SCIENTIFIC ABSTRACT MELNIKOV, N. N. - MELNIKOV, N. N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033510003-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Organic Insecticides and Fungicides 7,-2-,. 1,"r-
A New Method for the Production of Mixed Esters of Thiophosiphoric Acid
accordance with ..I. Kabachnik, S.T. loffe and T.A. Liustry'llova
(reference 4), since 0,0-dialkyl-zi-aryl-thio hospi,ates and in
onl.y once case thianisomers predo;:iinate in the reaction .)ro~.Act.
The results obtained show that tht: iuantity ratio of' t .,ie iso.:Iurs
is more influenred by the attacking reagerit than bj th~ reaction
.:iedium. The viorking methods as well a:, t,-jblL-s uf ',~ie pro e r t i r-.,;
of eaters are -iven. There are 1 table, and , Sluvic rLf r.-rices
0
ASSOCIATION: 3cientific Institute for Fertilizers, Insecticides and Gungicides
04auchnYj institat po udobrenija~m i inse1z,tufanlaitaida-i)
SUBMITTED- January 16, 1957
AVAILA3LE: "ibrary of Con:,ress
Card 2/2

r,, 0 V , W, fV -
AUTHORS.' Mandelfbaum, Ya, A., Meltnikov, N. N., Petrova, N. I. 72-2-42/6L
TITLE: Urganic Insecticides and Funrricides( Iz
oblasti orguniched-kikh.inrektofung~Ltsidov)
XXXII. The Synthesis of Some lixed Ethers of Thiophosphoric Acid
(XXXII. Sintez nekotorykh smeshannykh efirov tiofosfornoy kisloty).
PERIODICAM Zhurnal Obshchey Khimii, 1958, Vol. 28, Nr 2, pp. 479-48o (USSR).
ABSTRACT.' The reaction between mixed dialkylchlorthiophosphate and methanol,
ethanol resp. was investigated in the presence of caustic soda. It
is found that the corresponding trialkylthiuphosphates are obtained
with good yields (70-940/o) in the reaction. The reaction can scherna-
tically be represented as follows:
RD \PSCI + R"CH + NaCH -+ RD > PSOR " + mac i + 11 0
R1 2
0 RIO
The major Dart of the compounds obtained have hitherto not yet been
mentioned in technical literature. The specific properties of the ob=
tained compounds as well as the preparation process are given.
There are I table, and 3 Slavic references.
Card 1/2

Organic; Insecticides and Fungicides 79-2-42/64
ASS CIATION: Scientific Institute for Fertilizers Insecticides and Fungicides
I
?Nl;iuchnYY institut po udobreniyam i insektoffrgJitsidam).
SUBMITTED: January 16, 1957.
AVAILABLE' Library of Congress.
Card 2/2

'5- L
AUTHORS: Kukalenko, S. S., Mellnikov, ii. IN., 7)-2-, 5/0-1
Naryshkina, T. 1. , Shuyk-i_n_7---T-.
TITLE: Ur,;anic Insecticides and Fungicides Iz oblasti
organicheskil-ch inoijktoi 'ungitsiuov) AA.~M. !~jnt!,.esis
Derivatives of 4,7-L-ndoniethjleriet~,,tr~thy(;roiridari
tez nekotorykh proizvodiVkh 4,7-endo,-uetileritLtrt~,i(ir,oii-,('aiia).
PERIODICAL: Zhurnal Obshchey Khimii, 1958, Vol. 28, Nr 2, pp. 4FJO-483 (~L;-H)
ABSTRACT: In order to investigate the insecticide-properties of chlor-
dane and heptachlorine homologues, an adduct was obtaiiied frc.m
hexachlorocyclopentadiene and 3-methylcyclopentadic;ne-2,4' by
heating at 85-1050C. It is assumed that t,ie reaction ta'."'~3
ce as follows:
C1
CC12 + 3
Cl C
,I 1~c
1~j C1
The product, a yellow viscous liquid, was chlorinated or bromiz-
Card 1/2 ed resp. and the compounds obtained were tested for their in-

79-2-43/64
Or:,,anic insecticides and Fungicides. =I1. 3ynthesis
of Some Derivatives of 4,7-Endomethjierietetrahydroinuan.
secticide-properties. It was found th--.t all of them have a
lower insecticide efrect than "chlordane". These comoounds
have hitherto not been described in technical literature.".'he
working methods and the specific data of the compoui-,ds are
gLven. There are 5 references, 2 of which are Slavic.
ASSOCIATIU.'i: Scientific Inz'kitate for Fertilizers , Insecticick-as and Fungicides
ana Institute for Ur~~anic Che;..i-3tr.:- I'S J~;L~A (Nauchnyy iristi-
tut po udobreniyam i insektofungitaidam i Institut organi-
cheskOY khimii Akade~aii nauk SiSR).
January 16, 1957
AVAILABLE: Lilbrarj of Cun.,r-ss
Card 212

MMINIKOV. U.N.; KANIMIBAUM, Ta.A.; BAKAHOVA. Z.H.
Organic inaecti- and fungicidea. Part 34: New synthesis of trialk7l-
phoaphites. Zhur.ob.khim. 28 no.9:247)-2474 5 158. (MIRA ll.,11)
(Phosphites)

