SCIENTIFIC ABSTRACT MAVRODIN, V.V. - MAXA, P.
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December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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NAVRODIDI. V.V.; VABILITEV. A.A., nauchrWy red. -. ROZMWAIRB. I.Ya., red.
[Memorable places in Leningrad Province] Pamiatrqe meets leningradekot
oblesti. Imaingrad, Gb-fo po rasprostrananiiu polit. i nauchnykh
znanti RVSR. Leningr. otd-nie, 1957. 44 p. (HIRA 11:5)
(Ioningrad Province-Deecription and travel)
"HAVROBIN# VladUdr VasilOyevich
(11cononle growth of Hassis, the domestic and fon)i~p policy
of toarism at the and of the 17~h and during the first half of
the 18th century; lectures read at the Leningrad Interprovincial
quadrennial party school] Mronomichookil root Rboolt, vnutronnials
I vneshniela politike toarism v kontse XT11 - pervol polovins
XV1.I1 vake; laktoli. prochitwuWa v Leningradskol wshoblestuol
chetyrekbg9dichnoi partiinoi shkole. KDskva, Tyashain partiinals
obkols pri TsX EM. Kafodra Istoril SSM. 1957. 67 P.
(MIRk 12:6)
(Bassis-Iconomic conditions) (Russia--Foreign relations)
PHASE I 1300K EXPLOITATION 866
Mavrodin, Vladimir VaBillyeirich; Sladkevich, Naum Grigorlyevich;
-- ------------- Ell -'s-a-z--~~rb
S ZV,----~on ~dA ek wich
Leningradskiy universitet; kratkiy ocherk (Leningrad University;
a Brief Sketch) [Leningrlkdl Izd-vo Leningradskogo univ-ta,
1957. 127 P. 3,570 oopiei3 printed.
Sponsoring Agency: Leningradskiy universitet.
Ed.: Vostokova, E.S.; Tech. Ed.: Vodolagina, S.D.
PURPOSE: This book was written for persons interested in Leningrad
University and also for Persons who are enrolling in the
University and who desire to obtain concise information about it.
COVERAGE: This essay on Leningrad University gives Information
about its history, about the activities of its outstanding
Card 1/2
Leningrad University; a i3rlef Sketch 866
scientists and professors, and about the lives of statesmen
and famous social, literary, and political figures who were
educated at the Univers1ty. Among those listed are, Herzen,
Chernyshevskiy, Lenin, D.I. Mendeleyev, and such scientists
as: I.P. Pavlov, (physiology), A.S.Popov (radio), and
Lebedev (physics). Famous writers, painters and sculptors are
also mentioned. The book describes the faculties, institutes,
professorial chairs, laboratories, scientific and publishing
activities, and other special features of the University.
TABLE OF CONTENTS:
History of the University From 1819 to 1917
5
Leningrad University After the October Revolution, 1917 - 1945 34
The University in Recent Years 77
AVAILABLE: Library of Congress (LF4373.M35)
Card 2/2 JP/Jmr
11-24-58
V C C 'D /, Itl) ~/ V
AUTHOR: Mavrodin, V.V. 12-1-16/26
TITLE: Against the Falsification of the History of Geographical
Exploration (Protiv fallsifikatsii istorii geograficheskikh
issledovaniy)
PERIODICALt Izvestiya Vseeoyuzriogo Geograficheakikh Obahcheetva, 1958,
pp. 81 - 86 (USSR)
ABSTRACTs This is a review of a book on arctic exploration, by
K.S. Bagidin, a Hero of the S%viet Union and we 11 known
navigator, "The Road to Grumant" (Put' na Grumant) published
by the TsK VLKMS " Molodays, Gvardiyall publishing house in
1953. The critic reproaches Bagidin for utilizing falsified
r4wr'ence material and not only of giving wrong historical
picture but of influencing other authors. The critic considers
the role of the book to be negativet it cannot be approved
by Soviet scientists.
There is one Russian reference.
Ancient Russian name of the Spitsbergen Archipelago
AVAILABLE: Library of Congress
Card 1/1
SOV-3-58-8-26//26
AUTHORS: Struve, V.V., Academician; Viatkin,
Predtechenskiy, A.V., Revunenkov, V.G., Professors; Ste-
fanikbinqV.V., Docent ; and Gusyatnikov, P.S., Candidate
of Historical Sciences
TITLE: Letters to the Editor (Pis1ma v redaktsiyu) To Create the
Scientific History of the Country's Vuzes (Sozdat' nauch-
nuyu istoriyu v-uzov strany)
PERIODICAL: Vestnik vysshey shkoly, 1958, Nr 8, pp 95 - 96 (USSR)
ABSTRACT: The authors point out the outstanding rolo which the coun-
try's higher educational institutions have played in nat-
ional and world's science, in training intellectual per-
sonnel and in developLng the country's industrial forces.
They advocate the writing of a scientific history of every
vuz and considers thia to be a matter of urgency and of
great educational importance.
Card 1/1
HAVRODIN, Vladimir Vasillevich.
Russian navigati n on southern seas (Black Sea. Azov Sea and Caspian Sea) from
ancient times to the last century. Simferopol', Kr7rizdat, 1955. 178 P.
