SCIENTIFIC ABSTRACT MEDVEDEV, S. - MEDVEDEV, S. S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033310001-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

0

: .1.
.1
til
~-j

d i=soptl bl&c"roidde. U. RoacUca be-
t2rnzoyl kydroymidde or 1144 a amd triphenybaebyL S. & Maw
'~fb F.' ALlf"BEIVA. 1. G~x. Chem, W S S. Rt. I 11K; 0, 121M RM01). l." '*9
4, ?4 1 c
l;TFMlT IRE ~L %%.F,, ATICk
'j, 0 49 AX
if clK R Tart tie(, n
0 0 0 0 0 a 0 t 0 0 a 0
0 0 0 0 0 0 0 : : 100 0 0 0 0 0 0 a 0 * 0 0 0 0 6 a 0 0 3 0 0 0

k 0 a S 0 9 0 0 0 0 0 q q1 0 0 0 0 * 6 0 0 0 0 0 0 6 0 " -
a 0 e 0 0 0 0 0 0 0 40 0 9 6 0 0 0 a 0 q a 0 0 o a 0

As J!

Oxidation of mathans to lonmildishyde S s. Alixfvv-
Ov. Nalural Galsi V. S. S. R. No. 4,5. N 42(11132j.
CH. jumsed av" * catalytkc ut*As prelxf fruni Fc burn,, 0
.o.I Sit rhuspbAtT at OW 10* Y'Adcd 1~~3 U.14-4 CIW W1 0
1.
'( qaj Illixt. Ncsemv of 'Em"Ma tuj'79) licl in the
XX UIIX(. CU[WdCfMbIY IVA-ItClUrOll the yicLd of clW in tht,
; -00
WrWOLO of Al and Fe phosphatic atalys;%, but on a further
,&-rew-c of the HCI ~a, the yield was lowered. An in-
m (4 in the gaamisi. faymed the (, tru-tiono(OW,
K--l lit. "uw' of 'If.. The unda
(oat "i CH. With SLI tat the pr-We .1 utalystBi yiCid-i

.1 ClIro. omdation with O~ yielded 3". A ~h^ng~ 00
to the gas mixt. duriag the rcaction had fittle influeme uu 0
tht Yteld and Lmupn. of the fur-tnalin condrosate. The

liquid cmdcusate mntminrd 25--4)% JICHO A lay~t 00
,d the app. ft~r the xidalmn .1 Lit. frm t4t, Surxkhwy
unturtal S= tCo, :N),3, 3~51, 19,0, C11, 55.9 and
C.H. 5~134%) is o- A A flodcurny 00
.00
0 0

00
09
00
-90

0 0 0 0 o 0 4 0 0 9 0 0 0
fp 0 0 0 0
ff-~' -7
7T

W-W
IR
.

0 0 0 9 04 *-C4 0 0 0 0 0 0 G 0 a a 0 0 0 a

C11 Z' 13 4 V X If 0 $1 U U U Z h tr 8 0 4 -1 G G 4 45 C
-L r L AA Pj a W M_~ 00
00

ortanic per acids and
let. B Uh 1 Phyj -of
k All' P~r
1-0~ P-
i .00
mfou.i~ gkn,l 'orgy 'A 1- 1y '~JUA
M-1 f,,i:,- the btmA, la~ ic, 14,olo, al he Atth,m-
2""
' a ftmI-1 1, 0 of the -'I fl- 0

f'a P-nltTll
00
k"'. d.- derlul uton dw hiu- ~d
- F H R.
t-hrx"le 1
1w rwtwt~ of the ",rnt :;Q 0
~f ""vauk Witt, Cy'j-
in , y1eur) being C'Aw
Fh~ rea, t Y.t wi ot m,yi , ad,caj,
T in 'Anie -'Jet IM he
i-I'd- I he ~-)- -I K 26
d
l
00
..w'. -
o 'Ir
4r, f'K the per Acid tn
" ') ,"I 2r, rrip . a,
'
072 ). 1, t,~, O
VJ4.
o 1W, P-M,thsy. '00
'A,. 212, t.-rm~phihow () jj-- 0
1,ermipht h,,ic 1) -AO; P-tutt"

A7 0

I q ILI q is q

'
0 '
0
4
o 0
0
0 0 1 a a a 0 a 0 a
6
0
g
0
M

1-
0 1
w
la
0
o
1
~n
m
M
E

0 0 0 0
0 tb
a
0 Q
A,fl L r. a m F T t

y of Wo mothAars A 1) AlAin aml 5, 1,
00 R,w 14.,V, I. 10, ~N. 1 WJ4 Hall, 11"thall" .00
at, .1 cc .1ld m qh~ ~Ar- I'll-
tri 11., "1 .4 . 1-.1- ,( S".

00
as
04 -016
Go A 0
A 0
AD 0
044

00

-) is tee
1 4 7 i yj &n a OA 0 Al I
If 0( all '(a ift1f, it n , -

0
0
0 0 00
a 0 0 0 0 0 0 0 0 a 4 00 0 0
0
0
0
0
0 0 0 0 0 0 0 of* 0 0 0 0 a 0 0
0

to is
4990*000100*10000 0 0004 vrww... *goes** 4
.90 * 0 * 1 *
q 4 v to h fill) D)03 )4416' )0 Oil IF U 11 11 11 11 0 7 1 0 .1
A I L 2- -,L~ X 2 Al I ).-t k-119 JL I A AA 10 V, Co U-4-0 a
0 76-A
so, The rap" plia" c&Wytc hjdMyw of aftyl hades -00
00
11, The ptepatratioc of meu=ol, fcnjWd*byds an4' -09
hvilizaWlarido from methyl chlMde, dictilasumethA-z
so and KcArichloli-de. A Ahkin ai%41 S 00
%1-~,wl 1034, N- 1. 31) 4: cf. j 114,j .00
f< - A. 7:11MCM, Mr("[ Arid C1111-Ch
0 1 :Da y N. hV111,11Y101 try I hen) wil 11 11--aill avrr ~-n
0 lh-plialk lict-i'm -it Pumice- li(l, alul mixtq. of -00
31~ 01,41 V, phl-Olat" art- Whts It,
00 jmly ... I at 41k; . 11cCl ttv- 16% MOM at,d 18W, .00
00 C11,I) C11,C1, 7AACL C11,t) It olixt. of %I,( 1 0
.U'd k lfrcl, - t 4:0 1', Cff-.Cl. at- c1l'i
go And 1h, NigrO 1~ ;W% Ill, IT'Airl"I I-)w re-Wo.) Ni't i
;na V 'th. rmrcui-t-lf, in which ca,a 3 4 cych-, all- r"m-l
or.1
00 j ((I ~'JIAA' rhe ral to of clikwidi-i itp Its(, ftvf hv,jrok Zoo
Mccl, Anil 11,I) it) thr Fallo I .,I
60 $4(' give s#14-, 111c1. 1(
00
00
00
t-0 0
& 0
:r6
Is,* f
also
It T 4"
'IF -1 V-FA S it aw 0
I i I ) I - -42"
a 41 K a 111 a nituwwn Ito
o P
6 444
0 0 4 0 0 0 0 0 0 0 0
0 IS 0 9 0 0 0 06 00 0 0 06 000 00010 0 0 0 4 0 4 0 0 0 10 0 0 000 0

__4

4 $ 4 1 a - ad 11 U 13 14 1J 14 11 11 IV Z , IL J2 D U b A 21 AL 11 11 11 14 IS 11 0 #1 V a- a
00 A fi -r.A.ZJF_k_JL_J 1 1-0 fit Q A I I W ----A -100

