SCIENTIFIC ABSTRACT LIPOVSKAYA, T. N. - LIPOVSKIY, P. I.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
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• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

TUVACHEVA, N.Ts.; LIPOVEKATAf.,__T,,A.,;_AVMUKH, NoMe . insh, , red*;
TALAGINA' ;Q .-red.
(High-strength mgnesium cost iron; recomended bibliography]
Vysokoprochnye wgnievye chuguny; rekomendatel'nyl splook
literatury. Pod red. H.K.Averbukh. Leningrad, Ob-vo po rospro-
stramenUu polit. i nauchn.znanii RSFSP., 1959. 70 P.
(MIRA 13:2)
1. Leningradakiy dom nauchno-takhnicheakoy propagandy.
(Bibliography--Cast iron)

.LIPGVSKAYA, V.I.; SHMERBAKOVA~ Ye.Ya.
Distribution of the ten-year maximum thicknesses of the
snow cover of varying probability in the Eurollean part of
the U.S.S.R. Trudy GGO no.149138-47 163. (MIRA 17:1)

LIPOVSKAYA, V.I.
Use of Kolmogorov's criterion in determining the distribu- Ir
tion curves for monthly precipitation totals. Trudy GGO
no.149:35-37 163. (KRA 17: 1) "-

I-IFOVSKAYA, V.I.; SHCHLRBAKOVA, YaJa.
Prosp&ctlve maximum decade heights cf she snow ccver of
varying probability on the territory of the U.1- .`~ .~. r1i C; I.,
GGO no.161:10-22 164. (Mih~ .'1~9'
j

LIPOVSUYA, Valentina Mikhay-lovna; SHIROKOV, K.A., red.
- 41----.- 1 ~ - I .
[Experience in the work of the volunteer bureau of
technical information in the Kirov Spinning and Yarn
Combine] Opyt raboty obshchestvennogo biuro tekhniche-
akoi Informatali priadillno-nitochnogo kombinata Im. S.M.
Kirova. Leningrad,, 1961, 26 p. (MIRA 18s4)

LIPOVSKIY, A. A. RAMDVSKIY, A. 11., YAKDE)VA, P. P.
KALITL ZAYDEL', A. N., ard
"=KIYj__ff. 1.
"Spectral Analysis of the Gdp Ia., and Sm Content of Metals,,"
by A. W. Zeydel ' I N - I . Kaliteyevskiy, A - A - Lipovskiy, A. 11 -
Razumovskiy, and P. P. Yaki va, Vestnik Leningradsko&o Uni-
versiteta., Vol 32, no 4, Oct-Dee 56) PP 18 40
In the introduc-lAon to the article, it is pointed out that a number
of rare earth elements including Gd, Lu, and Sm have exceptionally IwW
cross sections of thermal neutron capture (38,000 barns for Gd, 2,500
barns for Eu, and 8,000 barns for Sm), which are equaled only by that
of Cd (2,800 barns) and that consequently many materials must be freed
of even the smallest trace of these elements. To accomplish this, semi-
,tive methods of arAlysia are required: the sensitivity of the deternim-
tions must be no less Uum of the order of 0-0004. It is stated that
although two US papers on the spectroscopic determinatiop of small
anDunts.of rare earths in uranium and one US paper on the determination
of rare earths in zIrcon4um have been published, a reliable, universaLly
applicable method for the determination of rare earths in metals is
lacking.

Tha:authors then say that work on the davelopmMt of a Isuitable
'method for this purpose waB conducted at their laboratory during the
period 1949-1954, and proceed to outline the results of this vork, which
~dealt with the development of a set of analytical procedures based an
eadssion spectroscopy. They first discuss,the method of concentration
of rare earth elements used by them, which involves introduction of
lanthanum that ar-te aF a carrier - A general section on the spectral
analysis of the concentrates obtained by the method described follows.
kdetailed description of the determination of traces of Gd', Eu, and Sm
in thorium. is then given. According to the description, the rare earth
elements axe separated from thoriun before the spectral analysis by
extracting the nitrates with ether. The effects on the analytical pro-
cedure of impurities consisting of iron, aluminum, silicon, chromium,
and cerium axe discussed. The procedure for the determination of Gd,
_14, and Sm. in uranium,,vhich is described in the next section, is es-
ally the same as -that for thorium.
In the section on the determination of Gd, Eu, and Sm in beryllim,
the statement is made that beryllium oxide which is used in nuclear
power technology must be pure, and that the determination of traces of
Gd, Lu, and Sm, in beryllium is therefore of considerable practical im-
.portance. Separation of the rare earths (including the La carrier)
from Be in the procedure described is achieved by precipitation with
oxalic acid from a BeC12 solution with the use of calcium as an adAi-
tional carrier.

In comectlon with the description of the procedure for the deter-
mination of Gd, Eu., and Sm. in bismath, it is stated that Bi has a small
cross section of thermal neutron capture and can be used as a reactor
coolant. Under the circumstances, according to the article, procedures
by which one may check for the presence in bismuth of rare-earth elements
vith a large cross section of neutron capture are essential. Separation
o-f.the rare-earth elements from bismuth is effected by the hydrolytic
decomposition of bismuth chloride during the course of electrolysis.
The section on the determination of rare-earth impurities In zircon-
im is introduced by the statement that zirconium is used as a construe-
tion material for nuclear reactors, because it has a mmll cross section
of thermal neutron capture and a sufficiently high stability at high tem-
,pere-tures. According to the article, zirconium for nuclear reactor
applications must be free of rare-earth elements with a large neutron
capture cross section. The chemical procedure for the separation of the
rare earth elements from zirconium, which Is baBed on the precipitation
of Zr in the form of its phosphate and that of the rare earth elements
in the form of their oxalates, is rather complicated. It Is described
in detail and illustrated with a chart.

zIn conclusion the authors say that the results of the vork done by
them on the determination of Gd., Eu) and Sm in Th, U, Be, Bi, and Zr
confirm the advisability of using the analytical procedure which they
have developed. They add that they have also done work on the deter-
mination of rare earth elements in Fe, Al, and Mg in connection with in-
vestigations on the rare-earth content in soils and checked the possibil-
ity of applying their method in the determination of Gd, Eu, and am in
Cu. They found that the sensitivity of th-- determination of Gd, Eu,
and Sm in all the metals mentioned .above amounted to approximately 10-5%,
and that this sensitivity can be increased still further by subjecting
larger samples to analysis. For the reasons stated, they assume that
the method used by them is satisfactory and generally applicable for the
purpose of determining rare-earth elements in metals.
S

83. Nitrate C221ex of Urapyl in Acetone Investipted
"Concerning the Formation of a Nitrate Complex of Uranyl in
Acetone," by V. M. Vdovenko,, A. A. Lipovskiy) and M. G. Kuzina,
Zhurnal Neorpnicheskoy Khimii, Vol 2, No 4, Apr 57, PP 970-974
The formation of a complex uranyl compound in acetone when aniline
nitrate or pyridine nitrate are used as donors of nitrogroups was in-
vestigated. The constitution of the complex compound was established
by-the spectrophotometric method. The constant of the stability of this
compound was determined. It was shown that the stability of the complex
IU02 (NOD31 ion depends on the type of solvent used and the content of
water in the organic phase. A new complex compound of pyridine nitrate
with uranyl nitrate was isolated. Its composition was found to corre-
sp6nd to the empirical formula (C5115KH)2 U02 (N03)4 . 2H20. In the ultra-
violet part of the absorption spectrum of the complex (UO2(NO3)31-iOn a
re lar structure was found against abackground of continuous absorption.
(Ur

82. Extraction of Ur!MI Nitrate With Dibutyl Ether Investig!ted
"The Distribution of Kttrie Acid and Uranyl Nitrate Between an
Aqueous Solution and Dibutyl Ether," by V. M. Vdovenko, A. A.
Lipovskiy, and M. G. Kuzina, Zhurnal Neorganicheskoy Khimii,
Vol 2, No 4, Apr 57, Pp 975-979
The distribution of nitric acid between aqueous solutions and dibutyl
etber was investigated. The high solubility of nitric acid in the ether
is explained by the formation of an oxonium compound. The distribution of
uranyl nitrate between an aqueous solution containing nitric said an dibutyl
Iether was investigated in dependence on the concentration of nitric acid in
the aqueous phase. it was established that, as the concentration of nitric
acid in the aqueous phase increases, the concentration of the complex IU02
(NO3)31 ion in the dibutyl etber alBo increases. The reduction of the co-
efficient of distribution of uranium at very high concentrations of nitric
acid is ~xplaiued by a competition between the substances being extracted.
(U)

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ZLYIMLI, A.M.; KAT- TE7EVSKIY. V.I.; LIPOVSKIY, A.A.; RAZUHOVSKIY. A.M.;
TAKINOVA, F.P.
Spectrochemical determination of Gd, In, and Sm in metals.
Fis.abor, no.4:37-40 158. (KIRL 12:5)
I
1. IfIzIcheekly institut Leningradakogo ordena Lenina gosudar-
stve=ogo universiteta iment A-A-Zhdanova.
(Ge;lolinium-Spectra) (Fnwopium--Spectra) (Samarium--Spectra)
k

