SCIENTIFIC ABSTRACT LISITSYA, M. P. - LISITSA, M. P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000930110013-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

N
KOMILEM, -I. I
A new high-brightness hydrogen lamp. Nauk. sap. Kiev- u-no
13 u&.7,.131-143 155. (MULIL q..
(Elydrogen--Spectra) (Blootric lamps, Are)

USSR/OpticH - Physical Optics., X-5
1
Abet journals Pieferat Zbur - Puna, No 12, 1956,t 35791
Authcws Lisitna., M. P., -SIdshlovskiy, A. A.
-Instituticms None
Title: The Calculatiou.. Preparation and Investigation of a Polarization
Pile
original
Periodicalt Nauch. zap. Kiivafk. un-t, 1955,, 14, mo 8, 141-157
Abstract: A t3wory is given for a miLtilayer polarizer consisting of any
number (m) different non-absorbing thick plane-parallel layers.
A separate analysis "van for the case of identical absorbing
layers. Equations are obtained for the intensities of the.light
beams, reXlected or transmitted through the multilayer pile., and
equations are given permitting calculation of the degiie of
polarization (Pdm) in the absence of aboorption,,using a glass
pile as an example. Its suitability is shown for all the working
range of angles p.. The folloving results are obtaineds
Card 1/2

USSR/Oktica PhYsical Optics, K-5
Abst Journal: Referat Zhur - FizikEL.,-No. 12., 1956., 35T51
-Abstract: (a). In the Tange 0 4C 11*/Vd~ there is a maxim=,, the position
of vhich abifts as m increases oward the region of smaller
anglesj as m becames infinite it corresponds to the Brewster
angle. (b) At 9 - -1T/2 we obtain Pd. = const, regardless of m.
Tbevalue of Pd~ is determined in this case only by the index of
refraction n. It is shown that the degree of polarization de-
pends substantially on the absorption, leading to-an increase in
Pdm. Investigation of oeleni= p:Ues (m a 1., m V 4) absorbing
in the visible portion of the spectrum (A = 589 *), led to re-
oults that are in good agreement with the calculatediftta. The
authors propose that -the established dependence can be used to
measure the absorption of solid isotropic substances. A de-
scription of the tecbnology of preparing a selentum.pile., in-
tended for polarization of infrared radiation, is given.
Card 2/2

XMIJJXXO.1.1.; LISITHA.M.P.
"amoesu-I'M40 Mr-I
A now Intense-14;ht hydrogen lamp. Izv. AN SSSR. Ser. f is. 19
no.1:87-88 Ja-Y 155. (MM 8:9)
1. Xafedm eksperimentallnoy fiziki i optiki liyevskogo gosudar-
strennogo univeralteta, imeni T.G.Shevchenko.
(Spectrum am] is) (Spectrometer)

USSR/Optics Photometry. Colorimetry. X-10
Abs Jour Referat Zhur - Fizika, No 3, 1957, 8077
Author Kondilenko, I.I., Lisitsa, M.P.
Title New Hydrogen Lamp 15flf-di Brightness
Orig Pub Zh. tekhn. fiziki, 1955, 2-5, No 7, 1316-1322
Abstract Description of the construction, technology of manufactu-
,re, and test results of an hydrogen arc tube of low pres-
sure. The cathode is a nickel hemisphere 15 mm in radius.
Its internal surface is covered with oxide. Heating is
indirect. The electrons emitted by the cathode are inci-
dent on the anode through an opening 3 mm in diam ter,
made in the center of a molybdenun disk, tightly covering
the cathode hemisphere. The anode is made of a molybde-
num plate in the form of a saucer with an opening in the
middle (diameter 5 M), which is attached to a nickel '
ring. The maximum discharge current without water cooling
Card 1/2 - 128 -

YSSR,/Optics Photometry. Colorimetry. K-10
Abs Jour Referat Zhur - Fizika, No 3, 1.957, 8077
is 17 amp, and the current density is 240 amp/cm2.
The most favorable hydrogen pressure is 1.6 -- 4.2 mm
mercury. Increasing the discharge current causes the
radiation intensity to increase linearly, and the ener-
gy distribution over the spectrum remains constant.
The dependence of the discharge current and of the volta-
ge drop across the tube on the change in the hydrogen
pressure was investigated. In the pressure range bet-
veen two and 1;2 mm mercury the tube operates as a rec-
tifier. Increasing the pressure decreases the differen-
ce between the firing and arcing potentials.
Card 2/2 129 -

LISITSA, mop. Clj"Ttsia, M.P.]; SHISHWVSKIY, O.A. [Shyshlovalkyi. 0.A.]
Speotrophotometrio method for determining the polarization degree
of alloys. Nauk povid. KW no.1:21 '56. (MIRA 11:4)
(Alloys--Spectra)
(Polarization (Light))

LISUSY1. H.P,:._~H:1SHLOVS1KIY. 0.A.
Concerning certain characteristics of Interference light filters.
Nauk.sap.Kilm.un. 15 no-5:3-3-18 56. (MLRA 10:7)
(Light filters) (Interference (Light))

D:EKARS I'Lly 9Th,S.; LISIT~/A, M.P.
Zffect of interference on the polorization properties of multi-
layer films, Hauk.sap.Zley.un, 15 U0.5:19-26 '56. WRA 10:7)
(Interference (Light)) (Polarization (Light))

LIS!::AhXA&U*TSVILYKH, N.G.
Interferential microscope for measuringthin coatings and the
phase shift* Zave lab, 22 noo9slO72-1073 136, (MLU 9:12)
1, Kiyevskiy-gQoudarst4enrwy-.?4niversit~st imeni T. G. Shevchenko.
(Interferometry)-(Xioroscope) (Metals-Testing)

_~77,71
IT

r
Pa1K 14 ~40. F
24 3 PHASE X BOOK EXPLOITATION SM/1365
yNaterisly I Vsesoyu2nogo s*va9h&hxnJy& Vo apelctrookovIl. t. I
X61*kUlyarwa spektroak.-'~piya (Papers of the 10th All-ftion
Conference on Speetrucop7. VOX. It V41acular SPect"OcOPY;
(L-voy) Izd-vo Ltvovskoso jrAly-ta# 19 a
In@ 499 po 4 DOD oopie
printed. (3erioss Itst Visyclwy a rayk, vyp. W)
Additional Sponsoring Agenoyi Aksdemlya nauk SSSR. Komissi7a po
spektrOokopil. 34.a Oster, 3.L.) Tech. Ed.$ SarAnyuk, T.Y.,
Editorial Board- Lan4sterg G.S., Academician (Reap. W.. Dace..d),
Noporent, B.B.,'Doot" or hx;aioal MA Hathoutatical sciences,
Fabellmkly X.L. Doator of Physical and Mathematical Sctenc4a,
Y&UrUmt, M.. boator or Physical and Mathematical Sciences.
KormitaUU, V.G., CuAidate of Technical Sciences Rityakly, S.M.,
CUAIdete of Ph7sical &M Mitthazatical Sciences, faiswitkiy, L.K.,
Candidate or *Sioal And Ytat.14ruttLeal Sciences, Hillyanchuk, V.S.,
Candidato of Ph.79i"! " Mathematical Sciences and 01suberaw,
A. Yo., Candidate of nqsioil wd Mathamt1cal 141*11404.
CAM 1/30
Sp*atrophotamtrlo Study of the
r4apersion wA Absorption of Solids 97
Fodlorchooko, R.I., and N.M. SuWhohinskiy. Use of
RleatronL4 Clap-tere fo- %he Calculation of
Frequencies of Wle4alar Vibraticqs 99
Petrash, O.G., S.D. Rautlan. Accuracy or the
M11surmwnt of Optioal Dawdty 102
Rsutl44 3.0. 0.Q. htrash. Auuraoy JA $cgouring
the ka;;;;~AbsoW.Ion Lima While naudiva the
Apparatus lhmtioA IC7
Voll4hkl=. T.3., L.P. Mikheysya, am LA. Yak.,zey.
Molecular Dispersion of Light VwdrC Phase Trano.-
foruatiou in Solids III
Ginw4m, V.L. Scattering of Li4ht Xsar the The".
transition rointe
Card a/ 30
777777-.

1 4
AUTHOR: Lisitsa, M.P. and Shishlovskiy, A.A. 51-5-14/26
TITIR: Polarisation of Light Reflected by a Pile (of Glass Plates)
(Polyarizatsiya sveta, otrazhennogo stopoy
IODICAL: Optika i Spektroskopiya, 195?,, Vol.2 lio-5.
pp.637-644 ZUSSR)
ABSTRACT: The dbgree of polarisation of a pile of m plane-par4lel,
glass plates, e;;ch of a r~raotive index n is given by:
2 1;
--a(n7- - 11 sin tp cos(p (4)
&u2 y2 + < a W)2 2 2( )2
cos~p - a c0 Al a. c0 stp + M(n c0 8(P - a) W. 0 s(P
where (p - the angle of incidence and a n2 _ sin 29)1/2
.-A pile of plates is used since only about ?% of the incident
light is reflected by a single plate. The incident beam is
usually divergent, so that only axial rays can be made to satis-
fy Brewster's condition for complete polarisation:
n
7'7~ 7"
sin 47 + COO T - 477 7
For the above reasons, it is of interest to find the depend-
Oard 1/3ence of P- on m, and n

51-5-14/26
poja:risatioU Of Light Reflected by a Pile (of Glass Plates).
11 s consisting
2 show dependence Of P or, p f or 1 e ~ 11
pigs. 1 and plates (1113. In Fig.
Plates (II) and 10 ical value)-
of 1 plate ~I)j 3 in pig.2 n = 2.92 (a theoret rowing
n = 1-516 (glass); that an increase of m causes nar
These two figures show
of ~4(p I the ranaii of incident angles at which maxima of P
occur. Increase of the refractive index W makes this effect
Of m On A&y very pronounced. Fig-3 shows ood agreement
between the experimental values (dashed curves5 and the theor-
;'..._etical ones (continuous curvea) for m = 1, 3 and 10, respect-
~-.--`ively. The authors studied the way in which in a single plate,
Ilections into sec-
the incident ray is broken up by multiple ref
I.onqq,:ry rays. The number of these secondary raysjk9.!~epdnds-on the
plate thickneBS, its length and the angle of incidence of the
original ray. The effect of - k on polarisation P in a
singl late is shown in Figs. 4 and 5. Fig. 6 shows calculated
P =eR~p) curves for a five-layer pile of selenium (n = 2.42
in infrared);~ curve III is calculated from eq. (4) on p.63?,
which includes the effect of all the secondary rays; other
curves (I - III IV - VIII) take into account only selected
secondary rays. Fig. ? shows dependence of polarised-3ight"
intensity on (P for the same selenium pile; curve I includes
Nard 2/3 the effect of all the secondary rays, 11-V only some selected
Polari8ation of Light Reflected bY a Pile (Of Glass Plates). 51-5-14/26
ones. A student of yj7ev University, V.A.
experimental work.
There are 7 figures and 1 Slavic referenc Andrey'evs:helped in the
ASSOCIATION; e.
KiYev State University (Kiyevskiy Gosudarstvennyy
Universitet).
I -
SUBMITTE.D:
AVAILABLE: September, 25, 1956.
V.ard 3/3 Librax7 of Congress.

