SCIENTIFIC ABSTRACT MIRONOV, V. F. - MIRONOV, V. G.

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• Collection: Scientific Abstracts
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• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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MIRONOV, V.F.-, DZHURINSKAYA, N.G.; PETROV, A.D.
Reaction of alkenyl- and alkyl germanium chlorides with hydroVen
bromide. Izv.AN SSSR.utd.k~im.nauk no-11:2095-2r98 ,j 61.
(MIRA 14:11)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN S~-Sll.
(Germanium compounds) (Hydrobr3mic acid)

AUTHORS~
TITLEj
PERIODICAL
S 3 9
A
r, e T,-. an -F N x.~ V 7
L!zg---.:)v, S.A.
Rea:)tiw. -.,' a-*.r, e*.ny-
'b a n 7 e n e ELn a , r tL T : r -Y na a r p % .9
Zr..;-na. PrItif.air. y Kt.'n r 40~
TEXTi 7- -z:
14'. an e tLn i m- 4." -3
-benzene3 -,r. ._i a
d i h i !r
a t
e
r ei

R e a 0 t r! ~ f v 1: A
pr a a ont, -'r.-. *-a I. 1kr
b on z or, P r h )m La
H B'I,
benzene -r i-, -j:t I ~ ~- i s ~ ' a r. r; -i F3 a -1 A P%r.7y p-, a' :-,I
Eng. Chem., 51, 91 1 ~l y y
than ir, *,hb f-':F!l lydrLie anj xL:-y-
hal!dA rps-4 _'n iraoa ;a irasi, a, ~x eTt.;~rf 'n f. v-'rg 3yatema
at 5000--'CC^' Ref e Yl . A . y 3 r, e - s' . DA-15 SSSR i - ~l
Ref 9 1 -'b ltd 1 R A~L_ Pe,..~.. f. % it. ~,,4
(1959), Rof I'. V-A F t Tte
present expqrizqr.~.s WE r r m; a: f, :f ar)
y. e
chloroei:unap and c 'he
occurred in a rctating s*.etj_ '.aje r a IfF mi : r. en a was
1 j I with 0.' weight f a t a". y a t an d :,r t a -- t me :-, h., at va-ry.ng
temperatu.res from 230 The reaulta ~Fig ;.rdl-a'e the h-'ghe-
activity of methyldl_n'...r~,9 ar. u _' r. - r mp ar I a or. I , r I lh I o r r, a : ar. e Thle
is in agreemAnt wlth 7buervat.,.-nq '.r. Rpf ', bi, J'.Ffers fr-:m the stalemnn.
Card 2/5

S/15491/0 34 /002 ~022/02 51
Reaction of silicon hydrides .... A057/A129
given by N. N. Tishina et al. (Ref. 51 "Khimiya i prakticheakoyeprimeneniye
kremeorganicheakikh soyedinenly" ("Chemistry and practical use of alliconorganio
compounds"), I., Izd. TaBTI, L. 91 (1958) that HBO has no catalytic activity fw
reactions between trichlorosilane and benzene. Spehral analysis demonstrated
that the obtained arylahlorosilanes contained: 10 - 90 % ortho-, 40 - 60 % meta-
and 30 - 40 % para-isomers. Characteristics of the obtained arylohlorosilane
are presented in the Table. Chlorination and pyrolysis of the arylahlorosilanes
to styrenes were carried out by methods developed by D. W. Lewis (Ref. 12: J.
Org. Chem., 23, 1893 (1958))- At the present time the authots investigate the
third method of arylahlorosilane synthesis to compare the yields of the three
methods. There is 1 figure, 1 table and 12 references: 10 Soviet-bloc and 2 non-
-Soviet-b~oo.
SUBKMED: May 11, 1960
Card 3/5

