SCIENTIFIC ABSTRACT NUDELMAN, B.I. - NUDELMAN, Z.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001237620011-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I.
Conditions favoring the formation of er7stalline calcium carbonate
during the solidification of certain cements in air. Uzb.khio.zhur.
no.6:17-27 159. (MIRA 13:4)
1.OPrtnYY zavod Upravlanira proizvodetva stroitellnykh materialov
Tashmovnarkhoza.
(Calcium carbonate) (Cement)

SWUMAN, H- I.
Crystal structure of caletua silicates 8jid alumdxates forming at
lov texperaturese Vzb. kh1x6 xhur. no..3:66-72 160.
(KLRA 13:10)
1. Opytnyy savol Upravlonlys, proizvodstva stroitelOrM oLtert&-
lov Tashkentakago savvArkhosa.
(Calclus silicate) (9SICIUM &1-1 6)

NUDELIMAN, B. I.
Cand Chem Sol 11 Man -- "Low-temperature calcLum compounds and the
atmosphopto stability of bIn4ing materials on their bass". Tashkent,
1961. 19 pps 22 am (Acad of Sol UzSSR. Joint Sol Council on Mwm of
the Dept of Cool-Chem Sol), 170 copies, Not for sale (KL, No 9g 1961,
P 1-77v No 2428o). Z61-5236g

NUDELIMAN, R.L., inzh.; PTASHCHFM09 I.P.0 inzh.
Combining the processes of vibrating and molding
plastic ceramics. Stroi.mat. 7 no.6:22-24 So
in molding
161. (IMA 14:7)
(Ceramic industry)

ROZOVI M.N.; -NUDELIMANO B.I.; UVAROVA, I.T.
Intensification of the production of clinker in rotary ki-Ins.
TSement 27 no.F,-,14,-15 S-0 161. OURA 14: 12 )
(Portland cement)

pyp!~' N, B.I., inah.
Changes in the mechanical strength of a loess body during the
kilning process. Stek. i ker. 20 no.12:20-22 D 163.
(MIRA 17:1)
1. Konstruktorsko-tokhnologicheakoye byuro po stroitelloym
materialam i konstruktsiyam Upravleniya promWahlonnosti stroitell-
nykh materialov Soveta, narodnogo khozyaystva UzSSR.

LOBANCIP Ye.M.-, SOLOD01INIK011, A.C.; KRYLOV, Mo., NUDELIMANi,~.I.
ROZOVS M.N.
Use of radioisotopes in testing the lining of rotary cementation
fu'rnaces. Atom. energ, 19 no,2t2O4-205 Ag 165, (MIRA 18t9)

ITUDELIMAN, B.I.; TOYHTAKHODZMYEV, S.T.
Effect of the addition of salts and oxides on the reactions
occurring durln~, heatinr of 3CaC'0? + S102 and 2CarO + SiC.
mistures in the 800-1400" tempera ure ran~!e. Uzb. kh?m. zhur4
9 no.4:17-22 165. (Kl~. 1e: 1~1)

TJ~~LIMAN;~ BOI.; TOUTAKHOWMAYEV, S.T.
Effect of the additiom rf iml,~.q and axiAes on
place on heating mN-turoo of 3CaGO) -+. A] 0 and GhC03 L 01
within 800 - 14000 tamperature rrn~ge. Tjzb.2VI-m. zhur. 9 rio.~)4
14-17 165. 18.-12"
1. Tashkentakiy nauelLn,>.-iasledovatellqk',-y proyektny-y iristvl-,Lt
stroitellnyk.h materis.lov. Submitted July 7, 19641.

DUSYATSKIY, A.Ya.,q inzh.; MELIMAN,, G.E., inzh,; SEMNYUK, A.I., inzh.
Storage and transportation of bulk flour. Y--kh.i avto=oproizv.
16 no.4z2Z-24 Ap t62. (MIRA 15:4)
(Flour-Transportation)

NUDELIMAN, G.E.; YEGOROV, V.P.; KATS,I.G.; IffSINj A.P.; MACHIKIIIN,
VELITSHCHEV, V.N.
(Continuous line for the production of halvah] Potochnaia
liniia proizvodstva khalvy. Moskva, TSentr. in-t nauchno-
tekhn. informatsii pishchevoi promyshl., 1964. 16 p.
(MIRA 18:5)

NUDELIMAN, Goda Srulevich
Gbaracteristics of distance-type relays based on the com-
parator principle. Izv. vys. ucheb. zav.; alektromakh. 6
no.12t1380-1386 163. (MIRA 17ti)
1. Starshiy inzhener Chuvashakogo elaktrotekhnicheskogo
nauchno-issledovatellskogo instituta.