SOV/79-28-11-49/'55
ArT"ORS: Volodkovich, S. D., Mellnikov, Plate, A. F.,
Pryanishnikova, M. A.
TITLE: From the Field of Organic Insecticides (Iz oblasti organiches-
kikh insektofungitaidov) XXXV. On the Reaction of the 1,1-
Difluoro-Tetrachloro-Cyclopentadiene With Some Unsaturated
Compounds (XXXV. 0 vzaimodeystvii 1,1-diftortetraklilortsiklo-
pentadiyena s nekotory-mi nepredellnymi soyedineniyami)
PERIODICAL: Zhurnal obshchey khimii, 1953, Vol 28, Nr 11, pn 3123-5126
(USSR)
ABSTR--~T: In the investigation of the effect of the chlorine containinE7
insecticides of the type of "aldrine", "dildrine", and their
analogs as well as the de-pendence of the fatal effect of these
compounds on insects upon the molecular structure it was
of some interest to investigate in this respect the
to unknown fluorine containing analo.-s of "aldrine". First
the folloving compounds vere synthesized by the reaction
of 1,1-difluoro-tetracliloro-cyclol)entadiene with bicyclo-
Curd 1/5 (2,2,1)-heptadiene-2,5 and bicyclo-(2,2,1)-heptene-2: 102P3,4-

SOV/79-28-11-49/55
From the Field of Organic Insecticides. XXXV. Cn the Reaction of the 1,1-
Difluoro-Tetrachloro-Cyclopentadiene With Some Unsaturated Compounds
tetrachloro-lo-lo-difluoro-1,4,5,8-diendomethylene-1,4,4a,5,8,8a-
hexahydronaphthalene, and 112,3,4-tetrachloro-lo,lo-diL'luoro-
1,4,5,8-diendomethylene-1,4,4a,5,6,7,8,8a-octah~'dronaphthalene.
As the next analogs of "aldrine" they are of great interest.
Besides, the adducts of the 1,1-diflijoro-tetrachloro-cyclo-
pentadiene with cyclopentene, 5-amyl bicyclo-(2,2,1)-heptene-
2,5-methyl bicyclo-(2,2,1)-lieptene-2-carboxylic aci~-5,
acryl nitrile and the esters of maleic acid were synthesized
(Table). The reaction of the above pentadiene with the men-
tioned unsaturated compounds taken place easily, the yields
are, however, small as it is easily polymeri~;ed arid trans-
formed into the inert dimer. All synthesized compounds have
a weak insecticide effect. Only the difluoro "aldrine" is
an exception an its insecticide effect is similar to that
of the chloro indan. There are I table and 10 references,
7 of which are Soviet.
Card 2/3

SOV/7.)-28-11-4 1-1,~rl; 5
From the Field of Orw~lanic Tnsecticides. XXXV. On the Reaction of the I, I -
I)ifluoro-Tetrachloro-Cyclopenta!lienc With Sonic Unsaturated Compounds
ASSOCLITION: Natichnyy inatitut ;~o udobreniyari i insektoftingitat-111m, i In-
otitut or,-anicheskoy khinj4 '!-ZLde7niJ r.Pl"'
(Scientific Incttitute, of Fertilizers and Insecti- and Fungicides..
and the Institute of Organic ChemistrylAS USSH)
SIT BMITTED: November 1, 1957
Card 3/7)

AUTHORS: Mel I nilkoy if. N, , Vol odkovi ch, S. D. SOV/79-28-12-3-/41
~A-- Y I
TITLF: From tho Field of Or~,-,anic InnPcti(!idetj (I,-, obl~knti organirhea-
kikh insel-tofiin,yitni~!ov) X'~.XVI. On tl~e Reaction of Tetra-
chlorc and Pentachloro Cyclopentadiene With Some Unsaturated
C0:P,p011,ndfj (XXXV1. 0 vv.Limodcyntvii tetrakhlur- i pentLkhlor-
tslklopent~~di,,,,onov o nekc%toryml neprodellnymi soyedineniY[Mi)
PEPIDDTCAL. Zhurnul ol,,,3:irh,,y )-hi%iii, Vol 20, Nr 12,
Pp 331' - 3319
ABST~A",T: The -~ynthu,,;~,q and inve~;tij.-ation of the firal products
obt.-ined in th,~ reaction of 2,1,,4,5-tetrachloro and
cyclopentnrliene vith unsaturated
co:npoun,ls are of ,,,reat interest with respect to the dependence
of their insr-cticide pro:)erties on their structure, as also
the clarif-l"cLtion ~)f the ef"ective mechanism of the given
6zroup on in3er-ts pl~--ys a role in this problem. It was
especially interertin,z to co,.ipare the insecticide activity
of the flur,,r4.r:e contE~inir~, of aldrin obtained by
the authors-, i).me time n;Eo with the compounds containing hydro-
gen anc a atom in the endomethylene bridge. The
Card 1,j- ~oiL:.uis carried out. condeiisations of the two above-mentioned