S,'02 " '61 `1 'P OC~ 025
25-A5 B 10 11, 321
AUTHORS: Dzhir.'rskava. 1: irsnov, V. F., -an' Petr~v, A.
TITLE-
Pr-9 10D I C A 1, Akaiemi~~A n;iuk 3.:SR. Djklal.;, v.
TEXT: Tre aj thors haJ a I rea dy f u ~-:J , Re DAN, 12 8, ? V,
% e JJGeCl ca n n P -i I J e d
Ref. 2: DAN, 151, 98 (1960)) that trichloro german
to prac t ica I ly any unsa tijr~, t ed com;, o,jnd w i t no,i t hc t i va t i )n anj w 1 t h(-u t
catalysts: I I
Cl GeH + C - C ;e(;
3
Hence, they conclude that HGeCl 3 1 n th i s reac ton ~.aq a o~ ~ wher reac t i v i ty
than HSiCl %hich can on17 be aJded under harder condit,.ons and in tne
presence of catalysts. In the present paper, the authors Jescribe the
addition of HGeCl 3 to a series of other unsaturateJ compounds (Tahle 1,.
Card 1,,7

25 A5 91; 0201 () ?,I ~H, 001,, 01 , '02
Addition of' germarium hydrides 10... B10-j/B21r
They found that the production of propyl trichloro germane ri-.-3 H,GeClx
by this method is much easier than t~:e "direct" or argi_,n:)maFnesium syn-
thesis. The addition if HG,,.*Cl5t) cYclot)entadiene is vigro,is %tiereas
HSiCl3 could not be adde(i even ~y bo:.ing in the presence of H 2Ptci 61 T~
determine the relative reactivity of hydrides otner tnhn C1,14H, the authors
produced (C 2 Hl~ MH (%i tf, M - Si , Ile, ind Sn, by reducin.- trie corresponding
(,2H5)3 MHal with LiAlH 4* The synthesis of (C 2H05 GeH by the action of
C 2H5MgBr on HGeCl3 was not succesqf,il; mainly (C2 H,),Ge formed wnereas
high yields of (C H, SiH were o~)ta~ned by a simi' ar met~.cJ .The *.reatment
2 _/
of (C2H5)3 MR with 1 N alcoli,-~I-KOF qo1,iti:,n caused te juantitative escape
of hydrogen at 200C in a Tserevitinov device LA--s'.racter's note: Device
not stated.] only with: silicon ;Ani tin hydrides. The ~iber-_ttion of 114 2
from triethyl Permane was imposoirle, even at 800C. All three hydrides
(C2H M" are added t) ropar,-yi a1cinol ~tnl acr_-.e4n. S:nce tniq re;~-t43n
Card 2/7

2533$
Addition of germanium hydrides to
S/020/61/138/005/Cl5/025
B105/B215
is very vigorous with triethyl stannane, the authors could not isolate
any monomers; they only produced polymers. Triethy" germane, like
(C2H5)3 SiH, added to propargy'l alcohol only with a catalyst IIH2 PtI-16),
thus yielding r-(triethyl-germyl)-allvl alcohol; (C H 'eH
2 5 3
+ HC ~ CH2OH ---P-(C2H5)3 GeCH- CHCH2OH. The only difference f:;und between
(C2H5)3 GeH and (C 2R5)3 SiH lay in their interaction with allyl alcohol.
Triethyl silane only forms ally! hydroxy-triethyl silane, whereaq
triethyl germane already adds to the double bond thus forming f-(tri-
I
ethyl-germyl)-propanol; CH CHCH OH+ (C H ) GeH H ) IJeCH CH OH.
2- 2 2 5 3 1 -2-51 3 2 2
These two hydrides are a.so added to two different reaction centers ~)f
acrolein. Triethyl silane adds in positions 1-4. The authors repeatee
the experiment of M. Lesbre and I. Satge (Ref. '(j- C R.. 247, No. 4,
471 (1958)) and convinced themselves that triethyl germane is nct
easily added to acrolein and probRbly forms the correaT~ondinw a~lehyde.
The authors synthesized organogermanium carbosubs!ituted
Finally, they obtained the first organorermanium merc,,tptan:
Card 3/ 7

