SCIENTIFIC ABSTRACT MOLCHANOV, V. A. - MOLCHANOV, YE. I.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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ACC NRc AP6025255 The effects of radiation noise on the emission from the GSI-IM laser were also evaluated. The authors showed that 'the lifetime of the excited state of neadymium, ions decreased at high pump densities, resulting in corresponding elevation of the threshold and a drop in the laser efficiency. Orig. art. has: 3 figures and 6 formulas. MI SUB CODE; 20/ SUBM PATE: 26jun65/ ORIG REF: 004/ ATD PRESS: 7 If L 4222fL-6k FEWT(m)/T/E@@P(t)/ETI IJP(c) M -A:C-d _NAx AP6015472 BOURCE CODE: UR/ 667oo 0-57-1907M] AUTHOR.- Mash*wa, Ye. B.; Malchanov, V. A. ORG: Moscow State UniversiW 11n. M. V. Lomonosov (Kookoveldy gosudareftennyy universitet) -Mstal, scattering TTrM: Ion SOURCE: Fjzjka tverdogo tela, v. 8. no. 5, 1966, 1517-152el TOPIC TAGS: particle scatter, coulomb scatter, crystal optic property ABSTR&CT: In. earlier articles, the authors showed that many mechanisms of ion-solid In- terface Interactions allow a simple quantitative Interpretation if the Coulomb-dependent pre- dominant smaU-angle particle scattering Interaction Is taken Into consideration. rh this paper, the autbors show that the application of the earlier derived concepts to the scattering of tons by single crystals makes It possible to explain some other mechanisms being observed. The authors present results of an investigation of the power spectra daring thescatterN of inert gas long with energies of 26 - 30 kev by facets (100) and (114) of a _q@4nLstaV -The results obtained show that during the scattering of tons by crystals, un&r certain conditions in the 1/2 LqErd L'423("6 ACC NKc AP6QI5472 scattered beam, ions which have undergone two-fold scattering Predominate. R Is also noted that the extremely idealized model of the mechanism presents a quantitatively correct repre- sentation of do mechanisms observed. Yu. V. Martynanko performed some of the evalua- tions. Orig. art. has: 5 figures. MB CODE: 20/ SUBM DATE: 210ct65/ ORIG REF: Q1Q/ OTH REF: 007. Card ACC NR- APG015783 SCUMS CCDE: Ult/0048/GG/030/005/0854/0856 AUT11OR* Hashkova., Ya.S; Holchanov, V-A--- OM: Scientific Ile search Institute of Nuclear Physics, Bloscow State Uni eE@!Lty Agk. 1J.V.Lomonosov (Knuchno-issledavatel'skiy institut yadernoy fiziki HaskGvskogo gosudar- stvannago universiteta) a., I I TITLN: Ion scatteri R by crystals /Weport, Twelfth All-Union Conference an the Physical Bases of Cnthode- troni hold in Leningrad 22-26 October 19657 SC4JJbL;i;: AN SSSR. Izvestiya. Scriya fizieftestcayn, v* 30, no* 5, 1966, 654-856 TOPIC TAGS: ion scattering, multiple scattering, copper, noon argon, krypton, ion encrj@y A11;7"ACT: The energy spectra of qipittally monoenargetic No , Ar , and Kr:'* ions scatter ed in ,ho (110) plane of n c,3ppct:4'Atjf@stal from (100 and (114) faces have been recorded in, nn Livesti-ation of mulJ-Ple scattering of ions front crystals. The monoc-nergetic iou bo-ims were prodticed with the mass monochromater described elsewhere by V.A. Molchiaov and V.G.Tallkovskiy (Veatti. Itosk. ttn-ta. Ser. fiz.-astron., Ile. 1, 22 (1961)) da@a ive presented for scattering of 25 keV Kr+ and 30 keV Ar+ and X0+ ions. The ions scattered through a predetermined angle from the converging mortoenorgetic beam (conver_ Gencc an,;1c, 20) by the crystal face entered the I x 4 mm slit (located 16.5 cm from Cite scattering crystal) of a 10 cm radius 1800 electrostatic energy analyzer (energy L 36.3-3-3-605 ACC NRI APG015783 iresolution, 1 %) and were recorded in a Faraday cup. The presented spectra, recorded ,it grnzing an-les; from 10 to 170 and scattering angles from 27.5 to 500, showed that ,the contribution of doubly scattered ions to the scattered beam increased with decreas- xn- distance between the scattering atoms (i.e. , in passing f rou the QAQ to the (100) scattering faces) and with increasing atomic number of the scattered ion. Under some conditions doubly scattered ions predominated in the scattered beam. Calculations of Yu.VAIart;yncnko (Fiz. tverdogo tela, 6, 2003 CL964)) indicated that the probability of I of dotible scattering should increase with increasing atomic number of the scattered ion and the scattering atom, and with decreasing energy, distance between scattering atoms, and scattering angle. The present measurements are in good agreement with these con- clusions. The authors thank L.A.Artsimovich for discussing the organization of the work and for assistance, and Yu.V.Uartynenko ind E.C.Parilis for discussions. Orig. art. has: I formula and 2 figures. CODE: 20/ SUBM DATE: 00/ ORIG REF: 003/ OM OF , (102 L 33115-66 'XC__C Mt.- - AP6024W3 SOURCE. CODN: UR761w/91666W&@jW6206 AUTHOR -. Zav tyalov, k. .; Get fman, A. A. i, -1461chanav, V a D o; KrMZ!!k, ff. P.; Agranovs@!Y_, K. Yus; Berger, A6. Tao; Greyere 4, *1- 01 6 9! r - T] ar, To* V.; PTaitman, K.- 1 6; - AST-ju-tu' v - F. i GUbanov, - v . V.; Oran__sQ5;,__F1e_1 o; Yevseyor,' M To Merkin, Go B.; Sinellnikov, Too No; Avilov-KarnauMFov_,_3_.ff_.; INEguatif A* Gi; -Bolymyev, I's Po; Peklmrt r._T_e_,_ChhrMuvsUy,_r6 I* ZZ/ ORG: none '7 L' TITM: Q* Be Bron (on his 70th b1--thday) SOMCra IrJZ. ftektrormIchanika, no.,2, 1966, 235-236 TOPIC TAGS: electric engineering personnel, circuit breaker ABSTRKI't Osip Borisovich Bron Tms born in 1896 in Klintsi. In 1920, he graduated from the physics-math faculty of Kharv_kqV.,,Z qdl.Inatit@@* Ile bacam a pro- fassor in 1930- He defended his doctorts tbbsis ih-_i9W-; D@@jgthe second world war, he was in the nav7o After demobilization in 1950. Engineer Colonel Bron went to work toaa1xing at the Lanin;Ead Tr-dustrial. Correspondence School. Ife became the head of the CImir of Theoretical Bases of Electrical Technology in 19-58a Ito is 07osely associated with scientific and development work, and has cooperated closoV in this area with the Lenin 191ektrosilaff plant since 1946e His work has been in the areas of am high-power t breakers. Its has published over 140 scientifts works and 19 iwmntionso JPRS, sm Coo: o5, og / mm DArz.. nons MOWIMOV v F. Matrix elements of irreducible representations of a symmetric group. Vest. MosIC. un. $sr. 1: Fat., mekh. 21 no.1:52-57 ja-F 166. (MJRA 19:1) 1. Kafedra teorti funktsiy i funktalonallno'go analiza Moskovskogo gosudarstvennogo universiteta. Submitted May 8, 1964. MOLIMANTi. V,F., inzh. .Irc-miim plating. Mash-, nostroenie Obte.iw.rg comb:Lned coatirga in c, no.40MO Jl,,*.v, 164. (K?