SCIENTIFIC ABSTRACT LIPATOV, YU. S. - LIPATOVA, T. E.

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SCIENTIFIC ABSTRACT
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,LIPATOV Yu 3 ~~~jp Dielectric relaxation in the surface layers of polymethfl meth- acrylate and polystyrene. Vysokom. soed. 7 no.8:1430-1435 A 165. (MIRA 18:9~ 1. Institut obshchGy i neorganicheskoy khimii AV BSSR. 2984-66- .-E7V?T(m)/M-(P)ZjWCJ)/7 OF NRs AP50226i2 Ssjo~ UR/01-90/65/067/069/.1626/2632 66.095.26+67P.62 AUTHORSi Taybulikol A. Ya.; atovas T. E.1 Lip "tov, Yu. S. -;Us TITLFt Gopolymerizati iaturated novola aster with a nel SOURCE: Vyaokomo1eku3,yaruyye soyedinenive., V. 7j no. 9. 1965,, 1626-1632 TOPIC TAGS; polymers polystyrwes graft copolymers copolymerization., thermo- mechanical propertyo eaters styrene., novolac, infrared spectroscopy ABSTRACT: The detailed study of copolymerization of novolac ester with styrenes the physical and chemical properties of the copolymers and the reaction mechanism I and reactivity of reagents are described. The reaction is both theoretically and, practically interesting since copolymerization with participation of oligomers is unusual and also leads to products capable of solidification. Preparation of modified navolao (novol'ac methacrylate) was described by the authors earlier (Vysokomolek. soyed.j 6, io%s 196h). Copolymerization was conducted in a dimethylformamide solutions in N2 atmosphere and in sealed glass wVules, by heating the reagents for 30 hours at 70C and using asodiiaobutyronitrile as an L ACCESSION NR: AP5022612 initiator. The ratio of reactants was varied, andits effect upon the composition of the product was measured by turbidimetric titration and infrared spectroscopy. It was found that graft copolymers of polystyrene with the oligomeric.moloculas were Vormedj and the frequency of branching was a function of the reaction mixture composition. The reactivities of the double bonds of styrene and modified novolac during copolymerization were calculated using equations of A,'D. Abkin and S. S. Medvedev (Zh. fiz. khimii, 21, 1269, 1947). It is assumed that the law reactivity of methacrylic groups is due to steric factors which also affect the polymerization:1 proC8BB* Study of thermomechanical properties of the graft polymers has shown that they can solidify upon heating. Small amounts of polystyrene grafted onto the modified novolac have a large effect upon increasing the flow temperature. Origo- art. hast 3 tables and 5 figures. ASSOCIATIOM Institut obshchey i neorganicheskoy khimiij AN BSSR (Institute for ~-Ceneral and Inorganic Chemis!M. BSSR) SUBMITTED: 26oct64 ENCM 00 SUB COM 00,0 G-C NO RBF SM 006 OTHER: 002 Card 2 LIPATOV, Yu.S.; SEIRGEYEVA, L.M. Some regularities of' the adsorption of macromolecules from -solutions. Koll. zhur. 27 no.W17-223 Mr-Ap 165. (MIRA Ie,:6) 1. Institut obshchey i nearganicheskoy khl.zTdi AN BSSRq Minsk. SERGEYEVA, L.M.; LIPATOV, Yu.8. Adsorption of vapors in the awtem polymer - filler. Xnll.zhur. 27 no.33435-440 My-.Te 165. (KTRA 18'.32) 1. Inatitut obshche:v I neorganicheskay khimil AN BS-':!R, Minsk. Submitted Dec. 2, 1963. T. ACC ART~6046245 SOURCE CODE.; OR/0000/65/000/000/0056/0063 AUTHOR: Lipatov, Yu., S. (Doctor of chemical sciences) ORG: Institute of Chemistry_of High -Molecular Compounds AN UkrSSR, Kiev (Institut _..~khimii vysokomolekulyamykh soyedinenly AN UkrSSR) 1~~TITIXt:' Sc=6:'vhvsi,~6mical aspects of the mechanism of r~einforcing_Rlastics by fil- ,-SOURCE.i. AN-_AfictS8R*:,Modifikatsiya svoystv polimerov i polimernykh materialov (Modifi- cation,of the prOpe:*.ties of polymers and polymeric materials). Kiev', Naukova dumka, 145, 56 63 TOPIC. TAGS: solid mechanical property, plastic strength, polymer, filler, plasticity -ABSTRACT: The mechanism of plastic-fillerl(interaction (which results in improved me- chanical properties of filled plastics) is discussed on the basis of data in the lite- rature and the authors' previously published studies. The reinforcing function of fil-, lers on plastic.is'.'explained in tems of the special orientati9d of polymer chains at- tached to. the filler surface the firmness of'polymer adhesio0to the filler surface, band the chemical interaction between the polymer and the -fil r surface. ,8UB CODE: 07/ SUB14 DATE.- 06Oct65/ ORIG REF: 0211 OTH REF: 002 LIPATOVA, D.L.1 DZHINS-ISTI, G.Ys. Standardization of projective transformations. Uch. S&P* Nook. use no.181:235-240 156. (MIM 10:4) (Transformations (Mathematics)) (lowkMphy (Mathematics)) LIPATOVA, D.L. -:Z~ Limit of a converging sequence of measurable operators, Uchozapo Fed.inat,Gerts. 218:343-345 161. (MIM 14 110) (Sequences (Vkthematics)) (Operators (Mathematics)) LIPATOVAI F. A. Lipatava, F. A. - "Nomographing the Equations of Three Variables by the Method of Their Equalized Points with Identical Transformation of the Left- Hand Side of the Equations into the 14asseau Determinant." Min Education RSFSR. Moscow Oblast Pedagogical Inst. Moscow, 1956 (Dissertation for the Degree of Candidate in Physicomathematical Sciences). So: Knizhnaya Letopisl., No. 10, 1950, pp 116-127 88900 S/044/60/000/007/057/058 Xing C1111C222 AUTHORs TITLEt The solution of the problem of K.Y&,Zalte PERIODICALs Referativnyy zhurnal. Matematika, no-7, 1960, 228. Abstract no-8325. Uch.zap.Kaliningradek.goo.ped.in-t,. 1958, vyp-5, 129-143 TEXT: It is shown that for the representability of the left-hand side of the equation Ix Fl(x)C,(ypz)+F 2(y)C2(x' z)+F3(Z)C 3(XIY) . 0 by a Masso-determinant, i.e. for Fj(x) fj(x) gl(x) F C +F C +F C F2(y) f2(y) 92(y) 1 1 2 2 3 3 F3(Z) f3(z) g3(z)l it is necessary and sufficient that one of the three conditions of compatibility is satisfied for the system Card 1/3 The solution of the problem... f29 3-f3g2 2 C1 f f -C 3gl- 1g3 = 29 f 1 g2-f291 0 C39 where the functions C 1* 0' C2* 0' C3 to' following conditions is satisfied: 1) 2el 'A C2 C -Tz- C2- 12 1 a 3 'W3(z); 2) C3 C lie1C 1- -U- 3 C2 V2(z); Card 2/3 8R'A': S/044/60/000/00 7110 (17. C111/C222 I.e. one of the three I ') 13 88900 B/044/60/000/007/057/058 The solution of the problem... C111/C222 3) 1 C2 0 IOC3 3- bx YJ(X). C1 The solution of the problem is given under the assumption that Fi+ const (i-1t2,3).A numerical example is given. CAbstracter's notet The above text is a full translation of the original Soviet abstract.1 V/1 Card 3/3 88899 .6n S/04 6o/oOO/007/056/058 C1 11 YC222 AUTHOR: Lipatova, F.A. TITLEs A new method for the nomogram-Ing of the polynomials M(x,y,z) for which 213M(Xly,z)l .0 PERIODICALs Referativnyy zhurnal. Matematika, no-7, 1960, 227-228. Abstract no-8324. Uch.zap.Kaliningradak.goa.ped.in-ta, 1958, vyp.5t 144-155 TEXTt The proposed method consists in the fact that the sum of the first three terms of the right side of the identity.M(X,Y,Z) - Ml(ylz)+M2(xlz)+M3 (x,y)+Fl (x)+F2(y)+F3(z)+S is represented as a Masso- determinant and the conditions of this representation are reduced to the conditions of compatibility for the system f 9 -f - 2 3 3g2=Ml(y;z), f 9 f - (1) 3 1- g3 =M2(x'z), f1g2-f 291 --a x3(XPY). Gard 1/2 88899 S/044J60/000/007/056/058 A new method for the nomograffivoing... C111/C222 Then the representation of the polynomial M(X,Y,Z) is considered by a Masso-determinant. It is shown that this representation assumes the following conditionst 1) Compatibility of systems (1), 2) compatibility of the systems (1) and (2), where (2) has the form ag 3-bf3 aF 3(z), 4f 2-og2l= P2(y)P (2) ad-bo aS. The investigation of the compatibility of the systems (1) and (2) is carried out for several cases * Ubstracter's notes The above text is a full translation of the original Soviet abstriact.3 Card 2/2 1 LIPATOVA, G. . ...WW-OMMM" The structure of starch thickenings. Zhur, prikl. khim. 29 no.12: 1881-1883 D 156. (MIJU 10:6) 1, Kafedra fizicheakoy khimii Moskovskogo tekstillnogo inatituta. (Starch) (cellulose) (Adsorption) PA To Me G- V Host of Wall 4114 01111111two of low-mitlecul" ccem~ Zpa"481. I. Sm.41,110M.1 6. V. 11ij "o- Kolloid he" I T~ .11 - UI (t 4 - Ile bc '); cl of "it of Na ofeute in 11,0 is -.'I ral,/C. M III' J1141 - 11 31 W). : this ChAnar it flor to tile gradual -tvIvIting" of fit,- Iftlernitel. 