SCIENTIFIC ABSTRACT NELSON, K. V. - NELZINA, O. S.

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SCIENTIFIC ABSTRACT
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Rotmi "Were and lbe poy"Issisatims of w"lit"s IVA At SwAmmiftu (A A /fUlAMOV. V0*WI Ikw. Vdmk J.~ S -,; M. 75, 097. 7.0t 1wiIII. - rhe Ijnmv lf.etum wo. by frwirtkination front div lKilymewisatir of %treC:Clis with lloW.. sbowcd th,- k.omain frequencies 1101, 1404. 1644, lddA, aml '*0 cut I (A thew. (he Iffid line cvrmpmds to a CX Immid out at I Ile rud of The cb~ziu. J., bidic-ates the PITWIKV 94 tile I-IMM' lUffIU %lCA:Cll:CMC, The Fr- tuAinins Hums inkimis Au the end SfuuWng C Cit.. i.e. iudi- CAtt the uAll"Iff SteiCC119C UttClit. 11W IFiItWf. prqid by wAyumviation with dorWin. showed the double4pand frequencies 4 - I IWO, 4 - I**. . - ma, P. - M2, .4 - 1671. and , - 30Mt cfn. -'. Of thew, r5 caffespondi to a doul* WOul kwat ~i in the middLe of the mol.; the jrv, 'n.aiiiing 4am 1mrhaut to 1411 end girtalp C:Cli,. cou%~ quently, The tiruvirr Is a nuxt. of L%mn"ic tomm; The tetra. in". atw th~ &-fi. jm,w~t It-, 4,, 141M. n - Itt.'41 . .....I J07b Cu, ~-.J-ujuug to th, ,,,I moup C Cit,. the fIVqUVIIVy CUSIV11KIII411111i 10,1 11111,11114' 11011d III flu! 11111611e 'he nvol I. al-ist. l1w osw tpphr, I,, the Imutiowt, wb abuirs only the doubIc-bood hot, 4, 111M. 46 0..% - 16W... - 1649, .. 30Mcw 'I'll no line at about 1670 ctu. Conwiluently, thc pen- Of oal f MCICCHICU. *R1.'C=CJd*C'JYfX!1Tf", ic 'A arth 4 7 'W~Irirnmr t thr Irrquenrin A, - I I (r., " W ::t. w - I, And Ps - jt"W cin '% all tx-- to an ~nd gmptist C:Cllv, Th(fV A10 tWQ IFC- lying syttunctrwall t on but It m,fvs ,( I he IN 4 line. wbkh ir absent in the htjch~-f ;wAymcri. firum thr Ironer ul, Tlmimmrllfrequencics~ hift.-d synimirtrical1v relative to the , 16441imeby8cm. lintlictri.mr.7cm ltuthrlrtr~mi .-I 6 cut. -- in I hc ... th~ h'gh- lilt. pheting t I I hy 1-n. g-,iblv by rotati=ti L1_1wII!In"- I*h.." assummi ad PWYNWS aw low malecialm WtIght and the plilyriengatm d tia4mityiese I- F Ct,-. 1, N,jj,.mj,~ ... f V., %t ShI..Im t A A /.1,,l ...... Itm, I ... rxiiingrad) Zhu, Fn jkk,- .15-til -,I I.. . -1. 1. 1 Its eltiesdAte the stnwturr of ptIlymAmItylen, 'he ltm- ~pcctra of the following polymtr* of tvabutyleur Are %I udie,t- IhIller. triturr. ictr4mer. prutatner. ind A 1~4YUIer Ad ft-I WeiffilMll Both IkIW-4NC fUFMV Ulf file 4hIIWFAFV tkb~Cf~&Nl F4W tile other Inols.. Our Alluctures hAvInat .4 flouble tubmt al the end of the Omm are ialofreti rhi% rm,ims. wiiaci, I. ,11holmnliAliml by mtaly~-. ,f th, jw-lu~t, f t ...... I).,, .I Ow letranwr, 1A not in k4mimis with tile If Whilimpre. d d I C I SS. 65(41. WW" 1. St"Iml fi-I't-t '17 PR1KVi0T'K0, F 24 (7) 3 PHASE 1 B-K R"LOITATION SM/1365 Wwov. thiver"t*t ftwrlaly I V'w"k5YuznO9O gov4shchaAlya Pc spektroskopli. t. It golskulyarnA.7a spekt.'.1"ply. (?&;Or@ of the IOU All-Unjcn Conf*rsnc* OVI SP*ctr,acopy. Vol. It Molecular spectrosco;y 1L'VOTj lgd-'Fo Llvovskogo iinly-ta, 1957- 499 P. 4 000 cople)a Printed. (SnriGes lt8t Pizichnry xbirAyk, v". S29~) Additional SPOn"Orln0j AgORCY: Akadestya nAtLk SSSR. Komisalya po $Pektroakopi.l. sa " 'Jager, S.L.1 Teoh. Ed.: S&r~xWuk T.V I tdltorlal Bcuirj, LA.-visterg, G.S., Acadeadolan (ROMP. id.p 6;44&&44)s Uporent, 3.111., Doctor of PhYsLcal and VAthaztatloal 3clentses. .Pabellnski,y X.L. Doc-or of Fhygtoal ecd Mathematical Sol Ivabelkwaft. M.. boetor of ftsioal and Mathematical Solen441141call' I:GrultRkU* V.G.# Candldat4 of Teu~nical So'encostatays'dy. ':'.. C'4Wid&tQ Of "441dal and Mathematical Solana* Imays1dy L.K., C&Adidats of ftys-'eal And Mathematical Science:: Millyanchu. V.S., CaWldats of Pt4sloda a--A Science& and Gl&WWrmMm. A- YO-. CGWittAte Of Physical and kstheati,al fielcapes. Card 1/30 8"&4 LX-. and Ye. s. Solqv, "T- P-tatlanal Uo.. ulrl- - the Hrr..t of Al Temperat ure an the rELrftr" ,sorption speot.'a of Some Parrafrina ftstcv~kLY& A F 14A- 5AIIwT A 3 Mn4xlnsldy - - amd "- T-1-;;;; V ~ L - ariation in S tr U01:u" Of Kalum &Atddl*m ltttbb.,r in tb. PrOO411 6 Or Ught 0Z1dUom la"zo-A N A 423 . , -. and D.A. D-gadIdn. Infrared sovpy v"4 Spostro. " scudy UA Isters 0 s e 4 ftr las or Rubber am U*wckl*tova N.A. "tU4 Of the CbANdCAL Tarl&UM4 of lrqt;~-d zoea 436 vi rIUA tsflcm') M%dav the 1,, M" of ft." memo at Urftr" 4%0-367-- Ts- todubMy so 430 . swu4oss r %6 N14r*8*39M4%%ft OV &a" DUM, 17, ?30 N C L '5 C, N K, V, ALJTHOI(S Nellson, E. V.L PodclubnjY 1. Ya., 20-3-34/59 7'-':TLZ: The Structure of Molecular Chainn or' Poijisopr,,!nes, as Revealcd bj Infrared Abscrption '3pectra (Issledov~.Lniye 3trukturi arn.ykh tsepey pcliizopr,3nov po infrakrasnjm spektrumpogl(.shch4-11i,-a) PERIODICAL: Loklady Akad. nauk SSSR, 1957, Vol. 115, Nr 3, PP. 545-547,(USSR) A.35TaACT: 1n the entire problem of the synthesis of caoutchoucs witY prescri- bed properties the study of the influence of the polymerisation conditions on tile structure and spatial configuration of the basic link of the molf!kular chains is rather important. In the present paper the mircontructure of a seriee of polyisoprene caoutchoucs ras investigated according to the method of infrared spectra. Such ones from a catalytic fclymerisatiori (SKI) which, according to their physical-mechan:Lcal properties, are a near ap.roach towards natural caoutchoucs are investigated as well. as emulsion pol.,isoprenes which were produced by polymerisation under the influence of' free radicalS. The f)rmation of 4 various structures of macromolecule .Anks 13 possibLe. They differ in tile position of the double bin- cling with regari to the bgsic chain as well as in tne spa-Lial con- fi-uration of tie atouis with regard to the doible binding: 1,2;~,4; ID I ',is-1,4 and Traas-1,4. Prom the data of table 1 it can be conclu- that all investigated SKI caoutchouc patterns have a high con- -Lent of Cis-configurations (up to 75~o of the total amount of the Card 1/ 1,4-links of the molecular chains). Thus it is furthermore shown 20-3-34/59 The Structure of Molecular Chains of Polyisoprenes, as Revealed by Infrared AbsorptLon Spectra. tha--. the existt.