-t 37. 10) mowffmoV V.F.1 KAMEVITSKIT, V.A., kand. tekhn. aduk nt (Rapid chromizing) Skorostnoe khrow-drovanie. Kiev Tokhnikas 1965. 249 p. (mim 18til; MOLCHANOV, Vasilly Fedorovich; VORONITSYNIp I.S., kand. tekhn. nauk, --dots.---d j. nau bryy-rucr.; BOGGRAD, L.Ya., red.; KATSIMISCH, N.Ye., red. izd-va; BEELOGMUVA, I.A., tekhn. red. (Rapid self-regulating chrome plating; characteristics of chrome plating properties of deposits, and selection of efficient -methodsiSkorostnoe samoreguliruiushcheesia khromirovania; osoben- nosti khromirovaniia.. svoistva osadkov i vybor ratsionallrqkh re- zh4mov. Leningrad, 1962. 59 p. (MIRL 15:12) (Chromitm. plating) KCLP,HAIfOV, tiktor Grigorlyevic4; LITSHITS, Ta-L., red.; SAYGMIKO, TO.T-s tekbn.reds [Ethiopia] IfLopiLa. Koskya. lzd-vo gZaania.' 1960. 31 p. (Tasaoinzaae obahchastTo Po maprastranealLu politichookikh L nauchuykh znanil. Ser.7, Kazhdwmradnaia, ao.20). (KIRA 13:10) (Ethiopia) I K&CHINSKAYA, I.T.; BARKRASH, MOLCHANOV, T.I. ------- - -- ------ Reactions of aldehydes and ketones with acetic anl7dride. Part 3. Re- action of cyclopentanoas, acetone, and methylpropylketane with acetic aldehyde. Zhx=.ob.khim. 23 no-5:756-759 NY 153. (KERA 6:5) Orstoaes) (Acetic anhydride) NOLGEMY T I Unusual wear of core bits. Hazved.i oich.nectr 21 no-2:52-53 Kr-AP '55- (mm 9:12) (Boring machinery) 15-57-3-ZBWD Translation from: Reeferativnyy zhurnal, Geologiya, 1957, lir 3, p 194 (USSR) AUTHOR: Molchanov, V. I. TITLE: Some Problems in the Technology of 3hot-Borin (Neko- toryye voprosy tekhnologii. drobovogo bureniyal ABSTRACT: Bibliographic entry on the authorts dissertation for the degree of Candidate of Technical @ciences, presented to the Tomsk polytechnic Institute (Tomskiy politekhn. in-t), Tomsk, 1956. ASSOCIATION: Tomskiy politektin. in-t (Tomsk Polytechnic Institut6) Card 1/1 14(5) SOV/132-59-2-5/16 AUTUORS: Molchanov, V.1 Hatrosov, V.M. TITLE.- On the Choice of Initial Parameters for Vibration-Rotary Action Drilling Machiaes (K vyboru iskhodnykh parame- trov burillnykh mashin vibratsionno-vrashchatel9nogo deystviya) PERIODICAL: Razvedk-a i okhrana.nedr, 1959, Nr 21 pp 25 - 30 (USSR) ABSTRACT: The article describes the results of six years of re- search conducted by a group of scientists of the Ka- edra, tekhniki razvedki (Department of Prospecting Technology*)of the Tomsk Polytechnical Institute, on the creation of highly productive drilling rigs and the improvements of existing drilling processes. It was found by empirical and graphical computations that: 1) the volume of rock crumbled by one percus- sion depends on the angle of percussion and reaches its maximum at the angle of the most advantageous ap- plication of force ( P) in addition,@.to the angle of friction ((p); 2) the maximum efficiency of percus- Card 1/2 sion-rotary and vibration-rotary drilling is obtained SOV/132-59-2-5/16 On the Choice of Initial Parameters for Vibration-Rotary Aclttlioa Drilling Machines at such correlation of oscillation frequency with the rotation speed at which the direction of the percus- sion coincides with the angle-P ; 3) the experimentally found- values of the ang-le~ permit the calculating of - axial speed of the drilling bit at the moment of per- cussion at a given speed of the drill; 4) the rotary. speed of the drill and the calculated axial speed of the bit are the initial parameters for the choice of the optimal drilling regime and for the construction. of vibration-rotary drilling machines. The analytical and graphic computations are described in detail. The author mentions the following scientists who took part in this research: I.S. Mityushkin; G.I. Tols4u--ykhi G.A. Kushnikov and V.I. Butov. There are 2 graphs and 1 set of graphs, 2 diagrams, 2 tables and 4 Soviet re- ferences. ASSOCIATION: (SNIIGGIMS) Card 2/2 MDLCITANOT.-V-.I-.-,,-imnd.tekhn.naukI LESHCH&Vp D.A.1 inzh. Calcualtion of loss of pressure in standard and ella hales, Trudy SNIIGGIMS no.10W-108 t6O. (KERL 1@:12) . . . . (@Oring) IESHCHEV,,'D.A.; MI)LOHANOV, V I Gazient carrier with doping bottom. Trudy SNIIGGDS n*.ID:-16W- 170@960. (KM @5112) (Oil well ceme#@ng-Equipment and supplies) ISSHCHE:Vv D.A.; YOLCIIAIIOVt V-I. Comparative analysis of the designs of subsurface samplers. Trudy SNIIGGIM no.WI75-187 161. (MM 15:8) (Core drilling-Equipment and supplies) MOLCHAROVt V,I. I Thq@ry of SNI.IGGIY3 parabolic jet bits for dri1ling soft rocks. WU@ no.18:192-205 161. (MM 16:7) (West Siberian Plain--Boring machinery) MOLCHMOVO V. 1. @, , -- ... .... Kethcds for detemining the angles of optic axes by indireat means using the Fedorov universal stage. Up. Toes. min. ob-va 93 no.1:60-a 164 (MIRAL 1W) 1. Sibirskiy nauchno-iosledovatellskiy institut geologii, geo- fiziki i mineraltnogo e7rtymp Novosibirsk* MOILHANOV, 7.1. Ivan Fadorcvich .1695-; on tic 70th birtMay. aad.-Mmed. akzFert. 8 no.1:61-62 Ja-Mr te-5. ('M:R@ 18'.5) AMSHINSKU, U.N.; MARIMI, I-V ; VIPLCIM@_Ljtj OHLOVA, L.I.; GORB, A.M.; KUZIJETSOV: YU. -A.-,-rtauchn. red.; SPORCHKOV, I.Ye.,, nauchn. red.; y;'@YzjjAjiQ","SKIY, V.A., ved.red. (Accessories of the granitoids of the Altai and methods for studying them] Akt-pssorii granitoidov Altaia i me- todika i-kh izucheniia. Moskva, Nedra, 1964. 175 P. (MIRA 17.10) 1. Chlen-korrespondent AN SSSR (for Kuznetsov). ZAPOROZHETS. B. I.. inzh.; inzh. Preventive maintenance of 110 lcv. transformer entrances without disrantlin- them. Energ. i elektrotekii. prom. no-3:67 JI-S 164. 0 OMIRA 17: 11) I* MOLUANOVt V.L. 2. USSR (600) 4. Viticulture - Uzbekistan 7. Leaving vinegyards uncovered during the winter in Uzbekistan. Sad iCf. no.10, 1952. 