1. Black Sea - Navigation - Hist.
2. Caspian Sea - Navigation - Hist.
3. Azov, Sea of - Navigation - Hist.
~.LVRODINII,,.Y.V.. daktor IstorJoheckildi nauk, IEW.D. G.N., Iand.teklm.nauk
t, ~ I
Raviewa and biblirig-aphy. Vest. All 8&'~'R 35 -31 1~5.
c'
(ULTRA l8z8."l
UVWDINDY. N.
Diagnostic value of various precordial leads In electrocardiography;
preliminary commanication. Naacb. tr. ISUL, Sofia 2 no.1:221-236
1953.
1. Ratedra po vatreshni bolesti sue surdechno-sudovi zaboliavaniia
Zav. Katedrata: dots. V. Toonchev.
(ZMTRDCAIRDIOGReff,
precordial leads, diag, value.)
MAVFDDINDV, 1l.; TOSHKOVA, B.; BOTEV, B., JLADUILSKA , A.; DDBERVA, I.
Treatment of hypertension by irradiation of the mesencephalon.
Suvrem.med., Sofis, 6 no-3:59-63 1955.
1. Is katedrate, po vutreshni bolestl sue surdechno-sudovi-sa-
bollavantle, pri ISUL (sav.dots. Y.T.Tsoacber), Fengenovila
Institut, pri ISUL (zav. prof. G.Tenchov) i XVII polikliniim pri
SGIM na TST - Sofiia.
(HYPUTINSION, therapy
x-irradiation of mesencephalon (Bul))
(RADIOTHERAPY. in var.dis.
hypertension. irradiation of mesencephalon (Bul))
(MMENCEPHAWN, eff. of radiations on.
x-rays. ther. of bypertension by mesencephalon irroLdiation(Bul))
RAVRDDIMY. N.; SOKRWV, Mr.; MADZHAWV, G.
Some functional manifestations of hypertension during treatment
In the health resort of Blanka. Suvrem. zed., Sofia 7 no.9:41-46
1956.
1. Is III vutreshna klinika pri ISUL (Direktor: dots. V. TBonchev)
I sanstorlys No 2-Bankia. (G1. lekar: D. Kochankov).
(FffPXRTNNSION, ther.
determ. of pbysiol. manifest. during & after ther.
in health resort)
KAVRODINOV, N. I BBWV,, IU; MMOV, Kh.; FOFNIKOLOV, S.
Discussion on our experience with patients with beart disease
SUMI d br classical clinical methods from the viewpoint of
valvalotoW. Suvr. mad. 34 no.113-7 163.
(NIIM STENOSIS) (RHMATIC RMT DISME)
HEw suRGm) (Rom cAmmaZATION)
RMTROGARDIOGRM) (PHONWARDIOMIAPHI)
SOV/133-59-6-23/41
AUTHORS: Protskly, N.Ye. and Mavrodiy, P.D.,, R4;inearz
TITLE: Introduction of Cooled Piercing
Mill (Vnedreniye okhlazhdayemykh opravok na
diskovom proshivnom stane)
PERIODICAL:Stalts 1959% Nr 69 PP 546-550 (USSR)
ABSTRACT: On the basis of experience of operation with various
designs of wator cooled mandrels a new design was
developed on the works (Fig 1). Its main features
are: comparatively thin nose; internal and external
water cooling. The method of fixing the mandrel to
the bar and the diagram of the water cooling system are
shown in Fig 4 and 5 respectively. The suitability of
a nit ber of steels for water cooled mandrels were
tested (table 2), the best results (table 3) were
obtained with 3Kh2V8 steel and satisfactory results
with steels 12KhN3A and 12N3A. Small mandrels can be
made satisfactorily by machining stamped semis, forged
in accordance with the external shape of the mandrels.
The durability of water cooled mandrels on 140 disc
piercing mills was 10 to 15 times higher than that of
Card 1/2 ordinary mandrels. In addition, working conditions of
SOV/133-59-6-23/41
Introduction of Cooled Mandrels on a Disc Piercing Mill
mill operators were improved (number of operatora
decreased by 6 men) and the basis for a complete
automation of the mill was presented. There are
7 figures, 3 tables and 3 Soviet references.
ASSOCIATION:Nikopollskiy Yuzhnotrubnyy zavod
(Nikopoll Yuzhnotrubnyy Works)
Card 2/2
FOLUMN, P. I., prof., d6ktor tekhn. nauk; OSAWRIY, V. Ya., kand.
tekhn. nauk; GOLUDCHIK, R. M., kand. tekbn. nauk; RYMOV, V. A.,
inzb.; KIRVALIDZE, N. S., inzh.: YESAULOV, A. T., inzh.;
GLAMEH2 D. V., inzb.; MAVRODIt, P. D., inzh.
Improving the grooving of roughing rolls of unit 400 plug
rolling mills. Sbor. Inet. stali i splav. no-40:319-~26 162.
(MIRA 16:1)
1. Moskovskiy institut stald i Yuzhnotrubnyy sawd.
(Rolle(Iron mills)) (Pipe mills)
L 43097- 6
ACC NR: AR6014379 (A SOURCE CODE: UR/O137/65/OOO/O117_150_3_7/'ff3
AUTHOR: Mavrodiy, P. D,
TITLE: The performance of two- and three-roller reduction stands in Nikopol' Pipe.
