SCIENTIFIC ABSTRACT MARGOLIS, L.YA. - MARGOLINA, YU.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001032320004-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

lit-
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uthois t. If. 6 ovic Y~ lis ra
Uylay.31
I hl
e
Tit! atiom zchamsm~for, t 6 atio-m o:C-- CO act
tea ir S
oxid Over.:

SS' 703.' -
ok,~ -AU-
Sk iol/4 47 (Z Apr 5-

AbstraW-
a Uo'n r' acti - of dtiva'WO2,iiai-i'inv~,66iiga~ed-atia
Tha:txi a e on~ GO:- over a
,
"

t emperature of 200_.~a
I l6w
o
stitic -pressur es
w The preparation,
for the AAi6ni.. the -,4-P 't, he" es"t- i1i Ittelf -,are
para ure ~a -nd t prcfd
1

des0k a
6
1 aUL 6UA that the:
is
d d
p4yeis of t
z*d
,
l
~
i~* regardj~pss t presstres~,iatei~chang6s,with:the.
of the lim&:~tes
surfaO -or: the. 1'~aO2_ Od* that thisIsptopia.,-exe. nge is -gDverned by

. ... .. ._th6':Iak of-. first, mg
6cc of CO: v&th KhO dur theirs.
6Ft

rd-aqUon: at~ 2-0- was Tound n6t td -d6p6nd upda. th6 0
he a fttact
'

thel.~ ta
sur ac%.
The exchange wa dUferen ~tha
t

USSR I ~Wk and I ~Englis (192J~
T

T
-Crap
bl b~
a, d;~
9t tation,

-td
Fi
T Of;'-ic USSR -Ifidtitatte- o-
127
6
3
esen
d
Y, k~
cademiciah.
rbe
19

tie

C
I ,
Czenct -of ethwene ox de:
Comm. Of AW In"the pr
'
rated bp~bonx. avavustifina coutatm.
__
- IN. all* of great Interest.- - CO WALS farmed in wt eqttai ex,
'
th --
SGOr
t
t b
id
f
A
H

4 AV

Z. -,Ito
Do kad.
uk
-
h
f tht
64
6
94
k
61
19 en
ox
o
ut
mw
c
e;
from."
biahied train the 41dehyde bzd 20%
the Cot wils a

t-
~ WoC
_Pose o
).
r!T
.
e, Fur
j
(
wo toVuddatelthe-Vo -'rolenf ethylene aside,
ssib 6 ,

ethylene Oxide. The Pjdehy&wRA ambtil.ni

,
_
M-Uttlintamediatt looduct. said tht rtown for Its absente In a. fit
Ott.the Contact sufface tham Was the-ethyrene

On OwItitt of the aimationot tthylcne~ over ox(cres. ~': The

:
-
h-
n
t
i
i Win o"he rates of formatfoux of Mand, t .4.

with
cam put of:
-but ft,vras 1
vldehyde
3
d Its-t
ethylent
-AxIde w
ix
s,
w
t
- '
.
.
,
'
-
-
h
l
f&
h
b
t
k
im
e
-ti
d title conditions Over
ug&'with.Ct&wiis-c*Med.outun ers
A
: mte
r
a 11
qx
,. T
solut
vV
0
et
en
e a
y

a u
V, 'of' ho t 0.5 nim. and a~ temp. of 350*.
a pressuves 2,6 tim jIL dy ,f-+
from the akehyde (acruse-I by
, COI umitfom -The ethyl id -
enc ax c,
-it- ')isibIeA6`_ follow - th
-0twuttf" m0 fm eAvandormatioa of

tE. of the Lddehydej (nonea;X2 I c Pit oz ation.
'

and to ~ crucidate the
In Thus was encoun all 1 -0
terad pie ot ut d f
ct
'
.9t.nitl6jr&tiadihlil*of-diffeiiatr6i(cdon products Data twu (midizing =actions,
U911 ip try.
Pam

ox~&tict~ carried: out witk Jhy~L
Ate 0t$vIC%k

-_
'
'
'
l
~ th
wasconnectedvriththe on e ditio Of e

h contact
-SELO
AIOUS
COMM6IE tO'bOfftieaC :Dat&
*ed tha
ZUrkCC
.
From the L
otopic
bfi.
al eve
c df~~indJo
6i MD
VA
from the
titin
f C6imd Co
ubn
t
liff
fat
6 .
-
-neither the aldehyde. . nor the,ethylene -oxide coo be the
Old
. O
agi
t
It e
ft
A
e
anid-ei~hylene Oxide was caled. - And . 1 chief Intermediate- vrodlkt-of. oxideitl6m of,6=td Aydro_

-
od: the+ hbsence of-
wbons. wid this might.depenci tither
,
,
M from etWene and jtL.LrdS its com-.,, Afable Infermedlati
otodueft & the- ~Vocesajvrnn the
-

~a6c6w of aifdattm ind de_-~:' of compds. not Audied yet, eg.; Acj0j or Me ff.-t
C tI
Orma on
7"
0 dy s. S.

. . . . . . .- - - - - -

L

'held t
hemi.,
Arj Fwo; C a ry"
1/2 40 ---~.2/zr

_MUya ova -.E Elj and Rpgifiskiy', 3 z
larg zae) r

ntl~ The' kinetics of ~'oxidati6n of.:simple unsaturated hydrocarb,
one over
V-- on act
jzv*':AN..SSSR. Otd. khim nauk:6. 95E�-.~965,,.: Nov-.wDep- 1954

'4~wmt v:: --of formation of aldekv~des; carbon moftoxid6 and carbon dioxide

The order
duririI the- oxidatia -6f . j~rjejje over vanadiua contacts is described.
n pro__
ner on of aldeWesj
The. reaction activatibn e gies',necessary. for.1th formati
-00 "dIC.6, Trom' simip'le unsaturatid.,hydrocabbons were determined.. The
an

JLnetic ;f Ae6o~positio'n. and oxidation f ~a etaldeWel overY 'antacts
k
!~was nves
i ~ tigated and, the. activatio energy- of these reactions was ea-

ish'
tabl ed.
lnstit~tidh- Aaaae.. or Scs.. USM., Institut.e.of PhysicaLChemistry,
Submitted Jult24,,1954

Catalyst Suff=e
t as the conen. Of :L
es in =inparban -
3;-~-decream-of 0
D, i R-
.e.'kdim tng--

USSSR/Chemistry - Isotopes 11 Sep 52
14
"The Synthesis of Ethylene Tagged Witb C
E_ L.Ya.
U."
Cn Margolis, B.V. Klimenok, O.A. Golovina, Inst of
Phyz Chem, Acad Sci SSSR
"Dok Ak Nauk SSSR" Vol 86, No 2, PP 313-315
Ethylene, tagged with C14 was prepd by reduc-
ing acetylene at low (10-~ mm) pressures and
at atm pressure using CrC13in HC1. The use of
the latter insures the complete reduction of
acetylene into ethylene. Iarge quantities of
radioactive ethylene are prepd more readily at atm,
pressure. If the radioactive ethylene is to
235T25
undergo prolonged storage, the authors recommend
converting it to ethyl bromide, which may be re-
converted readily to ethylene with metallic zinc.
Presented by Aced A.N. Frumkin 10 Jun 52.
r .%-2 \
~C, 41 -j
235T25

USSR/Chamistry - Catalysts, Heavy May/Jun 52
Oxygen
"Study by Mans of 018 of the Oxygen Exchange on
Vanadium Catalysts," L. Ya. Margolis, Ye, G.
Plyshevskaya, Inst of Phys Chem, Acad Sci USSR
"Tz Ak Nauk, Otdel Xhim Nauk" No 3, pp 415-421
Heavy oxygen was obtained by electrolysis of heavy
C02 caxtg 0.9% 018. Using oxidation catalysts
0205, V204, Wr2O4, Ag I which did not contain 016
studied exchange with 01 in the gas phase. Using
.the same catalysts into which 018 was intro ucea
by m6ems of 920 studied exchange with 019 in the
220T.6
gas phase. The kinetics Of 02 adsorption on V
catalysts at temps 250-4000 were established in
this manner. The inhomogeneity of the surface of
V catalysts was demonstrated. Oxygen exchange at
catalysts of mild and severe oxidation was deta
at the temp of the oxidation reaction (350-4500).
no mass-spectrographic method of analysis was
&PPlied in investigating the oxygen regulging from
the exchange after conversion into C01 01 and
COJ6.

