SCIENTIFIC ABSTRACT LUKYANOVICH, V.M. - LUKYASHKO, D.N.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

IF F tuc t ro n -i it It roatup ic Htady of Wloldal objectives by'
luttaxis of development. A. V. Frowlicry, 1@_.W_Lu"
yd" int,"Ya, L. V, HaOnsliltvich, and K. V.-
S R: "lell, v. v. N'
)In ')V'
J, CA, 47, 971W.-'11je inethod of development (ti, CA'
46, 18,126).as a.nieans.of detecting, %vlth the _ckarciu-mi-
a"I structlires of colloidal prepno. la fur-
ther drmomtruteti with Zn(011)s hydrosols (1) and with'
dil. eoins_uf tobicco 'rumalc vints (11). Colloidal Ag
fornied by reduclug 0 ,O&N ALTNO, in I with I drop of 170,
.'hydratine Is condenkid at the sharp edges with noh@, on the
ufneecifthepl4tesofil
An fomied by reduting 0.2% AUC4 with I drop W 1%
Ircauw of the opaNty of I the dry preptz.*1
NHOH-HCI, L
on the cellulose fifin I;i treated with a drop of 0.01Y HCL
th 1* tdd phase:b1atted -off trith suffi- of Biter 1xipa,
%,uhci vith litt); and dtied, The outMici cd I,Lhus test
(Cre tiliiierved by prefiniftuiry infrivetion Wotq-@t4e ocid treat,
incrit.- Colloidal Ag formtd by mductinn with Lydrazinc
In a coodess"S at ilia sharp end-to-Lnd leiintri of the Tods of
11. None coittlemes on tile surface., Unlike with ViO,
-n tin
tn(fcctthedhtz1-
hittlaitof Agon IL,-this indicates w3tunlyttillsutropybu
@Jl
Aw a tnore conipatt, luiperintubbe, (to Al

KADANER. D.G.;-LUKIYANOVI-CH. VON&; RAI)USMVICH,.L.V.
Adsorption and capillary condensation of Tapors on nonporous carbon
black. ]Doklady Akad.Nauk S.S.S.R. 87, 1001-4 152. (MLRA 5:12)
(CA 47 no.14:6734 153) /@ I X

WBININ. H.M.. akademik. otvetstvennyy redaktor; KIBBIJCV, A.V., professor,
radaktor; LWYANOVICH, V.M. kandidat khimiche6kikh nauk, redaktor.
[Methods of studying the structure of highly dispersed and porous
bodies; transactions of the conference of June 25-29, 19511 Ketody
iseledovaniia struktury vyeokodisperenykh i poristykh tel; trady
soveshchaniia 25-29 iiunia 1951 9. Moskva. Izd-vo Akademii nauk
SSSR, 1953. 16) p. (MIaA 7:4)
1. Akademiya nauk SSSR. Otdoleniye khimichookikh nauk.
(Porosity) (Adsorption)

BROHBERG, A.V.; UJKYANOVICH, V.H.; NEHTSOVA, V.V.; RAIYJSMMVICH, L.V.;
CHMUTOV,
Electron-microscopic study of vanadium pentoxide sols. Zhur. Piz. Khim..
27, 379-88 '53. (HLRA 6:5)
(CA 47 no.19:9717 '53)

7".

AUectron mWoccope studies of the form of the contlnuo I

R par" *(activated carbons from sugar. V.%,LLxtk')-.xtioY1c1t
:
a V Wtalikevich. Doklady A
l 91,185-7@1053).-By continuous pore is nitant an tinin-
tempted canal of minute diam., pas,ting all titc way through
4L material particle. Cirbons madc froat Ougar tad a,:ti-
vated by inorg, addasi have,44sorptlon properti"- thit sug-
gest c of continuous pores and, at the utne time,
the=
r the
ti
d
m
f
b
on un
e
a am easy to prep.
or o
s
a
clectm rukroscupe. Three sets of photogruphs show:
!(A) Wnw Pok:e 4 X.13,40;L (b) ran of (a) at X 47,OW
with a dear Case 01 !ontilluous part; (2) thice III
sugar carbons X 47,WO;
-rubon at X
scope pbotogrugh of Sligar t IIJX)O@
cr
ljontinUOUS pCge, are wid to itave di,.ncu!@jon, J.thQ @rd
of 10-4-10-6 cm., adsotplion M@asutclj':1'1@ it-Ac'!EOL 01@kt
j adivated sugar Coke conwln3 a 1:417ge: Ito"Or
of 10" cin V. It.
order
diams
afthp
,
-
.

Ail" J_@ f@

The Comaittee on Stalin Prizes (Of the Council. of Ministers LMR) in the f LeldAo of
science and invention announces that tbe folloving scientific vorks, popular scien-
tific books, and textbooks have been suInitted for competition for Stalin Prizes for
the years 1952 and 1953. (Sovetskaya Wtura Vascm, No. 22-40, 20 Fab - 3 Apr 1954)
Name
Chm-utov, K.V.
BromberGy A.V.
V.11.
lfe.at:3ov,
Luk Iyanovich, WM.
i@aadushkevichy L.V.
Title of Work
Inves tij!ati oil bY ""IectrOll-
IllieroS@.07)e 0, the ?i:le
Structurp anrl I ror),@rties
P
of Collr)icls"
fkadnated by
institute of Physical ChemiStry,
Acaderry of Sci.-mces U33R
SO: W-3o6o4, 7 July 1954

to ap toduc 0
a 9 944 out
A
3f a
mot,
Of
d
replica pro
uction W= used, the callodlon and the t 4
C

-s were first -treated wit IF,
q=e. @ The sampk '
P
I
L
e troo-takrawope ple-tures at 14,000 magnifo--Ations
showed that the SiOr gel consisted of somewhat elongated
rounded pankles. The porous glass photomicrographs
exhibit a different. s1ructure, namely a blistered, spongy
strature. with Pam of the order of hundredths and tenths
of So. These parts are expL41ned on the ljasii tit

arm
las I ation method in whIch sol, Components Tle
Was-Uleste gtw. -i

anov I bm
4,@&nd=Jr. f0kc U. A. Levativ V M
aud- Z. Ya -4S kat'skil (Pof@rtcch. Im
ffauk 1050,
-wil.- Ake uk 5

Category : USSR/Atomic and Molecular Physics - Liquids D-8
Abs Jour @ Ref Zhur - Fiziks, No 3, 1957, No 6432
Author :L h V. M.
L
Title ; Methods of Investigation of the Structure of Highly Dis-
persed and Porous Bodies (Conference in Leningrad).
Orig Fub Vestn. AN SSSR, 1956, No 0, 101-103
Abstract On 13 -- 18 June 1916 there was held in Leningrad the Second
Conference on Methods of Investigeticn. of the Structure
of Highly-Dispersed and Porous Bodies, organized by the In-
stitute of Physical Chemistry and the Institute of Chemistry
of Silicates of the Academy of Sciencec, 'USSR. A brief
contents of the papers end diEcuvaions is given.
Card 1 1/1

LUKIYANOVICHIP V.K.
lmk 11
@ TV,
-"./ -i - VVN@K ---'
Second conference on methods used In studying the structure of
highlY dispersive &ad porous iolids,.Ixy, AN SSSR. Otdkhim. nank
no-lltl423-1426 N 156. Wak 10:3)
(Sorbants) (CaLt&l7sts)

j@.j
KISEM, A.V.; LEONTOYMV, Ye.A.; IUK'YANOVICH. V.M.; NIKITIN. Tu.S.
Adsorptional and electron microscopic Investigation of the struc-
tural changes of aluminosilicate catalysts. Zhur. fiz. khIm. 30
no,10:2149-2159 0 '56. (MLRA lo:4)
1. Institixt neftyanoy prom7shlennosti, Adademlya nauk SSSR, Inati-
tut fizichaskoy khtmil, Moakwao
(catalysts) (Aluminomilleates)

LMIRT ITEEV, Ts.A.; LUKITANOVICH, V.M.; HILIMAN, B.S.
Electron microscopic investigation of the structure of
spheroidal graphite in cast Iron. Dokl. AN SSSR 112 no.
3:461-463 Ja '57. (MT-RA 10:4)
1. Institut fizicheakoy khimii Akademii nauk SSSR I TSentral'M
nauchno-iseledovatellskiy institut tekbnologii I mashinostroyaniya.
Predstavleno akademikom M.M. Dubini-,Wm.
(Cast iron) (Graphite)

WO-AITUTICH, V. I.I., DUDINTIN, M. 1-11., LLONTIYEW, Ye. A., MXLCHOV, A. i.
"Examination of the Porous Struesture of Activated Charcoals."
paper submitted for presentation at Fourth Int'l. Conference on Electron
Microscopy, Berlin, GFR, 10-17 SeP.68.
Institute for Physical Chemistry, USSR Acad. Sci. Mosew.
Iff
C-3,800,829, 25 Jul 58.