Plant
SOURCE: Ref. zh. Metallurgiya, Abs. 11D265
REP SOURCE: Sb. Materialy Konferentaii po teorii i praktike redutsir. trub.
Sverdlovsk, 1965, 170-171
TOPIC TAGS: pipe, metal working machine, metal rolling
ABSTRACT~% In the Nikopoll Pipe Plant four reduction stands are installed as part of
the i e manufacturing assembly. Great attention is paid to the perfection of roller
calibration to improve the quality of pipes, to decrease in the fraction of re-rolling,
and to promote unification. In the construction of new pipe assemblies it is
expeditious to install four-roller reduction stands with a combination of driving and
idling rollers in each stand. L. Kochenova
Oranalation of abatrsoV
SUB CODE: 13
Card 1/1 MLP UDC: 621.774.35.00
5.!
----------
GEMAOi Clara; GUTEMUER, I.; MAVRCKATI, Elena
Genetic study of wheat-rye hybrids. Studii cerc biol veget 13 no.3:
369-381 161.
1. Comanicare prezentata de Al. Priadeencu,, membru corespondent al
Academiai R.P.R.
---, .~C2Ata (Bucuresti)- MAVMMATI,, Elena (Ducuresti~;-
M
ORAUS ~ - -
Organogenesis of the reprodualve asm"to Of4mr3 4~.
Natura Biologie 15 no. 3: 3-13 015~-Je 163. .
ZARETSKITY, Illya Semenovich, dots. (deceaf-~ed];,IiliVi(('~'t~ATI, 11alina
Spiricionovna, dotq.; YEIREOLIN, N. F., loktor
V~
pr . , =e.
[Design of d.c. machines; courve dc~lign mlinwil] lumchet
eloktriche,sklkh mushin postoiarmoru toka; posobie po
kursovor.u proektirOVaT'AiU. lh,,nirigrau, P~.21. 18' .
( I -. I-` " A9 : L
1. Leningrad. Fiektrutukrm-lche-kly
elr',tricheskikh -j;shir.
skogo iristituta(for Z retsk-y,
shchiy kafedroy C.
Elektrote'Fhnicheskogo irstitiita (fcjr Yem-oiin).
14A lit Ul 5 T A*" , I
khir.
Voy:
tra
USSR / Human and Animal Morphology (Normal and S-2
Pathological). The Peripheral Nervous
System.
Abe Jour: Ref Zhur-Biol., No 10, 1958, 45515
Author : Navromati-,-A.-&1
In8t :-Ku--rbk ReOdIcal Institute
Title The Innervation of the Periosteum of the Bones of
the Skull. (Preliminary Information.)
Orig Pub: Sb.-tr. Kurskiy med. In-t, 1956, vyp. 3.1, 74-77.
Abstract: In the Innervation of the.periosteum (11) of the
participate
not.onl-ir branches
bones of the skull
of theArigeminal nerve,.but also branches of the
facial nerve and of the cervical plexua. Some
nerve!branches penetrate Int.o.the P spontaneously,
others through the thicknes8 of museleis and tendons,
and often proceed in a longitudinal direction,
Card 1/2
20
VRC14ATI,V.ing.
CURIJ, Flop iig,; GRIGORE, Livia., ing.1 PETRESCU, Maria., ing.,LM&
Processing of -the sulfurous complex concentrateB of heavy
nmferrojas metals in rotating furnaces. Re7. chimie Min.
petr. 19 no.821+45-458 Ag'6.
TRUIW.,.Ange3a;_ 14AWMAT12 V.; OIARU 0 Fl,
Modan methods of roasting cuprous ecacentrates. Rev chinie His
petr 23 no.6:334,~~39 Je 162,
TRIANDAF, Angola; HAVROMATI, V.; OIARU, Fl.
Modern methodg of roasting copper concentrates (II). Rev chimis
Min petr 13 no.7:589-395 J1 162.
ism -Won-m 14 -~- ---
~-- -.-I.- - --l -
~j
~. '_ -- 7 ~'~ -..- . ,
j, . .....
77
-- 16
I A 1 1.11 " lp I ,If .
I I
,, -I- r j ci;i "A )rs to lp tj-iri na t I on of scam r-t; .1rac toer 1 st ic s C) f the
tfichno,lw,lcul puso:-, and volatile dust from pyrometallurgic
of the -bmutntan nonferrous m(tttilwor~s. Rev rtimie Rin
y,c-,r 1~ -).11,6r7--66., 1 16,4.
V.
MAVROV, M.s. Gand Chem Sci -- (diss) "Synthesis of
ellemes
and their C`94maw,94
I
in a reaction of synthesis." Mos,1958, 14pp
(Acad Sci USSR. lnst of Org Chem im N.D. Zelinskiy)
1-10 copies (KL, 21-58, 88)
- 7 -
AUTHORS: Nazarov, I. N., Mavrov, M. V. 62-58-3-21/39
TITLE: The Dehydration of Vinylearbinols (Degidratsiya
vinilovykh karbinolov)
PERIODICAL: IzveBtiye. Akademii Nauk SSSR,Otdelenie Khimicheskikh
Nauk, 1958, Vol. Nr 3, pp. 365-366 (USSR)
ABSTRACT: In connection with the systematic investigation of the
diene condensation of hem-derivative butadiene (of the
kind of 1,1-dimethylbutadiene) the problem of the synthe.
sis of these dienes was formed. Similar dienes can be pro=
duced by means of the dehydrogenation of easily accessible
vinyl alcohols (of the type 1) (see table 1) as well as
by means of other unsaturated carbinols. The authors sue=
ceeded in working out a catalyst dehydration of unsatura=
ted alcohols (Refs. I-V). It is carried out in the vapor
phase on -the catalysts. The dehydration of alcohols took
place in the HerlTus (Gereus) oven with one passage of the
alcohols over the corresponding catalyst (see table 2).
