SCIENTIFIC ABSTRACT MANAKIN, G.A. - MANAKOV, P.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001032110011-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 13, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Acoustic Coagulatlon of Sul.'u-1- A,,L,J FoC, 4
7 1
301-1/1'.,
Vapors of sullfuric aci:11 we-e o,)Tained 'by -..I IX Ln fE a,@
vapor with 3ulfut,Lc arihy@-_IrL-Ile (obtalrie,,j `@v ox!-13-1--,@or-,
r 1, he .:7 1 e r
of SO., vilth air in the co,)tact, ovell
The ga- `,el@ Cenerator GS-1- 01 )---Ilie mo.!,-,
Hartmann (Gartman) whistle (constructed' In 0-!ess;D
Folytechnical lm3titute viLt.h pat,tl@-Iuatioti of N. A.
Ivatiov)--wa.,; i'o,,@ coa-,ulai.lot, i n t he
glass ',.i@bc (1-1 '-, min .U,-,rr., lenj@tii 50u mir.). So it;
PL'equen,,_-.y wa.; trica@3ure,,; w 11-th at, EC)-',' 0:@,r- , 1 loi-rapil an 1
ICh-() Crequetic, , The coagulate-I fof-@ ariallyza!
-y meter
by photonephe'Lometer (17@). To prevent vapor con,!ermi,,ition,
@hc face Frla3:,)er, of the L3.Dml)le tilbes ol" tlle nel)helor'ucter
-) lby ciccuLatLnL, ,v3tlcr Ct,or. the Ate-mo@;@at
were kent al, Yo P
The nephe 'Lorne te r- valueo were lll@@
,_Iata of' @-hcml-ul (or @i"SO"',). The ut:aiJ,3l::
oC acou.;IJ,: _,oarul.-,itLon ot' 11.)SO11 fla";
C@ivil II/P,)

Acoust ic Co,-Jtluli 10@, o" S--;! A 1-1 Po;-
SO
hu t'e .-L?.t2 OP 1. Irl q Lie r I e
towjr ie 1; w
ot) 11- IT!
a
!,6!1@21,10!1 ol, @,Oljr.t 1,culquolicil
3 - - (3 1 A: *,, _) q j7@
Li
,D!, le ol'. (A)
pho,lo!,ephe
Gene,.-ator r)o@vit!r ll,i vatt.,;)
(a) "; (b)
70
60
: nhowi vavlai.loit tt@ IeL,.-ee
w i a o 1 1 j, I j C),,q I, ,A

Acoustic Coa6ulation of -Qulfur, -@ Acld Fog
F Ig, Flnal concen,
t va'. Ion of H- SO, fov, as
u9ctlo': of' acolistic
Re a rl, in gs
o@' pho@cl. -L
-eohe omete@,
1.
sca-e (livislons),
P) a-@oustic
s P re -
,,uenc- (in Kcyc'es'
.4
6V
0
1,e
rmike i,hi,,, el'I'e-1 pvono,-w 11.
E-l'Cect. o" LnItLal :on(,entr@-A'lon oC Hl,-@SG;4 `op@ iipon
coagulation Is :ihown irj Fig. if (time OC S0,11),11rIF
C' ard 4.'( sec; t@as lfiovi 5.6 1/inin).

Rcaw8tlc Coagulation of Sulfuric Acid Fog 77494
Fig. 4. Degree of
coagulation of.H2so4
fog as function of
initial vapor concen-
tration (in g H 2so 4/M3
at STP). Frequency (In
Iccycles): (1) 14.6;
k2) 25-5.
Better than 97% coagulation Is achieved at
1.7-8.7 g/m3 concentration of H2S04, Increase
Card 7/8 of initial fog concentration above 5 g/m 3 leads

Accustic Coagulation of Sulfuric Acid Fog 77W)4
SOV/80- 7),@- I -:14r)
to a gradual (decrease in coagulation. Plo@ of coaw,@-
lation degree vs. the time of Sounding
S-shaped curves. By ch,:.ngirr, the cha,,,ac',er of sound,
It was found that conditions for formatlon of stat ionery
sound waves are more !'n,lorablc (,,',-ie of soun,:111.nr-, can be
. ........
e n -3 k- 1,00% coagulation There
si!oc' -1, 1.5 times fo -1
I'Lgurer,; d tabies; 27 refe:,r@,@r,es, Soviet
(-,""Man, 1 Fre9ch. I J:- .oanese, 4 U.K. , b U.S.
-he r_@ most recenit U.K. ai4l' U.S.
:-elf'erences az@c: .71. 1:i;-ter, R. H. Bolu, SonIcS
Technlquc@; `ot@ IT-,e f Sound and Ultrazowid in En)-,11-@eering
an,i S,-`,erwe, N. Y. 01`65); Melvin Norii, Chem- Er-
(L,)10); F. K. NeUman, L. Norton, Cheri. FnE-,. Prorr. Symp.,
I, ir(, 4 E. Brum, R. M. G. f3o@w",iev, J. ACOU3@-
Soc. Am., .2cli, 5, '1771 (1957); It. W. Dwi3er, E. P. Ncuw,-In.,
Inti. Eng. Ch., 41, (j,)4q).
SUBMITTED: June 13, 1)",)
Abstpacte-'s -)ot.o: The ,znMentifie-i :,eferences 3re:
L. Pimonov, Anan. TeleCoMmUn.,
5"Y (1951); J. Hartmaiin, The Acous%lc Ali, Jet
Card 8/3 IngenLorvidenskabelLue Schrifter, 4 (1);,9).