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SO',T/58-59-7-15876
Translation from: Referativnyy Zhurnal Fizika, 1959, Nr 7, P 176 (USSR)
AUTHORS- Leontlyev, Ye.A.,_j; @Iy@n@ovich @V_ _
TITLE: Electron Microscopic Stuaxlf the Structure of Porous Bodies Using the
Replica Method
PERIODICAL: V ab.: Metody issled. struktury vysokodosperan. 1 poristykh tel. Moscow, V/
AS USSR, 1958, pp 19 - 36. Diskus., PP 37 - 44
ABSTRACT: The authors describe various methods of preparing replic@s for the study
of the structure of porous and highly dispersed (single-stage colloidal
and carbon) bodies, and two-stage polysterene-quartz, colloid-quartz, and
colloid-beryllium bodies, preshadowed with chrorium. They carry out a
quantitative check of the accuracy of the replica method for particles
- 100 X in size. The results of this check show that the various replicas
yield very similar data. The authors note that It is expediOnt to use
stereoscopy for the study of porous bodies. The bibliography contains
24 titles. (In-t fiz. khimii AS USSR Moscow).
Card 1/1 A.N.P.

AUTHORS: Leontlyev, Ye. 7 M
Neymark, I. Ye., Piontkovskaya. @M.
TITLE: Investigation of the Structure of Titanium Dioxide Gels
by Independent Methods (Issledovaniye strul"tury
geley dvuokisi titana- nezavisimymi metodami)
FERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimiche.--kik-h -:aul--,
1958, Nr 9, pp 1o37 - 1044 (USSR)
ABSTRACT: In only a few papers on the structure of titanium dioxide
gels is the dependence of the catalytic and adsoipt-ion
properties of titanium dioxide gel upon the conditions of
their preparation exclusively considered (Ref Tile
porous structure of the titanium dioxide gels is not
considered in this paper. In order to get a comprehensive
conception of the structure of these gels and to define
more clearly the various methods with which they may
find pract-'cal application the authors of this paper
investigated titanium dioxide gels of various structures.
Independent mc-thods of investiiSation were used. Working
Card 1/3 in cooperation with the Institute of Phyoical Chemistry

Invest ijrat ion of the Structure of Titanium Dioxide 3 1,7/;@ 2 - 5E-- 5 -4/12
Gels of Independent Methods
AS UkrSSR (preparation of the titanium dioxide gels
of various structures and investigations on adsorption
and structure) and with the Institute of Physical
Chemistry AS USSR (electron microscopic, X-ray, and
electron diffraction investi.-ations) they obtained good
results. The adsorption and electron microscopic
investigations were extended to a series of gels of
titanium dioxide, which was pre --,ared by the hydrolysis
of titanium chloride. The gels consisted of spherical
particles which appeared non-porous at first sig1it. The
specific surface area of the gels depended mainly on
the size of the particles, whereas the character of
the porosity depended on the size and the density of
packing. The pores appeared as interstitial spaces
(between the touching particles). T'-,e exchange of water
present in the gels for other liquid of smaller surface
tension made it possible to adsorb larger particles while
maintaining the tight packing of particles. incr-asing
the formation time for tile titanium dioxide gel in the
Card 2/3 formation solution diminished the porosity as a result

Investigation of the Structure of Titanium Dioxide
Gels of Independent Methods
" ly
of the adsorbed particles becoming more close
packed. There are 7 figures, 2 tables, and 14 re-,erences,
10 of which are Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
of Physical Chemistry IAS USSR) Institut fi,:icheskoy
khimii im.L.V.Pisarzhevskogo Akademii nauk Ukrainskoy SSR
(Institute of Physical Chemistry imeni L.V.Pisarzhevskiy,
AS UkrSSR)
SUBMITTED: March 28, 1957
Card 3/3

3107Y60 )4/009/0115/0,-z
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B015 Do 5
LMORS: Dubinin. W. II.. 11ohn nk@vs. W. V.. 23..
L*onklye v, To. A.. U.,'3
A7

Lr .1W. by S---
for St "r-g
th
3tr. ctmr. of Lct.ft.di.t. and St..r.-;c f A.111.
:1
FrRIODICAL: flsI.hs.k.y kbI.11. ?00, 1.1. 34, 3.. 9.
vp . 2019 -2029
A thoravu 6b IM-St Igettom Of the truct- @f i.t.r=-.jiAt. pores.
a .
.has. j.. 1. bet.... micro- - . of -a- lypic-I kl@d- I
Ay_!4 to
;aal (from the type AY-10 - (AU-10.; AU;I )) "Ib ln@-'
0ra :Sty is carried out by- the method or 'IIis y4co"'2.'i.. a.
(ban as or by ;r ... I,g is nor ry, or b 11
a or. -o.ad
Data concerning the vclu=qs of the i ati%.he
in-tig.t.d kimis of coal -. g'-. is t.bl. end h.- %he% in %11
Card 1/3
those of the i@--
par.* by . multiple. Th. S.4 rri.1 .,%
evithnitrogen ,,or, I , sod is, toIth I-rtz
a pt n . bt 10."1". 1*
04.1-8. A detail.d.. ; 'b 1, R.f.
) S1-.hC,p.'
sorption isothermal lines (7igs. 1-3 1
the beginning of b-'rt corrv.;..d! tc@ the pr:...r-
'/p 0.175 far b.m.:n' 11 10 C and (P/P.) 0:41 ',,r.,Ilrg a t
-1959CO f .- i
. . rby h'j
;,For.tb..#aorpo;. . dot.rainihg %be ;.rc, t ..: ...
f pra 1.4 is raw . tes par- I-ug- f the typ. nA-4.(PA-4j(H.f a)
(an. far is. and as. r.r high pr .. I-) -. ..ad. Far .1
topic a Y3M-100 ( electron ztcr.-p . ... ... 1.
earbon replicas or* recorded (F 1,. 13. -1 par, ll,,,I*r* from
v to
I a . . 6@h. , i. . ...he
1 0-:4-1, 7h, I-Mti h-l -Ir I
ist .".I *L.ith -p..1 to the. of.. h! *I,.:. r.
..I*ul.%., toarpti@a isotherael. lines for b ...... .4 .or.ei -aw
from
Card 2/3
%*murr. .1 . r. ntoo. of th@..911@
4 g t
ey A-M."-f.r'm ages, go a
it r I:h
.131 f...d. Th.
so. It .Iu*. qI&ILIattvoly confirm the sorplitn v4luftl -A the cs-,r.4
values obtained by pressing in sort' B. F. 'R.ri.q @I V.-T. S-i-ki'
- th..k.4 for their Interest in th7p-rosent paper. Th .to or* a
I Wile, and 13 rv foremcon: 12 3ovi*t and I
ASSOCIATION- Lkwl.mlya soak 33SR in.tit.t flatch-koy khicill
LCAI12Z-2f SC19,CV, USSR, T@Y%OAt. of P".I@.l C@-i't@T)
snun-nD, December 24. 1958
card 5/3

LLTKIYANOVIC11, V,, M.; RADUSM,V1CRj L. V..; TSITSISIMLI, 0. V.; YFRMOLE-NKO, N. F.; DUBININ,
M. M.; BERING, B. P.; SERP1NSKIYj V. V.j
YThe adsorption from vapors and liquids."
report p"gmted at the Your+.L All.-Union Caaferame on C0110idal Ck-l try:
Tbilisi, Gecrgjan SU, 12-16 May 1958 (Loll ZIMWJI 20,5, p,67-9, 58, Wubmn, A,B)

AUTHOR: Luklyanovich, V. M. (Moscow) 74-27-6-3/6
TITLE: The Present Stagsof Transmission Eiectron Microscopy and
Its Application in Physical-Chemical Investigations
(sovremennoye sostoyanlye prosvechivayushchey elektronnoy
mikroskopii i yeye primeneniye v fiziko-khimicheskikh iss-
ledovaniyakh)
PERIODICAL: Uspekhi khimii, 1958, Vol. 27, Nr 6, pp, 690 - 716 (USSR)
ABSTRACT: In his introduction the author gives a survey of the develop-
ment of electron microscopy since the construction of the
first electron microscope (1932). The technical possibilities
in the field of electron microscopy increased especially in
the course of thepast 2-4 years. A number of newly published
surveys is mentioned in which the development of electron
microscopy is discussed from various points of view. (Refs 7-12).
Paragraph 2 deals with -the basic methods employed in investi-
gations carried out by means of electron microscopy such
as: 1) Direct investigation of the object in the electron
beam passing through.
Card 1/3 2) The shadow-casting method employed for the purpose of ob-

