SCIENTIFIC ABSTRACT MICHALSKI, J. - MICHALSKI, T.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033810019-5
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• Document Page Count: 100
• Document Creation Date: January 4, 2017
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

POLAND / organic Chemistry. Synthetic Organic G-2
Chemistry.
Abe Jour: Ref Zhur-Khimiya, No 23, 1958, 77747.
Abstract: 2-C 5 H4NCII(CH3)PO(O02 H5)?, (II), mp 141-1430,
which differs from the isomeric picrate of I
(R = P(OHOC 2 H5 )2); 11 has a bp of 95-97')/0.05mm,
n25 D 1.4920. 1 (R = P(O)(OH),) and I (R--,'C5 H4-
NCTI (CH3)P(0)(0H)2) form salts with C6 H5 CH 2 NH2
having mp's of 179-180 and 1710, respectively.
-- V. Gilyarov.
Card 3/3

Distir: 4E2c(j)/4E3d,
of Sulfur and
t~
67 7 iiiiw';' -in"g-16-h')
oppaciphosplumm compc6. with a P(Q)SCI group ( I
$2, IOWA) tosym. olefins lute been studied. Dyadd,
of (RO&MACI (1) or W(ROMO)SCI (11) to C8114 MO.
MesC: Met (IV), or cycl*hexcue, tile lotlc~wuilg compods.
have been ptepd. yield, ni?, dis given): (EtO)s-
P(O) 4), Ki 't3H*/O 06 1 47WO, t.2270 (Mor-
risiou, C-A. 30, 780h); 00, -
6
07'/0.02, 1,4940, 1 11100, MOWMSCILCILCI, 77,
72'/0.005. 1.4751, 1.1057; (PrOhP(O)SCMc3Chfe.CI, 40,
80*/0,01. IAM. 1.09W at 25"; (6o-PrO P URI.-
CH,CI, 70, 1000/0.9, 1.46M, 1.4262; = Us-
Cf[sC[. 66, 92.6*/0.015, IA731, 1.1208; Et(BtO)P(O)-
SC11sCT1sCl (VI), 74. 640/0M. 1.4058, 1.1941; Et(BuO)-
P(O)SCHjCHsCI, 76, 80*10.05, 1.4885, LIM at 25';
(EtOWO)SR (R - 2-chlorucydobexyl), 62, OV/0.1,
1.4963, 1.1948; PI%CHCICHPhSP(OXEtO)s (VII), 59, m.
9"* (repeatedly from CJL). -, -. E.g.: I (R - Rt)
J20.4 g.) dild. with 30 MI. C4114, kept at 5-10% pure III
Introduced until the yellow Color disappmml, the lialn.
wm3htd with HgO, satil. NAM, aad 11,0, dried, and tlit
r-C. Cith cv~jfd., guve V. The oynthesk (if V1 wits Imforilled
at 10-20 ; that of V11 required 3 days'expcmure tq light.
-/*?
A-

A
11171=1 ddiddea to
Lenard-Bovda, Jan leis
;W" I sad. SM.
"Sol lffrg:~
~Egtkh C.A. $I
1001M I 0~- yiewen
RO a 1 1), and elky
1 90) 0 1 (U). am spiat"004*
and 4( Ju and eydobnew.
'The 0 uliftiall tion by suakht.
W.4 6. (Nto 0 30 ad, C4% with M (CM) at
19.7 UJs4.5%j IRO)SKO)SCHr
it 31) (lv)abol; ;" SVP . 785, 46 12M.
a b
% ): 77F.L~NZ
0. 4W 11462 86; 84, 05.2*/0.01. 1.4731,
dG. TbU&wQwerscwvrqd.: Rt(zto)p(o).
%a 64'/000# IAM. 1.1041, 74; (StONX
ila~- '67/0.02, 1AW 1111084 60, Rt.
%Ck. " _ I d
SP/0-06, a9 AU. . 6W.
0)8C 000. 064/0-01, OV 1AM, do
~MON O)SQRtA3-0. 914.1. 1.49M. du
:194. ds; ( to O)BCHpbcl. Yidd N
Thit - '" of w" ved0d bi Inthftle by Mwdwu
(C W. W, md by ankadve cbWrl"tlw ac-
$* (cA, A, IdUft), The amp_&. In.
0k *Wvfty sad do not posew my Witter.
PMPWY. C&e*wbTljdlwks.,. w
7-
Z e,
\Aj

CHI L
how
'qwl t"
Z,7
ti
NP
ur
I wile
mi,
IT,
IWO. -I.Tu WN

Z
L
i~'~ ;V
:J
;7
_Xi Ii
W.,
r
dptkall kW" n
T.Mf-
ed by, preO-,,4
'Ewf' nibstituflied P
U ied p
+ for u
ItMty w I
Of this optfciLU)r alive L4omczg Of F-C
ELmnejwfemyt chlome
P e
nidve& by,owne. to tfm
nothfotc;acId.vm
dW.T. mA tL
b,, ggi% *I.- 1~6 "S."
catw a;
the Wean
chforlde PTe a alive form
piecluded ddu.'~ d ~Qx activity.-
which
ANY
and p
e Cut the m-
.. ...........

compoundE r
Pnc
(-)r-, fun ro,,~rr r 7,~iosptx-r.s 1r.
y1 !-r-] encn~ -r. r
3- riaD:-
4
th I-,- Li~ of z-ast ~.i. ~5s :.F

Itemcdom a W ' -AC disulue: with 4

.-phompkit" age Goamn 4"Oval sew
"f
I
7
s4
k
O
O
T
0
0
-
r
Am.
I
,
.
'
" p
"l
-&k
tois and OS
,
Y
]an mic1halski
Ian W k
I a
.
Oct I
and Boic R.&J
.
Ckm-.-3J-,MrM nnglishy.-The reactions bL-
t;~~n acyl disulfides (1) s.
M. dialkyl phosrhitZ% dialkyl
r V
hl
i
N
i
V
r
a der
t
tes (111). or the
va. (
) an resp.,
hio~L"p
.--- %-.V., - vAd mV given for the -m0
t
below). 11 react spoataneously only with I to give (RO
118020AOR)l (K - 8t), 78-1101/0.03. 1.4453, and
00~ ~R - Fj), 624*M.03, 1.46". In 70% yle6d.
read with In Cgff4 at 20' its veil as with diaryl or dialkyl
d1suMdes 01), RISSRI. to yidd RONP(O)U' (R - Et,
A
- El. R' - Ph), 115-
R' - fim: 13"0/13. JAMI (
I
*
i
on takes
and R
SMI. An axasogo" react
W/0.6 1.$M
pism i;twm if mw W givin 447p 0.0-diethyl S-butyl
i
i
I
h
h
h
I
gA
C MtC
M N
d
t
ate, AN
M
bowsp
IV
W f
hi
1
Th
l
b
d
gto
an
or t
m.
e rtact
on
ounmA
s md
Wi
ilk
l
i
I
l
A
d
C
d
d
ie
s
to sma
eat
at
on
ue to
W%l
ng
wy
y
---.A.,-M -- --" -8
hich
R%F
-
, w
pvc
(0 0 W-'SR.--W an ameterhed so
oaks: R Et, RI - 9m, sm. 12340&
Whe" -y-Wds -o-1- V"Z-lwwv
A. K

JfV
empmob d odr,
for
(20
d. C
RP fkar ON
ddorMes. (K
A given dWk (2 'cj
With I Inde rMstu-015 to 00. The pm
Ims bolatool) is chlorinated with .1 mob a
the ommis temp. After C"Wvd of on so
m M Po by oww. in socso at taq
dign. is now. I (R Et). b�4 61-3',
obtsiod.