I -S, i T-s am -
'AVTHORt Lisitsa..- and Tsvelykh, N.G. 51-5-23/26
TiTIZ: Thin-layer Optics (Optika tonkogo sloya) I.' Phase Shift
on Reflection of Light from Thin Films of Silver, Germanium,
Tellurium and Selenium. (I. Sdvig fazy pri otrazhenii
sveta ot tonkikh plenok sertibratgermaniya, tellura i selena)
PERIODICAL: Optika i Spektroskopiya, 1957, Vol-2, fio-5,
Pp. 674 - 676 (USSR)
ABSTRACT: By thin films, the authors understand transparent or non-
transparent layers whose properties depend on their thickness
and differ from the properties of bulk samples.-, This paper
studies quantitatively the phase-shifts of the reflected light
for films of silver, germanium, tellurium and selenium when
the thickness of these films changes. The phase-shift 6 was
studied on wedge-shaped samples. The samples were prepared by
deposition in vacuum on glass plates. Purities of the materials
deposited were as follows: silver - 99.98%, tellurium - 99.7%t
selenium - 99.5%. The purity of germanium can be inferred
from its besistivity which was 50 Q.cm. The phase-shift is
meas-ired by the method described in Ref;79 Results are shown
in Figs. 1 (silver), 2 (tellurium~,3 (9 rmanJum) and 4 (a elen--
ium). In the figures, the thickness d is giyen in All
Card 1/2these results refer to reflection of the 5464 1 wavelength.

51-5--23/2b
Thin-layer Optics I. Phase-shift on Reflection of Light from Thin
Films of Silver, Germanium, Tellurium and Selenium.
Comparison of the four figures shows that in each case, at
the lowest thicknesses, there is a phase-shift minimum. In
addition to that minimum, there is at least one maximum of
phase-shift for each substance. Silver differs from the
other4three semi-conductIng substances by reaching a value
6 . 1.24 at ahout 100 A and this value does not materially
vary,with further increase In thickness. Semiconductors, on
the other hand.. show further,minima and maxima in t1ke phase-
shift with inereaae-in thickness.. These differences may be
re. ated to the structure of the films (it is Imown that
silver and tellurium films are crystalline, selenium and
germanium are-ar4orphous.), The results quoted in this paper
are not sufficient for firm'co.nclusions on this point.
There are 4 figures and 1~~,references., of which are 34avic,
ABSOCZATION: Kiyev-State Uhiversity (~Kiyeyskjy G6sixdar*stvennyy
Uni*ersit
SUNITTED: Januaiy 7s" 195T
AVAILABLE: Library orf Congrpas
.Card 2/2

75W I/ /I
120-3-13/40
AUTHORS: Lisitsa, M.P., Malinko, V.N.
TITLE: Ojiantitative Spectral Absorption Studies of Liquids in the
Fields of Strong Vibrational Bands (Kolichestvennyye
spektroabsorbtsionnyye issledovaniya zhid-kostey v oblastyakh
intensivnykh kolebatellnylch polos)
PERIODICAL: Pribory i Tekhnika Eksperimenta, 1957, Nr 3, pp-52-54
".' (USSR)
ABSTRACT: There is not much information on the infrared absorpt-
ion of liquids, particularly in those parts of the spectrum
where the coefficient of absor-otion, k , reaches tens of
thousands cid-L . This is mainly due to experimental diffi-
culties ivhich occur when one tries to use the law
I =;I 0 exp(-kd) directly. Already at k = 104cm-1 d is
of the order of a It for kdr-il. No one has managed to ob-
tain such small thicknesses. In the present paper a possible
way of removing this difficulty is considered. If the ab-
sorption of the liquid is large, then, instead of a contain--~
er of the usual type, it is possible to use one which does
not include spacers, i.e., the thin layer of liquid is held
between the plates by surface tension forces. Such a meth-
od has already been used in transmission measurements (Ref.
Card 1/2 3). By regulating the degree of closeness of the plates it
u

12r)-3-13140
Quantitative Spectr4l, Absorption Studies of Liquids in the Fields
of.Strong Vibrational Bands.
C2
is easy to change the thickness of the layer. Furthermore,
the effect of reflection must be excluded. This method was
used to obtaJ.n -the absorption curve for liquid CC14 near
12 ji The thickness of the layer was varied between 0.5 -
1.5 11 Results of measurements are shown in Fig.2. The
curve --onsists of two components with maxima at 762 and
784 cm-1 . ..'The splitting is equal to 22 cm-1 and is due to
Fermi resonMice. There are 2 figures and 8 references, of
which 1 is Ibissian, 5 English, 1 G~-rman and 1 French.
ASSOCIATION: Kiyev .3tiate University im. T.G.Shevchenko(Kiyevskiy
gosudarstvevmyy universitet im T.G.Shevchenko)
SUBMITTED: December 3, 1956.
'~f Cotgress.
AVAIL~,BLE; Library 0
Card 2/2 1. Liquids-Infrared absorption-Analysis

Spectrophoiomtka azii3ysix of disperkon and absorption by solid
substances; 71se abore no,3.197-98 157e (MIRA 3.118)
1. Kirevskly gonuaaret*e Itat im. T.G. Shevohsn)~o.
(Absorptimap=Vrea") (GypoVA-4eatra)

5 7-_~ A2 1-92
61-3-14/14
AUTHORSt M. p. and Malinko, V. N.
.~An-.Ints.rferenee-eum-GraphioaI Method of CaJ~ibration
of infrared Priam Spectrometers. (Interforentsionno-
grafieheskiy.metad graduirovki infrakrasnykh prizn;ennykh
sp~~ctrometrov,)
PERIODICAL: Optika I Spektroskopiya.- 1957,, Vol.III,, Nr.3,, PP0294-296.1.
;�R)
ABSTRACT: tf' a-.suffioientl --thin plane-parallel layer of a
transparentor wevkl
, y,abs6rbing substance'implaced In
opt .0f.,a 'spectrome
fi ter slit.. interference. bands are
obtained in the continuous spectrum of the light source.
A' layer or. air, is suitable-, for calibration of infrared
The authors:show.-that the order N' of
the interference maximum observed is proportional to the
wav -number V Us'ing known emission or absorption
speotruta,up;to 10 points are found on the straight line
N.1i T4is st*aight line can then be extra-polated
C
-in both directions (see Fig,2). Since to each maximum
Card 1/2 there corresponds a definite pouitlon of the spectrometer

'70
AUT-ii~,A-.A Lysytsya, M. P.
TrITE: '10-er-manium polari-zers. I
SlOr-8162)0'00100610461136
A061/A101
PMIODICALt Referativnyy zhurnal, Fizika, no. 6, 1962, 11, abstract 6089
("Visnyk Yvyivslk. un-tu", 1958, no. 1, ser. fiz. ta khimiyi, no. 1,
9 - 14, Ukrainian; Russian summary)
TM-i A combined polarizer, in which each component consists of a three-
layer Ge-Si-Ge film, is described. The theory of this type of polarizer is
kriven, and the results of an experimental study of its optical characteristics
are presented. It is shown that three films are perfectly sufficient for the
full polarization of the light that has passed through. Thus, the polarizing
qualities of the new device are better than those of a selenium pile which is
the most widespread polarizer of infrared radiation. A distinguishing feature
of combined films is their greater mechanical strength as compared with selenium
:films. However, they fall behind the latter as to transparency.
Abstracter's notet Complete translation]
Card 1/1

AUTHORs
TITLEs
S/058 6P,/0')!/047/136
A061 A101
YA
Germanium polarizers. II. Mirror polarizers
PERIODICAL: Referativnyy zhurnal, Fizika, no. 6, 1962, 11, abstract 6090
("Visnyk Kyyivstk. un-tu", 1958, no. 1., ser. fiz. ta khimiyi,
no. 1, 15 - 22, Ukrainian; Russian summary)
TEXTs Some designs of new rigid polarizers made with Ge are described.
The best characteristics are displayed by polarizers of the interference type
operating on reflectioncr transmission. The most accomplished design of a re-
flecting polarizer consists of two mirrors, whose reflecting elements are pro-
vided by thin Ge layers (d - 1,100 R), applied to a rock salt backing by evapora-
tion in vacuum. This system is characterized by high light-gathering power and
by a degree of polarization that practically attains 100%. About the same char-
acteristlas apply to the most efficient interference polarizer, which operates
on transmission. It consists of a plane-parallel rook salt plate, either face
of which is coated with a thin Ge layer. All calculations and measurements of
Card 1/2

S/058/62/~/006/047/136
Germanlimn polarizers. II. Mirror polarizers A061/A101
optical characteristics are performed for the Brewster angle, Part I see ab-
stract 6089.
[Abstracter's notes Complete translation]
Card 2/2

LISITSA, M.P. [Lyaytsia, M.P.]; MALIIM, V.H. [Nalynko. V.M.1
Effect of aggregate state an the intensity and structure of certain
iisorption,bands of carbon tetrachloride in the -presence of hrmi
resonance [with sumrAry in English]. UkT.fiz.zhur. 3 no.4:482.--ITUWQ,17
JI-Ag 158. (MIRA 11:32)
1. Kiyevskly gosudaretveuyjyy universitet.
(Carbon tetraeblorlde-Spectra) (Molecules)

I-- 4-_~-*14/30
-1
AUTHORS: Lisitsa, M.P. az_id T~.-e';-vkh IT.G.
TITIN: optics of Thin Films. II. Pr-Dpeities of Tellurium.
~Optika tonkc-go sloya. II. S-,rcj -a tellura.)
PERIODICAL': Qptika i Spektroskopiya., 1958, VoIXT, Nr."7,,
pp. 3"3-377 (USSR)
t
-ellurium were prepared (by evaporation on
ABSTPACT: Films of 4V
glass plates) as wedges whose thi-,kness -zariea from
0 to 1000 A. The authors obtla-_;-ed cur-,i-es of
variation of the ccefficients of refl-.c-uion R (on the
air-film side) and R1 (on the glas----.film side), the
transmission coefficient T, the real (n) w-A
imaginary(K) jams of "he coup-.1ex refractive index,
with change of the film thickness d. Measurements of
the reflection coefficients R and R7 and of the
transmission coefficient T were made using a mono-
chromator UM-2. A silver-wilphide photoalement was
used as the receiver. Measurements were made on
freshly prepared films (up t-o one day old). The
transmission coefficient, T was meas-ured with an error
of 3yo. The errors in measurement in R and R1 were
Card 113 2 - Q/1 16. Calculations of n and K were made following