@@i/74-27-6-3/6
The Present Stage of Transmission Electron !ficroscopy and Its Application
in Physical-Chemical Investigations
taining better contrast effects when reproducing the object.
3) The replica method: A thin film is removed from the ob-
ject, which reproduces the surface relief of the said ob-
ject. The bases of this method are discusse@ : Bradley (Refs 359
36), Kiselev, Leontlyev, Luklyanovich, and NiKizin knel qz),
Adams, Voge Oef 43).
4) Extraction replicas- 5) Ultrathin sections. 6) The "en-
closure" method. 7) Cooling and heating of the preparations
in the electron microscope. 8) Special -methods of application.
9) Additional remarks: a) application of microscopy. b) the
effect produced by electronic irradiation of the object.
The third paragraph contains some general remarks concerning
the application of electron microscopy in biology and in
metallurgical science. - Faragraph 4: The application of
electron microscopy in physical-chemical investigations. The
following subjects are discussed: 1) Electron microscopy,
electron diffraction, and radiostructural analysis. 2) Elec-
tron microscopy and sorption-methods of investigation.
3) :,:lectron microscopy and the investigation of the catalytic
activity of massive contacts. 4) @.lectron microscopy and
Card 2/3 chemical methods of investi@-_,,ation- 5) Electron micro--copy

@j@, 1, 74-27-6-.1/6
The Present Stage of Transmission Electron Microscopy and Its Application
in Physical-Chemical Investigations
and colloid-chemical methods of the investigation of sols.
6) New problems arising in connection with electron mi,-.-
scopy. There are 27 figures and 146 references, 47 of which
are Soviet.
1. Electron microscopy 2. Electron microscopes--Applications
3. Electron microscopes--Operation 4. Electron microscopes
--Effectiveness
Curd 3/5

Leontl,_-ov, Ye. @-*.., Luk a n cv i c h
J
TI T Thc Preparation Technique in the 1-1,lectron-'PIlicrosconic _'n-
vesticationo of Porous Bodie.9 t,@nd Powders According to Lhu
a,eT)lica Method (Tekhnika preparirovaniya pri provedenii
(,lektronno-milzro3l-opiciteskikh iusledovanii poristykh i
poro2hkoobraznykh tel metodom replik)
P-,jRI0DIC,IL: Zhurnal fizicheskoy khimii, 1958, Vol. 32, lir 8, p-P. 1922-1_,@@
(Tigs-il)
1%BSTRACT: :!one modifications of the technique employed in thi-, lp,,oparli-
tion of replicas are described. in the explanation oftlic.
selection -nd applicatDn of the replica of porous bo,li--@@ @t
is mentioned that the carbon renlica obtained r-ccording te)
the method by Bredli (Bradley) (Ref 3) yields tha bc-st i--
-3ult,?. The well-knovrn polystyrene -quertz method is recorr-
mended for carrying out the two-state m@@thod. The separation
and nroces,.in- of the replicas is expl.-.1-ined accor7.!J_.n,.- to
four noints, and an apparatus for stripping the rGplica io
described. Some instructions are 6-iven, and in the
of the tYDe Of reDliCa the character of the Dorous strucl-,-
Card 1/2 of the object is pointed out. A preparation mc-thod of

C-()V/76-32-8-32/37
The PreDaration Technioue in the Electron-,)jicj-oscoDic 1-nvent igat ion!, @)-L"
Porous Bodies anr! 2owdern According to the Replica '.."ethod
r@,
,pl4Ca is described which is modified acuording 4-o
ubility of the powder. There are 2 figures and 7 refern-nct-7--s,
2 of -,-,Iiich are Soviet.
,.oskv:@
5 L@ 0 C I AT 10 If :kademiya nauk SWR Institut fiziche.-.koy khinii
(AS IJZ313RPInotitute of '-hysical Chemictry, :.!osco,.,.,)
Card 2/2

T- 1 '111
I -Y 1 T.-II 11. M.. F-4,.F -VI 1%4 11.4. .-711%IU-@TY @! , '. ',. . -VT'7 T r
, LACUr'
j, F
LU I I I --, I - -- , 'I. ri . - I . @.
"Research by microdiffraction on the structure of lampblack particles."
report to be submitted for the 10th Annual Meeting, French Society ,f Chemistry
(structure and Reaction Kinetics of Graphite) - Paris, France, 7-10 Jun 1960.

PHAISEE I BOOK SOV/4767
Luklyanovich, Vsevolod Mi@lovich
Elektronnaya mikroskopiya v fiziko-khimicheskikh issledavaniyakh; wtodlka i
primeneniye (Electron Microscopy in Physicochemical Research; Methods and
Application) Moscow, Izd-vo AN SSSR, 1960. 271 p. Errata slip inserted.
7)500 copies printed.
Sponsoring Agency: Akademiya nauk SSSR. Institut fizicheskoy khimii.
Resp. Ed.: K.V. Cbmutav, Corresponding Member, Academy of Sciences USSR;
Ed. of Publishing House: A.A. Babad-Zakhryapin; Tech. Eds.: T.V. Polyakova
and T.A. Prusakova.
PURPOSE: This book is intended for physicists, chemists and other scientists
interested in electron microscopy as a tool of physicochemical analysis.
COVERAGE: The book describes tY,3 field of electron microscopy. Historical
data on electron microscopes and the characteristics, handling tenhniques
and fields of application of the transmission electron microscope are
discussed. The Appendix contains 91 sample electron micrographs. No per-
sonalities are mentioned. References follow each chapter.
aa=ba'@6

LEONTIYEV, Ye.A.; LUKIYAROVICII, "I.M.
Electron microscope stud7 of the porous structure of active carbons
with the use of the replica method. Izv. AN SSSR.Otd. khim. nauk
no.11:1955-1961 N 160. (RIRA 13:11)
1. Institut fizicheskoy khimii AN SSSR:
(Carbon, Activated)

CHMUTOV, K.V.;, LUKIYANOVIGH, Y.M., kand.khimicheakikh nauk
...
Structure of graphite and the kinetics of its reactions. Vest
All SSSR 30 no.9:73-74 S 160. (MIRA 13:9)
1. Chlen-korrespondeat AN SSSR (for Chmutov).
(Graphite)

LEORTIM, Ye.A.;@LUKIYANOVICH, Y.M.
N
--ili
Structure of e--ja--A@fcles of graphitized thermal carbon black
and of the products of their dissociation. Dokl.AII SSSR 134
no.2:384-336 6 160. (MIRA.13:9)
1. Institut fizicheskoy khimii AN SSSR. Predstavleno akad.
M.M.Dubininym.
(Garbon black)

LUK-YANOVICH, V. M.
Doe Chem Sci - (diss) "Electron-microscopic study of the struc-
ture of several highly dispersed systems and porous bodies."
Moscow, 1961. 22 pp; (State Committee of the Council of Min-
isters USSR for Chemistry, Order of Labor Red Banner Scienti-
fic Research Physical Chemistry Inst imeni L. Ya. Karpov);
150 copies; price not given; (n, 6-61 sup, 196)

A I IT H OR I)iilltran, M. M.,
7hukovskny,i, Ye
nnrl Sprikhov, A
S/C62/6_1 00/OCP/0()?/OD
1/0
Pil7/u.00
Vishnyp@ov,,3, IM. IM., ?@'Ivprinrl, Yn. D.,
G.. Leontlvev D? ly@inovich, V. F.,
I.-
TITLE: Stuoy of z?rlqorptlon nroperties and fitructur-f of seronrlnry
pores of ndsorbents hQvinp 4@hr. effert n','.* molr@rnjl-ir siovell.
R,@-Port 1. In(iust.rini s.,lmj)L-.s of' synthotic 7enlitris
PERIODICAL: Iz-,,estiya Akad,@riii nauk 1"65F. Otcleleniye khirlcheskilth
nauk, no. 3, 1961, 396406
TEXT: The authors studied some T)eculiarities of the adsorption pronerties
of tv-picnl industripl snnples of synthetic zeolites ;@nd th.,3 structure of
their second @ry T)ores. Their used industrin.L sanpl-s from no.Lecular F-iqvPF
rla!iiP.,nnd bv Linde !!A (desirnpt.@d by ITC-liA (M.9-bA)), inrl qll@ (desirniterl In,
MC-5A (MS-'@A)) in the form' of @t-8 mm !on!, j-,rains with an nvernge dinmqte@
of"3.2 mm. Sorption isotherms Pod, in some c-7-ses, desorption isotherms
of nitrogen vaDors at -1.950r, Pnd writer, l,enzene, and cyciollexAne VADOI-S
-it 200C
. wpre determined. A sinil.)r i-narntus Ps +hat flervriheri in Pet% 2
Card 1/1