-nce of smaller branches in this polymer is on t:,e who'.e due to th,~: c)nnections in the 3,,j-position (isoprenjl groups' The number of 1,2-Links is low here (1-1,5/6). The mitrostructure of the emu.lsion-i3,)prene-caoutcho-Acs is to a certain extent influ- encvd. by the poljm,3risatiGn temperature. In such produced at -147-00 the 1,4-links are entirely built in a Trans-position. A further riSE! Of teriperature leads to the occarrance of a certain amount of Cis-1,4-links. It :.ncreases monotonously with the temperature rise and aMOUntE1 to 8111-1 itt+500. The content cf 1,2-and 3,4-links remains practically constant in this temperature range. The authors obtain- ed from tne above rientiuned data a total analytic expression on the strength of whJ,ch a relative content of the corresponding ni- crostructural elemf:nts for all polymerisation temperatures can be computed. From the (here given) equations it appears that in the range of pclymerisation teaperature of from -47-+500 the formation of Trans-ccnfigurationB is energetically more favorable than that of Cis-configuraticne. %ita regard to the prolongation of the chain in the 1,4-positior, compared to the 1,2-connections, the activa- tion heat- and entropy values favor the formation of a basic chain with inner double bindings C - C. From the relative content of the 1,2-and 3,4 connections one can conclude as to the regularity of Card 213 the molecular chains from the standpoint of their structure wnich The Structure of Molecular C.'Iains of Polyisc.prenes, as Revealed by 20-3-34/59 Infiared Absorplion Spectra. may be "head to tail" o.:-"head to head". This content was -,n the ex- periments approximatively the same in each case. This leacis to tr-E final conclusio*hat thii macromolecules of the caoutchouc SKI form mainly regular chains consisting on the whole of Cis-1,4-links which are jointed in s head-tail position, whereas the molecular chains of the emulsion polyisoprenes consist of irregularly alter- nating Trans-1,4-links Y-hich with the same probability are joined in both positions (head-.tail and head-head). The former case causes the ability of the SKI isoprene c;aoutchoucs to crystallize in the case of extension. TherE are 4 Slavic rel'erences. PRESENT ED BY:Academician Kargin, V. A. I Febrixtry 2, 1957 SUBMITTED: Jan. 3o, 1957 AVAILABLE: Library of Congress Card 3/3 AUTHORS: Nellson, K.V. arAi Sicripovs. L.S. sov/.51-.5-6 -11/19 TITLas On the Study of Infrared S oactra of Insoluble Elastomars kOb lzuchenii infralcrasnykh spektrov nerastvorimykh eiastomerov) PMUOVICAL: Optiica i Spektrosicopiya, 1958. Vcl 5, Nr 6. pp 704-706 (U"R) ABS'aACT: Using coispressed powders the authors studied infrared absorption sq^ctra af the foilowing insoluble rubbar-like polymers: copolymer of diriayl with. 2-methyl-5-vinylpyridino, copolymer of vinylideno fluoride with 3--f luoroch lorethyl one kSKF-32-12), vulcanized silicon* rubber, " for the saire of comp%rison - the spectrum of vulcanized silicone rubber in the form of film. the powders must consist of uniforu particles with dimensiomi not exceeding the infrared vavelongths, i.e. for measurement of spectra in the 2-15 )1 region the particle dimensions must be or the order of one micron. Vulcanized silicone rubber vias pulv,sritod irt 2 hours using an aggte mortar together with KBr cryttals. SKF-32-1.2 aubber was pulverized, together with KBr crystals, in 8 hOUrs. In pulverliation of copolymer of divinyl with 2 -metkyl -5-vinylpyrid info and KBr, carbon tetrachloride ma used. The amount fif KBr ia powderti varied from 0.1 to 0.5%. To rouove all moisture Card 1/2 -covdars wera dried for 15 min uvdor an infrarad lamp and in the process On the 3 tud yof Infra:,-ed Spectra of Insoluble Slastomers sov/51-5-b-1-3/19 of press'Lng they were outgassed until a pressure of 0.5 = H wa rea ched . The powders wore compressed unaer a pressure of M '1,,/.2. The sample thickness was 1. 5 mia and the diameter was 25 m. blea-suremignts were made using an IIM-11 infrared spectrmoter with a NaC1 prijim. The spectra are given in Fig 1 (vulcanized silicone rubber; curve I :reproaenisa ccutpressed powder and curve 2 represents a film), Fig 2 keopolymer of' divinyl with 2 -mothyl -5-vinylpyrid ins in powoor form) ani Fig 3 (30-32-12 rubber in powder form). Curves 1 and 2 of Fir, 1 show that the spec-,ra of a powmer and a film are identical &part from the background. There are 3 figures and 9 references, 4 of which are ANIarLcan, 3 Geman, I international and I translation. SUMITTSD: May 4, 1956 Card 2/2 AUTHORS TIMM: Ne ijng*..*_w SOV/138-58-il-t/14 ova, * PoJ1ibnYY, I. Ya; Krupyshev, Y. A. and SM Z. D. Investifjat:ons on the Micro-Structure of Butadiene Rub- bers (Issledovaniye m1krostruktury divinilovykh kauchukov) "Nr 11, pp 3 - 5 (U33R) PLPRIODICAL:Kauchuk i liezina, 1958,1,\ ABSTRACT: Card 1/4 S. V. Lebedev et al. (ReJ1.1 - 3) determined the Influence of t~ie polymerisation tenperature on the content of side chains tvinyl groups) in butadiene rubbers obtained by polynerisation with Li, Na and K. With the aid of this data, dependence of the glass temperature of butadiene polTmers on the mimber of monomer chains, added In the 1,2 position, cou:.d be dotermined (Refs. 5 and 6). The micr:)-structure of polymers can be defined effectively by analysir~a, their absorption spectra in the infra-red regi:)n. RE)SUlt-3 ELVe f-WE)n on the dependence of the micro- structure of butactiene rubbers, obtained by catal7tic polyinerisation,on the conditions of their preparation, the :.,lature of the Initiator (Li, Na and K) and the temper- ature of fhe process. The infra-red spectra bet.'Yeen 800 - l"000 cm- were analysed. The polymer molecule in buta- ~8-58-11-2/14 %OV/L1 Investigations on the Micro-3tracture of uta iene Rubbers diene rub'.)ers shows three types of addition to the C2A, borid; in the 1,2-, trans-1,4- and cis-1,4- positior. If the addition occurs In the 1,2-position absorption occurs in the 909 c-m-1 band- heptene-1 was taker, as a standard. Analysis of the trans-1,4 configuration shcmed absorption In the 967 cm-1 band; in this case trans-octene-3 and trans-de-,ene-5 were taken as standard. All. sampleswere tested in 082 solutions on a VM-KZ apparatus with a NaOl vism. The samples were prepared by Z. A. Khrenovaya. lie average experimental error wast:5%. The lithium-sodium- and potassium-butadiene polymers were prepared by polymerising butadiene when thei temperature7a of the thermostat were as follows:- 5, 10, 20, 30, 40 and 600C. Neozone D (2%) was added to the polymer samples after the L;aseous products had been separated under vacuum. The glass temperature, viscosity and physico-miechanical properties of the sam- plos were determined (Table 1). After purification and vacuum dryiT-C at room temperature, 1% of solutions in Or) were prepared. Data on the quantitative determination of"the m1cro-structure of the rubbers Is given In Table 2. Card 2/4 The polymerisatioti temperature influences the micro-structure SOV/138-58-11-2/14 Investigations on the Micro-Structure of Butadlene Rubbers of lithium-butadiene rubbers (Fig.j). The micro-struc-,ure of sodium butadiene rubbers, repetred at various tempera- tulles, is similarly affected 5ig.2). On incrc-a,3jnC the polymerisation temperature a decrease in the addit'Lcn in the 42 position and an increase in the number of chs.ins In the cis-1,4 position can be observed. T-ie trans- 1,,4: confl uration does practically not change, and remains at approximately 15;-/,. Hardly any changes occur in the Investigated temperature interval In the micrc-strvcture of potassium butadiene nibbers (F13-.3). The reatio: trans -1.4 0 rs-1, 4 for all samples wast--,,3 (trans -1, 4 --,,30% and cis-1,4-~'10%) ThElse res'alts agree with data published by A.I.Yakubchlk Card 3/4 SOV/138-58-11-2/14 . investigations on the Micro-Stmct~~re cf Bu~a3lene Rubbers et al. (Refs. 2 and 3). There are 2 Tables, 3 Fi--r-ur-ei and 11 References: 3 EnLlish and 8 Soviet. ASSOCIATIONg- Vsesoymng nauchno-issledovatel'ski Institilt siitp~'!