SCIENTIFIC ABSTRACT FR:MALYUKOV, B.A. TO:MALYUGINA, L.L.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001032000035-6
Release Decision:
RIF
Original Classification:
U
Document Page Count:
Document Creation Date:
November 2, 2016
Sequence Number:
35
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTR
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Body:
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,ACChS~3I0N 1~i11~s AP4038T63
Kranig tine structure. Orig.art.has; 8 ;formulas and 8 ;figures.
ASSOCIIUTIOZt; xnstitut mineralogii, geokhimll i kristall~ochimii redkikh elementov
(]astii;ute Ott Idinerology~ Geochemistry and Cxystalloche,a~ietry at Rare l~lemente)
' 8UBb1]T7BDs X10 DATE ACQs 12Jun84 RNC~L: 00
SUB COL!>;: Olt NR RTF SOV: 009 OTHER:015
i '
'- .
r
f
Card 3/3
..... ..~,r._.....~....._..~....._ , . ~-_ ~ V.. .. .. ~ ~ ...
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ACCKSS ~tON Nit: AP4038753
data ol~tain~:d from the Sc III optical spectrum. The K'~ spectrum wA,s obtained with
an und;Lsclo~3ed solution. The shape agreed with that obtained by S.ti;iyono (Sci.Rep~s.
Tohoku Univ. ,Ser.1,37,No.3,1953) and was adequately reproduced by c;alculatilans em-
ployin~; the method o! Nadzhakov and Harinskiy with an effective ct-a~rge o! 2 and an
effective quantum number of 2.5. These values agree with data obtained lrom the Ca ~f ~
II opt:tcal spectrum. The field o! the water molecules surrounding tho daub;ly charg-
ed K-i~onize~i K+ ion was approximated by that of two charged spher~.s~ , and the Schroe-
dinger equation !or the motion of an electron in this Field was sulived. Three bour-d
statag were found, and the shape o! the ICS' K absorption spectrum wt~s adequatoly e~c- ,
plaine~d in terms o! their influence. Thus the spectrum can be explF~ined both with
and without taking account of the water; it is concludEld that experiments with they .
spectra o! ions in solution are insufficiently sensitive to distinl~uish bet~waen the,
two interpretations discussed. The C1" speotra were obtained usini~ 0.25 N, 4.5 N
and 2 N NC1 solutions and a 0.5 N KC1 solution. Tho HC)l spectra a~~~reed within the
experimental error, and they were accordingly averaged.. The long ~arsa;velengtn edge o!
the absorption bead was well represented by an inverse tangent wi~ti~ width equal to
;that a~! the lirst chlorine line in gasps. The absaorpti~m band shawiad two maxima and
~a minimum. Thin atruotura could noti bo explasnad >~y bcnutd statoN tl~ the tioid at
the K-~ioniz~ed CZ' iaat and the surXoundiag water mol�au;tea ~ and it :ta aaaribed to
Card a13 ~' _
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~ti
ACCESS ION NR: AP40387~i3 S/0048/64/OitB~/005/0?91/0796
AtTI'HOR: Barinskiy ~ R. L. ; I~alyukov ~ B. A.
I.E K Absorption spectra of -calcium 'potassium and chlorins i~~Yw in wat~aig~Rea
SIT = held in Yerevan 23 ~iep 1 Oct
port, Severnth Conference on X-Ray Spectroscopy
SpDgCg;; AN SSSR. Izve$tiya. Seriya fizicheakaya, v�28r no.5, 1964, 790-796
TOPIC TAGS; x-ray absorptions x-gray apectrum~ ionization phenomena solutions cal-
cium~ potaalaium, chlorines excitou theory
ABSTIU4CT; In continuation of a program of testing the applicability of the exciton
theory i~n i;he form given by Ye.G.Nadxhakov and R.L.Barinskiy (Dok1.AN SSSR 129~1279~.
