SCIENTIFIC ABSTRACT LY*GIN, V.I. - LYKHIN, V.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001031110014-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AMMM NE: AP403717"*' S/0069/(4/026/003/0324/03n,
AUMOR: ' Kisel"a A* To; Ly*ginl To Iq Solamonovai 1. No
TITIZ; InfrLred study of chemically moRfied aeros12
SOURCE; Kolloidny* 324-329
y zhurnal, V. 26, no- 3p 1964
TOPIC TAGS: aerosils modified aerosi2j, aerosil adsorbentp gas chrcoatogragbyp
infrared aerosil spojwunj ipubstituted dichlorosilane, surface active esterp
radical heat resistance, bydroxy groupp aerosil adsorptive propertyp deuterium
treatmentp chlorine containing groupp allyl radical
ABSTRAM The work concerns aerosils treated vith surface-active eaters, allyl
and chlorine-containing functional gmps, for use as adsorbents and carriers for
gas chromatogmpby-or fillers andpigments'-for polymara.' Tha'aarosil used (Mae
by Degus) bad a surface of 1T0 m2/g. Substituted d4ch' ros"alm a vith carboa
cbA-'n of.. various langth and functl=" andaroups vere used an =d4 Lars In a
diome medlun.
Card
V3-
14, F

Acawaw n: AM37177
CHI
CIBSICHICHiCOOCH3; C12SICHiCH-CHt; C1sSjCH2CHjCH3C1; 41aicf,
IlThe laboratory procedure is described. The extent or substitution of surface
1,bydroxyl groups by organic radicals was found at less than 50% (C detenaination. by
wet combustion). The material obtained was pressed into tablets for infrared
inspection. The spectra were obtained and it was concluded that mainly.free
surface hydroxyl groups'participated in the modification reaction; the functional
ester and chlorine-containing groups surface radicals are hydrogen-bonded to the
remaLning surface hydroxyls; and the most heat-ivaistant, radicals were those with
ester and chlorine-containing groups., allyl was less heat resistant. At the low
1: experimental density of the modifying layer, the remaining hydroxyl groups deter-
mined essentially the adsorptive properties of the modified aerosils. Treatment
~.with deuterium and methylation of.the latter's surface revealed availability of
part of the surface hydroxyls for small molecules and another part for large mole-
...culeap such as dietbyl ether., For gas chromatography denaer layers should be
Icarz-1
.2/3

Borimamw for
Ob. ~rw salmors vUh to Vxank D. Micharbakov and Is Ve
their belp in modifying the specimens and in th*ir aualpie-* Orl& azt- h":
TA ro==Iw andl SUP=,;
tot
.ASSOCtA=(Xs HookovskLY vnivervitat Im. X. V- rag=OsMp MdrAcbe taku).
(Xoo=v Univervita CbemLstry. Faculty)

'ENCIA 00
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NO BV owl' 021

3/3-
.

A V Cj T,;~ -1; V T
K I S E I:E-V
~sc~lrcm !.magr.~-tic reson-unce Spectra Of graphl, ~,a'-Dnn
blacks. Koll. zhur. 26 ro.5:651-653 S-0 t64.
17; 10)
1. Moskovok 'Xii-ve-sitet imond. Lomonosova, khirrd,~heskiy faku-- f t,et.

W1_ - 11T~ - - - 0 -
Acci;SSTO,11 14R: AP4034593 S/0076/64/038/004/1044/1047
AUMORI. Abramov, V. N.; Kiselev, A. V.; Ly*g:Ln, V. 1.
TITIE: Infrared study of the adsorption of phenol, apiline and nitrobenzene on
Aerosil and zeolite.
SOURCE: Zhurnal fizicheskoy khimii, v- 38, no. 4, 1964, 1044-1047
TOPIC TAGS: infrared spectroscop~r, adsorption., phenol, aniline, nitrobenzene,
Acrosil, zeolite, molecular spectra
ABSTRACT: In this work a study was made of the change of the infrared spectrum
of the hydroxyl groups on the surface of Aerosil, during the adsorption of phenol,
aniline and nitrobenzene, as well as the IR spectra of these molecules themselves,
upon the adsorption on Aerosil and zeolite. Fig. I shows the spectrum of Aerosil,
evacuated at 400 C and the spectra after adsorption of phenol, aniline and nitro-
benzen6 under saturated vapor pressure of these compounds at 25 C. Due to the
overlap of absorption bands of the associated surface and intraglobular.hydroxyl
groups'~of Aerosil and phenol it is difficult to establish accurately the magnitude
of the,shift of the groups of Aeroull with reapect to the absorption band of free
Card !/4

ACCESSION NR: AP4034593
hydroxyl groups:perturbed by adsorption of phenol hydroxyl The magnitude of
shift during adsorption of phenol is not more than 350 cm- DurinG adsorption
of aniline the band lies aroung 3200 cm-1 and the shift is 550 cm-1. During
adsorption of nitrobenzene the band of perturbed free hydroxyl groups on the
surface of AeroGil is completely masked. Therefore., one can only say that the
!"shift is much leas during adGoi3tion of niLrobenzene than during adsorption of
phenol,~and aniline ( e-150 cm- ). The changes of IR spectra of the adsorbed
molecules themselves are also shown in Fig. 1. The greatest changes are observed
in the vibrational frequency of OH in the phenol and NH in the aniline. In the
..case of nitrobenzene no significant changes are observed. Changes of molecular
spectra during the adsorption on zeolite are greater than during the adsorption on
Aerosil. Oris.~art. has: 1 table and 2 figures.
ASSOCIATION; Mookoveldy gosudaratveanyy universitet im. 14, V. Lomonosovaj
Khimicheskiy faculltat (Moscow State University im. M. Vs Imonooov., Chemistry
Departmpnt)
SUHUT~6; 05Nov63 ENCL: 01
Card 2/4

1111n= _i
ACCESSION NR: AP4034593
SUB CODE: GC NO REF SOV: 012 Cfrr[ER-. 006

ACCESSION NR: AP4034593-
Fig. 1. Infrared spectrum of Aerosil
1) pumped down at 400 0
after adsorption
2 pbenol
3
~ aniline
4 nitrobenzene 4.
a OH excited
b
~ transmission

ENCLOSURE: 01
Card 4/4
vew J00 .7400 J2001 Ctf 10U 14001 /Z,10

jL-23055-65-
-AP4047981
CdjtMON NR: S/6076164103810101240812414
AUTHOR: Zhdanov,: S. P-~ (Moscow); Kiselay, A. (Moscow); Lygin, V.
Titova, M.. I,~~ (Md.660W)
TITLE: Infrared spectra of synthetic faujesites of varying composition and of
their adsorbed water
.7~ al fizicheskoy khimii, v. 38, no. 10 1964, 2408-2414
SOURCE: Z
TOPIC TAGS:' synthetic faujesite, infrared spectrum, faujesite type zeolite
ABSTRACT: The IR s'ectra of synthetic faujesite-type zeolites of differient coma
p
position -a n'd-with, different: cations, and of ze~ql~iites (mntaining adsorbed water
z__
e crvs
whi4~h Was desorbed from the channels in the crys al under different conditions
were investigated. 'Sodium faujesites with 3i*A1 ratio varied from 1. 2 to 2, 5
and fa-ijesites in which the Na was extensively replaced by Ca or Sr were prepar-
e d. T he- A1,0 bond frequencies in the tetrahedral framework were very sensitive
to the speciea of the compensating cation. The fauiesites with a high Al content,
i. e. with the. greatest concentration of exchange cations, displayed several diffe r-
Card.

