD 0
k too
9 if R U K U tt It N
s
se
e 0 0 0 0 0 0 0 0 0 9 0 0 0 IS 0 * 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0
e1; : 0, 0 0 0.0 0 o 0 o 0 0 o 0 0 0 0 0 0 0 0 0 g 0 0 0 4 0 4 a 0 4 0 0 0 0 0 0 0 0 0 0 0

::144
a
00
00 4F
I a it Ill IS IS 66 it If 11 W C M Is 4 If M s At `1I a 41 a *~o
'0 1' A' k__
0xidising naphthento In Ihv loafw# of 011694. some
VAUMf tWft"ll- %- L Chvi'lli"blikov
au4rl4 cool
K"Itu- Sc0pil AAk'swillirl'. as. No. W
1-.Kts For ga peirojefta TotA. 3. .1,77 144 IMS); 4.
a MlotKil he oxidation was carrirql out with a
paraffin od whh h .4. pfirligoillmlily littil of Sall Mmillds.
We ne-bilitenir-. the 1,4100111f; comixis. hirint othilill",
"1 11 i larforr the ollidmilion: III4Mul,- stild Iiii4lat. p1wisolit. il
midarbirdev. krtottv,. quils,"Wil. latly A-1- -01- f"o Ill-
ivii, hivirlmity achlo WPI - 11001 thip alikhord oill, rrv-
Its litfthirt. M-1.4111"I a% a tv.1111 14 oliddlion of vanou.
14"IT4, frMINKI. ploillivil . 14t, holo vol"I"IlAtillitle.
44 11W heavv 114141thAlloi clivill. CAI. little 14, lwtlmvl
, _(pjjj. ji.jo., Ioooo- mod liolimitlear iuufiil~ mild N.
q
hctrrvxi0r,. Ajid- u4. ill lwtr, ribri lifroloolt
oxidation, while the Art-1 of hydroxy avids Is Imil on 11 if
Al"fill. In 1.,flll li. and thirriforr they wilm he mirntwWril
A L A .641~ALLUNOKAL LITIMATURI CLAIWICATIGO
salatortli, ON. Ott

Ill. I'lit-liol. i I '111ill"ol, I I -pp, tt'int 44 alo
losticofigill(UP111-3
Affql't the atilitAointr ill Iliv -,it Ahhhldr-, Looors,
melds. hviinny a6d. nd j,h,t,,,l avid. lower their im.

bilitir, which is Ill true- In oruc ritt-fil for &h-,. Remn. .00
derliltij fruill Ilaphl 111,11. , Mod i-*I' f4 whru 2411101 to lost
' 800
VUlk-111%. have nit inlhwotc~ I
1l,- od hotild tvvivir 8

';*.CO. aind olti I Nallil malturtil, %incr ifir lattirf fr- 0
to.lv- ph.ool-. Sio.11 4%o1, 0 I'vy'-dAllot h,.Il.l 1. '*0
lotiroduird lot oil, 4 stability. II&Ws Mich
as 11) ri'llor, 'Jillolill"r &fail olher N hirler'..vch-i Pfrw"t Ili

11
,
1
low-ir art-itilvAlion frilos, 1,il shidair fiwiromiliviv
V
1
Whito
.
Ii.
Iit hil-ticallux -ill, AfolliAlk, 111"Itol. ill

owfill whIn.. The OF1114.1willf
Ant of -4 "Holi4
o
I
" .1 dirliell.1 ull file 41111. of ~ 1'revol to the'viotwi. .
=, .06
r
f
cluelltlY Indqvirtident of the tape ttf 8 nmllvf
The clipt 6life 4escrIlKA arol the rMlit, t&bl&lcd iod =9
A A. llorlithugh

tie 0
to 0
l

too
WF *-. i
- ree
!7A
W
T
V
lp u a AV 10 Al 1; IF I I F-it
A 41 two Rol* 149443$v
to a it
0 0 0 0 0 0 a 0 0 6 0 0
04
To :@*:::1** 9910 of 90 00 000 0 0 411106 00 1

lu L"'Y11p S. E.
"O.-cid-izability of 111ineral oils tv (Okislyayemost 1114ineralnykh Flasel"), by
N. I. Chernozhukov and S. E. Kreyn,, ONTI, Aznofteizdat (United Scientific
and TecImIcal Publishing Houses), Azerbaydahan Petroleum Publishing Office,,
1936
xi

P. was man ;;N_0
4-1-L-4-t-A k-AL-A.-t A,
"4,&..Ksm (vtow, Oft Cbm., IN? 3,71 *00
tout
7MDW: sl,~*-=
go#
srwgwwm
oxvw= at To a b do
dw y
-00
PWO obarA 15(r but rAt
Air > bv WdhfirY Am #A
uded pine
It is cot~d tbas It
owl
hy:mf7m
turpatim b" bso
god 1-6 (1). NO be und sa bodw
R. T.
**a
too
Wes
9*0
a**
NO&
000
wee
UTINATOM C&ASWCATON wee
IJ4- V
goo
44694a Hit dov
u A# 00 As a

1~9 0000 0 off fee 0 fee 0 to 0 6 0 6 too
0 a M It ff a is
W
0 1
S it 0 t-
10
-A- A AA
Cr u
ctv~tsj
.8.14M%
0 a
Oxidation W heptyllientese and deabytitonsplithAlvair
k
". Krelit.
In IM Ij uwsd AM, N. 1. Cher no'Thokuy and S. l
11
9(
h
0
F
1, 4
renc
in
J. AP SO 40. U. A. S. R.) 1
, 14
P
1V37).-Hc%vlt*n"jw (25 x.) of decishydron3ph.
l444)
thakne (40 g.) were atildistj by sit with a comt. stirring
-
l
ed into a ster
with a glan volffer in a glain beaker plaii
autorlavir. The ttmp, of tbrespis. varied within 78
and the Pressure of the air was kept "intit. t 10 aint. I in all
.U the expts. The oxidation was stapped by o,tAing thr
*
hC.%1J.ti"nj.1-1-
Sufaclave and its contents with it~. 7
ucts were analyred arid the data tainflated. The main
anti
i
h
1b
i
d
id
i
f h
f
t
enteric were ar
s
e ox
ucts o
t
at
on o
etity
pfo
lots, and time of detathydronaphthalene were acidi, 'Ot
*0 mainly Insiol. in pett. ether. deciabyriftinaplithaltnevii.
t
l
d
h
l
id
bl
f
id
d
-
ra
e rmls. o
neu
a
cons
era
pro
togenic ac
. an
p
ucti of an excessive oxidation (asphaltenc4, cart-toes and
cathoids). The temp., and to a it%-wr degfite the taine of
oxidation, affect the proce". by pfurnoting an o0l3tion of
410 the intermediary pradticts of oxidation to Ott, next -%tda-
tion stage (acids to 110 acids, 110 acids it)
acid% and tari to asphaltenri) withoia changing the
principal scheme of the autoxidatinn o( the sdopie oinilmili.
'00
Twenty-one Were". A. A. ll,.Iir-ny 91111

AS. tLA &ttAi.&LP4K&L WtRAT"f CLaIVIK&UGN
lie t

I
, .1
1 110-10
of I 1
I 1
0 o
rt
0
a I Is 9 Its a
0 0 0 0 0 0 4 0 0 0
0
0

0
0
9
s
0
: 0690 000 0 0 90 0 0 0 0 0
f
0 0 0!0
0
00060 0 of* 0 0 a 0 0 6 0 0

RMMEPM

A L I f. P JA At I C 14, It j If 43:rf

0
a
0111
r
t('k"llwhrA.w

it, ZOO
00
00 140
00
00 -00

"00
Woo:
~
10 0
-00
0
60 do.
'

3-1-11 400
0 IM t- for it 31.) '1 .4 5 1 '4o,
j
00000000000000000000004000 00000 000900000*00~

P I #111111131415tou 0 a to
"
A 4 -aLJ C, 1. L-1 I &--t
A-AA. Jg~,G

'60
X
00 2613. IMCIULNISH OF ACTION OF A14TI-CORROSUP. ADLITIVES.
-
'
*0 and Tarmanyan, G. S. (Kett. Khoz., 1947. (11), 45-50)
Acid
*
00 val-as cannot be taken as a guide to the corrosive action of oil*
on Cu-Pb alloy. Tests show that ol6ic and palmitio &aide are SO-
94
IV 1009 more aggressivio than naphthento soids of equal said valu*.
9 all! Oxidation tests of oil containing added naphtheni-a acid show that,
00 0 in absence of anti-oorrosive additive, attack on Cu-Pb is roughly
4~6 a proportional to acidity developed. Trials with various additives
*0 (sulphurized al2o, tributylphosphite, ana proprietary brands)
indicate that ti.eir effect is to raise threshold limit of acidity

0 to which oil can rise without serious attock on the metal. Sffoot

0
r of additive in not to inhibit oxidation of oil. but to form pro-

g tective layer on met-Al. such layer beinZ continually renweido,
Variations of additive effect with type of bass oil are due to
tendency for polar compounds present in the oil also to form a
film on the metal surface.

