SCIENTIFIC ABSTRACT KRYLOV, V. YU. - KRYLOV, YE. I.

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SCIENTIFIC ABSTRACT
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"Games or Automata." report presented at the Symp on Relay Systems Theory & Finite Automata, Moscow, 24 Sep-2 Oct 62. I AMiSSION NR: AP4036509 S/0103/64/025/005/0668/0672 AUTHOR; Ginaburg, S. L.'(Moscow)., Kry*lov, V. Yu. (Moscow).' Tsetlin, M. L. (Moscow) TITLE: Example of a game of many identical automata SOURCEt - Avtomatika I tolemakhanika, v. 25, no. 5, 1964, 668 -672 'TOPIC TAGS: game, automata game, game of permutation ABSTRACT: A simple example of a symmetrical game of many automata which permits a natural interpretation is discussed. if of each player is equal The payo to the power of his strategy divided by the number of player* who have chosen the same strategy; this game Is termed the "game of permutation. 11 A modificatiop of i this game includes an agreement between the players to 3;eceive a ~=timazn total payoff ajid to divide it equally; only the first strategies are used, and each of them Is selected by only one player; this modification is called the "game of Card I /Z KRYL(')Ilp V,Yll# Ail :5,I)TI, 163 ni;.2-.28),.-2)2 JI (MIRA 180) .1. Submittod Doromtxir 28, 1964. GtD WCff -R-Ri SOURCE CODE: WON AUTHOR: .-Ta-vtIlm, M. L.; Ginzburg, B, L,; Krylov, V. Yu. ORG.- none TITLE: Example of the collective behavior of finite automatons :4 SOURCE: Moscow. Institut avtoma*tiki i telemckhaniki. Samoobuchayushchlyesya avtomaticheskiye Elstoi r-(g-eT[--Iis-t-m-c-tgg-Etuf6-m'a7fe-systems). Moscow, lzd-vo Nauka, 1966, 165-169 TOPIC TAGS: finite automaton, game t cory, computer simulation ABSTRACT: The article containt; a description of an example of computer shnuIntion of an 11assignment gnme" by many automatons. A stniple example of a symmetrical ganio permitting a natural Interpretation Is selected. Resultant conditions and equilibrium pointa are studied, and the behavior In this game of automatons Interrelated by the "common pool" procedure In studied. The audiors sliow Lhat automatons Invested with puil)oseful behavior under stationary random condItIons will likewise behave "reasonably" In this case as well (provided that their memory capacity In sufficient). Three stratepy examples are analyzed Rud win factors arc do- rived for dIfferent memories and for situations w1di and ;vIthouL dic "common pool" concept. SUB CODE- 09j1Z/ SUBM DATE: OZMar66/ ORIG REF: 002/ OTII REF: 002 Card I T.i Ac, KRYIDV, Ya.; IVEMNOVA, V.I. Plastic deformation of germanium single crystals (by insertion of a spike). Kristallograftia, 6 no.5.*784-786 5-0 161. (MBIA J-4: 10) 1. 14ookovskiy gosudars tvennyy universitet imeni Lomonosova. (Deformations (Mechanics)) (Germanium crystals) KRTTkV. Ye. 1. Universal instrument for measuring wear of parts. Sudestroonle 26 no.9:6-5-67 8060. (KIRL 13110) (Nechanloal wear) (Pistm-Testiag) 25)" PK2 -1, r-" .1 - 1 -7 "~;f ;r'f~'-"-:~:lF';-' '7 ~ - - ~ m SGIOV, V.A.; IMYWV, Ye.I. Uso of tho CKII-1 all-purpose indicator for moasuring tle war of moclmnical parts, Zav.lab. 28 no.6044 0621. (MA 15:5) (Tooting machinos) KRYWV, Yu,I, Interference preventing capacitive filters on electric locomotives. Avtom., telem. i 9*ias' 7 no.8:41-43 Ag 163. (MIRA 160) 1. Starahiy lnzh. laboratorii signalizatsii i avyazi Severnoy dorogj. (;leotric locomotives-Electric equi ment) - .,(Railroads-Communication systeMS5 'TY, uf autu%at-lor, in prom. 16:3) W-71 V.V. , in zh. U.YLOV, Inzh.; CAPO,;, A.;,',: ecTnn,~- Pvtilru:Ld -witching from the trachiniat'r, cabin. Gor-zhur- no. 2: 62-6~; F 164 -:1 FA I -T: 4 1. Institut avtoratiki Gooplana UkrSSR, Kiyev. GBIZU'URG, L.G.; Prinimali uchastlye: Ni-STEROVt G,F,, i5po1nyayushcbiy otyazannosti starshego inz~.enera; 'YHYLOV, Ye.1..,_i5po1nayau--~ch1y obyazannosti inzhenera Effect of lubricants on the formation of a carbon deposit in diesel engines. Inform. sbor. TSNIIMF no.47. Tekh. ekspl. mor-flota no.3:49-57 '60. (MIRA 15:1) (Marine diesel enFines--Lubrication) Oylinder oils for slov-rm bigb-powered diesels. KhIm.1 tokhotopl. i mael 6 noolt54,-57 U 162o (MIRA 14:1) lo Wentrallmy naucbno-ionledavatellskiy dizel'W institute (Diesel fuels) YEGCRGV, Yu.V.1 NIKOLAIEV, V.M.; ERMV, Yej2j TKACHERKO, Ye.V. Fogsibijhty of using a mixture of isotopes of Sr89 and Sr 0 Y in direct radimetry, Radiokhimia 1+ no-4:516-518 162, (MIRA 15:22) (Strontium-Isotopes) (Yttrium-lootopes) (Radiometry) Z: YZGOROV,'Yu. Vq KRYL-OV# To, I. Nature of absorption of electrolytes by some precipitates. Ivy* vyes uchabe savel hiso i khim. takh. 5 no.5t749-752 162* (MIRA 1611) 1. Urallskiy poUtakhniebookly institut lasni, S. M. Kirov&* kafedra khimii i takhnologii rsdkikh olementoy. (Adsorption) (Blectroly-tes) 12 5/166/63/005/002/001/003 C075/9136 AUTHORS: Yegorov, Yu*V., and KryLov, Ye.i. TITLE: Some peculiarities of sorption of strontium-90 on active manganese dioxide PERIODICAL: Radiolchimiya, v-5, no.2, 1963, 211-215 TEXT: Sorption of micro-quantities of 90Sr was studied on an active Mn02 resulting,from the action of H202 on K MnO4 under conditions of free coagulation, whercby the precipitate (Mn02) sorbed a proportion of K+ ions and the pH of the system remained constant. The dependence of [OH-3 on the mass "concentration" of, the sorbent fm,] was determined acicrimetrioally. The following equations wei:e obtained: tm j - n 4 ~ms I ef = 0' 64 al 1 ~01i-j - 0.42 (2) where tl-ms3ef - effeative mass of sorbento The quantity of 9OSr re.moved by Mn02 is given byt Card 1/2 Some peculiarities of sorption of S/186/63/005/002/001/005 E075/E136 C M 12,92 viliere Kj - constant. Eq.