SCIENTIFIC ABSTRACT LOZOVOL, A.V. - LOZOVOY, A.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000930630006-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 71
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

so** a* a a& a a a as r a W-w- w-
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0 0
10 a a if b $i V 19 0 11 11 01,01111*00 11 &1 0 40 a
n a w 15 1 F A,
A. - i T 70-110.
so If .-M-M-4 it O's 1-1
09'
go
ISSIS ..o 011croollos -01-
00
Deaftwtive hydrognation of peat. ucer tar
A. D. KharlAmpovicMiWat. -00
v
I-MW19U).-A Ps-productr tar "imift
?do .00
hom Khvmikhr"k pent, cost 75.08. H 9.U. N
a 2.6k 0 + 5 12A2, uh O,W,
%.Or- catbolds 0.0.
00 Al IS! -boxylle &d& 1.0. rAtools V11.0, parallhis and woucs
7.1 %. WAS 117416censted at an initial preawtv of too atm. .09
in tbw pnwpoe MoBs + AlA,!Crvch + Ni + Cu. .60
and MON + AAMI
Ni. HftvY tn& were rerycled
vdth the A". d more H after removal of the fractim b. p see
beim2WO- AykWotupto45%atgasoUrjewWktlrosme
.00
be ObWMd bY hYdrWfttW at 420-M', coo
andw2OD-Watin.lotbepreow OIUA+AIA+Ni.
The product ciNtaim vvy amall amtv. of 3 in san. to 2- ago
3% phenok. wbkh we cattily removed wIth csmk-. The
n-C-4ud *16 1MV shoo" identical for on tlw eawym, too
tbcugb WIN* vk- crackhm was observed for the cats.
a i tes the formsticss ol gones.
'90
=vpubogrnols wW so parafts before bydrow".
tifte did not gt" better
results. UA Promotes the
00 a hydrogavatim of C.H.-insol. compIls. of tar. The moo
active phend-red i catallYsts am Ilo& + AIA &W see
act
+ M.
AJA T N Gasoline b. 40L2301, dw the '00
-al of Pbewh aM bases, bad d,4 0.7974, 1 no. 18.22
moo
wWcwtakwdOAl6%S. Data ch~xrbing the pimper.
ties of comods. obtalfted we tabulated. A. A. B. Zee
&14-~LA OtIALLURrKAL LITINATURIE CLASSO'bCATICIS
--- --- ---- -- -- -= --- too
G-V &if jtoo
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A a IL a L-1 A AL-4-&--A~ A It p u I v A 0 cc W It
00 00
041
00
of Chellablask brown coal. M. 9,
00
of iri
A 1
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l
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h
d
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"
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ir.l. I,,
n
was
rifIrtual"
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y
00 a., SIVO 65", t0f. tht %ICU'.CF I'Aft It, :N111 350". With it

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it,
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ittaiall, It. initul H 1-t4tific, uiLtt Wil
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t'."ll 40u') t%)jjvej~mn Ili I1r&VV slid nit,tistattif till, Vail Iw
00
00
1%,11(med by a %xilivrisl"ll is, Imillivir Anil kirlowlir dl
00 1 It. hli~r
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0

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01
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1 0
444
0 9 0 0 0 0 0 0 0 0 0 0 0 41 0 0 0 4 0 0 0 0 0 0 0 0 o 0 4 0 0 0 0 * 0 0 0 0 e

low so w 11
4 r A It It 14 11 14 1? If IV x M 324,15 24)7n)" Nil W is m Is It 1) W 14 W it it 41 46 a
"I T to kk W it I k 4
a L L a it r u, v V-A L
As is Opim 41 do dwaltail roes
"A sweleft of bomb~t 6# Prim "=.bleak
we" ON. U. am I Ct
submiambe ilEEW4abt-"r tmctka
0 2 end , 1. Cbertkovia. Comps.
Sri. U. R. .5. S. 2. 390-4M(IMS) (its Engfi%h
:0 400J.-Thme"t
00 brown coal conteinal 3?jl% The primry tats.
Ifte 49.4% coml of pbmdv and wide IP or' III
10
'A-tk
00 1.3% of ncpktbtuti~,11.4% of paraffins, 17.2% of unseed.
=66
00 hYdrocafb0w,OA%StNl' . Samidetutral0compldi.
am %,A detd. The mutral "benthat" fraction enoxisting
0 of 40% aromatic c .. 34.0% tinned. compils., 2.70,
naphthirnift OW 22.746 permAns cannot be freed fnxn 5
:*,,3 dtttn. by the usual tumnaus. This and stabillsetion are .400
IS achkvrdc~~b Chao. tion In the Priew-me of h(0,% or
Cos at I ten. land 400' (or 2 hn. This decrems the f A
litme. of named. cowepc1s. which go largefy to naplithene,
with COS Im" to ampletbre" and Parlsons with mm%
00 PIP011% 86 to 111774, of the crude -bansine" i. rmwvmf an.1 roe
If.abambed up to24%of chirp. ThestabUixed"fien. 0
thist" pontains 42-8% momatic compits., 6-17% unsaltd.
cOmPds. 10`25% nalplItheries and 20-30% PlarmAts hydra- ZOO
ccrtioni. It is free from 9 and &talk on storage.
R. Baltzly
l.-oo
AILTAILLURGICAL LITIN&UPIE CLASSIFICA110M
j :Zi AS-SLA
40
It 1 14,10t, - 0
T- I ',-A An
U a 4 IS U It a it It cc i4w n go va
00 0 0 0 0 0 00 000 00 0000 -i~ J11
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1
:
4
1 0 If u a m Is 4 9 10 to i 21 n it 11, 0 v all units 111110R441 90
0
--A-A- I A--a *--L-
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f
1
. O
A ." a
0461.
00
A O=adag the dwmkal =tics. properties sad

d
W
6*dMg Cb*abbmak brown
!
u 00
Cook. 1. Dedrd
l"
.
tloa of ate priamy W
MY = -00
km cbelyah" brows 4eWs. A. V. LuzoM antl
-
so
-00
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M. K, Dyako". J. APOW CWN

C. A. 39, ItKN,. .00
11. The
de the kht tMetift fiven
O
4W k. bz brows coals md the
"= -00
d"
.U
ad the by
*,a
i!=M01
-00
M. K, D'y"an. A.
S. 1. Chenkirva.
-00
J. A pp1W Omm. (U. S. S. R.) 8, 695-7050a Frewh 706)
(193M.-Sm C. A. 29.7001. A. A. BachtUask

000 coo
coo

0*
go*
001 00
NO*
voo
be*

sic", **WtAv
0
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94nogo -d
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U 0 AV PC is
W, tit It Is Kko n old

0
0 a 0 0 e 0 0 0 0 0 0 0 0 0 0 0 0 0 :10 0 0 0 0 0 0
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0
NOW-

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tot
out I i - I - .9 VI .9 U ON 0, -1.1 flu.- a. I Ims- ~11- JL
so A - I I I - I ---- - .~ .
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hydro. ;so
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A62-SLA MIALLOR"AL LIMAIM CLAUVKATM
52t&
I,, f.Ad*9 -d 1 1814".116 ORT age IwIllmall 31 GIN G" It; 0
At Am A I a ado 1161mrIM9,04 9
tip P3 q r I
W a V 11 11 10 1 ~411pl to
0 9 0 40 0 0 41
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0-0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * 0 0
11 is IS it 0 Al -A A I! u )I U b Id J1 m m v 1: tj U 0 o
Oii is
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AI- $1 'VAP!0__P!Tf_# 5, - -I----
00 Al -00
09 c
*0 Wigh-pregaurs hydngintAtion of bitutgna
00 a M. K. Wyakova, A. skand T. G.
SICIPSULSOVS. J. Con. CAwm. W. SMM.) 7. 722-8
a
flitcM.-AlClUnnethyllIentMe 1b, pentamethylbenzene
let rantel hylbenzene (thuctum) (M). PhPr
JU). 1.2.4,15
00 as- and o., on- anti p-xylcneo when hydrogenated In the pres.
I. for
M. of NiCt catalyst at 2twIl Antl 120-2:91 H itim
-'M lots. fialonj ttw j-orrr~pondiaj; d-mrolheml t1&PI'-
11murs wilhoot a cleavage of NIc,.,jpy,) group, 1. 11 jonj
M re.,ollrd front xvIen" with K nd AICI,- I ' -
a! Imp fjoill, was t-olopIrfely hydrogenated after w, h.:
00 autoclavin affostling 01% hetionethyk-ydohritane (IV).
b. 210-101: It ooj4j,j of fracilial b. 210-14",
x I.int '5110, moll 1, '-'14 M'. j. 1.41m. (I:* o.ll
g:
AS.-ILA 49TALLUOGKAL LITER."4111 CLASUPICATICH
1,oint Nt J". Tht, prosturt
was,
=blylini rittst. of rit- anti Ifamt-IV. li ififfffrd in it%
ff o
11111itint"I bV D11H. ft fit. I C, .4. 28, 11711
and front the Coll:. hyd 'W boo,, loolaird by Matwly
from vatiou. peirtilrum pr WILIRC'to. In 21141n. 143 FV. aliout
30% of a kiwer-boiling fraction was (ocrurd
the nature of which is Iwirig invvilticultA. If wa- hvdto~
grunted (tir the Ist mot, ft gAvi
cyclohexanc N) 14 mit voint.l.i. 1.~ IKI 7' 11 - ..:
Wpd. Into 2 liactionli- I-,. INI d', -1.1 1 .14101. .1:, 1 st-1.
M. R.j. IWIM. I'bNII, Itomi Anti 1". IN'. Ni-
1.4.W. d:- IPA214. V mit-ts. diffi-r Imin llo~ -if Iw.
trolcurn picnianittliviml-thoxane it'r 1*1~' fl:'
anti the poulml oblaoiril l3v Straffind i.lam. tomlihuttoNos
hquidlit 4, KI, 317ilv-11ii. 111. m 7!". ml? l4lCL1,
gave na"r than (16";~ 1tv,, 1W
1.5'. ml.' 1. 1XI. d:" 0.71M. 11*11NII, l.olit "o 8% told.
wt. 1311. M. R.I. 411.24 willlcd. 46.1141. It is Wcutical wilb
the proijuvi Inciml. by Aimprit i.4mm. 420, HIM). TIw
following nallbilallicli rrilullrd In licarly throrelh-al ylc Ill
LVIVI, d:' 11.7811, PhNII, illoint 44.9'. I~Wh-riv
th. "1" 1.12-1. iW 11.76-1" I,hNlfl liolint
49.5". 1,4-Deriv., N- I W.L
1.1-4 .5", air d!' it 7M.
PhNII, point 50..V. chala. Platic
lgill*j It tills Vit
to It
00 0 fl 0
1141.
'51
W 0 V -I 'Wr -ii-F -im it
NA
is 0 00 4 0 0 0 0 9 0 0 0 0 0
I
0 0 0
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I I I i I I ? I, I IQ It It it W is is 11 M If 41 It I R It V It M U N U M 41 43 41 0 10
-1 F R- i_- U.-T 1-1 (X U4 A.- I. IL- It L &- A-- I IL A-X- L
00 A . I ." 1~i~
00
.60
0
AIXTUM. Losovoi*
go 6D58. SOME FHYSICAL CONSTANTS OF HYMOCARBON
KV Dyakovg, WA gad StspStoova, TO Q. &an chem u.e.s.r.
Of ff
go 1!376, 7, 1119-1132; u.o.p. surv. for. pistrol. lit. tranal.
00 4 a 38 IM, u.s. bur. min. abstr.) The changes in refractory
go Indexes n 20/0 and aniline polvits of binary
2()D), ap.Sr. A
mists. consisting of monorAoloai~ arazatic9tand the oorresponding
'e "Oo
a naphtheses were dotd., depending ujpon the copn. of the mitt.
060 The data obtained say servo for quantitative anal. of mixts.
0*4 of thin type with sufficient precision. Data for 12
differont binary mix
00- to. are Ubulated. ;ze o
goo
200
moo
tsoe
.(TALtt-ftfK~L UTIENMAC CILASSIFOCA,tCo ttoo
Igoe
T.
r, 1-4 1 too
U S1 A,
19 tP 11 11 at U t It 9t R " U w IM -j-Zj
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it 4 l7 "I it a Ila 21114)l All 11 ~ 1; 11 12 11 ~4 b is 11 m v 4, 44 41 0 or*

