SCIENTIFIC ABSTRACT KUKHTIN, V. A. - KUKHTO, A. P.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

RMY, Gillm; KUKHTIN, V.A.
AddItion of phosphoras and phosphinous acid estere to conjugated
systems, Part 4., Addition of phenylphoophinaus acid eaters to'
c( 1 0 -unsaturated aldehydes ard acids. Miur. ob. khim. 28 no.'41
939-941 AP '58. (mm ., 1, ..q)
1. Kazanakiy khImIlko-tekhilologicheskly Institut.
(Phosphinous acid) (Aldehydes) (Acids)

AUTHORS: Vukhtln2 V~ A., r. t'l I -m Kamay
TITLE: ~o i~(11-1 F'Stpra of Phospherous
Pb-,cDh,Lni(- t!o1d to Conjugete-d. S y s t e ,,tyedineni ye
PO.Lnykh efiicv foEforistety
sopl-ya?henflym 5.1)4teir,3m
V. On I.hL- Probl-Pni e,1' Lhe Conversion Mecham ~~m of Tri alkyl-
t h~ jysteffl~; (V. X 0 mekhan.17,me
V im,-i d V rty 4 q 4 s f em a m i
M.
PERIODICAL-, Zhurnf,-tl -)b-h~~Ilc-v Yhim.ii,, 19'~P; -'70.10 're., Ur :i~
~3STPACT: Tn previo-!).a repr--r"s (ref.3 1,?) the authr.~rs described a new
kind of rezrm) in-
T, Lhy i.,,~ the articn of the group
C - C! -.4"Y'stems or. (h-~ esters of phosphcrous
ac %4
3:!'ds. Tbese ronotions take p`a,~u accord,~n~,
to the ';L!WMt! I'. Thts i~chmnkt t,,, the authors
demands ionization ;-T the reacting
molc_cu2p con rewith it
d vstem. Tn connpo,~jcn he'
could be aE1,c,:;-!---:t zhe aolvents promoting 4.c.,nm.zation could.
acceleratr-- the ad(li-rzior remtion of phosphi'Les tc the
Card 1/3 conjugated Tt~e on thr- -act!.on intpncity

Addition of the Full Eqtpr-s of Ph-)-vh(-.r,,~us Acid e.nd (-.I- 2e, - 9 -
Phost)hinic ;.(-Id to th.~~Conjugat~ed~~ysterns-
V. On the Pr--blem of t~,,e nrnversior Vttc-halnj?m of Traa."~v;-,
phosphites WiLhConjugated &9YSteM[3
(-f Lhe cf tributylphosphite i~,, mp-a,try.:i-
acid -in variouE- solventi Proved thi, :),co. mp Under the
mentic.)ned experimental cnitiditions. Hle results mertioned. in
table I could be obtained, The experimental data show that
the strorger the polar :2o!.v(?.rt Uie more intenSiye the
conversion react;.on takes place.: in th...s the ccl,.'-ents,
which have a hian dielee*ric corqtant- acceier,%te the
the weakly -;o1vPiats --.!~,w It down. as
conpared t.-~ Lhe cane of the rea6tion tak:Lng piace withovt
solvents. Thus the experimental results can eerve as prcof
of th(~ earlier suggested scheme. Just a8 xpll thr~ reactions
of triulkylphosphites with ct,-0-unsitturated acids and halogen
alkyltl were investigated in which canp the assumption by
the that Lhe phosphite in the 1'jr9t phase had
rpr.("'predominantly with- the a-P--unsaf-t-trated acid, and In
the second pha-:tp,llle halogen n1kyl with the formed dipolar
ion or the intormedinto produt-1; nocordint- to -riiom~
Card 2/5 fully proved, 'Pil-ece are 3 tables an,! :) Soviet referdences.

Additi.on of the Full Fsters of Phosphorous Acid -and :~f
Phosphinic Acid to the Conjugated Systems.
V. On the Problem of the Conversion Mechanism of Trialkyl-
phosphites 'With Conjugated Systems.
ASSOCIATION: Kazanskiy khimiko-tekhno1ogioh=-,-k1y institut
(Ka zan IGhemic,,~!-TechnologlcFil
SUBMITTED- April 15, 1957
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AUTHO' R S - A., Orekhova, K. 11. S01019-28-1o-33/6o
TITLE: Affiliation of the Complete Esters of Phosphorous Acid
and of the Phosphinic Acid to th,s Systems
(PriBoyedineniye polnykh efirov fosforistoy i fosfinistykh
kislot k sopryazhennym sistemam)VI.ioih! Action of the
Alkyl. Ealides and of the alp-Unsaturated Acids on
Trialkyl Phosphitas (VI.Sovmestnoye deystviye galoidnykh
alkilov i app-nepredellnykh kislot na trialkilfoafity)
PERIODICAL; Zhurnal obshche khimii, 1958, Vol 280 Nr lo,
pp 279o - 2797 ~USSR)
ABSTRACT: In connection with the experience collected in earlier
papers (Refs 1,2~ the-authors continued their in-
vestigations in the same direction by investigating the
joint action of the afp-unsaturated acids and alk7l
bromides, as well as alk'yl iodides on the trialkyl
phosphites. The experi7w3nts with alkyl bromides fully
proved the earliez- propused scheme, with the mixed
p-dialkyl phosphonium carbonates and the corresponding
alkyl halides being obtained (Table 1). The reaction
Card 1/3 of acrylic acid and alkyl bromide with the trialkyl

Affiliation of the Complete Eaters of Phosphorous SOY/79-28-le-33/6o
Acid and of the Phosphinic Acid to the Conjugated Systems. VI. Joint
Action c-f the Alkyl Halides and of the a,P-Unsaturated Acids on Trialkyl
Pho&phites
phosphites takes place more enerC;etically than that
of methacrylic acid. in the reaction of ethyl bromide
with the intermediate product which is obtained
in the affiliation of tributyl phosphite to the
methacrylic aoid the butyl bromide and an ethyl ester
of the P-dibutyl phosphon-c-i-sobutyrie acid rias
separated (Reaction Scheme 1). The joint reaction of
mothaorylic acid and alkyl iodides with trialkyl
phosphites offers only small yields of esters of the
phosphono isob-ityric acid (8-16%)(Table 2). The
reaction takos place not only according to the above
mentioned scheme. In driving off esters of the general
formula RIP methacrylate and dialkyl phosphorous
11 (O'R)2'
0
aoids werd'obtained (Table 2 and 3-~herme 2). ConcluGion:
It is found that on the basis of the experimental
results the joint reaction of methacrylic acid and alkjl
Card 211,3 iodides with the trialkyl phosphites can take Place

cloy
Affiliation of the Complete Faters of Pho8pborous ; /79-28-lo-33/6o
Acid and of the Phosphinic Acid to the Conjugated Systems. VI. Joint
Action of the Alkyl Halides and of the a,P-UnsaturatEd Acids on Trialkyl
Fho-,,phites
in three different directions according to the
conditions prevailing last Scheme). There are 2 tables
and 3 references, 3 of which are Soviet.
ASSOCIATION: Kazanskiy khimiko-tekhn-o1agicheskiy institut imeni S.M.
Kirova i Kazanskiy fil~lal nauchno-issledoyatellskogo
kinofoto Chemotechnological Institute
imeni S.U.Kirov and Kazan~--Branch of the Scientific Research
Tastitate of Cinamtography and Photography)
SUMUTTED: September 17, 1957,
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ADTHORS: Kukhtinp V. A.,
S1nchenRo,--L7A.
Kamay, Gillm, 20-3-24/59
TITLE: Telomerization of Metacrylic Acid With Trialkylphosphites
(Telomerizatsiya metakrilovoy kisloty s trialkilfoafitami).
PERIODICAL: Doklady AN SSSR, 1958, Vol. 118, Nr 3, PP, 505-508 (USSR)
ABSTRACT: The first two mentioned authors proved that (ref. 1) trial-
kylphosphites under the action a, P-unsaturated aldehydes
and acids can be subjected to a regrouping according to
Azbuzov. The authors continued research in this line and
stated that on oertaln conditions not one but several molecules
of metacrylio acid can be combined with one molecule of
trialkylphosphite, so that reaction in this case becomes
telomerization. The reaction takes place without catalyst
and at room temperature; triethylphosphite must be carefully
purified (with sodium) and must have been subjected to
fradtioned distillation. The amount of the telomer how-
ever, also in this case is very small. Therefore a suitable
catalyst had to be found. Benzoylperoxide proved to be
the best catalyst. Depending on the quantitative ratio between
Card 1/3 initial component and catalyst telomers of different mean