1--ods at higher tritip. The Q in FtOll i, I At MA -M, '141* and eoe*; let the Letter fll!:#~`r (I is "'Ol't I_ m- dl tile Noed, aw, W.,kri, 1w,uh-to Ile v .4 .14 11% -1 IV,, I... I. I"4, mul #'.ps-fly al 1.11th.-I I"1111, lle.", -1. N is 'I Chh.f.millic It'diove ill I, Net, Z 1, 1 1 - . At Ill", 31 ~W. .1 114411111 A ", 7 ". IN I A mme, isteel.4 k*hry.qJ,.ouw (111,11 ILI of 16. It :.) And 2.14 At 5*, 10% *It *, And Nft'~ 'Fite tIm-feth,,el Ima 4 ,tan. (,), Was cAlm. (mm (dlnK;'d1') - 1.1 If, Q Of I W-A* eflUal 10 Q' ilt LW; for 11, 20 , wheruti Q'mt higher temp. was 2-3 filters as grr;.t A, (I Ile (), fit lit w;1% greater film) (I at 4411 truells. At 25*, Q Was 3370. 1 IMI. And 43P) c.d. 'nude (let 1. 11, Reed Ill, r-v 'rhe Q, L% t,k) CICA, ~4- jk:dr I% -tim.-tin.mv rt.-m ..( higher Ittop. A% it rr,111t .,( the roll.ou"I fle,tilmlily .4 it,, -lye views. J. J. Illkerm.", Ll P AT Oll , S . M. [ Up it ta u, ; . M. I [ d o c , - U; I od 1 - I I.;, ~: i ~ a ~~ ~v, , i - ~,-- . Diaschasnava, I.K.1i, rl~ TOVA G V. ', 1~)AjVA~~ , L Phnse demixing in the system polyrr-r - poly,,,?~r - Vestsi AN DSSR. Ser. flz.-tekh. nav. no.4356-60 162. (MIRA 18t4) MI-IMUVI R.I.; bTUVil.'CHEYEVj F.A.; J!~~, J.p. Deterialnution of the individual hydrocarbon com-paition of Tttar petroleww. Report Ilo. 4: Ligroine obtainod i'rom zlomashYdno Deposit cru.6cs. Izv. All SM. Otd. khim. r-auk no. 1:109-114 ja 161. (2-ar-A 14:2) .1. Kliimichaskiy inatitut im, A.Te. Arbuz(ria Kuzanskogo filiela -AN SSSR. LES B.; IZMAYLOV, R.I.; URMANCHEYEV, F.A.- LIPATOVA I.P., KHASHAYET, S.-Kh.G.; LAMANOVA, I.A.; BUKF",LYF.V I R.G. Individual hydrocarbon composition of the petroleums of Tataria. Report No-5: Ligroine from the petroleum of the Bavly Oil-Field. Izv. AN SSSR. Otd.khim.nauk no.7:1310-1315 J1'161. (141RA 14:7) 1. Khimicheskiy institut im. A.Ye. Arbuzova Kazanskogo filiala AN SSSR. - (Bavly region--Petroleum) (Ligroine) LE, B.; URMARCHEYEV, F.A.; LIPATOVA, I.P.; BUKHARAYEVA, R.G.; LAMANOVA, I.A. Determination of the individual hydrocarbon conposition of oils of the Tatar A.S.S.R.. Report No.6: Ligroin cbtained from petroleum of the Shugurovo oil field. :-zv.AN SSSR.Otd.khim. nauk no.10:1858-1863 0 161. (MIRA 14:10) 1. Kazanskiy institut organicheskoy khimii AN SSSR. (Shugurovo--Petroleum--Analysis) (Ligroin) URMANCHEYVI, F.A;; LE, B.; BUFARAYEVA, R.G.; LAMA10VA, I.A.;-LIPATOVA, I.P. Determination of the individual hydrocarbon compositiin af gas- olines in oils of the Tatar A.S.S.R. Report Ho.7: Gasoline from Shugurovo oil fields. Izv.AN SSSR.Otd.khim.nauk no.11:2063-2065 N 61. (MIRA 14:11) 1. Institut organicheskoy khimii AN SSSR, Kazan'. (Shu,yuravo--Gasoline) LE, B.; KASHAYEV, S.-Kh.G.; PNYATOV, M.Z.; LIPATOVA, 1.P.; LAMANOVA, I.A. 4Raman spectra of normal paraffinic hydrocarbons Cll - C17 and their spin-lattice relaxation time. Khim.i tekh.topl.i masel 8 no.112 22-24 N 163. (KRA 16t12) 1. Kazamlkly institut organicheskoy khimii AN SSSR i Kazanskiy gosudarstvennyy podagogicheskiy Institut. LIFATOVA, I.P. Vanadyl cb1cride z:olntioriB in organic zolvunf-, the !%e4I.,3ds of infrared adsarptlon arid -~~Iectron parafu,~~r,nl.lr: !"+,-,~.'tra. Dokl. AN SSSR 164 no.4:849-851 0 165- (MIRA 18:10) lo Institut organicheskoy 'Ahimil AN 74~7wi. Su--i!Lted March 22., 1965. L-169,33-65 EW(m)/ZPF(c)/T._ Pr4 WE 2_/ 7 Aar"ES$ION NA r A~W2 611/000 b66/1484/1h86. AM101b"-, Bq Urnmicheyew, F. AO; Watowl, j3!*hoirayvvP,, R. G,; TITLE i Determinntion of imlividual hydrooprbon composition of petroleum of Taterias Report 8, Lifw6in 'of Rom,-.shkinqk1y deposit (Al I m at I yevnk "YD Irea petroleum) SOURCE: AN 586P. Izvestiy,-. S-riyn khimicheskaya,, Po. 0p 196h., 1484-1488 TOPIC WGS: crude, petroleu:n, hydrocprbon rV Abstract: The individual and group composition~of Ligroin (150-2000) of V.:Petrolet;m.from-the Romachinskiy Deposit, Allmet'yevskaya Area, was investiga-, ted. 46 aromatic and hydroaromatic hydrocarbons were found. The 146-2050 fractLon Cn2B.= 1-.4362- d20 = 0.7778, sulfur content 04108%) was separated .1 4 by0silica gel adsorption into a naphthene-praraffin protion NPCh-1 (83.8%; n 1.4246; d2R - 0.7627) and aromatic hydrocarbons A, (14.8%;, n2B 1,4980,w 20 = 0.8747). A catalysate was obtained from NPGh-l (yield 88?7%; n~ = 1.4~30; d20 - O.M7), comprised of 86% naphthane-paraffin portion NPCh_2 and 11 . 71 aromatic hydrocarbons A2 (8.7% of ligroin and 9,1%' in recalculation to converted six-member cyclanes). It was found that the Card 1/2 SHEYNKER, Yu.N.; POSTOVSKIY, I.Ya,; BEDNYAGIIJk, N.F.; SRMNINA, L.B.; LIPATOVA, L.F. .- Equilibrium between the tetrazole and azide forms in benzothiazole- tetrazole. Dokl. AN SSSR 141 no.6:1388-1390 D 161. (14MA 14:12) 1. Urallskiy politekhnicheskiy khimii prirodnykh soyedineniy M.I.Kabachnikom. (Benzotbiazole) institut. im. S.M.Kirova i Institut AN SSSR. Predstavleno akademikom (Tetrazole) (Azides) LIPATOVAV L.F.; POSTOVSKIY, I.Ya. Certain amides of sarcolyBine. Zbur.ob.khim, 32 no.4:1062-1064 Ap 162. (MIRA 15:4) 1. Urallskiy politekhnicheakiy institut imeni S.M.Kirova. (Sarcolysine) POSTOVSKIY, I, LIPATOVA, L.F. De4yAtivea of acenaphthene containing a bi a chloroethyl)-amino 9r"p, Zhur.ob.khim. 32 no.4:1067-1068 APT7,62. (MIRA 15:4) 1. Urallskiy politekhnichaskiy institut imeni S.M.Klrova. (Acenaphthene) TYURENKOVAP G.N.;_LIPATOVA L.F.; POSTOVSKIY, I.Ya. Collector action of certain-substituted 2-nercap benzimidazoles. TSvet.met. 36 no.2t77-90 F 163. 1 (KMA 16s2) (Flotation-Equipment and "pplies) #, (Hercapto compounds) L117ATOVA, L.S., asPL--ant Rolp of ra"llonal !,,Li,rtf,Lrn -,f childrem of' :ichc,,;l ag.!~ llr prevention of derital cnr'ns. Trudy TSIIJ 64:;11-j'-, f~~ - L (141RA 17:51, 1p VA.) IV -&.Meow ~N% aA co 6i;i-~_= Fw tim r tbt to-,. ljo x t0-4. tow. !pl.j74GX 10 so 21- lp ILVI. jkboll d WE 9 LIPATOVA, L.V. (Leningrad) Streptococcal anginas, analogues of scarlet fever. Vest.otorin- 22 no.2:19:22 Kr-Ap 160. (KIRA 13:12) 1. Iz kafedry infektisionafth zaboleveniy u detey (ispolnyayushchiy obyazannosti zav. - dotsent A.T.Kuzimichevs) Leningradskogo pediatrichookogo meditsinskogo instituta i detskoy infektaionnoy bollnitay Sverdlovskogo rayons. (WR3PTOCOCCAL INFECTIONS in inf. & child) (TONSILLITIS pathol.) (SCARLET PEW pathol.) -LIPATOVA, L.M. Catapmestic observations on children who have had streptococcus angiha. Vop. okh. mat. i det. 6 no.11:49-52 N 161. V'URA 14-12) 1. Iz kafedry infektsionnykh zabolevaniy u detey (zav. - dotsent A.T.Kuzlmicheva) Leningradskogo pediatricheskogo instituta. (dir. - kand, med.nauk Ye.P. Semenova) i Detskoy infektsionnoy bollnitsy Sverdlovskogo rayona. Leningrada (glavnyy vrach - zasluzhennyy vrach RSFSR N.A. flikitina). (STW,' TOCOCCAL DIFECTIONS) (TONSILS-DISF-ASES) USSR/Farm Animals. Rabbits. Q-3 Abs Jour.- Ref Zhur - Biol., No. 22, 19582 101225 Author Kim, M.M., Lipatova, N.A. Inst Scientific Research Institute of Rabbit and Fur Animal Fusbandry Title Norms for FeedinR Rabbits with Vitamin A. Orig Pub: Byul. nauchno-tekhn. inform. No.