SCIENTIFIC ABSTRACT LIPATOV, YU. S. - LIPATOVA, T. E.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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,LIPATOV Yu 3
~~~jp
Dielectric relaxation in the surface layers of polymethfl meth-
acrylate and polystyrene. Vysokom. soed. 7 no.8:1430-1435 A
165. (MIRA 18:9~
1. Institut obshchGy i neorganicheskoy khimii AV BSSR.
2984-66- .-E7V?T(m)/M-(P)ZjWCJ)/7
OF
NRs AP50226i2
Ssjo~ UR/01-90/65/067/069/.1626/2632
66.095.26+67P.62
AUTHORSi Taybulikol
A. Ya.; atovas T. E.1 Lip "tov, Yu. S.
-;Us
TITLFt Gopolymerizati iaturated novola aster with a nel
SOURCE: Vyaokomo1eku3,yaruyye soyedinenive., V. 7j no. 9. 1965,, 1626-1632
TOPIC TAGS; polymers polystyrwes graft copolymers copolymerization., thermo-
mechanical propertyo eaters styrene., novolac, infrared spectroscopy
ABSTRACT: The detailed study of copolymerization of novolac ester with styrenes
the physical and chemical properties of the copolymers and the reaction mechanism
I and reactivity of reagents are described. The reaction is both theoretically and,
practically interesting since copolymerization with participation of oligomers is
unusual and also leads to products capable of solidification. Preparation of
modified navolao (novol'ac methacrylate) was described by the authors earlier
(Vysokomolek. soyed.j 6, io%s 196h). Copolymerization was conducted in a
dimethylformamide solutions in N2 atmosphere and in sealed glass wVules, by
heating the reagents for 30 hours at 70C and using asodiiaobutyronitrile as an
L
ACCESSION
NR: AP5022612
initiator. The ratio of reactants was varied, andits effect upon the composition
of the product was measured by turbidimetric titration and infrared spectroscopy.
It was found that graft copolymers of polystyrene with the oligomeric.moloculas
were Vormedj and the frequency of branching was a function of the reaction mixture
composition. The reactivities of the double bonds of styrene and modified novolac
during copolymerization were calculated using equations of A,'D. Abkin and S. S.
Medvedev (Zh. fiz. khimii, 21, 1269, 1947). It is assumed that the law reactivity
of methacrylic groups is due to steric factors which also affect the polymerization:1
proC8BB* Study of thermomechanical properties of the graft polymers has shown that
they can solidify upon heating. Small amounts of polystyrene grafted onto the
modified novolac have a large effect upon increasing the flow temperature. Origo-
art. hast 3 tables and 5 figures.
ASSOCIATIOM Institut obshchey i neorganicheskoy khimiij AN BSSR (Institute for
~-Ceneral and Inorganic Chemis!M. BSSR)
SUBMITTED: 26oct64 ENCM 00 SUB COM 00,0 G-C
NO RBF SM 006 OTHER: 002
Card 2
LIPATOV, Yu.S.; SEIRGEYEVA, L.M.
Some regularities of' the adsorption of macromolecules from
-solutions. Koll. zhur. 27 no.W17-223 Mr-Ap 165. (MIRA Ie,:6)
1. Institut obshchey i nearganicheskoy khl.zTdi AN BSSRq Minsk.
SERGEYEVA, L.M.; LIPATOV, Yu.8.
Adsorption of vapors in the awtem polymer - filler. Xnll.zhur.
27 no.33435-440 My-.Te 165. (KTRA 18'.32)
1. Inatitut obshche:v I neorganicheskay khimil AN BS-':!R, Minsk.
Submitted Dec. 2, 1963.
T.
ACC ART~6046245 SOURCE CODE.; OR/0000/65/000/000/0056/0063
AUTHOR: Lipatov, Yu., S. (Doctor of chemical sciences)
ORG: Institute of Chemistry_of High -Molecular Compounds AN UkrSSR, Kiev (Institut
_..~khimii vysokomolekulyamykh soyedinenly AN UkrSSR)
1~~TITIXt:' Sc=6:'vhvsi,~6mical aspects of the mechanism of r~einforcing_Rlastics by fil-
,-SOURCE.i. AN-_AfictS8R*:,Modifikatsiya svoystv polimerov i polimernykh materialov (Modifi-
cation,of the prOpe:*.ties of polymers and polymeric materials). Kiev', Naukova dumka,
145, 56 63
TOPIC. TAGS: solid mechanical property, plastic strength, polymer, filler, plasticity
-ABSTRACT: The mechanism of plastic-fillerl(interaction (which results in improved me-
chanical properties of filled plastics) is discussed on the basis of data in the lite-
rature and the authors' previously published studies. The reinforcing function of fil-,
lers on plastic.is'.'explained in tems of the special orientati9d of polymer chains at-
tached to. the filler surface the firmness of'polymer adhesio0to the filler surface,
band the chemical interaction between the polymer and the -fil r surface.
,8UB CODE: 07/ SUB14 DATE.- 06Oct65/ ORIG REF: 0211 OTH REF: 002
LIPATOVA, D.L.1 DZHINS-ISTI, G.Ys.
Standardization of projective transformations. Uch. S&P* Nook. use
no.181:235-240 156. (MIM 10:4)
(Transformations (Mathematics)) (lowkMphy (Mathematics))
LIPATOVA, D.L.
-:Z~
Limit of a converging sequence of measurable operators, Uchozapo
Fed.inat,Gerts. 218:343-345 161. (MIM 14 110)
(Sequences (Vkthematics)) (Operators (Mathematics))
LIPATOVAI F. A.
Lipatava, F. A. - "Nomographing the Equations of Three Variables by the
Method of Their Equalized Points with Identical Transformation of the Left-
Hand Side of the Equations into the 14asseau Determinant." Min Education RSFSR.
Moscow Oblast Pedagogical Inst. Moscow, 1956 (Dissertation for the Degree of
Candidate in Physicomathematical Sciences).
So: Knizhnaya Letopisl., No. 10, 1950, pp 116-127
88900
S/044/60/000/007/057/058
Xing C1111C222
AUTHORs
TITLEt The solution of the problem of K.Y&,Zalte
PERIODICALs Referativnyy zhurnal. Matematika, no-7, 1960, 228.
Abstract no-8325. Uch.zap.Kaliningradek.goo.ped.in-t,. 1958,
vyp-5, 129-143
TEXT: It is shown that for the representability of the left-hand side
of the equation
Ix
Fl(x)C,(ypz)+F 2(y)C2(x' z)+F3(Z)C 3(XIY) . 0
by a Masso-determinant, i.e. for
Fj(x) fj(x) gl(x)
F C +F C +F C F2(y) f2(y) 92(y)
1 1 2 2 3 3 F3(Z) f3(z) g3(z)l
it is necessary and sufficient that one of the three conditions of
compatibility is satisfied for the system
Card 1/3
The solution of the problem...
f29 3-f3g2 2 C1
f f -C
3gl- 1g3 = 29
f 1 g2-f291 0 C39
where the functions C 1* 0' C2* 0' C3 to'
following conditions is satisfied:
1) 2el 'A C2 C
-Tz- C2- 12 1
a 3 'W3(z);
2) C3 C lie1C
1- -U- 3
C2 V2(z);
Card 2/3
8R'A':
S/044/60/000/00 7110 (17.
C111/C222
I.e. one of the three
I ')
13
88900
B/044/60/000/007/057/058
The solution of the problem... C111/C222
3) 1 C2 0 IOC3
3- bx YJ(X).
C1
The solution of the problem is given under the assumption that Fi+ const
(i-1t2,3).A numerical example is given.
CAbstracter's notet The above text is a full translation of the original
Soviet abstract.1
V/1
Card 3/3
88899
.6n
S/04 6o/oOO/007/056/058
C1 11 YC222
AUTHOR: Lipatova, F.A.
TITLEs A new method for the nomogram-Ing of the polynomials
M(x,y,z) for which 213M(Xly,z)l .0
PERIODICALs Referativnyy zhurnal. Matematika, no-7, 1960, 227-228.
Abstract no-8324. Uch.zap.Kaliningradak.goa.ped.in-ta,
1958, vyp.5t 144-155
TEXTt The proposed method consists in the fact that the sum of the
first three terms of the right side of the identity.M(X,Y,Z) -
Ml(ylz)+M2(xlz)+M3 (x,y)+Fl (x)+F2(y)+F3(z)+S is represented as a Masso-
determinant and the conditions of this representation are reduced to the
conditions of compatibility for the system
f 9 -f -
2 3 3g2=Ml(y;z),
f 9 f - (1)
3 1- g3 =M2(x'z),
f1g2-f 291 --a x3(XPY).
Gard 1/2
88899
S/044J60/000/007/056/058
A new method for the nomograffivoing... C111/C222
Then the representation of the polynomial M(X,Y,Z) is considered by a
Masso-determinant. It is shown that this representation assumes the
following conditionst 1) Compatibility of systems (1), 2) compatibility
of the systems (1) and (2), where (2) has the form
ag 3-bf3 aF 3(z),
4f 2-og2l= P2(y)P (2)
ad-bo aS.
The investigation of the compatibility of the systems (1) and (2) is
carried out for several cases *
Ubstracter's notes The above text is a full translation of the original
Soviet abstriact.3
Card 2/2
1
LIPATOVA, G. .