2
AU Varlar7ov, 0;
7 7 7.-F T nv e --'-c -a.-- - r,i'- -.r."
(V sb. "Primener-Aye u'-'traakust. k !Ssieci.
@7
-Ilie sound -e',' rf ,a j-a.s-jet 7enerit@-.r r,,-'
6", mm)
d Lrn-eter I@i.V@, mm; rezonatnr f`i-7n-eter
.,;-as investieated, and t-e exis-.-nce of opt-'.-Um
of sound attains a was z'@,bstantiate,!. 5arabo' ic
,%bo,,-;t 20 ti"Mes over t-e i-.te,-.sl, tof s3,,,.nd t-e axis tne 7enr:rat:@r
y
a. distance of mm as co@pared -,-iith the intensity of somd refle@,-
it was establ'shed that under opt,*-xur-. ad@ustment t-F, G@'-7 --@@nerat:-,r wit--t
+o-
reflector can y1eld acoustio up to I.i'-,2 (frerie-
reflector up to 1.19 kw (f-eq;:ency - kc' , which excec(iz
the power as calculated b- r.-,,ea--.s cf the Hartman fo-mula. T@rlere 'S
Card 1/2

nvest-E at" on of the,
5r(,ci--e
cl@arged by t! e gas r-- 'T'. 71,e
tor ir,,Ie- good -r tne
7nr the generator n
and the fl@..x @-,f *@hf- Ft'.r emt@rg!@-,-r fr
wh1c,h prevents its bei@@ 'sr t.-.t-
7:-r'DVed MOdel of the
of' the souncir.F a4-r iz -,-reventc-.@. T, e a r
directed at a rig-t a:.j!F! t`., of tl@e 1'@-)
a. special aperture. Te.3t-4:-:@ -enerat-Dr 3.
generating on its a-yis t-) watt/= or 1
,)cl;,,er of this genera-or -.@n@er a@@ ",,5t@nent t3
h
efficiency of 25". c-amher (dirmeter r,
the mean level of sound a@cng hr., a-z's and at I'll-, encl' eq@;a-s
the end of the sounding chanber It amounts to 16_1 d h -4 i 1 ;;:3 e d
with open lid.
rr-.bstracter1r, note: ComDlete trarslation!
Card 2/2

VARLAMDV, M.L., doktor tekhn. nauk, prof.- RANAKIN G.A.- STAROSELISKIY, Ya.i.;
ZBROZHEK,, L.S.
Analyzing the ammonia method for the removal of nitrogen oxides
from the exhaust gases of a nitrose tower sulfuric acid system.
Report No.l. flauch. zap, Od. politekh. inBt. 4004-33 162.
Analyzing the ammonia method for the removal of nitrogen oxides
from the exhaust gases cf a nitrose tower sulfuric acid system.
Report No.2. Ibid.. 34-4,4 (@URA 17:6)
1. Predstavlena ka-fedroy "TekhriologLya I uvtomatizatslya
khimicheskikh proizvodstv" Odesskogo politekhndcheskogo Instituta.

MANAKIN G.A.
a b3,--) -T)' 1 On @n
ronTparing the cOef@ic@el)*s 4' a ri
iut;nni m vnrious t",PP3
0)(l,dpg by !Ilklll@ SC)
pol"tPO".
ep. o r No. lauch. Uip. r
:n-, "por,.mer","'
Clorpptil'@
v a r
oXiCieS by 'AM-
lo
k@lm-lcnt-sk ,,n f

VARLAMOV, M.L., doktor tekhn. nauk, prof.; KRICHEVSKAYA, Ye.L.;
LIMONOV, V.Ye.; FNNA.N, A.A.;
KOVIIATSKAYA, B.S.; &W
KOZAKOVA, L.M.; ZEFLNEK, L.S.
Study of the absorption towers of the granulation shops of a
superphosphate plant. Nauch. zap. Od. politekh. inst. 40:
62-72 16'. (MIU 17:6)

VARLAMOV9 M.L.; KRICHEVSKAYAp Ye.L.; ENNAN9 A.A.; KOZ4KOVAq L.M.; M.ANAKIN, --G-.A-., .
Acoustic coagulation of a fog containing fluorine compounds. Zinw.
prikI. khim. 34 no.lz78-84 Ja '61. (KMA l4al)
1. Kafedra tekhnologii i avtomatizataii khimichesklkh proizvodstv
Odesskogo politekbnicheskogo instituta.
(Ultrasonic coagulation) (Fluoriqe)

,I L Z-"-
A.R. L
14
Removal of @r@)M, hfi te grige.9 in trie prr-Gac*.-,-In
of' Z;10.

VARLAMOV, M.L.; MAKIN, G.A.; STAROSELISKIY, Ta.l.; ZHROZHU, L.S.
Ammonia method for the removal of nitrogen oxides of low concentration
from gases. Zhur.prikl.khim. 36' no.li8-15 Ja 163. (MIRi 16:5)
(Gases-Purification) (Nitrogen oxIdes)
(Ammonia)

ZBROZF
VARLAMOV, M.L.; MA IEK, L.S.; STAROSELISKIY, Ya.l.;
.-M
Friaimala uchastlye: TSITKO, A.S.
Ammonia method for the removal of nitrogen oxides from the
waste gases of the tower nitroso-sulfuric Bystew.. Zhur.
prikI. khin. 36 no.11:2335-2343 N 163. (MIRA 17:1)

