SCIENTIFIC ABSTRACT KRUPA, J. - KRUPAUER, K.

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SCIENTIFIC ABSTRACT
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KRUPA, J. Studies an tlie physiology of germination of Bpores of FLmaria bygrometrioa (Sibtba) Acta soo botan Pol 33 no.ItI79-192 164 1. Department of Plant Physiology,, Highor Pedagogical School, Krakow. --1, 34913-66 AU; Nks AP6026595 SOMCE CODE: CZ/0034/66/000/002/0127/OIL28 AUTHOR., Krupa, Juraj (Engineer) ORG., VU11P, Bratislava TITLE: Calcium chloride as the best chemical aigent for insuring smooth supply of powdered substances during winter SOMICE: Hutnicke listy, no. 2, 1966, 127-128 TOPIC TAGS: steel industry, Iron, calcium chloride ABSTRACT: For cres with a water content of 4-5% 1 to 2 kg of CaC12 are required per ton of ore for temperatures up to - 15*C; below thig level 2 to 5 kg are needed. The chloride is added in the form of an anhydrous powler. Experience obtained in shipping iron ore with this additive in Poland, Yugoslavia and Rumania is described. It is important to prevent contact between the chloride and snow. Experience in Czechoslovakia during the winter of 1964/65 was very favorable. Orig. art. has: 1 table. (JPRS'- 34o7791 SUB CODE: ll~ C7, 05 SUBM DATE: none Card 1/1 77 KRUPA, Uh.~F., J, ; Te-.hnicka spolilyrace: UTPATA, rhe sourco of fat and the problem of thr- nmmint of fat necessary for fat emboll5m. Bratlsl, lek. listy 44 no.6;337-352 30 S 164. 1. Vyzki =.y nstav tratimatolorirky Prr.-, (v!llt#~! prof. M1.11jr. V. llrwak). KRUPA, Josef Sporadic cretinism in a 3-year-old girl. Geek.psychiat. 55 no.6: 397-402 D 159. 1. Detake odd. psychiatricke lecabny v Kromerizi. (CRETINISM case reporti) Jursj, ina. flydrophobic meterial-- -,xnd n ty V.,j Fail- roads. 77el dop tAih 12 nc.,.,.t3?-,3) KRUPA, Juraj, inz. ',#6v to ensure the continuous unloading of loose materials during winter. Zel dop tech 11 no.9t254-255 163. ,~. I- T' t% ,L . y (S, a . I-e:~orted in osko-~irzodkowe" nall-f-Ic.,! cutters)p by L. Krup f7drql,iarki wi Nm,--o 1,;3ooks (Nowe Kni2zki), No. 12, June 1~, 1956. KRUPA, Lucjan, dr 1nz, Influence of the tool feed and machining rate on the power of the engine of a longvall chain cutter. Przegl mach 23 no. 5:151 10 Mr 164. KOLEIIDDV.qKI, Jerzy, dr inz.; KRUPA, Luejan, mgr in Iz. Automation of coal cutters. Przagl gorn 19 no.ls25-35 Ja 163. UIT r ----U-~j-hemical 4ec lugY Chemical Products and Their Application. Treatment of hno Natural Gases and Petroleum. Motor Fuels. Wbricantol 1-13 Abst Journal: Referat Zhur Khimiya, No 19, 1956, 62588 Author: Krupa, Marianj Masiarczyk, Helenaj Palczevski, Jan Institution: None Title: DesulfurizgLtion of Petroleum Products Obtained from High Sulfur Content Petroleum Original Periodicals Odsiarczanie produktow naftotrych otrzymywanych z rop Wysokosiarkowych, -Nafta (Polska), 1956, 12, No 3, 72-76; Polish Abstract: Considered are the presently practiced in Poland procedures for desulfurization of petroleum products obtained from high sulfur content petroleum and also procedures recommended for adoption in practices catalytic desulfurization of gasoline vith the use of decolorizing clays or bauxite, extraction of mercaptanes with soda solution in the presence of methanol, etc. Card 1/1 The 2d Congres3 is approaching. P. 1. Indisoolubln friendship. p. 1 Vol F, no* 51. Dec. 1955s ROLNIK ~TOLD7,P-IJ;A. (k). 1."e share our experiencea. p. 2 Jo: .~Qntern Tbropenit Acmwlon. Vol 5., no. April 1-956 KRUPA, S. All should participate in the pre-ConlTess competition. p. 1. Vol. 9, no. 5, Jan. 1956. Tff)U.IIY SFOLT)7MCA. ',-,'arszawa, Poland. SOURCE: Fast Furopean Accessions List (I-EAL) Vol. 6, No. 14-Arril 1957 KRUPA Tadeunz The Conference of the Workman's Self goverrm-ent of the Choe.-Iez )rke decrood 'to modernize the plants. Prum mat budow 9 no.170 30 Ap 162. SOURCE CODE! CZ/oo53A5/011./OU4/(-YJ-"2/0322 AUTIJORi Zathureckyj L.;,Krupap Vj Rochovap M. ORGt Institute of Pharmacologyv CSAVO Bratislava (Famakologicky ustav CSAV) TITLE: Passage of cardenolides through the small intestine of rats in vitro LThis paper was presented during the Twelfth rharmacologic Days, Smolenice# 27 Jan 65-1 SOURCE: Ceskoolovenska fysiologie, v. 14, no. 4, 1965, 322 TOPIC TAGS: rat, digestive system, biologic metabolism, carbohydrate, processed plant productp biochemistry Study of convallatoxin and helvaticoside, revealed 'the presence 9r convallatoxol (C-10-aldehyde-reduced convallatoxin metabolite) and (i.e. de-rhamnose convallatoxin) in rat jejunal lumen in j/ .vitro 4 hours after immersion; 2 unidentified metabolites as wall intact convallatoxin were also present;'at the' same t'imi helveticoside, strophantidine and an unidentified metabolite were i6entified. The C-10 i(steroid ring) reduction is a key step in the metabolism of cardenolides. ;Quantitative analysis of breadown and speed of Intestinal transfer agree with .1the relatively poor. off get of peroral stropk4ntidine cardenolides. (jFRS1 SUB CODEt 06 / SUBM DATE: none jrn ZATIMPYLKY, L.; K1U'PA,V,.; PCP,!'C!VA,M.; J-7JB;7.,J. Stabilit7 of the fat in wool in the preserce of some anii- oxidants. Cesk. farm. 14 no.I.-2-8 Ja 165 1. Farmakologirky. us#,av Cesko,,i1,,)verskej akudemie ved, PracovJsko Bratislava. AID P 2620 Subjeot. USSR/Meteorology Card 1/1 Pub. 71-8 - 23/26 Author Krupa, V. A. Title On the exhibit of economic and cultural achievements of the USSR in Peking Periodical Met i gidr, 4, 60-61, Jl/Ag 1955 Abstract A detailed account of the 1954 exhibit which had an entire section devoted to hydrometeorology. Soviet specialists read reports on their latest technical achievements in order to acquaint Chinese visitors with the latest Soviet methods. Institution None Submitted No date E,~'~;'A p Wasyl, mg-r. 111Z. ' , I K'' !' NY, ;Cr I-,, Digital internitcnrz ind t1wIr ap,,,: 357-360 J116-1 KRUPAC1171, 1. F. 20122 KRUPACIIEV, 1. F. Koctinirovanniye ranenlya mdi i zhivota. V ab i Voprosy mAnoy khlrurgli T.P.M.., 19h9, a. 159-6h. SO: LETOPIS WIDUL STATET, Vol. 27, Moskva, 19h9. 0 __ __ - 'IT KRUPACHE'l-, -I.!. . --- "Sub-Diaphragmal Abseesses in Post-Traumata of the Thoracico-Abdominal Region," Kldrurgiya, 110.3, 1949 Evacuation Hospital T The Committee an Stalin Prizes (Of the Council of MinIgUrs UMB) In the fields of science and Inventions announces that the following scientific works, pcipular scien- tific books, and textbooks have bow submitted for camps Itlon for Stalin Prizes for the yea" 1952 and 1953. qm!!~m Kultump Rmcovp No. 22-40, 20 ftb - 3 Apr 1954) NUW title of Work Wainated by 1. F. V. 1'1;7FP1'N1f(0V' ].I. r,. Y.