1959; Izv.AN SSSR ~Ser. f iz.24 X407,1960) the K absorption spectra of Ca2+ ~ K'~' and C1'
in aqueous aolu~tion wbra obtained and are discussed. Th� exporime~ntal tochr-ique is
described ~3laewhero (R.L.Barinakiy, B.A.Mulyulcov,Izv.AN SSSR~Ser.t'iz.28~80:--1964)
Lsee Abatr,act AP4038'7867. The Ca spectrum was obtained with a Q-.7 N CaC)l2 solu-
tion .and a;n absorption path of 20 microns. The shape w-as adequatE~l.y reprad~~ced by
calculatio,nP employing the method of Nadxhakov any Bao~ 12 6 YThes ''valueaWagreenwith
fective charge of 3 and as effective quantum numb
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Interpretation of ~th~: K a~~sor"j,ti~.on... b102~~~~~i
should be split. This line can thus be assumed as being compared of three
lines of equal intensity (1.0 ev broad), two non-split lines (U.Uj ev) and
a third line shifted to the shortwave aide by O.j ev. The spliti;in~; oz
the exciton p-levels in HAS is carried out with the well-kr,~own paining -
Van Vleck: method (cf. Cotton, ~allha~sth~'threefold degenera,teop-1ev~lst-
ical apps~oximat ion. It is shown tha
are split; into three sublevels due to the action of the elE:ctrostati.c
field of the H molecules:
ectt = -- 2e~gC~ -}- 0,17,
P~~~ -- --- 2e74Cn --- 0,(38,
e~~~ _ - 2eagGo - 0,085.
cf. Fib. 4. These results agree with the experimental onef3~, Due to its
Td s;/:nmetry, the Ca50~ molecule should display no splitting3 of its exaitan
p-~evels~. The first line of its K-spectrum is, however, ra'rhEx brand,
which could be attributed to a p-level splitting caused by more dis1~ant
lattice .atoms (the crystal is of CZv symmetry). The maximwn possib;te
Card 2/3
,'
I~ '
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P ~ i r. E+(1'I
;%M048/b2/o2E~/'QC~~/013/'015
.~~~ ,~~~~ t ~~ ~~~~~ l/,~ ~j ~j ~ ~r ~.5'~'~~ 2,102 B104
~.U'I'II0~5 : J3arinnkiy, fit. I~. , and ~+1~~'~A
TITLk~; :Interpretation of the: K absorptian spectra of sulfur i.n
molecules and crystala by the excitor Stark E,f'fcct
FEl~IOD~Cr~L: Akadeu~iya nauk ~:~aZ. lxvestiya. ~ieriya fizich+-;:~'~:aya,,
v. 2b, no. 3, 1yb2, 412 - 418
TLXT; In order to explain the nature of the Zeeman and Sta:^t; of 1'eci;s ob-
served a't the K absorption spectra, an experimental and then ~~etical :ln-
vesti~;ation of these spectra of S in the gaseous molecules of 50L, ~SOCI2,
S02C12 and H2S and in the CaSO4 crystal was carried out. S was chp:yen
because ~f its narrow Y.-band (0.35 ev). The spectra of tY'ie first three
gases are very similar; the first and most intensive line is narrow ~/
(1.0 ~ 0.05 ev), i.e~., the first excitor level of the K-spectrum of aulf'ur ~~
will not exceed 0.1 ev. This first line of the ;H2S spectrum is rnuc,a
broader and shouts a Structure on its shortwave side. According to calcula-
tions of the charge distribution in this molecule, the excitor p-levels
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,; I~ardness 8tt~dieshp~a~r. ie~eresults of mechanical
$A~,rimens welded ~ta~a ~~~ ~eate` and ~nicrosiki~uctural +and
ifiom~~.natioaa a~ith 3
;`,~uL ~ ~~:~~teek, indicate - ~A ..eel fn anneslec!
. ~' air; and ciz~uut~atin that; the.. ex~ex~nal. caolin state in a
~'t,he Wend $ water dare
.. g oft the weXdi~;ng
> - whikctr ree~l.~~ in a weld au ~ ~eld~ng c~u,~e~ -an.~txceaave .hard f.
