SCIENTIFIC ABSTRACT MIRONOV, V. F. - MIRONOV, V. F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001134520012-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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141ROMOV, PLTROV, A.D.
Synthesis and polywrisation of compounds containing hydrogen
and an unsaturated radical at the silicon atom. Izv.AH SSSR-
Otd.khim.nauk no-3:381-384 Mr '57. (MLRA-10:5)
l.Institut organicheskoy khtmii im. N.D. Zelinskogo Akademii natLk
SSSR.
(Polymerization) (Silicon organic compounds)

~-! 1/, "0 1 ~ . II
PETROV, A.D.: HIRONOV, V.P.; GWKHOVT3XV, V.G.-, YEGOROV, TU.P.
Synthesis and properties of some of the big-(trimethylsilil)
propylenes. lww. AN SSSR. Otd. khtm. nauk no.9:1091-1100 3 157.
(MIRA 10:12)
1. Inetitut organicheakoy khtmii Im. N.D. Zellnekogo AN SSSR.
(Propone)

AUTHORSt Petrov, A. D., Mircn-v, V. F., 62-11-17/29
Komanicn, L.
TITLEs Synthe8is of B-Chioro and 6, a-Dichlorovinylalkyldichloro-
silanes (Sintez B-Khlor- i B, B-dikhlorvinilalkildikhlor-
silanov).
PERIODICALz Izvestiya Ali 353R, Otdelenie Khimicheakikh Nauk, '957,
Nr 11,pp. 1393-1395 (MR)
ABSTRAM Here the best conditions for a synthesis of CICH - CHSiC1 V
as well as the alkyl- and alkoxy-derivatives of them, among
them also the difunctional (in the silicon atom)
B-chlorovinyleth.vienedichlorosilane, were obtained. The
development of C. L. Ag-re'8 (reference 2) was continued
here and it was ascertained that the trichloroethylene can
also be condensed with the alkyldichlorosilanes. This is a
very simple way for the synthesis of the dichlorodialkyl-
silanes with the functi,nal groups in the alkyl-chain
Cl2C CRCI + HSiRCI 2 ---) Cl2C - CffSiCl2R + HC1
Card 1/2 where R CH3 and C2H 5' It can be judged on the coura of

Synthesis of G-Chloro and 8, B-I)ichlorovinylalkyldichloro- 62-11-17/29
silanes.
the reacticn acc,,rding to tne given equation and on the
position of the chlorineatome according to the corresponding
physical properties of the B,B-dichlorovinyltriethylailane
which were obtained by kgre and by the authors. There are I
table, and 3 references, I of which is Slavic.
ASSOCIATIONt Institute for Organic Chemistry imeni N. D. Zelinakty- of the
A-N USSR (Inatitut organioheakoy khimii im. N. D. Zelinskogo
kkademii nauk SSSR).
SUBMITTEDs June 21, 1957.
AVAILABLE: Library of Congress
Card 2/2

AUTHCRS: fetr~,v, A.D.
TITLE:
Gerffaniw vi T 1,., 1,1' T 1- 11, t I I i A
jc)v.,'~
F&HICDICA.L: Izvesti- a 33311 Ctrl, Yll
--p
ABSTRACT! The AfInt (Cli.,), s1cm rT.,
aieana cf -~hc
CH C" CFMJ'(C2-Fr",? Jy t
Thl~~ -Ahc,91z -as 1-ter -1~o -cr ct--r
cr&a.nic _-C)aq.~.wds f or C-H~ 3 L'-' ii.
liei~ydroohl:ri
ew~
rAUtllrlr-l f0,',.3 th:, 7 of rill's! I ..... . .
mt:thod of rcl
.13
tc the c it-- t
reagent rith Tt '!!If t I al t
tile r ":-~7,qnz (clf ca"fix.,
0 1,9 2 1', r I c:

7 D,.:~-I- ~U -,c
cf Silloon,
n.
A.9SCCIATTC-,':
3311
.1ruz" tit C'C'a;
"-;SP) .
SUBIITT'-r:*D: JaIj ; . '9~ i
AVAILABLLi U-bnr; -' 3~:
Card ~12 1. Tetrzetfi~-'- T-t~
L3

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uj
Or fts, added ~5 M 'CHO: cj~j~ftji
ftlini the mrxt' d,
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SiCAWCUiv b tr"Ied v4t" A0 Jde*l % B
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naLirly
At, 9,srPh: C14.- b,.- w
bv-148,b-i j,443 -0
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44
7&63
aw

KORSHAK, V.V.; POLTAKOVA, A.M.; PETROV, A.D.- 141HDII)V, V.P.
Pol.vaerization of unsattirated germanium organic compounds.
Dokl. AN SSSR 112 w.3:436-43A Ja '57. (KLRA 1014)
1. Chlen-ko rres pond@ nt AN SSSR (for Korshak. Petrov. Hironov)
2. Inatitut elementoorganichookikh soyedinenly i Inatitut
orgenicheskoy khtmit im. N.D. Zolinskogo Akademli nauk SSSR.
(Germanium organic compounds)
(Polymerization)

MIRONOV. V. ' (Moscow)
E Vergleich der Reaktionsbereitschaft von -aementen der V. Gruppe des
Periodensystems und Synthese von Einigen Verbindwigen"
paper submitted for the L~ymposlum on ~)rganic and licn-Siliceous "-'Mc~:n Chemistry,
Dresden, 12-14 -'lay 1953.

,-i I ;i,(X. - V , V . . * .
V. F. M iron ov, V. A. i r umai =rixr), - . Y a. fz-:1 kov a, - I- . in i . - .
fetr~ov, "t'he -ynth-si, A' 1 rmaviwn-ji-anic -omp,)w i8."
i(eport pr,,~sentv ! at, the ~e,-,)n ! Al 1. -u,,i-ri - n t* - -ri --. r k ? i I .- - f I - ~ 15 * , : Y ;I: ,
I'i-ac t '-cal Appl,catikm o" 9i!L:on-u:rarAc -ompuwk,is ttel~ -n '" i-f.,,.-a !. m
2'.-27 ")eptevber 116F.
Zhumal pr Lkl,-i inoy krit. t i, - ~~, '.,, .4r 1, .,,p Z3~ -2L40 ~'jS,': 6,

AUTHORSj Yepc,rov, Y'J. i,. , Ley t e o, L. A.
TITLE: Traii s -~ o:,f i ~.-ura t i oo f 1 2 - Di s i ly 1 ju - j t,,
nes '0 tranz-':o~-- ~i r- at siI , 2 - i i sil z a.::~E:- B:.--
etilenov)
PERIODICALs Izvestiya Akadenii ;i a u~- ~3jM,Otde I e-Jye Kl..,7~,
1 )58, Nr 4 , i P. 51(-- - 512 ~''L;:A "
A,BSTRACTt In pre viuus p ape rs 'R ef a 1- 5,' 1 1,.e a,,:t!.orf;
first time the synt:,eais uf
and 1,2-bi3-~tril.10t;~:1131'.Yl -ethjlene aa vie!l a~j
bination dispersion of' +1.1.o 1-tter
alse uttered tl.e t~.at t:.c -~7idenir,;-- i,ff
quency cf t~.e bi:~ary bl.~diaC to 2c cm-1 ~Jbgf-rved i-, 1-2
spectrum car, possible- t)e explained by t~,e
The KRS- spec trum (Re f 4 ) of 1 , 2- b i 3- t t ri c!~ 1 crcs;.
was described by Batuyev anl utiiers (spec-trorra-.~i
T.1,e aut. urs cf ti.e preoent a,-,,r re' L."t t at
IK-spectra cf 1 2-bis-~frc;,,.or, 3,.,y1
-\t \Wit in tl.e rar,,-e fr
~N
Card 112 cr-.- , .

Tr an sconfi,-ur at icn of 1 2-:il3i ly.3
Ethylenes
It was re:orted tl~z--t tliese
tranjconf;f.-uration.T~iere are 2 2
reflerence3, If vl!~ic~' ~s S
ASSOCIATIONt "ngtitut
'lauk j33fi ('f'.."'t;t'lte for Organic
AS UISSR)
SUBMITTEDt ';ovember 27,
AVAILABLEt Lih,*-.ry .,f
1. Disilyloubstituted othylenes-Transconfigurations
Card 2/2

AUTHORS: Vironov, V."., Petrov, A. D,
TITLE: The Syittenio of Vinyl-illd 0-11alo,7envinyl-Su', -,titiited
(Sintez viiiil- i P-.,,,tlo
PERIODICAL: Izve ;tiL(a naul~ SSSI~, Jtleeniye !--hi 1,!,
195`11, Nr 6, ;),). 7 7 C:331,1)
ABSTRACT: In the prp~ent tho. mithors tell of t,!e
carried out cor3orsation of CH 3Cl 2SiK with chlorovin,'l
the common -jascaCe t'rougk rul em,,ty tulle he~' tel U, to 5,)G0:
CH3C1 2SiH + ClCH-CH 2 55d ) CH'Cl 2sicy-CH 2+HC1.
The yield uf vin'll-iet`.il~ i,: hl oroF,i lane in this rca--tion --ou-:ts
to 50-/'j- In tlie dehydrobromination of C1 3SiCFprCH2 Br 4uinoli:.e
oplits off tne bro-iinc-p-ritom, 7r~ierc-~s Fluminiiim -hlo i~,~ - 11"s
off the brotmine-Q-qtoLa. L- P-.d P- bromovinjltri7ot~--Iril ~-Ps
forn reactive Gri,,-ird re~ in tetrahylrof,~rtlr.. T.-iere -~re.
5 refere-cea, 3 Sf wr,.,"ch ire Soviet.
Card 1/2

T'he Synthec I B of Vir-,-' I - ., d-or vir,y I - i' 6 2 - ')' - ~ - " -,- / " 7
-SuIntituted Sil-trea
ASSOCIATION: Irit, t i t i,t or,-arAcherkoy 'Aiimii im. 7.D.Zeli.:n.~o -o it'. - 1--;i
SSSR (II'Stitiite of 3r -.-.nic C~ie.ri!,~try i-,!eni "I.D.Zel i- :, iyl Ik5 UsSR;
SU'_`:.',ITT ED :January 26, 1956
1. Silanes--Synthesis 2. Substitution reactions 3. Vinyl
chlorides--Chemical reactions
C_-,rd 2/2

