SCIENTIFIC ABSTRACT FR:MALENOV, R.K. TO:MALENEV, V.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001031700006-6
• Release Decision: RIP
• Original Classification: U
• Document Page Count: 2
• Document Creation Date: November 2, 2016
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTR

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Z'he Oxidation of Yin;ylacetyler~e Iiydroca.rbons 'i+itrz Ur~ar.ic 7)-2-3,;~6~;
Hydroperoxides. VI. The Uxiaati~~n of 1-I~he~rily-3-il:eth,~Iocter:e-3-ins-1 '~rith
9,cetylhy drop eroxi de .
to the acetylene binding. d r,eto~lycol was isolated y~hich then
foams 'the two last mentioned compour..czs by dehydration is formed
transitorily. `1'he aiu~ultaneau;~ h;;dxation ~::nd dehydration accor-
ding to tPiu re~xct;ion of P~t.G. Kuct~~,rcjv was ob~~~arve:cl k>,, tl~u au-
thors for the First t:irl~; at thy: 1��phr:;lyl.ethynylry~,loc~i~.xerle:-1,
Experimental and specific d~;ta. of tha s.bove :~entiorr:d coinpouiids
are given. There are 2 S1avi.c references.
ASSOCIATION: ~iinak :f:Iedical Institute (~~linskiy Iaea:itUiai:~kiy in..,titut~
SUB~TTTHDr r'ebruary 149 157
AVAILAHL~: Library of Con~resa
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AUTHORS; Iaialenol., IJ. i.:., n~il'~:ina, ~. I%., 79-2->~,~~c
TITLE: The Oxidation of Vinylmcetylene H~droc,~rbons ~it~i Orr;:nic
HydropE;roxides (Ul�;isleniye vinilatsctilenovykh uUlevoaoroGov
organicheskimi gidropere':tisy:.~mi) V1. T}ie Oxidation of 1-1'iic:ci,/1-
-3--I~,ethyloctene-3-ins ��1 ;ith tlcetyl}~,~crapcroxi~?e (VI. G;::io1o-
riiye 1-fenil-j-rietilokten -3-iria-1 ~;icirop~:re}cis'yu atsetila)
PERIO~ZCAL: ~hurns:L Ubshchey F;himii, 1 gSS, Vol . ~'S, dr ~, pp. ri34-~~3U (USSR)

ABSTRACT: 1-phenyl-3-irlethyloctine-1-o1-3 , as obt:lined according to ;~h.I.
Totsicla and. by dei7ydration trar.3:for~;;~:d into 1�-~Ihenyl-3-~~ctl~iyl-
octene-3-in-1 v+hich yields 1-~}henyl-~-I~~ethyl-3-oxydooctinc~-i
(I) and 1-phenyl-3-Alethyl-j-a.cetoryoctine-l-o'i-4 b;~ the oxid;~-
tion with acetylh,ydroperoxid,e. 1-pilc:n,;1-3-;:~ethyloctin~-1-clxol-
-3,~ i;s formed in th�~ hydrol.y:3i3 of (I) y~,itii }l~`'U~f of.' 1;,,, 5e-
condar;y reactions occur eas~i.ly if the ox:icic; rang in the t~cety-
lene hydrocarbon is bound tc~ second ry and tertiary, or tertiary
carbon atoms . In tho hydratz.an of t}i~ oyidc (:I) according to
Ii~S.G. Iiucherov tyro ;;ubstanceW~ vrEre al~taircc~: 1-i,iieriyl-3-:~~.t}lyl-
oct ene-2-o1-.}-on-1 and 1-pher~;;1-3-..l~:th;~loctadiene-2, - or:-i
the formation of ~rhich is e~~plained b,,~ the faci t`iat taro grater
:aoleculea are producr;d by trio influence aC the ;ac-rc:zru c~ilori~,e.
Card 1~2 One is added to the fission place of t.e oxice: rim;, the other
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The Oxidation of V.:'tr,~y~.acety~.er.Q-.{;ydracar?~on;s ~tiith G'r fan is Hydro=- i %~.2.~~e~.~97~ina..5 i 3,b~d.ietiloktad,~~.2,~~.-~.na.-~ gidro~
perekis1yu atsetila).
PERIODICAL: Zhurnal Qbshchey Khimii, 1.958, Vol. 28, rlr 2, ppa ~.29~;.,~1; (USSR).