Kaliteyevskiy, 11. 1., Lipovsk~iy, A. ~A*,~~-13-3-24/27
Razamovskiy, A. N., YaliWmova
Spectroscopic Analysis by Means of Evaporation
(Spektrallnyy analiz metodom ispareniya). 01
Communication 6. The Determination of Cadmium, Germanium,
Indium2 Gallium, Gold, Antimony and Lead in Pitchblende
(Soobahcheniye 6. Opredeleniye kadmiya, germaniya, indiya,
galliyal zolotaj surlmy i avinv'sa v zakisi-okisi urana)
Zhurnal analiticheskoy khimii, 1958, Vol 13, Nr 3,
pp. 372-373 (USSR)
The principles for methods of evaporation were published
in earlier papers (References 1-3). The possibility was
also shown to determine admixtures of other elements in
the difficultly volatile oxides U 308' 112031 ThO 2, Be02
in this manner. The main condition for the efficiency
of an evaporation method is a sufficiently high differen-
ce in the liquids among the admixtures to be determined
and the chief component. In the present paper an evapora-

Spectroscopic Analysis by Means of Evaporation. 75-13-3-24/27
Communication 6. The Determination of Cadmium, Germanium,
Indium, Gallium, Gold, Antimony and Lead in Pitchblende
tion method for the determination of a number of liquid
elements (Cd, In, Ge, Ga, Au, Sb, Pb) in pitchblende is
worked out. Experimental data on the evaporation of the
admixtures were already described earlier (Reference 1).
The evaporation is performed at the air, as on heating
in a vacuum a decomposition of U 308 under formation of
the more easily volatile UO 3 takes place. In the determi-,
nation of r--3.10-5% cadmium and indium difficulties
arose. At 16oo-17ooOC an intensive evaporation of CdO
occurs, but it is not complete, as cadmium is anew de-
posited at the electrode on a temperature rise to
19oo-2ooooC. For avoiding a systematic error the evapo-
ration must therefore by all means be performed at-2ooo0c.
This temperature is also sufficient for completely ex-
pelling all oxides of all other elements to be determined
(In, Ge, Ga, Au, Sb, Pb) and is not high enough to cause
Card 2/4 a marked evaporation of U 308* For the determination of

Spectroscopic Analysis by Means of Evaporation. 75-13-3-24/27
Communication 6. The Determination of Cadmium, Germanium,
Indium, Gallium, Gold, Antimony and Lead in Pitchblende
Cd, In and Sb weighed portions of 2oo mg U 30a had to be
made.
When dividing this amount into four portions and four
times evaporatinB the admixtures at the same electrode a
more intensive blackening of the respective spectral lines
occurs than in works with the total amount. The division
therefore increases the sensitivity, but considerably re-
tards the analysis. The technical data of the spectrosco.-
pie analysis of the sublimates *are given in the paper.
As the sensitive lines of the elements to be determined
lie in different parts of the spectrum it is expedient,
simultaneously to photograph Olt, -spectrum on 2 spectro-
.-raphs 'ISF' -22 or Q-24 an6 ISP -51). For the line In I
(4511-,3 X) silver electrodes iere used, as on copper elec.-
trodes this line of indium is'overlapped by the intensive
line Cu 4509~4 1. For recording the line Cd 11 (2265 1) -
which lies in the distant ultraviolet special photogra-
Card 3/4 phic plates ("spektraltnyyell, type III) were used. 'The

Spectroscopic Inalysis by Means of Evaporation.. 75-13-3-24/27
Communication 6. The Determination of Cadmium,
Germanium, Indium, Gallium, Gold, Antimony and Lead in
Pitchblende
mean quadratic error of an individual determination of one
of the above-mentioned elemento does not exceed 15-2o%.
Tho anal1ytical lines of the individual clemento ueod for
the determinations and the different sensitivities are gi-
ven. A. If. Zaydell gave valuable advice, G~. G. Kuid per-
formed the control experiments.
There are 1 figure, l'table,and 3 references. 3 of which
are Soviet.
A350CIATION: Leningradskiy go5udarstvennyy universitet im. A. A.
Zhdanova
(Leningrad State University imeni A.-A. Zhdanov)
SUBMITTEDs February 7, 1957
1. Evaporation--Applications 2. Pitchblende--Spectrographic
analysis
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5(2); 21M SOV/78-4-4-25/14
AUTHORS: Vdovenkc, V. M., Lipovskiy, A. A., Nikitina, S. A.
TITLE: On the Formation of Chloride Compl, Uranyl CompolmdE
in Acetone (Ob obraz3vanlii khloridnykh kompleksnykh
soyedineniy uranila v atsetone)
PERIODICAL: ZhurnaI rieorganicheakoy khimii, 1959, Vol. 4, Nr 4, pp 862-865
(USSR)
ABSTRACT: The fcrmation of complex compounds of the uranyl ion in accetone
wit-h hydrochloric pyridine and hydroxylamine as Cl- dcr-ors was
investigated by the spectrophotometria method. The author3
plotted the absorption spectra of the solutions and the de-
pendence of the molar extinction coefficient on the conceat-rat-ion
of the complex-forming substance for various wavelengthas
(Fig 1). Uranyl perrhlorate hexahydrate was app2ied as an
initial compound. With a ratio of the components
U0
(C1-0
: C
H
is formed. With
N.HC1 the complex UO
)
2
2
2 2
4
5
5
increasing concentration of hydrochloric pyridine or, more
preoisely, hydroxylamine also the complex formation is Inten-
Card 112 sified. The complex UO Cl- In herein formed with hydrochloric
2 3

SOV/78-4-4-2:; 444
On the Formation of Chloride Comple.-. Uraayl Cowp.-,vzAs in.Acetn.-t-7
hydroxylamine. The abscrpt-11on spectra of UO 'Clo
2 ~ - 4) 6H20 a;-,d
those of the chloride complex compounds of the urax'Y'L ion in
acetone are represented in figure 4. With the act~lon of thci
uraryl abloride complex UO 2012 on hydrochloric pyridine a new
compcund is produced: (C 5 H5NR)2Uo2Cl4* The compound is in-
soluble in diethyl ethex, cyclohexanonev tributy! phosphate,
pyridine, benzene, and carbon tetrachloride. There are
4 figuzes and 7 references, 2 of which are Soviet.
SUBMITTED: January 17, 19158
Card 2/2

5(2) SOV/78-4-10-12/40
AUTHORS: Lipovskiy,-A. A., Chernyavskaya, He Be
TITLE; Spectrophotometric Investigation of the Formation of Sulphuric
Acid Complex Hydrides of PuIV in Nitric Acid Solution
PERIODICAL: Zhurnal neorganicheskoy khimii,-1959, Vol 4, Nr 10,
pp 2244-2247 (USSR)
ABSTRACT.* The-transuranic elements can be precipitated by potassium- or
lanthanum sulphate. The exact form of the complex ions of
PU IV has hitherto not been known. Therefore the investigation
mentioned in-the title was carried out in solutions of 1.5
normal nitric acid. Since the absorption spectra of the trans-
uranic elements change in dependence on the composition of the
solution, spectrophotomet-ric methods;(spectrophotometer of
SF-2M type) could be applied. As can be seen in figure 1, on
addition of K 2s04 a considerable change of the spectrum occurs.
In order to find the form of the complex 'ions of Pu IV , the de-
pendence of the molar extinction coefficient of some absorption
bands on the concentration of the potassium sulphate was il-
ie lustrated graphically (Fig 2). In a similar way Be G. Pozhar-
Card 1 2 skiy and V. V. Fomin had proceeded in the investigation of the
P

SOV/78-4-10-12/40
Spectrophotometric Investigation of the Formation of Sulphuric Acid Co=plez
Hydrides of Pu IV in Nitric Acid Solution
complex compounds of Pu IV in sulphuric acid. It was found that
plutonium forms a continuous series of sulphuric acid complexes.
'The rapid variation of the intensity of the absorption bands
by small additions of sulphate ion already indicates the high
stability of sulphuric acid complexes in nitric acid solution.
This must be considered in the spectrophotometric determination
IV
Of Pu in nitric acid, since the presence of small amounts of
sulphate ions significantly influences the molar extinction
coefficient of the absorption bands A - 476 mA. The authors
express their gratitude to V. I. Grebenshchikova for valuable
advice. There are 2 figures and 4 references, 3 of which are
Soviet.
SUBMITTED: July 2, 1958
Card 2/2

5(2) 05864
AUTHORS: Vdovenko, V.M.t_ -1ipGvakiY#_A+ SOV/78-4-11-17/50
Kusinag.M.G.
TITLE: The Distribution of On, Cat Sr and La Among Aqueous Solution
and Methyl-butyl Ketone in the Presence of Uranium
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 11,
.pp~2502-2504 (USSR)
ABSTRACT: Uranium W be *&oily separated from elements of group I,
II..azkd-III of-the periodic njotem by means of the methyl-
.b?1ty1-kotone (MBK) in which the nitrates of theme elements
are uns6luble. ke'uranium in, under certain conditions,
extracted alsoas HUO 2(N03)3 (Rof 3)#'it is possible that
On, Cat Sr.and La are included in the extraction in the form
of the corresponding salts. The authors therefore investi-
gated the distribution of Cs137' CA45, Sr 89, Sr 90 and La140
among the aqueous solution' of nitrates and MBK in dependence
on the uranyl-nitrate concentration. The latter was-yaried
from 0.1 - 0.5 mole, the concentration of the nitrate ions
was kept stable by a corresponding addition of C&(NO )
Card 1/2 and hydrolysis of the uranium salt could be preventea 9; the