Telomerization of Metacrylio Acid With Trialkylphosphites 20-3-24/59
molecular weight were formed. All telomers are white powders
without nignificant melting point. They can be softened
and carbonized when heated. When heated the telomers are
soluble in mothancil and acetic acid. The experimental results
are collected in table 1. A diagram of the tolomerization
based on earlier works is given (ref. 1), although also
another structure of the telomzjr is possible, It was uot
inveetigated here. In order to prove the die-gram suggested
anequimolar mixture of triethylphosphite and metaorylio acid
was stored at room temperature until triethylphosphite he.4
disappeared completely. In this an intermediate product of
the regrouping according to Arbuzov which corresponds to the
first stage of reaction was suggested. Only then a 4-fold
excess of metacrylio acid plus catalyst was added. An
intensive formation of telomers with a good yield set in
immediately. This result proves: 1.- The formation of an
intermedi4te Product, and 2.- The probability of the
telomerization mechanism suCSested. Unexplainedt however,
remains the part of the catalyst as well as that of the
mechanism of its influence on telomerization. With the
Card 2/3 'increasing the mean molecular

Telomerization of Netaorylic Acid With Trialkylphosphites 20-3-24/59
weight of the telomer increases. This is also the oase
with the increasing concentration of benzoylperoxide. The
capability of the Intermediate product to enter telomerization
makes possible the assumption that the binding P-0 is of
ion character. From this is deduced a presumable scheme of
the structure of this intermediate product.
There are 2 references, I of which is Slavic.
ASSOCIATION: ftwAnl, Cbmaical wA,Tacbholdgical Institute IWeni. S..M. 'Kirov
-.4 (Kazattakiy khimiko-tekhnologioheskiy institut im.
S. M. Kirova).
Yj=n1Br,of the Scientific Research Institute for Cinema and
Photography (Kazanskiy filial Nauohno-isaledovatellskogo
PRESENTED: November 13, 1957, by B.,A. Arbuzov, Academician
SUBMITTED: June 28p 1957
AVAILABLE: Library. of Congress
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AUTH04:S: Kukhtin, V. A. , Pudovik, A. Iii. (Kazaal ) SOVI"*74-28-1-5/5
LI T Several New T.~rpes of' tlrbu,,,(jv
(1-jokotoryyc novyyu vidy pere:,antppi-covki Arbuzova'j

J. I U A I,,: Vol 26, 1'r I (USSE)
I..'spekiii khimi-J, 1'9519 ,
.."i"Y: .','he reaction listed in -the scientific publican tion-- ~ns the
rearrangement of Arbuzov ~,.-as diBoov*pred in 10/05 by
A. Ye. Arbuzov, At present it ropresonts one of the most
important methods for synthesizing eoter.,, of' phosphinic acids
and their derivatives. The authors of this LaDer give a review,
of the most recent research work on this reaction and on
broadening its application. In summary it may be said that the
chemistry of trivalent phosphorous has entered a new phase o-z'
development. The basic typo of Arbu-zov rearrangement has been
found to to characteristic of a whole now series of reactiont-,
of phosphites with various reagents. The current undorstandinf~-
of the Arbuzov reaction, which has been concerned only with
the effect of alkyl halogens on the eoterss oC trivalent
phosphorous (Refs 86, 87), must be expan(led on the basis of
existent experimental material. -The transformation of esters
Card 1/4 of trivalent phosphoroue to di-rivatives of pentavalent

Several New Types of Arbuzov Rearrangements SO-V/74-28-1-5/5
phosphorous, which takes place using saturated as well as
unsaturated electrophilic reagents -aith and without halo,~-on
atoms, should be considered a part of' the Arbuzov
rearrangement, since it is accompanied by the formation of a
now P-El bond (El- C, 11, 01 S, and others). 'Phe nature o1' the
rearrangement- ccn,-Aets in the primary attack on the eopccially
electrophilic part of the molecule by the nucloophilic
phosphorous atom to forng usually, an intermediate form. Thic,
form then splits off the ester radical of the phosphite
thrbUghthe effect of the especially electronegative part of
the associated reagent form the endproduct, in which the
P=O bond has formed. There are at least three basic types of
Arbuzov rearrangements: 1. Rearrangement under the effect of
non-conjugated systems:
01+ ~_ + x
(Ito) P: + Z --+X -(RO) P )(RO
3 3 )2P_Z + RX
z 0
Card 2/4

Sev~3ral Types of' Arbuzov lqearrangemcnts SOV/74-28-1-5/5
2 "carran-cmont, tindol- tho effoct of C-. vi-conjugated system.
Th i s a) Reaction
typo cin occur in the dir~~ctionr.
accordinig to ocheme 2-1 -uithouL tvinsfer of the reaction center;
4 13
+
3 +
C='/, 0
b) Reaction accrordin~; to scheme 4-1 or ,-.-ith tran.9fer of the
roaction center:
S-
4 3 2 1 1
SVI
(1w)3P: + ""=C-C-x Z-0 3 P\ --~,(Jio)2P-,",-M + RX
Z-C=C A
3. Rearrangement involvina Tr, Ir-conjugated systems
apparently occurs alvrays by schelac 4-1 with transfer of the
reaction center:
Card 3/4

Several New Types of Arbuzov Rearrangements SOV/74-28-1-5/5
4 3 2 1 C'
(RO)zP: + Z=C-C=" P --.3,(PO),P-Z-C=C-Xll
3 \ C -H
z - 0
These three basic typeS apparently cannot include all the
various cases of this reaction. Complicated electron systeins
with a mixed conjuEa-tion (e.g. halogen acryl-ates, lactones,
and several others exhibit specific behavior in the rpaction~
Reagents which tend to form free radicals can be included in
the Arbuzov rearranC;emcnt under certain conditionsq according
to -the radIcal-chair mrichanism, -;,rhich differs -from all tile
others mentioned above. Esters of trivalent phosphorous have
not only the tendency to undergo the Arbuzov rearrangement, but
they can.also undergo numerous other reactions. Further
research work on the rearrangement of Arbuzov promises to
yield new and interectinff, results, There are 87 rreferencE~s,
57 of which are Soviet,,
Card 4/4
USCOMM-DO-60841

AUTHORS~: Kuk.htin V A Gillm Namay, SOV/79-29-2-32/71
j'Ti~nchenko, L. A., Orekhova, K. I.T.
TITLE: Affiliation of the Complete Eaters of Phosphorous Acid and
Phoaphinic Acids to Conjugated Systems (Prinoyedineniye pol-
nykh efirov foeforistoy i fosfinistykh kislot k sopryazhennym
siatemam). VII. Telomerization of the Methacrylic kcid With
Trialkyl Phosphites (VII. Telomerizatsiya metakrilovoy kis-
loty s trialkilfosfitami)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 2, PP 510-515 (USSR)
ABSTRACT: In continuation of the common reaction of a,p-unsaturated acids
and alkyl halides with trialkyl pho3phites (Refs 1)2) the
authors intended to find the catalyst most suitable for telo-
merization, to determine the factors which exercise influence
upon this reaction and to determine the structure of the
telomers obtained. They found that carefully purified tri-
ethyl phosphite can telomerize with methacrylic acid also with-
out a catalyst. Temperature does not inatter in this connection.
The yield is small in this case (Table 1, Experiment 13).
However, if a methacrylic acid is used for a rhile that Is
Card 1/3 not stabilized with hydroquinone, the reaction takes place in

Affiliation of the Complete Eaters of Phosphorous SOV/79-29-2-32/71
Acid and Phosphinic Acids to Conjugated Systems. VII. Telomerization of the
Methacrylic Acid With Trialkyl Phosphites
a very violent manner under intense selfheating and with a
high yield of telomers (Table 1, Experiment 12). The trialkyl
phosphite that is purified only by separat 'ion through dis-
tillation does not telomerize with a methacrylic acid that was
liberated from the inhibitor immediately before the experiment,
It was interesting to know the way in which this telomerization
would take place in the presence of triethyl amine and sodium
methylate tested by R. M. Connel and 11. W~ Coover (Ref 3) as
catalysts. Yet only small yields were offered by these experi-
ments (Table 1, Experiments 1,2). Also the application of
alkyl iodideo for telomerization did aot quite meet expectations.
Benzoyl hydroeen peroxide turned out to be the most favour-
able catalyst for telomerization. In dependence of the molar
ratio of the initial components, on the noncentratton of the
catalyst and the phoaphite radical telomers with various
avera,,re molecular weights were obtained in this telomerization
(Table 1). According to previous and the preseht results it
may be assumed that the above-mentioned telomerization takes
Card 2/3 place according to the scheme mentioned in concluuion,,