Card 1/2 The catalytic dehydration of isopropylvinyl-methylisopro-
The Dehydration of Vinylctkrbinols
62-58-3-21/39
pylvinyl-,diisopropylvinyl-,dimethylallyl-,dimethylpro=
penyl-,methylisocrotyl- and isopropylpropenylcarbinols
were systematically investigated. New methods for the
production of hemdimethylbutadiene substituents were
found.
There are 3 tables and 3 references, 1 of which is Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo
Akademii nauk SSSR (institute for Organic Chemistry
imeni N. D. Zeiinskl~y,, AS USSR)
I
SUBMITTED: October 45, 1957.
Card 2/2
AUTHORS: Nazarov, I.N.(Decoased), Mavrov, M.V. SOV/79-28-11-0/55
TITLE: Diane Condensations of the Hem-Substituted lutadienes.1
(Diyenovyye kondenestsii gem-zameshchennykh butadiyenov.1)
PERIODICAL: Zhurnal obahchey khimii, 1958, Vol 28, Nr 11, Pp 3061-3071 (USSR)
ABSTRACTs As far as there is always one of the alkyl groups in hem-substituted
dienes in the cis-position it was of interest to inveBtigate systma-
tically its behaviour in the reaction of the diene synthesis. The
1,1-dimetky1L-,1,1,4-trimethyl- and 1,1,4,4-Letramethyl butadiene
were selected as hem-Bubstituted dienes. First, the synthesis of
the two Iatter was carried out. In the catalytic dehydration of the
compoumd (111) on zirconium dioxide and pumice easily separable
mixtures of (IV) and (V) were quantitatively obtained at about the
same ratios (Scheme 1). Compound (VI) was obtained by the dehydratim
of the isopropenyl carbinol in the same way (Scheme 2). In contrast
to the result obtained by Bacon (Bekon-Ref 3) (VI) and (VII)
(60 % : 40 %) were formed. The compounds (IV), (VI) and 1,1-dimethyl
butadiene with maleic anhydride yielded only amorphous polymer pro-
ducts. The use of methacrylate, acrylonitrile, crotonic aldehyde
for diene condensations reqaires more accurate temperature conditions
C
d 1/2 in a yield of
ields the adduct (X) only at 2150-2600
Thu
(IV)
ar ,
s,
y
Diene Condensations of the Hem-Substituted Butadienes.1 SOV/79-26-11-36/55
20-30 %. In the condensation (IV) with orotonic aldehyde (XIV) was
sepaid-ted. On heating the 1,1-dimethyl butadiene %ith acrylonitrile
an adduot mixture of (XV) and (XVI) is formed (Scheme 4), and by
its condensation with crotonic aldehyde the adduct (XIX) is formed.
Thus, the diene condensations of 1,1-dimath;yl- and 1,10A-tetavamethyj
butadiene take place under the previous iooinerization of the dienes
into the 1,3-dimethyl- and 1-isopropyl-3-methyl butadiene. On a
heating of (VI) with methyl acrylate the compounds(XXII) and(XXIn)
are obtained. There are 17 references, 8 of whicK are Soviet.
ASSOCIATIONs Institut organicheskoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry of the Academy of Sciences,USSR)
SUBMITTED: November 2, 1957
Card 2/2
30V/ 2o- 12o- 1 - 22/163
AUTHORS: Nazarov, I. N., Member, AcadeL-,j of Sciences, USSR (Deceased),
Mavrov, M. V.
TITLE: On the Dien-Alter-Condensation of Geminal Substituted Di~tad.ienes
(0 diyenovykh kondensatsiyakh gem-zameshchennykh butadiyenov')
PERIODICAL: Doklady Akademii Nauk SSSR, 191--8, Vol. 12o, Nr 1,
pp. 86 - 89 (USSR)
ABSTRACT: The question of the entrance of the mentioned butadienes into
the dien-alter-synthesis was open until very recently. Opinions
on such a poooibility differ. The authors chose for the purpose
of determinating such kinds of condensation the raost
compounds such as: 1,1-dimethyl-W, 1,1,2-trinethyl-(I1),1,1,3-
-tri-aethyl-(III), 1,1,4-trimethyl-(IV), some 1,1-dimethyl-2-iso-
propyl-(V)-butadiene and di-isocrotyle (VI). Ac dionophiles,
malein-anhydride, acrylonitryle, metacr;rlate and croton-aldehyde
(figure 1) were used. The I-, IV- and V1- dienes under differe-A
conditions of temperature, durations of reaction, LOlvents etc.