it
v
t

00 VS1WAq ad at aronmuc hydro-
y
~
oarbollml. 1. A
,
V.W,,mg,and Ill. K. 1XIAKOVA
GO& Cbom"W V
(J
7
Mt
2977
Th
_O*
*0
00 -
.
).-
e
,
,
rmatiam o(hydrogenation of PhUe, o.. w., and p.
l
-
M
l
d
C I[
it
-
ao,
www &
_
xy
-. Co
us'. PhEt. Phi
,
,
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04 and p-0 v6h
01 caw
,
4
li
5
C
go 0
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ty && 75-
tv=.1.11
M . At <
rio
ty
90 1* of h)drogecatim of Mills In Inde ndent of tho
ps 1.00
0 pire"U". whilet at M-211m* it im cc prmum, over
tho mnge .00-140 atm. It. T.
00

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too

Us 0
I CLAWFKAMN
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1

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4
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A I
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carbon

g:
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W-kimli Vv His is 11 If b a it if a Vv
A-L-UAFILLI-4 W-w A 1~
LAO"fi
EL
mombonis. JL- - X.- Duxovxtlmm~~~
am Chem avAl., I A,
of
WayA (W- IQ!
r
A[^ "a.) to
v m %M. -Vbm a is a* Velocity for
%r Sybuss, 0 has in ow adw P. > p- >
Nam YW, of q to Obtalml for MO
4 PMY. but 9 for Phlir Is > for PhIV.
R. T.
zoo
fee
see
0
0
-09
ILA, SCIALLUVGKALkITINAlUICCLAISPiCATICto off
vjw SONOW
14144,2 it fpV O-C 43,11" HJA4414W&R is
u $$&Y to is[,' 1""I An L t I ~d 0 It WIN14004 III
lp
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9 0, : 00 : :1o 0060 4 a o o e 0 off, *go 0 09 so* 0 *****sees *::I
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:

a it U Is 14 Is L6 it IS a It zz a 14 J3 11 .1 2~ 16 It 13 13 34 Is Is 1, M n 46, it 1.1 a U A3
K-9c M cl 'i~ -L t-L -t-
A
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Of
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00 Sl
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solution of Colds. M. R, I P'Yak'n't. V I A
T. G. Stewtsevu and S
A.
.
'
d
ara
. sti. U. R. S. S. 20, 691-4(lSQS);in E
nsliihl.
Coab ground to 10) mesh were heated I to I firs. in a5llj-
-0 0
in la at 275-410' will; wveral successive
n'-
-h
~~ ;g. , Xent. 'nit- amt. di-Aved wa,,; caled.
.00
th incres-c iis ash content of the Yciidur. ';,Ali.
l l
= ~00
14ow
below X25% cathtlaiiatitm tx-vuY4 alitive 41W.
Each kind of coal has it% own optinnitt, r%ttt 1~liw ; .40
dried C04 A-WAVC1 MOM readily than MOilt. tile dft,. .00
are suitable raw materials for hydrogenati(xi. rliv
A 0
foll.)wing givi-i cogil. siAellt' no. '.f lWorti"lls 4 %i4ient
Si
F -00
-
Av,t
ti-ol and 1wri'village of Coal di's-Olvvd.
lWri4l1 (1l. 3ntln;M-TtlC t'll (111, :t- '%"; too
1, U, i, (tin,ler lo Asm. initial 11, pi"mitrl; cild
ItUI&C brown etial, U, 5, A7.6; young brtown ctml im), '40
11, 2. 7.5.4; M. prituary tar front I (IV), 1. 0 S; saPto-
lKlite M. 11, 2, W.1; V, 3hale-61 diStillAl'! 4VI). -1,
'. V, IV, 1, 79.7; oil shale. VI, 4. M. 1. G. R. Y.
S"itrittion proem io-tho-Rhcollivieur
1- ~1
7)
Mr
9
,
4
-
,
Ii
i
f
i
cat
on o
v~n, are examd. The
iipp
of
varmo: stag"
t lie data oblainefl,to cota. practice it diwilvied, - 1 -

It. C. 11. A.
goo

1.00
A
A OETALLUItQKAL Lr?tN&lWr CLAIIIPKA?tC#
77- _-7
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WYAROVA, Y. Y., WZOVOY, A. V.
V.
"Hydrogenation of Certain Fomologues of Benzene Under Pressure of Hydrogen II, Zhur.
Obshch. Khim., 9, No. 1, 1939. Institute of C6mbusztlble Minerals, Acadelrj of
Sciences USSR, lAboratory of Hydrogenation, Received 5 MaY 1938.
Report U-1517, 22 Oct. 1951.

11 1, is a It u 33 Ad is 10 v a AP 41 41 L144 doomgl
0 A, c A
JY
0
00
t"On 08 ---- - -- relixtures.
Ile Wm)VA, atilt T. (a.
pqTUVL (J. Oeq..~QWm.
Sim
recoftw for
the bbwj sy-items y1ben1eb-&kk'W1u1'c'&w .4 see
10, wtY.1), it. of P.
oe's alk I " W is"My', pl-C ~ x.9s.
or .4-R-propylryclobessne,
indene, jwd te ydrompbtha-
00
00 9dy ickmxe, b.p.
Uatene. M
00, mm., to deveribed. H. T. 0
-00
AA-!
;Zoo
-see
'-oo
woo
tie*
A A 5 1 AEFALLUROCAL 011SArVIIE CtA$jfPKAT1OX U00
*o wool
AT 43 1% il R Ail A
0 Off MSI Ocif No FrUtt 1909M4411 I Ana,
0 0 9A) 0 0 * 0 : 0 * 0 0 * a 0 0 0 0 0 0 $;o 0 0 0
~4do 0 0 0 0 Ilfo 0 0 0 0 0 a a 0 0 0 0 0 0 0 0 0 010 0 0 A

All 0 a 0 0 0 0 0 0 0 0 4 0 0 0 0
Air 0
0
0 4 S A I I I ia It it 11 W is 14 11 is ID it It n it M 11 M is M I? P W W 11 U is 0f&
A r- It- 1 7- -1 J, 4 4 A I
A - 'td
0
11*00 ~
-00
00 ;-*~
0 M!jdjoSj"tlaa YeAftutut of aromatic hydrouirboas -:0
:
4 Re"doot velocity and structure of hydrocarbons. - III
~-V' M. K. D'Yakuva. J. Gex. Chem. i-00
00 IN 4. r. A. M. -52W.
046 51147
I I.-Hydrogestittion velocities vitte dctd.. with Xi +
0it- A" as a catalyst. of a nu. of aromatic 4dromboas to go
establish the influence of the structurt on hydrogenation
:6 velocity. A comparison of the hydrogenation vriocificsof .00
00 benarric boroologs. such as toluene lip to 'Jelylbentelle,
0 mhowed that the lengthening of the aliphatic %idr chain
0 (ruin I to 6 C atonts bad little influence an the velocity 0
00 with which H was abombed by the armatic ring. The
hydrogenation velocities of Am I'll. iso-AmPh. p-PiCill.1te
00 M
and p-cymcne revealed that branching of the ~idr chain 04
0 did not influence tLe hydrogenation velocity. P-Xykne, zoo
0, irtridin and ii-ftC~H.1fe absocti It with the satur velocity.
Frain the prevent and previous rillits. it is cunch,ticef that a;* 0
40Z acither the length ow the structure ofaliphatic sidechains
exertA any pmtkw inflacnce on H absorption by the C.0 0
V !9.
bratme nuckes in the p elance of a Ni catalyst. The
hydrogenation velocity is, however, influenced by the
TO : .00
no. of substituents present In the beturetur nucleus, r. g..
the Shurption of It becosurs watc difficult with all inereas. Zoo
0 ing no. of substituents. Gertrude Befend
0:
10-0.
StIALLUrGICAL UTIMATIAll CLASSMICATION tz
00 81 - ------ -- 10.-.-0.0. too
too
AV 10 is 0 K K Cr It 9 K At N It N NO 11 1 94 All I I I ad 0 W I 1 9 IN 13 Alia 3- 1 VL1;A'
9 It 4nd
0 0 0 0 0 0; ,p 0 0 0 0 0 o 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a
of 0 * 0 #.* * 0 0 0 0 0 & 0 0 0 6 0 0 0 0 *1 0 & r * 0 * * 0 0 0 *to 0 0 0 48~':