-1- 4 -7-14/:io
Optics of Thin Films. II. Proper-ties of Tellurium.
the Abeles method: from three measured (~uantuities T,
R and Rt three unknowns r-, K and d are f ound.
Fig.1 gives the rariation of the coefficients T, R and
RI with thickne ss d. Fig-2 gives the -jarf;-.ation of
T and R with th4--laiess d at three wavelengths:
700, 560 and 460 M4-,. Figs-3 and 4 give the depend-
ences of n and of on film thickness d for the
same three wavelengths as in Fig.2. Fi 5 and 6 give
the dispersion (dependence on wavelengthFoof- n and
for various film thicknesses from 45 to 370
Fig.? gives the absorption of enereZr (in %) by
tellurium films as a f~anctior. of fila thickness. From
the results obtained the authors nake the following
conclusions: (1) oa depositilon of tellurium on E;lass
at room telpera-f-. hous film is ftimed up to
bure, an amorp
about 30 X; (2) vrith increase of thickness the amorphous
phase is transformed into fine-grain ci-jstalline structure
with grain size increasing with increase cf filr, thickness;
this does not oontrad1r,,t con,31usions from elle,.,,-trical
properties of tell7ariuix fillas and of elef.,;tror- diffraction
Card 2 3 and electron nicrosc-.)pq ix-ve st, i gat ions; (3`4 separate

-'~-14/30
Optics of Thin Films~ II. Propexties cf Tellul un.
ains jo-In up to form a continuous film at about 400 1;
resonance effeots are observed in. optical character-
M
istics of thin films of telluriual (5) since calcul-
ations of n and k carried out in the present paper
were based on the theory which holds only for thick
layers, the values of these quantities should be
regarded as qualitative rather than quantitative.
There are 7 fiVares and 6 references, of which 3 are
Soviet, 2 French and 1 English.
ASSOCIA.TIONiMye-v State University imeni T.G. Shevchenko.
(Kiyevsk-ly goffudarst-xenn7y -UMxVersitet- im. T.G.
Shevchenko.)
SUBMTED: June- 3, 1957.
1. T6 Uurium Mm-Properties
Card 31-3

AUTHORS: Lisitsal M-P and MalinkO, V.A- Sov/51-4-4-5/24
TITLE: requefteies and Intensities of the Infra-red Spectrum
of carbon Tetrachloride (Chastoty i intensivnosti v
infrakrasnom spektre chetyrekhkhloristogo ugleroda)
PERIODICAL: Qptika i Spektroskopiya, 1958, Vol IV ' fir 4
pp 455 - 46? (USSR5.
ABSTRACT: The present paper reports results of measurements
of the infra-red absorption by liquid C01 4 in the region of
4?Q - 12 500 em- and identification of all the observed
frequencies. For the fundamental band %~ and its first
harmonic spectra of vapours ivere also obtained. The absorption
spectra were measured using an autocollimating spectro-
photometer IKS-6 at room temperature. Precision of measurement
of the wave numbers and the absorption maxima is limited
primarily by the precision of calibration of the spectro-
photometer (see Table 1). To exclude the effects of reflection,
the measurements were made using pairs of cells; thickness
of one cell in such a pair was approximately double the thick-
ness of the other cell. Thicknesses of cells for liquid CCI 4
,Cardl/4 were between 0.8 - 1.5 11 in the:egion of the fundamental

Sov/51-4-4-5/24
Frequencies and Intensities of the Infra-red Spectrum of Carbon
Tetrachloride
absorption band tabout 12 IL) and up to 10 cm. in the regions
of very weak absorption bands. Very thin layers of CC1
liquid for studies in the regions of ver7 intense abso;#tion
were obtained by.compressing a drop of liquid between two well-
polished plates of rock-salt. To obtain the coefficient of
absorption of the C01, vapour, the aithors measured absorption
of a cell filled with gas and absorption of an empty (evacuated)
cell. In the.region of pressures used in the studies of
.vapours (up to 7 mmHg) the effect of pressure on absorption
does not exceed the experimental error. The error in deter-
of the absorption coefficient for the majority of
bands and harmonies does not exceed 7-10%. For the funda-
mental band * the error reaches 15-20% and at the longest
wavelengths, the error increases to 30%. Figure 1 shows the
absorption of OC14 in the region of the fundamental band N) 3
Curve 1 represents liquid and Curve 2 - vapour. Figure 2 shows
the structure of the long-wavelength component of Fermi
resonance doublet for gaseous CC14. Figure 3 shows the
Card2/1+

Sov/51-4-4-5124
Frequencies and Intensities of the Infra-red Spectrum of Uarbon
Tetrachloride
splitting in the region of the fundamental band N)3
.Figures 4 - ? show absorption by liquid CC14. Figure 8 shows
absorption by liquid (Curve 1) and gaseous (Curve 2) CCl 4
in the region of the first harmonic of the -~3 vibration.
Table 2 gives splitting of vibrational levels due to the
presence of OC14 molecules with difference isotopic compo-
sition and dIfference symmetries. Table 3 gives the
structure of the Fermi resonance doublet in the 750-800 cm
region for liquid and gaseous CC14 at 293 OK. Table 4
gives the frequencies of fundamental vibrations of CC14 used
by various authors in the identification of the CC1 spectrum.
The p3~esent authors use the tetrahedral model of tit CC14
molecule in identification of its infra-red absorption
frequencies. This identification is given in Table !5,
together with the results given in Refs 7, 10 and 14. The
pyesent authors obtained the absorption coefficients for all
CardVk

sov/51-4-4-5/24
Frequencies and Intensities of the lafra-red Spectrum of Carbon
Tetrachloride
the frequencies observed and for some frequencies, they
calculated the integral absorption and the band half-widths
(Table 6). There are 8 figures, 6 tables and 35 references,
20 of which are in English, 6 Soviet, 4 German, 3 French,
1 Dutch and I translation of a Western work into Russian.
-'JWSOCIATION: Kiyevskiy gosudarstvennyy universitet im. T.G.
Shevchenko (KJyev State University imeni
T.G. Shevchenko)
MMITTED: May 41 1957
Card 4/4 1. Carbon tetrachloride--Spectra

SOV/51-5-2-13/26
MMORS s Usyavskiy, V.M. and Tsvelyich, N.G.
~~SL~ a ~'M F -
TITLE: Thin-Layer Optics (Optilca ton1cogo sloya). III, Properties of
Selenium (III, Svoystva selena)
PMODICALs Optika I Spektroalcopiya, 1958, Vol 5, Nr 2, pp 179-183 (USSR)
ABSTRLCTs The paper gives results of measuremint of the reflection coefficients
and"the transmission coefficient ot selenium layer& of variolas thicLaaesses.
These layers were prepared by sublimation as described in Reg 1.
Standdrd methods of measurement of the coefficients of reflection on
tlie air'side (R) and on-the base side (RQ and the transmission
coefficient (T) were eaployed (see Ref 2). The authors used wedge-
shaped platen with 1.52 refractive Index for the sample supports.
The coefficient R, R, and T were measured only for layers produced
using a symmetrical evaporation source, but In the study of variation
'
s used. The
of the phase-shift d a spherical evaporation source va
method of determination of if was described in Ref 3. The errors in
measurement of T reached 5% and those in measurement of R and R, were
scmatimes In excess of 10%. All measurements were made immediately

Ca rd 1/3 after preparation of thW-.'layer, at fcur separate wavelength& in the
visible regions 540, 595, 620 and 700 m1i. Calculations- of n and K

Thin-IAyor Optics - III Properties of .Selenium BOV/51-5-2-1.3/26
(the refractive index and the absorption coefficient respectively)
were made using Abales I method described in Ref 4, except that tho
layer thickness d was measured independently (Ref 3). The
results obtained way be divided into -two groups. The first group
includes cf. R, Rt , T and absorption A a 1 - R - T. All these
parameters vare obtained by direct measurements and they are subject
to experimental errors only. The second group includes n and K, which
ware calculated using -theoretical considerations, and therefore
their values are affected by the approximations of the theory used.
The results are given in Figs 1-6. In all figures, except Fig 5,
the four wavelengths t 540, 595, 620 and 700 mjx are repros onted by
curves marked 1, 2, 3 and 4 respectively. Figs 1 and 2 give the
dependences of R and RI on the layer thickneas d respectively.
Figs 3 and 4 give the values of T and A as functions of d. Fig 5
gives the phase-shift d as a function of the layer thickness d for
one wavelength (546 m~L). The results obtained lead to the following
conclusions. (A.) The optical properties of selenium layers vary
Card 2/3 with thickness in a vilde range of thicknesses. (B) In the range of

SOV/51-5-2-13/26
Thin-Layer Optics. III Properties of Selenium
thicimess studied here (up to 1000 2) the coefficients R and RI
behaved similarly. This indicates that there are considerable
differences in the topography of the selenium layers at the
boundarles air--layer and layer--glass. (0) The phase-shift
dipandt on the fom of the evaporation source used to prepare the
selenium la~era'studied. The shape of this source affects the forL-.
and dimensions of the grains of which the layer is mado. (D) The
interaction of light vith selenium layers near 160 1 in thickness Is
of redonance nature. There are 6 figures and 7 references, 3 of Aich
are Soviet, 2 French, 1 Gexmm and 1 English.
=OGIATICRI.- Kiyevskiy gosudarstvannyy univeroitat (KiywState University)
SUBUTTEDs September 25, 1957
Card 3/3 1. Selenium films--Optical properties, 2. Mathematics--Applications

AUTHORS s SOV/51-5-5-21/23
Tavalykh, N.G.
TIMSs Thin-Layer Optics. (optika tonkogo sloya). IV. The Properties of
Germanium (IV. Svoyatva germaniya).
PERIODICALs Optika I Spektroukopiya, 1958, Vol 5, Hr 5, pp 622-624 (USSR)
AESTRAM Germanium layers were prepared by emporation In vacuo from a tantalum
boat. Other conditions of preparation of these layers are described
in Ref 1. The technique of measurement of the reflection coefficients
R (on the air side) and R' (on the substrate side), and of the
transmission coefficient T is described in Ref 2. The affect of
multiple reflections in the substrate was dealt mith as described in
Rof 3. All measurements were made on freshly prepared layers. The
transmission coefficient T was measured rithin 57. For R and RI the
error did not exceed 1016 Fig I Aovs the d ependence of the transmission
coefficient T on thickness d (in A). The four curves represent
measurements at the following wavelengths: (1) 555 m1h (2) 630 mjA,
(3) 720 mtk and (4) 7SO m1A. Fig 2 shows the dependence of the-reflection
coefficients R and R' on the layer thicitness d.- The four curves in each
case vere obtained a-. the wavelengths given in Fig 1. The absorption
Card 1/2 coefficient A = 1 - R - T is give.n In FIG 3 as a Aination of the layer
thickness d (the four curves ware obtained at the wavelengths given in