GODLEWSKA-ZWIERZAK, Krystynak MICHALSKI, JAV; STUDNIARSKI, Kazimierz
Alkyl and alkenyl pyridines. V. Some now aerivativea of barbituric
acid with py-ridylethyl side chain. Rocz chenii 33 no.4/5:lZl5--lZI7
#59. (ESAI 9:9)
1. Katedra Chemil Organicznej Politechniki, Lodz.
(Pyridine) (Barbituric acid) (Urea) (Alkenyl groups)
(Alkyl groups) (Sodium ethoxide)
(Pyridylethylmalonate)

MICHALSKI, Jan; MARKOWSKA. Anna; STRZELECKA, Helena
Reaction of dial k oxyoxoph osph orane sul fenyl chlorides iwbt axtines.
Rocz chemil 33 no.4/5:1251-1253 '59. (ERAI 9:9)
1. Katedra Chemii Organicznej Politechniki, Lodz.
(Amines) (Alkoxy groups) (Phosphorane)
(Sulfenyl chlorides)

MICHALSKI,-Jan; BORECKA, Barbara; KAPECKA, Teresa; STRZELECKA, Helena
Reaction of dialkoxyoxophosphoranesulfenyl chlorides with organic
thiols. Rocz chemil 33 no.4/5:1255-1257 '59. (RAI 9:9)
1. Katedra Chemii Organicznej Politechniki, Lodz I Zaklad Syntezy
Organicznej Polskiej Akademii Nauk, Lodz.
(Alkoxy groups) (Thiols) (Phosphorane)
(Sulfenyl chlorides)

-ONCIII.NLt, mid NaCN (5 [111-)
froin 11, p
lid tile a. id ruin ~ oil a
Thenyllutinoi- was poured over Ul a
W-k steassi b4th. Vie sfAn. k)it its r7- jmv::npd.;J.4,5-
7.. trillietholyphenylglyoxylic "id sclxl uut simultaneously
I" ui~4~k Nat
IMIKM~).=4 tltiffibR-61 as lotl colorlm acedles. at. 160-1* (IIjO), yield 5M mg.
)-P - ozo - (3.4.5 - trimcdioxy-' -(76 .5 " !I; 2,4-dini'ruplien thydrozene, ortulge CHOW
Xepd. via the method of needles, in. 207.51 (RtOll~, 2-hydroxy-3-(3,4,&trrr11eth-
4Sj 2746g), followed by h rolysiji to the oityphenyl)quinexallne, yellow needles. in. 239" (aq.
yl)alkane cargxylic acws. HtOll). Similarly, from 1-diazo-3-(3,4,5-trimetbtjxyphen-
I CtIlarlde, pre 3,,1,& ft2,prupunone, via 1-chloro443,4,&tritnetlioxypl)cnyl)-
pd. from 50 g
In the WKW mal"na, was added -proponone (white needles, in. 7fl.&-7.0*), was obtained
0011cl, (it CtIsNj which had been cooled to a-(pp-dijawthytaininopheiiyliiiiii3o~0-oxo - -y - (3,4,5 - trimeth-
)henyl)bu1ytonflrIIe (IV), violet needles, in. 223.15-
Aftir a while 27 g K 3.4,"Itizetboxy-w-
olyj
900111111:ip. out. in ;a; "ted and con- 4.15 . Acid hydrolysis of IV with dil. IICI In hfe*CO pvt
the W rewrappment to 3,4,5-trImetboxy-' -043,4,&trimcthoxyplienylyo-oxopropionic acid, colortt"
#WetawAft., romakling W ev"A. to dryn needles, in. 167-11". P43,4,&-Triinetboxyphenyl)propion-
volue" amide, obtained from 1.411a~3,4,6-tsluietlmypfmnyt)-Z-
In 940, MI sd&d till N r =
wft 1W, dtW am OiCle, anid reduted In ropanone (I I X.) via the Wolff rearrangement, in 100 mi.
YA,1 g. M011 boiled 0 hrs, with 10 - "OH In 60 tul. HoO, muted,
a WOR as white ntedles, AcId&4 with dil. 14S0., the ,ptd. NaccB04 sopd., the vol.
decreased, ncutralliced with KOH. and cuefully rvacidilled.
ml.) Powmi Over 15 g. 1. use
MV my I
time W 010 , and muted gave 10.7 g. yiekled cryst. P-(3,4.5-trimaboxyllbetcyl 1101110 &Lid M
-YIPGAdinitun chloride colorlen needles, tn. 104' (IljO). Werd"ded V (5.4 g.~
Wdsinyphictatu
&M CFO", in. , &-3.0' (HtOH- dlitiolved In 100 ml. CHt, to which had been added a MI.
It.) Its 711 mi. RtOH and 4.6 g. SOC6 acid several drops dry CGHsN. kept 40 bra. at 15'.
to were added rapid) heated 3 hre. at 65% diazatized to the diawketone, and then
tq 15 g. U 100ml-EtOIJ. T(Ic treated with JICI till the N evolution O"sed ielded I-
in
bioccd4ed nwmentarily. tien the chIvro4-(3 4 5-trimetb"phenyl)-2-butanone (11), color_
limino)-ji-010 less crystZ: in. 74-4.5 . The coff esponding pyridinium
HU116.1 1,,., 891~ chlorlile was prrpd, In tht desatibed matcaer from Vt which,
V" idded a 10 n., It (Hure by treatment with p-0*4Cslf#NMej mind N%CN, pv* &4#-
A - Re- ditnethytaminoplienylbulnoYO - oxo - A - (3,4,6 - titmethou
&ben dil. EtOH, and drk
x"! (3:2) yk4ded garnet red, 1110110. henyl)valeranitrile (VII), otange needles m. INTP
MIX. metallic she'en), in. 184-50. P-Ho-EtOH). yield 91%. VII (6M wil.) heated 10 adn.
yIjmIjja)-O-u"-(3,4.b- on a steam bath with 160 mt. ci-CJUN110,; In 20 ad. AcOH
_ophe~ and a few drups HISO., cooled, 11jO added, pptd. 2-12-
Monoclinic PrNtus (Vic?-
A_", ljt-1.51. yitld 85%. vitils prepd (3.4.6-trimettioxypitenyl)t!thyljquinoxWint - 3 - carboultrile,
tn. 165-71. Stefan

M IC P A LS RYj T
,4kaia"dwy-2.6-dlbr,, pVhW)hbutA
W-M. 81m--ri (Unly. Brnu, Czech.)
MO IM); cl. V.711. 3 ",8W.-Cteav, ge
=tkoiypWttyI)v&1sroa" 1) with dil. IICI leads to a-
O"Wria,4414rianatitoupbeny0butyric acid (11), and not,
orte loc. cit.), to 3-hydroxy-4,5,0-tri-
4 acid. As prod, a-oxo-1-014111-
Nis Ny-2A4%roWopbftyI)bu%yfk acid (1111) was ptepti.
bY aW chavap Imm a4p-dlmethylawinoilbenyllmlno)~-
NUse mW twMWve decadmitylatloa with HA led to
triewelboxy-04ibromoplainyl*oPkak acid (V) with
OW01011111001011COm- is 111630JORmanner, lied tollwhich. la
1"fal HA Oda., split of COs almost quant. to yield 0-
(314 me ). E.g., Br
3 Was slowly to a sola, of
AS. i t 2 hn. st room tcmp., the excess Rr removed
a , UK milt. dild. with 2W tril. HaO, and the pptd.
Cust. V recrystd. from EtOlf, at. 119-2900, yield 3.3 9.
Dry Cjfo (3D ini.) und 2.5 ini - SMI, were added to 2.3 g. V,
dlsksolvM and heated 3 hri. at 70% the oily acid chloride dis-
Solved In 1011111. CH, and added slowly. with cotat. stirring,
to an KtjO soln. of CIfjN3 cooled to - 15*, the whole allowed
to stand 20 hrs. at - W, filtered, HC1 (gm) added till N
evolutioaceased. and kept (for u while. After washing with
HsoI asid drying over C-AC12, the I)t.xluet was teduced in
Va. t1j yield, after rLer;5111. front Nicoll, I-cliloru-4-(3, I,&
(Vill. "I.it'
needles, M. 107-80. (2j) -as diswireii to 10 ma. dry
and Rt&O added to Pitt.
C411&N, btated 30 min 5
the pyrWittlans chloride as an was sepd. mad poured,
with vigorous stirring. luto *W.U, "NCjf4W*l (750
I ml. WOH) and N&CN (5'W mg. (a I mi. M) at
4MOS. toolforat a deep red mist. which ykided 1.7 IV
m. 170~20 (CoUrStOll). IV (400 mg.) was b;
30 min, to 40' with a mixt. tif 10 mt. Met 0 and
heatin
15% HCL MesCO was evapd., the oily a-kettive
extd. 3 times with 20 ad. HtO, washed with HA the RttO
avapd. in vuwe, the oily reminder taken up in MesCO, If,O
a a few drop# till. HC1 added, and left to stand several
days III Ptd. PA shiny tnothar4if-purl colured k-aveil
t= = over PA m. 83"W; 2,4-dinitto-
pitcay1hydravioe. yellow nettiles. tn. IW7*- and 2-hy.
dfo!,v-3-(P-(3,4,5-trimethoxy-2.6-dibmniopIkenri)ethyllquin-
oxallite, needles, m, 224-5'. M (42.6 mg. dissolved In
I mi. O.IN KaOff. the soln. brought to pH 7. treated with
0.3 ml. 3% HA, released In 15 min. an shoost. qusut. amt.
of CO: Oneasttred voluinetrically in a su microburette),
acidified and V. m. 120-l", recrystd. from EtOH. AmIxt.
all V and 0-(3.4.5-trimethoxy-2A-dibromopben rt*lwic
acid showed no mixed in. p. depression. 59)KIrly, It,
prisms, m. 130-7*, yield 80c,10, was obtained by acid cleava
(if 1; its 2,4-dinitfophenyl jyjjWUlMjdeep red needles, in
211-13*. It was decarboxylated with HtOz as above to yit
!
VI in. 101-2*, identical in ni.p. and fnixed m.p. with P
(3,4,ri~triiuethozyptienyl)prapi,)nic acid. Stefan Berg~j
W