(4) was confirmed experimentally for a solution of K MnO29SO.192 to 1.15 mM/t), KCt (8 g/fl and about 10 microcurieg/J. Sr precipitated by H202- Kl was found to be 164. The amount of coagulant (KCe) affects strongly the distribution of 90Sr between Mn02 and the solution. There are 3 figures and I table. SUBMITTED: March 26, 1962 ILI Card 2/2 CHUPAKIIIN, O.N.; PtCHKAMAp Z.V.; KR Renctions and derivatIves of qu1naldine. Vest. AN Kazakh. SSR 19 no.9185-92 S 163. (MMA 16:11) NIKC)LAYtV,, V.M.; KRYIZVP Ye.1.1 BAGRE"ISOV, V.F.; TEGOROV, Yu.V. Behavior of radiocolloide of cerium In sorption systems. RadiAhimila 5 no.5162-2-626 163. (MIRA 17t3) KRYLOV, Ye.l., inzh. Detonations In engine bousinga. Ener.gomashinostroenie 9 no.11:48 N 163. (MIRA 17s2) .-000 0000 0 0 0 0 0 0 A 4, T 'a v -0 - I III's I I I&, so A I I V t Iz 1 L Y - I , . I I 4 .011 ..6 4 a S -lye* 040COISIS map 008011-1,41 " 00 A 00 00 , .00 0 dam M I m" Khavyakove Mr F u 00 , - . - l Iy S, o. h1okimshin. V, J. (v. S. IV' Itj 3, cf. C. A. St. (-4w -0 0e a , -TW jUM kwimM by 11,Mon The "off- r4sq, CuCI, -00 is I"el4r to 11.5 (cf. C. A. 29.7748*); Its tbbrkrA'%*'n .0 It. C. A. 00: We 0 see ass 00 coo 00 too oo a fee too doe 8*0 .lilt -see IWO 0 Boo 0 0.9 '1' -Ifill; Im m~4-4, 8 Od U:A'0'0:000600000000*0 0 0 go *60000000000000000 0 0 & 0 0 0 0-0 0-0 0 -0 0 a 0 : o J of* 0o i o a 0 o 0 0 0 0- CO 0 410 0 lose 0 4 0 0 0 of 0 0 00000 0 00 a & & 0 0 a a : ! S, r I! r"T v ! . . . p co as 15 I C a V 6 8 X L pa 0 S I w - #1141, goo "No Ar 0 0 00 owl to Will" ""MAW P" A1pMW j" Goo Will 0 111, mw A* a jq .00 (-fl"We 111) Ammi, 00 aq, 00 "1 "M 9 Aq 44 amp v*w No p -Ina 00 pa"I"" pow -Ow wo 0 an pow 441 00 MWO IMSAad NJ &Vp Amp VW q 00 v -q opium OR An"U& 9 111 rd to pml Wat OILL 00 0 4p ME x NJ pjmmmpW&O^.wu go " v allnuiis u" sea f- "Wipf"Mmmirl"Opop Poe 000 %M) rn OU . 441 If"Ab -113M 111 so 444 ra 'sum Ov lWMP Imp V# 0" oil r -43MI Ou p$1=Pw 00 raM an ollva",11du 'Y" III pe4p" am 0 00 in 'we" SRI go 00" so p 040, W"Pw 6" in 44ft -soft I ")I n amil p ON p 00- Tit p ww an opqo a Off of 1111--00*11 NMI Om 1 7 go. INV Is go. "Ay 'Somy lot IN 0 00 amp" ow go 00, 00 640" mu oar pow 11'solood owl 11"13000 -goof" 40t 4.4 it I IF A's 0 1 * 111, a, 11 i I I 1 0 0 ;, 0 117T. I VV6 a oil, imulal W~Jb 110 0 0 0 0 0000 0 . 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 f : of 0 g,0 000 0 0 0 000 000 r ff t=/ Chemistry I olarorrraphy Card 1/1 1 Pub. 2P - 22/49 Authors S Krylov, E. I.; Kolevatova, V. S.: -and 5ararina, V. A. TWe I 11olarographic investigation of titanium and niobium sulfate solutions Parlodical I Dok. AN SSSR-98A, 593-595, Oct. 1, 1954 Abetmt I Experiments were conducted to determine the possibility of obtaining Vb and Ti, waves from their sulfate solutions and to establinth the basic conditions for polarographic quantitative determination of Ti and fib during their combined presence in the solution. The results obtained indicate that during cathode reduction of.ilb and Ti from their sulfate solutions, over a mercury drop cathode, certain clearly expressed waves, corresrondini, to ion overcharge processes, appear on the polarogram. Five references: 2-Czech; 2-1135R and 1-lerman (1919-1953). Table; graphs. Institution : The S. M. Kirov Ural Polytechnicum Presented by : Academician 1. P. Bardin, March 18, 1954 -041 r4ktavatkid ""UhLeff2a Of tram ffulphuria MW Oatto 1"44 7hala". ~911_ in 11,~_ j4: So pr( c'nt.) gives a j%itafoglaphic Wave With twn ttepl. Th4e hatf-WIL%t px)tential for Nby -* Nbl's Is 1-033 V t s. tht, S (~ L, TitADtU= In H,&O, J-C 4 L) a ~"v With a tL;Llt-*-av* pOtrnbAj ~ 0"51714 ',FYT`7dm* rk)t Tiva 4 WAVV Unckr thastr condttkirs. ~ro detevnitnO and Nh lit Ott%, etAL., 0 5 g i't dexAMPOrA.4 in a platinum diqh with 11,S0, an4 IfF. the "- utv,rs I* "srw~rated w dryness, the reold-je to fu-qcti wiO 15 times ml weight of K,%O,, itad the melt Lq treAtrJ with RIO ml of 10 fw cent H#SO, and lf,0 The filtettd off. the filtrate is tytated wil 60 MI !f!%.i'C' H,50, and the "ation is evapo(ated to fumes Tho whiCion is then dilutc,4 to 10 petr cent. 111,90, With WItef,"Itid 13 MI MIS t4ken foe the jvlarogyaphic dftrTminatkan. GetAtin is a4lded as max. 3upiness% and It is paned thmujh the solu- tion. G. S. Smirm so ce~mMltlan and Viinwilas of (ho hydtoch1vic acid t;ltl- V. tq!v. J. Vol. T 4VI-MR RN-UN rj CA. 49. 