S/C)62/t,l/UUO/00 3/002/0D
Studv of adsorption Dropertles... P117/E20
(P. P. Pering, 14. M. Dubinin., Ye. G. Zhuko@rskqya, A. 1. S,-!ra'khov, Ind
V. V. Serninskiy, Zh. fiz. khimii 31, 712, 1957) wis anpiied. To study
the structure of sicondary pores olf-MS-)-A nnrl MS-5A rrnins, low- -m,' hivh-
pressure porosim-@ters were used. The intter was a redesigned device of
the[IA-h (PA-)!) type (Ref. 5: T. G. Pl,-Ichenov, V. A. Aleksandrov, and
G. M. Tlilotserkovskiy, Metody issiedovaniya struktury vysoko-d-ispersnykh i
r)cristykh tel, Izd. AN SSSP, M., 1953, str. 59). For the electron-
microscopic examination of the structure of secondary pores, the method of
sinple-stage carbon replicas wps used. The pictures of cnrbon renlicns of
MS-11A and MS-rI-A taken by mr@nns of (UEM-NO) electron microscone
showed no marked differences. A thorough analysis of stereophotoFranhs
indicntef tbnt there vas no dense mckinp of the zeolite crystals in the
grains. There are interstices of thp order of mgnitude of small crystn1s,
i.e., some tenths of a micron or some thousnnr4ths of an @-mFstrom. Strong
-mlargr,ments show that the crystal surf@lce is not amorphous. The studies
of MS-IiA and MIS-9A disclosed that the potentili adsorption theor7f could be
,-)r)lied to them. As the Puthors hPd not obtained any experiment,11 dqn,
a
they us-d the results obtained by N. V. KPI 'tsev, for water vapor at 200
and HUOC and at equilibrium oressureS D = 1 ind 25 mm Hg, which had been
Card 2/3

6tudv of ndForntion nronertie@!... P117/1,2W3
.wde Pvallable to them. The r@r,-t-ured vij-ues of ?dsorT:)tlon davipte from.
the calculated values by 3 '% at most. !@q. (1) exT)rpsses the temperature
dependence of the adsorption isotherms sqtisfPrtorilY:
a = (1;1,/v) exp D T2 (log D,.F/P)
[-- ;7 - d
Wo = limiting volume of the adsorption space, which is PoNal to th- volujr-.e
of the micropores of the @rdsorhent; P = constant denendent on the
dimensions of the microDores, whinh deter--iina ths increase of tho ndsorn-
tion potentials; V = a ffinity fnetor of the charpct,-@ristic lines;
v = volume of 1 mI?-T of the vanor linuefied it thp evperimentai temarltlire
T. 14hen consid,@rinrf, the structure of the seconrlary nores, it vnr-, folind,
that it may b--@ cunntitatively described by the sorntion and n--reury
methods of mif.,asuring the por-@s. The chnrant-ristins obtnin@A for the
por,@ structure of MS-bA and MS-5A nre ,,ivpn in Tnble ),.
9 figures, 7 tibles, ind 13 references: 12 So-,,riet-bloc Pne 1 non-:@oviet-
blo,!.
AS'-0CRTI0'.-I,'.- Institut fizicheskoy khimii Akadernii nauk S@)SR (ITI.StitUt9 Of
[e-mail] Chernistr1r, A(,--delr.3r of SCienCeS TJS,'@.R)
Card 313

SPIVAK, G.V.; VERTSVER, V.N.J@@ @,V.M,.; LEVIN, Ye.Ye.,-
SKAKOV,j Yu.A.
Third All-VnJon Conference on Electron Microscopy. Radiotekh. i
elektron. 6 no.5:852-862 My 161. (MIRA 14-4 1
(Electron microscopy--Congresses)

5/06 61/000/008/003/010
B I 17YB2o6
AUTHORS: Dubinin, M. M., Zaverina. Ye. D. (Deceased),
Luklyanovich, V. M., and Yharlamov, N. P,
TITLE; Investigation of the adsorption properties and the
secondary pore structuve of adoeirbontn having the Woot
of microfilters. Communication 3. Components of grains
of synthetic A-type zeolites
PERIODICAL: Akademiya nauk SSSR. Izvestiya, Otdoleriiye khimicheskikh
nauk, no. 6, 1961, 1380-1387
TEXT: In sorption technique synthetic zeolites are mainly used in the
form of grains, tablets, and balls. The main components of the grains are
crystalline zeolite powders and binding agents. In order to clarify the
properties of these components, the authors invest'@ga%ed the dispersity of
zeolite crystals and their adsorption properties as well uo the ahare of
the binding agent in sorption. Crystalline qpe@,,Impns of A-typq zeolites
were used, which were synthetized by aom:@ Soviet I. YA. Neymark
(Nm), Ya. V. Mirskiy (Mr), L. M. Maks1mcTa (lilk) and B A. LIpkina (Lp).
Card 1/4

S 0 00 C i C /010
.. B20(
Investigation of the adsorption... B117//
The designation of the specimens is compo9ed of thp abbre,.rifitea riame of the
scientist and the specimen number given by him., Ameri-an oommerci%!
specimens in the form of crystalline zeclite powders of the types 4-A and
5-A by the firm of Linde were used for comparison, To the sodlum form
(NaA) belonged: HM-300 (Nm-300), Nm-347, @Ip-275 (Mr-,275), M@,,-90 (Mk-90),
Mk-1 experiment, PrT-202-2 (Lp-202-.2) and Linde 4-A. To the oalrium form
(CaA) belonged: Mr-276 and Linde 5-A. The sp-cimens were photographed in
an electron microscope of the type M-100 (T)EM.,100) wilh 800-fold
magnification. Purther magnification was achlevi:.-d optically.. The photo-
graphs made of different places of the preparatior-i were statistically
evaluated after magnification. Distribution curves of these crystals
according to their size were plotted on the basis of these dara,. The
zeolite specimens synthetized by Neymark and Mirakiy were found to be
distinguished by relatively close distribution. Crystals of 'he size of
0.75 4 are predominant in the preparations by Neymark and of :the size of
1.2 g in those by Mirskiy. The zeolite specimens prepared by Maksimova and
Lipkind are not only more coarsely disperse, but also have a wider
distribution of the crystals. Benzene was used foz investigating the
adsorption properties. The adsorption isotherms were diterm"ned at 200C
Card 2/4

S/1062/6 1/000/006/00 3/0 10
Investigation of the adsorption... B117/B206
by means of sorption scales in vacuum. The curves Eihowed a similar shape
as those corresponding to M. M. Dubinin, M. M. Vishnyakova, Ye. D. Zaverina,
Ye. G. Zhukovskaya, Ye. A. Leontlyev, V, M. Luklyanovi,,h and A. I. Sarakhov
(Ref. 6: Izv. AN SSSR, Ord. khim. n. 1961, 396). The adiorption. isotherms
of water vapor were measured by sorption scales, for romparigor; of the
adsorption properties of crystalline, completely dehydrated zeclites, The
crystalline A-type zeolites synthetized by 3oviet s-@iertistq are generally
marked by good adsorption capacity which is characteristi., -@f za-oliles of
this type. The Debye powder patterns of spe:@imens of Soviet and American
origin are identical. A clay specimen of the betonite type uied by
Ya. V. Mirskiy for the preparation of granulated zeelites served as
example for the binding agent. The adsorption of benzen,= vapurs was
investigated at 200C on a specimen which was heat-treatsd at 600cC., The
application of-betonite-type clay as binding agen! was found to have no
great effect on the adsorption properties of zeclite granule.@@,, Thfi
authors thank B. A. Lipkind, I. Ye. Neymark- Ya. V, Mirskiy and
L. M. Maksimova for supplying synthetic zeolite spe@,,imens,, Th-3re ara
3 figures, 5 tables, and 6 references: 2 Soviet-bloc. ana I ric.n-Soviet-
bloc. The four references to English-language publi(@ations read as
Card 3/4