Diatr: WO/Wc(j)
ethen at emn of Soddoroakaboh. (WO)SKOAct (r b
treated with Cffs:CHORt in CJ4 1=6Ltta yield (Rt~)r
P?)9CHjCRtjOH&I (95 ) h Wattr gives
t( C 0 bim 82'. *if 1,4708
210 OACHI
=41=11. 1. 160.). Mtmeat of 11 with excess
HIM gives (RtOhP(O)SCHtCH(OKt)j (IV) (75%). bs4v
90', sif JAMI. degraded by alkall to memptoacttaide-
hyde diethyl acetal, bn 72-3*. wit 1.4409 (m.p. and mixed
m.p. of 2,4-dinltrophenyt thioether W*) (Parham, ti W.,
C.A 48. Offid - Hem and jorder, CA - 47. 9975h). Acid
hydroiyolootRyields][111(60%). CondensationofNatutt-
captoacetal with diethyl phoophorochlorldate also yields IV
(60%), boa 81-2% ait 1.4WO. Reaction of I with Ctfj:.
CHOAc gives unstable (EtOhP(O)SCHjC1I(O.%.c)Cl (V) In
rit. yield, which 12 converted at 100* to 111 (05%). bq.%
r
. "U 1.4093. with somcAcCI as volatile product. Treat-
Ment of V with I mole water gives III (FA%). I with Iso-
Orgl'Ucetate Ives (RtO)tP(O)SCII'COhIe (VI) (60%).
CO
mit LIM (p6--'traphenyIhydraznne m. 02-3*),
and AcCl. Direct comle=tiou of I with ?,feCO al,.w
yields VI (50%). C.A~~
Y"C
5
Card 1/1 aht
P, ~

-21CIP59Y,-97 CA S3, 21876t.-The title compils. were
mkrmngvd by in MeOH to the corresponding a,$-
unsaid. Me which added
C11ith's to give 2 asolli"vi. lit 41-phthalinvidocrotonate
(1) 100 wit.). dil. 00i. and 5 ml. AcOlf were heated I hr.
at 100"; OW SWO. was tben coned. to amall vol. in vacuo to
100% 4
'I %thallmWocrotinvic acid (11). m. .194-6*
A H). I ( mg.) was added to an excess of CHIN, in
f
EttOvand the mixt. kept 20 hrs. to give 385 mg. Me 4-phthal-
-inikimuthyl2-p)=oUnt-B-carbosybtt (111), in. 164-6*
(with evolution of N) (MeOH). 1 (8 it.), 50 ml. 37% &q.
HCl. awl 50 ad. AcOH were heated 2 firs. at 100; the
mixt. w" the" evapd. to drynew and the residue recrystd.
Ifran HrO tat Five crack 11 which wa-% then added during 10
m1P.toCHjNvviaRW. After 30 min. the soln. was filterw
and then bept 24 his. to give a ppt. of 3 S. 111; Concri. of the
EtIO motber liquors gave 3.9 S. hie 3-chloro-4-phtfudimido.
butyrate (IV). M* OW (MeOH). IV (500 mg.) was
hydrolywit with. 1: 137% HCl-AcOH for 1 .5 hr*.; tvapn.of
the mixt. to dryam and r=ryan. of the residue from Hso
gave 3-clitloie-4-911ithalimidobutyric &cW, m. 100-70% which
with CHINs asi before gave IV.
IV (200 mg.) in 50 mi.
MeOH 'Was beated.6 hes, at 100* with excess freshly pptd.
AezO- 'the 3Wxt* was tben decolorized with C. filtered,
~M. to 2 ad., =W cooled to give 1. 2-Bromo-4-plithati.
midobutyric " (4.5 C.) and 50 ad. SOCII were refluxed 2
hrs.; the excess SOCI& was then removed in vocuo and the
reSidue'was taken up in Cottvv, added dropwise to CH,NS In
960 at IV; wid*the,mixt. kept 12 - 10* to give
hrs* at
2.15 idudinaldopentan-2-one (V). yet-
.ra
A0111vi" H).~ Aq. H& (40%) was; added
ad. AcOH until the evolution of N
.1'. . :.. ":! . ' '. ;
- Ctased; alter 311 tinti, the mixt - "s dild. with [Oil . Hd_'~
to give 00 nig. 1,3-diLwin"-phtlialimido ntan-2-one, in.
W-7* 200njg,V with 37%~%q.l Clsinjilarly live
180 ing. I -citioro-3-bromo-&piitfuttimidopeiitait-2-~mte.
needlei. ITI. 03.3* (NleOH). Freshly liptd. AgtO (from 8 C.
AgNOi) suspended in NleOH was a4ded to 8 g. V in 150 nil.
freshly distd. MeOH; after the initial violent reaction
ceased Lite inist. was refluxed 10 hrs., decolorized with C,
filtered. coned. and cooled t.) give 4.8 S. Me 5-plithalinvido-
pent-2-enoate (VI), in. 03-4' (MeOll). V1 f 100 Ing.) in 10
mi. RtOll was reduced with Ff over 50 Inc. 51,'l Pd-112SOt itt
room temp. and I atni.; the inixt. was then filtered avid
evapd. tot dryness and the residue recrystd. from a little
hievii to give Me 5-phthalinvidovalerate (VU). in. 42-3'.
-AgO (from 4 g. AgNO.) was added to 10 g, 1-dikzo-5-
hthalimidopentan-2-one in 150 ml. MeOH and the mist.
n
geated 5 hrs. at 80* and then worked up as before to give 9 g.
V11. V1 Mllg.) and 1:1 37%aq. IiCl were )tested I hr. at
100';~ the mixt. was then evapd. to dry new and the residue
recrystd. from HtO to give 2.5 g. 5-plithatimidopent-2-enctic
acid (VM), in. 202-3' (in a sealed tube). VIU (200 mg.)
and exem CffsVt in EtIO were kept 12 hrs. at room temp.;
the mixt. was then filtered and coned. to give 190 mg. Me
-442- hth&Hwidoethyl~~pynamihK-&"rboxylate, in. Its-
21- ~vsith v.ltion of N) (MeOH). IMe following homo-
logs of these compits. were similarly prep-d. (compd.. %
yieJd. m.p., rwrystn. medium given): IiAllazo-3-bromo4l,-
chthalimidolvexan-2-one. 82-4. 10&4*, MeOH; l"i
romo-O-phthalimidolvexan-2-one. 03.4. 99-102*. MeOH.
1-chInto4-bromo-6-phthalimidoheian-2-one, 69-3. 111-12*.
MeOH, Me "lIthaUmido-2-heitenovite, 55.1. 85-81.
McOH; Me 6-phthalimidovalerate. -, 45-8'. MeOH; 6-
phthalhuldo-2-hexenoic acid, 88, 153-15% HsO.