w
11121jif nis 011 it ju ~1- -
11 ti b :4 .7 4 ,v A it 1: is 14 11 It u It It 41 Aj 11 17
oo C. 0 1 -I Y ( -I 'A so tx go it 4- j, h j
P
Thermal solution of coal and by U40 of Coe A9
Solutions. 1. sarsass saproinyxile.47T. D'yakova,
J-dlPP1ifd('htM- .00
"Ab-SI (In 1,*rvlwli. MA) I I WO); cf. C. A -
soly, of wAtirtuoy%ite In atithracene t-0.
8 prollary tat and hydfogerat-1 shale tar -as
The optitual conditions for dissolving sapromyxitc, arr~-
ratio of coal to solvent 30. 70, temp. 4(X)-:.5* and litessure
4~-W atilt.: 14-15% of r"al (on the org.
iiat lt;ghcr than,
;
,d. 111v N411s. wrte evalml. 111111ri it 111n), at 1.4u)* 1.) 111)%
atilt hydiogrilill'A ill tile jur% 11"r .4 111~' Mol~ of
9 '1 Ml -140' untirr Initial If. littioure of 1141 lifin. 7--l 9 Ill,
11icie wetcobtainct! oil W.Cf, watrr 1.15,,-rg. residue inwl.
0 15 In C41 1. 2. 1 (im,forr hydrogrnal i.43 gas 4.8 atilt hxw~,
file gas containctl CO Ls. 11'. WLI and C.11..
al."ll N),*~.,f c..l ca's 1w
4P
0~*x
0 0
ki
A 0
a I L a
U VI AT so at
11 it It .1, 64 411 It it a It is it it AO I Q I V to 5 61 a

"7be Speeds of Hydrogenation of Aromatic and Unsaturated Hydrocarbons," Part IV, n1ur.
Obshch. Rhim., 10, No. 1, 1940. Institute of Mineral Fuels, Academy of Sciences USSR
Received 17, July 1939-
Report U-1526, 24 Oct 51.

Ia 1% (M It It H 'A 15 IS
If if is
AA N.V. C214. I
r .2 A - It
- - - - - - - - - - -
to of hydrogestation of afrossfatia: hydraicirlaill". V. srof this to tetrabirdar... and then
0 aromatic hydrocarboust. wtaihy4s,,o Tat fit n,riw, lawl pfjrnarahr~nr 11twitilit tile w.,
0 P*64VT. -4w(1140). Cf (*. ;1. stein Jai lardrowenstiom
j I. , (11. S. S. it.) Ia. INVI
34, 4171-11P.-I'lor fractions studied am- divitied 'intn *I taccur alwitit 11) tinirs f,4*(rr than thow fit group I still ~it
01 Its %Too(, I (all the twandarmations of tattristin twatily the ~tiw Tate har all tractions ill the viltap in 00
0 ID to =11n. Irtrallaydro- to decithydronaplaithadene. 2.6. poup 3 are f(atind the hydrogrnations of l'b,. I'h,C'11,.
00 i Adinattivitetndin to 2,11-dinletityidevalin. and sym-octa. 11h,01 atut thu,"ne. In thew iwn-vmulrn~,l jjur,~. -00
00 1~X, hydio- to 1wrhydruanthracrite. nifte reactiom twe- at Ili% a-k,, atilt A iu,iie ril,44-t. -00
0 seat hYdraiteriation all the Call. ring anal event of tale, Ph. 1101"r"I'Mr, At Ill.. --t, fail, A, C.11.410
elinall 14) thaw .I .01.011"tC41 Call# derival. In groat tile tale --f Niel't, 141,011 -,,-1 thwmie -00
lattlatri,2
0 4t* found hydtogerwailun .4 nal-lithalefir to 1. M,qv 61"Wly thAll air-Ild I- -;wCtird I.v fill. title. All gas 0
aacemplithent to tetishydnmictuaplathene, 2.6-dintelbyl. tile tea,ti-nu w--d at -%-t- -w itelairly v.11111. Tat-.
so i~ uapbtbaktw Ia 2,113-dimethyltettalin, anthfaccuir to ti-ts"lly 1111til file 11-11.1'. III'Migh In
k-a-s tile tat-- 1wili'l, w fjjI .,IT aft"t all,
00 r.49 0
so 000
so .3 to 0
0.
0 goo
00
90
we 0
:500
ides
31
F!ez
t3oo
11140
'Wl ill 41 Go
ja~ I ai-) 't -1
-I ki
V" 1.
9 as of or 41 It it It I
0 of 00 0 41 0 0 0 0 0010 0 0
0 0 o so of go 0 0 0 0 00 0 0 0 -W 0 0 Goo 00 a 0 000611116 0 0 0 0 goo,//

1. LOZOVOY, A. V.
2. 1133,R (600)
"The Influence of Certain Substitutes on the L~Peed of,Hydrogenation of tb-
3enzene Ring" Zhur Obeshch. Khim., 10, No. 21,1940.71nstitute of 'Mineral Fuels,
Academy of Sciences USSR. Received 19 11-'ay 1940.
9. IV Report U-1612, 2 Jan. 1952.
Q-,
iM a

0 0 0 0 0 0 0 0 0 Or* 0 1111 0 0
. .0
to to 9, .0 '1
.
L )RO A" 41. Coates
dowallfts desove.
h

00 y
--
11
1
1
9
4

00A 0
9
4011
11,
#
0
-
Amysp
.00
#*ON -
r"
14 The pmKikVIth
OWO' win
oft 1WM Irm of , 43) &M 4731 And
C" at I to atm. In a MvW alita.
f h
h
d
b
l see

0 racar
ecompa. o
aw at
e c
ve, veladtles t
y
76 nom, Wn I
be suw character of Chaw. nattlely
0 is Pa. tig in the followbW arda -. duclectoxw.
**a mid naotkislent, where ilecalin and
=-
with l"Cly the seine VVI(Wity, -00
r
tly sold toaphths-
Z

*04 h
The "k the
& Igoe
of -3 kilmil velocities of pn
: no*
e00 at 3W. 430 wW 416* am expreamed by the fullawft valises
datleam. UJI, dualln 2.2. walin 1, asOlkskike 027. coo
The emynikomi of V* hydrorlaboau undri IlivrstIptlat; coo
In We dedractive bydiruirrmi6p arv suble" In the Airst See
the cam of slight demnipol. too the law of
=
t
vm1ons. The caled. appm. valun of
.
= to 0

jF Ills imp. mft.ol The YtW~y' of the roaction at decompu. Are*
of bythroiciarbotts in the case of slight
wolf filum fm the temp. "Mac of
2.14. aWfor temp. of M-1750 tube, 1.63 to2.02. The
enerV 0 iscilvailati of the iltempa. of bydro-
cartoolas is expressed by values of the notistiltude of WAW
B
A
f
A
.
.
errum.
.
to 73,OW cial./mal. Twelve re
a illo

glow 40MAR.
-
Wase 0440 04V $61 litinal 0o
WiE - ----

JA A I V ard 6 0 v I w 0 0 a 4 2 0 v -
z
I
m
*

i
i
1111411111o1111 000041
0
t 0
ill 0 0 6 0 0 0 0 0 We 0 a 0 0
0 0 0
1
ire
i
S
0 0 0-6 0 41 0 0 0 0 4 0 0 0 0 0 0 0 0 0 -0 a 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 41 M
-9
M

0 og:*-~ggv:~*.* 0 0-0 w
0 * * 0-0
a w a
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thr
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a c"
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thm
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lk"m sl"qtiv*
0"613 -A 1414W Wit MW tilt Outs t
u a a* so
00 0 0 ; 0 00
oi* 0 sees 'a 0
Pn;.:

IW47301 the a -60

-00
"Ptotoc" .00

a "Sam IN .00
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IH Vw
C
NO*
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k
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t
c
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r
I;AdA=
P. zoo

also
,doe
doe
See

fs*o

NNW "Ni"If
00
0

0 0 0 0-0 6 41-0 0 6 0# O~W# * 0 ,00
-0 000*00*0040000060400
oil I 'I "111211140161IM"Al
L I , U V
00 JL-
0110CIt"I A.D P4C*IMfsI& .Cto
00.
0e.%
W- W- 1W 1WW W VF-
0 411 0 0 0 0 0
1#11 12U its 3,IUANOAI 414j*d 0
'A
f to 0
)1~793. VEWCITlES Of DZCU"I?IMF NTMOC4MXS IN MAUCM VZ
1:
oft f1i BA Q. appl. cham.
HYMOGEHATION. Losoyc,l,__~!_end Sanyavb,
002 u.s.s.r. 1945, IS,, 43-9; u.o surv. for. petrol. lit. trans.
T
004 5478; u.s. bur. mines. abstr ~he previouly reported
experimental data of those authors protaining to destructive
Lydrogenation in the presencls of molybdw= sulphide, are
correlated with litoraUwa data on thermal cracking and
-
a
9 tioncl
tolone drawn pertaining to the affect of virious factors
: in destructive hydrogenation of hydrocarbons. It in concluded

0 thatliquid phase destructive hydrogenation in theyrsoence of
00U suspended molybdenom sulphide is for the most part a wn-
c&tglytic process. With rise of the temperature from 38D to
00 J i;j 475 the activity of mol#bdowam sulphido as a cracking
catalyst apperea%ly inmea"d and a slight drop in the onergy
of activation occurs. The parallelian of thermal cracking
to decomposition occurring in hydrogenation is pointed out.