KISELEV) A.V.; KUBELKOVA, L.; LYGIN, V.I.
Study of the adsorption of methanol by synthetic faujasites by
the method of infrared spectroscopy, Zhur.fiz.khim. 38 no-11:
2719-2725 N 164. (MIRA 18.2)
1. Moskovskjy gosudart3tvennyy universitet imeni Lomonosova,
khimicheskiy fakulltat.

KISELEV, A.V.; IAGIN, V.I.; TITOVA, T.I.
Specific adsorption of amnonia on silica and zeoliLe ET;udlied lc~y
infrared Bpectroscopy. Zhur.fiz.khim. 38 no.11.273,C-27/33 N 164.
(MIRA !8:2)
1, MoskovBkiy goBudaretvannyy univemitet imeni LomonoBova..
khimicheskiy fakulltet.

GALMN, G.A.; KISEL"Ev, A.V.; LYGIN, V.I.
Variations in the infrared spectrtba of beazene a- or aerosil
as a function of coverage and dehydration of the surface. Kin.i
kat. 5 no.6:1040-1048 N-D 164. (MIRA 18:3)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova,
khimicheskiy fakulltet I Institut fizicheskoy khindi AN SSSR.

N, P
54777-65 EPA WV/,RVz
i ACCESSIO111 UR: '~AP5014521 UP/0069/65/027/033/0320/0325
41
541.163
-r. K.; Galk-*n, G. A.; Kiselev, A V: -Ko
Ro rolev, A. Ya.;
AUTHOR, -r1sova,1_ Lygin,
!TITLE.: .'Infrared: study-of the nature.of the active.adhesii layer on the surface
f
:SOURCE:'~, Koll6i4nyy:zhurnal, v. 27, no. 3, 1965,323-325
YOPM:TAGS. pol-tet
4~. rafluoroethylenei surface property,surface treatment, polymer,
ir spectrum.
fl. Oropokvm~er
iABSTRACT, The.IR spectra or~ surface compo nds- based on polytetrafluoroethylene
!nOdifled bv diffiti6nt~.M'ethods -were s.tudiedusing Folymer. filv-_. Modification of
wi , k _-ffq_uid_
:he---f iW-!!-y~th r in-d wm~napU_tWa_J:e_6e_6a,,; ~ev.,~rn
soil on-:- f- tallic-sodium-
-in: um acetate) produced hydro-
ma. ..o me and. . molten p9t,assi
lphobizatiombf-thesurface and improved the adhesiva properties of the polymer. In-.
ifrared spectra vem -studied in surface compounds based on multilayer poiym--r films
lbefore and aft6r modification. Conjugated double bonds were found in the surface
I Ca~ 1/2..
1_7

ABRAMOT, V.N.; KISELEV, A.V.- Ij
,_ '~~oskva)
Vibrational spectra and Otate of vater molecules adsorbed or
synthetic zeolites. Zhur. fiz. khim. 39 no, ls123~-128 Ja 165
(MTRA 19il)
1. Moskovskiy gosudarstvannyy universitet imeni M.V. Lomonosova,
khimicheskiy fakulltet. Submitted May 199 1964.

KISELEV, A.V.; KOZLOV, G.A.;_.LYGIN, V.I.
Electron paramagnetic resonance of modifted Ukhta channel' b-',a(--Ks.
Zhur. fiz. khim. 39 no.5:1256-1263 Mj 165. (M!P-k 18;8)
1. Khimicheskiy fakulltet 14oskovskogo gosudarstvennoFo
universiteta imenj M.V. Lononosova.

GALKIN, G.A.; KISELEV, A.V.- LYGIN V.I.
Infrared spectra and energy of interaction in the adsorption
of aromatic compounds on aerosil. Kin. i kat. 5 no.5;935-
938 S-0 16/4. (MIRA 17:12)
1. Inatitut fizicheskoy kbim 'i AN SSSR i Mookovskiy gosudarstvennyy
universitet imen! Lorionosova, xhimicheskiy fakulltat.

ABRAMOV, VA.; A~V.; VII.
,ria Y~4s o' the vibre--, -or4 Ie c of adsorbe-, a=onia.
Zhur. fiz. kiiim. 395 j-, 164.
(MMI 18:3)
1. Moskmskiy gosudarstvennyy univeroitpt imeni Lomonosovall
k2himicheskiy fa~ulltet.

ZEDANOV, S.P.; KISELEV, A.V. I; LYGIN, V.I.-; OVSEPYAN, M.Ye.; TITOVA, T.I.
Infrared spectra of synthetic zeolites type NaA, NaX, itTnij a~rld
their decationized forms. Zhur.fiz.khim. 39 no.10:2453-2458 0
165. (MIRA l8t12)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova,
khimicheakiy fakulltet i Institut khimii silikatov U1 SSSR.
Submitted July 6, 1964.

1-,,(G.1 N) V. 1.
nfrar~jrl and re=aance srecu-a r,!' ~~h~nnell
b
'I ~ - _., -L , " 7-
.1 kc. Zhurj' ris.21:2? '1-2778 N
Aonko,,-sk,.v gc:;u(!4rst%rsnn3r un (Ml Pj-. :L8z 12
r ivencitat imeni M.V.J/-,,mc)nv6ova.

ACC NRi AP6031651 SOURCE CODE: UR/0020/66/170/001/0139/0142
AUT]HOR: Zubov, P. I.; 4iselev, A. V. ; Kryl.ova, L. M.; Sukhareva, L. A.; Lygin,
V. I
1-ORG: Institute of Physical Chemistry, AcadeaV of Sciencee,SSSR (Institut fizicheskoy~
khimii Akademii naUk SSSR), Moscow State University im. M. V. LomoBov (Moskovskiy
gosudarstvennyy x!niversitet)
TITLE: 7Effect of molecular interaction between polymers and solids in the
mechanical properties of polymer coatings
SOURCE: AN SSSR. Doklsdy, v. 170, no. 1, 1966, 139-142
T01?IC TAGS: polymer-coating, molecular interaction, internal
ttiN-ngth, -m=Warg adhesion
stress, emu-ting I P" (_
ABSTBA&': A study ~as been made of'theointeraction of polymer functional groups
with filler sur;faces, and of the effect of this interactionon. the internal stresses,
strength, and adhesion of'polymer coatings. The experiments were conducted with
PN-1 polyester resin or FL-50 akyd resin, and aerosil filler, both nonmodified or
modilied with actadecylamine. 'The interaction was studied by IR spectroscopy.
The ~results of the experiments given in graphic form indicated that the mechanical
properties of polymer coatings are highly dependent on the nature of the molecular
interaction between polymers and solids. Orig. art. has: 4 figures.
SUB CODE: 11, 2o/ SUBM DATE: O7Dec65/ ORIG REF: 008/ OTH REF: 001
i Card 1/1 upc: 541.68

EYDELISHTE321, I.A.; LYGIN) V.T.
Investigating operating conditions of the Pk-4 and FX-5 cutter
loaders. Nauch. trudy KNIUI no.13w.213-219 164
Results of testing the PK-4 and Fk-5 minig cutter-loaders in
the Karaganda Basin. lbid..1219-226