- cheskoCo auchul$im- S. V. Lebedeva TResearct for Synthetic Rubber i-. S. V. Leb--3.eV) Card 4/4 50) XVI'20- : 2 4 -1 - AMORS Dol go plosk, B. A . , r , k :3 u 3 3 _R Kropachelra, Ye. "I., Nel'sonp K. V. TITLE: The Ci a-Tran s-I somerizat i on o f ',:.q t u ral 90. r Und e r t ~. e Ef f L, ct of Organo-Aluminim Compounrls and Tit. rium. Tt_--racltloride (Tpis- trans-izomerizatsiya naturallnoro knuclru.,kr.iod vli-1,ari.yer. al:.'u- miniyorganicheskikh 00yedineni, i chetyrekliklil )r--* +lo,-o tit -a) j d PER I OD I CAL DoklaJy Akudemii nauk SESH, 195b, Vo) 12.7, ANr 4, p,? 685 - 687 (U-31 ABSTRACT: A.3 is known, the entalycts of Ziej-lor i (T~-iF' or) have receritlj gained ii,;)portance in the gyntliesis of pol,,!,.,,i-s of regular structure, especially of cis-poly-isoprene (Re's Pre- viously, the effect of physical and chemical prop-rties of t-~e cataly3t3 have been made renponsible for ti:e break of the str-,ctui~e of the chain due to the formation of tr%nii-,ien!:ers. These prDperties were spid to influe-~ ce the -,:dition c-iaractpr of the m:)n,:>r,-!er (diene) in the col:rne of polymerizr-~.ion. In tte prp~;entijaper it --,f; .,rcvr.-d that the re~r)ilar str-rti)re c--,r: de- pend on the isomerization of cis-me-ihers to in, Card 113 a complete polyrier clhair. Thi.9 is dtie to the comi!one.,.ts usel T1-e Cis-Trans-Isomerizat ion of lfaturrl Rv.!,'-(~r Unler t'-Ie SOV '2o-' 3 Effect of Organ o-Aluminu,m Compoun Is --ind Tit ;.- il,-I Tetrtic..lor - de for stinnul;,.tinj~- tl.e pr-)c'ef"S. A SI.Ort E'r:rv(,.Jr of publicr:~ionc (T:e~s in The i. knovin in the case of (Ref 7), hiwqver, not for natural ri--'.-j'.,er un~.er F!inil-r conditiona. The i3onzeri,.-.ir~,," effect of tl-ic coj,ourdr in trio titlo wn5 i.,;vefzti~--'.Ed in coluticn3 of (~'R) in sealed glass aripciiles in i1r---,on. 'I",.e r!h3r---~for n-,.d the r-icrostr.cture of the c.n.ir! of e-4' eh s-nIc w~--re de',r..-ii-ed. For the latter infrarcd s.;ectr% arc-r,~1n,' to the --.etho,! the last mentioned LUthor, re!'ere:~ce C, ireve used. Table -,4ves the results obtair:ed. T':-r~from it i.9 conrli;.1--e t',t the cou- ponents of thu Zie,-ler c,- 1,-c' ("I'iciV A1.11,, A1R,C1) exert ar isomerizing effect on th,, poi.,,, Pr ch,~in of n-tiir.1 rLll;,,)er. By the example of TiCl/ it prove(I tl:it tho nu-.-.!.-or -f trar:p- members incre~,seo w th th,.. crin-ent-ation r)f t'ie isomerizing agent and the loni;,er Jur-tion of the action. Figure 1 very clearly the iso.nerizit-.ion of polyifoprene on atsar.-)tion banJs of infraied rLtlia-tion w',Iirh corre.-ii~ond to vario!ls contcrts Card 21 of 3is- and trans--ei~e=. This iso,ierization is ;~cconnpanied The Cis-Trans-Isonerizat ion of Nqt1iral Riib~er *,'nd.?r the SOV/20-1 Effect of Organo-Aluminun Compou-,~-, an~ Tetrac:11or--de by a conBidera~!le decrease of the unsatural,ed cnaracier of the polymer. A,)parertlr this depends on: a) C./clization rocesses witt.in the chnin, 1)) The zx,lditivi,.~- of the mentioned com~ourds to the C=C bond. It is prol!ably preceded by the for-iation of an urntr.ble co-.i,.,1ex which car derDrapose tinder tote for-lation of initial suLst.L,ces. Triethyl iluminum dic~.lorile C1,111ses deeper seconda-y chnjes of n.titrul rijb~,cr; unsolvFil,le amor~1=3 powders with MA .1 ,:)i neltinc; point!, -ire f-umed. Tirl 1e:11'8 to similar res,~lts, but onl.,, if l,r-e imoiint~ are u2id (loc4i Of the rublier weigh,t). T!~,.re 1 fii_-ure, 1 table, and -,' refer- ence:,, 3 of which Lre S,)vi-!. ASSOCIATION: Vsesoyuziiyy institut -intet,,r-~eskogn kauchuka im. S. V. Le)edeva (,Ill-Union Scie,.tific Rer-:,arcli Institute o! Synt-iet'c Riii)!:er i--eni S. V. Lel.--lev) SUBMIT'"ED: Au.-~iist 22, ")~b Card 3/3 4 69507 AUTHORS: 3oldrreva, 1. 1., Dolgoplook, B. A., 510201601131104103110T3 Corresponding aber, AS U33F-, BO11/BO17 Kropacbeva, To. ff., Nellsoh, K. V. TITLE: Cie-trans-isomerization of Natural Rubber Under the Influence of Hydrogen Chloride and Ethyl Aluminum Dichloride PERIODICAL: Doklady Akadsmii nauk SSSR, 1960, Vol 131, Nr 4, PP 830-832 (USSR) TEXT: The authors investigated the effect of anhydrous HCI and of ethyl aluminum chloride on a benzene solution of natural rubber under conditions which had been described earlier (Ref i). HC1 was introduced as a saturated benzene solution. The microstructuro of each sample was charactedzed by means of the IR-aboorption spectra. The quantitative content of cis- and trane-configurations was determined on the basis of the band 840 cm-1. Since, due to the HCl addition, the non-saturation of the polymer is partly reducedg the relative content of the links of each con- figm-dion was calculated in % of the double bonds remaining in the polymer. Table 1, and figures I and 2 show the results. The authors emphasize that the data of the relative content of cis-trane-links only characterize the qualitative picture of the process since the accuracy of spectroscopic determinations sensibly decreases with decreasing non-saturation of the polymer. Since the solubility of the poly- mer is limited, it was not always possible to compensate for the decrease in the Card 1/3 69507 Cis-trans-isomerization of Natural Rubber Under S/020J60/131/04/031/073 the influence of Hydrogen Chloride and Ethyl Alu- B011/B017 minum Diobloride nil-bar of double bonds by increasing the concentration of the polymer in solu- tions. Table I above that ethyl aluminum chloride as well to HC1 exercise an isomerizing affect on the polymer chain of natural rubber. The number of trans- links increases with the concentration of the isomorizing agent. In both cases, the isomerizationlis accompanied by a reduction of the non-aaturation of the polymer chain. 