Affiliation of the Complete Eaters of Phosphorous SOV/79-29-2-32/71
Acid and Phosphinic Acids to Conjugated Systemo. VII. Telomerization of the
I
L
iethacrylic Acid With Trialkyl Phosphites
Thus, the structure of telomers resulting from the telomeri-
zation of methacrylic acid with trialkyl phosphites was
investigated and a scheme of reaction was suggested in ad-
dition. There are 2 tables and 3 references, 2 of which are
Soviet.
ASSOCIATION: Kazanskiy khimiko-tekhnologicheskiy institut (Kazan' Institute
of Chemical Technology)
SUBMITTED: December 26, 1957
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S/058/60/GOO/007/002/014
A005/,4001 -
Translation from: Referativnyy zhurnal, Fizika, 1960, No. 7, P. 37, # 16068
AUT'HORS, StepMov. V G Kukhtin V A
TITLE- An Ionic Frequency Converter for Feeding a
PERIODICAL: Izv. Tomskogo politekhn. In-ta, 19M9, Vol. 96, No. 1, pp. 119-129
TEXT. A series of circuits is proposed of ionic frequency converters for
feeding a betatron, which do not comprise --,n inverter unit and make it possible
to produce frequencies of 150, 300, 450 cps and more. The description is given,
and a detailed analysis is per-formed of two types of circuits of valve frequency
converters. The first circuit makes it possible to obtain at the output one-
phase voltage of tripled frequency; such a converter consists of two-three-phase
controlled lonic rectifiers operating alternately with 120 0 electric leg angle.
In the circuits of the second type, both half-periods of the transformer secondary
winding are utilized. Such circuits can be applied '.-o converters eith the
frequency ratio f2//f, - 3, 5, 7, 9 etc. A comparison of the frequency conversion
circuits is carried out. The calculation methods of the typical transformers and
Card 1/2

S/058/60/000/007/002/014
An Ionic Frequency Converter for reeding a Betatron A005/AOOl
the conversion power coefficients are presented. The linear diagrams of the
secondary transformer phase -voltages and the voltages at the converter output
are given. Results from experimental investigation are presented for a circuit
built with thyratrons. The circuits proposed have lower cost, larger efficienoy,
higher simplicity, and reliability In comparison with circuits having an
inverter unit. [Toniskiy politekhn. in-t.]
V. A. Kramchenko
Translator's note: This is the full translation of the original Russian
abstract.
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5(2', 3)
AUTHORS; Kukht-in, V. A., Orekhova, K. M. BOV/20-124-4-25/67
TITLEs Addition of Complete Esters of Phosphorous Acid to
p-Benzoquinone (Prisoyedineniye polrykh efirov fosforistoy
kisloty k p--benzokhinonu)
PERIODICALs Doklady Akademii nauk SSSR, 1959, Vol 124, Nr 41 pp 819-821
(USSR)
ABSTRACT: In previous papers the authors described some new reactions of
the above-moytioned esters with variousirr -conjugated systems -
the esters of ot,/3-unsaturated acids (Refs 1, 2) with
0e,/3-unsaturated aidehydes (Ref 3) and diacetyl (Ref 4). Thesa
reactions take place according to Arbuzov's scheme uf rearrange-
ment (Refs 2,, 4). In continuation of the study of the new kinde
of that rearvargement this paper deals with the reaction of
phosphites with quinones. The authors g1ve a survey of the
respective publications (Refs 5-8). They synthesized addition
products of some trialkyl phosphites to p-benzoquinone. Their
constants are giver. in table 1. The saponification of these
substances in weakly acid medium yields hydroquinone as the
main. product. The saponification with alcoholic-aqueOU3 alkalisr.
Card 1/3 takes place also an the separation of the phosphorus-containing

Addition of Complete Esters of Phosphorous Acid to SC.-V/20-124-4-2-/67
p-Benzoquinone
portion of the molecule. Yet these data do not' confirm that
the products mentionad possess a structure (IV) (see Scheme)
since the bond P--Ar car. be easily hydrolyzed if thers is an
oxy or amino group in the ortho-or para-position (Ref 9). Thus,
the addition product of tripheny! phosphinp to p-benzoquinone
(I) on. the formation of hydroquinone and tciphenyl phosphine
oxide is easily hydrolyzed (Refs 5, 6). For the purpose of
checking the structure of the addition products mentioned
the authors carried cut a counter-synthesis of
diethyl-p-st-hoxy-phenyl phosphate, whereby a product was
obtained that differs from the addition product of triethy-1
phosphite to p-benzaquincne as far as its constants are
concv.~rned (Table 1). Iv addition to that, a free hydroxyl
group is lacking in it. Accordingly, it may be assumed that
the phosphorus ir. the additioa produczs mentioned conspicuously
is not bound to nitrogen but. to the a7omati'c ring. Lz'ke the
addition p.roducta of triphanyl, phosphi-ne to p-benzoquinone.,
these products do not possess the structure (IV) bul.- IkVI).
Unlike the trialkyl phosphites, tripheryl. phosph-jte does not
Card 2/3 react with p--benzoquinonp- at- room. temperature. If heated. for

Addition of COMYlete Esters of Pho3phorovs Acid to
p-Benzcquinone
'_()V/20-124-4-25
scme time in benzarq, a precipit-a-tion occurs. Only a car~'~~iv
amount of pheno! oculd be disti.Ued off from the liquid p-ortion
of the reaction product. It is an addition product, of a
triph9ny1j. phosph-ite motacule 'Lo a benzoqu-.Lzians molecul.,-;r and
presumiably tho product of -.he ft_,sl. jtage of reaction wit~11-11 a
structure M. The second stag~i of rearrangement accord:4--g t,:,
Arbuzov cannot be carried ont aeparatgly since thri real,,c~(111
products are resinified. 14. S. Garifl-anov recorded the apectra
of paramagnetic resoranca of ss-treral products. No formatioii
free radicals could be found in them. There are I table and
9 references, 4 of whial'i are S~~-Tlet.
ASSOCIATION; Kazanskiy fil-J%al V_qa~Bayuznog;~ na,,.i--nr.)-2..-slaiovatellskog--~
kinofotoins',iituta (KazaZ Branch of 'tvhs All-Union. S-.ie1itif-ir,,
Cinema-Photography Research Institutn)
PRESENTEI)i October 9,. 1958, by B. A. Arbuzov. Acaaemioian
SUBMITTEDt October 1, 1958
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-H* 57 J 6 J 0 66423
AUTHORS: Kulchtin, V. A., Abramov, V. S., Orekhova, K. 1. SOY/'tO-128-6-2a/62
TITLE: Regrouping of the Eaters of X-Oxy-alkyl Phoaphinic icids to
Isomeric Phosph&tes
PERIODICAL: Doklady Akademnii nauk SSSR, 1959, Vol 128, Nr 6, pp 1198 - 1200
(USSR)
ABSTRACT: The regrouping mentioned in the title (Refs 1,2) can - according
to reference 5 - only take place if X is split off as an anion.
Otherwise, a decomposition into aldehyde and dialkyl-phosphorttio
acids (Ref 6) must occur under the influence of alkalis. A
simLlar regrouping producing isomeric phosphates is mentioned iu
reference 7 (see Diagram). The 2nd author made dialkyl-phos-
phoroue acids directly act on diacetyl (Ref 8), and obtained
eaters of the a-oxy-p-aceto-ethyl-phoophinic acid (Table 1 ,
Products A). Under different conditionag products with other
constants were obtained. In a glass flask (instead of soldered-
up ampullae), d-ia]-l-J-1 phasphites with diacetyl yield the prod-
ucta B (Table 1) at-a temperature above 1000. Table 2 shows tho
influence of experimental conditions on the course of reaction
with the use of dLethyl-phosphorous acid. A comparison of prod-
Card 1/3 ucts A and B showathat A contains 8.16~ of the hydroxyl group

66423
Regrouping of the Esters of X-Oxy-alkyl Phosphinic SOV/20-128-6-2e/63
Acids to Isomeric Phosphates
(according to Tserevitinov4s method) Its infrared spectrum
shows an intensive band at 3,290 cm-i (Ref 9). Hence it seems
to be certain that A is an ester of a-oxy-p-aceto-ethyl-phos-
phinic acid. The absorption at 3250-3300 cm-1 is missing in the
infrared spectrum of B. On. saponification with barium hydrate,
it yields a barium salt of diethyl phosphate and, therefore, is
a mixed diethyl-3--keto-2-butyl ester of the phosphoric acid. A.
diagram shows the interaction reaction of dialkyl-phosphorous
aoide with diacetyl yielding the isomeric products A or B de-
pending on the oonditions of execution. Sodium alcoholate ao-
celerates this reaction and yields product B exclusively. The
authors explain the regrouping under review in a way difforent
from reference 5. An accompanying splitting-off of the haloid
ion is not necesaarf. Thus, the authors detected a now inter-
esting regrouping (as mentioned in the title) to isomeric mixed
eaters of the phosphoric acid. It takes place under the influ-
ence of oodium alcoholates in alcoholic solution, or due to the
influence of dialkyl phosphites on diacetyl at 125-1300. The
Card 2/3 names of B. A. Lrbuzov, V. S. Abramov and A. S. Kapustina are
V

66423
Regrouping of the Esters of X-Oxy-alkyl Phosphinic BOY/20-120-6-28/63
Acids to Isomeric Phosphates
also mentioned in the paper. There are 2 tables and 10 ref-
erences, 5 of which are Soviet,
ASSOCIATION: Kazanakiy khimiko-tekhnologicheakiy institut im. S. K. Kirova
(Kazan' Instituto of Chemical Technology imeni S. M. Kirov).
Kazanskiy filial nauchno-iseledovatellskogo kinofitoinstituta
(Kazan' Branch of th-- Sn-iontific Research Institute of Cinemato-
graphy and Photography)
PRESENTED: June 12p 1959, by B. A. Arbuzov, Academician
SUBMITTED: June 1, 1959
Card 313