AIN-SLA SI TALL40*60CAL &ITIRATWE CLAIMPICAT300
11W
4o too. #0WOW
t
.4.
7
U 1," 10 As

0 -1-
V

'A
T I Wk L I a 1W 0 a 01 W 14 1 a 1 3 0 V
1:4
0 A 0
0 0 0 0
0 0 0 40 40 I'm
0 106 ~
0 a 00 0 0 0 0 0 do
6 0 a *
600060000000
Vo
100
"106
.00
see
:00
441
COO
Joe
$00
400
C9 0
goo
goo
lot

0 0 -- 0 0
a Ail.
1.0 r.014%
so
C 1 i PIN
to. I . I -, 5 4 ~
Z--
so V~~ lilt 6 ;k
, . - w
la
ivol I I t
so
00
so-
zMel
1.1;11 a
~Vlm 111
so -6
hill ~
so
14,
re. o' .0 .0
- ,
-tj
, Zz
zoo
?
~- I
Foe
I
goo
-4 k
I 46A A
goo
Use
SLI 011ALLUCLKAL kfTIl4TL*9 Its 0
7,11 'A k
so
fig

&-l- A.
-A I_ L -A.
'A I -**
2842. EFMT OF N-TE.'MM ADDITZ"M ON DIMMING FROF -,'R= OILS.
Wreta# So F. , U shtein R A. &W A19mandroy, A. Id. (Mort. Qws., 00
194 so .43
00
*0 -00
A test method has been develoW for measuring the detergertay
(dirrarolve power) of an oil by 41soormining the time required for the .00
041
settling from the oil of a weighted amount (0.4%) of toot of constatt
sesh. The toot Is accelerated by centrifuging and heating the oil.
00 A rermeatability of 10-15% is obtained. Tests on seven oils show "t
06" whilst the dispersIvIty of an Individual oil I# a function of the
004 v1sc., it varies for different oils (tested at the saae visa.) and
*0 that the toot particles do not follow S,,oksfe law. OLD contain natural
-Too
anti-coagulating agents, the" being *or* evident In residual all# 0
Mkom. then In distillates. An Increase In the deg"* of refining deagenges
th: dispersivity of an oil. Tests on additives indicated that mrtoo Woo
th nates (in 1% conen) were very effective in the case of the Co Peep 1,190
WO 0
and slightly in the caae of Fb Zu and Ba naphthanates had no effect,
-e-50181 0 1 , ~ , 1
Trials with nine proprietary additives showed that, vith the oils zate
umd, a Co-ba" product. (Santalubs _U0) -And a pr*duct bas*4 an 3 and
ka~ #,,-too
to.
ao, 4.9 $11111 C. IL,ai aw a., '6
ViZZ I I V
0 a 1 0 rw 0 00
U U AV 00 LS 0 of x a W0 "a ov I I"
OU no 0 4` 0 0 0 0 0 0 0 0 a Is 0 0 0 4P
0 tee,
00 : 0 010 0 0 0 * 0-0 0 0 0 0 1 * : : .30'~

a$
0:
0
00
P compounds of Za (Lubrisol 736) were the met effective. The efficacy
of additives dsoresood with Incroselag teal-rature. Susceptibility
of various olls differ& to such an ext4at that an additive my LWrea"
the dispersivity of one oil wMlst lowering that of another.
0
00
so
00
00
*9
00
00
00
00
00
04OMS

KP,M 9 S. F.
"Additives Improving the Quality of Oils" (Primadki, Uluchshayushchlye Eksnloatataic
Svoystva Mosel),--S. E. Kreyn and R. A. Upshteyn, Gostoptekhizdat, Moscow/Leningrad,
1949, 68 pages, 3 rubles 25 kopeks.
This %ndbook was compiled by the Office of Technical Information.
SO: Uspekhi Kb&ti, Vol 18,, #6, 1949; Vol 19, #1, 1950 (W-10083)

KREVI S. L. and BOROVAYA, M. S.
"Lubricating Oils for Automobile Engines, It pages 154-156 of the monograph,
"Investigation and Fae of Petroleum Products," edited by N. G. Puchkov, Gostoptekhizdat,
Moscow-Leningrad, 1950
Translation D 399729

s. F. N15
614 - 7
- r~5
Fhi-miyq Vin-ralIny](h Masel (TIrle Chemisti7 of Yineral GITs, by) ~N. 1.
Chemnozhukav, S. E. xrey-n (1) B, V, Losikor, YosPw, Gostoptelichizdat, 10,51.
307 p. Illus., Diagra.. Tables.
Bibliographical Footnotes.

it I-
1./13
73;5 . n 2 5
.Y9
1:0m, s
Sumochnoye manlo i dvigaWlI- (lubricating
oil and Lhe ci-Cine, by) S. E. Kroyn, Yu. S. Zaslavrkiy,
11. P. Voinov. Moskvap Gostoptekhizdat, -19-51-Y
198 P. dingrs.

"T . - I - ---B- . -.. ' 11.), "T"IfTY."ON- A. Ye.,
~~ 7Y',' `~ Yp. I BRO; . Z. (71MI . K- - t .... ,j
oils i1nd "'Atj - ArIl'J.'18is
7romrties of oils at low temperatures for the elt~ctric power industry. Mek.
stn. 23 No. P, 1952.
9. u'0-nth!X List, of Russian Acce!:sions, Librnry of Con,~-,ress, November -9521 UlCIL.

The CoznIttee cm Stalln Prizes (of the Councll or ministers mia) in ue fieida or
scienco!- rnd Inventimts announces that the follovIng calentIfIc vorks, rX.1pill.ar
A
t4fiC b4DOka, and textbooks have been subaLitted for empetition for SWID Prizes ror
the yearo 1052 wA 1953 - (Sovetakaya Kulturn, YQaccw, No. V-4o, 2~; Feb - 3 Apr 1954)
Nam
rl.
TItle of Work
0" ::L
RomiLated by
SO: W-30604, f july 1954

CHXRNOZMJKOV, Nikolay Ivanovich; KUTY Serafin Iffalmovich, LIVOVA, L.A.,
veduRhehly redaktor; POLOStit,- redaktor
[Oxidation of mineral oils] Okielianmoat' minerAllnykh manel. 3-c
Izd., perer. HOBkva. Goo. naxichno-tokhn.izd-vo neftinnoi i gorno-
toplivnoi lit-ry. 1955. 371 P. (MLRA 817)
(Oxidation) (Mineral oils)

USSR/Chemical Techn,-,Jc--.gy. Chomical Products and Their Application -- Treatment of'
natural gases and petroleum. Motor fueels. Lubricants,
1-13
Abst Journal: Referat Zhur - M31;miya, No 2, 1957P 5588
Author: Kreyn, S. E., Lipshteyn;, R. A.
Institution; None
Title; Procedure for Determination of the Oxidability of Oils in a Thin
Layer at High Temperature
OrJ.g:Lna1
Publication: Sb. Metody issledovaniya neftey i nefteproduktov. M., Gostoptekhiz-
dat, 1955., 174-183
Abstract: A laboratory method has been developed for determination of the ata-
bility of oil to oxidative condensation under conditions approximatirg
those that occur within the zone of the piston rings of internal com-
buBticn engines. A I gram sample of oil, in the form of a thin layer
(0.4 mm), in a flatftbattcm J' hermetically closed, aluminum dish, is
oxidized for 3 hours with a current of air (50 ml per minute), In
Card 1/2

USSR/Chemical Techn,,-I.ogy, Chemical Products and Their Application -- Treatment of
natural gases and petmleum. Motor fuels. Lubricants,
1-13
Abst Journalt Referat, Zhur - Khimiya, No 21 1957j 5588
Abstract: the residue thus obtained are determined: oil and neutral tarn, by-
droxy acids and asphaltenes,, carbenes and carboids. The apparatus
can be used for the analysis of volatile oxidation products and also
for the determination of the degree of oxidation on the basis of oxy-
gen absorption. By means of the method that has been worked out an
investigation was made of the stability to oxidative condensation of
MK oil from select Surakhanskaya petroleum, and also of naphthenes
(N) and aromatic bydrocarbons (AH) isolated from this oil on silica
gel. It is shown that on oxidation in bulk as well as on oxidation
in a thin layer the AH are considerably more stable than N,, and that
stability of the latter is greatly increased on addition to them of a
di.-finite amount of AH, The stability of AH is also greater than
that Qf the oil from which thV were isolated. On oxidation of N
there are formed only 4.6% of aspbaltenes and bydroxy acids, whereas
20% are formed on oxidation of AH. Rate of oxidation of the oil is
inversely proportional to the depth of its layer. By means of ex-
periments conducted in an atmosphere of nitrogen it is shown a thermal
Card 2/2 decomposition of oil does not take place at 2500,

;64
/
V
I

ltiim vf A.1ti-Cout, -ion

'Anit. i.tlii.; aftill lfwa-iok k
tnrtoldj~ itt, alt~ra~. W~-Otl.)
Kit-ir, 4itf, J,- N.

sut
f addLtif'", rA t,A~f,0.Ct"w S and 1'. R,
u-, of tho C,J,
v4lAmting film and
do".
ej if
O
ric'n
t
u"

Y t

4naftsUPWO 94 lU Xedwdtm of tho AdM of And.