-i. in-ta kroli- kovodstva i pushn. zverovodstval 1958, No. 2,13-14 Abstract: One hundred ard forty young rabbits (11-2 months) were employed in experiments carried out by the Scientific Research Institute of Rabbit and Fur Animal Husbandry. The rabbits were divided into 7 groups (20 animals in each -roup). During the entire experimental period, each animal in a ,group received the following average amounts of Card 1/2 62 USSR/Farm Animals. Rabbits. Q-3 Abs Jour: Ref Zhut " Bibl,j Yo. 22, 1958$ 101225 vitamin A (in m units) daily: Id the Ist group, 655; in the 2nd group, 3,068; in the 3rd group, 1,577; in the I+th group, 5,304; in the 5th group', 7,395; in the 6th group, 7,120; and in the 7th group, 22,476. According to these various groupings7 live weights of baby rabbits at 2-4 months of age did not very greatly; at 4-4.5 monthst respective weights (in g) amounted to: 27360; 2~295; 27380; 21095; 21170; 2,133; and 27435- Card 2/2 UPATOVA Xi= Tvannvna: STEPANOVA, 011ga Mikhaylovna; KHARAS, K.-K'-"fiau6hri. red.; ISH, N.N., red.; TOKER, A.M., tekhn. red. (Industrial training of cooks] Proizvodstvennoe obuchenie povarov; metodicheskoe posobie.- Moskva, Proftekhizdat, 1963. 187 P. (MIRA 16:9) 1. Zamestitell direktora po uchabnoy rabote profeasionallno- takhnicheakogo uchilishcha No.10 Leningrada (for Lipatova). 2. Starahiy master proizvodstvennogo obucheniya professio- nallno-tekhnicheskogo uchilishcha~-No.10 Leningrada (for Stepanova). (Cooking schools) 8/070/61/006/011/007/013 B101/B147 AUTHORS: Morozov, I. S., Toptygina, G. M., Lipatova, N. P. TITLE: Investigation of compounds formed by titanium trichloride with chlorides of alkali metals and ammonium chloride PERIODICAL: Zhurnal neorganicheskoy khimii, v. 6, no. 11,1961, 2526-2535 TEXT- A special problem of producing titanium metal from chloride melts by electrolysis is studied. Conditions under which compounds of TiCl 3 with MeCl (Me =Cs, Rb, K, Na, NH 4) form, the composition of these compounds, and their solubility in HC1 are examined. These compounds which formed in aqueous solution were compared with those forming in salt melts. In the systems TiCl 3 -MeCl -H20 saturated with TiCl 3 and MeCl at OOC, no interaction could be determined visually. When saturating the solutions with dC1 gas, light-green precipitations deposited which were analytically identified as pentachloro-aquotitanates (Ce 2 TiCl5H20, Rb2TiCl 5H20, (NH 4)2 TiCl5H20, K2TiCl5 H20). They have a high hygroscopicity Card 1/3 S/078/61/006/011/007/013 Investigation of compounds formed by... B101/B147 and are attacked by 0 2' The potassium compound immediately decomposes in the air while the sodium compound does not form. Birefringence is characteristic of the Cs-, Rb-, and NH 4 compounds: Compound N I N2 Cs2TiCl5H20 1.678 10.002 1.645 10.002 Rb2TiCl5H20 1.682 10.001 1.638 +0-003 (NH4)2 TiCl5H20 1.694 10.002 1.664 +0.002 Solubility of pentachloro-aquotitanates (% of TiCl3) for ^J44 % HC1 is 0.35 for the Cs compound, 0.26 for the Rb compound, 0.67 for the ammonium compound, and 1.50 for the X compound, With decreasing 1fCl concentration, solubility of pentachloro-aquotitanates increases with simultaneous decomposition. In the solid phase, alkali chlorides and (for the Cs compound) TiCl 3' 6H20 occur besides the complex compound. In dilute HC1, only the mixtures of alkali- and titanium chlorides precipitate. Thermo- Card 2/3 V/ S/078/61/006/011/007/013 Investigation of compounds formed by... B101/B147 graphic and X-ray analyses proved that H 20 of pentachloro-aquotitanates is inside the coordination sphere of the complex. On heating, water in separated, Temperatureas 2700C for the Cs compound; 2120C for the Rb COMDound; 1160C for the Nff4 compound, and 1120C for the K compound. In hydrochloric solution, titanium has the coordination number 6. The compounds found in anhydrous systems by other researchers do not form under the conditions described. A paper by M. V. Kamenetakiy (Tsvetnyye metally, j, 39 (1958)) is mentioned. There are 4 figures, 6 tables, and 14 references: 10 Soviet and 4 non-Soviet. The reference to the English- language publication reads as follows: P. V. Schossberger. Ind. Eng. Chem., 51 (5), 157 (1959). SUBMITTED: December 22, 1960 Card 3/3 S/078/61/006/011/008/013 B101/B147 AUTHORS- Morozov, 1. S., Toptygina, G. M., Lipatova,11. P. TITLE: Thermographic and X-ray analyses of compounds formed from titanium trichloride with chlorides of alkali metals and ammonium chloride PERIODICAL: Zhurnal neorganicheskoy khimii, v.6, no. 11, 1961, 2536-2544 TEXT: In a previous paper (Zh. neorg. khimii, 6, 2528 (1961)), the authors synthesized the pentachloro aquotitanatis of Cs, Rb, NH 49 and K. In the present paper, they report on 1) the synthesis of pentachloro titanates of Ca, Rb, NH 4' and K; 2) the powder patterns of pentachloro aquotitanates and pentachloro titanates, and 3) the thermal analysis of these compounds with Kurnakovlu pyrometer. Results; 1) The temperatures at which aquo compounds separate 11 0 are: 270`C for Cs TiCl H 0, 2 2 5 2 2120C for Rb 2TiCl 5H2o, 1160c for (N11 4)2 TiCl 5H20, and 1120C for K2 TiC15H2 0. The compounds Cs 2TiCl 51 Rb2 TiCl 5' (NH4)2 Ti C15' and K2 Ti C15 Card A -3 3/078/61/006/011/008/013 Thermographic and X-ray analyses of ... B101/B147 were obtained by 6-8 hr heating in HCI stream under slow temperature elevation from 250 to 3500C with the Cs compound, from 200 to 3000C with the Rb compound, and from 100 to 1500C with the NE 4 and K compounds. The light-green color of the initial compounds changed: into olive-green with Cs and Rb compounds, and gray with the K compound. The NH 4 compound remained light-green. 2) The powder patterns of these compounds are shown in Fig. 1~ They differ from those of pentachloro aquotitanates, which are also given. Lines of components do not occur in either of the two powder patterns., The X-ray data of K 2TiCl 5 differ from those of F. Ehrlich et al, (Z. anorg. Chem. 299, 213 (1959)) obtained by another method of synthesis. X-ray analysis reveals that the crystal structure is changed by removing H 20 from inside the coordination sphere of the complex whereas the skeleton formed by heavy atoms remains almost unchanged. Ti has the coordination number 6. 3) Due to the low stability of the compounds, the thermographic analysis was conducted in an inert gas stream. It showed: (a) that all aquotitanates separated water at the given temperature. At a further temperature elevation, interaction Card 2/0 '?, 3/078/61/006/011/008/013 Thermographic and X-ray analyses of... B101/B147 between free 1120 and Ti compounds caused side reactions by Ahich deciphering of the thermographs was rendered difficult. (b) Pentachloro titanates have two phases, one of which, TiClY is disproportionated into TiCl2 and TiCl 4' Nil4of the Nil4 compound is decomposed, and titanium nitride forms. A paper by M. V. Kamenetskiy (Tsvetnyye metally,.?., 39 (1958)) is mentioned. V. G. Ku-znetsov is thanked for advice, and Z. V. Popova for assisting with the X-ray analysis. There are 2 figures, 3 tables, and 25 references: 12 Soviet and 13 non-Soviet. The three most recent references to English-language publications read as follows: K. Komareck, P. Herasymenko. J. Electrochem. Soc.,)105, 216 (1958); F. V. Schossberger. Ind. Eng. Chem., 51, 157 (195 ; H. P. Klug, E. Kummer, A. Leroy. J. Amer. Chem. Soc., 70, 3064 (1948)- ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. N. S. Xurnakova Akademii nauk SSSR (Institute of General and Inorganic Chemistry imeni N. S. Kurnakov of the Academy of Sciences USSR) SUBMITTED- February 24, 1961 Card 314 ~"' MOROZOV, I.S.; LIPATOVA, N-P-* SIMNICH, A.T. Therml ~d tensimetric studies of the system NbCl 5 - ZrCl - XCL* Zhur.noorg.khim. 8 no.l.