SCIENTIFIC ABSTRACT MANDEL, V.S. - MANDELBAUM, YA.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001032110017-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 13, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

CHERITYAK, N.I. [Ch6rniak, M.I.]; GAVRILOV, D.A. [Havrylov, D.O.);
-@PF-41 1 0 V..S.
Effect of metallurgical defects on the strength of 3K:ql3 steel.
Prykl. mekh. 10 no.4&40?-415 164. (MIRA 17,,10)
1. Institut mekhani-ki AN UkrSSR.

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KLMMI I ra.mo
Advanced training for feldshers of independent feldsher-milwife
stations. Zdrav.Ros.Yed. 2 no.10323-25 0158 (kmu u: 10)
1. Glavnyy terapevt Tambovskogo oblazdrevotdelao
(TAMOV PROVINOV--MICM, RURAL)

- -
Congress of feldshers and midwives of Tambov Province.
Vdra7*Rose Fade 2 no.lot47-48 0158 (KIRA 3-1:10)
(TAMBOV PROVIIIM-HBDICM, RVRAL)

KANMI, YaGM. (Tanbov)
Concerning N.A. Chernotakaia and N.N. Nazarleva's article *On the
etiology, pathogenesia, and treatment of acute leukemia.9 Arih.pat.
20 no.9:92 S 158 (MIRA 11:10)
1. Iz terapevticheqkogo otdeleniya Tambovsko7 oblastnoy bollnitay
(glavnyy vrach -zaslyzhennyy vrach RSFSR Yu.I. Melikov).
(LL'MMIA)

KA=L19 raoxf
Conducting interdistrict conferences of therapentiats on theoritical
and practical problems. Zdrav. Ros. Ireder. 3 no.5.33-35 Ky 159. 1
(KIRA 12:7)
I.Glavuyy tore6pevt Tambovek*go oblzdravotdela.
(TARM PROVINCI-MEDICIEN, IMMM)

FALIN, V.N.'- n-'IRE-Ll @Ya-M`%
Plaming of work in a province public health department. Zdrav.
Rose Feder, 4 no.9:12-14 S 160. (MIM 13:9)
1* Iz Tambovskogo oblastnogo otdola sdravookhraneniva.
(PUBLIC HMT11)

FALIN, N.N.; $AMEL', )[a.M.
Organizing research for doctors practicing in Tambov Province.
Biul. uch. med. sov. 2 no.5:24-26 S-0 161. (MPA 14:1-1)
(TAMBOV PRMINCE-KEDICAL RESEARCH)

MA03Lf Ya*Moq 2WIuzhennyy vrach RSFiR
14@"@.ion of ther@apeutic care in a ruml area'. Zdrav. Ros.
Fader. 5 no.1:22-25 Ja 161. (MIRA 14--l)
1. Iz Tambovskogo oblzdravotdela.
(TAMBOV PROVINCF@-THERAPMICS)

SPIRIDOIJOVA) A. V,; MATIDELIp Ya. M. (Tambov)
Incidence of diseases of the cardiovascular system as revealed
by data from a thorough study of rural districts of Tambov
Province. Zdrav. Roe. Feder. 6 no.5:12-15 14Y '62.
(KCRA 15:7)
(TA@MOV PROVINCE-CAPDIDVASCULAR SYSTEK--DISEASES)

114AMEL I BAUM, A. B.
CardB filed under YANDELIWIM, A. B.

MANDELIBAUM, A.I.; VOLKOV, K.M.
New machinery developed by the All-Union Scientific Research
Institute of the Peat Industry for the production of peat-
mineral-amonia fertilizers. Trudy VNIITF no.18:54-71 161.
(MA 17:1)

MAMELIBAUM. A.I., inzh.
@fork of the All-Union Scientific Research Institute for Peat
Industry in 1959 an the industrial procurement of peat and mineral
fertilizers. Torf.prom. 37 no.4:15-18 160. (MIRA 13:7)
1. Voesoyuznyy nauchno-iseledovateliskly Institut torfyanov promysh-
lennosti.
(Peat) (Fertilizers and manures)

IGMELIBUI, A.I., inzh.
Ilew machines for producing peat-qnineral-ammonium fertilizers.
Torf. prom. 38 no.4:12-15 161. (MMA 14: 9)
1. Voesoyuznyy nauchno-issledovateltakiy inatitut torfyanoy
prmyshlennoisti.
(Peat machinery) (Fertilizers and manure)
iev

A. I. MAIMEL'APM (USSR), K. I. Chekalov,, N. I. Morgunov
" Production of peat fertilizers at Industrial Peat enternrises "
Report submitted for the 2nd International Peat Congress, Leningrad,
15-22 Aug 63.

Fnicticuittim of cQuIage with cupirturtmaclum sWitaws.
V. V. Shulyatikova and D. 1. AlAndel'baum, Zku,
P,ikAsd. Kkiw. (1, Applied Chem.)
V.triatlon of the grolus 2mt. of the cupmnialonium "n
wit i low Cis coorn. c4n be ts@l oti;; bAnt, f-w fractionation tit
%ince the miln. lit cellulow rviluiret fiat only a
It.Articular concti. fit Cu Elut also it ctirtitin total mill. of Cit
&-III 6W hrillipillf"I (if 1110 clivollilffm VIIIIIii1re At fl* III
Ao llf%tij@ INKII41114 Am A14114141, climptelviv IV. 'Cult lit
five demdruction fly Ifiv fill Practitnt,
th.xt ACT regenrintled front %lift. AW,%VA Iflow 411 Oleml,V
tit the drpre tit liolyincrimAthin. A cellulow .1wrimen Is
itin,ed 5-10 mim In fin aq, Medium, fitteml by tuctian. air.
dried to 7-1)" ffrO and a I-ji. wornple 14 pl;A,v,l lit zi, duk.
11444 vV*WI (414 Q.) ain't emo , with the d-lml clitn"ItIl-
in,"slunt imilis. for :1 bro- At I)* with mirrinfir; file In*d )on -
11,111 1. diet-i-rd Vy suctiall and WA.11.1 Willi IAI,@ NIIAll,
11.4), 10"; AcOll, And IlsO mid dried The lw,t cin)['4111-
Moldiffn SUIll. MotAint 0.23-4.211`0 Cit. 7110 r"IlItS 11f
fractlomition of wveril specimens in m4rc! to mol. wt. dl@
tribution are given firafshically. G. M. Kowl2poff

The frectimatim of cellulose frm cupfammonfum solu-
tims. N. V. b% I atiltma anti D I %lanlsl:
OU
- ft WEB
Applied CUm . UTS.R. Z4, '-Vr'Z tra"s-
pon) -See C-A, @6, 2.52g. R. M. S.

1. ROGOVIN, Z. A.: SHUELAT3DVA, N. V.: MANDELIBALPM, D. I.
2. USSR (600)
4. Cellulose
7. Relationship between readtivity and solubility of cellulose preparations. Koll.
zhur. 14 no. 6, 1952. p. -:5-c-o
9. Monthly List of Russian Accessions Library of Congresf, March 1953. Unclassified.