LAI, 1,,'~ 1~-t Ph" Cb- Acad
1-."q Alt4d S4vk S S 8 k
Ord.6 Aftm ~%cuk 19%2. .16-fo The o.vlAtvm wa~
4MI.wd a w~ U.-kr l,'O Rim-ures '9 1-2 min
Iig in ~*rwl vnth X~I IQ4), of A ~p swfa~
,f ~q M g -tbfiim 1, ~,,Mplete X. CFA alpf
a Cilf. - O~ ~.Iil . - Inst.!
4 4 17 -9 IS mm )4. v 2-V. the r,te J the r, -
4T 11w grlcre,w of pr"~r, N:~4 "47 With
1~ S t~a~tctitivt run- an ttm i,aA ~t2ly~t.
thr irct.0" of "114 tpmt in qxv!ATv.M decTra-4. 1-M on,
r~n to a-Alics. w!:;le the fraction subtricte,l I- a - ~,Nptitn.
., -be 4ulymt thus. isbile 14 3. -7e, -~ 32, 0;
4.: -, ,~; ~,~ of ~Iw C.,lf. -err found Atortw-d in tb, !, -,:,.
- ~tj% t oipts . -be ;~r-entAzv% sl Cjf. oxvlur,! -e 79 '.
0,'- ~, '~ 1-2. '1 4 fr -, There 1, an alm~t ml., Ir,
t., 4 J4 Ijrb ~ ?:t73tb-u ad~xb-,-, now r--
-~t;~ the uxac- dx" = tAr,=~ wd -Ith ~ Not-:
A. f's (,h. the f-ActiM S;MMI in nxidatv,,t
in ,---,utjvt mmv 79 S. 79 (). 0.2.8, S1 2, IK '~'; (w-
,-i vr?~C- as lot Clf.;. and the fraction -t~W ,,
14 5. zl) Ii. Z:J-A. -17-3. M 2~e: but T~,e un-j-'s
.' 4. S-2. 1,s 4. 19 5, LV) I ~' . The uitf-,
.Y7ni4=:=4ted tj?' adwirPtiria of C,H. can be by
C), IV., M= tlg~ And then the original attivitv 1,
r-.~Zur~. %Vn~uu nbch ruz, the rate can be reprx-,ented b~
,at a ge --f 'r$ - C " -hCTC C h the amt. racted; th~
!~ term-,' the -helerogimenst-f C~ff - In. ewtv rij-,
4 thr re~&~.,on is m,wt nowir e2ponrrlLal. but -
IWII-T,-~Ok ro~, T4 br~jm~ ux-easingly more newIv I,v.
O~ef T'h th, r.!e tr 1,, tb~t is interprete,l a, A
d ld-crtu&mg .- of th~
!,-e W lzicywx~d Chemisi3rptum- Addu. a 1. 2. -w
Nt W&CAtt to *h* catAlyst chzng" the ratrs, lyut n-,t
w L. - "Vith -IP - tbance of the prt%ture fin
ffA . 11, r-Ale if the reaction is ir - UV, --Jv (.here
-2, mo "f we ",! tt-~ integrul (1,2 .7, a-%p Ing oul -
B--te. 2 1-9 11 -V.) ,'k,9
t-len eA% The c,rfY t~
~5- - log I - ~'C
V, Es:,C of -ij (m= tritu., an4l of . (min
jyr IAX the 3,14 chnmute 9 ", a-it, f, Iff); CAIA.
r- ; 4A4 0 Ulf). 1V0- ~ ~-,,j 0141J.
C G
0
of
a"eT the ......
M.- - ,,I th~
B,.R"
-13
v

L. Ya.
Chemical Ab;t.
Vol. 48 go. I
Feb. 10,- 1954~ 1
Or
ganic Chemistry
a(Widrocarbot. L V..o-%Ir.'XQjL- I
M - 20. 17G-RU(IU,5I I.-ReVIOV a IC placutal I
= th"41 f wdyti. --idatien of hydro-
C"b=,wMIa5rde=Czs,
~cu involves as intermediates some 0- i-7-1raamrs;
which am utitb&r amehydes nor ketnnw, Nt. fc.
J

44 4 Goo 4 4 6*0'
V 1' 11 11 14 t'W 17 4 " 22 21 22 a J' 21 A ZY a "I to 'I M Z is u wife 41 ou idise
A L
11 r 4 1 1 V V -A L ~ L- (X 00 0"-1 it-s-t- a , , . - . . a . _1'

4269' Nauk Nh-SH.
Y'
.
a 01111, fili J 11'. %,-h 1" 'J S, wi f the ( ssit ). S- two -*G
N.I.-t-, Wo 1911. 1, 2'02-2fr' -00
00 11-01R.'fed IM) mm)*(' if, Ime, -00
Im-mit . ..... I ..ih "'Mau'- ..I -Imm It - ~I At,
06 1"~I 11m 'mfj~v 1, 1-1 --l 11,41 111, 1111 -
frif"itum A 'urta" jxmf-o b) Activation , I., (g% 1,
A"t"I b% \J;(.'O. J11,11-

*0 zoo

00

ee Z;
0:

00

6 a 0 4 a a 0,0 0 IPF a 0 0 a a a 0 a 0 0 0 48 6 c 0 0 0
A
- . 4 a a a is 0 c a a & a d& a At 0 a a A st a & - M l
-

0411 40411004114,04,0000, 9,
S I a if is is W ts to 17 0 1 a is a
004 A!j i.!~
"c#10141 og.
00
00
00
S, '1023. itax(ificallon of utalym.. If. On Russia".) Ya.
slar Aurml Obtlichei Kbimli (Jourrul
_gplis and 0, V, Kryk)v, I
0 of-C~Ger4l Owtuist"), %~ 20(82). Nut. 1%50, 1). 1991-Pplis.
*Olt 4' (it QWAUCKI (If CtlIYlCr1C (III A
00 Ultruouto CAtalYlt with different ainounts of Additions of the
000 "Itrin salt of silick- acid was studied. Vk- .mw liftcuouterta of
luodirication w" obsmed during midatiun t)f iso-tx-tane an
00.3 tumpten otides. both pure AM with additiorm Gf NaOll, wai
also, itudlecl. Data are tabulated and charted. I I ref.
00
1;
JI
'10~$L* 0TALLIAGICAt U7944Ikol CLAISIVICAT #0N
c4c
IS All fC fE (g Lr IX a I
~,- *,t,
a It fle 0 4
0
a Is v x IF a 0 a (a a
c4l-
sau
I'!L
0 6
.00
-00
.00
-00
-00
.4110
go*
z0o
Coo
COO
zoo
zoo

