SCIENTIFIC ABSTRACT MOROZOV, N. M. - MOROZOV, N. V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001135220011-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 98
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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Kinetics of the Thermal Lecompositicn -,f Ozone 50/76~35-10-,41/45
ASS OCIAT ION: Fiziko -,,.him icheskiy inst it t im . L . Ya . Ka rpov a ;'4oskva (PhY -
sicochemical Institute i:~~(~ni L. Ya, Karpov, Moscow
5JBhlIT"_!-Di March 31, 1958
Car~ 3/3

SHCHTBRYA, G.C,.-,
Kinetics i-rd rnou.hnninm of a ~P~'.alytic re,-Ict4r).'
moroxide uid w8ter vhpor. Fnr-t 2: Renctlinr,
copper rxide catFily-t- Kin. I lkat.
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511CHIBRYA, G.G.; MOROZOr, N.M.; THAIKIN, M.I.
Kinetics and mechanism of catalytic reaction between carbon
monoxido and vater vapor. Part ls Reaction on ferrochromium
oxide catalyst. Kin, i kat. 6 no, 6:1057-1068 N-D 965
(MTRA 19W
1. Fiziko-khiinicheskiy Inatitut imeni Kexpor7a. Submitted
February 13, 1965,

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MOROZOV. N.K., inzh.; POKAMESTOV, V.V., inzh.
Kechanized drying of a wet layer of milled peat on the side of
piles. Torf. prom. 35 no.6:9-11 '58. (YTRA 11:10)
I.Vaesoyuzny3r nauchno-issledovatollskdy institut torfyanoy pro-
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(Peat--Drying) (Pont mitchinery)

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Ji 07 5 / 6 o/
B020/BO61
AUTHOR; Morozovj N. I"i.
TITLEi Determination of High Concentrations of ozone
PERIODICA"s Zhurnal analiticheskoy khimii, 1960, Vol~ 15, No~ 3,
pp. 367-368
TEXTi The e are no accounts of the determination of high concentrationi
of ozonelli: publications. The moet widely used method of determining
ozone in lcr concentrations depends on its absorption by a potaggium
iodide solu ion (Ref. 5) according to the equationg
H20 + 2KI + 0 3 ' 2KOH + 1 2 + 02- This method is very simple, and well
suited to ice purpose (Ref. 6). However, there are many difficultips irt
1~ 13
the determ nation of high concentrations of ozone, which are atipulat-30
in the firit place by the aggreBeivity of the concentrated ozone, and
besides, a local rise in the basicity of the inedium may occur at th~.4
contact p( nts of the analyzed gas with the KI-solution, wh4rh ili~iy -J,
in an alke.1 solution, instead of a separation of free indine to ito
Card 1/2

,-germination ol hif_~h oncenzra-.ions o_t
Ozone B020/BO64
oxidation under formation of potassium iodate (Ref, "t:-
up to some percent lower can be obtained. The method descri")~-d h-~_-
makes it possible to avoid these difficuliies, A peculiarJry 3f the
method is the use of evacuated weighed flaF;ks with a volume of 200-1~100
(Fig.). The performance of the deter-minati,?n is also described in de+ail.
The reproducibility of the refults was tested ~)n ozone - oxygen mi'xturaq
of constant composition. A process of producing mixtures of concentr;,1-1,
ozone with oxygen is described, and the data obtained from the analysis
of such mixtures is given (Table). The temperature fluctuations in the
weighing room during weighing were +0.50. The main sources of erro-r
are given, their elimination is described, and finally the main advantiFr~n
of the method described are detailed. There are I figure. I tRbII7-,. inl
6 non-Soviet references.
ASSOCIATIOF~ Fiziko-khimlicheskiy institut im, L. Ya. Ka-,pova, Mcqkva
(P~Iljillo-chemical Institute imeni L. Ya. Karpov, Moqrr.)w)
SUBN'ITTEDi March 6, 1959
Card 2/2

33488
S/195/61/002/005/013/027
Elll/E485
AUTHORS.~ Temkin, M~I.,, Nakhmanovich, M.L. Morozov, NM
,TITLED. Kinetics and mechanism of isotope exchange and gas
reacting on the surface of solids
PERIODICAL; Kinetika i kataliz, v.2, no.5, 1961 722 726
TEXT. Use of isotopes as tracer atoms permits dire,~t
observation of the different stages in a catalysed reaction.,
The object of the present work was to illustrate. with simple
examples, the relation between the kinetics of reac;tions on th--'.7
surface of solids and the kinetics of tsotope-exchange processes
The simplest heterogeneous catalysed reaction can be written as
1~ A + X + I
2. B + (I) ~4y +
41~--
(2)
where A and B are reactants, X and Y reaction products
( ) is a vacant site on the surface ard (I) a chemisorbed
intermediate particle, Addition gives the overall reaction
Card l/ 5

3 3488
S/19 61/002/005/013/027
E1113/E485
Kinetics and mechanism
The cases considered are those of the reaction of watergas
on a magnetite catalyst at 400 to 500'C, the reaction of .-arbon
with C02, the isotope exchange by oxygen or carbon betwisen
carbon mono- and dioxide. the exchange of deuterium between water
vapours and hydrogen. All these rea:tions can be --onsid-2-r-4A
particular cases of a general equation, If the adsorbed
intermediate obeys the Langmuir isotherm this equation 16
W Kl.PA"2PB.--H-lPX".-2PY--...-
1PA " " 1PX * "2pB 2P'.
where w is the rate of the reaction 41 the rat,~ ronsTant or
the first stage in the forward direction H i that in thc-
reverse direction (K2 and m 2 same for th-~- 6&-.ond stag,;O
PA the partial pressure of A (or the product of theLr par~ia.l
pressures if several substances partl,:Ipate and so on) rf th,~
intermediate compound adsorption followb a logarithmi is:therm
then
Card 2/ 5

33488
S/195/61/002/005/013/027
Kinetics and mechanism ... EIII/E485
I(" Px'4 PY
_P
sin a;t (X' PA + )'"-,Py)' IPX + )itPB)' (20)
Here xO is the value of iij at the greatest adsorption energy
of the Iintermediate compound, and so on; a is the proportiona-Lity
coefficient between the change in the adsorption energy and the
activation energy; f is the ratio of the adsorption-energy
change range to RT. Both equations correspond to steady-state
conditions. Eq.(20) is supported by some experimental data at
medium degrees of surface coverage by the intermediate compound
(e.g. Ref.4: V.A.Yevropin, N.V.Kullkova, M.I.Temkin, Zh. fiz.
khimii, v.30, 1956, 348). The authors report unpublished work
on the reaction HDO + H2 ';�11D + 1120 in a flow systein with water
containing 2.2 or 2.5 atomic % deuterium. Since
PHDO