Po~ ! :- - vA

s Z
TITLE:
3 C- i. ng n a
-IL., e.? K n Z
'
. .1
:n e
FERICDICAL: 7
9 ri -i,,
-
-
ilf 4 (
us
R'
ABSTRACT: T~'
war, d h -a,
Dr- T a - f C
-7-e AS S S R A 1%
rs~
F
-
r r R~f , ar

d ^d
j T
hyj - J r S a* J
P
nd-r, a f h
y 1 .1 e

In y t
j.
e ne
f H
2 p c

CH CH, CH~= CH CH -CHCH
, a!
1: 1) - L) - . - T

f Nex 3
A3SCClAT:uN:
3'~BM'-TED
N. D. ~jc
SSSR -3
AS ',SSR/
M~v 4
cti : ; ~ ~2

AUT 1H) RS lAirunov, V. NJ
TITLE: T,,.e Relatio,-. Bi~,tw,p- t- S,~- -t -f
come Dur, 1.,~
PERT"
Izv,,
f od
f t "n e 1 7~, r v
1- 0 7 J F. t .,2 e U C'
e ac:q
of t.-. e,.I u I c- 7n. C,
c a. cui t I r,
a, c r z -a i c
Ca rd 2 severa:

T-e Re'_- tion
n e -a v r-r v
i rlt e m c) ref r
whi :!~ i s I I rec t r.); r t t
whic!. ca~lse t_ f; r, C r - 'I Fr (2 f r
v ra, *i (j,.
radlicp-s wt.'c!, hrj~.Ied tj t:.,. -it
5 till:les and' r,~`ezc: (:en, 2' 1 vi.
ASSCCIATION: In sti tut orga, 7 p 3 k. ~ )y i T%
SSS- I.,: rl t i t _1 to f C~ :- --iC
3 1. -B W IEl) F e t, rry I 'j
Card 21 2

A I'T"CR S: Kartnev, Syr~in, Yn. F.,
Acr ... "irono-1, 7.
of 3( -,nce ern~
TITLE: 'Pte I S,
.)I Cle "ompnts of S~mc,
(Di;,ol'nyye m,~,m.(--nty -,ekotoryU kre,-nip -)~,elinenjy)
PERIOD'~tL: D-klal- Alknlemii nai-k SSSR, 191,0, 'j-' 1,~.
t'.01 s -ep! sijrel t',.e '.e -oLents ,. some .311
AISTRACT:
.r,anic cc~r.-. iccordin(, to the ~.cteTj lyne t
2' In -,:e e,-tr,,3:c,1,.*e!
ci~ I a t fA a cc orl in :; t,) a f rmu I ~, of ';p 9 t ra n,j
i r7h n t a i n 11 c on , t 9 1 o:.. i i:- t o
t a ken n t , a c(-,)in t . T I)e e x-er i i(,n ta I z- -% I ts n re -i ve% n a
t --il- I eA I i s ', i n- t ive --ecu I i ar-, ty o f '.'x -3 J I '.' c on r om~ minds
iv tl,e increased p"11rity wit'i respect to tl.e ccrre I n1inf;
-arbon ')onls. Accor-ling to the nvnia~ 1e !atf,, t-ie 1 ond
noment of Si-T! -- ~y be estimated to 1D, i:.i t e ',un;l moment
of Si-, - to C,f-D. In ~~Oth of those canes, the -Ositive en'l
Card 1/2 of t'.e li~ole i.- iir~?ctud towards the silicon. it. t~,e I-onds

"lie D' pole !,.-~rnen to of S,,me Si 1 i-on-Or:-anic ~om, ),,n Is 3OV/'2o- 12,`- 1 -"", 411
34 -0 ri:~;l 3i-~ -11r -r"n, t~.i, weif-ht of the ionic st-ite is
11iimermis an ! Ieta il-I 1~i t;i -ro ~-iven. '11".ere are I t:i~ le mi
1, refererco-,.
ASF)OC'ATIOIT: !Joskovskiy Instit,it t,)nkoy im.
V. Lomov~osova
ln.;tit~ito (,~ "ino -1,eric~il -Pcl~nolov-y ;.meni !.!. V.
Lom on o s ov )
SUPY IT" ED: ?
Car A 2,12

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C;/.l 0 e t or. I
f r

c r t

n t Y t
t
h t
I
t CY t
t of
lot,
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of

Add i t ion of Thi olv7-' i c 1 t ) Al y1 -TT- I I s
-~ I tann C ont ri i n,.r
a r~d Synther t s of '.e r-:.
t ') be id iont i r -L1 . Wi tr. ro ~o ren,,,e t j the o -d -of 't I I t i or,
of 11SCOCIT to y-but,ny1-tr":i;',Y1 it 11 -t
tho hyIrolyni: of the t~-ioacet-qto!. ol~t iiro-i I - t t'
fnr,i~itiori of ~-ilil fluth", :" f I I I ..,I t
estim:ite tio, rr,,.,tt ive re:lCtiVitj Of thO ~!11 I
of tn,~ ho-,olo,,ous series 11 SH (n Find
t lo--7 rr t
i r t ~.- r-'.- t i -)7 Y,,,. t h--k r,.,lni t ri I i r!p , I I
1-1 T1.1
ly + i t i
r
mer c a t;in -,p same eaW wV tI- t I
pr )i:yl-et'.Jl su I f i 'I ewa t , -1-4'd t-) '~r '1e its 'er
of 'i,ldition. The infr -rel s~~,-tra of t".is -1--il i con . u i !e
t-,e -i1 i,-.()n mil ri,le obt :ined from (CH, Si -,H, t .y I
mercri,,t-in ~.rnvr-] t-) be i~entic%l. H- -...vt,r, t..o 1 1 i r.
:,,ul f iI e oh t%i,te I f ro-n t ri mp t nyl -al 1 y1 s i 1 np in t - e s:i oni f i -
cation of t-' e -0.1 ct of ii-net-.yl-dithioph-).,i:,I..,-lc : c w s
I t . Thus , t h e --t ~- s,z~7 'pt )r. I
iuite liffere. i on i F: - fr --d f
t h i t thij q1 t i on of d ial ~yl - 1 i t h i o 1-hr, ,.h i : i c a c , 11 t,) t r i -
Carl 2,'3 a 1 ~ y I - -L 11 y 1 i I -I ns t a, p 9 ~ 1 -1 c e a r r o r ' 4 r~ , t -) -t r- o v,'1 i: ov I ~

Ad I it ion of Thioac~.,tic A ci 1 A 2 -T:-, -:1 S-,
i nd 3 nt!-.e- is o f 7.'e r c -i t -In ~q o -,t r. i - n
I O-P WIr. It wr~r. f!t1l"el t:-. t i
F! A. m a x t . r e i p -i - i I r
si c on i t I t I T table
g7i,,r( s "' -) o - - i ic n o - -)u- s t -.e., I
au t 1i - rf- i - f r n t ~-vn e s:- rj
Th. re r-r(, ' t:i~,le -ir '7
A:- 7" A T I-)N' - I, i t 11 t o r -.i:. i c -)y
t it 71 t -if ~Ir --i - i c
kiy of t - p '. c e r!Y T'
SIT B,.'IT-'Ej", A:ril
Card 3,13

5(7
K,)-,:-, h,-; 7. V. o v

T ITL --ri- tijn of 'li- I r. e: v
of t- V t r2 t
n-~ h (7-v :7
?K'l D T ~l L v e r t i y;i A i i k
r I ~,p 17 '_" o
r, B nt ~Cyffuauri qt 1 Or. t
reuc tiv" ty of u- t,~r,i f t
IVth gr-up in i on ri,:i t ~ or:3 !trd 7-:1 i - 1 1
It was found t1l., t th~' r-l-tivity 0" t' P:.- cc,-
c r-a s,- s in i or. r(-,3,, t I on.; i r. t hp -r P 1, 1 e ;n T
in - 11' r t i on o f t 1~ 'i e -- f-,7 , ur -, r -
incre;-se!~, in th- -~-r ~er Df :3n e
Among th,~ t_--ctur;,',ly ri-11 _r q f t
i n v e n t i - i t !d i I I
ition . iPius r,:) loa-tiv tin,., :"r- t o -r-
the silir-,n r~tom in po',
C ird 1/ 2 carbor, n to-,s in r i- -tu r y
poly-,?ri:--tior of Vir- -1 '1,' A t
of the ,Vth Group
I ta n n 't n F d o n,) t o i y
ca~ay'le of i!'C ~01 wity,
Furthermore, ro., ol t ion
r. e r ma n i um w r- 0 1: t e . r"
t,-3 11 es 7 t 7'
In - t ' t ut el e, t n I Y
r o -
-i n i c
N. D. A~ I n ',t-
cnem i -try t
SUBM I TT:). j

50)
ZUTHORS: Korshak, V. V-1 Folyakova, A. M., Mironcv, V. F., SCV/62-59-6-27/1'56
Fetrov, A. D., l-,Im'jorLse-~ra, V. 3.--
TITUt On the Polymerization Mechaniam of the Llkenylhydride 3ilangs
CO mekhanizme polimerizataii alkenilgidridsilanov)
PLUODICAL: Izvestiya kkademli nauk SSSR. Otdeleniye khimir~heskikh nauk, 1959,
Nr 6, pp 1116 - 1125 (USSR)
LMTRACT: The polymerization capability of mcnoalkery1hydride sil~.ne with the
H
general fOrT=lA a-Ai-R was Livestignted. In this formula
R4
H 2 CH 31 c2l~ , a, X2~5; B12 CH 2-cli;:CH 21 G~M2-CHsCH2 ex-id CH2-CwCH2'
CH3
The peroxide of the terbi&-y buthyl, and platinum or, coal served as
polymerizers. Uke In the oase of other investigations (Refs 2,3),
polymers of the general formula (CH 3)3WCH 2;113i(Mi313 with
n!:1,2,3 W) n-21 (III n--2 (111) nz) were found. The structure of the
Card 113 polymers obtained was letermined by mearis cf the infrared spPotrum.