vtvA4m amU. of 4S'aA(% up to * max. at Vj'q. The max.
6 km sbacp (h4% In the former raw, As a 2ad ez&w le
the ctimptiete usidAl6a of lzodctane on WO& wAx at=:
with A011 as An, impusity. Pure 118WOO was put Into
.WAU. by mexas of all exec" of a coacd. wtm. of MEOPH.
The man. was evapd. to dryness Is wo Crutillk;
the resultiag white crr4tab aci dccvu by bmtwg 2 him.
inairst4w'. Tbeyeplowpowderw richtobtalnedw"
Active. Phe activity was detd. at a dow raw of t0 L/br.
Aud &CWA&ct time o(O.1 Win, The Catalyst w"Capponed
00 AAbCfito* (50%). The activity k Vras computed from the
lst~wdcr kineticlaw; k is pcQpwtjotW to the Amt. a cats.
I"tup(oC*W"Ooo.t%hrNt%f^, Thastnt.o(NaOllim
114tille the contact vatin Ex-tutvil UZ And 8179 of WOB. PM
!Caw. k* does VA have a very h1h gtchtoo (15-3G%): thl*
is due to the small activitY t Catalot In the temp.
"Lar Invelticated (2804w'). k. h. ad f a
shap max. at 0.75-1% Impurby. A Now 1=w-
twan a cd lot k. Is verifimd. The follawbu cattlimts
are 5=CdVe: (6) aZbM(rA 10, WOO 50, MOH 17J; (i)
sibescas 50, N&OR 50; (c) mbestas 99. MOH V-' The
data Are said to coafino the tbeory of contiAct ~.!&.tiou.
Michel soudAn

SL A-ri a AJ -AVAILIA131-6 QJ /S 7.1 2-
w COODWS Uwable. 1.
Mt I it 1 4( t
A 49 Mit
V
Itowt w tatw tka Gma W 9CrA_U I (a)
two
The Ust4we WS
awto. ad Im (0 t
an ad dried at 100'. 1
!V "A"WOM S55-
OM H&M. Him. B&SM.N"Ot. Ba(KCale. HF.
up to 2U% tbm Impusitim fail to Catalya when supported
directly am asbegfin. go. gulfam "VAN 4 a with 1-4~
IfJN% 4 4,V. d-UQCV9wft 44
There-
.Nrtwa IN *( aftfa ;#. 1. as 0 wowdiag to the impurity can-
teat (C.A. 4Z. 1W). The acdw ad the Adivit k
dwage abruptly at goose Cgft. emm. of do fm
give the activation 8
Plo" of i0c k qxwd (11
t. Is caw. tons k - k* esp. (-a/ n.
7he activity N 1"%"VCXtCd Its a lul, lateewl do tilzp
,;,bl.
41mccla"Waad *Alt&*. 4letwo,1418 (in The Cittalpt. Ila
0(thoul Vilect 0" 1 but It affecu lu. The effect of Impud-
fks is d&cuswd on the biAas, of the toWodus resuka: (a)
Ekth &4 end 5 incresios: sharply with do impurity content
. They decrease With (UVACC adda. of the in
rip to a max
;==iSwzft= to 2 to
R OA NMI
ZYlocke.between3and17.
between X iwd kse 1% wlx4h 44m NO tkta mow"Wy wvu,
NO Vk(44ftK4U9l Is V*Wl, VCIXFA (d) (t W CWC6ded that
Itto COUCOPA al pc0awee NMI poken has to be wwdeud.
A gLwa "madUice" may be eltha it pcwwtm or a poWm
.600 1 to k& cow. It may dcgoge the order of the
C,
Catall tutdoes and It exerts an laikwuce on both S and
V?L, YA Uartotis sad 0. V. Rrytov. 1W. 1901 -8.
-The theory of Contsirt tmxfukvf ki" is S"llin4m to Aw INI
test. The cmpkte oaktatkos 4C.11. w4R&OAA. d- Uoo
(1) i'tw(d. Vok"t. NMI-. 'd .14",k% W" laressle4led I= am
Opp, dtt"dy d4writ-od by U. and Tades (C.A. 42, IMO).
1 !irakXcuced with the impurity. the catatim dried at
100 a4vocted on asberem. The coucti. of VA$Sio,
was varied bttqt 1.5 and 4% ol pure 1; the emcn. o9 the
*C"ytt C an the sabeam. betymen I atut 3,%. Samp"
cootc. 3c. asbestos act tw4tkoughows.
6 to pt
_"tkm4d to tho couca. of cotAlysl ca tic mppact.
k. - kit to uw4 to del. 9 (rum laSk.-(1~11 p&ws. kofade-
Oped by A. The kluetla a juation for
I IU)~ + 2 HgO was found by i arride the
QH4 CWCU. X at a Coust. 531W rate ol 20 1./&. - %
of C" oddlwd depends only 14filly an X. Is diating a
Itt-OrdW reUtion. k Was computed by A - (221U)
-be - A 1; 66 is the On Coom, - 204 (U1 Vot.
0,11/0
a , tho- Contact time in mim.; Y is the PCs ta-Lte of CO.
after the- react;oo. The tcwp. was vaied betwe 2dO*
and MI. The mufts dww a behavior similar to the one
(ouvA for ho6ctam oxidation: 8 and to Inctraoc with in-

04010904119t10101
fliftillowtell
40
8
.8
43
13
13
go
SIT Ito conek
6.0 of
00,01:*:6969909"
0,01 0 000000*00
It 2 JOIN lilt 111119441 QU (Ad
-!;)
195 Dff
Catalytic azidadoct of hydnctitious. 11. Vu. ItuiVisin 1107") -,c Nixt 1-4:t,4 1, tat :M i. tit. i,toj.. tint.-rut"vs show
and I Do&Lj,~v Atad. Nim,* S.S.N.R. k 't-1, It- 1'. ., itk.4% foiNt."I hy KlAdU41 derrei4te. in.
66, 4( 8"I'mg) '-The pco"insts of the lumlitcetwous, dicatitic that thc reactiori, initmird oam
~5 the cmairst, ctm -
and the heterogeneous rates Of OlidAtiOn Of Ctlfl,-tit1UC4 in the 11119 PkAIC at ~a XrAdUAIIY &CITMIng rAte.
Call,, and Calls by pure Ot wem dctd., in static czpts., by A similar Lurve is nittained when 09 and then the hydro.
"Unultancous mtammateats of the temp. rise indicated c,iftion 2re admxlwd o" the caraly,t. Ill ctuttralt thereto. 1*0
Ity a thmilocauple pL-tced along the axis of the TV4Ctf0a With C-AL41YSt" Pt'W"06119 Only Mild Oldd-4600. %uCh Al 600
V--WI AtkI one in contact with the wall couted with the i Ag (at *;(it)*). cmly the surface of the citalyst is he3ted up,
catalyst. the total rate of the reaction being tatrasured am - ictup. ri--c is observed in the gas PhaSC. Ill this
=00
!nanamuctrically by the change of pressure. At low in- caue. the.rLAction is entirely .14.Thon
RiAl pce-~Mrv., 0-1-10 mm. lfg, with caWyst% kadims to P,
.1-t. oxi'lation (to C(N and [Ito) -urb as Ill on U&SA). (W1 ZOO
Zoo
See
ISO*
t:OO
a&*
A I a - S L A METALLURGICAL UTENATURe CLAUWICAT40
Item 11.141av.
1-oo
dw a- It,
..~ 0 4
All k I a #W 0 4 1 It of 'a 4 3~ =
0 fie 96 9
a** let OP000 00 01
A
06 4
of
.T.-CO000 Oil* 0
a & e 9, 0 a'* 0 0 6 6 ffl- 0!-k. 1,