Investigation of the adsorption...
follows: D. W. Break, W. G.
T. L. Thomas, J. Amer. Chem.
J. Amer. Chem. Soo 78, 5972
Faraday Soo, 54, 1;72 (1958);
Chem. Soo. 82, 1041 (ig6o).
5/06'2/6@/000/006/003/010
B11020@
Everaole, R. M. Milton, T B. Read-
Soo @8, 5963 (1956); T- B.. R@ad,
(19;6); R., M. Barrer, W M, Melir
L. Brous8ard, D P. 3h(.--emairer.,
D W. Breck,
Trani.
J, Amer,
ASSOCIATION: Institut fizicheskoy kh1mii Akademuli nauk SSSR kInstitutr,
of Physical Chemistry, AS USSR)
SUBMITTED: December 12, 1960
Card 4/4

LuvwTOVICTi V M.
Some urgent problems arising in applied electron microscopy; survey.
Zav. lab. 27 nu. 12:1475-1480 161. (KIRA 14:5)
(Electron microzcopy)

vnrg.010--Qin
LUKIMOVICH, V.14.; MAMIRKO, V.V.
Electron microscope investigation of silicotic dust, Dokl.All
WSR 145 no.3:609-611 JI 162. (MM 15:7)
1. Inatitut fizicheskoy khimii AN BBSR i Fermskiy nauchno-
issledovatellskiy ugollnyy institut. Pred6tavleno akademikom
M.M.Dubininym.
(LUBGS--DUST DISEASES) (ELECTRON IMROSCOPY)

LEVIN., YE.Ye.; LUKIYANOVICH, V.M.
All-Union Conference-on.Electron Kicroscopy. Zav. lab. 29
no.10:1276-1277 163. (MIRA 16:12)

- LUKUMOVICH, V.- M.; KASATOCIIKIN, V. I.; NED-OSHIVIN, Yu. N.; FBIMMSHMM, G. B.
"F,lel-troner~mil--roskol,ische Untersuchuang. der Pusse."
report submitted to 3rd European Regional Conf, Electron Microscopy,
Prague, 26 Aug-3 Sep 64.

V. @f
LUKIYA14OVICIII 1'..
Of C'Iectron --croscor'.7 2-72tc)
- J- I @ -
Gcnferenc@-@ the .
industry. Zav. lab. 30 no.1:121-122 164. (YlkA

KAVTARADZE, N.N.; SOKOLOVA, N.?,,- LUKIYANOVICH, YA-M.; YEVKO, E.I.
Preparation and structure of solid finely dispersed metals for
spectral studies. Kin.i kat. 5 no.6slO95-1099 N-D 164.
(MI-RA 18:3)
1. BBtitut fizicheskoy khimii AN SSSR.

L U25-66
iw(MVT
ACCESSION URt APS022938
UR/0062/65/000/00er/1500/JL502
541*183+546.284,,.
AUTHOR-. Dubildn, M. M.- Zhukovskaya, Ye. G.; Luklyanovich, V. M.; Mm@ K.
P anov, ye.@ F*f enderof,-M.1;
ITITM Ads
[e-mail] of synthetic mordenites
SOURCE: AN SSSR. IsvestLya. Seriya khimicheskaya, no. 9, 1965, 1500-1502
"CIA)
'To
PIC TAGS: molecular sieve, synthetic zeolite, mordenite
I
!ABSTRACT: Adsorption.(pore) volumes of sodium and hydrogen forms of synthetic mor-
denite were determined in order to check them against the corresponding values.cal-@
Iculated on.the basis of X-ray analysis. ror comparison, also H-Zeolon (product of
'Norton Company) was examined. The saturation volumes of Na and H synthetic morde-
Inites were determined from water vapor isotherm at 200C, nitrogen and argon isotherms
taken at -1960C, and from sorl)tion and desorption isotherms for benzene taken at
200C and various pressures. For all mordenites an excellent agreement was found bew'
Itween the calculated Ipore volumes and the values obtained from water vaporg nitrogen,
and argon-adsorption measurements, while.b4ozene adsorption gave values for the pore--
1volumes.that were too iow. This was due to the fact that the small cavities in thel
[Card -1/9

PREODRAZHENSKAYA, T.P.., MAKSIMOVA, T.S..@; LUKIYANOMI V.M.-, YEVXO, E.I.
@ - - -.1- 1
Uving carbon raplica methc.,d for tht, el,5rtron microw@oplc
strudy of the surface of Actinomyces spore;3. MikrobioIGg2p.
34 no.3.,519-523 165,
(MIRA M31)
3. Inatitut po izyckaniyu novykh antiblutl@rv RI-rdsterstva
zdravookhraneniya SSSR.

__.L21T63.;66
FACC NR. AP6011247 SOURCE CODE: UR/041316@-/066/006/0090/0091
96
INVENTOR: Kogan, P. A.; Luk'yanovskaya, L. V.
ORG: none
TITLE: A-stand for testing gas. jets. Class,42, No. 179967
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 6, 1966, 90-91
TOPIC TAGS: gas jet, test stand
ABSTRACT: An Author. Certificate has been issued for a stand for testi gas jets,
consisting of a receiving chamber containing a nozzle fitted on a rod, 71ocale for
visual observation of nozzle position, and ball-bearing supports mounted in vertically
moving brackets, with a rod mounted in the supports and capable of longitudinal motion.
,stand is equipped with a drive
To determine the efficiency of remote gas jets, jhp
mechanism consisting of a cylinder with a nozzlefioT its rod. To position the nozzle,
a locking device is used which consists 6ra housing in which moves a piston connected
to the lock, which In turn, interqcts with the cylinder rod of the drive mechanism.
(WHI
SUB CODE: 13, 14/ SUBM DATE: 22Feb65/ ATD PRESS 14 V2 7
1 Card UDC! 533,697.5:620.1,052.5

@XISKI GeoV ' e@vic@
rg i y'5@leL4 h, kand.tekhn.nauk; )%ROSHNIK, Boris
Martynovicti,'@pzh,; LTJKIYANOVSKIY, S.V., inzh., red.; VERINA,
G.P., takhn.red.
[Construction and repair of railroad car trucks] Uetroistvo
i remont vagonnykh telezhek. Moskva, Gos.transpahel-dor.
izd-vo, 1958. 343 P- (MIRA 11:5)
(Railroacls--Cars)

LUKIYANSKAYA, Te.1, uchitelinitea
--"4r -! I I
.W
Nature study room at the Chismena seven-7ear school. Biol. v shkole
no-5:58 S-0 '58- (MIRA 1L 11)
1. Chismenskaya. samiletnYaya shkola Volokolamskogo rayona Moskov-
skoy oblasti.
(Nature atudy)

LUKYAH�@@I,. (Lukjanaki, Mj (Pol'sha)
Role of functional studies of the respirator7 apparatus in surgical
treatment of pulmonary tuberculosis. Probl. tub. /+2 no.3s23-27 164.
(MIRA 181l)

LUKIYANTSEV, I-ye.
a-W -
Mechanizing the opening of cupola furnace bottoms. Lit.proizv.
no.9:32 S '57. (MIRA 10:10)
(Cupola furnaces)

ZHENILOV, B... instruktor uchebnoy yezdy, (Yaroslavl'); STAROBAKTX, N.;
prepodavatell mashinoy6deniya i avtodela (Slutsk);
14AWFEYEV, Yu., shofer-ekskavatorshchik (Lodeynoye pole);IVANOV, N.;
slesarl; OISOM, N. (Yoshkar-Ola); IVANOV, B., mayor mi2itsii;
BORODIN..@., spoytsmen 1-go razryada, gvariiii. starshina; YEHELOYANOV,
Yu., sudlya Vse6oyuznoy kategorii (Mosk7a); STRELICHIK, M. (Moskva);
YF14EL'YANOV, I.J. shofer (Astrakhan).
Our discussions* Za rul, .19 no,4:8-9 Ap 16L ('KM 14:7)
1. Nachailnik*2-ko gruzovogo avtokhozyqystva,, g. Tomsk (for Starobakin).
2. StarsUy inspbktor Gosavtoinspektsii Len'fngrada (for B.Ivanov).
3. Predsedatell Federatsii vodnomotornogo sporta S-SSR, (for
Yu. Yemeliyanov).
(Automobile drivers) (Automobile racing)

DENISOVA, Z.I.; SHAPOSHNIKOVA, Ye.M.; LUKIYANTSEVA, V.P.
Gamasid mites in rodents of K-x-sk Prcvin2e. Sbor. tru@i.
gos. med. inst. no.16:101-105 162. . OMIRA 17: c,")
1. Iz kafedry obshchey biologii i parazitologii (zav. - dotsent
G.M. Tkachenko) Kurskogo meditsinskogo instituta i Kurskoy oblast-
noy sanitarno-epidemiologicheskoy stantsii (glavnyy vrach - V.I.
Latanov).

