SCIENTIFIC ABSTRACT MASTRYUKOVA, T.A. - MASTYAYEV, N.Z.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


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USSR/Oi~anic Chemistry Sypthetic Orgaric Chemistry, E-2
AbBt Journal: Referat Zhar - Kl-~r,-Lya, N--)
6 V7 _r [Irliez.,layeva, Ye. N., Uvarova, N. I., Shosta&ov-
Author: %struykocrra, Tl%rAr,
--Ln.'Lk M. 1.
6 yy
Institution: AcadeW of Sc-,ences *'SSE
Title: On the Rea-tioi. of with Thiovinyl Ethers
Original
Periodical: Izv. AN SSSP, 3ection on Chemical Sciences, 1956, No 4, "3-4zG
Abstract: It is showr Llir--t 'IiC') !-S~33 (1,1 easily with C H2 = (I"
in accordance with Markoviiskoff's ruie with the formation of
(RO)2PSSCH(CH~)SRI (III). The following compounds of the type III
20
have been prepared (R, R', the yield in percent, bp in 0 C/mm, nD
and 40 are indicated in -chat order): C2H C2H 5 (IV), 70-75,
, 1.529,~, 1.1"cr2; C2H51 (' 1 9 1
110/2-5 1 '1+H9 M, 6~: 0 -110/2, ..5198,
i.o9651 C2 H~' C1,119OCB,2CH,2, 60, 123-125/3, 1.5125, 1-0940; 'so-C4H(,,
C2%, 78, l13-11:)12, 1-5070, 1-0556; isO-C09, C4H go, 1121-12212,
1.5 52, isO-C4Hc,, C),~iqOCH2C42, 60-8o, .4-?;6/3, i-50i2,
I-ard 1/2

USSR/OAanic Chemistry - ~~rganic '-'~~emiqtry, E-2
Abet Journal: Referat Zh~.x - fQ--:Lmlya, No i, 9r;'
Abstract: 1.0422. rne szr.lc-~ux-e of 11:: vas established by their sy-r-thesis,
carried out as fol 1V and V, from CH(SR,'
(C2H50:)2PSSK (VI) and CH3 '-1
(VIII) as well a.,, by cleavage of III v th HgC!2 in alcohol; the latter
reaction ~7-~Ci(OC2R,)- (VIII;, R'SHgC1 (IX) aDd (ROVS-31'9C.1;
the last na-med j.'.Eiproport--4onates or purification to '-TPCI)2PSj2Hg (XI
and 2 moles of HC-. The HC,'- ::ar be titrazed quantiatively with N
H.), are addek-,
NaOH. For tb!a s~,nQiesls -of TV, C.Ocy moles (R = C2
0-068 moles I, 11R z C"H5) at 60-620; the mixture is shirred for 3u
minutes and allowed 1*.~ stand 12 hours, after which it is distilled.
The remainLng I!-- cLn ae prepared by ttie same method. Wf.~ei- . -)-,
moles VII (R : c2H;'; are aided dropw'.se -.0 0.05 moles of VT J-; L-. 1L_
ether and a mLxt-,1xe. heated 3 hours at 400, followed by filtratioi. ol
the KCI, IV is obtained from the filtrate in yields of 52%. A sijLi-a:-
procedure can be used fo2:, the preparation of V in -11% yields .'rcu VI--
(R = CO N and V:. When 0.0036 moles IV and 0-0081 m01" H9Cl2 &re
reacted ti~ 11 ml 96% aicohol, VIII is obtained in yiaids of
the latter reaction also yields HC-1 (yield 97.7%), 0-8 gms Ix (11'
C2H5) and C..7 gmiz X ~R :: '21ic-,,, mp 121-1220 (from '-en7erje; ecom pos e~;
Card 2/2

KABACHKIK. R.I.; MLSTRYUKOVA, T.A.. KUROCHKIN. N.I.; RODIONOVA. N.P.; POPOV,
Roactivity of alkali salts of alkylthiophosphinic acid asters.
Alkylation and acvlation. Zhur. ob. kh1m. 26 no.8:2228-2233 Ag '56.
(mlak 10:11)
1. Institut slementoorganicheskikh soyedineniy AN SSSR.
(Phosphinic acid) (Alkylation)

atra,
a, I- tn - M cl~ C.
:5-j- j ._'9_16. -4u 1. 144b;,- 7,41%
0,0.1
ylu , I -
GRP
ajA t!
4 14 9 -1 NEU
!Jb- A
LOOM. ':11z !a zal;,Vtme Sbowed good
with s ic act*, lp~
7- -..r

MASTlWJKOVA, T. A. (Inst. of Elementary Organic Compounds AS USSR, Moscow)
"Research In the Field of Organophos-DhoruF Insecticides" (Issledovanjya v oblast4
forfororgfinicheski.kh insektitsidov)
Chemistry ~3nd 'j~-cs --f C,,-r-,c.-,cn,.hot1phornur. C(zipoundr,
s-Zredncr~iy),
Trudy of FirLt C~jnf~-rcnc(,, Decer2ber 195~1, Kazan,
pp. Fublisbed by Kritc--n Affil. A,7) USSR, 19c~~,
3
Research carried on in lab. of organophosphorus compounds under direction of M. I.
Kabachnik, Corr. Mbr. AS USSR. Report discussed by B. A. Arbuzov (Chem. Inst. im.
Acad. A. Ye. Arbuzov, Kazan Aff. AS USSR), V. A. Yakovlev (Institute Of the Brain
AM USSR), Yu. S. Kagan (Kiev Inst. of labor Hygiene and Occup. Diseases), and
H. I. 14ellnikov (MMIF im. Ya. V. Samoylov).

/"///'S 7
USSR/Chemical Technoioa Chemical Products and Their 1-4
Application. Pesticides
Abs Jour Ref Zhur - nimiya, No 1., 1958, 2321
Author Msti7akova, T.A.
Inst Aca-TEky of ~Sciences USSR
Title Research in the Field of Oroanopho3phorur. Insecticides
Orig Pub Sb.: Klaimiya i primeneniye fosforgan. soyedineniy. M.,
Ali SSE23, 1957, 148-162. Diskus., 162-163
Abstract A review. Synthesis of a number of esters of thiophospho-
rous, thio- and dithiophosphoric acids and studies of
their insecticidal action.
Bibiiography 14 references.
Card 1/1

()v,7 9-28-6-2 9/6 3
AUTHORS: Mastryukova, T. A., Odnoralova, V. N., Kabachnik, M. I.
TITLE: On the Reaction of Dialkyldithiophosphates With Ethylene
Sulfide (0 reaktaii dialkil--ditiofosfatov s etilensullfidom)
PERIODICAL: Zhurnal obshchey khimii, 1958- Vol. 28.. Nr 6, pp. 1563-1568
(USSR)
ABSTRACT: Some time ago the authors published a paper on the binding
between dialkyldithiophosphates and ethylene oxide (Ref 1)
on which occasion the P-oxysubstituted esters of dithio.-
phosphoric acid form without difficultyt
(RO)2PSSH + CH --CH 2 ---* (RO) 2 PSSCH2C112OR
In the present paper in this reaction ethylene sulfide was
taken instead of the oxide. The investigation showed that
the dialkyldithiophoophates combine with ethylene sulfide
to dialkyl-.S-P-mereaptoethyldithiophosphates:
I -* (RO)2PSSCH
(RO)2pSSH + CH~-----CH 2CH2SH
Card 1/3 S

sov/79-28 -6 -29163
On the Reaction of Dialky1dithiophosphates With Ethylene Sulfide
Contrary to the oxide reaction this binding demands more
stringent conditions. The reduction with ethylene oxide
takes place already at room temperature and that of ethylene
sulfide only on heating. In Table 1 the constants and ana--
lyses of the obtained dialkylm-S-p-mereaptoethyldithiophos-
phates are shown. They are colorless and thermally instable
liquids, they are soluble in organic liquids, cannot be
solved in water, and decompose in,alkali liquors. The ace.-
tylation of their sulfohydryl groups takes place easily:
with acetic anhydride in the presence of pyridine the co:r--
responding acetyl derivatives were, for instance, obtained
(see scheme 3); their constants and analyses are also men.-
tioned (Table 1). The P.-mercaptoethyldithiophosphateB re-
act with diazomethane in the presence of methyl alcohol with
the sulfohydryl group being methylated (scheme 4). Products
of similar kind had been known already earlier (Ref 1o);
they belong to the-,.--=-Ifective insecticides arranged in systems.
There are 2 tables and 8 references, 7 of which are Soviet.
Card 2/3