A"". cuum _~t -OM*,, *lth thd surface cmted vifth C'oxidtc~
T.- ~.4nA theaami~ black,afler gmphitizing in H, at 17,00'for 1.61
F
Iza. Tide differential heat of adsorption m these sajnple4
'~Lud Cie n-C&H,4 vzpor ndzo.7,ric,, ~sntherm were detd. with
attomatic recording mlwimeter with eQuat hcat ex.
in tbe Asc;n.~tirjn app. The ;mphitLuttin:i treat-
ment made the surfare more uniform and increased the ad.
add tLe heat of adiwcptkin of hexane- The max.
All-4

th V-R -1 idwrptlctn' U-C-3r-4,
o
the IC:aTiZm~Ir adsorp66
Th
t. range it conforms to thtEl.E.T, equatimi
'Wation betV7Mq the free and the total ener , and the va~:
4dwrptjou tbenr, were investigated, FLnd tv, o=csponding
nd -aftor -and wmiag valluz- 4fre det:j. The
d
SIA
'te vm~s calcd.
rpt!b.
enugy of ad -w n of hemne upon gruptit
hite Inttice
lati-In on 100 cic,5est gmp
therintic5liY by sumn
-0-w of - '! m
aforns- The disp-muma! imer,.ic he vi7,~rb~ of:$.
of hv~-.-~i,-, N % linear tm-, "f t ll~ C at!m-u- in
energy urree. w &I -=-E~6tff
. ..-

k- I '~ '% W A11 a:-' -Q~.
AUTHORS: Avgull, N. N., Isirikyan, A. A., 62-11-4/29
Kiselev, A. V., Lygina, I. A., Poshkus, D. P.
TITLE: Adsorption Equiibria and the Energy of Adsorption
Powers (Adsorbtsionnyye ravnovesiya i energiya
adsorbtsionnykh sil).
PERIODICAL: Izvestiya All SSSR, Otdel. Khim. Nauk, 1957, Nr 11,
Pp. 1314-1327 (USSR)
ABSTRACT: Here the theoretical and experimental investigation of the
adsorption powers in physical adsorption, mainly of complicated
non-polar molecules with adsorbents of an atomic and ionic
lattice, is brought. The results of the theoretical
computation are compared with the measurings of the dif-
ferential heats of the adsorption. Here a method for the
computation of the adsorption energy of non-polar molecules
with regard to three terms in the potential of the dispersion
powers with constants, which are computed by means of
polarizibility and magnetization-coefficients, was worked
out. With it the induction potential by the averaGe
polarizibility of the adsorbed substance and the average
electrostatic field of the adsorbent was taken into
Card 1/3 consideration. Furthermore the push-off potential with a

Adsorption Equilibria and the Energy of Adsorption Powers 62-11-4/29
constant in the exponent, which is computed from the
individual constants of the : adsorbent, is taken
into consideration.'Finally all interactions of the eiven
power center of the molecule of thH adsorbed nubstance are
added up with all adsorbent-lattice centers. The puah-
off constant before the exponential function J5 determined
from the condition of the minimum of total enerCy of all
interactions in an equilibrium distance from "he adsorbent-
surface. It is shown that the computed adsorption energy
amounts of inert gases, nitrogen and 13 hydrocarbons of
different structure (normal and isomeric alcanes, alcene,
aromatical ones) on graphite are similar to the measured
adsorption heats on graphited soot. It is shown that the
computed adsorption energy amounts of the n-alcanesp of the
benzene and toluene on maEnesium oxide are also similar to
the measured adsorption-heats. Furthermore it is shown, that
in the case of an adsorption on graphite the amounts of the
first, second and third term of the enerGy of dispersion
powers and the absolute amount of the push-off energy were
90-95, or 5-10, or 0-5 - 1, or 35 - 40 % respectively of
Card 2/3 the total energy of dispersion powers in the investigated

Adsorption Equilibria and the Enerey of Adsorption Powers 62-11-4/29
adsorbed substances (adsorbates?) In the adsorption on
MgO the amounts of the first, secuid and third term of
the energy of dispersion powers, of the energy of
induction powers and the absolute amount of push-off
energy were about 81-83, or 12-14, or 3, or 2, or 42-48 %
respectively of the total energy of the attractive powers
(the dispersion and induction powers).There are 4 figures, 3
tables, and 41 refererces, 15 of which nro Slavic.
ASSOCIATION; Institute of Pbysical. Chemistry of the AS USSR and
Laboratory of Adsorption at the Moscow State University
imeni M. V. Lomonosova (Institut fizicheskoy khimii
Akademii nauk SSSR i Laboratoriya adsorbtsii Yloskovskogo
GoBudaretvennogo universiteta im. M. V. Lomonosova).
SUBMITTED: September 3, 1957
AVAILABLE: Library of Congress
Card 3/3

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and a samy'!r-. of -~-A-med
qt
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T,12
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Zit i~
mcremm
ei Thi~ tzl~, i-
uiv.

.Y. ~7-~
LYGINA, I. A., Cand Chem Sci (diss) "Energy of adsorption
of hydrocarbons on graphitized carbon black." Mos, 19561- 14
pp (Auad Sci USSR, Inst of Phys Chemistry), 100 copies (KL,
18-58, 96)
-20-

5 (4)
AUTHORS: Avgull, N. IT., Berezin, G. I., SOV/62-59-5-5/40
Kiselev, A. V., LySina, 1. A.
V--------------------
TITLE: Adsorption Heat of a Nwber of Isoulkanes, Naphthenes and of Toluene
on Graphitized Carbon Black (Teplota adsorptsii ryada izoalka-
nov, naftenov i toluola na grafitirovannoy sazhe)
PERIODICAL; Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 5, pp 787 - 796 (USSR)
ABSTRACT: In this work the following hydrocarbons were investigated as to
their adsorption heat: three isoalkanes (neohexane, isoheptane,
and isooctane), two alicyclic hydrocarbons; cyclopentane and
methyleyclopentane, and the alkylaromatic compound toluene.The
hydrocarbons had been selected in this way in order to investi-
gate the effect of the chain branching, the rin.-- formation o.f
these chains, and the introduct:Lon of aliphatic siibstitu-,ntE
into the naphthene and benzene ring on adsorption. The hyd-r)-
carbons used in the investigations had been synthetized at th-
InBtitut organicheskoy khimii AN SSSR (institute of OrCan-11c CL'.-
mistry of the AS, USSR) by Ye. A. Mikhaylova, A. P. Plate, A. L.
Liberman, and S. V. Zotova. The authors express their gratitulliq
Card 1/3 for their help. The constants of these substances are 3un--ma7iz-

Adsorption Heat of a Number of Isoalkanes, Naj;hthenea soVO/62-=O-r-r/4_
and of Toluene on Graphitized Carbon Black
ed in table 1 . "Sferon!~-6 was used as adsorbent; it was grapl,"-
tized at 17000.-The differential adsorption heat was
at 200 in a calorimeter with constant heat exchange; -the az, --:nt
of the adsorption was determined by means of a capillary va(:_~iZ
liquid microburet. Figures 1, 2 show the isothermal lines -.f
adsorption of the various substances and figures 3, 4 sh',)w 46"~Z-
dependence of the differential adsorption heat on the a!Lourit
of heat adsorbed by the individual substances. The figures
that the normal adsorption heat of iaoalkanes and naphthene~l Is
lower than that of the corresponding n-alkanes. The value ~,'
the addorption heat of cyclopentane amounts to only -half of
that of n-pentane. Cyclopentane, therefore, shows graater at-
traction towards the adsorption layer, its isothermal line of
adsorption is concave at its beginning. It can be seen from the
thermodynamic evaluation of the experimental data obtained that
the isothermal line of adsorption of cyclopentane cannot be rs-
presented by the Langmuir equation or BET equation but by an
Card 2/3 equation which allows for the interaction adsorbate-adsorbate