'n the case of aluminum chloride, this seems to be mainly due to the intramolecular ring formation. HC1, however reduce@ the non-saturation only insofar as it is added to the double bond tFig 1). The aaount of RCl added corresponds to the reduction of non-saturation ofthe chain. The non-saturation continuously deoreases with extension of the reaction time (Curve 1). In this connection, the relative content of trans-links (Curves 2 and 3), and the chlorine content in the polymer, increase steadily (Curve 3). Figurs 2 shows that the isomerization and the addition of HC1 already start at -70 , and that they considerably are accelerated in the case of a temperature rise. At 600, the total oontent of double bonds, and of added chlorine, is only 82% of the theoretical content. This is apparently due to the ring formation. The experiments of the authors show thett under the described conditions cis-poly- butadienetia not sensibly isomerized. The high sensitivity of cis-polyisokE!pe__4 to iaom*rization under the influence of ion catalysts is probably connected witA m vard 2/3 69507 Cis-trans-isomeriisation of Natural Rubber Under the Influence of Hydrogen Chloride and Ethyl Alu- minum Dichloride 3/02 60/131/04/031/073 BOIIYBO17 the iso-structure of the chain. The easier stereospecific synthesis of Cis-poly- isoprene as compared to that of cis-polybutadiene is probably also due to this faot. There are 2 figures, I table, and 9 references, 2 of whica are Soviet. ASSOCIATION-. SUBMITTED. Natichno-iBaledovatellskiy institut sinteticheakogo kauchuka im,. S. V. Lebedeva (Scientific Research Institute of Synthetic Rubber imeni S. V. Leiiedev) October 26, 1959 Card 3/3 3/190/61/003/001/013/020 B119/B216 AUTHORSs Gruber, V. N., Nellson, K. V., Kozlova, N. V., Mikhaylova, T.A., MYlkhina, L. S. TITLE: Mechanism of' catalytic polymerization of cyclic dimethyl polysiloxanes. III PERIODICALt Vysokomolekulyarnn-e soyedineniya, v. 3, no. 1, 1961, 89-92 TEXT3 In previous studies on this subject (Refs. 1,2) the authors were able to show that the polymerization of cyclic dimethyl poly siloxanes by the catalytic action of FeCl,, Al(SO ) -211 0 + H 30 or concentrated H so 3 4 3 2 2 4 2 4 leading to resinous products is due to redox reactions which cause the forma- tion of active centers at which chain-formation takes place. The following redox scheme was suggested for If2so4 catalysiss Card 1/3 S/19 61/003/001/013/020 Mechanism of catalytic polymerization... B119YB216 H 2S0,5 H S 0 T 2 2 8 1 F H2SO3 ( H 2s04 The present work deals with the quantitative evaluation of the redox processes occurring during polymerization by H 2s0 4* The amount of catalyst used for the polymerization tests corresponded to 2% of the silicone oil portion. Samples were drawn at intervals in the course of the reaction and analyzed quantitatively !or H 2SO3 (iodometrically, (Ref. 3)) and H 2s05 (by the method described by L. 1. Kashtanov, 0. N. Oleshchuk (Ref * 4) , and infrared-spectrographed 'in the NKC-11 (IKS-11) infrared spectrometers to determine the quantitatike relation between cyclic and linear polymer (the former has an intensive band at 1090 om- 1 and the latter peaks at 1025 and 1110 cm-1). The peak at 1025 0m'" I characteristic of linear polysiloxanes Card 2/3 S11901611003100110131020 Mechanism of' catalytic polymerization... B119/B216 increases in the course of the reaction, while the peak at 1090 cm- 1 corres- ponding to the cyclic form becones weaker and shifts to 1110 am- 1. The findings sifmify the simultaneous presence of the lower-oxide and peroxide form of the catalyst in the reaction mixture to be due to redox processes involving cc-natant regeneration of these forms. The decrease of H 2 s03 content and simultaneous inoreaae of H 2so5 content during the reaction process indicate the occurrence of macro stagea according to N. M. Emanuel, (Ref- 5). The H2so5 content in -the reaction mixture is directly proportional to the formation of linear polymer. 5 Soviet-bloc and 2 non-Soviet-bloc. SUBMITTEDo June 7, 1960 There are 2 figures and 7 references: Card 3/3 IN 6v w- SKRIPOVA, L.S,,; KOZLOVA, N.V. 4antitative analyais of the cis-trans configuration in synthetic polylsopromis, Zmv. lab. 29 no.6:704-706 163. (KIU 16:6) 1, Vessayusayy nauchno-looledowatellskiy inatitut sintatichaskoge kauchwm.- (looprone-Spectra) -- -------- L 199006.63 "~Y EM/EW1- (J) /EPF(o) /EWT(m) /BDS ASD/ESD-3 Pe-4/Pe-4/Pr-4 ACCFJSZON Iffif AP3006591 3/0020/63/151/006/1322/1325 AUTHORS i Arealer., L.-A Me mmbor AN SSSR); Dolgoploaks'l B. A.; Kcopacheva 41 #Ban V.; Nikitina, A. P. N, W~; N TITO: study of copolLporl. __1;roces3 of butadlene-1 Alt- 2.3-dinethylbutadleno-1.3 n the presence of various catalTe-ts of t ionic rype, SOMCEt AN SSSR.' Doklady*:, v.151,, no. 6. 1963# 1329-1325 TOPIC T&GS: butadienes synthetic rubber copolymerization, lithium" 2.3-dimetbylbutadione, buty:Llithiwn, H01, C sup 14, Al, tatrahydro- furan, IR, absorption spectrum, 2,3-dimethylbutadieAe, aluminum, Li ABSTRACT: The relative activities of 2.3-dimethylbutadions and but-i adiene during its copolymerization in the presence of anionic type catal h as butyllithium complex7vith totrabydrofuran, cationie Zats suc type catalysts such as aluminum ;Twdichloride in the presence of bydrochloric avid, and complex organo-metallic catalysts was studied, The micr03tructures of the polymers obtained by thi above systems L 18900-63 ACCZSSION WRI AP3006!')91 i4iso also studied. Butadiene tagged with carbon a-14 wall used to study the *omposition of copolymer. The non-radioactive polymeric microstructures were investigated by IR absorption spectra using NaCl prism. The vitrification temperature of the polymerized pro- i duct mixture of butadiene and 20-dimethylbutadlene under the Influ-1 once of oa~alysts decreases with an increase in its butadiena ratio. I This points to the formation of true copolymers and not homopolymers,1 It was found that 20-dimethylbutadiene is more active in the cation- Ic polymerization mechanism and butadiene is more active in the an- I ionic type polymerization. Copolymers f armed in the presence of com-, plex catalysts are enriched in butadiene as compared to the initial monomeric ~ mixture. The relative activity of 20-dime thylbutadi one Is slightly lower than the activity of ja2pEqne. Orig. art. has: 3 tables and 3 figures, ASSOCIATION: Nauchno-isaledovateltakiy institut sintatiohaskogo kauobuka im. S. V. Lobedeval,(Sciantific research institute for synthetic rubber) rA Rt ,5L-~i Sl k3 Tr zial -31 7r 5-30 F?llfTlx P RAI MOM, 1, A Val Rj .4 A hr ZORRI?m X'M ~VL -A, 4,L, 4, -0, N5 tv~ Of iZl r0fi ON .1 d L-qBO6-66- ACC NRs. AT6000048 conoonttadon weviodsjj~ ihOod DAM, 1OJkmM OM RZIN 001 MM REIN W2 fiv. Me.pure The avenp relauve WTW. is Dud hdwed I pwalls a A* of dw ------ wL- Mm: 3 ftm YMO-KOVA, T.T.; KHn';,A'lHF'lA, Ye.N.