From the Field of Or,-,-,,-tnic Insecticides. UX111. n t ; c. SOV 79- 28-12-35/41
Reaction of Tetrachloro and Fe:.tachloro Cy7~lopenta-iiene With Some Unsaturated
Compounds
Card 2/~,,
cyclopentadiones with bicy(-lo-L2,2,1 heptene, bycyclo-
9-
C2,2,13-h,~Ptadienc--2,5, the enters of maleic acid and some
other compounds (Table). This reaction takes almost the same
course as in the case of hexachloro cyclopentadiene at
110 - 1300 within a few hours. Some hitherto unknown tetra-
ard pentachloro derivatives of the polycyclic compounds were
synthe:-i~,ed. It aa:3 shown that the substitizents of the endo-
methylene bridge exert a considerable influence upon the
toxic effect of Vne compounds of the aldrin type. This
effect is decreased at the transition from the .!ichlor,, to
the monochloro and furV!er to the difluoro derivatives.
1,2,3,4,1-.D-Der,tachloro-1,4,5,0-diendometliylene hexahydro-
naphtha'lene is the mo9t active of the compounds synthesized
by the aitthors for the first time. In this respect it exceeds
chloroindan twice, ard is e,iu.;l to aldrin. There are
~a*uie and 8 r--~fercnces, 4 of ,,ihich are Soviet.
L i-, L, a,

MELIIIIKOVP H.He" prof.
FVngicides and disinfectants of seeds. Zaahch.rast.ot vred. i bol. 4
no.455 R-Ag 1159. (MIRA 16:5)
(United--.%tate"eeds4isinfection) (United States-Fungicides)

PAVWVSKIY, Ye.N.. akademik, glavnyy red.; GILYAROV. H.S., otv.red.;
LOM, A.G.. red.; KKk!YLKpT -,red.; YRDOTROT, D.K.. red.;
YAKCVUV, B.T., red.; ZINYAKIN, L.A.. red.; SABLINA, T.B..
red.izd-va; VOLKOVA, V.V., takhn.red.
[Transactions of the International Conference on the Study of
the Colorado Beetle and the Development of Measures for its
Control] Trudy Mezhdunarodnogo soveshchaniia po izuchenlin
koloradskogo zhuka i razrabotke mer bor'by s nim. Moskva, Izd-vo
Akad.nauk SSSR. 1959. 329 P. (MIRA 12:8)
1. Kezhdunarodnoye soveshchaniye po izucheniyu koloradskogo
zhuka i razrabotka mar bor'by a nim, 1956. 2. Nezhduvedom-
stvennaya metodichaskaya komissiya po koloradskomu zhuku.
Akademlya nauk SSSR, Moskva (for Gilyarov). 3. Nauchnyy in-
atitut udobrenty i insektofungitaidov, Moskva (for Kellnikov).
(Potato beetle--Con4gresses)

PHASE I BOOK EXPLOITATION SOV/3494
Reaktaii i metody issledovaniya organicheskikh soyedineniy, Kn. 8 (Reactions and
Research Methods of Organic Compounds, Bk. 8) Moscow, Goskhimizdat, 1959.
446 p. Errata slip inserted. 4,200 copies printed.
Eda (Title page): V.M. Rodionov, Academician (Deceased), B.A. 103zanskiy, Acad-
emician, I.L. Knunyants, Academician, M.M. Shemyakin, Academician, and
N.N. Me~llnik ~ Professor; Ed. (Inside book): V.P. Yevdakov; Tech. Ed.:
-V-.r-Zazullskaya.
PURPOSE: This book is intended for laboratory personnel at industrial plants,
for instructors and students at higher educational establishments, and par-
ticularly for scientists and researchers vorkiag at the numerous research
institutes in the Soviet Union.
COVERAGE: This is the eighth volume in a series *Reactions, and Research Hathods
of Organic Compounds." This series does not duplicate the one published in
English under the title wOrganic Reactions" and appearing in Russian transla-
tion*, however, some material, of particular interest, is included in this pub-
lication. The present aeries is primarily devoted to revieving the works of
Soviet chemists. The eighth volume of this series deals with thiocyanation
Card 1/4 _)_
Reactions and Research (Cont.) BOV/3494
reactions of organic cOmgDunds and method, of studying them.
data on analytical methods using thiocYanates for the Study of It Presents
Oils,, and volatile oils. fats, mineral
It discusses the use Of thiOcyanate for p to-
gr3phic emulsions, acceleration Of rubber vulcanization, stab a ho
lubricating oils, ilizat,on of
Purification Of tars, abatement of corrosion and Purifics-
t'On of metals, Production of mustard oil, and Synthesis Of Sulfur-bearing
Compounds. It also discusses the use Of thiOcyanates as solvents for
acrYlonitrile Polymers, as intermediate Products in the synthesis of dyes,
as antiseptics, bactericides, medicines, insecticides, and fungicides. The
book contains 327 pages of tables listing 1449 initial organic compounds
subjected to thiocyanation. The tables give fozT=las of the
Pounds, the names and structural formulas initial com-
Conditions, the reaction Products and thei of the compounds, the reaction
the theoretical yield r Yield percent as compared vith
., as well as references to the literature on Which the
data are based. There are 797 references: 376 English, 228 German
47 French, 17 Italian, 25 J , 74 Soviet
Tapanese, 7 Polish, 7 Scandinavian, 3 Belgian,
8 8vi8si 1 Dutch, and 4 Hungarian.
Card 2/1P _~,_

ki.
jr.
SIT
! r
91-
- -------------
'fill Or
Ell [III Ma
ch. c1
A
I P31
Fj-g Corti k1
r
f6 Bu --I
xj
to -11as rj
;IaR
aal
IV "ir- if
, J"
,
fr
jjcs
vu