05864
The Distribution of Ce, Ca, Sr and La Among Aqueous SOV/78-4-11-17/50
Solution and Methyl-butyl Ketone in the Presence of
Uranium
SUBMITTED:
addition of O.In HNO 3* Table 1 demonstrates the influence
exercised by the ursAyl nitrate upon the distribution of
Go, Sr.and La. Table 2 shows the same for Ca, the latter
being determined.radiometrically and gravimetrioally. With
rising ooncentration.of U02(NO3)2 an incr .easing amount of
Ce, Ca, Sr and La is carried away by MBK in the form of the
salts NUO 2(NO3)31 the existence of which was proved by the
absorption' spectrum (Fig 1). There are I figure, 2 tables,
and 5 references, 2 of which are Soviet.
July 2, 1958
Card 2/2

VDOVZNM, V.M.; I~IFOVSKIY, A.A.; KIJZINA, M.G.
Spectrophotometric investigation of the formation of complex nitrate
compounds of p~utonyl in acetone, 'Radiokhimiia 2 no,3:301-306 160.
(MIRA 13:10)
(Plutonyl compounds-Spectra)

VDOV=M, V.M.; - LIPOVSKIr, A.A.; KUZINA, M.G.
Spectrophotometric investigation of the formation of complex nitrate
compounds of platonyl in aqueous solutions, and extraction of Pa(VI)
with dibutyl other. Radiakhimiia 2 no-3:307-311 160. (MIRA 13:10)
(Plutonyl compounds--Spectra) Oktraction (Chemistry))

VDOVYM, V.M.)- - I UY.,
JIM -6 --A..A.; KUZINA, M.G.
Formation of the complex compound neptunyl trintGate. Radiokhimiiw..
2 n0-3:312-314 160. (MMA 13: 10) ;.
(Reptunyl compounds)

LIPOVSKIT, A.A.
Symposipm on the theorr of extraction. Radiokhimiia 2 no.3:37-7-380
160. (lbetraction (Chemistry)) (MM 13:10)

VDOVINKO, Y.M., LIPOVSKIT, AoA. NIZITINA, S-A,
Extraction of uranium from HC1 solutions by means of tributyl
phosphate. Zhur neorg. khim. 5 no.4:935-940 Ap 16o.
(MI" 13:7)
(Uranium) (Butyl phosphate)

7z4Y.1
S/186/61/003/003/017/ol8
-i~ /1 3 02 0 0 E071/E435
AUTHORS: Ydovenko, V#M*9)4~v ~y,-A,A._and Kuzina, M.G.
TITLE: On the Adsorption of Uranyl Nitrate From Organic
Solvents With Anion-Exchange Resins
PERIODICAL: Radiokhimiya., 1961, Vol.3, No.3, PP-365-371
TEXT: Strongly basic anion-exchange resins are widely used for
separation of simple and complex anions from aqueous solutions.
High molecular aliphatic &mines are also used for this purpose,
At present extraction with amines is considered as an ionic
exchange on a liquid anionite. Also, for the extraction it is
considered necessary that the element under separation from its
aqueous solution is in the state of a complex anion. It in also
possible to describe the extraction (and adsorption on a resin)
starting from the formation of a non-charged complex, forming with
an amine salt, the extractable complex compound. In both cases,
after the extraction the same compound is found in the organic
phase. An experimental proof of the mechanism of separation
related to the formation of a complex compound can be obtained by
investigating the separation with anion-excbange resins from
solutions which do not contain an excess of anions and in which the
Card 1/4

22493
s/186/61/003/003/017/018
On the Adsorption of Uranyl ... E071/E435
element under separation is known to exist in the form of a neutral
complex. For this purpose, the authors investigated the
separation of uranyl nitrate from a number of organic solvents on
an anion-exchange resin AM, the capacity of which in respect of
N03- ion was 2.9 mg-equiv. per 1 g of resin. A weighed sample of
the resin (1 g) in N03- form was shaken with 10 ml of a solution
of uranyl nitrate dihydrate for 20 to 25 hours. Previously it
was established that this time is sufficient to attain
equilibrium. Uranium was washed out from the resin with 0.1 N
nitric acid and analyzed colorimetrically. The analysis of the
equilibrium liquid phase was also carried out. In experiments on
the separation of uranium from organic extracts, air dried resin was
used, in all other cases it was dried at 700C.- The coefficients of
distribution of uranium between resin and organic solvents were
calculated from the formula: Kp(mg U/g resin) /(mg U/ml solution).
Data on the adsorption of uranium from 16 different solvents by
dried resin were obtained. The results indicate that adsorption
of uranylnitrate depends on the nature of the solvent. As the
stability of uranyl trinitrate complex depends on the content of
water in the-organic phase, the influence of the latter on the
Card 2/4

S/186/61/003/003/017/018
On the Adsorption of Uranyl ... E071/E435
separation process was also investigated. It appears that the
change in the dielectric constant of the solution due to an
addition of water cannot explain the difference in the degree of
adsorption and some change in the resin phase should be assumed.
The presence of maximum on the adsorption curves at a certain
content of water in the solution could be explained by the fact
that at a certain water concentration, its presence leads to
dissociation of the formed uranyl trinitrate complex. The
influence of the concentration of the uranium in solution on its
adsorption on the resin was also investigated. It was found that
the coefficient of distribution (K ) is inversely proportional to
the uranium concentration. Thus a~ low concentrations, uranium
can be particularly well separated from organic solvents. From
the resin, uranium can be easily extracted with 0.1 N nitric acid,
the desorption can also be done with tributylphosphate. On the
basis of the results obtained' ' it is concluded that adsorption of
uranylnitrate on resin can be related to the formation of
complexes with the resin. There are 2 figures, 2 tables and
11 references: 2 Soviet-bloc and 9 non-Soviet-bloc. The four
Card 3/4

22493
s/186/6i/oO3/003/017/018
On the Adsorption of Uran:yl E071/E435
most recent references to English language publications read as
follows: L.Kaplan, R.A.Hildebrandt, M.Ader, J.Inorg.Nucl.Chem.,
2,153 (1956); J.Kennedy, R.V.Davies, J.Inorg.Nucl.Chem., 12,193
(1959); W.Gerrard, E.D.Macklen, Chem.Rev., 59,1105 (1959);
C.W.Davies, B.D.R.Owen, J.Chem.Soc., 1676 (1956).
SUBMITTED: JulY 5, 1960
Card 4/4

26602
s/186/61/003/004/001/007
E141/E164
AUTHORS: Vdovenko, V.M., Lipovskiy, A.A., and Nikitina, S.A.
TITLE; on the mechanism of the extraction of tetravalent
plutonium with primary alkylamine from 112SO4 solutions
PERIODICAL,. Radiokhimiya, 1961., Vol-3, NO-4, PP~ 396-402
TEXT. Extraction with high molecular weight aliphatic amines
has recently found wide application. C.F. Coleman, K.B. Brown,
J.G. Moore and K.A. Allen (Ref.li Proceedings of the Second
International Conference on the Peaceful Uses of Atomic Energy,)
have described the extrac~tion of UIVI ThIVI CeIV and ZrIV from
H2SO4 solutions, but they do not give any data on the mechanism of
the reaction. The authors investigated this reaction mechanism.
The authors used a mixture of primary aliphatic amines consisting
Of C7 - C9 AtOms (d = 0.7846), the amount not exceeding 0.5%;
chloroform was used as organic solvent. The PuIV content in the
aqueous and the organic phase was determined by measuring the
a-activity of aliquot samples on a standard device type D~ PUIV
was re-extracted from the organic phase into a 1.5N HN03 solution.
Preliminary experiments showed that equilibrium was attained in not
Card 1/5

26602
On the mechanism of the extraction s/186/61/003/004/001/007
E141/E164
more than five minutes, The concentration of the amine in the
starting solutions was determined by titrating with acid in an
alcoholic solution whilst using bromophenolblue as indicator.
After extraction the amine content in the aqueous and organic
phase can be determined with alkalized solutions when the amine
is converted into the base. The concentration of nitrate-ions in
the organic phase was determined after re-extraction by titrating
with indigo-red (Ref.6; J. Ungar, J. Appl. Chem., Vol,6; 2, 245
(1956)). The sulphate-ion was determined gravimetrically as BaSO4
and in some cases after p-irradiation with s35 whilst using
tagged H2SO4., 11hen determining the distribution of the amine
between the chloroform and the aqueous H2SO4 solution, the sulphate
was found mainly in the aqueous solution. The coefficients of
distribution of plutonium (a) increase with increasing
concentration of the amine and of H2SO4 in the aqueous solution.
This 3-S POSSibly due to the formation of complex sulphate compounds
of PuIV containing the amine, The composition of the separated
compound was determined by investigating the dependence of aPu(IV)
on the concentration of the amine at constant concentration
of PuIV and H2SO4- It was found that two moles of amine nitrate
Card 2/5