SOV/51-5-5-21/23
4 -1-a-LaYor Optica IV. Frop-;rti
Fig 1). Frota the oxparWantAl values of T, R and R' the real (n)
and imaginary (K) parts of tho co..,iolex rafractive index IN = n - U
-roro de%armlriod. Tha method of calculation io given in Refs 2, 4. The
results are shown in Fig 4 where curves 1 and 2 represent n for tYa
w,.4-vel3nGths of 630 and 720 zaprospectively Und curve 3 roprcwants K.
In tha rango of thic~weDsas from 300 to 600 A tho valuas of n and K
ob-~-_ined by the prazi ..nt aut-hors are of the sa=e order as erinLe
reported in Refs 5 and 6. There arg 4 figures and 10 rofarunco5, 6 oC
-~;'hich are Soviet, 1 Garaan, 1 Franch, 1 A;~,arica~ and 1 Ent-lish.
SU b T 13D L~iy 15, 1958
1. Germanim--Optical properties 2. Thin films--Preparation
Onrd 2/2 3. Mathematics

AUTHORS: Lisitsal M, -P. Malinko, V. N. sov/48-22-9-29/40
TITLE: Influence of Temperature and of the State of A,-X'regation
(,,On the Infrared Absorption of Carbon Tetrachloride
liyaniye temperatury i agrdgatfiogo 3ostoyaniya na
infrakrasnoye pogloshcheniye chetyrekhkhloristogo ugleroda)
PERIODICAL: Izvestiya, Akademii nauk SSSR. Beriya fizicheakaya, 1958,
Vol 22, Nr 9, PP 1117 - 1121 (USSR)
A13STRACT: Such investigations are of paramount importance for
the determination of the factors which influence the
intensity, the half-width, the shape, and the structure
of the oscillation bands. Individual absorption bands
of carbon tetrachloride were chosen by the authors
as vehicles of their investigation. They were studied
at different states of aggregation and at temperatures
near the point of transformation. The spectrum of CCI 4
is at present tho.-oughly investigated and the majority
of frequencies has already been identified (Refs 1,2).
A method which was developed already earlier was used in
Card 1/4 the quantitative measurement in the range of an extremely
E ~7~ M -q

Influence of Temperature and of the State of 507/48-22-9-20/4o
Aggregation on the Infrared Absorption of Carbon Tetrachloride
Card 2/4
intensive absorption (Ref 3). First the very
intensive double band was investigated as to its temper-
ature dependence. One of the components of this band
(-,j= 784 cm-1) corresponds to the treble degenetated.
fundamental oscillation N)3and the second (-,)= 762 cm
corresponds to the compound oscillation N), +1 4* Owing
to a Fermi resonance this oscillation band attains an
intensity comparable to that of the fundamental oscillation.
For the temperature investigation two isolated doublets
were chosen from several dozens of compound bands. A
Fermi resonance was found to occur between its com-
ponents. The separation of the doublets into their components
is not difficult if both components are assumed to have
a symmetrical shape. The data known at present are by far
insufficient for an explanation of the temperature de-
pendence of the intensities of the bands of infrared
absorption and are even more inadequate for a conotvuction
of a theory which agrees with the experimental evidence.

Influence of Temperature and of the State of SOY/46-22-9-29/4,o
Aggregation on the Infrared Absorption of Carbon Tetrachloride
The only statement which can be made must be limited
to the fact that in this case a temperature reduction
leads to decrease of the matrizelements of the transitions.
The magnitude of the latter is not only dependent
upon the type of molecule but also upon its surroundings.
Supplementary investigations were carried out in order
to determine the influence of the state of aggregation
upon the intensity of the compound absorption bands.
A computation of integral intensities has shown that
I(,,d, is reduced by almost to half its original value
for the long-wave component of each doublet at the
transition from liquid to vapor. With short-wave com-
ponents and in particular with the band \), +J) 3 this
reduction is insignificant. The weakened resonance
interaction leads to a more pronounced reduction of the
intensity of the relatively weaker component in the case
of oscillations \) 1 +V 4 as well as in the case of-~ 3'
Card 3/4 The circumstance that the half-width of each component

Influence of Temperature and of the State of SOV/48-22-9-29/40
Aggregation on the Infrared Absorption of Carbon Tetrachloride
remains practically constant in the phase transition
in question is a characteristic feature, although the
maximum of the long-wave component changes to an iso-
topic structure by splitting into 2-3 components. There
are 3 figures, 2 tablesv and 7 references, 4 of which
are Soviet.
ASSOCIATION: 1~iyevskiy goo. universitet im. T.G.Shevchenko (Kiyev
State University imeni T.G.Shevchenko)
Card 4/4

S/058/62/000/005/056/119
A057/AlOl
AUTHORS: Lisitsa, M. P,, Mayevskiy, V. M., Tsvelykh, N. G.
TITLE: Optical properties of thin films of some semiconductors
PERIODICAL: Referativnyy zhurnal, Fizika, no'. 5, 1962, 6, abstract 5G46
(V sb. "Fotoelektr. i optich. yavleniya v poluprovodnikakh", Kiyev,
-AN USSR, 1959, 227-232)
TEXT: Quantitative data are presented on investigations of optical proper
ties of Se and Te. Results are given on the investigation of phase shifts,* which:
arise when light is reflected frok the interface air-layer of Ag and Ge.
[Abstracter's note: Complete translation]

05455
SOV/120-59-3-26/46
AUTHORS: ~ijLtsa M. and Mayevskiy, V. M.
TITLE-. A Semi-empirical Method of Measuring Thicknesses Along
a Wedge-Shaped Layer (Poluempiricheskiy metod
opredeleniya. tolshchia vdoll klinoobraznogo tonkogo
sloya)
PERIODICAL: Pribory i tekhnika-eksperimenta, 1959, Nr 3,
PP 113-118 (USSR)
ABSTRACT: The first part of the paper presents a rather inconclusive
theory of deposition from an evaporator (Fig 1 and
Eqs (1) - (121)); the results from this theory, which
give the thickness C as a function of the angle cc, have
to be checked by some independent method in the first
instance. The equations from (11") to (14) deal with
one way of checking the results; thicknesses d, and d2
are measured at two different points. The equations
down to (17) introduce corrections for non-sphericity
of the source. The next section deals with cylindrical
sources rather briefly. Fig 2 shows d and CU) (curves
1 and 2 respectively) for selenium, Fig 3 gives results
Card 1/2 for two layers of selenium deposited from a

05455
SOV/120-59-3-26/46
A Semi-empirical Method of Measuring Thicjcnesses Along a Wedge-
Shaped Layer
semi-cylindrical evaporator; :~n each case theory and
expemiment-agree well.There are 3 figures and 4 references
3 of which are Sovietand 1 English.
ASSOCIATION: KiYevskiy gosudarstvennyy universitet
(Kiyev State University)
SIYUBMITTED'.- March 10, 1958
Card 2/2

SOV/120-59-4-25/50
AUTHORS-JAsitsa, M. P., Tsyashchenko, Yu. P.
-.'TITLE: `DT`spTFftW-Mv"_trements in Regions of Strong Infrared
Absorption.
PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 4, pp 108-112
(USSR)
ABSTRACT: The method described here is based on reflection and is
intended for use with liquids. The cells are hermetically
sealed in order to eliminate interference from the vapour
(the.examples given relate to CHGl and CC1 ). Fig 1 shows
3 1 4
reflection curves for Cel 4 near 12 IL; the top curve is for
a properly sealed cell, while the bottom one relates to a
cell with a vapour leak. The window used to seal off the
liquid is an optically worked plane-parallel plate (e.g. of
rook salt); Eq (1) gives R , the measured reflectin
(,g power,
in terms of I. (the reflected intensity) and Io he
incident intensity), or in terms of R12 (the reflection
coefficient at the outer surface of the plate) and of R23
(the reflection coefficient at the inner surface). Eq (2)
gives R12 as a function of n . which is known accurately
Card 1/2

SOV/120-59-4-25/50
-Dispersion Measurements in Regions of Strong Infrared Absorption
-and so Eq (3) gives R Then Eq (4) gives R2, in terms
of the parameters.of tO liquid and plate, and Eq 5) gives
a for the liquid. Fig 2 shows the reflection unit; Fig 3
shows the optical system used (the angle of incidence does
not exceed 100). Here P is a mirror and C is the cell.
3ig 4 shows results for C61 . and Fig 5 does the same for
('.'IHC1 The values of x Ire taken from Ref 5 in the case
of C6 and have been measured by the method given in Ref 5
u n t described here) in the case of CHC1 The paper
(b t
concludes with a brief theoretical note on tRe'interference
iaethod:of measuring n for the wings of the absorption curve;
a thin film of liquid is used to form interference bands by
Aitultiple reflection. The method is suitable for regions in
which the absorption is too strong for a prism to be used, but
is too weak fo- the method above to be suitable. There are 5
figures and 12 references, 1 of which is German, 4 French, 6
B'nglish and I Soviet.
ASSOCIATION: Kiyevskiy gosudarstvennyy universitet (Kiyev State Univ.)
SUBMITTED: May 12, 1958.
Card 2/2'
I

24(7). 24(4)
,^_U,WCRS;
TI 77,3
SOV/51-6-5-8/34
Liaitja, M.P. and Tsyashahealcc, Yu.P.
quantitative St-idies of Infrarevi AbsorptIon and Dispersion of
Chloroform (Zolichestveanyya issltdovaniya infrakruna0epo -,~~glcshcheniya
I disparaii Lh1crofcrmaj
7a-,ODICAL-. Optika i Spaktrosko-,Aya, 19.7-9, V-A 17r 5, pp 605-615 (USSR)
ABS MV,T Althougli the amouzit of pvbliah!4 -wirc --n 12=14-z is large kR.-.fz 1-1,3), a
complete and systematic a~.-Nuzt, of data xa ths infrared spectram an,-;
its intezpretation is' still laa4mg. --13paraion of ch'Oroform is
dealt with in aa, evoa smalIsr a="t of Irablishei v3rk (Refs 12, 20).
Vie rreseat authcra ~'atarrinzZ ths aba,%~ptioa cDafficients r..f liTa'L&
GHGI~x in th6 47C-.11W. -z!--l ra,,,PA&nd Vie dispersion zu.-,3 ;-n the
region. of the m-~st ILTwave !a& kcz,:-,-.-aa?=ce'!ar, t~D -the 1"unda-ments.2.
vibration )$j). Ths mWoTptiva c:~:~fiftclonts -wer3 mt~asurod using en
infrared SpedtV=-3tel' 113-C-. absorpt'l-3n ".,3ffialents were CSIZ.AzatZ4'
fr,= 11/12 = aX2 -;, 62.)], whers 17 and 12 are th~e intansitle5 of a
U&M,beez wh.-Ir.,h lhaz ~passw2 t~rc.,gh. thl;-~-,esses ?,l and d2 of The
09 X an! of the i-n-hogral ab&::jj-pt,,,un JKVeV -ffq:~e daterrnined to
the
reSion where the err~,r -was
card 1/3