" at 1.1111,
06
Y" A.AbW a" 00

0 * WW S. Afedwit$lcia. J. Gains. ckarm. (U. S. 4.
I
S. S-4 00
ttaturiti (1) diasolvard
1407-140M.- in ltqtikl
Us
CO Cme.C CO- CIlcTI!aIa-L I ~jf
00 a a oftled tube at rnmn tci,sp. within 3 (lays 11W.P..
,
L
t
4 lite Nils Suld Nfifille'litk"S Of the MIdUr with dtT boiling '
it
Cli
I
NIr VII
C
if

00 ic
Phil Clavv In talent r1rid lite av~,J. (11) ad -asoMoo.o. .
,
.
.
o
0 44fil. Ill. M2 ~j state 1 11 with hol 4LIL411 iolu , MU 0
Als.. sod 11,4) hilt NoW 1. 0111PAWSh JFV It to OldI110. 0 00 ClAte C01 ClICIISIv,01koll

111110
11 crysid. Imm CIICI, with I ntW ef CIICI& imea-ved
I I so
4110 11.11114101Y MAY by 1`141111116 IN 740.00. In the p4reon" 61, Vill 611c, Clio t'll, .46
ad awAituor both Nils and C1ICIs vntr "ml while tIma (IV)
00 vtyst foatu was ortsfurd. It vom pail laosaitile tea ""iyeft

D* it to the tactat" knothall 4 1. A411d. twMalwo voless ata- II(JaeCcW c- -c1 J~ cli CIM, c(l
I&I-I (to llac trwtut. IIII for mommic ". ".11 um. I I I
Froved luctluall foat piepa. 111 Lxacumisto in milluxinq.; 2W IF.
0
o1 0.0fe CHo ClIale Clio Clio
4
f), with 2W cc. H.
for I hr. in the aboxeme of
W _ ____ - , 460
M. the. adding W c. of I and buffing for 12 hr#. Coal. (V) .

ins, staLkins In Portions with coovd. HCJ, exill. with
N114COCNIc C -C(i 00
Go R110. carave. The MO. Purifying by'liwialving Ill Nva.co.
.00

0 mAn. send FrppIS with 1ICI and litudir rceriturg. twkv
41"
tW)
1
f
I
b
l
111
1
M HOCIICliC?,[, Clio Clio
00
2-
ront
aye ca
el
ess
1
. tn.
, in
%
% ylvid.
I i
(
h
M s
ith II
1
IV)
hi
ld b (VI) -

0
e
"
s K*Ve It
0910 (
. W
C
roU
e
.,

on"
imItome"OtImlactumM. IV cave the altakfac M) Nit CO C?ttc C-- Co
"h Liquid N116. VI ISTV lite factoun (M) but c, fol
R
j
&
i
not be -o,awt led to VI 1. Ill I SA g.) its 210 cc. Ac
o
i1 -Il.
II, Clio Ofe, (All ~4111 0

ite I
--Z
C C-
co cSf (VII)
00
e
,
0 NH.CJ61e:C- CO - CHCIIj(cC0Jj
1
Cli
m. Cli
&
c
~11 06
S
o
o
.
CO C161t.C CIM111) ClIclimccosilt,
00 1 1
t

00 CJl:CIl-CAf*. Clio
1l.
.00
so I ~. I ..
11, .. .., "00"
-
.0, q -fai l*,,
4N

a
'
as 11 1, .. 1; 9 a -,
as
*
0 0 0 0 0 a 8 0 0 0 0 0 0 0 0 0 4 a 0 l

t~Rl -
- I -1--- 1-1
1
6-4~4 li-*G 0 0 o 0 0 0 a 0 0-04-0 e 0 6 a a 0 a 9 a a a (k
0
00 0 a 0 0 * 0 0 0 0 0 0 0 0 a 0 0000000400000600
#J to 11 a a
W P u u m 4 10 v m 0 a
11 a

0 L f, L -1 S 0 6
I -A-1 4 14 (X
v 1~
P
A .4 L L~ A X
4
.
.
.

A D
S. Kfirnenkov. Rm- 4.,.066, :jn, IIK;:,
c PcAmcrualinn is efftrted in thr preumv ol teirshn -00
as calaiv.1 -00

.00
00
9

=go
coo
go
00
60
00
00

so
06
go

t v a a it N go
%a ado 54 -3 0 4 3 1 1
14
0 0 0 0 4 00 0 06 0 0 49 0 a 0

00000000*000

Ij it 01114 4 60 fill "a 111214JIUVIVIV
F A a 1-1-ti-A.111

00
00
*/
c'
for various thro
iodkAitN that
slootty fSJU to
decovIposicke of "Mid".
Z. Ph tim
d A
1
l
d
"
E
n wry sk"y tL-&
S.
1ca
ve
ev ao
.
Y.
- HCOji tO 6%
Aftt:-Z-
)UftC0Wgv- .-A
3
P. S. S. 2. 4M7-&A(
,
b
V
d
N
d tk
h M
M11
th" %kndy de
e
au
was passe
"m 4
port
rou*
o
.
, Ufto after the
1.:M1. asid then Abcough a reactim tube 14- temp. of c1ccomil
glaut Iwo" to MHMI. 11K poducts of decrvdam but
MvUH, Nte,0. HCHO. HCOH. Oz. CO. C09 and HtO docreames to S'
00 0 bat no H, off C114. MeWH was didd. by "actiou with C-4- Indicaft
I cc. 251" If.-So. uW 1.5 cc. 10% Xf. left PADdittg f0ir
I '~v
thca titrated with NatSo" oaks. The vahm as
hi 1W, MCOOH -
.
foand is Ibca -,fUt%, M)-)% Uld 90.14% Of the UM C00M. U--OH. ad H
?A M10011 (Of 0.21 0.1 and OB5% Was- crip..W. sedvation raeri

s It Ct a III a 4 It a a 0 41 0 a a dew
6-4 4 It A i - 0 0

00
'-00

4 contact as temps. if"" Alt) to j(Aj 00
te amt. of McOlf FI-6 14) Q`-Af- then i'00
u% -&Sul km C0 film to ~Z%' Me#() 1-00
to at levo. 25%, IlCI(0 rises to 10%, 1

C
Uld COr gotWACII late FiSCS In 6 ad
1f, a '0411
1
tsws alato. TbA "A 041
ax. of Wolf is Const. With lars
. thie suit. of Ifevo IM'read" amt 1 11 MOO
auto Inctcaars; Of Lvicrenart. IfC0jlI 00
. CO is c-Imt., CCh increstLes. 'rkm
2 processes, 'fix.. MCWH ClIgo 4- roo
HCHO - MCOOCHIOH HC01H + l
'
t
1
0
00
Oji - Co -t- f1do with Ita over-an
=46W
of IO.M cal. ad k. 0.01(a
Is IS utdonctrically in A can-deGoot for Me00H WILS 6 a
00 g C(hlI was 4maverted to the Na Wt. &W thta aW 4 7.00 at 2M* and 812 at 3tv'. F. If. R. ZOO
detd. by the Kbln04-Ir-1-Na#SA method. and & 4%
00A ,arrection factor applied. GM" Wm detd. in a Schmidt SO, 0
00~-# app. The C-If balarice was alway good for the IM Of
theprodurt.4. Tbeconwn- 0(th-21trod-tsof the reacti0o Soo
ago
zoo
LIS ILI -ITALLOCICAL U7111474111f CL&SUPKATICS 1-9-
die 1:10 0
-74WI-N.J.
T- qvjq#~ k. *.- dac 4114110-C' eal C.. 11,
It.
100,10 wig wa gas offset ItI111110" I TA a two 0613CII-jag )I W KIM
4ft
0 0' 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 411 a 0 A 0 0 0 0 0 0 0 0
~'9*0~4 0 0 * 0 Oie 0 0 * * 0000 0 0 411, 0 0 0 0 0 0 :!4i 004 0 0 a & * 0 0 0 0 0 0 9