RANDBLIBAUM. D.I.
Method Of d8ternining the viscosity of viscose cellulose.
Bum-Prom. 30 no.1:10-14 Ja 155. (NUU 8-3)
1. YsesoyuzWy nauchno-issledovatellskiy institnt iskuastvannogo
voloknae
(cellulose)
The time to det. the viscosity of cellulose xarthate (I) solns. is reduced
from 21 to 5.5 hrs. by the use of an emulsifying agent in the dissolving step.
The finely divided pulp (0.88g. bone-dr-y at 9 :t 2% H20) is kept 15 min. in 45 cc.
H20. One drop sulfonated oleic acid ester, 92 cc. 17.5% NaOH, and 3.2 cc. CS2
are added, the mixt. is shaken 15 min., rotated 5 hrs. at 25 + 0.20, and the
viscosity of the I soln. detd.; duolicate
samples agree within 0.85 mIllipoises, and the viscosity is within 5 MiUipOi3es
of that of an 1% 1 soln. detd. by the 5tandard method (mercerization-comminution-
Y.anthation-soln.)

WDE1,173AU4, D.I..; KONKIN, A.A.
Effect of the polydioperse state of cellulose on the ph7sical
and mechanical properties of 7iacose fibers. Report No.l.
Khim.volok. no.1:22-26 '59. (MIRA 12:8)
1. Vaesoyuznyv nauchno-iseledovatellskiy institut iskusetven-
nogo volokna iCellulose) (Rayon)

MANTZLIBAUH, D.I.; KODKIN, A.A.; SHULYATIKOVA, N.V.
Effect of polydisperse state of cellulose on the physical
and mechanical properties of viscose fiber. Part 2.
Khim. volok. no.2:35-40 '59. (KMA 12:9)
1,Veoooyuznyy nauchno-ioaledovatellskiy institut takusetvennogo
volokna.
(Cellulose) (Rayon)

.. MANDELIBAUM, D.I.; KORKIN. A.A.
Effect of the natural structure of cellulose on the physical and
mechanical properties of viscose fiber. Khim.volok. no-3:23-26
'59. (MIRA 12:11)
1. Vaesoyuzrqy naucbno-inaledovatel'skiy institut inkusetvennogo
volokna (VIIIIV).
(Cellulose) (Rayon)

,AATIDF,MIBATJ'4, D. I. Cand T-ch 3ci (dina) -- "Tnventigation of t.@,c c-rrt.ct. or r;oty-
I
dispersion and structure of cellulose on theproperties of viscose fiber". Mosrow,
1960. 13 PP (Min Higher and inter Spec Fduc RSFSR, Moscow Textile inst), 190
copies (n, iio 11, 196o, 133)

HAM113MR. D-I-,- KONKIN, A.A.; VISHNYAKOVA, M.H.
Connection between the submicroscopic structure of natural and
regenerated cellulose. Mdm.volok. no.5:31-33 P" I ..
(MIRL U:12)
1. Tsesoyuznyy nanchno-iosledovatelskiy inatitut iskmastvannogo
volokna (for Kandel;baam, Komkin). 2. Leningradakiy tekstil'MY7
inatitut imeni Kirova (for Vishuyakova).
(Cellulose) (Viscose)

-JTRTTVF K,V,, KANDEL'BAUIM, D,l.
ino Lr
Spectral method for the analy3--@ c' mlric-.-a- .--
lulose for chemical processing. KhLm. volok. no,4;3c,,-318 '64' -
(MIRA 18@4)
1. Lan-ingradskiy tekhnclogicheskly instit,_it kl,.olodilinoy
promyshlennosti (for S-1r,j-ie). 2. Vsasoy@,iznyy
.Wnli f-r Man@',el`
skly linstital, !-3kus-9'lve,,,,-. - r, a

1--FDIV. 3ec 8 Vol 12/11 Nizurology Nov 59
5701. AN UNUSUAL CASE OF RABIES IN MAN - Niezwykky przypadek wdciekl4z-
ny u cz1owieka - Mandelbaum J and Podolak W. Szpit. Mielsk. Nr
1. Legnica - POI:.TYG. LEK. WIAD. LK. 1959. 14/16 (724-726)
A peasant was bitten in the face by I weasel. He had no hydrophobia. drinking water
greedily wh'gn it was offered. Excitement and salivation appeared an the 5th day
after admission to hospital, a few hours before death. Histopathological examination
revealed Negri bodies In the brain. (L,6.8)

/1* E? (" Z /8 ALI j"VIO,
VASILITRY, Tiktor Grigorlyevich;
Ivan Petrovich; KRATCHEY10,
nrk-- k4roamoft- HORIS(ff I
i-eTaIR-or-,,POLOS;NA, A.S.,
KALUOV, Yevgeniy Nikolayevich; KARASXV,
Taygeniy Vasillyevich;
A.A., redaktor; FILrPPOVA. Ye.A.. vedushchly
tekhnicheskiy redaktor.
[Geological structure of the southern Siberian Platform and the
oilbearing prospects of Cambrian rockel, Geologicheskoe stroenis
tug& Sibirskoi platformy i neftenosaost' kembriia. Pod red.
A.A.Borispva. Moskva, Gos.nauchno-tekhn.tzd-vo neft. i gorno-
toplivnoi !it-ry, 1957. 226 p. (MIRA 10:11)
(Siberian Platfora--Geology,, Structural) (Petroleum geolo&7)

pRIMUO yuj,; SAVINSIaY, K.A.; HAMMLIBAUX, M.N.; TROIMIYO V.N#
Keane for a practical solution of the problem of oil and gan
potentials of the southern part of the Siberian Platform. (;eol,
uefti 2 uoe4t5-ll AP 1589 (KIR& IUD
1. Tostalbueftegeofisika.
(Siberian Platform-Petroleum geology)
(Siberian PLatforift-Gas, Katural--Geology)

@@ R N @ & L'(@ h 0 M, - NJ .
3(5) PHASE I BOOK EXPLOITATION SOV/2544
Savinskiy, Konstantin Aleksandrovich,.Mark Mironovich Mandellbraum,
Vsevolod Nikolayevich Troitskiy, Naum-Io-d-if-o-vi----E-gh-eZff,--a-ncT-
Nikolay Pavlovich D'yachkov
Effektivnost'* geofizicheskikh metodov razvedki v yuzhnoy chastl
Sibirskoy platformy, vpadinakh Zabaykallya i Dallnego Vostok@
(Efficacy of the Geophysical Methods of Prospecting in the
Southern Part of the Siberian Platform, and in the TransbVkal
and Far East Depressions) Moscow, Gostoptekhizdat, 1959.
114 p. 2,900 copies printed.
Sponsoring Agency: Glavgeologiya RSFSR. Voutsibnefteteof'Lzika.
Ed.: V. G. Vasillyev; Exec. Ed.: Ye. G. Pershina; Tech. Ed.:.
I. G. Fedotova.
PURPOSE: This book is Intended for geophysicists, geologists,
petroleum geologists, and area specialists interested in the
Siberian region.
Card l/-/