Adsorption Heat of a Number of Isoalkanes, Naphthenes SOV/62-c0-5-a/40
and of Toluene on Graphitized Carbon Black
Fig 5). The entropy curves (Fig 6) indicate that the state of
isoalkanes and naphthenes in the dense adsorption layer on gra-
phite is much closer to the liquid state than that of n-alka-
nee. The methyl group in the toluene molecule reduces its mo-
bility with respect to the unsubstituted benzene and the other
purely cyclic compounds. With regard to the theoretical calcu-
lation of adsorption heat it was assumed that, in the case of
the ramified hydrocarbons, the adsorption heat is an additive
function of the number of carbon atoms in the molecule. The
free adsorption energy and the surface of the adsorbent occu-
pied by moleculeswere determined according to the same assump.-
tion. There are 6 figures, 3 tables, and 17 references, 12 of
which are Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences, USSR)
SUBMITTED: July 25, 1957
Card 3/3

5 (2), 5 (4)
AUTHORS: Av,- Soll/62-59-7-7/38
gull N. IT., Kiselev, A. V.,
Lyginal 1. A., ?Onhkus, D. P.
TITLE: A Contribution to the Calculation of the Energy of the Adsorption
of Fonpolar Molecules on Graphite (K raschetu energii adsorbtsii
nepolyarnykh molelml na grafite)
PERIODICAL: Izventiya Akademii nault SSSR. Otdeleniye Ichimicheskikh nauk,
195% Nr 7: pp 1196-1206 (USSR)
ABSTRACT. In this paper the details of a calculation-'of the adsorption
energies of simple and compound molecules carried out in a
previous paper are reprecented. The calculati= were carried
out according to the forndw from paper reference 1 according to
which the adsorption energy is determiLea by the expressione
6 1
C r- _ C r~4 0 + B!
ii ij i2E r1j8 Ci3 ij j
C r_6_ Ci2j:r-8 C r-10 + Bit ~:,-l 2
ii 13y~ 4i
j ij ij i ij t i -..

Card 1A rij is the distance of the center of -the i-th adBorption
molecule from the center of the j-th atom of the adsorbent.
0

A Contribution to the Calculation of the Energj of the SOI/62-59-7-7/3e
Adsorption of Nonpolar Molecules on Graphite
Cil,2,3 are constants of the dispersion reaction. BI and B" are
the constant of the exponential function and the constant of
the repul3ion precedina the powers. 9 is an exponential constant
of the repulsion. The calculation is carried out in two parts,
the geometric one in ... hich the distances of the adsorbed link
to all atoms j of the lattice of the adsorbent are calualated fez
different distances of the former from the surface. For this
calculation only the lattice constants of the adsorbent have
to be known. For the second part of the calculaticn of the forces
the constants charaterizing the reactions of both substances
have to be determined. The calculation of the sums of r.. was
3.j
carried out for n - 6, 8. 10 and 12 for the different distances
of the adsorbed link from the basis of the adsorbent equal to
2p 2.5, 3, 3.5 a (a is the distance of the nearest atn.,.i). In
table 1 the recults of the calculation of the surao
Er-n are combined. The distances of the remaining graphite
ij
Card 2/4 volume were determined from the integrals (3). (4), (5) (Table 2).

A Contribution to the Calculation of the Energy of the SOV/62-59-7-7/38
Adsorption of Nonpolar Molecules on Graphite
ri n
The sums F r- + I are represented in tables 4 and 5 and the
'J (n) rij/0.28
graphic representation in figure 2. The value Ze-
for 9 in table 6 was equated to 0.28 according to referonce 6.
For the sums of tables 4, 5 a simplified form with the constants
Pn and qn, the values of which are given in table 7, is introduced
and the functions (1) and (2) are represented in the variable z
(6), (7)- ri r-n + f. V z-qn Next, the calculation of the
ij n - n
reaction constant Cil,2,3 is carried out. The values for
different adsorptives are given in table 7 with the constants
&-and)L (polarizability, magnetic susceptibility) being
necessary for the calculation of Cil,2,3. ~' and viere then
Card 3/4 determined by the aid of computed constants. The results for ~ 11

A Contribution to the Calculation of the Energy of the SOV/62-501-7-7/38
Adsorption of Nonpolar Molecules on Graphite
are given in tables 10 and 11. The calculation of the attraction-
and repulsion constants was carried out from the balance energy
of the adsorption of compound molecules on the basis of an additive
scheme. There are 6 figures, 11 tables, and 8 references, 2 of
which are Soviet.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute of
Physical Chemistry of the Academy of Sciences, USSR)
Khimicheakiy fakulltet Ifloskovskogo gosudarstvennogo universiteta
'im. M. V. Lomonosova (Chemical Department of the Moscow State
University imeni M. V. Lomonosov)
SUBMITTED; November 16, 1957
Card 4/4

AVGULI, N.H.; BMEZIN, G.I.-, KISELF.V,A.V.,,.LYGINA. I.A-.
Adsorption and the heat of adsorption of n-pentane and n-hexane
on barium sulfate. 12V. AN SSSR-Otd. khim. nauk no-11:1948-1954
n 16o. OAIRA 13; 11)
1. Institut fi%icheakov kbimii Ali SSSR.
(Heat of adsorption) (Pentane) (Hexane) (Barium sulfate)
11

AVGULIg N.N.; BEREZINg G.I.; KISELEVt A4V.; LYGINAp I.A.
Adsorption and heat of adsorption of normal alcohols ongraphitized
carbon black. Izv. AN SSSR. Otd, khim, nauk no.2:205-214 F 161,
(MIRA 11,:2)
1. Institut fizicheskoy khimij AN SSSR.
(Adsorption) (Carbon black) (Alcohols)
I

AVGULI 11 N.N.; KISEIEV, A.V.; IIA I.A.
Adsorption energy of CO 21 -c (CHj)2ClD and (C2F ) 0 on
,~21
graphite. Izv. All SSSRO' Otd.khim.nauk no.8:33c.~Iiimig
t61. MIRA .14:8)
lo Institut fizicheskoy khimii AN SSSR.
(Adsorption)

AVOULI, 'R.N.; USEIEV, A.V.; LYGINA., I.A.
--------------
Adsorption energy of water., Cccholp# ammonia., and tethylamine
on graphite, Izv. AN SSSR. Otd.khim.nauk no.8:1404-=
Ag 161. (MIRA 14&8)
1. Institut flzicheakoy khimii AN SSSR.
(Adsorption)

AVGULt, N.N.; KISEaT, A.V.; LYGINA~ I.A
Isotherms and beats of adsorption of alcohols on carbon blacks
of various degrees of graphitization (with sumnary in English].
Koll.zlxr. 23 no.4:369-375 JI"Ag"61. (MIRA 14.8)
1. IAstitut fizicheskay kchimili AN SSSR, Gruppa khimii poverkh-
nosti, MoskVa.
(Alcohols) (Ifeat*of adsorption)

AVGULI KISEMV I A.V.; LYGINA I.A.
Adsorption and heat of adsorption of-isomeric butanols on
graphItized carbon black. Koll.zhur. 23 no.5:513-520 S-0 161.
(mm 14-9)
1. Institut fizicheskoy khimii AN SSSR, Gruppe, khimii poverk-
I=sti, Moskva. ,
(Butyl alcohol) (Heat of adsorption)