26602
on the mechanism of the extraction... S/186/61/003/004/001/007
E141/E164
associate with one mole of the metal nitrate, forming the compound
l,R3NH)2 Me (N03)69 where R = alkyl radical. The amine sulphate
is not extracted by chloroform. The composition of the complex
compounds extracted from H2SO4 solutions and from nitrate-sulphate
solutions was confirmed by extraction and with the aid of
absorption spectra. on the basis of concept on the anion-exchange
character of extraction processes, carried out with amines, the
eparation of PuIV from H2SO4 solutions can be envisaged as a
ulphate-ion exchange on an anion complex of PuIV which is formed
:
in the aqueous phase:
4+ 2 - 2-
PU + 3SO4 PU(SO4)3
2(RNH ) S04 + Pu(SO4) 2- (RNH )4pu(SO4)4 + so 2- (1)
3 2 3 3 4
The extraction can also be described by the formation of neutral
plutonium aulphate which is formed from the amine sulphate of the
extracted complex --ompound:
Card 3/5

26602
on the mechanism of the extraction ... s/i86/6i/003/004/001/007
E141/E164
PU 4+ + 2SO 2- PU(SO4)2
4
2(RNH 3)2SO4 + Pu(SO02 # (RIVH3)4pu(SO4)4
(2)
PuIV is known to form complex sulphate compounds even when a
considerable excess of nitrate-ions is present in the solution
(Ref,5: A.A. Lipovskiy, N.B. Chernyavskaya, ZhNKh, Vol.4, 10,
2244 (1959)). Experim-ants were therefore carried out on the
extraction of plutonium from a mixture of HN03 and H2SO4 solutions-
At low concentrations of the amine the nitrate is hardly extracted
by chloroform but with increasing concentration polymeric amine
aggregates are formed which are extracted by the organic solvent.
An increase in the concentration of HN03 in the aqueous solution
at constant concentration of the amine leads to an increased
content of the amine nitrate in the organic phase. Colloidal
13 olutions of amine nitrate in chloroform show a different behaviour
In extraction with respect to ions which are present in the aqueous
solution and experiments were carried out to investigate the
behaviour of the sulphate-ion during extraction from nitrate-
sulphate solutions. When the concentration of HN03' and therefors
Card 4/5

26602
On the mechanism of the extraction S/186/61/003/004/001/007
Ei4i/Ei64
also of the amino nitrate in the solution was small, the Amino
sulphate was not extracted into the chloroform. Deposits were
formed at the phase boundary as well as during extraction from pure
H2SO4 solutions. At concentrations of approximately 0-15N HN03
the deposits disappear and the concentration of the oulphate-ion in
the organic phase increases sharply. A gradual substitution of the
15 ulphate-ions and nitrate-ions takes place during the later stages.
it is also suggested that the amine sulphate in separated from the
nitrate-sulphate solutions because a finely dispersed phase is
present in the chloroform, the dispersion being formed by the
amine nitrate. Acknowledgments are expressed to L.N. Lazarev for
his cooperation.
There are 5 figures, 2 tables and 7 references: 2 Soviet and
5 non-Soviet. The 4 English language references read as follows:
Ref.l: an in text above.
Ref-33. A.S. Wilson. Proceedings of the Second International
Conference on the Peaceful Uses of Atomic Energy.
Ref.6: An in text above.
Ref.4: D.J. Carswell, J.J. Laurenset. J.Inorg.Nuel.Chem., V.11, 1.
Card 5/5. SUBMITTED July 5, 196o. 69 (1959)

31889
S/186/61/003/005/007/022
p.440 0 9071/E485
AUTHORS-. Vdovenko, V.M., Lipovskly, A.A., Kuzina, M.G.
TITLE. The extraction of uranium (VI) with solutions of
trioctylamine nitrate
PERIODICAL- Radiokhimiya, v-3, no-5, 1961, 555-566
TEXT- The extraction of uranium (VI) with solutions of
trioetylamine (TOA) in various diluents (carbon tetrachloride,
benzene, trichloroethylene, chloroform, chlorobenzene, bromobenzene,
tetrachloroethane, dichloroethane, butylbromide and nitro-benzene)
and the dependence of the separation of uranium with an anion
exchange resin AM on the composition of the aqueous solution were
investigated. Equal volumes of thn phases were used for the
extraction. The coefficient of distribution was calculated from
au = COICw where Cc, and' Cw -equilibrium concentrations of
uranium in organic and aqueous phases. The re-extraction of
uranium was done with a soda solution which was subsequently used
for the colorimetric determination of uranium- In experiments on
the separation of uranium with a resin,-a strongly basic resin AM
was used, its capacity in respect of N03 was 2.9 mg/equiv per Ig
of air-dried resin. The coefficients of distribution were
Card 1/3

31889
s/186/61/003/005/007/022
The extraction of uranium (VI) E071/E485
calculated from k a g Ug resin
P g U/ml of solution
The -.omposition of extracted compounds was determined by the
absorption spectra. It was shown that the lack of correspondence
in data obtained by various methods on the determination of the
composition of uranium compounds in the organic phase is due to
changes in the nature of the association of amine nitrate caused by
the extraction of excess nitric azld. In all the cases
investigated the extraction of uranium with TOA nitrate is related
to the formation of a complex compound of uranyltrinitrate, The
dependence of the coefficients of distribution of uranium on the
4omposition of aqueous solution indicates that the formation of
uranyln1trate molecules in necessary for the extraction of uranium,
The extraction of uranium with TOA solutions in various diluents can
be represented as a prozess of complex formation between neutral
molecules of uranylnitrate and molecules of aminenitrate, The
sorption of uranium with anion exchange resins can be described
similarly, The analogy between the extraction of uranium with
amines and its extra,7:tion with oxygen containing solvents from
Card 2/3

91889
S/186/ 1/003/005/007/022
The extraction of uranium (VI) oo E071/z485
nitric acid solutions an well as from solutions containing
salting-out agents was pointed out. Changes in the extracting
properties of TOA nitrate in various d1luents is related to the
polar properties of the diluents used and interactions in the
system extracting agents-diluent. There are 4 figures, 3 tables
and 20 references: 12 Soviet-bloc, 2 Russian translations of non-
Soviet publications and 6 non-Soviet-bloc. The four most recent
references to English language publications read-as follows:
Refo4g W.E.Keder, J.C.Sheppard, A.S.Wilson, J. Inorg. Nucl. Chem.,
12, 314, 327 (ig6o)3 Ref.6: D.J.Carawell, J.J.Lawrence, J. Inorg.
Nucl. Chem., v.111, 69 (1959); Ref.17; J.K.Foreman, J.R.McGowen,
T~D.Swith, J.Chem, Soc., 738 (1959); Ref.18: A.G.Gobbe,
A.G.Maddock, J. Inorg. Nucl. Chem., v.7, 2, 94 (1958).
SUBMITTED; October 27, 1960
Card 3/3

VDOVMOI V.M.; LUIOVSKIY, A.A.; KUZINA, M.G.
Absorption of uranyl nitrate from organic
of anion exchange resins. Radiokhimiia 3
(Uranyl nitrate)
(Anion exchange)
solvents with the help
no.3.,365-371 161.
(MIRA 14:7)
11,,.~;: I
, - 1

VDOVENKO, V.M.; LIPCIVSKIY A.A.; KUZINA, M.G.
Extraction of uranium VI by means of trioctylamine nitrate
solutions. Radiokhimiia 3 no.5:555-566 161. (MIRA 14: 10)
(uranium) (Trioetylamine)

S/186/62/004/006/001/009
E075/9433
AUTHORS; Vdovenko, VJI., Li Nikitina, S.A*
P
TITLE: On the mechanism of extraction of U(VI) with
. solutions of tridecylamino fluoride
PERIODICALi Radiokhimiya, vA, no.6, 1962,.625-632
TEXT: In order to elucidate the mechanism of the extraction
process, some.relationships in the extraction of U(VI) from
solutions in HF and NaF with tridecylamine fluoride (TDA) were.----
studied.-''---Using-& spectrographic.method it was shown that in
organic solutions complex compounds TDAHU02F3 and (TDAH)2.U02F4 are
formed. The composition of the complex compounds was also
determined from the results of the analysis of equilibrium organic
solutions'and construction of the dependence IS atu on
19 CTDA-HF (where aU - the coefficient of distribution of
uranium). It was shown that complex compounds with the ratio
F/U > 4 were niot formed. The investigation of the extraction ofl
uranyl fluoride from aqueous solutions with tridecylamine fluoride
indicated that t1fe.e-xtraciion takes place due to the formation of
complexes qf U002 with one or two molecules of TDA.-HF. The
Card 1/2

On.the mechanism' E075/E433
best remova!l of U with amine fluor'ide is obtained on extraction
from solutions Of U02F2 not coniainink an excess of fluorine ions..
There are:5,jigures and 7 tables.
SUINITTED August 46, 1961
-,I
iCard 2/2

