SCIENTIFIC ABSTRACT NAUMOVA, N. A. - NAUMOVA, S. F.

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SCIENTIFIC ABSTRACT
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OVA, IN A. Agriculturo Analysis of seeds for fungi and bacterial Infection, Sel'khozgIz, 1951 Monthly 11st ff lWaslan AccessloM. Library of Gongress, June 1953, Uncl. 1. HAMOVAO N.A. 2. USSR (600) 7. "Data for Founding the Nmissible Noma of Infactedness of Wheat Seeds by Stinking Skut", Trudy Vaesoyusn. In,-ta, Zaahchity Rasteniy (Works of the All-Union Institute of Plant Protection)p No 3, L951,, pp 101-114. 90 Mikrobiologiva, Vol XXIj Issue 1, Noscow, Jan,-Fab 1952p pp 121-132. Unclaaalfied. mumov"', 11. ~- . Analiz nemian na gribmdu I bakteriallmdu infekti-Hu (Analpip, of floA~ for f-Ingi and bacterial infection). Sellkhozgiz, 1951, 140 p. SO: Mohthly List of Rusniart Accpsni,~,ns, Vol 6. No. 3. June 1953 A, MA 11t,P&MAPOOKIM re 6ypno limmaos. IThov effect of temperature mi the Pumvelitibilit'v 4 spring Wheat during the gwwth peri(od to brown rust.1- IkIT. MPH- V- &,(- U-SJ;-R-)- A 1, PP- 39-46- 1951- As & result of firld irma at U-ningraoil. Rugov-m-Nn, Betench4k, and Irkutsk wheat varieties were c"fird arvording to their miottance to bruwn, mat (f'"Mak IrOicima) [R.A.M., is. p. M2; ig, p. .1%; So,p. 1511 into three gmups: highly "istant, fairlY resiptant, and those. such m Marquig, Mope. Ottmet. Thatcher. ,,1r4r;rww 13M19. hdrfflmns 227 11. Itorstrou 062, end Atirdrift~(1217, whome sumorepti- I)ilitv varit-41 urvall-v with the external icniperaturem during the early gmwtb 1101"'id. At the Pan-,Siviet Institute for I'lant, Prvtecti~m, Lorningrail. th; effect of differrnt mowing dotev; upcm the rorsistance of the above rnentit;wwl varieties to two mcps,'.Wand 17, of the rust was studied in the greenhouse. ItwaslixindthAtthore Od wu is wrsW" betwom tempenturs dariag pbsisms a( 4n*"mi uid fUldman dor* mciag. This relsOombip w" clouse for nwe 30 them for 17. Dwbq"w#wl~pbwmlQwOr Me 44 WWMVW t~ to red While Web tomalwaturm i Mlity. W60 t6 Ave dwive the shootift am t* did wt ow"d 8-70 C., the maraws. (krwt. aw KOPS a- lky re"O. but they tweante oboe lo 6w (manplia). IS4' (Ilepe), &ad 13.1 Thatcher, Awdeopme 027, 1wrimal t3~191 auld I I , n711 ovided to foist the disease der* oirie$ When the Average I i wm durisig their early 4mkp~mm4 did me4 eased S' to 15% but showed do kwrqwwA sumoqdibifily at 13* to 18'. Fkftber stalin am mearlal to meamish tho cfkw average tempmatwo for "Ch Variety. 0 V /-I ~ 8 . /9. NAUKOVA, U.A. Ustag ultraviolet rays to test @@ado of agricultural crops for hidden fungus infections . Bio.?iziim 2 no-3:376-377 157. (KIBA 10:8) 1. Toemorunnyy institut sashchity restonly yeeeoyUZnoy Akademit sell skokhoxyaystvennyida nauk iment Unins (UIMVIOLAT RAYS--INDUSTRIAL APPLICATIONS) (SJEDS-TISTING) (FUNGI, PHrTOPATHOGINIC) NAUMOVA, Nadeshda Alakeandroyna; RLVTfXATA. O.Ye.. red.; CHWAY11TA, I- I . ~ 7, T. 9- telft. red , - - ~ - . I . 0 0 [Good analysis for fungal and bacterial infection] Analls semian na. gribnutu I baktariallnuiu. Infektoliu. W.2. Nookva, Gos.isd-vo sellkhos.lit-ry, 1960. 196 P. (KIRA 13:5) (Seed adulteration and Inspection) (Plant diseases) . - - I I " ~ ~~ ~- * ~:w - : ~ ~.-. 1-: " -,Z I I", -, .- NAUMOVAO N.A., kand.sellskokhoz.nauk lWxmfulness of stripe ru3t infeating wheat noeds. Zashch. rast. ot vred. i bol. 5 no.9:21-~212 S 160. 04IRA 15+ (Stripe rust) (Wheat-Diseases and posts) NA111401A. N.A,j TOFIOWVSKIT,, V.A. -L.- Nov to assemble a fluorescent microscope. ftul.Qlaw~ bot. NO& no.39s"-100 160. (MU 248 5) 1. Vnesoyuznyy inatitut zashchity rastenLy. (Fluorescence meroscovy) NAWAOVA, Nadezhda Alskeandrovna; REUT.I;KAYAp O.Ye., red.; B"OVA, L.G., UFthn. - (Potato late blight] Fitoftom kartofelia. Leningrad# Izd-vo nellkhoz, lit-ry, zhurmalov i plakatovp 1961. 180 P. (MIRA 1533) (Potatoes--Diseases and pests) (Fungi,, Pbortopathogenic) SHIIAMOVAI A.S.; MMOVAO N.A. Using alkali for the peeling of horse-radish and parsley rootao Kotwei ov*prcme 17 noo7:19-20 Jl 162. (MIRA 15:6) 1, TSentralfr4y nauchno-isoledovatel'skiy institut konserynoy I ovoahchemushiltnoy proMehlennosti. ' (Root-crope-Preservation) (Canning and preserving-Squipment and supplies) SHELUMA, A.S.; ~~~~LAPUTIN, V.I.; DERBEDERVAv Z*A. DoWrorressing of fruit vg~vegetablexe ICMO* I ov, prono 18 no.&15-18 Ag 163. 1 (KIRA 16tg) 1. Mentrallm nauchno-looledovatellskly Institut konservnoy I ovoshcheaushillnoy prowyehlennosti (for Shelamoval Hawmova). 2, Voesoyuznyy nauchno-iseledovateliekly institut kholodillnoy pronyahlennosti (for Shelaputint Derbedene"). (food, Frozen) SIZLAPUTIN, V.I.j, kand.tekhn.zaL-k; DERJ;!=Ir&VA, Z.A.,, inzh.; SkUMOMI, t..S. kand.khim.nauk; _!!~ ~OV ~'~inzlh. Dehydrofreezing of vegetables and fruits. Khol.tekh. 40 no.3:30-32 My-jo 163. (miRA 16:9) 1. Vaesoyuznyy nauchno-isoledovatellskiy Institutkholodillnoy promyahlennoBti (for Shelaputin, Derbodenova). 2. Mentralln~y nauchno-iseledovateltakiy institut kanservnoy i ovoshchesushill- noy promyshlonnooti (for Shelamoval Haumova), (Refrigeration and refrigerating machinery-Research) (Food,Frozon) _~4PYMA, Nadeabda AlekftndrovnrA; ZIIDANOVA, L.N., red. (Potato late blight] Fitoftora kartofelia. 2. perer. I dop. Izd. Leningrad, Kolos, 1965. 187 p. (MIRA 18s12) a a a a 0 Is 19 w 0a *Sol ELY ffnAA fee ca ,17 008 1 see 00 I 00 00 008 jil a oat Of 41,4449 fit kka'a led bF N N 7 000 so* .00 Soo 0*0 see 11few alwassf. - I #1040ft OftiftV 4~ as I goes" -w osq W AV "1 4100, -asom III ,a 49 1""Ama some wpm 4 0an 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 MIMI 41111111901110 C a aiiiiaii waft" a Alm do - 'd poem in tk MdL V do 816L dew 10 $A md bigbw. sign see 8*0 gas ~400 Be* ,so '00 too '. . 1. .." . -- . - . I . . " Al I - -,-,; I I-,.I .: " f-, - , " - ~, L. j " - .. p "o -- i - , . I ,- -p . , . -- , , - I . . I-- . - - ~ ~-' e - ! , - , . - - I . , ;;- , i- - !, ~ 1-1. -~~ I -- -- i: ; . ; - - . ~. ~. ; ~ BUNINA. B.Z.; BZZAMCROV. P.T.; NAUKOVA. N.A.; KORSUNSrAYA. R.N. Nervous system manifestations In various forms of tuberculosis, Probl. tubark.. Nosk-we, no. 600-36 NOT-Doc 1952. (OWL 23:5) 1. Professor for Buntna; Candidate Kedlaal Sciences for Belosorov. 