AVOUL's N.N.; MELEV, A.V.; LYGINA, I.A.
........
Adsorption and heat of adsorption of diethyl ether, acetone, and
acetic acid vapors on graphitized carbon black. Izv. AN SSSR
Otd.khim.nauk no.12:2116-2125 D 161. (MIRA 14:11)
1. Institut fizicheskoy khimii All SSSR.
(Adsorption) (Ethers) (Acetone) (Acetic acid)
. I

AVGULI, N.N.; KISELEV, A.V-.; LYGINA, I.A.
Adsorption-and the heat of adsorption of pyridine and benzene
vapors on graphitized carbon black. Izv. A14 SSSR Otd.khim.nauk
no-1:32-37 Ja '62. (MIRA 15:1)
1. Institut fizicheskoy khimii AN SSSR.
(Pyridine) (Benzene) (Heat of adsorption)
0

AIGULIV N.H.; KISELEV, A.V.,, MINA, I.A.
Potential energy of adsorption of sphere-shaped molecules of
C--%43 C(CH3) . and CC~4 on graphite. Izv.AN SSSR.Otd.khim.nauk
no*8:l346--I%3 Ag 162. 0-MRA 15-8)
1. Institut fizichaskoy kbimii AN &93R.
(Adsorption) (~bleeules)

AVGULI., N.N.; USELEV, A.V.; IYGINA, I.A.
r-
Nblecular-statiotical evaluation of the change of thermodynandc
functions in OR adsorption on graphite. ImAll SSSF-0td.Zhim.
nauk no.8:135;-'1357 Ag 162. (1.01?A 15:8)
1. Institut fizicheakoy khim:Li AN SSSR.
(I-bthane) (Adsorption)

-J:
S/069/63/025/002/001/010
hL
gature of Ad~orptioft by ze6lites. -Heat of A057/A126 ix,
f wh
-..are', our sites in the cavity walls having cations in their centers idhare f
-:,":*vorab e for
1 the localization of benzene molecules. It can be assumed that the
'..--:Stretched and flexible n-hexane molecules depend less.on the position of these
cations.- Hence," the-adsorption of n-hexane is less lo' n to
calized in compariso
benzene.- The adsorption on zeolites, however,.is highly
affected by the geomet
8 ture of the adsorbed molecules, the geometry of th
and.eldetronic Ai-ua e cav
ities, and the nature'of the eleotrio afield of the adsorbent. The packing of
mol, eoul6s.of.'the adsorbate in the zeolite eavities,differs' therefore, from their
Polyani's potential theory of adso tion can-
packing-An the li4uid state. Thus
not,be-appiie4 to "the -adsorption of hydrocarbon vapors by zeolitps. The state i
packing of hydrocarbon molecules-iri zeolite cavities will find further ex-
Planations by e;)Teriments with n-alkanes with molecules of-different-lengths and,
I..': their substitutes with various . functional.~ groups, plane molecules, and different--
electron structure,as well as adsorption experlments with small molecules (ni-
t
7;-,, rogen, argon). after* adsorption of highly adsorptive, large moleculeag which are
1
0
osely filling Uie cavities. There areA figures#
.M6skoirskly.-imiversitet,'Khimicher.kiy,faku
jj~~JATiON s 11tet (Moscow University,
Card 2/3.-~-
-047
L

VOT-1 L K, IE S V A , V. 1,Y GI A, f A
I a:,
S --a n. ~a r e .7 r
no.S. Ag t
o '.,tt 'iz ml I
L

KISELEV~ A,Vo;- LYGINAO I,A.
Potential energy of No, Aro Kro Xal and CH4 OrYfltal UttlOds, Izv-
AN SSSR, Sar, khim. no.7t1143-1151 165. (MIRA 180)
14 1hatitut fisiahaskoy khimU AN SSSR,
I

RATUSHNYY, G.D.; KOMAROVA, S.N.!j LYGIN.AN.I.-* POGREBYNYAK, E.G.
4
Application of ion exchange for the acidification of fruit and
berry juices. Trudy KIPP no.22t371-37/#,161. (KIRA 16 s 4)
(Fruit juices)' (Ion exchange)

LYGINA, T.I.
----NMMWW
Zffect of phthivazid on the morphological picture of the blood.
Vrach.delo no.5:487-489 W 157. (MLRA 10:8)
1. Kafedra farmakologii, (zav. - chlen-korrespondent AMN SSSR, prof.
A.I.Cherkes) Iftyevskogo meditsinskogo institute
(ISCNICOTINIC ACID) (BLOOD)

.LY(,, NA-V-12if " . .
11-:A- ~~. `,- ; -., -
Cardiovascular changes induced by phthivnzid. Vrach.delo
no.1:57-59 Ja 158. (MIRA 11:3)
1. Kafedra farmakologil (zsv.-chlen-korreopondent AM11 SSSR, -prof.
A.I.Cherkes) Kiyevskogo meditsinskogo instituta.
(CARDIOVASCULAR SYSTEM) (ISONICOTINIC ACID)

LYGIXk,. T. 1.
Absorption, distribution and excretion of phthivaside. Yarm. i toks 21
no.6:62-64 N-D 158. (NM 12:1)
1, Kafedra farmakologii (zav. - chlon-korreapondent MM SSSR prof. A.I.
Charkes) Kiyevskogo ordena Tradnvop-o Krasnogo Znameni maditainakogo in-
stituta imeni akad. A.A. Bogomolftea.
(ISONIAZID, metab.
absorp., distribution & excretion (Itus))

LYGINA, T.L. kand.med.nauk
Some pharmacological characteristics of ketone of paluitic acid.
A~msh.l gin. 35 no.6:23-25 N-D 159. (MIRA 13:4)
1. Is laboratorii po lzyukaniyu I izachenlya protivozachatochnykh
oredstv (zaveduyushchiy - prof. Te.F. Shamray) Instituta okhraav
materinstva i detstva imeni Geroya, Sovetskogo Soyuza prof. F.M.
bjyko (direktor - dotsent A.G. Fan) Ministerstva zdravookhraneniya
USSR.
(PATTY ACIDS pharmacol.)
(CONTRACEPTIVES)

130GATSFAU, L.No, dot sent -#--ZLT- GINAv T.I., starshiy nauchnyy sotrudnik
Pharmacological characteristice of giLlascorbin. Vrach.delo
no.WO3 7 160. (KM 13:6)
1. Fafedra biokhimil (zav. - prof. Te.F. Shamray) Kiyevskogo
meditsinskogo instituta,
(ASOMB IC ACID)

I:ZGL,-,i.il V. V.
"Obtainln- of 11ohnite ~ lazi - : I',rorth` -* ~~
.1 -, n-'.
(ITI-i- ite) DLU-in, Reactions in "he -, 4- L~, v r-- . 11 r, n i 'I -.o1-' ' 1 n
I-VI Q I -~ 1, '1" -L
Sci [no Inst --iverij, L-enin--,rad, 1954. (HZhr;,.-,ol, 3e-P 54)
.2 u
SO: Sim 1+32, 29 ALar 55