.-qf/079/60/030/04/34/080
B001/BO16
AUTHORS: Kukhtin, V. A., Oxekhova, K. M.
TITLE: Addition of Saturated Eaters of Phosphorous and Phosphinic
Acids to Conjugate Systems. IX. Addition of Trialkyl
Phosphites1to d-Diketones
PERIODICAL: Zhurnal obshohey khimii, 1960, Vol- 30, No. 4, Pp. 1208-1416
TEXTs The reaction of trialkyl phosphites with q-diketones may proceed
according to two possible schemes (A and B), i.e. with or without shift
of the reaction center (Schems 1). A more thorough investigation showed,
contrary to previous ones (Ref. 2), that the addition of trialkyl
phosphites to ce-diketones takes place on a carbonyl group, i.e. accord-
ing to scheme A. The following facts indicate thist 1) The end product
(II) (R-C 2H5 ) is not esterified under any conditions with ethanol to
give triethy' phosphate (comparison with the statement of Ref. 3)~
2) Product (II) forms a barium salt of diethyl-phosphorous acid on
saponification with barium hydroxide (comparison with the statement of
Card 1/3

Addition of Saturated Esters of Phosphorous S/079/60/030/04/34/080
and Phosphinic Acids to Conjugate Systems. B001/B016
IX. Addition of Trialkyl Phosphites to
d--Diketones
Ref- 4)- 3) According to the Raman effects of compounds (I) and (II), the
latter show no vibrational frequencies of the double bond but are rather
indicative of -the carbnl group. The intermediates M
(RI-CH 3;p"'-2H5'C3H7'C4H9j were separated in pure condition, and
characterized (comparison with the products of Ref. 1). Compound (I)
reacts vigorously with water, and is transformed to (III). This takes
place already at atmospheric moisture (Scheme 2). The affect of temper-
ature, solvents, catalysts on the course of reaction of the second step
'Arbuzov rearrangement) in the afore-mentioned reaction was investigated
Table 2). Or anic acids react intensely with compound M, and trans-
~
form them to MI). The products (I) and (II) react with phenyl hydrazine
in which connection diphenyl hydrazones are formed quantitatively.
Considering the atructure of the intermediates obtained in the Arbuzov
rearrangement, the structure of formula (A) (p. 1210) seems to be more
probable than that of formula (B). The Raman spectra were taken by
B. A,, Arbuzov and V. S. Vinogradova. The autbors mention a paper by
Card 2/3

Addition of Saturated Eaters of Phosphorous
and Phosphinic Acids to ConJugatG S-MtAme.
IX. Addition of Trialkyl Phosphites to
c(-Diketones
S/079/60/030/04/34/050
BOOI/"016
V. S. A'r-rumov, L. Sh. Belokon', and F. I. Makhmutova (Ref. 5). There
are 2 tables and 8 references, 6 of which are Soviet.
ASSOCIATION: Kazanskiy filial na-uchzio-issledovatellskogo kinofot0in3ti-Wta
(Kazan' Branch of the Motiuit Picti-ire-and Photography
Scientific Research lnstituteT
SUBMITTEDi May 11, 1959
Card 3/3

S/079/60/030/05/26/074
B005/B126
ADTHORSi Kulchtin, V. A.. Orekhovaq K. M.
TITLE: The Addition of Neutral Esters of Phosphorous Acid and Full
Esters of Phosphinic Acid to Conjugate Systems~ X. The
Reactio'n of Trialkylphosphites.1 With n,n,n-Conjugate Systems
PERIODICAL% Zhurnal obshchey khimii, 1960v Vol. 30, No. 5, PP,~ 1526-1529
TEM The authors examined the reaction of trialky p osphites with trans-
and cis-diben hyleneland with nZlacryli c acid. Triethylphosphite
joy et
VL
reacts with trans.-dibenzoyiethylone in an ethereal solution at room
temperature, --forming a thick glycerine-like product which does not
crystallize and cannot be distilled in a high vacuum without decomposition.
This inter-product reacts with water, evolving heat, and it effects their
polymerization when added to acrylates. When the reaction of triethyl-
phosphite with trans-dibenzovlathylene is carried out under more rigorous
conditions (heating to 1200), a product is obtained which, when vacuum
distill-ad, gives triethylphosphate and considerable quantities of
295-diplienylfurane. Cis-ditenzoylethylene reacts with triethylphosphite
Card 1/'5

The Addition of Neutral Eaters of Phosphorous S/07 60/030/05/26/074
Acid and Full Eaters of Phosphinic Acid to B005YB126
Conjugate Systems. X. The Reaction of Trialkyl-
phosphites With itirgm-Conjugate Systems
in exactly the same way as the trans-form. The action of water on the
above intermediate of the addition of triethylphosphite to dibenzoyl-
ethylethylene is to produce dibenzoylethane, That indicates that
dibenzoylethylene behaves on the addition similarly to p-quinones. The
above formation of 295-diphonylfurane is apparently due to the thermal
decomposition of the intermediate of the addition. 295-diphenyl.furane
also forms by dehydration of dibenzoylethane, which is produced by the
effect of dampness on the intermediate of the addition. Vinylacrylic acid
reacts less vigorously with trialkylphosphitea than acrylic- or meth-
acrylic acid (Ref. 21), A small yield of phosphorvinylacrylesters results
from the reaction of vi~;ylacrylio acid with triethylphosphite; the main
product of the reaction was a telomer, which was formed by the addition
of some vinylacrylic acid moleculen to the triothylphosphite. Only thia
telomer results from the reaction of tripropylphosphite with vinyl-
acrylic acid. The authors explain these results thust since the for-
mation of a seven-membered ring is difficult, the intermediary dipolar
ion does not stabilize itself on the ring-shaped intermediate but adds
Card 2/3

The Addition of Heutral Esters of Phosphorous S/079/60/030/05/26/074
Laid and Full Esters of Phosphinic Laid to B005/B126
Conjugate Systems. X. The Reaction of Trialkyl-
phosphites With %irgic-Conjugate Systems
some more acid molecules, forming the above telomer. The inability of
the vinylacrylic acid to form the ring-shaped intermediate, proves the
covalent form of the intermediate. If the intermediate had ionic struc-
ture, it would also have to form in the case of vinylacrylic acid. All
the experiments carried out are fully described in the experimental
part. The Arbuzov Rearrangement is mentioned. There are 6 Soviet
references.
ASSOCIATIONj Kazanskiy filial Nauchno-iceladovatellskogo kinofotoinstituta
(Kazan' Branch of the Scientific Research Institute for
Cinematography and Photograp
SUBMITTEDs May 11, 1959
Card 3/3

S/0-.1/42/000/004/062/087
B150/BiN
AUTHORS: Khaykin, M. S., Derstuganov, G. V., Levkoye-v, I. I.,
Kuk~tiu.
_
V. A., Shamillskaya, D. B.
azolones-0) and
1 TITLEt The developing properties of some 4-aminopyr
their derivati-;res
PERIODICALt Referativnyy zhurnal. Khimiya, no. 4, 1962, 456, abstract
~
4L421 (Tr. Vaes. n.-i. kinofotoinstituta, no. 37, 1960, 17-26)
TEXT: A synthesis. is made of a series of derivatives of 4-aminopyrazoiones-L
5, and their photographic properties are investigated. Some of these
compounds, e.g. containing the methyl and rj~es cr enbstitution carboxyl t
group in position 3, are active developing substances. The introduction of!

~the amino or oxy group into position 3 reduces the developing power. The r
1 introduction of aubstitute,b into the phenol nucleus, which is in position
1 of the pyrazolone, has less influence on photographic properties. -It is-
indicated that the photographic properties of 4-aminopyrazolones are-
connected with the electronic character of the substituting groups.-
EAbstracter's notei Complete translationQ
Card 1/1
M.