-172-176 Ja 163. (MIRA .15) 1. Institut obahchey i neorganicheakoy kbimii imeni N.S.Kurnakova AN SSSR. (Chlorides) (Thermal~',&nalysis) (Vapor pressure) LIPATOVAS HoPol MMOZ-Np I.S* ConpoWs of niobdLum azychlorlds vith AIkaIJ wtal ablorldes and awmium chloride, Zhur, neorg, khlu* 10 noo2t429-436 IP #65* (MIRA issia) 1. submitted oat. 15, 1963. LIPATOVAI N.P.- ~IOROZOV) I.Se Z _- X-ray diffraction examination of pentachlorooxyniobates of alkali metals and ammonium. Zhur.neorg.khim. 10 no.12: 2817-2819 D 165. (MIRA 19:1) ALUMM, N.A.;- AISKKA IT, A.A.; ZOTOV, A.I.; LIPATOVA, N.Ya. Certain characteristics of the formation of complex conditioned motor reactions in am. Zh. vys. nerv. delat. 5 no.6:773-782 N-D '55. (HIMA 9:3) 1. Leningradskly nauchno-issledovatel'skly Institut fizichaskoy kulltury. (MWIAX, CONDITIOM, conditioned motor complex reactions in man, mechanism of form) KAYOROV, F.P.; PAVLOV, B.V.; LIPATOVA, N.Ya. Changes in the higher nervous activity of dogs under the affect of X-Irradiation of the cervical section of the vegetative nervous system. Trudy lust-fitiol. 5:79-102 056. (MURA 10: 1) 1. Laboratortya fiziologii I patologil vysshey nervnoy deyatell- nosti. Zavacluyushably - F.P.Kayorov. (I RAYS --PH" IOLDGI CAL IFFECT) (MVOUS SYSTIM) LIPATOVA, Kja.; KAYOROV, F.P.; PAVLOV, B.V. ,~- Iffect of total body irradiation on the higher nervous nctivity in dogR. Trudy Inst. fiziol. 6:310-321 '57. (MIRA -,11:4) 1. Laboratoriya fisiologii i patologii vysshey nervnoy deyntellnosti (saveduyushchiy F.P. Mayorov) (NMVOUS SYSTEM) (X RAYS--PHYSIOLOGICAL FIFFECT) LIPATOVA, N,Ta.-, MAYOROT, F.F. 9tudying the effect of total-body X irradiation on the higher nervous activity in dogs. Trudy Inst.fiziol. WO-76 159. (MIRA l3:5) 1. Laboratorlya fisiologil i patologil vymehey nervuoy dayatel- nostl (saveduyushchly - F*F. Mayorow) Instituta fiziologii im. I.Pe Favlovs, AN SSSL '(x PAys-PHYsiowmAL myrim) (commom uspoNss) L 54032-65 /E74P(h) Ps-4 IJP(c) JL ACCESSION NR; AP5013521 UR/0076/65/039/005/1108/1111 541.8 AUTHOR- Beloy, V. T.; Va&!RAj~_I. ~LLLipatova. H. Ye. ITITLE: Hydr -ation of anodic oxide film 0 ~lumin in aqueous solutions of in- !organic salts -4 _7 --[SOURCE! himii, v. 39, no. 5, 196S, 1108-1111 ~ITOPIC TAGS: aluminum oxide, hydration, anodic oxide film -formed by 1 ABSTIMM Volume of hydrogen in eracting water vapor and calcium 'hydr-ide, wan. measured to- d_etermine- the water-. content -of anodic oxide f ilmr, filled 7'. -4 to !with water at _95IC-in sodium dichromate, sulfate, and phosphate solutions (10 :1 mol/0. In the order of their effect an hydration of the oxide film, the anions i - - ;are: H 2- When the films are filled-in phosphate solutions, the, 2PO4 5 HU04 > S04 Er quantitj.6f the sorbed.phosphate ion increases with the concentratior of tile latterr' in the solution, and the water content decreases. In dichromate solutions, the water content of the filled film depends only slightly on the solution concentret- card 1/2 L -~"32-65- !ACCESSION NR*- AP50135-21, tion, but the water.content increases with risin concentration. In sulfate solu- 9 tions, the water content of the film increases with the concentration of the solu- tion, aad the sorption of the sulfate ion either promotes or.does not interfere with the adsorption of water. Differences in filling conditions have a pronounced i effect on the state of the surface of the anodic film; the sorption of anions and !the hydration of the film are variously affected. Orig. art. has: 1 figure . ASSOCIATION: Kazanskiy avi.atsionnyy institut (Kazan Aviation Institute) SUBMITTEM 12Dec63 ENCT': 00 SUB CODE: GC INO REF SOV: 012 OTHER: 006 i.Card, -2 LIPATOVA, O.A. - - Some results of observations made at Irkutsk to determine the total ozone content of the atmosphere. Trudy GGO no.141:80-82 163. (KRA 17:4) LIPATOVA, P.K.0 dotsent Glinical aspects and treatment of rheumatic polyarthritis with Penicillin. Vrach.delo no.6:651-653 Je 157. (MLRA 10:8) 1. Kafedra fakulltetskoy terapii LIvovskogo meditsinskogo institua (nauchnyy rukovoditell - prof. T.T.Glukhenikiy) (PSNICILLIN) (JOINTS--DISEASICS) (RHWUMATIC FXVXR) LIPATOVA, P.K., dots. Featuren of the mechanism of decompensation and compensation in respira- tory and ourdiac insufficiency. Vrach.delo no-8:785-789 A 158 A~ 11:8) 1. Kafedra fakulltetakoy ternpii, Ltvovskogo meditainskogo inatituta, (PULMONARY ZMPHYSEKA) (BLOOD VOLUME) (HDM FAILURE) LIPATOVA, P.I., doteent Compensatory factors In pulmonary emphysema. Vrach. delo no.4: 427-430 AP '59. (KIU 12:7) 1. Kafedra fakulltetBkoy terapil Livovskogo meditainakogo instituta. (UPffSXKA, PUIXONART) LIPATOTA, F.K., doteent Actlylty of some rospIratory ferments of the blood to cardiovasculAr and cardiopulmonary insufficiency. Trach.delo no.9s947-951 3 159. (MIRA 13:2) 1. 111alla fakulltetakoy terapli Llvovskogo meditsinakogo instituta. (UZTKIS) (CARDIOVASCULAR STSTION-DISRASIS) (LUNGS-DISTASIS) I.~FATGVA, P. K. Influence on stomach function of some physical methods of treatment (diathermy, novocaine electrophoresis, and paraffin applications. Vop. kur., fizioter. i lech. fiz. kal't. 26 no.1:27-31 161. (MIRA 14: 5) 1. Iz kafedry fakulitetsko terapii Llvavskogo meditsinskogo instituta (dir. - prof. L.N.Kuz (PTOMACH-DISEASES) (DIATHERMY) (NOVOCAINE) (ELE-CTROPHO=IS) (PARAFFINS-THEWEUTIC USE) LIPATOVA, P.K.. doUent Q = tity of the circulating blood in pulmonary and cardiac insufricienvy. Nauchotrudy Llvov.obl.terap.ob-va no~13189-193 161., (MIU 1615) 1. Kafedra fakulltatskoy terapii lachabnogo fakulsteta LO-7ovskogo meditsinskogo institata (zav. kafedroy - prof. S.F. Oleynik). (WWS124A3, PUMONARY) (FMCKARY MMT DISUSE) (BLDOD, VOWME) -LIPATOVA-j PA-9 dotsent Activity of-catalase in cardiovascular and palmo-cardiae in- sufficiency. lauch.trudy L'vov.obl.terap.ob-va no.11207-211 161, (HIRA 1615) 1. Kafedra fakulltetskoy terapil lechelmogo fakullteta LOvovokogo meditsinskogo instituta Nav. kafedroy - prof. S.F. alaynik). (CATALASE) (RMYSR4Aj PUIMONARY) (PUIMONARY lMqRT DISUSE) I LIPATOVAV P.Kop dotsent; IMTIYEVA, L.K.v vrach Artificial nitrogen bathe in the treatment of bypertersim. Nauch. trudy LIvov.obl.terup.ob-va. no.1:280-283 161. (MIRA 160 1. LlvovBkayq oblastnaya ballneologicheeka7u bolinitsa (glavnY7 vraoh - Ye.4 Solyakina) i kafedra fakalltetakay jerapli lechabno- go fakulltata Vvovskogo meditzinskogo inatituta ~sav, kafedroy - profe SOPS Olsynik) (ROMMSION) ?,VITRO=-THERAMTIC USH) (BATHSX MEDICATED) LIPATOVA, T. Z. USSR/ Chemistry-- Petroleum Technology Synthetic Elastomers 21 Jan 51 "Polymerization of Isobutene to High-Molecular Products,8 Acad A. F. Topchlyev, Ya M. Paushkin, T. Z. Lipatova "Dak Ak Nauk SSSRO Vol LXXVI, 10 3, pp, 415-418 Isobutene can be polymerized to dilsobutene which is later hydrogenated to isooctane. It can also be polymerized by means of chain reaction to products having high mol wt. In chain reaction. activity of catalysts with reference to dog of polymerization achieved is as follows: BY 3>C6H5 OCH3. BY :711 O.BT rff 3PO4. BY --,-(C 2H5) O.B1? Activity of catalysts is different with ref to the stepwise reaction resulting in low polymers: POIL-BF-1 ~- H90. By3>1 H2S04 By > B# >- (Rl) BY Solvent in which 3 3 + 3* pol- -C'arrted obLt has effect on deg of polymerization. Copolymerization of isobutene with n-butene or propene, w,s also investigated. 