S10 2(~'116 1/1 3 a,' I ~/rj 2 5
Addition of germanium hydridx3w, B 10 3/B21 r)
P-(~-(trimethyl-germyi)-propy,-mercapto)-prrpionit,~ile The Rhman
spectra were taken by L. A L-~j!-~-s AmonF. the c,miounls bthified, the
authorsalso mcntion 0 (4 '1- i:thj . , t , *:
germyl)-ethario., y-(triethyl-germy,'-I)rriptir-gyI alconl-i, t c, k-
germyi~-propyl thioacetate, and (-tiioll-prcpy! trimeti,_, ,
are 2 tables and 10 and I ncn-'.)V1et-bloc.
The th1EE TC-fel`er. pub,i,,,-r-, re 1*
ad -is lollows:
E. G. Rochow, R Didchenk.,
I R- C dest "Re;. Am Chem. S,c-
5466 (1951)'; R. H Anderson (Ref- 4i J. A::.. Ch~-m. Sf)c. , 71, 19 5 7
A. L. Allred, E. G. Rochcw (Ref 6 t J Inorif. and Nucl- Chem P69
(1958)).
ASSOCIATION: Institut organichesk y khimli im. N D Zeiinskogc Akalemii
nauk SSSR .'Institute of CIrrRnic Chemistry Imeni
N. D. Ze.ingkiy uF tho Acadpm.., of Sciences '33~'
SUBMITTEDi February );', 1901
Card 4/ 7

TI-MOVIL-1~-F P DZMMnOMP H.H.G.
A new preparative method for the syntbasis of germanium-cQntajnijW, mmomers.
Report Submitted for the 12th Conference on high molecular weight compounds.
devoted to mmomers, Baku, 3-7 April 62

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S i B M 1 T D: October 2~" 1~)61
Carc 2, 4

B 7,/B I 8c
AUTH0163 Mironov, V. F., and Makaimova, N.
TITLi~: Reaction of trichloropilane with hyaroc-arbon at hig~l
temperatures
K-RIODICAL: Akademiya nauk SIS6H. IzveFtiya. Otdeleniye khimicheakikh
nauk, no. 7, 1962, 1505 - 1505
T-'-XT: The reaction of trictil oros i lane yitn hjdrocarbons in a continuou3-
flow system (high-temperature condensation) was studied at -.6000C. With
isobutylene condensation occurred ano with divinyl only addition. With
cyclohexene and cyclohexane dehydrogen-ition and deep pyrolysis of the
corresponaing hydrocarbon yielded a mixture of' organosilicon compounds.
From the latter, methyl trichlorouilane (22 and 19~), vinyl trichloro-
silane (10 and 20%), and phenyl trichloro-8i!ane (16 and 15~) were
separated, andwith cyclohexane, 6,,b' allyl trichlorouilane. When hexane
and nonane were used, the yields of organosilicon R5iC1 3- type compounds
were more than 60% the theoretical. The yields obtained with methane,
propane, butane, and isooctane were somewhat lower. It was snown that
Card 112

5/06 ~/6 V 00 ()/007/009/013
Reaction of trichloroo iian#-. B1 17/b 160
hydrocarbon mixturos such as petroleum ether, gasoline, etc. crin Filso be
used for high-temperature condensation. The reaulting pro(;ucts aiNays
contain up to 50~6 CH5Sici5 and CH 2- GUL ici3whatever the h,,drocarbon used.
The experiments show that the new reaction of IISiCl 5with hydrocarbons of
the paraffin and cycloparaffin series is a simple method of producing
organosilicon compounas. There is 1 table.
ASSOCIATIONs Institut orgarichefl,,,oy krimii is.. N. L. Zelir,~~,