Distro 413444240
W siolm.
1. Actift of q2%L-f7d "Utir and owe
n U76
Mies self's -
1011"A"Oemed"
"d 1:411trawkyl th"Fr 192. 1.
CIO
ruw'ec and J. Micheletti (Imit. f.-K 1. Lods, Pola
an ze -
119W, W-0; cl. ,A 3U. 1 &a; a-0. low
ith
Dialkyl phosphochlo"te (0-1 11101e) w 0.1 molt tertiary
amine in 75 mi. was treated 3 fire. with II&S at 5", th,: nuxt
filtered, and the filtrate distal. to yidd dialkyl H thiophob-
hite (alkyl groups, % yield. b.p./mm., ar-4 all given)!
ki-(I), 83, 7&4'114, (13). 07, 100-/13, J.4620;
end Bu. 76, 81-3*/3. IAM; SOXIs (4.6 g.) in 10 mi.
,Cjf&addeddropwisetoO.0g.Uin3OmI .C4H4 at 3' and the
wilt. Sticm I hr.'pve 59 S. (PrOhPSCI, 1h4 113-14'. sig
IAU. HaS bubbled throuth 16.1 S. (PhO~PCI wA 5.6 g-
Cjf6N In 90 ad. Wis 2.5 fire., the adit. filtered, and distd.
at 700/0.001 am. gave 11.5 9. (PhOI&PUS. (1111). atif
1.5878. do I J1191. - Wh (82 s.) In 10 mi. CsHg added to
13.5 S. crude III be 50 ad. C4H~ at 0" aind the -adiat. stirred I
hr. gave 6.1 S. , Lrbowlsa, an. W. HaS pused slowly
Into 20.1 C. coy x%Aaaraclilo"ta and 12.5 A. pyri-
dine in 120 ad. C4M 2.8 lars. at 5'. the mist. filtered, and
distd. tA 6645*/O.T mut. pve 12 g. ethylene H th&Vbo&-
pitite, *V 1401. do IAM- 8111"'-dy was obtained trik
suethAme It Udopboophite, ban W. ta. 34". 4-BrC41le
AW CHAN tI&O a ) &W 17.9 x. PbNRU In 76 ad QHs added
tobhg. Khin25mI-CJI&at6*, the inixt.stirred t8iniia. 1~-dltf
then said. wit h HtS 5 firs. at 5" gave 9,0 g. (4. BrCj I Cl 1,0
Mi. an. 84*. Si-if- If, w" ob"iftell Wle (4-40'2N 14-
C11,O)gPSCI, in. 135". xS(2500nal.)bubblat into 3 ff.
(IRO)a PCI (IV) and 20.2 C. Eta N in 80 m1lC11f. 1.4 firs at
106 1 7.5 g. [(K(OWW1 ~(. tks 64 -5*.
5 tave g and
IV 16.2 g.) in 20 ml. CaflsAdded dropwiGe to 16.0 1. 1 and
I 1 .0 g. RuN in 80 mi- CJ114 at 20' and the mist. stirred 45
min. gave 19-611. V. V(10g.) with 2drops EtIN In 40 sul.
CJis imtd. I hr. with H.S at to* gave 8.0 g 1. 1110 (0.8
g.) in 100 ml. EttO added to 13.4 S. V and Stirred Is RAD.
gave-9-0 S. Mist. of I and (RtOWOH. Eky 0 bubbled
through 13.5 1. V in 15 nal. Cath 2.6 hr. at 70--80* gave 4-5
1. I(SIOWhO. ba.,.WO .. xV 1.4498. ZIV. Reactlast al
oak dbeloWdaftith hidW phowbites. J. Michalski
M
LUG ). Wacaurfowsk . Nil. SM-O.--(EtO;&P (1), (24.9
9.) &d3RrfflWW----TB-64.8 g. ble(dietboityphoWhinyl) di-
LCUNIG at W-5- and the 014"Et. distal. save 33 3 g. O,O.Se-
tricthyl,pbovbocosdeac"te. ba-as 39-41'. b% 130-10.
1.4768. -mad 42.2 S. tetraethyl seleitawyruphosphate, ba.
97-41",MV1.46M. Pb~Sft (30 g-) and 30 g-lbestedslowly,
then 190-210* 15 Oda. and distil. gave 22 g. KlScPh,
bo 8" . and 47.4 c. 0,0-diethyl So-Pb te,
b" 100". %1W I AM. 1. A. Giles-
All

.Di.tr,
U210(0/4334
olm @i the anotmpl. b"
MKOM-SM)ir goal.) GO" I
-(V)Jnso )IF
lKlost, boo a o
IWO. to
WM
lam C'm at W
cmmu.
RPLJ
MA 2 hn- th 16.4 S. S-ObYi 90dium thlow"m"
in 70 US. pvs 00 gewtim* sa&dr. I
c4m
omcdm (Eto)lPON&
2 bm at 110-20 Pve so 24 6 ' IX im 100 ud
O)SP
5 100 al ZWH odded to - fl-
at g.

BOULSKI, R.; MICHALSKI, .7.
Studies on the synthesis of divinylpyridines. Reaction between mys, -
colUdine and formaldehyde. Bul chin PAN 8 no-5-217-218 160.
(EW 10--9/10)
1. Dispartivent of Organic Chenistry, Technical UniverBity, Loft and
Department of Organic Synthesis, Lodz, Polish Academy of Sciences.
Presented by 0. Acbmatowics.
(Dirinyl pyridine) (Collidine) (Formaldehyde)

CCRAT,$jU,--J.VWWACZrNSKT, X.; ZAJACY H.
Imactlon between XpX! dioxide of 1,341-(21-pyridyl)-propane and
acetic ankwdride. %I chin PM 8 no.6:285-289 '60.
(zW 10--9/10)
1. Empartment, or organic chemistry, Institute of Teabnology, leds.
(Nitrogen oxides) (Pyridinym compounds)
(Propane) (AnWdridos)

NICHUSKI, Jan; SKOWRONSKA, Aleksandra
Orgempbospherus compounds of walfar and selenium. XVI. Dialkyl- and
alkylarylthiopys howphinates RRIP(3)CIP(O)RRI. Action of hydrogen
sulfide on dialbyl- and allWIArylphosphinic chlorides. Boas chemil 34
ao.5:1381-1385 160. (Ew 10:9)
1. Institute of Organic Synthesis, Polish Academy of Science, Lodz,
and Department of Organic Chemistry, Institute of Technology, Lods.
Sulfur) (Selenium) (Hydrogen sulfide)
hosphorus chlorides) (Organic compounds)
4
(Allcyl ups) (Aryl grouTs) (Phosphoms)
rplyrophospheric acid

FIZER, Bernardp MICHAMKI, Jan
Organophosphorous compounds with active methylene group. 1.11. Addi-
tion of pliosphinylacetic eaters and their &nalogs tovr-, 19 -Amsatt ted
ethylenic derivatives. Rocz chexii 34 no.5-1461-1464 160.
(ZEAI lOi9)
lo Department of Organic Chemistry, Institute of Technology, Lodz.
(Motbylene group) (Fhosphorua) (Eaters)
(Ethylem)

B170102
AUTHORS: Mic~.aluki, Jan, Zwierzak, Andrzej
TITLE- PreDaration of tetraalkyl pyrophosphates
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 2, 1963, 405, abstract
2N,15 (Polish patent 45271, Oct. 16, 1961)
TEXT: Tetraalkyl pyrophosphates represented by the formula R P 0 ki),
4 2 7
where R. alkyl, are prepared by a reaction of dialkyl phosphite3 R~~'Ho
(H) with NOC1 in the presence of HCl-fixing substances, such as
pyridine (III) or without them. A solution of 1-1.5 mole of NJC1 in
C6If6is added drop by drop at 20-350C to a solution of 1 mole of 11 and
1 mole of III in liproin or in C 61161 vigorously stirred and periodically
water-coolef. The hydrochlorile of TII is filterel out an] the solvent is
then eliminated by vacuum listilIntion. Very pure I is thus prepared with
a yield of 80-90~, in respect to 11. 1 may be produced by t~,e --j~tion of
NOC1 on IT %ithout the use of amine to fix HC11 but in tht cage the
Card 112

PreParation of tetraalkyl . . . P 17 1,'E 152
yield and the quality of I leteriorate. A 0.275 mole soDition of NOCl
in 100 ml of C H( at 25-')OOC in poure(] luring 30 min into a solution of
6 )
(71-25 mole of IT "R= C 211 5) and of -3.25 mole of III in 150 ml of I iproin.
Tho hydrochloridf~ of III is sepijrated, the solvents eliminated by vacuum
dintillation anI 30.2 g of I (R. C If ) fire obtained. Th in compound 1000
5 25
has a boiling point at 88-ngor.1 0.01 mm and n D= 1 4179. In another
" a t a temper;iture
cage, a solution of 0.1 mole of 110CI in 50ml of CrI.. 6
,~ ,o. is poure I luring 20 min into a stirred solution of 0. 1 mole of
unrefined IT (R- C6H 5CH,, ) and of 0. 1 m-)Ie of III in 1 D6 ml o f f"6H6* The
hydrochloride of III is filtered outt C H 18 eliminatel in vacuo. The
#1 6 6
re3idue is wasi-el with 50 ml of Aater and 50 ml of a dilute a,-)Iution of
NH3 until pH-6. After several minuten the oil crystallizes. The proluct
is filtered out, recrystallizel and I '(R= C H CH melting point
L 6 5 2~'
60-61.5'C)-] io obtained with a yield of 75%. (from benzene-cyclohexane)
~Abstracterls note: Complete translation.1
Card 212

MICHALSKI# J.; WOJACZYNSKI, K.; ZAJAC, 11.
On the mechanism of formation of 3-(21-pyridyl)-pyrrocoline from some
1,3-di-(21-pyridyl)-propene derivatives. Bul chlr.-, PAN 9 no.6:4Dl-404
161.
1. Department of Organic Chemistry, Technical University, Lodz. Pre-
sented by 0. Achmatowict.

---XWZAWK1, J-; PLISZKA, B.
Reactions of dialkoxvoxophosphoranesulphenyl chlorides (R0) P(O)SG2
with tetraalkyl enters of phospho;vus phosphoric anhydride 2
(RIO) P-O-P(O) (OR") . Synthesis of isomeric tetraalkyl thio-
pyro~Roephates. Bul Aim. PAN '10 no.6.267-269 162.
1. Institute of Organic Synthesis, Polish Academy.ofiSciences,
Warsaw, and Department of Organic Chemistry, Technical University,
Lodz. Presented by 0. Achmatowicz.