178T12 LIPPTOVA, T. E. USSR/Chemistry - Elastomers, Polymerization 21 Oct 52 "INitintion Mechanism in the Catalytic Polymerization of- '.nsaturated Compounds," A. P. Gantmakher, S. S. T-edvedev, Corr Yem, Acqd Sci USSR, T. E. Lipatova "Dod Ak Fauk SSSR" Vol 66, No 6, pp 1109-1111 A conclusion drawn by P. H. Plesch, IL'. Polanyi, H. P. Skinner, A. S. Evans, and G. W. Meadows is found to be incorrect. Those authors cl9im that in the catalytic polymerization of isobutene in the liquid state or in hexane solus with TiC14 and BF3 catalysts at low temps, the addn of H20, CCl COOH etc., is necessary in order that the reection may proceed. T9is i's disputed in the present work: It is shown that by raising either the temp or the dielec const of the solvent, catalytic polymerization of unsatd. compds can be made to proceed in the presence of aprotonic acids (SnC14, AIC13, TiC14, and others) without the addn of H20, CC13COOH or other substances acting on the catnlyst under for- mation of protonic acids. PA 234T25 ; ; [ - - ~- '-- ; - 1 -- a Dissertation: "Investipation of Carbon Copolyincrization of Unsaturated Compounds." Caryl Chem Sci, Order of Labor i'efj Fanner Sci Iles Physicochemical Inot imeni L. Ya. Farpov 17 MaY 54. Vecharroraya Moskva, Moscow, 7 May 54. SO: SUA, 284, 26 Nov 1954 VSSR1Gh(,1PiVt1'Y CatalYtic polyrrimrizotion, Pub. 22 22/49 Authors I Lipatova T. E.; Gantmukher, ;t. 11.; and Medvedev, S. S. Mcirb. Cori-esp. ussm Title j Catalytic copolymerization of unsaturated compounds Periodical, 'I Uok. All SSSR 10015. 925-928, Feb 11. 1955 j The kinetics of ceta)ytic copolymerization of isoprene-styrene. SnGl4 catalysts w s isoprene-alphs-methylatyrene systems over a investigateq to determine the copolymerization constants for the!~e systems. The dependence of the copolymerization rate upon the composition of the basic mixture and the molecular weights of the homologous copolymers were determined. The ion mechanism.of catalytic polymerization In the presence of an SnCl4 catalys' is exPlainea. Bight references- 6 USA and 2 USM (1944-195.5). Table; graphs. institution ....... SubmitW S' ;U1Y,3, 1954 AUTHORS: Lipatova, T. E., Cantmakher, A. R., SC)-1/76-'J!2-9-"3/-,'6 M-edVn 'ev, -- S .- -S . TITLE: The Catalytic Copolymerization of Unsaturated Compounds (Sovmestnaya kataliticheskaya polimerizatsiya nenasyshchennykh soyedineniy) II. The Copolymerization of Isoprene and a- Methyl Styrene (II. Sovmestnaya polimerizatsiya izoprena s a-metilotirolom) PERIODICAL: Zhurnal fizicheskoy khimii, 1958, Vol 32, Nr 9, pp 2o29 - 2034 (USSR) ABSTRACT: These compounds were polymerized in an ethyl chloride solution at OOC using tin (IV) chloride as a catalyst. The composition of the copolymers formed was determined from the volume decrease during the polymerization and by means of infra-red spectroscopy. The spectra are reproduced in figures 1,2, and 5. The molecular weights were determined by the osmotic method (Table 2). Diagrams show the course of the polymerization of a-methyl styrene alone (Fig 5) and of the copolymerization of isoprene and a-methyl styrene. The work shows that three components, isoprene, a-methyl Card 1/2 styrene, and a product of copolymerization with inner The Catalytic Copolymerizatillon of Unsaturated Comip~junds. S'ay/76-'2-9-13/46 II. The Copolymerization of Izoprene and a-Methyl Styrene double bonds take part in the polymerization reactions. Steric factors are important in the reaction between tile tertiary carbonium ion and monomers. a-methyl styrene is considerably more reactive than isoprene. The initial reaction rate in the polymerization of the a-methyl styrene is decreased by the introduction of isoprene into the system. Thin is explained by the fact that various complex monomer-catalysts are formed. This formation reduces the concentration of the complex formed by the tin (IV) chloride with a-methyl styrene, which is the more active of the two monomers in initiating carbonium polymerization. There are 7 figures, 2 tables, and 2 references, 2 of which are Soviet. ASSOCIATION! Fiziko-khimicheskiy institut im.L.Ya.Karpova Moskva (Moscow '7 Physical-Chemical Institute imeni L.Ya.Yarpov) SUBMITTED: April 4, 1957 Card 2/2 170) AUTHORS: Fmanuoll, 11. M., Corresponding Member, SOV/20-124-5-56/62 AS. USSR, Lipchina, L. P., Pelevina, 1. 1., Lipatova, T.. E. --------------- TITLE: The Selective Inhibition of tho Activity of Redul'tion.-Ox-4fdation Enzymes in Tumoral Cells When Acted Upon With Inhibitors of Chain Reactions (Izbiratel'noye podavieniye aktivnosti okiBlite.'Jl.lno-vosstanov:Ltel?nykh fermentov v opukholevykh kletkakh pri vozdeystvii ingibitorov tsepnykh reaktsiy) PERIODICAL: Doklady Akademii nauk SSSR, 19599 Vol -124, Nr 5, i)P 1157-1159 (USSR) ABSTRACT: Since many years the idea of a selective inhibition of fermentative processes J.n tumoral cells, as a rational principle in can:',er chemotherapy, focuses the interest of the scientists (Ref 1). The first two authors (Ref 2) proved an inhibition and a retrogression of leucosis in mice under the action of non toxic inhibitors of the oxidative chain reactions (butyl-oxy-anisole, ionong, propyl gallate)(Ref 2). There were reasons (the radical mechanism of the reduction-oxidation processes) for assuming that the inhibition mentioned in the title is one of the reasons of the tumor inhibiting effect of the mentioned substanues. This disturbs the formation provesses Card 1/3 of some energy-rich compounds which are necessary foT the The Selective Inhibition of the A-A_f.rity of SOV/?0-"-?4--5,- 56162 Reduction-Oxidation Ensymes in Tumoral Cells V11--en Ac?d 'Ulp,~n 37i'lli of Chain Reactions intense bioeyn-1-heeis -'.n the neoplastio growtt, In the present paper results (OUId b-~ 6btalred which -~cnfirm th~ ab3ve- assumpt*'on. The authors investigated emy-mes of the succincxidase syitex.. M a9ALt-*I,: an,,e.r of Ehrlich (Erlilch) in m'!-e. leuo.)sjs of 1,,'&,ik mAce (line C-57, strain LA), acridine sar-:-ma of and the Braun-Pirs tumor of rallbita served for thc: experimento. Cells of the I-an~tGr a-3 well as tum-ral t4,ssu.,:!s of rj%pr new f-.)rmafj.c-ns reducpd tc. small pier,~es were In-abated for 30 minutes in 0.75, 01-15 and 0.075% propy! gallate solation, These ~~or)-.-entrationa inhibit the acti7itly of suc~-"ne dphydrcgenasp in the calls of all tumors investigated (Pigs-!, 2). The at!tivity of this enzyme I's not s,)ppressed in healthy 11-i-ver and spleen c;alls by propyl gallate solutions of 0.15 and 0.075% (Figure 3). Incubation in a 0,75% solution is, however, inhibiting. This inhibition is rovers--ble in afflicted as well as .'La sound c-3119. The differences in the propyll gallate effect on the red-a.--tion-oxidation. process-'.p in normal and .-Ils are probably due to a differ-?nt Card 2/3 permeabj.'---*ty of the c-17s and their The Selective Inhibition of the Acttvity of SOV/20-124-5-56/62 Reduction-Oxidation Enzymes in Tumoral Cells When Acted Upon With Inhibitors of Chain Reactions to propyl gallate. Thus, propyl gallate has a w~leative effeit on tumoral cellD in certain conoentrations. Thi3 Ja oxproosod by the inhibition of the activity of dehydrogenases which. participate Jn various reduction-oxidation processes as well as of cytochror;-~*xidase. The thus influenned colle loose their implantatioi- power. There are 3 figures and 6 refererioe3, 5 of which are Soviet. ASSOCIATION: Institut R:him--*cheskoy fizlki Akad,~_mii naliK SSSR (institute of Chemical Physics of the Academy of Sciewes,USSR) SUBMITTED: November 25, 1958 Card 3/3 86330 5'gl 05 S11901601002101210191019 B017/BO78 AUTHOR: Lipatova, T. E. TITLEt On the Possibility of Hardening Unsaturated Polyesters With Titanium Tetrachloride PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 12, p. 1882 TEXT; The hardening of polydiethyleneglycolmaleate with styrene and of polyacrylate esters in the presence of titanium tetrachloride has been X studied. Polydiethyleneglycolmaleate and styrene were used in a ratio of 1:1. Thepolymerizates thus obtained were insoluble and did not swell in alcohol-benzene mixtures. When kept in benzene for a few hours, they swell. By hardening of polyacrylate esters, soluble polymerizates of approximately 50 % were obtained. After 18 hours of polymerization polymerizates soluble in acetone were formed, polymers insoluble in benzene,acetone, and styrene, but swelling in benzene were obtained after 48 hours. lt has been found that titanium tetrachloride can cause the hardening of polydiethyleneglycolmaleate with styrene and of polyacrylate esters.