~Tj7~7KOVI V. A. SO: W-30604, 7 JulY 1954 "Llood Supply to the Corc'L;ral Cortex Under Normal ~md PatholoCical Conditions" of Kxrcrinental and Cancer Thorapy., Accide:v of llfe,lical Sciences V KRUPACIMY, IJ. [Arterial system of the human cerebellum) Arterialln4a sistems, mosshechka cholovskao Kookye., 1936o 21 po' (KLRA 10:5) (OMMMMM--BLOOD SUPPLY) USSR / Hunwn ~,nd iinim.-l florphology (Norm;,l :,nd PatLolooical). 5 Cerdiovascular S1,-otei... Abs ~bu'i 6f~ Zhur -'IJA~'16 ','o '21j 1'1"561 !-;o 97083 Author &a,-choVg IqF, Inst Not f,,I--,,en Title On Clpssificption of tho *~rterias of toc !Tuia-n Cerebellum. Orig Pub Vopr. ncyrokhirurpii, 1957, No. 6, 14-16 ;ibstr,-ct A clns21ficntion of cerobellor ,rtcries -nd Vicir brnnchas) bcsod on n topoFr-phr~rn:,toraic,-I principle, is citud. Their division into p,-rts nnd &.grents is piv(;n, rnd zonas of blood supply -ro point~--d out. Crrd 1/1 EXCERPTA WMICA Sec 8 Vol 12/8 Neuroloey Aug 59 3598. THE TOMOGRAPHY OF ARTERIES OF THE IONTO-CFHFHEI.LAH AN6LE (Russia. text) - K r u pa c h e v 1. F. - VOPH. NEIROMIR. 1957, The structure of the cerebellar arteries shows definite characteristics arcording to age. such that in adults. as distinct from children.the re is observed a greater tortuosity of the vessels in the shape of arcs and loops formed by the stems of the cerebellar arteries in the various parts of the cerebellum. Where there is a strong development of the anterior inferior cerebellar artery and a high origin of the posterior Inferior cerebellar artery, the stems of the two arteries form extens- ive area tytng within the limits of the ponto-cerebellar angle. The wide arc tra- versing the antero-infortor surface of the pons, the middle cerebellar peduncle. the flocculus, the biventral lobule and the tonsil, In very often formed by the anterior inferior artery and less frequently by the posterior inferior artery. Usually one arterial stem in distributed to the antero-inferior surface of the Pons, but two may be found; in the latter case, the stems of the anterior inferior and posterior Infer- lor arteries, or the stems of the anterior interior and medial inferior cerebellar arteries, are men, frequently distributed to the area mentioned. In the region of the middle cerebellar peduncle the stems of the cerebellar arteries are distributed in the same order an on the antero-inforior surface of the pons. In the region of theanterlor quadrate lobule (on its anterior surface) a strongly developed external branch of the superior cerebellar artery can most frequently be observed. more rarely (in 20% of cases) the stem of the anterior inferior cerebellar artery. some- times together with a strongly developed branch of the superior cerebellar artery. In the region of the flocculus one arterial stem In most commonly met with. Where two arterial stems are distributed within the boundaries of the flocculus, they most frequently belong to the anterior Interior and posterior interior and less commoni to the anterior Inferior and medial Inferior cerebellar arteries. The topography or the arteries lying in the region of the flocculus in similar to that of the arteriesdis- tributed to the inferior surface of the pons and middle cerebellar peduncle. In either region. two arterial stems are seen more frequently on the right (in 24% of cases) than on the left (in 12%). This to explained by the fact that the posterior Inferior cerebellar artery (where it has a high origin) and the middle inferior cerebellar artery -rise Iron, the baollar artery more Irequently on the right I M n on the left -In the pontocerebellar angle Itself, the vascular formations are more marked on- thp right than on the left, In the re Ion o( the tonsil of sith#r aide, one art,rl.-st filem I- -nf "__-1.k Al.-IL..A. Y ~ . - L~_ - -, . . The structure of the cerebellar arteries snows uetinite characteristics according to age, such that In adults. as distinct from chiidren,there in observed a greater tortuosity of the vessels In the shape of arcs and loops formed by the stems of the cerebellac arteries in the various parti; of the cerebellum. Where 1here is a strong development of the anterior inferior cerebellar artery and a high origin of the posterior inferior cerebellar artery, the stems of the two arteries form extens- ive arcs lying within the limits of the ponto-cerebellar angle. The wide arc tra- versing the antero-Inferior surface of the pons. the middle cerebellar peduncle, the flocculus, the biventral lobule and the tonsil, Is very often formed by the anterior inferior artery and less frequently by the posterior inferior artery. Usually one arterial stem is distributed to the antero-inferior surface of the pons, but two may be found; in the latter case, the stems or the anterior Inferior and posterior infer- ior arteries, or the stems of the anterior interior and medial inferior cerebellar arteries. are most frequently distributed to the area mentioned. In the region of the middle cerebellar peduncle the stems of the cerebellar arteries are distributed in the same order as on the antero-Infertor surface of the pons. In the region of the anterior quadrate lobule (onits anterior surface) a strongly devtlolied external bran(h of the superior cerebellar artery can most frequently be observed, more rarely (in 20% of cases) the stem of the anterior inferior cerebellar artery, some- times together with a strongly developed branch of the superior cerebellar artery. In the region of the flocculus one arterial stem is most commonly met with. Where two arterial stems are distributed within the boundaries of the flocculus. they most frequently belong to the anterior Inferior and posterior Inferior and less commonly to the anterior inferior and medial inferior cerebellar arteries. The topography of the arteries lying In the region of the flocculus in similar to that orthe arteriesdis- tributed to the inferior surface of the pons and middle cerebellar peduncle. In either region, two arterial stems are seen more frequently on the right (in 24% of cases) than on the left (in 12%). This is explained by the fact that the posterior inferior cerebellar artery (where it has a high origin) and the middle inferior cerebellar artery arise from the basilar artery more frequently on the right than on the left. In the pontocerebellar angle itself. the vascular formations are more marked on the right than on the left. In the region of the tonsil of either side. one arterial stem is most commonly distributed, rarely two. Where there is one arterial stem. it usually belongs to the posterior inferior, and only rarely to the ante:"or Inferior cerebellar artery. Where both arterial stems are present, they