L 1726_.@& aq
(1 F@G CPW
WjO1"16VO001001610M10Y1,3 "I
@Aurfoftl _'VarismT." M. k4k; M-nah no 0, At; gnmPL-A.-A.
'tion of eogg
TITLE.* Iffveitla;U@6 of acMr1;'4c"=X% -tog-subjected to continuous
and, pulsed @soitnd .,t9, 5 .5
SC-MCE6,.MM' _@FizikA@W. 4., 196% M-133
Topic ftm'e aerosol, natural@@aerosol, fog, acoustic.cioagulation, aeiosol chamber
ABSTRACT:.- In view of the lack of theoretical means of predicting the effects of
aebust,le, coagulation on various aerosols, the authors used specialty designed ap-
ern"O - experimentally the. major coagulation parameters (number of
p4T 1113 to
e volume-.abd size distribution of -the. particles). Most of the
formulas for the particle-sizis distributionp and the premedure for
apparatus t
Or
the e.V Imei tstl-- reduction have been described in earlier papers by the
authors and their co-vorkers (Sb. Primenenlye ultraakustiki k issledovanlyu vea-
chestva [Use of ultrasonics @- -in '-materials rtmearck), no. 17s MOPI, M-s 1963, and I
.eiiiier--i6fe-r-e-n-c-e'o'i)'.--"fo-.~r'miWia-'s- ' aire- jp-rfe6efit6d f6k ae-teiii-ifffij ifi6_4e*ro661 coneentra_-,,.
$titns at,thb outlet of an a6rosol dhamber in terms of the time spent by.the aeroso@!
in the. dhamb erL and -in; terms of thb palse repetit~icii!frequendy!.(pulged, sound only) 4
The results have established that M@!Td sound at a frequency of 16.5 kcs, a pulse 11
Sard 3/2

L 1726@46
IACCESSION n, AP5021180
repetition. frequency of 2 pulses/sec, a 4reduced pulse duty factor of 2, and a I
total expobi*e-,,of 3-5 seconds consumes roximately half of the acoustic energy
app
requiredin the case of continuous sound. Orig. art. has- 4 figures and 5 formal" .
[02)'i
IASSOCIATION.- Odeaskiy politekhfilcheskiy institut (Odessa Polytechnic Institute).
o3oct63 ENCL: 00 SM3 CODE: ES
90 REP SOVI 005 OTHER., 000 ATD PRESS: Yoq6@
card...

TP Fi Oit .10W @ 741 - '4
T iT i, Cn th@-- "'hrvry @iie -tiangp" Partic:@s (K @eaiil -L:trutinyeri-
r na.i t i
'A! Zillif rl. 17,7 e c. r t@
U
ABSTRACT: 'I n t ti,- crci i tie mat i -@@i i rt .ei :.r,e tat cri the scheme by
Nn-, ch wi,w slLpgez;ted by P- a @-'@!pagnat and 11
T. t, r. t Y. .3 1 a np-H .i n r e g.E L o r.9 o t iri a u P r i t
t, fie t* - m r; i cc h;j rgr:? ,1" the s@;stem j*'
r, t a r v 1) r t
@i I r -ed iri a; s @ r c) n qatiri e i ec t: romagrie t; I r. r
, r, i ns Ph e i i c. I'p r m @ (-! n -, c , in r g eof a part ic le -- @'. a r, @1,- t e rz r,,
t 1-1 L't :* MH -1 1 -, f@ 11 f'U pe r Lic-s c@:' t h. r;7-. r t i -L iirr. ga r (I
T Ii i-m-At. T1 @ and inv@r,,-.-
i - 1, -A @,omf J v i ri i r -N j i : i these geneill]
wore V C-
rf, r,, -.1 s o a c. a I a f - m r t - c I es I
r @ U U di- v c a ou r t a 1 @- 0 s p @ n3 3 .)a s.
tne f i -gt @ina u Lind IS03pincrial Pa i17
9 uni k a nd 'i'hevefore only thp. @ vp. u@ :i u
ard ar- for a vart.cle In th-? tnecr@ @y d -A@@agna-

On the Theory of th- "." range" ps
a rd ' 'r n t h;, r@ , n n e c tc n@,@ t ween tne- p P.
I p d cm pjre T), T, 'j t r.-(' Isotrnp sum is b.v
I E. a .'Cr @i I
apt In 1n@' z3,rnr:p* and in the ele@trumqrro@t-, in-.@r
a c t i n r-na-rzi @-(-)nctwq- In the wo-ek intera-'-fc-n tv.@
t: rar. i 'Dr-,5 r; r @L L :t - - ' a r--@ permi t t Pd rh ) ch cor re A r,---d:-,
x i th n- (,i@ 1 1 Mmi r.- @ Go I li :.'a rin ) t runo, I t I@.n 9 rj.'@ r e, r -
par 1 -1 %,1 @h @h,@ ichom,, cy Cell -!..ann thp fo -,I owin
g
resu i * The Pe L i Mario @.t rangenfiss --) deno@e 9 t@ie d if f'P r,
b e t vie - r7. the Iscfermiont-- chargp u of th& rjarticie an.1
mi- t P(:;i i c , bary jr, ic ) chr@ rge n . S u n. The i -()'e i-w. i or.
criarge --i c, en A tisumm? on y jal tie. s f u r 1 r- rrr. s wit tj
I
the Isr-tove Fp2n 1 2 1 for anti 1.S0I'E-I*MICVS: for x@.c
It-) S or i ti wi'h I- 0 , r Ac c o rd i ng t o t ne c, r i r. @ @,r; rh-
v u thor t n. e a r, t i , t, r t',F. r in i c, ni r -- Ii a r ge o f a p a r ttt
ri'h n an@ I has tk, be regarded to bp a -rimar,;
of tfte P.-.:! t@e F'ranger-?ss -@nlv to t-? cne
pc,F;5;ibIe c:)rnbinationsl Thert- are I tabie and ') r-'e-encr-
6