.~
ABSTRACT: In a previous paper it was f'o~:~~1d that in the cxi.dati ~~n c~.~ c.{id.es are
produced by the hydroperox~.des of acetyl, from divirrylar:ety~lene hydros
carbons with ethylene bindings yn ~, ~ position to t~?e ac;E~ty 7.ene bins
ding (..CwC..C C.-C~.�) A whereas the ace�tytiene bi.ndin~ ~ ern2.i.r~:~ ur~chan=
ged. This was corf.~r.�r~:=c; by r.~rom:i?ata,o*?. The tt�:xee c~~~~~c~t~.,ds mentioned
in the tit~,e (I, YI, IIT) ct~tainc-;d k:~yr tt~e dehydratl~:~n ~~i' t,,E~ cr~rz~es-
ponriing; ~('..,acetyleneg'!yeo? wrr~A^~: ax~.d~.r~Frr in orc.ler to c~_}ni'.'u~m t;h.~s. ~'he
oxidation proces:7 was oi~ser-gyred vc~.lzmetrical~.y w.;.t}'i a~~ c~. 1 n f-~ypo5t~l=
f.i-te sc~1.~.ttivTx, whereas f;irEa t~r~+mi.:,~~~tic~~~ ~~.nd ~aynt}~uF~~:s ~r,~s~�;: :~~~~~;. .~:ca out
Card L./2 accord.ng to usTaal rrr.~l;t;oc,;,. ~~'hG~ d~.ox~:i.ii~,~;~ off' the fad. ~..~~'~~, I.r~; c~.tr~i~e~ur,cl.c:
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N K b 1 M R R ti K n It It A I ,~ AA 4 t tl W p N 1! l rf t1 b A 0]� tI~1AN, V,S.; VCRO~~YEV,, .~~,F.; GURVICH, L,V. ~
}3ER(~'fAi~ ~ G�1l, ~tEZP~ T~SKI~' y L.A. ; KGuE~V, V.P, ~
GAL ~ CHE`ri1K0, G.L. ; KiiGI~EV, Yt?: ~ S, ti K~iAGrEKU~Zll~V~ ~. A, ;
S0~(OLOq, Vu~3,p GGRl1KHOV, b~IV�; MONAYEIJKC~VA, A.S.~
KOMARdVA , A., ~', ; VEYTS ~ 7 . V, ; YUktKOV , G. ~ . ; ~~~,~tQv ~. G. G ~.!
S~,I~OVAS N.,L.: GLUSHKO.i V.P,~ akadem't.kp o�tv. red,;
MIKHA~'LOV; V.V. r red, s KARAPE~` ~XANTS, M.Kho r redo
[Thermal. cozistanta of substan~;es; reference book in ten
numbers] Te~~m~.c~hesicl.e konst:snty ve~heheatva; spravochnik
v deeiati vypuskakh, Moskva Na.l., 1965. l.t,~. p.
(MIRA 18:7)
1o Moscocr. ~i!seac~yu~nyy in: titut nauchnoy i tekhr=.~heakoy
informats~.i.-
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Structure of liquid waiter
2352
s,io2o/~, /, 3 x/006/0, , /020
R1' 04/201
1G8o, and i~ thus only slightly smal3.er than tZlrzt; of a r~etraYiedron~ F'luctua-
+ions of the a~.gle in t;he range of 107.-,112`' ;ire necessary here, because, as
is well known, the representation of epare with s. perfect;: dodecahedron witt:~-
nut interspaces is imporasiblee The stru~~tur.+a gc obtained exhibits a tnxea._
dimensional. pe.riodici.ty, and therefore cann,~~r be r�ea?zed in any cryats,l�
The bond length H2p ,t� 1'(20 is indica+ed by an avar~age ~of 2~8 A~, This struc-
+ure of 1~-quid water would give a density of 0,~ g~rm"'� To attain the
density of 1 g~cm , about 4~5 mol.eculPs mu,t, be contained inside the
do~iecahedror~., Basing on the assumption of a cis,~bonain.g between. the water
molecules, the authox has thus been ab1.a t;o i'Yn.d a structure of liquid waters
that is ir, good agreement with experirn~Wnta.l ~~~~su~ts, and which corresponds
to Paulingos results, There are 2 fi~,~arQS s,r,~d 10 non. ~Soviet~bx.oc referencesa
AS;;OCSATSON: Vsosoyuzn:nyy nauchno-issl~;dovatel~pkiy inst;itut transpo.rtnogo
stroitel stva (A11~-Union Scion*,.ific Research Institute of
Transport;~tion Construction)
PRESENTED: December 1~ , 19E0, by N ~ V ~ Be1 av , A+~ade,ni clan
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0 0 ~i~ 3 `, /~'~~ ~~ s'o ~
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AtfTHOR : IVTaI enkov , G o G o
T7:TLE: Structure of liquid water
2852
~/o~oj/~1 /137/oa6/o11 /020
TN {~ n
,~ .041 2,~1
PERSODICAL: Doklady Al~ademii naulc SSSR, v~ 137 r nog 6, 1961 r 13541355
TI~XT : J a Bernal (Natu:re , ~, 141 ( ~ 959) ; F'roc ,; Roy Inst fl Gr., Bri t o, ,~,
na~ 4~ 355 (1959); Scio Am., ~, nog 2, 1964) has found that, from the
geometrical. viewpoint, the structure of ]iquid w;~,ter differs considerably
from that of iced Crystalline prototypes of li.q�aid water are, according to
L~ Pauling (The Hydrogen Bonding, London, 19'5,9, p~ 3} hydrates of some gases
and liquidso This scheme by Paul.ing has bpQn confirmed by experiments of
other aufihorsa Basing on the followa.n~; prem_isesy the author has constructed
a structure of water: 1) Hydrogen bondings a.re straightlined and their
].~er.gths vary only within narrow limita~ 2) Each water molecule forms four
bona, and the angles between them differ on.l.y little from tetrahedron angles
3) The number of t~i.aWbonds has to be a maxirnucn~ Ry cis bonds the author
understands the mirror-symmetric bonds as a~;cur in icQ (Fig 1)~ A model
of this structure is presented in F:ig~ 2v 7'he angle between the bonds ig
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