2. Of the Therapeutic Division (Head Prof. B. Z. Buning) and the Pathopbratological Laboratory (Head Candidate Medical Solonass P. T. Belovarov) of the Ukrainian Tuberculosis Institute (Director Prof. B. N. Khmellnitekly) and of the Ukrainian Psychonsurological Institute (Director of NeurologiW Clinic -- Prof. A. 1. asymnavlah). NAUWTA, W.A. NffGOt Of Gmll does@ of alloxan on the pancreas. Fistol.shur. 6 o,'496-100 Jk-ir 060, (KIRA 13 0) : 0 Klyffskly neditalunkly Instituta lie. aked. A.A. Bogovolltva, - Islologil I Kharlkovekly lustitut tubarkuleva. (ALWIAN) (PICM3) NAWWAO N.A. St4wilation of the Insulo system of 'Vas pawrfts by mmll doses of 4=214n. Probl. andok. I gorm. 7 no.ls53-56 161. (INSULIN) (PAROWAS) (MIFA 14s 3) C NAUKOVA 9 N.A. Zffect of smell doses of allazan on diabetic ralkits. Fixiol. shur. [Ukr.) 7 no.It"45 Ja-F 161. (KIPA 1W) 1. Department of Pathological Physiolo 7'of the Kiev Medical Institr4te. (ALLaw) (DUMESI NAflf,,!')'Vlts III. A. VIVCGRADOV, A. M. Tekhhik i NATT.~OVA, N. A. 10 Ar~6i., V, A. A. Ar?)-,. llauchmo-issledovatellskiy institut arkhitektury zhil-ishcha Akademii Arkhitekt,iry SSSR Karknsno-3hchitovyye i shchitoryve derev7amn.,,7e odnootazhnyye doma z~svodt;ko,o 17gotovleniya massovogo tipa Page 71 SO: Collections of Amotations of 3glentifig Research %-,'2rlc Qn Copstj:ucti2p. cgmlotetj in 1950. Moscow, 1951 OSTIMUN,K.A., kwaidat arkhitaktury; XAUKCVA N.A inthener; -'- -1 n 11010W,S.Ya., inshemer; n;lh;Zr Plans for apartwnt houses designed Iby GIAVSTANDARTM. Rats.1 Isabr.pireds. v stral. no.102:15-24 55. (ML 8:10) (Buildings, Prefabricated) ZAL T U. A.H~~UKOTA, N.A.; FROMM, G.T., inxh., red. tzd-va: DMIIRIMA. UA.. arkhttaktor. red.isd-va: STELELISTSKIT, I.A.. tokhn.red. [Prinelples to designing standard proaktiroyanils tipovykh zhilykh po strolt. i arkhtt., 1957. 86 p. (Apartuent houses) apartment houses] Printaipy domov. Moskva, Go*. isd-wo lit. (MIRA 11:4) SOYINSKIT. 1.D.; BLMIN. P.N.; WILIBIRG, L.A.; ZHDAKOV. P.N.; ITASHCHXUO, I.P.; LUM. G.P.0- NA=VA N.A*; SNUMOT, N.Se; ARMTA. R.1e; ~ it NINCLAYN, N.A.; SaJORAmiurpt AOJUO; KOVALMSKIY. I.1.; LORACEW. P.T.; SAWT, S.F.; 19100. A.T.; FORAYONOT, N.K. PrIalmll uchastljm: AWAISKIT, A.S.; ASKUS, U.N.; BXZR=VA, Ye.M.; I0GA2=. Ya.D.; GOLIDING, N.P.; MNSHLA . 1.P,; NOSILAW, S.A.; RABINOTICH, S.O.; ROGOVSXIT. L.T.; KRCMWVA. L.P.; MUMEOPIL. I.N.. RODAIWO9 D.R., glaynyy red*; GALKII, T4.0., samst.glavnogo red.; SAPRYKIN, V.A., red.; SHCHIP1120T. T.N.. red.; NOVITCMWO. I.N.. nsuchuyy red.; VILKOT, G.N,qInxh,,, red.Lud-ye; TTAPKIN, B.G.. red. isd-va: ALIZINA. 2.M., tekhn.red, (Building your own hom I Spravochnik IndivIduallnoge sastroishchlko. Moskva. Gos.Ixd-v* lit-ry po straitemoterialsm, 1958. 442 p. (Kin 12:2) 1. Akedemiya stroitollstva i arthitaktury S55R. (Building) NAU,MDVA, N.A. --1-,--.-- 1 711-- Theoretical principles of the record"n,7 o" plant diseaE-,~s developed by A.A. JAchevskii. Tnidy 7117~, no.,-'3:14')-154 I ~,/, - 11)::", Aw!MOX-MIKOV , G. 1). -k I U Ua,~ 2 tl,.-Vy .;ubc. rl!~,,-l y rvv- i,c 1. TSentralIny, (for Ata-mairtlukov's Ynfl V i BARDYbrfFV, I.I., YUPWWO, V.I., ERILANTE, A F.; NAUMOVA, N.I. Continuous esterification of rosin. Gidruliz. i losokhim.pron. 17 no.2t2O-21 164. (AURA 17:4) 1. Institut fizicheskoy i organicheakoy khimit AN Belorusakoy SSR (for Bardyshey). 2. Kiyavskiy lesokhimicheskly kombinat (for Yefiwnko, Erilwm, Haumova). Al k) L( /~., () 1/ 61 Al f-~, . USSR/Kedicine Paratyphoid B, Heidelberg Type FD-3312 Cdrd 1/1 Pub 148-8/24 Author Kaslov, A. L and Naumova, N. K. Title Certain problems involved in the epidemiology and microbiology of Heidelberg's infection [Paratyphoid R, Heidelberg type] Periodical : 7-hur. mikro. epid. I in-un. 10, 42-45, Oct 1955 Abstract : Heidelberg eticroorgenisms were observed in the stools of patients hos- pitalized In the dysentery department, in clinically healthy carriers, in wash water used to clean objects used in the preparation of food, in pork, and In the excrement of a hog. Heidelberg bacteria were elim- nated by patients hospitalized for dysentery for from 1 day to as long a 2 1/2 months. From its action on the human organism, the authors ! conclude that it should occupy a place in the Salmonella group inter- mediate to Schottmuller and Breslau bacteria. The article Is illus- trated by one chart. No references are cited. rMstituion : A Sanitary-Zpidemiological Station (Head Physician - I. S. Naumov) Submitted ; September 30, 1954 KOSTYUKOVI, V,A.; STUKALKIN, A.K.; NAUMOVA, N.N. Contactless revolution relay. Sbor, nauch. trud, EINJI 2:186- 195 f62, (KMA 16t8) (Electric relays) (Electric looomotives-Brakes) HAU140VA.N.N. Species of Saprolegulaceac now to Leningrad Province (Saprolegnia- cearum regionis Leningradensis species novae). Bot.aat.Otd.spor. rast. 10:134-137 J& 155. (NIBA 8:7) (rAningrad Province--Molds (Botany )) MAUKOVA.I.N. New epooles of fungi on barberries (Species novae fungorum In Berberlde vulgari L.). Bot.mat.Otd.spor.rast. 10:163-164 Ja 155. MRA 8:7) (Barberries-Diseases and posts) (Fungi) ZAIFROTA, N.ra,,; HAUWTAq N~V* A~ - Some characteristic features of nouse life in forest dielterbelts. Tindy Inst.geog. no.66:150-1" 155. (MA 8:7) (Klee) (WindLbreake, abolterbalts, etc.) XAMTA. N. N* Now methods of prepalriag entomological collections. Pr1rods, 45 mo*81127 As 156o (=A 9t9) lJoalngrodskly gesudarefteaM univereltat Imeni A.A.Zhdaneva. (Imsects-Collection and preservation) MAUNOTA, N.V. l4oung asturelisto in the Ilskmes Autonomous ?roviwo. Diol. v ohkole no. 304-65 Ny-je '58. (KIRA 11 -8) 1. llhakeeskiy oblastnoy inatitut us over shone tvoTo nlys ucbtteley Krannoyerskago, krays. (9bakese Autonomous Province-Agriculture--Study act teschtng) MIUMOVA,O.A. Iffect of mastication on vascular reactions In man. OPYt Isuch. regofisiol.funk. vo-3:3o-43 54. (KUS 8:12) 1. tafedra normallnoy fiziologil Leningradekogo maditainakogo otomatologichookogo instituta (KASTICATIM) (RIWUMS) (VASCULAR SYS71K) IIAUMOVA, O.A. Changes in the higher nervous activity as an effect of the total amount of organic substances in room air. Uchozap. Mosk.nauch.