72-7--Wr

NEGOROSHKOVAj N.A.6; LEVINg Yk.A.; KUKHTINp V.A#
Condensed heterocyolea. Deri-.-ativ~o'of-l~phany:L-[2t3-.4-pyrazo:Lino-
pyrimidine. Zhu.i~. o1p. khim. 31 no. 2:495~-/+97 F 161.
(HIRA 102)
1. Fj.,zanskiy filial muchno-issledovatellskogo kinofotoinstituta.
(Pyrimidine)

a
KUKHTIN, V.A.; GARIFIYANOV, N.S.; OREKHOVA, K.M.
Addition of ogm-plete ester of Phosphorous and phoophinous acids
to conjugated systems, Part 11: Interaction betwoen trialkyl
phoophites and /0-~~-dnones. Zhur. ob. khim. 31 no-4:U57-1165
Ap 161. (MIRA 14:4)
1. Kazanskiy filial(naucbno-issladovatellskogo kinofotoinstituta.
Phosphorous acid)
(Benzoquinone) (Naphthoquinone)

LEV,IK, Ya.Aoj KUKHTIN, V.A.
Some new types of the Arbuzov rearrangement. Part 3.2: Action of
mercury acetate on txia3kyl phosphites. Zhur.ob.khim. 31 no.5:
1552-1553 W 161, (KIRA 14:5)
1., Kazanskiy filial riauchno-issledovatellskogo ~inofotoinstituta.
(Phosphorous acid) (Yaroury acetate)

LOVIN, Ya.A,; PDKHOVA. ~INV.A.
Synthesis of some derivatives of 40 51 ~O 7-dibenz-lp 3-diaza-2, 4,
6-cycloheptatriene. 21mr,obAhim. 33. no.5:1573-1576 4 161.
(MIRA 3-40)
lo Kazanskiy filial muchno-isslaudovantel'sk3go kinofotoinstituta.
(Cycloheptatriene)

-KUKMIN, V.A.I.KAMAY, Gillm.
'Ae~ctions of o(,/$-,uxuiaturated acids with trialkyl phosphitea. Zhur.,
ob.kh:Lm. 31 no.5.-,1735-1736 Ity 161. (MA 14:5)
(4ophorous acid) (Acids,, Organic)

WOM,
KUKHTIN, V.A.; KIRILLOVA, K,M..
Some now types of the Arbuzov rearrangement. Part 13: Interaction
of trialkyl phosphites with o- and p-nitrobenzaldehydes. Zhur.-
ob.khim. 31 no'.7.2226-2233 J1 61. (MIRA 14:7)
,1. Kazanskiy filial nauchno-issledovatellskogo kinofotoinstituta.
(Phosphoraus-acid) (Benzaldehyde)

KUKHTIN, V.A.; KAZV.-IOV, A.V.; VOSKOBOYEVA, T.N.
Synthesis of phosphocyanine dyes. Dokl. All SSSR 140 no-3:601-6C4
S '61. (MIRA 14:9)
1. Kazanskiy filic--u' '-`se-zoyuzno--3 naunhn3-issledovatel'skogo
0
kinofotoinstituta. Predstavleno akademikon B.A.Arbuzovym.
(cyanines) (Dyes and dyeing)

--nU11214 V.A. - KIRILLOVA, X ~M -
Thermal decomposition of the products of the addition of
trialky)phosphites to diacetyl. Dok1. All SSSR 140 no.4:833-836
0 (MIRA 14:9)
1. Kazanskiy filial Vs-ennvinnnan nam-hnn-A-ledovatel'3kogo
-- C.- ---
~inofotoinstituta. Predstavleno akademikom A.Ye. A.rbuzovym.
(Phosphowus organic compounds)

KuKHTIN, V.A., OREKHOVAS K.M.
"Some new forms of the Arbuzov rearrangement."
Fbinlyn i Prim'u---ntye 'C'N'"d -. -'~' (C-~ -,!
.~jI I ~j
anblication of Conn"
A~
by Kazar. Affi'- Ac.-!d,
Crdlectlun of com.-Aeti, fmper.,j pm~%erjttd qt.
,-- I ;", 0. . 1. 1
of xganu -i ~Jph u,
ur

FHAYKA, P.-,%- DERSTLIGANOV, G.7.; LIVIKOYEV, I.!.; KAY
t _~,I~KHTIIMI, V.A.; SRAMILIS A,
~, i
Povoloping prc)peutlao cr 11--py-razolones and their
derivatives. Trudy NIKFI no.46.5-16 162. (MIRA 18:8)

LEVIN, Ya.A.,- KUKHTIN, V.A.; GCROKHOVSKIY, VA
Effect. of structural factors on the stabilizing action of Wines.
Zhw-.nauch.i prikl.fot.i kin. 7 no.5088-389 S-C, 16 NEM 15:11)
1. Filial Vsesoyuznogo nauchno-issledovatellskogo kinofotoinstituta,
Kazan'.
(Photographic emulsions) (Purines)

KUKHT111, V.A.; KIRILLOVA, K.H. )I SIIAGIDULLIN, R.R.
Structure of prodii6ts of addition of trialkyl phosphite~o to
O~~-diketoneo. Zhur.ob.kh1m, 32 no.2:6491-650 F 162. OMMA 15;2)
i. KazanBkiy filial nauchno-isoledovatellskogo kinofoto-
institut.a.
(P euqnhn oua aeld)
,-h--,--r
(Ketone,i)

LEVIN, Ya.A,; KUKHTIN, V.A.
2-Su3.fo-4-hydroxy-&-m6thylpyrimidine. Zhur.ob.khim. 32 no.5:
1 1709-1710 Ifor 162. (MMA 15:5)
1. Kazanskiy filial nauchrio-issledovatellskogo kinofotoimtituta.
(Pyrimidine)

KUMTIN V.A.: KIMURA., K.M.; SHAGIDULLIN., R.R.; SAMITOV., Yu.Yu.; LYAZ12L-,,
7-7i~~-;RAKOVA, N.F.
Some new types of the -krbuzov rearrangemout. Part 14., Investigation
of the products of addition of trialkyl phosphites to diacetyl by
physical methods. Zhur.ob.khim. 32 no.6.~2039-2046 Je 162.
le Kawmskiy filial miuchno-issledovatellskogo kino-f'otoinstituta.
(Phosphorous acid) (Butanedione)

KUKRUINP V.A., VWKOBOYEVA., T.N.; KDRILLOVA, K.M.
Some new typos of tho Axbuzov roarrangoment. Part 15: i~~Idition
of trialkyl phosphites and diethyl ~I-omi lates to 1 2-cyclohexanedione.
Zhur.ob.kh-Im. 32 no.722-33,~-2338 JI 162. (MTIA 15.7)
1. v,-mu-i--kJ.y Miall naticlino-.Lasledoinitallskogo kinofotoinotituta.
(Reurangements (Cberdstriffl (-Phosphorou.9 acid)
(Cyclohexanedioxie)

KIRILLOVA., K.M.,-.~~IN, V.A. __
Some new types of the Ax,buzov rearrangement. Part 16: Addition
of tri&U,,yl phosphites to 1,2-naphthoquinone. Zhur.ob.khim. 32
no.7:2338-2340 Jl 162. (MM 15;7)
1. Kazanokiy Mlial nauchno-issledovatel'skogo kinofotoinstituta.
(Rtarrangements (Chemistry)) (Phosphorous acid)

MITITI., V.A.; KEPTIJOVA) K.M.
New types of the Arbuzov rear~rangement. Part 17- Refractions of
boi-ds and *the atomic refractions of phosphorus and its pentavalent
compounds. ZhtLr.ob.khim. '12 no.9:2797-2SOO S 162. (MIM', 15:9)
1. Kazanskiy filial nauchno-issledovatel'skogo kirofotoinstituta.
(Phosphorus compounds) (Rearrangements (Chemistry))

LEVIN, Ya.A.; 1TDOTOVAj A.P.; RAKOVAI N.F,; SAVIC40VA, G.A.; KUXHTIN. V.A.
Condenuod hoterocyclev. Part 2: Conde6sation of 5-alky-3--amino
-1-3--miino-1.2,4-triazoles with acetoapptic ester. Zhur,obakhime 33
no-4:1309-1311+ Ap 163.. (MIRA 16:5)
1. 'Kazanskiy filial Hau-chno-issledovatellskogo kinofotoinstituta,
(Triazole) (Acetoacetic acid)

LETIN, Ya.A.; GnIKINA, N.A.; KUIWTIN, V.A.
Condeni;,-d heterocycles. Part 3: Condensation of 11-ar-ino-1,2,4-
triazole wit'll nome /9-kotocarboxylic asters, Zhur. ob. khim.
33 no.8:2673~2677 Ag. '33. (MIRA 16:11)
1. Kazanskiy filial nauchno-issledovatel'skogo kinofotoinstituta.

LEVIN, Ya.A.; KUKHTIN, V.A.
Condensed heterooycles. Part 4: Condensation of 3-am-ino-1,2,4-
triazoles with diacelvlo- and dipropionitriles. Zhur. ob. khim.
33 no.8:2678-2682 Ag 161. (M]Yk 16:11)
1. Kazanskiy filial nauclino-issladovatellskogo kinofotoinstututa.

KHAYKIN, M.S.; PETROVA, V.I.
Chlorination of dih3nlroxycoumarins. Zhur,ob.khim. 33 no.12:3941-
3943 D '63. (~MU 17:3)
is Kazanskiy filial 'Isesoyuznogo nauchno-issletlovatel'skogo kino-
fotoinstituta.