9. Konthly List of Russian Accessions, Library of Congress, Jamary -1953. Unclassified. 1-%)LC1-a.OVp V. L. "The Dispordt-don and Main DeveloX-entel Conditions of' lonirr-*,- teed li iga Viticul-ture in Southern Uzbekistan." Cand A-gr Sci, M-Union Sci-Res Inst of 'Viniculture and -Titiculture, Tashkent, 1953. (RZhBiol, No 7, Dee 54) Survey of Scientific and Techrical Dissertations Deferded at USSR Eigher Educational Institutions (12) SO: Sm. No. 556, 24 Jun 55 v -@ 0 KO Ir r.- SHKIDT. K.S. % YAmunass for sconamisirg on electric power usai by the hoistlag amamtu of thi 01mg of tho OX08tv*740111, CO*IW. Prox, suerc, 12 no.7:22 JI, 157. (nm to.-Sy (Electric power) -DOGUIT-!Iuyf S.S,f inzt@.; OHK.AM)Vrv.1'., inzh. _!L j 3parkproof instmaent for i@.ea-sjring current and voltap in niner'. Bezop.truda v'pram- 5 no.!,.23-21 Z--, f,2. UOm-a jj;-:Z) 1. Kuznetskiy nauchno-issledovatellskiy ugollnrf institut. (Blectric meter3) BOGUTSKIFt S.S.; ZA@UJVA7jFjfTAj B.I.; KI-LIKAH, A.Sh.; KISLOV, A.H.; ionovsYM, P.P.; TAIRASEVICH, L.I.; BLUMLY H.A., o'f'v* -ed.^ BELOV, V.S., red. izd-va; OV=E EN`21,0, V.G., td',-,hn. red. [Automatically control-led minirg systems1Pudnichrqe avtorati- cheskle ustanovki; prakticheskoe posobie 'po avtomatizatsii na shalchte. Yoskwa, Gosgortel.-hizdat, 1962. 195 p. (MRA 15:12) (Minirg machinery) (Automatic control) BOGDAIIGV, Yu.V.p inzh.; 1.1191. @IUNRJ,N. Inzh. Program control of cutter loaders having a selective actuating mechanism* Shore RuzIMIJI no.,10:10-2-201 t64. (TC.P.A- 18.-q) 6 EEC(k)4/'EWA(hA__W_,T(_1) ACC NRi AP5025763 SOURCE 00121 Mt/0286/65/000/Mg/0130/0M AUTHDRS s V.1 Kidloval Vd, F'; w1chem? To at lbrazte ye, . I--- ! J Sbishorin, V, A, PojM* Ps L; Nikiforov, A, pg- ORG i none TITIS t A dibarete contactless pMea-sensitive Rigku class 74o NO. 174962 fannounced bylusnetak Scientific Reaggeh Coal Institute (Kuznstakiy nauchno- issladovatellaw ugollwy instnut)_/ SOURCEt Byulleten' izobreteniv i tovarnykh znakov, no, 18., 1965., 130-131 -:TAGS iL)hase me MPIC ter magnetic circuit.- mapet This Author Certificatepresents a discrete contactless phase-seneitive pickup consisting of a fixed toothed magnetic circuit vithcontrol windings and a moving magnslic circuit without windings. In order to simplify the pickup and to. obtain an unambiguous signal pickup, two readout windings are situated on two ex- tornal, teeth of the :Uxed mapatic'eircuit (see Fig. - 1). The mov4xg magnetic cir- cuit., which Isconnected to the moving object, is equipped with one readout, tooth, 1/2 =1 6Z.083.8262-503.83 L tqcL,c V. USSR/Forestry - aeneral Problems. Abs Jour Ref Zhur - Biol.., Ito 5, 1958, 20103 Author Molchanov, V.P. Inst Title Top Fire Spreading Conditions in Pine Woodsi Orig pub Lean* kh-vo, 1957, No 8,, 50-53- K-I Abstract The origin and spread of top fires is considered from the point of view of physics and a classification is made of the causative factors involved in this process* A heat distribution scheme is presented for the forty year old lichen and moss pine wood and the thermal dynanics are characterized* Card 1/1 94-9-34/47 The Kind of Instruction Needed for Fire Protection of Forests by kviatioa (coat.) the now instruction did not establish any detailed basis for co- operation betffeen the air and ground patrols. The question of setting up,atrfields is.equally obscure. The article urges that at least two parachAtists,be sent to the fire area and not one, as stated in the instructicn,-'and also that the age group for parachute jumps be restrictede The instruction issued by the USSR Ministry of Agriculture contradiots another eDdsting document. on the subject 'issued by the Main Administration of ''. Civil Air at the USSR Council of Ministers. For instance,' the norm for the cruising speed of fhe Mi-4 is incorrect (in the new instiuat-ion) and so are several other data, like the size of platform for parachute landing, data on jumps.over a forest,, atc. The article also criticizes the style and terminology used in the new instruction and accuses the editors of ambiguities* A. photo accom- panies this artimale, ahawlh& a forest fire. It was made by Yu. Baftin. The capttPn r4iAst an An-2 brought parachutists to the place on fire. AAHABLEt Library of Congress Card 2/2 USSR / Forestry. Biology and Typology of the Forest. K-1 Abs Jour: Rer Zhur-Biol-, No 6, 1958, 24651. Author 92ighaa=_r@@ Inst Not given Title The Change of-Humidity-of the Needles of the Pinus Silvestris L. In Connection with Tree Top Fires. 0,rig'P.ub: Bo-tan., zh., 1957, 42, No 2j, 294-296. Absti,act: A:study wasmade in young and fully-grown pine for- ests on the Karelian isthmus. An identical humid-- ity of the needles in various parts of the crown is registered. Graphs are given of changes of htunid- ity of the needles by age. It is pointed out that'. young needles have the most moisture, while the old ones are the driest. A sharp drop in the humid- ity of needles of all ages is registered in the springtime, which is explained by the approach of Card 1/2 SOT/84-5(3-4-23/48 AUMORS: Kurbatakly, M.p Molchanors V., Bitkovp P. (Leningrad.) TITLE: Laying Fire Barrier Strips by Helicopters (I?rokladka protivopozharnykh zagraditeltnykh polas a vertoletov) P MODICAL: Grazhdanskaya aviatsiya,, 1958# Nr k, PP 31-32 (USSR) ABSTRAM: The authors give first a historical sketch of attempts to lay fire barrier strips from aircraft in which they refer to USA experience. Since 1955, joint experimentation by the Central Scientific Research Institute of Forestry (TaKrUar-Tsentrallmyy nauchno-lasledavatellskiy institut lesnogo khozymystm), the State ScientMe Research Institute WOOM) of the 07, and the Central Aviation Base for Forest Proteetion has been carried. on. The article discusses various methods that have been tried. and. the remilts achieved. Limited success was due to the lacle of an efficient spraying device, such as a proper pump The PS-8 pmup used thus far- Is considered. too heavy (160 kgj. A photo- graph and a diagram accompany the text, 1. Forest rires--Control systems 2. Helicopters--Perrormance Card .1/1 3. Firefighting vehicles--Equipment RUDAKOV, A.; VASILIYEV, G.; EPONERt R.; MDLC @ -MOV -ly - propogals made Ir engineers. Pozh.d.elo 9 w.l2sZ5 D f62. (KEL 16:1) (Fire.preiention-Technological innovations). fee 60,064, of*** 07 0 076 r 0 0 6 0 0 0 4, : 0, 0 0 0 foe 6 of 0 0 0 0 0 0 0 Ill I I I , v N jr At Ar t I t 6 r f Ir a (c tz is it is -W tf 4 X0, 4-L I, --.) &_l_._,_T.