~icroarac~Cs. ,~y ~oritx~eet~ inteirc~al c~Qliri~oh a n~ of
~P,ostheat~g. mf the tra~acryr~tall~ to structure
,,.. 6 f the rol~,s filth eircuxating water and
center lire of the weld results in a ~rou hl
-- ~~rdnese ~~,~~ is , ~, tl~e lower th
tn+a-reorrer 8 y uni ~,x~ de
they-weld meta�X. does ~ en in the case of ~exi:ern~l cool;[~~ $x'ee of
Ara or the~~~he~aal a~~eali t di~plaY ~nY dfatnct tz'~n~~rr ~, and thhen,
tit ~~ e>ztire weldee ystel~~ite sCr'ac
+~~ the. w~~rt song to the harwdnes,~ - bf tChe~ tb~e~ ~tsrnace ~ture,
e~:pedient ;ta ~~ seam: ~eldie ~ ,this redu+c+~etl,~ in the wel.d~
then ths~ ~e~-ice l~~e of~~,~he eooli
Qrt~ .art, has:: ~, f9~~ur~ t.l ,~-~ _ off' '~ ~~ Gix~r~~et~�g ~ratejr,
table ~ 'mss"~ al l~yj , i$ ~i1r~ ~orao~er,.
s ,~,
,. , ~ ~ ~ ~
.: _
�, $ .s ~.. ~ ~ _ ~ ~ dime 1GQ;~~~a ~.
'fir Gtl' Ccj 'c ' .- ,~~ ~~~~ ~ ~ t
~~ '~
' ~.'~:..~?.-~ _ ass ''".w ~ + _ - ~ 4 ~.~.,~ } t.
i ~~ ~~ ~.z y ~ r
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UR/~I9~/I~~~'~~~rC~~~~~~20~t3U~~
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QR~:s . done ,~ _ tear "- _ -
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- ~ nt-~~chse~o~r infotef# .
"~t1P~C. TAGS: .: ., ,~ no, 8, ~9~6!S,
~' ; ~ ~~ . _. ~ enn~~e~in
20.22
h~,~~ ~reata~er~t, 7~W ~~1ay~ steel m
~~~~ ~'lae~ics~,t~r~ ~~~~ r~~ ~ j nrtax~s3tics
nn~m ~~dl~tn ~~~ s~~1/`
.oanader,~b~~ ,`~~chn~ca~,, di fGUl tie . .
l~z'ap~r ,~ai;iaing ~~ ~~-e~,lld
~~s~t~`c etx~aa~~ce ~ti;` . Y machine atsele in~ra
'�+~o~tt - hi`~ ~ ~ owing t4 the. pcs~iDl~~ ~p-$tt~n ~~~ ,~ 2ve~~
~ ~~~~.!~ ~ ~ardnees ~~~ brttlenas~ ~
- ~ ~ ^~~~~ o~ the ~
''~ ' h~~t~~ b
~~ ~ ~ ~.dno~;:; ~~ ~s~.~~~:
k ~~ the . r~~',
,, ~ ~~d~i
~~~
~ - +~~feor o,~ n theM ~~~,~~~,~ ~>f~ ,~ ten.
~ioe , a;~ tip the h~x~enn high
~ .,~a~n,~ can iii g. o;~ ~eidle an tie
~~~xe ~~l~a~ et~,m~~et~~ ~ +~i~`~ng~~, snKt
~~ o~th~; z' Y hert~;ytt'seting tha
Thy he~~ tx~e~tacet~t n~~~h~�~~~s~ a
~~. previo>~sly used for o asi~t,~ n
with .ic~terria~ c4va '~-eldiug; the '~ ~+ost;-
;g eot~g~ets iii hsat~ $ ~~ circu~a~n ~~t a~feat is pro-
n8 them ~a 6TQ� $ ~nt,~x~ Beet treatment
C in- a ftct~t~cn ~~. ;l hr wl t
h
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.~~u. 'a~nere ~.re ~ ~i~;ures. ,
Figu~~e 1. Schema(;ic diagram cif' ,:~;~r_+~,..
wslding a tight circumferentia.:l ,jo:E.r~fi
on a conventional machine wltlz m~.nu ~i
displacement of the ,part (a), aixl on ~k
machine equipped with ,gin electr~>c?c
head (b}
Tae~end: 1 -- ;head; 2 -part; ;j
welded ,point; 11 -upper electrode;
5 -Lower e~.ectrode; f7 - lowez~
electrode-at~taehment.