*, DOLGOPI,(~-K, B.A-, &kademilc; KOLITSOV, A.I., akademix; !"EL115W.-LY, Interaction of 3-me,,hyl-2-pen ten e vlwi catirin-tyTie catalyDts. Dokl. AN SSSR 159 nr~.4z815-838 D Ih/,. (MIPA 181l) jrj~3tl'f.,.jt _,,ntet4 - 1. Naue-bno-Issledav'atellskly 'cheskrigo katz"huka im. S.V. rAbedeva. ONO 00 AmP, '-REA. 61 L 98M-66-w -777- ACC NR. AP7001409 SOURCE CODE: UR/0413/66/000"/021/0110/0110 INVENTOR: Fokina, T. A.; Apukhtina, N. P.; Klebanskiy. A. L.; Nel'son, K. V.; Solodovnikova, G. S. ORG: none 'TITLE: Preparative method for polyurethans. Class 39, No. 188004 (announced by A'11- Union Scientific Research Institute of Synthetic Rubber im. Academician S. V. Lebebev ,(Vsesoyuznyy nauchno-issledovatel'skiy institut sinteticheskogo kauchuka)] SOURCE: lzobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no 21, 1966, 110 .TOPIC TAGS: polyurethan,~,.chemical synthesis, diisocyanate, di&ne,,, olefin !A3STRACT: An Author Certificate has been issued for a preparative method for poly- .urethans from diisocyanates and telomers of dienes, olefins or their mixtures. Lao,' SUB CODE: 11, 07/ SUBM DATE: 29May65j ATD PRESS: 5109 Card 1/1 UDC: 678.664 0A IV C cow 0713 jf, UA411,24- g, im lpj A ftbb4h, :~,Vr j Various -01 77,; i'*& T. `8~ no 12 2074 Y~ saii 43 lead compowd ti a p"cese* 4j,"t-4 bA m an of 4-i-Chlorofteawltormal (I) with 41OREMIs F usW lead tetrachloride th 61 i'K-:j, 03 (jj)~ kd telog4n.~ _Vaiod fftm 10: 1 to! 're *16OCr Inst except! In rft lor One fte course of wd by 3R mtIon ome a ............ . --ml ".0".26 j ji j7 Of *vskmd b tm., pose aw: &a ref4t 4a CA' vihi musti* i4w di- ocmw mod soli6, dism.- 91610to frm low 2W'W!~ am: aw i olot".t2t, Jikrs, C*4 ;q 71"a M-5 '5N -,-F Ow a 1~11~41SOIJ, Mikhail Solo )n,(jrjohVZXM14F.VA, S.T., inzh., red.; GRIGORtMA, I.S.,, red. izd-va; BEIDGUROVA, I.A., tekbn. red. [Quantitative evaluation of the reliability of machinery mid Instruments; according to reoulto of teating]Kolichestvannaia otoenka nadezhnoati sashin I priborov; po rezulltatam ispyta- nii. Leniwad, 1962. 31 p. (Leningradskii dom nauchno- tekhnicheekoi propagandy. Obmen redovym opytom. Seriia: KoD- troll kache9tva produktsii,no,7r (KM 15:8) (Machinery-Teating) Nnstr=enta-Testing) BALAKIRSKAYA, R.R.; BATALIK, B.S.; NEL1SONL-,~A.-,,;, K4KMENKOV V.V. Investigating the Inf'luence of chilling on the phase composition and structure of clinkers. Nauch. trudy PermNIU1 no.5:95-102 163. (MIRA 18:3) NEL'SOU-SKORMUKOV, W.B. [deceased) doktor tekhnichaskM nauk, professme. Flow of ground water into a river drainage channel enclosed with water imperseable sheet pile walls. Gidr.strol. 23 no.9:44-4,7 0 156. (ML" 9:11) (Water, Underground) 0oil percolation) TARAN, I.F.; POLYAKOVA, A.M.; NELYAPIN, N.M.; LUNINA, Ye.A. Characteristics of imminity in cutaneous vaccination and revaccination with vaccine from the Brucella abortus 104-M strain. Report No.2: Tenting the intensity of immunity producted by vaccine from the Brucella abortus 104-M strain in an epicutaneous application in experiments on guinea pigs. Zhur. mikr-obiol., epid. i immun. 40 no.6:128 Je 163. (KRA 17 16) 1. Iz Nauchno-issledovatel'skogo protivochumnogo instituta Kazkaza i Zakavkazlya. TARANP Ij.~--HELYAPIN, N.M.; POLYAKOVA, A.M. Characteristics of immunity in cutaneous vaccination arz revaccination with vaccine from strain 104-M of Brucella abortus. Report No.3: State of immunity in multiple revacoination with vaccine from 104-M strain of BrucelIr abortus in experiments on guinea pigs. Zhur. mikroblol, epid.1 immun. 41 no.107-81 Ja 164. (MIRA !P12' 1. ProtivochimuW institut Kavkaza I Zakavkazlya, Stavropoll krayevoy. TARAII, I.F.; NELIAPIN, N.M.; POLYAKOVA, A.M.; LUNINA, Ye.A. Comparative study of the vaccinal proceas and the intensity cf inmunity in guin6a igs vaccinated with Brucella abortus 19 and )D4-M. Zhur. mikJ66 U., epid. i imm. 41 no. 203-60 F 164. (MIRA l7t,4) 1. Protivochumnyy institut Kavkaza i Zakavkazlya, Stavropol' na Ka* 1#0 - ACC NR, 06032246 SOURCE CODH: Ult/0016/66/000/009/0070/007 AUTHOR: Taran, I. F.; Pogirelov, N. A.; Kulikova, G. G.; Kut6cmakina, A. Z.; audnev, M, M.; Nelyapin, N. M.; Rudneva, V. A.; Suvorova, A. Ye. ORG: Stavropol' branch. "Microbe" Anciplague Research Institute (Scavropol'skiy fili3l, Nauchno-isaledovatel'skogo protivochymnogo Instituta "Hikrob") TITLE: Brucellosis cultures isolated from rodents and their octoparasitus SOURCE: ;1hurnal nikrobiologii, epidemiclogii i immunobiologii. no. 9, 1966, 70-74 'ZOPIC TAGS: =~=:r, epidemiology, disease vector. rodent, parasite, animal disease. tiIaremia, lbrucellosis ABSTRACT: Twenty-eight bmcella cultures were isolated from wild rodents. their eezo?arasites and from domestic swine during z, study of the effects oi tularemia vaccination and infection upon brucella ;)enetraLion. Bacteriological as well as phage typing methods were used in identifying the individual strains. There was no cif!arence in cultures isolated from wild and domestic animals. Prolonged passaging of brucella cultures in mice. vaccinated with tularemia vaccina and infected wien virulent tularemia strains 576.851.42 ACC NC-WCO:~fiI2 did not alter their cultural or biochemical properties. !Zrgins- mission of biucalla fron wild rodents to the domestic hogiresed in -this study w" established. IWA-50; CBE No. 121 SUB CODE: 06/ SUBM DATE. 29J&n66/ ORIG R.EFI 004/ C.rd 2/2 BASHILOVA, 11. 1., NELYAPYA, 1,% 1. Possible errr~r of thallium -r.p ~;f iron. Zhur. ane.l. khim. 11) no.-L~t'1516-!1519 1 C,4 ( k I", A 18 -. I ) 1. N.S. Kurnakov Institute of' Genera-I and Ir -rpani,.- llt.em.,~try, Academy of Sciences of the U.S.S.P., 1-10svov. Aceratheres of Mongolia. Trudy Paleont. inst. ?7:108-127 160. (MIRA 1-3:10) (14ongolia--Rhi-noceros, Fossil) -L 04781-6-7- EWP(e)/EWT_(14_/LWP(L)iE'N LJ[ (c) JL) ACC V--AP6023444 ~ N ) SOURCE CODE: UR/0369/66/002/003/0295/0299 AUTHOR: !SL%~ash, N. G. ; Ntj3M!!j Mt~ -5-/ ORG: Uman' Pedagogical Institute,(Umanskiy pedagogi.,-heskiy institut); Physico-INLechanical Institute, AN UkrSSR, Llvov (Fiziko-mekhanicheskiy institut AIN U`krSSR) TITLE: Effect: of boronizing, borosiliconizing, calorilial and borocalorizing on the corrosion resistance of steel SOURCE: Fiziko-khimicheskaya mekhanika mate rialov, v. 2, no. 3, 1966, 295-299 TOPIC TAGS:, photocolor"imeter, metal coating, corro,, ion resistance, fatigue strength FEK-M photocolorimater, steel 45, steel 20 VD ABSTRACT: The effect of each of these types of the ~,urface uinpregnation of iteel was in vestigated with respect to such properties of steel 45 .'s corrosion resistancif ~ajW~Lo 14 strength and corrosion- fatigue strength. Boronizing was accomplished in a mixture of boron carbide and borax and of crystalline silicon with ammonitun