B166 B136
.AUTHORS: Borecka, Barbara, Kapecka, Teresa, Michalski, Jan
'r!TLE,. Organophosphorue lerivativea of sulfur and selenium.
Part XIX. Addition of liethyl-S-chlorothiophosphates
(RO)2p(O)SCI to unsymmetrical ethylenio hydrocarbons
PERIODICAL: Referativnyj zhurnal. Kl,imiya, no. 2, 1963, 256-237,
abstract 2Zh226 (Roczn. chem., v ' 36, no. 1, 1962, 87-95
[Eng.; summaries in Pol. and Russ.]
TEXT: When (ROY(O)SC' (I) are added to CH2'CR'R" accor3ing to
Markovnikov's law I
(R0)2P(0)SCH2'-(~^")R"R" (II) are formed. By chorinating
II in the presence of water Cl (III) were produced and these
~ 2
viere converted Into HIRIICH-CIIS-)2C1 ( !V). In the standard test a stream
of 3ry propylene is passed into a solution of 0.1 mole I Ot. C 2If5) in
30 M! C 6H., stirring and coolinp rell (;,-.-500C) until the yellow tint of
I disappears; the solvent 13 3. 1' led off under vacuum and II is
Card 1/5
15380
S1081 63/000/002/027/0138

S/081 '63/U-V-U-/'V-"-j2/027/08a
Organophosphorus derivatives of B 1 66/B 138
separated by distillation. The following data are given for 11, R, R',
R", yield ~-' b.p. in 0C/mm, nD (ternp. in OC): CH31 H, CHP 84, 0/0.01,
1-4840 (20)i C H El, rH (11a), N, 60/0.02, 1.4816 (20); n-C H9. H, CE36
2 51 3 4
56, 90/0-01, 1-4712 (20); CH 3 P CHAV CH39 95.5, 67/0-05, 1.4816 (25)1
C2F59 CH 39 CH 31 73, 73/0-05, 1.4755 (25); n-r,4H9. CH 31 CE31 73.2,
103/0-01, 1.4699 (25); CH 39 H, C 6H51 82, 95/0.62, 1.5459'(25); C2 B51 H,
C if 85, 105/0-01, 1.5292 (20). CI is bubbled into a suspension of 56 g
6 51 2
IIa in 0.2 1 water, stirring thoroughly and cooling (300C) until satura-
tion is reached, excess chlorine is blown off with air and III (R' - H,
9JR" - CH 3) (IIIa) are extracted %ith C 6H6 (4 X 50 MI), yield 80%,
b.p. -9C)-91r'(,'/15 mm, n23 D 1.4859. 0.15 mo lea C 6H5ITH2are added to a
solution of 0.05 moles IIIa in 50 m! C06, after 5 hre (- 200C) the
sediment in separated, the solvent is removed under vacuum, the residue is
dissolved in 100 ml 2 IT NaOH, extracted with ether and CH 3 CH-CHSO2NUO6 H5
Card 2/3

Organophosphorus derivatives of ...
is separated out by aa~jlfytng an aqueous solution with a 10% NCI soluttuN
yield 86-A 2-0. 24-95 0. The following lore produotj in th same says
R" a CH5)t yield 50%, b.p. 94-95~C/25 mm, n D i-48L,
(CH C-CH30"KHC'eu yield 6T%, m.p. 70-VoCs and III (R! - IG' R*
3)2 r_ U 5' 21
(TIIb)j yield 74%, b.p. 64-85'C/0-1 m, a D 1.5655. A solution- of
0.1 Molve CH is added a drop ot a tim, stirring
3 (V9 2' ' in 50 R1 C6H6
and o0oling (15 - 2000), to a solution of 0.1 moles 111b In 150 al 0061
the yield of V (R' - 9, R" - G 6H5) (rva) to 05~. CO 5CR. CHRO203005 *as
produced at a yield of 93% from 0.05 moles IV4 and 0*1 moles 005% to
06 R6(, 2000t I hr). Por part xmi see RMthim, 1962, 24Zh471.
~jkbstractor'ls notet Complete translation
6rd 3/3'

S/Ot~ 6 '/C /042/06 1
13144xl~(~
AUTHORS: Michalaki, Jan, Zwi,~rzak, Andryej
TITLE: Anhydrides of organophosphorus acids. Part 111. Reaction
of 0-alkyl phosphorous and 0,0-diethjl phosphoric
anhydrides with alcoliulo. A new way of obtaining mixed
dialkyl phosphites
PERIODICAL: Referativnyy zhurnal. Khiaiiya, no. I , 1 '163, 256, abstract
1Zh235 (hoczn. chem., v. 36, no. 1t lj62, )7-102 ~Dig .
summaries in Pol. and Russ. -1 )
T EXT : A method has been developed for synthusizing RC(R'O)PHO (I) by
alcoholysis of non-purified (C H 0) 11(U)01-'(G)(H)UR (11) obtained from
2 2
(C2 H50)2POCl (III) and Rul (0)(H)Oa ('V)' llydrolys'~'3 of ("0)2 PHO by the
equimolar quantity of NaOff if' 5uy.', alcoh-1 yields 17 (R, yield in ~- and
b.p. in OC are given): C2If 59 95, ld2-1e)3, C3IfV r)8, 191-1)3, iso-C 5 Ef 71
97, 126-1301 C4 1199 J3, 175-177. 0.25 inole of III is added dropwise in
Card 1/3

5/bo 1 14, 3 /C,,-,c /~-, 1 /C,?, 2/()6 1
Anhydrides of organophosphorue ... B1 44/B1 86'
the course c,f 15 min to O.Z) mole t,,round IV in 100 :n1 C6H6at 40-500c;
after 30 min (40-50 0C) 0.25 mole of WiR is eradually aJded to cool the
mixture to 200C, the mixture is stirred for 1 hr at 4C-50 OC and cooled,
then 0.25 mole NaOH it, 75 ml water is added drop-Nisu, and I is extracted
with benzene (R. R', yield in 0,16, b.p. ill OC/mm and n21C are given):
D
C H C If (Ia), 57, 1C~2-1(j2.1)/19, 1.41;,3; C Hr, iso-C H51, 40-41/1'
2 5 p 4 9 2 3 7
fl, CHP 51 135-06/0.03,
C H L-; C q C it CH CH 4 9 ,
1.4091; C2 6 5 - 2
55-56/1-5, 1.4279; C 1159 C'11 1 1 ..,11 C 11,, H, (Ib),
2 7' 6
49, 52-53/0-005, 1-4472; C115 te rt fl, 2 8 -
2 '1 .11 , (unstable even at
20 C), 1-4149; i,90-C3H7 f C4If 61 F - 5,/(:.,)2 , 1-4 16 4 ;i9o-C3 El 7'
CH =CHC.Tl 441 36-37/0-04, 1.4274; C 111)p Cyclo-C !17
2 29 4 6 11, ~5, 7"-75/0-01,
1.4522; C 4fl~ I C11i Cflcll'~ , lit -JU-1 i"'- I -'l 53~' ; C'117 11", 4FJ.5'
39.5-40/0-OC5, I - 41 0" ;;lule -f Il 0' = 0 , 11 is fl'ixed witli
0.05 mole of C 4It 1) oil it 2C and Tq is s,~?~,arated aft-~r I hr (20rC), yield
Card 213

S/081/63/Or)C-/OQ1/C)42/061
Anhydridesof organophoophorus B144/B1136
'6.51', b.p. .56-37vC/0-005 mm. 0.075 C4 If9OH and C.075 mole of
0
2,6-lutidine in 10 ml C 6H, are added to 0.075 mole of 'All (R - C2H,) in
10 ml C 6H6 in the course of 5 min; after 1 hr (5000 and 12 hrs (200C)
10 ml water is added, which has been acidified with 2 dropo of
concentrated IICl; Ia is obtained from the benzene layer, yield 50-5A,
b.p. 63-640C/11 mm. Ib is obtained analogously with a yield uf 52-~/. from
O.C75 mole of II (R - C H ) and U-075 mole of C 11
2 5 6111 OH in the presence of
0.075 mole of 2,6-lutidine in C 6 11 6' For communication 11 see RZhKhim,
1962, 18Zh264. i'Abstracter's note: Complete translation.-I
L
Card -5/5

MICHALSKI, Jan; MODRO, Tomasz
Derivativo,s of hypophospi;oric acid. Pt. 1. Tha synthesis
of tetrsalkyl hypophosPhates- Rocz chemii 36 no.3:,V-,3-488
162.
1. Dopartnent of Organic Cho-7,istry, Institute of Technology,
Lodz, and Institute of Organic Synthesis, Polish Academy of
Sciences, Lodz.

MICHAISKI, Jan; ZWIERZAK, Andrzej
Derivatives of hypophosphoric acid. Pt. 2. The synthesis
of tetraalkyl dithiohypophosphatee. Rocz chemii 36 no.3:489-495
,62.
.A., Department of Organic Chemistry, Institute of Technology,
Loodz.