IT
I nst i t u t,4
TT IV u r, t n,,t_ally@@. nnd !@ecember
T e V T1
1. Particles-Theory

MANAKIN, M., gvardii polkovnik, Geroy Sovetakogo, Soyuza
Improve planning of housekeeping c-.erations. Tyl i snab. Sov.
Voor. Sil. 21 no.11:54-50'! N '()I- (MIRA 15: 1)
(Russia --ikimy-Military life)

BUKSHTEYN, Mikhail Abramovich; BELENIKIY, Yakov Grigorlyevich;
MANAKIN N V red.; LMT, Ye.I., red. lzd-va;
'ISLANTIYEV@, P.G., tekhn. red.
[Manual for a worker in the manufacture of wire rope and
hardware products] Kanatchik-metiznik; spravochnik dlia ra-
bochikh. Moskva, Metallurgizdat, 1963. 230 p.
(MIRA l6t7)
(Wire rope industry- Handbooks, manuals, etc.)

RANAKC, V.I.
'11- 1 -- - --_ C@661om`c c-vst of @hp pericardium. Uch. zap. S@qvr. o.- .
7- -1
r
med. inst. .12:240 '63. (M 1@ 'k 1-7:91;
1. Kafedra fakulItf!tskoy khirurpij (zav.- 1)rnf. I . 1 . ftnzh@ir;ov)
Mod@ tBiriliKOJ@0 lnlit@ - - .
';tAvr-opoj'qk,-)f,,o jTo,-,iidar3',vt,nnoVo @ Oll

MANAKOV, A. A.
228N/5
iSi(CH 3)2]nl obtained in 65-75% yield, m.,p,.
340c'-3450C (under decomposition). It exhibits a much higher resistance to
thermal oxidation than a similar polymer obtained from (CH 3)2siC12 and
sodium in benzenG (2000C, 15-20 atm) (Ref. 1: see below). It is assumed
that the reactions described involve dimethyl silylene, a silicon ana1QK
of the carbene compounds, as an intermediate;
Li LiCl
(CH ) Sici 5@-_ (CH iLiC1 (CH
3 2 2 THF 3)2S 3)2S"
Card 2/4

27497
S/06 2/6 1 /coo'/cog/ci 3/014
New method of preparing B1 17/B1 01
In the absence of alkenes the latter is polymerized to L, Si(CH 3)2,n* In
the presence of alkenesp dimethy- silylene probably adds to the double
bond with formation of unstable silicon analogs of cyclopropane of the
corresponding diradicals. These then form derivatives of silicacyclopentane
and polymers by reaction with excess alkene:
C C'\ C\ _C/
\ / CH@ ] or [\ /Si/CH:
Si (CH,),, -I Si/
C C \CH, C- \CH
CH
C----C \/CHj [_ 1 1 )"
I Si + si-H-c-
C-C/ \CH, H, I I
@bstracterls note: Complete translat-ion.@
there is 1 Tijn-Soviet re-ference. This reference to English-language
publicatio.-is reads as follows: C. A. Burkhard, J. Am,. Chem. Scc.j_@, 963
0949); pat. USA 2554976, 2). V. 1951; Chem. Austr- _iU, 8809 (195
Card 3/0

27497
S/06 61/@:C0,'0091/013/ClA
New method of preparing ... Bl 1 11Y31 01
ASSOCIATION: Institut organicheakoy lzhimii im. N. D. Zelinskogo Akademii
nauk S33R (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
SUBbTITTFD: June 27, 1961
Card 4/A

NEFEDOV, O.M.; IVASHENKO, A.A@; MANAKOV, M.1j.; SHIMIZV, V.I.;
PETROV, A.D.
Pew method of preparing carbenee. Izv. AN SSSR Otd.khim.nauk
no.2-367 F '62o 04M 15@2)
1. Institut organicheskoy khimii Im. N.D.Zelinskogo AN SSSR.
(carbenes)
Art

NEMOVY 0. M.; I VP-M. N.; PETROV, A. D.
Organolithim svnthesiB of germanium hydrocarbon compounds
from dimethyldichlorOgermane. Certain reactions with a
possible intermediate formation of W12G6 Dokl. AN SSSR
1.47 no.6.,1176-1379 D 162. iMIRA 16:1)
1. Institut organicheskoy khimii im. N. D. Zelinskogo AN SSSR.
2. Chlen-korrespondent AN SSSR (for -3trov).
(Lithium organic compounds)
(Germanium organic compounds)
(Germane)

3/062/62/000/007/006/013
B117/B180
AUTHORSs Nefedov, 0. M.p Manakov, M. N., and Petrov, A. D.
TITLE: Synthesis of substituted 1,1-dialkyl silica cyclopentanes
from dialkyl dichlorosilanee and styrenes
PERIODICALj Akademiya nauk SSSR. Izvestiya. Otdeloniye khimioheekikh
nauk, no. 7, 1962, 1228 - 1237
TEXT; The reaction of dialkyl dichlorosilane and aryl ethylene with
alkali metals (lithium, sodium) in an inert solvent is here described, as
a new method of synthesizing aryl-substituted 1,1-dialkyl silica cyclo-
pentanes (30-75%). The reaction set in immediately with considerable
heat evolution when a mixture of-aryl ethylene and dimethyl dichlorosilane
was slowly added to lithium in tetrahydrofuran. The reaction with sodium
was less vigorous. Diethyl ether or benzene instead of tetrahydrofuran
decelerated the reaction, but hardly affected the yield (35 - 50%) of the
end products. In addition to silica oyclopentanes, polymers with silicon
atoms in the principal chain a1do formed during the above reaction (yield
up to 70%)- (Their composition and structure will be studied in detail.)
Card 1/2