Efficacy (Cont.)
SOV/2544
COVERAGE: The book contains the results of geophysical explorations
carried out in the southern pa3ft of the Siberian platform and in
the depressions of Zabaykallye and Zeye-Bureinskaya. Questions
in the methodology of geophysical studies are examined and sugges-
tions are made on the direction and content of future work in
Eastern Siberia. Oil- and gas-bearing possibilities of the re-
gion are discussed with an eye to future economic growth. The
southern part of the Siberian platform, the so-called Irkutskiy
amphitheater, is cited as being particularly favo@red in the
economic sense. Materjals collected in the field are used in
the work. No personalities are mentioned. There are 59 refer-
ences, all Soviet.
TABLE OF CONTENTS:
Introduction
3
-brief Review of the State and Extent of Geophysical Studies 4
Efficacy. of.Geophysical-Methods in Studying the Ged-log4cal
Structure of Individual Regions of Eastern Siberia 10
Card 2/4

Efficacy (Cont.) SOV/2544
Southwestern part of the Siberian platform 10
Gravimetric and magnetometric surveying 15
Electrical surveying 19
Historical development of the southwestern part of the
Siberian platform based on the results of geophysical ex-
ploration 25
The Irkutskiy amphitheater 27
Gravimetric and aeromagnetic exploration 31
Electrical surveying 4o
Seismogeological characteristics of the cross-section 51
Results of seismic exploration 6o
Industrial geophysical exploration 68
The Baykal-type depressiong 74
The Selenginskaya depression 74
Physical characteristics of rocks of the Selenginskaya
depression 75
Gravimetric and magnetometric surveys 78
Tectonics of the Selenginskaya depression within the
structural system of the Baykallakaya mountainous region 84
Outlook for gas and oil-bearing possibilities and the ba-
sic trend in exploration 88
Card 3/4

Efficacy (Cont.) SOV/2544
Depressions of Western Zabaykallye go
The Zeye-Bureinskaya depression 95
Rational Complex and Basic Premises of a Perspective Plan of
Geophysical Exploration 105
Basic Trends of Geophysical Works in Eastern Siberia 110
Conclusion 112
Bibliography 113
AVAILABLE: Library of Congress
MM/jb
Card 4/4 11-2-59

MANDEL-BAUM,-M. Mo
Cand Geol-Min Sci - (diss) "Geological structure and petroleum-
bearing potential of the zone of Upper Angarskiy dislocations."
Moscow, 1961. 17 pp; (Academy of Sciences USSR, Siberian Division,
Main Board of Geology RSFSR, Irkutsk State Univ "Vostsibnefte-
geofizika" ); 200 copies; price not given; list of author's works
at end of text; (KL, 5-61 sup, 180)

TKALICH, S.M.; MINEYNV, I.K., glavnyy red.; RYABENKO, V.Ye., zam. glavnogo
red.; TUMOLISKIY, L.M., zam. glavnogo red.; KURIYLNOV, F.K.., otv.
zav vypusk; BASSOLITSYN, Ye.P., red.; BLDINIKOV, I.I., red.; DAUKSHO,
Yu.ye., red.; DZINKAS, Yu.K., red.; ZHAMOV, M.A., red.; ZAVALTISHIN,
M.A., red.; M.M., red.; MATS, V.D., red.; MALETOV, P.I.
red.; NOMOKONOVA, N., rea-.; NOSEK, A.'@'., red.; SERD, A.I., red.;
SEMENYUK, V.D., red.; TAYEVSKIY, V.M., red.; TIKEONOV, V.L., red.;
TROFLMUK, I.N., red.; TOMILCIVSKAYA, M.V., red.; FOMIN, N.I., red.;
SHAMES, P.I.., red.; TROSHANIN. Ye.I., tekhn. red.
(Biogeochemical anomalies and their interpretation.] Biogeo-
khimicheskie anomalii i ikh interpretatsiia. Irkutsk, 1961.
39 p. (Materialy po geologii i poleznym iskopaemym Irkutskoi
oblasti no.3). (MIRA 17:1)

MANDELIBAUM, M.R.
Geolca and the oil and gas potential of the zone of the upper
Angara dislocations. Geofis. isdl. i probl. neftegaz. iuga Sib.
plat. no.2:3-108 162. (@MtA 15:8)
(Angara Valley-Petroleum geology)
(Angara Valley-Gas, Natural-Geology)

PRITULA, Yu. A.; GRIGORIYEV, V. M.; M-DELIBALIM., M. M.; MIKU-TSKIY, S. F.;
f4DKSHANTSEV., K. B.; SOKOLOV, D. S.
"Oil andk@Ls deposits of the Siberian Platform."
report submitted for 22nd Sess, Intl Geological Cong, New Delhi, 14-2@2 De-@
1964.

TROFIMIJK, A.A.; VASILIYEV, V.G.; KARASEV, I.P.; KOSOROTOV, S.P.;
MANDEL113AUM M.M.; 14USTAFINOV, A.N. [deceased); SAMSONOV, V.V.
Basic problems of the prospecting in the Markovo oil field in
Eastern Siberia. Geol. nefti i gaza 8 no. 1:15-20 Ja 164.
(MIRA 17:5)
1. Sibirskoye otdeleniye AN SSSR, Vsesoyuznyy nauchno-issledovatell-
skiy institut prirodnogo gaza, Gosudarstvennyy trest po geologicheskim
izyskaniyam na neft' v Vostochnoy Sibirl i Institut geologii i
razrabotki goryuchikh iskopayemykh AN SSSR.

1@%WR, V.B.; SMISMOV, V.V.
Recent data on the oil and gas potEntial of the Irkutsk -am-
phitheatre. Neftegaz. geol. i geofiz. no.10-.9-11 164
OKIRA 18:1)
1. Gosudarstvennyy trest po geologicheskim izyskaniyam na neft'
v Vostochnoy Sibiri i trest. "Vos'wsibneftegeofizika".

.7-7777 @.7-
9S37- g-
f "c an, Loiier-', wJok m i,
N@azk
urasslc'@Ad& Cretaidedue--de- A lteihl@i@liic
poaits.@,--Gms-- don, quad
i 4d-t- bi i i el- i iiii: @ i h- - e-l.:'--lf':d- d' P@"'
130" qynecltse@: an re-Vorkho
cks, hiii@ S:ib4riaW-: ar e n@@ ar
id-;-Vas'.7' scove r h
df L-d thOse% rcicka 'in the dout
t
a ritidt
hado-":2 On a .
-22ft*64/-@.