0 14 111-1 -1 L J. ii 14 AIt 1) 16 A L11
I
0111
U 11 11 1
A
.
1 00

diew at Gmdaic) P01=6
S
h
a
.04 a.c
al
Ntvd vicir, 1-1 (-*1-
V
s.
S-~f
r! fit tIL171
nor
t
.
.'
s

so
so Ize*
or

roe
Zoe

TFNIT.Al CL.1510K.100. I I

it
-
-
YA
An 4 1 aada0
I
I
V
D it Ifvfif Ila Nil n 1 14

0 0
0 4 0 0 0 0 see 4 00g0
0 0 0

1 0404111*60006600 fvfr
Owl I oil I to 91111gummay
6-.L- L a j it, A. -&-l-A.-E-a-M-1-
f lit ~#-e
00 A
Is*
o0
a It u a No 1610 100441 Ala "44*
It & I A M I G A -.6-2 A -4-9.,.JU -
Its. U. R. S. S.
ProcesSes are IWY
in the o"tim of ItIdgumbow. The dm is due to the
tbermul activatimm at the Origiml lubstsacte "W the me-
so WA to CbG fAtMOUIVA Of the CMffWY UbCMtgd daft OW
h

0 deco= of pmm"m For the fim pracem, t
e ca=
M

: 01 ..
O.., F., depeaft an the mature of the w
0 hydrixubm. wd the rate. in, dqxn& sumticl it.--
P
diff
ti
l
U "h

06 era
tt
e
e
temp. For ck tKaW pmcm
.
carr" of activation ad the deempa. reactium of alkyl
pt-taxicles. a-* Is proportional to es ic - hydrocarbon
2
00 couca.). am tacrums aW in decreatmes witb Lmcreaw in the
rotten. of pa We and cwbanyl comptlo. w# to alw ife-

-
creawd sM. durbq tim Ant sug" ow I* inciva" by an
l

0 tln
cUmber. Durft
fncrmw In The stitute al the react
the OW&SWO at teman (1). 1 1=7 (n) &W tefft-
00 low (0) me fixturd. The I of a (acress" the
00 midaltion rate of 1. the locreaft being the
W=h-
the
III Central of ik Original I in Wall.
00 total cmittatiock rate. B. C. P. A.
a. It a *11144,064CAL Lin#Afbno C&AtWOC&TAN
a
s
114-
so
-09
-41100
-09
=09
4:00,
400
Lo
00
irlr;j ;iif Aivol #12m& Is,, 0 Is 2 1 w a 2 a a 3 0 v
0 All 0 0 010 0 * 0 0 0 0 0 0 0 0 0 & 0 0 a 0 0 01* 0 0 0 0 v 0 0 G # 0 0 4 v 0 0 0 9
0 0 0 411 0io 0 a 0 All 0.0 0, so-41111110 go 0 0 o III e 0 0 o o 0 0 0 o 0 so

*****so** of wow*

-0 a Plk IU, 1. 14k 0 k
p. 1,f 'A T (4)

Y. V.
Prom, 14. No. 7. 67, 7.1dMAT. '%wformace of tio Sft
44backug M&CWUQ. 11. '1. 74derAGet. lbw. 7+-I 0*
~
"Ttil Of I* M ddb*ddV41K MaChIlIS, 9- V, ZcAQVA-
IN,- 7840. -Canstructi-ml wnd o
eralk
d
i
o
e2a
Js.
p
00 Chas. HlArw
00

00 00

06 -00

00 V 1%
00
00
-00

410
00
41

.00

so 00
~-o 0
A S a I L A Ae

00 it

4
' '
3
"
1, I
x A I
9 0 0 0 0 0 0 0 a
0 00606
10

10
0 064 000 00 so 0 a w w
v4 0 0 * 0 00* 0 0
0
*
s
o
0

'we 10, ow Ow '00 *,age,
ll~A
00 46
00
*0
so of
0
00
v
00
0 0 0 v . - -
" w a is a a 0
L A f
--ILA a A IL
At. D.vte,
WqM." Smot Akd- Son* oWi.
"llM."41_ .34
31896. Rtwo C. Mctmr
rl::::100:000000000*00
FOO 004000soc-zoo
Set 414-ii-I sw-omw All-
T " Am A I v ad 6 is 6 do 6 3 9
40"000900000000000000
40000000000000900000
.00
-00
.00
.00
coo
LO 0
fee
do*
1~0 0
A,*
0
wo 0

V tv-s- 0
j I
I AA A_A_A_
4
-#OMSK* As* fatfor(OAD9.
RUN lo
a* maodmd
AGNOW OAV8,.==. I
a klj~m~. Add
r).-MwtL dial
S. S. sit TU-0090)(iff M
U. R.
d 9
time Me. a
an
Tw w", ox,
-I(JkC+b)AhK
b
l
vm
rm
s
ft
a
d

so a
4
for UNN 0MU
-m-
~
l
aw &0 (we (M - dw comm. of
le"Gull "its" 2:1 _G"
Wwwo ady the raft d rmW ;!;Ze ;,;;. The .490
04 4 "d the remom onats.

-
'A"' m
rl -a 0 do*
.
A
A. k.. A,
*
0.0, 7
0,0, Xsee

see!
-
od ff WSW bas
Obbi 00
be test."
, I I . TM 6ONLO AM* 0
Po4warfatim is fist 0 a no it dw to a assluff-
&"WW.4d (W On dib-chda I 'g 0 the sum
A
00
,
tiow;emaw, to an

54-SL4
MO. CLAIWICATM
MINTALLONCAL LIM
480
IN
NNW 21119211"
-
-
j

sma". .4
t
Fi%v
foldso W&
on
age. 414411 MIN off &It

a.. a I IA NN 'I

JAf
&-,# I 1 11 IM 0 11 10 If SO 9 A 4 3
', ~ a . Zf 'a W, It 4; 'aa
1
'o
0
.. _.
0_0 0 0 0-0
4
4
p
r
0-0 S oc
0:0 0 0
o
;i

WDVEDEV4S8 600
1. MEDVEDE , S.; CHILIKINA, Ye.; KLDI:ENKOV, V.
2. USSR (6oc)
"The Polymerization of Chlorophrenell Part I. "The Kinetics of the Polymerization of
Chlorophrene in the Condensed Phase Under the Influence of 4drogen Peroxide of
Tetralin," Zhur. Fiz. Khim, 13, No. 9, 1939. Moscow, Physico-Chemical Institute
imani Karpov, Latoratory of Polymerization Processe!3. Received 21 A-Pril 1939.
4" Report U-1615, 3 Jan. 1952.