OGrMdT# Additf"As 09s III ed ' III to
by R4 a vo in (a r1.10 Ya. a.
Z"1G-nkY-T1r-R-- I . ME=
t..Mmin, 414:1 nur-wz~-.
-
t

I
1054
7117M. 818-1821).-Jfn Aawidnj. A m!V
is dedclibed rar studying fln krmatim otyrj~tird
edr-
dm
iGw
tb
d
fi
j
an
,
a
e
n
l
flaromtfou of L protec-five- film on, the sutfoce, of the MeW.
Lwretw In temp. lacreamLL the mis of fomatiov. &rA demwacs
the anal thickneu, of tbA MITI. .,Then U a dewt3 M12-t"
-w8 -,,A 11 atollis into ths metal *W of meldi stozwln~ UIT
pmtective filLa. At lower temp. adsorptian Is Im-dominant,
fkthigitertcntp.cbew.intemetionI
in wacentnithm of the additive up to 11", in W, 1hr thiekatt'.1

tril, ww I,
or
e P-twdivil 6 in
v
4
A
A
W
Ib
L
A
'
'
n
JUL
~L
. C-

Subject
Card 1/1
Authors
Title
Periodical
Abstract
USSR/Chemistry
Pub. 78 - 14/25
Kreyn, S. E. and 0. S. Tarmanyan
AID P - 3826
Influence of sulphur compounds of various composition on
the tendency to corrode of mineral oils
Neft. khoz., v. 33, #11, 71-76;p N 1955
In tabular form, a list is given of sulphur compounds,
their characteristics and their varied corrosive
Influence on mineral motor oils as tested on lead-copper
alloy plates. Tables, charts.
Institution I. N. Tits and A. Ya. Levina, Moscow State University
Submitted No date

VINOGRADOT, G.T.; KUSAKOV, M.M.; BYZBORODKO, M.D.; FAVLOVSKAYA, H.T.;
ZEUIISKIYI V.D.; Kam? SON.; BOROVAYA, X.S.
Mbw
Wear-preventive properties of petroleum #Ile. XhInA takh.topl.
a9.1:61-3 of cover J& 056. (MLRA 9-7)
(Petroleum)

4_11

C~ 36U fir). wilh a rid wi I b;,at e,i, (%i, V,!. ,!"t,

W-4a:Ail JAI Ity

do lt,r-~,itj,w,
to ~;t~ tr_ d.,t.!-4-
na~,, very 216~s rjlly~ a-4
Om r-ji-!56, w, (AN
wk- a o,~~ a,

--------
-
-

Q4
20)
I
n c1p.-
.
typo EY-2,n, cl.nt'-lrllrz Zi
'rW). 251 0. 410, 90 a~ 150, min r-rd aftcrwarcL2 cyary hnt-- at,

C'
U-0. 170, 200, and 2ZI:P fc~r G h0ilra
Tho vo
U1
fil
l
0
m waa caL
culAtc-d fror. the at, rjoll
Ult;
14 M-'atr cd a lrU afur- - tr& - tw I~C(t p vq'e' - V-1 t~41 U 0 1 f"I Lvl~ nt U14
~=a on uie plat-,, n t r"C"
pl-mro dcUrWn~,d, ovary djW. , T%G rcraj ~jyj ty of Ula (,,Ltj-,od
10
g-P For clorl C I rcp dl
III= convilrl., I Y
Iwrt=vd-tr0 4 Wilul. cl--rMVrlstJc kr each rctt~l nrd Et4n levol-16d "fr:
Mch, an I=anza In onnxplyr I
WiVcraWce, tho rat-^ of rtlm ( ~cx c zz cd
T.-,c flatex. of tt--- M.:2 dmra.-.zod. krutlognua rcvjlts vv:n~ * 5 t;- I rc-A
wtvl tte r.111ptf;Mrcd olla. Aroly5L~ or va plaC3 S'!Y~WW ElLit th,;~'
(tcpch r4 Powiratfor. tor exh trotal rm~ dtroa~ly rqLtvtj E~2
ru4tfort Wro, mZ -6~rzentrarjon of Ura, Wditlyad Ixffluntion
wL" f7ento.,3r, (rboiit, 0.01 rzgjsq.cr. 140 -4L donp after U lictws rst with 15
-
B
C
-
In Cho rAl) for
locd trome. The tclncWu -'( (11D femclon vzx- 't1iia
04~P-c',' t1l rwzLxIng thrr rco'wictivity of tto eM, K:
,
ll~;
lllurcd bYjrald, cas t I ro r, P;~ stc-ol plr-t.~a (",xithlraliz- CtWut O.CV

~t, 110, 140, 170, 13S 2CO, cM 220'~ I'milln oc~rr Im Or
Oach 011 1703. 'e., I
ftmt daorca3cd mie ocTroalon tut pitcr mo p,;Irt coxr-o-4v.;.r4Inc tro Lt~ milrurl
gain In varterm of u7,0 Provotlyu rilm vv,3 ui~~ lowralty of tr-o
aomoalm irrreazrA ftrx! Uic WeIght, of Uic fl',z docrc-.~--d. Frvm f1r;a r-S:ar--,
it Is C~Cncla!cd that tho rXIMIptj. cfrc~t of U.C, cddlLlvas In Uc oliz
at the formtIen of a Ixot-cativo tilra an tho nct--l surfaoc. Te.,o carpeclnc-
prc-;~2cses accur rimlt~nccusly: (1) fjl_-2 fOr!-rLl,.-n rhe C6AElVe al-Xf
T-lict MCZ,11 -'-YJ Lho Ir"Casc In Vic CbWimnxi -if Lha flip. cautc-.1 ty
actaorptior; (2) oxidation of oil vhIch lei~~ to ui,2 f=-r~acl~,n of okAcL,,
pt4wla, ctc., w-,d V-;eIr ialts, Mifeli grWually destroy *.c pr6tc~~tfyc- f I lm.

KTJLAKOVA, R.V., kandidat tokhnicheskikh nauki S..1 .,.,-doktor
takhnichaskikh nauk.
Folar and neutral hydrocarbons of mineral oils. Yest.olektroprom-27
no.12:52-54 D 156* (MLRA 10:1)
1. Nauchno-isaledovatellakly institut Kabellnoy promyshlennosti.
Ministeretvo slaktropromyshlennosti.
(Hydrocarbons)

LOSIKOV,B.V.,prof,rvA;0ETN S.X.ftof.red; FUKS, G.I., kand.khim.neuk; red.;
LOSBYAKOVA, T..t-.,--v'sduehch1y redaktor; MUXHINA, B.A., tekhn.red.
[Improvement in the quality and the use of lubricants; a collection
of pRpers] Povy9hanie kacheetva I primenente smazochnykh materialov:
abornik dokladov. Moskva, Gos.nAuchno-tekhn.izd-vo neft.i gorno-
toplivnoi lit-ry, 1957. 364-0. (MIR.A 10:12)
1. Moskovskit dom nauchno-tekhnicheakoy propagandy imeni
F.E.Dzerzhinakogo.
(Lubrication and lubricants)

i,)~ 3.
yu. '13., 1,dlEylij XzROVA, 11. V. and SHOR, G. I.
"Radiochemical Iriventigation of thf., Actlcn of Oll AldLt!,;Cni," P. (6t5-
,In 1),,,,,)k Study and Us,--- of Petroleum, Prod ucts '*'Moscow, Gcsteptekhlzdat., 1957, 213nP.
This collection of articles givea the resul-LO of the scl. rej. work rf tllz~ Au 'Eci.
R,z!s. Inst. for the Procesaing of Petroleum aud GaG for the ['roduction of 3,
ki
Liquid.

