SCIENTIFIC ABSTRACT NEYMARK, YU. I. - NEYSHTADT, L. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136820011-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

BOYART".W. V.S. (Gorlkiy);
Vibration of a shaft in ball bearing. Izv. All SSSIR. 101uh. no-3,
1 0
49-59 14y-je "5. ~'Mmk 18:7)

GOLIDBERG, V.N.; tTv-,Y~'~,4RK,_Tu.T..-(.0orlkly)
Correct formulation of a rionlinenr mixec"I nroblem for a wave
function on a plane. Mht. Sbor. 67 no.1:16-54 My 165.
(MIRA 180)

c a- r. r-, :7
12u,
1 . Is s lt-dovu to -i It i y t' 1 z 1 ko-tekl ni (--I, i-,. sik ins 1 tl~ r i T' G V K C-U!
gorjudarntvennot:: 'I '(,CI
July 28, 19~-4.

L 20621--g, T/Wll) UP(d)
SOURCE CODE: UR/028016610001001/0017
NRo AM"10515
#kLy)
StcomgLng Re Qv (Gor
AUTHORt 1eynarko Yu, 1, (Q*r'kLy)j
ORG: none
.TITLE: Approach to the problem of-aearchLag for the extremum of a
functiork on the basis of the principle of maxLmum information
,SOURCE: AN SSSR. IzvestLya. Takhaicheskays, kLbernatLka, no. t,
17-26:
TOPIC TAGSt automatic control, information theory, mLaimax problem,
function extremum searching
ABSTRACTt A n6v approach to the problem of searching for the extre um
of a function is proposed,usLug the concepts of information theory%
It is assumed.that the rea'l function (P(x) whose extremum is sought is
defined an the net X and belongs to the class of functions 4 in which
~'the a priori dLstrLbution.E(1P) of probabilities #.(x) that function
(P(x), has &a extresum at the polat :x6k' is gLvea, Using theme facts#
the entropy 11(z) of the location L~':Gtroduced. When the addLtional
information I concerning the function 4P(x) is obtatned, the candLtioa&L
antropy H(x/I) is introduced &,ad the amount of information
card 1/ 3

L 20691-66
ACC NR_- AP6GGS5t5
H(z) -H(xll) > 0 (L)
concerning the location of the extrenum is derived. Assuming that
there Is a set E of possibilities of obtaining information concerning
the function (P(z) the search for the extremum-consists of a.sequence
of stepstevery one of which tAtLILzes a certain possibility aCeZ.
Utilization of posaLbilittes a is. coupled with certain, tosses,-! there-
:fore* -the -concept of I the ."cost" of searching in the form of a real
function Tk so Tk(ClIso-Ok, 10 is introduced.. - The totality of rules
detarmining which possibility must be utilized~at each step of the
search is catLeUthe search:strategy S. The problem of determining
~effectLvely the strategy S which corresponds to-a relatively small'
cost of searc#~Ls considered. The proposed method consists in deter-
mining on the (k + I)-th step- a possibility- oCiE which ensure# the
maximum mathematical expectation of the obtainable information con-
cerning theiestramun of 9(*) per unit cost of search. Such choice of
sLbLlitiesi, principle of maxitdum information and the
oe s called the
P
corresponding strategy S is called.the maximum strategy* Search for
optimal strategies by, means of electroinic computers is presented for
models la 'whitch classes of function* #1 and, 02 consist of functions
with one minimum and which are described by.firzt--,~atid second~-order
difference equations, respectively,,The:choLea of optimal strategies
_r 3
Card 2/
i JI I I.I

L 206 -66
A& NR: AP6008515
F
is also analyzed for the clmss of functions described by first-order
Aifference equations with rmndom.parameters. The search for the
extremum of.the function 9(x) in the presence of noise Is also
considered. The effectiveness of the.method presented here is com-
pared with the mlinimax method of 1. Kiefer. OrLg. art. has: 2 num-
bered equations,.6 figures., and 4 tables. (LK)
SUB CODE: -047,1-2SUBM DATE: 040ct65/ ORIG REY: OTH REP: 004
ATD PRCSS:q~L'?-3

NR: 'AP6004554 -SOURCE CODE: UR/01031(i6fQ6d/O6tlDlL3/*'iL"87-
AUTHORS. uo to (Gorlkly); StrangLn,, R. G. (Gor'k1y)
ORG: none
TITLEt Search for the extremum of a function by the principle of
maximum Information
SOURCEt 'AvtomatIka i tatemekhanika, no. 1, 1966# 113-ttS
TOPIC TAGS1 automatic control, extremal control,optimal strategy,
function extremum.
ABSTRACT: The authors analyze a procedure for determining.the
,V extremum of's real ftinction q)(x) defined on the 'set x and pertaining
1-5-to a class of functions 4 In which the a priori distribution f((P)
of probabilities that the extremum of function.900 Is at the point
is given* When some additional information I concerning the
function q)(x) is obtained, then the a priori distribution f(q)) is
replaced.by the a posteriori distribution f((pfl). The entropy H(x)
and conditLonal entropy H(x/I) are considered as the measures of
Information concerning the location of the extremum. Assuming that
there Is a act E of possLbLILties a for obtaining the information
conceraLag function 9(z), the process of seeking the extramum consists
card 1/ 2 UDCt 621.391.133:519*3

j 'U7Q-
ACC NRs AP6004554
of a sequence of steps, a certain possibility being used at each step.
A set of rules determining which possibility -'aesX Is to be utiLized
at every step is called the strategy So The search for the extremum
is carried out in such a manner that the mathematical expectation of
the information obtained at every step concerning the location of
the extramus is maximum. The strategy for selecting the possibilities
satisfying this requirement to called the optimal strategy. As an
illustration of the method, an example is presented in which the set X
Is taken as the a discrete points of the number axis*and the class of
function* 0 consists of all possible solutions of a fLret-order
difference equation with random coefficients and random initial condL-
tions. The optimal strategies Sopt were determined with the aid of a
computer. Orig. art. hass I formula, JLKJ,
SUB COD6 .01'/ SUBH DAM
12Apr65/ OTH RM 002/ 1 ATD PRESS: 'Y-W/1

L 25,994-66 :D(Wd)/L~003, IJP(c)
Mks AP6012542. FOURGS CM& =4076MUM702361/10=
AUTHORSt Keywark, Ytt.. 10 (Gor'kiy); Yhfayev, N. A. (Gor'kiy)
OROt none IZ3
VITLEt Stability of steady motions,of holonomic and nonholo c 5-ydems
WMICt Prikladnaya matematika i mekhanikat v& 30j, no* 2# 1966# 236-142
TOPIC TAGS: motion stability., imadulum mechanicso coordinate systemp
porturbationj,
ABSTRACT! It is shown that dynamic systems with a manifold of steady motions possess
a number of singularities. Some results of a theoretical study are illustrated by an
example of a plane pandulume A systen with incomplete dissipation of mechanical
energy whose motion is described by
aL d OL
7t--Fj-j- + YJ NA
is considered. In the case of holonomic as well as nonholonomic systems, the steady
motions forn a manifold of a certain dimensionality q > Oe In the case of a holonomic,
n - in,
systems q > The singularities of the system are expressed by the presence
Cavd -112-

ACC NRs AP6032647 CA) SOURCE CODE: UR/0020/66/179/003/0533/40536
AUTHORS: Neymark, Yu. I.; Fufayev, N. A.
.............
ORG; Scientific Research Institute of Applied 2-Tathematics and CybernetiC3 at Gorlkly
State University imeni N. I. Lobachevskiy (Ifauchno-issledovatellskiy institut
prikladnoy matematiki i kibernetiki pri Gor1kovskom gosudarstvennom universitete)
TITLE: On the problem of track stability of vehicles on pneumatic tires
SOURCE: All SSSR. Doklady, v. 170, no. 3, 1966, 553-536
TOPIC TAGS: stability criteriont potential energy, kinetic energy, motor ve"nicie,
aircraft tire
ABSTRACT: Using the various theorems first derived by M. V. Xeldysh, an ana-'Y3~-.- 13
made of oscillations of a vehicle with pneumatic tires. The equations of motion for
a vehicle with m-pneumatio tires are written for small departures froj a straight
line motion, along the OY-axis, with a constant speed V. The vibration of the tires
(without slipping) is given by the two equations
xt + ~l + Vol + VW 0; 6, + T', 1%,VEl + PV(P, + T'V%, = 0,
and the kinetic energy of the system is given by
UDC; 531