MEDIIEDEV4S8
1. CHILIKINA, Ye.; IZMDEV, S.
2. USSR (600)
600
"The Joint Action of Hydrogen Peroxide of Tetralin and Nitro Compound on the
Polymerization of Chlorophrene" Part II, Zhur. Fiz. Khim, 13, No. 9, 10139.
Moscow, Fhysico-Chamical Institute imeni Karpov, Laboratory of Polymerization
P
frocesses. "eceived 21 April 1939.
-"O Report U-1615, 3 Jan. 1952

041 1 Iasi, I I I a litIllulsil, fill "all n SO a IS is a a % u a " a 41 NJ As (a 4.40
IL -9-1. A- v x 1 2 a a-" a.--- 0 a
Jo A[ -.!!, ~~I~A~rl~ !~irlv! , ..-- .
ORCOcor'll
00A
00
**.-I
*0 Khm"m 11 of hu"dim" in *00
UrVIONAM A. Anaug wId S.
jxj"g;!�pO- WIL Oieav'Ruac. 10319. 13. 705-- '00
MW
008 (A., Ism ml Is Amplifiet
00 r polyumbation I* n 60ififtil to Uw Offimm of the .00
bumide bsts W-vachwat It. Ths,orp-
00
00
A 30--W-, go oidw of the pobwmb&Um reiaccuou
00 13t w" tAmp: Wwom I aid 2, ,,.qmfig -00
iWA Twiations in 4W Lpdlex of the dimpt" imotherm.
we. j%p rel&Uon betwom the mte of polimermtion am
*44"lif dilamim of the monommidds in t
00
mok&, hat bftn *&MMM. &a vaLL of the n-c!z.
00 1 ME mg cuerU of actlystion have boen calc.
0 0=9 R. C.
.000
!No*
too
its**
too
i 4e- 11, 1 L 6 alld~,LURGOCAL WISMAI CLAIVOK&MV a 1 00
to
a Ali 1 4 11 pw 0 Ad 1.1 do I 16 v ll~f
0 'a ".0 cinip mot oil Ogg platt KO 01 94 Ock
0 0 o 0 0 0 0 0 0 0 Ze 9 0 9 0 0 0 0 0 0 0 0 0 0 0 * a 0 0
1
~*401 : 000000 Io, 0 * 0 0 0 0 0 * 0 & a 0 0 0 0 0:

010 eggs,
'000004
so
040000*6664
00*00060600
of *GFOO 004 a a 4e,
:*go***** 600 *owes;
At a Is U a Is a I M
IRV ..D e apt a,
Oxiddieft III
071
A PQDJAPOF~
oK&jjL (L PhpL Mau. Rcr-.. 1". M 710-737;
I
-MV
149.).-O"flea bv 0, at (L
*kfe cWAy tetcaWs H pw-LW* i1) &W tetnitune I-so
00 (LI); no acidd at aldakydes an formed. (1) ac-ler-
0, &W4 the reaction. whIM 111). which is formed by the
j R so
demmp. of (1). retards, by an amount which rises
and then bectomes comt. " the mum. of (11) In.
creases. The oildisMion can be resolved into two
independent aft9wnary Chdkt*n cmeetkind. one arIEWIS
d
i
M
l
ti
f
:1
s
&r
sitera
^
from the thermal activation o
n, .
b (11 . &W prooeeilIs Is echanklm similar to
am]
11721
IMI
11"(100 of LWO (A
L Tth -
1000
!
Jkle .,
,
e 0
,
the weand depm& on IM &mmp. of a compounil
formed on the wall by wiUmion of a (1) mol. with an
Both
t
d b
k
t
(11
nd i
l Zee
.
s acce
rit
e
-silsorbed (U) mo
.. a
.
y roe
:trooksas lead to tLa aectunulation in UM system (if
141). whieb givea As oxidation an automtalyfio
character.
i too

4 24TAL1,04KAL L1111411,4141 CL4tjtFIC&TICW
:
t

U TI AV i0 is
Ir I
OA A 1 9 tit 0 s 2 1 it

0 P It 0 at K It a 4 Q U t9 4 WO 0 1 K4
Is
0
0 0 0 0 Wo 0
0 0 0-0 0 0 0 0 0 0 0

-
Soo
to 'a e
in I a 3 4 % 6 1 4 , 7, ve, .0*0*,Oo*4
punsdow try "-! a a a a a 36 a anon 34 a 9 a p 0 a a 4 a
-

00 A 00 I!R I [A I IS WK 1, 1 , I
"Does .6,
procts"t "a "CrIOV46i w"* "
IF

! TP CAW= Of dw FIVONOWNIM 4 -*-OA=*.l
do" d(ba

'
A
c*v. L. Cludittand
I
A Ayr. MINI. (U a & R. J, 1,1180-1402(jon),
The klft~ of th

00
e clikropcew (1) ad
de(4. .404F

by a manometric method. The soly. al I Im d9wAtyl
phthalate is civ= by PlOb K with a - 0.730. 9 - .00
2.13 at 3(b*: a - OJM, K 3.93 at W. The poly- 4*0
p9dw procew is beterocemeow; the rate increasel
locreaxine conca
of I add b
l
id
.
ettwy
perxis
e M)
tip to a certain mm. and then remaim; cam. This
coo
il greater The greater the Mutace evailaW, varying
*0 -3 from 2 to 8% U. WIth 4 a. The CwCy of "Val"
A
betwee 3O&udGO*1*12
. Outhebas(modesawly. roe
.00 w J,:
i 1 sis ad the kinetic 4ru, it is coachided that the Wtki scuve
004
004 centem form as the result of rewtin bet. I and ion.

z sted U radicabs adsoirtled (m the waUs. Thew rowd.
nudei them kave thi isall and the polymerization
takes pkee (a the sufai. vol. Deactivation may occur
-l
titber b
reaction with
i
d U
b
Lfi
un
on
ze
or
y co
sim with
y
of 1. If. Rathm-n-
off

see
A
noo

slow 11.1611w. q Ia.. dowanw-
IIftoso j
tall OK am" 414
S11444h) War G-v a" ."Mae, of
win
1 5

J 46 Olt I
a I za /a
la
j
tg at K"
'
g 00 g
0 0 0 0 0 0 0 ~~ o 0 0 o 0 o 0 0 0 0
0 We 0004000 goo 04 0A * 0.00 Gooo 0 0 0 0 6.4-0.6 0 0 0

* ;ZZ to'p We 0, 'a Zo-; ow 0, *4 **,.
0* a
00
00
00
*04
04
a- a- a v 9
. a a 0 9 9 a 4. .
1 400 41. Ciotti -We
"a- P440torgi WACE A0,
--**:Fwodu Ow own 00
V" &~~ lo . IL .02. .00
U- -00
a P~A~
a
a"
~by
9 (Maio
Mkimum" p4m
%fact of am Cam coma
mimmm""
I Iwo
1.
U"dtk,4 pro-"
sum to the see
,fir, -1 CM0900"
"=d. Imats wu Ob-
alcm ,4K"Qyl DeCM 4L
be &d . pv~~ sp-
to M, w-payum, LO 0
(mm- 040
F, Rk""
!me*
coo
M*~
too
&A*
zoo
4*0
IZ
lu""m4l
101 0 0 0 0 a 0
* 0 0 0 0 a 0 0 0 0

god
go
got
goa v !i,
0*0
00
00,
e.* * 0 * -9--o-W477 0-0-9 F
ooo 4F 4
it U is 4 V to " ID it a 0, m h 11 12 01A V V N V 9 41 43 41 U
ft ;.p .I it. A 1 -.1 &A VC te g 4 t
~n sue.
'6. A
Is bunrA 4131101" 5'
Ad. P
U. R. S. Aurms).-Woel. do
as atim j"t wets" is ammm& Lva
to 4 its IN taw -,%M t*0.40 If 1011nudAIR
in bommm 30 to
tb--ae 01 tue surface amf1wo in 11 tables mW I 4g.
1r( f P-Gov Y reacom ii mlim ad a vinyl acetate-
Namoo WmWe Compiest which on reaction with ifte
A-Cli" Cefftem, The
ly, ;;;Zvumus. The enclay OF
C~. ?be re"faft cact". Is emu by
'A I/it - KA, 4 10~31'b With KA X UP - 23.5 at
gd*,! IAI " 73'. 1. at W, 0.423 at 50". Tlte av.
eactim chain karb and the dftm of paiyrnmigatim
bommum the latter depea& " upon
CAvent kadx.;
ir,ZW1Ri7bc N;Zrm.4W_jn* =Jr'_tlsc"vd reaction
do" on, otse the :"I
equation %P/C - 1 .4
+
use chemp of the devee d pot
camn-aftbesda., whack - 2.44C
A at j.tLjm;jcAL Lagja well withdod by the expd. da
OUT.
04V dag mg
'Wr
AW 10 AL11; "'t " A ; C', ; 1, 1
ire
000 **so 0 4w 4
0- 0;
enew of ectivadom
2 of vinyl acetate tbb
ctd- equall-. 11m
151'f1) Is dertvvd &sr
rmaintim with the I
- 4.8. Tbeesivatim
t&. P. H. R.
alp
SO
0
2 Wo
tso
no
An a S a nd a 0 a I IF a 0 a 16 11 9 9
-a 0 0 0 0 00 0.0 V's go SA
00