r-8DOTOV, JI.J.; GEYER, R.I.; GEWSIM,3110, L.N.; LUKIYAETSEVA, V.Ya.;
FMIANM, I.P.
Relation betup@)n the degree of m@zroflora permeation of canned
food before -,tcrilization a----I tl,G re3ults of t,,ic bacter.olorrical
aruilysis of the finishod 1), Juct. Kt _i.i ov.prom. 17 n.-7:37-39
( f ','I TU,
ji 'G@. 1 15:6)
1. Ukrainskiy nauchno-issledovatel'ski-y inotitut konservnoy
pronyohlennosti.
(Food, Canned--Ff@erili,@ation)
(Food-Bactel _ulowj)

Q-
all-47-66- Pwr(i) EvIA(h)
ACC NRt AT60,06766 SOURCE CODE: UR/2657/65/000/014/01TO/oi84
AUTHOR: Luklyanuk, I. Ye.; Naumov, Yu. Ye.
ORG: none
TITLE: Examination of transient conditions in a' semiconductor delay line
SOURCE; Poluprovodnikovyye priboiy i ikh primeneniye; Bbornik statey, no. 14, 1965,
17o-184 ,
TOPIC TAGS: circuit delay line, carrier lifetime
ABSTRACT: On the basis of the solution of the continuity equation, an analysis of the
basic characteristics of a semiconductor delay line was made. The study covered the
transfer constant of the circuit, the magnitude of the delay, and pulse widening at
the output* Graphs of the basic characteristics of the delay circuit, and its de-
pendences on the mode, geometrical dimensions, length ofthe diffusion path, and the
lifetime of minority carriers are presented. The results of experimental measurements
are also given. Orig. art. has: 6 figures, I table, and 24 formulas. [Based on
authors' abstract) [JKP1
SUB CODE: 09/ SUBM DATE: none/ ORIG REF- 001/ OTH REP, 002
Card l/lQt1- uDc: 621-382.001.24

MAYSURYAN, N.A., akadAmik; STEPANOV, V.N., prof.; KHNETSOV, V.S.,
dots.; LUKII.ANYUK, V.I., dots. CHEFd-1%1AZ, P.A. dots.;
- I
OZERM -9".,
1-V. , red.
[Plant growing] Rastenievodstvo. Izd.2., parer. (By] N.A.
Maisurian i dr. Moskvay Kolosp 1965. 471 p. (MIRA 18:4)

LUKIYANYCHEVA, V.I.; TIKHOMIROVA, V.I.; BAGOTSKIYY, V.S.
Effect of the state of platimm surface on thle e2ectrtcchp-.-,ic-E2
adsorption of oxygen in acid solutions. ElektrokhL-aiia 1
no.3:262-266 Mr 165. (YJRA 18:12)
1. Tnstitut elektrokhimii AN SSSR.

AUTHORS:
TITLE:
PERIODICAL:
1 8
53
S1089 611011100110101010
B102/B214
Nikolayev, 11. S., Luklyanychev, Yu. A.
Investigation of the hydrolysis of uranium tetrafluoride
Atomnaya. energiya, v. 11, no. 1, 1961, b7 - 69
TEXT: There are entirely different and sometimes conflicting views on the
problem of the degree of and conditions for the hydrolysis of UP 4 in water,
and whether it occurs at all. Conflicting views are published, for
example, in Refs.3 and 4. So the authors of the present paper have investi-
gated recently the hydrolysis of UP 4* The tetrafluoride in the form of
UF 4* 2.5 H20 was obtained by the electrolytic reduction of uranyl fluoride
solution. Experiments were carried out on it with the help of the cation
exchanger k'/-2 (KTI-2) and the anion exchanger (EDE-10P). Experi-
ments. showed that the uranium was absorbed by the cationite by up to
90 - 95@6, and not all. all by the anionite. From this it may be concluded that
the UP4 in the solution is present in the form of cations. The hydrolysis
Card 1/5

25381
S/069/61/011/001/010/010
Investigation of the B102/B214
of UF4 was followed by pH measurements at different concentrations of the
solution. These measurements had an accuracy of 10.02 pH units. The
results are shown in Table 1. The saturated UF 4 solutionn are seen to haye
a high degree of acidity, which can be explained only by the assumption of
hydrolysis. The data obtained in two series of measurements were used for
the calculation of the equilibrium constant of the hydrolytic reactions.
The hydrolysis may be described by the reaction,equation UF 4+nH20 1
4+ 0-1.
U(OH)nF4,-;,I+rM, or, if account is taken of the low solubility, by U +nH 2 C-
U(OH)4(4-tl)+nH+, where n is the number of hydroxyl groups; n=1--4. Thereby
n (OH) +(4-n 1+1n
one obtains for the equilibrium constant K = LU n
p LU4+ 1@
C is the total concentration of uranium in the solution. Table 2 gives
the KP values obtained for the two series of measurement and for four
different hydrolytic reactions. The general instability constants for the
Card 2/5

S/089/61/01--/.001/010/010
Investigation of the ...
B102/3214
o 3+ 2+
h
yd3z xy-complexes UOH U(OH) U(OH)+ and U(OH) were calculated from
2 3 4
@the X values. The results obtained were: 4.4-10- 12 (ionic force'*0.008),
p
22
2 107 (ionic force 0.001), 2 -31
.5* .0-10 (ionic force 0.0004) and
40
5-7-10- (ionic force 0..00,01), respectively. There-are 2 figures, 2 tables,
and 9 references; 4 Soviet-bloc and 5 non-Soviet-bloc. The references to
the English-language publications read as follows: Ref-3: J. Dobratz et
al. Reports _L U
,N-34, A@pril 9, 1943; Re'.4: A. Roberts. Reports, B-64, - -
February 6, 1942; Ref-s.8,gi K. Kraus, F. Nelson. Ji,Amer. Chem. Soc. .72,
3901 (1950) and IZ, 3721 (1955).
SUBMITTED: February 1, 1961
Card 3/5

TANAMYEV, I.V.- NIKOIAYEV M.,- LUKIYANYCHEV, Yu.A.,- OPALOVSKIYj A.A.
S, Y --- - .. - ------- -----
Chemistry of uranium fluorides. Usp.lzhim. 30 no.32:.I/+90-1522
D 161. (MRA 14--l-1)
1. Institut obshchey neorganicheskoy khimii imeni, N.S.
Hurnakova., All SSSR. (Uranium fluoride)

S/05 621012100410121014
B1 02Y3104
tl ---I cc
AWIHORS: Nikolayev, 11. S., Lu I an chev, Yu. A.
TITLE: Determination of the solubility product of thorium tetrafluoride
PERIODICAL; Atomnaya ener,-iya, v. 12, no. 4, 1962, 334-336
TEXT: V. I. Spitsyn (Zh. rus. fiz.-khim. o-va, 49, 357, 10,17) and I. V.
Tananayev and A. D. Vinogradova (Zh. neorganich. khim., 2, no. 10, 2455,
1957) had already determined the solubility product of ThF 4 and obtained
1.2-10- 29 and 1-84-10- 24, respectively. The present authors determined the
solubility of a ThF 4'0.5 H 20 as a function of the solvent (HC10 4) con 'centra-
tion. The solubility was found to increase rapidly with the concentration
up to about 0-5 14 HC104 which indicates a reaction of the type
ThF + (4 - n)H+, @ThF4-11 + (4 - n)HF- This reaction can be described by
4 n
Ig jThF'-nj= !'-- Ig (if 11+
n 5-n
+ I IgKp- 11-11 Ig (4-n)
Card 1/3 .9 n 5-n-

S/06 6-/012/004/012/014
Determination of the solubility B102yrII34
where KP is the equilibrium constant. As the HP 4 solubility is a function
of the hydrogen ion concentration, n can be determined from the slope of the
straight line -logS - f(PIO ((4-n)/(5-n) is the tangens of inclination).
The reaction equation reads: ThF + 3e'-z-ThF3+ + 31IF; the equilibrium
-11 4
constant is 8.1110 The solubility product is obtained from
SP = [Th4+][F-]4 with [P-1 - 4[S,hj/(1 + [H+J/kl), k, 6.9-io-4, the
dissociation constant, and ITI.j4*)= S'J'h IF-Ii
+
K
iThPi
Kq,rj,(oji)JI-Ij
i.q. 1-4. For KThF3+ = 1.2-10-6 and Y`ThoH3+ = 0-15, SP - 4-5-10- 26 is
obtained. The deviation from the SP value obtained by Tanana-rev and
0
Vinogradova is attributed to the fact that they neglected complexation and
Card 2/3