@o 41;v I Ste. II& of r! reimexua of ownut POCOSOM and $a- 0 294t(Isk"t. -ar uw. of a pperw graphite mll the T dmompa. pn(m(W 4 KF 4twi NAP w" ewtd. tiv itreZ 00 in (lie curm(.0cKentiml curve. RratIcs, KF. Oml*. 2. Cl as t V.; (40'. 2-M V.: MV. I.'.(# V. . NAF. *;(1,. 2.(11 V.; .90 tag'. DKI V. XAJ V. fimt kr=% :,M V. *0Z H. W. Fwfit""te =00 of 400 00 get --so a, @8116. "WI got A, I L A OCTALLVGICA& LITMT146 CLASSWICATION Of U fS tr on. it it- aft 9, S_ -4 'et- W-4-4, it s it 0 0 0, 0!G so of 4, 4 too** 0 0 0 0 Or 4 0 0 of# asset *feet** #000000 0041604 7 I& it X it )v It, I( w $I m IL it if a of 4i 4( It v is 41L - ti J#1-it.1 tit tit tilt FU lit- tit at I At A :Z WX fit 4 'a _b@@tjoa pokoWs of x1micum oddo in ftmd o s rwtda%-%kif asuf V. S. Xfokbitnov. (V, s. S. 14,1 to. : 4: % K(*.f 1.10 CIA (,cc tbeftact, NIAP t9t it Alt'. (m,44, 2 10 Ir. at C ItXKI*, (tor tiall 614 1 All's IbAlv otto 2 (k-lut- --9 0 t.," (foc vxw@ 4"d I'm It. idt 8W). tor the 0 ittitt, NgtAlfct plus 12% Or wt.) AIOi. 1.317 and 1.45 v. lit Vila" and IOWA, rcap., and for 20`,@jj AIM, LW and 49 J.&I V., mtt, Tilt M(dvt shuwLqt a tectifilwair refattQ4 vq(ttf the tirtup.. thus the It a (nme" (I, dhit"d all 1(tv"tILAtion. rhe owtimi 4 A(Pe mi F at (ItI, a(k4e, c -cd VI 0: act ac%mmikums ,t AIN. atut the 0 filwomcd 49 Itte ((&Kff feemot Cc%. 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K are Coo fee *so moo 0 Is: moo som" No Q%v aft OK OK- 444 W* %I f I ; A it iE it a fiva Ot L C V W 0 K 0 1 N 94 5 a 9 31 It W e, 0 0 0 0 6 0 # 0 0 0 # 0 0 *#**#**a 00 00 0000*00000000001:0 a 409004*0690600*0 0 0 0 0 v x pp*,it I; its: Ica %W awco u(saar.0 **@,L JLXLAI@ I it -L.. 9 W f I f-I A Wcc wtl.,-,, h. -C-A-t-f -1 OL. 'i lit CVPC-l Wf-fs ...... ...... MP*c Chen" damtr at &M hL nktim to Us tbwmd bla- 0ow-Ardikic. Prow. I*. M. V. Condoide .04 00 tie .00 00 go -00 coo 0 Ao 06 Joe tpo 00 sela4i .44? amf log ii4ol MK 4.. All NOLA& -Ali -. "f "1. 4 4 AV go LS1 %Ak 0 tf w low JS It Ic IL oc (t (C (c 01 ft #$009 eAv 0 0 0 4r00 0 94 0 d 6 t C .00 W1 MAW 1 0 R Ct tf It It tF IS I# a 1% U a x a ji@ VLkx,,,kIV psi U& MV ILIVC it Ixtr m429 _t__4_ftA St @c M ctit..1 @c H@t method oc C. W" the le" yb4mun &a . 7w bility of Sit". cwkCiAlly by AMWINWAL IttleAtkat ccaftw4cay(c. A. S4,3OWtbc=Mtr [a Aq. "a. gig- > clw=. &a. Window Cis- > > electrode dim ?. metadtkuc At- tb-, deta. of chrm. sta- h at MMU t of clatu OMIS. 00 jtw"pfopowdtGc%p(Tw(hc a relative Value -(fmc of equal de$(CW- - i me. d-t-cclort Cf. t -00 ve 0 j -As hpQ Ct 00 ift aft* - i- - - --]ago Or 49 2 a I N7, Ir Ir Ic It It (C tr (C Or so 0 f 0 *4 it a &&if $00 0 4P*04[ O_f&** qro# w 0 IA o 0 0 t.t 1 , 1 0 0 O a 1 A - IL 2-11 AIT , v . 1 ! 1 . A Mcps POACOMI MO ftC*E#1;U WAt 4-6 V. S. Mckka, Prm' 194 2 3-7 tical gLZ';;nuld' Wif A ark& of o A C A , p in Runia ;;;ri tested with mptd to,dick water and ;W see mahtility, Tht mutts of IrAts or, 1,1101141rd. U.V.C. fol see SOO IrO 0 we* age 00 LIS LA SITALLUSOC&L L[T'@RATURC CL"UPICATIOPI woo laa@ OTIS --rarc-&Q, A. C.7 I All an a- nt AP LS IOW 0 P I IF 9 A 6 3 2 V tc a KO NA I 0 0 9 eg * 0 a 0 0 0 0 0 0 0 0 A a S AOSIDAGAG& 0-0-66 a 00, 0-0- 0:00of** 0 0 0 Wa A@Ljdw y. K4104f. ilhoop. IS. OU 41(10AO@ @Wlwis at t -%% KAW I 1W Ift CLUNO NIrQj( (bt IS c e4co am added to MA41. BLOC Wo thm two layers 10M. fir M3% Xj,Ws solit.. the bottom fayw cootaWd c c 401W $olid m4mue (L?% Nato and.12%.Not) and ti;@ i;; lf;lrd h.-i 3.1% sulkis 4,111% "'1 tl% swo Ibu*. Fav, [It Ow. v uquat brstjocit tAlet. t'u Wi(a(is (Aw Otittj of N ;.( W)g Wag at Iftit VV cqi-tivc. NiGtill alusc be gat . @@ aa laj;Q tomat wbk* (he ratio r of SI(h:.V%4 Is I or rMter. It the bottom tayrr was (mted - mmin wftk NH40R. r Itt It Loc"stcA tuxther. e.C. fmns I A ItslAt. The 6yre forinslints of "A- &14(4( 14(t. I%y Xjf@(Ij-% C(L4, (Okkulc4o MOLCHANOV, V. S. 1 Sep 52 USSR/Chemistry - Silicon Compounds, Cooper end Iiickel Compounds "Diamine Complexes of Copper and hickel Siliestes," 1,.Ye. Frikhid1ko, 0. S. Molchsnova, V. S. Molchanov, Inst of Silicate Chem, Aced Sci USSR "Dok Ak- Vauk SSSR" Vol 86, No 1, pp 83-86 Three new complex compds contg silicic acid and related to the diamines of heavy metals were discovered. They are 2 ethylene diarnino and one propylene diamino silicates of copper and nickel. Presented by Aced F. V. Grebenshchikov 26 Jun 52. P.A 234T15 .. . ....... OAtA44 by - -a qw-T-tf Oww" 41nij t v d -1p) I lu 9 MA ' d sod om ckr- was: by solutions sodium . hydioidde An = 6.. V, S. Muleh iy Int - d4tl@@fiorx. js-,W:portvona1 Tim dtptlt. the M, An hl- i4l. -WPnA44 6@- Oil@r, fit the z1h, lit *6 -Ok 92%140-, ttu3p cftA*x- AC4 on, 0 -0" ftad that - ' Ot6," gad *,b harzr wrfa tlie r6ostg@bk, C'jY 3t; 0, 1 qua, El ru mono KMCHMOV, V.S. .(Leningra&); SILIC I , T.N., [deceased) (Leningrad). - @-- k cage of glass soUrimtion. Prirod& 46 no.1:114-7-15 -T& "57. (Ultr&Tiolet rays) (MM 10:2) (Glass painting and staining) 3(8) PHASE WO.K EXPWITATIOU SOV/1310 Soveshchaniye po.eksperimentallnoy I- tekhnieheskoy mineralogii i -h Leni ngrad., 1956. petrografii 51, Trudy.... (Irransactions of t;l-,.e Fifth Conference on Experimental and Applied Mineralogy and Petro raph Kosaow# Izd-vo, AN SSSRI 1958. 9L 516 P.; lj8OO copies printed. Sponsoring -Agency: Akademiya nauk SSSR. Institut geologit rudnykh mestorozhdeniy, petrografti.. m1neralogii i geokhimii, and Akademiya, nauk:SSSR. rnstitut khImii silikmtov. Resp. Ed. Tsvetkov., A.I.; Ed. of Publishing House: Tvanov,, B.V.; Kis.e eva, A.A. PURPOSE: This book is intended.for scientis-'Us and students of miner&- logy and petrography. COVMU(]E.