1MYN. BOROVAYA, H.S.
.,
Influence of chemical and fractional composition of oils on their
visoosity-temperature characteristics. Xhim. i tekh. topl. i Manal
no,9tll-20 S-!57. NLRA, 10ill)
(Lubrication and lubricants) (Viscosity)

65-12-2/9
AUTHORS: Kreyn, S-E Mitrof anov, M. G. and Puchkov ii. G.
TITLE: On the Cho:Cce of Oils of an On timur. Chei.,.~ical Coi,-i,position
and Methods of Their Production (0 podbore ipasel optim-
allnogo khimicheskogo sostava i putyakh ikh proizvodstva)
PERIODICAL: Khimiya. i Tekbmologiya Topliva. _J M,'-_,sel,_195r/, No 1~)'
pp. 13 22 (USSR~.
ABSTRACT: The importance of group-chemical comrosition of
lubricating oils and not only their physico-cliemical constants,
for the evaluation of their perforLiance cl-caracteristics is
discussed and illustrated by some examples. On the basis of
the data cited it is concluded that the :production of oils of
better performance characteristics is possible with the exist-
ing production methods. It is pointed out that at present the
production of oils of low performance is caused by an incorrect
approach to the evaluation of oil quality. On choosing oils,
their quality is evaluated on the basis of their physico-
chemical indices and not their chemical composition and results
of tests on corresponding mechanisms in spite o -I the fact that
the former do not determine the behaviour of oils under operating
conditions. The most rational scheme for the investigation of
lubricating oils and the choice of their optimum composition
uardl/2can be as follows: 1) an investigation of group-chemical

65-12-2/9
On the Choice of Oils of an Optimum Chez,,ical Co_-position and Mu~thods
of Their Production.
composition.of the raw material and the determination of the
available naphthene-paraffinic and aromatic components;
2) an investigation of physico-chemical and operatin"DY, Imperties
of the individual structural-group fraction of hydrocarbons in
the pure state and mixed in various proportions under laborutory
conditions and on modelling equi-,.,ment of the n2jB type and
similar; 3) on the basis of the results obtained, the choice
of optimum compositions of the above fractions with and without
additives should be made; 4) testing of the chosen composition
of oils with and without additives on single-cylinder engines
and the introduction of the necessary correction in the compo-
sition, and 5) the production under industrial conditions of
experimental lots of oils of the chosen composition and their
testing on single-cylinder and full-scale enCines. There are
1 figure, 10 tables and 8 Slavic references.
AVAILABLE: Library of Uongress
Uard 2/2

Jill.
1
AUTHOR: Kulakova, R.V., Candidate of
Doctor of Technical Sciences,
110-12-4/1
Technical Scialces, Kreyn, E.
and Zhuravleva,
TITLE: An Investigation into the Decomposition of Oils, Individual
Groups of Hydrocarbons and their Mixtures in an Electric
Field. (I8sledovaniye razlozheniya masel, otdel nykh grupp
uglevodorodov I ikh smesey v elektriche8kom pole;
PERIODICAL: Vestnik Blektropromyshlennosti, 1957, Vol.28 No 12,
pp. 11 - 15 Nssi).
ABSTRACT: The reliable operation of oil-impregnated and oil-filled
cables is affected by the evolution of gas in the oil through
ionisation. The article describes work with a "gassing" cell
very similar to the old Pirelli cell; the inner electrode is
a tungsten rod 2 mm diameter; and the outer electrode is tin
foil on glass. Tests were made with atmospheres of air, hydrogen
and nitrogen; the results are given in Fig.2. Aitrogen gave
considerable gas evolution and air considerable absorption,
whilst hydrogen was more stable. Accordingly, a hydrogen atmos-
phere was used in the subsequent work. After aot~ieBalng the
Influence of experimental variables,a study was made of the
gassing properties of low and high viscosity oils from both
naphthenic and paraffinic crudes; the properties of the oils
Uardl/2 are given in Table 1. The more viscous oils did not evolve gas

110-12-4/19
An Investigation into the Decomposition of Oils, Individual Groups
of HydrocarbonB and their MixtUren Ln'an Electric Field. .
but the low-viscosity oils were much more active. The curves
given in Fig. 9 show how the degree of refinement of transformer
,oil influenceB the gas evolution. The results of gassing tests
on naphthenic paraffinic fractions completely de-asphalted and
freed of aromatics are given in Fig. 10; all were gas-evolving,
but again the heavier oils were more stable. The effect of
adding aromatic hydro-carbons in reducing the gas evolution of
the fraction is shown by the data in Fig. 7. The oils were also
analysed after exposure to ionisation, which was found to cause
somewhat greater complication of the molecules. Because fractions
from which the aromatics have been removed are more gas-evolving,
it is concluded that the aromatics prevent gas evolution;
further, that their addition reduces the tendency to gas-evolution.
On exposure to ionisation, the dielectric properties of almost
the oils berm? w The afe 10 figures, 2 tables and
lreferences 0 wgri'N'are Hav C.
fi
ASSOCIATION: NII raiS
SUBMITTED: December 20, 1956
AVAILABLE: Library of Congress
Card 212

ZASLAVSKIYt Y11,S,, kand. tekhn. nauk; MYN, S.S., doktor tokhn. nauk.
Radioactive Isotopes In the oil Industry. Priroda, 46 no.8:35-44 Ag
157. (KLRL 10:9)
1. Vaesoyuznyy nauchno-isoledovateltskly institut po pererabotke
nefti I gaza I poluchaniyu iskustyennogo shidkogo topliva, Moskva.
Oletroleum industry) (Radloisot6ex-Industrial applications)

V.,
T
~szcw' lt~-o AN 15~_. 2 f o
&tc~..y And Aka!t=1yana=k
X41toriLl Board cr 24t. V.I. Dlkmahln. Acad4ftIcaln (XsNP, Id. H.S.
awlmilovsic_y (B4'~ty hemp. rd.), ra. 3. zaslawskiy (Z~epqty R.8p.
Ed.), L K. Tatochemko. B.I. Vors=ovsb", S.T. XazLmv~ L.I. Pat.
and x.0: Ze levinakaya (Secretary).
Nd. or Publishing House; P.M. Belyaniz; Tech. Zd.s T.?. Folmovew
MMP=t This book is Intended for specimaiate in the field of a&-
cnine and Inst--wnt manufacture -ho use radioactive Isotopea in
the study of materials and processes.
C07EXA(Mi This collection or papers covers a very wide field of the
utilization or tracer methods In Industrial research and control
I cbnl
.a Qu*a- The topic of this vOlume-Is the use or radioisotopes
in the "chine-and in*%--uwnt-aanur&:turIn$ industry. The Lndl-
vidual papers discuss the apPliewtions, of radioisotope tothr-squam
In the study of vot" and alloys, problems or&lctlon and lubri-
cation, metal cutting, engllne perforasuce, and defects lit metal&
3everal Papers are devoted to the use of radioisotopes in the me;.-
;:tio,n,or industrial processes. recording and measuring devices,
all control. '101meters, level Sauges, safety d*vicoat redo-&.
o c
Ountfrs. Otc- These papers represent contributions or var-
I'll Scvl*t Institutes and laborm,*riva. TUNY were publlah*4 as
trans. on. .1 th -I!fnion Coftf*rwn':,-.cw% the V-- of aftoac-
tj 3t&bl. :~A t
"a and I op Ard Media lor. the National Sconow
d 3clenct, April, 4-12, 1957. W4 personalities 4" mant1mcmd.
farences A" C.-wen at the and of most of the Pape".
N%k1Zin_X.D. (Tsontrallnyy namich-Laalodavatol-skiy disol-ayy
u Dismal ROB44-ch Xnatitue). .]Wect or the Number of Me-
vo~utl.n- a. ..I- Cycle Pressure an the Wear of Upper Flatom
and Cylinder Sleeve In Diesels 43
tra1CtGrvj7 1AStitut-
rector Research Institute). Study or the Iff"t of Dust on the
Wear or Parts of Tractor Zrqa"s 47
a.I. Shor, and I.A. Ngrgzov& (VXXI po perers-
batka .6ttl I gaza lpol%ichenlym Isiegmstrennogi-aaldkogo toplIva-
ki-Onlon scientific Research institute for the Processing or ft.
tr.lvUU and Oas and the Production of Synthetic Liquid Tool).
R.du, tlon of the Low-temperature wear or ciiinaere-riston vmi%s in
IngInes by the Use of Oil A441tIves 52
_rrcTA' "a 0.1. 81ber
Z..1a'skly, Yu.s.,
(VVII po p*rorabotg Raza I poluchonlyu lalmestrennogs
shidkozo topliva - Ali-union scientific Research institute for
the Processing or petroleum and ass and the Production or symbeti.
Liquid Fuel). Study of the Mechanism or the Action or Antleoj"_
alve Oil Additives
rum&kow_A.X., 0.1. TLnogradov, JJL_aLrwKp)=&.
and AT__Ul 'yano-4 (Inatitut n*rtl AM 33SR - petroleum Ins%ltute'
Acs4#aY-tvf4k%1s^c*m, OWR). Study or the Mechanism or the lots,
action of Oil Additives wltk Metal* 6y
Bt-~Itx' TA.Ta. (T"soyusnY7 nauchno-loaledovatel'skly v
t ofl
tnotltut -Union Mining Research Institute). 2 udy the
a; All
War o arm In SIRIAS Rack4norr 73

"Effect of' the Chemical ':rmpocition, of
Frcpertie,."
Compooltlon and Prcpertles of the High Molecular Weight Fractlon of
Petroleum; Collection of Paperso Moscovp lzd-vo AN S8SH, 1958. 370pp. (Inta neftf)
2nd Collection of papers publ. by AU Conference, Jan 56, Moscow.
'17his paper Is a study of petroleum oils obtained from va~ous Ba',,.u crudes.
Components were separated by adsorption. The distillates were refined by sulfuric
acid and solvent pro~2esses. The effect of the composition ard the hydrozarbon.
structures on the quality of lubricatinU, oils was determLned for 2everal types of
oils. 'The role of' quantity and structure of' aromatici-,,
hydrocarbons, resins and sUfur compoundn, was -,tudLed In motur -1-11s as ri fa,.!~or
modifyhig the cliaracter of naphthenic-paraffinic hydro-carbano. The t~Te of thie
crude and the prupose of' the lubricating oil determine the refinin.,07 processeo and
their extent. 'rhere are 23 tables and 9 referen-,e.,i of -whLc-h are I!,c)-ilet and
4 Enirli-11.