~There are 2 Soviet references. Card 1/2 86330 On the Possibility of Hardening Unsaturated Poly- S/190/60/002/012/019/019 esters With Titanium Tetrachloride B017/BO78 X, SUBMITTED: June 22, 1960 Card 2/2 . , IaPATOVA, T.B. Some problems in the kinetics of the telomerization reaction. Dokl.AR EM 4 no.4:164-167,AP 160* (MIRA 13:10) 1. Institut obshchey i neorganicheakoy khimii AN BSSR. Predstavleno akademikom AN BSSR B.T& Urofeyevym* (Polymerization) 89585 S/19o 611003100210031012 B130%202 AUTHORS: Lipatova, T. E., Lipatov Yu. S., Tutayeva, N. L. TITLE: Effect of the grafting of polystyrene on the properties of orientated polyethylene PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 2, 1961, 184-190 TEXT: The authors attempted to modify the polyethylene properties by means of grafting. The polyethylene film washed in benzene and dried in the vacuum was orientated by elongation to 435-460% of its initial length. The elongated film was 0-004-0-0044 am thick. The purified inhibited freshly distilled styrene was grafted in the vacuum (10-3 mm Hg) in a quartz ampoule at 250C under the ultraviolet light of a TW-2 (PRK-2) lamp according to a method by G. Oster (Ref. 9 see below). Benzopheyxre (3f* solution in benzene) was used as sensitizer. Before grafting the films were immersed into the benzene solution for 15 minutes. Subsequently, benzene was evaporated in. the vacuum. Birefringence of the dry film was by 5~ less than before treaAment. To avoid the homopolymerization of styrene, first the film was exposed, and then styrene was added in the vacuum. The authors studied the Card 1/2 89585 s/igo/61/003/002/003/012 Effect of the grafting B130/B202 birefringenoe of the grafted specimens by means of thP,7yKC--56(PKS-56) poiari- scope polarimeter as well as the temperature dependence of shrinkage. Birefringence has a maximum in the case of 7% po3ystyrene, it is strongly reduced at 9.20, and begins to increase again at 12.3% to attain a maximum at 18-3%. Grafting inhilAts shrinkage of polyethylene on heating. The present studies and the changes of An as depending on the polystyrene added indicate that grafting takes place in the submicroscopic cavities formed due to shrinkage. V. A. Kargin is mentioned. There are 6 figures, 1 table, and 13 references: 9 Soviet-bloc and 4 non-Soviet-bloc. The reference to English language publication reads as follows: G. Ostert H. Moroson, J. Polymer Sci-, JA, 4/9, 1959- ASSOCIATION: Institut obs1rhey i neorganicheskoy khimii AN BSSR (Institute of General and Inorganic Chemistry, AS BSSR) SUBMITTED: June 14, 1960 Card 2/2 LIFATOVA, TX.; TUTAYEVA, N.L. Effect of the _rrafting of styrene on the dotible refraction or orient,~d polyeth,yIene. DoIld.Al" BSS.7'& 5 no.1:12-11~ Ja 161, (MRA 24:2) 1. Inotitut obahchey i noor[:anichoskoy klibdi MI IM".. Predotavlrno al.ader.dkom All BSSR M.M.PavIyucher0co. (Polyethylene--Optical proportieA (St~a.cnc) LIPATOVA, T.E.; -cKOPYTIINA, I.S.; LIPATOV, Yu..5. Polymerization of styrene in the presence of the glass fiber treated by titanium tetrachloride. Vysokom.so(,d. 3 no.12:1877 D '61. (MIRA 15-3) (Styrene) (Polymerization) (Glass fibers) 71 S/020 16 3/1 48/002/02B/C,7 B1 1 7/B1 86 AU'fHORS: Lipatoval T._4_,_, Berlin, A. A. TITLE: Carbonium Polymerization of polyacrylic acid esters PERIODICAL: Akademiya nauk SSSR. Doklady, v. 148, no- 2, 19063, 353-356 TEXT: The carbonium polymerization of polyacrylic-acid esters in vacuo was studied at 20 + 0.10C in the presence of v0.4 moles/l titanium tetra- chloride. F~ormation and properties of the following P-polymers were investigated;~. mr~ -9 (,YGF-9) ditnethacrylate(bis-tTiethylene elycol)- phthalate, TMPE-11 (T14CF-11) totrainethacrylate(bis-glycerin)-phthalate, and MMF-2 (MD~-2) dime thacrylate -die thyl elhe glycolphthalate. M.DF-2 yielded the largest amount of 0-polymer (UP to 40,), and TY,.GF-11 fielded the lowest (5-8~j~Q)- P-polymers are able to convert spontaneously into infusible three-dimensional polymers, in air as well as in vacuo. Their properties differ considerably from those of three-dimensional polymers obtained by radical polymerization of polyacrylic acid ester. The analysis of IR spectra and thermo-mechanical studies showed that the three- Card 112 S/020/63/146/002/028/07 Carboniuat Polymerization of ... B117/B1801 dimensional polymers obtained by carbonium polymerization are unsaturated. ion ~n-GF-9, TMGF-11 , and 1,,'.DF-2 type P-polyi,,iers are suitable for the product' of elastic coatings fur glass, metal and ceramics, which are stable against numerous aggressive media. These polymers, which harden under the action of atmospheric oxygen, do not require the use of bardeners. From. concentrated solutions of P-polymers in mixed solvents fibers can be formed which cross-link in air and assume*a three-dimensional structure after being shaped and stretched. There are 3 figures-and 1 table. ASSOCIATION: Institut obshchey i neorEanicheskoy khimii Akademii nauk BSSF (Institute of Gener'al and inorganic Chemi3try of The Acade..,iy of I.-ciences-BSSR); Institut khimicheskoy fiziki Akadejaii nauk Sl"'SR'(Institute of Chemical Physics of the Academy of Sciences USSR) PRESENTED: January 18, 19062, by V. N. Kondratlyev, Academician SUBMITTED: January 15, 1962 Card 2/2 LIPATOVA, T.E.; BUDITIKOVA, V.A.; LIPATOV, Yu.S. Interaction of polymers with fillers. Part 5: Effect of the cOnditions of depositing a polymer on glass fiber and the method of treating the glass fiber on the properties of tho polymer. Vysokem.soed. 4 no.9:1398-1403 S 162. (MIRA 15:11) 1. Institut obahchey i neorganicheskoy khimii AN Belorusskoy SSR. (Glass fibers) LipATov, yu.js~;_k2gQU,,-j~ VASILERKO, Yaj.; SERGEMA, L.M. Interaction between polymers and fillers. Part 7: CUSS transiticM. point and packing densities of filled polystyrene and polymeth7l methaorylate, Vyookomoooedo 5 no.28290-295 F 163. (MIRA -16 s 2) 1, Institu~ obahchey i neorganiebooko7 khinii AN BSSR. (Polymers) (Mass f1bers) IJPATOVA, T.B,; EMIN,, A.A.; Prinimala uohastiye KAKSDIOVA, V.P. Carbmim polymerization of polyester acrylates. Doki. AjT SWR 148 no.2053-356 Ja 163. (MLRA 16S2) 1e Inotitut obehehey i neorganicheskoy khimii AN Eslorusakoy SSR i Institut khimicheakoy fiziki AN SSSR. Predstavleno aka- demikom V.11. Kondratlyevym, ("fic:17lic acid) (Carbonium canpounda) (Folymerization) SKORYNINAJ, I.S.; LIPATOVA, T.E. Grafting of polystyrene on glass fibers. Dold. AN SSSR 153 no.3:661-663 N 163. (MIRA 17:1) 1. Institut obehchey i neorganicheskoy khimii AN BSSR. Predstavleno akademikom V.A. Karginym. SOURCEt: AN BSSR.