50 3491 S_0_uRCE__C_0D_E__:___ __- /6__676_6_6/_of8_/dH_i_/dH~_
UR/0413
INVENTOR: Gershte fludelInan, I. Ye.; Promin,_V ekht-
man, L. A.
ORG: none
TITLE: Method of processing gravimetric survey results . Class 42, No*
186155
SOURCE: Izobret prom obraz tov zn, no. 18, 1966, 111-112
TOPIC TAGS: gravimetric survey, gravity isoanomaly, dielectric sheet,
pobentiometer, gravity parameter . 0,e#?V1"70rV'1
ABSTRACT: A method is proposed for processing gravimetric survey data
based on analysis of isoanotnaly gravity maps. The isoanomaly map is
put on a dielectric sheet, the interspaces between isoanomalies are
filled with conductors, and a potentiometer adapted for each interspace
Is attached. A point-shaped charge is moved above the dielectric sheet
which measures the current. Parameters of the gravity field are deter-
mined from the intensity of the induced current. This method permits
a continuous distribution of the gravity field, higher accuracy, and a
shortened processing to be obtained. Orig. art. has: 1 figure.
UDC: 550-831

--
,3349 9

NUDELtMfl, YERIEMOV, M.G.; ZHULIN, V.Ya.
Istwedmew gee~ eeenomy and iniustrialization In- thw laying
of foundations in rural construction. Oan., fund. I makh. Crun,
7 no, 6:1-2 165. (MMA 18:12)

22(l)
SCV//3----1-13 ~-12
AUTHCRi Nudel I man, L.G. , Cindidr-- -P of * Pcr)nic.-I I
TITLE: The Reserve of 3hortened Ti--e
P -'-'R 10 D I C AL Vestnik vysshey shkoly, ':r 4~ P 37 fU,;
AB3TRACT: An attempt to re,.iuc-., the numb~.,r of students' r(-, iu.re. exer-
cises, and, above all, the numbr,r of lecture (.urL;, in a :-e-
nerally known fact. ~~herp --re many ways to d,o it, t..u*- it is
difficult to choose the most acceptable one, a--i it is si:-ut-
aneously necessary to s,!,fegruard the of t~~e
its und(,r3tandinV and a hieh scientific Jev,~l. 71;c .:.o.,;t r-
liable way to reduce the nu;.iber of lecture hour.: isv n 4 '.: 1-1
author's opinion, to ex,t.ound the :~:aterial r)f the coursei a
generalized manner. He provrs this by an cxample. H ~: r
I.V. Kharizomenov's guggestion to or/,anize a
ing of lecture summaries and manuals in ev--ry vu:,. as a v2111:-,
le one.
A,;SOCIA11'IO1: Orenburgski.,,, scll.,,kokhoz...,aystvc-nri,,,,y instil.ut (M-on:,ur- Ar ;- i -
cultural Institute).
Card 1/1

MUDZLIKAN, L.G.
Investigating the rigidity of P415A hydraulic press frames.
Kuz.-shtam.proizv. 1 66.12:28w33 D 159.
(MRA 13:4)
(Hydraulic Vresses-Testing)
4F.