121(.%s. R Ol kith L;t 11,0 wail Irv.- Iniit. (A 4 frkt~loy I I lei it It", 4 1.7), nil. 11,0, forming IZAT V, III At Ift f, ,Cycral d:-S i op.ilt . t ~ v :1%. 1 m r)I't . IN't, i~. L (1,,0. by pvl-l 1 1 "'. -o ! !,V rf Nlfolorby diltitwg 'Z I.,! I int. wh :P), I.,flilig %4~.Veral 111in, [IC,' Ia I 'j. 1,6' dly V. TITA.'eat'A 1,5, v, t t h A 41 N, ~m V, N!~:Cl v~kriul frolit 1 :3,5.1 tti, I .,i 1,~, ffi!r,ali fif flifillAikm Of L I C, o4l:~i ',Qi, !1;I,XY with Naoil. KNAVI. owd WP h ew:h I wKs obta:nrd a miri. fit cuild. to oie t,)i at I [C! liteirrit fit 1. fit wrh cim. ififte .,:ii it, filrecli,!i it; th, rwid. curve bdwt: ifte min. -o m-O,-11, 'r1w itiflert;.)ns . indimted that patt tf V,it, VC4 wftA %nx to t1te D1,11,;C wid 11- 111"1. I.AV, 14 it,,, UMN11 was ("%owitly .3 1, ;,;,,P wot. of "free- 110 varitid. Tbull 1he it Wobjum raychizaale. 4 j;', tanloinktas of Wdum and tirt and their lipliatts.- 1. Kryloy and I it. I ~ Alt k,;r,.v. ZAN,. i k,1 Uim. in "i'l, KOH s,,Iti oai rnked with vpjiv. anits of C.t(rofj~' g,/Inl, CA ') allA 11;1(011), g./.ni. M., ') 4111., the w):itt upt, CaMbO,h.211:0 and plad. T IOr wily., In g./Lsil 16', And ~4y. &,u. v14 Nb") %erc. rop, (10r)"M, 1,24.1 X (MON'ti, 3A,1i )< If) -". Under a ;t~wjv tellip. Ike thev olco-tiltol. at 1"14- X'17' and reip., in glyt flit ollidi wrre stable top to Ilic razge-.143-4W aml -TN', Istp., ut %filds the 6iir~ly W)wd. atthyd. salti weto fl,rtntdi the. li"Ong irr(julted IM mill. M.ps. and (14. wrre: Ca( 1310', 3.7-111; 1-2W, 4.044. X-ray data (Ve tlnir'!~Ioll) on 14111cl. Ixt"ni'lloit wid inityplawlT dilul-etit Arv xi"tn ff~r Ow mitsyll, F':Altn' and for lh~ Ngti't llpifilrq; flit flIMICt lift' thiAt%lit (A) h3Vr R (1VC-4:CtttMA C.UhiCit I-Atfi(T- ol' (fie, flitntspat type, like- that of ',;r(Nb(h~ As alliMcArd, while the l,tttrr li;iVe a siatitir firucture excq)t for flit, 11,f) in R4 v,crs. C-ifenn. of d. from x-ray tla4a agTevi with the vxpil. fl; Alvpfn J. Gem. CArm. V.S-S-R. 23, 101.110( VM5), traliqlatilm). Malcolm Andurm-n IRYWV, Yo.I.; SHMIN, A.A. - ". ~ I Synthesis and proportion of -aloblum bronzes. Zhur.ob.khlu. 25 no.9:168G-1685 3 153. (MBA 9:2) l.Urallskiy politakhnichookly institut. (Niobates) : . x~ "i - E ~- fl ~-- ~P Pl. Vi INS =,-L4 . -I - -ii ~41. *. ,.:,. i-~ 1.. 1 7 1 1 ~ ~ ~, ;: T KRTWV, Te.l. Synthesis and properties of yttrium orthotitanate. Zhar.neorg. khIm. I no.3:366-367 Mr 156. (MLRA 9:10) 1. Urallskiy politakhnichngkly institut Iment S.M. Kirov&. (Tttrium titanate) - - - - - - - - - - - - - - - - - - - - - - - - - - - - e t/ USSIR/Inorganlc Chemistry - Ccuplex Compounds, C Abst Journal: Referat Zhur - KhImiya, No 1., 1957, 659 Authort Podchaynova, V. N., rXYJOY,, Ye. I.j. and Ryabchikov, D. I. Institution: Xw AL 01 J, d, Title: -On the Valency of Copper in Some Complex Compounds Original Periodical: Zh. neorgan. khimii, 1956, Vol 1, No 3, 4o6-41i Abstract; The magnetic susceptibility of a number of Cu complexes has been measured at 180 with a view toward establishing the valency of Cu in these complexes. Cu "ditizonat" ~ Or. note: diphanyldithiocarbazon- ate !7 and the thiocyanate of Cu-n-anisidinate obtained by treating ethoxyaniline a dilute CuSO4 solution with an excess of p-anisidine 5 7 (I) and KCNS are diamagnetic (the composition of neither compound has been establIshed), which indicates that they contain Cu. The follow- ing complexes are paramagnetic (the numbers 1n parentheses give the Values Ofl,,~erf) in calculated from Curie's law)t Cu p-anioldin- ate sulfate obtaineegy treating a dilute CuSO4 solution with an Card 1/2 Category: US511 Abs Jour: PM--;.jj, No 3, 1957, 7755 Author : Solov'yev, 3. 1., Krylov, Ye. I., and Kononova, L. P. Inst : Not given Title : PurifIcation of ll'Aobium from Titanium by Means of Cat i on-R,-diant;e Resins Orig Pub: Zh. NcorGan. Khimii, 1956, Vol 1, 11o 4, 660-663 Abstract: The separation method is based on the ability of freshly prcclpi.L-Ited niobic acid to form a colloidal suspension of niobium oxychloride after treatment with concentrated HC1; t7he oxychloride is not adsorbed on the cation-exchange resins, whereas Ti and other i=urities present in the form of cations are adsorbed. Three gradea of cation-exchariCe resins were used I.n. the acid form: Espatit-1, Eapatit-A, and Sulfou- gol-K. Some adsorption of Ub was observed on each of the above cation- exchange resins (Sulfougol-K showing the least adsorption). At FC1 concentrations of 0.1-0,211, the 11b is retained in the cluent while Card 1/2 -2- Categoz- ./: USSR Abs Jour: RZh--n, Ito 3, 195Y, 7755 the Ti Is 90% adsorbed even when present in considerable amounts; however, the leas Ti is present in solutlon, the more complete is the adsorption. By relpeated recycling of the solution nIobRLm of purity in ex cess of 9).9% can be prepared. The adsorbed 71 is reco-iered b.