-issl.inst.san. i gig. n0-3:60-61'60- WIFA 16:7) (COUDITiONED RESPONSE) (AIR-POLLUTION) (RESPIRATIOTI) SUAIEVA, Ye.M.;,IIAUMOVA, O.A.; GI11MBURG, Yo.G. Role of the =ygen factor In preventing increased coagmUbi-lit.7 --,f the blood in experimantally induced nervous Unsion. Trudy Goo. nauch.-IB91. psikhonevr. inst. no.24s6l-65 161. (14IRA 15-25) 1. Patofiziologichookaya laboratoriya Gosudarstvennogo nauchno- isaledovateltakogo psikhonevrologicheskogo instituta imani Bekhtoreva. (STFVZS (PHYSIOLOGY)) (BLOOD-COAGUIATIOII) NAUMOVA, O.A., kand.rned.nauk; BLIPMER, L.I. , ke-ni.med.nauk Scientific conference on hygienic problems in water'transportation. Gig. I san. 26 no.12:99-24 N 161. (HM 14S 11) \*NATAL HYGIENE) ZELIGEER,, 11. B.; ADIGHATEV,; HAUMOVA, P. A.; ClikYlEGY, S. D. NAUMOVAA P. A. "Telegraph Foundations," Moscow, The State Publishing of Literat-ire cn problems of Comminications and Fadio, 1950. ;- - I .. - :- -~ ~~,"~., .- . . 4. - Wamy# R.V. I. X11MUMNA, R.I.; UUMNA, P.I. Transition t"peratmes of m1tiphame Uquid states. Zlrtw.ob. khim. 32 noJW65-1368 W 062, (mm 1515) 1. Saratovskiy gosWarstvemWy univeraitst. (Phase rule and equiUbrium) MAKOVp I4uben# NAUNDVA, Roza,, inzh. Use of polyethylene in the gluing of garment parts, Teksti1na prom 12 no,4t22-24 163, 'I/ I--- KOSTOVP V., inzh.; NAKOV, L.; SAVCUV, Ch., inzh.; IIAUMOVAI__R~.inzh. Fireproof finishing of cellulose fiber articler. Trud Inst tekstil prom 3:21-34 162. N!"JI-4CIV A 9 1 i~)Z" 9 In . , Ghavdir, Inzh. A reexamlr~at!Tr of s-)-ce te chno logic FG. prnc-,~,25,-f- ' ~r boiling rnd bl,~-ttrhing of flax yarn and ffinr-'c-i - rn recurrent method of bleaching with hypc-,~Iora~r 6-,r! hyar~~- gen peroxide. Takatllna prom 11 no.6j25 162. ~- - , ~ !- .. '," ", 11'~?Ili!-IWF-11~ t1r.", 111 :9 ~1~1. NAMOVA, R,, inzhe, nauchen sutrudnik; SAVCHLV, Ch., inzh., nauchen Bleaching or linen yarn and cloth. Trud Inst tekatil prom 4:71-83 163., SEMENOVI S.M.; KORGIIAGIN; V.B.; NAUMOVA R.G.; SJVMS!'-~FTNA, 1-3. ------- -=- Study on the Stability of the antlp?~ag,'- a~tll~n r-f Antibictiki 9 no.1%81-84 Ja 161.. ,Niip-;, A -,,' 1. Vaesoyuznyy ~9 Mo 9 kva . Axtu"OvIto k. All. R~TMLIRAIJKogkva) Intrwanous Weations. god. sestra no.1:15-19 Ja 155. (KM 813) (UnCTIM, Intravenme, tochao) KAUMOVAq R.P. Comparative study of napthLlene-oxidizing bacteria in underground vatero. Kikrobiol~oia 29 no.31415-4M II)ae 960. (KM 1397) 1. VaesoyumW nauchno-insladovatellokiy institut gidrog6ologil I inzhenendy geologii, (PSEUDGHOW) (NAPMHAME) (MROLEUH--UCTERIOU)GY) NAMMAP R. P.m, kand. med. nauk (Odessa) Diagnostic and prognostic significance of serum aninopbera"s in Botkin's diseaso. Klin. mod. no.2:58-62 162. (mru 15:4) 1. Is kafedry infektalowykh bolesney (sav. - prof. L. K. 6 all Ei~tek kogo zeditainskogo institata inani N. I. 'IdIr?d azaeluzhannyy doyatell nau)d rofe I* Ya. i goro;skoy Infekt9lonnoy bol0nitsy Tglavnyy vrach L. T. Zhidowlenko) (TWSAMINASES) (HEPATITISP INFECTIONS) NALMOVA. R. P. *Treclpiti~tion Fanctiu. for thi 1)i, n~,~j!3 of Tl,,, -qnth1,,3-,Ls (As-vrldpo an4 Tacniarbynchus).* Cand Med Sci, Odessa Medical Inst, Odessa, 1953. WhBiol, No 7, Doe 54) Survey of Scientific and Technical Dissertations Defended at USSR Higher Educational Institutions (12) SO: Sum. No. 556, 24 Jun 55 r r; t - ,1% ./- . ' , MAUMOTAI R.P. Antlgealc properties of Ascarls and Tasnia saginata. Nod. paraz. I paras. bol.24 no.2:114-117 Ap-Js '55. (NLRA 8:10) 1. Is kafedry lnrektolonwfkh bolezney (zav.-pror. L.K.Koroviteldy) I kafedry blokhtull (saw.-prof. D.A.?Smverksloy) Odeaskogo meditsinakogn inatituta iment N.I.Piregova. (ASCARIS, lumbricoldes, antigenic proportion) (TAMA, saginata, antigenic properties) (ANTIaM AND ANTHODINS, Warts lumbricoldes & Tasnis saginata antigenic pro- perties) ROURMUN, M.G.; =NOVA. R.P. . ClIaloal "peau wA treatmeat of bUck wolf spider bites. Trach. delo no.2:191-194 r 156. (xm 9:7) 1, lkfadra Infektolonafth bolenney (savedurushchty professor L.K. UravlUkty) Odeaskogo w4ttainskogo Institute, i OdLeeskays, gorod- AV& protivwmalWlymys, stantelys, (Man-IMIOLOGICAL W T) (SJPMM) KCROVITSCIT. L.K.. professor; MAUKOVA. R.?. "IMMON Course of recurrent and liv4gering forum of paeumococcal neningitts. frach.delo no.5:477-479 NY 157. (KERA 10:8) 1. Klinika infektsionnykh bolesney Odesekogo neditainakogo instituta I gorodakaya infektotonneya bellattea (NIKKGITXS) BOG014OLOVA, T.T. [Bohomolova, T.T.1; %V4,0VAP R.P,. Use of brucello-hydrolyeates In diagnosing brucallosis In man. Wlkrobiol.shur. 21 no.4:44-47 159. (KIRA 12:11) 1. Is Odeaskogo moditainakogo inatituta. (BRtMELLOSIS diag) NAUKOVA, R.P. .................... Variations of the clinical course of polsonine canoed by the kRrakurt, Ned.parms. I parasebol. 28 no.2:227-228 " '59. (MIRA 12W I* Is kafedry Infektalono7kh bolesney Odenskogo meditatuskogo Iftstituta Iment N.I.Piro*va (dir.inatituta - prof.LUAlwynelm, xav.kmfed.roy - prof*L.K.Korovitekly) I Odeaskoy Corodskoy Wektalonnoy bollnitay (glavnyy vrach L.I.Zhidoylanko). (ARACHMIDIOX Latrodoctue tredect"r) ttatus bites, variations of clin. course (Rua UUMOVAj, R.P.,, kand.med.nauk (Odessa) Glinical characteristics of anicteric and *low ictericO form of Batkin's disease* Yelld. i akush. 