SM The established similarity of thermal cracking and liquid phase
destructive b4drogon stion refers, not ot t1* entire process,
but primarily to the decomposition of the molecule. This relative
ASO.ILA .11TALLURGICAL LITERATURE CLAWFICATION
)NI; -A 1 1034#3 4g, a.. MIZA31 Got O.W 'it -I
U 0 IV N) It" I a rw
0 0 a I I V
looo*OIOOOOOOOO 001t *000000000004900000
OTIONOOOOO010 so 0 gee 0:0**0:.:::V*1
00000-000000004046000
460
00
.00
~-00
-00
-00
.0
0
see
=00
COO
coo
go*
ass
-Ve 0
'.00
800
'Xoo
800
USIM,
000
000
WOO

00
~90
4141
64
00
00
00
00
0
010
00
00
to
of
velocities of decoaposition of solevAes %dth about equal numbers 00.
of carbon atoms, decrease in the following order; normal pareffinA so
polynuclear naphthenes, partly hydrogenated fused ring aromatics 00
fused ring aromatics, i.e, hydrocarbons with close mobers of to
carbon atoms undergo destructive hydrogenation the more rapidly of
the higher the proportion of hydrogen they contain. otmong 00
aromatics the foUowing ea*los Is formed in the order of in- 00
creasing decomposition velocities$ naphthenen, anthrecese 0 0
(phenenthrens), bensanthracene. Xachalditional ring in the 00
molecule accelerates the reaction 5-10 Uses. In the naphthene 00
series the oorrempondingincres" In 16 tins#. The above 00
regularities at* valid for the temperature range 380-475 of
Within 38D-4" , the temperature oodfficient of the velocity 00
of the destructive hydrogen In within 1.85 to 2.05, the 00
apparefit energy of activation from 55,000 to 650000 cal./sol 00
within 4M to 475 theme values are 1.6-1.75 and 48jOOO- 00
58,000 callmole r9ppectively. 00
00

90
0
00000000000000000000000000000000000000000:0:0
* 0 0 0 0 0 Is 0 * Is 0 0.0 0 0 0 0 0 0 0 , 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 * 0 0

i5t~ 7 qw V
t

ammatid gnd unsaturated:

-
't" a hydrnenition of
"

;Of
ods tion In the Presenae
r
6"... V1, HYdrogem
Ybd.
SboMik Sklef ObskAef-WRIM., AWd. IV414
'
2 -050953); cf. 'CA1 35, 437M-Relative fales. of
*4
;hydrogenation-of monoeyelic aromatic hydrocarbons (C%Hl,
1tePit, 12tPh. iti-xylene, mesityiene, MesC,111) as well as
C11114, cyclohexene, I-rnethyjcycTohcxene, and 1-methyl-3-,
-
Y- IQ-
eye ~WACde *ere diid. in the presence- of Mo,% at 380' and
_J 420' at high'.11 pressure. The rate vf hydrogication is.-
Alff-xt unaffe&ed by Introduction of 1-8 Me p-oups and the
previatoly established rule (10c. cit.) for NI do" not apply in
'
this instance, Neither Is there a noticeable effect. produced
by Increasing the size of the sidechain from Me to~ M4
Tetrohydronaphthalme is hydrogenated about 3 times as
IV, C%Ha about 14 thn as rapidly, and I-methyl-3-
rapid es
cyi:16hexene about 180 times as rapidly as CgH&. In..
troduetion of Me at the paint of unsata. retards hydro-
utlon; e.g. I-methylcyclohexene Is hyxlrogeuattd at a
rate which 13 4070 of that of hydrojenatlem of cyclahexene.
-The rate of hydcogenation of tthylente compounds Is greater'
-cyclic type, whicb L- turn are
than, that of aromatics of poly
Mon reftedve than those of (me benzenoid compds. Atlow
detmes cf converslon the hydrogenation of CjH4 approaches
a zero-order reaction -In -respect-to kydrqcarbcn_4.%d- nearly-
ist.( tr In respect to H. The teinp. coeffs. In hydrogenv
atlon of CHe and McPh In the interval 410-30* are 1.22
J 19, witlz
and zactivation energies of 10,000 and 24,500 cal./
alyzes hydrogenation
mole. At high pressure of H, SloSt cat.
-Mapoff
of C411, even at 240-50 M. KOs

JDZOVOYi--Aj--L -and -SEEAVIN -J A
On the Rate of Hydrogenation of Aromatic Hydrocarbons. VU. Hydrogenation of
Benzene and Its Homologues in the Presence of Tungsten Disulfide, pace 1035.
Sbornik statey po obshchey Ehirdi (Collection of Papers on General rhemdstr7),
Vol II, Moscow-Leningrad, 1953, pages i68o-1686*.
Inst of Mineral Fuels, Acad Sci USSR

lit i'tlattorsflip be--yeta the ;trut;turf,- ,it hydrtwdrb~,ns
"Ild ph~aolzl' afid the rat. of
and ird!xiimi tuidin h di - p it Loin,'%mL,
;7grylich, 54'a 'jC;1S't1 kdd. N, 3':
6t!
dtitructive hydpopezmfi,~a of N~L-] Dis fl'esl;
r~;Ptnr'-; of C
of till atd. FlYW wi~
obiuds, the t;p1luing of moh. by 1lYdr');.FLnatjj)ll
lot Ox fragrrm-11k, 411141 the reductior I)! tfic 0, :IT, avd S
'upifi. Ify(ho,'arban redurtia.-I V.-tv; studied ill thc lifilliJ
C
o
pha-~e at 40-2J-()* aud ;15-70atin, prc:!-,me ,Iml wifli a
'vere first mOuily lrce'l frum trj~~ Of czktaly~'t poir"n-m by
tmut with 94% 1 and Na. At) A14M cmaly~it w7l~
uEW under "catalyfic,,O)y aicptic- condh1wis, r-, ij~-en'-LCd
previously, and the c~daly- t retabu:41 It.-i or;g na) activity
broughoot tlv~ t-"S. IV, M.
- ---------
K~'
IM

o Z 0
U&CM/Chemistry,- Hydrogenation processes
Urd 1/1 Pub#151 - 18/37
Authors v and Senyavin, S. A.
Title Rate of IVdrogenatlon of aromatid hydrocarbons. Part 8.- Hydrogenation of
condensed aromatic hydroc-arbons in the presence of tungsten disulfide
Periodical Zhur. ob.~khlm, 2-4/10, 1803-2-809, Oct 1954
ibstract Therdlative rates of hydrogen,ation.of condensedaromatic hydrocarbons
halenex aAnth3~acene, ch sene and their hydro-derivatives, was-investi-
napht ry 1 .0
gated in the ~vremce of a WS 2cata4st at 400 temperature and a pressure of
150'.atm.. The kinetics of hydrogenation of condensed aromatic hydrocarbons
.~As analyzed.-The results obtained are.shown in tables. The effect of mole-
cule complication on the rate of hydrogenation'of condensed arom. hydrocar-
bops-, in, comparison to the rate of naphthalene and chrysene hydrogenation., is
Wiplained. Ei&it!'references- -6-03SR; 14Sk and-l- talian (1928-1953). Table
I~stitution Academy~of Sciences USSR, Institute of Minerals
Submitted' .'-May 13t 1954

.Mrs;
aise, ar--sl-r-ic.
pe
bd L.,! tc-u-Zl u -L
ft
i~f W-140

USSR/Chemical Technology Chemical Products and Their 1-12
Application. Treatment of solid mineral fuels
Abs Jour Referat Zhur - Kh1miya, No 4, 1957, 12869
Author Kazanskiy B.A., Gonikberg M.C., jozovoy A.V.j Gavrilova
A.Ye.) Blonskaya A.I.
Inst Institute of Mineral Fuels of the Academy of Sciences
USSR
Title Investigation of Hydrogenation of Coal at Hydrogen
Pressure Above 1000 Atm,.
Orig Pub : Tr. In-ta goryuchikh iskopayemykh AN SSSR, 1955, 6, 3-15
Abstract : Investigation, under laboratory conditions, of the hy-
drogenation of coal at '4200 and pressure of 300-1700
a-1w,mospheres, with and without an Fe catalyst. It is
~etown that under the given conditions,the Fe cetalyst
'has no effect on the hydrogenation process. Increase
in pressure from 300-400 to 1200-1500 atmospheres dou-
bles the total yield of gasoline and middle oil fraction,
Card 1/2 223 -
- - - ----------------------------- ------------------- - - - --------------------------