S/186/63/005/001/011/013
E075/E436
AUTHORS; Vdovenko, V.M., Lipovskiy, A.A., Nikitina, S.A.
TITLE: Investigation of the solvation of uranyl chloride with
the molecules of tri-n-butyl phosphate
PERIODICAL; Radiokhimiya, v-5, no.1, 1963, 139-141
TEXT: Spectroscopic methods were used to investigate the nature
Of U02C12 added to a solution of tri-n-butylphosphate (TBP) in
CCI~. In the original solution (saturated solution of anhydrous
U02 12 in TBP dissolved in CC14) the solute had the composition of,
UO2Cl2-2TBP. As the proportion of TBP increased (100%. TBP),'the
UV spectra of the solutions changed and indicated that U02C12
coordinates with 3 molecules of TBP. The equilibrium constant
for the formation Of U02C12-3TBP is 3.1 + 0.2. The interaction
of P - 0 groups with the U atom was shown in infrared spectra to
be less strong in U02Cl2*3TBP than in UO2Cl2-2TBP. The complex
with 4 molecules of TBP did not form, presumably due to steric
hindrance. There are 3 figures and 1 table.
SUBMITTED: October 31, 1962
Card 1/1

Vf)OVENKO$ V.M.; LIPOVSKIY, A.A.; NIKITINA, S.A.
.
Study of the solvation of U02C12 with molecules of organophosphorus
compounds by spectral methods. Radiokhimiia 5 no.5:585-591 163.
(MIRA 1713)

VDOVENKO, V.M.; DEMIYANOVA, T.A.; KUZINA, M.G.; LIPOVSF-ly, A.A.
Hydrogen bonding in alkyl ammonium salts. Part 1., Infrarf3d
spectra and structure of trioctyl ammonium nitrate.
Radiokhimiia 6 no. 1:49-55 164. (KRA 17-6)

VDOVENKO, V.M.; LIPOVSKIY, A.A.; NIKITINA, S.A.
Hydrogen bonding in alkyl ammoniun salts. Part 2: Infrared
spectra and stru,~ture of trldacyl ammonium chloride.
Hadiokhimiia 6 no. 12-56-62 164. OCRA 17:6)

LIPOVSKIYp A.A.; YAKOVLEVA, N.Ye.
- . ........ :,-------,
Solvation of UC14 by n-tributyl phosphate molecules. Zhur.
neorg. khim. 9 no.3:767-768 Mr 164. (MIRA 17:3)

"IFOVSKIY, A.A.; KUZINA, M.G.
Infrared spectra and atr-uctura of c6rrj~~!-lx Coll"POUM113 01-
uranyl nitrate with cesium and pyridl.m.mi r1trates.
4
Radiokhimlia 5 no. 6%668-671, 163. WIRA 17,7)

- - " i - ' ' - I
V. 1-1. ( " eni ~ vq -L4~-d) -; -- "'. " p 1'*A. 0,oning-rad); MINA. M.G.
(Lcmingg n (1) - .4 1
I i'l., "NA, d ) ; JNIKITI JA, S. A.
(Leninr-rad)
Hydrogen bonds J-n alkvl arinonlum sa*Its. Dr. fiz. zhur. 9
no.4:453--457 Ail 164. (%',IfUi 17:8)

LIPOISKIYY A.A.; KWINA, 14.G.
Infrared absorption spectra and structure of sulfate, bisulfate,
and uranyl trisulfate of tridecyl ammonium. Zhur. neorg. khim.
10 no.6:1360-.1368 je 165. (MIRA IM)

L 17376-66 EPF(n)-2/MYT(z)/ZWPM IJP(c) 'NWIJDIJG
'ACC KR- - APS004504 SOURCE CODE: UR/,- 66/65/007/005/0509/0516
AUTHOR.- Vdavenko, V..H.; Lipovskiy, A. A.; Mikitina, S. A.; YakovIeva, N. Ye.
ORG: none 0
IV VI 49
TITLE: Investigation of the extraction of U and U from hydrochloric acid solu-
:tions by means of tri-n-butylphosphate
SOURCE: Radiokhimiya, v. 7, no. 5, 1965, 509-516
TOPIC TAGS: uranium, organic phosphorus compound, solvent extraction, complex
.molecule
'A
ABSTRACT; The lirgaiul ~as extracted from the aqueous phase by forming the complex
compounds which accumulated in the organic phase. The optical method (percent
transmission of 400-700 millimicrons) was applied to measurement of the concentra-
.tion of uranium-tri-n-butylphosphate complexes in the organic phase. The extrac-
,tions were conducted using either 20% in CC14 or 100% TBP. In the extraction ex-
periments 0.5-12.8 molac HCl solutions and 5-10.9 molar LiCl-solutions were used.
It was found that the composition of the complexes formed is a function of both the
UDC: 542.61:546.791.42791.r,
Card 1/2

L 17376-66
ACC XR: AP6004504
~HM concentration in the aqueous phase and the TBP concentration in the inert sol-,
VI
vent. In the case of U , the following complexes were found In the extracts:
U02Cl2(TBP)2, U02Cl2(TBP)3, and a complex anion CU02CI3(TBP) I . In the case of
:UIV , the organic phase contained UC14(TBP)2, UC14(TBP)3, andna complex anion UC19-.
IV VI
Under the conditions near saturation equilibrium, both the U and the U are com-
bined with two molecules of TBP. In the case of an excess of TBT, the complex in-
volves three molecules of TBP. In the case of higher HC1 concentration in the
starting aqueous solution, accompanied by an excess of TBP, the extract contains
~anionic complexes of UIV and UVI. Orig. art. has: 2 figures, 2 tables, 6 formulas.
~SUB CODE: 07/ SUBM DATE: 02Nov64/ ORIG REF: 013/ OTH REF; 006
Card 2/2 nist,

L 17375-66 zwp(j)/zwT(z)/r - Rm
ACC NR: AP6004505 SOURCE CODE: (ilt/0186/65/0071005/0563/0572
AMOR. Li sk* A A.; Mikitina, A.; Yakovleva, N. Ye.
__pOv IYI.
31
ORG: none
,TITLE: Investigation of the UC14 solvation by molecules,of neutral organophosphate
'compounds by means of spectroscopic methods
SOURCE: Radiokhimiya, v. 7, no. 5, 1965, 563-572
TOPIC TAGS: uranium compound, organic phosphorous compound, complex molecule, sol-
vent action, intermolecular complex, IR spectrometer, absorption spectrum
ABSTRACT: Solvation Of UC14 by tri-n-butylphosphate (TBP), diisoamine ester of
methylphosphonic acid (DAMPA), and tributylphosphineoxide (TBPO) was investigated
using optical methods. Absorption spectra were taken with an SF-2M spectrophotomet-
er (400-1100 millimicrons) and IKS-14IR spectrometer (7-11 millimicrons). Saturat-
ed solutions of anhydrous UC14 in solvents containing TBP-, DAMPA-, and TBPO in
CC14 and benzene were used. It was found that in the case of an excess of phospho-
organic ligands in inert solvents, the complexes of the general formula UC14S3 are
Card 1/2 UDC: 548.56 546.791.4 131 21-11-

L 17375-66
R: AP6004505
&CC N
A0
formed (mbere S is TBP, DAMPA, or TBPO). The equilibrium contents of the reaction
.UCi4S2 + S * UC14S3 are 55�3, 117t12, and 8614 for TBP, DAMPA, and TBPO, respective-
ly. Changes in the absorption spectra of U IV which occur at high DAMPA- and TBPO
concentrations are-attributed to the coordinatively saturated compounds of the
UC14S4 type. The increase in ligands concentration was found to be reflected in
weaker bonds between U VI , and UIV atoms and phosphoorganic ligands7ft UC14S3 type
complexes. It was found thatthe electron affinity of heavy metal! salts can be
measured in terms of,displacement of the IR absorption spectra of vibration of
P=O group of the coordination compounds containing equal number of neutral ligands.
,The similarity of the absorption spectra of UCI 2+ and LIC14S2 indicate that the
ligands are arranged octahedrally around the U4$ ion in the UC14S2 complex. A
,low symmetry is assigned to the UC14S3 compound. The absorption spectra are graph-
ed. Orig. art. has: 5 figures, 3 tables.
SUB CODE: 07/ SUBM DATE: 'O2Nov64/ ORIG REF: 010/ OTH REF: 009
..Card 2/2 not
77

LIPOVSKIY, A.A.; NIKITINA, S.A.
.
Infrared spectra and structure of trialkyl ammonium
fluorides. Zhur. neorg. khim. 10 no.1:176-182 Ja 165.
(MIRA l8sll)
1. Submitted July 18, 1963.