25 no.402-34 Ap 160. (MIRA 14s5) (HEPATITISO INF=IOUS) latIVAU,-WHMMWt H,l,j ~~Tm&-RAE-- Skin test for the d1mgmels of infectious hepatitis, Vroch, delo no. 496-100 161o (MIRA 14W 1, Virmologlobaskaya 3,aboratori)s (rav. - prof. 1A.K.Gimellfarb) Odemakogi iiitituts, epidemiologii i mikrobiologii i kafedra inf~ktaionn7)& bolemey (mv* - prof. L.K. Korovitakiy) Odeaskogo maditalukogo institutas (HF.PATITISt INFECTIOUS) WADKOVA R. P kwid. sod. nauk; STZFANSWA,, A. V. Diagnosis of effaced forms of Botkin's disease. Aracb. delo, no. 3 2 109-2U Mr 162. (KIRA 15:7) 1. Kafedra infektalonnykh boleaney (save - prof* L# Fe Karo- vitakly) Odeaskogo meditsinskogo institute. (HEPATITISO IMFZCTIOUS) NAIMVA R.P , kand.md.nauk Sme severe complications with the use of antibiotics in ouppurative mningitis. Vrach. delo no-5:83-85 My 162, WIRA 15- 6,, 1. Kafedra lrifektalonnykh bolemey (zav. - prof. L.K. Koravitskiy) Odesskoga moditainskogo instituta i goradskaya 4nfektsionnaya bollnitea. (HENIEGITIS) (ANTIBIOTICS-TOXICOLOGY) GRM3TM,, G.I*,, dotsent; HAUMOVAp R!P- kand.med.nauk j Course of the toxic form of diphtheria in recent yeare Pod., akusho I gin* 24 no.ls6-9162. (MIhA 16:8) 1. Klinika infektsionnykh bolezney (zav. - prof. L.K. Norovitskiy [Korovjvtvkyi.L.K.J) Odeaskogo meditainakogo insti- tuta (rektor - zaaluzbenrqy deyatell nauki UkrSSR 3.1a.Deyneka [Deineka., I.U.1) i Odeaskaya gorodska infektsionnaya boll- nitsa (glavrqy vracb - L.T.Zhidovlenkor. (DIPHTEMU) J-:f MWOfAv R.P.t kand.med.nauk (Odessa) Significance of cytologic study of liver ptweUttes In the dif- forential diagnosis of Votkin's disease. Virech.delo no.1:133-135 A 163, (MMU 16s2) 1. FUnike, infekWounlkh bolexasy (var, - prof* L.K. Korovitshy) Odeaskogo meditainskogo instituta, i gorodakale infektalannays bolOnitaa Odessy. (MCFATITISp UMTIOUS) (LIVER-BIOMY) KRIVAYA-USIfIRENKO, N.I.; NAUMOVA, R.Em., Study of the skin test in the dynarrics of epidemic hepatitis. Vop.med.virus. no.9:86-90 164. (141RA 148i/.) 1. Iz Odeaskogo Instituta epidemiologii i mikrobiologii I kafedr-I infektslonnykh boleznoy Odesskogo medltf;inqkogo instituta. . NAUW~TA. S. t. Dlssertm~iloas' Mthe 111notlas of InUbItod hIMAution of Notbyl Nothanorylate.0 CmA Chm.gal, Inst, of Obodstryt Acad Sal.Bolorusslan SSR, Minsk 1953. V--30928 SO: - No, 5. Doe 1953. Moscow, AN USSR ( 1111) n.'~ , ". R- . -. '. -~~ ~4'-~ ~, it-ill Mu kEy, --h Lit Namol-NN" Alk Z4, 'Nuf. V?'dji 11pull. ~:'C' ra k Te u -s" -~x -x 'wfu o-bWacd, whkh ZJ ter 8-P;1(1 xev-Y&tn. f to ~ i-. k1c. 1"a"rP pure cryst, xbLttic-rl,6(f -bJj.,. co'df., C' A r,-2S'X JOUvr4-1.72), A 6inho'u, -W2Ek 8,dd at) 3j Ullt-11 by b,:-3ting at P h-Azinn tin,pi. rLa13c of r~,c.t,-4 O.it of 11 11iffICT frOM C3t-h Vth'f .11--id, '.-~,TF. ! 21jo-3-5o 111g. uIth'Illa'.2 tl~ev- diviw t,';e ~'Imc Ak)rptiral speoram at 200-2b.; ma. ,%crc f imci ~1- in "CH. Im. -mt i-'i thc 'F r'vatvns' !,,I, '-j thc pzcptl:~.; -u;d'!'V.11l;~'j 1"P. PI-Mitig 101,11 ag"tL'I-t 4&t -Ul- 'u-p(li, co'M b~. lvx:,~tell 4-rit a %tr:agilt -till! d.tta for tile 4 c;Citil'* bc, A134) walght-ii7~e hali: ball obt.~iliv'l hy sting i~cid tio, az-aintt a ra~imil lt 2!~(', Iuu, or uji, IrOaLd,to its acid no., 4, by Ulu efluati,31k.. Iaj' + in aod P3 7 0 A' purt I it 11. jf.tf-l 1 3-1 'f-'I'Afjflt!%j 'arial '.1i wil"i) ill ti,tv li'lie. It xfi~'4-'P If-:,t ~7~4AW 'Mw* this 4"4 - f C Er, v ILI Al i NaM I -T7 z7lu T7 NAUY-OVA, S. F. and B. V. YEROFEYEV "Inhibitory Effect of Hydroquinone cn the Polynerizatior. -f' Methyl Methacrylate" Sbornik nauchnykh rabot, vyp. 6, (Collection of Scientific Works of ,he Iriotitute of Chemistry, Belorussian SSR, Academy cf Sciences, Nc. r~) Minsk, lzd-vG All Belorusskoy SSP, 1958, 271 pp. NNUMOVA, S. F. and B. V. YEROFEYEV "Thermodynamics of Some Reactions of Oiganic Sulfur ~::=pcunds-" F. 83. Sbornik nauchnykh rabot, vy-p. 6 (Collection of Scientific Works ~f the Institute of Chemistry, Belourussian SSR Academy of Sciences, No. 6) Kinsk, Izd-vo AN Belorusskoy SSR, 1958, 271 pp. SOV/81-59-10-37459 Translation from: Referativnyy zhumal. Khimiya, - 1959, Nr 10, P 577 (USSR) AUTHORS: Yerofeyev, B. V., jVaumova, S.F. TITLE: On the ~ihibiting Effect of Hydroquinone on Polymerization /of Met,h Imetha- crylate PERIODICAL: Sb. hauchn. rabot In-ta khimil AS BSSR, 1958, Nr 6, pp 190-227 ABSTRACTs The kinetics of the polymerization of methylmethaerylate In ~.he presence of hydroquinone at 65 - 800C has been InvestigaW4. Tho polymerlzntlon rate obeys the equation (vo - v21nh)/v,rh _ (kol/ko) keC (v, and vi,,h are the rates of polymerization In the absence and the presence of an innibitor, kol, k end k are the constants of the rates of the rapt,;re rear;tions on an iQbitor, 9at the interaction of two polymer radicals and the react-ion of chain growth, M and C are the concentrations of the monomer and the In- hibitor, respectively. A diagram of inhibition has been proposed, accord- ing to which hydroquinone breaks the reaction chain as a result of the Card 1/2 direct interaction with the growing polymer radicel with formation of ben- 39;/81-59-10-37459 On the Inhibiting Effect of Hydroquinone on Polymerization of Methylmethacrylate zoquinone and probably semiquinone, as an Intermediate product, which also break the L-,--- chain. A. Pravednikov Card 212 79-28-5-38/69 AUTHORS; Yerofeyev, B. V., Yemellyanov, N. P. I TITLE: On the Absorption Spectrum of Cyclohazadiene-1,3 Within the Range of From 220 - 300 ap (0 spektre pogloshchaniya taiklo- geksadiyena-1,3 v oblasti 220 - 300 mp) FERIODICAL: Zhurnal Obahchey Khimii, 1958, Vol, 20, lir 5, pp,, 1284 - 1286 (USSR) ABSTRACT: The absorption spectrum of cyclohexadiene-1,3 in the ultra- violet range has been investigated in a great number of papers (References 1-3), however, the reaults of different authors do not coincide. In table I the magnitudes found by different authors for the maximum positions and the absorption coefficients are mentioned. The given data (table 1) show that the results of different authors who investi-ated the absorption spectrum of cyclohexadiene-1,3 in the ultraviolet range do first of all not coincide with respect to the number of maxima on the absorption curve. It is possible that this deviation of the data of some scientists is based on the insufficient purity Card 1/2 of the investigated product. In connection with this the authors 79-26-5-36/69 On the Absorption Spectra of Cyclohexadiene-1,3 Within the Range of Prom 220 - 300 mp took the absorption spectrum of cyclohexadiene-1,3 in the ultraviolet ranE;s. The product was synthetized in the Labora- tory for Technicai Analysis of the Institute for Chemistry of the AS USSR and therefore can be looked upon as a purar com- pound than that of the other scientists. Thus tne absorption spectrum of cyclohexadiene-1,3 has, contrary to earlier data, only one maximum within the ultraviolet range (220 - 300 mv) which,as regards its vapors comes to lie on 250.5 mp (Lge- 3 73) and/as reeards its solutions in hexane and alcohol ', on>,. 