~ Dokiady*, v. '7, no, 8s, 534-537. TOPIC TAGS: resin, polyesteri polyester acrylate,,.oXigomer, beta polymer, three dimenni6nallpolymer, film, filament, infrared :J'- spectroscopy!, infra,red,,spectrum, thermomachantcal curve, thermo- -A mechanical propertyt MOP-2,,TMGF-11, MGF-9,, cross linking, deform tion strain,i unsaturationimbldingl, compression molding, prope ty fication modi The mech nism of,the formation of a three-dimensiolp -ABSTRACT i a network-in films and filaments of soluble polymers (0-~polymarx (T. E. 'Lipatova, V3~*sokom*L doyed.0 20 1881, 1960) of p u m methacry ate re i0has.been st died,. Infrared spectra.ana thit 0.! -prop:rties -of the polymers were determined., Three~ 04,~ .z':-':::- mechanical yolymers were synthesized from the following oligamers.t resip~ Card 1/4 - I. !11 .: ': _7 7 -:A P30-060dl;'' j A~ C4 9H ~NRI All F 1 n ;gl*e 1) :dimaiha'crylate phthalate MCF-9 (bis(diethy a 0 tatramethaerylate (sic]) and MDF-2P(irIethy,' ~Iene glycol'.dimethaery Ate~ -phthalate -a-egre of poly-~; [sic) with a e merization of 2)0 To study the~conversion of. the.oligomers t6~ three-dimensional polymers-, the infrared s.pectra of the three;: -spolymers in benzene-solution, films cant'from th~ oligomers 0 e 8 'benzeneisoluti e-dimensional polymer on, and the 'solid thre. were_ M measured, The three-dimensional polymers from MGF-9 and T CP u were-'obtained by carbonium-i'on'polymerizatLon or by compressi6h Iding.of their 0-polym .,ris. Owing to the low reactLv,ity of o e m doubl-e,bonds in 0-polymers from MDF-2, the:solid three-dimensi6all structure was obtained'b~,.ultraviolet irradiationjin vacuumiof~ tacky 0-polymers which1had been partially tross-Unked in air I From theinfrared spectralof HGF-9,'its $-polymer in benzene :ad-!' three-dimensional pol'mer, ind f'rom dat ..lution, and the solid I y It-7 the literature, the 1630.cm absorption bandg.which is present L J~. poly(met methyl.methaerXIateland absent in hyl methacry.late),Aw.a.s., 1: asure of, the degree..of-,uneaturation of the -._selected~as a me I Card 2/4' ..... ... ---- --- 1723--63 lilt -Ar3006001~~ ACCESSION' NR: -olig mars and that pp~lymers*i The 812'em-1 absorption- band 0 r 'used to verify the degree of unsaturation, 'and' the 745 cm- 0 sorption band, for quantititive determination-of unsaturati .1a method previously descriVed (T. E. Lipatova, Kand, dies. FK~..iml Karpova, M. 1954). It was found that unsaturation decreases;frdm the oligomer to the three-dimensional polymer. On conve ra i on o f, -polymer and to the thre* -dimensional 3101 Y~, the oligomerto the 0 a L 7 mer a~general increase.in background in the 1000-1400 cm region was observed, su'giesting that a three-dimensional net~6rk~ of C-C and C-O-C links;ia formed in the polymer. The resulte;of~ infrared-analysis were~ in:,good agreement with the thermomachalAi6al$' 'e data obtained.. The thirmomechanical curves-of a polymer moldid 'a' t from,the 0-polymer,, of'MGF-9 indicated that high deformati6 n -70C, increases with temperature,~and reaches a' axi-I begins at 60~ m i ~mum at 130-140C, Fufthir.heating caused a decrease-in deforma~i I_ I tiont owing::td network-structure formation in the polymer by'the; reaction of the remain~in~ double bonds. Polymers from TMGF-11 h di -thermomethanical propelrties ganerally associated with polymers i 6r'd 3/4 V-,17933~-63~ ACCESSION. NRI. AP3006001", "-having' a, "cons- il~erably denser three-dimensional:network, ~The d formatioli-of -this polymer was-low, despite the residual double bonds present,-Owing'to'restrieted side-chailn mobility. The ~~thermomechanicil curve or a -the polymer from MGF-2 reveals high,d formation, suggesting4 weakly croes-linked three-dimens I onal: at .ructure, Deformation does pot decrease. with an increase ln.te~_ perature,, since -the absence.of double bonds prevents further 'cross-, linking.~ It is concluded that by varying the molding conditionslit is possible to obtain:three-dimensional network-structures with A varliouszd,egrees of cross!-link.ing and unsaturation and thus to,regu -.1a't the:physicome*chanical.properties and chemical stability ~fl obtained from a his polymers given original polyester. Origo art* j~ T tab 1e and 2 figuress ASSqCIATrONt Institut opshche~y 4 neorganicheskoy khimii AN BSSR I n 9. t i t u t 6' of General land Inorganic ChemistrX, AN BSSR) j W DATE; ACQ,. ..I SUBMITTEDs 15Jan63 llSep63 ENCLt 00, 1 SUB CODE:; CH9- MA 'NO REF SOV: 009 OTHERt, 00 Ccrd 4/4. ILIFAT( -- )5AX-j.E.. -- ~ Catalytic polymrization of unsaturated polyesters. Carbcrliun polymrization of polyeateracrylates. Plast.massy no.10-7 164. (KIRA 17-.6) ACCESSION NR: AP4037287 S/0190/64/006/005/0910/0924 AUT11ORSs Lipatoyi.. To L; Siderko,, Ve He TITLEt Carbonium copolymerization of dimethecrylate-(bia-triethyloneglycol) phthalate with styrene SOURCE: Vy*sokomoleku3.yamr*ye. slyedinaniya, v. 6., no. 5. 1964, glo-914 TOPIC TAGSi carbonium copolymerizationo polyeateracrylate atyrene copolymerization# polyesteracrylate 3tyrenep monomer reactivity ratio; titanium tetrachloride catalysto copolymer unsaturation degree ABSTRACT: The copolymerization of the commercial MOF-9 dimethacrylate-(bis-tri- othyleneglycol)phthalate with styrene was conducted in a dilatometer in ethyl chloride solutions at a 1.25 mole/liter summary concentration or the monomers and in the presence of 0,003 molsAiter of TiC14. Dilatomtric measurements provided data on the reaction rate, while the composition of the resulting copolymers was determined bj infrared spectroscopy. The copolym~rization constants were calculated by the method of At, Do Abkin and So So Medvedev (Zh. rise khimils 21, 1269g 1947)9 the constant r3. for styrene was taken an 0.15 and the r2 for MGF-9 as 0.75. The Cora ACCESSION-NR: AP4037287 calculations were conducted under tha assumption that only one double bond was involved in the polymerization of MGF-9. This assumption was confirmed by the bromine number determinations. It was found that at a styrene content in the initial mixture up to 70 mol.X a continuous enrichment of the copolymer in HGF-9 takes place, and that at 63 mol.% of NGF-9 in the initial mixture the composition of the copolymer is the same as that of the mixture, The data on the initial rates of copolymerization showed that a small addition of MGF-9 had a markedly depressing effect on the polymerization of styrene. This indicates a preferential formation of complexes between TiGl4 and KGF-9,, with styrene taking practically no part in the initiation of the polymerization reaction. Up to 45 mol.% of MGF-9,, no unsatura- tion was noted in the copolymer. The degree of unsaturation increased from this point on up to the copolymers containing 70% MGF-9. above which it began to drop* The authors express thanks to A. Do Abkin for his discussion of the results and valuable remarks, and to A. A. Berlin for his interest in the work& Orig, art. has: 4 graphs* ASSOCIATION: Institut obshchey i noorganicheakoy khimii AN SSSR (Institute of General and Inorganic Chemistryp AN SSSR) Card. 2/3 z 'ACCESSION NRt ' AF4036725' 8/0020164/156/002/0379/0382 'AUT110R: Lipatove, T. E.; Budnikova, V. A.; Siderko, V. M. !TITLEt On the mechanism of carbonized polymerization of unsaturated polyesters SOURCE: XT SSSH. Dok3sAy*, v. 156, no. 2, 1964, 379-37M TOPIC TAGS: unsaturated polyester, carbonized polymerization, titanium chloride, polymer, ethyl chloride, catalyst, chemical property, styrene, copolymer, oligomer !ABSTRACT: The authors investigated the subject under the effect of a TiCl catalyst 4 land obtained polymers possessing valuable mechanical and chemical properties. This' ;resulted in an investigation of the carbonized copolymerization of dimethacrylate- 'bis-triethylene