ACC NRI ATU'023377 SOURCE COW: un/0000/65/000/000/0118/0123
AUTHOR: Kondrashov. V. A. ; Mandel'baum, M, M, ; Puzyrev, N. N. ; Surkov., 1-.. S.
ORG: none
TITLE: Technique of regional seismic investigations in Siberian plaiform areas
SOURCE: International Geological Congress, 22d, New Delhi, 1964. Geplogicheskiye
rezul'taty prikladnoy geofiziki (Geological results of applied geophynics); doklady
sovetskikh geologov, problema 2. Moscow, Izd-vo Nedra, 1965, 118-123
TOPIC TAGS: seismoloV7, platform area, sedimentary cover,
seismic- prospecting
AB8TRACT:' Regional seismic investigations conducted in platform areas*-6f Si@eria
for the purpose of studying principal features of the deep structure are. described.
Tfiis work was performed mainly in connection with oil and gas prospecting in the
area. To study the folded basement a special technique of single and-linear head-
wave soundings has been developed which makes it possible to inveatigate forest-
covered areas. The results of the field work have revealed oome featuren of the
basement structure which had previously riot been detected, including differentiation
of -the basement into layers according to their elastic properties. T@e* sedimentary
cover is investigated primarily IV the-reflection method in its various modifications.

ACC NR:
AT6028377
For regional investigations, wide use is mJe of single reflection soundings which
are a*pplied on a wide scale in the west Siberian lowland. Using this technique
ift area of nearly 50,000 km2 has been surveyed. Also widely used is a-tecbnique of
tegional seismic-refLection profiles including profiles along.the river6. These
in@vestigations have resulted in maps and cross-section diagrams vhich'pho%ilclearly
the effectiveness of the survey. Orig. art. has: 2 figures.
SUB CODE- o8/ suBm DATE: o6jan65
2/2

BELYAYTEV, A.P., red.; BE&30LITSYl;, Ye.P., red.; BLIMIIKOV, I.I.,
red.; DZlNKAS, Yu.K., red.; ZEXMV, .,,.A., red.;
KOAOVIli, A.V., red.; K! F.K., red.;
red.; NAILE-1-OV, F.I., red.; V.Ye., red.;
SAVINSKIY, K.A., red.; _'DW, A.I., red.; SEMMUK, V.D.,
red.;.-@ TTA.4MIOSKITY, L.Y., red.; TIKJ!CNGV, V.L., red.;
T OVSF
FDUK, F.I., 'Ay F
rtW A 1'.V. , red.; FOMB:,
N.I., red.B-X-..;:, Y,,.K., vt,('.
P@ecent data on the geoloQ,,, petroleum, porential.9, and
1.
mineral resources of Irkutsk Province) liovye d,-.rmye po
geologii, neftennono,-0 i polezrjym 1,-.kopaeiWm Irkutskoi
oblasti. Moskva, Nedra, 19r'_4. 278 p. 17:8)
1. Russia (1917- Glavnoye Lipravleniye geologii
i okhrany nedr. Irkut.i"Koye pr!(_--.)lo,r,,ichvskoye upr,:vleniye.

VOROPINOV, V.S.; KENZINA, V.L.; ODINTSOV, M.M., otv. red.; KARASEV,
I.P.,, red.; KUZNETSOV, M.F., red.; IAJWDEL"BAW P.M., red.;
d.; M"i, N.I.,
NEEZABYTOVSKAYA, I.A., red.; NOSEK,-A-.7@., rem 7170i
red.
[Geological studies of the U.S.S.R.] Geologicheskaia izu-
chennost' SSSR. Moskva, Nauka. Vol.24. No.l. 1965. 177 p.
(MIRA 18:9)

AUTHOR. Mandel'baum2_q,L._ SOV/115-58-1-44/50
TITLE: The Committee's Checking Organs Must Improve Their Work
(Uluchshit' deyatellnost' poverochnykh organov Komiteta)
PERIODICAL: Izmeritellnaya tekhnikag 1958, Nr 1, pp 89 - 90 (USSR)
ABSTRACT: The State Control Laboratories for Measurements, which are
subordinated to the Committee of Standards, Measures and
Measuring Devices, are supposed to perform the following
duties: supervise the departmental supervision organs;
check on the conformity to standards and standard speci-
fications, the correctness of measurements of fuels and
lubricants; study new designs of instruments in use;
supervise the work of instrument-building and repair
plants. In practiceg howeverg their possibilities to do
this work are limited. In the Azerbaydzhan SSR, for ex-
ample, 809% of the work time will be spent for state check-
Card 1/2 ing of instruments, and 10% will go for checking the con-

The Committee's Checking Organs Must improve Their dork
SOV/115-58-1-44/50
dition and accuracy of measuring devices and the conformity
to standards and standard speo-ifications. The main concern
of the personnel seems to be the fulfilment of the state
fee-collecting plan. The author thinks that no productive
work can be expected from the State Control Laboratories
and suggests practical organizatory measures to change
the situation.
1. Standardization 2. N-.@agwement --Stand ard s3. instruments--De-
sign 4. Ins trurkents-4/ja Intenance 5. 1nStrumPnts-._--nsj)ectj0n
Card 2/2

MANDELIBAUM, S*L.
Conference an standardization in Baku. Standartizatsiia 29 no-3:
54 Mr 165. (MIRA 18:5)

IBAU14f YA. A.
Cand Chem Sci
Dissertationt "Synthesis of Certain Effective Insecticides." 21/h/50
Scientific Inst of Fertilizers and Insectofungicides, 14inistr-y of Chemical
Industry USSR
80 Vecheryaya Moskva
Surn 71

C,@
estas of
ph=
Va. Blandelixum,
And
P. V. Popiv. DoWy AW.-Auk"S.5-S.'jr. it ,
4M5-7(l9aG).-Tbe following esten were prepil. by un-
OW Wmk-ibed Methods gad wtm tested apfint
@pAisfdk0&GdCdkMdrdjr4xm,". Thefigunminparem-
them ladicate the mim, permup content of tM estu
lWo hime" kill when used in dusting Powder,
be two WCC'-' r-P- -0tN
I t W414.0)^O&le@.
m. 145-7* (LIS-2.A, f. Pt Anakiff, IM)".. M.
JL%-T' (0-1-0-25; 0.1-0.25); Pr analog, ChISI-C, rn. jr2,3-
5. 08@0 96-7* (-; 5-0); Bu
in. 57-8' (m-03'% OH).P=
anal - W& -01
(.111 . 81-2-
d'-' I-MI8, -18
So d l"l, OV
79c' is' I Mt, Ott
.3; NP-uitF0 AnA1011- P ' - '
(0 (-; 5.0 n,,log W) d-- 1.27(M. *V
W
IM74 (0.0124).~-5""11*CI'12-0.(ii);"'i:N%CJ'-OPS-
65%. d:I 1.21M, sit dAm-Pr
(Opr) F. . a 5 6). di-Hu
.log. d-- I AV I.M78 (-. -
analog, 27%. dl.* I. KV t.5311. (-', 5-0): (P-Ov
(JIMM 11); above 10);
(%fe0)3pS (IM-2.5; (rr-to)-PS (1 -2.5; (3.5
DDT (o- 5.5; um 5.5); benzene bC%AChlGride
7.0; 3.5-7.01. TlW -tiviti, Of sit and Pt tstCr4 is noted
Im"t putent; W4- art
wW the p.oitru dedvi- am ast active;
least @ffective. Dialkylmyl deriv- a" In
07M liquids distinable only in bigh vamum
tbese 0. M. Ke-loupoil

looMELIBAU14, Ya. A.; SVMITSITSKIY, Ye. I.; MLINIKOV, N. N.
"The New Insecticide Diethyl-4-nitrophenylthiophosphate OllulT.-I-00),
Khimicheskaya Promyshlennost', No 9, 1952, Pp 1-3.