SOV / 79-28-6-29/63
On the Reaction of Dialkyldithiophosphates With Ethylene Sulfide
ASSOCIATION: InBtitut elementoorganichaskikh soyedineniy Akademii nauk
SSSR (Instituteof Elementa-l-mganic Compounds,AS USSR)
Vsesoyuznyy nauchno-issledovatellakiy institut iskus3tven-
nogo volokna (All-Union Scientific Research Institute for
Synthetic Fibers)
SUBMITTED: May 3-2, 1957
Ethy!E-Tiec,,--Cher-~ial- :ea-tio-s 2~ T~I-op!
I
actim,-.
Card 3/3

50) SOV/79-29-5-9/75
AUTHORS: Mastryukova, T. A., Shipov, A, E., Kabachnik, M. 1.
TITLE. Method of Preparation of Dialkyl-Thiophosphinic Acids (Meted
polucheniya dialkiltiofosfinovykh kislot)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 5,
PP 1450 - 1453 (USSR)
ABSTRACT: This paper reports on a method of synthesizing dialkyl-thiophosphinic
acids with different radicals on the phosphorus. The scheme of
this method can be represented by the folloving equations:
(RO )2P"0 + WMex --* R'2POMgX + 2ROMgX + RIH
RI2POMgX + S -+ R 1 2PSOMgx
R 92PSOMgX + HCI ---> RI2PSOH + 2 .',gXCI
According to this new method R 2PSOH-acids (R= C 2H5P C311 7' 'so-
C3H79 C4R9' 'so-C4H9 and C6H5CH2) were obtained. The yields were
Card 1/2 64 - 86%. In the table constants, neutralization equivalents,

Method of Preparation of Dialkyl-Thiophosphinic Acids SOV/79-29-1-9/75
data of the elementary analysis and yields of the resulting
acids are summarized. The formation of the dialkyl-thiophosphinic
acids according to the new scheme was coafirmed by the symthesis
of the ammonium salt of the dipropyl-thiophosphinic acid. There
are 1 table and 16 references, 10 of which are Soviet.
ASSOCIATION: Institut elementoorganicheakikh soyedineniy Akademii nauk. SSSP
(Institute of Elemental-Organic Compounds of the Academy of
Sciences, USSR)
SUBMITTED: March 27, 1958
Card 2/ 2

5 (3)
AUTHORS: Popov, Ye. M.,-Mastrvukova. T. A., S07/79-29-6-zo/71'
I. "En~
Rodionova, N. F , Kabac ik, M. I.
TITLE: The Vibration Spectra of the Organophosphorus Compounds
(Kolebatelinyye spektry foefororganicheskikh soyedineniy).
On the Problem of the Characteristics of the Frequency P-S
(K voprosu o kharakteristichnosti chastoty P-S)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 2-9, Nr 6,
pp 1998-2006 (USSR)
ABSTRACT: The investigation of the vibration spectra of phosphorus- and
organophosphorus compounds leads to the conclusion that in
molecules with the group P-0 a vibration occurs in which this
group plays the main role. For the structure and the analysis
of the phosphorus compounds also the spectral characteristics
of the group P-S is of interest. In order to determine the
so-called characteristic frequencies of the group P----S the
infrared spectra and the Raman effects of the organothio-
phosphorus compounds were obtained in parallel tc the
corresponding thiolphosphorus and phosphorus compounds, In
Card 1/3 the compounds investigated the bands connected with the group

The Vibration Spectra of tho OrganophonphoruB SOV/79-20-6-50/772
Compounds. On the Problem of the Characteristics of the Frequency P-.:i
1
P-S are in the range from 750 to 580 cm- . The frequency of
the normal vibration of the molecule in which thi3 group
participates, is considerably subjected to the structural
influences; in this connection each type of the substituents
changes the frequency by a certain amount, The frequencies
which are related to group P~S (Table 2) conserve their
constant values only if the central phosphorus atom is
surrounded by the same atoms or radicals. The bonds and the
angles which have no common atom with the group P~S do not
participate in the given oscillation and practically do not
influence the f-requency. A final explanation could not yet be
given, The authors thank L. 3, Mayants for valuable advice,
There are 2 figures, 2 tables, and 18 references, I of which
are Soviet.
ASSOCIATION: Institut alementoorganicheskikh soyedineniy Akademii nauk SSSR
(Institute of Elemental Organic Compounds of the Academy ef
Sciences, USSR)
Card 2/4

5 (3)
AUTHORS: EaBtryukovaf T. A., Yelentlyeva, T. A., ---0V/"19-29-1-18/93
,Q ov Z-- 91(dohnik, M. I.
TITLE: The Application of the Hammette (Gammette ?) Equation to the
Ionization Constants of Organophosphoric Acids in 7- and 80 %
Alcohol (Primeneniye uravneniya Gammetta k honstantam ionizatsii
fosfororganicheskikh kislot v 7 i 80 % spirte)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, 7,r 7. pp 2178-2182 (USSR)
.LBSTRACT: In connection with investigations in the field of the tautoraerism
of organophosphorus compounds (Ref 3) 'the authors determined the
apparent ionizution constants of the phosphoric acid series of
the general formula: A 0
B 011 in 7- and BO alcohol. It
Was of interest to investigate to %,.,hat extent the Hummette
(Garnmette ?) equation (1g -L = yE(T) holds in the case of these
Ko
solvents. It was especially interesting because the authors
determined the ionization constants of some types of phospKoric
Card 1/3 acids which earlier had not beon ineaeured, i.e. of diaryl

The Application of the Hammette (Gammette ?) Equation :~07/79-29-7-'. 81/87
to the Ionization Constants of Organophosphoric Acids in 7- and 80
phosphinic-(A=B=Ar) and diaryl phosphoric acid (A=B=ArO). "he
results obtained, to.-ether with some other data marked ?,.-ith
asteriks (Ref 3) are given in table 1. The constants q' for the
axoxy groups at the phosphorus have hitherto be,!n unk-nown. Their
apparent ionization constants (PY-1 and p1:2) of phenyl Luid
diphenyl phosphoric acid as well as of tolyl and ditol~,l
phosphoric acid were determined in 50 % alcohol as far as the
constants .9 and pK for the ionization of phosphoric acids in
this solvent are computed precisely enough (Ref 1). The results
obtained (Table 2), from which the mean values IV' for the
groups C 6H50 and C 7 H70 were computed, may be found in the last
column of table 2. The values found Cr were used for plotting
the diagram pKf`(2:cr) for 7- and 80 % alcohol and then exactly
determined by means of the data obtained from the t-ao solvents.
The final mean valtioc for the groupe C 611 50 and CH.,C6 1140 are
written do-on provisionally. There are 1 fiGure, 4 tables, and
17 references, 3 of which are Soviet.
Card 2/3

The Application of the Hammette (Gammette ?) Equation "OV/79-29-7-18/183
to the Ionization Constants of Organophosphoric Acids in 7- and 80 ~- Alcohol
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSTI
(Institute of Elemental Organic Compounds of the Academy of
Sciences, USSR)
SUBMITTED: Yarch 10, 1958
Card 3/3

5(2,3,4)
AUTHORS: Kabachnik, M. I., Academician, SOV/20-124-5-27/62
Mastryukova, T. A., Shipov, A. E., Melentlyeva, T. A.
TITLE: The Use of Hammett's Equation in the Theory of Tautomeric
Equilibrium (Primeneniye uravneniya Gammetta v teorii tauto-
mernogo ravnovesiya), The Thion-Thiol Tautomerism of Thiophos-
phoric Compounds (Tion-tiollnaya tautomeriya tiofosfornykh
soyedineniy)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, Nr 5, pp 1061-1064
(USSR)
ABSTRACT: The first and second axthors have proved (together with
S~ T. Ioffe) that Broensted's (Brensted) equation is appli-
cable to organo-thiophosphoric acids (Ref 3). The first au-
thor has also found that the relation between the equilibrium
constant and the ionization constants of the forms K1, = KISI"2S
is of fundamental importance in the theory of tautomeric
equilibrium. In accordance therewith the theory of Broensted-
Izmaylov regarding the acid-alkali protolytic equilibrium
(Ref 2) has been applied to the tautomeric equilibrium in so-
Card 1/4 lutions. Thus, a quantitative interpretation of the ion theory