-I, elution with Zi IM or a 5~ solution of oxalic acid; in the latLer case small amounts of 11b adsorbed by a mechanism different frcr, that a' Ion exchanr I _c (surface adsorption) are also recovered. Card 2/2 -3- USSR/Inorganic Chemistry - Complex Compounds) C Abst Journal: Werat Zhur - Khimiya, No 1. 1957) 653 Authorz Alekseyev,, Yu. I., and Krylov, Ye. L Institution: None Title: Hydrides of the Transition Elements. 1. Synthesis and Properties of Niobium Hydridea Original Periodical: Ukr. khim. zh.) 1956, Vol 22, No 2, 143-145 Abstract: NbCl reacts very rapidly with a 0.3 M C6H5MgBr in ether, forming) in tke opinion of the authors, a cinnamon-colored residue of Nb. The highly dispersed fib thus produced can combine easily with hydrogen, and the bydride separates out in the form of a sticky, dark, cinnamon- colored liquid. Upon washing with ether and drying at room tempera- ture in a stream of %, this liquid changes to a black amorphous Nb hydride (1). After treatment with C6H5Br, I again turns liquid. I is oxidized in air vith the foT=tion of niobic acid. Concentrated HN03 oxidizes I to niobic acid and NO2. The action of HC1 on I results ih Card 1/2 USSR/Inorganlc Chemistry - Complex Compounds, C Abst Journal: Referat Zhur - MiLmiya, No 1, 1957, 653 Abstract: the evolution of H2 and the formation of a yellow-green solution. The reaction of I with 92SO4 likewise liberates H2, but the resulting solu- tion shows the brick-red color characteristic of the sulfate complexes of lower-valence Nb. The composition of I, depending on the length of the action of H2, corresponds to the formulas NbH or NbH2. The authors explain a somewhat higher H2 content in I than that calculated from these fomulas by the absorption of R2 by the hydrides with the forma- tion of solid solutions. Card 2/2 / z e v I 'V" . 7: USSR/ Physical Chemistry - 319ctrochemistry B-12 Abe Jour : Referat Zhur - Khimiya, No 4, 1957, 11362 Author : Krylov Ye.I., Kolevatova V.S. Title Zoncern ng Etetrolytic Reduction of Niobium in Solutions of Its Sulfate Orig Pub Zh. prikl. khivdi, 1956, 29, No 8, 1292-1295 Abstract Study of the influence current dtnaity i, temper&tura and conpooition of electrolyte, on yield, on basis of carrent consumption (TC), in the elec- trolysis of solutions of Nb(5+) 'RnKbim, 1955, 25890). YC is considera- bly higher with Fb than vith Rg. On Increase of I, on lowering of tem- perature and of Nb(5t,)-concentration, YC drops. do incr a so e& e of H_ 4 content YC increases only sligttly. ftt reaulte obtained are aWFibuted to the influence of the factors undtr study on the diffusion rate of Nb(5-1-) to the cat-bode. t ZT PUZAXO, V.D.; KRYIOV, le.l.; SHIDL#TS, A.K. The nnture of ludium dichloride. Zhur. neore. khim. 2 no.8:1753- 1?56 Ag '57. (MIRA 11:3) 1, Urallskly politakhnicheakiv Institut# (Indlum chloride-Vagnotto properties) KRrWV, ye.j.; GqUKHLANTSET. T.G.; CHUNIX. V.S. -Studying solubility In the system tantalum pentoxide - selenic acid- water. lzv.vys. ucheb. say.; tayst. met- W*3:97-101 158o (WRA 111.11) 1. Ural'skly politekhnichaskLy Institut. Kafedra khtell I tekhno- lngii rodkikh metallov. (System (Chemistry)) (Solubility) AUTHOR: sov/1 TITLE: On Folynuclear Chlorides of Niobium and Tantalum (0 mnogoyader- nykh khloridakh niobiya i tantala) PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimlya i khimicheskaya tekhtiologiya, 1958, Nr 4, PP 676-679 (USSR) ABSTRACT: By the method of magnetuchemistry the valence state of the atoms of niobium (tantalum) in the polynuclear compounds 11b6Cl. 14' 7H2 0 and Ta6C',4 -7H20 was investigated. The syntheses of the initial products were carried out by the reduction of NbC15 (TaC15) with lia-amaigam in evacuated little tubes of molybdenum glass at 4000C. The analyses of the products synthesized correspond to the above-mentioned formula. The measurement of magnetic susceptibility was carried out by Gouyts method at 780, 2060, 2730 and 2930K. The polynuclear chlorides of niobium and tantalum are paramagnetic. It was found that within the temperature range of "18-293'JK the magnetic susceptibility of these compounds obey the Curie-Weiss law, with negative -ialues for the constant E). In the molecules Yb c1 ' 7 HP Card '1 /2 6 14 On the Polynuclear Chlorides of'Niobium and Tantalum SOV/11516-58-4-i6/49 and Tlt6C'14 -7H20 Me-Me atom bonds are present. It in shown that in the composition of the molecules of polynuclear com- poundn of nioblum and tuntalum two positive paramagnetic ions Nb_~ (Ta+) and 4 diamagnetic atoms Nb(Ta) are present. There are I figure, I table, and 11 references, 3 of which are Soviet. ASSOCIATION: Kafedra kh.