Cha the Folymerization Mechanism of tlie k1keny1hjirida 3ilzrace WI/62-59-6-?"'/36
The spectra were compared with the spectrum of the polymer
produced from (CH3j-2ff-SiCH 2-CHMCH2by heating with Dlatlnam on
coal (IV). L. 1. Leyte3 ard V. Ii. Smcrchkov plotted w~d
interpreted the spectra. The investigations cf the infrarA spectra
showed that ti,,~ e-1ljldLaLrj1 (aryl) silanes polymerlze in n
different wal tu;11cr f~)rmntic7u of difforentlj atruoturod polymera In
depende.-ice o.. the p,-3,ymerizer. Ln tue prosonce of the bathyl
peroxide aid at a pressura of UM atmcsph8res a ma--rv mo.'ec-,;le (A)
was formcd, in w'2-ch the 3-F1 1>and is rot split up, Thi3 =ciusion
J,
is made because of the preserve of the band (2100 om- j
-thara,oteristic, of tY.3 3-11 gr(mp, wh-':%!~ is &!so to be fovii! in the
qeotrtL-- of the initial mcnompr and -'n the spe~~trum (IV). The
other form Cf polymers (B) is prt.duced in the presence oL platinum
on coal. Tbay contain th,~ '-rx-d wealdy mentioned elther In a we-Ak
form or not at &!if f&-'le the bands ir, the rnz,ge of from 1050-1150
are clearly dete--uir-ed. TLeBe polymers exhibit the follo7,ing
R
4 1
structures -GH,)-CH -CM
R 2 2-~ 2-CH 2-CH 2- The polymers obtained are
Card 2/3 differently consist=-r-t substan--es, oily to solid, LL dependence on the

77/7
On the Polymerization Ilechanism of the Ckei.ylhydride 3ilanes SOY/62-59-6-_
character of the radicals or. the silicon atom. The data
concerning the differart polymer3 are given in table 1. Ix-. the
experimental part the syntheses of the single polymerE) from the
monomers concerning are described. Table 3 gi-ms the physic-LI
constants of the initial monomers and fiKares 1-16 show the
infrared speotra of Ve different polymers. There arv 16 figures,
2 tables, and 5 references, 4 of wd ch are goviet.
ASSOCIATIM t Institut olementoorganicheskdkh soyedineLly kkndemll nauk 333R
(Lnstitut.- of Elexcntal Organic Compounds of the Academy of
Sciences, USSRV) and Institut orguiicheakoy Ichimii im. Ii. D,
Zelinskogo kkademii nauk 3SSR (Iristitute of Oreanic Chentistry
faml U. D. Zelinakiy of the kc&demy of 3ciences, USSR)
SUENITTEDt September 19'7
Card 3/~

5 '(3)
AUTHORS: Mironov, V. F., Nepomnina, V. V. S ' 1116 2 - 5
TITLE: The Influence of the Chlorosilyl Groups on the M,-)bility ~-,f the
Chlorine Atom in P-ChloralkylsilanesDixing Their Del,jdrochlor'na-
tion by Quinoline (Vliyaniye khloroilillnykh Grupp na po(l-.rizh-
noet' atoma khlorn v 0-khloralkilsilannkli pri d,,,-1dr,-kh1orir-
vanii ikh khinolinom)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye kh-Jmich~-,skikh nauk,
1959, ITr 7, pp 1231 - 1237 (USSR)
ABSTRACT: In the present paper a 0-decomposition product Is obtained
the dehydrochlorination of CH3 Cl 2SiCH2CH2Cl with quinoline
which is produced according to the following reacticn sc-heme:
Si - C - C - x Si - + C - C + X (X = ha1,-,,-en,).
The reaction was mcre intensively investie,-itnd in a ser,.-s of
compounds of the type Cl nR 3-nSiC'2CH2 Cl. HC1 ia splitted off.
It was observed that the formation of a P-proluct C1 11:~ -,ISiCH-r-H2
Card 0 proceeds the more easily the Greater n is. From the fnr-

The Influence of the Chlorosilyl Groups on the scv/62-53--.1-12,"'A~,
Mobility of the Chlorine Atom in O-Chloralkylsilanes Zoir-
iftg Their Dehydrochlorination by Quinoline
ther investigation of the mobility of the O-chl~rinr, at-,m it
follows that this atom '.9 more mobile in the
C1 SiCHKH Sici and in a,a-, and P,"-dich!
3 2 3
chlorosilane than in the P-monochloroalkjl-tT-ichl~,r-)sil,):i2,,~.
Moreover, the follnwing substance was obtaine-1 t~%~
vestigations:
(CH ) Si/ CH - CH 1
3 2 1
CH2 - C H2
The different reactians and synthesis methids are dos-r-P-.-! In
detail in the experimental part. There are 1F'
which are Soviet.
Card 2/3

The Influence of the Chlorcailyl Croups on the S0V11r,2-c_---12 /7e
.~ j I
Mobility of the Chlorine Atom in P-Chloralkylailanes Dur-
ing Their Dehydrochlorination by quinoline
ASSOCIATION: Inetitut or(;anichasVoy khiviii in. 'T. D. ZelinakeL;o Akad,!-ji
nauk SSSH (Institute of OrGunic Chemi.Btry imeni 11. D.
Zelinskiy of the Academy nf Sciences, USSR',
SUBMITTED: November 23, 1957
Card 3/3

5(4)
UTHOR 3: Mi ronoy,_~E,--Z. , Yegorov, Yu . P SOVI (, 2 - 5 12
VeT-r-o~, A. D.
Silicon, ;er7aniu-n,
TITLE: Relative Reactivitieg of Some Organic
and Tin Ccmpounds an4 Their ~amnn Spectra
PERIODICAL: Izvestiya Akademii nauk S'.'SR. Otdeleniye khimicheskikh nauk,
1959, Nr 6, PP 1400-1407 (USSR)
ABSTRACT: In continuation of previous papers (Refs 1-3) the iresent
paper deals with the addition reactions of compounds of the
type It 2MC H:CH2 as a function of the nature of the central
atom hi whi h can be replaced by C, Si, Ile, Sn. The syntheses
of these compounds follow the reaction pattern for the firnt
time established in reference 4:
so2C1 2 quinoUne M MgBr
C H GeCl - Cl GeCH CH C1 C ~ GeCH - CH2-
2 5 3 3 2 2 (C" 3)3 'sCH-M2
Furthermore, 6ifferent possibilities tried out in various
publications and previous investigations undertaken hy the
authors regarding the preparritions of these compoun1r. are
discussed. In the oompoundo of the above type 11, wna nubutitutod
Card 1/3 by C, Si, Ge, and Sn, respectively, and thiocyann,-en was loined.

Relative Reactivities of Some ',rganic Silicon, SJV,162-~'j-6- 42
Sermanium, and Tin Comp,)unds and Their ~;imrtr, 3;,ectra
Data relative to these experiments are t) he f*.)un,i in fi-uren,
I and 2. It was shown that the reactivities of tl,e d.)u~le
bc,ijdr increase in the orler C ~_3;. < ^,e ~3n when the central
atom 11 is chrin~-ed. In a previous paper the author.- had found
th;tt a chan,-(- in tht~ re-tctivities of' the doublc honds in the
molecul( i~- a,-cc.-ipanie ! ~7y a c~~nnre in the Intensities of the
Haman fre uonci,-s cnitracteristic of theqp ~ :y ),,;. V,erf-forL.
the spectra of the metallic corni,ounds were i e
frequencies of the spectrum lines o~tqine,! are 7iven and inter-
preted- The intensities of the respective lines of the douhle
bonds in the Raman spectra exhibit the same -,)rder of P-lemonts
as the reactivities of the said compounds, The distances
between poli~)sy-njnetrical and defor-,.e,l lines of the valency
oacillati-)ns M-C ii.crease according t,, the geo.-rietrical ;)rc-
Kression n-1, erimental i,art the syn-
(n-aj~ ), r,-2. In the exp
thonii,q of the individual compounds ani th.,~ qd!iticin reactl,~,ns
are descrlbej~ It W"IF f 11nd in the Oynthe"31.1t that the npe-cific
effect of the Cl 3M-group (the 0-orientntion In -NI,sr1n:i*11 )n,
Card 21 the terilency towar-In a fi-decom,,,osition, ilfforont chlc)rination

Relative Reactivities of Some Organic Silicon, sov,62-59-8-10/42
Germanium, and Tin Compounds and Their Haman Spectra
rates) increases considerably at the transition from Si to
Ge. The authors conclude by thanking Bugorkova for the de-
termination of the thiocyanogen figures. There are 2 fioures,
2 tables, and 27 references, 12 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni 11. D. Zelins-
kiy of the Academy of Sciences, USSR)
SUBMITTED: November 30, 1957
Card 3/3

AUTHORS: Poiyakova, A. M., 31-jchkoia, M. D., 'iflovlji,
Mironov V .1 Kor,~hak, 'V. 7., P(--tv~-,, A. D,
TITLE: Concerning the Interac~lori uf Acetyli-iw WPA,
and Silane3. Briel' Communicat'lurs
PERIODICAL: Iz-i(.-3tLya Aka(lomll iaiul(
rialik, Ni, 1,), 1)1) "Y!
ABSTRACT: Purifted act-tyleric Ir,, rf-,wtlon with
HR :)SiOs)lR,)l[ (Wilul,(. H = (,'I[, arld C if,
pressurfi-, In X -~~I(woplil ln',
propanol ur plat. trilun uri -arbori, ga,;t
form of thick olls. IR ~3pt2ctra ,ind
data Indicate that th(-. muterr-)i-ioleclil-3
me rs 113 1 S tc) i r 1:3
Card 1/3

Concerning the Interac,jorl cf V-AY11:1,"
W.,t~-, Slioxanes and Sl-
Card 2/-)
yme r s
po
meth-11-
il T'C
under a'
platirlic
me t ny i '-karle
j;
C
1 d r,' or(' "i
in 9%
a r,,y r
'inu,
m
'"Ov I e' r"f