V.MIA UKHT-IN LEVIN Ya,A.; BODRIN, A.V., KISELEVA, I.P.,
VA, RZ AINOS DV,'1'11 . I .
V)ti;dyiylg the. stabilizi.nig effect of some derivatives of 1,3,4
Truzay Nl.KFl no.46.-2(--30 -62.
WIRA 18:8)

iff - - --
AMEDUANOV, M.A.; SLESAIREVA, V.I.; MAYMINI IM.S.; 4MUTIM, V.A.; BORIII, A.V.
Ufact of som &ntioxidants cn thp photcjgraj'hi-~ propertia3 and
ke6plng qjality of emuIsx,.rj laydro. Truly NTKFI no.46:31-35 162.
(MIRA 18-.8)

AccEssioN NR: A?4o3c)364
S~11)1~--/64/006/003/0473/01~19
AUTHORS: Khismatullinas L. A.; Levis So &t Kukht T!
-44
TITLE-. Synthesis and investigation of graft. copolymers of gelatin
SOURCE: Vy*,qokomoleku1VarnMa soyalineniya, v. 6. no. 32 1964s 473-479
TOPIC T.AGSi proteins gelatin% aox7l monomer., polymer, copolymer, graft copolymers
mothy1methacrylate, polymethy1metham.*ylates initiator of copolymerizations
potassium persulfate
0
ABSTRACT: After reviewing the synthosis of graft copolymors of gelattin with
various acrylic acid derivatives., thet authors centered- th-GAr attention on the
copolymerization of gelatin with metliylmethacrylate (101A). To a flask, containing
water kept at 86C, they added a 104P solution of gelatin arA various amounts of
potassium loersulfate. To this they added various doses of'monomers,, and heated the
mixture fo~ 45 minutes. After cooling at room temperature and drying, the product
was extracted with dichloroethane to,obtain the homopolymothylmethaorylate. The
residue was hydrolyzed with hydrochlo:~ic acids and the grafted branch polymethyl-
methacrylate fraction was separated outo While experimenting with ratios of gela-
.-tin to &M of 2il.. lil, 1:3, mid 1%4j, it was found that the amount of hoa0polymer
1/2
Card

ACCESSION NR: AP4030364
and of the grafted branch polymer fraction increased with higher 1-M content in
the original m:L-euure. It was calculated that for each molecule of gelatin of, a
molecular weight of 60 000 there were 13-17 graft polymer branches of a molecular
Welaht of 2700-2000. Experiments with concentrations of the initiator within the
0.75-9.10 range revealed that the firmness of the gel and the viscosity of the
solution decreased with higher concentrations of potassium persulf ate, while the
quantitity of homopolymeric MMA increased, and the molecular weight of the graft
polymers diminished. A study of the physico -chemical and physico- mechanical
properties of various graft copolymeta of gelatin with monomers of the acryl, aeries
showed their superior mechanical strength., elasticity., and thermal stability, while
the viscosity of their aqueous solutions, unlike that of gelatin., remained constant
within a pH range of 2.5-%10o Orig. art* hast 5 tables and 3 charts,
ASSOCIATION: Nauchno-issledovatel'skV kinofotoinstitut (Scientific Research
Institute of C:U&ematography)
SUBMITTED: llMar63 DATE ACQt May64 ENCL.- 00
SUB CODEs 00 NO REF SOVj 002 OTILERs 002
Card 2/2

LEVIN, YaL.A.1 SFRGEYEVA, E.M.; KITKETIN, V.A.
.1 --- ~. -1 . ..... - ". 1
4-
Condenspd h9teroeycles. Pavt 5- Interfiction of I chloro-6-mathyl-1,2,3-
triazolo[2,3-~Jpyrlmldine with some n1trogen bases. 2%ur.ob.k1dm. 34 no.
1:205-209 Ja '64. (MIRA 17:3)
1. Kazatiskly filial Naiiclini-,,-is3ledo,.,,,vtol'aRogo kinofotoinstituta.

WIN, Ya.A.; FEDOTOVA, A.P.; ~IJKIITIN, V.A.
Conden38d heterocycles. Part 6: Mechanism of the formatlan of the op.
tem 6-oxo-1,2,4-triazolo(2,3- lpyrialdine. Miur.ob.khim. 34 no.2i4W_-
501 F 164, (MIRA 170)-
1. Institut organichaskoy I:himi.l All SSSR, Kazixnl.

LEVIN, Ya.A.; KUKHT:N) V.A.
Condensed hot.aracyclas. PUt 71 Syntheses and transformations.of mome
4-substituted 6-methyl-1,2,,4-triazolo[2,3-cAjpyrimidines. 71itir.ob.khim.
34 no.2:502-508' F 164. (KRA 17:3)
1. Institut organichaskoy lihimii A14 SSM, g. Kazan'.

LEVIN~ Ya.A.; PLATONOVA, R.N.; HTTut V.A.
L~x --P ~...... . .
Condensed hetercayeles. Report No.8: Condensation of 3-amino-
1,2,4-triazole with cyanoacetic ester. Izv. AN SSSR. Ser. khim.
no.8gl475-1.480 Ag 164. (MRA 17:9)
1. Institut. organicheskoy khimil AN SSSRp Kazan'.

LIEVIN, Ya.A., SHVINK, N.A.; 0101TIN, V.A.
"~ i..
A 1--, ~.,
Condensed heterocycles. Repert No.91 Condensation products of
ethoxymethylenemalonic ester with 2-amonothiadiazolea and
2--aminothiazoles. Izv. AN SSSR. Sar. khim. no.8-.1481-1484
Ag 164. (MIRA 17:9)
1. Institut organicheskoy khimii AN SSSR, Kazan'.

KIRILLOVA, K.M.; MlITIN, V.A.
New types of Arbuzovis reeirrangement. Part 18: Addition of
trialkyl phosphites to methylphenylglyoxal. Zhur. ob. khim.
35 no-3:544-546 Mr 165. (MIRA 18W
1. Kazanskiy institut organicheskoy khimii AN SSSR.

IzTl,J,lAl0vA? K.1,%; I~IjLljN
, I -~'L
New types of Arxbuzzov rear rangeme n t. Part 19; Add4tion of trialkyl
Zhur. ob. khim. 35
plinsphiteE. to acetylenecarboxylic acids. I
no.7-,11,',6-.l1.49 JIL 165. (MIRA 18:8)
1. khlrnlil AN S-SISR, Kazant.

KHAYKIN, M.S.; FEDORINA, L.G.; FAMIRUTDINOV, A.S.;
Synthesis of-some derivatives of 7p8-dihydroxybenzopyrylium
chloride and 7,8-dihydroxycioumarin. Zhur.org.khim. 1 no.2056-
358 F 165. (MIRA 18:4)
1. Kazanskiy filial Vsesoyttznogo nauchno-issledovatellskogo
kinofotoinstituta.

K H f N, M.. S. ; fIA'WoYE'v~ 1. 1 , , KOK I.- HI, V. it.
.1 L
Sy-nthoa13 cd' cortair 3-mPthyll tir,'
71mr, org. khIm. I no.131P-136 Ja 165. (YITRA 18z5)
1. Kazanskiy filial Vsesoyuzncgo nauchno-i.,altidovatel'skogo kinofol-o-
In5 "'itut.a.

-L 3N56--,66--W,( UP(c) -66-
UR10077166TOll.TO02TO .1/66
AM NHs XP602407 SOURCE CODE:
AUT11101t: Mismatul-Una, ' A, t kGIEL.A.-M-1 Bogdanov, Lo He; Kukhtin, V,, A.
IS&
ORG: All-Union Scientific Research M-3tion Picture Institute (VaesoyuzrVy nauchno-
issledovatellski,y kinototoinstitut)
TITL',,~,: Investigation of the application of grafted gelatin copol,*Mrs for ]?~oto-
graphic emulsions p
SOURCE: Zhurnal nauchnoy i prikladnoy fotoprAfii i kinematogram. v, 11, no. 2,
1966, 81-67
TOPIC TAGS: photographic emalsion, graft copolymer, photographie procossing,
photographic property
ABSTMCT: Conditions are worked out for synthesis of grafted gelatin copolymers. As
a remilt, of physico-mchanical mid pho,~ographio invoBtigations of the graMd golatin
copol,vmrs, introduced to the amlsion in quantities of 25-50%, it has boon establish
that those materials have no negative offect on the photographic properties, but
increase the elasticity, strength and hoat stability of the amLlsion layer, which
makes the layer immano to cop
,Vat n ditring high-terperature photographic processing.
Orig. art& hast 9 tabloso rjr&
SUB CODE: 14, 07 / SUBM DAM -15Sep64 / CIRIG REFt 002 / OTH REFt 001
Card 111 -It" '
UDCt

TUOLOV, V.I., inz1i.;qaMjMjL.W4,k..inzh.; NNSXL', U.S.. inch.;
TOVKACHNV,'V.G., Insh.; PAFWV, V.I... master-olaktrotakhnik.
"Mercury-converter substation of electrolysis plants" by K.O. Za-
zantsev. Reviewed by V.I. Vukolnv and others. Vent.olaktroprom.
29 no.10:74-76 0 158. .- 041RAL 11:11)
(Electric substationti) * (Electric current rectifiers)
(Kazantsev, K.G.)