glycol-phthalate (MFG-9) with a styrene. Polymerization was effected lin a solution of carefully dried ethyl chloride at a total monomer concentration of !about 1.25 moles per liter and a catalyst concentration of about 0.003 and 0.015 ;moles per liter at OOC. Theoretical and experimental curves for both catalyst con-~ !centrations are presented in a figure showing the dependence of the copolymer com- ;position an the composition of the original mixture. It is concluded that in a ;Joint polymerization of an oligomer with a styrene In the presence of TiC141 the reactivity rate of the oligomer depends'not only on the structure of the double LCard, 1/2 I ACCESSION NR: AP4036725 bond but also on the whole molecule. This structure determines the composition and structure of the oligomer complex -- the catalyst, which, in turnp determines the reactivity of unsaturated polyesters and carbonized polymerization and, consequently, the basis of-all complex physico-mechanical properties of copolymers. Orig. art. has: I figure and 1 table. ASSOCIATION: Institut o~shchey i neorganicheskoy Idiimii. Akademii nauk BSSR (Institute of General and Inorganic Chemiatryo Academy.of Sciences, BSSR) SUBZUTM): lOJan64 DATE ACQ: 033un64' B14CL so 00 SUB CODE: NO REF SOV: 007 OTHER: OQ2 Card 2/2 ACCESSION NR; AP4040484 S/0190/64/006/006/1054/lOS9 AUTHOR; Lipatov,,Yu. S.; Tsy*bul'ko, A. Ya.; Lipato va, T. E. .TITLE: Polymerization of an unsaturated ester of novolac resin 'SOURCE: Vy*sokomolakulyarn;*ye soyedineniya, v. 6, no. 6. 1964, :1054-1059 :TOPIC TAGS: phenol formaldehyde resin, novolac resin, modified ~novolac resin :ABSTRACT: A modified, unsaturated novolac'resin which thermosets .without curing agents has been prepared at the Institute of General and Inorganic Chemistry, Academy of Sciences, BSSR.'Novolac resin .113-P-3 containing 13.362 O)l groups was modified by esterification twith methacryloyl chloride in pyridine to a degree of esterification ,of 52-56% as indicated by chemical analysis and IR spectroscopy. .The modified resin solution polymerizes at 60C in the presence of 'banzoyl peroxide by the free-radical mechanism to form a still-unsat- .urated polymer. The modified resin also polymerizes with styrene and Card 1/2 !ACCESSION NR: AP4040484 tacrylonitrile. Thermomechanical analysis and solubility tests showed .that the polymers and copolymers thermoset at 120-160C to a product with a three-dimensional network structure. The modified resin also .thermosets with the catalytic polymerization product of bis(triethylow ,glycol) phthalate methacrylate to a product with a three-dimensional ;network structure. OrLg. art. has: 1 figure, 2 tables, and 1 formula. :.ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN BSSR ,(Institute of General and Inorganic Chemistry, AN BSSR) :,SUBM1-.'.'-.. 05Jul63 DATE ACQ: 06Jul64 ENCL: 00 SUB CODE: MT, 00 NO REF SM 005 OTHER: 001 Cord A^ / 2 iACCESSION MRS AP4043792 S/0190164/006/006/133945391 1AUTHOR1 ~.iptt!vs._T. E!; Skory*nina, 11 so ]TITLES Crafting of tridimensional polymers onto Stage fiber jj'SOURCEt Vy*~okovo1ek%S1y&rny&ye liand insect facing p. 1409 soyedinentys, ve 6, no. 8, 1964. 1539 TOPIC TAGSt glass fiber, polymer glass grafting, epoxy resin, bLs- .(triethyXene glycol)phthalate dimethacrylate, titanium tetrachloride ABSTRACTS A study has shown that epoxy resin or the unsaturated oligomer bio(triethylene glycol)phtha *late dimethacrylate can be grafted;, onto TiC14-trested glass fiber. Grafting takes place on polymerizaticn. ;of ED-6 epoxy resin or HCY-9 bis(triethylene glycol) phthalate dimetha- 'scrylate in benezene solution in the presence of the * treated fiber. IThe grafted ED-6 or MGF-9 is not removed even after boiling in d1metW Iformamide and acitonep respectively# for 24 hro The amount of ED-~ I !grafted on varies from fractions of one percent t -o 5Z.of the weight of )the fiberl-and that of MCF-99 from I to 2%, Origs art, hask' I figured,--. 1ASSOCIATIONe. none ;ord A /2 -7 Card 7 / 2 -, ~ -- --- --- r. --- - - , - - --r, TUTAYEVA, N.L.; LIPATOVA, T.E.; LIPATOV, Yu.S. Grafting of polyam7late on viscose fiber. Dokl. AJI BESPI 8 no.2:108-110 F 164. (MIRA 17-.8) 1. Institut obshchey i neorganicheakoy khimii AN BSSR. Predstavleno akademikom MI BSSR M.M. Pavl uchenko. L 17821-65 1-~Wp(e)/EWT(m)/EPF(c)/EWP(v)/Ek/EWP(J)/T/EWP(b) Pc--4/Pq-h/Pr-h/ p s-4 w4ir W ACCESSION NR- AP4046081, S/0070164/0381009/2252/2254 AUTHOR: Lipatova, T. E.; Bakovshchik, M.~G. r TITLE: Investigation of t e la 's itanium tetrachloride styrene system by the electron paramagnetic resonance method SOURCE: Zhurn,al fizicheskiy khirnii, v-181 no. 9A 1964, -2,252- 2254 -,TOPIC TAGS: glass titaffiu M_ tetrachloride- styrene, titanium tetrachloride glass s'"stem, titanium tetrachloride st renesystem, glass TiC14 styrene s stem, y e16 ct ron. p;iramagnetic,'resonan ce spe ct rum. EPR-spectrum, paramagnetic center, -polystyren-e.,-glass,bonded polystyrene, fiPR: signal -intensification h-e-EP spectra of-hii- _t -1cl --styrenej and-the.glass ------- --- 4 ene sy terns -were studied,' '.The microporous glass, -prepared as _Ti.C14 --styrL 5 described by 1. V.,. Oreben,shch-ik ,ov and 0. 9, Molchanova (Zh, obshch, khimit, 12) 588, 1942).-was dried in vacuu ,m and the TiC14 -was condensed thereon under vacuum; in the ternary system- the styrene was condensed onto the glass-TiC14 Card 1/ 3 :,77 '~L 17821-65 ACCESSION, NR:. AP4046081 a,1.2 ratio of components wasused4n-the-TiCl -styrene system.- The-spectrum was.a 's inglet w th Alne width- of about 30 Oe and g-fac- of the TiC14 -glass system . i -tor of about 2; onIexposure to-air-for one- hour, the intensity- increased about 4 times. The spectrum of the ternary system was similar; its behavior on exposure to oxygen in shown * The TiCl4_ styrene system under vacuum showed no signal ,but on contact with oxygen asighal similar to-the others wCas produced; its inten-, increased by 100 times in a month then started to fall. Thus the presence of paramagnetic particles on a glass surface treated with TiCl 4 was established. The presence of two types of paramagnetic centers was indicated: paramagnetic center/on the glass surface, formed by.the portion of TiC14 actually bonded to the glassvalnd thepolystyrene graft .ed thereon; and paramagnetic centers in the poly- sty-rene polymer formed by the TiC14"which -was desorbed from the glass surface and dissolved in the mon.omer.~ The noted effect of oxygen on the intensity of the EPR signal was unique: the inten4ificatioh 'of the, signal was; contrary to all other .known examples where oxygen Ae6reas6d..sianal intensity. Orig. art. has: 2 figures. C d or o 26-6 ~1: 'tW(M)-/EPF(C)/PPR/,E'tiP(J),/T 4/P 4 RP1 VU/Ml Pa V/Pt ACCESSION r4R- -AF400,q896---- S10191164/006/001/0003/0007 - AUTIIOR.- Lipatwa,7--T-- E-- TITL-*E:-- :Cat"ic po 0 -ization of.-unsaturated-p lyethe'rs.--- Carbobium --jyrnet polyrnerlzation of -SOURCE: Plasticheskiye massy*, no. 1, 1964, 3-7 TOPIC- TAGS:~'-,- ionic -polynieriiati arboniurn volyme-orization- --polyether4cryi---- on, c ate polymer,, beta2polyrner,: unsaturated polyether polymer, lacquer coating, air-'drying lacquer. ABSTR#CT: T4e,carizonitkm-polymeri,zation-of-pol~ethe--racrylatesM_ and TMGF-1PV dthe roperties.of the resultant polymers were d -7PRI;7me'Zzationa~woere conducted in vacuum at 20C, ing Tn-vestigate, .7 us 0,4. mol/ 1. TiC14 Eatalyst; polymerization products were filtered and methanol washed. The three dimensional polymer remained on the filter; the beta- polymer can be precipitated _from the filtrate with methanol-water mixture. card 1/2