Concerning the Interaction of Acetylpne 77097
With Siloxanes and Silan(--3. Brief SOV11,2-r 9-12,-J~1/4
Communications
Chem. Sac., '(8, i0_1
,fj (jg,)6 ; J. L. Speler, D. B. Hook-,
U.S. Pat.
ASSOCIATION: Institute of Llemerito-Or-anl,, Compolinds, Acadi-rij of'
Sciences, USSR, and N. D. Zelinskly Inititut(- of'
Organic Chemlstr~y, Academy of' Science.9, UISSR (Irlsll-lfl~t
elementoorgaril0iesklkh soyodinenly Akademll nauk.
i Institut orj,anlch(,skoy khlmll lm~~iil N. D. Zelin3;-~Gl-c
Akademii rviuk L;2SR)
SUBMITTED: May `5, IT)')
Card 3/3

- MIWOV, Vladimi-p F.
Synthesis and charactoristios of allylaubstituted ethylone. In
Russian. GI.hem.dr. 23/211 no.1/2:21-28 158/59. (]MAI 9:5)
1. Akademiya nauk SSSR, Institut organicheelcoy khimli im. Zollnekogo,
taboratoriya khimii. uelevodorov, Moskva.
(Disilabutene )

50)
AUT11ORS: Mironov, V. F-P-trov, A. D.) SOV/'2o-124-1-28/69
Corresponding Member,AS USSR, Pisarenko, V. V.
TITLE: High-Temperature Condensation of Alkyl Dichloro-Silanso With
Chloroolefina(Vysokotemperaturnaya kondeneatsiya alkildikhlor-
Dilanov a khlorolefinami)
PERIODICAL: Doklady Akademii nauk SSSR,1959,Vol 124, 11r 1,pp 1o2-1o4 (USSR)
ABSTRACT: The authors present a survey of publications (Rafe 1-4) re-
garding the reaction mentioned in the title. In the present paper
it was established that not only (CH 3)C1 2SiH with vinyl chloride
is condensed at 600 0 to give vinyl methyl-dichloro-silane but
that also (C 2H5)3iCl 2H with vinyl chloride gives vinyl ethyl-
dichloro-silane in a 27% yield. This was possible not only in a
glass tube but also in an iron tube without considerably affect-
ing the yield. Trialkyl silane,however,cannot be condensed with
vinyl chloride as this reaction proceeds according to another
scheme. The author further- found that the condensation of
(CH3 )Cl2SiH both with cis and trans-dichloro-ethylene gives
the same results, namely 20% yields of C1 2(CH3 )SiCH-CHSi(CH3 )C12
Card 1/13 (structure proved by means of methylation and Raman spectra

High-Temperature Condensation of Alkyl Dichloro- SOV/2o-124-1-26/69
Silanes With Chloroolefins
Card 2/3
taken and interpreted by L. A. Leytes and Yu. P. YeKorov).
Irrespective of the fact whether methal~yl chloride or
isocrotyl chloride wan used for the condehsation~,
C12~T3)S'CH - C(CH3)2 (about i5%),small amounts of
C12 CH3 SiCH2C ~ r. as well as a mixture of xylenes
3
were isolated on the whole. Allyl chloride can be condensed
also with methyl dichloro-silane and forms (30% yield)
allyl methyl dichloro-silane. A small amount ( in the
iron tube a larger one) of propenyl methyl dichloro-silane
is then the result. Chloro-aryls can be condensed in an ana-
logous manner, but the saturated halogen alkyls are not able
to condense with hydric silanes. Surprisingly, (CH,)Cl 2SiH
reacted with ethylene, mainly vinyl methyl clich-loro-ni lane
(14% yield) was formed. A condensation of ClCF ~ CF2 with
(CH3)C12 SO M"as flames and a detonation broke out in
0
the tube above 500 , thus often causing the t(ibe to be destroyed.

Hiph-Temperature Corderf-ition of Ali-yl Dichloro- S--V, 2o- 124 -1 - 29/69
Silanez Tjlh Chlorciol-fina
A f r c t ion ')7 - 1000roul,4 however be innIrited which
proh'O'lly (irv:c~)r ' inj~ to W, f3pectrum) cont I m3
SiCF - CF T ere -tie 10 refereices, 6 if whicl- -ire
2 2. h
Sov et.
A35)CIATIOIT: Inctitut or,,anirhenkoy 'Khimii im. 11. D. Zelinnkol-,o Av"k4emil
nauk SSSR (Institute of Orv-inir Chemistry i-neni 11. D. Zellinskiy
of the Acade-y of Sc"ences US'Sfl
SUBUI'Y'TED: June 19, 1918
Card 313

')(2 , 3) ',-V --- - :P 1~?
AMORS: P,~ trov , A - D rr- -,. n6 , rqz, Ve L; n,i r
Dzhurinskaya, .11. G.
TITLE: AddiLirn of 'Fri t~, Acvtjl-~ne, L.11~ finc~l 1,d Their
Deriva. ti vt~s in the Abnenct! of :a talys to
PERIODICAL: Doklady Axademii nauk 33~3f(, Vol ir 301~- ~C
(US3H)
ABSTLiACT: On the baBis of t~ie putil ication sLrvo-~ (Ilefs 11-, i *I,e
pub! I catiun a by V, A. I -rionar(-nko qnd G . Ya . Vzen?ov a 'Acf 6
the authors state that - contrary to other as3ertir.rIS tjj(!
addition mentione-I in the title procueda vi,-orou3ly and under
conuiderable evolution of heat, immediatelj after mixing the
coml,onent:3 alreadj at rr-)(,m teml,t~rature withcut any catalysts
and initiators ThIla refers t(,, olefines (1,2) (fron et~ijlnne
to r)ct(:no-l), Fjf-etjlow~, irrylonitrile (4), ally! a2e-
tate (6), alljI cKloride and me''ha!lyl even vinyl
chloride and A similar
aAdition of' trialk,-l n1lan*29 to methy! rt-ryliite lescribed by
A. D, Petrov axid S I 3ac!ykh-ZadP (slof c)) it; mentioned.
Card 2 lable I indirat(~3 the ,ields a.,11 pr:,,-ertie.,i of the -,)m;,)unds

A d -~.i ti On c f I r I c r 3 c-- 1 V P
t he A b .3~- nc
b t~i r t f 1
tj tri
rm
+
-% .-,
r -j ~t, me friv
he h :,I I t I ri L'o III w,,j I q .11 E- T ;I~rjf
V t I I tit t ~t
: "i
i~-ci. r
t r r~
t i t :I, t t U,. I y9 2 1 1 Ic "x-
c t- ti 1 1, -tit 7i r Q'I":- ,jn(ii t s Thu
lot'.
r'V !It ~,A t +
r (ri c i ri n I, L: t i t han r- i n -o-. tn., Th~~ ro
ri 7 r r t,- j it c, a i,-
A5~~UC IAI I Pt L rl E L I t m ::I
n a u k. S j r"
f "nt, A- i m 3' A
Car

8308
AUTHORS: Korshak V. V.,
Mirongj,,_~j 6
TITLE: Polycondensation
SilanesiUnder tho
S/190/60/002/009/009/019
B004/BO60
polyakova, A. M , Sakharova, A. V,
Chernyshev,_1qA_L_
of Halogen Alkyll(Balogen Aryl) Halogen
Action of Metallic Sodium
PERIODICAL: Vysokomolokulyarnyye soyedineniya, 1960, Vol. 2, No. 9,
pp. 1370-1374
TEXT: The authors carried out condensation reactions with the following
five compounds: ClSI(CH 3)2 CH2Cl; ClSi(CH 3)(C6H5)CH 2cl; ClSi(CH 3)
(C2H 5 )CH,CH2CH2 Cl; ClSi(CH 3)2C6 H4Cl, and ClSi(CH 3)2 OSi(CH 3)2 CH,CH2ci~
The reactions took place in nitrogen current with metallic sodium sus-
pended in toluene as a catalyst. The molecular *eight was cryoscopically
determined in benzene. A table supplies the molecular weights of the
condensates, the polymerization coefficients, yieldejand silicon content.
Thp temperature dependence of the viscosity of polymer [-Si(CH 02 CH 2-1n
Carr 12 ~k

83478
Polycondensation of Halogen Alkyl (Halogen Aryl) S/190/60/002/0O91009/1019
Halogen Silanes Under the Action of Metallic B004/B060
Sodium
and of polymer [_ Si(C6H5)(CH3)CH 2-In is illustrated n a diagram. Despite
a lower degree of polymerization, the presence of the phenyl group gives
rise to a higher viscosity. The authors analyzed the resulting compounds
for the presence of -Si-Si- bonds by treating with concentrated potash
lye and piperidine according to A. P. Kreshkov's method (Ref. 8). No such
bonds were detected in any of the reaction products obtained. The authors,
therefore, assume a succession of -Si-C- bonds. There are 1 fi" re, 1 ta-
ble, and 11 references, 4 Soviet, 6 US, and'I German.
ASSOCIATION: Tnstitut elementoorganicheskikh soyedineniy AN SSSR
(Institute of Elemental-organic Compounds of the AS USSR)
SUBMITTED: April 4, 1960
Card 212

816M
5-5700
S/062/60/000/04/06/006
BOO4/BO66
AUTHORS: Mironov. V. F.. Shchukov8kaya, L. -
TITLE: Relative Reactivity of Some Alkenyl SilanesiDuring Their
Interaction With Trichloro Silane
PERIODICAL: Izvestiya Akademii natLk SSSR. Otdeleniye khimiche8kikh
nauk, 1960, No. 4, pp. 76o - 762
TEXT: According to Refs. 1 - 3, hydrosilanes were added to vinyl and
allyl silanes under conditions which required the performance of the
reaction in an autoclave. The authors used the catalyst of I. L. Speier
(Ref. 4) (0.1 N H 2PtC1 6* 6H20 in isoprop&nol). The reaction could thus
be carried out at room temperature in a Glass vessel. The relative
reactivity was investigated by allowine equimolecular mixtures of allyl
and vinyl silanes to react with an equivalent trichloro silane, and by
determining the quantity of the reacting initial substance. The follow-
ing was found: Vinyl trichloro silane reacted to 60%, allyl trichloro
silane to 40% only; in the case of Cl 3sica--CH2and (C 2H5)2CH3 SiCH--CH 21
Card 1/2