AID P - 2262
Subject USSR/Chemistry
Card 1/1 Pub. 152 - 7/19
Authors : Lozovoy, A. V, S. A. Senyavin and A. B. Vol'-Epshteyn
Title : Activity of certain hydrogenation catalysts
Periodical: Zhur. prikl. kh1m., 28, no.2, 175-184, 1955
Abstract Experiments with unsaturated hydrocarbons, naphthalene,
~
benzene, and tetralin) in the presence of 1
hydrogenation catalysts at temperatures of 420-4500C
and pressures of 180-220 atm. are described. The
catalysts consisted of oxides and sulfides of metals
of the groups 4,5,6, and 8 of the per4odic system.
Four tables, 2 diagrams, 12 references (6 Russian:
1937-51).
Institution: Institute of Mineral Fuels of the Academy of Sciences
of the USSR
Submitted Je 18, 1953

o'-"' OV16
V,
10.1%
% V 1~~ PHAM I BOOK EXPLOITATION 228
Vseso~lye soveshchaniye po probleme iskuBstvennogo zhidkogo topliva i tekhaolog-
ic h gazov. 2d., Moscow, 1954.
Rhimic skays pererabotka, topliva; trudy soveshchaniya (Chemical Treatment of Fuel;
Transactions of the Second All-Union Conference on Synthetic Liquid Fuel and
Industrial Gases) Moscow, rzd-vo, AN SSSRO 1957. 430 p. 2,500 copies printed.
Sponsoring Agency; Akademiya nauk SSSR. Thstitut goryuchikh iskopayemykh.
Eds.: ranin, V. A., Doctor of Chemical Sciences (semi-coking); je~~
Doctor of Chemical Sciences (hydrogenation); Shishakav, N. V., L,)ctor of Tech-
nical Sciences (gasification); Ed. of Pablishing House: Bankvitser, A. L.;
Tbch. Ed.: Kise3jeva, A. A.; Corrector: Bobrov, V. A.
PURPOSE: This book is intended to promote technical progress and to assist in the
exchange of experience among scientists working on the production of synthetic
liquid fuels and gases.
COVERAGE: This monograph contains selected reports delivered at the Second All-Union
Conference an Synthetic Liquid Fuel and Gases which was held in Moscow from
'November 25, 1954 to December 2, 19%. The reports deal with such subjects as
Card 1/20

Cbemical Treatment of Fuel (coat - ) 2-2-R
the theory and technology of semi-coking of solid fuels, gasification, bydrogenation,
and thermal diffusion. The reports also discuss the use of gases as raw material for
the pr.~duqtion of iynthdtid liquid fuel and efiemical products. This Mono-
graph is extensively illustrated with diagrams and tables. For references see Table
of Contents. The following institutions are mentioned in this monograph: IGI AN
SSSR (Iustitut goryuchikh iskopayemykh imeni G. M. Krzhizhanovskogo AN SSSR-Institute
of Mineral Fuels imeni G. M. Krzhizhanovskiy of the Academy of Sciences,, USSR), VNIGI
(Vesesoyaznyy nauchno-iseledovatellskiy institut iskusetvennogo zhidkogo topliva. i
gaza- All-Union Scientific Research Institute of Synthetic Liquid Fuels and Gases),
Irkutskiy gosadarstvennyy universitet imeni A. A. Zhdanova (Irkutsk State University
imeni A. A. Zhdanov), Urallskiy pol-itelchnicheskiy institut imeni S. M. Kirova (Ural
PolyteWmic Institute imeni S. M. Kirov), Institut teploenergetiki AN UkrSSR (Inst-
itute of Tbermal Power Engineering, Academy of Sciences, UkrSSR), Laboratoriya khlml-
cbeskoy pererabotki topliv Institute, teploenergetiki AN UkrSSR (Ukrainian Academy of
Sciences Laboratory for the Chemical Treatment of Fuels), Slantselchimic skiy kombinat
"Kiviyli" ("Kiviyli" Shale-Chemical Combine), VNIIPS (Vsesoyaznyy nauchno-issledovat-
ellskiy institut po pererabotke slantsev-,The.All-Union. Scientific Research Insti-
tute for Shale Processing),Institut nefti AN SSSR (Petroleum Institute, Academy of
Sciences, USSR), Institut energetiki i khimli Vostochno-Sibirskogo fillill AN SSSR
Card 2/20

Chemical Treatment of FUel- (Cont.)
228
(Power and Chemistry Institute, East Siberian Branch of the Academy of Sciences,
USSR),, TsIATIK (Tsentrallnyy nauchno-isoledovatellskiy institat aviatsionnykh
topliv i masel -Central Scientific He search T_nstitute of Aviation Fwls and
Lubricants), GIAP (Gosudarstvennyy institut azotnoy promyshlennosti-State Insti-
tute of the Nitrogen Industry), Saratovskiy gosudarstvennyy institut imeni,
N. G. Chernyshevskogo (Oaratov State Vaiversity imeni, N. G. Chernyshevskiy),
Vsesoyuznyy nauchno-isoledovatellskiy institut prirodnogo gaza (All-Union
Scientific Research Institute of Natural Gas), Vsesoyuznyy nauchno-isoledovatellskiy
institut po pererabotke nefti i gaza i polucheniya iskusstvennogo zhidkogo
topliva (All-Union Scientific Research Institute of Petroleum and Gas Refining
and Synthetic Liquid Fuel Production), VTI (Voesoyuznyy teplotekhnicheskiy
institut im. F. Dzerzhinskogo - All-Union Heat Engineering Institute im. F.
Dzerzhinskiy), and MI (Moskovskiy energeticheakiy institut im. Molotov-Moscov
Institute of Energetics im. Molotov).
TAME OF
CONTENTS:
Foreword 3
Kazakov,, Ye. 1.(IGI-AN SWR and VNIGI), and Bezradetskiy, ra. N. (iGi AN SWR and
VNIGI). Semi-coking of Solid'Fuels and the Tasks of Scientific Research in this
Card 3/20
7777777777277~

Chemical Treatment of Fwl; (Cont.
228
Field 5
There are 14 references of which 9 are Soviet and 5 are &glish. Reference is
A to the following institutions which assisted in the study of raw material for
semi-coking: Irkutskiy gosudarptvennyy universitet (Irkutsk State thiversity),
Urallskiy politekhaicheskiy institut (Ural Pblitechnic Institute), Institut
organicheskoy Vhimii Akademii nauk SSSR (Institute of Organic Chemistry, Academy
of Sciences, USSR).
T4nln~ V.A. (IGI AN SSSR) (Deceased). Role and Significance of Scientific Re-
search in the Effective Use oflow Temperature Tars 18
There are no references and no facilities are listed. The one personality refer-
red to is S. R. Sergiyenko.
Larina, V. A. (Irkutskiy gosudarstvennyy universitet). Raw Material Base for
Semi-coking in Eastern Siberia 23
There are 3 Soviet references. Twelve tables are included. The following per-
sonalities are mentioned: A. V. YAlabina, A. Ye. Favorskiy, and M. F. Shostakov-
skiy.
Card 4/20

Chemical Treatment of Azel (Cont.)
228
Levin, I. S. (UrallskiY politekhaicheskiy institut) Lignites of the Urals and
Siberia as a R%v Material Base for the Synthetic Liquid Fuel Industry. 36
The following personalities are referred to: L. P. Ukhov, Docent, and his assist-
ants A. A. Bashkirtseva and B. S. Gurevich; B. I. Timin, Docent, and his assist-
ants Ye. S. Rkell and Z. D. Kablova. Extensive vork in therml dissolution of fuel
was done by M. K. D'yakova and A. V. Lozov. One table and one diagram are in-
cluded. There are no references.
Shcbegolev, G. M. (Institat teploenergetiki AN McrSSR). Semi-coking of
UIrralmlan Lignite by Means of a Solid Beat Carrier
No personalities are zeferred to and there are no references. The only facility
mentioned is the Energeticheakiy institut imeni, G. M. Krzhizhanovskogo AN SSSR
(Power Institute imeni G. M. Krzhizhanovskiy, Acadeqr of Sciences,58SR). Eight
diagrams are included.
Card 5/20
45
IM

Chemical Treatment of Fuel: (Cont.)
Bkradetskiy, G. N. (VNIGI) and Turskiy, Yu. I. (VNIGI).
Semi-coking of Coal Mims in a "Boiling" Zone
There are no references. Five tables are included.
56
Perepe2itsa, A. L. (Vostochno-Sibirskiy filial AN SM)
Semi-coking of Powdered Cheremkhovo Coals 65
There are 3 references of which one is Soviet and 2 are English.
The personalities referred to are: Ye. I. Kazakov who demonstrated the advantage
of using a gaseous heat-carrier instead of a solid carrier; B. K. Klimov, Cor-
responding Member, ieademy of Sciences, USSR, active in the establishment (1945)
of the first power-chemical plant using gaseous and solid heat carriers at the
Gusinoozersk Power Plant of the East Siberian Railroad; 1. Ye. Kubynin and L. I.
Girshman, Members of Kbmissiya Prezidiuma AN SSSR (Commission of the Presidium,
Akademy of Sciences, USSR). The facilities mentioned are: Elektrostantsiya
zavoda Libknekhte ( the power plant of the K. Libknekht Plant at Dnepropetrovsk).
DPHZ (Doepropetrovskiy parovozoremontnyy zaved -Dnepropetrovsk Locomotive Flepair
Plant), Gusinoozerskaya elaktrostantsiya (Gusinoozersk Paver Plant),Sodovyy
zavod Buryat-Mongollskoy ASSR (Soda Plant in the Bur7at-Mongollskaya ASSR), IZTM
(Irkutskiy savod tyazhelogo mashinostroyeniya-Irkatsk Heavy Machine -building
Plant), Irktxtskiy gorno-metallurgicheskiy institut (Irkutsk Mining and Metal-
228

Chemical Treatment of Fuel (coat.) 228
lurgical Institute), Zavod imeni Kuybysheva (Plant imeni Kuybyshev), and
Institut energetiki i khimii Vostochno Sibirskogo filiala AN SSSR (Power and
Chemistry Institute of the East Siberian Branch of the Academy of Sciences, USSR).
Seven diagrams are included.
Al'tshuler, V. S. (IGI AN SSSR) and Shafir, G. S. (IGI AN SSSR).
Characteristics of Semi-coking of Solid Fuel Under Pressure 76
There are no references. Personalities mentioned are N. A. Orlova and N. D. Lik-
hacheva of the Khar1kov Coal and Chemical Institute; A. D. Kokurina, 0. A. Kry-
lova, F. Fisher and his assistants who studied the effect of pressure on the
thermal dissolution of fuels; B. K. Klimov, Ye. 1. Xazakov, P. K. Kogerman,
V. A. Lanin, G. Ye. Fri-Iman, and V. P. Tsibasov who studied the effect of gas
on semi-coking processes. Eight tables and two diagrams are in::luded.
Kazakov, Ye. I. (IGI AN SSSR) and Malashenko, L. P. (IGI AN SSSR).
Dynamics of Separating Volatile Products in Semi-coking Fine-grained Shales in
the Gas Flow 87
V20 There are 4 Soviet references. No personalities or facilities are mentioned.
Six tables and 7 diagrams are included.