0 1
jr

gg j

nL I NIKOV,~, -
Simazin, a now herbicide. Zaainch.raot.ot vrod.i bol. 4 m.3*53
My-Je '5 9. (Triazins) (MIRA 13:4)

RAKITIN, Yu. V.; M&LINIKOV. N.H.; SHIDLOVSKATA, I.L.; BOKAREV. K.S.
Structure and physiological activity of some 2,4.5-trichlorophenox7-
acetyl amino acids. Fiziol.raot. 6 no.6:?29-7.34 H-D 159.
(MIU 13:4)
1. K.A.Timiriazev Institute of Plant Physiolog7,.U.S.S.R. Academy
of Sciences, Moscow.
(Growth promoting substances)
(Growth inhibiting substances)

AUTHORS: Mandellbaum, Ya. A., i4e I I nilcov -2) -1- 59/74
Zaks, P. G.
TITLE:: On the Field of Organic Insecticides(lz obla.,ti organicheskikh
insektofungitsidov) XXXVII. S:vnthesis of Several 11,1ixed
Thio- and Dithiophosphoric Acidn (XXXVII. Sintez nekotorykh
smeshannykh efirov tio- i ditiol'oofornykh kislot)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, pp 285-285 (USSR)
ABSTRAM Besides thio- and dithiophosphates of the general formula

2 ~d_ _- 2 n
(RO) P ox X(CF_ ) SRI (I) used against plant pests, compounds
of the general formula
(R0) F !~~S SCH CON R
2 2
2 ArO '~, PSCI + (CIH30)21fg ---b. 2 ArO PS(GqHa)l + MgC13 (2)
C2H.()/
2 Ar0PS(0CsHs)jj + (CIH60)2AIg - 2 (CSHIO)2PS + (Ar0)2H9I (3)
Aryl.dichlorothiophosphates and magnesium ethoxide
taken in stoichiometric amounts gave chiefly alkyl aryl
chlorothiophosphates or the corresponding diethyl ar~!
thiophosphates. Transesterificatipn (Formula 3)
occurred only with large excess of magnesium ethoxide
and on prolonged heating. Accordingly, 0.1 mole
phenyl dichlorothiophosphate and 0.05 mole magnesium
ethoxide on heating for 3.5 hr gave O-ethv
.bl 0-phenyl
chlorothiophosphate (yield 64%; bp 95-100 C/0.2 mm).
The same reagents taken in amounts of 0.05 mole and
0.1 mole, respectively, gave on heating for 7 to 17 hr
0,0-diethy~ 0 henyl thiophosphate (yield 82-91%;
Card 2/# bp 120-122 C70.8 mm). 0.1 Mole 2,4,5-trichlorophenyl
3

Concerning Organic Pesticides. LII. 77380
Concerning the Reaction of Arnjl- SOV/79-30-11-4-7/78
Dichlorothiophosphates With Magnesium
Ethoxide
dichlorothiophosphate and 0.3 mole magnesivun ethoxide
on heating at 65-700 C for 18 hr gave 0,0-diethyl 0-~)
4,5-trichlorophenyl thiophosphate (yield 78%; bp 130 6) C//
0.13 mm); also, 2,4,5-trichlorophenol (yield 13%;
mp 620 C), and triethyl phosphate (yield 15%). Under
similar conditions, 0.1 mole 4-nitrophenyl dichlcro-
thiophosphate and 0.3 mole magnesium ethoxide gave 0,0-
diethyl-0,4-nitro~henyl thiophosphate (yield 40%; bp
1.56-1580 C10.3 mm; also, p-nitrophenol (yield 218%;
mp 1120 C), and 0,0,0-triethyl thiophosphate (yield 30%;
bP 51-520 C/0-3 mm). There are 10 references, 2 U.S.,
I U.K., 7 Soviet. The U.S. and U.K. references are:
H. D. Orloff, C. J. Worrel, F. X. Markley, J. Am.
Chem. Soc., 80, 727 (1958); R. F, Hudson, L. Keoy,
J. Chem. Soc., 1953, 246-1; T. R. Fulcuto-, R. L.
J. Agr. Food Chem., 4, 930 (1956).
Card 31