Card 1/3 produced only polymeric products. The 1,1-dimethyl-2-i.-opr.)i,,--le-
On the Dien-Alter-Condonvation of Gominal Stibatituted SOV/2o-12o-1-22/67
Butadienes
-(V)-butadienes as well as the 1,1,2-trimethyl-(II) with -ialciane
hydride (at looO for 15 hours) form adducts of a yield of 70
and 4cri'o respectively. Further investiE--tions showed that t,,e co--
pounds obtained comply with the adducts of the iconeric for,-..i of
initial dienes. The uce of dier;ophilos less reactive than ia-
leiane hydride requires h,-.rder temperature conditions. T*:iereby an
ample number of polyner is formed from the dienea I, IV, and V!,
whereas the condensation products show a yield of only 15 -30%~
It was possible to feed into the reaction all dienes already
studied (table 1). The structure of the obtained compounds as
well as the pro---ress of the above mentioned reactions is expiaine:71.
It was ascortcined that 1,1-dimethyl-butadiene and di-isocrotyle
enter into the dien-synthesis only after a preceding isomeriza-
tion of 1,3-disubstituted dienes. They form no sort of nor7al
condensation adducts. The 1,1,2-trimethyl, 1,1,4-trimethyl a:.d
1,1-dimethyl-2-isol)ropyl-butadieres apart from the adducto of
isomeric forms from also normal products of then 9,ynthcsio. Only
1,10-trimethyl-butadienes normally enters the mentionpd s.,-nt'~e-
Card 2/3 sis rcaction. There are 1 table and 5 references.
On the Dien-Alter-Condensation of Geminal Substituted SOV/2o-12o-1-22/63
. Butadienes
ASSOCIATION: Institut orrranichoskoy khimii im. N. D., Zolins-loL-;o Akademii
nauk SSSR (Institute of Organic N. D. Zeli~skiy)
AS USSR)
SUELIIITTED: December 21, 1957
1. Butadienes-Chemical reactions 2. Organic compounds-Synthesis
Card 3/3
OR (3 %
AUTHORS: Nazarov, I. R. Mavrov M. V. SOV/62-59-3-14/37
TITLE: Inv.stigation of Dehydration of Isomeric Hexenols (Issledova-
1ye degidratatsii izomernykh geksenovykh spirtov)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 3, pp 472-483 (USSR)
ABSTRACT: In the course of intense investigation of the diene synthesis
with endsubstituted dienes it was tried in the present study
to obtain the simplest representative of this class, the
1,1-dimethylbutadiene. One of the methods of production of thiE
diene is the dehydration of unsaturated hexene alcohols:
isopropylvinyl-(I), dimethylallyl-(II), dimethylpropenyl-(III),
and methylisocrotyl-(IV)-carbinol. As far as the three latter
are concerned the publications available contain an ample
but highly contradictory material. It was possible in the pre-
sent paper to carry out the dehydration of (I) in the vapor
phase on aluminum phosphate or zirconium dioxide which were
deposited on pumice stone. The investigation results are given
in table 1~ Both catalysts yielded about the same result: The
yield of conjugated dienes (V)-(VII) was 60-70 %, temperature
Card 1/3 and the transmission rate exerted no noticeable influence upon
Investigation of Dehydration of Isomeric Hexenols SOV/62-59-3-14/37
the distribution of the hydrocarbons. Only the degree of con-
version of (1) was affected. The dehydration of (II) yielded
on the same catalysts also mixtures of dienes (V)-(VII), but
in a diffe.-ent ratio. On the dehydration of (III) and (IV) on
zirconium dioxide a hydrocarbon was obtained which proved to
be nearly pure 1,3-diviethylbutadiene (VII). In interpreting
the results obtained it is to be considered -that first the
dehydration may take place in any possible direction, secondly,
that during the dehydrrtion an isomerization of the intermediate
carbonium ions readily takes place under the displacement of
hydrogen or the double bond; and finally, the isomerizing
effect of the catalyst which is accompanied by a displacement
of the hydroCen and the double bond, must also be taken into
account. In order to guarantee a normal dehydration such con-
ditions have to be established under which isome.-ization both
of the carbonium ions and the resulting diene-hydrocarbons
would be impossible. In the present paper also the pyrolysis of
isopropylvinylcarbinol-(VIII)-acetate, which can easily be ob-
tained by acetylation with acetic anhydride, was investigated.
As was to be expected the pyrolysis of (VIII) proceeded nor-
Card 2/3 mally and only
Investigation of Dehydration of Isomeric Hexenols SOV/62-59-3-14/37
1,1-dimethylbutadiene (V) was formed. There are 3 tables
and 29 references, 10 of which are Soviet.