I t I o n it ~, id Wea rs i s ta, ~ e i ~ 1, _ i~ e r: L e= L,11.
167
CoMaition and Propextion of the HiLt Moleculmr-Weidht Fmction of
Pe'trolcum; Collection of Papars, Moscow, Izd-vo AN S&SR, 1956. 370pp. (Inta nefti)
2na Collection of pmpera publ. by AU Conference, Jan 56, Moscow.
vilrious types ~_f DIPY OUS (naphthene-paraL'Ifin, fractions) 'were studied (_;n
friction-test machines in order to establisil their wear -re~; Istance properties
in relatLon to their chemical comuosition. Their wear-rez;L.,Aarl~.*e pmperties
depend on the rumunt of aromatic, fractions, (AF) whk~il are -,u1Nr 1)CRvLnt;, In rellitAn't"
to the 1111P (IT varlable vineost.ty and o;~Ldatluzi :;WbUlty. 17he oompo-
sif-I.cri of' olls and Ir.dividual fractions. deterudi,ei; their c,hara-terlloti~- behavicir
in relation to metals. These characterlotb,.,; vary t1hr,q;,.h(,)ijt. t.!~e crit,11-e
of productf; from d1.:i1J1.1ntes through ull.o to NPF artic-Au
11~ figures ,atA I taide. There are no references.

0
S91/81-59-16-58531
Translation from: Referativnyy zhumal. Khimiya, 1959, Nr 16, p 1a4 (ussR)
AUTHORS: Kreyn, S.E., Borovaya, M.S.
TITLE: The Effect of the Chemical Composition of Petroleum Lubrication Oils on
Their Properties
PERIODICALt V sb.j Sostav I svoystva vysokonolekul. chasti nefti. Moscow, All SSSR,
1958, PP 138-1166
ABSTRACT: Investigation results are presented concerning the chemical composition,
physical-chemical and operation properties (oxidation resistance, cor-
rosion activity) of the following substance3: distillates 't oils obtained
by selective and sulfuric acid purification from various types of petro-
leum; naphthene-paraffin fractions (NPF); aromatic hydrocarbons (AH) as
well as asphaltic-resinous substances (ARS) obtained by adsorption sepa-
ration of oils on silicagel. Besides that, NPF divided on activated coal
into hydrocarbons which are poor ( 11naphthene") and which are rich ("pa-
raffin") In hydrogen. The distillates of Baku oll differ essentially in
their properties. The purification changes shArply ti-.eir physical-che-
mical indices, but oils of medium viscosity obtained bY sylfuric acid and
Card 1/2 selective purification retain their individualily, D)e chemical composition

--(ri/81 - 59 - 16 - 58531
The Effect of the Chemical Composition of Petroleum Lubrication Oils on Their Properties
of the oils determines sufficientlyclearly their qualitative characteristics. The
composite NPF of various motor oils are very similar in their physical-chemical pro-
perties and chemical composition. The NPF of oils from Emba and sulfurous petroleum
differ somewhat in their properties and composition from the NPF of aaku oils. Com-
pared to the composite NPF in "naphthene" fractions the pour point decreases sharply,
the viscosity (,I) and the density (d) Increase, but in "paraffin" fractions the pour
point and the molecular weight increase sharply, but -1 , d and n20D decrease. AH,
depending on the depth of desorption from silicagel, differ significantly in the number
of aromatic rings and physical-chemical indices. The NPF have a lo-.-i antioxidation
stability, a high corrosivity, an inclination to varnish formation, unsatisfactory de-
tergent properties, and good viscosity-temperature characteristics. The character of
the raw material has no essential effect on the stability of NPF separated from medium-
and highly-viscous oils. AH are considerably more stable than NPF, and in the oxidation
in a thin layer are characterized by a lower varnish-forming ability. With an increase
in the number of rings in AH the acid number of the oxidized products decreases. Low-
cyclic AH in low concentrations do not practically decrease the oxidizability of NPF,
but polycyclic AH are strong antioxidants for NPF. Distillates strongly corrode Pb and
lead bronze.
D. Englin.
Card 2/2

SOV/65-53-9-23/14
'AUTHORS- and Makasheva, 0. P.
TITLE: The Resi tance of Petyoleum and Synthetic Oils to Air
Impact. ?TJ3toychivost neftyanylch i 3inteticheskilch
masel k vozdushnomu udaru).
PERIODICAL:
I iya Topliv i L~asel, 1058, 14r.S.
I
Khimiya i Tellnol f.-
pp. 9 - 15. ~TJ
LWW
ABSTRACT: The nature and mechanism of the phenomena during air
impact on the oil layer have not been investigated suffic-
iently. Aocording to some calculations the pressure in
the air pipe, when air is introduced under pressure of
200 atms,rgaches an order oil 1500 atms and a temperature
around 600"C. During the investig'"tions, the authors
found that the balls made of vlass wool and wetted with
oil melted under these conditions. Experiments on the
changes in the properties of oils durinp air impact
(chemical composition, structure etc.) were carried out
in a special apparatus. Two drops of the tested oil
were placed on clean asbestos fibres, situated on the
bottom of the apparatus and Icept under a pressure of 200 -
205 atms. The properties of the oils could be defined
Card 1/4 by taking into account the changes in the asbestos fibre

The liezjistance of Potroleum and ujl~- "o Air 1-11%0.0
which burned when the resist"tnee of the oil was too low.
Results varied accordinf-
~ to the type of oil used, and
accordinfr to its viscosity (Table 1). When oils LIT-22,
.0
?"S-210, IMIS-14 and the lubricatinF7 oil 13 wege tested,
(having a viscosity above 14-15 cps, at 100 C, and a flash-
point of above 2000C), practically no chan[-es were observed,
but oils '~-7tth a visco5ity of ~--PCU :.1 ten rature of
1000C, and a flashpoint o.-1' laG-20 061 (lubrrc.--,tin;- oil 6
and the machine o1i S'U) proved to be less resistant. Data
on the resistance to air impact of various structural
fractions of petroleum oils (Table 2),separated from oils
with v arying viscosibies by chromatot:raphic separation,
shownthat high viscosity oils, as well as the naphthenic-
paraffinic and aromatic fractions separ-.-ted therefrom,
are equally resistant to air im act. Lo*;,, viscosity oils
(turbire, transfomer oils etc3 and theIr separated
firactiono shcr., the same del-rce of instability t 0
air impact. The addition of anti-o:cidanto (parahydroxy-
diphenylamine, ionol, phenothiazine),or sor,-,e sulphur
co.mpouzids, (lid not af ~oct the unstable o113.
erf)erimentu were carried out on some synthetic pro(lucto
Card 2/4 (esteri bauerl on pentae
,j rythritol, tri-athanolanAna,

The Resistance of Petroleum -and 7nthatic Oils "0 Ai-97 I., -act
trimethylethane and diethyleneglycol) -and fr-10tiOn-3 Of
,5 fatty acids. Results of these estin~:j i;~ ons
0 irrv L
- a%oul L t 1,1
are t ated (Table 3), and show that esters of r1ei-latiol-
ao,
lnp_ _
amine and trim ethylethane ara unstable to air i C'.
Esters of diethylaneglycol (flash-ooint = 17000 showed
3.AtI317a~~tOrY reSl3tanf,-~~. When te a 4U-InC t-ie erL,--Fect of
polyrneric additives (polylsobut,, r1ene, polyinlathacrylates)
on thq viscosity-temporaturo properti~.~s, and on Vine reais't,-
ance o-10 the oils to air impact, it t,,ias -found that poly-
Mnt,,1.1CT7,rlatei had less efLlect than polyisobutylene, but
--ilien polymethacrylatf,~s ,-ioro arl,led the viocosit~ twilpavature
,, y
pvc..pertle!3 of the oils wera JIpro-,red, The same, coriipound3
wer~m teqLp,,,1 -as addi-I-Dres Cor pentaer-~hritol and diethylene-
U .7 k,
glycol. Mineral oils showed bettt~r viscosity-temPerature
propertles vthen sedimented ,*rith polymathacrylates. It
Card 3/4 v7a.3 -.cLoun,.l t',,iat 1u-7 concentraLlon of the polym:~ric

JOVI-5 -3-13-2 /14
The of PuLcoh--um anl 0jLjs to Air 1.-vict.
addJL4VeS did not af'i-~', tjie of ti.-le oils,
but at higher conco-itr4llon (up to Vh~.,
innrGa5es aliChtly. In the e xpa r 1:i-te ntal -:!or!r A. A.
Yemel?7anov.3. There are 4 Tablea.
1. Oils--'rest reultB 2. Compreswoo air--Chendeal effects
3. Pressure--Chemical effects
Card 4/4

rlvfls t irn tA F)rj W' 1" )to r 0 L I J a i;~ iLy at if 4of' I L:; u at! en.
at the ~-'if th :'etroleum
June 'ork.