15-57 -7-9443
Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 3,
p 103 (USSR)
AUTHOR: Lygina V V
TITLE: Obtaining Gehlenite and Anorthite by Reaction in Solid
Solution (Polucheniye gelenita i anortita pri reaktsii
v tverdom sostoyanii)
PERIODICIL: Uch. zap. Leningr. gos. ped. in-ta, 1956, Nr 117,
pp 33-54
.ABSTRACT: Pure preparations of CaO, CaC03, Al 03 Al(OH)3, and
S102, crystalline and amorphous, an~ ne-varly pure kaolin
were used as the initial products for synthesizing geh-
lenite (2CaO-Al2O3-S'02) and anorthite (CaO-Al2O3-2SiO
Preliminary treatment consisted of heating, drying, ani,
determination of the chemical composition, chiefly to
determine the iron oxide admixture. A mixture having
the stoichiometric relations of anorthite and gehlenite
was prepared from carefully ground material. Minerali-
Card 1/3 zers were added in the proportion of one percent by

Obtaining Gehlenite and 1-morthite by Reaction (Cont.)
15-57-7-9443
weight. These were: apatite, fluorite, cryol"te, molybdic
acid, and tungsten anhydride. The mixtures were heated in elec-
tric furnaces at 9000, 10000, 11000, and 12000 for periods of
2.5 and 10 hours. The products of roasting were examined in
immersion media under the microscope. In some instances X-ray
powder patterns were made. The reaction rate in the solid state
proved to be very low, especially when the mixture consisted of
the pure oxides CaO, A1203, and S102. The rate increased mark-
edly when a gas phase was present; when CaQ was introduced in
CaC03, and A1203 was derived from Al(OH)3, The use of amorphous
S102 in addition to crystalline material somewhat increased the
reaction rate. Fluorite and apatite proved to be the most
effective mineralizers. Study of the synthetic products of the
temperature stages from 9000 to 12000 has shown that the same
intermediate products are formed during the synthesis of both
gehlenite and anorthite. A schematic coarse of reaction for
both minerals may be represented by the following intermediate
reaction equations: 1) nCaO + mA1203 = nCaO4mAl2O3 (n,,m = 12:7);
2) 2CaO + Si%= P-Ca2S104 or 3) nCaO-mAl 0 +S102 =,8-Ca2SiO4
+ CaO- A1203; 4 8 -Ca2S'04 + A1203 = CaO. ~12k + CaSiO3; 5)
Card 2/3

obtaining Gehlenite and Anorthite by Reaction (Cont.)
15-57-7-9443
CaO-A1203 + CaSiO3 = 2Ca0-,Al203'Si02 (gehlenite); and 6)
2CO-A120-4-SiOo + 2SiO2 = CaSiO + CaO-Al2O3-2.'3iO2 (anorthite).
According'*'to this scheme~,gehlenite is formed from the high-
temperature combination of CaO-A1203 and CaSiO and not from
12Ca0-7Zl203 and CaS103 a's Yander (?) and Petri (?) had stated.
Gehlenite, as an intermediate product during the formation of
anorthite, was discovered in slags composed Of CaC03 - kaolin,
and this, too, is in disagreement with the results of Yander
and Petri. The optimum conditions for synthesizing gehlenite
and anorthite by reaction in the solid state are a temperature
of 12000 and sustained heating for at least 10 hours. The
initial materials for this synthesis should be amorphous S102,
CaCO and 1.1(OH)3. The sequence of formation of combinations
in Re, solid state in the system CaO-Al2O3-SiO2 has shown that
the most mobile component in the system is CaO, and the most
inert is S102. This circumstance may explain the earlier and
more frequent formation of gehlenite in these experiments than
anorthite, and also the rare discovery of gehlenite in nature as
an intermediate reaction product during the formation of anorthite.
Card 3/3 A. A. Leontlyeva

-LYq~4Aj,-,Y-Y-j.--SARANCHINA, G.M.
Geology and the characteristics of the metamorphism of crystalline
rocks*in the northern part of the Karelian Isthraus (in the vicinity
of Kuznechnoye). Vop,magm.i metam. W15-137 164. (MIRA 18:3)

Terminology in orthopedic stomatology. Stomatologiia 35 no.5:48-50
S-0 !56 (MWIA 10: 4)
1. Iz kafedry chelyustno-liteavoy khirurgii i stomatologii (nach.-
prof. V.K. Mukhiu) V6yeano-medltuiuskoy ordana Lanina akadamii imani
S.M. Kirova.
(STOMATOLOGY-TERMINOIDGY)

LTGUN. M.I, (Leningrad)
--l- -------
Iftmotional method of determining central occlusion. Stomatologiia
38 no.5:50-52 S-0 159. (MIIU 13:3)
(MASTIGATION)

LYGUN, M.I..... cu)
~.(Bak
A few practieal ouggestulana In 'the tec~mique of dental pron thesis.
Stomatologiia 42 no.39101 Ky-Je'63 (MLA -1'7 a!)

AUTHOR: L2&T4 SOV/130-58-7-1V35
TITLE: Friendly Mutual Assistance (Tovarishcheskava vzainopomoshch')
if 1,
PERIODICAL: Metallurg, 1958, hr 7, P 34 '+ 4 plates on pp.14-15(USSR)
ABSTRACT: The author stateb u"at the crew of his blast furnace
at the imeni Dzerzhinskogo (imeni Dzerzhinskiy) Works produced
3,989 tons of pig iron more than planned in the first quarter
of this year. He says that efforts are being made to increase
production still further and notes that the competitive marks
system has been abandoned. All are now helping each other.
There is 1 illustration.
ASSOCIATION: imeni lizerzhinskiy Works
Card 1/1 1. Blast furnaces 2. Iron--Production

~,'LM, Karoly
Bertalan Szekely; his historical paintings, 1860-1870.
Elet tud 15 no.22.-067-690 29 MY 160.

LMU, Karoly
Light and color dreams of Janos Vaszary. Blet tud 15
no.30:943-9/+7 24 n l6o.
A~.

LYKA, Karoly
"Becoming acquainted with arts" by Tivadar Artner. Reviewed
by Karoly Lyka. Elet tud 15 no.36tI146 4 S 160.

Munkaony and his Hungarian people. Elet tud 15 no.45:1423-
1426 6 N t60.

LYUp Naroly
The master of Zabegeny; to the memox7 of istvan szozqi. p_jet
tud 15 no.51s1614,1618 IS D 160.

LM , Karoly
In omemoration of Tozoef Egry on the 100th anniversary of
his death. Blet tud 16 no.8t240-244 19 F 161.

LYKA, Karoly
Joan Francoiq Millet, painter and poet of village !--.'L-le. -Elet
tud. 16 no.53zl680-1684 31 D 161.

44 0- Kuoly-'..-
To the memory of Karoly Kernstok. Elet tud 17 no.33.-1038-1042
19 Ag 162. %

LYKA, Karo
Paul Gauguin.4,painter of the tropics., Elat tud 17 no-24:751-755 17 Je
t62.