SOV/51-6-5-91/j-
quantitative Studies or Infrared Absorption and. !jisrarsicr. of ". loroform
To measure dispersion of GHG13 in the yj-band region a special
reflection method was developed ~Ref 26), in 'which the effect rf vapour
-was eliminated (vapours may affeA the measured reflectivity of a free
surface of volatile liquids). In the regions neighbouring with the
V5-bani the refractive 'Index was determined by an improved interference
method (Ref 26). The error measurement of a in the vi-band region
did not exceed 12-15% and outside the band it was 5-8%. The absorption
curves of liquid CH01.3 (the absorption coefficient K plotted against
wavelength) are shown in Figs 1-7. The wave-nmbers of various
vibrationa, their interpretation ani my=etry, the absorption
coofficientA at the band maxima, the integra! absorption (SIFV,1-9) and
the band half-widti. d in tho range 250-IbSM cm-1 are collected in
Table 2. This table includes also frequencioa measured by other
-workers (Refs 2, 3, 5, 6, 10-16). It is found that the partial
Identification reported by various workers (Refs 2, 5, 11, 13, 15, 16)
agrees entirely with the Identification deduced by the present authi.-;r3.
This Identification was based on the 05-, symmetry group model of the
CHC13 moleculo. The spectr= chovn in FIp 1-7 and th; data of Table 2
indicate that the most intense band is due to degenerate vibrations of
Ca rd 2/3 the G-011 Londs with a frequency Vi. The integral absorption of the

S O*V11- 1 -6 --': -~'/-34
quentitAtive Studler, of Infrared JJV~~iorption ar.41 Uispe.raion of Chloroform
fully qnm-stri.- :VI, with it:5 satellite, is mu-!h
smeller than the integral absorptiz)n of the vl,'hrationa ))~ anA. Va.
'Thl-- ic d-aa to the fact that the *,cO is easentially hom:r--~ar
(cevalent) while the 'G--CW1 boad is mar; ionic. The dispersion' xarvt3
of CH1013 In the 2).3-~end ragi= Is showa In Fig 0 together with ths
absorption index Tarve, (the absorption Index is given by 14= K/OL3~.
The disperA on cur7a (dencted ty n In Fig 8) In eeen to be strcn7ly
asymmetric. There are 8 figures, -9 tables and &0 references, of
vhich are a ovi et, 7 Fran,-!-., 6 Engli-sh. tt Garmaz, Italian, 1 Japane-z
and 1 translation from Eng,'Ash into
SUBMITTED: May 8, 1.958
Ca rd 3

SOV/51-6-5-23/34
AUTHORS: Lisitse., M.P. and Malinko, V.N.
TITLEs On the Temperature DepaJoms of Intensities of the Combination
Frequencies ij + % and v., + (vl + v4) or Gaseous CC14 (0 tenineraturnoy
tavisimosti intensivnostey sostavnylch tonov -v1 + v6 i V., + kVl + V4)
gazoo'brasnogo CC1,j)
PERIODICAL: Optika i Spektroskopiya, 1959, Vol 6, Nr 5, pp 694-696 kUSSR)
ABSTRACT-s. Voltkenshtdyn, Yellyashevich and Stepanov's theory (Ref 1) of the
temperature depedence of intensities of vibrational absorption bands
has not yet been verified, because of great experimental difficulties.
The present note reports the first attempt at verification of this
theory for the combination frequencies V, + 1~6 and Yl + (Y1 + V4) of
gaseous 0014. The theoretical temperature coefficiints for these
vibrations are given by Eq (1). The ex.pressions of Eq (1) can be used
to construct theoretical curves but their comparison with experiment is
difficult because the bands V, + -06 and 1), + (V 1 + -d overlap strongly
forming a aloes doublet. For this reason the total Ltegral absorption
of the doublet Yes determined and compared with the corresponding
calculated curves. The absorption curves cf the doublet were obtained
Card 1/2 between 20 and 200OC; three of these curves obtained at 20, 135 and 2000C

SOV/51-6-5-23/34
On the Temperature Dependence of Intensities of the Combination Frequencies V, + 1~5
and 11 + (V1 + V4) of Gaseous CC14
are given in Fig 1. Fig 1 shows that increase of temperature leads to
a slight Increase of the total intensity, broadening of each component
of the doublet and a fairly strong rise of the absorption maximum
of ~the long-mvelongth component. The curves or Fig 1 show only a
qualitative agreement o f theory with experi m-ent. This is con-
firmed by the data of Fig 2, where curve 1 was obtained experimentally
and curve 2 theoretically. AlthoUg~ curves 1 and 2 of Fig 2 are
similar in appearance, the theoretical curve indicates a stronger
temperature dependence of the total integral absorption than that found
empirically. The authors could notauggest a reason for the difference
between curves 1 aM 2. They did establish, however, that the Increase
Of Lthe partial pressure of C014 vapour with temperature cannot explain
this disagreement. There are 2 figures and 4 Soviet references.
SUEMTTED. October 8, 19,%
Card 2/2
6

60v/51-7-4-7/32
AUTHO13Z.- Lisitsa, M.P. and Strizhavalcly, V.L.
TIT1,'Ss On the Temperature Dependence of the Vibrational 4.boorption Band
Intensities In Gases in the Case of Fermi Resonance.
PERIODICAL; Optika I spelctrookopiya, 1959, Vol 7, Nr 4, pp 478-481 (USSR)
ABS,.mACT , Earlier studies of -the temperature dependence of the intensities of
two vibration& of gaseous ctirbon tetrachloride (Ref 1) confirmed
qualitatively the correctness of Vol# kenshtayn, Yell yashavich and
Stepanov's theory (Ref 2). Complete quantitative agreement was not
obtaineds the theory predicted a faster rise of the integral absorption
with increase of temperature than vas found experimentally. Among
many factors which may be responsible for this difference between theory
and'experiment the most impdrtant is the resonance interaction between
vibrational levels SO and 30
V1+V3 +(9 (the superscript o denotes
V1 1 41
unperturbed state). Transitions to these two 1~vels produce bands of
the vibrations studied. Allowance for this interactioa -was expected to
produce quantitative agreement between theory and experiment. This -was
Ca rd 1/2 Cound to be true when the authors modified Volikenahteyn's at al theory
by inclusion of the Fermi resonance, since this led to better agreement

-Xi/51-7-4-7/32
On the Temperature Dependence of the Vibrational Absorption Band Intensities in
Gases of Permi Resonance
between the calculated and experiwental vulue4 of integral absorption
In the resonance doublet i), + ;,, and -,~ + (-J1 + -->4) of carbon
tetrachloride (table on p 481). The differences between the
calculatod and experimental values lay bstxeen 3.6 and 5.8"
i.e. Avithin the. experimental error, which -tar, 10~.'- There are 1 table
and 4 Soviet references.
SUB!Z-'TTEDs February 17, 1959
ard 2/2

AUTWIC: L1s1tsS._M_A__" Tavelykh, N.G.
r
TITLES 'Thin-Layer Optica. V. Properties of Silicon
PIRIODICALs Optlka I spektrookopiya, 1959, Vol 7, Nr 4. pp 552-557 (USSR)
~ABSTRAM Wedge-shaped layers of silicon, convenient for studies of the
dapendencs of the optical constants an thickness, were prepared by
vacuum sublimation. The layer thickness (d) varied fr= near zeio
to 1200 1. Since tungsten, tantalum and molybdema'are all dissolved
by liquid silicon, a carbon crucible was used in the torm of a' parqUel.
plate of 0. 6 mm thickness and 5-6 mm width. The original material
'
contained up to 0.2% of impurities.
To reduce the amount of impurities
this material was malted several times; in vacuo which removed the more
volatile admixtures. The technique of meas-a#ng the transmission
cosfficisAtT (light Incident frm the layer side) and the reflection
coefficients R and R' (light incident from the base side) vas the
same as that Idescribed earlief (Ref 4). Multipla'reflactions in the
bass were allowed for (Ref 5). The final vaiue of T was correct,-to
within 5%; for R and R' the errors reached 10%. The transmission
curves (T in /0.) are sho ih Fig 1; here and in Figs 2, ~5 and 4 curves
1, 2, 3, 4 represent measurements at the following four wavelengths:
Card V3 560, 640, 700, 760 mp. At d < 200 the transmission coefficient T is

Thin-Layor Optics. V. Properties of Silicon SOV/51-7-4-19/32
gre&tor than 90% but with increase of d It falls gmdually foming a
wide minimum near d-600 A. Position of this minimum is different for
different wavelengths. Its displacement towards greater values of the
thicimoss d on increase of wavelength shows that the minimum in duo to
interference. The same applies to a maximurn at d-1000 1. Two small
maxima of T at d-200 I are duo to relazation effects. The'latter
effects are also responsible for minima of R near d-200*1 (Fig 2);
no*such relaxation minima are observed-on the R' curves (Fig 3) near
d.,2100 X. The dependence of R and R' on d is in general similar to
that observed in t6 case,of selenium and germanium layers. In-all of
them the interference maximum, which occurs at d-750 I in silicon, is
split into two componenta. 7his splitting is a structure effects at
thi6rnesBes of 500-600 1 uAlicon layers are still "granulated"
(discontinuous) and this is reaponsibla both for the resonance extroma
and a plitting of the interference ma:zimum. The- absorption coefficient
-1 the valuo
is shown as a function of.the thickness d in Fig 4. Below 420
of A was so small that it could not be measured. On increase of
wavelength towards the infrared region the value of A was found to fall
considerably. It is. therefore, suggested that" silicon layers may be
used to make non-absorbing multi-layer coatings, e.g. s.ati-reflection
Card C21135