NUIELIHANp L,G.
Investigating tha rigidity and strength of the P474 hydraulic press
housing. K:um*-shtsx*yroizv. 3 no.7:20-25 J1 16i. (MM 14:6)
(Hydraulic presses-Teating)

NOWMAN L.G.; Prinimali uchastiye: V-E'RESHCqAGIN,'Yu.F.; LIVOV, V.A.;
S;TT-,UT-S.KIY, V.S.; KOVALENKO, A.D.; SfWArOll, V.M.
Study of tho strength and rigidity of a P313 sheet stamping
press bed. Kuz.-shtam,proizv, 7 no.2:27-33 F 165.
(MIRA 18:4)

=ILI KAN 0 M,
-"Mm"MR0=4416 ~Pass from words to action. Orazhd.ay. 14 no.1:12-13 da '57.
(HIPA 10: 4)
1. Prepodavatell uchabno-trsalrovochnogo podrazdalonlya Ukratunkogo
territortallnogo upravl~nW&.
(Aaronautics--StudY and teaching)

25(5) MSE I BOOK E"LOTTATION BOV/2425
Nudel 'man, Mb7zey Grigorlysvich,, and Sewn Pavlovich Sayanko
L------------------------
Povyshmdye proizvodltelluosti truda, pri makhanichaskoy obrabotke detaley
mashin (Increasing Labor Productivity in Machining Machine Parts)
Kiyev, Mashgiz, 1959. 155 P. 5,000 copies printed.
Rpvieweri V. P, Zavertaylo, Candidate of Technical Sciences; Eds.: V. E.
Dampe, Candidate of Technical Sciences,, Docent, and M. S. Soroka; Chief
Ed. (Yuzhniy Division, Mashgiz): V. K. Serdyuk, Engineer.
PW.POSE: This book is intended for engineering and technical personnel
and production innovators in machin ry-manufacturing plants.
COVERAGE: The book discusses measures for improving production processes
and reducing the time required for machining apd support operations in
the production of parts on a custom or lot basis. Problems related to
parts Inspection and the proper layout of equipment are dealt with. A
method of calaulating the efficiency of productidn processes Id described.
No personalities are mentioned. There are 15 references, all Soviet.
TABLE OF COWENTS:
I
Card 1/4
1

Increasing Labor Productivity in Machining Machine Parts (cont.) SOV/2425
Fpreword 3
Ch. I. Thprovement of Process Engineering in Machinery-manufacturing
Plants Specializing in Custom and Lot Production 5
Design requiremonts for processing 6
Measures for improving process engineering 7
Technological documentation 10
Setting up production processes and production lines 11
Ch. 171. Basic Steps Being Taken to Reduce Machining Time 13
Measures for facilitating the reduction of support time 21
Ch. 17. Housings 34
Design characteristics and requirements for housings 34
Materials and blanks for housings 35
Production methods,, tools, and devices used in machining surfaces 37
Machining of basic holes in housings 39
Production methods, tools, and devices used in machining basic holes 43
Ma.chining of fastening and auxiliary holes 54
Precision control in machining housings 55
Laywt of equipment for machining houBings 57
Card 2/4

rners"Ing TAbor Productivity In MachInIng Machfte Parts (Cant,,)
Ch. IT, Spw and Bevel gears
Design vwlations and special requireWmts for gowz~
Wterlsk and blanks for gears
N=hWng blanks for gears
Raginmerl" processes for amtting spur and bevel"gears
Roughlng and amIdfinishing gear tooth
Finishing geor-tooth surfaces
Machining shaft bores in har4owd. gmars
Controlling the precision of gears
Le7out of eqmipeent for machInIng gears
Ch, V. Shafts
Deiign characteristics and requirements for shafts
Materials and blanks for shafts
Engiwwring processes in machining shafts
Production methods, tools,, and devices used in machining shafts
Layamt of eqnIpment for machining shafts
Ch. V1. Appraisal of the Technical and Economic EMcieney of the
Engineering Processes of Machining
SW/2425
59
59
63
9
92
98
107
109
113
118
1A
1A
125
126
129
138
140
Card, 3/4

J
AID P - 5143
Subject USSR/Engineering
Card 1/1 Pub. 103 - 2/18
Author : Nudellman, 0. E.
Title : Automatic loading mechanism in centerless grinding ma-
chines for grinding tap-borers.
Periodical : Stan. i instr., 5, 7-10, MY 1956
Abstract : The Institute for Organization of the Machine-Tool and
Instrument Industry (ORGSTANKINPROM) designed an auto-
matic feeding and control device for manually operated
centerless grinding machines, thus transforming them
into fully automatic units. The author describes the
details of construction and operation of the device at
the "Frezer" plant (Moscow). Seven drawings and 2 photos.
Institution : As above
Submitted : No date