ACC NRt AP6032847
M
d cIT OT (au a-VA au X WO
! +
-d--5-1 - Qj+ d~j aq, ax, a9
a*j I j aqj
(j = 1, 2_ nj'.
.
ese equations are then simplified by using the assumption of very large speed V.
h
This leads to the result
Vt'+L VZ'-VO'.
Three more equations are derived by taking the derivative of the potentiall energy U,
with respect to the three coordinates 9,, -X,, j9,. These equations are then
designated as generalized lead-angle hypotheses. As an example, the vibration of an
airplane chassis with three pneumatic wheels is discussed. This paper was presented
by Academician A. Yu. Ishlinskiy on 23 December 1965- Orig. art. hass 15 equations.
SUB CODE. %3 / SUBM DATE. 23Dec65/ ORIG REF, 008/ OTIR RFF. 006

ACC NR, IP6036752
Neymark, Yu. I.; Fishman, L. Z.
SOURCE CODE: UR/0020/66/-';/Wl/W44~00~f,
ORG: Scientific Aesearch Institute of Applied Mathematics and Cybc.:-.-.--.-cs at Gorlkiy
State University imeni 11. 1. Lobachevskiy (Nauchno-issiedovatellakiy -nstitut
prikladnoy matematiki kibernetiki pri Gor"Acovskom gosudarstvennom un 4.1;..-34tete)'
TITLE: On tho overall behavior of phase trajectories of quaoilinear c-'ferential
equations with lagging arguments
A21i SSSR. Doklady, v.
ordinary differential equation, parti..~l differential eq7uatlon, nonlinear
i
ABSTRACT: The overall behavior of phase trajectories is studied in a dynamic system
described by the quasilinear differential equations with lagging arjrunents given by
Aox + A Ix (i xt) + + A,,,z
IA/(t; Z(9). X(t - TI), X(f - V-))f
ahere x is an n-dimensional vector, the A iare constant matrices, the T i are constant
lag times, and 1A is a small parameter. For the special case when Al = A2
ILm- 0, the equation above satisfies the equation

ACC NRs
X (I (P (0) + JA j!A('-1.-) f (v, z (v) x (v - v.)) dv.'.
0
It in than~shown that for small jL, the eyatom described by the first equation leads
to a set of 2-nd order independent equations obtained by-averaging over the equation
L +
Ek Pata, 4: IL4 (Pk) 2 EA (f) + n (t) .... . Elk (t~
t, 2,
where 00 and the quantity FA(t Tj) is substituted by t-YA114 1). This paper
was presented by Academician I. G. Petrovskiy on 21 January 1966. Orig. art. h~s: 14.
equations.
SUB CODE: 12/ SM DLTEs 1.~Jan,66/ CRIG REF: 009/ OM REFs 001

Karl F~rantovicb.
Forging, stamping and equipment of blAck-mith shops Moskva, Gos. nauch.-tekhn. izd-vo
lit-ry po chernol i tsvetnoi metallurgil, 1945. 403 p. (49-56726)
TS225. N4

NNYIUit. A---------
A scientific basis is needed for improving the aftinistrative
apparatus. Sots.trud 4 no.7:126-127 Tl 160. (HERA 13-8)
1. Rachallnik planovogo otdala Aktyubinakago khimicheakogo
kombinata im. S.M.Kirova.
(Aktabiask-Chemical industrias)

NMT,R, Yu.L.
--- I...'' - - - -
In defense of thp branch principIc., NTI no,lill-12 165. (KERA 18:6)

Yj) V V'-
mr :nd r e
L~ f i f rn tj ri . 'v !a n

DF,MIDYUK, P.; CIERNETSKIY, G.; NEYKS,,A.
In the struggle for the title of enterprise, shop, brigade,
and shock worker of communist labor. Muk.-elev. prom.
28 no.7:22-24 Jl 162. (MIRA 15:9)
1. Umanskaya realizatsionnaya baza Cherkasskoy oblasti (for
Demidyuk, Chernetskiy). 2. Nizhnetagillskiy mellnichnyy
Kambinat (for Neyms).
(Grain handling)

DANCIW, V.I..; KORUILOV, Mjtj. OLIM. Y.Y.;
PROSHMAXOT, B.K.; STUALUNOT, I.P.; SYTNIKOV, M.P.
Uranium mineralization in carbonate sedimentary rocks.
Geol.rad.mestorozh. no.6:27-38 K-D '59. (MIU 13:7)
(Uranium oreiv)

NLD4-fSm,v, m.v.
Sinter formations of water iron oxides from m-*-ie -wa.e,,.- in
the Sary-Biya (nort-.ern Fer
gyana~. Zap. Fir. Otd. Vses.
ob-va no.5:'-17-100 1 ~,-, .
(l,'J!)A 1?:7)

5(3) SOV/79-29-5-18/75
AUTHORS: Petrov, K. A., I Smirnov, Ye. V.
TITLE: Anhydrides of Phosphono Isobutyric Acid. 3 (Angidridy fosfonizo-
maslyanoy kisloty. 3)
PERIGDICAL: Zhurnal obshchey khimii, 1959, Vol 29 , Nr 5,
PP 1491 - 1494 (US3R)
ABSTUCT: In the present paper acid monochlorides of phoophono ioobutyric
acid esters as well as inner cyclic phosphono-carboxylic an-
hydrides were described. The synthesis of P-acid-monochlorid.-as
was carried out by interaction of phosphorus peiitachloriae ,-;ith
phosphono isobutyric acid esters. The yields of acid chlrrides
are satisfactory if the reaction talres place in an inert 3olvpnt,
at 60 - 701 and at a molar ratio of the reactants of 1:1. _'kith
excess phosphorus pentachloride and at higher temperature a
mixture of P-acid monochlorides and P-acid dichlorides was "ormed
from which it was impossible to isc)lqte the P-acid monochloride
by fractional distillation. Accordin6 to the abovemeationcd
method acid chlorides of the dimethyl-, diethyl- al.d eti.y1butyl
esters of the phosphor-o isobutyric acid were obtained. Acid
Card 1/2 chlorides of diesters of the phosphono isobutyric acid are

79-25-5-1, '7'
Anhydrides of Phosphono Isobutyric Acid.. 7) S V, I
colorless liquids which can be distilled at low pressure
They hydrolyze comparativelr easily -.-.,ith -aater. Pheir t".
stability increases with an incr~.,asing number of carbon .t,
in the e3ter group. During thin r--~,action of the trim~:"~,." 1
of the phosphono isobutyric acid with FC1 5 at 700 in
to the acid chloride another substaiice is separatod --;it~. t. c-
melting point of 101 - 1020. It cont&ins no chlcrine, :-T--d
from the initial ester by its constants. Tlies--3 comj,ouiv's c:.-,. 2
formed because of an intramulecular separation of mpt!,yl c`~ e
from the acid chloride of tho dimethyl ester of the phoc,h-'rr.
isobutyric acid. The acid chloride of the diethyl evti7r Of t~.e
phosphono isobutyric ester also decomposes on continuous
up to 150-1700 and ethyl chli~ride and an inner ar-hydride ~-~f t-,Q-
P-ethyl ester of the phosphonc isobutyric acid are form(-'. .~"e
inner anhydrides of F-phosphono isobutyrates readily hydrolyze
with water and yield two-baof1c acids the titration of whict, con-
sumes exactly 2 equivalents of alkali. The P-methyl-phocptv.tic.
isobutyric acid methyl-ester was separated in the form of a .;ilveiy
salt. On alkylation of this salt with methyl iodide the authors
obtained trimethyl esters of the phosphono isobutyric acid.
SUBMITTED: March 20, 1958
Card 212

50) SOV/79-29-5-19/75
AUTHORS: Petrov, K. A., Neymysheva, A. A.
TITLE: Reaction of Aliphatic Amines With M-Chloro-Ethane-Sulfochloride
(Reaktsiya alifaticheskikh aminov s ~ -khloretansullfokhloridom)
PERIGDICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 5.
PP 1494 - 1496 (USSR)
ABSTRACT: In the present paper the conditions were investigated undE!r which
by the action of dimethyl- and diethyl amine upon ~ -chloro-
ethane-sulfochloride vinyl-oulfodialkyl-aqiides and dialky-.-amino-
etliarle-.gulfodial.',:yl-amidet3 are formed. The yields are about 5(),,,'.
The reaction was carried out in ether or chloroform at different
temperatures (from -10 up to + 600) and at a molar ratio .)f sulfo-
chloride: amine - 1:3- In all cases identical pruducts were ob-
tained. Probably the reaction of amines with A -chloro etrane-
sulfochloride proceeds in three steps:
(1) CICE CH SO Cl+ 2MN'11 -0 ClC11 C11 so + rl:~11 Ucl
2 2 2 2 2 2 2 2
(II) ClCH 2C112SOI)NIIR + MiH2-* CH 2 - CHSO 211HR + IG;H2HC1
Card 112 (111) C11 2 -CHSO2111111 + RNH2-4 immcu 2C112 so2NHR