belong o the two arteries mentioned. The stem of the posterior inferior cerebellar arter.1 quite often fdrms a very well de"loped are or scroll lying on the internal surface of the tonsil. A loopofthe descending portion of thestemofthe posterior Inferior cerebellar artery, a~'Ising from the vertebral artery. is distributed to the medulla oblongata. The distribution of the loop of the artery mentioned to the region co' the Postero- lateral parts of the medulla oblongata and Inferior cerebellar peduncle is observed on the left in 88% of Cases and on the right in 78%. The stem of the posterior Infer- tor cerebellar artery In distributed in consequence of a high origin (from the basil- ar artery) more externally to the medulla oblongata, on the left in 10% of cases and on the right in 15%, in 216 of cases on the left and In 5% on the right this artery is missing. The variability of the development and position of the cerebellar arterial stems, and their anatomical relationships with the roots of the craniocerebral nerves create a complicated topography in the area of the pontocerebellar angle. The author in of the opinion that it in essential to deliTnit 4 arterial zones, which should be characterized as danger zones where large arterial stems are concen- trated. Theme are the zones of the pons, of the middle cerebellar peduncle, of the flocculue and of the tonsil. Darbinyan - Moscow (VUl, 14, 18) 7 VFbTALA, J. Qcraping instend of grind jq in cemented gear Oicels. p. 10,- (Strolirenska Vyroba. Praha. in . Vol. 5, no. 9, Apr. 1957.1 SO: Monthly List of Fast European Accessions (17:"-:AL) IC.0 Vcl no. 7, July 19157. Uncle 14-41 -4 ;-y I ,,- " I I, o i"i"; p-aov; i'A 1 P. Va:. I a ,,,:, I - -/ IJ PrsUT' pfirius for gour bc.xes and trttniminal~n,3. -,lyr 12. 164. 1. Vy,,~--ximy raifl,-iych motoru, I r 1,4111~~;;.`-~~, dil- -- ----m I i IMUPAR, 301~ 0, J -: Laboratory tests with hard metal bits, p, 412 Vol. 11 No. 7 BANYASZATI LAPOK. Budapest, h1ungary. July 1956. SOURCEt East European List, (EEAL) Library of Congress Vol. 6, No. 1 January 1956. KA-UPA-Ro Z. *Research Institutes in the report on the Gottwald Five-Year Plan." (p. 110). STAVIVO (Vinlaterstvo atavebnich b3not) Praha, Vol 32, No 4, Mar. 1954. 80t last Eiwopean Accessions Listj Vol 3v No 8, Aug 1954 KRUFAR, Z. - --- --- -- --- - ---- - ---- -- -- - - "Our research organization in the Gottwald Five-Tear Plan." (p. 146). STAVIVO (Miniateretvo stavebDich hmot) Praha, Vol 32, Vo 4, Yar. 1954. SOt East European Accessions List, Vol 4, No 8, Aug 1954 KFUIPAROVA, M. Changes in the biological value of sweetened condensed milk during beating. Cook. byg. 10 no.3:264-266 My 165. 1. Uotav hygiony, Praha. A a a OL A 004 -04 ApOlodies of 69 mollsoml-al sooolOomi lift 441! Qll!i7 OOA 1111141 'kipof mull Im so" 000 own P. PI, K-,I too opmem of ift memir 0*8 comm. W Uwe --"OWN# mmimmitid. "lo. of %be stimmok) eft be dout by dw 00 I==* _0 76 ja 1 go P"Al 4 4. Ito, firiii-ililrb sk- &Pm Is- .1 the cdm*6*m 16 jkvsm of The 0"kv malm of I-pb- ovA wWh Ism tho time -vakw a tWW 14 Its parsaw"'S so 16 ""ll 011*044 off WW do the a" campommu + oviark). (4vl.*W lbe ftd sad &d pwtri sof Ow lisew-ti~1 rsootte 44% 1* sq,(Nfh)o MW NANO# "b- 4044. 0"1 Uv Owdy pmwtr" POWA."I. lly wool saw dwd. waltv Wm goril lor lr=* T -ratamor pumse wt" o - am" & Swamew aboof. the vdws stitalmod to lbr nmpw to 1 .4 via Pb(NV6)./NmNO# npm- W =14 1". X&SOA =41, 3111,111). OW/4". W)/3D a" fm)/Im The ~M-Jwq a" IMmObse ond the busubm lulds TW, f-ups .4 Its. ;4 a: *td, lly thrrnuw No Itoo, (21, woo - A A - jw "#Sao& via, (HsO 413, NaNth 42~0, V%INO,.A. In_x t 00 0 Al of "Wilm. AoWthW CWV," wl.%)mwbodrtd, 40*0 "Woouim live I I I .. amdufft"; 'Wh vtows of a *We Porto. The ld 'he nosirl. joy WsJ"j lists MWIlical of Was *Pomi" to 1. 1140411 Post I WIMS tbo $v vwoft of tomistd. spins.) b a salartkally the kmithke arnke of fles, so tf*471 =W" roplelly wkb der"aw In dml ~ coms- = =by she equadw r - - 1.4fur + WA2 ir"i at wamod. mWiss. VM aw r - - Ming I T I. wheft r k thr-Wt. O"motap dt 6#0 th t lop mummamid, ff flor wt. pfft"fagr at "A Tin vutmb. 'M 4m. am too amalm'd ll~ living lh~ rts"form (11.91 al-a ilmlog with dnTrams 10 tba vot7ft"MOM Wt W*. IvAl in a "ortaid"aw small" d"Ir" thook IVAW 41 A. NaWk 4 1. 1. F%( (z is 17.4 wt. % I ddhi olitilittv olo* OW momid. ad"O. TIN poWe ad M4~nwdw botwom km the compm. of thme ruictew won.. wbm dvtd. Sommusert. rks*y hosts tbe Mmuctirm a# the Use this "or. 04111 t "- 2 Pwtl "As Iw fe-q 4,td, CIRI'v"'COM I do" oW euvrd I wt two "f"vemm. :61111 #d t%C IUWIIxw Is a.;%& 11411ALLIAGICAL 1.11140110" CLASIOUT111111 4484" .40 d.1 40# Imalm. at.- OF 9 'r 0 00,00 0 - - - - - - - - - - - - ft firf, I A-W*-j-j.j A A 0--a-A -- Saw .00 "now Nor. it OW OW tm 1"0161 at W. a rAd do" OWY. 0( 140-ft k Nobel M mdom tbataillsois -00 M 11A ;a 1w 2; ftimpowl", is k .#4p *A mom b" 10 brim,, bra 400 have as GOA hwus 4( do v"w. aft. PWML- Tam Or aud do, ipw 1w 'go =40 bamsewAsw 0.1 On am. am. nmwwl 1w 0m- 004 is dwA 4M In tenes of kup.. vi Im im-prat. At (60404 41A =18 mw~W' - Awds M a aw Soso* 09 W .See m*.&a3vbww h Z=t*- b"s d3*1. tWb 1-0 ifi. goo mw ce 1w 10006 all goo Idth do mmy, Im OW th" PWd916 406 dA ~ 4d b4wwctka of aw woo As rW4 :1 f". ,:. a 3w. 34. 400 0" Isom Mm- amwakwu Use td dw d*4[mw do ummy wo* tu P" of 80 St 40, =j, 11j% ie. k IbWW to Obt !ft A,.)Mo--Rg IF Alf-%L& ACLVNWa Lf""Tow WOMAN 00 so= map W, am 681601 mow 6116 ii-a .0 All V -4 As a; it & :1 9 9 0 SLO 0 1 so so* 0:9*10**Ow 000 "Application of tho Zection "othod to Deternining the E(:utlibria In Throo-Ilembor Oystvmi In thair Solid Phases". Zhur. ob3hch. Mira. 10, No. 22, 1-91140. Laboratory or Inorganic Chemistry, Lolotov State University, Liolotov. iiieceived 13 Juno 1940. Report, U-1612, 3 Jin. 1952. 4~W x - r ...- . ~ ~ 1. - - I - . 1'. cuvv'j~q' 1!%timmin Ternary SySteM3 with closed stratification isoth--!rms. Zhur. ob. khLm. lo. 2, 1952. 9. Monthl List of Russian Accessions, Library of Congress, Au~u-t. Uncl. YR'UPATKT',T, 1. L. "Ternary Systems with Closed Layering Isotherms" (p. 184) SO: Journal of Gen.-rnl Chemis (Zhurnnl Obshchqi Khimil) 1922, Vol. 22, Not KRUPATKIN, I.L. Tornary systone with closed Ljyor'ng isoV.arna. Zhur. Obshc:i;ty Kiir. 2-2, 184-lio; J.Gan.Caem. U.S.S.R. 22, 2"9-j5 052 (CA It? no.191971;3 '53) cv~ ~ ~ e, - - .1 .11 -;'1 Mi'lzt I :"; : - - - - , . '. -, -. T,- : f -- NOW" ,,-1 41' -(lh '-'I- I ,I R, . 7 ', 4.- 1 !fp i,,- ~ ~' "'. , - - . I jr, ~l 1 ~'fh !~ 'y _ 11 .