2 58 wo (LgE 4-oo). There are 2 figureo, 2 tables and 3 references, none of which are Soviet. ASSOCIATION: Inatitut khimii Akademii nauk Belorusakoy SSH (Institute for Chemistry, AS Belorussian SSR) SUBMITTED: April 29, 1957 Card 2/2 TEROJIM, B.V.; MUK*A, S.jr.* TSTKAIO. L.G.1 ZHATNEM, N.A. Polyswrisation of 2,3-cyclohemadions. Dokl-AK BSSR 3 no-3-95-99 * 159. (91U 12 ' 8) (Gyclohazadism) 5/081/61/000/021/093/094 B106/B203 tAUTHORSt Yerofeyev, B. V., Naumova, S. F.. Kulevskaya, I. V. . ................................. , TITLEs Initiation of ethylene polymerization by a complex of etherates of Grignard compounds and titanium tetrachloride PERIODICALs Ref6rativnyy zhurnal. Xhimiya, no. 21, 1961, 507, abstract 21R55- (Sb. nauchn. rabot. In-t Piz.-organ. khimii AN BSSR, no. 8, 1960, 60 - 82) TEXTs It was shown that etherates of butyl mWesium bromide and phenyl magnesium bromide synthesized in anisole at 100 - 1200C formed an active catalyst with TiOl 4 for the polymerization of ethylene. The polymer yield was doubled when increasing the ratio HNgX s TiCl 4from 1.4 to 1.7. Etherates containing (C 2R5)2 0 did not,form an active catalyst with TiCl 4' ~bstracterls notes Complete translation Card 1/1 25265 S/190/61/003/007/009,/021 ?,03 B101/B220 ---------- AUTHORS: Naumova, S. F., Tsykalo, L. G. TITLE; Thermal polymerization of cyclohexadione-1,3 PERIODICAL- Vysokomolekulyarnyye coy:?dineniya, v. 3, no. 7, 1961, 1031-1033 TEXT: The aim of the present paper was to achieve a clarification of the widely varying publication data with regard to the polymerizatlDn of cyclohexP.diene-1,3;(C6H,). The authors supposed that an impure initial C6118 might be the reason for these different data. S. F. Naumova P.~ al. has developed a new method for the production of pure aHaand the spectroscopic control of its purity (author's certificate no. 110964, 1958; Zh. obshch. khi,aii, 28, 1284, 1958). The resul.9 of ttip polymeriza- tion of this pure C H. Rre given in the present papor. Frotinly Jistilled 20 20 C8H8, boiling point 60-50C, d 4 (,.8440; nD 1.4746. logE z 4.j0 for Card 1/4 25L065 s/i go/6 1/'r)o3/1-'-07/r-)09,'()21 Thermal polymerization of ... B101/B220 Imax ' 25B MA, was dissolved in hexane and alcohol, filled inte ampullae and liberated from air by freezing in vacuum. The sealed ampullae were heated in the thermostat at 100, 130, 155, and 2000C. The molecular weight of the polymers was determined cryoscopically in benzene. The data for a temperature of polymerization of 100-1550C are indicated in Table 1. The coefficient of polymerization amounted to 6-9 and was, thus, 4-4.5 times larger than that found by P. S. Shantorovich and 1. A. Shlyapnikova (Vysokomol. aoyed., 2, 1171, 196o). At 2000C, the polymeriza- tion was effected without Initiator. The degree of conversion amounted already after 10 hr to 83,-0 and increased to 88,~J, if the reaction lasted lonGer. The dimer determined after precipitation of the polymer by methanol and distillation of '.e solvent and monomer amounted to 33-50,.." the liquid polymers having a higher molecular weight than the dimer, to 12-22~o', the solid polymer to 17-33-5~ of the total yield. If the reaction was continued for 40 hr, the proportion of dimer did not change. Thus, the dimer is not able to participate in the reaction. P.A. va-r-V4v and L r,.. Vnllfqnn are mentioned. There are 2 tablea and 7 references: 4 Soviet-bloc and 3 non-Soviet-bloo. The moot important reference to Card 2/4 ermal polymerization of ... 25265 3/19 61/003/007/009/021 3101yn2o iglish~-language public~ation reads.ac follows: A.W. Crossley, J.Chem. le., P1, 1403, 1904. 1i SOCIATION: Inctitut fiziko-organicheskoy khimii kN BSSR (Institute of Physico-organic Chemistry, AS BSSR) BLUTTED. September 26, 1960 rd 3/4 AMORS: Yerofeyev, B V., ffaumova S. V P . Tsykalo, L G TITLE: Polymerization of ethylen-~ in the aluminum anisolate and titanium tPtrach1--)r2dP PERIODICAL: VyrokomojekulyarnyyP soyedinenlya. - 1707 5/119 6,100110,1/0-Z O-~ B, 10YB101 Kulevskaya- I VM Ft r presenzc, ~f tn- comp"~~x 0- vno TEXT~ Initiators from triethyl aluminum ansolatlr- (A) and TiC,, ~T, for -thylene polymerization have low self-inflammabilt ,y The th- properties of polyethylene (PE) prod-,iced with them, and th,~ -ffr-,-t -f the A-T ratio on -,to properties The AI(C2H05 CH5OC6HZ was proparpd nV reaction of brorrio ethyl wi th lufg-A! alloys k.gOA A~ ; 60A XF i r, an. a ' , 0 rro I P /1 *L,~, r o f A (bol 1'. ng po 1 n' 97 - 105 C/4 - 1, "Irn Fev) Wa, d -- S --, n heD',ane 11he TiCl4concent ra t1 on i r, r; - hpp tarip was 0 4 m~i' r- z,'. , , P:" Ethylene was pressed Into the reaction veseel at 12 liters/hr At f,~-t n-heptanp, after this TiCl In n-heptare. ind then. luring I m.n, A ~.r. M 4 .ard '13 A r 3/11 go/ 6 ."0() 5 1'r). c Polymerization of -~thylcnc. in thp. B , '0I/B10 I n-heptane wer,- added. Aftor 20 min, PE was precipitated by mear-,i f CHAOH with i~o HC', The I abul at ei v a I uos wi~,ro fclancl -;nde r atmo9php pr.,Uwlr~ at 50 0 C The den3ity Ic'"rii1ri-I .n victurp -ia, 9, 0 97 WIth in~roasing A-T ratio und :onetant T. thA moler,-u.aT f A ar / gn, of PE drops Then the arnuint alc-rm!iipEi th~ nuint.- c,f rosulting polymer ma~:r-,mclecule clia-.ns Thi A ~ T ra f I () wa s < and 1 . 6 In t t 6 Wh PE ob a. n, j Dy means r c a num an j T:.Cl R-f w ) had mr cu 1. ar wel gh .,3 000 0 QAO 1 11 C. the m-. Arr- 000 and mp"ting temp,:?r&tures :)f 11~ IZ9 f the a.,thors' PF wpre 9' 000 ~',6 000 t ,0 C T h e e - r a f + r, - 1~ T~C~ d ra+.,.