...WW-OMMM"
The structure of starch thickenings. Zhur, prikl. khim. 29 no.12:
1881-1883 D 156. (MIJU 10:6)
1, Kafedra fizicheakoy khimii Moskovskogo tekstillnogo inatituta.
(Starch) (cellulose) (Adsorption)
PA To Me G- V
Host of Wall 4114 01111111two of low-mitlecul" ccem~
Zpa"481. I. Sm.41,110M.1 6. V. 11ij "o- Kolloid
he" I T~ .11 - UI (t
4 - Ile bc
'); cl
of "it of Na ofeute in 11,0 is -.'I ral,/C. M III' J1141 - 11 31
W). : this ChAnar it flor to tile gradual -tvIvIting" of fit,-
Iftlernitel. 1--ods at higher tritip. The Q in FtOll i,
I At MA -M, '141* and eoe*; let the Letter
fll!:#~`r (I is "'Ol't I_ m- dl tile Noed, aw, W.,kri,
1w,uh-to
Ile v .4 .14 11% -1 IV,, I... I.
I"4, mul #'.ps-fly al 1.11th.-I I"1111, lle.", -1. N
is 'I Chh.f.millic It'diove ill I, Net, Z 1, 1 1 - .
At Ill", 31 ~W. .1 114411111 A ", 7 ". IN I
A mme, isteel.4 k*hry.qJ,.ouw (111,11 ILI of 16. It :.)
And 2.14 At 5*, 10% *It *, And Nft'~ 'Fite tIm-feth,,el Ima 4
,tan. (,), Was cAlm. (mm (dlnK;'d1') -
1.1 If, Q Of I W-A* eflUal 10 Q' ilt LW; for 11,
20 , wheruti Q'mt higher temp. was 2-3 filters as grr;.t A, (I
Ile (), fit lit w;1% greater film) (I at 4411 truells. At 25*, Q
Was 3370. 1 IMI. And 43P) c.d. 'nude (let 1. 11, Reed Ill, r-v
'rhe Q, L% t,k) CICA, ~4- jk:dr I% -tim.-tin.mv rt.-m ..(
higher Ittop. A% it rr,111t .,( the roll.ou"I fle,tilmlily .4 it,,
-lye views. J. J. Illkerm.",
Ll P AT Oll , S . M. [ Up it ta u, ; . M. I [ d o c , - U; I od 1 - I I.;, ~: i ~ a ~~ ~v, , i - ~,-- .
Diaschasnava, I.K.1i, rl~ TOVA G V. ',
1~)AjVA~~ , L
Phnse demixing in the system polyrr-r - poly,,,?~r -
Vestsi AN DSSR. Ser. flz.-tekh. nav. no.4356-60 162. (MIRA 18t4)
MI-IMUVI R.I.; bTUVil.'CHEYEVj F.A.; J!~~, J.p.
Deterialnution of the individual hydrocarbon com-paition of Tttar
petroleww. Report Ilo. 4: Ligroine obtainod i'rom zlomashYdno
Deposit cru.6cs. Izv. All SM. Otd. khim. r-auk no. 1:109-114
ja 161. (2-ar-A 14:2)
.1. Kliimichaskiy inatitut im, A.Te. Arbuz(ria Kuzanskogo filiela
-AN SSSR.
LES B.; IZMAYLOV, R.I.; URMANCHEYEV, F.A.- LIPATOVA I.P., KHASHAYET,
S.-Kh.G.; LAMANOVA, I.A.; BUKF",LYF.V I R.G.
Individual hydrocarbon composition of the petroleums of Tataria.
Report No-5: Ligroine from the petroleum of the Bavly Oil-Field.
Izv. AN SSSR. Otd.khim.nauk no.7:1310-1315 J1'161. (141RA 14:7)
1. Khimicheskiy institut im. A.Ye. Arbuzova Kazanskogo filiala
AN SSSR.
- (Bavly region--Petroleum) (Ligroine)
LE, B.; URMARCHEYEV, F.A.; LIPATOVA, I.P.; BUKHARAYEVA, R.G.; LAMANOVA, I.A.
Determination of the individual hydrocarbon conposition of oils
of the Tatar A.S.S.R.. Report No.6: Ligroin cbtained from
petroleum of the Shugurovo oil field. :-zv.AN SSSR.Otd.khim.
nauk no.10:1858-1863 0 161. (MIRA 14:10)
1. Kazanskiy institut organicheskoy khimii AN SSSR.
(Shugurovo--Petroleum--Analysis) (Ligroin)
URMANCHEYVI, F.A;; LE, B.; BUFARAYEVA, R.G.; LAMA10VA, I.A.;-LIPATOVA, I.P.
Determination of the individual hydrocarbon compositiin af gas-
olines in oils of the Tatar A.S.S.R. Report Ho.7: Gasoline from
Shugurovo oil fields. Izv.AN SSSR.Otd.khim.nauk no.11:2063-2065
N 61. (MIRA 14:11)
1. Institut organicheskoy khimii AN SSSR, Kazan'.
(Shu,yuravo--Gasoline)
LE, B.; KASHAYEV, S.-Kh.G.; PNYATOV, M.Z.; LIPATOVA, 1.P.; LAMANOVA, I.A.
4Raman spectra of normal paraffinic hydrocarbons Cll - C17 and their
spin-lattice relaxation time. Khim.i tekh.topl.i masel 8 no.112
22-24 N 163. (KRA 16t12)
1. Kazamlkly institut organicheskoy khimii AN SSSR i Kazanskiy
gosudarstvennyy podagogicheskiy Institut.
LIFATOVA, I.P.
Vanadyl cb1cride z:olntioriB in organic zolvunf-, the !%e4I.,3ds
of infrared adsarptlon arid -~~Iectron parafu,~~r,nl.lr: !"+,-,~.'tra.
Dokl. AN SSSR 164 no.4:849-851 0 165-
(MIRA 18:10)
lo Institut organicheskoy 'Ahimil AN 74~7wi. Su--i!Lted March
22., 1965.
L-169,33-65 EW(m)/ZPF(c)/T._ Pr4 WE
2_/
7 Aar"ES$ION NA r A~W2 611/000 b66/1484/1h86.
AM101b"-, Bq Urnmicheyew, F. AO; Watowl, j3!*hoirayvvP,, R. G,;
TITLE i Determinntion of imlividual hydrooprbon composition of petroleum of Taterias
Report 8, Lifw6in 'of Rom,-.shkinqk1y deposit (Al I m at I yevnk "YD Irea petroleum)
SOURCE: AN 586P. Izvestiy,-. S-riyn khimicheskaya,, Po. 0p 196h., 1484-1488
TOPIC WGS: crude, petroleu:n, hydrocprbon
rV Abstract: The individual and group composition~of Ligroin (150-2000) of
V.:Petrolet;m.from-the Romachinskiy Deposit, Allmet'yevskaya Area, was investiga-,
ted. 46 aromatic and hydroaromatic hydrocarbons were found. The 146-2050
fractLon Cn2B.= 1-.4362- d20 = 0.7778, sulfur content 04108%) was separated
.1 4
by0silica gel adsorption into a naphthene-praraffin protion NPCh-1 (83.8%;
n 1.4246; d2R - 0.7627) and aromatic hydrocarbons A, (14.8%;,
n2B 1,4980,w 20 = 0.8747). A catalysate was obtained from NPGh-l (yield
88?7%; n~ = 1.4~30; d20 - O.M7), comprised of 86% naphthane-paraffin
portion NPCh_2 and 11 . 71 aromatic hydrocarbons A2 (8.7% of ligroin and 9,1%'
in recalculation to converted six-member cyclanes). It was found that the
Card 1/2
SHEYNKER, Yu.N.; POSTOVSKIY, I.Ya,; BEDNYAGIIJk, N.F.; SRMNINA, L.B.;
LIPATOVA, L.F. .-
Equilibrium between the tetrazole and azide forms in benzothiazole-
tetrazole. Dokl. AN SSSR 141 no.6:1388-1390 D 161. (14MA 14:12)
1. Urallskiy politekhnicheskiy
khimii prirodnykh soyedineniy
M.I.Kabachnikom.
(Benzotbiazole)
institut. im. S.M.Kirova i Institut
AN SSSR. Predstavleno akademikom
(Tetrazole) (Azides)
LIPATOVAV L.F.; POSTOVSKIY, I.Ya.
Certain amides of sarcolyBine. Zbur.ob.khim, 32 no.4:1062-1064
Ap 162. (MIRA 15:4)
1. Urallskiy politekhnicheakiy institut imeni S.M.Kirova.
(Sarcolysine)
POSTOVSKIY, I,
LIPATOVA, L.F.
De4yAtivea of acenaphthene containing a bi a chloroethyl)-amino
9r"p, Zhur.ob.khim. 32 no.4:1067-1068 APT7,62. (MIRA 15:4)
1. Urallskiy politekhnichaskiy institut imeni S.M.Klrova.
(Acenaphthene)
TYURENKOVAP G.N.;_LIPATOVA L.F.; POSTOVSKIY, I.Ya.
Collector action of certain-substituted 2-nercap benzimidazoles.
TSvet.met. 36 no.2t77-90 F 163. 1 (KMA 16s2)
(Flotation-Equipment and "pplies)
#, (Hercapto compounds)
L117ATOVA, L.S., asPL--ant
Rolp of ra"llonal !,,Li,rtf,Lrn -,f childrem of' :ichc,,;l ag.!~ llr
prevention of derital cnr'ns. Trudy TSIIJ 64:;11-j'-, f~~ -
L
(141RA 17:51,
1p VA.) IV
-&.Meow
~N%
aA
co
6i;i-~_=
Fw tim r tbt to-,.
ljo x t0-4. tow.