Reaction of Aliphatic Amines With 0 -Chloro-Ethane- SO V/759-79-Ir - 1 ~,75
Sulfochloride
From data published and the results obtained in this st,,ty it
may be COnClUded that the reactions (I) and (II) pvocc,ol with a
high rate. The reaction rate of (III) dopeiida on Vie cl,.er-oter
of the amine. Dialkyl-amino-etliane-sulfodiall~yl--,mid,as ---7o ilso
obtained by the addition of dialkyl amines to viny1--ui.r!!4,,,1xy1-
amides at room temperature. There are 5 refere[LCeB, 1 'if -ii("h
is Soviot.
SUBMITTED: March 20, 1958
Card 2/2

AUTHORS. Petrov, K. A.; Neymysheva, A. A. SOV/79-29-6-10/72
TITLE; of Dialkyl Phosphorous Acids W'.t:*- ".e
thiocyanates (Prisoyedineniye dialkilfooforistykh kislot k
alkilizotiotsianatam)
PERIODICAL: Zhurnal obshchey khimii, 1955, Vol 29, Nr 6. pp 181QI-1821
(USSR)
ABSTRACT: It is shown in the present paper that the dialkyl-phosphites
u1t-, the alkyl-isothiocyanates, thus forming, the
esters of the alkyl-amidcl-phogphono-thioformic acid
(R0 )2POH + RNC SRONa -0 RC> P-C S
R 0 NRR
. The reaction proceeds
in the presence of sodium alcoholate under evolution of heat
and is completed by heating. Heating time and temperature
coinditiono markedly affect the yield in the end product,, If
the reaction mass is subjected to vacuum distillation
immediately after heating,. a decomposition of the reaction
product takes place after removal of' the low-boiling
Card 1/3 constituents. The eaters (if the alkyl amides of the

C--=bination of Dialkyl Phosphorous Acids the SOV/79-29-6-10/72
Alkyl Isothiocyanates
phosphono-thioformic acid can only be distilled after
washing the reaction mass with water. The reaction of the
phosphites with isothiocyanatee was carried out with methyl
and allyl-isothiocyanates. In the latter case the addition
took place both at the C-C and at the H-C bond. In the firot
case the eaters of the y-isothiocyanate propyl phosphinic
acid must be formed, in the second the esters of the allyl-
amido-phosphono-thioformic acid (Scheme 2). The latter esters
are determined by hydrolysis of the reaction products with
hydrochloric acid, in which connection phosphoric acid is
obtained, as was expected, which was separated in the form
of the trianiline salt. The alkyl-amido-phosphono-thioformates
are viscous, yellow liquids with a strong unpleasant odor,
which are easily soluble in organic solvents. When heated
with hydrochloric acid (1 : 1) 'they are hydrolyzed to give
ortho-phosphoric acid. The constants of the compounds
synthesized are given in the table, There are 1 table and
6 references, 3 of which are Soviet.
Card 2/3

AUTHORS: Petrov, K. A., Gatsenko, L. G.9 SOV/79-29-6-12/72
Heymyshevag A. A.
TITLE: Eaters of the Alkyl-cyaao-phosphinic Acids (Efiry alkiltsi.an-
foafinovykh kislot)
PERIODICAL; Zhurnal obshchey khimii, 1959, Vol 29, 14r 6, pp 1827 -- 11851
(USSR)
ABSTRACT: In addition to the authors' papers (Ref 1) the influence exer-
cised by the alkyl halides upon the dialkyl-eyaao-phosphites
was investigated in this paper. The authors assumed that this
reaction takos place according to the rearrangement of Arbuzov,
and eaters of the alkyl eyano-phosphinic acids were to bit ex-
pected which was confirmad experimentally according to the fol-
lowing scheme:
(RO)2PCN+RIJ RO )2p'\ iR +Rj
RO/ CN
N.-propyl-methyl-cyano-phosphinate was thus formed under pres-
sure at 1600 within 8-10 hours from di-n.-propyl-eyano-lihosphite
Card 1/2 with the 3-4 fold quantity of methyl iodide, the structUre of

Eaters of the Alkyl-cyano-phomphinic Acids 3OV/79-29-0..',2/72
which was confirmed by the analysis (8CF% yield). Chlorine, when
reacting with it in the presence of an equimolar quantity of
PC1 3' irields methyl-phosphinic acid-dichloride the constants of
which are in agreement with the data published (Ref 2) (Scheme
2). The synthesis suggested of the alkyl-cyano-phosphinates is
of general character. These esters are colorless liquids, sol-
uble in organic solvents and hydrolyze readily with water and
alkali lyes. The dialkyl-cyano--phosphites used as initial pro-
ducts were obtained by substitution of the CH-group for the
chlorine in the dialkyl-chloro-phosphites by means of silver
cyanide in other on heating. Alkyl-eyano-phosphites are liquids
of unpleasant phosphine odor, soluble in organic solvents, which
form solid complex malts with cuprous chloride. There are 3 ref-
erences, I of which is Soviet.
SUBMITTED- March 20, 1958
Card 2/2

5(3)
AUTHORS: Petrov, K. A,,, SOV/79-29-7-15/63
TITLE: Carbylaminolial-ides (Yarbil~a,-,~.ingalul,enidy). 1. Aliphatic
Carbylaminochlorides (I. Alifaticheakiye karbilaminkliloridy)
PERIODICAL: Zhurnal obshchey khimii, 1959, Val 29, Nr 7, pp 21165-2168 (ussil)
ABSTRACT: According to references 1,2,3, only ~-3hioroethyl and trichloro
methyl carbylaminochloride are knorn amona the little investi-
gated aliphatic carbylaminochlorides, rhich, horever, are also
little investigated. In the pros.:?nt paper the hitherto unknoun
methyl carbylaminochloride and the intermediate products
obtained by an improved method in the synthesis of trichloro
methyl carbylaminochloride as well as some 1~roperties of
aliphatic carbylaminochlorides are described. i'llethyl carbyl-
aminochloride was obtained by the chlorination of methyl
isothiocyanate in ether at 00. The authors used its charactariE-
tic property, i.e. to free iodine from acidified solutions of
potassium iodide, (1 mol'- 1 mol), for a quantitative
determination of methyl-, ethyl-, and O-chloro ethyl
carbylaminochloride. This process is shown bY a scheme.
Card 1/2 Aromatic carbylaminochloridea in this case separate no iDdine,

Carbylaminohalides. I. Aliphatic Carbylam-4nochlorides SOV/75-25-7-15/63
in contrast to aliphatic carbylaminochlorides. In this respect
trichloro methyl carbylaminochloride occupies an intermediate
position betreen aliphatic: and aromatic compounds. In contrast
to aromatic carbylaminochlorides, methyl- and trichloromethyl
carbylaminochloride do not reaat with H S; with sodium ar-d-
copper sulphides in solutions they reaci only at higlier
temperatures (above 1000). In the action of aniline cn
trichloro methyl carbylaminochloride alrays a complete
substitution of chlorine atoms takes place. From the reaction
products probably the guanidine derivatives (I) and (H) vith
equal empirical formulas viere obtained, however, they were not
further investigated. The syntheses of trichloro methyl
mercaptan described in publications (11efs 3,4) are very
complicated and produce low yields. By modifying Milton's
synthesis (Ref 4) it was possible to increase considerably the
yield, i.e. by reducing the amount and concentration of nitric
acid as well as by longer heat-ing of the reaction mass
(see experimontal part). There ;,Lre 13 raferoncon.
SUBMITTED: March 20, 1958
Card 2/2

5(3)
AUTHORS: Petrovt K., Aep NeymXsheval,4. A. SOV/79-2~-7-16/83
TITLE: Carbylaminobalides (Karbilamingalogenidy). II. SynthAsis if
Secondary Amines With a Trifluaromethyl Group (II. Sintez
vtorichnyk-h aminov a triftormctillnoy gruppoy)
PERIODICALs Zhurnal obahchey khimii, '1959, Vol 29 Nr 7, pp 2169-217-)( USSR)
ABSTRACT: This synthesis vas carried out by the authors by reaction of
hydrogen fluoride with carbylaminoctlorides. Secondary amines
with a trifluoro methyl. group on the nitrogen are formed as a
consequence of the subsequent affiliations of HF to carbyl-
aminohalidos and the separation of hydrogen chlorine from the
correspondf.ng compoundat C1
R-N-CCI2+HF 0 RNHCCI2F -HC1 ). R11= C + HP
HC1 + HF
Card 1/3 0 RNHCC1F 2'- . P, RN=CP 2 RHHCF 3