KVI (m) /EWP(k) /E74P(t) /FTT In
ACC NRt 14 A
AR6013850 I 0_,__,-_S_0__U,RCE CODE: 1JR/0276/65/000/01176W67GO46
AUTHORS: Gerike. L.; Volchkov, Ye.; Iqkasov, IT.; Bogarsukovo is
TITLE: Department of high accuracy casting with the use of malting patternsp at the
Kuznetsk machine construction factory
SOURCE: Ref. zh. Tekhnologiya mashinoatroyeniya# Abe. lIG360
REP SOURGEt Tr. Mezhotrael. n.-i. proyektno-tekhnol. in-ta. po a:wtomatiz. i mekhaniz.
mashinostr. VYP. 1, 1963P 154-159
TOPIC TAGS: metal caotingg machine industry
ABSTRACT: A casting department,'designed by the MlIMMASh inst.itute. for producing
1000 tons/Year, in described. The project includes three independent sections: a
section for producing low temperature melting patterns, application of heat resistant
layers, drying of the molds and burning out the patterns; a section for drying,
formingt firingy pouringg and remov~vl of the caotinga; a section for trimming, clean-
ing$ and 'Leaching of the cactingsoft) early output per worker will be 1-5 times higher
than at the cacting dopa_rTm_e_n__~_of1ho Podollsk mechanical factox7 and 2-5 times
higher than at the oxiating casting department of the Kuznetsk factory. 4 illuatra-
tiona. Bibliography of 4 titles. L. Yanovokaya Oranslation of abutraeg
SUB CODE: 13 11
ca UDCs 621.74.045

LYKHACHEVo M. F.~ LIUBINOV9 A. L.j,.STAVVISKIY; V. S.,
"Gas Cerenkov Counters of the K -Meson Channel of the Syvehronophasotron"
paper presented at the Intl Conference on High Energy Physices Rochester, N. y.
and/or Betkly California,, 25 Aug - 16 Sep 1960.

L 9MRAfifi_ DUN- ALEWP(t) TJP(c)
ACC NRt AP6005560 k SbURCS CODE: Ult/0148/65/000/010/0101/0105
AUTHOR: Grdina, Yu. V.; Lykhlnv--I. D.
3,5
ORG: Siberian Metallurgical Institute (Sibirakiy metallurgLebeakiy institut)
TITLS;~ Structur* of vanadium-carbon alloys
SOURCE: IVUZ. Chernaya metallurgiyaj,no. 10, 1965, 101-105
TOPIC TAGS: vanadium containing alloy, carbide, ternary alloy, phase composition,
chemical composition
ABSTRACT: To fill.the gap in the existing knowledge of the phase com sitio Of
Fe-V-C ternary alloys, it is primarily necessary to investigate the composition and
structure of the carbide phase of the V-C syrtem. So far there has not been much
agreement on the chemical composition of the carbides in the V-C system but at any
rate it is now generally admitted that two types of carbides form in this system:
with hexagonal (V2C) and cubic face-centered lattice (VC). But the boundaries of
homogeneity of thi-carbide phases have not previously been conclusively determined.
In this counectiong the-authors investigated alloys made of pure V (99.825%) and
spectrally pure graphite. One part of the alloy was investigated in "natural" state
while the other was vacuum-annealed (10-3 mm Hg) in quartz tubes at 1000, 750 and
5500C for 100 hr, with subsequent metallographic and radiographic examination of the
Card 1/2 UDC: 669.292:669*784:620,183

24
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specimens and electrolytic precipitation of the carbide residue. It was thus evi-ab-
lished,that the homogeneous region for the carbide V2C with hexagonal lattice extends
from 9.6 to 10,45% C (wt.), while for the carbide VC with cubic lattice it extends
from 12.5 to 17.8% C (wt.). A comparison of the findings with the conflicting data
available In the published litevature shows that the lower boundary of stability of
the vanadim carbide VC with cubic lattice cannot as yet be conclusively established
owing to the diversity of investigating techniques employed by various researchers.
r
On the otbAr havd9 the findings on the upper level of concentration of C in the ca
bides VC, spoic'Ifying it at from 16.6 to 17.8%, are generally in close agreemente
OrIgo art. has: 2 figures. 2 tables.
Yi
V
C=t -110 13j 20/ SM D&TS: 02Apr65/ MIG RM 004/ M IV: 006

P.A.. kWidat takhnichookikh nauk.
-
'Choice of borehole diameter in underground mining.* T.K. Mostkov.
Reviewed by P.A. Iqlffiln. Ugoll 31 no.6:48 Ja 156. (MA 9:8)
1. Dallnevostoohnyy politakhnichaskiy Institut iseni Ituybyshava.
'(Boring) (Moatkov, V.M.)

Ipandrovich; UTKIN. L.A., red.; TSYMBALIST. N.H., red.
izd-va; red.
[Using drilling and blahting techniques in intensifying horizontal
mining] Intensifikstsiia provedeniia gorizontallnykh gornykh vyrabo-
tok buro-vzryvnym sposobom. Sverdlovsk. Gos. aauchao-tekha.izd-vo
lit-r7 po chernoi i tovetaoi zetallurgii, Sverdlovskoe otd-nie,
1957. 137 P. (MIRA 11:3)
(Mining engineering)

KH / NJ
3-58-3-22/32
AUTHOR: Lykhin, P.A.p Candidate of Technical Sciences
TITLE: On the Experience of Establishing a Semi-Industrial Mining
Laboratory (Iz opyta sozdaniya poluproizvodstvennoy gornoy
laboratorii)
PERIODICAL: Vestnik Vysshey Shkoly, 1958, Nr 3, pp 76 - 76 (USSR)
ABSTRACTs Laboratory exercises of mining students frequently are riot
adequate. The students have access only to models cr i-.quip-
ment which enable them to study the construction and material
of the machines, but are given no opportunity to work on them.
The student, therefore, cannot gain sufficient knowledge of
a machine. Also, during practical training he is usually not
permitted to operate a machine. Thus, a mining student of the
3rd or 4th course is often unable to properly carry out a
number of taaks, including blasting operations. To improve
the training of mining engineers, thp Chair of Mining of Mine-
ral Resource Deposits of the Far-Rast Polytechnical Institute
imeni V.V. Kuybyshev decided to organize an underground labo-
ratory for boring and blasting operations and drifting. The
Card 1/2 laboratory will consist of a net of drifts of 150 m An length,

3-58-3-22/32
On the Experience of Establishing a Sf~_- i -Indd u3 trial Mining laboratory
including the adit, an ole~;trical sub-station, compressor
chamber, locomotive depot, the end of the mine's blind shaft
with the chamber of a hoisting machine and several operating
stopes of horizontal and upward workings, connected with the
surface. The students viorz;,ed Puccessfully in this mining
Laboratory during 1956/57., The construction of the under-
ground laboratory is not as yet completed. There is 1 photo.
ASSOCIATION-t Dallnevostochnyy politeklinicheskiy institut imeni V.V.
Kuybysheva (Far-East Polytechnical Institute imeni V.V,
Kuybyshev)
AVAILABLE: Library of Congress
Card 2/2

SOV/118-58-11-6/19
AUTHORS: LykkLaA.P.A.9 Candidate of Technical Sciences, and
Nevench--e--nTo', I.I., Engineer
TITLE, The Execution of Mine Working Using the PK-3 in the Far East
Coastal Region (Provedeniye gornykh vyrabotok kombnynom
PK-3 v Primorlye)
PERIODICAL: Mekhanizatsiya trudoy8mkikh i tyazhdlykh rabot, 1958, Nr 11,
pp 21-23 (USSR)
ABSTRACT: This is an article referring to the use of the coal combine,
type PK-3, at the Artemovskoye burougollnoye mestorozhdeniye
(Ar1temovskoye caE!Ldeposit ) in the Primorlye territory. In
1957, a total of ),282 linear meters of excavation were
driven by the PK-3 combine. The avernge speed was 273 meters
per month (for technical details see Table 1). On the whole,
the operation of the PK-3 horizontal driving combine is said
to be satisfactory, though 17 % of the working time must be
wasted for removing a 40 cm thick layer of coal or rock
Card 1/2 rhanually. Other deficiencies noted: the face flushing