*, The predent collection of articles are reprints of reports presented at the Fi&x Conference 'on Experimental and Applied Kinera- logy and Petrography, held in Leningrad on March 26-31, 1956, The Card 1/21T Transactions of the Fifth Conference (Cont. SOV11310 TABLE OF CONTENTS: Foreword 3 Introductory words by Academician., DS. Korzhinskiy 5 Ginzberg, A.S. Academician D.S. Belyankin's Role in the Development of Russian and Soviet Petrography , 7 Palatnik,, L*S. and A.I. Landau. Methods of Investigating Kulti-component Heterogeneous Systems 19 Belovs N-V,j Academician; V.S. Kolchanov and N.Ye. Erikhid1ko. Synthesis and Structur4of -Hydrosili(@ates- Containing Sim- ple and Complex Heavy Metal Cations 38 Toropovp N.A., Kh.S. Nikogosyan and A.I. Boykovas Synthesis and Analysis of 4ome Froperties of Hillebrandite and Other Calcium Hydrasilicates 44 Ryskinj, Ya.I. Infrared Absorption Spectra of Some Hydrated Calcium Silicates 55 Card 3/-M-, AUTHORSs Molchanov, V. S., Pritchid1kc, 11. Ye. 652-1-1129 TITLE: The Corrosion of Silicate Glasses by Alkaline Solvents (Korroziya sil-ikatnykh stekol shchelochnymi razt1vorami), Reporto 2: The Dependence of the Structure of the Glasses and Their Power of Reoistance to Alkaline Influence (Soobshcheniye 2. Zavisimost? mezhdu eos-.avom stekol i -ikh usluoychivostlyu k deystviyu shchelochey) PERIODICALt Izvestiya AN 33SH OtdoLaniye Khimichaskikh Hauk, 1958, 11r 1, PP, 3-7 (USSR) LBSTRACT: Any silicate material is to a caertain deg-roe subjected to the destructive in'fluence of alkaline solutions. Various elements, if combined with silicate2, make possible the unchangeable maintainance of their power of re3istance. Only in the ease of a considerable concentration of the added element the power of resistance is again reduced. Crystalline quartz haa the great- est power of resistance. Among other was found that zirconium- -containing quartz gi-asses have an extremely great power of resistance. Nothing definite, however, can be said about bery- Ilium. A series of elements combined with silicates increase the power of resistance, however, not to such an extent as; Card 1/3 does zirconium. It was of special interest to detect whether The Corrosion of Silicate Glasses by Alkaline Solvqnts 62-1-1/29 Report 2: The Dependence of t.he Structure of the GlasGes ar Their Power of Resistance to Alkaline Influence a aubstitution of silioium is also posGibl,@@ by various elements without a con3iderable reduction of tho pover of resistance against the alkal-J.-a influence. By mi2ans of the interferrometric method the thickness of tl-,_,@ dl.ssolved la7er of glass was detected and thus the power of rasistance of the Silicate glasses of the type (87-x)% against the -influence of alkaline solvents, as well as the power of resistande of the double-sodium-silicate glasses which contain from,-O to 33,3 molecules % Ila 0 (also titanium-ontaining flint) vrere de- termined. FurtGrmora it was shown that -except beryllium - all metals introduced to the double sodiiLia adicate Class in- stead of silicium reduce the power of resist@anae of the Ziasses against alkaline influence. In the beginning (up to 22 1,4o RO) the reduction of the power of resistance ic only unimportant, but in the case of a quantitatively increased substitution (bx metal) a considerable decrease of this power of resistance can be observed. The radius of the ion of the respective metal which was introduced plays an, important r3le(hara: the greater the radius, the smaller is the power of resistance. Ther are Card 2/3 3 tables and 16 references, 10 of which are Slavic. The Corrovion of Silicate Glasses by Alkaline Solvents 62-1-1/29 Report 2: The DeVendence of the St@oucture of the Glas3us and Their Power of Resistance to Alkaline Influence ASSOC 11,LTION: Inetitute of Silicate CheldstryAS UM tInstitut klilliMili !5:L.L_,ro_jov akademii na-uk- @@jj@i) SUBMITTED; OctQber 30, 1956 AVAILABLE: Library of Congreja 1. Glass-Corrosion-Test results 2, Alkaline solvents- Corrosive effects-Test results Card 3/3 AUTHORS; Molchanov, V. S., Prikhod,ko; 11. Ye. sov/62-58-7-1/26 TITLE- The Corrosion of Silicate Glasses Caused by Alkaline Solutions (Korroziye. ailikatnykh stakol ahchelochaymi raatvorami) Communication 3.' Inhibitors of the Alkaline Corrosion of Glasses (Soobshcheniye 3. Ingibitory shchelochnoy korrozii stekol) M IODICAL; Izvestiya Akademii nauk SSSR, Otdelenlye khimicheakikh nauk, 1958, Ur 7, PP 801 - 608 (USSR) ABSTRACT: It is known that the destruction of silicate glasses by neutral and especially by acid solutions is from the first moment accompanied by a peculiar self-protection: The formation of a thin surface layer (or film) consisting of the products of de- composition of the glass. Berger (Ref 4) was the first to describe this phenomenon. Lateron Geffken (Ref 5) et al. dealt in detail with this problea. The purpose of this paper is the further investigation of this phenomenon in order to make practical use of it. The authors found that some anicms have to a high degree the property of reducing the destructive effect of alkaline solutions on silicate glasses in which they are Card 1/2 found in small concentration (0.01 g-ekv/1). Beryllate, alu- The Corrosion of Silicate Glasses Caused by Alkaline SOY/62-58-7-1/26 Solutions. Communication 3: Inhibitors of the Alkaline Corrosion of Glasses: minmte and zincate ions exhibit an especially strong efficiency. The capability of inhibiting of these anions becomes especially clear in the destructions of all silicate glasses in alkali with the exception of the highly self-decomposing binary sodium and potash glasses. The results obtained by the experiments agree with the assumptions made by Berger and Geffken (on the mechanism of the inhibiting effect of anions). This inhibiting effect is not caused by the formation of a layer but by the action of the inhibitor on the elementary processes of which the corrosion consists. There are 4 figures, 2 tables, and 16 references, 8 of which are Soviet. ASSOCIATION- Institut khimii silikatov Akademii nauk SSSR (Institute of