-*mii redkikh elementov Ur-illskogo politekhnicheskogo instltuta im. S. M. Kirova (Chair of Rare Elements Chemiatry at the Ural Polytecbriic Institute imeni S. M. Kirov) SUBMITTED: April 7, 1958 Card 212 AUTHOR: Kr7lorir, re. 1. sov/ 78--3-7-W44 ---T-~~ TITLE: . The Xagaetio Properties of the Oxides and Sulfides of Niobium and Tantabim in Their Lowest Valence Stage M Kagnitane avoyetva okisloy I sul'fidov nioblya I tantala nizahikh vauntws toy) PERIODICAL: Zhurnal neorganiobeakoy kh1mil, 1958, Vol 3, Nr 7, PY 1487-1489 (USSR) ABSTRACT-i The ausoVtibility of Nb02, NbS2# Ta02 and TaS2 was measured at different temperatur-is. For tM dnt-irmIrAtion of the susceptibility of the above mentioned c.55- It was a grey crystalline material with a metallic lustre and had a density of 4.3 g/cm3. Niobium bronzes of calcium, strontium and barium were prepared by heating equimolecular quantities of niobium dioxide and the alkaline-oarth oxide at 12000C. The compositions produced were CaO.9NbO3 (blue-violet colour, lattice parameter 3.905), SrO.93NbO3 (copper-red, parameter 4.015) and BaO-75"03 (red-violet, parameter 4.08). The magnetic susceptibility of the niobium bronzes was measured in a magnetic field of 4000 oersteds at different temperatures. There was little Change in susceptibility with change in temperature. Table 3 sives the magnetic susceptibility of the niobium bronzes and that of the corresp?nding metal. It can be seen front the figures that the ion Nbi+ in not the source of paramagnetism in niobium bronzes. The data agree with the hypothesis that niobiunt bronzes are solid solutions in which there is some kind of equilibrium between cations and anions containing totravalent niobium. Card 2/4 S/153/61/004/006/001/ooa Niobium bronzes of the alkaline ... E021/E453 There are 3 tables. ASSOCIATION: Urallskiy politekhnicheakiy institut im. S.M.Kirova Kafedra khimii i tekhnologii rodkilch clementov (Ural Polytechnical Institute imoni S.M.Kirov Department of Chemistry and Technology of Rare Elements) SUBMITTED: January 29,, 1960 Card 3/4 5/07 61/006/001/016/019 B017YBO54 AUTHORSi Krylov, Ye. I.t Strelina, V. M. TITLZi Prassodynium- and Noodynius Orthotantalates PERIODICILe Zhurnal noorganicheakoy khimii, 1961, vol. 6, xo. 1, pp. 235 - 236 TEXTs The authors studied the synthesis of praseodymium- and neodymium orthotantalates and the magnetic properties of these compounds. Chemically pure oxides of tantalum, prasoodynium, and noodymium-were used for the synthesis of orthotantalates. Equimolar mixtures of tantalum anhydride and praseodymium oxide, or noodymium oxide, respectively, were ground inoan agate mortar, and subsequently heated in a corundum crucible to 1200 for 30 hours. Table I given compositions, colors, and densities of prassodymium- and neo4ymius orthotantalates. The compounds have the compositions PrT&O 4 and NdTaO 4* The magnetic susceptibility of prassodymium- and neodymius orthotantalatos was determined by L. Gouy's method (Ref-5)1 results are given in Table 2. In the temperature range of Card 1/2 Praseodymium- and Neodymiua Orthotantalates S/07 61/006/001/016/019 B017YBO54 78 - 2900K, these compounds are paramagnetic and follow Curie and Weise's law. The effective magnetic moments determined agreed with those indicated V1 in publications (Ref.7)- 0. A. Smolenakiy in mentioned. There are 2 tables and 7 referencest 5 Soviet, 1 French, and 1 German. ASSOCIATIONi Urallskiy politakhniohookiy inatitut (Ural Polytechnic Institute) SUBMITTEDj April 25, 1960 Card 2/2 1213, 15 , 21752 S./07 61/006/005/006/015 B121Y3208 AUTHORSt KrYlovt Yee-Iot Sanatinat V. N., and Shtollts, A. K* TITLEt Synthesis and properties of orthoniobates of rare earth elements PERIODICALt Zhurnal neorganicheekoy khimii, v. 61 no, 5, 1961t 1135 - 1137 TEXTt According to 1# .8. Morozov (Ref, 2t Zh. neorgan. khimii, 1 791 (1956)) niobio acid forms metaniobates of the composition R(NbO 3~3 (R - La, Ce, Pr, Nd) with the hydroxides of rare earths at elevated tem- peratures. The present paper deals with the synthesis of the orthaniobates of lanthanum, cerium, praseodymium and neodymium. The magnetic properties of the compounds were studied. The anhydrous rare earth oxides were sub- jected to heat treatment with niobium pentoxide in a ratio corresponding to the orthoniobatea. This was made in quartz crucibles at a temperature of 11000C for 12 - 15 hro The formation of orthoniob&tV was confirmed by chemical and X-ray analysis# The resultant orthoniobates have the follow- Card 1/3 J-' 21752 S/07SJ61/006/005/006/015 Synthesis and properties of ... B121/B208 ing colors and compositiones LaNbO 4t grayt 54PO ~ La20 3 and 44.5 ~ Nb2o 5* CeltbO t darkolive-greent 53#4 % CeO and 40,9 % Nb 0 41 2 2 50 PrNbO4 % pistachio-greenp53021 % Pr2o 3 and 44&67 % Nb2o 5# Nd1tbO 4t gray-violato 54*4 % Nd20 3 and 44#05 % Nb2o 5* X-ray analyses disclosed that the orthoniobates of the ceria earths have an isostructure with fergusonitee The lattice parameters of the orthonio- bates of cerium, praseodymium and neodymium differ little. The magnetic susceptibility of the orthoniobatee of ceria earths were studied; the re- sults are presented in Table 4* Lanthanum orthoniobate was found to be diamagnetic, cerium orthoniobate paramagnetic; the temperature