5-1320,5-3630,5.~610 77381
S0V/-9-,-,G --, -4
AUTHORS: M21~~ Shvetsova-Shllo,,~skaya, K. D., M.411sh'-e--
1. M.
TITLE: Concerning Organic Pesticides. LIII. Concerning the
Reaction of Esters of Thio- and Dithiophosphoric- Acids
With Tertiary Amines
PERIODICAL: Zhurnal obshchey khimii, 196c, Vol 30, Nr 1, pp 1-97-1-99
(USSR)
ABSTRACT: Looking for the explanation for the biological action of
insecticides based on organophosphorus compolinds, '~he
authors assumed "hat the phosphorylation of cholinester-
ase, advanced by many authors, cannot be the only
reason for this action. Another explanation could be
found in the formation of quaternary ammonium salt's in
the reaction of thio- and dithiophosphori,- acids wltr~
tertiary nitrogen atoms present in many enzymes and in
nucleic acids. It was established in ',--.he present study
Card 1/0 that esters of thio- and dithiophosphoric acid reac-ed
2--

Concerning Organic Pesticides. LIII, Con-
cerning the Reaction of Esters of Thio-
and Dithiophosphoric Acids With Tertiary
Amines
ASSOCIATION:
SUBMITTED:
Card 2/e
21-
77381
SOV/179-30-1-14-2/"'
on heating with tertiary amine3 and give the corresponding
ammonium salts as the chief product. The highest reac-
tivity was shown by esters whose molecule contained at
least one methoxy group, as well as acidic aromatic
radicals, The 11 new compounds thus obtained (s,e
Table) were extremely hygroscopic, and their density
could not be determined. There is 1 table; and 7 refer-
ences, 4 U.S., 1 German, 2 Soviet. The U.S. references
are: J. E. Casida, J. Agr. Food Chem., 4, 772 (1956);
T. R. Fukuto, The Chemistry and Action of Organic Phos-
phorus Insecticides, Advances in Pest Control Research,
I. N.Y. (1957); T. R. Fukuto, R. L. Metcalf, J. Agr.
Food Chem., 4,930 (1956), U.S. Pat. 2652416.
Scientific Institute for Fertilizer~,, and Pesticides
(Nauchnyy inatitut po udobreniyam i insektofungi'tsidam)
Jartuar"j 19, 1959

5.3630 77382
SOV/79-30-1-43/78
AUTHORS: Mel'n1kov, N. N., Shvet3ova-Shilo7skaya, K. D.,
TITLE: Concerning Organic Pesticides. LIV. A New Method of
Preparation of Trialkyl Dithlophoephates and Tetraal-
kyl Dithiopyrophosphates
PERIODICAL: Zhurnal obahchey khimil, 1960, Vol 30, Nr 1, pp 200-
203 (USSR)
ABSTRACT: The reaction between bis(dialkoxythiophosphoryl) di-
sulfides and dialkyl phosphites, in the presence of
triethylamine, proceeds with the formation of corres-
ponding esters of dithlophosphoric acid.
j(R0)2PS1ZS2+ (R'0)2PO H N((-'2ti,)3 - 2 (n0)2PSSR'+ (C2"5)3NHP03'.
The obtained produces are mostly new compounds (see
Table 1). The reaction between bis(dialkoxythiophos-
Card 1/jp M.a phoryl) disulfLides and triallry'l phosphites proceeds
3

Concerning Organic Pesticide3. LIV. A New 77382, SOV/79-30-1-43/78
Method of Preparation of TriaIVyl DithJ.o-
ohoophatee and Tetraalkyl Dithlopyrofihogphate.,,;
Table 1
Card 2/4
3
Formula-
(C It 30).2 P(S) SC I 1 70 51-52- t.2-338 1.5200
(0.2)
(qIJI,0)2P(S)SCJ13 88 63-5-64 1. 1951 1.5100
JOAN)
(C311,o),I,(S)sCII, 53 68-70 L0806 1.5008
(0.11
0 94 -C3"70)2 P(S)SC I i FA) 60-60-5 L0736 1.4950
(0.07)
(C4HQ0),F,(s)sCII3 63 89-90 1.0540 1.4960
(0.08)
-C4,,q0)2P(s)sCjI, 78 75-76 I.W83 1.4930
10.07)
(CH30)2"(S)SC,11, 32 48-50 1.1641 1.4958
((Ws)
(C2IIr,0)jP(s0C.,II,,- 61 57-58 I'ttit 1.5050
(0.0,41
(C311,0y,(S)sC., it, 57 7:1.5-75 I.W23 1.4968
10.081
(too C31170)21'(S)S(-~11.5, :17 6 1 -62 1.0757 L4910
JOA4)

Concerning Organic Pesticides. LIV. A.
CD
New Method of Preparation of Trialkyl
Dithlophosphates and Tetraalkyl Dithio-
pyrophosphates
77382
SOII/79-3-0-1-43/78
with formation of trialk-yl dithlophosphates, as well
as unsymmetrical tetralkyl dithiopyrophosphates. The
latter are not described in the literature.
RROWS11%. + (11,O)SP ~ (1(0)'.PSS1V + (ROWSSPO(OR12
ASSOCIATION:
SUBMITTED:
The above products are obtained, in good yields,
C3
accompanied by a small arnounts of side products.
There are 2 tables; and 10 references, 7 Soviet, I
French, 1 Japanese, 1 U.S. The U.S. reference is:
G. R. Norman, N. M. Lesuer, T. W. Mastin, J. Am.
Chem. Soc., 74, 161 (1952).
Scientific Institute of Fertilizers and Pesticides
(Nauchrkyy institut po udobrenlyam 1 Inaektofungitsi-
dam)
January 19, 1959
Card 3/4