Ilk

fd,rux ad(fill
powlim the*wtdyst it'd 1~ivorL~ s
.
Thc lfamr,dcpgade=q of tot Xt otE E'and I/r held am ti

iA
d
med(m. icinp., 0.- ted"m ds.-aucli -wi W-
Ott the C,
, 006,
Tf th
Pits,
l
Cat It It'
I a'r th-An Cat and Mo.,oit Contact w(th LV ?Ad v
J
proposcd datt thit catalyttc as welt.aw the h=ova
mish "StobteJuter.-,
-
wIlkh am r10,. oldch m ur ;6tion&-but tuft
bi

perarldeT.'. Under the same cottd(Ilauji..
_01f Vfd(f,.d
CO, d ~f%43 Draynitks'

i:j

at&i,of
Kin
At.
ezd 0, ts F"a -Kind
t_ ~.O=S~~rrv
Naak atwozens7f K CA-Jsk~ 281
z,
Cil CX

;UzTIT--O wax studled betuTat 300 and 600
cfPt
MCC
l
I
ac
ted4n the;lne'ducta The oxidation'was 2nd or

daft
:
wcfetrfc~ the n6crnali mrraadc~ or.
ir, Ild Ur, but Ut
foc r,
had
elk!
IL

K-
it ~I.Ctmtfnm cacr~lm. 9, of 16-46 kcal

I st. rdcr'rmPC&m& e~ltlblted.Z v4iluct 6f 2- ~a one:
highp

-,'izt ItIsli& teluD- Art Omit change frt Z o4murrtd friAhe
-Th~- Ke. rcw.4ned~
c~zt wh tim d4m, im(c vw" tamawd by- iL [Actor or. a.;
t*tltl E wtc! K. v=od cqnsNcr-.,bly;t~re UO'~ writh ry. cbaa~q'
wth tvkolhrdrombcousid, Thmcqndcjth&rfddl=-

tL% aLmn 350*~ are itot ~dilrWilt-m-
Tr ti'at ~6-
tform Aq r
I xw
-'Mm4ed. ft fs propmed
that it highm tmO, t :c.0
kl
l
~
fl
Cjc
lt,cas* o
njr,
Mid bt(weim 230
zad ordcr hi tllelpte%:~4
and
v
but xthmof Ilt, r(j, ~jjd Sllrid-type cifft4rits. - A (jamt.1
-3 '15 sd0v IV" -la with V~ cfiromit.-~ and 15 with -11, PC
''Und F(I;: %)x KI -A-14 litlearpj- deilellklent art E (pt rdt.
Ncmuseoi the
of line-) Od art E/ 7. rw;

N-7
at
~L 'Y-Sur~lss-bfficrx-tlt llfgh& idnip.
$Parfugly Volatile

inort, compf!i. -such " IT.PO.. FG130., Hks 13
0j,
ciSlOi,; wheit added to - LY wid VIrs arnts. of M10
dsed the ardor of Oie rmcdort.. A t- concris. of Opprax~".-
L
arkd Plum! both's alld~,Lft
they PrOMP.t.cd the c

L. YA.
PA qA9T10
USSR/OhM14trT - Organic -C=Pouads 48
chemistry - oxidation" Catalysis Of
wCat&23*j6, Oxidation of Varrims TYP68 Of Or9mic
Campounds in a Stream," L. YeL. Margollso 0. M.
Todest Ihst of Phys Uham, Acad Sci, Sao of Cata-
lysts and Fuel Chun, 7 3/4 pp
"zh= obahch, n1--i" vol X-M! (v=)e, No 6
Studies compjaze ozidation kinotica of -ariaus
hydrocarbons on api=51 catalysts and platimm.
Reaction conqtw~. 7"ida t1a accordance -with
luarl TAw over a wide tmpemtura range. Submitted
7 APr 1947,
9/4w., 0

***O::ee 00*0j-
00 t, 0 0 & 00 *1*, ~
A 400 PC
I Ck4d" moaraw -caw, tw4ft" ta's-mm cause. r ~ 24 min. In the tmqj~ nutte IOa-~W*_,_de-1
A gygm. IV. lareadCatiou d19 dagon"? ad ft creasing from 2.5 to 0.5 betwum 403 cad =~*; hvm aa.
00 is ai,~y djdditloa d tgooctme am a cma-hco- - tionary-state measurements, r - 2 min. (2) with r. - j-**
it mkmc&WVL initial temp. of the reaction space. C - beat ad the nav-
00 Ckm ACW.-&r-U,S.S.R-, U*Wcw)- ltwd- tion, A m chm. reaction rate coast.. a r - r - T. gad
% S.S.R.. &M. _e0
oog %:. Kkim, Nat* 1%#,U7"1; .1 r. - r. - re. movacutary and m:e. tmp. rim, mp,. I
00 d, CA. 42. 1794b.-XICUUMM.-ats at am tmp--HUPF- e, - Initial Cauca. of bodccamc, the race doe 6i
Hkd In ttm "J"tion 01 jW&-ftae. dowing at the raw of Md'a (4 Flo . - WO We I I - (ATAS r4 atlbr_.Pt~ ad I h~, 1
4014hr.. on CU-C1`CAWY2(S With 10- 30- "61 "Ve fall ol temp. due to km of heat Is Uhllw - Ar/r;
. are coutpared wh
COUX&Ct VAbg&OM 40 "bW- tbw. the rate al temp. CW depM44 CPJAtIVCIY W&C am r..
mticd ezvesswas derived for the statio-7 god the non- Graphs thaw thAt, at ce - 1.4%, the cums of fall of temp,
E ~ 1
ttatiamary state. (1) lizPat-atally the to" Of h"t corresponding; to vatiou To jimm 12 to 4W) intersect
tkque~astvectlmm by the gas stream is only W16 al thu the aim of rise ad temp. at a rvery dow to T. I- 4W*); t
total t bakom: the M(ft IOSS Of hCut occurs thenucts in other words. in the stationuary cute. &T1v saman. and the
t b
rcactim takes place in the kinctic= Howt%w. at a
the wait$ 0(tbe "action tube. Thestatku"Itcrap-cbe
004 ~1: AT. Cataldi%bed on equality of the rate Of tWutkn of Watewhat higher re - I.M. this only for G < Coo
i the hftt of reactiom, 904 the cute of loe* a( heat, i; Yllid. 4(10'; at r. > 4W'. (he Curves 010 Vie) * gad (d r/40) -
by Ar - WOr. where C - heat capaCity of the (cat. lue=dcally tangent. in other words The reactiqu pulto
at diffluslonal ranF. takcs place afnvm compwxty go*
too. r - "characteristic titne." at "MU-6- (lam the
4ame radiviflude r dets. The rate (A cooling on shutting all In Or namm reckin itt the entrance of the reActor, tri the
the WMW source a# bmt. 4r - AT40-4/r (I - timc). tcutp. tises sharply. These cauclus4ou om caudrvaed by
9
The gogguitude , can thus be deed. experimentally. either expt.; at To - W. oxidation al IvActane (am a IV; COO
from the stationary or the amstatiouseY State. for d Cu-Cr catalyst) can be kept at the " V~_, reaction"
cy * I jus P, beat exchana coca. a. best Capacity Stage. and prevented from becoming a 'hevermacou,
unit vol. C. r - rCj2.2. with IOkCd-/%q-m-/hr-/ catubtation. ' actly it ce Is kept law (< 171' 1 With a
beof ao% CrA-Cr catalyst. at c. - 1.7%. the " is .9 tb~
d Iqukt reaction" type.only below 1. < 300', with a 67~'
im qcd*a at 6 mia, Expel. data coaArm the flaeadly of
I) to a function at I for the moustationary s catalyst at still lewer r.; in the latter Caw. the kinetics
i independently Of the rate Of do" (16- 27.44 LAIJ, Ovtng the quict oxidation cannot be deed.. hutstauch as below
ce, 2W. the kinetic reactim Is too do*, ad &how tWO
> 250* It pas=s immediately into the diATUVA(Ld mage. no*
$w - "M
�*1Qxj m4t okv act Njis Iiiiii "_
1A #A L I a U 0 a 4 1 1 a 4 a v 106
t"cF m .Prom mc Ica K% ?CV99 a 3