Card 2i~
- r-- ~-,, .� �. ,ref a d wll iYV YSaii iJu l~ 1 1 3
~~ ..
t..~_
? ~ ,5
3
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�c
AOG~i/A 10 ~
~~F3�~. tl~Ct~"1, A. t+`, ~ vi.l'il~tti+, E ti, ~ I.:a"i:i.il~'.'~';`3
At1TIlOi25: y _, _ ._.,.....~
Tl`t~.~F.~: l'i pcat ~~relca:i.it~, Ylt~ri+_J -(.'c~z� ~,ix ~+ �
P ; IOI)ZCAL: ;;vaz'r~chnaye pro:izvac'~a1;va, rl_~, ? , ~'~';, ;~'ir j~`~
The authore~ have clc~veJ.apecl ar't c;7.r:ctx�ade }teaci for ~~'+~TII (~rP~'n) ~YFe
T~iCT
machines, autorna~t~.n~Q~he welrl~.r,~, of herlal~~~om~c} ~call~f~lswitchedioff a~'ter$1;he de-
ars ~.engtYl up to 360 tt1r, in~~.c'r7zn.. i.,
5.j.rE~iayeC't3.Qt] has btyc~~n wcl.d~;.~d. 'i'Y~~e~ }LC:rtci i. ;; rnc,uJ~t~:d on t.l`ie rnaChirte a.nste~d of ~'rAe
u per ht~lcter. The ~l~rt to b}~ 4,l~'1.tt~d .i.^yI}~..tic;c:~fi4c~r3ot{~;~~].clesigzziofdi;heEpaz,ttic~~ryi.~;-
p
Yrhic;h reps�escrits ate ' at~.~.chir~crr t tlizt caz t c,.,}~4~la.z..}
ure 1). '.Che head i;~ flxcd oritc~ ~~ .~1Jc1Eyr~ '~~`+ sp_c.n`Je?,i;3.ealdspizkdl.ee xi~eby~pthc~
electrode holder which can be cli:yplaced ~ r ~,,'1 Y-t~~, a iven
lOQ mm. ,4 dick is fixed to the :7nindl~tasl~'~v`e~14 r~ a~j c;,n~;T'andar crw i~~ a ~;ivf~n
angle. The electrode perfarm.~ ~ st,cp~~..
radius. '~'nen ,Joints alt~ng a i~0'~ arc ai''e. ~d~li~~1~~Cl~~i~.elTherheac~~}ctar~iobeissvitchQ~:l
versed by a switch changing the direction o
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An Investigation of the Spot and Seam ~1 SOV/135-59-1-10,%1~
Steel elz~ing of ":~z703'` Cade
have a considerable effect on segrega7;ion
cesses, which are less r pro-
of reduced overheat of phenseamemetali~andcase
adjant zone, and in the case of inter~.e;ifiedfh.eae
eliminationo The basic condition for a satis_ t
factory welding of "EI703" steel is intensifie
heat elimination, which can be obtained b d
1) reduced welding rate� y
Pressure; 3) larger electrc~dehsgrfacelectro~ie
and an improved cooling system. The i:nformat~ion9
includes technological recommendations, TherE,
are 6 sets of raicrophotos and 5 tables.
Card 2/~~
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AUTHOF~: "~-~y~'-~~-.~~ Ln~a.neer aCJV/~.~>-~9-1--1t~/].~
TITLE: An Investigation of the Spot and See.rc~ ~'Jr;lciing of
tclchec}lnoy i
i
ye
"E1703" Grade Stee]. (Tssledovan
rolikovoy svarki stall EI703)
pERIOI)ICAZ: Svarochnoye proizvodstvo, 1959, Nr 1, pp 31-'35
(USSR)
ABSTRACT: The weldability of "EI703" grade steel was in-
the re-
vestigated, and information is given on
sults obtained by experiments and in practice
d
E~ a
in the seam and spot weldixig of this steel ~;ra
racteristic of "EI 7~J3" steel in
h
a
A peculiar c
eam and spot welding is ;.i;s sensit:i,~ity to the
s
thermal cycle acid pronenes~~ to segregation heter-
ogeneity in the cast joint zone. Aug a resu:l_t,
weld joints performed with the same parameters
on steel of different cast:ing� have differe:rit
C:C'o~truC'~u:t:'GS and. Inechan:~cal propert~.es� TY~~.s
Iri~
.
appears ps,r~ticuls.~~~.y in the ,~ICam weld~.ng proces:~ �
eriments that ricat condi~t:ions
ex
d b
Card 1~2 p
y
It was prove
and the metal crystallization rate iri the nucleus
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M~m;~z x~., a. ~.