MELINIKOV, N.H.; OAFT, V.A.
Herbicides and Dlant regulators. Part 35: 5yntbesia of
some triphanylpheno-Valkylphosphonium salts. Zhux.ob.khim.
30 no.6:1918-1921 Je 160. (RIBA 13:6)
1. Institut fiziologii rastenly Ak--demii nauk SSSR.
(Phosphonium compounds) (Herbicides)

MOINVICH, A.G.; ZAKS, P.G.; R&MLIBAUM, Ya.A.; MILIMIKOV. M.N.
Organic insectofazigicidea. Part 55: Synthesis of some
alkylarylthiaphosphoric acid bydrazides. Zhur.ob.khizm.
30 hb.7:2317-2319 Jl 160. (MIRA 13:7)
1. Haucbny7 institut po udobreniyam i insektofungltsidam~ Koscow.
(Hydrazides) (Phosphorothioic acid)
I

MELINIKOV, U.N.; SMTSOVA-SHIIDVSYA1rA, F.D.; FAGAN, M.Ta.
Organic insectofungicides. Part 61: Interaction between bin
(dialkovthiophoerphono) disulfides and triar7l- and diar7lphos-
phitas. Zhur.ob.khim. 30 no-7:2319-2322 J1 160.
(HIU 13:7)
1. lauchnyy institut po udobreni7am t ineektofungitaidam,
Moskva.
(Phosphites) (Sulfides)

AUT110HS: S. 1).
TITLE.
I E't 10
11, A ('T:

QVI,
71
Cor 1-2 iiuii i,,; i-;.;~.p--,,a':,~-C.
Tri
Hupt-a
Lu Id w L t i, -1 Im. i "d C-d
va c
A Taj E

Concerning the Preparatlor~ o f j C.
"Heptachlor"
ASSOCIATION:
SUBMITTED:
3 L
274164o; lbld.,274it3S~;
e
us, P. W. ~-j-
E. Lidov, J. H. Kna -~verlon, d 2 7
Research Institute c." a,~J Pes je3
(Nauchnyy in~;tlt~,- P--
Jume -19~,ci
Card 3/3

5..34oo.,5.1320 '77651)
Sov/dl(j -~3 -2 -34/52
AUTHORS: Bellkova, N. A., Vol L. G., Kuznetsova, K. B.,
Mellrijjwv, N. N., Per-.-un, A. I., Plate, A. F.,
Pryanishnikova, M. A.
TITLE: Concernin,~ the Aldr-i .,-, ,Air,] Dieldvin
PERIODICAL: Znurnal prikladnoy khiiiilL, 1,-)60, Vol 33, Nv 2,
pp 454-463 (USSR)
ABSTRACT- The article de3cribeo the synthes is of aldrin
arid dieldrin based o.-, inCoririation rathered Crom
Coreiga patent literature and on the author,31 stulies
of the basic r.~actlon -Df h exaclilo rocyclopentadiene with
bIcyclo-(2,2,l)-heptadiene -2,5. The latter was
synthesized In a contin-ioa s flow installation, accord-
inC7, to the reaction:
If
if C11 if/ \11
/
+

Card 1/6 If
W
11

Co~,icernln- the Isolation -)f
Aldrin and Dieldrin
Card 2/6
molecule:
77659
SOV/80-33-2-34/52
TftecptImjm conditions l.(,r the al-o-ve condensation of
cyclopentadiene with acetylene were: molar ratio
1:1.1 to 1:2; temperatur-e 34~` C; pressure 20 atm.
The yield ol' bicycloheptadlerie inder those condItiO113
was about 48% and dropped sharply with risin:r tempera-
CD
ture . The spent gas contained 95-97% acetylene and
could be recycled. Investi~ratlon of the thermal
stability showed that bic~,(~lo-(2,'~l,l)-heptadiene-2,5
remained unchanged at 2()06 C, but under the conditions
of the reaction It reacted wltl-i one cyclopentadlene
if
+
If' I~H
1\ If/ If\
At 3400 C and above, b1cycloheptadiene was isomerized
Into cycloheptatriene; at 3(-)O0 and 8 atm the extent of
isomerization reached 201%, an-1 a small amount of

,cu rii 'Ln,:
It
If
Tne. ("oil C vuactlorl
Card 3/6

th L-~O IL
AldCifl :vL-I DIAd"Il', C. I
lit

(A

lilt lilt I I
Cl
CI,

It Cl

f'oijr) a',
w(2
it was
2
veac~ant
5
jp
0 1 1,D W., .
)(117-At Ill't' C. Tile
ilrl(- '-t C PC ;:11
CX
complete VII-th
'
'A IA LU
j '
Ill,,, opl~vat I I.
-
0 loll the rk-a'~ t Ion
i Li
cyclopenta( .
I
- n:-, (3)
d I
c
- a
p
Card 14/ pr,.)-Auct:; at