Silicate Chemi3try,AS USSR) SUBMITTED: April 24, 1957 Card 2/2 AUTHORS: Molchanor, V. S., Prikhidgko, K. Yes SOY/62-58-8-1/22 TITLE: The Corrosion of Silicate Glasses by Alkaline Solutions (Korroziya, silikatnykh stekol ahchelochnymi rastvorami) Note 4: The Destruction of Glasses by Means of Tarious Hydroxide Solutions (SoobshcheniYe 4. Razrusheniye stakol rastvorami --azliahaykh gidrookisey) PERIODIGAL: Izvestiya Akademii nauk SSSR, Otdeleniye khimicheakikh naukp 13589 Nr Bt pp. 917-922 (USSR) ABSTRACT: The characteristic feature of the action of alkaline solutions on various silicon materials is caused 'ky the destruction pro- cess through the ions of the silicon hydroxyl and of the poly- meric silicon- oxygen radicals. It is assumed that the action. of alkaline solution on glass changes according to the chemical activity of the solution. This activity is again dependent on. the degree of electrolytic dissaciation of hydroxide. After further explanat-41onB of the chemical activity of variou3 ;;y- droxides in the reactions in which hydroxyl ions are taking part, the authors discuss the publications in this field (Refs 5,6). In investigating the hydroxides the authors obtained the Card 1/3 following results: The hydroxides are distributed according S07162-56-6-1122 The Corrosion of Silicate Glasees by Alkaline Solutions. Note 4: The Destruction of Glasses by Means of Various Hydroxide Solutions to a certain order (in dependence on their strength): KOH > LiOH > KH4OH>B& (OH)2> Sr(OH),> Ca (OH)2' Caustic soda destroys the silicate glasses (of any structure) to a higher degree than the rest of the hydroxides. The authors call this process a "sodium anomaly". It is assumed that the latter is caused by-the characteristic feature of the peptization of silicic acid (by hydroxyl ions in the presence of sodium ions). The motion of hot water (9000) on silicate glasses of low resistance proved to be of a rather dissolving than just of a leaching out character. The calcium hydroxide solutions destroy the silicate glasses in most cases not to such a high degree as water,sitice on the surface calcium silicates are formed which have a greater resistance to alkaline influence. There are 1 figure, 4 tables, and 13 referencess 7 of which are Soviet. ASSOCIATION: Institut Ichimii silikatov Akadeaii nauk SSSR (Institute of Card 2/3 Silicate ChemistrypAS USSR) goir/62-58-8-1/2?- The Corrosion of Silicate Glasses by Ilkaline Solutions. Note 4: The Dastruction of Glasses by Means of Various Hydroxide Solutions SUBMITTED: February 27, 1957 Card 3/3 KOLGRANOT, T.S.; OZEM-SKOVSrATA, Y.G. AlkKU resistance of glass &ad deanlug of optical parts br &Ikalias solmtEctane Opt.-tmelch. prom. 25 ao'. 2148-51 r 158. (KIRA 11:7) (GlAtas optical) C&11@kuex) TASTREROVA, L.S.; KMCHOOT, T.S. Iffect of various factors on the ittructura of garface fLlzs gf silicate glass. Zhurprikl.khims 31 no,11:162&1636 N 158. (Glass) (Films (Chemistry)) (MMA 12:2) SOV-26-58-11-17/49 AUTffORS: I karova, T.U., Molchanov, V.S. .1a _C@eningrad) TITLE: The Spontaneous Motion of Drops Over Solid Surfaces (Samo- proizvollnoye dvizheniya kapall po tverdyn poverkhnostyam) PERIODICAL: Priroda, 19584,79r 11, pp 87 - as (USSR) ABSTRACT: The spontaneous motion of drops over solid surfaces is ex- plained by the phenomenon of a selective adsorption of octa- decyl spirit and stearicacid with oriented films on steel and glass. The phenomenon proceeds with such an intensity that the very thinnest film carries along a very large drop of oil. The motion comes to a atop as soon as the entire surface of the body is covered by the film. For demonstra- tion purposes, the easily obtainable motion effect of vase- line oil with an addition of octadecyl spirit is recommended. The dependence of the spontaneous motion on the size of the solid surface still remaina unexplained. There is 1 set of photos and 7 references, I of which is American, 2 British, I French and 5 Soviet. I. Drops--@btion 2. Thin films-,Surface properties Card 1/1 AMORI None Given alo4o *01OR91 at she Till 10081912yer Cow"as Y% vj ZWOUCALI 51OU9 I k$rAnik*. 1959, W, 5, , 1-4 (UM) ANT349TS ilk the DOC&PPAP6 a promis"tloa of $40 TOW Ulf to Me Forgopoex of the wildips materASI IFAVAtrIve for Atu'alimurq WA -19"VASSUre Increase at rVadvaSION, is POR1191W4.- The to k ploge Im x9saaw in the *00QD4 half of Pont or And VAk amt*t to US 1250k AmaLrersm. of Me grewS sobolarO* birthday. Quistmmetrig oboxi4st at she POT221 Union &ad Me NoAt's Pemoor"Ies al%:Wet theCopgre"". l C Po prablema of the dwVVl9p%qm% a r bepaltZ7 1mrs I the P1 Mary seelipffe a" the pqotxpjp at JMII : , If Cape"~ 090SIOnZ rXofsso9r 1. 1. FA%4qCOr9d@k1r Opened Ohs 09OUP90 Of the sub-smatigm for Clete SPA Care a warr#7 or Mo s"a of ders2opneas or aqviet gloat prodvg%l " il AS n of amber or prewlsIPS stake In the CAS24 of &Is 1, hoolop. :: X POrPOT9V, tb* follQVIUC 260tarpa Were holds Doctor Kornai (ft9PA*'B XOPUWIG Of 1100#9TT) IRTIOSS64194 M' struRISVO at go" IA the top-14jare of flawal 14aseves) "oQuessix SWI-Jur-PAROA 0; a CIM17 di-ppwrR4 0370sallipe, phave tram the 6146@ljkq ph"91 T.-T. Targta and 0,9@ @r- (COX) ropers9d on 0ogrptlon wpootras IwApIpgonav. jUSuGhtwiflol propirt2es of -&Mog Az@pv (091) ropart,14 on Me Au"WoUrn reciprocal relations bV%WWVa OX49XVd SPA #IN- rd4xvt Slane phase$; T&L. 2politut kwIML : izaaw Aw Paim (institute at KUM* chemisizi or the AG VM) iilmc%sead Ike rmapop4 for Me 41@%Mw*6A* an the P"Ilxqm of the strugWre or flone-II)m 0MV214POO111 rrare4war LUtsuch. &Ad 116 1--ZIUMTS. 