:,~MFF-077 S.
MM,014TOVAP O.z AMP14, A.: 1.1.1
Polymerize-tim Processes Laboratory, Moscow Physico-Chemical Institute i-m. L. Ya. Karpov,
(-1939-)
"The Kinetics of Polymerization of Butadiene - 1.3 in the Presence of Potassium
Phenylisonropyl (FenflAzopronilkaliya). if
Zhur. Fiz. Khjm., Vol. 14, No 1, 1940.

vrI-11 Alp-
_Ljj,,M4
-a orator-, of Pol-
~oyl :-, -
-_:i enz,-,ne 3
I .. .
..,- . - 1Z. I

-i Ul
awKe go mama won as exicropme am wwww" to tin
M*mdm Of4em A. Gantmelita; am S, MWVWJSV (Afla
ky7,-.;Jw., U.N.S.S., l"S. 10, 1-11P.-Raman-PlIft-a am gl~--
"
fer cklwopmtw (In. a 306, odutted alf polyroettiml (1) to the motiv..
memc, a ool"Ition of tM pollycoetidu in CsH, or CO.. anti thr pure
1KAyttic-ride: ccWTOrspootling data am Alto gilivo for 1"'Crtw Out
aeach case p ulylurisatium xiv" tu ic ugatc &,Utjl~
Wad line I I cm.-' In M and m not gi%,rn 1,%
the coamnuctide; a conjugate doubfig-Nitid line (1 0, 1640 rm 41
dweastm In Intensity As IV
G(rcisation pr 4~mtfs, hut re-main-
Much t than he 1663 CM. ltn~ h-, -PAO'
e n
of pol~" w7j, 1', -61
;~ 4YOZ, (tit! -1M%' Ths'
COM, 61 OW)i I k1flea-wA.
fowmr, PO(YMOW1100 ebtliftffleS aISO MtO 09 C01101,
mrAq ww, Aftwoittef, disid. lrzitd the polyn1w and
apJii mixod YA(h It, polyincrizesat tht, awtio 0 apfl tio d1muf
w4offod, -but 50111, =d repptn. of 1101YIner fcfflovo it,-
cfttaly~q activity. 71je corripj], ot a r lolgw- ftmd-
rM V
on tim Cmu, a -Aild 0 tk re-Saillff thil ro t Vt. ptQq 41 W
A-0fi(M Ot 2 IM ftwical.4 wt IT tile 2 mpolArw of LIM fjtfljlo-~
mixt A Mmt)le metbcd tof aomrti.1
11 RM
at froin'QU.,dan, Ii 46wfl, Now Me VO Ilgq nr a And 0
546 thp diodin doil W Moonjor pop5nitlifflibawPolyn-lor
IIII Z
can ho caled, ((J. C.A. 4 11JO. In tllc covoJYM- I +
In 1%
t
11, 67%.11 Itj p-&,ert! tig Irile Uq ctweeil 2 bm-
Its ~p bc
dione grou m and lit 1U FAI(/'7 lit IG III thig 44OFF3110
P#teru'
wo ep-aftflo"I of polym-44ratiou w4f;a 1 of Lhe
mwmnents 14 tistj isp shows Opt both compLvpnts are
ITT needed for the bmriching of the reaction chain.
J. 1. Bikerinan

GINDIN, L. 1-.7., ABYIN, A. D., and 6. L.
I
~'Problcms in Binary Go-Polymerization I. "Azeotronic' ',Uxtures," DoIc. A',', 56, No. 2f
1947

MEDYMEV, S*
P. Khomikovskii and S. Medvedevj, The mechanism of emulsion polymerization. 1. The
polymerization of vinyl cyanide in water solutions. P. 1027.
The probleir of this work is the investigation of polymerization ir. water solutionsp
in solutions of emulsif-.ers (in the region of colloid solubility) and in emulsions in
order to clear up the role of the processes going on in the separate parts of the emulsion
system in the general process of emulsion polFinerization. Vinyl cyanide, a i-,ionomer, was
studied first because it is easily sol-i~)lr 411 .Iatcr. Potassium persulfate served as
initiator of the polZrmerization.
The Karpov Physical "~heniical Inst.
Laboratory of Polymerization Processes,
Moscow
January 9, 1948
SO: Journal of Physical Chemistry (USSR) 22, No. 9, 1948

., m-,.v, S. S.
.ro-vaniye betona
24213 1MVEDEV, S. S. Vakuix-d
lorczl-n-~All; -okr-,-t4y. Sborn--:I!.* lokla-lov
- ~ __ u -1 tov vyss'-.
na 2-Y 'lauc,i. kon.'_'s;; slu -an
1-4,~, S. 37-412.
cl'_'trOJt(-'lts' o t 3,: -onto
6v
sluqenlov a, to. -c--lor.
L, - u
Uclhob. zave~.'~~nly
SO: Leto, --*r,, !!c - 32,

MEDVEDEV, S. S.
Khornikovskiy, P. -f.,Zal)olotakaya, Ye- V- And Medvedev, S. S.
"The nol,
,rmtrization o~ vinyl cyanide and methyl rnetacrylal:e
in soap solutions and emulsions," In the symposium:
Investigations in the Cield of coin! ltx-molecular coix)owids,
Moscr-Laningrad, L949, P. 45-55, - Bibliogt 6 items
50:U-5241, 17 December 1953, (Letopis'Zhurnal Inykh Statey, !lo. 2'~. 1,,t4))

Id
c,.,olr
"merization c4 ally[ x"ylste 1. MtetmLawS the
strutuce and maleculu weight of wtuble forras of poly-
&Uyl acrytate. L. Gandin, �. Medrk~Ivy. ~d U. FItibler.
.; (". - ch~ ~ fU.S.S.k.) 10","a. r, LlIg-
Wa trians6tvm I -Sm C.A. 44, lo-Au. U j C.

liallymelisatta" of atilt ikcfytdtoI 1116(ormination at
the structwo and mob"utar weight of tko whible formli of
I 'JUYI KCTYI&tO. 1. (411411U, S~ MCdVVdVV, Atilt Ii
I kup. 05-Akkef . I I I to
RIO) I"fitywitriullian A PkItyl scrylAte, Ill. I III
'21 V. if
. 1-4". d*.- OAVA (i'), III 2.A and A 7,"; .4ti, I,%
C.11. A1113 M Birth ~Aldlyst *I 1,A), giv" 1". 11-)
Mittill IN& St)IVCttti, With the "SAill ChAill IjIIk.4K-
f4m"Iltu.tan Ilyfruits the "A"y1w"(foutfic INO(W. The
If.- 3.1 to.*,' folat il'tutil. C4 thl, w
I Ovillw4i wills 114, "'Illyl- Is""I" 0,v liar I I'll-
I'l-1.1ir I., CO. A"Ill). ttw t.,t,.t tan'.1.4 *A,
drift. fly file brinniffir-tnti:13,11C methtici In file pre-ce .I
ff%SO4; the PtOMIUM4 Were 'AltVeMIllify tCIt"I Mt thV
G. hi.