I
,Thin-Layer Optics. V. Properties of Silicon-`
Ga rd 3/ 3
StM=TT8Ds
BOV/51-7-4-19/32
coatings, for the inf rared region. Abeles' formulae relating the
Values of T, R 'and R and the optical constants n and*% (Ref 10)-were
fouid to be inapplicable in the case of thin 911con layers. Using
a different method (Ref 11) the authors datezmined the refractive
index n for comparatively thick layers. of silicon (d ~> 1000 L. The
refractive index v4s calculated from
(2)
. n and dmax are the thicLaaesses at which minima and maxima
-there dmi
oc.cur on the curves R(d) and R'(d). The calculated values of n are
given in a table on p 566.' For I= 540 mp n = 2.6-3.97, for 580 =p
n = 2.64-4.2, for 640 Mg n = 2.6-4.1 and for .760 mIL a - 2.71-4.32.- the
higher values of n correspond to lower lacer thl:Arnesses. The authors
point out that the refractive index rises, In general, with increase
of A and that in thick layers the value of n is close to 3.5 reported
for monoarystalline silicon. (Ref 9). The authors found also that
after sereral days the originally amorphous layers of silicon with
dN9OO'X crystallized spontaneously; such crystallization did not
occur -in thinner layers (d< 900 1) - There are 4 figures . I table and
11 references, 7 of which are Soviet, 1 lInglish and 3 French.
February 17, 1959

LIS.ITSA2 M.P.
Polarizativz~--Photcmetric method for measuring the refraction
indices for transparent semiconductors. Prib. i takh. eksp.
no,'31125-1V MY-Je f6O. (MIRA 14".10)
1. Kiyevskly gosudarst universil
vennyy
(Semiconductors) actometry)

82553
s/iel/6o/602/007/035/042
e-2 7 r) B0061BO60
AUTHORS: Korsunakiy. V. V., Lisitsa, M. P.
TITLE: Infrared AbaorptioXnd Hole Band Structure of Tellurium
PERIIODICAL: Fizika iverdogo telaq 1960t Vol. 2, No, 7# PP. 1619-1623
TEXT: L, I. Korovin and Yu. A. Firsov suggested the use of data on infra-
red absorptionfor clarifying some.partioulare concerning the valenoy zone
structure of tellurium. Their group-theoretical investigations revealed
that two variants.are relevant for the form of the energy spectrum of the
hole band: one ellipsoid in the center of the Brillouin zone or two el-
lipsoids in the G-direation, A. decision can be made when the form of the
bandt which is established by the type of isoenergetic planes is known.
To determine such a form was the main task confronting the investigations.
In the course of them, the authors examined the edge of characteristic
absorption for two directions of the light veotor and background absorp-
tion. The test pieces ixsed for the purpose were made of tellurium single
crystals, that had'been produced at the Leningradgkiy institut poluprovod-
nikov (Leningrad Institute of Semiconductors)*'Poils were cut in parallel
Card 1/4

82553
Infrared Absorption and Role Band Structure of S/181 60/002/007/035/042
Tellurium B006YB060
to the C-axisp then ground and polished. As a consequence of such treat-
ment, differently oriented microcrystals formed on the surface of the test
pieoesq so that the reflection coefficients of the latter were practically
the same for both polarizations (E11Cp E10) in the whole spectral range.
The experimentall. error in.the determination of the reflection coefficient
did not exceed 5%o On taking account of all other factors, the total error
was found to be Ak/k n! 15 , In Fig* 1, the transmissivity and reflootivi-
ty curves are shown for natural and polarized light for two gpeoimens
(specimen 1: 0-83 mm thickv impurity concentration =1014cm-51 Specimen 2:
O.3T mm thick, impurity concentration c::L10 16 _1017CM-3). Only the curves Vi/
D and D,j (penetrability in the ordinary or in the B110-polarized lightp
respectively, for Specimen 1) exhibit a minimum at X - 11 p. By making use
of these data and results from Ref- 7t the authors calculated the absorp-
tion curves for polarized light; they are shown in Fig* 2. The position
of the absorption edge was then determined from the point of inflection
(Ist line of the table) and by means of the extrapolation of the linear
part of the curve to the point of intersection with the abscissa (2nd line).
Card 2/4

82553
Infrared Absorption and Hole Band Strw ture of
Tellurium, B006/BO60
The results arei
'oil- am- h ev "L am- h e v
2800 0.39 2600 0.32
2530 0.315 2470 0.308
The thermal width of the forbidden band was.found to be 0.33.� 0.01 av.
Some problems concerning the etructureless background bordering with
the obaractaristio absorption edge and extending far into the longwave
region, are discussed next. It appears certain that it is closely
related to the free carriers. That the absorption coefficient in the
background is dependent on polarization, is explained by the dependence
of the effective carrier mass on the direction, The'main issue is then
first discussed, namely, the hole absorption band.shape in the(region
A - 11 p. It is shown in Fig. 3. The three possible functions 4),
and (6) for k(-O)t based'on the one- or the two-ellipsoid model, are
written down. A number of experimental results admits only (5) and
(6) for selectiont and the fact that the absorption band is symmetrical
card 3/4

82553
Infrared Absorption and Role Band Structure of S/181/60/002/007/035/042
Vellurium B006/B060
and has a Gaussian form (Fig. 3, Curve 2) shows that only the k(v) func-
tion given by (6) describes the experiments satisfactorilyg and hence,
that the model of the two ellipsoids must be preferred. The authors thank
Yu. A. Firsov and L. 1. Zorovin for their interest and for having suppliqd
the tellurium single crystals. There are 3 figures, 1 table, and
12 references: 6 Sovietp 4 USP 1 Hungarian, and I Japanese,
ASSOCIATION: Kiyevskiy gosudaretvennyy universitet im. Shevchenko
(K!Zev,State University im. Shevehenko
SUBMITTED-. November 9, 1959
Card 4/4

s/1 8i/60/OOW6/013/036
B004/BO56
AUTHORS: Kholodar', G. A.
TITLE: -The Infrared Absorptio4and the Energy Structure of
CupFo'us Oxide
PERIODICAL. rizika tverdogo tela, 1960, Vol. 2, No. 9, pp. 2117 - 2125
TEXT: The authors aimed at interpreting the absorption bands of Cu 20 in
the--infrared region at 7asl=8 temperatures, taking the presence of ex
cess oxygen into account. The infrared spectra were recorded by MKC-6
(iu-6), pw-ii and a Perkin--Elmer-12B spectrometer in the re-
gion X .,0.6 - 24 p,, The samples made from pure copper, which had been
produced by Yu. I. Gritsenko, had a -thickness of 309 80, 200y and 350 4-
They were oxidizedg the thinnest lamella being heated at 10500C in air
in order that they absorb additional oxygen. The temperature dependence
of the spectra was investigated an 20-200 V thick samples. Some of them
were single crystals produced according to the method developed by
Tu. 1. Gritsenko (Ref, 3). The experimental data are shown in Fig. 1 LIK
C ard 113

8
The Inf-rared Absorption and the Energy S/181/60/002/009 013/036
Structure of Cuprous Oxide B004/BO56
(light tranamissivity of-the Cu 20 polyarystals at room temperature) and
Fig. 2 (absorption of the polyarystal 80 g at 20 0K. This measurement was
carried out at the Institut fiziki AN USSR (Institute of Physics of the
AS UkrSSR) on 0. V. Fialkovskaya 9 apparatusT-;Fig. 3 ~abeorption of
the polycrystal in the ragion X - 8.9 g between 138 and 2890K); Fig. 4
.(dto. at 1-98 - 4400K)i ~ig; 5 (absorption within the region X = 12.6 A
at 162 ' 2910K)l Fig. 6 (dto. for single crystals at 209 - 4580K);
Fig- 7 (position of the maxima of the 8.9 and 12.6 V bands as a function
of temperature)l Fig. 8 (bands between 15 and 17 g at room temperature
and 1400K). It follows from Fig. 48 that the thinnest sample, which,
howevero contained exoees oxygenv showed the greatest absorption. The
maximum of the 8.9 p band decreases with rising tempera+ure (Pigs. 3,4).
This band is attributer.1 to vibrations of the ion lattice. The increasing
intensity,of the 12A ji band with increasing -temperature, however, cor-
responds to ax. absorption on three holes. The band between 15 - 17 A is
narrowed by a decrease of temperature. This brighteningg which is of
particular distinctness on the longer-wave edge of the bandg remains con-
served after subsequent heating to room temperature. A superposition of
Card, 2/3

84072
The Infrared Absorption and the Energy B/181/60/002/009/013/036
Structure of Cuprous Oxide B004/BO56
the vibrational band is carried out by a band that is based upon the
photoexcitation of the polaron. Basing on S. I. Pekar's theory (Ref. 8)1
the excitation energy for the transition of the polaron from the a- to
the p-state is calculated to be 0.067 ev and A - 18-5 9, which ag-rees
.satisfactorily with the experimental data X - ITA ~L, 0-071ev. These
data are not sufficient for interpreting the new maxima found within
the region 9 - 11.6 IL. Ye. F. Gross, N. A. Karryyev (Ref. 1), and
I. Pastrnyak (Ref. 2) are mentionea.-Ne -authors thank V. M. Korsunskiy
and 0. V.-Vakulenko for their assistance. There are 8 figures and 9 ref-
erenoes: 7 Soviet, I US, and I German.
ASSOCIATION: Kiyevskiy gosuda'rstvennyy universitet im. T. G. Shevchenko
(Kiyev State University imeni T. G. Shevchenko)
SUBMITTED: May 4, 1959 (initially)
March 18y 1960 (afte: revision)
Card 313,

86805.
S/185/60/005/001/004/018
.211.6100 CIO`/a/ /09.5~ //99) A151/AO29
AUTHORS: Lisitsya, M.P.1, Str~zhev&y,, V.L.
t
TITLE: On the Fermi Resonance in the Case of Carbon Tetrachloride
PERIODICAL: Ukrayinslkyy Fizychn
_yy Zhurnaa, 1960, Vol. 5, No. 1, PP. 34 - 39
TEXT;' The paper deals w .ith tke problev~Iof the Fermi resonance in the case
of-carbon. t'etrachloride. Tts aim i~ to show that for CC14 the existing theory
is in a satisfactory agreement with the experimental data referring to the Fermi
resonance. A comparison is made of the theory with the experiment:for three
Fermi resonant doublets Of CC14- It was ascertained that in the cise of gaseous
CC14'the theoretical value of the splitting-#and the intensity ratios of the re-
sonating component are in satisfactory.agreement with'the experimental data. A
determination 'was also made of the distance Abetween the unperturbed levels, as
well as ofthe unperturbed frequencies of the fundamental oscillations of moleoukp
of gaseous and liquid CC14- 7he result,* of the experiment together with the non-
perturbed levels of an isolated molecule of CC11 are given in a table. A com-
parison of the~frequencies shows that in case o~ the phase transition gas - liquid
a general tendency appears toward a decrease of frequencies. This result is
Card 1/2