SOV/118-58-11-6/19
The Execution of Mine Working Using the PK-3 in the Par East Coastal Region
system does not work satisfactorily, the PT-3 combine has
no appliances for mechanical roof supporting at the stope.
There are 6 tables.
1. Mining engineering--USSR 2. Industrial equipment--Perforjrance
Card 212

SOV/11 8-59-3-10/U
28(l)
AUTHOR: Lykhin, P.A.) Candidate of Technical Sciences
TITLE: Use of Diesel Motors in Underground Conditions
(Primeneniye dizelfnykh dvigateley v podzemnykh uslov-
iyakh)
PERIODICAL: Mekhanizatsiya i avtomatizatsiya. proizvodstva, 1J'5J,
Nr 3, p 30 (USSR)
ABSTRACT: The application of diesel motors in underground condi-
tions entails great difficulties, especialiy in connec-
tion with the clearing away of gas. Nevertheless, such
means of transportation have been employed in the pits
of British Columbia since 1950. Much attention has to
be paid to fire security during the use of equipment.
It is recommended to use diesel fuel with a burning point
of not lower than 660C. The machines should be charged
in specially equipped rooms. Experience in the use of
diesel motors in underground conditions shows that the
established security regulations do safeguard normal
Card 1/2 working conditions. Industry produces various kinds of

SOV/.'.18-5j-3-l0/f-:2
Use of Diesel Motors in Underground Conditions
equipment using diesel motors, with an output of 40-1,20
HP. Enterprises possess explosion-safe equipment with
diesel motors, successfully employed in the pits, endan-
gered by explosions of gas and dust. The gas purifier
is in the form of a metallic tub filled with water.
Explosive gases passing though it lose their p04 sonous
components. Experience shows, that the best diesel fuel
for underground work has its burning point near 580C.
Card 2/2

LYKHIN,--,P,A.~ kand. tel-din. nauk; PETROV, S.A., kand. tekhn. nauk;
ZILIBERSHMIDT, V.G., inzh.
Using detonite in the making of lateial drifts in coal mines.
Vzry-v. delo no.55/12:115-120 164. (MIRA 17:10)

7AAKHAROVO IU.A.; BOLDIREVp V.V.; LYKHINj V.M.; VOTINOVAp L.A.;
SAVELIM, G.G.; BREGER, A.Kh.
Study of the effect of preliminary irradiation on the thermal
degradation of silver oxalate containing cadmium admixture.
Dokl.AN SSSR 145 no.1:122-3-24 Jl 162. (MMA 15:7)
1. Nauchno-isoledavateliskiy institut yadernoy fiziki, elektroniki
i avtomatiki pri Tomakom politekhnicheskom institute imeni S.M.Kirova
i Fiziko-khimicheskiy institut imeni L.Ta.Kaprova. Predstavleno
akademikom M.M.Dubiniwjm.
(Silver oxalate) (Cadmium) (Radiation)

BOLDYREV, V.V.; ZAKHARCYV, Yu.A.;.L)~~HIN, V.M VOTINOVA, L.A.
Effect of the addition of cadmium ions on the thermal stability of
silver oxalate. Kin.i kat. 4 no.5;672-682 S-0 163. (KIRA 16:12)
1. Nauchno-issledovatellskiy institut yadernoy fiziki, elektroniki
i avtcmatiki pri Tomakom politekhinicheskon institute imeni Kirova.

7: ---- ---1
25i4i,,'6
L
ION,-NR-
:--AC.CE AP5001518
ion a .e an
not coine de,~ dtxe~ app-arently
bf in
did
me
to
atip'n 6 th
rlitritd on,
on
the I following ionfiati of the air or increase of the oxt
undet. irt
aU00. Linear depeedence of the initial radia-
-ift lite ssoclat n ou -free voI m
0
pu the
cell Points e -of 4 the. c, emejitAl c~eystal
*6 h Y. Of the Cr yst
W. ffeCt Qf't i_- packing densit als an azide radi
ysis- ~v _Odg, d
Iffu di6h:of the-
e rad ~tjotj vroduct,--- CrYstal density
med th~ '0
-important -determinan 'of r'ad'iation- induced yield, in contrast to'-'
see
at t
that for tliermi-alAis'-
on theses salt,' I, this s"arts from actitre locltioris at
exterior arid: interlor.,defectS of- the crystal surface and is basically determined by
M,
th rel
e an electron fro; the azide ion. Radiation and thermal dissociation
:coir ida*lthough their endproducts are the g~lmc. "Trradlition was
thus donot ic
conducted h -instrument o ar
on. t e gamma f the Institute of Nucle Physics of the
vilsh Ita-exprew" their
Orig~: art.:jfta6-,,I_tabIe and 2figurea
AS~OCJATION! ~Aftatitu( khir~iehedkoy ~kl, _P~Hki, f gareniya. Sibirskop ol dclen~ya
Akadeiai of Che"mbqaI Kinetieg and:Combu.5-tion, Siberlan
Division .6-caderny of Sc-ience5 SISSR); yad~'Ri_-_
oy, fiziki pri Tomokom. poll' inatittit im. S, M, Kirova (Sc-tentific
"77'

ACCESSION:NRIAP606

::
Res- at ~611
uisfflvjt e,6r. g~01ediviiYaj O.'s, Tojiisk,' Pol~tecftnlcaj Institue)

ENCU 00 13 oor.: I C

tlqR 148P SOV'
OTI
.

Cara 3 1~3

OBLIVANTSEV, A.N.j LYKHIN V.M.; 13OLDYREV, V.V.
X-:-=-
Pz-dio2yeiB of alkali metal perchloratoo under the &-.tic;n of
gama irradiationo Zhur.VKHO 10 no.53598-599 165.
(MIRA 18ill)
1. Tomskiy politekhnicheskiy institut ixwni Kirova.

ACC NR, AP6029225 SOURCE CODE: UR/0195/66/007/003/0432/0430---I
AUTHOR: Boldyrev, V. V.; Lykhin, V. M.; Oblivantsev, A. N.; Salikhov, K. H.
iORG - Institute of Chemical Kinetics and Combustion, SO AN SSSR (Institut khimicheskoy
kineti~i-i goreniya SO AN SSSR); - S'c"i'entikic 'R~s`earch Institute of Nuclear Physics,
Tomsk Politechnic Institute (Hauchno-issledovatellskiy institut yadernoy fiziki pri
Tomskom poU_ta_Knrcfi_es)C6m_institut) I/
TITIX: Effect of additives on the radiolysialof potassium nitratell
SOURCE: Kinetika I kataliz, v. 7. no. 3, 1966, 432-438
TdPIC TAGS: radiation chemistry, radiation effect, potassium compound, gamma irradia-
tion
MiTRACT: The effect of Tl~, Sr+, Pbz+, and S04- on the radiolysis of KHO3 was studi-
ed using a CobU y-source. The samples were prepared by fusing YJTO3 with 0.1-5 mol
of TlNOS, Sr(NOj)Z, and KZS04 at 3400C. The 0.02-0.07 mm fused nitrate grains were
.T.Poules, sealed, and irradiated at 350-400C at 400 rad/sec. It was
placed in glass a
found that the Tl additive results in increased radiative yield of potassium nitride,
the final product of the+potassium nitrate radiolysis. It was also found that up to
1019 ev/g doses, the Srz and Pbi+ additives result in increased potassium nitride
yield; doses of greater intensity produced lower potassium nitride yields than those
Card 1/2 UDC: .541.15117