1p

,
1
L IN
1
-
I
A
00
Ao
l
4
il"L
-
rs~~% ffor
00 ft..
ve Atd-ZI(ioly). '11
,
,
At 2"
to the Sal-4, In MCI W.84drld. In Adda.
01
=
TAtiable Mac". of MUM)"Wr I At"I
tonteta. If
1
ft (be catua. ca=ts. of SAM -4fAldt - Akid,1811k, -
A
), when tile datlag A (At) mied between 0.4 AM
[as 1.4 mol-11. mO 8 was 01"M The cmd. W
of activre"ter was 0.00-1 I./moL
Mio. 4n-1 /it of the rAte of ChA10 11MY111108 W30 11.491111111), -'.
# 1% thq CAMd. 14 furt"tion ot If" rompte'Lat I iond StO.
Zhe r3utims atuos (ItAt W41%. of thill compte't tolattoth"
Ina. I Is the CAte-&q. Su0cfts. The temp. LoCiL of
IIMACIlon vrA* 1,77 betwee 0 And 3W. Whrn 'I. W.11% zoo
'11' (-IIA/41) increit"d "auto-catalytiodly" Showills
twanching of reactim Chula ; this effect was ahlent in the.
prewum of Smas + Ila or of (11coh. Frwu the vis-

O"Ity of polymer Sol'"' In CO. at 30", jqj - lim
(V.F/()
w
s
f a
ded
Itwa
x t
t i
a
d
foft " see
a
e
.
e
o
mos
n
ependent
s
.
he ;teerve of poirtacrizatim. and ;vAs 2.1 %/.!-. f'W
goo
0 0-~t Aymers produced At 201, after polymeriLition at I)'
'
M see
was LS tinves, Out after polymatrAtim at -III
. As
I q I was ladepeodent of B. Chains am Mac broken by recom -
biaAtion. IICI added to SmCl. acceferAted the ix4y- see
"tcrikatim mov the more 140 was v4d'ed until the mot, -

tiollwasmefied, ThelilofthepalYnt"Ohlained
r
A
W. J r III thr pieset" of SUC14 + [ICI was About 1/8 Mit III the
I'(' ~~IWC Of RIM. 1190 W4 giftlitAfty (11 IICI. I't-
owl.4111V If of IOCI.

114'. & MM&WOKat LITIENOW41 CLAIWICAINO 9.8 -'r7z. 104111411
14"60 04 to"" Hilo 414f 464 61111111 do a" Ot
t 0 9 . 0 a I I III
Im 11
6 "0 16- H
ST
:
i
4

1 KAI 64A PUY.
MO., 4' 2% 4111949) ; I I C A -
Mwo C1#,,%.#1OAc (1) was iffadi.61M 01, tilt
t"hifiRdom poe""t, if* (uglifer p4rawl ~tatmfo In "Iffavi-Art
44torml Wilb(out Way Indmuts" Wiwi, lwf.*. kutmAry
I" C"IhIX"PM, lot 4J. (C.A. 33, 4"s% t1w &s&mjj,,,
!1*144*1 Alto dost ito oftvuulti~a oil tiff 144hisficon fd '101-
1341 A., Ike rate 4 1.4jilitillatl"O V NOW. MAMMI11-
%-Any) Wall Can"' dUOUS All CAPL WIF&I ICAMW MILO. In
sattle. In HIOAc, or was propmtkmal to the akAe fractim
! of I bets, OJU and 1.09). After the kvadktim w"
tatempted. 0 dmtascd in too mc, to o.oti at its ndue.
P- Pum 1. 9 at 40" wsm 4 times that *1 106; bcav. the
I'M OF 011 wtivatim was NN" cut. The rate P, of PWY-
"Iff'1411311011 alf I 1114141(t4l toy (11&()), 1., mctWqj4ffg to the
titcrattor. tfortogimtkut4i (41 IVACM, *1401V It - cuml.
Of t i% A C11110% tVACIIAMI With-
) I. 111kcrinan

(Acal. '~-i. U.S.S.R.. hto"w
U7KkN1oM1tic.V10 2NI'M11511; cf- C.A. 44. !Xth-
AIM r1shwide [1) its PlOAr 1-1voteria"I in lixht at 3101
31.14) A. At & walt, t- In-telmn-fent it thin. -6 10.2 .11) ~n.l
1,t"j.wtkV1-41 t"light 4w"n0tv 1. .41 1 - d X fit - (41110.1)
. .4. , -4 X 10 5.4 X It, 1. :17 X If, 1. x 10 -
".1, M.C. V.- fit A', qW. 0": .411,13ft *. fir.j. 14taystlegiv. -
mn in ,he da,k. .1.. At" illonninwliew. WA. twithaPar
I'lle ItH4. wt . .11, detal. CfY05",11"Ily. of the tinod produr
wal, JIM-12111), MO, IM, and 410 at 75', 00', 43'. ion4311p,
F"P.; 1twasindqwnd"tolddo. The spixictol energy of
Activultim waA 4 UK) 4401 M. The active nulkal (III of
the Stowing ch:101 Mricli With a Intij. of I fuming (Willi
trActitto -mot. k.) a radiml ClIoXICC11, (111) whit-h L.
tnjl ItCliVe rntnjjgh ti) JVLjct Willi I lMt lIddJ4 10 11 IbUt JU-
teauptiog the chain. This trocchAnitim Vieldo the equaticto
t, w trittk4loPiksko; ghm consts. are for the reactkuni *'cx-
Cited tiloollow? + nzortilill MMI(Mltrf-2 nOntlAl 11101100191111"
40. *,V%ril"i 1114nn"nef - ra.fical" (k.). and "Md"I +
1111"11,111ri -- dinirr" jk#1. The t4juatilin -hit%%% that r J,
1114101WIliltill Lit thin. And PtI1110fliMnAl fit I In IN% In-
Scalwe file length .# file "Ificletic el"111" (, - life na. 44
tnotiontef, involved in a chain initiated hy wie rwticAl) is
"JUA t0 thA't Of the -132011. CtL-dU" (h - the 00. Of HUM10-
nlv~ its the tnal. of polynter); if4U WCTe " active 44 U. v
NIM1111 1W Pinch gTCAC7 than h. 111e itinCt" Of PtAYttttTi-
file rcldlkm lelwrv# A and V.
I , J. Hikemau

MEDVEDEVI Si S.
USSR/Chemistry - Plastics
Jul 51
"Kinetics of the Polymerization of V nyl Chloride in Solutions Under the Action of
Benzoyl Peroxide,w G. V. Tkache ko, P. M. Khomikovskiy, S. S. Medvedev, Moscow
"Zhur Fiz Khim" Vol XXV., No 7, pp 823-836
PA 206T24

Medvedev, S. S., ed.
KONI=FWSIIA po vysokomolekuliarrWm soedineriiam. 7th Moscow. Chemistry
and phy5ics-chemistry of polymers; report Moskva, Izd-vo Akademii nauk
SSSR, 1952. 312 D. (53-18332)
QD23l.P6K6