0 ( .1 41. 001., ; 4S, Expli. with
,%iKcfA),1%1Igf) 41141 010P.-CUO Catalysts tm("I with
- 0 5 107, If,11f).. (" in Cttt.
Ivio ".Watio"I U-ing the firrvimly dc-.Cnl~f technique (Cf.
C I 4Z, 17,14bl. with i~mkoailc. show"I the fljltowinc~
A.ifiranit- 4 i1tv I-A,nn the,mler,difterrActicm
.4 "SI'Litkiii g".111"Hir (r4"11 W,kv 1. 10 '.
to orto wife# III 111V Irasma .4 lotx.frf fractim) the
trinp tivil. of readkiti rate ftillowt Art henoWfisormulal i4m,
No activatim ril"gle, Vary ifelefultiff on lite volicn. of the
jmt,oii. A% "talyst cn?tclt. rise$, Wh E' And k. rice, reach
A mav. , then c1cclinc, the max. being %hnwn at " 370 cmcn -
with the Nig citalyir and 441% with Or catalyst. The
1116 ), thl)" 0 IiHCAI` CCUt I'M lit r"IK'Ct (0 F 41 All CAWS.
G. M. Kawkitlooff

.ItIM/Mewietry - Unzalyows Obt,1947
eb~eftistry,- Isotherm
and 1146aification' of Cratalyats,"'.-L. u.
11*4olI83 0. M. T6des, Catalysts and Topocheii Sea,
Inst-,rzqs Chem, Aced Sci USSR, 3 PP
CIj
','"Dok~Akad Hauk SSSR, Nova Ser" Vol LVIII, No 3
'--Roginsk=urrr showed that concentrated isothem
6:r the has optimum amount of eatalytid
iwtIv#y: Small adaitians of - isotherms Ipromote the.
r.fto'tian, vhereas too large anounts fl on" the
vois
ciiil"t. Authors describe resulto of experizl~nts
caad~6ted to determine the effect of nymn-1-1 adaitlow
(vi:iVinel-type catalysts. Their Interest directed
49M
WM/ChamigtrY Catalysts (Contd) Oct: i947
to- this reaction an result of inventign+iona dk re-
tr~jtd:,:Of catd3jtic oxidation of lso-ootan6. SA-
xitte&:by Academician A. N. Frumkin, 31 Mar 194T.'

o 0 0 0 a 0 0 0 0
0
T I I 1
1 1
9
A .8 C 4-&.J .4-91- A. _k__L A $1 Q I
-A T a I - Cc or t _t -A to
00 4
--tt ..00
-00
0 Kineeks o(excitheirmal reactiorts in gueatitiag Call. %to. toile thrill, Vchawfel"Ift'lli'lf.
M
iven tenip
t At the
t
l
h -00
Itilletics of catallytic combustion of Littl&Wito *Ad at c7do- .
a
ys
e given ca
g
Cti%ity of t
ZIA)*
t Air -00

0
k*16110. 1 Va Muculio,-Antl 0. M. Todrs. Ifull.
'ji-_C~ ,
1
e ('t
ld
h
ant
ion 4.1 truip., between
fullort
with the oullivrical valur~ (cataly~lt. hlmtr,-W-
oai
"' o
00
q.,
.
A I
aste sit.
im. 1947. 443-41
(in
flustian); cl C.-V 41, 3:150k. CittutmOofloo of flowing .
.41.110114r. Ilia A): 'AIN chroloote 4 Mill) (1)
I.,11.
'0

ioixVi. ol ?,j%1-IritnrthylptuIanr it) And of cyclolverianc :I", Ve clootoite 4 Froth (1) All. I I -
I.N. 17.
Co (Im I;el
S fit
V
1 0

'
(11) with air were eatirrictl (out betwt-vo 2.51)" anti liver -
;
Alt matirAnite 1
) 111141111
00 ~Tsiqcl-lyiv catal"tit (Chto"nites, afloninates.i ga-
"
n j#;.L1, ti; Cu chronlite + Clio (1) 15.15, 6; (11) 17 11. (3,5;
3
C
11 i
-00
tioe%, etc.) flit IANIW% loor, as Courn,%, varying lietweell
j e"
(), u
) 11. 1
;
thr Write (1) 36 4. 14; (
, -
01111 And 07,*; , 'o It,l to rosore a toovrojenj tilt, of CoolIKI'llon - .. 11. The
clo."latir (1) 15.16, 7. [it (1) 1:1 to, 9; P.1 (1) 1. I mes
j 41114"llitel, were pirlid. try ittv,mipti, of the clool"ale. le,o,floo 11 cv(dr(illy tvIlolly &.14, fly the kinetic r,.g" to.
4
~96
I
00 i alulliblatert fly (U-1110 14114 44 Al &till Obe de4ited oletill tilt
iml try dillospot. lite imirl,emicovi- 4 the tale -
h
J

00
counbilstions of I were also carried out oiref pt anti lo, e
I
louto. 4 0, tudittilvi Altuo,11 covirme

00 : or, asbestoil. In all ca". . the ct"bustionis
C Active AurfaAe with Clig, wfictraol the JIM order olight 111,11-
d
E

I'll to Pract"lly Purc C(I'l Anti 11,0; In no case was a an
to
Illol. activalcol c"InpICIV4. IiIiiih regard
cat, lot
00 flace 44 CO dorfected; the IIrO contairierl no njore than .1, tile -atalpts fall iroo;1 gToops, th~ %till E - 45. 34).
00 O-Ole-f Aldehydes &flit 0.01"t, Acids. Without catalpts, And 15; it is noteworthy that, owing to a high A, l'Urne
less aCtiVe
are floor an
j
l 2
I 1,egall only at RIO-41W. that of It sornewhat
w
D
Mi
t
h
I
i oi
gr(oolln
ill tile Ist Stil
y
thato tho~or tit the 3fit group. That the
.1 . hi
her tvo, l
r
ev-
OM
"g ti
t
e
nit
al conorn. too (in vial. re of to
-9 It in file mixt
douttles the de
ree of
omb
tio p.
g
%,cry ronkcd vatiAtion of A front Ito- to loll cannot be ee
.
C
us
n.
g
b.-tice, tile reaction ill rot lite "
Order. With W.Tibcd to (fitycirctic" ill surfACC area ill" shown toy Cleor- go
r;i lalym. k - I (e.1r) - I I / ho r. . where ti, - Val. ~V (N If'"l-IllIcTowt,joic orsaout.; in gmirlicutat, the high V4lUe of
1100
, tillic col Coulact ill lillo.. 14 Cooot. At
Const. .1 (or Ill anti I'll (A3 ontipAred will% the calal"aq qof the
h
l1
ro*
indflWn'leolly of C. &fill of ; on it, other hand, Al
, atnt%.
stuA
:till poop) I% novoililaintif. PriuntAims wit
., Ill 40 and .1 lotion Pit
ly rLowl) E Itoo. IA
.4 Illp
*Ilikill
i~ directly to tile comers. C
of the Catalyst .
.
g
N Thoo

oso

S L .114441JOICKAL LiTIOATLIff CLISSWKIWICO-

1,0110110 -4 1.1444 .1. C-
---
1
1 it'll, C*o l%.