81600
Relative Reactivity of Some Alkenyl Silanes S/062/60/000/04/()6/006
During Their Interaction With TrIchloro Boo4/Bo66
Silane
the former compound reacted to 23%, the latter to 77%; in the case of
Cl3SiCH2 CH=CH2and (CHA) 3SiCH2CH=CH 2' the former compound reacted to
60%, the latter to 40; The accumulation of chlorine atoms at the
silicon atom thus facilitates the addition of trichloro silane to
allyl-substituted silane and inhibits this reaction in vinyl-substituted
silane. A table presents the ten compounds synthesized for the first
time and their physical data, among them &, W-disilyl ethanes which were
obtained by addition of hydride silanes to various vinyl 81lanes and by
alkylation by means of RMgX or ArMgX. The authere refer to papers by
A. V. Topchiyev et al.(Ref. 2) and A. D. Petrov et al.(Ref. 6). There
are 1 table and 6 references: 3 Soviet, 1 Japanese and 2 American.
ASSOCIATION: Institut organiche8koy khimii im. N.. D. Zelinakogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D,,
Zelinskiy of the Academy of Sciences, USSR), Institut khimi
silikatov Akademii nauk SSSR (Institute of Silicate
Chemistry of the Academy of Sciences. USSR)
SUBMITTED: August 19, 1959
Card 212

KARTSIV, G.U.; SMIN. Ya.K.; MIROKOV. V.P.
Dipole moments of oome germanium organic compounds. Izv-LN
SSSR Otd.khim.nauk n0-5:948-949 My '60. (14IRA 111:6)
1. Institut tonkoy kbimicheskoy tekhnologii Imeni M.V.
loomonosova.
(Germanium organic compounde-Dil-.,ole moments)

82693
S/062/60/000/008/007/012
00 B004/BO',4
AUTHORS: Vironov, V. F. and Repomnina, V. V.
Synthesis of Alkenyl Sillnes by Addition of Methyl dichloro
TITLE: I
Silane to Diene- and Acetylene Compounds
PERIODICAL: Izvestiya Akadenii nauk SSSR. Otdelentye khimicheakikh nauk
1960, No. 8, pp. 1419-1423
TEXT- Other investigators (Refh6 1, 3) arrived at the concluaion that tri-
chlorosilane and methyl- or ethyl-dichloro silane are added to butadiene
in 1,4-Position only. The authors found that his also applies to the addi
tion of methyl-dichloro silane to piperylene.iThe structure of the reaction
product could be established by the identity of the Raman spectrum of the
compound obtained in the following two ways;
Card 1/4

82693
Synthesis of Alkenyl Silanes by Addition 3/062/60/000/008/007/0'2
of Methyl-dichloro Silane to Diene- and Acetylene B004/BO54
Compounds
CH CH-CH BCH
HC 1
2 03PICHCH'CHCH~
CH 'CHCH-CHCH CH CH
HSiC ZCH VFC.
H H
3C'2 iC121
CH3CH-CH%CH 3
Instead of platinum on oarbon, the authors used J. L. Speier s (Ref. 9'
ca t a ly a t f or tha ir syn theses, and thu 9 aou Id work und er al I d cc nd 1 t i r~ F, ~-3
at atmospheric pressure. With addition of methyl-dichloro aiiane to d1a:1y'
an isomer with a different position 3fthe double bqnl is formed besides the
6-heienyl-methyl-dichloro silane expected, which Was established by means
of the Raman spectrum after methylation of the compounds. Purtherl the
authors performed the following sy-ntheses: addition of methy,dichlore
silane to phenyl acptylene-,l
Card 214

82693
Synthesis of Alkenyl Silanes by Addition S/062/60/000/008/007/0'2
of Methyl-dichloro Silane to Diene- and Acetylene B004/BO~4
Compounds
C H C ~CH + HSIC1 CH C H CH-CHSICI CH CH 3MgCl , C H CH-CHSOCH
6 5 2 6 ~ 2 5 b ')
The 0-(trimethylailyl)-styrens thus obtained differs in its Raman spectrum
from the a-isomer produced formerly (Ref. 17). Besides, the 0-isomer %as
also produced by means of organomagnesium reaction (Ref. 18); here
C6H 5C Sa Csi ( CH3)3 van formed as a by-product. The addition of methyl-di-
chloro silane to nexine occurs with the formhtion of the a-isomor onich
was identified b.- the Raman spectrum: C 4H 9C ~_7H + MCI 2CH 5 -4- C4H9CH
.-CHSiC1 2CH3 --* C 4H9 CH.CHSi(CH 3),, Further, -,ne reaction van Oarried out
with ethyl-dimethyl-ethinyl silane, C,H (CH,),31C =_CH + HSiCH C"
C H ( C H ICH ci CH3MgCl C H(CH ) 'ICH-CHsi(CH Y The
2 5 3)2S'CH'Cl": 3 2 2 5 3 2 5
physical data and the Raman spectrum confirmed the structure of this com
pound as a 1,2-disubstituted ethylene (Ref. 2). The addition of
Card 3/4

32693
Synthesis of Ukenyl Silanes by Addition S/062/,- 00C/009,ioo-~-?
of Methyl-dichloro Silane to Diene- and Acety-,~ne B004/BO~4
Compounds
mothyl-dichloro ailane to isopropoxy acetylene io aloo mentioned. The
silyl group is always added to the C =-C bond. The authors thank L._Leytop
for taking and analyzing the Raman spectra. There are ?~ rnlf~ren'As;
15 Soviet, 10 US, and I Pritiah.
ASSOCIATION: Institut organichesk~j khimli im. N. D. Zellnskogo
Akademil nauk SSSR
(Institute of Organ-,- Chemistry Imeni. N, D, Zelinsk,,.y of
the Academy of Sciences, USSR)
SUBMITTED: February 27, 1959
Card 4/4

.117 0 12o,3 17- $10 'ZIN
86480
S/C)6 6 C/C,-
BOI 'ZX:C 71'~
AUTHORS: Mironov, V. F., Pogonkina, N. A.
TITLE: Relative Reactivity of CJ-Trialkylsilyl-su~stituted
Alcohols and blercaptans With Phenyl Isccyanate
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk, 1960, No. 11, pp. 1998 - 2002
TEXT: The authors study the reactivity of organosilicon alcohols and
mercaptans of the following homologous series: (CH Si(CH C11 and
3 3 n
(C2H 5)2 CH3Si.(CH 2)n SH, n - 1, 2, and 3. For this purpose, an equdvalent
amount of phenyl isocyanate was added to certain amounts rf t,,t,
silicon alcohol-methanol mixture concerned. The molar portion ~,f t~.-e
reacting organosilicon alcohol was calculated by analyzing ti- 'e si.icon
content in the resulting urethan mixture. The results obtained for three
organosilicon alcohols are given in Tahle I . It may be seen from therr,
that trimethyl-silyl methanol is 2.5 times more reactive than methyl
alcohol, and about twice more active than the homologs comin6 next to it;
Card 1/3

864M
Relative Reactivity of W-Trialkylsilyl-sub- S/062/6G/C0C/C1,/OG-/C16
stituted Alcohols and Mercaptans With BG1.3,3C78
Phenyl Isocyanate
0-trimethyl-silyl ethanol and y-trimethyl-silyl propanol. Als,.-, the re-
activity of organosilicon mercaptans of the homologous series
(C2H512 CH3Si(CH 2)nSH was examined and calculated by the same method,
with respect to butyl mercaptan. Results are given in Table 2. Diethyl-
methyl silyl-methyl mercaptan exhibited only about half the reactivity
of butyl mercaptan, and about one-tenth of the reactivity of the homG-
logs coming next to it and having the thiol group In tho 0- and y-pcai-
tions. The results obtained can be explained by a rapid extinction of
the positive induction effect of the electron-emitting trialkyl-alyl
group. This effect is obviously strongest in compounds with functional
groups In the a-pooltion. Tho ejeciul character of the compounds wit,
functional groups in the a-position is also obsorvablo in thou, rinfllyfliB
of the Raman spectra of the alcohols and mercaptans concerned. The
organosilicon mercaptans used were synthesized by the method lescrited
in Ref-4, except for y-trimethyl-silyl propanol. The latter was syn-
thesized as follows;
Card 2/3

86480
lr~;- f, . 0 / . . ( , , .
Relative Reactivity of :-3.1il-s S " /
7,1
stituted Alcohols and 7, t
Phenyl Isocyanate
CH -CHCH C CCH
2 2 2 2
In view of the hitch jiel:,, ai-I j
to be better than the one iescri zed L:, ~o2 f 'he '-a-Ta.,. qii?~'tra were
taken by L. A. Leytes wit!. ar, OC7-1 ' :,si -i
2 tables and 8 references: I S.vie't and I "'S.
ASSOCIATION: Institut orL;u,-,1:,,1,eskoZj khimii Jm. Zei--isr:c6c,
krkademii nau~: SSSP ~:.-isttutc of
imeni N. D. Zi:linski.,- of t!-~e -f Soie~.ccs '~'SSR,
SUBMI'.-TED Y ay 2 1
1
Pard 3/3