UM/OWNdstry - Blastomers;'Plastice 7eb 52
"WA3.7tic Po3perization of Ungstamted, Er.,Ajroc&Tbons,
M- W&I.7tic P017218rizatiOn of Isoprene.," A. R.
Unt=W&Mrjp S. S. Medvedev, PbTs Chm Ingt imni
L. Ta. MLrpov, Moscow
,"Mor Fix xhim" vol xxv , No 2, Vp 173-179
ROMMU on the cstal7tic polymerization of
V:Lth ftalk in an ItCl soln agme wIth those ebtalsed.
CIft 61tyr";. ne rate of reaction iwreaoe$,LVI+J&
Ujail Uesuge there its an automtalybic j=rftft of
tht XIMIAW of active centers In the bmwbA eWn
r"etlft', Bmwhing of reaction chains oems vaftr
rpaltle#stion of SW1) In agreezentwith tiw
~iseecbnn4mz, Z inhibirs acceleration of
=d laws" =1 vt of Vroducts. At.
VWritation of isopreW &Oas
%ranabed chain, P03,
even Vith s, lw* monomer. Intery-tice of
ebwww vitbL double bonds of P03,VMrL no's
rednition of deg of uwmtn. Reduation
df +Ai''conen of monomer rewUts in damvase! of deg
Of V6iatn and increase of the temp of gelatim.

f-1)
E-CMSR/Chemiatry - Elastomers, Polymeriza- 21 Oct 59
tion
02
to Initiation Mechanism in the Catalytic Polymerization
of Unsaturated C~ompoundsj" A. P. Gantrdakhery S. S,
Wdvedev, Corr Mem, Acad Sci USSR, T. E. Lipatova
"Dok Ak lqauk SSSR" voi B6, No 0, pp 1109-1111
A conclusion drawn by P. H. Plesch, M. Polanyi, H. A.
Skinner, A. S . Evans,' and G. W. Meadows is found to
be incorrect. These authors claim that in the cata-
lytic polymerization of isobutene in the liquid stitte.
or in hexane solus with TiC14 and BF, catalysts at
234T25
1M temps, the addn of H20, CC13 C00H, etc., is nedles-~~
nary in order 'that the reaction may proceed. This.1s'
disputed in the present work: It is shown that by
ralsing either the temp or the dielec const of the
Solvent, ca1calytic polymerization of unsatd compdo
can be made to proceed in the presence of aprotoftid
acids (SnC14, AlCl3, BF TiCl) and others) withou-b
the addn of if 01 C~~ C;~i"
"I ~a or other substances
noting on the cataj;s er formation of protonic'
acids.

USWChadsU7 - Plasticso Polymers
11 Jon 53
nha Nature of the &ww'Ing RwcUcc During Radical PolimerizatIon of Mr-nes,O
A. D. libktnp S. ff. 9a skayas S. S. vA&edev, Corr Km -Amd SA UZZ-H, Scd.-Hes
Pholochem Inst lumd L. Tn. Karpov
D" 3SSII, Vol 88, No 2, pp W0,271
A quant a,.;prai-,~al is ~,.,iade of I.r,- -s..,cclfic raLons of '~ e reacti)n Lne
polybutadiene ra~Iical and ;.oly'Duta-li,-ne particlots- at the ri,-~.no- bind ii-: ubst.-JItute-J,
dotible bond.
F- Z~.,TI5

kr~ p6lykairylit --filmi
D3.jqciing we, macro--
lcne.-.;sur. ajdd~,:'b
t f thia
F-iiA to t I k' 'Ah' " I
r.: a ness~ anl:g~--# PO Y.!!--
ayer . c)
I -JU
-fi;-k Ql~~'Ll 6~
dii'
~;Ua
!;h
e

P Pl. _P
-TI
jila'a serve,

Gard
AOthoj
~n 7
-I%riod

KKDVMMV, S-S. (ChkELIOV).
1-7-
-
, -Z,-
Regularities in the operator's performance [with Inglish summary
in Insert]. Avtom.i t9lem. 17 no.11:985-1000 9 156. (MLEA 9:12)
(Labor Droductivity)

XCDVZM, Si S. - -
, NnWiSt, 'k, ;V..
.V* #P
'ali,41 M,
.900
Relation of seismic action to the natural vibration periods of
structures. Trudy GeofizAnst. no.36:80-113 '56. (KLRA 9:8)
(larthquakes and building)

86-1-27/30
AUTHOR: Aronin, G.S., Engr Col, Docent, Candidate of Technical
Scisnces; and Medvedev, S.S., Engr Lt Col, Candidate
of Technical sciences.
TITLE: Estimating the Combat Capacities of Fighters (0 rashchete
boyevykh vozmozhnostey istrebiteley).
PERIODICAL: Vestnik Vozdushnogo Flota, 1958, Nr 1, pp. 84-86 (USSR)
ABSTRACT: Under this title appear two articles under the following
subtitles: 1. "Unjustified Method" by Engr Col G.S. Aronin
and 7. "To Continue the Re3earch for a More Acceptable
Method". by Engr Lt Col S.S. Medvedev. The authors discuss
the article "Combat Capacities of Fighters and the Method
of Determining Them" by Col R.Ya. Kudryashov and Lt Col
P.G. Nikitin, which was published in the No. 8 issue of
this periodical in 1957. Both, Aronin and Medvedar, raised
Card 1/2

86-1-27/30
Estimating the Combat capacities of Fighters (Cont.)
some objections to the method suggested by Kudryashow and
Nikitin. Particular attention is drawt. to the inadequacy of
the new concept of "determining the degree of superiority of
the figher-plane over the enemy", which is expressed by
coefficient C in the final formula of the computations.
AVAILABLE:
Card 2/7
Library of Congress

sov/86-58-8-13/37
AUTHOR: -ACqvedev, S.S., Engr Col, Candidate of Technical
ScienceY--
TITLE: Calculation of Dynamic Characteristics of a Gunsight
While Firing (Uchet dinamicheakikh kharakteristik
pritsela pri strellbe)
PERIODICAL; Vestnik vozdushnogo flotaj 1958, Nr 8, pp 37-39 (USSR)
ABSTRACT: The author states that a knowledge of the dynamic
characteristics of a gunsight is of great importance
In modern air battle, because this helps to improve
the accuracy of firing and reduces the time of tracking
a target. The author desiaribes how the main component
of total corrections, the lead angleis plotted during
the aiming procedure with the ASP-3 gunsight. Four
graphs.
Card 1/1

~-EIMEDEX 3. S., and SILEM-11ERY it. r.
-1 1- -
"'tudy of the lUrietics of Pol~,meriz-,tion ir, Cclloidl Solutiors of Sonps ard !-,voisions"
Z' 6 -
(Issledovaniye kinet'Lki polimrizatsJ-l -v 1-olluid.-,y1ch r~stvorakh mn.l i emullsiyljkli)
from the book T4eudy of the Third A-U-U-Iion 03riference on Colloid Cliemistry,,Vup. 450-457,
Iz. Id-11 SSSR,
fReport given at above Conference, Nlinbk, 21-4 Dec 53)

USSR/Chemistry of High-Molecular Substances, F
Abst Journal: Referat Zhur - Kh~miya, No 1, 1957, lliO
Author: Soboleva, I. G., Makletso, -., N.. V., Matveyeva, A. V., and
S. S.
I.WMMWA.
Institution: None
Title: Investigation of the Structure of Butadiene-Styrenre Copolymf-.rs
Original
Periodical: Kolloid. zh., 1956, Vol 18, No -1, 344-349 (published with a summary
in English)
Abstract: 0smometric (osm) and light-scattering (list) methods have beer, r-pplied
to the determination of the molecular weight M of a number of butadiene-
styrene copolymer fractions, prepared by carrying out- '.so1ympr'_1zat_'on
until varying degrees of conversion were achieved, as well, as of some
wfractionated. polymers; the dissymmetry factor and the in-,rinsic vis-
coBity were also determined. The large differences betweer, M (osm) and
M UiBt) which were observed point to the presence of rw?laTivelY large
amounts of very large particles in the butadiene-sty-rene c~,pclymer
Card 1/2