The Use of Hammett's Equation in the Theory of SOV/20-124-5-27/62
Tautomeric Equilibrium. The Thion-Thiol Tautomerism of Thiophosphoric Compounds
of tautomerism has been suggested. The fact that Broensted's
equation is applicable to the organo-thiophosphoric acids
rendered determination of the position of the tautomeric equi-
librium of dialkyldithio-phosphoric acids (Ref 3) and of the
alkylthioalkyl-phosphinic acids (Ref 4) possible. There was
every reason to use Hammett's equation for the purpose stated
in the title. This was possible with the aid of two equations
(1), It must be borne in mind, however, that the experimental
measurements did not give the ionization constants of indi-
vidual forms but certain effective constants K a' which have
a certain relation ((2), Ref 7) to the ionization constants
of the forms, The substitution of K 1 and K2 from equations
(1a) and (1b) in relation (2) enables the constant K to be
easily derived from the parameters of Hammett's equation (3).
This relationship is graphically expressed with the coordinates
pK and E a by the curve pK a ' which is asymptotic to
Card 2/4 the two straight lines I and II (Fig 1).

The Use of Hammett's Equation in the Theory of SOV/20-124-5-27/62
Tautomeric Equilibrium. The Thian-Thiol Tautomerism of' Thiophosphoric
Compounds
This facilitates a derivation of the experimental method of
the quantitative solution to the problem. Table 1 giver the
effective ionization constants (pK a) of the series of the
tautomeric acids RRIP(S)OH RRIP(O)SH, which differ by
the R and RI groups and consequently by the Z o values
(calculated according to references 6,9). As may be seen
from figure 2, there is a good linear relationship for the
points having Z a values between -3 and -2. Prom the results
obtained the parameters of the straight lines
pK pKo were determined, which define the ioniza-
tion constants of the thion forms in 7 % and 80 % alcohol
(least squares method, reference 10). The values found for
the constants of' the tautomeric equilibrium must satisfy
Hammettla equation; log K - log 0 + Z a (5). Figure 3
T K~ ~T
shows the diagrams illustrating the dependence of log KT on
T-
&~-d based on the data of the table 1. As may bee seen, the
Card 3/4 relationship according to Hammett has been EXpressed well

The Use of Hammett's Equation in the Theory of SOV/20-124--l-27/62
Tautomeric Equilibrium. The Thion-Thiol Tauromerism of Thiophosphoric
Compounds
enough. Finally, the percentages of the thiol forms were
calculated with the aid of the resulting equations for the
solutions of all substances investigated (Table I). Based on
the deviations of the linear dependence of Hammett's PKa
of the tautomeric acids from a (or Z a), a quantitative
analysis of tautomeric equilibrium can thus be given, There
are 3 figures, I table, and 10 references, 7 of which are Soviet.
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk 33SR
(Institute for Elemental-Organic Compounds of the Academy of
Sciences, USSR)
SUBMITTED: January 26, 1959
Card 4/4

5.563o ybob8
sov/62 -W -1 -
AUTHORS: KLi~,a,Iinik, M. I., Shipov, A. E., Mastryukova, T. A
TITLE: Le L 'I, e p ~, j t ~ i e E'd 1 1 o t, .Lsl,ers, of' Hyponhosphorouo A,, 1
PERIODICAL: lzvestly~, Ak~-idemll kJLW SSSR. Otdeleniye kh1michC:,3k.1-,h
na~lk, N1. 1, p 14~, (USSM
ABSTRACT: The autho:-:3 !,eport that the Collowing esters of' hypo-
pho:,,phorou:, ~v~ld viere obtained for, the f1r%3t t-lme:
0 0 -

n
bp .5 mm),
(C11
O)P(0)H,
,
,,
D
(C~H O)P(O)H bp 11_7~~o (2 mm), n
2) D I - 42 50,
5
"
5
d 1.1120. They ape colorless liquids, decompose
eAsily at room temperature, become crystalline on -ooling
(about -200), are stored at -60 to -y00. It is oxidized
In alp and hydrolyzed with water. Since hypophosphorous
acid is very often considered to be an acid with a com-
plex anion:
Card 1

Letter to the Editor. Esters of
Hypophospharous Acid
1; 0
> p <
H 0
H+
78o88
sov/62-6o-i--j,1i/-7,,f-
the exls~ence of' its esters was In doubt. On !~he
other hand., A. 1. Rrodskiy and coworkers showed the
presence oC tautoriievl.,,~m:
H /
,,p /,0 P-OH,
Ho/ \ti 4;- tio-,
Card 21~1
WhIch argued for- the, possibii-Ity of' existence r)f' It:-;
este[-B . P, W;.I:-', COUnd UINt, h:;P0ph03j)h0P0U:3 W-Irl
reacts (in the cold) with kil .-.oall(anes to f'orm
indicatLng that hypopho~3pho t~u Lis acid has a covalent.
not compilex structupe. The I'act that oiiiy I mole o,"
diazoalkane r,eacts with 11yoophosphorous acid (eve!1, it)
the preseice of' a larue excess of diazoalkane) in(i!~-z~tes
I

Letter to the Editor. Esters of'
Hypophosphorous Acid
that the following form prevalls:
78088
RO 0

ASSOCIATION:
SUBMITTED:
Institute of Element-Organic Compounds, Academy of
Sciences USSR (Inst-itut elementoorganicheskikh
soyedineniy Akademii nauk SSSR)
October 1r.,, 1959
Card 313

KABACHNIX, M.I.;IOFFE, S.T.; MASTRYUKOVA, T.A.
Tautomerism in aprotic media. Tautomeric equilibrium of phosphorus
thio acids in benzene and chlorobenzene. Zhur.ob.khim- 30
no.8:2763-2767 Ag 160. (MIRA 13;8)
1. Inatitut elementoorganicheskikh soyedineniy Akademii nauk
SSSR.
(Tautomerism) (Phosphorus acids)

MAS T.A. GEFTER, Ye.L.; KAGAN, Yu.S.; FAYKIN, D.M.; SJUBANOVA,
,-56 ~--- KA
M.P.-, GAMFIR, N.M.; Y3WIMOVA, L.F.; KAIWBDIK, M.I.
1~ioophoro3rganic insecticides. 3-Chlarobutanyl-2-Dhosphates and
thiophosphates. Zhur. ob. lehim. 30 no.9:2813-2816 S 160.
(MIRA 13:9)
1. Institut elementoorganicheskikh soyedineniy Akademii nauk SSSTI.
(Insecticides)

VA9=nT-~~ 7 T. A., K. FTRT-.-~T)V, N. I'l-
UL77, '/D-K V, , R.
rusla)
117-ie Si-nificance of Dnic Grou and ~f its .~-.)sition in ar
Anti-Cho'Zinesterase Substancc Mole3ulle for its Inter-a-t' n
witi C~,olinestemlses and for har-nacolo-ic Effects."
at tlp,~ --~) Tntemati npl Biocie~niqtry
M-.scow, 1)-16 Au,u.9L ' ~,Q

VOLKOVA, R.I.; GODOVIKOV, N.N.; KABACHNIK, M.I.; MAGAZAMIK, L.G.;
HASTRYUKOVA T .; MIMLISON, H.Ya.; ROMKOVA, Ye.K.;
.9 F*K.; WOW", V.A.
Chemical structure and biological activity of phosphorus
organic cholinesterase inhibitors. Vop. med. khim. 7 no.3:
250-259 MY-Je 161. (MIR!, 15:3)
1. lAboratory for the Pharmacology and Biochemistry of
Biologically Active Compounds, "I.M. Sochenov" Institute of
Evolutionary Physiology, Academy of Sciences of the U.S.S.R.,
and Laboratory of Organophosphorus, Institute of Elementoorganic
Compounds, Academy of Sciences of the U.S.S.R., Leningrad.
(C]IOLINESTERASES)
(PHOSFHCRUS ORGANIC CQKFOUNDS)