1"Utut asekle, ("ties lastila 61 -xvkgrttd OR She ravolugallon at the Gloat Olruotnrs by the Nothad at Therwal AP^Ijfl* 11�4 Ppileal rolom1*0419ml To. T. Pod-UG (Cox) "MOV4614 the Pow method or OZOOIC20 Class woffrp-S&PA the 0911SP6 of 012144190 Wr Rt"4 at 140-freivengy correatj Ta. G. ShterPberf r9PQr19A OR lawen wiSw9-VTT*-A4 &44 baron for falopq* a" pajollao which MOO b-son 4*lrvlgp*4 In Me 009940totTIA1127 kormacheakty IRSI&IAl (AWO 0940RIlArla Ropqxrok Xnaulute of cor"nosh 1@ 0. Uftsnlpavs. CarA 2/4 OM4 or (001) "vqmqO#A me role P24qwVF--1*h4 swage 511190-1 61ORN941 a" pe-stobeelogy of P14owpheso CIONVO61 kLTxj "Porteit on the xgb&ll$r of Sodium, IQ" in also@ tZroo or two symsem As O.A0.50,6 9. A. 110- dumve"42 (ni atroikersalks) she Fra4mpo of 4alOdulpf the almass V7 load xhprtkqvsklr polltokhalobe*kly AP0119% IR41AWS) gvpqrt*4 an allies$% foxv4ZA91% *P4 staltrIP9 Pr9GONRIN IN the VrIqueltod glans l@q9rj variant, nor $me of glove; 1--s- nor glees Xamil mAe) ropqrIet an US 4914roApallon of I.Furislts In &119& 1-7 NP49%r9@995to Rmlrnlsj ". D. B994009TS, 841 TO. P. grl:ra (Close 2Am4LSm%O rtportod R-Jyj4-Gqr electrode ffra-i-ftwhLoh boa beta devised lit $has. TO,-!-JLQvm01a (Close zPatituts) discussed the 111PISLOO of t1mv fors0lon of aryst&Ilinotion center* Is "a or glens I Z. X. onliskals (91099 1PAIIWA) 41~1*61#4 $be sonalls of She of US Isa4*PQ7 Of P406t4latle syntema tow%rdm glass rarmatloal 1--@,-qr-obApAk, X. I-J*Axorykh, SPA T. a. xsrFqQh9pkO (sillzl) I"- '19a of trpsm of wpp4aQp4V.41APC 99146 also$ an the wosia or y, , x. iE. 6 At Or-chgnlk, 1. T.jn -,kyyR, ?'W_ To A. ympbere (11=0 416cuestia the production of oqP4VA;l;,1-filpO an itpes of flags which contain 09pp9p,*%Io 00~43.7 to be redsperhod. 5(2) BOV/62-59-1-1/38 AUTHORS: Molchanov, V. S., Prikhidlko, N. Ye. TITLE: Corrosion of Silicate Glasses by _Jkali Solutions (Korroziya silikatnykh stekol shchelochmyni rastvorami) Communication T. Effect of Alkali Concentration on the Degree of Glass Destruction (Soobshcheniye 5. Vliyaniye kontsentrataii shchelochi na stepen' razrusheniya stekla) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye k:iimichesk-ikh nauk, 19599 1'r it pp 3 - 8 (USSRIJ ABSTRACT: In the present paper the authors investi,r,ated the corrosion of various glasses within a wide range of the concentrations of alkali solutions in order to determine accurately the influence exercised by the composition of glass on the kind of dependence of the corrosion on the alkali concentra- tion. The degree of glass destruction by alkali was determined by measuring the thickness of the dissolved glass layers according to the interferometric method earlier described (Ref 5). The results of me,"urement are given in 'table I and 'Figs 1,2,and 3 - It results from these investigations Card 1/4 that an increase of the aqueous caustic soda concentration Corrosion of Silicate Glasses by Alkali SOV/62-59-1-1/38 Solutions. Communication V. Effect of Alkali Concentration on the De,@--,ree of Glass Destruction within the range 0.5 - 10 11 exercises a different influence on the degree of destruction of silicate glasses: the corrosion of glasses rich in silica is proportional to the alkali concentration; at the beginning, the destruction of glassee rich in lead, zinc, cadmium and magnesium increases, but later on it is decelerated due to an accumulation of anion inhibitors in the solution and the formation of protec- tive layers of magnesium hydroxide; glasses with high calcium, strontium or barium contents are destroyed to the same depth by all solutions within the range of the concentrations in- vestigated. Concentrations of alkali earth hydroxide solutions exert quite a different effect. It results from the thick- ness of the dizsolved layers of 9 glasses (Table 2), which were obtained in 0.02 and 0-5 11 solutions of strontium and barium hydroxide, that 0-5 N solutions exercise not as destructive an effect as 0.02 N solutions. This is in contrast with-aqueous soda lyes which upon an increase of their con- centration destroy all glasses all the more. This specific Card 2/4 property of the hydroxide solutions of alkali earth metals -Corrosion of Silicate Glasses by Alkali SOV/62-59-1-1/38 Solutions. Communication V. Effect of' Alkali Concentration on the Deeree of Glass Destruction presumably may be explained by the formation of alkali- resistant solutions on the glass surface. Such a cation inhibition was already described (Ref 10). This was clearly confirmed by the investigation of the corrosion of glass- like sodium silicate in a 0.02 N strontium or barium hydro- xide solution. On the glass surface the formation of white crystalline precipitations was observed, which by X-ray phase analysis were identified as barium and strontium orthosilicates. This assumption was confirmed by comparing the interplanar spacings of the precipitations observed to those of the corresponding orthosilicates (Table 3). There are 3 figures, 3 tablesp and 11 references, 6 of which 4 are Soviet. ASSOCIATION: Institut khimii silikatov Akademii nauk SSSR (Institute of Silicate Chemistry of the Academy of Sciences, USSR) Card 3/4 5 AUTHORS: Prikhid@co, I N. ie. S07162-59-6-4136 TITLE: Corrosion of Silicate Glasses by Alkaline Solvents (Korroziva siliketn,vkh stekol shchelochaymi rastvorami). Comramicatioa 6, 'The lihanomeixoa of "Sodium, Carbonate Faradoxal (Soobshcheniyea 6. Yavleniye "Sodoyy%kh paradoksov') PERIODICAL: Izvestiya Akademii nwik SSSR. Otdaleniye khimicheskikh nauk, 1959, Nr 6, pp 9T5-980 (USSR) ABSTRACT; By way of -introduction- the definitions by Grebenshchikor * 13 school of tha paradoron mention .ad in the title (paradoxaa of the firstan& second type) are dealt with in brief according to different publications (Refs 1-12). The present paper reports on some experimental results concerning the action of sodium hydroxide and its salts on glasses. The intensity of this action of different solutions was interferometrically measured by the thickness of the glass layer dissolved. Half-normal solutions, were used at a-temperature of 900 and a4 action Upon'glass of 4 hours. At first the action of solutions on 41 glasses of different composition (2,34-component glasses) was investigated and the sodiumparadoxon (action of sodium carbonate is stronger than the Card 1/2 action of sodium hydroxide) of the first and secaad type, and of Co=osion of Silicate.Glasses by Llkdliae Solvents. SOV'/62-53-6-4/36 Communication 6, the Phenomenon of "Sodilun Carbonate 24--edcocill).'