!pl.j74GX 10
so 21-
lp ILVI.
jkboll
d WE 9
LIPATOVA, L.V. (Leningrad)
Streptococcal anginas, analogues of scarlet fever. Vest.otorin-
22 no.2:19:22 Kr-Ap 160. (KIRA 13:12)
1. Iz kafedry infektisionafth zaboleveniy u detey (ispolnyayushchiy
obyazannosti zav. - dotsent A.T.Kuzimichevs) Leningradskogo
pediatrichookogo meditsinskogo instituta i detskoy infektaionnoy
bollnitay Sverdlovskogo rayons.
(WR3PTOCOCCAL INFECTIONS in inf. & child)
(TONSILLITIS pathol.)
(SCARLET PEW pathol.)
-LIPATOVA, L.M.
Catapmestic observations on children who have had streptococcus
angiha. Vop. okh. mat. i det. 6 no.11:49-52 N 161. V'URA 14-12)
1. Iz kafedry infektsionnykh zabolevaniy u detey (zav. - dotsent
A.T.Kuzlmicheva) Leningradskogo pediatricheskogo instituta. (dir. -
kand, med.nauk Ye.P. Semenova) i Detskoy infektsionnoy bollnitsy
Sverdlovskogo rayona. Leningrada (glavnyy vrach - zasluzhennyy vrach
RSFSR N.A. flikitina).
(STW,' TOCOCCAL DIFECTIONS) (TONSILS-DISF-ASES)
USSR/Farm Animals. Rabbits. Q-3
Abs Jour.- Ref Zhur - Biol., No. 22, 19582 101225
Author Kim, M.M., Lipatova, N.A.
Inst Scientific Research Institute of Rabbit and
Fur Animal Fusbandry
Title Norms for FeedinR Rabbits with Vitamin A.
Orig Pub: Byul. nauchno-tekhn. inform. No.-i. in-ta kroli-
kovodstva i pushn. zverovodstval 1958, No. 2,13-14
Abstract: One hundred ard forty young rabbits (11-2 months)
were employed in experiments carried out by the
Scientific Research Institute of Rabbit and Fur
Animal Husbandry. The rabbits were divided into
7 groups (20 animals in each -roup). During the
entire experimental period, each animal in a
,group received the following average amounts of
Card 1/2
62
USSR/Farm Animals. Rabbits. Q-3
Abs Jour: Ref Zhut " Bibl,j Yo. 22, 1958$ 101225
vitamin A (in m units) daily: Id the Ist group,
655; in the 2nd group, 3,068; in the 3rd group,
1,577; in the I+th group, 5,304; in the 5th group',
7,395; in the 6th group, 7,120; and in the 7th
group, 22,476. According to these various
groupings7 live weights of baby rabbits at 2-4
months of age did not very greatly; at 4-4.5
monthst respective weights (in g) amounted to:
27360; 2~295; 27380; 21095; 21170; 2,133; and
27435-
Card 2/2
UPATOVA Xi= Tvannvna: STEPANOVA, 011ga Mikhaylovna; KHARAS,
K.-K'-"fiau6hri. red.; ISH, N.N., red.; TOKER, A.M.,
tekhn. red.
(Industrial training of cooks] Proizvodstvennoe obuchenie
povarov; metodicheskoe posobie.- Moskva, Proftekhizdat,
1963. 187 P. (MIRA 16:9)
1. Zamestitell direktora po uchabnoy rabote profeasionallno-
takhnicheakogo uchilishcha No.10 Leningrada (for Lipatova).
2. Starahiy master proizvodstvennogo obucheniya professio-
nallno-tekhnicheskogo uchilishcha~-No.10 Leningrada (for
Stepanova).
(Cooking schools)
8/070/61/006/011/007/013
B101/B147
AUTHORS: Morozov, I. S., Toptygina, G. M., Lipatova, N. P.
TITLE: Investigation of compounds formed by titanium trichloride with
chlorides of alkali metals and ammonium chloride
PERIODICAL: Zhurnal neorganicheskoy khimii, v. 6, no. 11,1961, 2526-2535
TEXT- A special problem of producing titanium metal from chloride melts
by electrolysis is studied. Conditions under which compounds of TiCl 3
with MeCl (Me =Cs, Rb, K, Na, NH 4) form, the composition of these
compounds, and their solubility in HC1 are examined. These compounds
which formed in aqueous solution were compared with those forming in salt
melts. In the systems TiCl 3 -MeCl -H20 saturated with TiCl 3 and MeCl at
OOC, no interaction could be determined visually. When saturating the
solutions with dC1 gas, light-green precipitations deposited which were
analytically identified as pentachloro-aquotitanates (Ce 2 TiCl5H20,
Rb2TiCl 5H20, (NH 4)2 TiCl5H20, K2TiCl5 H20). They have a high hygroscopicity
Card 1/3
S/078/61/006/011/007/013
Investigation of compounds formed by... B101/B147
and are attacked by 0 2' The potassium compound immediately decomposes in
the air while the sodium compound does not form. Birefringence is
characteristic of the Cs-, Rb-, and NH 4 compounds:
Compound N I N2
Cs2TiCl5H20 1.678 10.002 1.645 10.002
Rb2TiCl5H20 1.682 10.001 1.638 +0-003
(NH4)2 TiCl5H20 1.694 10.002 1.664 +0.002
Solubility of pentachloro-aquotitanates (% of TiCl3) for ^J44 % HC1 is
0.35 for the Cs compound, 0.26 for the Rb compound, 0.67 for the ammonium
compound, and 1.50 for the X compound, With decreasing 1fCl concentration,
solubility of pentachloro-aquotitanates increases with simultaneous
decomposition. In the solid phase, alkali chlorides and (for the Cs
compound) TiCl 3' 6H20 occur besides the complex compound. In dilute HC1,
only the mixtures of alkali- and titanium chlorides precipitate. Thermo-
Card 2/3
V/
S/078/61/006/011/007/013
Investigation of compounds formed by... B101/B147
graphic and X-ray analyses proved that H 20 of pentachloro-aquotitanates
is inside the coordination sphere of the complex. On heating, water in
separated, Temperatureas 2700C for the Cs compound; 2120C for the Rb
COMDound; 1160C for the Nff4 compound, and 1120C for the K compound. In
hydrochloric solution, titanium has the coordination number 6. The
compounds found in anhydrous systems by other researchers do not form
under the conditions described. A paper by M. V. Kamenetakiy (Tsvetnyye
metally, j, 39 (1958)) is mentioned. There are 4 figures, 6 tables, and
14 references: 10 Soviet and 4 non-Soviet. The reference to the English-
language publication reads as follows: P. V. Schossberger. Ind. Eng.
Chem., 51 (5), 157 (1959).
SUBMITTED: December 22, 1960
Card 3/3
S/078/61/006/011/008/013
B101/B147
AUTHORS- Morozov, 1. S., Toptygina, G. M., Lipatova,11. P.
TITLE: Thermographic and X-ray analyses of compounds formed from
titanium trichloride with chlorides of alkali metals and
ammonium chloride
PERIODICAL: Zhurnal neorganicheskoy khimii, v.6, no. 11, 1961, 2536-2544
TEXT: In a previous paper (Zh. neorg. khimii, 6, 2528 (1961)), the
authors synthesized the pentachloro aquotitanatis of Cs, Rb, NH 49 and K.
In the present paper, they report on 1) the synthesis of pentachloro
titanates of Ca, Rb, NH 4' and K; 2) the powder patterns of pentachloro
aquotitanates and pentachloro titanates, and 3) the thermal analysis of
these compounds with Kurnakovlu pyrometer. Results; 1) The temperatures
at which aquo compounds separate 11 0 are: 270`C for Cs TiCl H 0,
2 2 5 2
2120C for Rb 2TiCl 5H2o, 1160c for (N11 4)2 TiCl 5H20, and 1120C for
K2 TiC15H2 0. The compounds Cs 2TiCl 51 Rb2 TiCl 5' (NH4)2 Ti C15' and K2 Ti C15
Card A -3
3/078/61/006/011/008/013
Thermographic and X-ray analyses of ... B101/B147
were obtained by 6-8 hr heating in HCI stream under slow temperature
elevation from 250 to 3500C with the Cs compound, from 200 to 3000C with
the Rb compound, and from 100 to 1500C with the NE 4 and K compounds.