S/079/61/031/002/007/019
S' 34S0 BIIBIB208
AUTHORS: Mastryukova, T. A., Shipov, A. E., and Kabachnik, M. I.
TITLE: Method of synthesizing dialkyl dithiophosphinic acids
PERIODICAL: Zhurnal obshchey khimii , v. 31 , no. 2, 1961 , 507-512
TEXT: In view of Refs. 1-3, the authors synthesized dialkyl dithiophoBphinin
acids by reaction of dialkyl thiophosphites with alkyl magnesium halides,
connected with sulfur addition:
(PO)2p( S)H "' MRXI (Re PSMgX) 8 ~ (R0 pSSMgX) H' R' PSSH (Ref. 4).
1 2 2 2
The reactionsof diethyl thiophosphite with butyl magnesium bromide, with
sulfur addition, gave, however, tetrabutyl dithiodiphosphyl
(C4H9)2p(S)P(S)(C4H9)2 which also results from the sodium salt of the phos-
phite. Potassium dibutyl thiophosphite reacts with the Grignard reagent to
give a mixture of tetraalkyl dithiodiphosphyl and dialkyl dithiophosphinic
acid in low yield. The authors devised a method of synthesizing dialkyl di-
89514
Card 1/2

89524
B/079/61/031/002/007/019
Method of synthesizing B118/B208
thiophosphinic acids from dialkyl monothiophosphinic acids (Ref. 4) accordirg
to equation
PC1 NaSH H+
R2P(S)OH :-::4 R 2P(S)Cl 0 R2P(S)SNa R2PSSH. Of the two possible
reaction directions, the one according to equation
R2F(S)OH + PCI 5 ;N R2P(S)C1 + Pon 3 + HC1 (A) was found to be the only
correct one. This reaction proceeds smoothly with a yield of 80-95% of the
corresponding thioacid chlorides. The following reaction steps, i.e., reac-
tion of sodium hydrosulfide with the acid chlorides of dialkyl thiophosphinic
acids with subsequent separation of the free acid,also give high yields
(70-9*). Dialkyl dithiophosphinic acids are colorless, mobile liquids
which decompose on standing with H S evolution. They add to the double borA
of acrylonitrile; their sodium salis are alkylated to thioethers by alkyl
halides. There are 2 tables and 8 references: 2 Soviet-bloc and 3 non-
Soviet-bloc.
SUBMITTED: March 24, 1960
Card 2/2

MASTRYUKOVA, T.A. -
OTautomeriam, and structure of thioselds of phosphorus. Ifise of the
Hamet equation in the tboory of tautomaric equilibrium."
Klri"d.va i -'rimerseniye FosforvrCanlch--m~dO, liuredinf-niv ~Uheve-lqtr- I:,.
aimlication of orgarm-.)hos-)hDr,3~ conrourAit) A. 'q,, A -4 ~,I,
:'ubl~ by Kazar hffil. Acad, M-.3-cow 19i;2, , 't~
Collection of oupenu oresantt-d it Lhe ~,?~ ~,; - 11,
Chwdstry of ';umT)nijr4-).

MASTRYUKOVA, T.A.; SHIPOV, A.R.; KABACHIUKp M.I.
Dimethylphosphinothioic and dimethylphoi3phinodithioic
acids and their derivatives. Zhur.ob.kbim. 32 no.1-1:3579-3582
v 62. (141RA 15:11)
(Phosphinothioic acid) (Phosphinodithoic acid)

MASTRYUKGVA, T.A.; SAKHAROVA, T.B.; KABACHNIK, M.I.
Thin-layer chromatography of organothiophosphorus compoundF.
Izv. AN SSSR. Ser. khim. no.12:2211-2213 D 163.
(AURA 17. 1)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

KABACHNIK, M. I.; MASTRYUKOVA, T. A.; SHIPOV, A. E.
Reaction of phosphite amides and phosphinite amides with acid
anbydrides. Zhur. ob. khim. 33 no.l'-320-321 ?63,
(MIRA 16:1)
(Phosphinous amide) (Anbydrides)

KLBACHNIKI M.I.; MTRYUKOVAV T.A.1 MELENTIYEVA, T.A.
Ctmjugation phenomenon in the systems with a tetrahedric
atom, Part 2: Vinylphosphinic acids. Zhur.ob.khim. 33 no.2s
382-388 F 163. (MIRA 16:2)
1. Institut elementoo anicheskikh soyedineniy AN SSSR.
(Fhosphinic acid) Tonjugation (Chemistry)) (Vinyl compounds)

ROMANOVSKIY' YU.M.; HASTRYUKOVA, T.A.; BODROV, V.P.; POPOV, Ye.M.;
KABACHNIK, M.f.
Use of high-speed computers in the analysis of mtxturos of
organophosphorus compounds by their infrared spectra. Izv. AN
SSSR. Ser.khim. no.3:569-572 Mr 164. (MIRA 17:4)
1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova,
Instibit elementoorganichaskikh soyedineniy All SSSR i Inatitut
organicheakoy khimii im. N.D.Zelinakogo AN SSSR.

MASTRYUKOVAY T.A.; SAKHAROVA, T.B.; KABACHNIK, M.I.
Reactivity of thlo acid salts of phosphorus. Part 4: Reaction of an-
monium diethyl phosphate with dichlotoethene. niur.ob.khim. 34 no.l:
94-98 Ja 164. (MIRA 17:3)

KABACHNIKP M.I.; VOYEVOL'SYM, V.V.; MASTRYUKOVA, T.A.; SOUMNIKOV,
MEIJ-I'NT'YE'VA , T.A. -
Conjugation in the systems involving a tetrahedral atom. Flectrcn
pa-ramagnetic resonance spectra of some organophosphorus compounds.
Zhur. ob. khim. 34 no.10:3234-3240 0 164.
(MIRA 17:11)
1. Institut elementoorganicheskikh soyedineniy PJ4 SSLA' I lnsLitut
khimicheskoy fiziki ANI SSSR.

WC
S'T
i'me

KABACHNIK, H.I.;,.f4ASTRYUKOVA,,,T.A.,- VELENTIYEVA, T.A.; DOMROVSKIY, A.V.;
SW.VCHUK, M.I.
Conjugation in the systems with a tetrahedral phosphorus atom.
Part 1: Substituted benzovltripheny-lphosphincomthylenes. Teoret.
i eksper. khim. 1 no.2t265-269 W-Ap 165. (MRA 18:7)
1. Institut elementoorganicheskikh soyedineniy AN SSSR, Moskva
i Chenovi'skiy gosudarstvennyy universitet.

L 33128-66 94T m
C-1ZEp SOURCE, CODE: 165100610051069110698
M NR,-AP-6-02--4-i64 W01~2
matrosov, Ye. I.; Fi3hor, B.
AW11JOR: Kabachnik, Vi * Is ~sr m -
.Y -~k
pyq,--T ~s
mc,: institute of Organoelowntal Compounds, AN SSSR) Institut elemntoorganiches-
kildi soyedineniy All SSSR)
TITIE: Infrared spectra and structure of phosphorusmonothioncid salts
SOURCE: Zhurnal strukturnoy khimii, v. 6. no. 5, 1965. 691-698
TOPIC TAGS: IR spectrum, phosphoric acid, organic phosphorus compound
ABSTRACT: The Infrared spectra of salts of diethylthlophosphoric
and dimethylthlophosphorio acids wei6--studled. It was shown that
the anion of ammonlacal and alkali salts of these acids have a
mesomeric structure with the distribution of IonIc charge between
the atoms of the triad. Salts of nonalkall metals of diethylthio-
phosphoric acid evidently have an intracomplex structure. Depend-
Ing on the nature of the metal, the distribution of the bonds In
the phosphorus moiety can approximate the thlollo (Cu, Ag, Zn, and
Hg salts) or the thionic (Ca, Pb, and Mn salts) type. Salts of
heavy metals of dimethylthiophosphinic acid also evidently are
Intraeomplex In character, but their thionio character Is more
strongly pronounced. T. K. Nazarova and H. I - Volkova. took part in the experi-
mntal phase of the work. The authora-Diank G. B. ShRIUu-per for his valuable acIvice
during discussion of the work. Ori *art *has: 3 fijE;gs-and 13 formulas. fJPRB-7
SUB CODEz 07 / SUEM DATE, 12Fe 5 ORIG REF: 017 / OM RE-Ft 015
Card 1 0 UDC: 5M.343
118L - o 9 /Jr / 7 ff .3