Chemical Treatment of Fuel.(Cont.) 228
Kazakov, Ye. I. (IGI AN SSSR); Tyazbelova, A. A. (IGI AN SSSR); and Malashenko,
L. P. (IGI AN S53R).
The Effect of Thermal Treatment of Ukrainian Lignites on the Yield and Compos-
ition of Products of Semi-coking. 96
There are 6 Soviet references. Six tables are included. No personalities or
facilities are mentioned.
Kuznetsov, V. I. (Institut teploenergetiki. AN UkrSSR),.
Synthetic Liquid Fuel Obtained from Ukrainian SSR Lignite Primary Tar 105
There are no references. The personalities mentioned'are: R. P. Govorova,
A. G. Phdeicheva, A. A. Bobrova, M. K. Chernykh, T. B. Kigell, and P. I. Vorobl
yev (chief mechanic). The above are all staff members of Iaboratoriya khimiches-
koy pererabotki topliv Institute, teploenergetiki AN UkrSSR (Laboratory of Chemical
Purification of Fuels, Reat 1hermal Power Engineering Institute, Ukrainian Academy
of Sciences). No facilities are indicated. Five tables and three diagrams are
included.
Card 8/20

Chemical Treatment of Fvel (Cont,) 228
Nikolayev, G. A. (Slantsekhimicheskiy kombimt ",Kiviyli"). Operating
ling Tunnel Furnaces of the "Kiviyli" MAle-chemical Combine
There are no references. Me personalitAes wient-ioned are: M. S. Kulzhinskiy,
engineer, and P. M. Sheloumov, chief designer. They are credited with producia~g
the original desiga of tunnel type furnaces and L-rbroducing them in the slia-le
industry. Facilities referred to inclLide: Kukht2r.-Yarve Slantsepereraliatyvwj-
u,shchiy zavod (Kokhtla-Yarve Shale Processing Plant), Kashpirskiy slantsepere-go-n-
nyy zavod Kashpirsk Shale Distilling Plant), S1qMt2e-TYye predpriyatiya im. V. Fdng.-
iseppa (Shal- !aant im. V. Kingisepp at Sallamyae- in the Estonskaya SSR), Proy-
ektnyy i nauchno-issledovatellskiy institut mer3tnny i slantsekhimicheskoy prom-
yshlennosti (Planning and Scientific Research of the Local and Shale-
chemical Industry), Tallinskiy politekb--icheskiy inst-itut (Tallin Polytechnic
Institute), and Moskovskiy institut khimicheskogo mashinostroyeni-,% (Moscow Tns-~L-
tute of Chemical- Mar-bin Bullding).
Feofilov, Ye. Ye. (VNIIPS). Prodixetion of Synthetic Li-juid Fkz--l and of Chemical
Products from Shale %Lr
There are no refLerences. The personalities mentioned include: V. F. Pblozov
Card 9/20

Chemical TTeatment of Fuel (cent.) 223
and M. V. Kobyllskaya (both of the staff of VITUPS); H. I. Zel-enin aad S. S. Sen-
enov, who worked with the author in testing the components of shale tar; V. A.
Ijanin and his assistants of the IGI AN SSSR who studied the catalytic cracking
of phenol-free ifaale tar fractions. Others were: A. P. Sivertsev3 0. S. Yair---
tova; L. I* Oulvayeva.; B. 1. Ivanov; N. F. Sharonova; M. V. Pronina; G. N. Gem-
ovskaya; and Kh. D. Haudsepp. The research workers, A. Ya. Drinberg and others
of LKhTI (leningradskiy khimiko-tekhaologicheskiy inBtitnt- laningrad Institute
of-Chemical Technology) collaborated with staff members of the scientific re-
search organizations of Estonskaya SSR. Other or,_4anizations mentioned were:
leningradskiy veterinarnyy institut (leningrad Veterinary Institute); VIZE
(Vsesoyuznyy nauchno-issiedovatellskiy institut zashchity rasteniy-All-Union
Scientific Research Institute for the Protection of Plants); and TslAT124
(Tsentrallnyy nauchno-issledovatellrkiy institut aviamotorostroyeniya im.
P. 1. Baranova-Central Scientific Research Institute of Aircraft Etgines :Lm-
P. I. Baranov).
Lanin, V. A. (101 AN SSSR) (Deceased); Fridman, G. Ye. (IGI AN SSSR) ana
PL-resieni, 1. M. (IGI AN SSSR). Production of Motor Fuels from Generator
Shale Tar
There are no references, personalities or facilities. Thirteen tables are
included.
Card lo/20

Chemical Treatment of Fuel (Cont.)
228
Makarov, I. A., Data Gained from Starting a F4dmgenation Plant 146
There are no references, personalities or facilities. TVo tables and four draw-
ings am included.
Katsobashvili, Ya. R. (Institut nefti AN SSSR). Destructive Hydrogenation of
Heavy Petroleum Residues in Dispersed State thder Low Pressure in a Circulat-
ing Catalyst Flow. There are 16 Soviet references 159
N"; I
The personalitied iientioned axe: V. I. Karzhe-,i,-'Doett~ro:oseiences;-
N. S. Kurk6va ' A-.-.It;; -BrLmiWekhov%*k .',N.-* P. VolzimskiyF and IN. V. -M.darava.
All of "them arle W& Ib6 staff . of the-PetkObum Institute,'AdadomW,of.Sciences,U'SSR*
Ten tables azd two dravings are inciWed,
Lozovoy, A. V. (IGI AN SSSR) and Senypvin, S. A. (IGI AN SSSR).
'ki ~ti ~ ty in Hyd=genation und Decomposition of Hydrocarbons.
Conditions of Destructive Hydrogenation in the Presence of Sulfide Catalysts 18o
There are 5 references of which 4 are Soviet and one is German. The personal-
ities mentioned Include: M. S. Nemtsov, Ye. I. Prokopets, V. N. Khadzhinov, and
I. I. Yeru. Eight tables are included.
Card 11,20

Chemical Treatment of Fuel (Cont. ) 228
Bogi~anov, I. F. (:1GI AN SM). Classification of Catalysts for Hydrogenation 195
There are 17 references9of which 14 are Soviet, one English, one German and
one translated from German. No personalities or facilities are mentioned.
Kalechite, I. V.; Strakova, K. A.; and &tkova, L. M. (AU of the Institut
energetiki i khi-4i Vostochno-Sibirskogo fi3lala AN SSSR). Conversion of
Benzene under Conditions of Destructive Hydrogenation 206
There are 15 references.of which 13 are Soviet, one English., and one German.
Thepersonalities mentioned are: N. A. Orlov, B. L. Moldavskiy, M. S. Nemtsov,
I.-B. Rapoport, A. V. Lozovoy, Ye. I. Prokopets, S. A. Senyavin, and A. Filar-
etov. Eight tables are included.
Kalechits, I. V., Pbpovx~,,N. I., and ~WlftjreAva.. F. G. (All. of them from
Institat energetiki i kbimii Vostochno-Sibirskogo filiala AN SSSR). The Compos-
ition of Raw Materials, of Semi-Products and of Destructive Hydrogenation
Products of Cheremkhovo Primary Tar =16
Card 12/20

Chemical Weatment of Fuel (Cont. )
228
There 18 Soviet references. The following personalities are mentioned: A. V.
Lozo-%- - Ye. I. Prokopets, M. S. Nemtsov, G. S. Tandsberg, B. A. Kazaaskiy,
N. D. Zelinskiy, I. A. Masayen and G. D. Gallpern. The facilities mentioned
are VNIGI and IGI AN SSSR. Ten tables are included.
Tan1n, V. A. (IGI AN SSSR); Pronina, M. V. (IGI AN SSSR); and M2yazeva, M. S.
('1GI AN SSSR). Chemical Composition of Fractions of Liquid-phase Hydrogen-
e!bed Cheremkhovo Lignite Tar d 231
There are 7 references of which 3 are Soviet, one German, one English, one
French, and one Datch. The only personality mentioned is Ye. I. Tomina of
VNIIPS (Vsesoyuznyy naucbno-issledovatellskiy institut po pererabotke slantsev-
P-U-Union Scientific Research Institute for Shal Processing). Twelve tables
are included.
Golldshteyn, D. L. (TsIA=); Agafonov, A. V. (TsIATIM); Hysakov, M. V.
(TsIATIM); and TL-regtilov, D. Kh. (TsWIM). Hydroffning of S4ftrous FL-trol-
eum Products to Obtain Commercial Motor Fuels. 245
Card 15120

Chemical Treatment of Nel (Cont.)
228
The following personalities are mentioned: B. L. Moldavskiy, V. N. POkorskiy,
K. P. Lavrovskiy, P. V. Puchkov and A. V. Agafonov. Nine tables and 7 draw-
ings are included.
D'yakova, M. K. (IGI AN SSSR). The Manufacture of S3mthetic Liquid Fuel and
Chemical Products by Means of Terml Soluti,3A of Solid Fuels 261
There are 7 Soviet References. No personalities or facilities are mentioned.
Seven tables axid 2 drawings are included.
D'yakova, M K: IGI AN SSSR); Vbl'-E~pshteyn, A. B. (IGI AN SSSR); and 276
Sovetova, L: S ~IGI AN SSSR). Development of an Effective Method for Proces-
sing Coal and Shal Slurry Obtained During Hydrogenation and Thermal Dissolution.
T12ere are 9 refirences of which 3 are Soviet, 4 English, one Japanese, and
one German. No personalities or facilities are mentioned. Eight tables are
included.
Card 14/20