chloride; calorizing, in a mix- ture of ferroaluminum. and ammonium chloride; and boronizing-calorizing and calorizing- boronizing, in boroniz*- and calorizing mixtures (G. V. Zemskov, N. G. Kaydash, MiTOM, CQrd 1/2 ------ 1141N cc 8e- '-AP6023444- - 1964, no. 36 1965, no. 5). The steel specimens thus treated were tested for corrosion in freshly prepared I % aqueous solutions of table salt, NaOff, if C1, If 1130 HNO and phosphoric acid, 2 41 3 with subsequent analysis of the spent solutions for Fe and diffusing elements (B, Al, SI) and visual observation of corrosion damage to the specimens (cracks, pits and peeling of the dif- fusion layer from the base metal). Quantitative analysis was performed with the aid of a FEK-M photocolorimeter. Findings: diffusion boronizing, borosilit:onizing, calorizimg and borocalorizing all enhance the corrosion resistance of 45 steel in 1011o aqueous solutions of the aforementioned aggreasive media. In the NaCl solution the corrosion resistance of steel is best enhanced by calorizing, calorizing-boronizing and boronizing; in the NaOH solution, by calorizing, boronizing, borosiliconizing, and boroniziA--calorizing; in the HCI solution, by borosiloconizing, boronizing, and calorizing-boronizing. Considering that many work parts perform under loads while being exposed to aggressive media, the effect of these types of surface treatment on the fatigue and corrosion- fatigue strength of steel 20 was also investigatedl and it was found that boronizing and borosiliconizing enhance the fatigue limit of the steel in corrosive media by as much as 35 and 80%, respectively. Boronized specimens dispLay a higher ; corrosion resistance and lower corrosion-fatigue strength than borosiliconized specimens. Ilis indicates that for diffusion coatings -- at least for those of the boride type -- there does not exist a correlation between the corrosion resistance of metals in nonstressed state ancr their corrosion-fatigue strength. Orig. art. has: I figure, 2 tables. SUB CODE: 13, 11, 20/ SUBM DATE: 26Jan66 / ORIG RE: F: 009 Card 2/2 oae- 06420 SOV/107-59-5-15/51 AUTHOR: Nelyubin, A. TITLE: The Way to Mastership PERIODICAL: Radio, 1959, Nr 5, P 13 (USSR) ABSTRACT: The author praises the radio gmateur activities of Yuriy Kuznetsov having a station with the call sign UA3-1063'7. Yu. Kuznetsov is presently a radio opera- tor in the Soviet Army where he can practice his skill in radio communications. There is 1 photo- graph. Card 1/1 KOROVYAKOV, I.A.; NELYUBIN, A.Ye.; RAYKOVA, Z.A.; KHDRTjOVA, L.K.; GONIsliAKO- VAO V.I., hAuchnyy red.; POSPELOVA, A.M., red.J,zd-va; IYERUSALIMS- KAYA1 Ye., tek-hn.red, [Origin of Norillsk trap intrusions bearing sufide copper-nickel ores.] Proiskhozhdenie norillskikh trappovy1ch intruzii, nesushchikh sullfidnye medno-nikelevye rudy. Moskva, Goageoltekhizdat, 1963. 100 P. (Moscow. Vaesoiuznyi nauchno-issledovatellskii institut minerall- r nogo syrlia. Trud,, no.9). (MIRA 17:2) 1. Vsesoyuznyy nauchno-issledovatel'skiy Institut minerallnogo syrl- ya (for Korovyakov, Nelyubin, Raykova, Khortova). Minos and Mining Cv Mining lbehinery 461mitanome mining at ore in'Upeaert and Spquonmj" D, To Selyublul, V, zca AWO, 3 pp mnwaal' No 10 'is asthcA working vas O~ted wA, th* ~ln var 09 mining andt "Wakuleal 0 a vor6 ust- it the =4 low9l. for varking *ji ate-, In" as tba7lvIde, ""j6pnelve bitt tW& r4oultv,, sui -liciit vhl'ch a" ~be vorked,, the v: "dvoitZoO a mfoty, of an Operat AU fow vndomimble qu&Utl**. NELMOIJORNINIOUR filir"W"'Ahs ZILIPUT, I.T.. redaktor; SMINIKOTA. L.A., redaktor isdatell-e-Tv-1; SHITS, V.P., tektinlebeekly redaktor [Work practiose of the Unurl lumber utll] Opyt raboty ussurtiskogo lemosavodae Moskva, Gotlesbusisdat, 1956. 25 1). (KNU 10: 1) (lesosavedsk-Sawnills) USPENSKIY) V.N... filav. red.i TER-ARUTYUNYANTS, G.O., zam. glav. red,; AIF--LiAJ3P!,T&N'. YP-A., red.; _ECGORAD, D.I., red.; KAPLAN, L.Z., lnzi.., red.! MAUSMIKO, C.A., red.; MEZENTSEV, I.V., red.; L~OCDA~IIVIKC. ;.!., re~.; NELYUBB, K.P., red., 0 red.; POGFXBOV, 1".N.-)--fe-cT-.j -9MUK, I~M.' Izand, tek~.P_ nau~~., red.; SrANISLAVSKTY, A.I,, red.; SLIJTFKl'-V, G,.,~',, reti.; ._;0LOF11ENKC), L.A., red. [Tranmportal.' 'ma arva ongineecu.- '..-~,,-]!Ues of cities; an aid to designe-t-,1 Tran_+ort I lnzhenernoe oborudovarde gc~- rodov; v pomos~i,hl j;.-fektir-,Dvv.:ch1ku. Kiev,, L~idivellnyk, 1964. 100 p. (MIRA 18-5) 1. Ukraim-kly -:-u,-i':i.,7trmy'y Institivt ~~ruyuktirovaniya gorodov. 2'. ~';Sl (for Kaplan, )rekhov). 3. Gosstroy USSR (for 4. Kiyev-kiv inoti-tut (for 31ivak). 5. Kiye vskiy Go mid arvtvennyy,.Anqtitut Pviv..-44rr)van"-L,vu gcxodov (for Uspangkty, Ter-Arutyunyants, Malysbenko, Mezentsev, bondarenko). 6. Leningradskiy Gosudar- stvennyy inst1tut. pruyiAtirovaniya gorodov (for Nelyubin). 7. TSentral',yri-v w-mv: hnt'.)- 1.9.9led )-va tal I t3kiy i proyektnyy inBti- tut po gradostr,i~j,.Itatm, Ho!,,.-va (for Solo "nonko).S.Kiyevskoye upravleniye po pr~rjektirovnnLy-u zhili.,hchno-grazlidanskogo i kommunallnogo str-ital'stva (for Slutrkly). NELYUBIV, N.L.p saal. uchitell shkoly RSFSR; KACHANOV, I.A.; i-IONUOVA, L.I., red.; PARFERTIYEV, M.V., red.; TARASOVA, V.V., tekhn. red. (Vanual tral.ning in eight-year schools; conference on theory and practice of the Sverdlo-irsk Province teachers] Iz opyta tru- dovogo vospitaniia. v vosImiletnei shkole; nauchno-praktichaskaia konferentsiia uchitelei Sverdlovskoi oblasti. Pod red. L.1. Wovikovoi. Moskva, Izd-vo Aked. pedagog. nauk ILSFSR, 1961. 190 p. (MIJU 15:4) 1. Akademiya. pedagogicheskiIih nauk RSFSR, Moscow. InBtitut teoril i istorii pedagogiki. 2. Dii-ektor 3verdlav,,-,kof4o ohlnstnovo inn"-- tuta usovershenAvovaniva uchitolov (for Nelyubin) ~ 34 ZaVOduyushCjjiy kabimt4m 1xidagogild Sverdlovskogo oblastnogo lustituts usaver- sbensbmvankva uchitel" (for Kachanov). 4. Zavedm7ushchaya labo- ratoriyey talidovago Tospitaniya Nauchno-issledovatell skogo insti- tuta teorIA i istorii pedagogiki Ak-ademii pedagogicheskikh nauk RSFM (for Novikova). (Sverdlovsk Province-Manual training) NELYUBIN, V., kapitan-nastavnik -------- Control of back erosion on the, Amu Darya, Asch. trump. 21 no.12:36-3? D 162* (MIRA 15:12) (Aau Darya River-Zhore protectlon) Cig INEoJ6IN,vK,, ad =fem 49 Sumemim wArimes wedw ow d idleb. T~ V. Zabolutdad " V. K. NOITUNn. 11,61" A&W~ Nash S.S.S.R. 75. 2M-117- obamvatioa was mak al the cb4ag" bwousbit aboad m erristal bAbit (Irma aeWk- to Isometric forms) by tbe follow-lag Ions: K. Na, ca. as. za. Cdo" Pbl*. F*O*. CO' 411 Intradeced 4s aftearev; Nil, asks of CA-. 