71

ee
u % A V -0 At
z
.
1 1 Aft L S I Pill 4 a I ill 94 -j a 4 3 or q ot
0 a a 0 0~0 0 0 a * 0 a 0 0 0 0 0 0 0 Ole 0 0 0 0 0 0 a a 9 a a Ill 0 0 0 0

MARGOLIS., L. YA.
11 Laws Underlying the Selection of Catalysts for Cc--ple+-(-- Oxidation of Organic
Compounds," Dok. M4, 52, No. 5, 1946 (with S. Z. Roginskiy, S. Ya. Elovich and
G. M. Zhabrova

OIL
2-7
L L-f
'o
004 Kinetics of Catalytic o-Wadou In a 91-6111- OXidallo'!
d
T =00
es.
o
01 EsO.Ocune- L la. MIT and 0. M.
rts of the
R zoo
00
40 epo
Battelle translation ram
f Sciences of U-S-S.R., 52. no.
=
0 '-V o
622
9 so
0 -
.
p. 61
f the above reaction were studied
l ;;

90 cs o
The kinet
using laboratory equipmen which to dc5cribed-
t-

0.9 o activation energies
Specific rate constants and
ental results using
i
m
were obtained from the exper
d various compounds hav- .00
00 Fintinum. Palladium, an
inel type structUrefl. (Or example, nickel
' .00
in aluminAte, etc- as Catalysts. Results
ng I, i r
chrom
so
00 plotted, and discussed.
e tabulated
,
ar 4 a
0

2 1
CL&S%kF'CAIIC"
Re
8ET&LLUpGK4L nd 0
AO 4na
71
Ur 96

a
s L9
t 00
0 *i

vajo *-*.* 0 0 0 00 0 0
10104900
1?01
oj~ 41 1 4 0 4 r 0 1
A a L
004
000
sea
009
60 "V
004
oo Ir
.
00
"I
0013
60-3
oew
j"
P 00 1* 0000000*60
all
100000
11 00 HIS 360 18000 4441
1 14 t$ Is 9? 14
rao MUM= 09 C&Wjtk Gedatba Im a I&MM-aidda.
tion *# Iso6dane. L. Va. Warois and 0. m Todes
(Acad. Sci. USS.R., Mew"). Comr. rexJ. acaJ. wi.
U.R.S.S. 52. SISAR(IM)(N Hnzfis .-Air-iswctanc
streatnt Were paved over 8 spinel-like catalysts at 3OD-
GOW. The catalyst conem., tpread an asbestos. mied
from 0.5 to 67%. Situdsur Pt and Pd catalysts coutd.
TheprodWswes pfacticaystaiLki-
d alnttr'c Cos and 'W' By Variation 01 L-46ctane cancn)
the reaction was found to be second order and Indepead-
ent o( 0. The sp. catalyst const. (per unit % catAyst)
obeys the Arthenfus law K, - IiC. e-AF/Rr. The catalysts
IfIl into 3 groups with E = 45, 30. and IS kcal. and Ks va-
rKs from UP to 1017. A catalyst with kigh E may show a
high rate owing to high K~. F. 0. Wug
AI4.1LA 41TACLUKKAL UTICATIAE CLIMMATION
sufarli W&F Cm. Got 414411
u6 11 a L,- t% ; JE ; CC 916 t( 49 Ka m
(is a a a '01-6 0 0 a a 0 0 0 9 0 0 a 0 0 0 0 0 a
43411, as: OKV Ali
A L S a %d a 9 - 11 1 It IN I da a 3 a v
US
a 6 0 0 0 0 0 0 a 0 a 6
0 0
-046
.00
"00
-00
.00
Aroo
COO
Cleo
coo
1900
tloo

u
13 u
& is $6 it 4

Plkafl"%
00

00
go The kGoitics of e

to rent. 11. Theo"
V;k_L-Matolis a
00 %1,~w). Ad4
flfflfi)(in Vnqfl-kh)
00 ittach. Htputioni
rt-art#w at t1i)t frin
*0 gunes, "quiet reac
-tablished 3-,; in th
:0 tinction regime, the
activity of the cat
linrar relation; thi
LA
.:i method of tvittuatin
I 4 CivW reffictioa.

AAL4jf

S It - S 1. A WALLOICKAL tIMAINSt U&SIO'KAUGH
itithertmal
nd
Pkyjitorkint.
;
timi"
e
alyst
s
g
All: 1.
A.0 PP_V#fF)ft WIT

.44

~aitxlytic reacUuts In a cu.
of readko 00 4 1110st CQUtKCt layer.
0. M. T(xtei (Imst~ Phys. Cliem.,
II.R.S.S 21./ M'P-98
'
'
_TM-M_
cf. C.A. 41, 1.
Kf7c
am 4crivcf for acr"ParatiTcly quMt .00
small rates t4 flow. Two org,jv rr-
and "etuntmitim rrgimv." *rV
prtvitmi-4 caw. For an unAtrady ex- 5 .00
rate of cf"ing d the reactor and the
zoo
can he connected by an alm("t
permio the development of a simple 00
the relative activities o(catalysts for
AdIttw Fleiwba

coo

7-
0
)I INC; MISAII C44 0.0 lit
0 0 a I it H 2 a a
U00 n I I a
0 * *J! * * C & 4B 0 0 0 *
. A . ~ ffl~ ^ at a - - M - ~ ~ iA at, . ft
WU ISAT to
C, r, V.4 fen lie rziert ItsE
4& 0 a Q
- - - .

IL
4 1 4 it It It w it t# Of 9 54 IS W 0 IA X 10
f 1 4 j
SA W 61 Q o IA a zip
A
4 5_4 4
4 so'
.0
VOC
I
S
0 .
C
M
.00~
.A
t Tke wtubLut1d uplidduk adds to witiff add Ike defemination of th-ilt dftwds-
i
H
kil
L
k
dA
k
At
l
N
A
.40
00 m cma(autv. .
a
and
i1
dmi
ot
t
,
yatt
to
ifiloastoe
. Va. Mapilim.
KAn~cldw IQJS. No. 3, 7541-Saku toptathcusc acid* irtgn n4philial, kelim-sle
and vu W, mp.. have stcM vm. 310.5, Wkco, IM.2; msA. wti. 176P.S. 216. L187.
SM X 10-1
21 x to-'
divwm Cwtus
(Inj x to -1
8
41
09
05
4
.
.
It% wairr In (11 .
.
.
.
,
;
,
L 37
7
h
firol
41
22
k
f
1 N
t
i
h
g.
1.11 X io-f
Ne alto 1
1
21 X
;
Lcm%
*, ti
.
y%
f
r
t
,
,
p
o!'
IM X 10"s
M's
r
i
0
O
b
0
fi
4
.
.
.
0
044
Thus to dc(cmictin
M rt
.
.
trui
; pe"j
y(
34,
A
mp
,
,
A c
m
W
h
t
b
A9
.
.
g
ahmtd he bom irt atbA that it s 4
cn.
rif
r &6
Itap
l
iqf% in Zfeam r1indlefildfr it
hould out excsvd tis, tirnit sit 1h.,ji trut. v4y
tkvuuw he
.
Ptcftvcc Of "Phtbcnic adds k, uUd&l state Will msf~L -b-m turbidity in the nrpbci.
Ometer. A. A. BoAtlinCk

ZA 0

A 0

ROGMSKIY, S. Z.; MAROOLIS, L. 'N.
Carbon - Isotopes
Application of a ta.aged carbon in the study of the mechanism of catalytic oxidation
of ethylene over silver. Dokl. AN SSSR 89, No. 3, 1953.
9. Monthl List of Russian Accessions, Library of Congress, June 1953, Uncl.