MASTRYUKOVA, T.A.j MFIANTIYEVA, T.A., KABACHN.-K.. MA.
F,pactivi ty of pnospriorus arld sfi, ts. Part ~ : . F;
y i ,e.
phosphor- -ation ' V.r
7 -1 ~, n, " r ~r- PI.A i
P..F;
"nur. oL. khlrr,. . -;. 7 -, I -~ 1-"~ ~--. I ~ ,

MASTRYUKOVA.V.-T.A.! SHIPC",', k.F... AIVLYAYFVA,, V,V.; MUCHRA., Ye.Ye.~
K~BNMITIIA'~ M.I., Fjkridc-m~.k
Retic-'.-,'v.'t,y of ambident arlons. Aikylat-ior. of lodium Jeri',~anfrx-s
of ar-f,oaceti~, est.er and A-rtyla~!etone by rif.-",nyl axon~llm'
fluoborid-~. Dokll. AN SSSR 164 no.2040-3431 S '65.
OCRA --8:9"
1. inatlrut eleimertcorganif-heskilch soyedinenly AN SSSR,
--..0

ACC NRt AP6012080
SOURCE CODE: UR/0062/65/000/005/0895/08981
AUTHOR: Senyavina L. B.; Sheynker, Yu. N.; Zheltoval, V. N. Dombrovskiy, A. V.;
""iaba
Shevchuk, 9. i~n_ik, A.; Melentlyeva
ORG: Institute of the Chemistry of NaturaT Compound-so AN SSS.I( (Institut khimii
prirodny h
TITIT-1: Infrared spectra of aroyLme thyle tie t r i phenyl phn s phora ni 9 and their salts
SOURCE: AN SSSR. Izvestlya. Seriya khimicheskaya, no. 5, 1965, 895-09R
TOPIC TAGS: IR spectrwn, organic salt, organic phosphorous cr-mpound, el-ctron donor,
cyclic group
ABSTRACT: The inte(-,ri'- intenoities of the carbonyl absorption in the infrared
spectra of aroy1mothylenetriplicny.
'phosphoranes (in which the carbonyl group is
bonded to a phenyl ring) and their salts were moasured. The data were considered
from the ntandpoint of electron donor and electron acceptor properties of the
phosphorus atom and the aroukitic rini,-j or the aroyl group, as well as the influence
of substituents in the aromitic ring on the absorption intensity. The addition of
an aromatic group to the coLrbonyl in phosphoranea led to a decreaue in the frequency
and intensity of the valence vibration of the carbonyl group in compari3on with the
corresponding aliphatic derivatives, evidently as a result of the functioning of
the aromatic ring as an electron acceptor, competing with the carbonyl group for
electrons from the strong electron-donor phosphorus atom. The frequency and in-
Card 1/2 _U_ DG. 5-43 4Z4 It

ACC NR! AP6012080
-tensity of the C=:O vibration are also determined by the configuration of the mole-
cule, determined in turn by the size of the oubstituent at the carbonyl group. In
phosphorano salts, the totracovalent positive phosphorus playa tho role of an
lelec-iron acceptor, resulting in a sharp drop in the intensity of the C=O band in
-comparison with phoaphoranos. The absorption bands in the region of 1317-1390 cr~_
,for arylmethylenetriphenylpliosphoranes and 1389-412 curl for arovlmothyltriphenyl-
IphOBphoranes were tentatively aBeigned to the vibration of the P=C bands Orig. art.
has: 2 tables. [JPRS]
SUB CODE: 07 / SU13M DATE: 20Ju164 ORIG REFt 005 / OTH REF: 004
e- /~~'

Ad SOURCE CODE-: UR10413166,/000-101910030/0030
ACC NR,Ar6035680 (41
AUTHOR: -j%ja,s-try4kqvp,_T1. A.; Baranov, G. M.; Perekalin, V. V.;
~Kabachnik, M. I.
:ORG: none
!TITLE: Preparation of 0, O-dialkyl 1-methyl-l-hydroxy-2-nitroalkyl-
phozphonates Class 12, No. 186462
ISOURCE: Izobreteniya, promyshlennyye obra-tsy, tovarnyye znaki, no. 191,
1966, 30
TOPIC TAGS: =phosphorus compound, dEft
phosphOnate) QAAJ~4~c- OAJL-Z~-
ABSTRACT: In the proposed method, 0,0-dialkyl 1-methyl-l-hydroxy-2-
nitroalkylphosphonates are obtained by the reaction of
0.0-dialkyl acylphosphonates with nitroalkanes in the
presence of basic catalysts, e.g., diethylamine. (PSI
[WA-50; CBE No. 141
SUB CODE: 07/ SUBM DATE: OqSep65
Cardl/I UDC : 5-47-t-2~6 1118 .07

MASTRYU40VA, V. M. C,~nrl '.'ec z~~i -- (diss) "On the proble7 o" r: - .- c. ,. -. - -~ - s
of trophic di.,~ordrrs in cps, F -)I' I -,c, I p- `e - S of' 1nrfe (loses of ioni zinv.
irm.digtion." Mos, 17 ;, (Ac-i ~'eri ~.ci W961R.), 2t~ .o ies
(KL, 3~-E,8. 107)
- 1!k3 -

MASTRTIJEDVA. V.M.
Changes In vascular permeability caused by the local effect of
ionizing radiations in large doses [vith BummnrY in English]
Ued.rad. 3 no.2t66-71 Mr-AP158 (MIRA 11:5)
(ROENTGEN RATS, aff.
local irradiation on vase. permeability of skin (Rus))
(SKIN, eff. of radiations on
x-rays on vase. permeability & lymphntic vesselo (Rus))
(LYNMTIC VESSELS, off. of radintions on
x-ray on lymphatic eirc. of skin (Run))

RAS!ERYMVI, V.H.; POLIVODA. A.I.
Changes in the elastic and viscous properties of the skin following
massive doses of local irradiation [with summary in Inglish]. Bio-
fi2ika 4 no.1:101-107 Ja 158. (MIRA 12:1)
(SIUN. eff. of radiations,
x-rays, on elastic & viscous properties (Rue))
(ROENTGEN RAYS, effects,
on skin elasticity & viscous properties (Rue))

PUASE I BOOK EXPLOTrATIOII SOV/51,55
Kiselev, P. X., Professor, 0. A. Gusterin, and A. 1. Strashinin,, Edo.
Voprosy radiohiologii. t. Ill., Sbornik trudov, vynahchennyy 60-lotiyu ao
dnya rozhdpniya Professors M. N. Pobcdinskogo r4oble= in Radiation Biology.
v. 3-. A Collection of Works Dedicated to the Sixtieth Birthday -)f Professor
M[ikhaill N[ikolayevichl Pobcdinskiy (Doctor of Y44.icinel) 1--ningrad.
Tsentr. n-ioal. in-t md. radiologii 14-va zdravookhrananiya SSSR, 1960.
422 p. 1,500 copies printed.
Tech. Ed.: P. S. Peleshuk.
PURPOSE: This collection of articles is intzmded for radiobiologists.
COVERAGE: The book contains 49 articles dealing vith pathogenesis,, prophylgr1op
and therapy of radiation diseases. Individual articles describe investigations
of the biological effects of radiation carried cut by vorkars of the Central
Scientific Research Institute for Yedical Radiology of the Ministry of Public
Health, USSR. [Tsentrallnyy nauchno-Issledovatel'skiy lawtitut meditsinakoy
raaolog:Li Kinisterstva tdravookhraneniya WSR] during 1958-59. The follming
Card 1/10