- j - ,!, I I I . . -. - I 1 .1, 1 KRUPATKIN. I. L. Study of Motastable FAluilibria of Liquid Phases I# Page 151, Sbornik statey po obahchey khimii (Collection of Papers on General Chemistry), Vol 1,, Moscow- Leningrad., 1953o pages 762-766 Chair of Chemistry, Cherkasek State Pedagogical Institute KRUEATKIN. I. L. and LESHCHINSKIY, E. F. On Mutual Transitions of Stratification Zones, Page 244, Sbornik statey po obahchey khimii (Collection of Papers on General Chemistry), Vol 1, Moscow- Leningred, 1933, pages 762-766 Chair of Chemistry, Cherkasek State Pedagogical Institute 1;1 "11 1, lit ?~lvl bA r., t (.n vi C. A ir-V ~H f41 i~ t"r % , 1~ i CA '5:m. 7(,, t1i 7 Ti i ANIO,.01,I) lo 1 7: .% ~ v. c e 4 i th iv ~ ~ . -i c ` M a ii ir. I r nw- acul 'iCf t1l;'k ii A1110,11YO-111:0, unot an dt Tin: .93 simn j, iiclilir tu L!" ,va"m Th- Al nr~ owd.f, r.i:.!y ti~rmpqmfinz fl~ dk~. Aid,my 11. Al.,Ln'N.-c St,.Yly of Ketaqthble Xqii1libria between Lilpitl kiiatims. ir, j~sAf-,e 1221. Sbornik Statey po O'bahchey khtmit (Collection of kapers on General Chemistry), Vol 11, Moscow-Leningrad, 1953, pages 16811-1686. Cherkasok State PedagaSlcal Inst t KPLPATKI.N, 1. L. Relative Positions of Stratification Isotherms, page 771, Sbornik statey po obshchey khimii (Collection of Papers on -.general O'emistry), Vol II, Moscow-Leningrad, 1953, Pages 1680-1686. Cherkasak State Pedagogical In3t Phases. .2,4mr. ok~chi Kkiii-117- I(A*__I 103( MIA-Ax an ex-lirlOt of a ttrnzry My-Atem iu which only one (.1"lPorltnt it"llwinA in ' 111c Ullid Ihase the slsttm (1~4-siaph- l thyLatuille (11) Was invvit1gittil. 1,111. 2 ililkiii,in LIT1.1r), I systrAns 4 thii tes-oary wvre drid. 1 11 is A ~hjqde titt,clw willi 83%. 1 at 42 . In thr tAiLtry .9v,trits S It the cly!Ltil. Cum colli,ktt of j tuNvii': J S zit Ithl, j1d A R-J-0 S 4 1 j A fW.LctACAl1Y #ooruwatill Vtwla 1,16-01 GO - 1 - - 103'. The lativAr ir fircrtly slix,ire th, "'"' 1141C piilit. 100.5' willi 70.W"70 S. of the bin-1 d cul" of ("l.jurAc sow. Tbe teirlary oly'ltIrl wal I,Y (J 41 1,Lmrs pxsoinig thtjugh tht S %Age M tht pli,li, Awl ck,,ir,g tile 1-11 Wnatlf At W, W, 40, 64), 70, and 11. All pAy. ther"ll cnnsi5t of a UlfitilAWA.1% ClyStll. CUrVe "Vtr a biw,dil CLUVe %ith Ok WCJI-dCf11lf1I CEMSUIU(C ix,ml. A pUnc r:., 1 ~; 1i g thIOUgh, the 9'-O$OftllC 1-iFiti GI All OlC p1l)OWIMI , Uttlil~g thV C1.Ylltn-(tlrVC!i Llit(CtlY AWIVC :093ILiN (J 2,41in,,t 1),4 r ~d 1~ I *CtLryts with slight dips: at 961' *ith 46% 11 in ij,c, CtUrve and a shallower dip, at 1011, itt thc cry~tu~ ur, ISollitrIng tht(A1111 thf. pf~,aj at 8r., 1.0. 9,% 1(1), al,,l "nisisl *1 1% fainfly lif .1L.,lILr (livir'l w(licatiog ti-xi, S -1~ . in the liquid phaw with t rivil. jrjt~j of I; I. _%t tl,1,* l!j, Max. W,ly.uf 45riol Sio~.1111~ in 1161'.0 vVilli " at 951 S; th,- the wily in tia lndi4luA hqui,13 ol 4,;' j , .. . , ~ $44, (A "id S in the v"al-irltd liquiii% is j ,, ,0 p,,j ' 1 , i. I I with 30 11%4 j,nj~jt ~ !j~t - %o In th(,~ Ji%tljvkjll,iI liqtlj,jq~ , actcris I Ic Of this tt-flwy Systfits is a bil".141 Merfaire pvq4rg froni thr t,ir,.Iy S I to thzt .f ~,j 11 Couti.111JOUS CryStil. bUjft,r it: tile Utille try,ilil~ CKS1 and JL-3-4vinx lit tfr-lj?, i1ove tl~l R 'f This cAlia-t fully t-e t%pL,jn,,1 by ?,koda 's th". y fl. Metislin anI V~~v, C-4 . 46. MAch) an,i mqjvt4s tLe rti,l, ~4 I- Krucatkin. J. Gen. Chern. U.S.,SVI-u , ~65551 CA. $0, (31W. P. M. R. ~x N USS~/Physical Chemistry Thermodynamics. Thermo:1-emfg! 'ri. Equilibrium. Physicochemical Analysis. Fraei, TrargitionsY B-8 Abet Journalt Referat Zhur - Xhimiya, No 19, 1956, 61OLI Authori Krupatkin, 1. L. Institution: None Title: Investigation of Unstable Equilibr.~a Be!,w"n L-Iqutd Phases. IV, Original PeriodIcalt Zh. obshch. kh1mii, IR'55, 25, So 9, i640--1645 Abstract: Studied were equilibria :in the sysr.-~m plcrl: ac-d (I)-salicylic acid (II)-,Mter (III). Binary syAtems: 'I) There was found a region of stable equilibrium between AqLid phases with an upper critical point; (2) 1-1-I11. There was fnu.)l a region of unstable equilibrium between liquid phases with an upper critical point over which is an almost horiznntal p-.Irt!~,n cf the crystallization curve; (3) T-II. The system is hrmogenef~.a in stable and unstable state. Tn the system was P,.>und a pllcratt cf molecular composition 1. .6 (21.64% picri: acid) stabie In t,hm lflqlj~l phase. The investi- gation was carried out by the pclythirmal im~th~)dj on the basis of Card 112 USSA/Physical Chemistry - Thermodynamics. Thermochtmistry. Equilibrium. Physicochemical Analysis. Phase Transitions, B-8 Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 61o4i Abstract: the obtained poly-thermo4ere plotted isotherms for 65, 68, 70, 80 and 900 the projections T)f which are reproduced on the composition triangle of the ternary system. At temperatures of 700, 800 and 900 stratification isotherms are diaposel In the form of 2 sepa- rate binodal curves. At 68-50 these carves are touching and at lower temp8ratures they merge to form a singular synclinal edge extending along the straight line Joining the ar-.x of water and the pole of composition of picratt (1:6). C-.:;mwun1 cation III, see Referat Zhur Khimiya, 1955, 11288. Card 2/2 p 7 with )a 0 Clem Cal compoun w -Nzig "t the m tcmaiy k tilt I wo 1. s~ii y -p4tmi o. in I'm f, B',~ mg 5t.-m -AV. 11"'vn)i 'AU64 ba 'A,1-11 451.1111d (1) , W00- J1111.1.0 (ur; ' rl'~Vtol . 1,4U"1~ -heb) lamhu, - i III) ; I" I forlwAl (IV) Ifato. wAlwfo'.1 .34". lm", 111110 Are 'At,% It tAk' tf.~ ('117M fif ' (4) ak t1TA'1,f,1 till, Ca". Witt, J.'au'r Oct-'al1-1 (IV", "r ~t ~Ihd 11b On '). 41~~ I.-C-ti uf iAuL.Itty of it'. Itord (.m~ '-'is f ti" I'lao), %)~t-l plit"Ift _1114tion 4 vvy 41- tal p"'It" , a Ow *..thermi. 'I he 'l'.' 1~jt"'Jj' ~)'IC""l tq 'Al 0"! cm~' ~ Arwqltl I'l.-s v, AAJ'km.~j Ily jll~jf-4 1~t 111-14111.1 Wll!-IM tj~,' J,j"4$)f -777~- ---------- IRUPATKIN, I.L. Application of TaY.Alskmesyle rule to ternary systems. Zhur. ob.khim. 25 no.M2023-2028 0 055. (MM 9:4) l.Charkasokly gosudarstyannyy pedagogichaskiy institut. (Pha" rule AZA -6�~MIVHUA) 4A;, KRUFATKIN, I.L. Kethad of two solvents. Zhur.ob.khlm.25 no.12:2lA9-2198 N 055. (Klak 9t4) loCharkavokly gosudaretyannyy podagogicheskiy inatitut. (Solvonts) (Phase rule wA equilibrium) 'N 7~-l 7 -1 1 T_ ; ~ !V -I L- USSR/Physical Chemistry Thermodynamics. Thermochemistry. Equilibrium. Physicochamical Analygig. FUse Tmnsitions, B-8 Abet Journal: Referat Zbur - Kbimiya, No 19, 1956. 61019 Author: Krupatkin I. Institution: None Title: On the Rule of Reverse Similarity Original I .. Periodicals Zh. obahch.!