MANDEL'BALAI, YA. A.
N. N. SILL'NIKOV, YA. A. MANI)EL'BALBI and I. L. VLADIMIROVA, Fertilizer and Insectofuirgi-
cide Institute in Moscow
"Organic Insectofungicides. XII. Synthesis of Mixed Esters of Phosphoric and Thiophos-
phoric Acids", Zhur Obshchel 1(him 23, 429-32 and 433-G (1953)
All of the compounds listed in the paper are far below the insecticidal action of Parathion,
which is just about the US standard at this current time. While it does not seem likely
that these compounds are war agents, it actually cannot be said with certainty whether
or not they are sufficiently toxic to humans to cause death or disability. The only
Soviet chemical work dealing with dompounds that have biological action analogous to the
US and UK published material on the f1porophosphates (that is, anti-cholinesterase action)
is the published research by Mel'nikov and co-workers on the synthesis and insecticidal
properties of some esters of various phosphoric acids. As I have said before. the real
significance of this type of work lies in the fact that It deals with anti-cholinesterases.
Nlel'nikov's published research in 1950 appearing in Doklady Akad Nauk SSSR 71, 485-7 is
the first acknowledgment in the Soviet press of compounds related to Parathion, that is
to say, compounds that are organophosphorous anti-chollnesterases.
Digested translation of article available
SO: B-67003

GALA3MINA, '.11. L.; UADIVJROV;*@, I. L.; Ya. A.;
In sccti f up,;" 5
Organic inzectifujus. Part 13. 3ynthesis ol,' r,,Axu,:d f-, of pi.oci:t;orlC -i@l
U.iopl,.osphoric acids containine tl.e olum sub-,Utuents in L"I.e
radical. Zhur. oL. Ichim. 23, No. '@, 19,513.
Monthiy L@@ of Russian Accez@sions, Lib 'ary of Conres,;, June '-@,5j. ;Inc'..

77-
h;@lthidph6i@

7 m
. and MEMINIKOV, N. N.
IlPreparation of Dialkyl Chlorothiophosphates"
paper presented at Nn First Conference of Phosphorous Compounds, Kazan,
8-10 Dee 56
SO: B-3,084, 841

- ------- ---
A4

-az

BAKANDVA, Z.H.;,KANDELIBAum Ya A - KM'NIKOV, N.N.
- =r, 0- 1 Z@l @
Organic Insectofungicides. Part 22. Interaction of lialkylchloro-
tblopboapbates witb )b-nitropbanol in the presence of pyridine
bydrochloride. Zbur.ob.kbim. 26 no.9:2575-2577 S 156. (MLRA 9:11)
(Thiophospbatas) (Nitrophenol)

KMELOBAU14, Ya.A.; MINIKOV, U.N.; WKAKINA, V.I.
Organic Insectofungicides. Part 25. Synthesis of mixed esters
of tbiopbosphoric acid. Zhur.ob.khtm. 26 no.9:2581-2583 8 156.
(MLR& 9:11)
(Thiophosphates)

jt
W @Z@imi
cow
r.; 4-01 1, 6Ver, g -lay ---4- a,., p4 115v",

ni,p -mr
Ismoled wid
er-W-and tr6ted ollowly umi-P
Tl.
'a- MOP
t product UL ns f)
jugs ls added 0,05 Wflivi,and a little CC!
-over in(,'
NY
moug ab
Pot Istal

_71
:@H
t
Hit
t: 3,17 1:-, a :C 4. --5:1pO"6 -@Liuv
ded ip-acc; tile 1-9gt
b 1 don of IA-Tn6l_@ (E
vCS Me ;=Ten
ck- f-TI
P(k,k UWCU' tit',
-e- to 340
in
Jt4 all. Pbs@M_Glf.
:-ris_C7 to:-3 a &r vv c ry N, is pero"Tated thm tv ihc-:
ug.
t.L"i 45@7' 314.5hra-un6l IMewAutibri 5-cps, dien the,
riuU 40 min. to rmcw@e re-sidual IICI at
perco atim is eoutii
ith -fEtah-mj@'
-ttereoidueis tmat-xLovurA& iuht@ %v
IL
K. Ug C1.50 ad un. b
p
_kfi
after Al
50'; cooled aud
(gtO)'-j?SCI s.: 12% @_Jj
tl"-Zi hut@
4@_
qj _@66
r
Q7
fir prepti. v
-Tin cal,.td, ti. of MvOil Lt wklf!@Ftu, V:@@
hint. _@ v
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M
o -66_@ the, -tI
smr E---- t - -
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dild- -with 11:1G. aud 44ktu _ILI@ Luz
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-
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@m@ftu@ ado li:
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.
(11), --irldilir. rr,15@d- da- I @-hoiphorcvh'Wniz: aAd. Ut

lo,@k sevena, wcehm A hl@htr degn@p. of p
b"? oi rel@tior- ar@d
'
-
-
--qni
dryi.&I-by m
o@ a hyd@
d-is.-Cived in bonaeno-and chromatog-rapl-cd an c-,cfivateill A47@1-
Th -I @Wororaa' kirj- anhydride m2@ viras obLa [ne-d :3y chic-rinaf im of
l
ma
lok anhylridi@ at
al me
'
'
'
-
-
thiml@s with P-nl-@Opllcnol In oi-pv-dine
h-drmhforLN

I
MANDEV BAUM, YA. A. , MRL NIUIF Im. Ya. V. Samaylov. Moscow)
"On the Production of Dialky1chlorothiophosphates" (0 poluchenii dialkilkhlortio-
fosfatov)
-Chemistry- and Uces of
(Khirliya i primenoniyE f c rorgant ch n i,iy),
ed c
TrUdY of First Conferenc,-, bece:!bc" Y
PP - Published by K K,-.zzn,
A@@ FT@Zl),, jt@5'
7
185-193,

,@akv N.- -t -

MELINIIKOV, U.N.; MANIOLIBAUM, Ya.A.; SVENTSITSKIY, Ye.l.; R&MOVA, Z.M.
On organic insectofungicides. Part 27: New method for the
preparation of esters of chlfwothiophosphoric acid. Zhur.ob.khim.
27 no.7:1908-1910 J'l '57. (MIRA 10:10)
l.NauchW7 institut po udobreniyam i ineektofungisidam.
(Insecticides) (Chlorothiophosphoric acids)