T-,
,KUKHTINA. A.Y.
Oll '%K"i0W*AW-
Sffect of andiwa bromide )a the conoor e!ontant of the brain (with
klirimary in Nnplichl. UkroblokhIm. zhur, 29 nc.3.,295-291 157,
(Ilmi~ w:9)
I.- Kafedra biologli I kafedra biokhimti Meditainsknea insl),tuts
~T. st-111no.
(BRAIN) (COPPER EN THE RODT)
(BROIA INS- -PHYSI OLOGICAL KRYM)

SAMOVA, N-H.; RIMOINA, A.V.
Parasites and predators of'quarantine and certain other pests of
farm crops. Int.obos. 34:210-217 155. (MLRA 9:5)
I.,Otdol entomologil TSentrallnoy laboratorii po karantinu
sel'skokhozyaystvannylkh rastenty Hinisterstva sel'skogo khozymystva
SM, Koskya.
(Insects, Injurious and beneficial)

SO..'
ACC NR. JV ~
A1116019616 U11CE CODE: UR/0048/66/030/002/0255/0256
.,~AUTIEOR: Gridnev,K.A.; 1(rasnovoL.V.; NuIdAina, I.N.; Luh-'yanov, V.X.; Nikitina,~-V_1.;
Furm=~i V, 1.
ORG:
TITIM.L" Calculation: ol. dixect nuclear: rencli2as
jay the distorted wave method/Raport_
Fifteen AAAUPP. _Co4feronce : on.. Lo
Nuclear..Spectroscopy.r
I ilinsski.. 25 January to 2 Februnry.1965/
SOTJFCE: AN -SSSFE.- v. 30, no. 2, 1966,.~-255-256
TOPIC.-TAGS.- hticlear reaction, -mathomatio method, Airac4h~auo r.
ABSTRAM The authora havo employed an electronic computer to oalculate differential
across sections for
(d,p) reactions in the distorted wave approximation under the
following simplilying assumptions; 1) the range of the nuclear forces is zero 4the
iiiearaQtIon poteutial Is a delta-function) and 2) there s no spin-orbital coupling
The calculated angular distribution of protonn from the4l 56 57
(d,p)Fe reaction Voith
an incident deuteron energy ofG.GMW is acmpared with the nngular distribution
calculatod in the plane wave approximation (Bmtler a theory) and with experimoalpal
data of V.p.13ochill, X.I.Zhorebtsova, V.S.',Iolotarev, V.A.Nomarov, L.V.Krasnov,
Cord

ACC NR; jjp6Olq6lC-
V.F.Litvin, Yu.A.Xemilov, avd I,.G.?;ovatfi]I;i'Y (Ventn. 78 (1903)).
Miu oxperlmun'-al data are in much better agroament with the distorted wave calcu-
Ilations than with the plane wave calculations, The authors intend to publish a do-
tailed description of their calculations and expect to relax the simplifying assulap-
tions 1) and 2) in future work. Orig. art. has: 2 formulas and I figure.
SUB CODE: 20 SU13M DATE: 00 ORIG. REF: 001 OTH REF: 002

KUMITINA, M.K. (Moskva, Leninshy proopokt, 72, kv. 593)
Comparative anatomical characteristico of subcortical structures
of the optical and auditorr analyzors in guinee. Age and squirrels.
Arkh. anat. gist. i embr. :39 no.6:65-75 Ag '60. NIRA 13:11)
1. Kafedrb, anatomii i fiziologii cheloveka i zhivotnykh (Zavr
prof. M.M.Kurepina) Moskavskogo gosudarstvennogo pedagogicheLogo
0, inBtituta imeni Potemkin&.
(BRAIN) (RODEYM)

OKWINA, M.M.
Compa.rative morphology of 0u) eyes of 3cine rodbyit3. Ui;h. zap.
MGPI W425'-~-270 162.
Comparative morphology of tho cocldua7 uppuratus of t-he ear of
some rodenta. lbid.t271-278 162. (MIRA 17:5)

KT,OSOVSKIY, B.N.; KMTIDIA, Zh.M. (14oBkva)
Localization of the ganglion cells in the retina of the eyep
transmitting impulses to the external geniculate bodies or to
the anterior tubers. of the corpora quadrigemina. Vop.neirokhir,
25 no,1:21-26 162. (MIRA 15:1)
1. Iaboratorlya patofiziologii mozga. Instituta nemlogii AMN SSSR.
(RETINA-11MVATION) (OPTIC NERVE) (MUM)

VELIKORETSKIY, D.A.; LORIYO-p FINICELI, I.I.; GRIGORCIM., Yu.F.;
URGERI L.Kh.; 'IMROBINAI V.V.;-KJIARC;,I'ENKO$ V.P.; 1,231IMMOV, A.V.#
student V kursa" OBEREWCMENKO, Ya.V., kand.med.nauk; NIKITI11, A.V.;
10KNOUIDOVA, S.N.; KUSMARTSM, L.V., assistent; KU21ETSOV, V.A.#
p
dotsent; KUKIITIIIOVA. R.A... assistent; BONDARENKO, Ya.D. (g. Fastov);
KURTASOVA9 L.V. (g. Fastov); FEVCHIKII, V.V.; CIIURAKOVA, A.Ye.;
BABICH, M.M.; KUVWN~ K.F.; FAVLOV, S.8.; SHEVLYAKOV, ~.V., kand.
mod.nauki- IGNATITEVA, O.M.; ZEMLIHMAKIIER, G.A.; GUTKIN, A.A.;
POLYKOVSKIYI T.S.
Resumes. Sov.med. 25 no.11:147-152 N 161. (MIRA 15:5)
1. Iz Instituta grudnoy khirurgii A1,24 SSSR (for Velikoretskiy, Loriye,
Finkel'). 2. Iz bollnitsy No.3 Gorlovki Stalinskoy oblasti (for
Grigorchuk). 3. Iz Tymneaskoy oblastnoy bollititay (for Berger,
Utrobina). 4. Iz Karatassikoy rayonnoy bollnitsy Yuzhno-Kazakhstanskoy
oblasti (for Kharcheako). 5. Iz Gospitallnoy khirurgicheskoy kliniki
I Moskovskogo ordena Lenini meditsinskogo inatituta imeni Sechenova
(for Meahchoryakov). 6. I!a kliniki propedovtichoskoy terapii Stalinskogo
meditsinakogo instituta na baze oblastnoy klinichankoy bolinitay
imeni Kalinina (for Obereimihonko). 7. Iz kliniki goopitallroy terapii
Voronezhakogo moditsinskogo inatituta (for Nikitin, 11,11IMioyedova).
8. Iz kafedry obahchey khirurgii Kishinvookogo meditsinskogo instituta
(for Kusmartseva). (Continued on next card)

VELIKORETSKIY, D.A. I---(continued) Card 2.
9. lz akushersko-ginakologJ.cheskoy kliniki Stalinskogo meditsinakogo
institute, na baze bollnitsy imoni Kalinina (for Kuznotsov, Kukhtinova).
10. Iz gbaljitallnoy terapevticheskoylcliniki lzliovakogo meditsinskogo
instituta (for Fevchikh, Ghurakova). 11. Iz Nosovskoy rayonnoy
bollnitsy Chernigovskoy oblasti (for BabichY. 12. Iz Vyborgskoy
mezhrayonnoy bollnitsy (for Pavlov). 13. Iz I-y gorod:jkoy bollnitsy
Tyumoni (for Ignatlyeva). 14, Iz 2-y infektsionnoy bollnitay
g. Zaporozhlya, (for Zeygermakher). 15. Iz infektsionnago i
prozektorslcogo otdeleniy, Fetaozavodgkoy gorodskoy bol Initsy
(for Gutkin, Polykovskiy).
flumniVTNE--ABSTRACTS)

KUMIETSOV, V,A., dotsent; ~WITRTOVA, R.A., assistent; SOROKA, P.G.j
assistent.
Extensive congenital skin defects in newbom infants. Akush. i
gin. 39 no.413L-1319 Jl-Ag163- (MIRA 16t12)
1. Iz akushersko-Dainekologichaskoy klinik-i Notl (z-av. - prof.
P.P. Sidorov) Donetskogo meditainskogo institute imeni A.M.
Gortkago.