SV06 2~_C
0 3C'
AUTHORS: lliroa~~T. F. , !,akslmo', F-,
TITLE: Synthesis of Uns:.turate~ Crgancsiliccn Czmpounds on
Propargyl Alcohol Bases
PERIODICAL: Izvestiya AkademLi nauk SSSR. Otdeleniye khimicheskikh
nauk, 1960, No. 11 206'
TECT: This is a brief report on ~he ir.vostij3ation of t'-e c.:,nversLons jf
propargyl alcohol accordinC t,) the sc~xme attached:
RnSi (OCH,C=CH),_,, (CtH,),CH,SlCH-CHCH20CH,CH,CN
RnSicl, N
cli, - cmc.
cli.-Cticm
CH=-CCHz0CH,CHjCN ---CYl=-C-CH,0FJ- (CH,),01,SiCH-CHCH,Cll
RMgX i(CH.),31cl
4
ClsSlCH-CHCHjOCHCH,CN (V), (CH2)3S1C=-CCHOH (1) (CjH6)jCH3SlCH,CH,CM,0H
I C"'Mccl I Clif.mirer (I v)
(CHg)jSiCH-CHCHjOCH%(-HtCN (VI) Cl,CH,SlCH,CH,CH,O,CCH,
Card 1/4

86482
Synthesis of Unsaturated Organosiliccn S/06
Compounds on Propargyl Alcohol Bases 3078
Special reference is made to the order of addition of R 3SiH to pro-,ar&.fl
alcohol, which does not agree with the order of addition of these silico-
hydrides on (CH - -1 (Refs. 2 and 7).
C
3)2C(OH)C
~113 CH3
R SiH + CH=-C-C-011 --~- C111 -C-C-01f. Pro(3Qeding from propargyl alcohol , the
3 1 2 1 ~
CH3 R3si CH3
following products were obtained: y- trimethy'. silyl)pro.-arv.,/l alc-',1
(1) - -C~H- ~3-10- - -bviling -point 650-C--~ di
I 1C mm) yield 43.56-
y-(diethyl methyl silyl)allyl alcohol III) C H SiO - boiling point
8 is
99 0- 1000C(10 mm) - yield 67-%. The products of the addition of
acrylonitrile to alcohol (II) t Ir5o
yielded C H" SiNO - bcling poin C
(20 mm) - yield 60~/'O. 7-(diethyl methy. ei"Lyl)propyl alcohol (17)
C H SiO - boiling point 86'C 'q -im). Iilthough the refractf-ie index and
8 20
boiling point of this alcohcl somewhat diverGe from t~ie established
Card 2/4

86462
Synthpsi3 :-f "Insat--r-a.ed
C=pounds on PrD~arwy-'
y-(di etLy I met hy I a: 1j: I i T
the exce~tiDn of tEe .9 i r r
SiO - boiling puin. 1 1
6H1 2 1 .1 ~ ~'. I ! ' _-. ~ 3 7. 1
manner were synthesized: H S 1 C C i ~1!
mm C 117 ) s i Dc!i -1 t,
3 2
2HrSi(OCH 2 C =- C H 3 -bo 111 r,,, i nt 1 1 1 C mm
P-(y-trichlorosily! al I yl o xy , i r~) 1) 1 -,n i r i I
Point J~jCf-'C (7 :TM' / "il.- rrI(,t,,.,,:aI,,- r, , f " 1; ME" 1,a 'is t(
Y-tr' ':rj(jt!,Yl ally'. al"JI xy, ~ I oi
yield 50*;o. Th, Ramiar. s;,e, lrawer- laker; b~- L.A. L.
A. D. T~--tr~v ani L:. F. re ment'-)-.ed.
-eferer,-,-,~S.
Card

86481
Synthesis of Unsaturated CrganGs.'I~crn S/06 60/ccc/,:' - '~- * z,/-. ~
Compounds on Propar6y! Alc:h~l Bases --- 0 1 ~ Y-;~ 0 - E.
ASSOC !AT !ON: Inat' tut orgar.. -,hes k,)y kh Imi i , m. N. D. ZP I irs,. ,,-
Akaaemi! nauk SSSR (Institute Df urgar,'c Chum.-stry
.N. D. Zalinskiy of the A,~ademy -)f Sciences USSR~
SUBMITTED: April 26.
I
j
Card 11/4

86484
LUTHORS: 7 F.
T IT LE: Reaction
PLRICDICAL: T z v e a t i y a Ak ad e.,.l n a S 5 S I, J I I
nauk )i,C, N
TEXT. In this "Letter tu ~ne Edi
'icnaf allylhalides with A n--v rf-a-ti~,n
germane with a7lyl arA al.1-:1 was
I eads t-e f =a r. f a', 1 r r man a
la ";: CH, - CH7;1,X
Ally! *ri,:horctfe!-.iane nas r,
from allyl --h. -, r,, J-~ ard f :113 r a r-
'C
Boiling prjlrt 11)1-1~ 7 1- r. 8 C . If e
tc dif fer from HSa~. ly i to r, v: 'j W,
at rocm t,~mperatur- aids h- 'r, s 's 7,:5
bard 112

Reaction ~ fA I I j IH FA 1 ~ i f- aN r-:. LLnt~S fl
ja* 1I t- f q!Ln~
and their derivati vea wi a -t, t'
C11 ~CHCH Cl + IlGeCl CH Cfl,~"ecl 12 o'er H`ie-~: 1i it s
2 2 2 e
added to ally! brcmide t~.e reaction proceeded, 1~3weve:- , iccc r ii ~-,j, t
formula (1). Thus, allyl trichilorogermane with a yield of -Vas
tained from allyl bromide. Alec, when HGeC1 3, was added to all:~!
the reaction prozeeded a~c-)rding t~, formula I) prov4ded ty.19 sag dc~--e
in ether. The yield in this case amounts to 17'7'0. 'it -.s n.)tvd a
similar reaction -,,' HS:C75w,,',h a:li, -1-cride has ~,-ei-. krjwri r.
nical literature ',Refs. 4 and however, it takes ~Ia-le only, at iery
high temperatures \'6CCOC) in the gaseous phase, whereas the above-de-
scribed reaction took place Ir. the liquid p-.ase at roGm ~ez-.~erat-;re.
lhere are I Soviet references,
T
ASSOCIATION 7nsttut organicheskoy khimi: Im. N. D.
l l I -
Akademii nauk SSSR /T natitute of Organic ',hcmistry
Imen'. N. D. Zelinskij ~-,f t~.e Academy ~f Scien,-,os 7SSR,
SUBMIT"'ED. A 2,, .
'lard 212
1

he
IJ

I t)6
t n e -4 : a
f.1 ri~i T
-r.e "r es t e I T ir
I*~ I 'r, 'r . t I f I
1 c, r iJes I t waa fo,,n I t t i e r
i ne h i i e 19 sa f f ri 1 m ie
-r id e ~,3 The k r. r
~jy r r i r;i I f. 3
t h
Air

P-7166
Synthesis Unsaturated Drgar. -ou, in !s 3,
by Denyd roch I jr 4 na t i ;r. ~, f r 'e.
rf- -'r
evi I ently mi,st, j. I it f' fr-m -,mi, :,e
c 'I-,ro-s i !;Ine type h I -, r,, - e
h chlc-r,-, LJ lane split :iff 11M 7u cK e~;,i rp I iy in J (- r
;~iperidinr- (y-chloro-alkyl) q I I ~n err. lor ide.i ~,e.,i;~v-i
dependence was observe] jnler *~.e ;tc i r, f i
'i t ~:i ~~ 'I es -t r. Jrf P r o!, c P.-I
r
t ~.t, zt
-3. ~r:y . T%e
r
ASZOCIA-IOTT: In t i1ii

AUT17ORS --I., rny3:.ev, Ye . A. rono v , V. F.
T '17 LE ':ew Methol for t~.o Pr-~arat ion of jrg%nos
~~y Figh-temperat:ire Conlansation of
Ary Is ani Ole f ins With Hy,] ros i lanes
lenote silaneg in whi -h the sili ~on
uns,Ab9titutel hydrogenN
:I icor. Ycr, 7-Prs
Alkenyl Ch'.~rlieil,
~Ex; reso i-)t. is-1 t
1 7-
PER IODICAL Izvestiya Akademi4 nauk SSSR. Otleleniye
1960, No. 12,
TEXT: The present publication treats t,.e invpstigati,)r~ , f h i ~7,,. -e 7-, e ra tr-
condensation as a Meth0J 3f preparing )rAfinoti il mni.- ro. 2 r
the synthesi s of v iny I s i 1:ine ,:. !'Dri Je.,) ',' t.e eX;,re3S 1
is -inel by the author to Jenote that all av~iilalrle hylr,),-Rr,
,silicon are replaced by chlorine~, was Inveloped at the 11 0.- r it t -ir I yik 1,
u f7l e vod o ro d ov Ins t i tuta organ i ~,hesknj kh iml 1 AN' SS3R ~ Lal-ra t -,r,, -~ f
~!ydrocarbon Chemistry of the Inatit,ite if Organl.,,~ ~hem-'-try AS 'S ~7R
practical rpalization, however, meets wit?-. Jiff'cultiezl. F--r '.h.s rp i
I
'lard 114

New Method for tile
Monomers by f1i gh- tempera tur e
Alkenyl Chlorides, Aryls ani
P7167
Conlensatii)n f no 0
'Iefins With
.3;1i:.e time ~tnother m~ '.h,- 1 -~he r. -il
h i gh - tempe ra t ur e (-. oni ensu t i or, , b!, 9 1 nt7 t,,p r .9 tudy o r, pul i C ~ ~ i r,:~ , ....
C. L. Agry (Refs. 4, 6) - In this investigation, whi-n was start,,J i r, I 'i"
the authors tested the general valility of the reaction Jescritei ty Ap,,r,'
and extended it to complic~,ted hylrcsilanes (Refs. 0, 0 1 - 1 ' , . The im -A 1
conditions for this reaction were founJ to be 1~0-")O 7 a 7 -
of 20-25 sec. The simplicity f the reji ired apparitun, P s i
materials , safety FirA high yie' Is ren ler tr-, -, q roar t i cr. r.P r,f
* Pn J. ent -)f t he e x i F, t I rq-, me t hr, I o r ~iy r, ti.es 1 z i n;, v i n,- I r. e 1 r,. d e ...e
* u t horn s tu i i e,J t lle h , h - t em[ er it t. -i r P 7 onJ er, s ~i t 1 r; h , t h i r.,.- r i I f-
the hyJrosilanes c)f t'!P serien iiS 2, -1 Y e
a n
I ) n 3 une 0' T:- e.~'
of up to 90/0~ were A-t-.-Inel with tric~.I-lr
(n=') gave no condensation reaction 'Fil,. I This compo,.iri --lave a J, f f er -?
reaction which the authors termeJ a reduction to 14 53tir.,Tu:sh i* fr-),.~ tl- e
cor.densatior,: .9 SiR + 71-H=7F, --4 R S-, ZH~ -E The
e -4 P 1 e
-arl '/',l

q716 7
e 7. t n j f - rt ~-e prt.:
Mcnomers by H igh- temT er,. r~,
Alken,71
Hyd r - -
C, er re
;i I t - jstitute -h e r
.yr, hes i z i n,-,, unsatu r:i -1 1~c 1, 0.'. me :-:j
t he re t " )n is --in ient,.rc 1y nf--,h -nuy f r~n r,
A r i be d a ~3 homnl~,tit- _i,. ly: i ;,,,i r r
the synthe.91 s n f a r,,,n, i r., .3,, in -,Ml-r,~ ,
f (-,u r t ~i r- p r
50- 70D 71
nd n F-, itI R71
4
e r~, i v P r, ,.e r i
t e 10 I~us'jl P.,
i n I ic;t t, i
7arl '/','