dependence of the magnetic susceptibility follows the Curie law, while that of the orthoniobates of praseodymium and neodymium follows the Curie-Weiss law. There are 4 tables and 6 references, 5 Soviet-bloc and 1 non-Soviet-bloco ASSOCIATIONt Uralfskiy politekhnicheskiy institut (Ural Polytechnic Institute) Card 2/3 ilm 3/070/62/CO7/004/005/016 Bi 1 O'/~Pi 01 AUTHORS: Krylov, Ye. 1. , Dmitri,,ev, 1. A. , Strelintt, 14. TITLE: 7hermal decomposition of potaoalum- and oodium meta-niobate PERIODICAL: Zhurnal neorg~nicheskoy khimii, v. 7, no. 4, 1962, 003-806 TEXT: Composition and propertien of the thermal decompooition products of sodium- and potassium meta-niobate were studied in vacuo. The aggregation of volatile dissociation products In the reaction zone was controlled In a vacuum unit by means of a MoBain quartz spring balance (for K- and Na metals at > 8000C) and by measuring the pressure with a7iT-2 (LT-2) manometer tube (for 02). The alkali metals were condensed in a quaKtz tube. The bright coating was dissolved in a3ua dests and titrated with 0.1 N HCl. Tests were first conducted at 400-800 C and 1.10-4 mm Hg. Pure 02 was separated in the decomposition of NaNbO3 in Pt-, Ta- and quartz vessels. The rate of separation was in the sequence Ta>quartz,> Pt. Further experiments wore, thereforej conducted in Ta Younels saturated with 02- A KNb03 weighed portion was heated for several hours at 7500C, until constant oxygen pressure was established. The reaction vessel was cooled to room Card 1/2 5/076/62/007/004/005/016 Thermal decomposition of B11O/B1O1 temperature and the oxygen pressure wan lowered to 1-10-4 mm Hg. Decrease of the equilibrium preaBure of 02 proves that the system is bivariant and possesses two degreesaf freedom (temperature and concentration of the solid decomposition product in the initial ceta-borate). No new phase was formed in the decomposition of KNb0 at 400-7500C, as it in only impoverished in 02' Niobium bronze is foQd with good conductivity, slight paramagnetism, and alkali- and acid resistance. NaHbO 3 and KNbO 3 decompose at > 7500C under separation of alkali metals, the degree of decomposition increasing with the temperature. KIM 3 decomposes more easily than WaNbO Y The color changes from greenish-blue at 750-BOOOC towards black at 12000C. The residue was investigated roentgenographically. A great number of lines proves here the presenoe of NbO2. The origin of the remaining lines has not yet been explained. There are 2 figures and 4 tables. ASSOCIATION: Ural'skiy politekhnichookiy institut im. 5. M. Kirova (Ural Polytechnio Institute imeni S. M. Kirov) SUBMITTED: April 7, 1961 Card 2/2 OREM KRYLOV,, Ye,I,j MITER,*, I.A.1 STRELINA, M.M. Tharmal decomposition of potassium and sodium metaniobates. Zhur.naorg.khim. 7 no.41803-806 Ap 162. (KRA 15W 1. Urallskiy politakhnicheakiy institut im. S.M.Kirova. (Potassium niobate3) (Sodium niobates) YEGOROV, Yu.V.; KRYILV, Yea ;-TKACHENKO, Ye.V. -vowwmmm~ I A~mlysis of the sorption capacity ofdron hydrbxide. Trudy Ural. po1itekhAnx~.nc,.l2lt39;*" 162. (MIRA 16t5) (Iron hydro3cides) (Sorption) YEGOROV, Yu.V.; KRYLOV, Ye.I. Effect of the mass of a collector (hydrated oxide) on the sorption of trace amwints of certain radioRctive isotopes. Itadiokhiniia 5 no.2005-211 163. Characteristics of the sorption uIt' strontium 90 by active manganese dioxide. 211-215 (KMk 16s10) 3ANNIKOV, Tupl.1 KRYIWV, ZOLOTAVIN, V.L. Magnetio sudoeptibility of iron vanadateB, Zhur,nearg,khim. 8 noe5s1157-~160 Vq 163, (MIRA 160) lo Urallakiy polltakhnioheakiy institut imeni S.M.Kirova. (Iron vanadatea-Magnetic propertisa) KRYLOV, Ye.I.; Pinayeva-Ztrelinap M.M. Orthotantalatee of lanthanump samarlump and europlux* Zhuro neorg. khlm. 8 no,lOs2254-2257 0 163o (MM 16;10) 1. Urallskiy polltekhnicheakly institut im. S.M. Kirova. (Tantalum compowidS) (Rare earth compounds) KRYIXP vAe,l.; SANATINAO V,N, Samarium and ourori.%im orthontobettes. Zhur. neorg. khim. 8 no.11:2507-2509 11 163. (MIM 17: 1) 1. Urallokiy politakhnichookiy inatitut. i N]KCIL,ViEV, V.M.; BAGETSOV, V.F.; KRYLO", Yo..I.; - N, Scrl)ti.cn of microquantltipii of coMum 134 by wmi-,lite under (~jnamlc conditionoo Zhur.prikl.klilm. 37 JI 161,. (MIRA 18,4) IWO V.I.; ANATINA, VA. ; LAPITAlf, A 7. PlagnatIc properties of potaosium sall.2 ar Ids. Zhur. neorg. khim. 10 no.L272-2715 Ja 165. 1. 'ubmittrA Sept, 16p 1963. . .. . ...... L 3680-66 EPF(c)AwT(m)/Eyip(k)AYIA(c)AwP(b)AwP(t) IJP(c) JDIHYIIJG ,ACCESSION NM AP5012966 UR/0070/65/010/005/1017/1021 546.76111 AL)THOR: Proskurnikov, As A. Krylov. Xe. Y q 5 .TITLE., Synthesis and pr4erties of chromium hydride ~SOURCE: Zhurnal neorganicheskoy khimii, v. 10, no. 5, 1965, 1017-1021 TOPIC TAGS: chromium platin I chromium compound, hydride, electrolysis ,ABSTRACT: This paper is t~ text of a report given 28 November 1963 at the Firs-t- :Conference on the Chemistry of Inorganic Hydr'des, Moscow~ffn-i-ilf~t-i-'Z~f-General an CEn~Er7j~~nl 6 - Ch-e"mfis-f-r-y-- -N-.