86805
S/185/60/005/001/004/018
A151/AO29
On the Fermi Resonance in the Case of Carbon Tetrachloride
observed as a rule in all mAeoular compounds. The data of the table give a
qualitative proof for the aqsumption that the maxima of-the fundamental absorpt)on
bands:shift in the case of the mentioned phase transition (see also Ref. 8). ir
cloning, the authors point out that the results obtained in this work prove that
It, is possible to"do away with the nonharmonious members of the potential. energy,
in the case when the Fermi resonant is absent. There Is I table and 9 referenow
8 Soviet and 1 German.
ASSOCIATIONt Kyyivs'kVy dershavnyy universytet im. T.H. Shevahenka (Kiyev State
University imeni T.H. Shevuhenko).
SUBMITTED: July 1, 1959
Card 2/2

S/0-51/60/008/04/006/032
9201/1691
AVMRSs (Kponam, N, Y*., Lisitsa, M.P. and Tayashcheako, YU. P.
TITLIs Frequencies and Intensities in the Infrared Spectrum of Br=oform
PnioftaiLsOptika I spektrookoplya, 1960, Vol 8, Nr 4, pp 465-470 (USSRI
ABSTRAOTt The absorption spectrum of bremoform (GHBr3) was investigated IA the
-region 460-11700 cm-1 wing a technique described earlier (Refs 10, 11)
The absorption spectrw obtained is shown In Fig 1. The Interpretation,
83mmetry, abso:rption coefficients at the band maxima (Imax), half-widths
(r) and integral absorption (a) are listed in a table on pp 466-7. The
values of a arvi r are given only for the fundamental vibrations and
for isolated bands which can be easily separated into sysmetrical
components. The table includes also the published (Refs 4, 8)
frequencies of various band maxima. The intensities of the fundamental -
vibrations and harmonies were explained in terms of the degree of
polarity of the chanical bonds. Gomparison of the absorption spectra
of GHBr3 and CHGl,3 showed that the integral absorption of the
card 1/2

a /oryl/60/008/04/006/032
Prequenoies and Intensitiom In the Infrared Spectrum o f -,~B romo' f
fun4ameutal vLbration bands depends an the degree of polarity of
the bonds.,which detemine the foms of these vLbrations. There
are 2 figures, 1 table an4 16 references, 7 of vhIch are Soviet,
3 Bnglish, 4 French, I Italian and 1 translation from Inglish into
Russian.
SUMITM u Jun* 29, 1959
card 2/2,

. LISITS&, M.P.
*Optics of thin-layer coatings* V G.T.Rosemberg. Reviewed
by M.P.Lisitsa. Opt.i spektr. 9 n0-12130-132 Jl 160-
(MM 1337)
1 (NUM0 (Gh8mi6U7)) (Optics, PJVsic&l)
(Rozenberg, G~T.)

8/051/60/009/004/00)+/03)+
9201/H191
AUTHORS: Lisitsa, KE,, and Tsyashchgnkg, Yu.P.
==M~ -
TITLE: The Temperature Dependence of the Infrare-d-Absorptio
Band Intensities of Liquid Chloroforml
PERIODICAL: Optika i spektroskopiyal 19609 Vol 99 No 1+1 PP 438-445
TEXT*. The authors made a quantitative study of the
temperature dependence of total infrared absorption in the
fundamental vibration bands 01 and V)+, the most intense harmonies
2'41 and 2%+, as well as the combination frequencies ~l + 4~1+7
*4 2- + N) 6 and '*) 3 + "~ 6 of liquid chloroform. Thes e- measurements
were carried out at five temperaturess -587 -30, +20, +40, and
+60 00. A. cell us.ed In this study was described earlier (Ref 1);
between 20 and 60 OC it was heated in an electric furnace and
below 20 00 it was cooled in a cryostat shown in Fig 1. some
results are given in Fig 2, which shows the fundamental vibration
bands *41 (Fig 2a)~ '4i~ (Fig 2-6), combination frequencies
'42 + -4 6 (Fig 20) 9OjL + 14 (Fig 2Z), and ahamonic 2-~Jl
(Fig 20). The intensities of the bands Vl (Fig 3, curve 1),
Card 1/2

6/051160/009/004/00V03'+
E20l/El9l
The Temperature Dependence of the Infrared Absorption Band
Intensities of Liquid Chloroform
-k (Fig 3, curve 2), ,%), +,,)I+ (Fig 4, curve 1), '-)2 +
(Fig 1+, curve 2), \N3 + 16 (Fig 4, carve 3) all fell linearly
with increase of temperature. The intensities of the harmon-ica
2'41 and 2'01~ were independent of temperature. Comparison of
the temperature variations of the vibrational absorption bands of'
CHU . CHBr3j , CC1)+ and _jft -,I established a correlation
3 9_
between the volume expansion coefficient of each liquid and the
mean temperature coefficient of the intensity of the bands.
There are 4 figures and. 20 referencoss 10 Soviet and
10 English.
SUBMITTED: January 4, 1960
Card 2/2
777777~z.`-~`.e

777i-

LISITSA, M. R.
Doe Phys-Math Sci (diss) "Intermolecular interactions and infra-
red spectra." -Minsk, 1961- 34 pp; (Ministry of Higher, Secondary
Specialist,.and Professional Education Belorussian SSR, Belorussian
State Univ imeni V. I. Lenin); 200 copies; free; list of author's
works-on PP-33-34 (35 entries); (KL, 6-61 sup, 191)

S/051/61/010/001/004/017
E201/E491
AUTHORS: Lisitsa M.P. and Strizhevskiy, V.L.
TITLE: The Temperature Dependence of the Intensities of
Vibrational Absorption Bands in Gazes
PERIODICALi Optika i spektroakopiya, 1961, Vol.10, NO-1, PP-48-54
TEXT: The authors consider theoretical aspects of the
temperature dependence of the integrated intensities of
vibrational absorption bands of gazes. Apart from the
"Boltsmann factort' (Ref.4), the authors consider the effect of
anharmonicity of internal molecular vibrations and the effect of
light emission on the intensity of vibrational bands, Formulae
are derived which give the temperature dependence of the
integrated absorption. The new formulae differ somewhat from the
usual expression. Comparison of the available experimental data
on carbon tetrachloride, bromoform, chloroform and other
molecules (Ref,l to 3) Tith the new formulae showed fairly good
agreement but further work in necessary for reliable conclusions.
There are 15 references: 14 Soviet and 1 non-Soviet (translated
Card 1/2

S/05l/6i/o1o/oo1/oo4/o17
EM/E491
The Temperature Dependence of the Intensities of Vibrational
Absorption Bands in Gazes
into Russian).
SUBMITTED: Plarch 30, 1960
Card 2/2

M-P.
G.G.,- LIS !A
Infrared absorption spectrum and molecular symmetry of heza-
ethyldisilomme. Opt,i spektr. 12 w.ls�5-6o n 161.
(14IM 14.,10)
(SUnzane-Spectra)

LISMA, M.P.; KHAIJMDIIOVA, I.N.
Absorption band of -moyiossubotite-
ted benzenes in the region of the valence osci34tionv of
C Harom bonds. Opt. i spektr. ~ 13. no.2:285-191' Ag' 161.
(MIRA 34-8)
Benzene)
romatization)
R

VAKUIENKO$ O.V.; KIMY,, G.G.; LISITSA, M.P.
----------
Temperature affect on the infrared spectra of organooLlicon
compounds. Part 2. -Crystalline hemaethyldisiloxane**. t.
i spektr. 3-1 no.2:196-202 A 161. . (MIRA 3-4:81
(Infrared rays) fZaoxane-Spectra)

~Mp ~-~OMVAP BIN*^
Texpe3rature effect on the a4sorption of benzene monosubstitutoo
in ths.region of valence oo4illations of C - H bondo. Opt. i
opektr. ll,no.3032-341 8 161., (KM 140)
-1(BenzeAWp~6tra)

T.TRTTqA M.P. [Lysytsia, M.P.); STRIWVSKIY V.L. (Stryzheyalkyl, V.L.],
*91660VA I.11. (Khalimonova, I.M.1
Temperature dependence of the intensities of vibration absorption
bande of molecular liquids. Ukr. fiz. zhur. 7 no.10:1090-1100
0 .-162.. (MIRA 16tl)
1. Kiyevskiy gosudarstvennyy universitet i Institut poluprovodnikov
AN UkrSSR.
(Molecular speotra)

17-5 A 42766
S/185/62/007/010/008/020
D234/D308
AUTHORS: _LyBVtsya, j Stryzhevatkyy, V. L, and Khalimonova,
TITLE: Temperature dependence of the intensities of vibra-!
tional absorption bands of moiecular liquids
PrRIODICAL: Ukrayins1kyy fizyc~hnyy zhurnal, v. 7, no. 16*, 1962,
1090-1099
TEXT; Measurements were made in the whole temperature range where
liquid phase exists, for fundamental vibrational bands and their
combinations. The liquidu were CCl , hexaethyldisiloxane, octa-
methyltrisilox,ane, toluene,. chlorotenaene', nitrobenzene, aniline
and bromobenzene, The intensity of any absorption band varies'ac-
cording to
S 8 +q(T T
T 0- 0
Card 1/2
Temperature dependence of~.'..
S/185/62/007/010/008/020
D234/D3oa
the temperature coefficient being negative. For the first overtones
of the vibrations, the integral absorption does not depend on tem-
perature. Theoretical calculation (using the Frank-Condon principle)
gives
W.1 28(O)
qj qj
(16)
and the sign of o(is estimated to be negative. There are 4 figures.
ASSOCIATION: Kyyivslkyy derzhuniversytet; Insvytut napivprovidny-
kiv AN URSR (Kiev State University; Institute of
q-miconductors, AS UkrSSR)

KIRBY, Q#'G.,j LTSITPA9 MsP.
Temperature effect on the infrared spectra of silicon organic
compounds. Part 21 Liquid bexaethyldiailoxane. Opt. i spektr.
12 no-3076-380 Mr '62. (MIRA 1513)
(Silicon organic compounds--Spectra)

KIREY, G.G. LISITSA, M.P.
---l-
Temperat,we effect on the infrared spectra of organosiUcor. cm-
pounda. Part 3. Octametbyltrisiloxane. Opt. i spektr. 12
no.6014-717 Je 162. (MM 1515)
(Siloxane--Spectra)

8/020/62/145/006/008/015
B181/B102
AUTHORSt' Lisitsa, M.-P., Strizhevskiy, V. L., and Khalimonova, I. N.
TITLEs Anomalous intensity-distribution of vibration'bands from
Fermi resonance
PERIODICALt Alcademiya nauk SSSR. Doklady, v. 145, no. 6, 1962, 1262-1264
TEXT: The Fermi resonance in absorption spectra of multiatomic molecules
was studied theoretiQally, paying special attention to intermolecular
interaction (A. S. Ddvydov, Teoriya pogloshcheniya oveta v moleknlyarnykh
kri.stallakh - Theory of light absorption in molecular crystals - Kiyev,
1951). It has been found that the doublet lines must.be polarized at
right angles to one another. Measurements made in polycrystalline layers
of CCI4 showed that both lines are polarized eqiially. Absorption in the'
region of vibration from plane deformation of the symmetry B 1 with the
complex term of the same symmetry were studied in the case of liquid and
crystalline iodobenzene and chlorobenzene. The intensity ratio of the two
doublet' lines I /I is almost I for M for the liquid benzenes < 0.1,
v V 49
1/3
Card