3/062/62/000/007/006/013
Synthesis of substituted ... B117/B160
These polymers were the main products obtainet! by the reaction of di-
chlorosilanes and conjugate dienes (e.g., piperilene) with alkali metals
(Li, Na). As a possible mechanism of the formation of silica cyclo-
pentanes, the reaction of dichlorosilane with dilithium derivatives of
styrolene and their dimers (reaction A) is suggested, or possibly that of
dichlorosilane with the "dimerizing" adduct of lithium to styrene (reae-
tion B) are suggested or the oarbenoid mechanism.* Synthesiied aryl-
substituted silica cyciopentanes might possibly be used as monomers for the
synthesis of chemically and heat resistant polymers but this has not yet
been confirmed by experiment. There are 1 figure and 1 table.
ASSOCIATIONs Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSH (Institute of Organic Chemistry imeni
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTEDs January 26, 1962
Card 2/2

NEMGVP 00M.; 14AUKOVO &N.; IVASHENKO, A.A.
Addition of dichloronarbene to some I-substituted 1-cyclohexenes.
Izv.AN SSSR.Otd.khim.nauk no.7:1242-121+8 Jl 162. (MIRA 15@7)
I
1. Institut organichaskoy khimii im. N.D.Zelimkogo A14 SSSR.
(Garbenes) (Cyclohexene)

)11642
S/02 62/147/006/023/034
B144 101
AUTHOFS: Nefp-'ov, 0. M., Manakay, M. N., Petrov, A. D.,
Cor- ponding Member AS USSR
TirLE: Organolithium synthesis of germanium hydrocarbon compounds
from dimethyl dichloro germane. Some reactions with
(CH3)2 Ge as a possible intermediate product
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 147, no. 6, 1962,
1376-1579
TEXT- (CH Gecl which behaves like (Cii ) Sici combines with Li
512 2 3 2 2
dissolved in tetrahydrofuran (I) at 20 - 450C to form a cyclic hexamer,
@(n Ge.11 ! , easily soluble in organic'solvents; m.p. 211 - 21.3 0C;
2 6
yield up to 80%. At -OOC, @(CH ) Ge 11 a strongly hydrophobic compound
3 2 'Int
similar to polydimethyl germylene and insoluble in organic solvents was
also obtained; m.p. 200 240OC; yield 4V6. Reaction scheme:
2nLi -n LiCl
n(CH ) GeCl > n(CH Ge(Li)ci n(CH ) Ge: )I Ge-
3 2 2 -nLiCl 3 2 3 2 [(CH3)2 in -
Card 1/3

S/020/62/147/006/023/034
Organolithium synthesis of B144/B101
(CH5)2 GeCl 2P styrene, and Li (molar ratio 1 : 2 : 4) in I yields the
following products when stirred violently at-.,OOC: (1) X,XI-diphenyl-1,1-
dimethyl germanacyclopentane; yield 40.5%, b.p. 140 - 1410C/0.2 mm Hg;
n20 1.5920; d 20 1.1688; (2) A polymer with the general structure
D 4
hicn s easl ly sol-.,ible in ether, and benzene; after
k n w
3
twofold reprecipitat'lon with methanol a white powder is obtained
0,
m.p. 74 - 89 @.; molecular weight 2790, 2960. Substitution of vinyl
toluene for styrene yielJs 455 X,Xl-Ii-*,3lyl-I,I-dimethyl germanacycla-
pentane under otherwise equal conJitions; b.p. 150 - 151OC/0.18 mm Hg;
n20 1.5825; d 20 1.1346. The melting point of the Ilinear polymer obtained
D 4
by reprecipitation was between 58 and 700C, and its molecular weight was
1280, 1220. The course oil the reaction as given shows that the products
Card 2/ 3

S/02 62/147/006/023/034
Organolithium synthesis of B144YB101
obtained from Li and styrene with (CH ) GeCl @nd also the intermediate
5 2 2 9 -
product (CH 3 )2 Ce: react immediately with C6 H5CH=CH 2' The sructure of the
resulting compounds and their similarity with the corresponding silicon
compounds were confirmed by the IR spectra. There is 1 figure.
ASSOCIATION: Institut organicheskoy khimii im. N.D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni
N.D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED- September 26, 1962
Card 3/3

NEFEWV, O-H-9 H&NAMV, M.N.t AND P&TROV9 A.D.
--------
Investigation of the reaction of organohalides of silicon
and germanium with lithium and its compounds.
Report to be submitted for the Second Drqsden Symposium on Organic
and non-silicate silicon chemiatz7,, from 26-3o March 63, East G@rmarv
Institute for Organic Chemistr7 of the Academy of Science$ of the USSR,
Moscow,

AccEssim NR: APW37241 8/0062/64/000/005/0840/0844
AUTHOR: Nefedov, 0. Me; Manakov, M. N.
TITIZ: Reaction of dialkyl(aryl)dica;@6silanes with alkall metals in the presence
I of conjugated dienes.
SOURCE: AN SSSR. Izv. Seriya khImicheskays., no- 5, 1964, 8W-8"
TOPIC TAGS: dialky1dichlorosilane, diaryldichlorosilane, reaction, conjugated
diene, divinyl substituted silicacyclopentane, unsaturated silicon containing
polymer, silicacyclopentene, production
ABSTRACT- Continuing their earlier works (Izv. AN SSSR Otd. khim. n. 1961, 1717;
1962, 1228) the authors investigated the reaction of dialkyl(aryl)dichlorosilane
and conjugated dienes w1th alk-all metals in tetrahydrofuran. A mixture of 0.2 M
i dichlorosilane (dimethyl-, diethyl.- or dipheny1dichloro-silane), 0.4 M dieae
(divinyl, ieoprene, piperylene) and 4-5 gm Li or 12 gn Na was reacted for 0-5-1
;hour at about 30C in 50-200 ml absolute tetrahydrofuran under dry nitrogen* The
!product was filtered and the filtrate vacuum fractionated (0.2-0-5 Em Ixg). Three
types of products, vhose zelative yield depends on the initial. reagents aud
Card :114