MICIU,LSKI , Jan; P.;-TI.-JC7,LK, Aleksander
-.. Organophosphorus compounds of sulfur and selenium. ?t. 21.
Rocz chemii 36 no.4:77c-776 '&:.
1. 111~epartmer.t o.' (rganic ChE.,mistry, Technical Univerrity, ~odz.

HICHALSKI, Jan; RATAJCZAK, Aleksander
Organophosphorus compounds of sulfur and selenium, Pt. 20,.
Rocz chodi 36 no-5:9U-919 162.
1. Department of Organic Chemistryo Institute of Tenhnologyp
Lodz.

Mlf;ll,~ISKI, Jan; !.'jSIERO,:ICZ.
Organophosphorus derivatives of oull'ur wnd seleria-z- t. . 1.
Rocz chemii 36 no.11:1655-161,9 16.~.
1. Depart:--- 11 r., ~,try, ~.': vt-i r.; ~ t -, iA,,iz.

H1,I)NAUK, P.; BOI A iZ~ I, R. j M, I:HAi-f% 1 , J(. I MUS-IFROWICZ, S.
Alkyl-anrl alveny'l- jyr-,I!ro3. I-t. 8. Iti-11. ch,,,fr ?Ali I- -n.4;
507-51.1 163.
I
,. I rist4 tilt p :f Org it .,' - i, fl, 1,Cjdz Branch, Po I. sh A car1pnry
of ScIlences.

14ICHALSKI, J.; 14IKOLAJCZYK, M.; MLOTKOWSKA, B.; SKOWRONSKA, A.
Formation of tetraalkylthloropkraphoffphat--s tnraugh isawrization
of their thiolo-Isomers. Bul chim PAR 11 no.12sW-W 163.
1. Department of Organic C~emistry, Technical University, Lodz
and Institute of Organic S~-thesis, Polish Academy of Sciences.
Presented by J. Michalski.

MIICHALSKI, Jar; TLLD.1(1.4SKI, 3dzIslaw
-'I-'---'67g's.n'ophosphorus compounds of sulfur and selenium. Pt.24.
Rocz chemii 36 no.l2tl781-1785 163.
1. Departmei-it of Organio Chemistry, Technical University,
IDda.

MIMUSKi, Jan; PLM&A-KRAWIECKA, Bozena; SKOWAONSKil, Aleksandra
Organophosphorun derivativus of sulfur and seienium. Ft.26.
Rocz chemii 37 no.11:1479-1487 '63.
1. Institute of Organic Synthesis, Polish Academy of Sciences, Lodz.

MARUSZEWSKA-WI1ECZ0nKO,dSKA, Elzbief.a; 'S~PALSKI, Jan
Anhydrides rj~' orr;.nopnospriorus aricis, Pt, 5, [4z(-z 37 ru-,
12:1579-1588 '63.
1. Department of Organic Ghemistry, Technical University, Lodz.

BOCHWIC, Boleslaw; XICILALSKI, Jan
Osman Achmatovicz. !Iau/-a fo-':jca 12 no.4.62-65 --'-Ag
1. 14--mber of Polish A.-ademy of Sciences, Warsrv.4 ("o - "l; c!.ulse; ) .

rr
red
ELM.' T d"M t.

77.
mal-vb-Wf~- ~'k
7, -~R,

MCfA1,6Ki, K.
MGHAJA~)Ki, K. Development of a base for the raw plant materials of the food
industry during the period of 1956-196o, p. 22F
Vol. 10, no. 6. June, 1956
PRUML SPOZIWCZY
UCHNOLOUT
Warsaw, Poland
Oo. Last Accession Vol. 6, no. 2, Feb. 1957

MTr!LAT, -,t T , Y .
Protrct: on of -pipar beets Irojr a, I.' T . .
GA?7-'TA CTIKROTFIC-~. (,; t. owa r z'-s7f-ria Na-i~owo-TeclLniczr.,- Inzynierow I Trchnil.ow
Prz". slu Rolnego i Spozvwczepo i Gentr-.lny Zarzad Przetrysl" Cukrown 4CZerCN
j
',-Iarszawa, Poland. Vol. 61, no. 2, Feb. 1959
Monthly List of Last Lurorean Af , ession LC, Vol. --, -ic. ', July
Uncl.

POLM/Churaical Tcchn,l,;r-y
,5 - Clicidcal Pr)Cucts cxif~ Their
plicati n - Water Tnntzicnt, Sowa. e W,:Aer.
Abs J..)ur Ref Zhur - EldrAyn, N- 9, 1953, 29214
Autl r Micl,alski, K.
L-I G t
Title Mo- 'uialysis )f P.Autr-A Surface Waters.
rT i C Pub GcLz-Wjr'n-Techn sanit, 31, N) 6, 217-218 (1957, (ii-- P
Al~stract N.. abstrict.
Card 1/1

MICHAILKI, Y.
Examination of contaminated wnter and bacteriology. p. 221.
GAZ, IADA I TECHNI" -IANMLhM4. (Stowarzyszenle Ilaukowo-'Aechniczne
Inzy-nierow i Technikow Sanitarnych, Ogrzewnictwa i Ga7ownictwa)
Warszawa, Poland. Vol 32, no. 6, June 1958.
Monthly list of East European Accession r'AI) IL, Vol. 9, no, 2, Fet., 1960
Uncl.

SWIRSKAL, Alicja; g;qlgSKI, Uzimie z
Airan derivatives of 3~-nmlno-2-=mzolidinone. Acts. pol. pharm. 19
no.5s459-460 162.
1. Z Instytutu Fa ceutycznego w Waresawie.
C! N
(OXAZOLES~ (FURMS)

WESOLOWSKI, Jan; GASIAR, Stanislaw; MICHALSKI,-K4zjzia=; STEPNIEWSKI, Waldemar
Keamuvwnt of alph-ray radloactiv-ity in the atmosphere over
localities in the Low Silesia district. Nukleonika 6 no.12*801-812
161.
1. Universytet Wroclawski we Wroclaviu, Katedra Fizyki Dosviadcxlnej.
Akademia Medyczna we Wroclawiu, Katedra. Fizyki.

/1, ~ I - ,I I I
MICHALSKI A-- K.
The use of polyesters for the construction of motorc,r hodles.
P. 360 (Techrdka Motoryzacyjna) Vol. 7, no. 10, Oct. 1957, Warszawa. Poland
SO: MONTHLY 1NDFX OF EAST EUROPEAN ACCESSIONS (EFAI) LC, VM- 7, NO. 1, JAN. 1958

POLAND/Chem~cal Technology - Spitlictic Polymers. Plastics. H-29
Abe J-)ur Rcf' Zhur - Khimiya, N,) 24, 1958, 83531
Author Mic.-,aiski, K.
Inst
Title The PIDlyester Glass PlibtLc5 as a Constructim Materiai.
Orig Pub Tochn. wcturycm., 1953, 3, m- 1, 8-12.
Abstract r,!view jf the pr3pertles and the application uf gla:35
plastics reinforced with glass fibers and glass mats.
Card 1/1
- 53 -

~9CHILSYI. Y. , PE7RYYCF-4XirI, A.
The use of plastics in the construction of machinery. (Conclusion)
p. 434
K,GHANIY Warszawa, Poland Vol. 32, no. 8, Aug. 1L)59
Monthly List of East European Accessions (EEAI) LC, Vol. 9, no. 2,
Feb. 196o
Uncl.

MICHALSKI, -Konrad,_jjgroinz.
liew synthetic materials and their use iE Plaln beal-inc'21- 7achn
C
motor 11 no.8:274-278 Ag 161.

MICHALSKI. Konr j mgr inz.
Molding-pressing of parts from thermohardening plastics. Ylechanik
34 no.8:411-413 061.
1. PRIS, Warszawa.

MICHALSKI, Konrad-,--mgr. inz.
"Coatings from plastics" by Zbigniew Kowalski. Reviewed by
Konrad Michalski. Machwdk 35 no.50Q4 Vq '62.

MICHALSKI, Leszek; CHRORDISKI., Andrzej
Bicautograpbic azialysis of growth regulators in haze! (Corylus
avellane L. 4 g-rminating pollen. flauki matem przyrod Torun
no.6:65-71 1W.
1. Zaklad FizJologii Roslin,, I:niwersytet im. M. Kopernika, TorLn,,
i Pracownia FizJologii Roslin, Osrodek Badawczy Mologii Stoso-
waneJ Uniweraytetu im 14. Koperniks, w Torimiu w Pivincach, pow
Torun.

MICHALSKI, Leszek
Changes in plant growth regulators in the generative organs of
yellow lupine in different stages of development. flauki matem
przyrod Torun no.6:73-81 160.
lo Zak3ad Fizjologii Roalin, Uniwersytet im. M. Kopernika, Torun.

MICHALSKI. Leszek
Blectrophoresis of plant regulators in agar plates. hauki mal-em
przyrod Torun no.6:89-95 160.
1. Zaklad Fizjologii Roslin, Uniwermytet im. M. Kopernika,
Torun.