Result of atudyi~ tha ~t~aiolagq of the la,taral tine auzalysor
in fish b;~ conditioned r-eflexee. Zhux.~e.n;erT.deiat.~i no.3:426-~
4z9 My-Je �55. {Mr,~a ~l:lo)
1� Se~fedrr~ fialolpgiS ,ahivotr~kh Moako4ei~o~;~o gaaudaral~vennogo
uni~eraiteta im. M.Y.T~monoaova.
(Y;[~BATION, ~lfel~ta~,
on fish, determ. of physiol. of lateral line analveor
with conditioned reflex)
(FT SH,
eff. of vib~catione on lateral li.na, determ� with
conditioned re~lea)
(R~B'LLK. C OI+tDY T:[ONED,
deterrn. of ~phyaiol. of lateral line in fish in
response t~ vibrations)
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RETS~I'TOR, Xa. (g.Moskva) ; SHAKIROV, 0. ; " NOdK, A. ; 6PRL'Rl4i~ANIKOV, i3. ~
ekonomist; K~ialT, 1~.; ~'ILIPPENRO, A.; l3tTYY~'Yt~(',,2a0Y, ~l. (Dages~tan-
skaya ~S55R} ; aflIGOIl' Yh'iT, A. ; DZHURINSKIfY, N. (g,g,Lf~hinev) ;
MALYt1KHA, L. (g.glin); POLISHCRCIR', I. (s,.Pe:woural�e~'rt,
`~v~KtTo"vs oy o 1. ); tIRIZ0~R7B, Yu. (4~~runze); CHI(-A~Y, A.
Letters to th� editors. Sots. trod 6 na. 1;136-141 Ja '61.
(M zRS 14 : ;~ )
1. Glavnyy inzh.shakhty 2do. 31 treats Kirovugol', g�$.araganda
(for Shakirov). 2. Nachal'nik planovogo otdela shak:hty No. 3l:
treats Kiravugol~ ~ g. Karaganda for Noak:). ~, alavnyy bukhge-lter
stroitel'nogo upravl~aniya "Tya~hmashstrov", g.Kramatorsk, StaA~
linskoy obl. (for Khan). 4. Narhal'nik atdala trud:a i
zarabotnoy platy vo11sl:ogo zavoda "Metallist" (for ~'ilippeako).
5� Naoh~~l'nik otd�la truda i xaraboCnoy platy laning;radskogo
zavoda "Kinap" (for l~ribor~yev). 6R p'avinskiy l~no7avod
KOpt~`omgkoy oblasti (for Ohigorev).
(Wage payment systems) (Industrial manadment)
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141ALX~JK1 '~tagil,~.~ ~.~efromovi.rh~ :lslttor; ,fIlAI3~ASpNI~O, I~1ika].~.y ~akcrol~v~.ch j
~Wnaucrmyr sotrn; Cb'UMAC~i~;l'1K0, Vasiliy Petrovich, usuchxyy sotr.;
DEt~iENDZ~iI, D.L, 9 red, ! GLt~SHI{O, GaI. [Hlushko, H.I. ], t~ekh~t;
red,
[Dneprodzerzt~.nsk; raf~~ronco and ~ui.dQbaok] Dniprod$erz;hins;
dovidnyk-~~utivnyk, Dni~rapetrovsk, Dnipropotrovsike k~ayzhkove
vyd-vo, 1~~fiQ n 1Fari 1'. ~~iSRA ~,~: ~.
lm Dreprodzsrzhisn~;iy ~,~orodslcoy komitet Kor~~.~unistich~sk~oy part3i.
Ukrainy (f'or i�~alyuk}, ~e Dnepropetrovskiy g~~sudarstvenn;py isto-
rjcheskiy muzey (for Kr~a.~.asmNiba9 Chumache;ako~,
(Dneprod zerzl~.nsk-~-Guidel~aoks )
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f'/ ~~ ~~'3 ~` j V 1
USSR ,/ }iuman; s~nc~ l~nimc~z P~Ia~~pl~o~.o~y, (~~tarrlk~J. f1n~1 ~tq,'ttio~.o~:s~-ow~-;~ �
Cardi.dvascul.ar System.