Aldrl,-, an-1 McIfAi-In
SOV/8,0-_33-2-_-34/52
corideii~;atloii oC bicjclo,iuptadlene with hexachloro-
cyclopentadiene; (4) iteam distillation of the
excess bicycloheptadlene; (5) separation of aldrin from
water; (6) separation of bJcycloheptadiene from water
and returnin,!2, it to the condensation stage (1).
The steam-distilled bic~clo:ieptadiene was 95% re-
covered anl could be u3ed ai,-ain without any further
purification. Dieldrin was obtained on oxidation
of aldrin ',,, mearis of 3-fold excess of 27% hydrogen
peroxide in 80% acetic acid at 1000 C. Dieldrin
thus obtalri,-cI .-iad mp 100-1300C. The content of
dieldr-In in te,~hnJcal prcduct was aboat 80%
If
Card 5/6

I'l I L tML 1'- (1) 1 ~ I I - 1 -1 r L',j t
Aldi-in and
77 6 5
SOVI/t(D -3 ---; -2 -34/52
Oume won'.. via.~ by G. A. Tara:,ova at
oi' Orearli- C,.11-inistri, Acadeirny of
(J')':;R. D(2 te vin j fiat Ion of combustion tempera-
w:L:; :iiale by M. P. Koz.1na arid S. M. Shte'r[her
at. 1-1te Llu-~Inin Laboratory of' Thermochemistry of
Lom.)iLo,3ov M,--)scow State U&er3lty. Cyclopentatriene
analy,;is vja,~ mad- by M. Ye. Vollpin at the Institute
of' Elemeiit-Organic Compo-ands, Academy of Sciences,
USMi. Triere ar,-~ 4 flfrures; 1 table; and 23 references,
(J U..-')., 2 U.K., I Catiadlari, I Indian, 2 Swiss, I East
G, 1-ol-L11, 7 Sovl(,I,. The ~ nio.3t recent U.S. and U.K.
i-, Cei-encez; arc: Handbook of Aldrin, Dieldrin, and
Et,J-.1.rt F.innil:OJOns, Shell C~iemical Corp. W--'54);
llin( J. A. h~ L. H. --tlko W. E. Ga~dner,
M. 111w,, J. Am. S')~---, 77, 3, Y)li (P~:~)5)
1'. E. Wd v, 1J. Pa L - Y-1-17 21 - IV - 1'-J~-)3; B.
[J.,'3. Pat. LW- V R. E. Lidov, S.
I% S(--~1f-)-.-iay, B-it- Pat .
2--) 1'

iq&i -

MELIKKOV, N.N., prof., red.; GAZIYEVA, G.B.,, red.; DZHATIYEVA, F.Kh.,
- tekbne- rede-
[Herbicides, insecticides, and fungicides; a collection of
translations from foreign periodicals] Gerbitsidy i insektofungi-
tsidy; sbornik perevodov iz inostrannoi periodicheskoi literatury.
Moskva, Izd-vo inostr.lit-ry, 1961. 290 p. (MIRA 15:7)
(Herbicides) (Insecticides) (Fungicides)

TARASOVA, G.A.; PLATE, A.F.; MELINIKOV, N.N.; VOLIFSON, L.G.; TISHCHENKO, A.I.
Condensation of polychlorocyclopentadiences with acetylene.
Neftekhimiia I no.1:65-69 Ja-F 161. 04IRA 15:2)
1. Institut organicheskoy khimii AN SSSR imeni N.D.Zelinskogo.
(Condewation products (Chemistry))

HELININOVP N.N.
Problems involved in the manufacture of chemicals for the protection
of plants and for weed control.'-Abim.prom. no.5.*29'1-299 My 161.
(MIRA 14:6)
(Plants, Protection of)
(Weed control)
I*YU
f

I MELII~Mq~j ~.N. GRAPOV9 A.F.
Reactions of aryldiazoniun salts with thio- and dithiophosphonic
acids. Zhur.VIjIO 6 no.1:119-120 161. (MIRA 14:3)
1. Nauchnyy institut po udobreniyam i insektofungitaidam.
(Diazonium compounds) (Phosphonic acid)

. MELINIKOVI N.N., prof.
Outlook afid tasks of chemistry in plant protection. Zashch.
rast. ot vred. i bol. 6 no.llx19-2l X 161.
(MIRA 16:4)
1. Nauchno-issledovatellskiy institut po udobreniyam i
insektofungisidam imeni Ta.V. Samoylova.
(Agricultural chemicals)
(Plants, Protection of)

MELINIK ILN-;- SHVETSOVA-SHILOVSKAYA, K.D.; MAKSIMOVA, Z. I.; BOCHAROVA,
_ I
_!SIN 0
L.P.; SHAPOVALOVA, G.K.
Recovery of insecticidal preparations in aryl esters of the N-alkyl
carbamic acid. Khim. no.10:15-17 0 161. MRA 15:2)
rln'~s"e- cti c ides)