The light-green color of the initial compounds changed: into olive-green
with Cs and Rb compounds, and gray with the K compound. The NH 4 compound
remained light-green. 2) The powder patterns of these compounds are
shown in Fig. 1~ They differ from those of pentachloro aquotitanates,
which are also given. Lines of components do not occur in either of the
two powder patterns., The X-ray data of K 2TiCl 5 differ from those of
F. Ehrlich et al, (Z. anorg. Chem. 299, 213 (1959)) obtained by another
method of synthesis. X-ray analysis reveals that the crystal structure
is changed by removing H 20 from inside the coordination sphere of the
complex whereas the skeleton formed by heavy atoms remains almost
unchanged. Ti has the coordination number 6. 3) Due to the low stability
of the compounds, the thermographic analysis was conducted in an inert
gas stream. It showed: (a) that all aquotitanates separated water at the
given temperature. At a further temperature elevation, interaction
Card 2/0 '?,
3/078/61/006/011/008/013
Thermographic and X-ray analyses of... B101/B147
between free 1120 and Ti compounds caused side reactions by Ahich
deciphering of the thermographs was rendered difficult. (b) Pentachloro
titanates have two phases, one of which, TiClY is disproportionated into
TiCl2 and TiCl 4' Nil4of the Nil4 compound is decomposed, and titanium
nitride forms. A paper by M. V. Kamenetskiy (Tsvetnyye metally,.?., 39
(1958)) is mentioned. V. G. Ku-znetsov is thanked for advice, and
Z. V. Popova for assisting with the X-ray analysis. There are 2 figures,
3 tables, and 25 references: 12 Soviet and 13 non-Soviet. The three
most recent references to English-language publications read as follows:
K. Komareck, P. Herasymenko. J. Electrochem. Soc.,)105, 216 (1958);
F. V. Schossberger. Ind. Eng. Chem., 51, 157 (195 ; H. P. Klug,
E. Kummer, A. Leroy. J. Amer. Chem. Soc., 70, 3064 (1948)-
ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. N. S. Xurnakova
Akademii nauk SSSR (Institute of General and Inorganic
Chemistry imeni N. S. Kurnakov of the Academy of Sciences
USSR)
SUBMITTED- February 24, 1961
Card 314 ~"'
MOROZOV, I.S.; LIPATOVA, N-P-* SIMNICH, A.T.
Therml ~d tensimetric studies of the system NbCl 5 - ZrCl - XCL*
Zhur.noorg.khim. 8 no.l.-172-176 Ja 163. (MIRA .15)
1. Institut obahchey i neorganicheakoy kbimii imeni
N.S.Kurnakova AN SSSR.
(Chlorides) (Thermal~',&nalysis) (Vapor pressure)
LIPATOVAS HoPol MMOZ-Np I.S*
ConpoWs of niobdLum azychlorlds vith AIkaIJ wtal ablorldes
and awmium chloride, Zhur, neorg, khlu* 10 noo2t429-436
IP #65* (MIRA issia)
1. submitted oat. 15, 1963.
LIPATOVAI N.P.- ~IOROZOV) I.Se
Z _-
X-ray diffraction examination of pentachlorooxyniobates
of alkali metals and ammonium. Zhur.neorg.khim. 10 no.12:
2817-2819 D 165. (MIRA 19:1)
ALUMM, N.A.;- AISKKA IT, A.A.; ZOTOV, A.I.; LIPATOVA, N.Ya.
Certain characteristics of the formation of complex conditioned
motor reactions in am. Zh. vys. nerv. delat. 5 no.6:773-782 N-D
'55. (HIMA 9:3)
1. Leningradskly nauchno-issledovatel'skly Institut fizichaskoy
kulltury.
(MWIAX, CONDITIOM,
conditioned motor complex reactions in man, mechanism
of form)
KAYOROV, F.P.; PAVLOV, B.V.; LIPATOVA, N.Ya.
Changes in the higher nervous activity of dogs under the affect of
X-Irradiation of the cervical section of the vegetative nervous
system. Trudy lust-fitiol. 5:79-102 056. (MURA 10: 1)
1. Laboratortya fiziologii I patologil vysshey nervnoy deyatell-
nosti. Zavacluyushably - F.P.Kayorov.
(I RAYS --PH" IOLDGI CAL IFFECT) (MVOUS SYSTIM)
LIPATOVA, Kja.; KAYOROV, F.P.; PAVLOV, B.V.
,~-
Iffect of total body irradiation on the higher nervous nctivity in
dogR. Trudy Inst. fiziol. 6:310-321 '57. (MIRA -,11:4)
1. Laboratoriya fisiologii i patologii vysshey nervnoy deyntellnosti
(saveduyushchiy F.P. Mayorov)
(NMVOUS SYSTEM) (X RAYS--PHYSIOLOGICAL FIFFECT)
LIPATOVA, N,Ta.-, MAYOROT, F.F.
9tudying the effect of total-body X irradiation on the higher
nervous activity in dogs. Trudy Inst.fiziol. WO-76 159.
(MIRA l3:5)
1. Laboratorlya fisiologil i patologil vymehey nervuoy dayatel-
nostl (saveduyushchly - F*F. Mayorow) Instituta fiziologii im.
I.Pe Favlovs, AN SSSL
'(x PAys-PHYsiowmAL myrim) (commom uspoNss)
L 54032-65 /E74P(h) Ps-4 IJP(c) JL
ACCESSION NR; AP5013521 UR/0076/65/039/005/1108/1111
541.8
AUTHOR- Beloy, V. T.; Va&!RAj~_I. ~LLLipatova. H. Ye.
ITITLE: Hydr -ation of anodic oxide film 0 ~lumin in aqueous solutions of in-
!organic salts -4
_7 --[SOURCE! himii, v. 39, no. 5, 196S, 1108-1111
~ITOPIC TAGS: aluminum oxide, hydration, anodic oxide film
-formed by
1 ABSTIMM Volume of hydrogen in eracting water vapor and calcium
'hydr-ide, wan. measured to- d_etermine- the water-. content -of anodic oxide f ilmr, filled
7'. -4 to
!with water at _95IC-in sodium dichromate, sulfate, and phosphate solutions (10
:1 mol/0. In the order of their effect an hydration of the oxide film, the anions
i - -
;are: H 2-
When the films are filled-in phosphate solutions, the,
2PO4 5 HU04 > S04 Er
quantitj.6f the sorbed.phosphate ion increases with the concentratior of tile latterr'
in the solution, and the water content decreases. In dichromate solutions, the
water content of the filled film depends only slightly on the solution concentret-
card 1/2
L -~"32-65-
!ACCESSION NR*- AP50135-21,
tion, but the water.content increases with risin concentration. In sulfate solu-
9
tions, the water content of the film increases with the concentration of the solu-
tion, aad the sorption of the sulfate ion either promotes or.does not interfere
with the adsorption of water. Differences in filling conditions have a pronounced
i
effect on the state of the surface of the anodic film; the sorption of anions and
!the hydration of the film are variously affected. Orig. art. has: 1 figure .
ASSOCIATION: Kazanskiy avi.atsionnyy institut (Kazan Aviation Institute)
SUBMITTEM 12Dec63 ENCT': 00 SUB CODE: GC
INO REF SOV: 012 OTHER: 006
i.Card, -2
LIPATOVA, O.A.
- -
Some results of observations made at Irkutsk to determine the
total ozone content of the atmosphere. Trudy GGO no.141:80-82
163. (KRA 17:4)
LIPATOVA, P.K.0 dotsent
Glinical aspects and treatment of rheumatic polyarthritis with
Penicillin. Vrach.delo no.6:651-653 Je 157. (MLRA 10:8)
1. Kafedra fakulltetskoy terapii LIvovskogo meditsinskogo institua
(nauchnyy rukovoditell - prof. T.T.Glukhenikiy)
(PSNICILLIN) (JOINTS--DISEASICS) (RHWUMATIC FXVXR)
LIPATOVA, P.K., dots.
Featuren of the mechanism of decompensation and compensation in respira-
tory and ourdiac insufficiency. Vrach.delo no-8:785-789 A 158
A~ 11:8)
1. Kafedra fakulltetakoy ternpii, Ltvovskogo meditainskogo inatituta,
(PULMONARY ZMPHYSEKA)
(BLOOD VOLUME)
(HDM FAILURE)
LIPATOVA, P.I., doteent
Compensatory factors In pulmonary emphysema. Vrach. delo no.4:
427-430 AP '59. (KIU 12:7)
1. Kafedra fakulltetBkoy terapil Livovskogo meditainakogo instituta.
(UPffSXKA, PUIXONART)
LIPATOTA, F.K., doteent
Actlylty of some rospIratory ferments of the blood to cardiovasculAr
and cardiopulmonary insufficiency. Trach.delo no.9s947-951 3 159.
(MIRA 13:2)
1. 111alla fakulltetakoy terapli Llvovskogo meditsinakogo instituta.
(UZTKIS) (CARDIOVASCULAR STSTION-DISRASIS) (LUNGS-DISTASIS)
I.~FATGVA, P. K.
Influence on stomach function of some physical methods of treatment
(diathermy, novocaine electrophoresis, and paraffin applications.
Vop. kur., fizioter. i lech. fiz. kal't. 26 no.1:27-31 161.
(MIRA 14: 5)
1. Iz kafedry fakulitetsko terapii Llvavskogo meditsinskogo instituta
(dir.
- prof. L.N.Kuz
(PTOMACH-DISEASES) (DIATHERMY) (NOVOCAINE)
(ELE-CTROPHO=IS) (PARAFFINS-THEWEUTIC USE)
LIPATOVA, P.K.. doUent
Q = tity of the circulating blood in pulmonary and cardiac
insufricienvy. Nauchotrudy Llvov.obl.terap.ob-va no~13189-193
161., (MIU 1615)
1. Kafedra fakulltatskoy terapii lachabnogo fakulsteta LO-7ovskogo
meditsinskogo institata (zav. kafedroy - prof. S.F. Oleynik).
(WWS124A3, PUMONARY) (FMCKARY MMT DISUSE)
(BLDOD, VOWME)
-LIPATOVA-j PA-9 dotsent
Activity of-catalase in cardiovascular and palmo-cardiae in-
sufficiency. lauch.trudy L'vov.obl.terap.ob-va no.11207-211 161,
(HIRA 1615)
1. Kafedra fakulltetskoy terapil lechelmogo fakullteta LOvovokogo
meditsinskogo instituta Nav. kafedroy - prof. S.F. alaynik).