5/060,/452/01 2/004/0.12/Cl 4
Determination of the solubility ... B102/B104
hydrolysis of the Th ions in the solution. There are 2 figures, 1 table,
and 7 references: 5 Soviet and 2 non-Soviet. The reference to the English-
language publication reads as follows: R. Bell, J. George. Trans. Faraday
Soc. 49, 619, 1953-
SURINUTTED: June 16, 1961
I/
Card 3/3

S/089/62/013/002/007/011
3102/B104
AUTHORS: Luklyanychev, Yu. A., Nikolayev, N. S.
TITLE; Solubility of uranium (IV) hydroxide in hydrofluoric acid
solutions
PERIODICAL: Atomnaya energiya, v. 13, no. 2, 1962, 179-181
TEXT: As only scarce and contradictory data have hitherto been published
on the interaction between U(IV) and P ions, the authors examined the
solubility of U(IV) hydroxide by two methods; (1) Freshly prepared U(IV)
slime was filled into a teflon container with a stirrBr and a hydraulic
seal and kept under a H 2 atmosphere. Equilibrium was reached after 3 hrs.
(b) Together with hydrofluoric acid the U(IV) hydroxide slime was fille
d
into a polyethylene flask and nitrogen was passed through it.' Equilibrium
4
was reached after 25 days. The u4+ concentration increased with the molar
-4, -3 -10-2 -ic-5, 6.;6.10-5,
F conQentration (HF: 5-10 ; U4+: '4.6
1-10 , 1 0
1.0s-10-4). Results: The dissolution is characterized by the formation
of complex ions: U4+ + nHF,7-@U-14-;-n
Card 1/2 2n + nli+. The change in the HF

3/089/62/013/002/007/011
Solubility of uranium (IV) ... B102/B104
concentration does not alter the pH value of 5-5-7. The equilibrium con-
stant is found to be
[UP +,n UF4 n
,_n] [
r 3 - I 4-n] + log (K/Kl
K F] n IF-]n or log LUFn - n log [F_] 'HF
lo.-S as a function of F is almost a straight line with an inclin---
0 4+ log LF 3+
tion of 45 i.e., U + Hp@_
�UF + e (S = solubility). The instability
constant of UF3+1 X. = [U4+j LF-] , was found to be 6-0-10-5.(a) and
in IUF3+ 1
,;.6-,,0-5 (b). The Up3+ equilibrium constants were*equal to 15 (a) and
21 (b). There are I figure and 3 tables.
SUBMITTED: December 27, 1961
Card 2/2

JZKIYMGHL.,V-,-Xu.A.; NIKOLAYEV, N.S.; ASTAKHOV,, I.I.; LUKIYAXYCHETA,
V.I.
Mechanism of copper fluorination at high temperatures. Dokl.
AN SSSR 147 no.5:3.130-U32 D 162. (MIRA 16 t2)
1. Institut obahchey i neorganicheskoy khinii im. N.S. Kurnakova
AN SSSR. Predstavleno akademikom I.P. Tananayevym.
(copper) (Fluorination)

ACCESSION -0: AP3003473 S/0078/63/008/007/1617/1622
AUTHORS: LuktLeSy!chev; Yu. A..L Nikolayev, 'N. S.; 14khayloy, Yu.N
TITLE:_ Couplex uranium pentefluorides
SOURCE- Zhurnal, neorganicheskoy khimi v. 81 no. 7, 1963, 1617-1622
TOPIC TAUS: uranium, uranium pentafluoride, thermogravimetric curve, hydiazine
AWnWT: Uranium pentafluorides complexed. with hydroxylemine, hydrazine, and
aniline vere:,synthesized. These were uranium hydroxylemine pentafluoride,
uraniun hydrazine pentaffluoride, and uranium aniline pentafluoride. X-re;y arxl
chemical data vas obtained. Thermogravimetric curves indicated thermal
Instability of all 3 compounds. The hydroxylamine and hydrazine complexes
-decomposed to UF4.which in turn decomposes about 4OOF- the aniline complex
dehydratedi-then decomposed at about 24OF to a black residual U and F containing
material,Orig.-art. has: 7 figures, 1 table.
ASSOCIATION: Institut obahchey i neorganicheskoy khimii im. N. S. Ktwnakova,
Akademii- nauk;... SS'SR (Institute of General-and Inormniq Chemistry, AcqAemy 0?
Sol anceq.-MM)
@a rd

LUKIYANYCHEV, Yu.A.,- NIKOLAMI, N.S.
Solubility products of uranium tetraflucride. Zhur. neor
khIm. 8 no.7t!786-1788 JI ;63. (KERA 1670
1. Institut obshchey i nevrganicheskoy khimi'L imeni N.S.
Kurnakova. AN SSSR.
(Uranium fluorides) (Solubility)

LUKIYANYCHKV, Yu.A.; UIKOLAYEV, I-I.S.
Solubility of uranium te'urafluoride in aqueous acid solution. AtL,=.
energ. 15 no-5;423-425 N '63. (MTRA 16:12)

-Card

1 12
To

ZMBION
Ar@=446
-.,-!:A'Ak,ad-eiai--( ndilk@@WSI
ScienceBASSSR).
0
)eiierAl-;and';IuorgaAic Cbemistry@ Acade

SUB K4
TaL 00 CODE.
in? i 006. S: 3267
ATI> PPM

1 25 EWA(k)/EWT(1)/EWT(m)/EPF (c)/ET'C/EiVG(m)/EWP(t)/SVO(b) IJP(c)
JD JW/JG/LHB
--wol8l/65/007/006/1892/1
um ApmW6
V@uklyanychevf Tus A*; Malyuchkov# Oo To
4UTHOR: Baturina. Ef @i
Investigation of trifluoridea of rare earth elements of the cerium group by
]th nuclear magnetic resonance metr
e
T, no. 6, 1965, 1.892-1894
@SOURCE: Fizika tverdogo tela, v.
MPIC TAGS: cerium, lanthanum, praseodymium, neodymium, nuclear magnetic resonance,
line widthi fluorine compound
19
iABSTRACT: The nucleL magnetic resonance of F in LaF 39 PrF and NdF was in-
vestigated with a spectrometer using a permanent magnet of ide*nslty 5035 Oe and a
I ated at a frequency
jPound type generator*. The permanent magnetic field was modul
73 cps with a depth not exceeding 0.1 of the line width. The resonance was observed-
linthe temperature interval from 22 to -150C. Comparison of the calculated values
lof the second moments with the experimental ones shows that the symmetrical nuclear_
magnetic resonance signal of diamagnetic LaF is satisfactorily described by dipole-'
2 -
dipole interaction, In the case of the other irl-ML-or-IddEG the experimental
2. d the calculated value dfa@ctkiej@dncy Is attributed t
'second moments exceede
19
1 the contribution of paramapetism, A decrease in the temperature distorts the F
ard

L 13563-66 gn(u)IETO(r)ISWG(S)IS-WP(t)IVWP(~) IJP(c) RDW/JD/JW
AP6001235 SOURCE CODE.---U--'R-'/'-O*.1-6"-3-/6-5"/"-0-0-1/-O--I--2-/-2'-I8-2/-2'18-8--'--
AUTHOR: Luklyanychev, Yu. A.; Baturina, E. A.; Malyuchkov, 0. T.
ORG: Moscow Institute of Steel and Alloys (Moskovskiy Institut stall I splavov)
TITLE: Study of the composition and st@ucture of lanthanum and cerium trifluoride crystal
bydrates
777a
SOURCE- AN SSSR. Izvestlya. Neorganichesidye materialy, v. 1, no. 12, 1965, 2182-2188
TOPIC TAGS: lanthanum compound, cerium compound, r^*,3'ro4i- --3reor reolPf- o9,voc.
ABSTRACT: Lanthanum and cerium trifluorlde crystal hydrates were precipitated from hydro-
chloric and nitric acid solutions by adding 40% hydrofluoric acid. Chemical analysis showed
the composition of the crystal hydrates to be LaF.- (0.8-0.5)t@O and CeF - (0. 5-0.3F120).
NMI1, x-ray phase analysis, and IR methods showed that the hydrates have a lattice similar
to the anhydrous salts. The water molecules entering into the composition of the crystal
hydrate are located In the vacancies of the lattice and form hydrogen bonds of the type F...
H-0 of different configurations. The presence of water molecules in the lattice appreciablp
affects the mobility of fluorine atoms. X-ray phase analysis, NMR, thermographic and
thermogravimetric, methods established that the removal of water molecules occurs gradually
in LaF4- 0. 51160, at 60 - 80 and 80 - 225C; In CeFd- 0. 5D60, at 60 - 80, 80 - 360, and 380 -
450C. The structure of phases dehydrated below 225C remains unchanged, and on further