*!,~;ii, 1955, 25, Wo 13, 2420.420,6 Abstract: For the equilibrium of 2 liquid phases the! authr.;r proposes a rule of "reverse similarity": Wn the c-ncent.ration- triangle of a ternary system with an equilibrium betwe-Aon 2 liquid phases we draw a straight line parallel to the side ot the binary predominant system (this term is used to denote that binary system in which the interaction predominates over the interaction in the 2 other binary systems), approximately at the m-411le of the diagre , limited by-the solubillty curves this _q~ CIIX~Ocentratf,,-~n lire will divide the loothe-rm of stratification Int": rtranchmn wkO.ch qualitatively will Card 1/2 USSH/Physical Chemistry - Thermodynamics. Thermochemistry. Equilibrium . Physicochemdcal Analysis. Phase Transitions, B-8 Abet Journal: Referat Zhur - Xhimiya, No 19, 1956, 61019 Abstract: be similar to each other but vill be reverse in their curvature and disposition of their gevmetrical elp-ments. The regions of applicability of this rule are showi. Card 2/2 USSR/Statistical Physics Thermodynamics. D-3 Abs Jour Referat Zhur - Fizlka, Ito 5, 1957, 11421 Author Inst Title Determination of Critical Points of Solubility. Orig Pub Nauk. zap. Cherkaelk. derzh. ped. in-t, 1956, 8, 65-68 Abstract An analysis is given of the existing methods, and a new method Is proposed for exact determination of the coor- dinates of the critical point of solubility on the equi- librium curve betveen the liquid phases. Card 1/1 4?11. '.4 Category: US8R / Physical Chemiatr3 Thermodynamics. Thermoch4tistry. Equilibrium. Physico- chemical analysia..Phase :*,ransitions. B-8 Abs Jour: Referat Zhur-Khimiya, No 1, 1957, 29923 Author Krupatkin I. L. Inst n3t-a-lv-en Title Theory of Stratification of Liquids Orig Pub: Zh. neorgan. Ithimli, 1956, 1, No 6, 1M0-1222 Abstract: Investigation of linear zate of stratification in binary system phenol - vater (I), sulfur - alphs-naphthylamine, sulfur - beta- naphthylamine, sulfur - diphenylamine and sulfur - qu1nolinep de- pendin on composition o: the initial solution and the degree of supercooling. Linear rate of stratification and also the rate of. phase-layer separation Lre maximm in the case of compositions corres- ponding to the critical point, and are min'-- in the case of compo- gitions at the edges of the binodal curwe. Kinetics of stratification of (I) has been studled by the microphotographic method. It was Card 1/2 _W_ Category: USS / Physical Chemistry Thermodynamics. Thermochemistry. Equilibrium. Physico- chemical analysis. Phase transitions. Abe Jour; Referat Zhur-Xhijzdys, No 9, 1957, 29923 B-8 found possible to distinguish 3 stages of the process: a) formation of latent stratification state; b) for7ntion of two liquid phases and proya tion f the stratification front throughout the entire cr= 0 system; e-layer separation. A qualitative picture is pro- posed of the stratification mechanism, vhich explains a number of specific features of this process. Card 2/2 The devEl"I'llwnt of b6inogencowi miary ' - - ~ J j .A ,t; 111,1 y fit. (- -rjq J!, ttr i) .1 , ' Dw vhl-f ll -61~ r - t, i-f sl.ti tw5cd ill wiij,im ::,-t; thr X-111 it liw 4 ill 111,~ witcr --w A at Oli 06, 11-i~ it V-4 jlf,~vd 6~tt lb, XAVO ckiio its 't 'We ,10crud to 1~(.- ill ILL ~,mx %f--ar, cfvilo. [Ili . fv-riismud p,irti-,:i (:so-70',~ AiW). Pp.- . cto I sccti,w, J ill'! ft~ril.kry S) stk,14 pri'm vvcrr~ttl thr alra-1 ~ I plli,r "rim, 1"'re r~l ll,lisilol, lbe mi. (1:1vt dr-livit t1lt;iktljtt tile Ituall. ,( J.'IyOwmist exililkit,; 't J-i~lt 1hilectioll IN-11'.11 i'low'd 11~ t6olgill'a (,,~61ilinlt hr Itiple crit. IN,ill~ A, IA.7' ;. X. ro 0,1-~ Jl!(,) m M."jell coill, id'i with the p'-It s4 111`t~ il,jbf7T;1 11 4~[:.p,jq -Its Ox 01.111gill.ir irt-.Ikvql~ for at', ,f,f 1": LU!!. it) tk A - l'-1 I Mill ofllt!r m) 11''Its tr~%~ ; art; tLe f~-T;11,11 I n ( ~l C,1111,1. ot iii a plix (ill thii CA ~ X.1) Its thc prc-iilitle tii:,arv .s) tv,o; thr fivnir, d -f lhi- cvtitj,,!. its the '-'rd lintinit : -tj!,l I IT;- p. ~ -cr!( r i I ojic- , f t~,- ~tc bju.iry q~ irl a r,tafe (.I -int ip:. w ;)11.1 - Fvn", IV B-8 r J ~ "~ Equilibria- iermOchemistry* Transiticns. Lynamics - Tt aly.j.. ?hase USSR/Ther=1 Fhysjc,,l.ChemicR1 M go 6, 1957, 18521 _kbs jour Ftererat Zhur . Khtmil ~aljcylic I.T., Kr-upa~t-~- ibril- in r-yramidon Author of Phase ?*"' Title Acid - Vater SYGtem' 1956, 26, No 41 105(),1c,62 Zh. obohch- i~himlil orig pub )yramidon (1) - salie ylic th, system I compounds 01 Uilibrium in Me studied. Two Abstrar.-C The el..) . water (111) ~ A, P, 970) and 3with the acid (me] were found in the system the 'composition I : I W (decOmP- 63~ Of 11) and two mr.ltinj6 point &t '9jtjon point, (93-50) 51-0 Of 11 one trans av W ) I ic pointo (8100 10 of II? nd . 111, on In the sYst'e'n 1e discove- ellt'-Y't were fWInd' i. ' '1,,er Corl7c3ponaingly) , two critical W '-'Of .111) and ,n .rve th .3 paratiOn c' (680, 50 a rlctasLable lower Tpoint In the zone of the re'll one (1690) 60~ of upper card 1/2 ""MINN Physical. C?r1nochezU Ab .a jour Cbeaac 6try ROferat Zhur . al Anal;8,10, Phase a. MIJUYU ~' So K Nnsit, 0118. orystall, Is ae zatlon 18527 COMPlIsh curve III the system ecl. at 7Oe5O th logou. T - rr set)4r4ti e Monutect, th zone oil e corapo I thro Xxr, th Burra I eq, I j9h ces (SC.) -Pottnd 1Uncl 0 vhIch th ere IS betu, 01111 b,1 4W 9 detec r the Ob are fl composit, ' Beet,, een th Xed phi'lle ted I -, )n em an hor b1nary nature. 0 n fhO 11 on 1 Of the 40 lystem the SS guld ph 'passes. Pri a,, of (.138 50.* 16% XXr butt,,, 4se a?)d 7hia con, tL'at ' Of an U ea I r the g ng"'nst th c , a hYdro composlito Zq% of Per ternar ef c section 11 - 4 e author er Woo d, Y crltl,,, Of the ny Ca Aph4a, vh of the p.-I ScOvered- Point Ma Ich 18 am Of th j it Is Mi fig 1 8 es zes that th Of bytir e e OMPO 8l- 13 S.Ya to Judge ab e sepa OPhoble und Of the tefts. Ot4t the str4tlOn nature, 7bL rue tur S t UdI es Card e of comp dt in sfor. -2C8 IRUPATKIN, I.L., Study of metastable equilibriums among liquid phases;. Part 5o thurvobokhime 26 noe711811-1837 JI 056. (XIRA 9tlO) 1. Cherkasekly gowAm-styannyy pedagogichoskiy Institut. (Phase rule anA equdlibrium) (Diphanylazine) (C40inoline) KRUPAT1119 I I Investigation of unstable equillbria between liquid phases. Zhur.ob.khtm. 26 no.12;324c)-3246 D 56. (KLRA 10:7)' 1. Cherkasekiy goeudermtvemiyy pedagogicheakiy institut. (Phas* rule and equilibrium) 'iJ Avg, I- T r a It fl KRUPATKIN, I.L. 0 -di W lamination In two-component chemical systems. Zhur. ob. khIm. 27 no.3r %1-566 Mr 157. NLRA 10W 1. Cherkasskly go"aretvennyy pedagogichaskiy Institut. (Systems (Chemistry)) -,4- Usk ,__.KRUPATKIN W.4wffl- -- I - ~i k W-k~, ~- " Using the method of two solvents for studying Interactions In liquid systems. Zhur. ob, khIm. 27 no,3:567-573 Kr '57. (KIRA 10W 1. Cherka ly gosudarstvannyy pmedagogicheekly institut. (Syst::kI (Chemistry)) (Antipyrins) (Benzoic &a1d) KRUPATKIN, I.L. Investigation of Irrational systems by means of two solvents. Zhur.ob.khim. 27 no-511113-1118 MY '57. (KLRA 10:8) l.Charkasekiy gosudarstvennyy pedagogichaskiy institut. (Systems (Chemistry)) jWTHOM Krupatkinj I, L,, and Todorov) If A$ 7 ?