1ACCESSICK NRI AP4037241
'reaction conditions, (see Table) were formed: I--divinyl substituted silleacyclo-
pentaaes, 10-50% yield; II--unsaturated silicon hydrocarbon polymers with 81 atcas
in the main chain,, molecular weight of 1000 or more; and I31--ailicacyclopentenes,
0-10% yield. -
R"
R( -CHR
(D R'
R"/K\R"
H R
",PcR - H CHI ; R' H, CHI R" CH; , C-I HS, COH&_.
lip
IICII (m) C (RI CHCjj,Aj + 11 Sicl,
17
R S1
A& Re Re
24

Acmaicif NR: Ap4o37241
Initial Reagents Reaction Products
Silicacyclo- Gilicacyclopentane Polymer
pentene (111@ (1) (11)
Dichloro- Diene Metal
1311 an Yield Yield Yield Moleculs
gm gn. gm. Weight
1
CH3
2SO12 Divinyl Lithium Traces - 3-4-7 9-14 22-23
2 CH3 2S'C'2
@
@ Isoprene Lithi= Traces - 10.0 26 22-5 950,1060
3 ic Piperylene Lithium 0 '0 Traces - 32
4 X-S'ct Isoprene Lithium Traces - 21.6 49.5 16.5 920,810
5
C 5 Pic Isoprene 06dium 2.7 9 6.9 15.5 23
6 c 5
@@;ic
@ Piperylene Lithium
7
6.2 14
31
1770@UW

05 2SiC12 Isoprene l Lithiumn T cesl 8.0 12-5 1 36
Orig. art. bas: 3 formulas; 2 tables.
Card 3/4

!':ACCF-c,SION NR: Ap4o37241
ASSOC=ON: Institut organicheskoy kbimii im. N. D. 2;elinskogo, Akademii nauk
;'SSSR (Institute of Organic Chemistry, Acadewj of Sciences SSSR)
I's SUMUTTEM 26oct62 ENCL: 00
5U CODE; OC No rop sov: oo4 OUM: OCA
Card

NEFEDOV, O.M.; 14ANAKOV, M.N.; PETROV, A.D.
Mechar.4.sn of' I.he- I'armation of aryl-substituted
from organodichlorosilanes, styrenes, and lithl=. A new
method of preparation of aubstituted disilacyclohexane.9.
Dokl. AN SSSR 154 no.21395-397 Jalb-4. (MIRA
1. Institut orranicheskoy khimli f'm. N.D. Zelinakogo AN SSSE.
2. Chlen-korrespondent AN SSSR ("or Petrov).

NEFEDOV, O.M.;MANAKOV, M.N.
------
Formation of reactions of silylenes, silicon analogs of
carbenes. Zhur. ob. khim. 34 no.7t2465-2467 T1 164
(MIRA 17:8)
1. Institut organicheakoy khimii imeni N.D.Zelinskcgo AN
SSSR.

--K-AN , !kikolaT_,@!kssudravich; SEICTM AKOVA. G.A., red.; TODMAGIIIA,
S.D., tekhn.i4C----
[Unified State plan for the development of the national
economy and the balance of the economy] Zdinyi goau-
darstvannyi plan razvitiia narodnogo khosiaiatva i balans
narodnogo khosiaistva. Izd-vo Lsningr.univ.. 1959. 48 p4.
(xin iz-6)
(Russia-Economic policy)

MAWOV N.G. 'n"
---I-- --- J- . -2 --.
Detazmining tha humidity and stability of soils in a small device
for stands d stabilization. Ayt. dor. 26 ne.5:27 My 163.
(?ff.RA 16:7)
(Soil-Tes ting)

IVAYCV, Fedor 1 14 khaylovich; !kD('W I I ga Aleksa-ndruvra;
Wj;.@Ilcv, '.4.,,azbek G@,Ibdlanovich; V.F., red.
[Flanual for the rerearch workor irt r(,adi rr.ater'ia.10,
17
Spravochnik XoAva, Trailo TIO rt
1964. 199 m Iv

RANSHILIM, V.V.; AGAFONOV, A.V.; MANAKOV N.Kh.; VASILENKOY V.P.;
MASLOV, I.Ya.; KNYAZEV, 0- 1. A.; Prinimali
uchasti.ve: VAYLI, Tu.K.; NMETS, L.L.; BELOUSOVA, I.V.;
STOLYARENKO, Ye.G.; YEVELOYANOV, A.A.; RYABOV, Y.M.;
BEPMOVSKIYI V.D.; ZEKROVA, Ye.G.; CHELOGWZOVA, Ye.F.;
SOLOTSINSKIY, S.Ye.; BOLISHAKOVAY Y.A.; KHRAMOV, A.Ye.
Catalytic cracking of raw heavy distillates on a microspheric
catalyst of Troshkovskiy clay. Whim. i tekh topl i masel. 8
no.3:1-6 Mr '63. @MIRA i6:4)
1. Vsesoyuznyy nauchno-isslet4ovatel'skiy institut po pererabotke
nefti i gazov i polucheniyu iskusstvennago zhidkogo topliva.
(Cracking process) (Catalysts)