ROZP.KOV, I.S~; GRINBERG, G.A.; K.UKHTTN5KIY, C,,G,--.--
Some characteristics of the geolopy and metallogeny of the upper
Indigirka Valley. Geol. i geofiz. no.11:3-13 '661. (MIRA 15:2)
1. Yakutskiy filial Sibirskogo otdeleniya AN SSSR.
(Indigirka Valley--Gold ores)

KUKHTIY9_Y4 VINOKUROVp A., mekhaulk; XORSUNSKIY, V.
Renovation of the MI/+00,trench digger. Prom.otroi.i inzh.
soor. 4 no.504 162i. (MMA 16sl)
1. Nachallnilt proizvodstvenno-6tekhnicheskogo otdeleniya
Mikopollskogo gidrostroya (for Kukhtiy). 2. Starshiy
proizvoditell rabot proizvodstvenno-tekhnichesogo otdeleniya
,Nikopollskogo gidrostroya (for Korsun8kiy).
(Excavating machinery)

KUKHTO, A.F.
"Antngonism" of the causative agents Of nuttalliosis and infectious
anmmia of horses. Trudy Inst.zool. AN Kazakh.SSR 1:205-210 153.
(min 10:1)
(Ineactious anemia of hor )(BlGoa-Parasites)
(ProtozoR, Pathpganic"s3s(, MrseR--Diseases and posts)

KUKHT.0 kandidat biologichesk:Lkh nauk.
I
Tozoplaomosts. Vaterinarlia 33 no.11:86-90 N '56. (MM 9:11)
1 (Toxoplasmositi)

ORLOV, P.M., doteent. kandidat veterinarnykh naulc; METALKIN, A.I., professor,
doktor biologicheakikh. nauk:, redaktor, lalKLMQ._Aj_,..."daktor;
BORISOVICH, F.K.,. re&4ktor; SOKOLOVA, N.H., tekhaicheskiy redaktor
lIaboratory methods in veterinary research] Laboratoruye metody
issledovaniia v veterinarii. Moskva, Gos. izd-vo sellkhoz. lit-ry.
Vol.4. 1957. 511 P. (MLRA 10:7)
(Veterinary researcb)

KMTO. A.F.,.Imndi(IELt bil.ologicheskikh nauk.
Vesicular ozanthem in swine. Toterinariia 34 no.8:87-90 Ag 157-
(ftanthemata) (Swine-Diseases and pests) (KLRA 10:9)

tLTK T .7
.ro ' 7
Y
i , A. v . , (Candidate of Biologival Sci~,ncc,8)
Fruritis of she.-p (scraple)
Veterinariya vol. 3P, no. 7, July 1~.61 p. 85.

tMTO A.F., kand. biol. nauk; SVINISOVA, A.P.
Veterinary m3dicine abroad. Veterinariia 38 no.7:85-89
J1 161. (19A 16:8)
(Scrapie) (Abortion in animals)

RAGROV, N.A.;,-KUKHTO,,A.P.-
Variability of mean monthly temperatures and altitudes of the
500 millibar isobaric surftoe. Sbor. rabo po sinop. no-3:139-152
159. (MIRA 12:11)
I..TSentral'ny7 institUt prognozov,
(Atmospheric temperature) (Atmospheric pressure)

3, ~~-o o 0 B012/BO54
AUTHOR: Kukhto, A. P.
TITLE- Thermal Structure of Poorly Mobile Anticyclones
PERIODICAL: Meteorologiya i gidrclopiya, 1960, No. 12, pp. 19 - 22
TEXT: Anticyclones shifting at an average rate of at most 15 km/h and
at most 19000 km from their original positior within 5-7 daYs
(Refs. 1,4,9) are called poorly motile (quasisteady). The present paper
describes an analysis of 10 typical, high, poorly mobile anticyclones
which were in a steady state for at least 3 days (Ref-7). Isothermal
charts on the 850, 700, 500, 300, and 200 mb levels were plotted for the
analysis of the thermal field of anticyclones. Three types of thermal
fields were found for each level on the basis of a join" analysis of the
position of high ariticyclones and that of the thermal field at different
altitudes: 1) T group: the high anticyclon,)s are situated in the heat
sourp.e or heat crest; 2) X group: the high antitiyelones are situated in
the cold source or in the heat trough; 3) T/X group: a combination of
the former two groups. Tables 2 and 3 give the results of investigation
S/050/60/000/012/00,71/005
Card 1/4

66645
Thermal Structure of Poorly Mobile Anticyclones S/05 60/000/0112/003/005
B01 2YB054
of thermal fields, separately for the period of stearly state and that of
the mobile state. The numerator indicates the number of days, the denomi-
nator the percentage. Tables 4 and 5 show the mean temperature changes
At and the altitude changes 6H of the isobaric surface of the anticyclones
investigated from one day to another, as well as the corresponding
changes Att and AHO in the area where the anticyclones are situated V
afterwards. An investigation of the eddy showed that; the eddy values
varied within relatively wide limits on the 700 and 500 mb levels. The
extreme eddy values in the steady state of anticyclones, however, were
equal on both levels. This was not observed ir mobile anti-:~yclones. As
to the Laplacian values, no essential difference was observed for the
various states of anticyclones. A pa 'Der by S. P. Khromov is mentioned.
There are 5 tables and 9 Soviet refe:"ences..
Card 2/4

BII,j Tep- wo 5,1 P SI'I;coole 11ollepmeenlif
KOM -
q
850 700: 500 300 200
i
33 39
- 37 25
- 1
_
80.5 �Y.
2 90.2 .5
W 31.3
2 3 20
x
-K j - -T.-3
6 2 4 12
T/X T476 -,I-,8 -976 30- WO
j) 41 41
- 40 30
-
Bccro 106 -106 100 Iw fo
O
SICY,501601000101210031005
B0,12*1
A054
Legenc! to Table 2:'Character of
the thermal ffeld above anti-
cyclones, in-the st6ady state:
i
1) Type of thermal field , 2) Iso-
baric surface (mb), 3) t6tal.
W306apiiqewle nOBeP:c"OCTH Legend to Table 3: Character
BiiA -rep- (,w6) of the thermal field*abovo anti-
Koro cyc lones in the mobile state:
850 700 500' 300 200 1). Type of thermal field, 2) iso-
surfaces (mb), 3) total.
T .-.23.. .28 25 '212
69,8. 84-8 T5_8 R_. -9-.7
2 1 2 is
-97 _~7 7~i T5_;~
i o
10 3 7 8 6
_57 TI _,2 f575 76.1
TIX 00.2 - 1
33 33 33 31 23
Card 3/4 31 Ocero IOC f 0-0 Td-(j- To-o To TO

H3-,ietietisie TemrtepiTypbl It DbICOThl
itio5apitticemux nonep.X11OCTCA WITH-
LtIlIU10HOB B Maim CTaI(tIOIIIIPODMII$7
1100CI)IMOCTI,
850 +0,19 LO.28 +0,91~+1.07
700 -0,12 -o, 18 + o,61 4-1.67
500 -0.12 - 0.26 +0.73 1-2.49
.300 +o.13 -0,63 + 1. 17 +3,7'a
200 ~-0.43 t2,12 +3,40 +6.34
rd6,t u4d
HWICIIelliie TC51rtepaTYPI.1 H nbICOTbI
If3orjapimecHux nUBCPXIIOCTCfi WITH-
LtIIKJIOIIOB B MAitit FICA31IMMOCT.11-
N30ODpwiecKast I
-S t A A H'
nOUCPXIIOCTb H`
8; 0 321- 0 45 +0 24 +1 72,
-RO -0: :80 1'~2 26
161-0,17 +0
500 +0 19 -1 05 +1 ,301+2.19
300 +O:uIjj-0:29 +1 501-4-3.12
200 ~-I ,0 -3 14 4-2:2.1 +3.37
Card 4/4
6.6645.
S/050/60/000/012/003/005
B012/BO54
Legend to Table 4: Changes in
temperature and altitude of
isobaric surfaces in anticycloned
in the steady state: 1) isobaric~
surface (mb).
Legend' to Table 5: ChangeE; in
temDerature'and altitude of
isobaric surfaces in anti-
cyclonps -in the mobile state:
1) isobaric-surfaces (r',,b)-

BAGROV, N.A-;-KUIGiTO)LA!-p
Determining the Laplacian field from the geopotential.
Meteor. i gidrol. no.4:2.3-27 Ap 161. (MIRA 14:3)
(Migteorology)

iACC N6-AT6033366 UR[3118/66/000/009/0029/0042
AUTHOR Kukhto, A. P.
ORG: none
TITLE: On the circulation of the atmosphel7e over-the Atlantic European region during
a period of Deveral years
SOURCE:'!Mirovoy meteorologicheskiy teentr. Trudy, no. 9, 1966. Statisticheakiye
svoystva meteorologicheakikli poley (Statistical properties of meteorological fields),
29-42
TOPIC."TAGS: synoptic meteorology, long-range weather forecasting, atmospheric
circulation
ABSTRAc.T: The Hr field of natural synoptic periods has been analyzed by
J00
Chebysbew's orthcgonal polynomial for the 25 year period of 1938--1962. The trend of
individual components of the field was studied and the recurrence of coefficients was
shown to approach Gaussian distributions. The characteristic variability of com-
ponen 'ts from period to period and seasonal and annual variations of selected coeffi-
cients were computed and tabulated. The reE;ults were compared and found in good agree
ment with indexes published by other researchers. Field coefficients with high varia-
bility have satisfactory synchronous correspondence with anomalies of air temperature
and to a lesser degree with river flow. Probably, similar correlations of coeffi-
cients with hydrometeorological parameters could be established also at.shifte in