9061-. PQ.O-., salts KCI, USSO. Mgas, im wad cameew A "nuudldcutka Uw*" (Call is dedwd as the aid. cows. of the ion is qw2da, " to the sula., wWck brbw Nout dw t. transkitas ad the atollin to t1w ==* = C. is Zd. by the vskee, of the laws: tho bigber this is, The Iowa a Ca, 0 10".108 suits per 1. of the %*11..N% sale. we ;ad;;t for X * W.1 Sa *; 0.07-0-08 fw PV* &w ZOO% 0.08 for Fes* and Cr&*: 0.09 CI -; 0.06 50.1-; 0.03 PO.*-. The crysta.-Imptding effects of adsorption films and anoma- loss aM. odw. are discumcd, tspmially for the vakw7 qffvc a. W. Fitel NELYUBIN, V.P., nauchrtyy sotrudnik; RUDI, I.A., veterinamyy vrach Ditilin in the castration of swine. Veterinariia 40 no.10.40 0163. (MIRA 17:5) 1. VoesoyuzWr nauchno-lasledovatellskiy institut veterinarnoy sanitarii (for Nelyubin). !IELYUBITTY V.P., nauchnyy sotr-udnik , osig of tuberculoid lesi,)ns in the veter-inar sar, " ta *~ 4. " ?-; Dia~m - y control of swine carcasses. Veterinar[la i,I no.2-105-106 (I 1. Vsesoyuznyy nauchno-issledovatellsdy institut vet~rinarnoy s~,nitarii. NELYUIPIN,.-J[.B.v nauchnyy sotrudaik Ve';erinary hygienic expertise of' pork from swine with poeudotuberculosis. Veterinarii& .41 no.10:85 0 164. (MIRA 1831.1) 1. Vaesoyuznyy nauchno-issledovatellskiy institut ve-terinarnoy sanit5trii. NELYUBIV, V.V. Gharacteristics of the hydrogeological conditions of cc,,-.-.Jrr--n:aj sediments in T:~xuaenf Province. Mat. ~.om. po izucl,.. pocizem. v0d. Sib. i Dal' Vost. no.2.37-43 162. (MIRA 17:8) - NELYU13IN ti Vitalty Yak2.,,Llevichj_MATIRjSHjNA, S.P., red.; TIKHONOVA,Ye.A., [Am Darya] Amu-Darlia. Mosivra, lad-vo 014orskoi transport,, 1963. 130 p. (MIRA 16:6) (Amu Darya--Navigation) -NELIMINA G.A., =mmm2m~-- State of the bronchi In primry tuberculosis in children. Probl. tub. no.7:24-29 162. (MIRA 15212) 1. 1z kafedry legochnogo tuberkuleza (zav. - prof. A.D.Semenov) Leningradskogo instituta usovershenstvovaniya vrachey imeni S.M. Kirovaq detskogo (rukayoditell - dotsent Ye.F.Gaganova) I rentgenolo;icheskogo otdeleniy (rukovoditell - prof. A.M. Rabinovich) Leningradskogo instituta tuberkuleza. (TUMMCUUXIS) (ERONCHI--UDIOGUFRY) (BROEHOSCOPT) HOT 44-- W IVA* _04il mt:~ 49'~' U-4. P 9d'n W4.q* 3i _~'ij J, lk w Aw. Mr -"t; 7:. KWOVICH, V.L.; KAGAN, Z.S.) NLLYUBINA, G.14. 0( -keto-~ -methyl-n-valeric and (~ , /5 -diaxy..-,d methyl-n- valeric acids as precursors in the biosynthesis of isoleucine in wheat. Biokh-imiia 27 no.ltl8l-1&7 Ja-F 162. (MIRA 15:5) 1. Institute of Biochemistry, Acadomy of Sciences of the UvrS.S.R. and Technological Institute of Food Industry, Moscow. (VALERIC ACID) (ISOLEUCINE) (WHEAT) 1. IUM-YUBOV) A. A. 2. USSR 'j-L'00) 4. Steel - Heat Treatment 7 . Gradual method of hardening machine parts mace of ,OA steel. 'Jest. 32, :,0. '3 1952 9. MoRthly List of Russian Accessions, Library of Congress, FebruaU 1953. Unclassified. ULTUBDT. A.I., Inzhener; ACWCUIN, I.P., kandidat tekhnichookikh nauk. Machine for drying green forage, preparing hay meal and making It into briquets. Sellkhosmashiza noAt3-7 Ap 156. (MLRA 9:7) (&w) (Agricultural machinery) MELYUBOV) A.I. (JAn Fxperinental Investigation of the Process of Dryine Finely-Ground Green Fodder"; dissertation for the degree of Candidate of Technical Sciences (awarded by the TWryazov Agricultural AcadenW# 1962) (Izvestlya Timix7asevskoy Sell Wwkhozyayztvennqy Akademii, Moscow, No. 2, 1963,, pp 232--236) NELYUBOV, A.I., inzh. Conversion of SZPB-2.0 grain driers for dryinr greE.n forage. 'frakt. i sel'khozmash. 32 no.1:23-26 Ja '62. (MIRA 15:2) 1. Vstisoyuznyy nauchno-issledovatel'skiy institut sel'skokhozyaystven- nogo riashinostroyeniya. (Forage plants--Drying) ,*,'I,YUBU.V, I.D., nrni t,,~j-)SJS 4 , drMa -,rks on pui I try farms in ~ e-- L -I n Pr-rr-, . _ _ 34 tC Trudy TSIU 68149-51 '64 . Charac-,ertstlcs of an -)rn~,thosis (.-)tltbret3x Ln ei pol:-t;-y slaugl~,,irnnus't. I bid . 1 152- 54 NTR~ - NELYUBOV., I*D9 --- Experimental Study of the mechanism of the transm-I'ssion of ornithosis infection. Trudy TSIU 80:25-27 165. (M-W 18!11) I.S.; DEVY-ATTA, fJ~1,YTJ*BCP.T, 1.1). A.,~ily-is cil `-e cccrirran:~- c1' orril-thosts in t,il- :. . 'I . -,: . p . . 'I~nidy TSM 8C:20-1141 165@ ( .., 4 1. NELYUBOV, L. F. 2. USSR (6C0) 4. Water, Underground 7. Divinional districts of underground waters of the Quaternary deposits of the region-covered by the glacial formations of the European part cf the U.S.S.R. ZAbstract,7 Izv. Glav. upr. geol. fon. no. 2, 1947. 9. Monthly List of Russian Accessions, Library of Congress, March 10.53. Unclassified. ~6 L: USSR/Cl:tsmochedotry Geo---.h--%mjstry. Hydrochendstry, D Abst Joixmal: Referat Zhur - Khiziya~ Nc 19, 1956; 61358 Authr-~r: Semikhatn-v, A. N., Dukhan!,na, V. 7., Neiyubcrv, L. P., R-,11.,r-v7 N. V., Garmataov, I. V.. Tolstcy, M.-7~-~,okrxsb�meq Ya. A.: et al institution: None T.Itie: Map -~f Ground Wat e:- s cBur -.pe&n P,; r' i --in, r~f '-.TSSR -- n a 'L: Iq(X: 0~ Scale with Explanal/)ry N,-)tes Original Peri-dical: Sb. nauch.-tekbn. ~.nf:-,rm. M-vo geril. i okhrany ne . 1955 dr. N~ 5 1 Abstract: The ccimpiled map -,.f gr.-,und waters of European p,.;rtion of USSR made it possible tri render mcire precise the distribution Of WELters c,f different type ac:.-rd~mg tr) tbe:~r chemical ccmposition and m:Lneral- !.zation. Lim.t,3 ~ r vary within a range frCM 40-60 t, 190YO00 mg~f1. R~-veaied a--t areas of hfAher K-content in spring and wa-tr- vt.,:Lc:h makee, 1.1' pose-f.ble tc; undertake eixpI.--r-at-c,ry Card 1/2 USSR/Goamochemistry - Geochemistry. Aydrochemistry, D Abst, Joijimal: Referat Zhur - Khimiya, No. 19, 1956, 61358 Absl-ract: w(.rk fjr K Lo underground waters of subsa',-tbear,'-ng betl;-i Lcrw~-:: Cambrian deposits. Card 2/2 BAKIROT, A.A.; LANG1, O.K.I,__HILTUBOV, L.P.; SERMMVA, N.A. In mmory of Alskmandr Sergeavich Sergeav. Sov. geol. no.62:158-165 157. (KIRA 11:6) (Sergeev. Alsksandr Strgesvich. 1878-1942) ANTIPIN, V.I.; BUDANOV, N.D.; KOTLUKOV, V.A.; LEYBOSHITS, A.M.; PROKHOROV, S.P.,, kand.geol.-miner.nauk; SIRMAN, A.P.; FAIDVSKIY, A.A.; SIEEYN, M.A.; BASKOV, Ye.A.; BOGATKGV, Ye.A.; GANEYEVA, M.M.; ZARUBINSKIY, Ya.I.; IL'INA, Ye.V.; KATSIYAYEV, S.K.; KOMPANIYETS, N.G.; KEIZUBOV. L.P.~- PONOMAREV, A.I.; REZNICHENKO, V.T.; AULEV, N.A.; TSELIGORGVA, A.I.; ALSTER, R.K.; SHVETSOV, P.F.; VYKHODTSEV, A.P.; KOTOVA, A.I.; USHKOVSKIY, G.N.; ILSEV, F.I.; ROMANOVSKAYA, L.I.; PROKHOROV., S.P.; MATVEYEV, A.K., dote., retsenzent; CHELITSOV, M.I., inzh., retsenzent; KUDASEOV, A.I., otv. red.; PETRYAKOVA, Ye.P., red. izd-va; ILIINSKAYA, G.M.,, teklui. red. [State of flooding and conditions for the exploitation of coal- bearing areas in the U.S.S.R.] Obvodnemost' i usloviia ekspl-a- atataii mestorozhdenii ugo3.lnykh raionov. Pod nauchn. red. S.P.Prokhorova. Moskvap Gosgortokhizdat, 1962. 