- --- S-. - -K-u-r- n--a-- -_q f authors kov. Aca eTy f_~qie es SSSR.,IITI~p ~~-onil-d-e-r ti~e---'~-ffect oi-ia--ii~'-o~us-f"a-*c'-t"o-r-s'-'in"'-e'-l-e-c-tr-olysis (electrolyte composition, current density, temperature) on electrolytic synthesis of chromium hydride. The purpose of the study was to determine whether chromic anhydride in the electrolyte. can be partially replaced by sodium bichromate. The stability, microstructure and magnetic properties ofthromium hydride were also studied. The methods and equip- ment used are briefly described. Curves are given showing solubility of hydrogen in chromium as a function of CrO3 and 14a2Cr2O7 concentrations in the electrolyte ;Card 1/2 W, L 3680-66 ACCESSION NR: APS012966 at various cathode current densities. Hydrogen solubility in the cathodic chro~ .mium increases with a reduction in current density and also with an increase in -,the concentration of chromium anhydride. Maximum hydrogen concentration (Cr:H 1:1) is reached at a CrO3 concentration of 000 g/l. Hydrogen solubility in- ,creases with the addition Of Na2Cr2O7 until a maximum Cr:H ratio of n-0.9 is reach-* ,ed at an electrolytic composition of 200 g/L CrO3+400 g/t Na2CrZO7. The hydrogen ,solubility begins to drop off at this point with an increase in ?1a2Cr2O7 concentra-: .tion. The yield with respect to current also falls off shar3ly at this point, band therefore current densities should be kept above 15 a/dm . It was found that, ,stoichiometric CrIl is deposited from an electrolyte containing 400 ?,/t CrO3, 400 g/Z Na2Cr207 and 4 9/L 112 S04 at current densities from 15 to'50 a/dm2. Maximum hy- drogen absorption in the chrome deposit in observed at 0 Na2Cr2O7:CrO3 ratio of 0.5-1.2. The magnetic moment of chromium in Cril was calculated on the basis of meaT surements of susceptibility in the temperature Interval from 193 to 2950K. The value of this moment was found to be 1.73 v., which corresponds to a single un- paired electron, Experimental measurements show a value of 1.77 w., which agrees quite well with the theoretical value. Ori-Y. art. has: 8 figures, 2 tables. ASSOCIATION: Urallakiy politekhnicheskiy institut Im. S. M. Kirova (Ural Poly- technic Institute) 0 SUBMITTED: WanW,` ENCL4. 00 SUB CODE: GC, MM Card 2/2 NO REF SOV: 000 OTHER, 008 1k L 13103_!!04_-__.' 7WANEWLTI-w-ut 1-w(b)- Jq(o) JDJ~97, ...... /1566/1568 iAL-C-NRi AP5025795 SOURCE CODE: UR/0363/65/001/009 t AUTHOR: Pinayeva, M. M.;_Krylov, Ye. I.; Ryakov, V. M. ORG: Ural Poixtechnic Inatituto im. S. M. Kirova (Ural'skly Politsk nicheskly institut) TITLE: Magnetic properties. f gadolinium, dysprosium and holmium oxi es and o-rthotantalates C I? --- 1~ I ') 7 7 -SOURCLS., AN SSSR: Izvestiya.- Neorganicheskiye materialy, v. 19-no. 9,-1, 1965, 1566-1560 TOPIC TAGS: magnetic susceptibility, gadolinium compound, dysprosium compound, holmium compound, tantalum compound, paramagnetism. magnetic moment ABSTRACT: The magnetic susceptibility of Gd203, DY203, HojO3, GdTa041 DyTa04, HoTa04, and Ta205 was mea.sured by the raraday method in the range of 291-12730K in avacuum at-various magnetic field strengths (8100-10200 Oe). It was found to be Independent of the magnetic field strength, and to be adequately described by the Curie-Weiss law (ex- cept for GdTa04), X. z C/ (T - 0) and for GdTaO4 by the Curie law XH C/T. The decrease in the Weiss constant from gadolinium and hol- UDC: 546.65'221 + 546.651883.5 Card 1/2 L 13103-66 ACC NRi AP5025795 mium oxides to their orthotantalates Is attributed to magnetic dilu- tion. All the orthotantalates studied were strongly paramagnetic. The effective magnetic :moments were calculated from the formula Peff + where g is the Lande factor, and were found to be very close to -the ex- perimental values for all the compounds studied. In conclusion, the authors express sincere thanks to 0. P. Shveykin for providing the ap- paratus for measurements of magnetic susceptibility. Orig. art. has: 3 tables, 1 formula. SUD CODEt 07/ SUBM DATEt 26May65/ ORIG REF: 004/ OTH REF., 005 2"/2 1W:.*K'u6J I KIN FRY ~(Jv~ Ye. 1, Marrvi"c sus~-el,M11ity of t:rivallent, in chromic asid aolutions. 1 kh1m.t,"kh. 8 no.4:583-586 165. I. Ili-a' Igkty plitekNitcheskly inutitut, kafelra khlimii I taktinologii redk1kn 6~W ?01,'(:IIAYNOVA.. V.11.; CHECIiNEVA, AA , KPTICIV, Ye.1, Compoundn of platinum with phenyl substitutfid thIO8eMIC.4r- bazides. Zhur, neorg. khIm, 10 no.2t535-537 F 16c, iMIT(A 18,11) 1. Ural'skly politekhnlcheakly Inatitut. 2ubirdtted May 1964. L 21190-66' EWT(m)MMAWO IJP(c) JDImAu ACC NR: AP6008049 SOURCE CODE: UR/0020/661166/004/0876/0979 AUMOR: Krylov, Ye. L! Sharov, V. A.; Degtyarev, Y. r.