�,
Abs Jour R~af Zhiir ~ ~io1*, ~'So 2~.�, ~95~~ cjo S~7C93
Author ri~~7.yult V T
Inst L,~ov ~asu c~.entific Society of anatomists: Histola~is~ts
and Lmbryolo~i:~ts
Title ail the I orpholo~-~� of tl~e Intramur~^l. Vessels o.i' the Thor~~eie
Duct c~i t'.ie Doer'
Orin :Pub St n~~vchn, rGUot, L~vo~.~sk. oi~l.~ nauchn. o~vo any tomov,
~ istol. i enl'~r].ol,, x.958, vyp,l, 5"7-bn
~bstr~3ct : It was shal~rn on 5 do~�g, aftox a da.7.~utc supx~lv9.t.~1 infection
oj' the artcr'i~~l~. system, that a~,ho ~~.ood ves el s. of the
tYioracic duct (TD), ~.n tP~e for;: of .a doll?~1e~l~,~j~ore7cz rcjtwork,
are distril~ut~d mostly in its r~dvc.~nti~L-x7~ Tn s;maller numbers,
they plume into the external layers of nnascult~;r mucosa cif
TD, whero ~ t ~a.rd vessel layer is formed, The ;9,ntima h< Janina r~editaineko~ra inetf.tut~a,,
(xUPtTS BRYTEiD~fAxCStTS o ~?xSSDMI~fA7;'ED, in it~f ,- ~~ ch x~.d
saute, clip. picture ~ aut~~ome ~Rn~))
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USSR/I~~rr� I,ni~-:e1Q. Tho Scrinc
~`~- ~
Ab=ilrre, the ~n:l rroLap received 1-1.5-2 k:~~, end the.
fir: croup received 2-3-1i lc,~. The :a.lr~;c cent^incd 1.54 1'cr-~
ccnl; of lrctic rcid, 0.55 P~crcent of free r.cctic acid, +�nd
0.0~ rcrccnt of butyric rcid, According ~o ~'ac;clin~, the
ever^~�o doily ?~~oi~�ht r^in~ ^~�ount,ed tc 570-7~0-7(; Itg for
each group. The ~xpon'.ituro Per ecehk~- of ;~oi;;ht, i.nerti.-~c
c~'ountcd to 5�>-~�9-1'.5 fund unit, It i:- rccc:::,,nclcd th~t
silc~-c c^r;- bo foa in proPcrtianf of not ~~orc thrn ,35 pcr-
ccrt ai" thc~ nutritiL~n~1 vclue of divan r^tion~..
Card ; 1/Y
49
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The Pola:rographa,c ]3ehavior of zireo ~ 501 ~..f,.,~-..
nium :in Is ua ~7 ~ ,, ~2/q
q Dias 5cjuti%:a
conium complexes w9.th tl~e si;lpha,te ion, The f~,r~mat'
complexes of the zirconyl _, aon c~f
potassium oxaZata, ammonik~otihiacha~l~~~ic acit~.~' acetic acid,
man~~a� and ti,ietha:r~ylamine and tr. i] ox; ~ weredinvaut:ions of
With complex pa,r~t;aers tlia zircon -,,,~ sti~ated.
By c;"mplex��ion z Y- ton forra,s na z~aducti~on wave.
ircoll l~�c,om lei is bound sa ~hl~t the
lY'tj:e effe:~t upc,n thr-.yws,ve oi' 't}iE h, ' ~i~ta..
Th-~re ara 2 f'i~-r.~sv 4 tal~l.cs,, acid ~'drogen :icin :ts co,~ipensated.
axe Soviet. 7 refe.rence~3� 4 of wt-ich
AsS4GIAT~'AN. P7auchno~.ir
~sZedovutel. ~aki,r inst.itui
univexsitete im, .~~,
(Sci~sntific; x� Lobschcvskc~o
Rescsreh Zristitu,;: i'or
vere:Lty imeni Pd. I. Lobachovak~.,y~
9UBMTTTEp: d'an~u~~ry gyp, 13~~
C$rd 2/2
kh.imii Sri C~ar'kavskom
Chemistry ut Gor'lc.iy Uni-
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sov/7~~~...~22~~F
~ (~~ gar ehunov ; I . A. , ~r~aly~~?~n...~�rR.`....~`~....._.