DINITAX(NAt f,A,j,.LlPO.VS.KlTF 4.A.
bfvvmd "tra and lWdragen bDndlng in dlooVI - - Iva
Bats. Zhur.noorg.khtm. 10 noslM2801-2906 D 165. (MIMA 19o1)

LIPOVSKIY, D.
Lipovskiy, D. "Our native land--the oirthplace of the kelicopter," Vestnik
vozdush. flota,-1948, No. 12, p. 6-10
SO: U-2888, Letopis Zhurnalinykh Statey, No. 1, 1949

- ---- -----
S/l47/62/ooo/oo4/oo8/oi9
E031/E113
AUTHORS: Kan, S.N., and Lipovskiy, D.Ye.
TITLE: Stability of circular cylindrica frameworks under
axial compression and transverse pressure
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy,
Aviatsionnaya tekhnika, no.4, 1962, 79-90
TEXT: This is the first of three articles. The calculations
are based on the assumption of a structurally orthotropic shell,
the force elements being-smeared out". The energy method is used
to calculate the)critical stresses and it is assumed that under
the action of the critical external forces the system has both a
straight line and a curved form of equilibrium, corresponding to
the minimum potential energy. The usual assumptions of the theory
of thin shells are made. Considering first the critical stresses
'.for the,axial form of the loss of stability, the necessary
condition for the minimum potential energy leads to a'fourth order
differential equation whose characteristic equation has roots
i (a I pi). The displacements can increase without limit if
either a = 0 or PL m1t, where L is the length of the shell.'
Card 1/3

5/147/62/000/004/008/019
Stability of circular cylindrical... E03!/EI13
From the first condition -can be obtained the critical axial
compressive stress; the second condition gives the number of half-
waves m along the generators at the loss of stability. The
transverse pressure has no effect on the critical stresses. In the
case of a non-axial form of the loss of stability, the assumption
that the cross-sectional axis remains fixed and the condition for
periodicity are used to give an expression for the tangential
displacements,and the axial displacements are obtained from the
condition that the mean surface is not displaced. Using these
relations and the expression for the potential energy of unit
length of the cylinder, Euler's equation leads to a fourth order
differential equation which has the same complementary function as
the previous equation. From the condition a = 0 it is deduced
that positive (internal) pressure increases the critical stress
and negative pressure diminishes it. The condition pL = mit
gives a relation between the number of half-waves m along the
generators and the number n of waves round the circumference at
'loss of stability. Expressions for the critical stresses may be
obtained similarly for other boundary conditions. -For the axial
form of the loss of stability the critical stresses increase with
Card 2/3

Stability of circular cylindrical... S/147/.2/000/004/008/019
E031/E113
the strengthening of the longitudinal elements, whereas in the
non-axial form it is the transverse elements which are important.
There are 3 figures.
SUBMITTED: March 19, 1962

L_~()86-6L EWT(d)/FYIT(M)/EWP.(~)/EWP(k)/Fd~.(ii) Pf-h/Pft Anw(P)IM(f)
ACCESSION NR- AP4040970 8/0147/64./000/002/0034/0046
1A
AUTHOR. povskly, D. Ye.
TITLE., Ile edge effect In anisotr6pic circular cylindrical shells under combined axial
and radial. pressures-
SOURCE' : rVUZ Avisitsionnaya 7takludka, -.no.: 20: 19649 34-46,
TOPIC TAGS: ~ 6hell cylindrical shell. a)&jnmetrIcally loaded shell, anisotropic edge
-effect, edge effect damping, stiffened cylindrical shell
ABSTRACT: The author analyzes the edge effect in anisotrople circular cylindrical
shells under uniform lateral and longitudinal pressure. A differential equation describing
the edge effect (long4tudinal variation of the radial displacement) to derived by a varia-
tional method, taking initial imperfections into account, and the edge effect in the neigh-
borhood of elastic and ri&,Id frames Is determ!ned. Expressions for the integration con-
stants for certain boundary conditions at the end supports are given in a table. The
damping of the eAlge effect distrubatice is also analyzed. Finally, the length and amplitude
of Che strain waves, the damping decremo-nt, and their dependence on the compressive
and tmiatle stresses are dis(mased. Orig. art. has! 21 formulas. 4 figures and 2 tables.
Cordl/2

L 9086-65
ACCESSION NR: "4040ri 0
ASSOCIATION: none
SUB.CODE. AS
SUBMITTED: MOW ENCU 00
NO REF SOV,. 005 OTHER: 000

C~l
!;v~- -LLgating t3irri-lifications of the equa-,.-.cr.!i of
stres.-Esd stat- and stribillity of cyli.ndrical -vhells. inzh.
5 no.3-52"-53' 165 (MIPA 18:"'

.',X4007943 BOOK' EXPLOITATION S/
Bel'skiy, Vladi-mir Leonidovich; Vlasov, Ivan Petrovich; Zayrsev,
Valentin Nikolayevich; Kan, Saveliy Nakhimovich (Doctor of Technical
Sciences, Professor);_.~.~rSo-zh'it-s.kiy, Vladimir Pavlovich; Kots,
Veniamin Markovich; j,:k2.qy.skiy, David YevseyCAF0cF
Aircraft design (Konstrukcsi.ya letatel'nykh apparatov) Moscow,
Oborongiz, 1963. 708 p. illus.', biblio. Err-ata slip inserted.
6200 copies printed.
TOPIC TAGS: aircraft construction,,aireraft scrength, aircraft
dcsian, aircraft rigidity, aircraft hydraulics, aircraft pneumatics,
aircraft servo aircraft service life, aeroelasticity, aerodyna-mic
h a a c -1. ng
PURPOSE AND COVERAGE: The book is 'intended' for aeronautical engineer,-,
co-cerned with airca f t design and,manufacture. It may also be
useful to students of technical schools'of.hig'her education. The
principles of aircraft construction and strength are discussed.: The
principles of arrangement are examined,and design methods for strengt..
-ad rigidity are given. External design loads are analyzed,,and other

A%14007943
problems in the construction of airplanes, rockets, and'helicopcers
are examined. The pneumatic and hydraulic aircraft systems as well
as hydraulic servos are described. Considerable attention is paid
to tha problems of acroclascicity, service life, and aerodynamic heat-
in. The factual and numerical data and the schematic diagrams of
aircraft are taken from non-Soviet sources. The authors thank K. A.
Ly*nsl=sky for. writing -article .3 of 'Ch. 2 and N-. yj .Mi tro-
fanov who particpated in selection of material for some chapters.
Spacial appreciation is expressed to A. M. Okulov for illustrating
the b o o k a n d t o Doctors of T echnical S ciances A. R. Bonin and
Professor L. P. Ninokurov and Candidates of Technical Sciences N. G.'.
Savusya, L. A. Kolesnikov, A. A. Yarkho andyV. P. Rusanov for their ~
valuable suggestions during the review and revision of the manuscript.
TABLE OF CONTENTS [Abridged];
Foreword -- 3
Introduction 5
Card 2

AID Kr. 967-13 15 MaY
COMBINED COMPRESSION AND FLEXURE OF STIFFENED CIRCULAR
dYLJNDRICAL STIELLS (USSR)
Kan, S. N. , and V, Y &_LJyDygk& Izvestiya vysshikh uchebnykh zavedeniy.
Aviatsiomaya tekhnika, no. 1,' 1963, 33-47. S/147/631000/001/0051020
The states of stress and strain of circular cylindrical shplls stiffened by
stringers and rings are analyzed. The shells are subjected to transveriml
loading combined with axial compression uniformly distriouted along the
faces. The effect of manufacturing imperfections of the shell's middle sur-
face is taken into account. The problem is discussed in a linear formulation
under conventional assumptions of the theory of el*stic thin shells. For so-
lution of this statically indeterrnihatt Problem. Kan' a method, -eniploying energy
principles and structural- mechanic4 techniquito6ja used. .*T4p axially Ifynunetrical
and asymmetrical states of stress (caused by axisymmetrical and arbitrary
loading, respectively) are investigated, and formulas for the critical (buck-
ling) load, radial displacements, bending moMents, pnd longitudinal and cir-
cumferential stresses ate derived. The behavior of shells under arbitrary
Card 2/2

AID xr 967-13 15 XaY-
COMBINED COKMSSIOK (Cont'd] 6/14V63/000/001/005/020
is shown in dia grams for various rigidity parameters. A numerical
samp..e calculation is presented of a simply supported stiffened shell under
combined uniform continuous loading consisting of axial compression on the
faces and a downward vertical load on the inner side along the bottom genera-
trix. Nondimensional stresses relative to their critical values are calculated
in the axial and circumferential directions, and their distribution ~n - c r o a a
sections is shown in diagrams for length-to -radius ratios of 5 and 10. T he
effect of manufactuting irregularities on the shell's stress'strain state and
the behavior of the -stiffen era ar e Also --dtaelits seO. JVK)
Card 2/2

BELISKIY, Vladimir Leonidovich; VUSOV, Ivan,Petrovich; Z,AYTSEV,
Valentin Nikolayevich; KAN, Saveliy Nakhimoviclidokt.tekhn.nauk,prof.;
KARNOZHITSKIY, Vladimir Pavlovich; KOTS, Venianin
yov
Markovich; IIJNV4Kr,6 Dald Yeves k,,BDNIN, A.R.t
rets -- -'I', , A.I., inzb., red.;
doktor tekhn. nauT, retsenzenT; 9wV
KUZIMINp G.M., tekhn. red.
[Design of aircraft] Konstruktsiia letatelInykh apparatov.
'LBy] V.L.Bel'skiy i dr. Moskva, Oborongiz, 1963. 708 p.
(MIRA 16:8)
(Aircraft)