Cax-bylamino,halides, II, Synthesis of Secondary A-mines SOV/79-29-7-16/83
With a Trifluoromethyl Group
Carbylamincchlorides react rigorously with HP at low temper-ature;
in this connection, according to the reaction conditions,
secondary amines or polymers of carbylaminofluorides are formed.
The reaction of hydrogen fluorides with phenyl, p-tolyl-,
9 -chloroethyl-, and trichloromethyl carbylaminochloride led to
the following compounds: phGnyl trifluoromethylamine (68.5
p-tolyltrifluoromethylamine (70 %), hexafluorodimethylamine
(85 jfo), and acid fluoride of ;I-cliloroethylcarbamic acid. In
the reaction of aniline with phenyl trifluoromethylamine onl.,r
one fluorine atom is replaced by the aniline re S4 idue, and cnly
by the actic-n of water diphenyl urea is formed (Scheme 2).
The ease with which hexafluorodiu..ethylamine is formed in the
reaction of HP with trichlorometbylearbylaminochloride is
explained by scheme 3. In the en,3rgetic reaction of
P-chloroethyl carbylaminochloride with aF at low temperature,
rithout solvent and with an excess of HF, difficultly
separable polymers of fl-chloroethyl carbylamincifl--iorides ar~?
formed. In the action of aniline on acid fluoride phenyl-
~ -chloroethyl urea is formed. The hydrolysis of
Card 2/3

Carbylaminohalides. II. Synthesis of Secondary Amines SOV/7r,-'-??-7-16/9,2
With a Trifluoromethyl Group
hexafluorodim43thylamine is illustrated by sch6mr-, 4.
There are 5 reforencess nale of which is Soviot.
SUBMITTED- March 25, 1958
Card 3/3

SOV /79 -2,; -6- 55/8 1
A 1'HORS: Petrcv, K. A., Ne;,
'-ITLL:
Carbylamine Halides - III. A New Method of Synthesizing Carbyl-
amino-flucrides
PERIODICALt 4"hurnal obsnchey khimii, 1Q59, Vol 29, Nr 8,pp 26?;-2-_'98
ABSTRACT: The syntheses of carbylamino-flaorides according to R. N. Has-
zeldine (Ref 2 -and others are of limited value since they
only yield i)~ri'lici,o-alkyl-carbylamino-fluorides, and cannot be
applied to the synthesis of carbylamino-fluorides which contain a
non-fluorinated radical. which is directly bound tc the nitrogen.
The carbylamino-fluorid.es already known are listed in the table.
In the present paper, a new method of s,ynthe5izing the carby.'-
amino-fluorides is described which is based on the splitting-off
of hydrogen fluoride from secondary amines containing a tri-
flaoro-methyl group. Sach amines can be synthesized (Ref 3) by
reaction of the carbylamino-chlorides w1th hydrogen fiuoriae,
Phenyl-ti-ifluoro-methylamine and hexafluoro-dimethylamine were
dehydrofluorinated. On heat4ng the former wit?i potas-cium fluor~"e
ui) to 14G-1500 without a solvent for 4-r hours, the pnenyl-carbyl-
amino-fluoride is formed. It boils at 490 (12 = Hg,, and is
Cara 1/2 rather well preserved in a closed container, also vjithoat a sta-

Carbylamine Halides. III. A New 1.ic-thod. of Cynthesizing SOV/79-29-8-5j/~Jl
Carbylamino-fluorides
bilizer. On heating with quinoline, no njdrogen fiioride is
split off. By passin.a the nexafluoro-dinethylamine va-pors t~-.ree
times through a glass tube fillcd with granulated KF (9 mm dia-
r.,t,ter) at 14o_15oo, ti-ifluoro-mc-thyl-carbylamino-f-uor-'-de is
obtained (70/'6' yield) in addition to a product of unknown nature
(Experimental Part). Attempts to obtain carbylamino-flucrides by
substitution of fluorinE' for chlorine in carbylamine chlorides
by means of different metal fluorides, were unsuccessful. The
trifl,,ioro-methyl-carbylamino-fluoride boils at -32-530, reacts
vi orously with amines, hydrolyzes with water to form CC2 F- and
M1 4' This hydrolysis takes place according to the s -,heme
F
+H20 / //0
CF IT- CF ) CF --114 CF NHCV There are 1 tablE
3 2 3 3
.Uri F
and 5 references, 2 of which are Soviet.
SUBIMITTEL: March 25, 1958
Carc- 212

50) 30V/'79-29-9-46/7 6
AUTaORS: Petrov, K. A*, Neymyshova, A. A.
TITLE: Synthesis of the Derivativps of PhosDhor.osulfonic A,~ids
PERIODICAL: Zhurnal ob.13hchey khir.,k 4. J- 1,9, Vol 29, Nr 9, pi~, 3026-3030
(USSR)
ABSTRACT: Apart from a patent lle:3 C TJ-b:'-n1g the syntha-sis of ~rimethyl
phosphonosulfonates 1y reacting t7ialkyl phosph-ites w--'th sul-
fones (Ref 1), the phoapi-onosulfonJ~. ac-*ds are only little in-
vestigated. in the pres-~nt pape-r ".-le G~znthesfs of similar
pounds is made by the addition of halky! phosphites to the
derivativea of vinyl sulfon4 'c, acid. Esters, dialkylamide5 and
the fluoride of vinyl sulfonic ac':1 aere used for the reacticn
with phosphites; howevel-, not irl all cases derivatfves of
ethylene phosphonosulfonic arid :.-,-,3,ulted. Th,~ di--Ikyl phoephises
add the dialkvl amideo of vinyl sul-fonic acid in ,he presen-,e
of sodium alcoholate in heating to 110)c' witnin 6 hours, and
eaters of dialkylamictoo of athyleno phc3phoiosulfoni:~ ao~d art;
formed in yieldo of' 60-70~6. Unlike dialkylamildeo !"he
of vinyl sulfonic acid adds the dialk.~! ph.~sj~hites in ths ab--
sence of sodium alcoholates. In this ocnnectior. th-e intro-
Card 1/3 duction of fluorine con2iderably intensifiets the acti-.r4ty :,f

Synthesis of the Derivatives of Phosphono-sulfornic Acids
SOV/179-29-0-416/76
the double bond. The react4,Dzr, takes place at 1101 according to
the scheme (RO) POH + C11 'C11SO,F---9,RO PCH CH 30 F. In the
2 2 211 2 2 2
0
action of di-(P-chlorol)ropyl)-disu'~phide on sodium dfethyl
phosphate, diethyl-S-P-..,-,hloropropylphosphate (Scheme 2) re-
sulted instead of the expected compound. Di-O-chloropropyl)-
disulphide reacts with triethii. phosphite inder the formation
of triethyl thiophosphate* The synthesized S-~Llalkylamfie~-; and
S-acid fluorides of tho diestz~::s G--' ethylene phosphonosul.'cn-,
acid have hitherto not been described in publications. In ths
reaction of KF with chlorosubstituted .-ompounds especially
aith such having a mobile chlorine atom a substitution of the
chlorine atom by fluorine takes place at the 'beginning in a
dehydrochlorination and. thE fc1lowing fluoride is formed:
CH2ClCH 2R 4- K F -T 0 H2 FCH2R + KC1. Hydrogen f-'Lu~,ride is separated
by KF and thun compoun~ls with a double bond are formed.
CH2FCH 2R + KF ) OH2= CEIR + KF.HF. Thus in this case a dehyd--,D-
Card 2/3 fluorination takes plar!s -instead of dehydruchlorinaticn as x,3.5

SynthnsLs of the Derivatives of Phocv-,nr,.r V SOV/79-29-11-46/716
~; S-j if cn-' A I: ~ ,,
- C A
Iii t h e r t o a s qu m i-_. r1.. T' -~ : ~-, n. i --- ' r g , * e -- e n c ~- - , 1 : f .v ~, 4 i f, ~ E3 -- , :- --
I " -, - 3 i.
SUBMITTED: July 31, ljo~-8
Card 3/3

5(3) SOV/79-2919-5-47,'76
AUTHORS: Petrov, K. A*, Neymysh~;-,,a, A. A.
-------I
TITLE: S- Chlorodiethy! Thiophosphate
PERIODICAL: Zhurnal obshchey kY-4mi.'-, 1919, Vol 29, Nr 9, pp 3030-3032
(USSR)
ABSTRACT: The present paper deals with the oynthcsis of S-Chlorodie~hyl
thiophosphat,~ and its pz-opert-~e,3. It is made by cleaving
tetraethyl bisthiophosphate (Ref 1) with chlorine or sulph-,ryi
chlori&-. at --oom temperaturn.
C2H50"\-P
,-AC2H5
P';;~;O
Y50N
t-
s
-s-
- -
-p
, Clf---.* 2
C H / **~'-3 C I
0/4 \"O
H
C
H
C
0
o
2
2 5
5
2
5