-1 L-2/56 TITU; An Investigation of the States of Equilibrium i3etweert 11ia~;eq in the System Pyramidon-Diethylamine-~';ater (Issledovaniye fa7rvy;-h ravnave- viy v sisteme piranidon-dietilamin-voda). PM-IODICAL4. Zhurnal Obshchey Khimii, 1957, 'Jol. 27, ,'r 11, pp. 2916-2921 (USSR), ABSTRACT: The properties of homogenization of the compounds forming In system are hardly investigated, although they may be of practical importance in the selection of mixed solvents. It was not th#; sj-;ter, pyramidon- salicylic acidoaatur as In the proceding inveatjgati(,A wjjjCh was tao kon herop but the now systom pyramidon-diethy3ju1iM*&aLor,, whero tho presenca of the discociated compound couLl be determinuti in the pres vailing system pyramidonidiethylamlne~ This compound and the two doubs lo 3ystems separating in layers permit the assumption that two indis vidual domains of the separation of layers i-xint in the ',-riple system selected. The double system pyramidon-diethylamirc was irr;esti&ated with regard to fusibility. An incongrijently reltir;C conpolind was deo termined in this system. The aystem pyrwildon-dietLylamine-water was investigated regarding the separation of layers and the furibility. The diagram of the state of the triple eystem indicates two indiviu Card 1/2 dual surfaces of the separation of layers, with lower critical point3. An Investigation of the States of Lquilibriwn iutwcor, flia3es in ti;e 79-li-2/516 Oystem Pvramidon-lilethylamine4later. This kind of equilibriun between the liquid phaies; depend3 on the strongly homogenized qualities of the conpound of the prevailing double system which are cannect W- with the dt-3soclation in the third componentj water,, The contact nection (kaianiye) and the point of contact for low critical tempturaWres wcre found at the nurf-ace of the separation of layurn on the dollble syoterri. There are Is figures, 1 ta~)le, and () Slavic references. AZSOCLtTION: Cherkaaay State Pedagogical Institute (Wicrkasskiy j;osu(1arstvenr1Yy SUBMITTEW. November 17, 1956. AVAILABLE; Library of CongreBs. 1. Pyramidon-Diethylamine-dater system-Phase studies 2. Chemical equilibrium-Anp-lysis Card 2,2 t ~%'i 'k-i"'.70"P T AUTHORM LrRILkin, '1.L., Todorov, I.A. 153 58-1-4/29 TITM The Kinetics of the Sopamtion Into Layers of Liquids in Systems With Maxinsa Critioal Points (Kinstiks, rasslairnl-va, zhidkostey v sistanakh a verkhn4-4 kriticheskimi. tocul-4 PERIODICA14 Izvestiya vysshikh uohobnykh z&veasni4;,Khim1ya i khimiohesk&Ya tekhnologiya, 1958, Nr 1, pp. 2D-27 (USSR) ABSTRAM On the strength of kinetic and miorephotogmphioal investigations of the decay of liqaid solutions and of the study of the equi- libr-ium of liquid phases one of the authors (Ref 1,2) already at an earlier date worked out a theory of the meohan' m of the sepa- ration into layers of liquids. This theory provides for three stages of separation. In order to extend the applicability of this theory the authors investigated the kinetics of the separa- tion Into layers of liquids in the system n-nitraphanol - water with stable separation into layers. It was shown that the laws and rules governing kinetics confirm the correctness of the sug- gested theory of the awohan4em of the nepamtion of liquids into Oard 1/2 layers. Furthermore, the kinetics of the separation of liquids The-Kinatica- of the Separation Into Layers of Liquida 153-58-1-4/29 in System With Usidmism Critical Points into layers was investigated in the system saliqylio s,cid - water with a metastable sepamtion of liquids into layers. It was possible to prove that the kinetics of metastable separation into layers is governed by the saw lavo as stable separation, There are 4 figures j 4 tables , and 6 referawes, 4 of which are Soviet. ASSOCIATION: Ivanovskly khimiko-tekhnologicheskiy institut. Kafedra neorganioheskoy khJ-4i (Ivanoio Chemioal-Tachnological Institute. Chair of Inorganic Chemistry) SMUITTED% September 7, 1957 Card 212 5(2) AUTHORSs Krupatkin, I. L. Todorov, I. A. SOV/153-58-3-3/~~O TITLEs The Kinetics of Separation Into Layers in Systems With Lower Critical Points (Kinetika rasslaivaniya zhidkostey v sistemakh a nizhnimi kriticheskimi tochkami) PERIODICAM Izvestiya vyashikh uchebnykh zavedeniy. Khimiya i khimioheskVa tekhnologiya, 1958, Nr 3, PP 15 - 20 (USSR) ABSTRAM The theory of the mechanism of the process under review was elaborated in systems with upper critical points (Refs 1, 2). It may be assumed that it is applicable also to systems with lower critical points (Ref 3). An experimental proofp however, is required by the assumption that the latter systems do not differ in principle from the first ones in a particular phase equilibrium. That proof was the objective of this paper. Therefore the kinetics mentioned in the title was studied at I o w e r a t a b 1 e and 1 o w 9 r m a t a a t a b 1 a critical points, i.e. in 2 kinds of systems of this type. The system of phenol-o-phosphoric acid was chosen because it is a doublo system with a stable lower critical point, and has already been investigated as Card 1/4 to the separation into layers (Ref 4). Pyramidon and water The Kinetics of Separation Into Layers in Systems SOV/153-58-3-3/10 With Lower Critical Points served as a double system with a metastable lower critical point (Ref 5). The results obtained for phenol-o-phosphoric acid are given in table 1, figure I and curve 1. The kinetics mentioned in the title for the system pyramidon and water is presented in table 3 and figure 3. For comparison, figure I gives the curve of the separation into layers (P a) of the systems investigated with a lower critical point K. The dependence of the linear rate of extension of the separation into layers on the superheating was studied in the same mixtures (80.58% and 49-96% o-phosphoric acid) (Table 1, Fig ij Curve 2). The latter curve is qualitatively very similar to curve I and has a distinctly marked maximum. The volooityzentioned increases by about the tenfold in the transition from 80.58 to 49-96% o-phosphoric acid. On super- heating in a mixture that nearly corresponds to the critical point, the velocity mentioned is 3.5 times higher than that to be found in mixtures which are near the edges of the binodal surfaces. Figure 1 shows that superheating rapidly Card 2/4 increases the linear rate of extension (up to