Problems In Radiation Biology (Cont.) SM/5435
topics are covered: various aspects of primary effects of radiation, the
course of some metabolic processes in animals subjected to ionizing radiation;
reactions in irradiated organisms; m3rphologic changes in radiation disease;
and reparation and regeneration of tissues injured by irradiation. some
articles give attention to tie effectiveness of experimental medical treatments.
No personalities are mentioned. References accompany almost all of the articles.
TABLE OF CONM S:
Foreword 3
Gusterin, G. A., and A. 1. Strashinin. Professor Mikhail Vikolayevich
Pobedinskiy (Commemoratina his Sixtieth Birthday) 5
Lebedinnkiy, A. V. (Yember, Academy of Medical Sciences USSR),
11. 1. Arlashchenko, and V. H. Fast On the Mecl~nlsm of Trophic
Dis Ionfzlyg-Radi.FIOV~a- 3.1
Zedgenidze, G. A.,[Member, Academy of Medical Sciences USSRI, Ye. A.
Zherbin, K. V. Ivanav, and P, R. Vaynahteyn. Hormonal Activity of the
Adrenal Cortex in Acute Radiation Sickness and the Effect of Desoxy-
corticosterone Acetate on the Disease 17
Card 2/10

YASTRYUOVA, V.M.
Changes in the lymph circulati= following hig-Y, local dozes
of ionizing racliation. Med. red. 5 no.1:23-28 Ja 160. (YITV, 15:3)
(MIFE)
(RADIATIO111-THYSIOLOGIGAL EMGT)

S/219/62/054/olO/003/004
D296/D307
AUTHORS: Mastryukova, V.M. and Strzhizhovskiy, A.D
TITLEt The reaction of the corneal epithelium to
local irradiation with different doses of
soft x rays
PERIODICALt Akademiya meditsinskikh nauk SSSR, Byulleten'
eksperimentallnoy-biologii i meditsiny, v.54,
no. 10, 1962, 107 - 110
TEXTs The authors studied the mitotic changes in
the corneal epithelium of white mice after local irradiation with
various doses of soft x rays. Doses of 100'r (296 r/min), 700 r
(296 r/min), and 2000 r (600 r/min) were applied at a voltage of
20 kv, at a focus distance of 10 cm, through a 0.1 mm Al filter.
The x rays were kept at a degree of softness permitting their
complete adsorption in the cornea. The irradiated as well as the
control mice were killed simultaneously on the 1st, 3rd, 5th, 7th
and 9th day after the exposure. The cornea was fixed in Bouin's
Card 1/2

3/219/62/054/010/003/oo4
The reaction of the corneal ... D296/D3O7
solution and the sections were stained with Weigert's hematoxylin.
For each mouse the number of cells and the number of normal and
pathological mitoses was counted in 100 fields of vision. In the
control animals the mitotic index reached in the morning (peak of
mitotic activity) 8.3 %&,, irradiation suppressed the mitotic index
and led to the appearance of pathological mitoses (multinuclear,
giant-cells etc.) All 5 doses used decreased the mitotic index and
differences became manifest only in the rate of restoration; irra-
diatio.n*blocka the passing of the cells through the full mitotic
cycle and prevents regeneration. As the normal pru,.;css of desqua- f
mation continues the number of cells decreases in the experimental
animals. Only the dose of 2000 r caused direct radiation damage
to the corneal cells. There are 3 figures.
SUBMITTEM: August 9, 1961
Card 2-12

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t
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6
a d: rabb ts. i6h -- b6ne,marrow
ci~6v-ocul,ar_-*fluld7 nomArradtate-, ails. They
[ALF 01 .-, - - --- - - -, - - --.11- . . . ml :_.: ;~l % -

ACCESSION 11M: AP3007750 S/020.5/63/003/005/0667/0S70
AUTHOR: Mastryukova, V. M.; Strzhizhovskiy, A. D.
TITLE: Effect of high energy protons on the lphysiological
regeneration of the cornea epithelium
SOURCE: Radiobiologiya, v. 3, no. 5, 1963, 667-670
TOKC TAGS: high energy proton irradiationp cornea ep eli-um'
mitosisp chromosome aberrations, radiation dose, genetic eff(i---f,--
relative biological efficiency
ABSTRACT: Experimental male mice were exposed to total high energy
proton irradiation of 200 or 500 r on a proton synchrotron.
Following irradiation the mice were killed at different periods
ranging from 1 to 9 days and contrDl mice were killed for the same
periods. The cornea epithelium was stained for microscopic
examination. The number of mitoses per 10,000 cells and the number
of chromosome aberrations in lihe anaphase stage were couhted for the
two lower reproductive la-yers of cells at the periphery and in the
center of the cornea. It was found that 200 and 500 r radiation
doses inhibit mitotic activit-7 and decrease the amplitude of daily
CoM 1/2

ACCESSION 10: - AP3007759
mitotic activity oscillations. This decrease is particularly marlmd
in the period between the 3d and 5th days for,the 200 r dose. The
number of cells within the microscopic field of vision decreases
slightly. The correlation between radiation dose and its genet16,;
~effect is linear with a maximum level of chromosome aberrations in
the first few days after irradiation. The relative biological
efficienc7 of proton radiation geneti6ally is .6--7- Orig. art. has:
2 tables.
ASSOCIATION: None
,SUBMITTED: 22Dec62 DATE ACQ: 22Oct63 ENCL: 00
.SUB CODE: M1 NO REP SOV: 003 OTHER: 001
Card 2/2

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LZBEDINSKITY, A.V.; MAI.TRYUYOVA, V.M.; NAFHJL'NT'f.;KAYA, ".N.; I " *.
Effect of !-cn-'z-'ng racila-,Ion on ',he s-,ae of rega- -!c.v-~ - 1.c ', -. ~- ~
in the organism. Radlnbl'ologiia 4 no.",'V-93-70C) '(4
(!-'~ ~j,

ACCESSION NR: AP4042357
S/02119/64/058/007/0106/0109
AUTHOR: Mastryukova, V. M.; Strzhizhovski7, A. D.
TITTZ: Effect of ionizinj3 radiation on the 24-hour rhythm of mitotic
activity -In the corneal epithelium of mice
SOURCE: Byulleten' eksperimentallnoy biologli i meditsiny*, v. 58,
no. 7, 1964, lo6-log
TOPIC TAGS: ionizing radiation, rRdiation damage, mitotic activity.
rhythm, corneal epithelium, local radiation, whole-body radiation,
mitotic Index, tissue metabolite level, general metabolism damage
ABSTRAGT: The effects of local and whole-body irradiation on the 24-
hr mitotic activity rhythm of corneal epithelium were investigated in
i 200 white mice in two experimental series. In the first series the
corneal epithelium of mice was exposed to local soft x-irradiation
(Dermamobil unit, 30 kv, 15 ma, filter 0.1 mm Al, 1533 r/min) of
single 200 and 700 r dooon calculated to be almost completely
absorbed by the corneal epithelium, In the second series mice were
1/4

ACCESSION NH: AP4042357
x-irradiated (RUM-3 unit, 180 Irv, 15 ma, filter 0.5 mm Cu + 1 mm Al,
20 r/min) with whole -body single 200 and 700 r doses. The animals
were all irradiated in the morning. Groups of experimental and con-
trol mice were decapitated at 8 AM or 3 PM on the 1st, 4th, 7th, and
10th days after irradiation. Preparations made from the cornea were
stained with hemotoxylin and the mitotic index wag determined by the
.number of mitoses per 10,000 cells. The mitotic index for the
corneal e Ithelium of control animals was found to fluctuate from
15.75 at 9 AM to 4-18 at 8 PIA. With a 200-r local radiation dose,
mitotic activity fluctuations of the tissue are completely depressed
24 hr after irradiation, are partially restored by the 4th day, and
axe completely normal by the 10th day. Mitotic activity fluctuations
are similar for a 700 r local radiation dose. For a 200-r whole-body
.radiation dose the effect is comparable to that of a 200-r local
radiation dose, but mitotic activity fluctuation is only partially
depressed after 24 hr. With a 700 r whole-body dose mitotic
activity fluctuation is even loss depressed, but with passing of time
,the fluctuation amplitude decreases significantly compared to the
.other mitotic indices, The authorst explanation for the mitotic
.activit7 fluctuation is based on the position that there ia a relation
Card 2/4