sov/65-59-4-5/14
AUTHORS: Agafonov, A.V., Basov, A.N., Manakov, N.Kh. and
Manshilin, V.V.
TITLE: Combined Plant for Fractional Distillation of Petroleum
and of Catalytic Cracking Residues on a Microspherical
Natural Catalyst (Kombinirovannaya ustanovka pryamoy
peregonki nefti i kataliticheskogo krekinga ostatochnogo
syr1ya na w1krosfericheskom prirodnom katalizatore)
PERIODICAL: Kh:Lmiya i tekhnologiya topliv i inasel, 1959, Nr 4,
pp 25-31 (USSR)
ABSTRACT: Petroleum refineries have to process asphalt-tar
substances of petroleum which can be extremely difficult.
Processing methods hitherto applied use high temperatures
(above 4500C) at high or low pressures. A high yield of
tarry residues and poor quality gasoline or distillate
fractions and petrols of low quality and also hard
residues in the form of petroleum coke are obtained by
thermo-cracking. The temperature is an important factor
during thermal destructive processes. It has been found
that temperatures should be selected to give fractions
Card 1/4 with octane numbers exceeding 70 and that the cetane

Sov/65-59-4-5/14
Combined Plant for Fractional Distillation of Petroleum and of
Catalytic Cracking Residues on a Microspherical Natural Cat%lyst
number of the diesel fuel fraction should not exceed
42 to 43. The VNII NP have developed an economical
catalytic destructive process for the treatment of
residual petroleum crudes which makes it possible to
obtain high grade gasoline and diesel fuels in
industrial quantities. The process was tested under
laboratory, pilot plant and industrial conditions.
The VNII NP is, in collaboration with the Giproneftezavod
Institute. at present designing two plants where the
simultaneous fractional distillation and catalytic
cracking of the petroleum crude can be carried out, one
with an annual capacity of 2 million tons and a second
of 3 million tons. The lay-out of both factories will
be the same as is shown in Fig 1. The asphalt-tar
substances will be subjected to the direct action of
aluminium silicate catalysts which will be sufficiently
active to ensure decomposition of the high molecular
petroleum fractions (boiling above 530 to 5500C). The
light gas-oil fractions of the petroleum will not be
Card 2/4 decomposed and the cetane number of the diesel fuel

SOV/65-59-4-5/14
Combined Plant for Fractional Distillation of Petroleum and of
Catalytic Cracking Residues on a Microspherical Natural Catalyst
fraction, obtained during the process, should be 42 to
43 or higher. The newly-formed fraction of the gasoline
should have an octane number of 76 to 78 and above. The
crude petroleum or fuel oll can be directly supplied into
the reactor. Various further improvements in the process
are described. The percentage composition of the end
product obtained on a natural microspherical catalyst in
an industrial plant is given, as well as experimental
data, obtained by VNII NP during 1958, on fuel oil
subjected to catalytic cracking on a pilot plant. The
coke deposited on the catalyst can be separated by
roasting at a temper%ture of about 600*C; the importance
of the catalyst is discussed. By using pneumatic
transport for the catalyst in a highly concentrated
current it is possible to decrease the height of the
plant and, therefore, to lower construction costs. The
regeneration of the catalyst is intensified. The
considerable enlargement of the desorption zone in the
Card 3/4 reactor, and also the creation of a counter-current

sov/65-59-4-5/14
Combined Plant for Fractional Distillation of Petroleum and of
Catalytic Cracking Residues on a Microspherical Natural Catalyst
desorption zone in the regenerator for degasification
and activation of the regenerated catalyst, decreases
coke-formation and the yield of methane, gives higher
grade gasoline and simplifies the further separation
of cracking gases. Practically all the heat,
generated by burning the coke and other component
gases, is utilised. These vapours are used as power
and also for desorption or for heating. The plant is
also equipped for utilising the effluents. Comparative
technical and economical characteristics are listed in
a table. The authors also refer to a relevant article
by Sherwood which was published in "Petroleum", 19599 Nr 2.
There are 2 figures, I table and I English reference.
Card 4/4

S/065/62/000/006/004/007
E I 94/E 1' 36
AUTIiGIZS :-i ri s h i I i i i V V 'n i na L. L) y h , -1 V" t f n n 0 V V
V.-I -.5i 1, eri:'o V P M'Is I ov T . ya , , Fri Y.xzov V S ,
AITLE: T es t i n Ir r) t, n u n t, r, r i n @- e v v I (:) pm e n t r-) r s vs t ern
for t'li.iid caL.ilvtic crac'@i.nz
P-'AiUDIC@'L: i t'('k!),-IoIozjy.i toplix, i i.i,iqn.], no.0,
TEXT : To prev(,nt s,@ont.inoou.,, if(orhiirnin ',-@ of, C.11-hol-I I!ojloxide
,ind otiiei7 caniousti!)ie '-,:,i:@es which can occur in the ro,,ener,itors
of fluid catalytiC cx"Ic!@vrs, -Iamaeing the cyclone and caus@ng
other faults, the regenerator te:-,perature is kept below 60coc,
thou,,h in mnany rc.F-.,,-)ects it would be advantageous to raise it to
650oC. To aci-iieve this t!!e free oxygen content'of the 3ras in
the regenerator :@iust @)e recluced by raisin-," the level of coking of
the catalyst, by greatly improvinu the contact between air and
catalyst or by a combination of these two methods. A regenerator
which achieves this combined effect is the main feature of the
system here described. Vie construction of a pilot plant reactor
unit %..,hich includes the reactor, a turbulent scrubber,
a regenerator and two pneumatic catalyst transport lines is
Card l/ 3