'ACCESSIONTUR: AP3004719 3/0147/63/000/002/003VOM3
"'I'AUMOR: Kan,A.g.) LipMkiy,:,D. Ye,
TITIZ:'
The lload-car4ing capaalty Of stiffened thla'aircular cylindrical shells.
under c I
6mpresision.
SOURCE: IM.a Aviats.,tekhnika
A no, 2.' 1963Y 34-43
I TOPIC TAGS- load-cari-ling Capacity,, compressed cylindrical shell, stiffened
shell; thin shell, shell, critic"alstress, crushing-loaAs,initial deflectionp
manufacturing.imyerfection.,
ABSTRACT: The 'article, -which. is the conclusion of'the work or the authois
published in IVUZ..*"Avjatsio=aya tekhUika," No. 4, 1962, and No. 1, 1963,
presents a simple-method for predicting the load;-carrying capacity of a thin,
-i compressed, circular cylindrical shell stiffened by a'system or rrames and strlngersi
jand discusses.the effect of conatructiopal parameteison the shklle capacity. The
method is bas ed on the assumption that the most essential factor reducing the
load-carrying capacity~qf the shell is the manufacturing Imperfection (initial
re of a shell under axial. compression
deflection), ithich causes the stringe
..to be subjected.to a combination of oompression.and transverse flexure. The cases
Card 1/2

i'ACM310NOt 03~719,
of, exially symmetrical and. asymmetrical initial deflection are discussed, and the
formulas for critical. (crushing) stresses for stringers arapdarived, - The effect
of the In'ternal pressure and of the-rigidity of frames on the magnitude of the
critical stresses is analyzed,- Illustrative-numerical calculations of the critical
stresses and crushing load of a bhell are given for both oy*etrical and non-
symmetrical cases The possibility of extending the application ef the proposed
method to the case. of lateral loading, which is equivalent to d cartain initial
1 deflection, and to other types of deformation ~ (benUng, combined compression and
bending) of 6ells is mentioned.. Orig. art. has: 2 figures end 21 formulas.
ASSOCWION: none
IM
06Sep63.
SUBM=D: 1~~2 DM AMi
CODE: AP No RU SMI'. 005
;!Card,. 2/2

nal and lateral bending of
Izv.vys.ucheb.zav.;av.tekh.

SMOYLOVSKIY, N.;_LIPOVSKIY,_G.
Analysis of the efficiency of capital investments for the improve-
ment o? harbor facilities. Rech. transp. 20 no.5:3.1-13 My 161.
(MIU 14: 5)
1e Glavnyy inzh. proyekta Novosibirskogo otdeleniya Giprorechtransa
(for Smoylovskiy). 2. Nachallnik Novosibirskogo ports, (for Lipovskiy).
(Harbors--Finances) (Capital investments)

STAROVEROV,, Yu. (Astrakhan'); BONDARI, N. (Kiyev); NEFOMYASHCHIT V.
(L'vov); WAS HMO, A. (graimodar); ;aPqyLKIT G. '(Mlnsk~
ANALUNt A. (S'1;1~)
Editorlo mail. Okhr,truda i oote.strakh. 6 np.2s28 F 163.
(Industrial hyg*e) (MIRA 16s2)

LIPOVSKIY. G.
i-
Cut peat in an economic fuel. 920 no.6:40 Je '59.
(MIRA 12:9)
Lzamestitel, prodsedatelya, Belorueskego reepublikanskogo
pravleniya nauchno-tokhnicheskogo obshchestva bumazhnoy i
dereveabrabatyvayushchey promyshlenuosti.
(peat)

LIPOTSKIY, G.
Republic conference on automation. VZO no-9:50-51 8 '59.
(MIRA 13:1)
1. Zanastitell predeadatelya Balorue8kogo reeptiblikanskogo
pravloniya Nauchno-tokhnichookogo obahchostva bumaxhnoy I
derevoobrabatyvayushchey pror7ablennosti, Minsk.
(Wbite Russia--Paper industry) (Wbite Russia---Automation)

LIPOVSKIY. G. I.
"Iwo
I!ntnr r or/ schonl to an irstribqnt rf exchane,* of F-dvancad
motbodn and oxporif3nCep Bullopro"t 34 no.7,32 -Tl 159-
(14IFA 12'.10)
1. Zamnntitall prodeedatelyn Bolorusakogo roBpiibliknnakogo pravleni-
ya Nanchno-takhnichookago otdola burlazhnoy i asrevoobrabatyvayus-
chey promynhlonnosti.
(Whito Russia-Pap(gr influstry)

L.IPOVSKIY. G.J.
Conference on the automatic control of production processes in
the paper and hardboard industries. Bum.prom- 34 no.10:28-29
0 159. 04IRA 13:2)
1. Zam"Stitel, predsedatelya Belorusakogo respublikanokogo
pravlantya Nauchnn-telchnichaskogo obahcheatva humazhnoy i
deravoOmbotyvayushchey promyshlennosti.
(Paper InduBtry-Couffose"o) (Automatic control)
(Hardboard)

18.2000 70-05i
SOV/13o-6o-3-20/23
AUTHORS: Dorofeyev, B. A.
!-.y _(Chief
(Director),Lip &~,
2vskly,
of the Experiment _--
al and Research laboratory)
TITLE; Stone Casting for the Industry
PERIODICAL: Metallurg, 1960, Nr 3, Pp 35-36 (USSR)
ABSTRACT: In 1958 the first stone casting plant in the Ukraine
was put into oper ation in Stalino. The charge of' the
Stalino plant to made up of' M: rock--70; dolomite
dust--20; quartz sand--5-10; chromium-magnesite powder--
max 5. Chemical composition M.-
Composition of' Charge Materials M
Components S102 A1203 FeO 4. Fe2O3 CaO Mgo Others
Rock 50-54 20-25 9-11 2--4 3--5 5--6
Dolomite 9.8 3.8 2.3 50.2 31.5 2.4
Sand 97.40 0.13 0.39 1.44 o.4o 0.24
Card 1/4

Stone Casting for the Industry 70-051
SOV/130-6o-3-20/23
The new charge and the technological process were
developed by engineers A. I. Sibilev and N. A.
Bukhavtsev in cooperation with the authors. All raw
materials except rock are precrushed before delivery to
the plant. Rock is crushed before charging. The melting
period in 1-1.2 ton coke-fired furnaces varies between
2 and 2.5 hr at 1,450 0 C. The plant specializes in the
production of 185 x 115 x 20 mm plates used for the
lining of various bins and conveyers of ore, coke, sand,
etc. The plant also produces 1,200 mm long pipes
(150 and 190 mm d1am) and 250 x 250 x 40 mm plates.
At present the plant is trying to introduce ball mill
linings and balls as well as insulators and intricately
shaped plates. The plates are cast In heat-resistant
steel chill molds and crystallized-in a muffle furnace at
950-1,0000 C. Final annealing In a Lehr furnace takes 14
hr. Tempevature of 8he finished plates as they leave
the furnace is 50-60 C. Technical characteristics of
Card 2/4 stone casting at the Stalino plant are:

Stone Casting for the Industry
78051
SOV/130 _60-3-20/23
Specific weight (g/CM3
Volumetric weight (g/cm3)
Oxidation resistance (according to State
Standards GOST 475-53) M:
in sulfuric acid
in hydrochloric acid
Abrasion resistance (g/cm2)
Mohs' Scale hardness m2):
Mechanical strength (kg/c
compression
bending
tensile
Water absorption M
3.08
2,8-2.9
99-~5
99. 4
0.03-0.o4
8-8.5
to 2,500
6oo
150
0.01
Heat resistance is determined 8y heating specimens to
1000 C and water-cooling at 18 C, and equals 7 to
Card 3/4 lotemperature changes.

Stone Casting for the Industry 78051
Chemical Composition of Casting M
Sio2 A1203 CaO Mgo FeO + Fe203 Na20 +
45-49 18-20 10-13 8-10 8-9 2-2.5
Structure of the stone castings Is dense and uniform.
Hardness and abrasion and oxidation resistance indicate
the applicability of these castings in numerous fields.
The authors recommend their use in roller-type screening
machines, working wheels, and bodies of sand pumps, etc.
The troughs and bins at the new Krivoy Rog Beneficiation
Combine (Novokrivorozhskiy obogatitellnyy Icombinat) are
lined with cast stone plates. Cast stone pipes are
used at Chumak6v Central Beneficiation Plant (Chumak-
ovskiy TsOF), Mironovo State Electric Power Plant
(Mironovskaya GES), etc. The economic advantages as a
result of the application of cast stone parts are tre-
mendous: The life of the equipment increases from 5
to 10 times and thousands of tons of metal are saved.
ASSOCIATION: Stalino Stone Casting Plant (Stalinskiy kamneliteynyy zavod)
Card 4/4

DOROFETEVP V. A,, inzh.; IqOVSKIY, I. Yo., Inzh.
Use of cinders from electric power plants for stone caB ting.
Energetik 10 no.8:12-14 Ag 162. (MIFLA 15; 10)
(Stone, Cast)

LIPOVSKIY, I.Ye.., inzh.; NASIELISKIY, A.,M., inzh.
Investigating the mechanical strength of cast stone at high
temperatures, Stek. i ker, 22 no*315-6 Hr 165.
(MIRA 18210)
1. Donetskiy kemneliteynyy zavod.