/V 1) -.-r @- 'I /V1 I @ /) , /4 1
AUTHORS: Mellnikov, N. ;N., i,,ande1'bau,-;, Ya. 7)-2- 1,'-
Lomakina, V. I., --
TITLE. Ur-,--inic Insecticides and Fungicides
(Iz oblasti organicheskikh insektofull'itsi(IOV) A New i;i@thod for tile 11ro-
duction of wixec Lstere of Thiophosphoric Acid ( XXXI. --ov."i
sposob polucheniya s;.;e8hunnykh efirov tiofosfornoy kislotj)
PERIODICAL: Zhurnal Obahchey Khiaiii, 1958, Yol. 28, Nr 2, pp. 476-47i
(US,9R)
ABSTRACT: The reaction between aromatic diazocouipounds with salts of the
dialkylthiophosphoric acid was investigated and mixed ethcrs of
thiophosphoric acid were obtained in acid-aqueous solition Y,ith
a yield of up to 50',-. Uere schematically seen an is(;ner @i:ixtare
of the tautomers is formed:
(RO //S AnD (RO) P4'@- OAr + 11 1+ Va.@
)21"oNa 2 2 2
(RO ) 2 P':@)S Na + Ar 112X 2IfYAr + 2 + illax
In the prescnt paper tht equilibrium of the tauto@ers of tne
Card 1/2 dialkylthiophosphates is moved to the side of the thiolfor-i, in

Organic Insecticides and Fungicides 7@-2-, 1/611
A Nev Yethod for the Production of Mixed Esters of Thiophostphoric Acid
accordance with L.I. Kabachnik, S.T. Ioffe and T.A. Iaastrjukova
(reference 4), since 0,0-dialkyl-6-aryl-thio_.hospiaates and in
only one case thiordsomers predorairiate in the reaction :)rokLict.
The results obtained show that the quantity ratio of the iso:iers
is more influenced by the attacking reagent than by the reaction
medium. The working methods as well as tables of the properties
of eaters are taiven. There are 1 table, and ', Slavic ref@ri-nces.
ASSOCIATIONt Scientific Institute for Fertilizers,, Insecticides and Gungicides
(Nauchnyy institat po udobreniya:a i insektafungitsidai@i)
SUBMITTED: January 16, 1957
AVAILA3LE: 'library of Congress
Card 2/2

AUTHORS*" Mandelfbaum, Ya, A., Meltnikov, N. N., Petrova, N. I. 79-2-L2/64
TITLE: Organic Insecticides and Flunricides( iz
6blabti organiched-kikh,inrelctofungitsidov)
XXXII. The Synthesis of Some 1-ixed Ethers of ThiophosphoriC Acid
(XXXII. Sintez nekotorykh smeshannykh efirov tiofosfornoy kisloty).
PERIODICAL: Zhurnal Obshchey Khimii, 1958, Vol. 28, @.Tr 2, pp. 479-48o (MR).
ABSTRACT: The reaction between mixed dialkylchlorthiophosphate and methanol,
ethanol resp. was investigated in the presence of caustic soda. It
is found that the corresponding trialkylthiophosphates are obtained
with good yields (7o-940/o) in the reaction. The reaction can schema=
tically be represented as follows!
HO PSCJ- + R"CH + NaCH -+ HO >PSOR" + NaC1 +
H20
RIO RfO
The major part of the compounds obtained have hitherto not yet been
mentioned in technical literature. The specific properties of the ob=
tained compou;-ids as well as the preparation process are aiven.
There are 1 table, and 3 Slavic references.
Card 1/9

Organic Insecticides a-nd Rmgcides 79-2-.42/64
0
ASS IATION: Scientific Institute for Fertilizers,,Iusecticides and Amgicides
?,?WUchnYY institut po udobreniyam i inseirtoftgitsidam).
SUBMITTED: January 16, 1957.
AVAILABLE'. Library of Congress.
Card 2/2

MELIKIKOT, U.N.; K-AN=!BAUM. Ya.A.- BAKANOVA, Z.H.
Organic insecti- and fungicides. Part 34; New synthsais of trialk-yl-
phoffphites, Zhur.ob.lchim. 28 no.9:2473-2474 S 058. (MIRA 11:11)
(Phosphitem)

AUTHORS: 9 @ -59/74
@ndellbaum, Ya. A., Mellnikov, L. SOV/79-20-1
TITLE: On the Field of' Organic Insecticides(Iz oble-sti organicheskikh
insektofungitsidov) XXXVII. S@-rithesis of Several 11aixed
Thio- and Dithiophosphoric Acids (XXXVII. Sintez nekotorykh
smeshannykh efirov tio- i ditiofosfornykh kislot)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, pp 283-285 (USSR)
ABSTIUCT: Besides thio- and dithiophosphates of the general formula
X
P C.--'X(CH
SRI (I) used against plant pe3ts, compounds
(RO)
)
2
2
n
of the general formula
(RO S R: I
)2p!'!@ SCYOt<
have come into use during the last years (Refs 1, 2). The
so-called "acetyl urea" (Refs 3, 4) may serve as an example
for the compounds of this kind investigated in the USSR. While
investigating how insectidide activity of organo-phosphorus

Card 1/2 compounds depended on the@ir structure, and in the search for
new insecticides, harmless to warm-blooded animals and humans,

On the Field of Organic Insecticides. SOV/79-29-1-59/74
XXXVII. Synthesib 6f Several Mixed Tbio- and Dithiophospboric Acids
the authors particularly directed their efforts towards the
synthesis of the mixed esters of thio- and dithiophosphoric
acids of the general formulas (III),(IV), and (V). It uas
carried out by the reaction of diethyl-thio- and diethyl-
dithiophosphates with the corresponding monochloro acetic and
monochloro thioacetic acid on heating the reaction solution.
As expected, the thionic isomers of the thiophosphates were
obtained (Refs 5, 6)(Table). Activity against insects did not
quite come up to expectations compared to
0,0-diethyl-0,4-nitro-phenyl thiophosphate.
There are 1 table and 6 references, 4 of which ai4t@ Soviet.
ASSOCIATIOV: Nauchnyy institut po udobreniyam i insektofungitsi-dam
(Scientific Institute for Fertilizers and Insectifungicides)
SUBMITTED: November 20, 1957
Card 2,12

SOV/79-29-2-35/71-1
AUTHORS: Mellnikov, N. N., Mandelfbaum,_Xgl. A., Zaks, P. G.
TITLE: On the Field of Organic Insectofungicides (Iz ob-,asti orgar.--',-
cheskikh insektofungitsidov). XXXVIII. On the Reactii@)n of
Thiophosphorus Trichloride and the Alkyl. Dichloro Thiophosphate-3
With Alcohols (XXXVIII. 0 vzaimodeystvii tictrekhkh1cristcgc,
fosfora i alkildikhlortiofosfatov so spirtami)
PERIODICAL: Zhurnal obshchey khimi-J, 1959, Vol 29, Nr 2, pp 522-526 (USSR)
ABSTRACT: In continuation of previous papers published by Mellniko;r and
coworkers (Refs 1-11) the authors investigated the reaction
of thiophosphorus trichloride and the alkyl dichloro thio-
phosphates with alcohols under various conditions. They obtained
various products according to the conditions of reaction and
the ratio of the reacting compounds. On the reaction of 2 mn!5
ethyl alcohol with I mol thiophosphorus trichlorlde the ethy:
dichloro thiophosphate (45-50%) and ethyl thiophosphoric ac-,ds
(20%) are obtained at 40-500. The reaction of I mol tiii@-
phosphorus trichloride with 4 mols ethyl alcohol at 50-601 'Leads
to a mixture of esters (46-48%) which consists of 80% ethyl-
Card 1/3 dichloro thiophosphate and 20% diethyl-chloro thiophosphate.