L 13563-66
ACC NR. - AP6001235
heating the compound changes from a metastable to a stable state; this transition is ass'o-
elated with a change In the position of the fluorine atoms. Orig. art. has: 5 figures and
2 tables.
SUB CODE: 07, 11 SUBM DATE: 23May65 ORIG REF:. 004 OTH REF: 009

-A
A t- -L-41
5w
-of 0
-Xii
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G, ignud c laxid
I .
-UTI"
and
lo-oraf. the (g
of
0.- until tl@d wht,:
c@@ @a o-d
'ac
OX

LUK,yAjrfCjMVAI v. I.: Mai3t-ir Chem Sci (disa) -- "Investigation of the artlva-
ting and deactivating effect of o@zfgen aboorbed from the Pan phaae on the
electrochemical behavior of iron olectrodea In allmli solutiona". Moscou,
10 -D
@p (Inst of Physical Chem Acad Sci USSR), 150 CoPies (EL, ITO 5), 1959, 1),11)

LUKIYANYCHEVA, V.I.; BURSHTEYN, R.Kh.
Impedance measurement of an iron electrode in alkalin solutions.
Zh&.fiz.khim. 35 no*6:130-1350 -Te 161, (MIRA 14:7)
1. Akademiya nauk SSSR, Institut fizicheskoy khimii,
(Electrodes, Iron)

LUKIYANKFEVA, V.I.; BAGOTSKIY, V.S.
OxyFen adsorption on smoth degassed plati-= in electrclyte
solutions. Dokl. AN SSM 155 no.1:160-163 Mx '64. (Mi-ItA 17:4)
1. Institut elektrokhimil AN SSSR. Predstnvleno ORdemikojn
A.N.Frumkinym.
--

TIKHOMIROVA, V.I.; LUKIYANYGHEVA, V.I.; BAGOTSKIY, V.S.
Oxygen-hydrogen peroxide equilibrium on a degassed platinum in the presence
of oxygen traces. Elektrokhimiia 1 no.6t645-650 Je 165. (MA 18:7)
1. Institut elektrokhimii AN SSSR.

rl-t,?I, vf Vn-!
1i:jbitt*f-% fr,!- rz@pr i t ir, N r in rrl?rp
:. I., @ j,
LA ij fA C7,f 4LI
Nwne
Sokolov, IT. S.
Yaj:Okov, P.
Chizhevskl.v, M. G.
Cherkasov, A. A.
Shestalov, A. G.
Gulya!-Iin, I. V.
Peterburgsidy, A. V.
Troitskiyj A. 11.
Lul I vanyuk, V. L
.Savz,-Iarg, E. E.
Trofimovich., A. Ya.
'.k'uznetsovy V. S.
Kudryavtoov, IT. Ye.
Pronin, A. F.
AlekYdn, IT. V.
Sachli, S. N.
Tit! @,f
tural Acadenv
"Elements of Fam. ing Moscow Arrricul
(textbook) imeni K. A. T-iriryazev
i4

MAYSURYANY N*A,, akademJ15 kand. sellskok-hoz. rauk
Centerinial ef domestic r,2ant groving. Zemledelie 27 no,,9989--96
3 165. (RIPA 18-11-0)
1. Vaesoyuznaya akademiya i3eltskokhozyaystvennykh nauk imani lenina
(flDr Maysuryan).

tmtfAN*, V.r.
LUKIIANIUK., V.I. How to attain high winter wheat yields, Moskva,, Goa,, izd-vo sellkhos,
ut-ry., 1954. 95 p.

LUKITAHM.M., kandidat sallskokhozyaygtvenrWkh nauk.
.0 -.%-- -,Ir,
New varieties of corn. Ilanka i zhiznl 22 no.4:49-50 Ap 155.
(Corn (naize)) (KM 9:6)

FAWN, Vasiliy 141khaylovich; 1:.,0171TSK1Y, Konstantin Amosovich;
LUK'YATIUK, V.I., muchn. red.; ISHALYT, N.A., red.
[Cultivation practices for pi-incipal farm crops] Agrotekh-
nika vazhneishildi selskokhoz1aistvenxwkh kulltur. Moskva,
Vyashaia shkola, 1964. 234 1). (I-11RA 17:9)

.L
LUKIYANYUK, V.I., kand. sellskokhoz. nauk, dotsent; VASILENKO, '.I., aspirant
Effect of high fertilizing rates on the formation and performance
the photosynthetic apparatus in winter wheat plants. Izv.
TSKHA no.2r7-18 163# (WRA 16:10)

JASHCHzilow. Bil; UJKIYASEMD, D.
Meteor activity of the'Quadrantid shower. Astrono taire no.189:
19-20 7 158o (KMA 11: 8)
I.Kharlkovski7 politekhnicheakiy inotitut im. V.I. Lenina.
(meteors--Januar7)

KASHCHEM , B.; LUKITASHKO, D.
-, @ - -.I - i@
Radar observations of sporadic meteors In January and February
1958. Astron. teir. no.191:22-23 My 158. (MIRA 11:9)
1. Khartkovskiy politekhnicheskiy institut im. V.I. Lanina.
(Meteors) (Radio astronomy)

29661
3/-169/61/000/005/018/049
A005/A130
AUTHORS: Kashcheyev, B., Lukiyashko, D.
TITLE:: Radar observations of sporadi,,z meteors during January and
February 1958
PERIODICAL: Referativnyy zhurnal, Geofizika, no- 5, 1961, 7, abstract 5 G
45- .(Astron. tsirkulyar.f. 1958, 8 maya,.no, 191,,22-23)
TF,XTs The authors observed radio reflections from meteor trails on
a 8-13 m wavelength. High activity was recorded on the nights of January
15 and 16 and February 16. The hourly.number of meteor.reflections is
given. In the main, the duration of reflections amounts to fractions of
a second- 54% of the number of sporadic meteors whose velocity was
measured in January had a geocentric velocity of 25-45.km/seo,
G.Z.
[Abstractor's note: Complete translation.]
Card 1/1

LIM I YAS FEKO,._ -D.
Observation of the Geminid shover. Astron. tsir. no.199:24' Ja
159. (MI-RA 13:2)
I.Eharlkovskiy politekhnichookiy institut im. V.I. Lanina.
(Meteors--DeceLlber)

KASHCHEYEV, B.L.; IMEbINETS, V.N.; LUKIYASHKOI,
Radar observations of meteDr activity under the program of the
International Geophysical Year in 1958. Mezhdunar. geafiz. god
(Kiev] no.2;32-36 160, (PaRA 14.1)
1. Kharkov Polytecbnical Institute.
i: (Metebra) (Radar in astronomy)
i

KASHCHEM, B.L.p, DUDNIK, B.S.; LAGUTIN, M.P.; LE INETS, V.N.;
WKIMUKO D.H.- LISENKOP IlL
Radio echo observations of meteors in Kharkov. Issl.ionosf.i met.
no.8:7-20 162. (MIlU 15:4)
Oet:eora) (Kharkov-Radar in astronomy)
I
I

43280
S/831/62/OUO/008/001/016
E032/Ell4
AUTHORSs Kashcheyev, B.L., Dudnik, B.S., Lagutin, M.F.,
Lebedinets, V.N., Luklyashko,
Lysenko, I.A.
TITLE: Radar observations of meteors
SOURCE: Ionosfernyye issiedovaniya (meteory).
no.8. V razdel programmy MGG
geofiz. kom. AN SSSR. Moscow,
7-20
D.N., and
at Khar1kov
Sbornik statey.
(ionosfera). M6zhduved.
Izd-vo AN SSSR, 1962,
TEXT. This paper reports the results of analyses of radio
echoes from meteor traits which were recorded at the Kharlkovskiy
politekhnicheskiy institut imeni V.I. Lenina (Khar1kov Polytechnical
Institute imehi V.I. Lenin) during JulY 1957 - May l9j9. The
observations were in accordance with the 1GY pkogramme and were
carried out at 73.2 Mc/sec and 36.9 Mc/sec. Special measures were
taken to suppress extraneous interference. Pulse lengths of
ten microseconds were employed at repetition frequencies up to
500 cps and ower per pulse -50-70 kW. The detector sensitivity
was 5 x 10- W. The half-power beamwidth in the final
Card 1/3