DOROFEYEV, V.A., inzh.; lnzh.; KORABLIN,, V.P.,
inzh.; KHANp B.Kh;, kand. tekhn. na-~k
Obtaining stone c-dotings of amphibolites. Manhinostroenie
no.1:38-41 Ja-F 163. - - (MIRA 16:7)
1. Dometakiy kammeliteymyy zavod (for Dorofeyev,, Lipovskiy).
2. InBtitut liteynogo proizvodstva AN UkrSSR (for Korab3in,
Khan).
(Amphibolite)

___ -- I- ~ I - __ - - -
.LIFOV5KIY,I_L_. I'l-
and--afi'drs
"A Yethod for Measuring Resistance of Oxide Coatings in Receiver
and Amplifier Tubes," pp 3-11, ill
Abst: A method is examined for measuring the impedance of a layer of
oxide coating, that is, the entire series of three layers. The applicability
of this method is shown for various types of tubes with oxide cathodes from
the viewpoint of reliability of measurement and most rational conditions of
measurement.
SOTTRCE: �hgr. ~Iaterialov Po Vakuumnoy Tekhnike Goa. Soyuzn. Ordena Lenina
Zavoda (A Collection of arterial in Vacuum Technology of the State All-Union
Order of Lenin Factory), No 13, Moscow-Leningrad, Cosenergoizdat, 1057
Sum 1854

KOSHMKOV, R.Y.; LIPOVSKIY: L.S.
New pressure eA~-twzk- equipped truck ZIS-136A. Avt.trukt.prom. no.8:22a-b
Ag 153. (KLU 6:8)
(Hotor tmolco)

LIPOVSKIT, M., kand.tekhn.nauk; NIKIFOROV, Yu.Ye., inzh.; SPIVAKOV, M.S., inzh.
~'-. ~-. 1.
For further lowering of the weight and construction costs of apartTent
houses. Biul.tek-h.inform no.1:6-8 Ja 159.
(. 5 (KIRA 12:4)
Precast concrete)

K U.' -11 F". VI N. V. 0 ! , 1, 1" i ~~ .
c-l' tna~ Y~3rt .ice] of f ' gas. Geol. rpft'.
u,"
I gaza 8 )or lb4l. (PTRk 17,W~
1. lJ!zhnp-Vo*l-,'tskjy llratltu,; gec~jcgj!
1 Peuf! ?~ki.

LIPOVSKIY, M.A.
,C; V-::~,-_-_______ _,", - D
Sulfate-ion determination in natural waters by amperometric titration.
Trudy VNIGNI no.11:273-277 '58. (MIRA 13:1)
(Water--Analysis) (Conductonstric analysis) (Sulfates)

---- 'LI.POVSKIY, M.A-
Thermodynazide basis of regularity in the distribution of oil
and gas fields. Geol
,* ne f,t,i i gaza 6 no. 1: 18-23 Ja I ~~
(M 15:1)
1. Nizhne-Volzhskiy Nauchno-issiedovateliskiy institut geologii
i geofiziki.
(Petroloum geology)
(Gas, Watural--Geology)

LIPOVSKI, M.A. (Lipovskiy, M.A.)
Thermodynamic substantiation of the laws governing the distribution
of pertrolam and gas deposits. Analq~e geol geogr 16 no.3:67-72 JI-Ag
162.

L 2177~46 EWT(d)/EV1P(h)/E%'1P(1)
G
A
C NR: AP6002597 SOME GODZs UR/0286/65/000/023/0093/W93
Ale
AUTHORS i Lipovskiys_~~:~!~ Karelin., A.. K.
ORO: none
TITLEt Vertical vibrational conveyer. Class 81, No. 176820
SOURCE: Byulleten' izobreteniy i tovarnykh znakov., no. 23, 1965s 93
TOPIG TAGSt. conveying equipment, conveyer transportation system
ABSTRACT: This Author Certificate presents a vertical vibrational convey.. lor
transporting friable materials, It consists of a load-carrying unit in the form
of a tube with a bottom,, loading and unloading devices, and a vibration drive*
To provide for the transportation of materials in a smooth tube by only the
longitudinal vibrations of the tube, the loading device is in the form of a feed
tube placed inside the load-carrying unit. One end of the tube is mounted
coaxially with the load-carrying tube with a gap between the end and convex totton
(see Fig* 1)e The other end is brought out through the side of the load-carrying
tube into an annular hollow under a loading hopper and is fastened between the
external surface of the load-carrying tube and two truncated cones* The larger
UDG z
_Card 1/2 621*867*522*2_1

-L 21773-66
AGG NR a AP6002597
1:0
0 V
A .0
C:
z A
bases of the truncated cones are connected t6gethers and the smalliw-4o the load-:
I carrying tube. To increase the transportation heightp the load-carrying tube is
made of several sections rigidly fastened together, each having a convex-bott
om
and feed tube. The annular hollow is used to transfer Mterial from one section
to another, Orig., art, hass 1 diagram,
suB cous. 131 suBm Dust lWg63
LI

HAMNSTNIKOV, Alakeandr Fedorovich. kand. takhri. nauk; BELOUSOV.D.P..
in2h.-, VOLKOT.Ye.B.. kBnd.takhn.nwik; LIPOVSKIY,14.S., inzh.;
SAYZDARG.Y.N., red.; BALLOD,A.I.,
[Collective-form cannery] Nolkhoznyi koneervnyi zovod. Mo-
skva, GosAzd vo sellkhoz.lit-ry. 1959. 275 P.
I (MIRA 14:5)
1. Houchno-iseledovatellskiy institut konaervnoi i ovoshche-
sushillnoy promyshlonnosti, Moskva, Novoslobodskeya, 7 (for
Xsmestnikov).i 2. Gipropishchoprom, Butyrskiy val. 68 (for
Belausov)
(Conning industry-Equipment and supplies)

LIPOVSKY, Pavol-
How we produce larp shall corets. Slovarenstvi 12 no.5.,190L-191
0
My 164.
1. Zavody Jana Svermy, Brno.

18(517) SOV/135-59-9-le/23
AUTHOM: Balkovets, D. S., Doctor of Techpical Sciences and
Lipovskiy, P. I., Engineer
TIME: Moscow Oblast Conference of Welders
PERIODICAL: 3varochnoye proizvodstvo, 1959, Nr 9, pp 43-45 (U33R)
X3STPUM: The Oblase Conference of Welders was convened in Moscow
from I-larch 18-20. The results of scientific and pro-
duction worl: in 1950U were discussed at this conference.
The conference was convened by the Welding Section of
YONITOMASh. More than 400 representatives of different
organizations in Moscow =0, the Moscow oblast , as well
as represc-tatatives from. Leningrad, Chelyabins'le., Penza
and other places pLrticipatea in the conference. It
was opened by the Corresponding Member of _A~; USSR 11. 14.
Rykalin. 47 reports ~Vlere heard and discLissed at the
conference. A. A. Vikhirev and S. S. Gudimen1ho spoke on
welding problems in the Moscow area. 11. A. Ollnhaiishiy
(I;IVTU) spoke on welding by electronic ray in vacuum, and
the same ther,'ie, was discussed by 11. 1"'. Ryl?.Llill, A. A.
C ard 1/3 Yerokhin, L. L. Silin and V. A. 1'\.uznetsov (IMET). V. D.

SCAT/135-59- 9-18/23
lfoscoT,., Oblast! Conference of Welders
Kodolov (D-W) spoke on arc and "electric slag" welding
and I. D. Kulagin and V. A. 1_11ikolayev (IIIET) discussed
metal processing ~~ethods. This %,-as also the thet,e of a
report by K. V. Vasil'yev. The weldability of molybdenLun
was examined by A. I. Pagin Lind 11. Kh. Shorshorov. A. S~
Gel'man wid M. P. Sandlur M1,111ITIL-'Sh) discussed welding
of large diameter pipes and R. 1. Zahson and V. D. Voz-
nesens1dy (NI ITMaTUROSEL I KhOMASh) examined automatic
welding methods. Improved weld quality was the theme of
N. 14. Novozhilov and A. M. Sol-.olova (T&1-,'I1TMASh). V. 11.
Suslov ".TsNIITMASh)_-ejY)rted on semi-automatic welding.
K. V. Lyubavskiy, V. 1.I. Nihitin and G. F. Murov (MV14I)
spoke on automatic welding Nrithin CO-) of prc-hardened
devices of .3OKhGSA steel. A. V. Petrov (ITIAT) spoke on
autorziatic welding of thin, heat resistant steel irithin
argon. V. V. Kudinov (WTHAVTOGEN) reported on a manual
burner E3R-3-58 for argon welding. Ye. V. Vasillyev
spoke on a new electro-riveter. Automatic flux welding
was the theme of -11. P. Yemel'yanov and F. S. Tkachenho
Card 2/3 MNIIMPS), as well as of It. I. Sorokina WWI), 3. 11.