SOV/79 --29-2- 35/7",
On the Field of Organic Insectofungicides. XXXVIII. On the Reaction of Thao-
phosphorus Trichloride and the &lkyl Dichloro Thiophoaph@ates Wltn 11_-cn@_s
however, it is possible to synthesize an almost pure diet@,yl-
chloro thiophosphate in a yield of only 10% if it is heated
for a while in a boiling water bath. Besides chloro thl-
phosphates also ethyl thiophosphoric acids and ethyl -.h1oride
are formed under the above-mentioned conditions. The reactions
of thiophosphorus trichloride with alcohols and their succ,-s-
sion can be represented by the schemes (3)-(7) ment'oned.
According to these schemes the authors arrived at the --on..
clusion that gocd yields of dialky'l chloro thi-,phospha-.es -an
be obtained on sufficient dilution of the reaction med'-u-M w_'th
alcohol. This assumption was fully confirmed by experiments
(Table !)'. Much better yields of dialkyl chloro thiophosphate,;
are obtained by reaction of alcohols with alkyl' diohlorc, @hicj-
phosphates, in the course of which methyl alcohol offers
highest yield (Table 2). The reaction of methyl alcoho- with
thiophosphorus trichloride or alkyl dichloro thiophosphate.
leads to trialkyl thiophosphates, however only with small
yields (Table 3). Therefcre, thiophosphorus trichloride and
alkyl dichicro thiophosphates react like typical chloric an-
Card 2/3 hydrides, similar to acid halides of the other inorganic and

SOV@/-70-- 29 -2 - 5:@
On the Field of Organic Inse--tofungicides. XXXVIII. O-n the
phosphorus Trichloride and the Alkyl Dichloro Thiophosphates With Alcoh-c-18
organic acids. There are 3 tables and 12 references, 9 -f which
are Soviet.
ASSOCIATION: Nauchnyy institut po udobreniyam i insektofungitsi-dam
(Scientific Institute of Fertilizers and Insectofunginides)
SUBMITTED: December 24, 1957
Card 3/3

5 (3)
AUT--ORS: Mandellbaum, Ya. A., '-!ellnikov, 'T. N., SOV/7 9 4- 2 5/-7 -7
TITLE- From tile Field of Organic Insecticides and Fungicides
(Tz oblasti oreanicheskikh insektofungitsidov). XLI. On "he
Reaction of Dialkyl-chloro-thiophosphates and
Thiophosphorus-trichloride *-7ith Phenols in the Presence of
Tertiary Amines (XLI. 0 vzaimodoystvii dialkilkhlorti0fL03f:.t0V
i tiotrekhkhloristogo fosfora s fenolami v prisutstvii
tretichnykh aminov) .
PERIODICAL: @hurnal obshchey khimii, 1959, Vol 29; Nr 4,
pP 1149-1151 (USSR)
ABSTT1ACT: In connection with the papers mentioned in the references
1-5 theauthors especially investigated the reactions of
dialkyl-chloro-thiophosphates with phenols in the presence
of tertiary amines. This reaction proceeded already at room
temperature in good yields and produced the corresponding
diBlk.y-aryl-thiophosphates. The solvents were of no
importance, and the reaction proceeded also without solvents,
but in this case the stirring of the reaction mixture is
dard 1/3 difficult owing to the crystallization of ammonium chloride.

From the Field of Organic Insecticides and SOV/79-29-11-25/77
Fungicides. XLI. On the Reaction of Dialkyl-chloro-thiophosphates and
Thiophosphorus-trichloride With Phenols in the Presence of Tertiary Amineo
Dialkyl-aryl-thiophosphates are obtainod in good yield also
in alcoholic soliltion, which indicates that the reaction with
phenols prot@t-,@@ds inore rapidly than with alcoholq. The authors
invft-tigated the reaction of lialkyl-chloro-thiophosphates
with phenole in the presence of triethyl amine. 0,C-dialkyl-
0-aryl thiophosphates were found to ro3ult. The mechanism of
the formation of dialkyl-aryl-thiophosphates from dialkyl-
chloro-thiophosphates and phenols in the pre3ence of tertiary
amines can be best explained in the following way: There is
an exchange reaction between amine phenolate and dialkyl-
,;chloro-thiophosphate, yielding the hydrogen chloride of the
'anine and of dialkyl-aryl-thiophosphate. On the reaction of
thenols with thiophosphorus trichloride in the presence of
triethylamine aryl-dichloro-thiophosphates were obtained in
sufficient yield. There are 1 table and 5 references, 4 of
which are Soviet.
Card 2/3

From the Field of Orgrinic Innecticide3 and 3OV/7q-2Ii-/,-25/77
Fungicides. XLI. On the Reaction of Dialkyl-ohloro-thiophospliptes and
Thiophosphorus-trichloride With Ph6nols in the Presence of Tertiary fi..Ln@:B
ASSOCIATIOJ: Nauchnyy institut po ulobreniyam I Insektofungitsidam
(Scientific Instituto of Fertilizers, Insucticide3 and
Fungicides)
SUBMITTED: M-4rch 12,195@;
Card 3/3

ffANDEL1BAU14,Y-9-A-;- LOMAKINA, V.I.
Investigation and development cf new preparations repelling
bloodsucking insects. [Trudy] NIUIF no.164: 159.
(KRA 15:5)
(Insect baits and repellents)

MRLtNIKOV, N.N.; MANDEL,@BAUM,. YtL.A.; SHVETSOVA, K.D.; BAKANuVA, Z.M.
LOMAKINW-,-V-.-I-.; ZAKS, MILISHTEM, I.M.; POPOV, P.V.;
POKROVSKIY, Ye.A.; BOCHAROVA, L.P.; SEDRH, A.S.; UKRADRTS, N.S.
Improved technology for producing thiophos, metaphos, chlorophos
and other phosphorus organic insecticides and investigation of
new insecticides and fungicides derived from the esters of
phosphoric acids. [Trudy] NIUIF no.164:11-14 '59. NIRA 15:5)
(Insecticides) (Fungicides)

Ya.A., kand.1&.1michoskikh PavJ:; SITOUTOW, V.14, kand.
me&--fs-i-ns-E-" nauk; LOI-IAMU, V.I.
Chorucal iuact repellents. Zhur. TITO 5 no. 3:307-312 1W.
14:2)
(Insect baits and repel-Lents)