AUTHORS
olaro raphic Behav~.or of l~irconium in Aq`~ooug Solution
TSTLE: The F g' ovedeniye +,sirkaniya v vadnykh
(I'olyarog~'aficheskoye p
rastvoxakh)
L: ZhL~rnal neorganic;heskoY khimii, 1~~9~ Vol ~., l:tr. 5,
pERIODICA
pP 1077-1080 (USSR)
dxoP alec~tz~od+a in
ABSTRACT: The behavior of zirconium on the mercury
' Lions of acids and simple 9a1ts in t~~a~x~G~ut~onf,irconium
s o.1u
cok~npieX formers was inveatige.te~l� As ~ni resent ary z~ii"conyl
nitrate (pH ^~ 2.5) in which zircan~.u~ndsipon the aancentration
ions was used. The dependence E1/~
SO and the chlorine ions was inv�stagated :-end, reaul�ta are
~ W:i.th an increase of i;he ~~ircclnyl-i.on
given in tables 1 and 20 atc;ntial off' the
conce~xation the marginal cu~~x~ant and the p
eE;miwave shift towards poait~-ve values. It i;s aaeui~edonh~ache
the zixconium st~.lts exercisUn~.v~li~hy~ncincre~~~3coi'l~the sul-
reduct�ion of the hydrogen i ~ atenta.al of the hydrogen semi-
plauxic acid concentration th,. p
' w,~ve shifts towards a negative value with formation of zir-
Card 1/2
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Rf:duction o~: Titroj,hL~.ols on ~~, :~i;lci~::rak, ..:~~rct:r;~ C~.w ,.;~e
:solutions frith pii f,ro.: ~ to 2,~ t}ie x;itroj;ircnol:~ ~.r~: ',:l~.i,l,, re-
t with t#tr tvntstt. r et( Nllet,.'ti;#; i-t ~ � 1,'.t,
a, (, ~1, (t i~', I .. �-U.,R:,?, '-Il,.rti ,.I-,II't, (t tti, U.itl
u i,# v. At cvtttst. c, r trnueitu ~adctrrudrut ut thr irngr,
IM�terre�tt IR hurl ^i:3~, wltrtr,tr tltr di(laattttt rnttrnt iurtr,trr.
with tier trtn#t 'Thai tltr tru,�tinn 1>riwty^u t.'n(~tlt,}�tttd
ltiltrl^'ti4, {tt tltr 1NrNrtlcl! nt Nlf rttta^sa ei# Ihr i,tllt�1, ,ts�IIt,111Y
rertt~i~iri at d f,v#ttrtkxl rd t'u t r to t'tt', i~ 1NMni' ~Htt Irv tiu,
NlrtttitY t,l thr #x,l;u~ratu with tlt.tl trletKiuwl In a w~ht, .rf
"Ctt4t in tt('I !rt tttr ~aoeure ni \IdtCtiti^ h t-trtltrr rvnt~
t~titt!ltttllt li (tRUYNt#'t~ 9y thr;tpitl~ulhtn nt ilkttvir#t' tttrntttl,e
I~trnn tint Iht+�,tt gtatrh t-# � ett(,ehtgt r, Ilu+ rc>1Kr9ttt,ttiont tru
to �^ 4. #.+' tiu^ evetnl+I+~tl fMs the cvnflt+tt C^ttll'NKI,
~ .uui a d�tiMa^n, cv~tt.rt h trt 7 k IU " ihuw t!a^ fart that ~,
^ttnl lug r1, atr itairfx^ntfrnl err trnyr., it (rrlitrrra th;tt thr^
ltrat e.( #ext:uNt+at ~d tlu^ evnntrMs fftNil i1Y HNIK to rl,wr ter
cstc,, :~, t'funr
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e
cd9
~alu~tr+tr~hi~ Iotrts~tl~stiaxt of compiox~: of comer trilh
~rrlAta+rE, 1, ~, Iikrshuuav and :~. I :~i~lvvgtn:s +;.t.tr,
F:niv., tlutki~, X~ar. Qbs~i~c~f AAim, t 1 ~C'+~~t';"L"'t>i�rS, +
1q, 4t-3-{~{1~5t-l.--Yvtarographic cttrt~rs arr ,;Jtmvn f+,r
C.u in itsl).(f[PI N nitrate noin. with O.t t 1 :\' k \tt, :sect coat K
~iyritttr~ frt~p Q.l.M(.65 to 'p.iJi? dt, ut '~ ~' ilir sr;s~ fom�d
mtt by H frottt cltx:trotys;inu and I A. Karshunnv,lh,Lrugl A-fn
j+ ~r�
!11 ~` IilirhrYkY,i Khinui (Journal of Analytical (;hemis� ~' ~�
i lry ), v. 'd, Nuv -per. 1947, p. 34t-344.