"716 7
New for t,,~e --ir zt i
c
A Ik enj r i I
r f-, r -
r, i ),j .9 r,-,
y 1e J
_i .. ,r
Tat I e e mr, n~, I j) r- 'ir
r
i L P 1 t h ig~ier e j
,: a t a t i r e a r. t 1 o ri f -ir o ma t i f~ -A I:y r -
t ~i h I e
z e (:.Ii i, i (-),v;i k i;i r,
ASS~'-t- TA'
ri I li 1(
e r, q r
SUBMIT"'T-.:) J,ine r. te-I 3#-,. teriii~r
Car-I 4.11

AUTHORF F:- L Kh F
T~ TLE S u iy f Hyl P" f 7.!~!" Yl
'7 o rti n I
S k - "I I
FERIA,', ',Al,i I z y I A kI
n aU K, ' '1' .~ ,11
TEXT: T h L I y --
'17
hy I , rt. n I s r, I
CH 0 CH R 7 F S rC H H r, I CH H F,
C H C 11 F, H F H T t.
re p ~i r y Y I V t'
r) r k~ W ~W r ti. r 7,
I c n m -
Re ad n~.7 waL_ perfo r,,T i r t o r

r)r the HyJr
Al I y 1 r
-ml Tin -~r q Skele, -r-.
, * t, r- i t . :j r.
I K'
r q
77
AS' -.A"
x
JBM ITT ELI:

MIRONOV, F.-
.rnthesis of unsaturated silicon orgw-ic compounds
New method for the w
by high-temperature condensation of olefins and chloroolofins with
vilaneB. Coll Cz Chem 25 no.8;2167-2172 Ag 160.
(ERAT 10:9)
1. Inatitut organicheskoy khimii im. N.D. Zelinakogo, Akademiya
nauk SSSR, Moskva.
(Silicon) (Olefina) (Silanes (Drganic compounds)
(Chlorine)

s-- j -) 0 Oro) 688114
9(2) , 54) S/020/60/131/01/027/060
ATITEORSi Mironov, V. F., DzhurinakaZa# N* G., B011/BO06
Me rov D., C iponding Membert AS USSR
T IT 1h, I Addition of !:GcCl to 11z,.logen Substituted Ethylene Derivativea.
Dehydrochlorini-Lion of c(,A-Dictiloroothyltrichloro(7ermane
I 'ALODICAL: Doklady Akaderiii nauk SSSR, 1969, Vol 131, 11r 1, pp 9L-100
(USSR)
"ACT:
The authors investi(.nted the r,-(L'-tion of IlGeCl to varioue
chlorine substituted derivi,tivec of ethylene (f!"O*n ClC1:-C11 t o 44//
2
Cl2C-Ccl 2)' which hardly add 11SiCl 3' In tKe 1,~_,.er, the
authors proved, that trichloro6orrianeg however, to di-
chloro-, trichloro-, and tetrachloroethylene in a completely
uncatalyzed reaction. The addition proceeds under slight
spontaneous heating. If vinyl chloride is bubbled through HGeC1 3
the addition is accompanied by more intense spontaneous heat-
ing. The most astonishing result obtained was that no (X-, but
Card 1,4 only P-chloroothyltrichlorot,ermane (33P was formed (nee

6684
A(~(,ition of HGeCl3 to Halogen Substituted Ethylene S/020/60/'131/01/027/060
i'ei-i-Aives. Dehydrochlorination of o(, 04ichloro- hO11/BO06
ethyltrichlorogermane
scheme). In this connection, the sequence of the addition of
MCI to vin ridelwas investigated. It was found that
3 ll_chlo
C.
Hsicl and CIT Cl',~ill likewine, can only be added to vinyl
3 5 -
chloride b,,, -e4jctin[; in an autoclave, despite the presence of
a catvlyst ::- :,ctive ,,s chloroplatinic acid, yielding
only 6% o(-chloroothyltrichlorosilane (see scheme). The authors
have thus proved that the sequence observed in the addition of
HGeCl 3 to vinyl chloride is different from the one in tri-
chlorosilane addition. The reaction mechanisms are evidently
different in the two cases. The dehydrochlorination ofcx,o-
dichloroethyltrichlorogermane was effected both by means of
uinoline and aluminum chloride. The authors previously
efs 5,6) investigated a similar dehydrochlorination by the
N
two latter reagents for an analogous organosilicon compound,
C1 3SiCHCl-CH 2Cl. Now it was found that the rules observed then
are also valid in the prejunt.cano, i.e. that quinoline splits
Ca 1-6 4 off the A-chlorino Aoi.i, nil !liviinim chloride the (X-clilorine

6881L
A,'dition of HGeCl 3 to Halogen Subiitituted Ethylene S/020/60/131/01/027/060
Derivatives. Dehydrochlorination of ~(,A -'Dichloro- BO11/B0O6
e thy I tri ch I orogermane
atom (ace scherae), In the caz_ of o(,A-dichloroalkyltrichloro-
silanes the mechanism of dehydrochlorination by incans of
aluminum chloride was formerly (Refs 7,C) explained by re-
arrangement of the /3-carbonium ion formed, involving a shift of
the trichloroeilyl group from the q-carbon atom to the ~-carbon
atom. The authors believe that it ,;igl-:lar rearrangement mech,~nism
occurs in the present case (see ache, c-') . Ex:,eriments to split
off 11C1 from Cl 3Sicir2CHCIGeC1 3 with t!~e ~.id of quinoline only 1,K
resulted in 0-decomposition (see scheme). After some hourc,
c(-chlorovinyltrichlorot,,ermane autopolymerizes to a milky,
opaque solid (Refs 6,9). Only three of the chlorine atoms of
(~-chlorovinyltrichlorot,rern,ane are hydrolyzed by titration with
0.1 11 alkali solution. Decomposition -ccompanied by liber,,tion
of acetylene (Ref 11) does not occur in this case. The 1:ropertiorn
of the five germanium compounds synthesized f r the first ti:c
are listed in t,-ble 1. L. A. Leytes took the spectra of these
Cr--rd 3/4 compounds. There are 1 table ard 13 references, 10 of which

8
I on of H'Gecl 3 to lfaloCen i ~.jj r-( ~-,t I 10 'j/020/60 131 01/027/060
v-,.tivec. Dchydroch I or im-tion c,f c< 13--D , Ot I oro- hol 1/BC06
othyltrid,loro,-emane
are Soviot.
C". institut o-.;anic!;c.--ko,,- A i A):: 0c; j i nmik SSSH
qnstitlit') 0~ On. , ic ~ m,, : try of th,! Acadcr,, of Scici,coc,
u s s n )
"Ovenber

MIRONOV, V. F.
Doc Chem Sci - (diss) "Carbo-functional organic compounds of sili-
con and germanium." Moscow, 1961. 40 pp; (Academy of Sciences
USSR, Inst of Petrochemical Synthesis); 280 copies; free; list
of author's works at end of text; (KL, 10-61 sup, 206)

c, N L ''%! V ~-
PHASE I BOOK ECPWrPATION sw/56o6
Petrov,, Aleksandr Dmitriyevich, 71adlynir Florovich Kironovp Tasiliy Andreyevich
Ponomarenko, and Yevgeniy Andreyevich Chernyshev-
Sintez kremniyorganicheskikh monomeroy (Synthesis of Organosilicon Konomers)
NDscov, Izd-vo AN SSSR, 1961. 550 P. Errata slip inserted. 4,500 copies
printed.
Sponsoring Agency: Akademiya nauk BSSR. Institut organicheskoy khI-Ji in.
W. D. Zelinskogo.
Rusp. Ed.: A. V. Topchiyev, Academician; Ed. of Publishing House: L. S. Povarov;
Tech. Eds.: V. 0. Laut and 1. A. Streletakiy.
PURPOSE: This book is intended for chemists and graftate students of chemistry
and related fields and may be used as a handbook by engineers interested in
the synthesis and properties of polymeric materials.
COVERAM The book gives the results of the authors I research on the synthesis
of monomeric organosilicon compounds and revievs data published throu& 1960
Card I/-&-

Synthesis of Organosilicon Monomers 80V/5606
on methods of synthesis and properties of the more important and videly used
organosilicon monomers. The Introduction and Cho. 1,, H. and W vere vritten
by A. D. Petrov; Ch. III and Part III by Ye. A. Chernyshev; Ch. 7,, jointly
by Chemyshev and Mironov; Part II by 1 7 Kironov; and Part IV by V. A.
Ponomarenko. The tz-n-Miion vas vritten y R ~rW, Wronov, and Cbernyshev.
The authors thank R. Kh. Freydlina, Corresponding Nember,, AS Usal and
N. G, Voronkovp Candidate of Chemical Sciences. There are 142 references:
92 Soviet, 44 English, 1 Italian, 2 French, and 3 German.
TAPM OF COMMM:
Forevord 4
Introduction 5
PART 1. IMMODUCTION TO THE CHRMISM OF ORGANOSILICON CONYMM
Ch. I. Indications of Similarities and Differences in Organic and
Organosillcon Compounds 13
References 21
Card 2/-)v