- both types was determined with diffqrent glaoses (Table 1). The .Vwadoxa are connected with the absalate alkaline resistance of -the glasses. They were found tp be ospecially Laarked with hardly resistant glasses. It was furthermare observed that glasaes containing Cat Sr, Ba, and.Fb incredze; the paradoxong, whereas it do4s not occur with Zn azl& Cd. Thas there is a specific action of the carbonate ion,upon glasses, which destroys the silicate-oxygen group and by itself forms silicon acid compounds. Corrosion by the carbonate on the surface of the glass only occurs in case of a difficultIj soluble salt. Orthophoaphate iond also-@ethibit strong capacity of corroding the glasses. They split apthe siliaGa-oxygen bonds and then they form difftaal'tly soluble compounds with the cations. There are 3 tables and 16 references, 6 of which are Soviet. ASSOCIATION: Instit-mt-lchimii ailikatov Akademii nauk SSSR (Institute of Chemistry of Silicates of the Academy of Sciences, USSR) SIUBMITTED: AUgmst 50, 1957 Card Z12 S/153/60/0031/006/007/009 B103/B206 AUTHORSt Makerova, T. V., Kazurin# 0. V., MolchanovL_j__S_ 1@ -------- TITLEt Electrical conductivity and chemical stability of silica glass containing two alkali metals PERIODICAM Izvestiya vyashikh uchabnykh zavedeniy. Khimiya i khimicheakaya tekhnologiya, v. 3, no. 6, ig6o, 1072-1078 TEXTt The authors studied the phenomena which are the mutual basis for the processes of electrical conductivity and chemical destruction of glass. As is known (Refs. 2,3), the electrical conductivity as well as dielectric losses can be reduced by replacing one alkali metal in the glass by another one. This phenomenon was named "neutralization effect" by G. 1. Skanavi (Ref. 4). The authors do not consider this special term to be suitable an& propose the designation "Two-alkali affect". This effect permits the im- provement of the glass insulation properties without notably changing the other properties. Table I contains data on the composition of the glass types studied in % by mole. The chemical stability of the glass was deter- mined by its behavior against water by the titration method. The destruc- Card 1/6 S11531601003100610071003 Electrical conductivity and... B103/B206 tion of the glass (powder 70-501A) was determined through titration of the water extract with 0.01 9 HCL (indicator methyl red). Table 2 shows the resistivity, specific gravity and resistivity (1) of the glass types. From these results the authors draw the following conclusions: 1) The increase of the resistance of glass types which is caused by replacing one alkali oxide by another one (two-alkali effect), changes only slightly with regard to value and position of-the maximum, if oxides of bivalent metals are introduce& instead of silica. The resistance is thereby increased by several orders of magnitude. The maximum is reached at a ratioNa 20 IK20 = 4:5. 2) With a gradual replacement of N 20 by K 20, the chemizal resistivitr of glass types against boiling water passes a maximum which lies at IT20 : K20 = 5:1- For the glass types investigated the resistivity increase lies between 74 and 15%, as compared with the resistivity of the best one-alkali glass. The nature of a bivalent metal admixed to a two-alkali glass influences the value of the maximum, but not its position. 3) The aforementioned differences prove that the change of the electrical con- ductivity on the one hand and the chemical resistivity on the other hand, Card 2/6 ---- - ----- S/153/60/003/006[1007/009 ,Electrical oonduGtivity '.and...@. B103/BZ06 com S. MO.C Legend to Table It: SIO: R- () mg Cao BaO uO Pbo 1 Index:of 1 the series, . @ ST 113 :84 iM 70 17 13 C 70 17 J3 -B 70 17 A3, 70 3 :p ' .70 IT Carl 416 15 Y 60/M/006f007/6" 09 B B206, 03 I 'Legen-d-to @Tabla @r @-i content @of Lr"ot"%, -4) Sp ecific -v i gre 4-Y, 3) @onsum-ptiom HCl mole; @4) 1 t es., of O.Pl N H K,O, .[ @ ..Pacxoi Igp apli % .r 0 PacXoA [ZF hpK AWb- S cTeK- 40tiv 30 .T creic yAejtr.- Huft ace 0,01N ticl, @,Ccpitz a (RIO 13c' RO 0). rCePME C (RIO' LT. CIO 13) 0 2,U M :6,97 -4,81 .'0 2,53. 29 15 * 5M 2 TFZ 182 9.42 5AS -2 25 23 9 4@: 6 2.32 130 ' -945 * 6.39 ' 4; ..23 1 6.79. 1 233 160 95 9 6 92 ' 6. 253 ' 26 10,0 ,. 7,2 S H 7 '33. 33 252 6 87' G '6 '2 50 2 2: 27 1 39 11,39 100 7.86 7 5 . 2 20a 77 6 8 5 1 -1 -2 - 340 @,48 5T 6, rCepita @R 10 16i Po 0) .,-C pHa 9 (R BaO.= 13) e 20. 17, ' fe , 2,35 58 6, 4;51. 0 ' .2.94 -.-73 8.89 api ra- a 2e35 2 294 996 @ 'U T4, rp, :8,81 2,89 14 5 ,@T i, q A, , S/I@V60/003/006/007/0 oq Electrical conductiviti'a nd ... 5/B206 36 2, 409 9 W, --tr-6 2.91 T ; 2 141 - 1,11, 6 5 -269 1 I 1:` 493 9.79 W. 12 2.8t 8,14: 2,36 470 -8,23- 87, , 1 5 'JT- Z90, 4io 10,36 7,01, (R30 79 M.go I ust Z (R3.0 IT, ZnG 13@ 2.44 ; 32. 23 7 4 2 66 12- 703, 4,97 2, 2.44 , 25 , 809 5 .43 2 It 9:05' 5 45-,;' 4 - I .43. 2 " .23 8:76 to 8 5.9T j, 24, 27 9.11 6,42- 6 2AG - _9 g's 29' 101A 7,02, 8,5 2,64 13 - 1000 U. 243 39 _12 M 2.4 - 10. 7.00 14 - -.9.67 6.69 . 14 2G 9.55 6.6i I 17 71@ .8,09 5,72 IT. :2,55 -18, 8,15 5,75:. Cepun P (%O@Cx 17" PWM 13) 0 3X 35, 9.01 02 6 - ; 85 23 11.95 26- 2 9 3.2 27 10.10 .@n IT 34 4., 3. 2 IOA, 741 14 3 18' ' 118 @''Card 616-@@- 3. 21 14 @TA 7 I 130 19 10,07 7.45 S YF,VSTROFCMV, K.K.; KUURIi, O.T.; MLCHM07% V.S. HalatIon betweea certain phytdcochemical properties of glasses and their composition. Zhur.MO 6 no.1:114-116 f6l. (KM 14:3) (Glass) 25640 S/032/61/02T/OOT/012/012 K, Ul Go B110/B203 AUTHORS: Korolev, N. V., and Molchanov, V. S. TITLE: New interference apparatus for measuring the alkaliproofness of glasses PERIODICAL: Zavodakaya laboratoriya, v. 27, no. 7, 1961, 913-916 TEXT: To study the alkali corrosion of silicate glasses by the interference method, one part of the previously polished sample is protected by a rubber coat, the other one is exposed to the reagent. The height of the step formed at the boundary of the two parts, representing a measure for the alkaliproofness, is determined by measuring the interference band shift with the microinterferometers MAM-4 @'NII-4),KVIW-5 (KII-5), and 03K-46 (IZK-46), if the transition zone is