() truism,,, i a. i7-r,im yno r p. J1 e X T ELI - e r q~ 'N r a~.K,:agc, p r ri, A C-~ E Padtn Afil- lulyr.vm- utlov of uthylvne in the ... B11U/B1O1 A330CIATI ON : In.9 t I tu t f i zi It o o rj.. an i. chesk oy khi nj i I AN B55R ( I n at I tu t e r) f Physical and Ort-unic Chemintry AS B'"S11) ~;U B !!l TT L D: December 26, 1960 Tv.b le. Ethyl;:nll' DOlylfieriZati0n. 1,(~-'und: (i) tu3t no.; (2) amount of initiator conponentq; (4) polyethylene yield, g; (5) molecular weight; (6) meltinC point, C. Roaffnemn Omannerms G) ~) IDISIOX 0 MOAP.117.1"Pffus ~ T. ro A. T. AIT ALMOA ACOAU 1,23 6,0 0,21 1,37 116000 ; 128 2,47 0 0 0,41 1.98 z 600 i' 1 "Y) Tab I e 3 3,70 6:0 0,62 2,60 180000 127 A I'm 5.0 0,70 2,3A - - 5 4,0i 6,0 0,82 2,89 91000 110 11 6,57 4,0 I'M 2.52 91 OW t3o card 3/3 NAUKOVAq S.r.; KOVALEVA9 V.N.I"ZHAVVERK09 K.A. __or Production of li,2-Mydronaphthalens through 1#2j,3#,4-t*trahydro- 1-naphiol hydroperoxide. Dokl. U BSSR 5 noo3slo9-111 Mr 1619 (KM 14:3) lo Institut, fiziko-organicheakoy khimii AN BSSR. Predstavlano akadmaikow AN BSSR B.V. Yerofeyevyu,, I (Niphthalene) (waphthol) 11R. 3/786/61/000/009/001/006 1065/1242 AUTHORS: B.V.Yerofeyev, S.F.baumova,_V.P.Markyking I.V.Yulevskaya, L.G.Tsykalo TITLE: The dependence of the molecular weight of polyethylene on the TiCl 4/Al(iso-.C4H9 )3 ratio'in the Ziegler catalyst 0"UURCE: Akademlya nauk Beloruaskoy SSR. Institut fiziko-organi- cheekoy khimii. Sbornik nauchnykh rabot. no.9. 1961. Monomery, avoystva I protsessy polucheniya polimerov. 59-62 TEXT: In the polymerization of ethylene initiated by a Zie&ler catalyst with excess TiCl , the molecular wei ht of the polyc-thv- lene obt;)ined Increases w1th decrease of the MR 3]/[Tir,141 ratio. These findings disagree with the data of Badin (J.Am.Chem Soc. 80, 6545, 1958). The polymerizations were carried out in a giass vessel equipped with mechanical stirrer, reflux condenser, gas in- let tube and a burette for the introduction of the dissolved cata- lyst components. Molecular weights were determined viscometrically Card 1/3 5/786/61/000/009/001/006 The dependence of the molecular ... 1065/1242 (in decalinet at 135 OC). The interpretation of the experimental results is bE.sed on the assumption of a very high value for the stability constant (K) of the complex TiCl4 + AlR3 TiCl 4' AIR so that K >> 1 LrTiCl 410 + [AIR 310 where the subscript o,uenotes initial concentrations. Then the concentration W of the TiOl 4' AIR3complex can be represented by the approximate expressions rTiCl [XII --j [TiCl 410 for L 4 0 -~ [AIR 3 0 14" A~j [AIR 310 for (AIR 310 < (TiCl 41 the component at the lower concentration being the limiting para- meter. Since the degree of polymerization Is inversely proportion- al to the catalyst concentration [X)-I)q the molecular Card 2/3 3/766/61/000/009/001/006 The dependence of the molecular ... 1065/1242 weight of polyethylene will increase on decreasing the [AlR 33/ TiCl ]_ ratio when [AlR 11 < (TiC141 , or on increasing the [AlR 31/(TiCl4] ratio whin~[AlR 31o"~ eTiC'4]0. There are 3 tables. Card 3/3 3/786/61/000/009/002/006 1065/1242 AUTHORS: B.V.Yerofeyevq S.F.Naumova, V.P.Mardykhin, O.D.Yurina, A.ii'..'Zonovulova- TITLE: The polymerization of ethylene in,the presence of butyl lithiwa and titanium tetrachloride SOURCE: Akademiya nauk BelorusLkoy 33R. Institut fiziko-organiche- skoy khimii. Sbornik neuchnykh rabot. no.9. 1961. Monomery, svoystva i protsessy polucheniya polimerov, 63-70 TEXT: Catalyst systems containing lithium organic compounds are capable of initiating stereospecific polymerizations. VaAiMUM yields of polyethylcne are obtbined at a C HqLi/Tiw ratio of 4 '14 about 2. The activity of the catalyst depen 8 on the atmosphere in which it was formed. Highest activities were achieved in an .et.-iylene atmosphere, lowest in nitrogen. The purpose of this work was to study the mechanism of polymerization of ethylene with C4Hc)Li./TiCI4 catalysts. A cylindrical double-jacket glass vessel, Card 1/2 S/786/61/000/00J/002/C06 The polymerization of ethyleno in 1065/1242 equipped with a mechanical stirrer, reflux condenser and gas inlet tube reaching the bottota wac used for the polymerizations. The polymerization reactions -;,ere continued for 20 mins. at 300~;. The reaction mixture Yvas 1,oured Into OAceso ethanolt the precipitate was collected, washoug and dried in vacuo at 800C. Viscositler, were determined at 1350C. The pr7pertles and molecular weights of the polyethylene samrles obt~Aned at different 0 H Li/TiC14 rrtloe are practically ind-penoent of catalyst composition, (as long a8 C4HgLi/TiCl4 > 1). The or(Jer of' addition of -the catalyst compo- nents is of major importance. Fourfold higher activities are ob- tained when C4H9Li solution is added to the TiC14 solution. Tnc_~,e observations can be explained tentatively by asLuming the formation of the very unstable complex 2 C4H9Li + TiC14. There are 3 figureo and 1 table. Card 2/2 S/786/61/000/009/003/006 1065/1242 AUTHORS: B.V.Yerofeyevj S.F.Naumovaq L.G.Toykalo TITLE*. The mechanism of' thermal polymerization of 1,3-cYclohexadiene SOURCE: Akademiya nauk Belorusekoy SSR. Institut fiziko-organiche- skoy khimii. Sbornik nauchnykh robot. no-9-1961, Monomery, evoystva i protsessy polucheniya polimerov, 71-79 TEXT: The thermal polymerization of lt3-cyclohexadiene with the simultaneous formation of the dimer (1,4-ethylene-104,5,6,9910- -hexahydronaphthalene) and polymeric materials of unknown molecular weights has been Studied by Hoffmann and-Damm (MitteilunG 3chle- siach.Kohlenforschunginstitut, 2, 97-146 (192~); Chem.Zentr.,. 1, 2342-Z344 (1926); Chem.Abstr. 27f 1249 (1928) . The purpose oT this work was to study the mecRa-nism of this polymerization. 1,3- -cyclohexadiene was prepared from cyclohexene hydroperoxide. The monomer was placed in ampules# connected to the vacuum system, Card 1/3 S/786/61/000/009/001-00( The mechanism of thermal polymerization-IOWI242 degassed and ~,eUed oft' under vacuum. The sealed ampulec ;.ere placea in baths thermostated at bet;-.,een 80 and 2000C. The polymor was precipitated by the adaltion of four volumes of methanol. The precipitate wa6 dis6olved in buzzzene, reprecipitated YAth methiinol and dried to constant Aeit:ht in vacuo. The dimeric matprial %as 71-itation by vacuum distillation of isolated after the first 1-reQlp the solvent and monomer. The quantity of trimer formed wa-,- ev Ilu- ated by difference. l'olymerization runs %,ere carried out Pt 2C.C, 180, 1601 130, 100 and 800C. The dimer and trimer are probably if.