3/0") 5/(,2/ULC./CG()/OC/' /GG 7
Testing of engineerin@ ... Z 1 `,, -' /E 4 3 6
described. The re@--ener,i -@or -s i vert Lca I c-v L i.nder w it 1i -"-,rc()roC f'
1 in ing of 1400 im;i i r. t e r@ia I d i,k,i-e t e ri t li,ts -x thr(:42 si-- c,;c lone
ill tile uppf@!r Wi t 11"i rl t.11" 1@011,1 Of' th@' f'I Uid, @'Cd IATI inner
hollow st eel cyl inde r (- OG ; v@', di J:nf, t er c on ti in 1. c o@l c 0 i 15
with air distribution arrange:-i-.ents. The spent c,italyst is
delivered to the a;@.nulir zone of' tile regenerator and, under
conditions close to those of ideal mixinF, suff-@cient c()ke is burned
to maintain the tp:-.@-)erature in this zone at about 6C)COC. 9ecause
of the intensive -iixing there is little local overheating.
Combustion of the coRe is completed in the c(-)ntrnl zone In,' the
temperature of tht- c,it-lyst le-ivin., the nart of the zone for
the reactor can he controlled by coolinlv coil. The regeneror-im
nrocess is split into these t1--,o st,iges to i-mr'ove com)WSLion of the
col@ce . Most of the colke is removed in tl-,e first zone, where the
mean content of co;@e on t-,e catalyst Is high, tile cor-lbustjOn being
intensified by the counter current conditions and :-osir of the
oxygen used ur). Oner;itin:@z condit-Lons are given f-or the v,-lr-ious
d@krts of the unit and 1-he results obt-iined provide :11" the
necessary dixta for des.;1,,nia7 Cull-sclile indl,.isti-il Pll-.nt .-.-ith
Card 2/3

s /o6'- 16 2 /0(1 c, /oo6/oo /1 /007
To.-iting, of' . . . EL91j/E1,36
reactor and re:,,ener.itor at L:i(, sar;e high level. iisiri!-7
,mr,uniiatic transi)ort of ( iiv!, ) .The two-stap,e anrl three-stave
cyclones in the re-ictor And regetierritor respectively g,lve
satisfactory reterition o'L catalyst dust and rot@irnerl it to tile
fiLlid bed. There Lre 5 figures and 5 tables.
A 5 S 0 C IA TI ON :WNT I I N F
Card 3/3

V W LENKO, V.P.; MANSHILIN, V.V.; MANAKOV, N.Kh.
Pneilmatic-tube transportation by a high concentration flow.
KhimJ takh.topl.i masel 7 no.7@1-4 J1 162. (KIRA 15:9)
1. Vsesoyuznyy nauchno-issledovatellskiy institut po pererabotke
nefti i gazov i poluchenivu iskusstvennogo zhidkogo topliva.
(Pne-Atic-tube transportation)
(Cracking process-Equipment and supplies)

GREKOVAq A.M.; MANAIKOV, N.Kh.; MANSHILIN, V.V.
Some hydrodynamic properties of a fluidized bed of powdered
catalysts. Xhim.i tekh.tiplj masel 8 no.1:4-10 Ja 163.
(MIRA 16:2)
1. Vsesoyuznyy nauchno-issledovatel'skiy institut po pererabotke
nefti i gazov i poluchenlyu iskusstvennogo zhidkogo topliva.
(Fluidization) (Catalysts)

MANSHILIN, V.V.; @MJIAKOVj,.R@,; VASILETIKO, V.P.; VAYLI, Yu.K.
Longitudinal mixing of components of the gas phase Ln a
fluidized bed of aluminosilicate catalysts. Khim. i tekh. topl.
i ma;jel 8 no.7-.30-35 Jl 163. (14DA 16z7)
1. Vsesoyuznyy nauchno-issledovatel'skiy Institut po pererabotke
nefti i gazov i polucheniyu iskusstvennogo zhidkogo topliva.
(Aluminosilicates) (Fluid--zation)

I
GREKOVA., A. M. - 'Ei%TTS, L. L@ ; M , ',-. 7i @ .- -M@-'AKOW., N. Icr .
5 a t,,, ' ,!- i*,,.r !:*,@- 3 .- ' rx@ry
Us @ng a r p I
lov ocrvientre-@4@a.-i. Kl-'m i --op". -. 7
0 1: C". _- .

TUCHONOV, G.V., vetvrach; WaROV, N.N., zootekhnik; Y&TVN-,-'NV, A.A.. 78t.
folldsher.
Miminating fascioliaoic and dictyocaulools from sheep on the stock
farm. Voterinariia 35 no.4:49-50 Ap '58. (MIRA 11:3)
1. Vblogodskiy vaterinarnyy takhnik3im (for Tikhonov). 2. Kolkhoz-
"Kmanoys znamyall (for Manakov, Patvayev).
(Sheop-Diseases and posts)

j,@,%J@t,KCV 7i TA L',.VV',TTCT1
MANAY, MIKILAYLICHINKO, B.. redaktor; N3DOVIZ, S.,
tekhnicheakiy redaktor
[Innovation in machining of cutting tools] Nove v obrobtai rizelinoho
instrumenta. LIviv, Knyzhkovo-zhurnallne vyd-vo. 1956. 25 P.
(MIRA 10:9)
1. Golovniy inzhener Llvivslkogo instrumentallnogo zavodu (for
Kanakov)
(Cutting tools)