3- chlor c-die t hyl th4ophosphate is liastablej i-t, lor,.9es the
chlorine rather rapidly, and passes into an undis'..'llable liquid.
It shows strong similarity with sulphene chlorides with respect
to its chemical properties and its reac-tivity. Thus it
separates iodine from acidif-Led potaS3J.UM iodide solutions
and passes into disulph!de (Scheme 2). It addr, to ethylerg and
Card 1/3 cyclohexene and reacts with diazomethane und,3r the formaticr, of

SOV/79-29-9-47/76
S-Chlcrodiethyl Thiophoi~phate
0,0-d-.*etliyl-S-P-(,,hi~,:7ce-,h~.-I phosphate and sim.--ax ccmpounds.
) 4 t
Like the sulpheno chloridi-f, (Rcif 3 ~ reacta w'-th dialkyl
phosphites. The reaotior with dl~,~thyl paosp"----.o yieldo
ethyl thiopyrophosphai;a (SL:h.--mt- 3). The assumed strict-ar;.- ' -f
ta th
tetraethy! thiopyrophospha-"-b agr~ei3 w-- -2 data of the DIIP-
ceding paper, where J-t was shogn that sulphe-ne cihloridc!3 which
have the same functional S-Cl-gro,.~p as 3-ch!Grodiethyl th4C-
phosphate react wit-.Ii acid and neutial phosphates under thc~
formation of thicesters of phosph~).ric a-,id i.e. thir-I phr-,S-
hates (Ref 3~- Opiiniors iiverge concerrLng the above t~--'c-
I j
P
pyrophosphat-,. Thu5 tetraetkyl. thiopyrophosphate which is
tained by the reaction with H S with diethyl ~~hlorophcsphatt!
2
and pyridine ie ascribed to a thic'- structui-,~ (Ref 5). It is
ascribed the samt, struct-.ire if it forms due to the acti-c~n of
sulfur dichir-ride on dipthy! phosphite (Refs 6,7). According
has a th-~cn-strjc'ure (Ref 8) (Scheme 4)'-
,o G. Schrade- L~ - t,
A. Ye. and B. A. Arbuzov assume also that tetraethyl th-Jopyrc.-
phosphate 3ynthesiz,~,d by di 'fferent meth:)ds has a thion strv.--;-
."e of the d'fferen' method cf production
-:ure because - in splu L 6
:tt shows the same r~onutaats. There are 9 references, 4 of wh-43h
Card 2/3 are Soviet.

6 7 5.3i 4
S/07 60/030/012/019/027
BooiYBo64
AUTHORSs Petrov, K. A., Maklyayev, F, L_ Neymysheva, A. A.o and
Bliznyuk, N. K. - ------
TITLE: Synthesis of N-Chloro Phosphamides
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol, 30, No 12,
PP., 4060 - 4064
TEXT: The authors synthesized various N-chloro phosphamidee and
developed a general method. The initial phosphamides were obtained by
reacting the amine with the corresponding acid chlorides in ether or
chloroform (Refs.2-4). Table I lists the constants of the hitherto un-
known initial phosphamides. The substitution of chlorine for the
hydrogen atoms in the alkyl amide group of phosphamide took place under
the action of an excessive alkaline solution of sodium hydrochlorite
upon the chloroform solution of the respective phosphamide The dichloro
amides were obtained by chlorination of phosphamide with gaseous chlorine
in the presence of sodium acetate or zinc oxide in carbon tetrachloride.
The N-chloro phosphamides are obtained by -extracting the reaction mass
Card 1/3

87534
Synthesis of N-Chloro Phosphamides S/079/6C)/030/012/0!9/027
B001/B064
with chloroform or M 4" by drying the extracted product, and thorough
removal of the 3olvent at room temperature in vacuum (without subsequent
distillation), The diphenyl amido phosphate which is insoluble in water
and M V was chlorinated with gaseous chlorine in a mixture of CCI 4 and
water (1 s 2) in the presence of an excess of sodium acetate. All
N-chloro phosphamides have a strong odor, yellowish liquids, soluble in
organic solvents (some of them in water) Under the action of a chloro-
form solution of N-chloro phosphamide upon a potassium iodide solution
in acetic acid medium, iodine is quantitatively separated, which is
titrated with hyposulfite; thus, it is possible to determine active
chlorine. N-chl.oro phosphamides (d.erivatives of methy! phosphinic acid)
proved to be the least stable They decompose already after 24 h, the
content of active chlorine being reduced by 1-2%,. N-chlore methyl-amiic,
diphenyl phosphate in which the chlorine content did not change during
25 days, proved to be the most StUble The content of active chlorine
in N-dichloro dimethyl diamido phenyl phosphate was reduced by 3% within
30 days. The constants of the N-chloro phosphamides are given in Table 2.
V, I. Viryukin (1956), V. M, Grigorlyev (1957), and 0 A Pan'shin ('1957)
Card 2/3

9
Synthesis of N-Chloro Phosphamide,3 17~d~9/60/030/012/0!9/02-
BOC)1/Bo64
took part in the experiments. There are 2 tables and 4 referpnces-
1 Soviet, 1 US, 1 British, and 1 German
SUBMITTEDi February 15, 1960
Card 3/3

89535
S/079J61/031/002/008/01 9
B1 1 6/B208
AUTHORS: Petrov, K. A. ,_XqypysheV& l A. A., Fomenko 9 M. G. ,
Chexnushevich, L. M., and Kuntsevich, A. D.
TITLE: Reaction of N-chloroimides of carboxylic acids with trialkyl-,
halogen-, and cyano phosphites
PERIODICAL: Zhurnalobabohey khimii , v- 31 , no. 2, 1961 , 516-522
TEXT: The authors studied the reaction of N-chloroimides of eaters of acetic
and carboxylic acids with trialkyl-, halogen-, and cyano phosphites. Con-
trary to the vigorously reacting sulfene chlorides, chloroamines, and alkyl
hypochlorite3o the reaction of 11-chloroethyl acetimide with triethyl
phosphite proceeds smoothly and with little heat evolution. Separation of
ethyl chloride occurs only on prolonged heating at 60-700C. This reaction
probably takes place in two stages:
Card 1/4

Reaction of N-chloroimides
(C2H50) 3P + ClN ~
CH3
C%**,~~OY 5 0L
89525
S/C)79/61/031/002/008/019
B116/B208
Z CH3 +
(C2H 50)~Pll ~ C.,x OC2H 5JCH cl-
(C2H50) 2 T, N - C 3 + C2H5CL
8 ~OC2H 5
The free phosphonium compound was not obtained.. Chloroimides of carboxylic
acid esters resdmore vigorously with phoophites I main products are the eaters
of dialkoxy-mothylanamide of phosphoric acid. The chloroamides react with
dialkyl chloro and dialkyl fluoro phosphites,alkyl dichloro and alkyl di-
fluoro phosphites in a similar manners giving the corresponding halogen
amidophosphates in yields of between 27-5 and 70. Yla
Card 2/4

89515
3/079/61/031/002/006/019
Reaction of N-chloroimides ... B118/B208
RO Rf Hal RI
PEal + CA - C / PH ~ C + RCI.
\ Hit Rit
X X 0
Dialkyl fluoro phosphites give with chloroimides rather stable phosphonium
compounds. Prolonged heating of the phosphonium compounds reduces the yield
9f fluoro, phosphates; the reaction mixture was, therefore, distilled in
vacuum after heating for 1-2 hr at 40-500C. The fluoro amidophosphates are
./thermostable and are slowly hydrolyzed with water. When treating difluoro
amidophosphates with aqueous alkali lyes at low temperatures, only one
fluorine atom is hydrolyzed. On the action of a calculated quantity of
sodium alcoholate in the solvent, only one fluorine atom is substituted by
the alkoxy radical. Chloro amidophosphates are not thermostable, contrary
to fluoro amidophosphates, distill only in high vacuum, and are easily
hydrolyzable even at room temperature. When treating chloro amidophosphates
with potassium cyanate in water at 50C, the cyano group is substituted for
chlorine, in addition to hydrolysis; in this way, the ethyl eater of
Card 3/4