MICM.IEWICZ, M.; MICHALSKI, L.
Changes in the level of growth regulators ir lepves and reprc-
cl,Tctive orgars of the radiBh RephanuB sativux L. 'r. Its dif,lerert
sta;-es of development. Acta a.robotanica 9 ro.2:~,,~-111 (.(o
1. Zaklad Fizjoloqii Roolin, It1wers.-Aet Mikolaja Koperrika, Tor,x..

-. I i-
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I ~ CA) 41 -A 1~-U Ck- ~ ~ k C~ I
POLAND/Optics - Physical Optics
Abs Jour Referat Zhur - Fizika, No 5) 1957) 12980
K-5
Author Michalski Ludivich
Inst
Title Optical Measurements of Surface Temperatures of Soiids
Belov 7000.
Orig Pub Pomiary, automat., kontrola, 1956, 2, No 9, 342-346
Abstract No abstract.
Card 1/1

POL'diD/,.tomic and M,,iccular Phy:3ic- - Ht.-at D-
,,bz Jour Ref Zhur - Fizika,,
No a44~
Author Vdchalski Ludwik
In3t
Titic M---asu-cmcnt of t~-c- 1-bzpc:ratur,, rl' 4ct-.IL in ti. LiquI 1 'it--.t,
Orig Pub PoL-dary, automat., koztrola, 1958, 4, Nr, 5-6, 25A-24.;)
.bstract Survey article on the measurinG methods and d,.~vices, read at
the Conferencu on Prvcision Mechanics --nd Measurr-men-.
Technology in ItlarsLw, J,-mc 1958.
C, rd 1/1

MICHALSKI, Ludwik, Ar inz.
Temperature measurements of the surface of rotating eyiinders.
Pomiary 8 no.9:4017-1+10 S '62.

KMHAT -Ludwik
Vork of an electric furnace in case of inpressed frequency
of the coupling of the heating power. Slektryka Lods no.10s
81-95 162.
1. Katedra Grsejnietva Elektryesnego, Folitechnika, Lodz.

I MICHALSKI, Ludyik, dx~. , inz.
M*asur~-rant of the surfmco temp?raturt rf rctetinr cv'ln~ori. :!eT 1
rAsz przoplyw no. 39/40:61-73. 162
1. Kat*dra C-rzvjnictwm Plektryczne.po, Prlitvchnlk8, I.cdz.

MICHALSIa. inz,
Precise temperature control of electric resistance furnaces.
Przegl mach 22 no.3:81-82 10 F 163.
1, Folitechnika, Lodz,

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il o n T- ~ 'r - --i -:~ :, - t. r' n - , - - ': . I I ...
FRZ331 AD J, -,r 1 -1. . .-" !,-.. 7 Kom 17~* - ) - -, , -
Vol. JJP no. 11 9 junp I '.
L'~!' , Di ' Florc-enn A-!('F~Ii T!- (EEi~:,, I ., I . , .1 . .
;nc. .

MICHAISKI, M.
Untapped sources of coal economy. p.267
(PRZF'MAD KOLFJOWY. DRO(n)Y, Vol. 8, No. 12, Dec. 19~6, Warsaw, Poland)
SO- Monthly List of East Furorean Accessiona (EEAA) IL, Vol. 6, No.9, Sept. 1957, Uncl.

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XAMUJA W am Affeatiew"Mils of the .1"W-
AW IFA AM "., S= deps"al Asialysis.
-Sdwm"y ursidash ..Iuk% Praerywaxiew, jako uodia. emisil
v analidit sWktnLlnej'* Preernyd Chmkmy No S. IM. pp 282-
M. 5 figs
Advantag" -if the Interrupted arc- are *mphasiml in ec"r4wri-
son with other niethoda of exciting the onSLU60n of Charactertotte
radlaUon In apectra.1 analyst& TOSLID9 and Improving the method
appiled by PleflatIcker led to the ConstriscUon of an installation
nourlabed only by alternsUng cWTInt inesilift no current switches,
by tavanxi of which 100 separate dUchaftes per sev between the #lee -
troda a obtained The advantages of this IrWAUlation, conjUL in
greater Intensity of discharges. Increalft the sensibility of detecting
rivinenta With characteristic Work qW&m such as arvenium. pho-
sphoruiL carbon etc There is &Lao a po"bliltv of quantitative Spec-
U&I sn&IyM Schem&Uc drawings of taftalliations are Included

-Ml
C ZW ::d&
ILI
"ante"upted -ttc** an dta 71w wave diagram
devyibird by Pfrilaticim (I. KkUrachm. 45. 719(lW-o);
Z MfOallbands W. 211(IlMd)) is kaproved Upon to give
of detecting the Wectra of As, P. and C are tkus imemsed.
Frank Gowt

M~C,IAALSKO,

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MUROVSK 1. V. ; 141CHLISK 1. N. -, KIZCZKOVSKA. K.
Polarographic method of determination of oxygen combined with hemo.-
globin and of blood oxygen capacity. Acts, pbysiol. Polon. 3 SW1. 3:
253-254 1952. (CIAL 24:1)
1. Of the Department of Blochoulstry (Head-Bagdasarlan. N.9.) of the
Institute of %barculoste in Warsaw.

TYSAROWSKI, V.; NICALLSKI. K.; LLZCZOWSKA. H.
Polarographic mthod of determination of oz7gp In oj7he"lobin.
Polski tygod. let. 7 no. 45:145371461 10 Sov 1952. (CLKL 24:1)
1. Of the DqWtmmt of Mochemistry of the Institute of Tuberculosis
(Director--Prof. Janina Mislevics, N.D.)

MICHAISKI,, Maksymilian, inz.
Colorful painting of workshops and production instaLLations.
Przegl kolej mechan 13 no.8-.239-241 Ag 161.

MICHAISKI, Maksymilian, inz.
Estrich gypsum a new building materUl. Przegl ~olej drog i4 no. " i 81~~ P-9
My 162
1. Dyrekcja Okregowu Kolel Panstwowych, Szczecin.

MIWALSKI, Hys-rd, mgr Inz.
Properties of frictirmally w-Ided jointa. P, gI apaw 16 no.9a
221-223 St64
1. Welding I~nst!tute, Gliwice.

t~ 1 . - '; , rydion, m,-,- in--..
MICHALSKI. T,,':' ~ I I
1 ;1- -. I -W ~ ~ I . ?-- ~'d - - - :~ i J~' :-4- :3 i :7 t rl r; - e -We -' - 4 ' ~ - .- : I ..
, r. ~i '. I Z -1 ,,'I
I "
9 Fi,i a ~ n , .;. . ", - -~.. A ~, "
" . ". , I , ~w - .- - t , I
. I %,~ , , . ; - 1 1,

ROLK1. Waldemar; MI2dasxi. Stanislaw
MONNNNIULk ~
Experimental application of dextract in guinea pigs and
consecutive renal and hepatic anatono-pat~iolcgical changes.
Par. polska 7 no.3:273-278 July-Sept 56.
1. Z II Kliniki Chirargicznej A.M. w Gdansku. lierownik*
prof. dr. K. Debicki. i z Zakladu Anat. Pat. A.M. w Gdansku
Klerownik: prof. dr. V. Czarnocki. Gdansk. Upowa 3.
(LIVER. effect of drugs on,
dextract, histopathol. cha W a in guinea pigs (Poi))
(KIDNEYS. effect of drugs on,
Same)
(DIXTRAN, effects.
on kidneys & liver. histopathol. changes in guinea pigs (Pol))

MOLKE , Waldemar; MICHALSKI, Stanislaw
Hepatic changes in guinea pigs and rabbits after the administration
of periston. Pat. polska 12 no.4:473-478 161.
'4
1. Z II Kliniki Chiruriicznej AMG Kierownike. prof. dr K.Debicki
Z Zakladu Anatomii Patolo icznej A14G Kierovnik: prof. dr W.Czarnocki.
(LIVER pharmacol) tPOLYVINYLPYRROLIDON-L pharmacol)

MOLKE, Waldemar; MICHALSKI, Stanislaw; ZAWISTOWSKI, Leonard
Periston as a plasma substitute. Pbl. przegl- chir. 35
no.10/11:1148-1149 161.
1. Z II Kliniki Chirurgicznej AM w Gdanaku Kierownik: Prof.
dr K. Debicki.
(POLY-VINYLPYROLIDONE) (LIVER)
(PHARMACOLOGY) (RNA)
(LIPID METABOLISM)