(CATALASE) (RMYSR4Aj PUIMONARY)
(PUIMONARY lMqRT DISUSE)
I
LIPATOVAV P.Kop dotsent; IMTIYEVA, L.K.v vrach
Artificial nitrogen bathe in the treatment of bypertersim. Nauch.
trudy LIvov.obl.terup.ob-va. no.1:280-283 161. (MIRA 160
1. LlvovBkayq oblastnaya ballneologicheeka7u bolinitsa (glavnY7
vraoh - Ye.4 Solyakina) i kafedra fakalltetakay jerapli lechabno-
go fakulltata Vvovskogo meditzinskogo inatituta ~sav, kafedroy -
profe SOPS Olsynik)
(ROMMSION) ?,VITRO=-THERAMTIC USH) (BATHSX MEDICATED)
LIPATOVA, T. Z.
USSR/ Chemistry-- Petroleum Technology Synthetic Elastomers 21 Jan 51
"Polymerization of Isobutene to High-Molecular Products,8 Acad A. F. Topchlyev, Ya M.
Paushkin, T. Z. Lipatova
"Dak Ak Nauk SSSRO Vol LXXVI, 10 3, pp, 415-418
Isobutene can be polymerized to dilsobutene which is later hydrogenated to isooctane. It
can also be polymerized by means of chain reaction to products having high mol wt. In
chain reaction. activity of catalysts with reference to dog of polymerization achieved
is as follows: BY 3>C6H5 OCH3. BY :711 O.BT rff 3PO4. BY --,-(C 2H5) O.B1?
Activity of catalysts is different with ref to the stepwise reaction resulting in low
polymers: POIL-BF-1 ~- H90. By3>1 H2S04 By > B# >- (Rl) BY Solvent in which
3 3 + 3*
pol- -C'arrted obLt has effect on deg of polymerization. Copolymerization of
isobutene with n-butene or propene, w,s also investigated.
178T12
LIPPTOVA, T. E.
USSR/Chemistry - Elastomers, Polymerization
21 Oct 52
"INitintion Mechanism in the Catalytic Polymerization of- '.nsaturated
Compounds," A. P. Gantmakher, S. S. T-edvedev, Corr Yem, Acqd Sci USSR,
T. E. Lipatova
"Dod Ak Fauk SSSR" Vol 66, No 6, pp 1109-1111
A conclusion drawn by P. H. Plesch, IL'. Polanyi, H. P. Skinner, A. S.
Evans, and G. W. Meadows is found to be incorrect. Those authors cl9im
that in the catalytic polymerization of isobutene in the liquid state
or in hexane solus with TiC14 and BF3 catalysts at low temps, the addn
of H20, CCl COOH etc., is necessary in order that the reection may
proceed. T9is i's disputed in the present work: It is shown that by
raising either the temp or the dielec const of the solvent, catalytic
polymerization of unsatd. compds can be made to proceed in the presence
of aprotonic acids (SnC14, AIC13, TiC14, and others) without the addn
of H20, CC13COOH or other substances acting on the catnlyst under for-
mation of protonic acids. PA 234T25
; ; [ - - ~- '-- ; - 1 -- a
Dissertation: "Investipation of Carbon Copolyincrization of Unsaturated Compounds."
Caryl Chem Sci, Order of Labor i'efj Fanner Sci Iles Physicochemical Inot imeni L. Ya. Farpov
17 MaY 54. Vecharroraya Moskva, Moscow, 7 May 54.
SO: SUA, 284, 26 Nov 1954
VSSR1Gh(,1PiVt1'Y CatalYtic polyrrimrizotion,
Pub. 22 22/49
Authors I Lipatova T. E.; Gantmukher, ;t. 11.; and Medvedev, S. S. Mcirb. Cori-esp.
ussm
Title j Catalytic copolymerization of unsaturated compounds
Periodical, 'I Uok. All SSSR 10015. 925-928, Feb 11. 1955
j The kinetics of ceta)ytic copolymerization of isoprene-styrene.
SnGl4 catalysts w s
isoprene-alphs-methylatyrene systems over a
investigateq to determine the copolymerization constants for the!~e
systems. The dependence of the copolymerization rate upon the
composition of the basic mixture and the molecular weights of the
homologous copolymers were determined. The ion mechanism.of
catalytic polymerization In the presence of an SnCl4 catalys' is
exPlainea. Bight references- 6 USA and 2 USM (1944-195.5). Table;
graphs.
institution .......
SubmitW S' ;U1Y,3, 1954
AUTHORS: Lipatova, T. E., Cantmakher, A. R., SC)-1/76-'J!2-9-"3/-,'6
M-edVn 'ev, -- S .- -S .
TITLE: The Catalytic Copolymerization of Unsaturated Compounds
(Sovmestnaya kataliticheskaya polimerizatsiya nenasyshchennykh
soyedineniy) II. The Copolymerization of Isoprene and a-
Methyl Styrene (II. Sovmestnaya polimerizatsiya izoprena s
a-metilotirolom)
PERIODICAL: Zhurnal fizicheskoy khimii, 1958, Vol 32, Nr 9,
pp 2o29 - 2034 (USSR)
ABSTRACT: These compounds were polymerized in an ethyl chloride
solution at OOC using tin (IV) chloride as a catalyst. The
composition of the copolymers formed was determined from
the volume decrease during the polymerization and by means
of infra-red spectroscopy. The spectra are reproduced in
figures 1,2, and 5. The molecular weights were determined
by the osmotic method (Table 2). Diagrams show the course
of the polymerization of a-methyl styrene alone (Fig 5) and
of the copolymerization of isoprene and a-methyl styrene.
The work shows that three components, isoprene, a-methyl
Card 1/2 styrene, and a product of copolymerization with inner
The Catalytic Copolymerizatillon of Unsaturated Comip~junds. S'ay/76-'2-9-13/46
II. The Copolymerization of Izoprene and a-Methyl Styrene
double bonds take part in the polymerization reactions.
Steric factors are important in the reaction between
tile tertiary carbonium ion and monomers. a-methyl styrene
is considerably more reactive than isoprene. The initial
reaction rate in the polymerization of the a-methyl
styrene is decreased by the introduction of isoprene
into the system. Thin is explained by the fact that various
complex monomer-catalysts are formed. This formation reduces
the concentration of the complex formed by the tin (IV)
chloride with a-methyl styrene, which is the more active
of the two monomers in initiating carbonium polymerization.
There are 7 figures, 2 tables, and 2 references, 2 of which
are Soviet.
ASSOCIATION! Fiziko-khimicheskiy institut im.L.Ya.Karpova Moskva (Moscow
'7
Physical-Chemical Institute imeni L.Ya.Yarpov)
SUBMITTED: April 4, 1957
Card 2/2
170)
AUTHORS: Fmanuoll, 11. M., Corresponding Member, SOV/20-124-5-56/62
AS. USSR, Lipchina, L. P., Pelevina, 1. 1., Lipatova, T.. E.
---------------
TITLE: The Selective Inhibition of tho Activity of Redul'tion.-Ox-4fdation
Enzymes in Tumoral Cells When Acted Upon With Inhibitors of
Chain Reactions (Izbiratel'noye podavieniye aktivnosti
okiBlite.'Jl.lno-vosstanov:Ltel?nykh fermentov v opukholevykh
kletkakh pri vozdeystvii ingibitorov tsepnykh reaktsiy)
PERIODICAL: Doklady Akademii nauk SSSR, 19599 Vol -124, Nr 5, i)P 1157-1159
(USSR)
ABSTRACT: Since many years the idea of a selective inhibition of
fermentative processes J.n tumoral cells, as a rational
principle in can:',er chemotherapy, focuses the interest of the
scientists (Ref 1). The first two authors (Ref 2) proved an
inhibition and a retrogression of leucosis in mice under the
action of non toxic inhibitors of the oxidative chain reactions
(butyl-oxy-anisole, ionong, propyl gallate)(Ref 2). There were
reasons (the radical mechanism of the reduction-oxidation
processes) for assuming that the inhibition mentioned in the
title is one of the reasons of the tumor inhibiting effect of
the mentioned substanues. This disturbs the formation provesses
Card 1/3 of some energy-rich compounds which are necessary foT the
The Selective Inhibition of the A-A_f.rity of SOV/?0-"-?4--5,- 56162
Reduction-Oxidation Ensymes in Tumoral Cells V11--en Ac?d 'Ulp,~n 37i'lli
of Chain Reactions
intense bioeyn-1-heeis -'.n the neoplastio growtt, In the present
paper results (OUId b-~ 6btalred which -~cnfirm th~ ab3ve-
assumpt*'on. The authors investigated emy-mes of the
succincxidase syitex.. M a9ALt-*I,: an,,e.r of Ehrlich (Erlilch)
in m'!-e. leuo.)sjs of 1,,'&,ik mAce (line C-57, strain LA),
acridine sar-:-ma of and the Braun-Pirs tumor of rallbita
served for thc: experimento. Cells of the I-an~tGr a-3 well
as tum-ral t4,ssu.,:!s of rj%pr new f-.)rmafj.c-ns reducpd tc. small
pier,~es were In-abated for 30 minutes in 0.75, 01-15 and 0.075%
propy! gallate solation, These ~~or)-.-entrationa inhibit the
acti7itly of suc~-"ne dphydrcgenasp in the calls of all tumors
investigated (Pigs-!, 2). The at!tivity of this enzyme I's not
s,)ppressed in healthy 11-i-ver and spleen c;alls by propyl gallate
solutions of 0.15 and 0.075% (Figure 3). Incubation in a 0,75%
solution is, however, inhibiting. This inhibition is rovers--ble
in afflicted as well as .'La sound c-3119. The differences in the
propyll gallate effect on the red-a.--tion-oxidation. process-'.p in
normal and .-Ils are probably due to a differ-?nt
Card 2/3 permeabj.'---*ty of the c-17s and their
The Selective Inhibition of the Acttvity of SOV/20-124-5-56/62
Reduction-Oxidation Enzymes in Tumoral Cells When Acted Upon With Inhibitors
of Chain Reactions
to propyl gallate. Thus, propyl gallate has a w~leative effeit
on tumoral cellD in certain conoentrations. Thi3 Ja oxproosod
by the inhibition of the activity of dehydrogenases which.
participate Jn various reduction-oxidation processes as well as
of cytochror;-~*xidase. The thus influenned colle loose their
implantatioi- power. There are 3 figures and 6 refererioe3,
5 of which are Soviet.