89515
S/079/61/031/002/006/019
Reaction of N-chloroimides ... B118/B208
diethoxy-methylenamide of cyano phosphoric acid results in a 20% yield.
By reacting chloroimides with cyano phosphites, cyano amidophosphates are
obtained according to Arbuzov's rearrangement (Ref. 2) in yields between
30 and 50%. Dialkoxy-methylenamides of dicyano phosphoric acid are un-
stable and decompose with separation of gaseous products. There are 1
table and 4 references: 2 Soviet-bloc.
SUBMITTED: February 15, 1960
Card 4/4

PETROV, K.A.; NEDIYSHEVA, A.A.; DOTSEV, G.V.; VARICHP A.G.
Reactions of sulfenyl chlorides and N-chloramines with phosphorus
trichloride, dichlorophosphines, and red phosphorus Zhur. ob.
khim. 31 no.4.,1366-1371 Ap 161. ~MIPA 14:4)
(Chloramine) (Sulfenyl chloride)
(Phosphorus organic compounds)

BYSTROV, V.F.; UEYMYSHEVA, A.A.; STEPANYANTS,A.U.; KNUNYANTS, I.L.,
akademik-
Additive relations for chemical shifts in magnetic resonance
spectra on F nuclei of fluophosphates and fluophosphonates.
Dokl. AN SSSR 156 no. 3:637-640 164a (MIRA 17-5)
1. Minstitut khimicheskoy fizikl AN SSSR i Voyennaya akademiya
khimicheskoy zashchity.

NFYMYSHE.VA,, A.A., kand. K-hjm-,chp.,,k--Lkh
Lettei to the Zhur. VPKO !~~ n,.3.-"48-349 '65.
(ff-,:~A 18: 91

L 31795-66
ACC-WRI AP60-11685 SOMIC& CON: UR/0079/66/036/003/0500/OTO
AUTAIGI: i'eyzvL~iova, A. A.; Savchuk, V, I.; KmuWants, Is L,
ORG: nono
TI'i.L,'.: S-alkylthiophosphonic acids and their dorivativess Is Influonco of inducti
and conjugation~n the dissociation constants of the acids
L
'SOUIRC:~- Zhuri L bahchey ldiiimU, v. 36, no- 3. 1966. 500-506
TOPIC TAGS: phosphonic acid, nonmetallic organic derivative, conjugate bond system,
dissociation constant, substituent, organic sultux compound, chlorinated organio
compound
AB&j',VCT: A series of thioesters of al~qrlthio MI oniol and arylthiophos-
phonic acids were produced for the first~e ryMmeacou'on of water an
benzone solutions of the corresponding thiolchlorophosphates. Acid thio-
asters of alkyl- and arylthiophosphanic acids are thermally unstable ccn-
pounds. in contrast to their oxygen analogs; S-alkylalkyl- and S-aWl&r-11-
thiophosphonic acids are stronger acids than their oxygen analogs. The
dissociation constants of the acids were determined and were found to depend
not only on the inductive influenceof substituents. but also on the ability
of the atoms or groups of atoms bonded to the phosphorus to participate in
conjugation with the vacant 3d-level of the phosphorus atom. The influencss~
of induction and conjugation upon the dissociation constants of-the acids,
are discussed. orig. art. has: 6 tables- fi-PR-ff
SUB CODZ% 07 / SUM DATE: lqApr65 / ORIG REF: 005 / OTH REF: 007
Card 1/1 1 um. 547.419.1+543.257.1

L 06501-67 Ewpp_)/EWT(m~ ki.1
ACC NR, D700047 SOURCE CODE: UR/0079A6/0136/006/1090/109~
DODMHEVA, A. A., IM11WARTS, 1. L.
Nucleophilic Substitution in the Series of Derivatives of Phosphorus Acids.
I. Kinetics of the Aydrolysis of Chlorides of Dialkylphosphinic Acid
Moscow, Zhurnal Obshchey Wilimi Vol 36, No 6, 1966, pp logo-io98
Abstract: To explain the increase in the reactivity of organophosphoras com-
1.pounds with decreasing filling of the d-level of the phosphorus atom die to dia-
l placement of the p-electrons of.the oxygen atom of the alkoxy-group, as well
as the influence of other factors, particularly the steric factors, upon the
reactivity of organophosphorus compounds, the authors studied the kinetics of
the hydrolysis of a number of chlorides of phosphinic acids and chlorophosphon-
aten. It was found that in addition to the inductive influence and effect of
conjugation of atoms or groups of atoms bonded to the phosphorus, a great
role in the reactivity of halides of phosphorus acids is played by the steric
factor. The reactivity of chlorides of dialkylphosphinic acids varies by
three orders of magnitude on account of the change in the entropy factor vith
a negligible chango in the activation energy. Additive ratios of the influence
of substituents in the series of phosphinoyl chlorides are observed only in
those cases when the significance of steric hindrance is small. Investigations
of an extensive number of examples indicated that the influence of subatituenta
L Card__A/2 UDC: 546.18 + 50-878-
/__) 9,5L 23

L 06501-67
_4cc NR: _~W060416___
has little effect upon the free energy change. The reactivity of dialkj1phos-
phinoyl chlorides carbe described by a Hammett-type equation, considering the
additive and crossed factors of influence of the steric factor and hypercon-
jugation of the alpha-C-H bonds of the substituents with the 3d-orbitals of
phosphorus. The sigma constants for alkyl groups, calculated from the rate
Iconstants of the hydrolysis of phosphinoyl chlorides.. cannot be transferred to
the reactivity of chlorophosphonates. The reactivity of chlorophosphonates is
determined chiefly by the structure of the hydrocarbon radical bonded directly
to the phosphorus atom and depends less upon the structure of the alkoxyl
radical (an exception being the methoxy group). Orig. art. has: 1 figure,
:2 farmulas and 6 tables. IJPRS: 37,(T231
ORG: none
iTC)PIC TAGS: alkylphosphine, hydrolysis, chemical kinetics
SUB CODE: 07 SUBM DATE: 19Apr65 ORIG REF: 007 OTH REF: 006
Card 2/2 1~,

ACC NRo 414700af4m)IIEHPW RM S it C-E-C dIj_ff'__U R/60- 7 ~96_676 ~ _6_[O_ 0 6 A JfO_5 [I
LOSHADKI31, N. A.) MARKOV, S. M-. POIEKUN, A. M.. URMHEVA, A. A.,. K41(LYAYEVP
F. L., KNUNYAHTS, I. L.
Nucleophilic Substitution at the Tetrahedral Phosphorus Atom. III. Relation-
ship between the Structure and Reactivity of Phosphorus-Containing Compounds.
Role of the Vacant 3d-Orbitala of the Phosphorus Atod'
Moscow, Zhurnal Obshchey Khimii, V01 36, No 6, 1966, pp 1105-1113
Abstract: A study of the alkaline hydrolysis of nitrophenol esters and halides
of phosphorus acids indicated that the free energy change is less sensitive to
changes in the influence of substituents bonded to the phosphorus atom than the
activation energy and steric factor. The effects of changes in the structure
of the substituent were investigated: effect of replacement of the oxygen atom
in the P=O group by a sulfur atom; effect of the structure of alkyl groups
bonded to the phosphorus atom; effect of replacemantof an alkyl group bonded
to the phosphorus atom by an alkoxy group; effect of structure of the alkoxy
group. The standard deviations of the rate constant of hydrolysis, activation
energy, and steric factor calculated indicated a significant difference of
these quantities, depending upon the structure of the organophosphorus com-
pound. The intruduction of subatituents capable of participating in p i-d pi
conjugation (R0 group) next to the phosphorus atom leads to a relativZ
Card 1/2 UDC: 547-18:541.63 +

_L_q65-1+7~7--
ACC NRj AP70010478
small, but significant increase in the energy and entropy of activation. The
presence of a compensation dependence of the change in the activation energ7 and
entropy of alkaline hydrolysis of nitrophenyl esters and fluorides of ph sphorus
acids was demonstrated. Orig. art. has: 3 figures and 3 tables. LdFX5: 37,
ORG: none
TOPIC TAGS: activation enprgy, organic phosphorus compound, hydrolysis
SUB CODE: 07 / SUBM DAT~: 27Jul64 / ORIG REF: 017 '/ OrH REF: 019

IWOLOVA. V.I.; BOBTLIV. P.G., red.; MKOVA. Te.I., tekhn.red.
in fatting owine on collective farms in Chernigov
Provinefol Opyt oticorma avinei v kolkhozakh Chernigovskoi oblasti.
Moskva, Goo. izd-vo sellkhoz. lit-ry, 1957. 147 P. (Bibliotechka
po avinovodstvu, no.1) (MIRA 11:4)
(Chernigov Province--Swine)