MARGOLIS".-L,'D.; YEEIPTSOVA, Z.V. ; ZHLREBNOY, I.A.
---
13 . I'/
Sodium content. in aluminira. Ta'vet. 37 ~e
f!,T
; III J~ 1 v : r) ',

MARGOLIS,, L.D.; KRAVCHKNKOv A.P.; MUZYCHENKO, V.V.
=Mwours"amm-
Flame photometry detaTzination of sodium oxide in slimea of
alumina production. Zav. lab. 28 no.9*.1072-10'75 162o
(HMA 16: 6)
1. Dneprovskiy a1yuminiyevyy zavod im. S.M. Kirova.
(Sodium. oxide) (Flame photometry)

ZAKHVArKIN, M.O.; SAPIR, A.D.; SFIVAKOVSKIY, V.b.; ZIMINA, V.A.;-MARGOLIS,
Le D. -
Exchange of experience. Zav.lab. 28 no.3:290 162. (MIRA 15:4)
1. Chelyabinskiy metallurgicheskiy zavod (for Zakhvatkin, Sapir).
2. Kiyevskiy gosudarstvennyy universitat (for Spivalkovskij, Zimina).
3. Dneprovskiy aly-uminiyevyy zavod imeni S.M.Kirova (for Margolis).
(Metallurgical analysis)

MARGOLIS, Kh.Sh.
Mechanism of disturbanne of the function of the tump qr-d ansatorlosis of
the renented stomnch. Vest.ront. i rnd. 31 no.3:P)J-86 )V-Je 158
(MIRA 11:8)
1. Iz rentgenovnlrogo otdeleniya (zav. Kh,Sh. Hargolis) gorodskoy
klinicheskoy bollnitsy Ho.12 (glavr~y vrach A.M. Kricherskiy). Moskva.
(GASTRECTORY, compl.
dysfuyict. of stum-p & nnjqtomoAs. mechnniam (Rua))

ShMMUSAYG's A. I.; KARGOLI .,~J.Ho-Q.Sovetskaya Gavan', Khabarovskogo kraya)
Curing a pulmonary abscess by intrapulmonBry administration of
antibiotics in a t-do-year-seven-months-old child. Pedintriia no.g:
88-89 S '57. (HIRA 10:12)
(LUNGS-ABSCESS) (ANTIBIOTICS)

~MOLIS5,
Automatic thickness gauga.
1. Tomskiy kabelInyy zavod.
(Rubber-Testing)
Nauch,i reso 21 no-406-39 Ap 162.
(IMA 15-4)
(Thickness measurement)

T'L==MLY&, G*Le; IV-uM0IMtF4*
KEmtics of urea dacawcuiticu in Qo prose= of maam-nnrvlxrl
phwpbato, Tm-dy HMIF no,,208:3-7 165a
Qmt0r=7 853t= of ureajp ===I= n:Ltmtop MOUOSM=Ifxr..k
phoophato at 25CO, Md.&7-16 (IMA 18:33.)

-MARGMIS F G kand. tekhn. nauk; GLAZOVA, T. V.; SVERDLOVA, A. I.
Recent developments in the technology of complex fertilizers
using the nitric acid treatment of phosphates. Zhur. VKHO 7
n0.5:507-512 '62, (MIRA 15:10)
Phosphates) (Nitric acid)
Fertilizers and manures)
I

MARGOLIS_,_FAG,; GLAZOVA, T-V.,- SDIOROVA, O.N.
Ammoniation of nitrate solutions in the production of carbonate
nitrophoska. Khim. prom. no.2:85-89 F 161. (MIRA 4:4)
(Fertilizers and manures) (Phosphates) (Ammonium nitratl)

VOLFKOVICI, S.I. (Volfkovich, POLEAKOV, N.N.
[Polyakov, H-M-I
Gomplex fertilizers obtalned through the dec=position of phosphates
with nitric acid. Analele chimie 15 no.4:136-150 O-D 160. (EFAI 10:3)
(Fertilizers and manures) (Phosphates)
(Nitric acid)

Complex Fertilizers on the Basis of Phosphates 5/064,/60/000/01/07/024
Decomposed With Nitric Acid B022/ 1,008
various processes is discussed and the most important of then are described
in detail. The composition of the products obtained by these various proc-
esses is given under special consideration of the individual forms of the
P205 (Tables 20). A. I. Loginovaq A6 V. Husadve, S. Yao Shpunt, T. V.
Glasova, and 0. N. Simonova, (NIUIF)p A. G. Bergman, I. F. Boahkarev,
A. P. Belopol'skiy, M. N. ShulOgina, A. I. Sverdlova, and M. I. Bogdanov
as well as papers by the GIAP (Stato Institute of the Nitrogen Industry)
are mentioned. There are 3 tables and 37 references, 21 of which are
Soviet.
Card 2/2

s/o64
/6o/ooo/m/07/024
B022/BOO8
AUTHORS: Voltfkovich, So 1.9 Margolis, F. G., Polyakov, N. N.
TITLE: Complex Fertilizers on the Basis of Phosphates Decomposed
With Nitric Acid 11
PERIODICAL: Khimicheakaya promyshlennostg, 1960, No. 19 PP- 34 - 41
TEXT: The authors describe fertilizers containing several nutrients as
"complex" ones, that is without considering whether the fertilizers were
manufactured by mechanical or chemical means. Six methods of decomposi-
tion of phosphates with nitric acid are mainly used in practice in the
USSR and abroad, i.e.: 1) with RHO and H so j 2) with and H PO
3 2 4 HN03 3 4
3) with -AV 3 and (ITH4)2SO4or other sulfateei 4) with HNO3 and C021
5) wJ,n RHO 3 only, with frejezing out of Ca(HO 3)2 ; 6) with HNo3 0'aly, a
solid product - nitrophosphate - being produced at once. A list of
foreign firms manufacturing complex fertilizers according to phosphate
decomposition with nitric acid is given in Table 1. The chemism of the

MARGOLIS, F.G.; DUBOVITSUY, A.M.; GL~ T.V.
I
ObtRininp, ammonium nitrate from rAtric acid decomDosition of
phosphRtes. Ezim.prom. no.4:219-?23 Je '57. (MIRA 10-9)
1. ffauchry:,, institut no udobreniysm I IneektofungitsidRm imeni
-
%'hosn!intes) (Ammonium nitrate)

USSR/Chemical Technology - Chemical.Products and Their Application. FerUlizers,
1-6
Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 6212o
Author: Dubovitskiy, A. M., Margoli
Institution: None
Title: State and Trends of Production of Fertilizers by Treatment of'
Phosphates with Nitric Acid in Capitalistic Countries
Original
Periodical: Zh. prikl. khinii, 1956, 29, 110 3, 321-330
Abstract: Review. Bibliography, 19 titles,
G8rd 1/1
'A

G
AID P - 3416
Subject USSR/Chemistry
Card 1/1 Pub. 152 - 1/18
Authors Margolis, F. G., Z. N. Lunskaya and S. I. Vol'fkovich
Title Reaction of potassium chloride with mixtures of sul-
fur dioxide,air, and steam
Periodical Zhur. prikl. khim., 28, 5, 453-458, 1955
Abstract Experiments were carried out with a gas mixture
containing 5-7% 3 021~gasvelocity' 300 ml/min.)
in the presence of Fe 0 (catalyst) at 500-5500C
for 1.5-2 hours. The co v4rsion of KC1 to 1
.~S04
amounted to 94-96%; 40% of So reacted. Ka in (3%)
added to KCI prevented the laher from caking and
exerted a mild catalytic effect. Four tables 3
diagrams, 1 drawing, 2 references, 1 Russian ~1942).
Institution : None
Submitted : 0 29, 1954

MkRGO1-T3, F. G.
Subject USSR/Chemistry
Card 1/1
Authors Dubovitskiy, A. M., Margolis, F. G., and Glazova, T. V.
AID - P-88
Title z Dendrite structure of nmmonium nitrate and its effect on caking
of the salt
Periodical Zhur. Prikl. Khim. 27, no. 4, 368-375, 1954
Abstract Under certain conditions, formation of dendritic crystals of emicnium
nitrate takes place from both solutions and fusions. Dendritization
of ammonium nitrate eliminates caking of the salt. Ten referew.-as
(six U.S.S.R.)~ 1891-1952. One table; four photos.
Institution Scientific Institute for Fertilizers, Insecticides and Fungicides.
Submitted August 17, 195-1