15(5) PHASE I BOOK EXPLOITATION SOV12866
Kreyn, Solomon Efralmovich, and Revekka Viktorovna Kulakova
----------
Neftyanyye izolyatsionnyye masla (Petroleum Insulating Oils) Moscow,
Gosenergoizdat, 1959. l43 p. 6,ooo copies printed.
Ed.: B. V. Losikov; Tech. Ed.; N.'I. Borunov.
PURPOSE: This booklet is intended for engineers and technicians
engaged in the production and utilization of insulating oil.
COVERAGE: The booklet reviews the technology of insulating oil
production and presents a comprehensive analysis of different
types of insulating oil. Several methods of manufacturing
insulating oils with dielectric and antioxidative properties
are examined and discussed. Considerable attention is devoted
to insulating oils with a low solidification point, and to oils
used for impregnating and filling high-voltage cables. The ef-
fect of such additives as depressants and antioxidants, as well
as additives to prevent the oil from emitting gas, Is discussed.
The chemical composition of insulating oils is analyzed and
equipment used for production of insulating oil is shown. The

Petroleum Insulating Q11s
SOV/2866
authors thank Professor B. V. Losikov. There are 63 references:
47 Soviet, 13 English, and 3 German.
TABLE OF CONTENTS:
Ch. 1. Designation of Insulating Oils and Required Characteristics 7
1. Transformer oil
2. Oil for impregnating and filling high-voltage cables provided
with paper insulation 10
3. Capacitor oil .14
4. Oil for disconnecting switches of high-voltage lines 14
Ch. II. Chemical Composition of Mineral Insulating Oils 16
1. Naphthenic hydrocarbons 17
2. Aromatic hydrocarbons 20
3. Paraffin wax and other solid hydrocarbons 24
4. Unsaturated hydrocarbons 214k-
5. Components of oil which are not hydrocarbons 25
Card-2-/,
7_~

15(5) PHASE I BOOK EXPLOITATION sov/1948
Chernozhukov, Nikolay Ivanovich, Solomon Efraimovich.Kreyn. and
Boris Vitallyevioh Losikov . rl!~
Khimlya mineralinykh masel (Chemistry of Mineral Lubricating Oils)
2d ed., rev. Moscow, Gostoptekhizdat, 1959. 414 p. 4,000 copies
printed.
Exec. Ed.: L.A. L'vova; Tech. Ed.t A.S. Polosina.
PURPOSEt This book is intended for engineers and scientific person-
nel engaged in lubricating oil chemistry and technology.
COVERAGEt This is an enlarged and revised edition of the original
work of the same title published in 1951. It clarifies the basic
problems relating to the nature of lubricating oils, the changes
in lubricating oils under operating conditions, and the technology
involved under these conditions. It also contains much experi-
mental material on the chemical composition, inner structure,
solubility, viscosity, lubricating properties, resistance to
Caz~~~

Chemistry of Mineral Lubricating Oils SOV/1948
oxidation, scrubbings dispersing, and corrosive properties of
lubricating oils. No personalities are mentioned. Each chapter
is accompanied by references.
TABLE OF CONTENTS:
Preface to the Second Edition 3
Ch. 1. Chemical Composition of Lubricating Oil Fractions 5
1. Hydrocarbons of lubricating oil fractions 9
2. Sulfur compoimds 50
Asphaltic tar substances 56
Napthenic acids 3
5. Phenols 42
Ch. II. Physical Properties of Lubricating Oil Fractions 87
1. Physical state of lubricating oil components 87
2. Viscosity properties of lubricating oils 112
3. Lubricating properties of oils 141
4. Solubility of hydrocarbons of lubricating oils 157
Card 2/4--

If
0EYHr-134H.L GOLIDBYM, D.O.; AXIMOV, V.S.; TMrDOKIMOV, O.P.; ABRM40VICH,, S-Sh.
I
I
Additional means for increasing the output of high-quality
lubricating oils. Xhim.i takh.topl.i masel 4 no.2:4-10
F 159- (MIR& 12:2)
(Lubrication and lubricants)

KREYN, S.E.: ARTEMIYEVA, O.A.; MITROVAITOY. M.G.; MATITYWENKO, A.G.
Ways for improving the lubricating performance of residual oile.
Trudy GrozNII no.4:171-183 '59. (MIRA 12:9)
(Lubrication and lubricants)

5.1110,15-5000 T(542
so-V/65-60-2-2/15
AUTHORS: Are3Ln, S. E., Kalaytan, Ye. N., Stuplohin, Yu. V.
TITLE: Anasta3lyevsk Crude Oil ao za Raw Material for Produc-
tion of MK-8-Tjpe Lubricant.-.
PERIODICAL: Khimiya i tekhnologiya topliv I nia,!el, 19060, Nr 2,
pp 6-11 (USSR)
ABSTRACT: The sulfur- and paraffin-free crude oil from the
Anastaslyevsk deposit recently began to be used for the
production of transformer-, MVP-, spindle AU-, and some
other oils. The possiblIlty of it3 u3e for productLon
of MK-8-type lubricant was examined. Cl-Lide oils from
only a few deposits are thus far ii-.~ed for this purpooe,
since the solid point, otabill,ty, distIllatlon range,
viscosity, and density of the lubricant must meet very
strict specifications. The experiments, undertaken by
M. G. Mitrofanov, et al., in the Scientific Resear~:h
Institute of Groznyy (Groz. NII), falled to produce
Card 1/3 sat'isfactory MK-8 lubricant rrom Anastaslyevsk oils.

Anastn,31yevak Crude 01.1 as a Raw Matcl,tal (542
for Production of MK-.:8-Type Lubricants soli/65-60-2-2/15
The necessity of a high-degree purification was obvious.
-This was achieved in the Yaroslavl, and Gor'ki refin-
cries, and by the authors, after trial experiments in
which 6.4% to 50% H 2S0, solutions were used. The ex-
perimenta]. data revealed that the distillates purified
with 6 to 10% 112304 had density, aniline point, and
,viscosity not consistent with the specifications. The
diotillates purified with 50% H2S0jj had satisfactory den-
olty, aniline point, and viscosity; addition 'of 0.1% iono)
improved their antioxidation propertle3. However, light
fractions of MK-8 form Anastaslyevsk oil and those of
trade specimens evaporate easily, and the viscosity of
the residue increases at low-temperatures by 4 to 5
times. !If, instead of a distillate whose boiling point
ranges from 260 to 4400 C, one selects a distillate wrtth
45% of fractions boiling at 320-3700 C, the viscositY
of MK-8 Improves essentially (Table 5). The mK-8, com-
posed of a narrow rangre of fraction3 and tested in
plants, proved to be of much higher quality than commer-
cial MK-8 lubricant from crude ollo of Baku. There are
Card 2/3 5 tables; and 3 Soviet refevencez3.

-rADLE 5. PHy5tcoc"cmcnL Pp opkRric5 oF SOV/6 -1
EXPERlm~),Irfll- OIL SAMPLE ; COMP0.30-D EXPI;OMA141AL fAM~'LCS o f jUApjC,jNTS
or mPRRow RAW;C 0;: FiT ,
kCTIUMS 016rf Alms YAS '14,VSA CAvo r vjL
FROM I)N/)5rn5l YE-v5K cp ur)c OIL. .tolordrao, rVoll fll;lf-k" fit,tix-
I
rALL i f 10:4
-
Q"4q 1
6a r I
IA T MY
1

Jran BAR a
(Cos T) VYf 7. Q .
,
(So mi'le I Ar,0jf
VsrA1
con 'k I)
MX-j 0;/

SAMPLC 1. tISE,-jmTjC Viscasiry
im cFo ri S To KE T
Arso% c fi.3 5.1; 1
AT zo 'I'- C crqocvr 30,0 17.1
4r- q06 C befoxv, cv,j?pnriotj (;IXX)---71xg) 2 ViO 2, 101 1

AT
SOcC Arm E-VAPDR010N 18IM-211M
1.
:
38M W,
Sbinc 2. x1sn-mric V,,-cLllry
Argo-C DoviDfb ar pir
Kips,MATIc viscnsiry
Ar 2o*c &A r, o j ..!,7
SAmkc 3. 3rqiiA.,ry:
Pp&,co,*#rArc offrf*.f
nelt) Numjri~ AmA
. IN m,$. KOH Pf A / !p ou
I
"
mr -
t. FLAYMPO
SAmne
cmscl) cave'al.f. vc
-r ~"i 7- 0,:
SA11OLC S,
135

200c
PErisiry ar 55
PL 6' 7*
N, I r PO*#r
I- Aj
1. 8 85
0,885 1
,S,q in r 1. C , 79 6 IM 65,0
2!- 91,
- - 37.9
-, I Card 313