NEYFERT, K.V.; GOLOVACHEVSKIY,, Yu.A.; SHEVCHENIAO, D.N.; SMYSLOV, N.I.
Use of a partially packed absorber with atomized sprayers
in the production of tower acid. Khim. prom. no.5:390-392
My 163. (MIRA 16:8)

HMWKGVICH, B.I.; NSYPERT, K.V.; GRfMV, A.P.; SAVDRAK, Ya.R.; ANSO, Ya.Ya.
lowering nitrogen oxide losses in tower sulfuric acid systems
by means of automatic control. Khim.prom. no.12:832-837 D 161.
(MIRA 15:1)
1. Vsesoyuznyy nauchno-issledovateliskiy institut udobreniy
insektofungitsidaw i Khimichaskiy kombinat Kaardu.
(Sulfuric acid industry-Equipment and supplies)
(Nitrogen oxide)

Xxmunc. YU.N.
In the Chechan-Ingunh A.3.3.R. the importance of plant protection
Is undorestirvitedo Zashch.raot.ot vred. I bols 4 no.1:17 Ja,
F 159. (14IRA 12:2)
(Chochen-In&iinh A.S.6.R.-Plants, Protection of)

PZTUKHOY. A.F.; IWMT. Tu.H.
Put an ond to the formal attitudp towards an important mtter.
Zashch.rast.ot vred.i bol. 4 no-3:16-17 M7-Je '59.
(KRA 13-4)
1. Zaved.uy-usbebty Velikolukekim punktom sluzhb7 uchota i prognozov
(for Petukhov). 2. Korrespondent zhurnala "Zashchita rastaniy ot
vroditeley i bolezney" (for Neypert).
(Pakov Province--Plants, Protection of)

HEYPERT, Yu.N. (Odessa)
Self-propelling sprayer. Zashch. rest. ot vred. i bol. 4
no.5:37 S-0 159. (KRA 16: 1)
(Spraying and dusting equipment)

VEYMT, Tu.9.
Wficient organizer. Zashch. rest. ot vred. i bol. 5 zio.4:17-18 Ap
,6o. (MIJIA 13:9)
(Khmellnitakly Province--Plant protection)
(Voialcovskaia, Ekatertna aidorovna)

12YPERT, Yu.N.
After the reorganization. Zashch. rast. ot vred. i bol. 7 no.1:13-14
162. (Brost Province Pl!Lnts, Protection of) (MLU 15:6)

NEYFERT, Yu.N.; 171OLYAKINA, Ys.A.
1 1
Seminar on plant . tection at the ExhibitiO12 of Acblbvewnts
of the National XF~Q:Cmy of the U.S.S.R. Zashch. rast. ot
vred. i bol. 7 no'2:57-59 F 162. (MIRA 15:12)
(Plant;, Protection of-Congresses)

LIMA, N.K.; LUKIYANENKO, R.H.; !~!Pw, Yu iw
In Tatarstan. Zashch.rast.ot vredi bol. 7-no.6r5-8-Je 162.
(KM 15:12)
1~ CELavnn agroncm Hinisterstva proizwodatia i sagoUvok sellsko-
kohomp.7st7annykh produktov PSMR (for Nikalinal. 2. Sekretarl
partipoy organizataii Hinisterst7a proizvodst7a i zagotavok
sel'skc,khozyaystvemykh produktov Tatarskoy ASSR (for laklyanenko).
3. Korrespondent zimrnalal Mashchita rasteniy ot vr(diteley i
bolemay" (for Vevpert).
(Tatar A.S.S.R.-Plants, Proteotion of)

NEYPERTS Yu.N.
In the zone of the activity of the Ullyanovka Ragional Admialstrati.-,n.
ZaAch, rast. ot vred. i bol, 7 no.8:10-12 Ag 162. (MIRA 15:12)
01.1yanovkaregiode-Plantap Protection of)

NEYFERT, Yu.N.
Closer to the needs of productLon. Zashch. rast. ot JL '-~cl.
8 no.6:8-10 Je 163. (MI.TtA 16:8)
(Kalinin Province-Plants, Protection of-Research)

IMPERT, Yu.N.
Ald of the "Sellkhozteklinika" machinery opearators. Zsushchl. rast. Ot
vred. i bol. 8 no.12:30-32 D '63. (KIRA 170)
1. Drogobychskoye Ilroizvods 1,ve nnoya upnivleniyo, Llvovskoy obi.

III-YrTIRT, yu~tj.
Tr I i5 I I g xi w~ : - ;- !- I ~~ -. , - - 1-~ : , r ;, , ~ :~ ~ I -,!. ~ rE La '. ~ 3 ~ ""-ftj ,
I ,ho 1 . 3 r t r-, . I ) ~- - , ( I'll ., R 1 17 , 6 ,

NEYPERT, Yu.N. (Kiyevo-Svyatoshenskiy rayon, Kiyevskoy oblasti)
Machinery should be used. Zashch. rast. ot vred. I bol. 9
no.8:12 164. (ICRI 170.2)

NEYPERT, Yu.
All.-Union BemInar at the Exr.-Ibillic;n o" -,' *,~,,-z
National Fconomy of the U.S.S.R. Zashch. rast. ot vred. 1 rc:.
10 no.l157-58 165. (MMA

T-SYGANKOVP A.; KOTOV, R., agronom po ztwhchite raziteniy; NEYPERT, Tu.
Model plwit protection farms. Zashch. ra5t. ot vred. I bc~'. .-~
no.3:11-15 165. ~' ~,[! F-.' , C, - -,
.1 .1 - ~
1. Nachal 'nik Bryanskoy Btant,91J. zaahc;aity rastmiy (for TSy -ank-v) .
p
2. Sovkhoz "Mar'Jnskiy" , rayona (f or Ko'~Ov' .

NEYPFRT, YU.
Let's tig'.rIten the control over the use of poisons.
Zashch. rast. ot vred. i bol. 10 no.8:5-6 165.
(141RA 18: 11)

NEYPERTf YU.
T.qt Is put chemistU In skillful hands. Zashch. rast. ot vred.
I b01. 10 no.9:2--3 165. (MIRA 18:LL)

IIETPOKOYEVAP T.L.; YAKLTILEV, A.M.
Letters to the editor. Med. sestra 2-2 no.6:61-63 Je'63-
KIA 16:9)
(NU-1-SES AIM liup'silm-ff'RIODIGAIS)

1-66 /17 WT T --IC
Ai~OAA9 soURCZ Col.)!-,: Uli/oor,8/6)/Uuu/()11/1)303/DC03
A17MORS: Druzhinin, V. V. Kurushin, Yu. N. ; Men~, A. U t ;':JN r
A. Ye.; Cherepanov, V. 1.
TITLE: Contribution to the theorr of energy spectra of paramagnetic ions in certain
oxides
SOURCE: Ref. zh. Fizika, Abs. 111)16
REr 801MCEt Tr. Komis. vo spoictratkapii. AM_~SSR, t. 3, vyp. 1, 1964, 514-519
!&WIC TAGS: paramagnetic ion, slx!ctrum P /01V EA,'Ee(;Y
Calculations are presented of the energy spectrum of a paramagnetic ion
In a crystal with spinel structure in the approximation of the average intracrystal-
line field. It is shown that allowance for the field due to the second az-A farther
neighbors can exert an appreciable influence on the Interpretation of the spectra
of such tons. quantitative calculation results are presented for Crl* In HgA110,,
and experimental data on this Ion. (Translaticn of abstract)
SUB CODE: 20

MUSHILID. T.G.; PANOVUH, B.N., inzh.; KOKURIM, YjI.L., kand.fiziLco-matem.
nauk. otv.red.; MOVICHKOVA, N.D., takim.red,
(Radio astronomy; annotated bibliographical index of' Russian sind
foreign literature. 1932-1958J Radioastronamiia; annotirovannyi
bibliografichookii itkazatell otechestvannoi i inostrannoi liters-
tury 1932-1958 gg. Mos1cva, 1960. 215 p. (KIRA 13:7)
1. Akadamlya nauk SISSR. Sektor seti ispetsiallnykh bibliotak.
2. Glavnyy bibliogref Bibliotaki, Fizichaskogo institute Lm.
P.M.Lebedeve Ali GSSR (for MaysM.11d).
(Bibliography--Radio astronomy)

NEYSHLOS, L.A., inzh.; YAS11K1UL, G.A., inzh.
Use of ADU-300 devices in mechanizing fuel handling operations
in electric power plants. Elek. sta. 33 no.5:77-78 My 162.
(MIRA 15:7)
(Electric power plants-Equipment and supplies)
(Coal-handling machinery)

I. mnrvin, A.
2. nz:;H (6co)
4. I..unicipal Services
7. Prompt solution of presjing problerrs in public hOUS4 ng and ser'vicos. -kom,
khoz. 3, No. 2, 1953.
9. Monthly List of Russian Accessions, Library of Congress, April --1953, Un421.