- capable of propa6atine the polymeriLation rei,ction. The lure -iimer did not undergo thermal polymerization. The rate of' polymerizition increased with rise in temperature, but the molecular weights of the polymers formed viere practically identical. Longer polymeri"'l- tion times did not change the concentrations of dimer, trimer and polymer formed, The formation of the dimer is thus a parallel reaction and not an intermediate stage in the polymeritation. The first stage of polymerization is the formation of an activated dimer molecule which can react in three possible ways (a) it can Card 2/3 S/786/61/000/009/003/006 1065/1242 The mechanism of thermal polymerization... undergo inactivation, giving an inactive dimer as final product, (b) it can react with a monomer to yield benzene and cyclohexane through 4ioproportionationg or (c) it can form an active trimer molecule which can either form a "dead" trimer through inactiva- tion or combine with a monomer and form an active tetramer which will propagate the polymerization with the formation of high poly- meric material. There are 5 figures and 2 tables. Gard 3/3 s/786/61/000/009/004/006 1065/1242 AUTHORS: B.V.Yerofeyev, S.F.Naumova, T.P.Maksimova TITLE: The effect of TiCl on the polymerization of 1,3-cyclo- hexadiene in heptaAe solution SOURCE: Akademiya nauk Beloruaskoy SSR. Institut fiziko-orgeniche- skoy khimii. Sbornik nauchnykh rabot. no.9.1961, Monomery, evoystva i protseesy poluchenlya polimeruv, 80-87 TEXT: The yields vary nearly linearly with vTTTM747. In all ex- periments an insoluble polymer (30-50~) was also formedp the quan- tity being dependent on the conditions of the experiment. The molecular weights of the soluble polymers (determined cryoscopical- ly) were dependent on both monomer and catalyst concentration. Highest molecular weights were observed at intermediate TiC14 con- centrations (0.06-0-105 moles/liter). The molecular weights of the -soluble polymers were found to be independent of the temperature of V polymerization (temp. range studied: 0 to -400C). All polymer Card 112 The effect of TiCI4 S/786/61/OCO/OC9/'C04/006 1065/1242 samples studied vere founa to contLin about 1 atom chlorine ~er molecule, indicating the direct participation of TiCI in the ini- tiation step. The molecular weights of the polymers formed in heptane solution Y~ere of the same order of magnitude as those ob- tained from polymerizations in other solvents. A polymeritation scheme is suggestedq based on the formation of a growing radical. Termination takes place by disproportionation of two growing chains. There are 2 figures and 4 tables. Card 2/2 S/786/61/000/009/005/006 1065/1242 AUTHORS: B.V.Yerofeyevg S.F.Naumova TITLE: The kinetics of the TiCl -initiated polymeri?ation of 1,3-cyclohexadiene in toluene eolution SOURCE: Akademiya nauk Belorosskoy SSR. Institut fiziko-organiche- skoy khiviii. Sbornik nauchnykh rabot. no.9.10,61. 1,;onomery, evoystva i protsessy polucheniya polimerov, 88-95 TEXT: The polymerization of 1,3-cyclohexadiene in different eol- vents has been studied by Yerofeyev and co-workers (Ref. 1: Lokl. Akad.Nauk BSSR 95 (IMM. In all the oases studied, polymers of rather lov/ ;oie,cular weights (about.one thousand) were obtained. In order to elucidate the reasons for the early termination of chain growth, kinetic studies of the polymerization were carried out at temperatures ranging from -70 to +200C at cyclohexadiene concentrations of 5.7-6.6 moles/liter and T1014 concentration of 0.017 to 0.16 moles/liter. Dettiilo of the polymerization technique are given in reference 3 (B.V.Yerofeyevg SeFoNaumovat T.P.MaksimovE4 Card 1/2 S/786/61/000/ 009/005/006 1065/1242 The kinetics of the TiCl 4-initiated ... Sb. nauchnikh rabot IFOXh, Akad.liauk B.S.SR, no.9, 96 (1961)]. The rate of polymerization of 193-cYclohexadiene in toluene ic approxi- mately first order with re--pect to monomer (C6H ) concenlration. The extent of polymerization was proportional N ITM412 and independent of the initial monomer concentration. The m8lecular weights of the polymers obtained in toluene was practically iuen- tical to those found for other solvents. There are 4 fiEures and 4 tables. Card 2/2' S/786/61/000/009/006/006 1065/1242 AUTHORS: B.V.Yerofeyevp SeFthaumova, T.P.Makolmova TITLE: The polymerization of dialin SOURCE: Akademiya nauk Belorueskoy SSR. Institut fiziko-organiche- skoy khimii. Sbornik nauohnykh rabot. no.9.1961. Monowery, evoystva i protsessy pblucheniya polimerov, 96-100 TEXT: In polymerization of cyclohexadiene under widely differing conditions only molecular weights in the range 500-4000 were ob- tained. In order to find out whether the high rate of chain trans- fer was caused by the cyclic structure of the cyclohexadiene mole- culet dialin (dihydronaphthalene , ClOHIO) containing the cyclohexa- diene structuret was chosen. Dialin was prepared by the dehydratibn of tetralol - 19293,4-tetrahydro-/?-naphthol. The polymerizations were carried out in a three-necked flask equipped with stirrer, gas inlet tubeg and dropping funnel. The polymerizations were carried out at -75 to OOC for 1 to 10 hre. At the end of each experiment, Card 1/2 S/786/6l/000/003/OC6/0(;6 The polymerization of dialin 1065/1242 the precipitation of the polymer arid decomposition of initiation was achieved by the addition of' 4 volumes of methanol. The polymer was purified by re-precipitation from benzene solution, and dried in vacuo at 400C. In the reprecipitated polymer no traces of the 6-atalyst were found. Two polymer fractions %ere ifiolated in oil experiments: relatively hi6h-mol.wt. fraction comprising 76-881,'.' of the total, and a low-mol.-Nt. fraction (probably diumer and tria- mer) comprising 12-W. The tLolecular weights were determined cry- oscopivally (in benzene). HiEh yields (90-100,) vere obt.Aned iii chloroform, and lo%er yieldF in heptane. In botii solvents the mol- cular weights were practically identical (.- 600). The molecular weights obtained with a TiCl4-Al('Elo-C4H9)3 complex were hielier 1000) thnn with TiC14 alone. The polymtrs of dialin are white amorphous powders, soluble in aromatic and enlorinated hydrociArLot.i-. They are not oxidized on exposure to air and have a density ofQ4 - 1.138. The absence of chlorine in all polydialin preparations P&Od the lower molecular weights (independent of solvent composition) indicate that the mechanism of polymerization is different from that in cyclohexadiene. There is 1 figure and 1 table. Card 2/2 5/250/62/W6/00/007/W IODI/1002 AUTHORS: YerofeM, 0. V., Naumove, S. F. aW Ty*Ab, L. G. TITLE: Formation of benaw in tbemic polymerization of cyclobendiene-Ij PERIODICAL: Aksdemiya nauk Belaruskay SSR, Doklady, v. 6. no. S. 1%2. 