the 14-fold). The Kinetics of Separation Into Layers in Systems SOV/153-58-3-3/._-O With Lower Critical Points Table 2 and figure 2 give the duration of the stratifica- tion ofthe phases in dependence on the concentration of the components in the whole concentration range below the strati- fication curve. C o a c 1 u 9 1 o n 9t In the systems mentionedi a) with a stable stratification into layers and a lower critical dissolution temperature, and b) with a metastable equilibrium between the liquid phases and a lower'critical point it was proved that the kinetics of the stratification into layers in systems with lower critical points obey the same laws as in systems with upper critical points. Thus it is confirmed that in both systems the phenomenon of the separation into layers takes place according to the same mechanism. Thus the theory of the mechanism of the separation into layers is fully applicable to systems with lower critical points both in stable and metastable state, There are 4 figures, 4 tables, and 5 Soviet references. Card 3/4 The Kinetics of Separation Into Layers in Systems SOV/1 53-58- 3-313 0 With Lower Critical Points ASSOCIATIONs IvanovBkiy khimiko-tokhnologicheakiy inatitut 4wncvoInstitute Chemical Technology) Kafedra neorganicheekoy khimii (Chair of Inorganic Chemistry) SUBMITTEN September 3, 1957 Card 4/4 Im st so Z W. Oil HE lip I I Sze i2 42 E13- lu: 3 u Li Z St jai iA 01 Z A. s Ve OZ. A Zj J* * R- . I I , * - z j 6 3L .'a d JJAI 00 112:1 JAI A IIJ Z JM a 4, -a 11 oil! -if 4; A TI. 0 A a -no" 3 Ilia 3 St ralis4h,; iovafl I M" - 13 -is. alr'- !, : .i A -. I I 'I I ---. : ! .1 -: ~.-- -.41 -11, OF v:j f5i ; I- - - .4 E:iv -*I !:?n id kv 'tpd -0 o"1013H.-ii-I 10 U, 13 Z:;" fa I -'~r I '.I'll -. 3 3 A i V 0 1x if I I -j jC131!3 hp 13 ills. 3;." Hii. A.S.-Nis 24 elk! 21 Ay r -d 2; a 1.3 vi a a A "i . . '41V 9 u 1 923-- Ht-4 jj:A A9-'.ho jil r ~o ' 2 I-o .4;-in -a .1 Wi 14. %3 Ao a 40' 1 p -. 9 Ego I.a g.A4 Ij I i" AH oil 9; '02. 0 -a I . I,i 3 A., -10,411 S3 0 AUT11ORs Krupatkin, 1. L. TITLEt Investigation of the Continuous Transitiunz From 3table to Metastable Separation of Layers (1,,saledovariye nelreryvnykh perekhodov stabillnogo rasslaivaniya v metastabillnoye) PERIOD1CALs Zhurnal Obahchey Kh1mii, 1~58, Vol. 26, Nr 3. pp. 023-829 (USSR) ABSTRAM The transformation of stai)la separation of layers to the metastable state can be of practical interest as a process which makes it possible to obtain the fusion of two and three bodies within the whole concentration interval of the binary- and tertiary system formed by them. It is shown that this transition in the ternary system takes place above the inter- section and above the point of contact of the fusibility- and separation- of-layer curves. As a whole, different types of continuous mutual transitions of metastable and otable separation of layers of binary and tertiary systems are in- ventigated. They consist of four basic types represented in the figures. The fourth type represented in fieure d ( ) has Card 1/2 not been found until now. This to find is the aim of the Investigation of the Continuous Transitiona From jtablo~ to 79 2 8 3 5 6 Metastable Separation of Layera present work. In the binary sy3tem salicylic acid-phenol in- veatigated with a view to itn fuoibilityn chomical reaction of the comj.~onontu was not found. Thu aelinrntion of layerl of the two tertiary systems salicyli-. acid-phenol-water and anthranilis acid-phenol-water was inveatigated. It =is found that in both cases the volume of tl.c separation of lajors of the ternary system binds the surfaces of the separation of layers of the two binary systems formed by water, and that it has a point of inflection. The cause of the formation of such types of diagrams of ternary 3ystems was explained. It is shown that in both inveatigated ternnry oyutems one of the types of continuous mutual transitions of' metastable and stable separation of layers of binary systems is realized in which the mentioned ~.rarioition through the point of in- flection takuo placo. There are 6 figurea, 3 tables, and 10 references, 6 of which are Soviet. ASSOCIATIONt Yaroslavskiy tekhnologicheskiy institut (Yaroslavl' Technological Inatitute) SUBMITTEDs January 12, 1957 AVAILABLE: Library of Congress Card 2/2 I AUTHORs Krupatkin, I. 79-28-4-57/6o TITLEt ~Onth`sE3i`abliah~m ~C-Zquilibrium Between 3 Liquid Phases in TLMary Systems (0 vozniknovenii ravnovesiya trekh zhidkikh faz v troynykh sistemakh) PERIODICALt Zhurnal Obahchey Khimii, 1958, Vol. 28, Nr 4, pp. 1108-1112 (USSR) ABSTRACTt In recent time Dtable equilibrium was found between 3 liquid phasoo J-"'~ernary systems which are formed of binary systems with stable phase separation.It was also shown that also in ternari system which contains binary systems with metastable phaue separation equilibrium can be established between 3 liquid phases (Ref. 1). Here also the equilibrium was metastable and was established according to the same scheme as the stable phase separation, Stable equilibrium between 3 liquid phases in a ernary system which contains one or more binary systems with metastable phase separation were not yet investigated. The research of this type of equi. librium and of the scheme of its formation was the object Card 1/3 of the present paper. The binary system anthranilic acid Op the Establishment of Equilibrium Between 3 79-26-4-57/6o Liquid Phases in li-rnary Systems benzine was investigated as well; it pertains to the systema with metastable phase reparation. The system water - benzine belongs to the oyatems with stable phase oeparam tion with an upper critical point which is to a great exa tent positive (Ref.1). The system water - anthranilic acid was investigated with resper,t to the phase separation. The curve of the me ~astable phase separation has a lower criti- cai point sq.70 C which corresponds to 38% of anthranilic acid, Thus ternary system used contains 2 binary systems with metastable and one system with stable phase separation. The system anthranilic acid - benzine was investigated by means of the melting point curve. The crystallization curve is s-shaped and very steep; the form of the curve is due to the existence of a curve for metastable phase separation. This curve lies, however, at such low temperature that they cannot be found experimentally. Their existence can, however, be detected indirectly. It is shown that this system belongs to the systems with metastable phase separation and a very low critical point. The ernary system anthranilic acid - wam ter - benzine was investigated by means of the phase separa. tion. It was found that the