ASSOCIATION: Institut organicheakoy khimii im. N. D. Zelingkogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelin-4dy
of the Academy of Sciences, USSR)
SUBMITTED: June 24, 1957
Card 3/3
5,(3)
AUTHORS: fiazarov, I. B., Navrov, N. V. BOV,162-59-6-18/36
TITLE: Structural Orientation of the Condensation of 1,1,3-Trimethyl-
butudiene (Strakturneya napravlennost' kondensataii 1,1,3-
trimetilbutadiyena)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nank,
1959, Nr 6p yp 1066 - 1070 (USSR)
ABSTEACT: By a previous investigation (Ref 1) of -the Institute mentioned
in the Association it has been shown that the compound mention-
ed in the title (I) with unsymmetrical dienophiles forms a
mixture of structure isomers. The present investigation was to
determine the orientation of the reaction of M with the most
simple dienophiles. This reaction is often dealt with in pub-
lications. (Refs 2-11). In the course of tho investigations
there were only the ortho-isomers founds s,11L attempts to dia-
cover also other possible isomers failed.. br synthesis of
1,113-trimethylbutadiene with scrylonitrile, which synthesis
lastad for 2 hours and was carried out at 2200, the authors
succeeded in obtaining an adduct - yield 7591"- which consist-
ed in a mixture of the cyclic nitriles (III) and (IV) meta-
Card 1/3 isoners~ 3.5%
structural Orientation of the Condensation of SOT/62-59-6-18/36
1,1,3-Trinethylbutadiens
CH3 CH.4 COOE
R.p A I
CH 4 ON ON COOH C00H
'~N -
ON III) OR ~j
3 H 3 1 3 PH3 HODC COOH
CH
H3~U ^. 4 4 --> 'd
A AC
H3 H3 C 1. COOR HOOC COOH
The above-mentioned mixture0was dehydrated by means of a
Or203/A'203 Catalyst at 480 in nitrogen current. Aromatic
nitriles were obtained. By treating them with caustic soda,
and by subseqTAent recrystallisation of the acid mixture a pure
2#4-dimethylbenzoic acid could be produced. When further treat-
ing this under pressure with nitric acid a mixture of trizel-
litic- an4 trinosic acid in a ratio of 3:2 was obtained. Thus,
the investigation dealt with by the present paper, besides the
Card 2/3 ortho-isoners, for the first time also lead to the nets-iso-
Structural Orientation of the Condensation of SOV/62-59-6-18/36
lpl,3-Trimethylbutadiene
mers from the reactions described. In the experimental part
the condensation and production of the different compounds men-
tioned are described in detail. There are 16 references, 5 of
which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences, USSR)
SUBMITTED: October 15, 1957
Card 3/3
5 (3)
AUTHOES: Nazarov, I. N. (Deceased), Mavrov, SOV/79-2c-1-27/77
M. V.
TITLE: Diene Condensations of Hem-sub3tituted Butpdienes (Diyenovyye
kandensataii gem-zamoshchennykh butadiyonov). 11. 1,
Trimethyl Butadiene (11. 1, 1, 2-Trimet-ilbutadiyen)
PERIODICAL: Zhurnal obshchey khimii,, 1950., Vol 29, 11r 4,
PP 1158-1168 (USSR)
LBSTRACT: The synthesis of 1,1,2--trimethyl butadiene (II) was first
described by Y. R. Nave-s (Refs 2, 3). H,? assigned tlie
structure of a meta-iBCmer to the affiliation product in the
condensation of (II) with croton aldehyde (Ref 3). This
conclusion was in contradiction with the assumed lavis
governing the structure.1 orientation of the diene synthesis.
The diene (II) was obtj7,ined according to scheme 1. The
formation of 2-isopropyl butadiene (III) was also to be
expected according to Vagner-Zaytsev. By dehydrating M
Naves and Ardizio (Ref 2) obtained a co'npound (melting point
104-1080) which was reGnrded " the dieve (II). The authors,
however, found by the dehydration of the carbinol (I) on
Card 1/3 potassium bisulfate, magnesium sulfate etc. that the reaction
1~iene Conlensations of Hen-stibstitute-1 7ut:,!i~ne-s. 1,1 1 0 - C
, / 7 7
II. 1,1,2-Trimethyl Buta-lienr,
product, consists of a mixture of the two pos~-,ibl- isomers (IT)
arid ~IIT)':50-10 of rlienp II). lh~-i striicture of tII) ani "IT.
Was confirmed by the oxidption with ner,-ma-n7annte. (II) ~oull
not be obtein r1 in any other way. Diene (IT) iso::ierized in thc~
iiene -yntbosia pn.rtiRll,! into the dien-iri (III) and (VI)
(.',chr~-ir- 2). For nomparison thr, diene conlensrstionr of !hCf7-
three iso-iers were therefore investicrterl. The -iene "'''I) was
synthesized according to scheme 3. Thus the oyntheqe3 of the
dienes (II), (TIT) nn~ (VT) were devised and tho.;r ~iene con-
densations with maleic anh,,dride, croton aldchyde and nethyl
acrylp,te investigFited. On the condensation of diene (II) with
methyl acrylate and croton aldehyde in addition to ordinary
affiliation products (20-40 4c) also adJucts of the isomeric
dienc-s (III) and (VI) were obtained. On the condensation of
diene (II) with -naleic anhydride primarily an adfuct is formed
which corresponds to the diene (VI). The diene condensations
of diene (III) with croton aldehyde nnd of (VI) with acryl
nitrile yielded a mixture of adducts containing 20-25 ""1 and
5-7 % of the meta-isomers, respectively. There are
Card 2/3 7 references, 2 of which are Soviet.
Diene Condensations of Hem-substituted Butqdiened. SOV/79-29-;-27/77
II. 191,2-Trimethyl'Butadiene
ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR
(institute of Organic Chemistry of the Academy of Sciences
USSIi)
SUBMITTED: March 3, 1958
Card 3/3
5 (3)
AUTHORS: Nazarov, I. :,. (Deceased), marrov, S OV/7 9 - 2 'Q2/7 -7
V.