313-315 TMff: M& Isa continuation of a previous work on polymerization o(cyclohexadiew-1.3 at temperatures 1600-MOOC (B. V. Yerefeyev, S. F. Nau=ova, L 0. Tyskalo, Sb. nauchnykh trudoy IFOKh, no. 9,1961). In the peceent work the spectrophotometric InvatiSation, was *pp1W to mcnomers obtained in experiments with Maw degrees of polymerization at various temperatures. It was established, that in the process of tho cbemical chmaW of cyclobexadkne-1,3 dimerization and polyrmerization to higher degrees are accompanied by a dispwportionation. A famula is given. for calculation of the amount of bentene in the monomeric products. There am 2 figures and I table. ASSOCIATION: Institut fiziko-orp*hakoy khin'W AN BSSR (butitute of Phy0cal-Orpm Chemistry AS BSSR) SUBMMIED- February 29.1%2 Cud lit 3/020/62/147/001/016/022 B106/B1011 AUTHORS: Yerofeyev, B. V., Academician,AS BSSR, Naumovat S. F., Tsykalo, L. G. TITLE: Products containing an odd number Cf monomer links, which form on the thermal polymerization of oyclohexadione-1,3 PERIODICAL: Akademiya nauk SSSR. Doklady, v. 147, ao- 1, 1962, 106-107 TEXT: Monomer products contained in the crude polymerizate were spectro- photometrically studied in order to clarify the mechanism which underlies thermal polymerization of 1,3-oyclohexadiene. The content of a trimer product in the liquid portion of the polymerizate was determined. The monomer products contained 16.1 + 5.9F,4 benzene after an B-hour pollseriza- tion at 1800C, and 21.6 + 5.1% b-enzene after 10 hre. After 2, to, ana 4 40 hra polymerization at72000C, the monomer products contained 47-1, 40.4, .and 23.5% benzene respectively. At polymerization temperatures of 140, 150, and 1600C no benzene resulted. The molecular weight of the liquid part of the polymer, separated by methanol, was determined cryoscopically in order to calculate the amount of trime., in the polymerizate. The result ng values (160-240) indicate that the liquid p&rt of the polymer Card 1)3 S/020J62/147/001/016/022 Products containing an odd ... Bio6/Bioi contained only dimer and trimer. 0The trimer percentage a changes between 0.6~4 (10-hr polymerization at 140 C) and 11-1~6 (70-hr polymerization at 1600C). The results show that active monomer radicals form on thermal polymerization of 1,3-cyclohexadiene, which either add to a dimer so as to produce a trimer, or else disproportionate into benzene. The first stagesof polymerization are: C H + C H C H * + C H 6 6 6 a 6 7 6 9 C H' (or C H') + C H )-C H C H; (or C H*) (2) etc. 6 7 6 9 6 a 6 7 - 6 C6H9* 6 a Dieproportionation may occur simultaneously with reaction 2: C H' + C H C H + C H 6 7 6 8 6 6 6 C H' + C H' ---.> C H + C H (4). 6 7 6 9 6 6 6 10 The polymerization mechanism assumed by P. S. Shantoroviob and I. A. Shlyapnikova (Vysokomolek. soyed., 4, 1369 (1961)) which first yields diner biradicals recombining into the polymer, is therefore impossible. Thor* Card 2/3 9/020/62/147/001/016/022 Products containing an odd ... B106/B101. is 1 table. ASSOCIATION: Institut fiziko-organicheakoy khimii Akademii n&uk BSSR (institute of Organic Physical Chemistry of the Academy of Sciences BSSR) SUBMITTED: June 4, 1962 Card 313 3/250/63/007/0()2/006/008 A059/A126 AUTHORS: Naumova, S. F., Tsykalo, L. G., Dudina, 0. S. TITLE- The kinetics of thermal polymerization of cyclohexadiene-1,3 at 130 to 16oOc PERIODICAL: Doklady Akademii nauk BSSR, v- 7, no. 2, 1963, 99 - 102 TEXT: The separate amounts of dimers, trimers, and higher polymers formed in the course of thermal polymerization of cyclohexadiene at 130 to 1600C, and during thermal polymerization in benzene and cyolohexadiene at 1600C for 50 hours have been determined. The experimental methods used have been described before (Sb. nauchnykh rabot IFOKh AN BSSR (Collection of Scientific Papers of the IFOKh, As BssR), v. 9, 1961, P- 71). The molecular weights of the solid polymer decrease withincreasing temperature and depend only little on the time of reaction. The portion of the dimer (~3) at constant temperature is independent of the initial concentration of oyolohexadiene-1,3 which shows that the intermediate product forming in one of the first stages of the reaction undergoes Monomolecular reac- tion with the probability ratio of conversion of this intermediate to yield the Card 1/3 S/250/63/007/002/006/008 The kinetics of theruu&l polymerization of... A059/A126 dimer or a higher polymer remaining constant. One of the stago2 of the reaction should be therefore C129116 /I C12H16 "9C12H*I9 where C12H16 is the active dimer intermediate, C12H16 the inactive dimer (ex- tracted product), and C12H*1*6 the new active intermediate capable of addIng a new monomer molecule. The most satisfactory results were obtained with the formulas: 1/2 "dimer - KC0 or [a3 3/2 dimer ~ KCO (1) (2) where ckis the portion of dimerized cyclohexadiene-1,3, and [a] the dimer con- centration obtained after 50 hours of polymerization. Hence, no monomer pro- ducts (including benzene) are formed in the thermal polymerization of cyclohexa- diene-1,3 at temperatures of up to 1600C following formula (2) which cannot be derived from the previously assumed polymerii tion mechanisms of this substance. Card 2/3 5/250/63/007/002/006/008 The kinetics of thermal polymerization of... A059/A126 There are 1 figure and 4 tables. ASSOCIATION: Institut fiziko-Qrganicheakoy Wmil AN B33R (Institute of Phyalo&l and Organic Chemistry of tho AS BSSR) PRESENTED: by B V. Yerofeyev, Academician of the AS BSSR SUBMITTED: June 26, 1962 Card 3/3 KHACHATUROV, A.S.; BAZHEMOV, N.M. (deceased); MAUMVA, S.F.; TSYKALO, L.G.; YEROFEYEV, B.V. - Nuclear amWetic resonance sWtra and structure of oligomers of 1,3-cyclohexadions. Dokl. AN BSSR 7 no.7s459-463 n 163. (MIRA 1611Q) 1. Institut fiziko-organicheskoy khimii AN BSSR i Institut vyaokodolskulyarnykh aoyedineniy AN SSSR.