/11) --1 fi Ug 4 / I-!~ F, C'.
I ITSXIY, A.H.; MaGOLIS, F.G.; GLAZOVA. T.V.
~ ~-, f -
Imp:!-Oving the properties Of dmacnium.altrate by the addition of
Inorganic substances. Xhim.prom. no.2:93-94 Itr 154. (KWA 7:6)
(Ammonium nitrate)

OS-00,60e* 0,0- *- a's j~
KARGOLIS, F.G.
---
Potassium nitrate and FAmmonium chloride from a solution of A-monium nitrate
and potassium chloride. Patent U.S.S.R. 77.419. Dec.31. 1949.
(CA 47 no.20:10816 '53)

A, T'*&
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A. P. Belopod-Aff"d F.G. 16(jurgous. J..A964cu".
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aWk.-The rate d cryllco. r - ded. by Anallting the;
Solt 141411
llan. at recular time Intervals from tit,-- Modlent of ravid
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!jij desired tenip. 1; the supenAin. I is the differvasv between .00
004 _1i !, ! the sconal coal.n. And the Cquil. lckova. all (Ito given 1, .49*
18 of '! f At I - lW (Al 0.5:). curves of a agicitut little clint6l J
j. 11!~ go InWAl twFlod Oulu) visible crylan. (LAtent period). 00
0
~: -IaWwcd by inerrwatitIgly rapid crylltu.. then it decrease cJ
1; the velocity. tevvIlag ad Ilk s - 4). The leactis rlk at the
latent peri-XI dectrasws, With itw"Asing Initial ts. 0 ce 0
18, 23, 40 a./I. r. - 180. 92. 40 ratio. Curve.
Solt
(Vatcd- froll's t"Ill to polar) Kaltiatt film POAN tht,.wgb a
mar.; its bright ioLvesaws with so, e a ft - 18 23 roe
09- Ilk r4lual filul 1114Y.; NAIfC(h 04 gal. +
F (Max.) - OAM 022 07.3 the 'drn' 14 MI-1 O.A. At 30' And NAHCO, 94 X./I. + NaLl 0*0
neve"ary to rr"; the -9;~. dmrraocs with increating dt.15'inerl Out frqtiirvkkt4-uI. Withtheedcctol
I e.g.. 8. -Is. 2b.33. T. - 3AO. 140.50 min. A130'. to thus chlaitlitnt. ifull"k-se CA I Ily A' 11 joutl4l it) rAtW r
adda. 0( NaVR)l (33.3 0.). N4%'0� (441.0 g.M. And I ittax.) It4iiii 0.72 Ilk 1) is). to Otorlro r. Ifolu M t. 44
zo 0
NACI (V-5 a./I.) to N&IIC(N ON c./1.) accelcrAt" [ilia.. r. (mill 114 to 441 noll.. &fill till, tatil Wacth of cry4to.
CITRIU. of the Iattrr. immaxingly in that order. In the front 244) to 175 inin. owitig to tuptvIllwition of the edects goINO
order given, r (max.) - 0.722, 0.90. 3.1 C./I./tain.. as o(chAnge. (if I and of is, *oIn4. Nal(Coj 124 ij./I. + NNCI
*quo. aplast 0.16 withatit adda.; r. - 85. 62.5 35 min.. as !I%'1g,/I.Cry%tAIIi1CfA~ICf 4I.&I'Mol ACE'.% Zt% the C&Ct
Agahl't ~N%). The r&Vt of the Wts vm%itts sitnuly In to al to avrrmupen-Alet thAt of 1; P jsutit.) - IIAW And 45
i Increase of 84 and 6 In actretticut with the known saly. at 3U' &tctd Will reip.; however. f. to blister at 3s, than
~Ai Zv" ld oh, system. To let. the purr cirect ot t. ft At 30'. thd CCOCI tit I IM114HIS614tilla 0VVr IhAt of Is tit this
(M. to be cot,'lt-t Ott di(Ec"Itt I Itid to be so, chow it N. Than 1:4411
fllgl.
k' MUM a.. It. \4 Ud
00
6-Y T
El U Is AV so AC; WX
Of 0, OP 61 b( It Or a It a INV at n I X4

a a
Oi 0 0
X
/Ice I
DUBOVITSKIY.A.M., kandidat tekhnicheskikh nauk; MARGOLIS,F.G., kandidat
tekhnicheskM nail
Production of non-caking ammonium nitrate. Khim.prom.no-5:136-139
Hy 147. (KLRA 8:12)
1. Hauchnyy Institut po udobreniyam i insektofungioidam
(Ammonium nitrate)

a 0 0 0 0 6 0 0 0 0 4 0 0 0 0 0 0
U 23 k is .1. 17 A
A, 4 L
0 4;
it
09
00
43
00
0*
0 0
10 11 V 13 M b b V lowsa 41 QU ifiss.mo
Productioc of storage-resistant antzscuium nitrate
A. M llitlmvit~kif and F. G. N(Arjuit%. Khi~ I ..... .. lee
1047, Va, 5. 8 f 1, NrAffinlc tmt4it Athl"I In qu.4tititi- -00
4 up to I' r"Incril thir moLmarr afr~swption oil it, -00
2 :1.5 times. This is attritstit"i to tht: furnuttioti of a hy-
drophuhic envelope around the particle, therrhv imcirristing g
the tuitimure fruits tunsing in contact with the NILNO, age
I~ttkim Ass midn. d 2-31-, of a -ob,tanur uch as Liu- 4
tin. 4~h. alutite ("cal, IMMT MCAI. II&MOIAl eArth. etC..
improml tile ~tomge rcsi%t&ijjcv still forther W Ifosell
zoo
zo 0
All zoo
tie 0
U04P
U**
10
An 10-9 4-42-4
0 0 a 0

MARGOLIS 0 F. 0.
'Tatalysts for the Production of K2SOL or Na2SO4 from KC1 or NaCl by
Reaction with SO2,11 S. I. Vollfkovich, and F. G. Margolis, Dole-lady
Akad Nauk SSSR., KLI, pp 23-5 (1943) (SEE: Inst. Insect/Fungi. in
Ya. V. Samoylov)
SO: U-237/49, 8 April 19419

MARGOLIS, F. G.
"Catalysis in Reducing Potassium and 50dium 5ulphates f rom Chlorides Decormosed With
Sulphur Dioxide in the Presence of Nrygen,"
SO: Dok. AN, 41, No. 19 1943. p-7-1-2-3
Mbr., Inst. Fertilizers & Insectofungicides, -1943-.

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of M61CO-Chl"M CAL FRORMIES OF AMOIJIUM
M~RAIS FRODUGSD 11% M U,5.S.R* A. Me WboTitski
lot
:0 and F. (J. Cban. Ind. huss.p 1938, 13p 158--
04
111 164).-The rate of absorption or 1~0 by f1wly-oryst. ~94
N03 (1) La> by coarsely aryst. (1), but the rinal lee
HZO rontent Is the saw. Storage In imprIornated
paper bags Involves the least Variation in 1;20 content. P roe
Under Central Asiatic conditions (extremes of heat tind
sea oold) the (1) undergoes o4lamorphio transformAtions
resulting In Inorsuse of role# with consequent burstlar.
00- of paper bagol these should therefore not be filled too
00'4 to capacity. Under factory conditions (I) is usually packed
while still w;Lrmj the storage proportion of the (I) COO
ars, greatly Improved If It ia packed at-< 320. R. T. 400
Coe,
woo
ASO-ILA A91AUVINGICAL LITINATLA9 CLASSWICATICIO
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