ASSOCIATION: Institut R:him--*cheskoy fizlki Akad,~_mii naliK SSSR
(institute of Chemical Physics of the Academy of Sciewes,USSR)
SUBMITTED: November 25, 1958
Card 3/3
86330
5'gl 05 S11901601002101210191019
B017/BO78
AUTHOR: Lipatova, T. E.
TITLEt On the Possibility of Hardening Unsaturated Polyesters
With Titanium Tetrachloride
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, No. 12,
p. 1882
TEXT; The hardening of polydiethyleneglycolmaleate with styrene and of
polyacrylate esters in the presence of titanium tetrachloride has been X
studied. Polydiethyleneglycolmaleate and styrene were used in a ratio of
1:1. Thepolymerizates thus obtained were insoluble and did not swell in
alcohol-benzene mixtures. When kept in benzene for a few hours, they swell.
By hardening of polyacrylate esters, soluble polymerizates of approximately
50 % were obtained. After 18 hours of polymerization polymerizates soluble
in acetone were formed, polymers insoluble in benzene,acetone, and styrene,
but swelling in benzene were obtained after 48 hours. lt has been found that
titanium tetrachloride can cause the hardening of polydiethyleneglycolmaleate
with styrene and of polyacrylate esters.~There are 2 Soviet references.
Card 1/2
86330
On the Possibility of Hardening Unsaturated Poly- S/190/60/002/012/019/019
esters With Titanium Tetrachloride B017/BO78 X,
SUBMITTED: June 22, 1960
Card 2/2
. , IaPATOVA, T.B.
Some problems in the kinetics of the telomerization reaction.
Dokl.AR EM 4 no.4:164-167,AP 160* (MIRA 13:10)
1. Institut obshchey i neorganicheakoy khimii AN BSSR. Predstavleno
akademikom AN BSSR B.T& Urofeyevym*
(Polymerization)
89585
S/19o 611003100210031012
B130%202
AUTHORS: Lipatova, T. E., Lipatov Yu. S., Tutayeva, N. L.
TITLE: Effect of the grafting of polystyrene on the properties of
orientated polyethylene
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 2, 1961, 184-190
TEXT: The authors attempted to modify the polyethylene properties by means
of grafting. The polyethylene film washed in benzene and dried in the
vacuum was orientated by elongation to 435-460% of its initial length. The
elongated film was 0-004-0-0044 am thick. The purified inhibited freshly
distilled styrene was grafted in the vacuum (10-3 mm Hg) in a quartz ampoule
at 250C under the ultraviolet light of a TW-2 (PRK-2) lamp according to a
method by G. Oster (Ref. 9 see below). Benzopheyxre (3f* solution in benzene)
was used as sensitizer. Before grafting the films were immersed into the
benzene solution for 15 minutes. Subsequently, benzene was evaporated in.
the vacuum. Birefringence of the dry film was by 5~ less than before
treaAment. To avoid the homopolymerization of styrene, first the film was
exposed, and then styrene was added in the vacuum. The authors studied the
Card 1/2
89585
s/igo/61/003/002/003/012
Effect of the grafting B130/B202
birefringenoe of the grafted specimens by means of thP,7yKC--56(PKS-56) poiari-
scope polarimeter as well as the temperature dependence of shrinkage.
Birefringence has a maximum in the case of 7% po3ystyrene, it is strongly
reduced at 9.20, and begins to increase again at 12.3% to attain a maximum
at 18-3%. Grafting inhilAts shrinkage of polyethylene on heating. The
present studies and the changes of An as depending on the polystyrene added
indicate that grafting takes place in the submicroscopic cavities formed due
to shrinkage. V. A. Kargin is mentioned. There are 6 figures, 1 table,
and 13 references: 9 Soviet-bloc and 4 non-Soviet-bloc. The reference to
English language publication reads as follows: G. Ostert H. Moroson,
J. Polymer Sci-, JA, 4/9, 1959-
ASSOCIATION: Institut obs1rhey i neorganicheskoy khimii AN BSSR (Institute
of General and Inorganic Chemistry, AS BSSR)
SUBMITTED: June 14, 1960
Card 2/2
LIFATOVA, TX.; TUTAYEVA, N.L.
Effect of the _rrafting of styrene on the dotible refraction or orient,~d
polyeth,yIene. DoIld.Al" BSS.7'& 5 no.1:12-11~ Ja 161, (MRA 24:2)
1. Inotitut obahchey i noor[:anichoskoy klibdi MI IM".. Predotavlrno
al.ader.dkom All BSSR M.M.PavIyucher0co.
(Polyethylene--Optical proportieA (St~a.cnc)
LIPATOVA, T.E.; -cKOPYTIINA, I.S.; LIPATOV, Yu..5.
Polymerization of styrene in the presence of the glass fiber treated
by titanium tetrachloride. Vysokom.so(,d. 3 no.12:1877 D '61.
(MIRA 15-3)
(Styrene) (Polymerization) (Glass fibers)
71
S/020
16 3/1 48/002/02B/C,7
B1 1 7/B1 86
AU'fHORS: Lipatoval T._4_,_, Berlin, A. A.
TITLE: Carbonium Polymerization of polyacrylic acid esters
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 148, no- 2, 19063,
353-356
TEXT: The carbonium polymerization of polyacrylic-acid esters in vacuo was
studied at 20 + 0.10C in the presence of v0.4 moles/l titanium tetra-
chloride. F~ormation and properties of the following P-polymers were
investigated;~. mr~ -9 (,YGF-9) ditnethacrylate(bis-tTiethylene elycol)-
phthalate, TMPE-11 (T14CF-11) totrainethacrylate(bis-glycerin)-phthalate,
and MMF-2 (MD~-2) dime thacrylate -die thyl elhe glycolphthalate. M.DF-2
yielded the largest amount of 0-polymer (UP to 40,), and TY,.GF-11 fielded
the lowest (5-8~j~Q)- P-polymers are able to convert spontaneously into
infusible three-dimensional polymers, in air as well as in vacuo. Their
properties differ considerably from those of three-dimensional polymers
obtained by radical polymerization of polyacrylic acid ester. The analysis
of IR spectra and thermo-mechanical studies showed that the three-
Card 112
S/020/63/146/002/028/07
Carboniuat Polymerization of ... B117/B1801
dimensional polymers obtained by carbonium polymerization are unsaturated.
ion
~n-GF-9, TMGF-11 , and 1,,'.DF-2 type P-polyi,,iers are suitable for the product'
of elastic coatings fur glass, metal and ceramics, which are stable against
numerous aggressive media. These polymers, which harden under the action
of atmospheric oxygen, do not require the use of bardeners. From.
concentrated solutions of P-polymers in mixed solvents fibers can be
formed which cross-link in air and assume*a three-dimensional structure
after being shaped and stretched. There are 3 figures-and 1 table.
ASSOCIATION: Institut obshchey i neorEanicheskoy khimii Akademii
nauk BSSF (Institute of Gener'al and inorganic Chemi3try
of The Acade..,iy of I.-ciences-BSSR); Institut khimicheskoy
fiziki Akadejaii nauk Sl"'SR'(Institute of Chemical
Physics of the Academy of Sciences USSR)
PRESENTED: January 18, 19062, by V. N. Kondratlyev, Academician
SUBMITTED: January 15, 1962
Card 2/2
LIPATOVA, T.E.; BUDITIKOVA, V.A.; LIPATOV, Yu.S.
Interaction of polymers with fillers. Part 5: Effect
of the cOnditions of depositing a polymer on glass fiber
and the method of treating the glass fiber on the properties
of tho polymer. Vysokem.soed. 4 no.9:1398-1403 S 162.
(MIRA 15:11)
1. Institut obahchey i neorganicheskoy khimii AN
Belorusskoy SSR.
(Glass fibers)
LipATov, yu.js~;_k2gQU,,-j~ VASILERKO, Yaj.; SERGEMA, L.M.
Interaction between polymers and fillers. Part 7: CUSS transiticM.
point and packing densities of filled polystyrene and polymeth7l
methaorylate, Vyookomoooedo 5 no.28290-295 F 163. (MIRA -16 s 2)
1, Institu~ obahchey i neorganiebooko7 khinii AN BSSR.
(Polymers) (Mass f1bers)
IJPATOVA, T.B,; EMIN,, A.A.; Prinimala uohastiye KAKSDIOVA, V.P.