GOLIDBERG., D 0 KREYN S'.E.- AKIMOVY V.S.; ABRAIMOVICH, S. Sh.j YEVDOKIMOV, O.P.;
L'
FATkuLjh?~iik'~,`. '.~;LIVICIIEVA, M.A.
Relation between the
characteristics of
the depth of phenol
(Lubrication and lubricants-Testing)
(Petroleum-Refining)
physicochemical properties and performance
residual oils from sulfur-bearing crudes and
extraction. Trudy Bash NII NP no.3:69-81 160.
(MIRA 14:4)

S/081/61/000/021/074/094
AUTHORSt Kreyn, S.. E., Yevdokimov, 0 P.
TITLE., Oils of optimum group chemical composition
PERIODICALs Referativnyy zhurnal, Kh1m.1ya, no ?',, 1961, 405, abstract
21M112 (Tr, 3-y Vses. konforents1i po tronlyu i Iznosu v
mashinakh, AN SSSR, v. 3j !960, 316 - 565)
TEXT: On the basis of preliminary investigations which established the
dependence of working properties on hydrocarbon composition, lubricating
oils have been produced in commercial conditions from sulfur-free
Karashukhuro-Surakhany and Zhirncvskty crudes, and also from sulfurous
Tuymazy crude. Samples of these oils were tested on motor and model stands
(~JAMW(NAMI), n3B (PZV) etc), in two. cylinder diesel engine 24-8,5/1 1, and
also on a stand with an ALJ-82(~H(ASn--82FN' --ylinzipr Commercialtik-22
(MK-22), produced from selected Surakhany :rudes,r.C 22 (IIS-22), from the
Karachukhuro-Surakhany crude of the Groznyy ref inery and MC - 20 (MS-20),
from the sulfurous Tuymazy crude of the N,3voufimka refinery. were also
tested for comparison. The results of analysis of hydrocarbon composition
Card 112

3/081/61/000/021/074/094
Oils of optimum group chemical... B138/BiOl
are given, together with the qualitative characteristics of the oils under
test. Preliminary evaluation of the anti 'wear, detergent and anticorrosion
properties of the oila shows that those produced from sulfur-free crude
have better operational characterictics than MS 20 and are almost as good
as MK-22. The oil from the Tuymazy crude has higher detergent and anti-
corrosion properties. The superiority of the anti-wear, anti-corrosion
and detergent properties of the experimental oil is very apparent when
comparing oils produced from sulfur-free 6rudes Trials with additivesi
Commercial ILHATVM-339 (TsIATIM-359). MHLIVIfi-22w (IMANP-22k) and GHO~j Hn-360
(VNII NP-360)) show that the experimental oils have very good su3ceptibility
to this kind of additives, LAbstracteris noted-, Complete translation
Card 2/2

MIMI, S.F.; KALAYTAII, U.N.; STUPISHIN, Ye.V.
Anastaslevokaya petroleum irl a stock for producing the MZ-8 type
lubricating oils. KhAm.1 tekh.topl.i Maudl 5 no.2:6-11 F '60.
(M1RA 13:6)
(Petroleum--Analysis)
(Lubrication and lubricants)

S/065/60/000/011/003/009
E030/E412
AUTHORS- KEeyn.SE Kalayman. Ye.N,, Abraniovich, S.Sh.,
Gollberg. D.O., Stupishin, Yu.V, and Smirnova, N.T.
TITLE, Preparation of Low Pour Point Distillate Oils of Type
MK-6(MK-8) From Tuymazy Devonian Crudes
PERIODICAL: Khimiya i tekhnologiya topliv i masel. 1960, No~ll,
pp.11-14
TEXT: A method has been developed for obtaining high quality low
pour point distillate lubricating oilsAof type M-8 from Tuymazy
Devonian crude and from Balakhany, Dossor and Anastas'yevka crudes,
Previous methods for obtaining MC-8 (MS-8) and transformer oils
from sulphurous Tuytijazy Devonian crudes had used refining with
phenol, followed by MEK/toluene or acetone/toluene extraction of
paraffins, and by contacting with clay, they all failed on
oxidation stability. The present method takes a very narrow cut
(IBP and 7,12,28,32,47,54 and 645' boiling at 47785,120,205,225,300i
330 and 3500C respectively), refines with phenol, and extracts the
paraffins by chilling to -650C with a mixture of anmionia and
ethanol and uses no further contacting. Typical data for the
oil are; density 0.835 !L~111/cc; flash point (closed) 158%~
Card 1/2

S/065/60/000/011/003/009
E030/E412
Preparation of Low Pour Point Distillate Oils of Type t~'tX,-8 (M-8)
From Tuymazy Devonian Crudes
viscosity 6.5 centistokes at 500C, sulphur content 0,375'. it
satisfies specification rOCT 6547-33 (GOST 6547-33)x\with a pour
point of -550C~ Even higher qualities may be obtained by further
fractionation, putting the 305 to 3550C cut through a column with a
250 to 2530C base temperature and taking the 50 to 65% cut with a
viscosity of 5.9 to 6.3 centistokes at 501C. This oil is superior
both to MK-8 and transformer oil, with lower viscosity, smaller
viscosity-temperature slope from -20 to +500C and greater oxidation
stability on addition of 0.2% Ionol anti-oxidantNineeting
specification TIOC1981-85 (GOST 981- 5). If 0.7% Ionol is added,
exceptional high temperature oxidation stability is obtained,
giving only 0.1 gm KOH per gm of oil for oxidation at I-(00C,
There are 2 tables.
V/
Card 2/2

KREYV, S.E., red.; SANIN, P.I., red.; 14MIASTYRSKIY, V.11., red.; EXBOV,
red.; LUBA., Ye.S.# vedushchiy red.; TITSWA, B.F.,
vedushchiy red.1 POLOSDIi, A.S.p tekhn. red.
(Additives to oils and fuels; papers read at a scientific and
technical conference) Prinadki k maslam i toplivam; trudy nauchno-
tekhn. soveshchanlia. Pod red. S.E.Kreina i dr. Moskva, Goo.
nauchno-tekhn. izd-vo neft. i gorno-toplivnoi lit-ry, 1961. 394 p.
(MIRA 14: 11)
1. Voonoyuznoye nauchno-tokhnichookoye noveahchanlya po prisadkam
k maslam i toplivwnj 1960. 2. Institut neftekhimichaskogo sinteza
AN SM (for Sanin)- 3. Vsosoyuznyy nauchno-isoledovatellskiy in-
atitut po, pererabotke nofti i gaza i polucheniyu iskusstvennogo zhid-
ko o topliva (for Monutyrokiy).
tFuel-Additives) (Lubrication and lubricants---Additives)

H'11.4too
11-.9100
AUTHORSt Kreyn, S.E.,
----------
TITLE: Influence of
oxidation of
PERIODICAL: Neftekhimiya,
S/20 1 /001/005/007/008
E075/E484
Rubinshteyn, I.A., Popov^, Ye.A.
organic sulphur compounds on the
stability of lubricating oils
v.1, no.5, 1961, 683-69o
TEXT: The paper describes investigations into the oxidizability
of lubricating oil distillates from Tuymazy crude oil subjected to
different depths of phenol extraction. The oils contained-from
6.3 to 25.3% sulphur compounds and from 16.9 to 34% aromatic
hydrocarbons. The saturate content varied between 76.8 and-40-7%.
In addition a series of oils was studied containing from 4.2 to
11.2% of the same type of sulphur compounds. The oils with a low
sulphur content were prepared by oxidation with 30% H202 in acetic
acid for 3h at 700C, followed by silica gel separatien of the
oxidized sulphur compounds. The oxidation was studied by
obtaining oxygen absorption curves at 150, 170 and 2000C for 24,
12 and 6 hours respectively. After oxidation, the amounts of
strong (sulphonic) and 'weak acids were estimated by potentiometric
titration and sludge determined by filtration and weighing. it
Card 1/3

33589
S/204/61/001/005/007/008
Influence of organic sulphur ... E075/E484
was concluded from the results that the beat temperature of
oxidation was 1700C. At this temperature full oxidation took
place in 12 hours and good differentiation between different oils
was obtained. The results show that the oxidation stability of
the phenol extracted oils increases with the depth of extraction.
The oxidation of the oils containing different amounts of the same
type of sulphur compounds indicated that an optimum concentration
of the latter exists, which gives the greatest oxidation stability.
This concentration is approximately 0.4%. It is thought that the
sulphur compounds in general oxidize more readily then the
hydrocarbons and at low concentrations decompose peroxides. At
high concentrations, however, the sulphur compounds react directly
with oxygen and then the oxidation rate increases. The formatlon
of sulphonic acids takes place only when the sulphur content is
above about 0.4% and then increases linearly with the sulphur
content. The total acidity also increases linearly with the
sulphur content and its minimum value is reached at the sulphur
content of 0.4 to 0,5%. The amount of sludge forming on
oxidation is proportional to the square of the sulphur content in
Card 2/ 3