HANDEL1BMx-TA,,-_ SAFtYANOVAt V.M.
Diethylamide of metatoluic acid, and effective repellent
against blood-oucking insects and ticks. W.paraz.i
bol. 29 no.5:570-575 S-0 160, 13:12)
1. Is laboraturii organicheskikh inBektofungitsidm Naucbno-
isoledovateliskogo instituta udobreniy i insektofungitaido7
(dir. instituta - prof,-K.N. Malin, zav. laboratoriey - prof.
N.N. Mellnikov) i otde;a infektoiy o prik-odnoy ochagovosttyu
Instituta opidemiologii i mikrobiologii Imeni N.F. Gamalei
AMN SSSR (dir. instituta - prof. S.N. Muromtsevp zav. otdolom -
prof. P.A.Petrishcheva).
(INSECT BAITS AND Mqajmm) (TOLUAMIER)

5.1320,5.3630 77380
SOV/79-30-1-4i/78
AUTHORS: Mandellbaum, Ya. A.,-M_ellnikov, N. N., Bakanova, Z. M.
TITLE: Concerning Organic Pesticides. LII. Concerning the
Reaction of Aryl-Dichlorothiophosphates With Magnesium
Ethoxide
PERIODICALt. Zhurnal obshchey khimii, 196o, Vol 30, Nr 1, pp 194-
197 (USSR)
ABSTRACT: The reaction of aryl dichlorothiophosphates with
magnesium ethoxide was investigated with the purpos-
of obtaining some new pesticides, and also in orde.
to study the relationship between the reactivity an-
the structure of the chlorothiophosphoric acid deri-
vatives. The reaction can proceed according to
(1), (2), and (3), depending on the ratio of the
reagents, the temperature of the reaction, and the
time of reaction.
Card 1/4

Concerning Organic Pesticides. LII. 77380
Concerning the Reaction of Aryl- SOV/79-30-1-41/78
Dichlorothiophosphates With Magnesium
Ethoxide 2 ArOPSCII + (C2H50)2M9 ---w 2 ArO PSCI + IWI,
C2H5O>
2 ArO
" PSCI + (C2H50)qHg ---b- 2 Ar0PS(0CjH5)2 + higCI2 (2)
CSH,O/
2 AroPS(0CjH5)2 + (CIH50)jMg - 2 (C2H5O)3PS + (Ar0)2M9I (3)
Aryl.dichlorotbiophosphates and magnesium ethoxide
taken in stoichiometric amounts gave chiefly alkyl ar-yl
chlorothlophosphates or the corresponding diethyl aryl
thiophosphates. Tran8esterificatipn (Formula 3)
occurred only with large excess of magnesium ethoxide
and on prolonged heating. Accordingly, 0.1 mole
phenyl dichlorothiophosphate and 0.05 mole magnesium
ethoxide on heating for 3.5 hr gave O-eth
%1 0-phenyl
chlorothiophosphate (yield 64%; bp 95-100 C/0.2 mm).
The same reagents taken in amounts of 0.05 mole and
0.1 mole, respectively, gave on heating for 7 to 17 hr
U
0,0-diethy; 0 henyl thiophosphate yield 82-91%;
Card 2/4 bp 120-122 C70-8 nun). 0.1 Mole 2 ,@,5-trlchlorQphenyl

Organic Pesticides. LII. 77380
Concerning the Reaction of Aryl- S
Dichlorothiophosphates With Magnesium
Ethoxide
d1chlorothiophosphate and 0.3 mole magnesium ethoxide
on heating at 65-700 C for 18 hr gave 0,0-diethyl 0-2,
4,5-trichlorophenyl thiophosphate (yield 78%; bp 1300 C/
0.13 mm); also, 2,4,5-trllchlorophenol (yield 13%;
mp 620 C), and triethyl phosphate (yield 15%). Under
similar conditions, 0.1 mole 4-nitrophenyl dichloro-
thiophosphate and 0,3 mole magnesium ethoxide gave 0,0-
diethyl-0,4-nitro henyl thiophosphate (yield 40%; bp
156-1580 C/0.3 Z; also, p-nitrophenol (yield 28%;
mp 1120 C), and 0,0,0-triethyl thiophosphate (yield 30%;
bp 51-520 C/0.3 mm). There are 10 references, 2 U.S.,
I U.K., 7 Soviet. The U.S. and U.K. references are:
H. D. Orloff, C. J. Worrel, F. X. Markley, J. Am.
Cherr. Soc., 80, 727 (1958); R, F. Hudson, L. Keoy,
J. Chem. Soc., 1953, 2463: T. R. Fukuto, R. L. Metcalf,
J. Agr. Food Chem., 4, 930 (1956).
Card q Al

Concerning Organic Pesticides. LII.
Concernintr the Reaction of Aryl-
Dichlorothiophosphates With Magnesium
Ethoxide
ASSOCIATION:
SUBMITTED:
77380
SOT,[//-,79- --? G, - 1 - @! 1, /7 8
Scientific Institute for Fertilizers and Pestic@@des
(Naucimyyyinstitut po udobveniyam. i inselctof-angillsidam)
JanuarY 5, 1959
Card 4/4

UNIMICH, A.G.; ZAKS, P.G.; HAMMLINLUK, Ya.A.; MELINZOV, N.N.
Organic insectofuiigicides. Part 55: Wathesis of some
alkylsa7lthlophosphoric acid hydrazides. Zhur.ob.khin.
30 lio-7:2317-2319 JI '60. (HM 13:7)
1. Nauchnyy inatitut po udobreniyam i insektofungitaidam. Moscow.
(Hydrpsides) (Phosphorothioic acid)

ROSLIVTSEVAp S.A.; YANDELIBAUMp Xa.A.; POPOV, P.V.
New insecticides acting on cont4at. Mum, prom* no.10:14-15 0 161.
(MIRA 15:2)
(Insacticides)

MANDELIBAMI Ya A.; KHMMYANs Kh.Ye.
Diethylamidg of the metatoluic acid (MTA preparation) and effedtive
repellent. Khim. prom no.lOs22-26 0 161. WFA l5s2)
iInsectioides)

MELINIKOV, N.N.,-_MANDELIBAUM., Ya.A.; WMAKINA, V.I.
Organic insectofungicides. Part 59t bvnthesis of certain deriva-
tives of dtalkoxyphosphonolmoplonic., butyric, and toluic acids.
Zhur. ob, khim. 31 no,3:849-852 Mr 161. (MMA 14:3)
1. Nauchnny institut po udobreniyam i insektofungisidam imeni
Ya. V, Samoylova.
(Propionic acid) (But7ric acid)(Toluic acid)

MELINIEDV, N.N.; MANDELIBAUM., Ya.A.; L04AKINA, V.I.; LIVSHMS, V-S-
Organic insecticide-tungicides. Zhur.obkhim. 31 no.12:3949-
3953 D 161. (KDU 15:2)
1. Nauchnyy institut po udobreniyam i insektofungitsidem
im. Ya.T. Samoylova (NIUIF)v Moskva.
(Insecticides)
(Acetic acid)
(Phosphorus organic compounds)