IdCh-A!3Ki T.
ldch~tls,d T. "'11h, ic ert t
of Yinifo -tlunll
(UOjUvInosc a !-rnosc 6.Yzr,,,'?(,rda oun,:tti metodit vi, IoKr ~n- o w
ilrzegla; -'ieoaezYjn
-Y No 1, '91,9, or'. "tj-10' 3 figs.
Th (- iu th or - ro ve , by n -j, - r i c a . e x:tr~ - p Ih-t I tn- er-1, eri jr .1' c-i r-ir* r-r-
i.t.;cs ~,f accur-icy f ;ianlfol i rpsection usu-ill- m-rdio i Oi,ear, err,)rs and
eLli:,6e of : e-.n errur/~ ;;i:w in be ,nt 1 1 '.v i ve.
15 i 0 - 3: li, e , i~ ij -I y, in ~h(- c .-~e o' r. : !ier v a' i on j - +-r jrr ~ uur fr ~r
-V-i- rv,,*., r, -,,i*,~!~- I r. I '. 3
a i~eometricai -~oirL ." vitni, I.,j v r tn& va.,ies . -
L i,:+ i *- ~j U f Me'Ln e. r o 1 3 +
man.v tivies in excess ul' the all n, ; n e ;uer.(-e
of re-balancing,, co-o. dinve-, ;irc- va.,tl 'v lif."erpnt fr.-)r '.?~e co- r.".n-i*.e3
orinnal Iv corrru'ed, an : f(-t charq ' f-ris-d as to accu -i,-- n - :i v, r-.,
,imall me in error in , Oir t I ()-: 0 i on. Il. t, h i j orin--c on, nf- vithor recorxends
the exercise c" ca,,tion in +he Pv~,'u;iti(,n ~)!' t~)e 'ic ir-r#-nts
tnp
on the ba-Az5 ol' r:t-,ri erro.,s, ii' ir y ih,r-. -oil r- 31 ! Of
variou5 trianj-~.' ~i'-iori3. f,h- n ex tr. 'rivi: r: --tr;t-u r. c,:' i r r iFr,
tnt author urges tna' it J.3 t cuncentrate the att~r.t4 n r-it-p-r
on t~~f arrinpev-ent f the 3ir~ce ~,n th- -vent of lacK of
effec-dve elements of conl~rol the accuri y .,f :oint io- 1,;,ve.
-)C: :o1i3h rec-+rdcal b~-r-icts - No. 1951

Idch 3,,i T.
Yichl-'3ki T., :,n,!.. "The I-Itc,dr,,~ of
(r,ontrol,. obli 7.en'. ?rzt-~,Ii: ;-o.--zy,jny. No. i-I., li~), rn. 7t)-7P
lhe checKin~-. c oc. -~u or..'3 s ro Cl- 3 il"', Nu- "!.t
detic il undert ii f f t:;- ri %hi
c) er ~t.JLori; corit rol' rru. i , - -
t~ie r ti culati cr,.; ir -t :e 6v tie [Y-111-ra ~l , A 1. t
ljy t-ri is U. dc.-Il.c.ons f -zi.-.u'-;.
c- '-ho c ir. cri-f c,,, S
(c!' :~Uirorsj ,nc:,eR-ie ,o-r int%t-] i..i _i(, ori~ "(F. r-f
r
;r-- ut" 1'. f.- C., f U: ~ c t
c r I
value,i ~ir- i t- ch #-!c . i n f r te .
X: 1 ol ~ -ir Terhi i - (7:, - t, , r t r , - ';o.

MICHALSKI, T.
"Weights of doterminine. Pleawn-ts In a two-dirprt!on Intorpoctlon'. D 214
(-,mr),Ez.TA r KARTO`-'-;,AFTA, Vol. 1. No. 4. 1952. largzAwa. Poland)
SO: MOnth Y- List of Eant Europe" Acr!pgslons. (E'"Al) .LC Vol. 4. No &1 4 .
Aw IQ5 ~,. nel.

YTCHAISKT, T.
"Yost AdvnntaFeoi!s Case of Ipspc+4on" '1 39 1 (CF07F-,A - 7AP-C-'T.A7-A,
Vol. 3, "o. 1, P"'4, Varszawa, rolrnd )
SO: I~onthly List of Erst Pi:ro-eqn Acce7s!ons, (F'M"y P-9 "ol. 4,
;0. 1, Jar. lOrr, T'ncl.

MICHALSKI, T.
Survey of the development in organizing geodetic works and som
conclusions; from a rigidly fixed team to an elastic production
brigade. Pt. 1. (To be contd.) P. 131. Vol. 12, no. 4, Apr. 1956
Whresawa
PR&GLAD GEODEZYJNY
SOURCE: East European Aosssion List (EEAL) Library of Congress
Vol. 5, no. 8, August 1956

MICHALSKI, T.
Survey of the developmnt in organizing geodetic vorks and some
conclusions; from a rigidly f1md tean to an elastic production
brigade. Pt. 2. p. 171. Vol. 12* no- 5, may 1956 wars"ma
PRZEGLAD GEODEZYJIfY
SOURCE: East European Acession List (EEAL) Library of Congress
Vol. 5, no. 8. August 1956

FICHALSKI, T.
Contribution to the analyqts of intprse,~,.it,n. "'r. f-om t~e P-jish. -. .5.
(Geodeticky A Kartograficky Obzor. 701. 3. No. 3. Mar 195 7, rraha, Czechoslwakia)
SO: Monthly List of East European Acce3sions (EEAI.) LC, Vol 6, No. 9, Aug IQ5?. Uncl

I .
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P/029/60/OOO/O04/Crj2/')02
'to 0 0 26006 A076/A126
AUTHOR. Michalski, Tadeusz, Master of Engineering
rrTLE- A method for direct marking of free terms during compensation of
multiple intersection
PERIODICAL-, Przegl~d Geodezyjny, no. 4, 1960, 122 - 123
TMT, During geodetic calculations values obtilned should be free of mathe-
matical errors, otherwise the marked elements are misleading and can not be regard-
ed as basic data for further work. The above condition necessitates that all val-
ue3 mus-t; be re-checked during calculations, especially in such calculations where
~ne greatest possibility of mathematical errors occurrs,i.e. compensation of multi-
ple Intersections. A number of control methods are known, among them the metnod
present.ed by Master of Engineering Jerzy Gaidzicki, published in the periodical
"aeodezja I Kartografia" 1957, no. 4, 243, which is however, rather complicated
and time consuming. The author of this article presents his own method according
to which, direct marking of free terms during compensation of multiple intersec-
+.Ions is calculated and re-checked much faster. It is seen from the following
equation I, . v,' - (Kij2O0g) (3)
C a rd 1/5

A mettiod for direct marking of ... 26086
P/o2gAo/D00/004/002/002
A076/A126
,nal between orientated direction Ki and the approximate azimuth vll a relation
7
ex's's V, = K~ + 11. illustrated geometrically in Fig. 1. If the free -.erm 1. does
not equal zero, the oriented direction passes by the approximated point P1, of 'he
i.nrer-sected point P and Is distant by the magnitude of
h S (5)
intersecting parailel to the axis cut in point Px, and parallel to the axis of
ordinates in point Py. It is easy to note that the position of the two points is
defined, as abscissa of point Px results in Ayl . ctg KI, and or~dlnate of point- Py
equals axi .tg Kil It is possible to determine the distance of PxP - Dx and PyP~-
Dy, namely Dx = Ay' ctg Ki _bxi,
Dy =by' Ax I - tg KI ~
Be-.ween !he sectors Dx and Dy and the sector h, tne following dependence exists
n = Dx - sin KI, ri = Dy - cos KI
ry substi-.uling them in Equation 5, the following is obtained
C a -,d --/ ~1,

P/029/60/OW/004/002/0502
A method for direct marking of ... 26086 A076/A126
II - -L . sin Ki ' Dx I Ki - Dy
Si I
iind by 'ransforming the above for Inverse directions, i.e. from interse("Ing pc.'I-
to re,~ecting point P,, the following may be written
I s n (Klt.009) Dx
I ~L . cos (Kij2OOg) Dy
sl
rl,,e .o tne fact that the free terms 11 are small magnitudes, It is possible t-,
s'.Lbs-It-iT,e In ~he above equations in place of values of oriented directions
(V, 12009) tne values of approximated azimuth vi. It is easy to note that coeffl-
cien's at Dx and Dy are actually direction coefficients of ai and bi defined by
Eq,,ation 4, but used also in transformed form as
. sin v; b Cos v
s
Aller taking into consideration the above dependence the following workable for-
mula is obtained
ii = ai * Dxi; Ii = bi * Dyj (6)
Ca rd 3/

/"Ild, a
SZUWA, Teofil; MORDARSKI, Marina; HICHAIBKI, Tadwuxz
An apparatus for seeding of Streptomyces. Arch. immun. ter. dosw.
4:)6)-)70 1956.
1. Instytut Imm-unologii I Terapii Doswiadczalnej PAN we wroclawiu
(Dyreictor: prof. dr St. Slopek) Dzial Bakteriologii i Antybiotykow
(Kierownik: prof. dr St. Slopek)
(BACTIRIOLOGY, appar. and instruments
appar. for seeding of Streptomyces)
(STHXPTOKTCAS, culture
appar. for seeding)