-~M~ELINIK~,-ILN" VARSHAVSKIY, S.L.; SHVETSOVA-SHILOVSKAYA, K;D.; ANDRIMOVA,
L.V.; BOCHAROVA, L.P.; KOFM&N, L.P.
Phosphamide, a highly effective insectielde. Kbim. prom. no.10:
17-20 0 161. (MIRA 15:2)
(Insecticides)

14EL I NIKOV , N. 11.
Some trends In studyi%- the made of action of PhosphomiD cortaining
organic insecticides. UAm. prom, no.10:20-22 0 161. MRA 15.2)
(Insecticides)

MELINIKOV N.N.; ANDREYEVA, Ye.l.; 31-iVETSOVA-SBILOVSKAYA, K.D.; IVANOVA, S.N.;
SKA=UBOVA, A.V.
Disinfectants of seeds not containing mercury. Khim. prari. no.10:
26-28 0 161. ~ MIRA 15-2)
(Seeds--Disinfection)

MELINIKOV,JUL; ZETKIN, V.I.; LIBMAN, B.Ya.; SOKOLOVA, Ye.M.; ZAKHAROV,
Ye.V.,- PARFENOV, A.I.; TRUNOV, P.P.; GOLYSHIN, N.M.
Organic fungicides as substitutes for copper-containin parations.
Khim. prom. no.10:28-30 0 161, 141 15:2)
(Fungicides)

MELINIKOV, N.N._;_KUKALENKO, S.S.; VARSHAVSKIY, S.L.; KOFMAN, L.P.;
-~BELOT, M. D.
Prospective herbicides. Khim. prcm. no.10:39-40 0 '61 iMIRA 15:2)
(Herbicides)

MELINIKOV, N.N,; -- -VOLIFSONt-L.G.i VOLODKOVICH, S.D.
Herbicides and plant grow-th regulators. Part 36: Synthesis of
certain tairachloro-9, pentachloro-p and hexachloro-3#6-
endomethyleneteCra. hydrophthalamic acids and their'imides.
Zhur, oh, khim, 3i no, 2:499-506 F 161, (MIRA 1.4:2)
(Phthalamic acid) (Herbicides)

SHVETSOVA- SHILOVSKAYAP K.D.; KSLINIKOV N N 94DREYEVA, Ye.l.;
ECCHAROVA L.P.; SAPGZR6v
Organic insectofungicides. Part 57: Synthesis, insecticidal
and fungicidal properties of certain arsenic organic compounds.
Zhur. ob. khim. 31 no.3t845-849 Mr 161. (MIRA 1-4:3)
1. Nauchnyy institut po udobrenlyam IL insektofungitsidam imeni
Ya. V. Samoylova.
(Arsenic organic compounds)
(Insecticides)(Fungicides)

MELINIKOVV N.N.; MANDELIBAU1, Ya.A.; LOMAKINA, V.I.
Organic Insectofungicides. Part 58: bvuthesis of certain deriva-
tives of dialkoxyphosphonopropionic., butyric, and toluic acids.
Zhur. ob. khim. 31 no.3:849-852 Mr 161. (MIRA 14;3)
1. Nauchnny institut po udobreniyam i insektofungisidam imeni
Ya. V, Samoylova.
(Propionic acid) (Butyric acid)(Toluic acid)
*I-

VIADINIROVAP I.L~I; MELINIKOV, N.11.
Organic insectofungicides. part 59: Syntl,,esis of some new
oxime dirivatives. Zhur. ob. :him. 31 no.3:852454 Mr '61.
(MIRA 14:3)
1. Nauchnyy institut po udobreniYaM i insektofungitsidam
imeni Ya. V. Samoylova.
(Oximes)

MELINIKOV, N.N.; KHASKIN, B.A.; SHVETSOVA-SHILOVSKAYA, K.D.
Organic insectofungicides. Part 60: Reactions between thio- and
dithiophosphoric acids and secondary arnines. Zhur. ob. k-bim. 31
no. 1-1:3605-3610 N 161. (MIRA 14:11)
'I. Nauchnyy institut po udobreniyam i insektofungitsidam.
(Phosphorothioic acid) (Phosphorodithioic acid)
(Amines)

MANDELIBAUM, Ya,,A -!-i~MINIKOV, N.N.; BAKANOVA, Z.M.; ZW,, Me
Organic insecticiee-fungicides. Part 61: Synthesis of some
mixed ethyl mereaptoothyl thiophosphates. Zhur.ob.khim. 31
no.3.2:3947-3949 D 161., (KIRA 15:2)
1, Nauchnyy institut po udobreniyam i insektofungitsidam im.
Ta.V.Samoylova, Moskva.
(Phosphothioic acid)
(Insecticides)

-MELININDVO-it", MANMIBAUMp YaA,; La%fA=A, V,I,l Lr7S=S, V.S.
Crganio inseatiaide-l~mgialdee. Zhur.obj*ft, 32-no~221
3"3 D t6i. (kMU 1512r
1, Nauoh= institut po udobreniyam L ineektofuWtsidan
Im. Ta'TQ Smyl.m (N=)l Moskva,
(Insecticides)
Acetic acid)
Phoephorus organic compounds)
~