', ~ ~- a 1 U{�:~rribr4 myth{�1 drvelo~cgl for utxwr deh�rminu ''* ,~ ~
� p ~+, titut in nolutiuna tut+l to furfural formuldrh)~dr. r ~ �
�il a rcx,nw. Accuracy wn~ �,i.~r;Y,. Cunsidrru{de tirnc - ~�
_ KaviuK in ron~purlK~n with athrr methrds is
d rtainlyd, ~ �
~ e� �
.;
~J~' y�7 ~ '~��
j
~.~-� ~e
n~i to ~~
~~i ,~~~ _.. -
A ~ e. S L A tl[ii1.tUF4{CAL 611tR~1`Uq! {lAliIfICA1i~N r i~H~ ~~Ntnr ~�
i ! M s ~
~:t)Vd.i atr qbY +Id{ eltiitlaC _ ___..____,__. .____. ._~ _ ~f+l _
;tl sartl)a^ +, .i_ ..._.....t-_~....~.-. i __,. -). s.__~_,..~. ..-~---~I-~7x ~-'Y- a nd o M r i xr r~ ~ ~ ~ ~ t ~
� ~ U ~ Ir ~ 1s j t< n n n ~t a K tt tt tc ~ K tt it tt DI n ! : xr
���;~��;i�~�p: jiii~i�iiiii4jilt�~ ~�r/iii~oiNwii�~~�
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krdtartion of tnugsl~it iadldae at Iaer! Med of m~tc~+tt
i-n !hc drnppltt~ taercury ttttitodE. ti,. 1, !-1n1~ ~~,.~ 1f
K. yhcht�niksm~� .utd 1. A. ~sxr}-unov i;t`,ik tr< +�~:i1
(.'uiv.), J Ctn. Cbrm. (U.~�:i.K.} 10, Ir"">i~{ 8(lUltit!i,t
1tu~5ian) �li'ith the cottti'n. d E:f in ~>!n. rising trans ss k
tis `..q 1", thr half-nave ix-teati:tl r rat t'!t`� changs~4 from
p.fi1 tn -~is.li3iN~ r ; tax llq ` �, ~'ity k t tr~xn t1 tt;, l�+ t is
i', r ehiftx from --t1: Kt to --u d.+. hrrnn the �hy� < ul
the t[raigitt liur~ r v.t. lug nsnru., tltr ctM~r4lsflalilns au ut
the ttylli,lCXfS,tu ixnh c:.txA, lx 4. 'I',-kittg (..r the r
valves at thr eiutf;fe hydratrt! t'b" and fig" ir~n.r
-U,'t.~sl nod ~ !l.~it+Cs v., rrsis� sine fin~l~ fix tht~ iu~t.,bslis ~.
r~�IIYt llt tilt rUinp~cR tO~~ldev' t"tt" fl) t, ~tK ,~ I`f~il ~r�
Slai '�~''
A ! M ~ S R 14 ~1ARRUR6tCA1 RItE$AttdtE tll~SlNICAt14u y~~,...^,-^
� stsfora ws- a+� oec -~.,_....,..~. a4i~.i1tN~
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ld I~ 1.aboratct~~.i Fk~>~:erzmental9roy onkelc~~ii ~aav, _ :cac~ln~~
zhennyy delta+~e1' nauki pr;;f, N,Va Lazarev} 7nst,iL~a},a ~anknlo;;~.i
AMN S55R (dir, ~ daystvir.e1.1r,~-y c~hlen AMN SSSR P'"oi'~ ~":,~To
Serebrov). A.ctres avtoro,Ya I~en~n~rad, Fw]?_~, 2~ya Bere;zf:vr~~a
a~.~.eYa, d,3, Ins tif:utd or~rc;;lr;~Ii ~~d ~:,:~SFt.
. . ~ ~, ii ~ u if u I ~ ~ -f ft >~ M ~ k i~fi >r lM fv ff li ~! I+ I+'!; �
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