Chemical Treatment of Fuel (Cont.) 228
ShiFthakov, ff. V. (IGI AN SSSR). Problems of Industrial Gas Froduction 291
There are no references and no personalities. The following facilities are
mentioned: VNIGI (Voesoyuznyy nauchno-isoledovatellskiy institut iskusstvennogo
z'iidkogo topliva i gaza - All-Union Scientific Research Institute of Synthetic
Liquid Fuel and Gas), VTI (Vsesoyuznyy teplotekhnicheskiy institut imeni
F. Dzerzhinakogo-All-Union Heat Engineering Institute im. F. Dzershinakiy),
GIAP (Gosudarstvennyy institut azotnoy promyshlennosti- State Institute of
the Nitrogen Industry), NEI (Moskovskiy energeticbeskiy institut imeni Molotov-
Moscow Institute of Fewer Eagin6ering im. Mgletov),MKhTI im. D. I. Mendeleyev
(Moskovskiy khimiko-tekhnologicheakiy institut imeni. D. I. Mendeleyeve -
Mscov InstituteaC Chemical Technology imeni D. I. Mendeleyev), IGI (Institut
goryuchikh iskopayemykh -Institute of Mineral Fuels), and VNIIPS (Vsesoy-
uznyy nauchno-issledovatellskiy institut po pererabotke slantsev-All-Union
Scientific Research Institute for Shale Processing). Two tables are included.
Novikov, L. Z. Industrial Gasification of Central Asiatic Lignite5in the
"Boiling" Zone of a Gas Generator for Manufacturing Synthetic Ammonia 309
There are no references. The only personality mentioned is N. V. Karkhov
(GIAP). The facilities listed are the Stalinogorskiy khimkombinat
Card 15/20

Chemical Treatment of Fuel (Cont.)
228
(Stalinogorok Chemical Combine), GTAP (GOBudarstvennyy inBtitut azotuoy promy-
shlennOBti- State Institute of Nitrogen Industry), and Vsesoyuznyy nauch-issled-
ovatellskiy institut iskusstvennogo zhidkogo topliva i gaza (All-Union Scient-
ific Research Institute of Slynthetic Liquid Fuel and Gas). One table and five
drawings are included.
Lebedev, V. V. (IGI AN SSSR). Continuous Metal-Vapor Process for Manufactur-
ing Hydrogen 320
One table and 13 drawings are included, and there is one Soviet reference.
No personalities or facilities are mentioned.
Kashirskiy, V. G. (Sexatovskiy gosudarstvennyy universitet im. N. G. Chemy-
shevskiy). Investigation of the Thermal Decomposition of "Obshchiy Syrt" Pul-
verized Shale in Vapor Flow 333
There are seven references.. of which 5 are Soviet and 2 are English. Plerson-
alities mentioned include V. S. Petelln , N. B. Lobacheva, and V. D. Toarev,
who participated in the experimental part of the research, and V. S. .
Vasillyev, Z. F. Chukhanov, M. D. Zalesskiy, and I. P.Nikhamov. Two tables are
included.
Card 16/20

Chemical Treatment of FUell (Cont.) 228
Anisonyan, A. A.; irblod1ko, N. P.; and Boldyreva, L. A. (All of them are from
the Vsesoyuznyy nauchno-issledovatellskiy institut prirodnogo gaza). Extract-
ion of a Cas Mixture Rich in Carbon Monoxide from Residual Synthesis Gas 341
There are no references and no personalities. Thme tables and 4 dravings are
included.
Anisonyan., A. A.; Volod1ko, N. P.; and Boldyreva, L. A. (All of them are from
the Voesoyuznyy nauchno-issledovatellskiy institut prirodnogo gaza). Invest-
igation of the Process of Incomplete Combustion of 14ethane in Oxygen Under
Pressure for Manufacturing Synthesis Gas 348
There are no references, and no personalities or facilities are mentioned.
Ten drawings are included.
Tesner, P. A. (Vgiesoyuznyy nau hao-issiedovatellskiy institut prirodnogo
gaza). Thermodynamic Calculation of Continued Processes for Manufacturing
Synthesis Gas 358
Card 17/20

Chemical Treatment of Fwl (Cont.)
228
There are 9 references of which 5 are Soviet, 3 Rnglish, and one German. Tvo
drawings are included. No personalities are mentioned.
Leybush, A. G. (GIAP). Catalytic Conversion of Methane with Water Vapor, 03(Mn.
and Carbon Dioxide 372
There are no references. The personalities mentioned., all co-workers at
GIAP,are: B. P. Kornilov, M. A. Shpolyanskiy, 0. V. Uvarov, M. A. Lyudkov-
skayap Ye, D, Shorina., and I, V. Shulyatikov. Three tables and five draw-
ings are included.
Poluboyarinov, G. N. (Vsesoyaznyy nauchno-issledovatellskiy institut po Ivre-
rab9tke nefti i gaza i polucheniyu iskusstvannogo zhidkogo topliva). The
Gasification of Donets Anthracites for Manufacturing Water Gas 383
There are 4 Soviet references. The facilities mentioned are GIAP, VNIGI,
a-,d Sta4linogorskiy khimkombinat (the Stalinogorsk Chemical Cc6lbine). One
ts-ble and four drawings are included.
Card 18/20

Chemical Treatment of Fuel (cont.)
228
Piolmen, M. K. (Voesoy=nyy nauchno-isoledovatellskiy institut po pererabatke
nefti i gaza i polucheniyu iskusstvennogo zhidkogo topliva). Gasification of
Lignites in the *Boiling" 2om.
394
There are no references. The facilities mentioned are IGI, VTI, and NEI.
Three tables are included.
Yermakov, V. G. (Vsesoyuznyy nnuchno-issIedovatellskiy institut po pererabotke
nefti i gaza i polucheniyu iskusstveimogo zhidkogo topliva). The Manufacture
of industrial Ganes by Gasification of Iman Fuel and the Removal of Slag in a
LJAuid State 400
Two tables are included. There are no references.
Card 19120

Chemical Treatment of Fuel (Cont.)
228
Bashkirov, A. N. (Thstitut nefti AN SSSR). So=
Methods of* Developing Synthese's from Carbon Oxides and Hydrogen, and Methods
of Manufacturing Synthetic Hydrocarbons 408
There are 51 Soviet references. The personalities mentioned include the follow-
ing co-4orkers of the author: V. V. Kamzolkia, Yu. B. Kryukov, Yu. B. Kagan,
V. S. Smirnov, S. M. Loktev, Ya. B. Cheztkov,.L. I. Zvezdki , M. I. Khotimskaya,
aud B. N. Dolgov. Institut tonkoy Ichimicheskoy tekhnologii imeni M. V. Lomon-
osova (Thstitute of Fine Chemical Technology imeni M. V. Lomonosov) is mentioned.
Bashkirov, A. N.; I~oktev, S. M.; and Novak, F. I. (All of them are from the
Institut nefti AN SSSR). Synthesis of Hydrocarbons From Carbon Monoxide and
Hydrogen on Silica Catalysts 418
There are 22 references of which 17 are Soviet, 4 German, and one English.
Five tables are included. No personalities are mentioned.
AVAILABLE: Library of Congress
BIC/fal
Aug. 28, 1958
Card 20/20

80317
SOV/81-59-7-24813
0 0
Translation from: Referativnyy zhurnal. Khimiya, 1959, Kir 7, p 464 (USSR)
AUTHORS: Lozovoy, AN, Senyavin, S.A.
TITLE: On the Relative Rates of rogenatio and Decomposition of
Hydrocarbons Under the Conditions of Destructive Hydrogenation
in the Presence of Sulfide Catalysts
PERIODICAL: V sb.: Kh1m. pererabotka topliva. Moscow, AS USSR, 1957,
pp 18o - 194
ABSTRACT: Investigations of the relative rates of the hydrogenation of
bydrocarbons with various types of double bonds (benzene ring
(HR), condensed aromatic ring and Isolated etbylene bond in
naphthylenes) were carried out in an autoclave at 38o - 4750C,
a pressups of 150 - 220 atm, in the presence of Mo and W
sulfides. It was established that an increase in the methyl
radicals in BR to five and the lengthening of the side chain
to C2 practically does not change the hydrogenation rate of
BR iK the presence of MoS2, The appearance of a condensed
Card 1/3 naphthene cycle at BR (the formation of tetralin) Increases
A,

80317
sov/81-59-7-24813
On the Relative Rates of Hydrogenation And.-Decomposition of Hydrocarbons
Under the Conditions of Destructive Hydrogenation in the Presence of
Sulfide Catalysts
the hydrogenation rate of ER nearly three times. The methy! substitutes at
the double bond exert an inhibiting influence in the hydrogenation of
naphthylenes.A A difference In the hydrogenation rate of hydrocarbons with
various types of doublebonds was noted: 1-methyloyclohexene-3 is hydrogenated
180 times and naphthalene 14 times more quickly than benzene (I). In the case
of hydrogenation over WS 2 an increase in the number of methyl radicals in a
one-ring aromatic nucleus to five leads to an increase in the hydrogenation
rate of 1.3 times per each CH 3-group; the introduction of a sixth CH 3 -group
sharply decreases the hydrogenation rate. As to its effect on the transition
from I to tetralin, W82 is equal to MoS 2. The addition of hydrogen to two-
and three-ring aromatic hydrocarbons takes place tens of times more rapidly
than to one-ring hydrocarbons; the transition to 4 rings (chrysene) sharply
decreases the rate of hydrogenation. The kinetic order of the reaction of
hydrogenation of I with hydrocarbon is the zero one and with hydrogen is the
first (over MoS 2); over W32 it is 1.5 and 0.5, respectively. In an analogous
Card 2/3