SOV/122-58-----24/3?
AUTHORS: fleyshtadt, D.1,;!. Wid IjhL'Ll,71-ttin, V.P. , EnLineers
TITIE: Special Procedures in Manufacturin-,,- Housin,-s -.)f Rotary
Furnaces and Tube Mills for CeLent Wor,:s (0,-;Lbeennosti
tekhnoloEii izEot:)v1eii,7a korpusov ii-rasi,c'-~.ayLts,.ci-~ilcLS,7a
pechey i trubnykh mel'nits dlya tsementnylift zavodov)
PERIODICAL: Vestnilt Mashinostroyeniya, Y)58, iir G, pr tj_,~,3 (USIR)
r
ABSTRUOT: Procedures used in the Siberian Leavy enLSineeria- plart,
"Sibt,vazhmash" for weldinC up the c,/lindrical '-.DusinL_-E of
rotary kilns and tube mills with diameters if 2.5 and
3.6 m and lenGths of up to r/5 m usi-au trito.-,~,~,ic 5uhi, ,,c, r, e d
welding equipment are described. The tai1c,riii- )f ShE-~t
is conceived. to reduce t.'-,,e nwnber of rin.- seaff.Z. DetLils
D
of manipultion and the conotruction of a special i;--chirie
for cutti-ng the f-ces are mentioned. TLerc a.Te 2
f il-,-res.
1. Furnaces--Production 2. TuI)e mills--Production 3. Are weiding
--Applications
Card 1/1

NETSHTADT, D.M.; LOKOSOV, A.T,
Using the LR-24 baring head. Maahinostroitell no.1:31 Ja 162.
(YlIRA 15:1)
(Drilling and boring machinery)

Lortosovp A.V., inzh.; inzh.
G3-3 self-propelled hydraulic device. Svar. proizv. no.606-
38 Je 163. (MIRA 16:12)
1. Krasnoyarskilr zavcd "Sibtyazhrash.11

SEDOKOV. L,14., karl-,
NWHOVSKEY, I.A. -, JXLMDI,~T, D.F.
naul; IIIIN, Yu.M.i ZHEAVOVICF, V.1',,
KI,'ZI,F,T,'lOV, Yu.I., inzh., retsenzent;
kand. takhn. nauk, red.
[increasing the productivity of herwy-duty inaOiinf) tools)
Po-.ryshenie proizvoditellriosti krupny~h metallorezhushchik.%
stankov. [By] I.A.14emirovskii i dr. Noskva, Mashinc,
stroenie,, 1965. 201 p. (MI~-A 18:5)

NEISHTADr, Elena Borisovna
To Morphology of the middle ear
Dissertation for candidate of a Medical Science degree. Chair of Normal
.kwktonW (head, Prof. V.I. Bik) Saratov Medical Institute, 1952

H
DZ~STER, L.I.; NEY5""ADT- EL~
;n~ -a and mm,~rpr'-
Kraux
.1 Ca
(.MIRA
i. i~,-n-yri a,, prof% ob"
!E- vs e
pa t, ny-Y
I - ,W1 P
ch-"En AMN SSSR pr~f~ onko-o~-. SSS,
-v, rqy 'R prc,! . A. br
(dir. - ieyi~ tr: A lkfll, I SS S Se r F
Adres avl~r,-;-.- i r 1 v UFi ;1 4
Institw. AMN

I e,
n k
e
e nA

1"NASTABIYEV, B.1,., inzh.; MIROV, B 14., inzli.; NEYSKADT, G.k., inzh.;
SAPOZIRID.CV, 701.~.,, inzh.
Tranamision of discrete Information for conver-rer ameltIng
control. Mekh. i avtom. proizv. 19 no.4:49-50 Ap 165.
(141RA 1-8:6)

LEVINA, L. S. ~IXYSHTADT, G. M.
Electric action of the brain in glm coma. 7est. Oft., Roakva
30 no.)5:8-1Z Sept.-Oct. 1951. (CLML 23:))
1. Of the Clinic for Sys Diseasos (Director - Prof. N. A.
Pletneva). Second Moscow Medical Institute imeni 1. 7. Stalin,
and of the Electrophysiolog7 Laborator7 (Head -- Honored Worker
in Science Prof. S. A. Chugunov). Institute of Yorensic Medicine
iment Serbskiy.

HEUBTADT, I., Inchener (Moskva).
Valuable raw materials left unixtilized. Pron.koop.no.11:~4
156. (KEBA ~,: 12)
(Moscow-Chemical industries)

-1
IIEYSHTADT, I.. inzh.
Dyeing articles made of polyvin7l chloride. Prom.koop. nc.10:29
0 '57. (MIRA M12)
Oyas and dyeing)

MrSIRADT, I.
lot's have more chemical goodof Prom.koop. 14 no.7.,:10
JI 160. (MIRA 13:8)
1. Zaveduyushchly laboratoriley bytovoy khimii Mauchno-
isoledovatellsIoDgo institute, Rospromsoveta.
(Chemicals-In&2ztx7-)

NI'MITADT, I. F. and Etlin, A. E.
MachLne Tools
- . :, I-
Spravochnik molodopo tokar-ya-skorostnika, ?'oscow, '!seso,-i,n,)e
Izdatellstvo Trudrezer:izdat, 1,,51. pi). 171P Cii-,L,-S., ta,)les, bibl4or.; 15 x ir'.
WII-2

1. N1.1R)ISHMI) A. A. ) NjSiVQDT, I. F.
2. Unir (6r-,0)
4. Machine Tools - Testing
7. Determining the sturdiness of !,-ietal-c-Litting machi;ies by the. mr-,-,hod .)f step-like
D - X1.
machining of a surface. 3tan. i instr. 24, I:o. 2, 1953.
9. Honthly List of Russian Accessions, Library of Congress, I'ay 1953. Unclassified.

MOZNIKF.R, Riva Abramovna; VFMHTADT-r-J64Ak-?41ikjQ_w_LQW UDALITSOV,
A.N., glav. red.; BRYANTSEVA, V.P., 1"i69 red.; STA7EV,
K.P.0 kand. tekhn.nauk, red.
[Lndading-cycle counter. Three-component device for measur-
ing cutting-force constituents up " M-UnISchetchik taiklov
nagruzheniia. Trekhkomponentny-i pribor dlia inmareniia so-
stavliaiushchikh ail rezaniia do 10 t. Moskva, Ia-t tekhniko-
ekon.informatsli, 1956. 13 P. (Pribory i atendy. Tema 2.
NO.P-56-462) (MIRA 16:3)
(Electronic instrumeRts)

NEYSHTAI)T,,, I.S.; SHILOV, I.A.
Present state cf the production of household chemical# and w4ye for
its, levolopmorO., -hiTi, PrQm. nn,1:65-67 Ja 164, (KIRA 17~2)

DOLGOPOLOV.- V.M., inzh.; ZISNATI, L.M., inzh.; NEMITADT, I.S., inzh.;
RANSEVICH, B.N., Lnzh.; URIN, V.D., inzh.
Operation of the automatic operator of a multiple-unit hydm-
electric power station with long-term frequency deviations
from the nominal -vdue. Elek. sta. )5 rio.2:35-37 F '64.
OGILA 17:6)

RMHTAM. L.B.
Organization of activities of medical personnel in the unified hospital.
Sovet.zdravookhr. no.6:39-49 Nov-Dec 1951. (GIRL 21:2)
1. Read Physician of Hospital imeni Uritskiy, Leningrad.

KONTAROVA, L.P.
BRIXT. L.D., laureat Stalinskoy premil;
PMTq I.T., professor. dcktor geologo-aiiaeralogichaskikh nauk,
redaktor; SKVOBTSOV. I.M.. takhnicheskiy redaktor
C ftineertag and geplogical research in tho planning and constritation
of hydroelectric structures; a manual of methods for engineering
geologists] Inthenerno-geologichaskis issle6ovaniia pri proektir(vanit
i stroitalletve gidroonarg6tichookikh sooriu;haaii; metodichaskoe
posobie dlia takhnikov-geologov. Moskva, Gon. energ. izd-vo. 195'
408 p, (OU 9
1, Russia (1923- U.S.S.R.) Ministerstvo elaktrostantmiy t
elottropromyshleanoati. Upravleniye kapitallnogo stroitalletva.
(Hydroelectric power stations)
(Engineering geology)