reciprocal solubility of two Card 2/3 liquid phases of this system depends only to a little ex. On the Establishment of Equilibrium Between 3 Liquid 79-28-4-57/6o Phases in TbMarY Systems tent on temperature. On the strength of these investigations it was found that this system has a domain of stable equi- librium between 3 liquid phases which lies at temperatures be. low 1240C (temperature of the critical conode), Temperature- concentration limits of the region of the three-phase liquid equilibrium and the compositions of the coexisting solutions of the critical conode were found. Furthermore it was shown that the scheme of the polythermal line of the occurrence and the developmerLt of a stable equilibrium between the three liquid phases lntternary systems which contain binary systems with stable and metastable phase separation is one and the same. There are 3 figures, 2 tables and 4 references, 3 of which are Soviet. ASSOCIATION tYaroslavskiy tekhnologicheskiy institut (YaroslavZTechnological Institute) SUBMITTED: March 18, 1957 Card 313 5 (4) BOV/79-29-e-7/01 AUTHOR: Krupatking I. L. TITLE: Employment of the Method of Two Solvents for an Investigation of the Formation and Properties of Organic Complexes PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29p Nr 8, pp 2490 - 2495 (USSR) ABSTRACT: This theoretically founded method (Refs 1-4) in at present being used - among other applications - for the investigation of the chemical reaction in liquid systemel in addition, it takes the effect of the medium into account. The above method has hitherto been used but rarely for the investigation of systems in which two complexes occur. To close this gap, the two binary systems "chloral hydrate - antipyrine" and 11pyra- midon - salicylic acid", previously investigated only in the polar solvent water (Refs 5,6), are investigated here in the homopolar solvent benzine. By V. P. klekseyev's method (Ref 7) it was investigated how far the system ''chloral hydrate - ben- zine" can be separated into layeral it belongs to the.systems with an upper critical point (Fig 1). The system pyramidon - benzine was investigated with respect to fusibilityl it is one Card 1/3 of the systems with latent separation into layers (Fig 2). In Employment of the Method of Two Solvents for an SOV/79-23-8-7/81 Investigation of the Formation and Properties of Organic Complexes this connection two complexes of the predominant system appear in the isothermal lines of the ternary system "chloral hydrate antipyrine - benzine" (Fig 3). k complex of the predominant system with the solubility minima, the upper ternary critical point, and a break in the critical line appears in the iso- thermal lines of the ternary system 11pyramidon - salicylic acid - benzine" (Fig 9). k region of separation into layers is visible in all three homogeneous binary systems whithin this ternary system, a phenomenon which is illustrated in more de- tail in the report. It was shown that in the investigation of the complex formation in organic compounds with two complexes the above method is reliable. It permits detection of all com- plexes of the system, and determination of their composition and a series of properties. It was further shown that of two complexes that complex is most stable which contains a larger quantity of the component of the reacting system which reacts more weakly with the third component - the solvent. There are Card 2/3 Employment of the Method of Two Solvents for an SOV/79-29-8-7/81 Investigation of the Formation and Properties of Organic Complexes 4 figures, 2 tables, and 11 references, 10 of which are Soviet. ASSOCIATION: Ivanovskiy khimiko-tekhnololicheskiy institut (Ivanovo Insti- tute of Chemical Technoloj SUBMITTED: June 3, 1958 Card 3/3 D1 KRUPATKU1, I.L. Reply to E.F.Zhuravlev. Zlnw.ob.khlm. 31 no.10:3485-3486 0 161. (MIRA 11.:10) 1. Ivanovskiy khimiko-tekhnologicheakiy institut. (Phase rule and equilibrium) XRUPATKIII, I.L. . Priority of D.N. Abaahev in tho discovery of tho isoth~-rjflal mothod for studying tho tautual volubility of Liquiclo. Trujy Inat.ist.eat.J. tekh. 35:376.-3?9 161. 0'. 1 ~-,% 14 : f) (Liquid,n) (Solubility) 7A n;, iri-#,t,,c n a!. LA ZHUKOV, P.A.; GANSHTAX, V.I.; KRUPATKIIU, B-, redaktor; ULITANOYA, M., takhnichookir redaktor (The leading role of socialist industry in the development of Soviet agriculture] Vedushcheia roll notsialistichookoi promyBhlennosti Y vazvitii sel'skogo khosialetva. 1954. 62 p. (KM 9:12) (Agriculture) (Industrialization) KRUPATKINA, D. L. Cand Mod Sol. - (dies) "Clinie and diagnosis of tumors of the oerebellopontils angle*" Sverdlovsk, 1957o 13 pp 22 om. (Sverdlovsk State Mod Inst) 100 oopies M' 8-57, 109) Ar VOL'FUVSKIY, G.K.; ~R ~ ~R.- - rVAUOV, A. 1. __ITgX Regu3AtIon of WR ovens equipped with separate regenerators In the course of heating with coke gas. Koko I khtm. no.11:25-29 160. (XIRA 13:11) 1. Koksokhtmetantelyas (Coke ovens) czEcHosLamaAfthemical TechnologY Chemical Products and H-13 Their Application - Ceramics., Glass, Binders, Concretei Abs Jour : Ref Zhur - Khimiya, No 3, 1958, 8752 Author : Yxupauer Yandl Inst --- ------------------- Title Compression Strength and Thermal Stability of Sight Glasses. Orig Pub Sklar a keramik, 1957, T,, No 4, 11.2-1-13 Abstract A study was made of the compression strength depending upon the ratio of thickness of the glass to its diameter. For this purpose use was made of round sight Glasses ground on both sides and made from cast glass having the following composition (in ~ by weight): SiO 73-72, Al 203 0-83, Fe 203 0-035, cao 6.4, i4go o.o4, L~O + K20 18.02) S03 0-221 Cl O'll As203 0.6. Thickness of the Card 1/3 CZECHMLOIII,UA/Chemical Technology - Chemical prod,,lcts and H-13 Their Application - Ceramics, Glass, Binders, Concrete. Abs JOUr Ref Zhur - Khimiya, 110 3, 1958, 8752 glasses was 8-20 mm- Only those glassea were selected for testing which were free from waviness and showed a uniforv. distribution of stresses up to a value of about go M/cm. For determination of thermal stability 10 glasses were u-nal having a thickness of 12-14 mm. All the glasses without exception failed to withstand temperature diffcrenc,~s in excess of 45 4 50. Sight glasses can successfully per- form their functions at temperature differences not over 30-350) internal strosses up to 90 m/cn and thickness of 10-15 mm. At the same time one must take into account the necessity of a two- to three-fold strength safety factor, indluding such elements as) for example., uneven fastening, material fatigue fOllowing prolonged strain, etc. Sight glasses must be made from glass material which ensures Card 2/3