Carbmim polymerization of polyester acrylates. Doki. AjT
SWR 148 no.2053-356 Ja 163. (MLRA 16S2)
1e Inotitut obehehey i neorganicheskoy khimii AN Eslorusakoy
SSR i Institut khimicheakoy fiziki AN SSSR. Predstavleno aka-
demikom V.11. Kondratlyevym,
("fic:17lic acid) (Carbonium canpounda) (Folymerization)
SKORYNINAJ, I.S.; LIPATOVA, T.E.
Grafting of polystyrene on glass fibers. Dold. AN SSSR 153
no.3:661-663 N 163. (MIRA 17:1)
1. Institut obehchey i neorganicheskoy khimii AN BSSR.
Predstavleno akademikom V.A. Karginym.
SOURCEt: AN BSSR.~ Dokiady*, v. '7, no, 8s, 534-537.
TOPIC TAGS: resin, polyesteri polyester acrylate,,.oXigomer, beta
polymer, three dimenni6nallpolymer, film, filament, infrared
:J'- spectroscopy!, infra,red,,spectrum, thermomachantcal curve, thermo-
-A mechanical propertyt MOP-2,,TMGF-11, MGF-9,, cross linking, deform
tion strain,i unsaturationimbldingl, compression molding, prope ty
fication
modi
The mech nism of,the formation of a three-dimensiolp
-ABSTRACT i a
network-in films and filaments of soluble polymers (0-~polymarx
(T. E. 'Lipatova, V3~*sokom*L doyed.0 20 1881, 1960) of p
u m
methacry ate re i0has.been st died,. Infrared spectra.ana thit 0.!
-prop:rties
-of the polymers were determined., Three~ 04,~
.z':-':::- mechanical
yolymers were synthesized from the following oligamers.t resip~
Card
1/4 -
I. !11 .: ':
_7
7
-:A
P30-060dl;''
j A~ C4 9H ~NRI
All
F
1 n ;gl*e 1) :dimaiha'crylate phthalate
MCF-9 (bis(diethy a 0
tatramethaerylate (sic]) and MDF-2P(irIethy,'
~Iene glycol'.dimethaery Ate~ -phthalate -a-egre of poly-~;
[sic) with a e
merization of 2)0 To study the~conversion of. the.oligomers t6~
three-dimensional polymers-, the infrared s.pectra of the three;:
-spolymers in benzene-solution, films cant'from th~
oligomers 0 e
8
'benzeneisoluti e-dimensional polymer
on, and the 'solid thre. were_
M
measured, The three-dimensional polymers from MGF-9 and T CP
u
were-'obtained by carbonium-i'on'polymerizatLon or by compressi6h
Iding.of their 0-polym .,ris. Owing to the low reactLv,ity of
o e
m
doubl-e,bonds in 0-polymers from MDF-2, the:solid three-dimensi6all
structure was obtained'b~,.ultraviolet irradiationjin vacuumiof~
tacky 0-polymers which1had been partially tross-Unked in air I
From theinfrared spectralof HGF-9,'its $-polymer in benzene :ad-!'
three-dimensional pol'mer, ind f'rom dat
..lution, and the solid I y It-7
the literature, the 1630.cm absorption bandg.which is present L J~.
poly(met
methyl.methaerXIateland absent in hyl methacry.late),Aw.a.s., 1:
asure of, the degree..of-,uneaturation of the
-._selected~as a me
I Card 2/4'
..... ... ---- ---
1723--63
lilt
-Ar3006001~~
ACCESSION' NR:
-olig mars and that pp~lymers*i The 812'em-1 absorption- band
0 r
'used to verify the degree of unsaturation, 'and' the 745 cm-
0
sorption band, for quantititive determination-of unsaturati
.1a
method previously descriVed (T. E. Lipatova, Kand, dies. FK~..iml
Karpova, M. 1954). It was found that unsaturation decreases;frdm
the oligomer to the three-dimensional polymer. On conve ra i on o f,
-polymer and to the thre* -dimensional 3101 Y~,
the oligomerto the 0 a L 7
mer a~general increase.in background in the 1000-1400 cm
region was observed, su'giesting that a three-dimensional net~6rk~
of C-C and C-O-C links;ia formed in the polymer. The resulte;of~
infrared-analysis were~ in:,good agreement with the thermomachalAi6al$'
'e
data obtained.. The thirmomechanical curves-of a polymer moldid 'a' t
from,the 0-polymer,, of'MGF-9 indicated that high deformati6
n
-70C, increases with temperature,~and reaches a' axi-I
begins at 60~ m i
~mum at 130-140C, Fufthir.heating caused a decrease-in deforma~i I_
I
tiont owing::td network-structure formation in the polymer by'the;
reaction of the remain~in~ double bonds. Polymers from TMGF-11 h di
-thermomethanical propelrties ganerally associated with polymers i
6r'd 3/4
V-,17933~-63~
ACCESSION. NRI. AP3006001",
"-having' a, "cons- il~erably denser three-dimensional:network, ~The d
formatioli-of -this polymer was-low, despite the residual double
bonds present,-Owing'to'restrieted side-chailn mobility. The
~~thermomechanicil curve or
a -the polymer from MGF-2 reveals high,d
formation, suggesting4 weakly croes-linked three-dimens I onal:
at .ructure, Deformation does pot decrease. with an increase ln.te~_
perature,, since -the absence.of double bonds prevents further 'cross-,
linking.~ It is concluded that by varying the molding conditionslit
is possible to obtain:three-dimensional network-structures with A
varliouszd,egrees of cross!-link.ing and unsaturation and thus to,regu
-.1a't the:physicome*chanical.properties and chemical stability ~fl
obtained from a his
polymers given original polyester. Origo art*
j~
T tab 1e and 2 figuress
ASSqCIATrONt Institut opshche~y 4 neorganicheskoy khimii AN BSSR
I n 9. t i t u t 6' of General land Inorganic ChemistrX, AN BSSR) j
W
DATE; ACQ,.
..I SUBMITTEDs 15Jan63
llSep63 ENCLt 00, 1
SUB CODE:; CH9- MA 'NO REF SOV: 009 OTHERt, 00
Ccrd 4/4.
ILIFAT(
-- )5AX-j.E.. -- ~
Catalytic polymrization of unsaturated polyesters. Carbcrliun
polymrization of polyeateracrylates. Plast.massy no.10-7
164. (KIRA 17-.6)
ACCESSION NR: AP4037287
S/0190/64/006/005/0910/0924
AUT11ORSs Lipatoyi.. To L; Siderko,, Ve He
TITLEt Carbonium copolymerization of dimethecrylate-(bia-triethyloneglycol)
phthalate with styrene
SOURCE: Vy*sokomoleku3.yamr*ye. slyedinaniya, v. 6., no. 5. 1964, glo-914
TOPIC TAGSi carbonium copolymerizationo polyeateracrylate atyrene copolymerization#
polyesteracrylate 3tyrenep monomer reactivity ratio; titanium tetrachloride
catalysto copolymer unsaturation degree
ABSTRACT: The copolymerization of the commercial MOF-9 dimethacrylate-(bis-tri-
othyleneglycol)phthalate with styrene was conducted in a dilatometer in ethyl
chloride solutions at a 1.25 mole/liter summary concentration or the monomers and
in the presence of 0,003 molsAiter of TiC14. Dilatomtric measurements provided
data on the reaction rate, while the composition of the resulting copolymers was
determined bj infrared spectroscopy. The copolym~rization constants were calculated
by the method of At, Do Abkin and So So Medvedev (Zh. rise khimils 21, 1269g 1947)9
the constant r3. for styrene was taken an 0.15 and the r2 for MGF-9 as 0.75. The
Cora
ACCESSION-NR: AP4037287
calculations were conducted under tha assumption that only one double bond was
involved in the polymerization of MGF-9. This assumption was confirmed by the
bromine number determinations. It was found that at a styrene content in the
initial mixture up to 70 mol.X a continuous enrichment of the copolymer in HGF-9
takes place, and that at 63 mol.% of NGF-9 in the initial mixture the composition of
the copolymer is the same as that of the mixture, The data on the initial rates of
copolymerization showed that a small addition of MGF-9 had a markedly depressing
effect on the polymerization of styrene. This indicates a preferential formation of
complexes between TiGl4 and KGF-9,, with styrene taking practically no part in the
initiation of the polymerization reaction. Up to 45 mol.% of MGF-9,, no unsatura-
tion was noted in the copolymer. The degree of unsaturation increased from this
point on up to the copolymers containing 70% MGF-9. above which it began to drop*
The authors express thanks to A. Do Abkin for his discussion of the results and
valuable remarks, and to A. A. Berlin for his interest in the work& Orig, art.
has: 4 graphs*
ASSOCIATION: Institut obshchey i noorganicheakoy khimii AN SSSR (Institute of
General and Inorganic Chemistryp AN SSSR)
Card. 2/3 z
'ACCESSION NRt ' AF4036725' 8/0020164/156/002/0379/0382
'AUT110R: Lipatove, T. E.; Budnikova, V. A.; Siderko, V. M.