Synthesis of Organosincon Mncwrs SOV/56o6
5. Catalytic synthesis of arganosilicon compounds in the
presence of metal halides lu4
6. Strength of the Si - H bond 108
References 111
Ch. V. The Reactivity of Organosilicon Compounds With
Carbon-Containing Functional Groups 116
References 140
PART rI, SYNTERSIS AND PROPERTIES OF
UNSATURATED (ItGANME=09 COKPOUNDB
Ch. TI. Methods of Synthesizing Unsaturated Organosilicon Compounds 143
1. Direct synthesis of alkenylsilane chlorides 146
2. Synthesis of alkenylailanes by the method of high-temperature
condensation of hydrosilanes vith olefins and their halogen
deftvatives 149
Card 5/10
2

Synthesis of Organoeillcon Monomers SM/56o6
3. Synthesis of alkenylailanes by combining hydrosilanes with
diene and acetylene compounds 155
4. Synthesis of alkenylsilanes by splitting-off BC1,, Rv.- No,
and halogenes from organosilicon compounds 161
5. Organometallic methods of synothesizing unsaturated organo-
silicon compounds 175
6. Particular methods of synthesizing alkenylailanes 181
Ch. VII. Chemical Properties of Unsaturated Organosilicon Compounds 184
1. Reactions vhich take place by addition to the multiple bond
of alkenyloilanes 184
2. Polymerization of unsaturated organosillcon compounds 205
3. Reactions of &Ikenylailanee vhich take place without addition
to the multiple bond 212
Ch. VIII. Physical Properties of Unsaturated Organosilicon Cooqxmnds 217
Ch. IX. Synthesis and Properties of ADEenoxysilanes 225
Ch. X. Synthesis and Properties of Organosilicon Compounds
Containing a Triple Bond 231
card 6/ #
7

Synthesis of Organosilicon No rs 807/5606
1. Methods of synthesizing aWylsilanes 231
2. Properties of alkynylailaws 235
Table of unsatwated organosilicon compounds 240
References 281
POr III, MMODS OF SYNMIZIDO AROKVIC AND
ALIPEMC-AROKATE ORWOSILICON MONONKRS
Ch. XI. Organometallic Methods of Synthesizing Aromatic and
Aliphatic -Ariamatic Orgwwallicon Monomers 293
1. Organowagnealum synthesis of aromatic organosillcon monomers 296
2. Production of arylalkoxysilanes by orgawmagnesius synthesis 307
3. OrganoUthium synthesis and steric hindrances during the
organonetallic synthesis of organosillcon monomers 309
4. Organosodium, synthesis of aromatic organosilicon monomers 313
5. Organozinc and -mercury synthesis of organ6silicon monomers 514
Ch. XII. Synthesis of Arylbal allanes by Interaction of Hydrosilanes
and Chloxv no- and Chlorodlailanes With Aromatic Compounds 315
1. Interaction of hydrosilanes vith aromatic covqxmnde in the
liquid phase 315
Card 7/1S

2)'975
AU'LHORSt Yegorc7, Y,,P.,
TITLE s A cc)zpaxative atuJy Jis~,er8l,)ri
spectra of aiky! 6.1-a.,Lte, and
a t annat e a
PIM10310VAI: Zhurnal str-aktcrn-y v. no. 5:
562-56b
TEXT i This to a oantinuatiar. ~t studies, In wtAl.,~ h
the wAtiiora Investi6ated tae ape-.'..ra --f s'.mllar carbor. and
siJL.I-,;cjii comFcunde and showeJ na- a- atom '-q affec*el by
double bonds wrUcr. are in a".i tz~a! in te~ra--
substituted ailanes the dc~ rc'16 Interact
witn eacL, Dtner. This leads t~-. e in 'A,,e vibrational
a pec '..r a -Jf *,he se compound a cf i~, :-e 5 w.-AI --n are per -
-t-Ine%t to e a,,; h sub at It ut;n6 6;-,-A~' Li -i:j a -,Kery- ~-r aryls
Card 1A

0 A)., C";
Ir, t,.e ~reuf'r". 5-.~dy' trot :Lt j:';:-
s j ec tr a of 3 a i ~~Yl y
stur-,.atr- . It w a g f -),,Y-,d tr. at ti a
Sr;. a*"jm
J.,rl tltle Of FA a! atJM, tLf~
rislr,6 adfjitLr~l'ally witn tz-.e r 3 y
atom witf, ti-C
trJ21 cl).-'alats of a
whiw~ lti,ei.,18 j.,, tite vibruti,..rs ;It -,]I W % A.
:' k q- A e r, r, I.,: ~) iAr e 1 1) w fi r e ti j-it ~l
uf trie atom IA witri an al.j i -'l1 ti"lefq
-Jr- the seris~s 8-1,
to the C = C bond geome-
tri,,al prcgres-iioa. ln the crest!--' -,v,--x, 'r,t~ 4uttv)rs otildit-1
tne comt,ined dispersion 8p ctrE% jl
'C D, CR;. GH
-' (;H-"IL 14.
0 H 0, H ("r e I ;e Qu 'Iii j CH
3 2 2 3
G ar d 2 16

3/1 )2/c,
A comparative study ... D;;-)02/D504
(CEY3 - Sn - C"2 - QJ1 - 0"2' They u'"~) Um
investi6ation of (CH ) G - CH.2 - CH - '12- wn!;n was
3 3 e-
reviously. The OD spectra were obtair,ed on tne apparatusWC11
SF)-51 with a medium camera; frequercles were checked witn ar.
N
Fe arc spectrum on th,61434 ~IZA)-~- c,cimparatorl t-e :aaxl.:aum iine
intensities were determined witnt4i$~LIF)-2 and MF-4 aicro-ptoto-
metere, by a method 6iven previc)tisly; tne inter~sities te-ln6
expreased on tnj cyclohexane s,~ale, tjiat of cyclonexane lines
maximum. 802 Ca was taken as 250 ur~its. As a control standard
the authors used tile (GH3) 3 - S' C" - QH2 spectr-im
which they determined precisely Fcr
the intensities Ir. respect of ar~ equall ,.umoer In
tne disperBin- voi,,Lae tney ,.ised
d where I -La r ar. e-j.al
0 0 c 7d (11 Ido r'sity f~'
,~ular number in the dispersir-C f r a
Card 3/-,

uc.-
:j- o.- "D 04
v, *-~~ae ar-A d and 1, 1 1!. -
the i~ivt!s I. it, ate d .,I
mn' e~,; tar we L6nts of
auti.ora also determ-Lried ti-C
m,.ist intensive OD lines vy I si '..7-
sing c -)mp -) irid wit- a cylina~,r i .:a. :,c~
ai,iat u~-re ,only sem,.quan'ita* ~Iv~; 3i,-- 'I-- ~-f . .
V e s t6k t e d r; omp u u n d a u r e k, 4. v wv L ' ,. I -. f~ ' - ~ 1' fr:
for intensity
mo, C- Le~ in trle di3persir,6 vDI "t, Ass-~a:-!~b trat /~ j~a- -i:-, -isf
tile 1,6H M -* CH, - CH = CH, typt r)e'.~~n6 *,u tae spa!~er 4r,.,-p
3 3 ?- C-
03V an d exriibit two symme tric; f cL', if A j
and ~2ne c)f ti,e E type, '.he wAt..,)rs "."Ie
of these frame vibrations, th~- tne-~r
n
.dard 4/6

2P')75
8/1 )2/61/002/~.)OS /CIJ2/OQ~~
A comparative study ... D202/D304
maxiaa, the integral intensities and tae de6r-c )f depolari-
zation; the inte6ral intensities aredeter;alneci un the ISP-~l
apparatus with an additiunal FBP utta~~n:aent L.A expresied in,
the cyclohexane scale, tne inte6raL cylclo:iexane ,ine i0l-, c,:i
being taken as 500 units. Tne res',i_11.3 are blven in a tut-~e.
Tne following scheme is propceed for tre cfcL;.tes in aI_y! 6er--
manates frame vibration frequencies, tak;.n6 ~Iace d,)ri'.,'6 ne
ch"ge of ayametryt (C Ge -4 'CH,3 ) 3 Ge
Tel 03V J'3 ) 4 C"2 - r"H C"12
- Ge - (GH2 - CH - CF. -4 ~H3 Ge GR2- CH CH
'CH3 2 2 2 2 3
2V C 3V
Tnere are 4 tables, 1 figure and 22 referencest 13 Scvlet-
bloc and 9 non-Soviet-bloo. The references t,,e, ~ mos'. re-
cent EngI i sh- language pub._'r_,at_Jc.,-,s rea.d as fc-11--wai W.F.E41i;e1l,
Card 5/6

~75'
1 /0 U C"
k c~-ij;arative study . . . D 04
C.H. Ward, J. Amer. Ghem. Sj- L.N. WL,! r s,
L.A. W~~,)dward, Proo . Roy . B( i D.P. Crli~--'
J Gnem. Soc - 31412 (1)54) ; i - Ci-a* W-"
4403 '~1954)
A,33u~~!A.'IJN: s t 1 t u t u r, ar. 9,,, if. D
0 SSSR '~ In s t i t u '. e f Or 6ar.. ~ C.
AS T.;SSit'?
S U B 1, L~L" 11 "ED sNcvemo,-.r 18,
Card 611-

MIROHOVI V.F.; NEPOJINA, V.V.
Effect of the character of the silyl group on the rate of dehydro.-
chlorination of some t4- and V -chloroalkychlorosilanes by
piperidine. Izv.AN SSSR.Otd.khim.nauk no.5s920--921 My 161.
(MIRA 14-5)
1, Institut organicheskoy Wadi in. N.D.Zelinskago.
(Silyl group) (Silane) (Piperidine)

3/66 61/000/006/023/081
D205YD302
A'MiORS., IMironov, V. F. and Nepomnina, V. V.
TITLE: The rearrangement of