335P9
S/204/61/001/005/007/oo8
Influence of organic sulphur E075/E484
the oil, the proportionality constant characterizing the speed
of sludge formation. This agrees with the postulated bimolecular
reaction of sludge formation from sulphonic acids and aromatic
hydrocarbons. N.G.Kalantar and Ye.P.Soboleva are mentioned in
the paper in connection with their contributions in thi.5 field.
There are 6 figures, 2 tables and 11 references: 9 Soviet-bloc and
2 non-Soviet-bloc. The reference to an English language
publication reads as followsi Ref.2: G.H.Denison, P.C.Condit.
Ind. Engng. chem., v.37, no.11, 1945, 1103,
SUBMITTED: August 14, 1961
VK
Card 3/3

KILEYN, S.E.; CHFJCKOV~ Ya.B.
Sixth scientific session on the chentistry of sulfur organic com-
pounds of petroleum and petroleum products. Khim. i tekh. tQpl,
i masel. 6 no.10:70-71 0 161. (MIRA -14:11)
(Petroleum products)

ABRA)"1()VT(,'H, VIPYER, A.D.; GO1,'W3ERc,,, 1).G,. iUyt,, ' E.; KULINICHEVA,
L 1~
M.A.; FATFULL!NA, U.S.
.Inf Iienue of tho del) th of phenol purl f Ica ticn on the group chemical
COMPOZ!Jtjon and prr-pertles of v1scou:3 distillate o.."L from 2our crude.
Trudy Bash no.5.259-272 162.
(1,1TRA 17:10)

MU"y TI , S, . E. ; V I i` I 'Eft I A . 11. ;1 1". ~ J. ; Ai~ : .-~ ~', " i , ;,. , -, . zr,.
Inf J ucrr..,tt -of th-3 d(,pth ul' tho pher,c) 1 pul'i Ii ri of dl -~ tiIi Ilate and
residut-i'L components on tha working proyortioci of compounde-I oils from
sour rudy Bash 11;'14P '-
T I I . -0
(MIRA 17.10)

KREYN, S.E.;_KAIASIIIIIKCV, V.P.; SHLKHTEII, Yu.N.; YEVSTRATOVA, N.I.;
WLIBERG, A.L.
Production of clear sulfonate additives. Khim.i tekh.topl.i
masel 7 no.2tl9-24 F 162. (MIRA 15:1)
1. M4kovskiy zavod '"Neftegaz".
(Lubrication and lubricant3-Additives)

i.-Al q
1 -1
s/o65/62/000/012/oo4/005
E075/E135
AUTIMUS i Vipper, A.B., Kreyn, S.E. , 1jernshteyn, S.S. , and
Lisovskayal M.
TITLE: Investigation of the dispersing capacity of used oils
with detergent additives by the'oil spot method
PERIODICAL: Khimiya i tekhnologiya topliv i masel, no.12,.1962,
50-55
TEXT: The method of oil spots (spreading of used oil drops on
a filter paper) was used to rate the dispersant properties of oils
IAT -16 O-rr-16) from Novokuybyshev refinery, containing additive
V11-22Y, (111-22K).
Samples of the oils used in a single cylinder
diesel engine for 30 and 54 hours had the*same dispersive capacity
at 20 OC, but at 150 OC the oil used for 511 hours had markedly
inferior dispersive properties. oils mr-16 froin Novokuybyshev and
Yaroslav refineries containing 60,u of additive GPY1h 4t-36o (VNII
NF-36o) had different dispersiv Ities at 20 OC, but similar
dispersivities at 150 OC. The Novokuybyshev oil containing the
additive loses its dispersive properties with increasing temperature
Card 1/2

'Iing s/o65/62/000/012/004/Ooj
Investigation of the dimpers
E075/E135
wore rapidly than tile Yaroslav oil. It was established that
differences in the response of the base oils to the same additive
are largely due to resins which have strong dispersive activity at
room tenipe~ature, but lose it at 100-200 *C. The resins produced
in sulphurous Kuybyshev oil are the more efficient dispersants.
Also the disper.4ive capacity of the more polar resin fractions,
obtained by chrotnatography'on silica gel, is higher than that of
the less polar fractions. At temperatures above 100 OC the resins
lose their effectiveneds and the dispersive capacity of ti-te two
oils is mainly influenced by the additive. Thus the response of'
various base oils to detergent additives depends on the nature and
quantity of resins accumulating in the oils during engine operation.
There are 3 figures and I table.
Card 2/2

VINOGRADOVA, Irina Emestovna; KR9Yx,.,S.E., prof., doktor tekhn.
nauk, red.; KREYN, S,E.,, red.; EN VA, O.M., ved.
red.j VORONOVA, V.V.,, tekhas red. -
[Additives for lubricants to reduce friction and wear]Pk-
sadki k maslam dlia anishenlia treniia I iznosa. Moskva,
Gostoptekhisdatp 1963. 110 p. (MIRA 16:6)
(Lubrication and lubricants)

SHEKHTER, Tully Nnumovich; KIU-,YN,SQlomon Efrnimovich; KALASHNIKOV,
Viktor Petrovich; LEVINA, Te.S., red.; STAHOSTINA, L.D.,
tekhn. red.
[Oil-soluble sulfonatea; their production and uses] Maslo-
rastvorimye sullfonaty; proizvodstvo i primenenie. Moskva,
Gostoptekhizdat, 1963. 124 P. (MIRA 16:10)
(Mineral oils) (Sulfonation)

CHERNOZHU.KOV, N.I., doktor tekhn. nauk, prof., nauchnyy red.;
ZHERDEVAt L.G., red.; IVANOVA, L.V., red.; ISAGULYANTS, V.I.,
red. ; ISMAILOV 0 R. G. , red. ~gpj_ S. E. , red. ; KULIYEV, A. 11. ,
red.; MAMEDOV, M.A., red.; PAPOK, K.K., red.; SFFATOR, Sh.Sh.,
red.; FEDOTOVA. A.F., red.; SHKHIYAN, S.Kh., i7ed.; LEVINA,
Ye.S., ved. red.; POLOSINA, A.S., tekhn. red.
(Improvement of the quality and the production of lubricating
oils] Uluohshenie kachestva i sovershenstvovanie proizvodstva
smazochnykh masel; trudy. Moskva, Gostoptakhizdat, 1963. 255 p.
(MIRA 16-6)
1. Vaesoyuznoye soveshchaniye po uluchsheniyu kschestva bakin-
akikh smazochnykh masel i usovershenstvovaniyu tekhnologii ikh
proizvodstva, Baku, 1961.
(Lubrication and lubricants)

ZHEILOV, 'Voovolod Ilikulayevich; KICIIKDI, Grigoriy Ignatlyevich;
VIROLTYANTS, R.A., retsonzent; MAZITOVA, F.A., rotsenzent;
ORLOVA, Kh.Ya., retsenzent; YEVISHEMMA, O.M., ved. red.;
KFMNx S.E., prof.p doktor tekhn.nauk,red.; POLOSRIA,A.S.,
*"takhm-red i-
[Clu-omatograplW in the petroleum and retrochemical industries]
Khromatografiia v neftianoi i neftekhimichoskoi pror,-,fslilen-
nosti. Pod red. S.E.Kreina. MoAva, %Gjo.3toptekhizdrt, 1963.
287 p. (VIRA 17:1)
(Petroleum industry) (Petroleum chemicals)
(Chromatographic analysis)

y , V
819199MMs TE-0-9 PUCMV, N-G-, ZLqIAr=# TIV.3s
Invvetigation of motor oil perforname ad mothode of evaluation
Report to be w=lttod for the Sixth World ?*Uvlsm CcWess#
ftwM~mrt, 1646 hm 63

EPF(c)/BDS/W(m) AFFTC/APGC Pr-4 RMA1,41WWAIAXIN
ACCESSION NR: AP3001320 S/093-1,/63/005/000/0236/0243
AUTHOR: Kr~yn, S. E.; Rubinshteyn, 1. A.; Popoya, Ye. A.
qT1T1F,.:- Effect of orgarzoulfur compounds
%.n the o'xidizability of lubricating
oila (Fevort ~te s~lk~~c e'ntific Session on the Chemistry of
Orgarosluflur CpMpounds of at'-Lyfa,
June - 1 July 1961]
SOURCE: AIN SSSR. Bashkire-kiy filial. Khimiya seraorganicheskikh wyedineniy,
,soderzha3hchikbsya v neftyakh i refteproduktakh, v. 5, 1963, 236-243
TOPIC T"GS: lubricating oils, organosulfur compounds, oxidizability, Tuymazy,
oil distillates, phenol refining, oxidation products; sulfonic acids, carboVlic
acids, sediment formation
ABSTRACT: The oxidizability of lubricating oils con A
Ata~ning organow~lfur ccapoundg:
has been studied with oil-distillates from Tuymazy crude, phenol-refined to
various degrees and dwaxed) and with i;everal specially prepared specl-rens.
Card 1/2