!TITLEt On the mechanism of carbonized polymerization of unsaturated polyesters
SOURCE: XT SSSH. Dok3sAy*, v. 156, no. 2, 1964, 379-37M
TOPIC TAGS: unsaturated polyester, carbonized polymerization, titanium chloride,
polymer, ethyl chloride, catalyst, chemical property, styrene, copolymer, oligomer
!ABSTRACT: The authors investigated the subject under the effect of a TiCl catalyst
4
land obtained polymers possessing valuable mechanical and chemical properties. This'
;resulted in an investigation of the carbonized copolymerization of dimethacrylate-
'bis-triethylene glycol-phthalate (MFG-9) with a styrene. Polymerization was effected
lin a solution of carefully dried ethyl chloride at a total monomer concentration of
!about 1.25 moles per liter and a catalyst concentration of about 0.003 and 0.015
;moles per liter at OOC. Theoretical and experimental curves for both catalyst con-~
!centrations are presented in a figure showing the dependence of the copolymer com-
;position an the composition of the original mixture. It is concluded that in a
;Joint polymerization of an oligomer with a styrene In the presence of TiC141 the
reactivity rate of the oligomer depends'not only on the structure of the double
LCard, 1/2
I
ACCESSION NR: AP4036725
bond but also on the whole molecule. This structure determines the composition and
structure of the oligomer complex -- the catalyst, which, in turnp determines the
reactivity of unsaturated polyesters and carbonized polymerization and, consequently,
the basis of-all complex physico-mechanical properties of copolymers. Orig. art.
has: I figure and 1 table.
ASSOCIATION: Institut o~shchey i neorganicheskoy Idiimii. Akademii nauk BSSR
(Institute of General and Inorganic Chemiatryo Academy.of Sciences, BSSR)
SUBZUTM): lOJan64 DATE ACQ: 033un64' B14CL so 00
SUB CODE: NO REF SOV: 007 OTHER: OQ2
Card 2/2
ACCESSION NR; AP4040484 S/0190/64/006/006/1054/lOS9
AUTHOR; Lipatov,,Yu. S.; Tsy*bul'ko, A. Ya.; Lipato va, T. E.
.TITLE: Polymerization of an unsaturated ester of novolac resin
'SOURCE: Vy*sokomolakulyarn;*ye soyedineniya, v. 6, no. 6. 1964,
:1054-1059
:TOPIC TAGS: phenol formaldehyde resin, novolac resin, modified
~novolac resin
:ABSTRACT: A modified, unsaturated novolac'resin which thermosets
.without curing agents has been prepared at the Institute of General
and Inorganic Chemistry, Academy of Sciences, BSSR.'Novolac resin
.113-P-3 containing 13.362 O)l groups was modified by esterification
twith methacryloyl chloride in pyridine to a degree of esterification
,of 52-56% as indicated by chemical analysis and IR spectroscopy.
.The modified resin solution polymerizes at 60C in the presence of
'banzoyl peroxide by the free-radical mechanism to form a still-unsat-
.urated polymer. The modified resin also polymerizes with styrene and
Card 1/2
!ACCESSION NR: AP4040484
tacrylonitrile. Thermomechanical analysis and solubility tests showed
.that the polymers and copolymers thermoset at 120-160C to a product
with a three-dimensional network structure. The modified resin also
.thermosets with the catalytic polymerization product of bis(triethylow
,glycol) phthalate methacrylate to a product with a three-dimensional
;network structure. OrLg. art. has: 1 figure, 2 tables, and 1 formula.
:.ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN BSSR
,(Institute of General and Inorganic Chemistry, AN BSSR)
:,SUBM1-.'.'-.. 05Jul63 DATE ACQ: 06Jul64 ENCL: 00
SUB CODE: MT, 00 NO REF SM 005 OTHER: 001
Cord A^ / 2
iACCESSION MRS AP4043792 S/0190164/006/006/133945391
1AUTHOR1 ~.iptt!vs._T. E!; Skory*nina, 11 so
]TITLES Crafting of tridimensional polymers onto Stage fiber
jj'SOURCEt Vy*~okovo1ek%S1y&rny&ye
liand insect facing p. 1409
soyedinentys, ve 6, no. 8, 1964. 1539
TOPIC TAGSt glass fiber, polymer glass grafting, epoxy resin, bLs-
.(triethyXene glycol)phthalate dimethacrylate, titanium tetrachloride
ABSTRACTS A study has shown that epoxy resin or the unsaturated
oligomer bio(triethylene glycol)phtha *late dimethacrylate can be grafted;,
onto TiC14-trested glass fiber. Grafting takes place on polymerizaticn.
;of ED-6 epoxy resin or HCY-9 bis(triethylene glycol) phthalate dimetha-
'scrylate in benezene solution in the presence of the * treated fiber.
IThe grafted ED-6 or MGF-9 is not removed even after boiling in d1metW
Iformamide and acitonep respectively# for 24 hro The amount of ED-~ I
!grafted on varies from fractions of one percent t -o 5Z.of the weight of
)the fiberl-and that of MCF-99 from I to 2%, Origs art, hask' I figured,--.
1ASSOCIATIONe. none
;ord A /2
-7
Card 7 / 2
-, ~ -- --- --- r. --- - - , - - --r,
TUTAYEVA, N.L.; LIPATOVA, T.E.; LIPATOV, Yu.S.
Grafting of polyam7late on viscose fiber. Dokl. AJI BESPI 8
no.2:108-110 F 164. (MIRA 17-.8)
1. Institut obshchey i neorganicheakoy khimii AN BSSR.
Predstavleno akademikom MI BSSR M.M. Pavl uchenko.
L 17821-65 1-~Wp(e)/EWT(m)/EPF(c)/EWP(v)/Ek/EWP(J)/T/EWP(b) Pc--4/Pq-h/Pr-h/
p
s-4 w4ir
W
ACCESSION NR- AP4046081, S/0070164/0381009/2252/2254
AUTHOR: Lipatova, T. E.; Bakovshchik, M.~G.
r
TITLE: Investigation of t e la 's itanium tetrachloride styrene system by the
electron paramagnetic resonance method
SOURCE: Zhurn,al fizicheskiy khirnii, v-181 no. 9A 1964, -2,252- 2254
-,TOPIC TAGS: glass titaffiu M_ tetrachloride- styrene, titanium tetrachloride glass
s'"stem, titanium tetrachloride st renesystem, glass TiC14 styrene s stem,
y
e16 ct ron. p;iramagnetic,'resonan ce spe ct rum. EPR-spectrum, paramagnetic center,
-polystyren-e.,-glass,bonded polystyrene, fiPR: signal -intensification
h-e-EP spectra of-hii-
_t -1cl --styrenej and-the.glass ------- ---
4
ene sy terns -were studied,' '.The microporous glass, -prepared as
_Ti.C14 --styrL 5
described by 1. V.,. Oreben,shch-ik ,ov and 0. 9, Molchanova (Zh, obshch, khimit,
12) 588, 1942).-was dried in vacuu ,m and the TiC14 -was condensed thereon under
vacuum; in the ternary system- the styrene was condensed onto the glass-TiC14
Card 1/ 3
:,77
'~L 17821-65
ACCESSION, NR:. AP4046081
a,1.2 ratio of components wasused4n-the-TiCl -styrene system.- The-spectrum
was.a 's inglet w th Alne width- of about 30 Oe and g-fac-
of the TiC14 -glass system . i
-tor of about 2; onIexposure to-air-for one- hour, the intensity- increased about 4
times. The spectrum of the ternary system was similar; its behavior on exposure
to oxygen in shown * The TiCl4_ styrene system under vacuum showed no signal
,but on contact with oxygen asighal similar to-the others wCas produced; its inten-,
increased by 100 times in a month then started to fall. Thus the presence of
paramagnetic particles on a glass surface treated with TiCl 4 was established.
The presence of two types of paramagnetic centers was indicated: paramagnetic
center/on the glass surface, formed by.the portion of TiC14 actually bonded to the
glassvalnd thepolystyrene graft .ed thereon; and paramagnetic centers in the poly-
sty-rene polymer formed by the TiC14"which -was desorbed from the glass surface
and dissolved in the mon.omer.~ The noted effect of oxygen on the intensity of the
EPR signal was unique: the inten4ificatioh 'of the, signal was; contrary to all other
.known examples where oxygen Ae6reas6d..sianal intensity. Orig. art. has: 2
figures.
C
d
or o
26-6 ~1: 'tW(M)-/EPF(C)/PPR/,E'tiP(J),/T 4/P 4 RP1 VU/Ml
Pa V/Pt
ACCESSION r4R- -AF400,q896---- S10191164/006/001/0003/0007 -
AUTIIOR.- Lipatwa,7--T-- E--
TITL-*E:-- :Cat"ic po 0
-ization of.-unsaturated-p lyethe'rs.--- Carbobium
--jyrnet
polyrnerlzation of
-SOURCE: Plasticheskiye massy*, no. 1, 1964, 3-7
TOPIC- TAGS:~'-,- ionic -polynieriiati arboniurn volyme-orization- --polyether4cryi----
on, c
ate polymer,, beta2polyrner,: unsaturated polyether polymer, lacquer coating,
air-'drying lacquer.
ABSTR#CT: T4e,carizonitkm-polymeri,zation-of-pol~ethe--racrylatesM_
and TMGF-1PV dthe roperties.of the resultant polymers were
d -7PRI;7me'Zzationa~woere conducted in vacuum at 20C, ing
Tn-vestigate, .7 us 0,4.
mol/ 1. TiC14 Eatalyst; polymerization products were filtered and methanol
washed. The three dimensional polymer remained on the filter; the beta-
polymer can be precipitated _from the filtrate with methanol-water mixture.
card 1/2