- ORG: Ural Polytechnic Institute In. S. M. Kirov (Urallskiy politekhnicheakly institut) TITLE: Polynuclear complex compounds of nickel carbonate with hydrazine 16-079- SOURCE: AN SSSR._ Doklady,_v. 166, no. 4, 19 -66, TOPIC TAGS: nickel compound, hydrazine compound, complex molecule, carbonate ABSTRACT: The paper reports results pertaining to the synthesis and determination of the structure of basic nickel carbonate (N12(OH)2(1120)2'CO3 and complex compounds of the latter with hydrazine, viz., Niz(0020202N2114CO3, N12(OH)2(N2H%"'5_1O3-3H2O,;, and Ni(N2H4)3CO3'1-5"20- X-ray phase, chemical, and thermographic analyses, dater-) mination of electrical conductivity, magnetic susceptibility measurements, and con-i ductometric titration with HC104 were employed. The experimental data suggest the following structure of these compounds: co, oil Card 1/2 UDC: 541.49.546.264174 546.171.5 T-7 C,,i~ :t~ or L 21190-66 ;ACC HR- AP6008049 lllOIC03 0" N N," 41,03 .'It is concluded that hydrazine complexes with an Insufficient number Of H2H4 M010- .cules have a polynuclear, structure with hydrazine bridges. The formation of the com- 'plexes (Ni2(OH)?.'(H20)2N2H41CO3 and IN12(OH)2(N2H4)51CO3-3H20 from basic nickel car- 4bonate is apparently due to a gradual penetration Of H2H4 molecules into the inner icoordination sphere, CO-3 then H20 being displaced Into the outer sphere. The paper' iwas presented by Academician 1. 1. Chernyayev on 9 June 1965. Orig. arg. has: 2 'ifigures, 3 tables. !SUB CODE: 07/ SUBM DATEt' 07Jun65/ ORIG RM 004/ OTH REFt 004 Card 2/2 J)P o 'iP6 AkcnN~,' 007905 AUDdOR: SOURC& C009i UR/0149/66/000/001/0031/0033 Krylovp Yet to 'Al ORG-,- -gral PolyteShnic lae tttuq,~_ Rare Netals Dept.(Ural'skiy politekhnichaskiy institute Kafedra radkLkh matallov) TITLE3 Production of nickel powder.)y reducing nickolous hydroxid ith_hyjLS!D* jqT37 -7,7 ~w SOURCE; IVUZ. TevetnaydmetAlluriLya, no, 1, 1966, 31-33 .117 TOPIC TAGS: powder metal, nickel compound$ chemical re-luction, hydrazine ABSTRACTs The reaction was accomplished in air at,21*C in a glass vessel I ca-in diameter and 8-cm in length, for 33 =in, on using pure nickelous hydroxide of the com- position 51 Ni(OH)2*NiCO *41t 0 and a 92% solutioa of N it, obtained frota hydrstine hy- drate by Raschig's meth2 Q~ Raschig. Bar,, vol. 43, f921 (1910). The solid prod 'ucts of the reaction were filtered, washed with water and alcohol and dried, whereupon they were subjected to X-ray phase analysis and chemical analysis. Findings: Nt(ad)2 does not form complex compounds with N21141 i.e* Ni metal is the sole product of the re- action with hydrazine. Further, the degree of the reduction of Hi(011) 2 increases with increasing concentration of HA; thus, reduction with 92% hydrazine (solid-liquid ratio 1:2.33) is of the greatest interest from the practical standpoint. It is merely Card 1/2 ACC NRI AP6007905 necessary to prevent the spontaneous heating of the mixture, causing the evaporation of hydrazine. The Wi powder thus obtained was analyzed for dispersity and pycnometric ,density in toluene at 230C. The dannity proved to be low, 6.78 g/cm3, apparently be- cause of the presence of pores. Thus, compared with the previously known methods of producing NL powder, which are -intricate and require intricate apparatus (alectroly- sis, autoclava treatment, the carbonyl method), the proposed method is simpler and more workable, and yields Ni metal powder that meets the requirements of powder matall, urgy. OrLg~ art, hass I figure, I table, SVB CODES 11.0 07/ 1' SM DOES MusW ORIG REFt 000/ OTH RUs 004 2/2 L 42379-66 E6T (m T IJP(C)--. Al )/r/EWP(t)/ET A.- ACC NR, A 0-2-2-8 SOMICEE CODET_Wod~8 Oil ow 07 AUTHOD _Pinayeva,_.~, M.; ~Mlovy__Ye. 1. 0R0: Ural Polytechnic Institute im. S. 14. Kirov (Urallskiy politokhnicheskly ins 7 TITILt Synthesis And properties of ytterbiAand lutetium orthotantalates SOURCE: Zhurnal noorganichoskoy khimli, v. 11, no. 4, 1966, 728-731 TOPIC TAGS: ytterbium compoundq lutotium compound, tantalum compound, magnetic sus- ceptibility , N vcx.) avict V) ~;is ,LBSTRACT: The oaper continues a study of the properties of compou.-.ds of the general formula ABC4, formod by rare earth elements with the anion of orthotantalio acid. Ytterbium and lutetiiii orthotantalatos were synthesized from the oxides. Measurements of the magnetic susceptibility of YbZ03 , Ta 205, and YbTa04 in the range of 293-1273*.K showed that the tormerature dependence of the magnetic susceptibility of Yb 203 and YbTa04 follows the ~urio-Weiss law. The effective magnetic noments of Yb3+ in Yb and YbTa04 were found to be resDoctively 4.38 and 4.36 pD. X-r-~'. diffraction analogi no monoclinic (with" of YbTaO4 at roon temperature s6wed the presence of two 'Ohases unit cell i)arameters a = 5.035, b = 10.82, o = 5.23, 61T~2 'Nhe other tetragon~i (with unit'coU paramoters a = 5.10, c = 10-81). It was found that LUT&O also exiq� in the form of two phases with parameters a - 5.03, b = 10.78, a - 5-239 840229 Card 112 UDCI _546,8816!6 L 42079-,ij ACC NR, AP6022,891 (monoclinio), and a 5.09t c 10.79 (tetrahedral). Orig. art. hast 2 figures and. 1 5 tables. SUB CODE: 07/ SUBM DATEI 30Ju164/ ORIG REFj 004/ CMI REF: 003