5/020/62/145/006/00~/01"5
Anomalous intensity-distribution... B181/B102
for iodobenzene crystal (T - -35 to -1670) about 10, and for crystallized
chlorobenzene about 1. The anomalous intensity ratio can be explained by
the results arrived at in an earlier paper (V. L. Strizhevskiy, Optika i
spektroskopiya, 8, 165, 196o). If v and v1 are resonance terms and if
2L 2
~~vv' < - k -1 6 , k;/>1; (1) is obtain
IVI/IV ;;"I., then the condition 6 k 161 ed
where L is the matrix.element of the vibration energy transfer from
VVI
molecule to moleoulev 6 is the "natural" distance of the splitting com-
ponents k w pov/povlt Pov and povg are the matrix elements of the dipole
0 0 0
moment for thbo corresponding transitions. If Lvvl< 0 and 6> 0, then
2
111~_, k (2) is obtained from (1) where % is the distance of the
>
doublet maxima* From (1) and (2) it follows that a migration Pf the
vibration excitation in the crystal, which makes intermolecular resonance
possible, is the cause of the anomalous intensity ratio. There are
3 figures.
Card 2/3

S/020J62/145/006/008/015
Anomalous inteneiiy-diatribution... B181/B102
ASSOCIATIONs Kiye'vskiy gosudaretvennyy universitet,im. T. G. Shevchenko
(Kiyev State University imeni T. G. Shevchenko)
PREShNTEDs April 13.,,1962, by I* Vo Obreimovy Academician
SUBMIT~kD: ';April 10f 1962

Card 3h

LISITSA, M.P.JLysytsia, M.P.]; VALAKH, M.Ya.
Infrare'd aboorption and the atructure of US zonse. Ukr.
fiz. zhur. 8 no.10:lW-1149 0 163. (MIRA .17:1)
1. Institut poluprovodnikov AN UkrSSR, Kiyev.

~L 12166-63 EWPI,'J)/EPF(O)/Wr(=)/~D.S--P.~--4 'r-L-FE/W.
AccEmox NR:- AP306E~186 Pt,,)051/63/014/006/0793/0797
N*
-ion
ispe;s on ot-crystalline clip 2~ZLenejin the infrared reg
TITIS a _h Ln Ll A(
SOURC&I Opt#~ i spek no.:6,
-troskopiya, v. 14 -1963, 793-797
TOPIC TAW:~ o'scillator strengths,, dispersion,, absorption,, diphenyl acetylene
ABSTRACT:,~-. Thti,purpose of the woric was to meaeuro the dispersion and absorption.of
crystallihe..diphenyl, acetylene in the 0.75 to 17 wy wavelength region, calculate
the oscillator strengths on the, basis of the dispersion and absorption data md -
compare the resultant values. The dispersion curves were obtained by the refflec-
tion procedure, The values of the index of rp-fraction were calculated by means of
'A formula involving the reflection at the cryittal-alr interface and the absorption
coefficient,-which allows of determining the index with an error of 15%. The
frequency dependences-of the index of refraction -and absorption coefficient are
consistent with.classical-ele6tronic.theor,7. The osciUator strengths were cal-
culated on - the basis -of the absorption by means of the usual formula and on the
basis of the. difipersion by means of two formulss lased on the Kramers relations.
The,oscillator i.itrengths computed oil the basis or the absorption and dispersion
CJV4: 1/~

~j , ! ~% - . ~- *., ~j ~ - -
.v . I - . - . - .

-3v Ire;n carriers in silicon
n P" inf ar,-ed
--r- -ad on I
-4., i:einperaturea
Flizika tuerclogo tela, v. 6, no. 9. 1964, 2880-2882
TIAGS: optical phonon, acoustic phonon, phcnon scattering,
T r, n r ri r-~ r t n d e t- P rTn i r, E- r 'h P r c, D ff a I )h,)r c-; s
-a ~ed abnorptl on spectrum o f p-S i i n ~h rec ion i- - 1 5 at
c:~-,a r ac 1- 1 c.3 t

ACCESSION NR.-" AP4044976
C11.;nrl to be ptoportio-ial to the waveleingth rari-ced; to tlhe (1.4 4 0.2)
ard is in crood agreenient with th~z-oript:-` --sults -.-)asc~d Cn
samption that Cic carriers arc- scatterE~l b,/ acoust;~ phorans.
-e=ults al--o indiimta that scatterineg by C4,'Liual photions ie
%. Sa
f-T Drig. art. has- 2 figures and 5 rcr7m.~ I as.

56", 5

Vakulanko, 0. V.; Lysytaya, K~ (Lisitsa, M. P.)

TLE Inves tipa tion o f in f ra re d nbs r) rn 1- 1 in In q 1.1 ,C (,n at ~ii gh temp-

Oij R CE Ukrayins'kyyfizychnyy zhurnal, 9 no. 12 , 1964 1 ~00-' 305

TOP I C CS sili(-on infrared absorpption , e tl~can nfvt ical pl',onon,
fTee carrier, free rzar!-.,~r
The int rared absorptlo,-i .3 p e c t r u ir P - i, ~vr - c m r rim
a i n v ( -4 L i ft a t c d a L L c 6 :ie r. ~i a r a c t e 1 9 C
of ou t i c a i D o n n, r n q 7 Al
n; e r a -:ure of the excitation - 18 1 a n, d 9 4 K
I I i
:u 4! - to determlae the role of o C I o o n s n e a s o r P t i s n
ca r r 1, er s in silicon.
e m;) c r a C LI r V 5
own c. o n du c t t v i t -i v 7)
gracuai c (i a n v e a e -i u D Q I e a 3
c. ar r I e r a is described by Sc h r.t 7; 9
~_-aLterinz of ca rr le C-fl e
2

-41
~A

L 21427-ai
ACCESSIOU NR: APSCO1550

A owii
S chAit the temperature dependence is a
lso :.n apreene
rit jich the

a LI C. VO Lo rmula. This results from the facr.
tha!. thr -Idt
i, of ~he 3 c-~ j d-
f
obtained f rom depen,.,ence az S.IM2 _El~ 1-1i
a- P 'I e n g q 2
-r 1u in t ia 1 v
e 9 c. n e r a v nown al u n r 3 i e t e v ;j j
-0. e d to be three time,; G
13 :1 MCS t :I a t o ;I a
o r).b y e1 e c t r :. ns Ti s co ri i1 3 a e 1 C a
I ,, 1,[ w A 4
e e -~a rease )~
- I
~
re s an f o rmu i a Ei .
Kyyi,,rsk'ky, derzhunive ra y t a t i a C . (KiV
'_'riversic
L 27Jun64 E N C 6
_vw UIJ ra
R I.' F~)'O V 003 OT H 9 2, i 01 '41 A a
~M- VT_7

ACCESSION IMs AP40201LU
IS/006
AUMOR: Vlojenko, K*A*jLiz1ts*, U*P~
TITLRt Optical constants of photosensitive, lead sulkide layei*
Optika I spektrtiskoplys, V.10, n0.2, i964, i97-303
boorption i
TAGS1 Idal.oonstant, reglootionj transwitImeet trIUM1101851ons 9
opt
[!Va
absorption cooffiolent,'Index of rogractiong lad sulfide# lead sulfide coating#
exciton absorption
ABSTRACTI
'n view of the potential value of PbS film and coatings prepared by
chemica
I Procedures-, for detection of infrared radiatioas there were measured the
..-J optical constants of such layers lo the approximate range from 0o4 to 5.5 $4. A fur-!'T
tfier purpose of the work was to elucidate the nature of,the'lons wavelength plateau,
adJacent. to the fundanto lal absorption edge, The thickneas d of the layers were dq-'
termined to within 2% by an interfororActric method. The transmittance T was
ed by means of SP-4 apdctrophotometor in the 0*4 to 1*2 Is interval and by means of;;.-
.:_IKS infrared npectrometer in the I to 5.5 IA range. The reflection coefficients R
"'from the layer vide end,R1 from the Substrate side were determined by comWison,

ACCESSION XPU AP4020933
''the reflection from the sinctmen with the reflection from a standard mirror with a
Imown R; a UU-2 monochromtor with an AgS photocell was used for the visible region':,
measuremen
to; an IKS-6 spectrophotometer for the measurements in the Infrared. Tsie;i
v&lues of the absorption coefficient k and the Index of refraction n were calculat--6:
ed on the basis of the measured values of T, R, RI and d by means of formulas ad-
duced in the paper. The inferred values.are presented in the form of curves and a It
table for n, and compared with the corresponding constants for PbS single crystals$;!
J,taken from the literature. In the 1 to 4 14 region the index of refraction changes
11little, but remains consivtontly below the value for single crystalso In the wave-!j
i11ength region below 3 Ii the absorption spectrum of the films agrees with.'the abs
i.,tion spectrum of single crystlals, but In the longer wavelength region exhibit ad-
:_,ditional absorption that depends to some extent on the size of the crystallites
~~;This additional absorption in tentntively attributed to the presence.in layer crys-,7
t
als of a high c a to de-:,
. oncentration of structure defects, for this absorption tend
=vase with increasing crystallite sizes The nature of the absorption plateau Is
'.,discussed and the absorption In this region is associated with an-exciton mochan-
ism. "Inio authors are sincerely grateful to V*Ye.Lashkarev for his interest In the
;.work and discussion of th.4i results and to P.P.Plogoretsitly and I.N.J(hallmonova forl
2/3
Card.- L - L.;

66' re dese'vibed:for the control oJ
ABSTRACT: pr edtire and~apparatus,a
the- ality~of-the'flat optical surfaces with accuracy not lower than
qu.
0. 01 Of. tbta, wavelength of visible light. , The procedure is based on
Im-alti-frequency multIpath interference, X~rnsdt used by D. R. Herriott
(JOSA v. 51, :L142, 1%1)-.~ The smoothness planeness-of the entire
sitrface can be*checked simultaneously Uy i luminating the sample with
aset-of monoobromatle light beam of nearly equal frequencies. An
af.,~tical diagram of-the apparatus is shown in Fig. I of the Enclosure.
Tae monochromatic set'of beams:was-generated,by-means of a single
,monochromator (UM-2),, witha set of equidistant slits placed in the
ird