243 p. (MIRA 15:7) 1. Moscow. Vsesoyuznvy nauchno-issledovatel'skiy institut gidro- geologii i irmhenernoy geologii. 2. Kafedra goologii i geo- khimii goryuchikh iskopayemykh Moskovskogo Gosudarstvennogo universiteta (for Matveyev). (Coal geology) (Mine water) POZDNYAKOV, B.V., kand.tekhn.nauk; _N L~~Iu_Vgornyy inzh.; TACHEV, A.A. Study of the shattering effect of large-scale blasting in the ZYryanovsk open-pit mine. Gor. zhur. no.11:46-47 N 161. (MIRA 15-2) 1. VaesoyuznM.,mauchno-issledovatel'skiy institut tsvetnykh metallov, Ust'-KamenogorA. (Zyryanovsk region--Blasting) POZI)VYAKOV, B.Y., kand.tekhn.nauk; gornyy inzh.; 3ERDYUKOV, A.K., gornyy inzh.; ZHUYKC, Yu.P.; SEDLOV, M.G. Effoct of short-delay blasting on the extent of the seismic effect of large-scale blasting. Ger. zhur. no.8:25-28 Ag 163. (MIM 16:9) 1 Vaeaeyuznyy nauchno-iseledevateltakiy garna-metallurgicheskiy in- stitut tovetnykh metallov (for Pezdnyakov, Nelyubov, Sordyukov).2. Zyryanovskiy ovintsevyy korabinat (for Zhuyko, Sedlov.). (Blasting) NFLYUBOV, YU.V., inzh.; BAZHIN, Ye.l., Inzh.; SVETLICH&"fy, S.I., takhnik Vibrations of the reinforced concrete tower headf-ams uWer the seismic effect of open pit blasting. Shakht. strDi. 9 no.7;20-22 .'l 165. (MIRA 18:10) 1. Vsesoyuznyy nauchno-issledovatollskiy gornometallurgicheskiy institut tsvetnykh metallov. ACC NR. AP70o5655 SOURCE CODE: uR/o4l3/61/000/002/0109/0109 R: Pozdnyakov, B. V-9 lrbov iINVENTO _!e V. ORG: None TITLE: A device for determining dynamic elastic soil deformations. Class 42, No. 190639 (announced by the All-Union Mining and Metallurgical ScientLfLc Research In- stitute of Nonferrous Metals (Vaesoyuznyy nauchno-looledovatellakly gDroometallurgi- cheskiy institut tevetzWkh netallov)) SOURCE: Isobretanira, prcoWshlemWe obraztsy. tovarrWye anaki, no. 2, 196T, 109 TOPIC TAGS: soil mechanics, elastic deformation, seismograph ABSTRACT: This Author's Certificate introduces a device for determining dynamic elas- tic soil deformations. The unit contains electrodynamic seismographs with identical constants and an oscillograph with galvanometer. To extend the measurement base and improve accuracy, the like poles of the working coils in the seismographs are inter- connected and the free poles are connected to the integrating galvanometer of the os- cillograph. UDCt 53l-76l:539o3;624-l31-55.OO2q5 I Acc Nat ApToo%~3 &-measurement base; Rn +rg+~.;.l and 2--vorking %I+RS2 coils; 3-Intagrating galvanometer com o8,49/ sm DATz: 2Tju164 2/2 FROLOVA, M,K.; FRIDRAN, O.A.; LIPSKY, A.I.; 6TUDENNIKOV, V.A,i NELYUBOVA. S. - L-1- ~- Waterproof roofing on a ba5e of bdtumen &nd rubber c=posit ,fcr, Stroi. mat. 11 no.2glO-ll F 165. (MIRA !8-3) NEL' I . - Tu'3077,,, ~~. L. Nelyubova, G. L. I'The effect of boron -)n Unp 7rowth :--rir! .111old of 5-,,,,nflo-.;ers, so:-be~ns, bucic-rheat, ~nt' oniozns.ll Vosco,., Cq--Ie-- -)' le-nin 'c,-Ae!-~y imeni Y. '.. Tiiriryazev. "-Osco-, 1`56 (D:Iss-rtation f-)- t'-C de~,--ee of '-andidate in Biolo,-4cal Scl-ence~ ,~nizhnaya leto-Asl 0. '1 .5, 1'-)5(. Yoscm, ussR/pjant physijl;[,7 - Mineral Nutriti.,)n. I Abe Jour Ref Zhur Biol., X~ 1.2, 1958, 53306 Author Shestakov, A.G., Pryanishnik--)va, Z.D., fielyubova, G.L. Inst Title Influence of Different Doses ~)f Boron on Buckwheat Fliver Develapment and fruiting Orig Pub &jkl. Hook. s.-kh- akad. Lm. K.A. Timiryntava, 1957, vYP- 29, 35-40 Abstract In experiments with buckwheat the dz)ses of bz;ron varied from 0 to 4 m6 in I k-3 Df sand. SiCps if a deficiency in plants which had not received D appeared after 12 - 15 days and were clearly uanifested after 1 - 1 ~ rix'&-hs. The optimal dose of boron in the experiments was 0.15 - 0.50 me in 1 kg of sand. The microscopic investiEption of the blossDms sh.~wed that with b-)rDn deficiency, apart from disturbances ia the normal structure 3f the eDnduc- tinC; tissues, there was observed a destruction of pollen Card 1/2 6 biol. nmuk NMTIM . Role of boron in the phosphorus metabolism of sunflowers [with suanar7 in English]. Izv. TSKU no. 3:167-176 058. (KIRA 11:7) (Plants. Effect of boron on) (Phosphorus metabolism) (Sunflowers) PETRJWWA9KIY, A.V.; ~T, ~YUBqVka G-.-L.- Methods for determiniaR the general anion-exchange absorptive capacity of roots by adsorption Fiziol. rest. 9 no.5.651,653 162. (HIRA 15alO) lo De4urtment of Agronomic and ftoioglcal Chemistry X.A.Timlrva v Moscow Academy of Agxdculture. (Roots(Botany)) (Ion exchange) (Plants-Chemical analysis) NKLYUBOVA, Q.L.v ka-rid. blolog. nauk Some conditions of the tifficient use of ',race e-lament. fertiliz(~.-j Ln the non-Gherriozem belt. Iz-v. TSKHA no.I: 84,91 't-4- (1-11."1 17-4) 1. Kafed,:,~I i. ~- biok.-Amii MoBko~rj,(Cy or,ienzi I-en-:1a akademii imeni Timi.ryazeva. VOLIPM, I.H.; RLTUBOVA, R.A. Our afficlency promoters. Kona. I ov. prom. 13 no.9:9-12 S'58. (MIRA 11:10) 1. Leningradakly konbinat ptshchavrkh kontsentratov. (Canntng in4ustry-Squipmont and supplies) MAN'KOV, D.F.; OREKHOV, N.I.; POWNETSKIY., S.D.; NELYUBOVA, Ye.I., red.; DUDAKOV, V.A., tekhn. red.; tekhn. red. (Agricultural machines] Sellskokhoziaistvenzwe mashirq. Moskva, Sellkhozizdat, 1963. 502 p. (VIRA 170) BU LKIN,, A,; KOROBEYNIKOVA, A., ekonomist; MURTAZINA, Kh.; NELYUBOVSKAYA, V. ------------------- Work conscientiously and have a creative attitude tov.-,rd dorkl Fin. SSSR 23 no.10:59-61 0 162. (RIRA 15:10) 1. Starshiy inspektor Z-hdanovskogo rayonnogo finansovogo otdela (for Bulkin). 2. Kiyevskiy myonnyy finansovyy otdal (for Korobeyndkova). 3. Starshiy ekonimist Timiryazevskogo rayonnogo finansovogo otdola (for Murtazina). 4. Starshiy ekonimist Finaneovogo upravleni~a Ispolnitellnogo komiteta, Mosgoreoveta (for Felyubovskaya). (Moscow-Finance) I -U,D I ijli(jVh 1, i,"i. ' ~J IN , V V I-Eld Arialycis of the hhu,-irlp foreall producu) fruir. Krazmfyar~sk ',err! ~t,nl tiriallz tramilortnykh izderzhek po vyvczu lesn-11 iz K,-w;nclirskogc kraia. Mosk-vn v T:;e-ritr. i n-1. *L,*-,Aha;, 1 rX tsii i tekhiiiko-ckc-.n. 1 .0 1-.0 1"FniO I, I -'~Ol ;I bumzhnol-,, derevcubraUI!.:r~,a*.i khoz., 1963. 18 p. RODIOROVS AoKaj IIMIZrI# Vol*& nsuclq7 catrudnft 5 Old WOPOMUen of the sawmillbW wW wood. uMkLV IQMstI7 Ln &WW7W~k TftrltftY* T"* TIIIPUAMhW nftg$3848 V. OMA 188u) RODIOWNO A.K.1 NEL-Zl.x,,V,Z,p nauabW notrudnlk AnaysW the snort of forest products from the KnumWar-sk Economic Region, TrWy UNIFILoodmv no.907-44 064. (mm m U) ASS, Ya.K.; NELIZINA, O.S.; PYA'MVA, V.N. Abstracts of articles received by the editors. Ort. travm. -4 protez. 23 no.10:77-79 0 162. kJURA 17:JC)- 1. Iz gospitallnoy khirurgicheskoy kliniki (zav.- prof. S.Yu. Minkin) Permskogo meditsinskogo instituta (rektor - dotsent T.B. Ivanovskaya) i Permskoy oblastnoy klinicheskoy bollnitsy (glav-nyy vrach- V.V. Pleshkov).