TITLE: Diene Con,~ensation of flem-substituted Ditnd0,n;~n (Diy~novy,rp
kondenpritsij. r-en-zq,.n,,shchPnnykh hut-"-,4iyt?nov) 1 -TT
2-isoprop.~-l 73utpeftipne (III.
PERICDICAL: Zhurnsl obshchey khimii, 1959, Vol 21-), 'Ar 1,
pp 11f')9-1176 (US3R)
ABSTRACT: In the systematic investigation of dlene COndenSRtions with
heminal d`m-ps also the behavior of 1,1-iimethyl-2-isopropyl
butadiene-1,3 (N)-was investigated. In order to obtain this
diene the dehydration of Iiisopropyl vinyl carbinol (I)
(obtained by the condensation of diisopropyl ketone with
acetylene and subsequent partial hydrogenation of the triple
bond of the reaction Dro,luct (60 1"))) waR carried out;
UCH 3)2CHJ2CC.---4C'13)2C"J2C - CSCH----.iP ~, CH 3)2C"12 C-CTI~CTI2
OTT OTT (1)
(CH ) C=C=c1i-cit~11 C=C-CH-CH=CH
3 2 2 2
(n) ci-*(Cli (ITT) C11 CH(CH
Card 1/3 3 3 3
..No,
Diene Condensation of Hem-substituted 3ut,~tdienes.
Ill. 1,1-Dimethyl-2-isopropyl Butadiene
The formation of the dehydration product (1) unexpectedly
proceeded in a far more complicated-way. In the dehydration
via distillation on Dotassium bi-iulfate as well as on
zirconium dioxide in the varior phase the carbinv: 'I)
yielded a mixture (1 of' (II) and iITI) which iYere
separated by fractional distillation. The position of the
double bonds in (II) and (III) was determined by Investigation
of their oxidation products. By the ozonization of the diene
(III) the authors separated formaldeh~,Ip, nnd while acetone
Rnd isobutyric acid were separnted In'- tnP oxidat-",)n of the
diene (II) with permanganate. The fractLon boiling it
130-132*50, however, which correaponds to the expected diene
(II) seems to contRin an irmpurity of th2 other posF:ible isomer
(VI) which might be formed by the iso-nerization of the
hydrocarbon (III) (Scheme 4) as indicat:1 by the spectroscopic
investigation. For the investigation of the diene
condensations of diene (II) naleic anhy4ri!!e, acrylnitrile,
methyl acrylate, and croton aldehyde -,tp:-e used as pre,~,i.oiisiy
(Ref 3) (3chema '-). On the condensrition with acr,.,In~ltrale and
Card 2/3 methyl acrylate in addition to the normi.1 proiucts of -liene
Diene Condensation of Hem-substituted Butadienen. 30V/7(9-29-1-28/
III. 1,1-Dirriethyl-2-isoprolyl 'Iltadl;ene
synthesis the corresponding adduct
(up to 35 4)
1,)-dimethyl.-2-isopropyl butadiene-193 -.9 formed. There are
4 Soviet references.
ASSOCIATION: Institut organicheakoy khimii Akademii rinuk, SOOSR (Institute
of trganto Chemistry of the Academy of Sciencos USSR)
SUBMITTED: March 3, 195B
card 3/3
KUCHEROV,, V.F.; KUZNETS(YVA, A.I.; HAVROV, M.V,,* ALEKSEYET, Ye.F.
Chemistry of polyenic and polyacetylenic compounds. Report
NvOs V-wWacetylene- and vinylacetylenecarkoVlic acids
and sone of their transformations. Izv.AN SSkcR.Gtd.khim.nauk
no.31464-490 It 162. (MIRA 150)
1. Institut organichedkoy khimii im. N.D.Zelinskogo AN SSSR.
(Acetylene compounds)
FAVROV,, H.V.,- KUCHEELOV, V.F.
Chemistry of polyene and polyacetylene compounds. Report fio.7i
Hydration of u aturated acetylenic alcohols. Izv.AN SM.Otd.
khim.nauk no.7:1267-1275 n 162. (MM 15:7)
Is Institut organicheskoy kbimli im. N.D.Zolinakogo AN &SSR.
(Unsaturated compounds) (Hydration)
KIMNOV.. V.A.; ~AVROVt'Mjq MaZMVA, A,N,
Substituted cyclopentadionee and related compormdo. Part 1:
1#3-Dimethyloyclopentadiene. Zhur.ob.kMa. 32 nog.&2723-2731
Ag 162o (MM 15:9)
1, Institut arganicheakoy Wall AN SSSR Imeni N&D. Zelin.skogo.
(Cyclopentadions)
9 VqAv; ld~V ~H.V.; =aZMVA,, A.R.
Substituted cYclopenUdienee and related compounds. Part 3:
3,,5- and. 2#4-Dinethy1cyclopentenev. ZhurobAbiu. 32 no,8:2739-
2742 Ag 162. (MM 150)
1. Institut orgmdabeekoy kbinii AN SSSR Imeni NaD. Zelinske-go.
(Cyclopentene)
-HAVROV, M.V. -; KUCHEROV, V.F.
Cyc.Uzation of methyl ester of OC -propionyllevulinic acid.