USSR/Chemistry of High-Molecular Substances, F
Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 1110
Abstract: solution. The influence of these particles can be detected only by
statistical averaging. The presence of such particles is also in-
dicated by the large values of the dissymmetry factor and the tur-
bidity factor. The authors assume that the macroparticles present in
soJution form the seeds of extended layers. The hypothesis postulat-
int, '.he formation of large --nolecules with extendd chains during the
polymerization of styrene with butadiene is also confirmed by the
low rate of increase in the assymmetry of light dispersion and the
reduction in intrinsic viscosity with increasing molecular weight.
It is shown that the heterogeneity of the fractions and chain length
of the copolymer molecules increase with conversion and reaction
temperature.
Card 2/2

GRITSMO, T.M.; KCDVAW, S.S.
Kinetics and mechanism of polymerization initiated by redox
systems. Part 2. Polymerization in aqueous solution of metha-
cr7lic acid and acrylonitrile In the preaence of certain redox
systems [with Inglish summary in Insert]. Zhur.fiz.khim. 30
no-7:1513-1520 Jl 156. (MLHA 9:11)
1. Fiziko-khimicheakiy institut imeni L.Ta.Karpova. Moskva.
(Hathaerylic acid) (Acrylonitrile) (Polymerization)

V
E
G V)
Category: U&*Chenistry of High-Kolemasr Substances ?.
Abe Jour: Referat 0mr-ftinlys, No 9, 1957, 30897
Author : Gritsenko T.M., Wdvedev
Inst : Acadexy of Scleaces 'USSR
Title : Kinetics of Polymerization of Acrylic Acid and Methaerylaltril
in Water Solution in the Presence of Cumene Hydroperoxide
OeLg Pub: Dokl- AN 8SSR,, 1956, 110, No 2, 235-237
Abstract: Study of the kinatics of polymerizatLon of acrylic acid (I)
and nitril of methacrylic acid (II) in aqueous solutions in
the,presence of cumene hydroperoxide (III) at 36-700. '1uma-
tive energy of activation of I and II, respectively, is of 9.0
and 20.2 kcal/mole. PolywriLLtion of II occurs with accele-
ration with lapse of time, which the authors attribute to the
capacity of II-polymer to extract II and III from the solution.
Order of reaction of the ==amer is 3/2 in both instances. De-
pendence of initial rate of polymerization of I and II on the
concentration of III, am analog=s to those ji6viously deter-
Card 1L/2 -9-

? S
VE DVED-V 5 tj,,.d PRATEDITIKOV, A. 1:.
ZLU-~~.v
"YAnetics T)nd mechanism of c~doroprcne polymrization," a paper
presented at the 9th Congress on tlie Chemistry and Physics of High Polymers,
21" jan-2 Feb 57, Aoscov, Knrprr,, Inst.
B-3,0e'W95

~,2DVEDEVJ S. and GAliTIMaU-,, A. A.
I S.j
"Kinetics of coplymrizatior," j paper presented at Uie ~~tth, Ccrit!p:ess
on the zind Fir-04('s Of MFli Polymers, 2C Jar:-2 Feb 57, 1,110scow,
Karpov Inst.
B-3,904,395

ILIXV-11)ILL S.jj~. wid T. 14.
"Initiat-ion of enuision, copollfmcri:,atior, with rumy-lhydropcro;pide," n
paper presented at the f~~th Congress or.. t'.-le Chemistry and P'-.,,-sics of HiGI,
Pd:~mrd, 28 Jan-2 Feb 57, Mloscolj, Karrcv Inst.
B-3,0~~--4,395

,EDVEDEV, S, S., and I'MOMIYUCOVSK-1Y, ". I.I.
I
I
"Activation energy in emulsion
the S)th Congress on the Chemistry and
57, 11.10scov, Karpov Inst,
polymerization," a paper presented at
Physics of. High Pol-y-Mers, 2C Jal~-2 IFeb
B-I;nC4,K-'5

~ 1) , ". V.
I-SWEDEV, St-~i, ar)d SABOILq'VJLYA
'IT'he role of absnrbeOl layerz ir, emulsion-i)oly-.~eriza'.J'D-.-," 0 pa-,,,r
-r,resented at the S~tth Congress or the Chemistry a
- , nd Physics 04, Polymers,
2,c-' Jar--2 Feb 57, 1-Ioscow, k-lr'-rjo-; I";3t-
B-3,084,3095

EDVEMV, S. S.
N
I
"Rodiation polymerization," a poper submitted atu the Interratiolial
Conference on Radioisotopes in 3cientific Research, Paris, 9-20 Ser. ;7.

MEDMEVO S. S. Prof I
"Mechanism of Initiations" Section II, paper sW3mitted at the
International &Mosiur on Hacrowlecular Chemistry, Fraguas 9-15 Sep 1957
C-398000271

AUTHOR: None Given 3-9-19/31
TITLEj Inter-vuz Sdmtlftc Coadn-amms(Mezlivuzovskiye aauchnrle konferentsii)
PBRIODICALi Vestnik Vysshey Shkoly, 1957, # 9, PP 73 - 76 (USSR),
ABSTRACT: In January 1957, the Second All-Uni.on Conference on Pho*.o-
synthesis took place, organized by the Institute of Plant Phys~-
ology of the Academy of Sciencoe, USSR, and by the Faculty of Soil-
Biology of the Moskva University. About 700 representativen of
130 scientific-research institutes, vuzes and ministries were
present. The in*,roductory report was made by Academician A.L.
Kursanov who described the development of photosynthesis during
the last ten years and invited the scientists to concentrate their
work on the application of radioactive and stable isotopes.
Nearly100 reports were read: 13 on photochemistry, 9 on the in-
vestigation of chloroplast structure, 19 on the invest~gatiozl
of pigments, 9 on the photosynthesis of water plants, Acteria,
etc.
Reports on the results reached in the field of photosynthesis
were made by: Doctor G. Polster from the German Democratic Re-
public, Professor N. Seledzhanu from the Rumanian People's Re-
pliblic, Professor K. Popov from the Bulgarian People's Republic.
Finally the Conference stated the great role Of Soviet Bcien-
Card 1/7 tists in the development of photoBynthe3is and gave some defi-

Tnter-vuz &ientific Conferences
3-9-19/31
ciencie5 in the research organization, in particular, the in-
sufficient participation nf biologists in the solution of the
problem in question.
The.Ninth Conference on High-molecular- Cc-mbinations took
pl ace f rom--n-J~'nuary- -to -1 _Peb_r_-u_a_r_y . - It w a a o-r--g- a n-i-zed by the
USSR Academy of Sciences and the MGD and concentrated on general
matters of polymeric chemistry and physics. About 1500 scien-
tists were pre3ent from 172 organizations and 37 towns of the
Soviet Union, the representatives of 42 vuzes and 17 foreign
scientistn from China, East Germany, Poland, Rumania, Czecho-
slovakia, Yugoslavia, the German Federal Republic and Israel.
The introductory speech was made by Academician V.A. Kargin,
who described the present state of science relating to polymers,
and invited the scientists to concentrate their work on new
methods of obtaining polymers, and new classes of high-molecular
substances. In the section of polymeric synthesis 43 papers
were read. The author enumerates the following reports:
Academician A.N. Nesmeyanov on the reaction of ethylene polymeri-
zation and carbon tetrachloride.
Member-Correspondent of the USSR Academy of
Sciences, on the kinetics of various types of polymerization.
Professor B, A. Dolgoplosks (Leningrad) on the initiation
Card 2/ 7 of radical polymerization.