ACCESS1014 HR: AP4042357
between mitotic activity of the tissue and the tissue level of
"determinant metabolites" necessary for mitosis. A distinction should
:be made between direct radiation damnie and radiation damaCe of the
general metabolism as they relato to determinant metabolite"
synthesis. The authors hypothesize that with local irradiation when
general metabolism changes are insignificants the intensity with which
the "determinant metabolites" enter the irradiated tissue is practic-
1 ally unaffected,, but the intensity of their utilization by the
dividing cells sharply decreases as a result of depressed mitotic
~activity. This results in an excessive accumulation of "determinant
Imetabolites" in the tissue, the tissue becomes temporarily independent
.of metabolite synthesis intensity# and mitotic activity fluctuations
,are depressed. With restoration of mitotic activity the fluctuations
.become normal. In the case of whole-body irradiation the intensity
~with which "determinant metabolites" enter the tissues decreases
Ibecause of general metabolism damage and fewer metabolites accumulate
,in the tissue during depression of mitotic activity. This explains
:the incom late disappearance of fluctuations 24 hr after whole- body
p
jrradiation. With a whole-body 700-r dooep general metabolism
,radiation damage increases with passing of time and the 24-hr
Card 0/4
- -- --------------------

!ACCESSION NR: AP4042357
~fluctuations gradually disappear. The 24-hr mitotic activity rhythm
appears to reflect the "determinant metabolite" level fluctuations in
the tissue resulting from the 24-hr fluctuations in general
1,metabolism, intensity, Orig. art. has: 1 table.
i.ASBOCIATION: Non
1SUBMITTED: 22jui63 ATD PRESS a 3077 ENCW 00
ISUB CODE: La NQ, REP 80vt 014 OTHER: 001
Cord

MASTYUMVA, Ye.M.
Role of birch injury and asphyxia !n the orig4r, of mental
reta -1dati on. Zhur. revr. 1 64 nr-7110r,3_10,57 16i_
(~47RJ, 117; J_),
1. Kafedra dGtskoy pBAkhAati-.'A (zavedu3-ushchly ---, r~. To.
Sukharevri~ -ir,3*,'t-,1tn us,)vHr:-,herTtv,-)vanIya vrar,,.-y,
MO a k-va .

fK) V A. S A R~ !q 'V A !I . 7 -R OV A 'fu EYIA,
fiemagg I I r- a,.: ng ~,c 13 '1, F,
no.6,- -/C'--7'16 N.-D tf)~.
~~L4 t
Mc. 9 kva

~MIAROKCI'l,
mrn
mr
Mi. ~- I, v -3 K -v I a

KASTYA'y E7h
PA 5^T?"
UBM/neotricity Jul 1947
Motors, Electric
WfIcIency; Industrial
"Increasing the Coeff icient of Capwity at Petroleum
Industries," 11. Z. Wetyayev, WI, 4 pp
"Mhergeticheskiy Byulleten'" No 7
Presents methods to increase coefficient of capacity
coo f . 1) selection of capacity of asynobroncuo en-
g1nes and transformers; 2) selection of type of
asynchronous engine; 3) utilization of synchronous
engines. suggests that me should be urged to produ,
a series of various static oonaeneors, one of the mo
effective methods of Increasing ooefficlent can f -

YO y e
AKIW,)V. Valentin Nikolayevich (deceased); APARDV. Boris Petrovich.
(deceased]; BALAGUFDV, Vladimir Alsksandrovich; GALTIM.
Fedor Fedorovich; EDROBAN. Nikolay TimofeTevich; LARJOIJDV.
Andrey Bilrolayevich, redaktor; HAS Nikolay Zostmovich;
SENWICH, A.M., redaktor; EKYOWWY, .9 Tweimnlenalm
redaktar.
(Princi lee for the electric equipment of airplanes and auto-
mobilsel Osnovy elaktrooboradovanils samoletov t avtomashin.
Pad red. A.N.Larionova. Moskva. Goe.energ.imd-vo. 1953. 384 p.
(MLR4 8:12)
1. Chlen korrespondent AN SSSR (for Larionov)
(Airplanes--Electric equipment) (Automobiles--Xlectric
Equipment)

'AUTHORS: 1)Larionov, A. N., Professor, SOV/lo5-58-7-1/'~2
Correspondinr, _-em'ber. Acade!.iy of Sciences, USSR, j!L_Lsty-.ye_--r,
Z.2 _1
1.1 . Docent , C-~:,Iida.e of Technical Scinnces, Or
Engineer
2)Panov, D. N., Candidate of Technical Sciences
TITLE: General Problems of the Theory of Hysteresis Motors (Obshchiye
voprosy teorii gisterezisnykh elektrodvigateley)
PERIODICAL: Elel:trichestvo, 1958, Nr 7, pp. 1 - 6 (1JSSR)
ABSTRACT: The first work on hysteresis motors was begun in the USSR in
1950, by the Professorial Chair of Electric Ec 'uipment of
Aircraft and Automobiles at the ?VTEI and later also by other
Scientific Research Or,-,anizations and Works. First, the
operational principle is described here. Next the character
of magnetic reversal and the field distribution in the rotor
are dealt with. Here the law governing the field distribution
in the rotor by taking account of rotor-hysteresis is inves-
tii;ated for the most general case: A cl-ar~--ed mot-Jr of
Card 1/5 reversible construction with a rotor which has in internal

deneral Problems of the Theory of Hysteresis Motors SOV/105-58-7-11/1 32
case (box) or rim(ring). If this rule is known, the formula for
the electromaaretic hysteresis-moment and for the paramters ef
the equivalent circuit scheme for the hysteres~is motor can be
found. It is assumed that ma,-netic permeability p ant, The
hysteresis an.-le y do not depend -in inductance. Work is based
upon some mean values. The error occuirinC in this connection
can be estimated at 2o%. Moreover, it is assumed that: 1) t ',*e
normal induction-component of the rotor-surface facing the stator
is distributed according to tile cosine-like law; 2)there Lire
no eddy currents in the material of the rotor; ~) the field
in the machine Is plane-parallel. It is shown that the character
of field distribution and of magnetic reversal of tne material
of the rotor may differ according to the properties of the
material, the dii,_iensionr;, the construction of the rotor and
the number of poles of tile motor. The electroma#,-rietic morient
and the parameters of the equivalent circuit schev~e are inve,,-.--
tigated in tile last chapter. The principle of posEible displace-
inents and generalized coordinates is applied and the equx,tiorl
for the electromagnetic moment of tile hysterefiis mot. )r (1') is
Card 2/5 written down. The formulae (17) for the effective component

General Problems of the Theory of H:.-steresis 11.1otors SOV/1 '~' - 1.~2
F2a of the maCnetizing fDrce of the stator a.%d formu_-i 16')
for the reactive componeiA F 2p of the same are lerived. The
equivalent circuit scheme of an ordinary asynchronr),us mot3r
and the formulae (17) and (18) are applied and the equivalent
circuit scheme for the hysteresis motor is obtained, The de-
termination of the parameters of the rotor circuit in the
equivalent circuit scheoie is briefly discussed, The ex 'pc-rience
gathered with projecting of hysteresis motors shows t,"..t mot3rs
with a relatively thin rotor have the best characteriLtics,
also where the one induction-component predominates and vhere
the other may be ne,-,-lected. For this case , f ormulae f or a m -,* -jr
with internal rotor with tan'l-ential mat-,netization and furt:,er
formulae for a motor with intc-rnal rotor and ma.,.-netac box (ra-
dial magnetization) are written down, The equival-rit cir-~:uit
scheme for the hysteresis motor can be built up on. t,.e lia-is
of the equivalent circuit scheme for an ide;11 hyste.-C-.:~i:3
and of one for an asynchronous mot~)r with a nassive. r -, r
Card 3/5 (witnaut taking account of the influer~ce of hi. :.(?r %._r!7,()nic