Izv.AN SSSR. Sor.khim. no.1:164-166 A 164. (MIRA 17:4)
1. Institut organicheskoy khi'mii im. N.D.Zelinskogo AN SSSR.
. MAVROV) M.V.; IWCMDVJI V.F.
~-' ~-- ~. t - --. . -~ -I;-' -
Chemiatz7 of polyene and polyacetylene compa=ds. ?epGrt So.10: Ccr--
densation of 1-bromo-2,3-dimethy,1-2-penten-4-yne with a sodi= malonic
ester. Izv.AN SSSR.Ser.khim. no.9:1653-1660 S 164-
(MIRA 17:10)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
ester Oly-
p
Ld
=d
:,of jfej76_
0 Ce R
d- tile
WCIY -th
_tZe 6r
eyr".P,h ologicial- activity to w-
An. . -e
he
unsaturabe 1 -cmftjk6 ds"Lv~ lafed- to --'natiara I-ones
plex:,po y
id.
,j us -thd'fGl!pwing genera" scheme of synthesis based on the condonsation of
7
-V
r;c
S
Y
T (cill), MR
-4; BiGiat c..... Q-
it
c
4-7
cupro
pentynoate
(GHS), GOOCHI
V11
Cl
40#
4
- -.- ., -- . . - -. 7 - x - :- ~ I~ 1. -- T~ . , - I
.., r ~ -
HAVROL N.V.-. DERZ111NSKIY, A.R.; KUCHER0V V.F.
.9
Reaction Of inner-molecular cyclization of vinylazety'learc
systems, Izv, AN SSSR. Ser. khIm. no.8sl460-1462 165.
(MIRA 18t9)
1. Institut organicheskoy khimij im. N.D. Zelinskogo AN SSSR.
'IV M.V.; JiUCHEROV, V.F.
MkVRL
si, ! methyl ester of 4-bromc-2,,3-butadienolo acid. Izv.
Synthes s. of
All SSSR. Ser. kbim. no.8-.1494-1495 165. (MIRA 18:9)
1. Institut organic-heskoy khim-.Ii im. N.D. Zelinskogo AN SSSR.
PAVROV) H.V.j XUOHEROVS V,F.
Chezdstry of polyene and polyacetylene compounds. Report Ko.U:
Intramolecular oyelization of vinylacetylene derivatives. Izv,
AN SSSR. Ser. Min. no.lOtl820-1827 0 164. (MM M12)
1. Institut organicheekoy khinii in. N.D. Zelinskogo AN SMR.
I V4 ~j :L * KOChEROV, V. F.
DERZKNSKIY, A.R.~ VUVH~L -t
Sy-nthesis of' acids of -he pol'yacetylene serits. Izv. AN' 3525R~
Ser, khim. lio.-I.-54-I.-546 165. A 1 r3 2 z 'II
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Trai.ning of the personnel of the Maritsa-Iztok I Thermo-
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Klektroenergiia 13 na*5/1600-51 MY-Je 262.
1. Direktor na Topolelektricheskata tsentrala ftritsa-
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A case of aortic aneurysm in the region of Valsalvals sinas.
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RUSEV, K.; VROV, :1h.
Unusual case of tuberculosis of the nasal mucosa. Ehirurgiia, Sofia
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A case of multiple foreign bodies in the inte3tines. Rhirurgiia,
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(INIESTINES for.bodies)
M&NMDCHIPS, 26
Uwswv~~, -~
t6 tpi~sr
Godishun:
Oligocene iirtrwdmx in the Wabarowo or& distriato
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ado
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mwww~
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i
I
I -
VERGILOV, V.; KOZHUKHAROV, D.; BOIANGV, Iv.; MORUDOWIEV, B.; KOZIIUKIIAROVA, E.
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-'1: 1
I - I
MAVIEV) D "\" 1 1 ' -
- ~., , , , - .. !., ~, .,. ~ . -. I- - -
i' . . - t)-- -.: . , I I
,F-trOlOj.~ '-- .. - I 1 4 ! ". ; - . I .
. - 1, _i _7 I - -
. i , , r .
I - .-
MIV4-RYCHEV, S.N., inzh.
Power dissipated in the hc-ating of a tranefomEr. 91~,-k- bta.
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~LVYYEV, 0. A*:
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SO: KnizhnMa Letopis', No. 41, 8 Oct 55
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37 JI-Ag 16D, (MBU .13:9)
1, Is kafedry gospitallnoy khinxgii (zav. - prof. 1.F. Berezin)
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(l;p,E;QlTIs) *
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(STOMACH-CANCER) ~AFFENDIX (ANATOMY)--TUMORS)
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Izv. AN Turka. SSR, No $, 1953, p 95
Mayyyeva, G.
"Daily V-griation of the Hourly Number of Leteors According to Observation in
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C_ ---
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ho
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Of
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eal DzS'z,R.
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77-~-
T,
A&16 h-
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(AGRICULTURR
bronchitis & pulm. onphysems. in farmers)
(MMUMA, PUIMONART
in agricultural workers)
(]BRONCHITIS
In agrIcultural workers)
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(BIRCMDOARDIOGR&PHY, in various die.
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(Us. (02))
(CARDIAC ENL&WEKW
'-HOG In right ventric. hypertropby in chronic pulm.
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Praha., Czechoslovakia
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Praha , Czechoslovakia
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Praha, Czechoslovakia
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