80317
sov/81-59-7-24813
On the Relative Rates of Hydrogenation and Decomposition of Hydrocarbons Under
the Conditions of Destructive Hydrogenation in the Presence of Sulfide Catalysts
order the temperature coefficients of the hydrogenation rate of I are 1.22 and
1.30; the apparent activation energy E. - 19,250 and 25,370 cal/mole. The
conclusion was drawn that MoS2 is a more active hydrogenation catalyst, but
W32 is more sensitive to a change in the temperature, concentration of re-
agents and the structure of hydrocarbons.
N. Kelltsev
Card 3/3

LOZOVOY, A.V.; KRICHKO. A.A.; MIMYVA, R.A.
-26- .. - ~,,
.1 Hydrogenation of enriched Baltic Sea region 2hales under low
presours. Xhim.1 tekh.topl.1 m9sel no.5:32-40 My '57. (MLRA 10:7)
1. institut goryuchikh iskopaysmykh AN SSSR.
(BnItic be& VegIon--,qhR1e8) (Hyrtrogenntion)
.-:, I-jp4 ~ -
,~~ - iA -N-M~-

-,-LOZOVOY, A.V.
Safe operation of gas networks and installations. 7,ezop.truda v
prom. 2 no.9:20 S 158. (MIRA 11:9)
l.Glavny7 inzhener kontory Odessgaz.
(Gas dietribution-Safety measures)

BDDN5KhYA, A,L; WZOVOT4 A,V.; MNLVVIGH, D.L.; RiLTIKOVICIII T.M.;
TITOVA, T.A.
Tvro-stago layott for the hydrogenation manufacture of inter-
mediate chemical products, motor fuels, and ganee from tare
of Cheramkhovo coals. Trudy IGI 9:5-14 '59. (141R1 13: 1)
(Fuel) (Coal tar)

BLONSKAYA, A. I.; WZOVOY, A.Y.
"
Lower phenols content of the liquid-phase tar hydrogenate
of Cheremltovo coals. Trudy IGI 9:15-25 '59. (HIM, 13:1)
(Phenols) (Coal tar)

.. I I ~ ~ : - - q -7'~,fs-, ~ ~- - 1,
KRICHKO, A.A.; IOZOVOT, A.V.; PCHELIW, D.P.
Now technological layout for hydrogenation processing of
semicoke coal tare under mnderate pressure. Trudy IGI 9:37-49
'59- (MIRA 13: 1)
(Goal tar) (Hydrogenation)

BLONSKAYA, A.I.; DDZOVOT, A.Y.; GhVRILOVA, A.Ye.-, GOIIZKBM, H.G.;
KAZANSKIY. B.A.
Investigating bydrogenation of lean coals nnd antbracitee
witb a bydrogen pressure greater than 1000 atm. Trudy IGI 9:
50-61 '~9- (Coal liquefaction) (MIRA 13:1)

KRICHKO, A.A.; KOWASHIIIA, R.A.; L040VOr, A.V.
Hydrogenation undar moderate pressure of cleaned Estonian oil
shales. Trudy IGI 9:68-85 159. (HIAL 13:1)
(Oil shales) (Hydrogenation)

ZAKHARIUM , V.A.; JLOZOVOY. A.
Ll-~
Comparative activity Of technical catalysts of the vapor-
phase bydroger-ation of fuel. Part 2. Trudy IGI 9:96-1o6
159. (14M 13:1)
(Hydrogenation) (Catalyste)
'F

LOZOVOY, A.V.; SENTkVIN, S,A,,- SOV=VA, L.S.
Transformation& of somo hydrocarbons during hydrogenation in
the Oenance of aluminosilicate catalysts. Trudy IGI 9:122-128
159, WILk 13:1)
(Hydrocarbons) (Hydrogenation)
N
AT

LOZOVOY, A.VI - ~i "
j
Relative rates of the reduction of alcohols under pre3sure of
hydro on. Tinidy IGI 9:148-153 '59. (MIRA 13:1)
~Alcoholq) (Reduction, Chemical)

D P SOVLTCVA,
G-ez:lcal products from nongyrolly-Zod, tar obtAined by continuous colcing
o--,' lfuznets~'-- coal. lzv.Sib.otd.;C0' Z53F no.12:~~95 160, ("P-A 14:2)
1. Institut goryuchikh is!;opaye:!-y',:h All SSSR.
(Coal-t~x pixducts)

5. 34 00
AUTHORS:
TITLE:
PERICDICAL:
ABSTRACT:
Card 1/5
r 7
I P I 11.) a , [i . N
Conversion of' Some Hydvocavbono on ion in
the Presence oi' Alumina-Molybdena Gatalyst
ZhUPrIal prilcladnoy khimil, 11)(JO, Vol NP 1,
pp 216-222 (USSR)
The chemistry of' convevsions of' 2,2,4-trimethylpentane
a mixture of C -C . n-paraffino, ethylcyclohexane,
ethylberizene, decalln, by de6 trLIC t: I lie
hydrogenation at: 75-100 atm and at 510 In the
presence of' MoO,+AlID07 was Investigated forn the flr3t
t ime .The chap ctei-I i' destrUCtiOn in all cases.
depends on hydpogen concentoation. The conversion ol'
2,2,21-trimethylpentane undi-~:, above conditions is givel
by (A). (Hydoogen ~ 0.9-0.'( ;:-/mil hour.) The conversion
of ethylbenzene ,-md ethyleyclohex,tine 1.--; ,,hown In (FO.

Conversion of Some Hydwoc~-a-bori~' on 7 7
Hydrogenation in the, Pr'e~sence of Alumina-
Molybdena Catalyst
2/5
elf, ell,
I - 1 +11,
MIN n I UCROA) 411, Orro CH,,
t t1r,
cu, Lit,
(Hydrogen = 0.9 g/rnl hour.:) The conversion of clecal-In
and tetralin is shown in (C) . (Hydrogen = 0.9 g/ml hour's
The degree of conversion at 300 atm is of the follow-LIng
order: tetralin > C -C,,-n-paraffins > Isooctane
> ethylbenzen(l, e~Ryl _yclohexane, > decalin; at
75 atm: C ] - 0' -n-pavaffins > isooctane > Ic-etral-Y,>
> ethY1cYcI;C)'-4;ane' > decalln > ethylbenzene.
There are 3 tables; and 10 ---eferences, 4 Soviet, 2 US~
2 UK, I Japanese, 1. French. T I U . S . a n!- I U. K.
(Yer
reforctices avcl: Hu'l, Fue L'2, P)5-5) ; V. 'N. -
Ipat'yev, J. Am. Chem. Soc., ~ Q , -] i
-'5696 ('()z-"); 'Ft. Slotboom,

1. yb de, t.;
CH
Ch 4 3 'H,
CV11
CH
cli
oki(,

V
17:

Cor,versLon of Soule o,-,.
.4,irdrggenat tar, Ln r;' e F!*;~ Sol I
Molybdena Catalyst
Perrolleur, P
ASSOCIAT TON: T--u~e 0' Fosz~'Ll Fuel~3, At--i--Ieq~v o,,' 15,nen.-,e~3- SF,,
0,
ae
SUBMITTED: Decembet 5 P
Card 5/5-

S/080/60/033/04/33/045
TITLE;
PERIODICAL:
lozovoy, A.V., Sen3ravin, S.A., Sovetova, L.S.
On.the Transformations of Benzene, Cyclohexaneland Isooctane in the Case
of Destructive flyk2onati-on=
silicate Base the Presence of a Catalyst WIth Alumo-
Zhurnal-prikladnoy khimii, 1960, Vol 33, Nr..4,,Pp 947 - 953
TEXT: This is an.,investigation of.the chemism of destructive hydrogenation of
benzene, cyclohexane and isooctance in the presence of a W-Cr-Zn-S-F-alumosilicate
catalyst at 5100C and a pressure of 300 atm. It has been established that the trans-
formation of benzene takes place by hydrogenation (about 37% of benzene reacted) with
subsequent isomerization of cyclohexane to methyloyclopentane, the destruction of cyclo-
hexane, methylayolopentane and other saturated hydrocarbons with a number of carbon
atoms in the molecule below six, and also in a small degree by alkylation of benzene by
methyl and ethyl radicals., It was found that~the destruction hydrogenation of cyclo-
hexane (depth of transformation 48.4%) includes its isomerization into methylayalopentane,
the destruction of naphthene rings with the formation of paraffin Cl_C6 hydrocarbons (in
which case among the C C hydrocarbons the isoparaffin hydrocarbons prevail) and a weakly
4_`6
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S/080/60/033/04/33/045
On the Transformatiora of Benzene, Cyclohexane and Isoo*ctane in the Case of Destructive
Fjdrogenation in the Presence of a Catalyst With Alumosilicate Base
developed reaction of oyolohexane alkylation. The destructive hydrogenation of isooctane
proceeds very intensively (73% transformed), the main product being isobutane (86 weight %
of the isooctane transformed; 8.4% are propane and 4.4% n-butane). Under the conditions
of destructive bydrogenation one of the C-C bonds of a quaternary carbon atom of iso-
octane is veryweak. The hydrocarbons -investigated are arranged in the fo34owing. series
+-EormAtlon rate- isooctane -;p cyclohexane benzene. Under the
1_-1r-dftf-3nO - - --- ~-P 200 atm the
4-".A1AVLUA rtrj~-!M-S of deatructIve h7droge-la'tlon or
aota,=z ol eyalIzatlazz and idrOMAIi.-MiTu- bs TA
are very weakly developed, There a": 3 tables and 2D releranoss, tf vhiolh are Savlat
and 2 English
ASSOCIATION% Inatitut gorruchikh lskopaysvVkh AN SSSR (Institute
AS USSR)
SMK7M% Septqmber 11, 1959
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