General Problems of the Tineory of' 11.,/oturecit3 Motors SOV/1o') Ili-7-1/,;2
maGnetizing forces of the stator) by adding the cirrult of
the eddy currents to tne scheme of the ideal motor, The cal-
culations of the characteristics of a series of motors
according to this equivalent circuit scheme with circuit iara-
meters obtained by -gay of testin-7 agree well with tl,e
iBtics obtained by expuri~-;ents. Unfortunately, it i.,; not
possible, at presej;t, to produce analytical terms for the
parameters of the eddy current branch, which. can be determined
only expc-,rimentally, The three ran.-es of the rotor in a
hysteresis motor with different mainetic permeabilities ere
investiE;ated. Tf~ere are 7 figures..
ASSOCIATION: 1.)Moskovskiy enerjeti(,,heskiy institut (Moscow 1n!,,tit1;tC- r,f
Power Engineering)
2.)Taganrogskiy radiotekhnicheskiy institut (Tai-arrog In.
stitute of Radio-En,:ineering)
SUBMITTED: October 219 1957
Card 4/5

General Problems of the Theory of Hysteresis Motors SOV/105-58-7-1/32
1. Electric motors--Design 2.-Elektilic motors--Theory 3. Hysteresis
Card 5/5

V.ATX , Yurly Mikhaylovich; )LASTUTEV, kBnd.tekhn.nauk. retBenzent;
BOROVSKIKH, Tu.I., kBnd.tekhn.nauk, retsenzent; GOLIEBERG, G.I.,
inzh., red.; FALIKO, O.S., red.izd-va; SLIKIND, V.D., tekhn.red.
[Electric equipment of automobiles and tractors] Blaktrooborudovanie
avtomobilel i traktorov. Moskva, Goo.rwuchno-tekhn.izd-vo mashino-
stroit.lit-ry, 1960. 275 p. (MIRA 13:11)
1. Kafedre *Blektrooborudovaniye samoletov i avtomobiley" Roskovskogo
energaticheBkogo institute (for Mastyayev). 2. MoBkovBkiy avtome-
khanicheskiy institut (for Borovskikh).
(Automobiles--Electric equipment)
(Tractors--Electric equipment)

26228
3/103/61/022/009/009/014
13, ~rlc D206/D304
AUTHORS: Mastyayevq N.Z~q and Orlov, I.N. (Moscow)
TITLE.- Starting time and its effects on the performance of a
hysteresis gyroscope motor
PERIODICAI? Avtomatika i telemekhanika, v. 22, no. 9, 196i,
1-220 - 1228
TEXT? The starting time of a gyroscope very often determines -~he
time of readiness of the instrument and it is of importance 1-n ihe
gyroscope design to evaluate the maximum motor power for an assumed
stariing limed In the present articles the authors derive ana'.y-
tically the starting time, the maximum theoretical power of a hy-
steresis motor required for a given starting time and analyze w1th
respect-to the above, certain of the motor characteristics, The
starting time of a gyroscope hysteresis synchronous motor is de-
rl-ed from bag.,-. a5sunpilons as an approximate
Card 11/7

26228
S/103/61/022/009/009/014
Starl,-Ing time and its effects D206/D304
to dw (5)
2n km -(k - k + I)
W40 m 0 W
which after Integraiion becomes
km
(6)
M k - k 1 lg k - 1~1
2n M 0 0
where M2. - nominal loading moment g. am$ J moment of inertia of
2_ *
revolving parts of the motor g. cm see synchronous angular
frequency of the motor rad/sec; k. Ms.c/x9n; Ko - the overload
coefficient ko = K2n/Mm, where Mm. the maximum moment at synchro-
nAWand K = Jw (gem sec) - the kinetic moment of gyroscopej 'to -
in sec. Expression (6) permits evaluation for a given hysteresis
Card 2/7

26228
S/103/61/022/009/009/014
Starting time and its effects ... D206/1)304
motor with known K, N 2np k 0and k. - starting time ts and also
analysis of the influence of various motor parameters on it. K and
N2n are expressed in terms of dimensions and of parameters of the
motor, with a cylindrical fly-wheel (Fig. 3) K is then expressed
by
K = jWs = 1.047-10-5 Y 5 !~[l _ (!-b)'In (g am sec), (7)
N DH %
and V 2n' within the range of D. and n is expressed by
P2nIA105 LH 5
N2n ~ 1.03n - 0.97 (a opo~ (1 + 5 B: )10 (g cm). (8)
In the above two expressions DH, DbP LH dimensions are as in Fig.
5 in am; I - specific weight of the flywheel material in g/cm3;
Card 3/7

26228
S/103/61/022/009/009/014
Starting tizre-~and its effects D206/D304
n - r.p.m.; 0 0 - the ventilation loss factors p - density of sur-
rounding medium in g sec2/cm4~ pl - viscosity of the medium, a.Iftb
= 1 + PDA Pvent - factor determining the amount of losses in the
overall resistance moment due to losses in the bearings P B and to
air friction. Pvent both in watts. From Eq~t (7) and (8)
K _i0 IH/% T 1 - (1) "/ D" )
M2n 1.08, 10 DJH 1 - 5LH/DH (aopo~/Fpr) tsec) (9)
is easily obtained. Its accuracy is stated to be jood enough for
a0~~4 1 or for gyroscopes with small kinetic moments and operating
K vacuo. When solving an interse problem, i.e. when designing the
power required for a given starting time t 8 the maximum electroma-
gnetic power of the motor is derived as
Card 4/7

26228
S/103/bl/022/009/009/U14
Starting time and its effects D206/D304
+ 5 Li,
-V 73 DE
5 (a op0Yu -\Ln
P 0.956-10 K I W- x ~1 J~
e4. max 2DH [1 (Lb)
DE DH
LH
+ 0.78,10 -i0 -CH DH (watts)(17)
-"v' "H
~a 00" YP') ta-V/n- (1 5
DB
where c Eq- (17) permits designing the gyroscope motors and
v k
consequently to relate the siar,~ing time t to the motor parame-
Card 5/7

I '
LEM
S/'103/61/022/009/009/014
Startingtime and its effects D206/D304
ters. Finally, since all electrical energy absorbed by the motor
results in heat dissipation, it is shown that with decreasing star-
ting time ta the temperature To of the motor increases according
to
IT0 PI K
T 0 rM Plo= 1 + O~725 (I - -to) taX2n' (26)
0
Several experimental data obtained for ditferent gyroscope motors
are within 25 % of theoretical data from the expressions in the
present article, It is stated that although such accuracy cannot
be considered as satisfactory it could be accepted for approximate
design criteria. There are I table, 3 figures and 1 Soviet-bloc
reference.
SUBMITTED,- January 21, 1961
Card 6/7

MMAYEV N.Z,,, ka~.tekhn.nauk, dotsent; ORIDV, I.N., kand.tekhn.nauk
Optinnm relationships for hysteresio-type electric motors.
RIektrichestvo no.7:51-58 JI 162. (MIRA 15:7)
1. Moskcvskiy energeticheskiy inutitut.
(Electric motors)

MASTYAYEV, N.Z., dotsent
Special featureB in the design of automobile and tractor
starter motors. Trudy MEI n0.39:257-274 162.
(MA 17-6)

LEVIP, A.F.;41ASTYAYEV,-N.Z.-, kand. tekhn. nw-ik, retsenzent;
GALKIN, Yu.M.., kand. tekhn. nauk, red.; VASILI'LIEITA,
I.A.p red.izd-va; GORDEYEVA, L.P., tekhn. red.
(Reliability of the electrical equipment a-rid dt!viees of
motor vehicles and tractors] Nadezhna,-~tl avt3trail'tornogo
elektrooborudovaniia i priborov. Moskva, Mashgiz, 1963..
114 P. (MIRA 17:2)

YAS'17YAYEV,,,A-
-.Z.;~ ORLOV, I.N., YUFEROV, F.M., dots., retsenzent;
BOBOV. K.S., prof., retser---entj I-P-RIONOV, A.N., prof.P
red.[deceased]
[Hysteresis motors) GisterezisrWe elektrodvigateli; po-
sobie dlia diplonnogo ii karsovogo proektirovaniia. Mo-
skva, Mosk. energ. in-t. Pt.2- LProbleMB of design] Vop-
rosy proektirovaniia. 1963. 186 p. (MIRA 17:2)
1. Chlen-korrespondent AN SSSR (for Larionov).

MASTYAY-LT N.7A,,jcand.tekhn.nauk, dotsent; OPJOV, I.N., kand.tekhn.nauk
Some problems concerning the design of a hysteresis motor.
Elektrichestvo no.10:39-46 0 163. (MIRA 16:11)
1. Maskovskiy energeticheskiy institut.