YAKOVIEVs Dmitriy Georglyevich; NUDELIMAN .9 A~aEmz!anuilovna;
Ka"VP VGFOV kand. tekhn. nauk# retaenzeiit-J--HALKOET-,-
A.F., red.izd-va; SOKOWVA, T.F., tekbn. red.
(Readjusted automatic lines of modernized multiple-purpose
machine tools for the maimfacture of taps] Perenalazhi-
vaepye avtomaticheskie Iinii iz modernizirovamifth univer-
sallrqkh stankov d1la izgotovleniia metchikov. Moskva,
Mashgiz, 1962. 226 p. (MIRA 15:3)
(Assembly line methods) (Automation)

20570
3/109/61/006/002/002/023
E14O/E435
AUTHOR: Nudel0man. P.Ya.
TITLE: On the Linear Correction of Transient Processes in
Finite-Bandwidth Systems
PERIODICAL: Radiotekhnika i elektronika, 1961, Vol.6, No.2,
PP-193-196
TEXT: The article considers an idealized linear system with
infinite attenuation in the stop band. An energy criterion is
adopted to estimate the intensity of the transient process occurring
in such a systemo The ideal frequency characteristics of the
system are assumed to be unity transmission in a band of frequencies
+ fl and zero delay over the band, with zero transmission outside
of the band, The response of the filter to an arbitrary waveform
y(t) is given by the Duhamel integral, The problem is to
calculate the waveform y(t) of duration T resulting in minimum
energy of -the filter response outside of the time interval in which
the waveform is actually present. The problem is solved in
functionals, leading to the Fredholm integral equation with
positive-definite kernel, Not surprisingly, the solution
obtained for the present problem corresponds to that obtained IX
Card 1/2

20570
S/109/61/oo6/002/002/023
On the Linear Correction of E14o/E435
previously by bl,S,Gurevich (Ref.2) for a pulse giving maximum
energy concentration in a prescribed frequency band. The result
is titan extended to a system with arbitrarT frequency
characteristics within the same passband - R. It is found that
the input waveform must be "matc-hed" to the system to give the
maximum energy concentration in time, There are 2 Soviet
references,
SUBMITTED: June 7, 1960
Card 2/2

ACCESSION NR: AP4024720 SIOL09/64/0091003104011040T
AUTHOR: Mudellman. P. Ya.
TITLE: Transmitting nv#tIdIzn@nsfon&L information aver a channel vvith & Limited
frequency band
SOURCE: Radiotekhn'ka I el*ktranika, v. 9. no. 3, L964, 4OL-407
TOPIC TAGS: Information transmission, multidimensional information.
conuuunication channel, vocoder. orthogonal vocoder
ABSTRACT: The possibility of coordinating a multidimensional (e.g. . tv.
vocoder) message with a practical (limited-band) commisn' ton channel by an.
expansion of the multidimensional signal Into a generalized Fourier series.
whose coefficients are functions of time, and by transmitting these coeffidents
over the channel Is theoretically studied. The method has been used in
orthogonal vocoders and theoretically og"red by K.,A. Mwelesimw ("Some
card LIZ

ACCESSION NR: AP4024720
problems in the theory of electric information systems," LKVVIA, 1966). The
present article specifically tries to enhance the efficiency of the method by
selecting optimum components for multidimensional-to-single -dimensional
conversion. The mean statistical error is minim' ad by selecting orthogonal
functions. transfer constants of filters. and filter passbands. TY scanning is
considered an a particular came of multidimensional signal transmission. "The
author.wishas to thank Do Po b(illman, A* Yue Lev# -and V. L Kulys, for their
I valuable advice. 11 Orig. art. has: I figure and 30 formulas.
ASSOC]ATION: now
SUBMITTED: 30J=63 DATZ ACQ: 1OApr64. - ZNCL: 00
SUB CODE: CO NO RZF BOY: 006 OTHM:

11117DELIMI P. Ya.
one relttionsh4p for amplitude-frequercy ard :hase-frea~ ei-cy
.L -
I
distortiors in-,.r(-d,,-xed by a linear s--stem.
19 no. 12:67-68 D '65 (1., T:,~A lc~ : I )

ACC INRt AR6019062 SOURCE CODE: UR/0274/66/000/001/AO07/AOO"
AUTHOR: Hudellman, P. Ya.
TITLE: Prediction of a stationary random process by means of a filter with assigned
phase characteristics
SOURCE: Ref. zh. Radiotekhnika i elektrosvyaz1, Abs. IA40
REF SOURCE: Tr. uchebn. in-tov svyazi. H-vo svyazi SSSR, vyp. ?2, 1964. 147-151
TOPIC TAGS: randolu process, computer design
:TMiSLATION: A form of amplitude-frequency characteristics (with given phase-frequency
,characteristics) of a linear filter, for predicting a stationary random pr*cess with
~a minimum mean square error, is sought. The solution of this task can be useful in'
Ivocoder (telephony) design. The linear prediction problem for a stationary ra.ndam pro-
Icess reduces to the following normalized expression:
,where n(t) is the predicted random process; h(t) is the pulse response of the predic-
ition instrument; M is the averaging of operations n(t); T is scme positive number; c2
UDC: 621.391.16
Card 1/2

L 09975-67--.---
ACC NR: AR6019062
lis prediction error dispersion minimized by the proper selection h(O. The search for
the extremum of functional (1) for a variation h(t) in the class of physically realiz-
!able pulse reactions leads to the integral equation with the kernel depending an the
tdifference of the arguments. The minimum of functional (1) is sought in a number of
'pulse reactions h(t) corresponding to the complex coefficients of the transmissions
H (0) (o) 11-14111) k (1) eI-ldl
iwith a given phase-frequency characteristic O(w). A physical realization requirement
lof the prediction device in this case is not Introduced. 1 figure, 1 table. 3 referencr
ies. P. N.
s
UB CODE: 09
l

to 32290 SOURCE COJIjE: UR/O106/66JO00J6d9Jod6_7-Td-o
AUTHOR: Nudellman, F. Ya.
- ........ ..
ORG: none
TITLE: Orthogonal vocoder with different-width channels for trimaittlM slow-varyL%
speech parameters
SOURCE: EA1ektrosvyaz', no. 9, 1966, 67-69
TOPIC TAGS: vocoder, voice communication, speech tranamiasion
ABSTRACT: This theoretical conclusion was verified experimentally: with a specified
overall vocoder channel band, it is expedient to have individual-channel bands of
different widths; wider bands should correspond to the Fourier coefficients with
greater mean energy. Various sots of filters were connected to a Chebyshev-type
vocoder, and eight Fourier coefficients of eech-spectrum expansion were transmitted
1 The best results are obtainable with
through these filters. It was found that: (S5
the widest-band filter in the first channel, a narrower filter type being used in
all other channels (2) The use of three wider-type filters brinEpabout practically
no improvement; (]5j A saving of 63 cps in the transmission band reduced the speech
intelligibility by 3-5% (syllable articulation evaluated by a crew of 5)- Orig. art.
has, 3 tables (031
/7
SUB CODE: 09 ~ SUBM DATE: 250at65 / ORIG REF, 003
Card III UDC, 534-4

NUDELIMANq R.I.
7-1
Melting of crystalline polymers. Inv. vys. ucheb. sav.; fiz.
no,1:8-13 164.. (MIRA 170)
1. Maromskly gosudarstvennyy pedagogicheskly inst1tut.

MILIKAR Serge& Boris oviah; SHIWV. ?.G.. redaktor-, BIUG. T.Ta..
U-
-' realiclor; d2MM-S.. takhaichasicty redaktor
Claras brick block apartment houses] Zhilya dome iz krupnykh
kirpichnykh blokov. Alm-4tla , Isaakhmkoe gos.izd-vo, 1956. 20 p.
(Apartawat houses) (Building blocks) (KLRA 10:7)

NUDSLIWP S.B.
Now type of miftinistration and general Berfriftf eombim with
storage for work and person4 clothes In d0dergr6und room.
Adm.-byt. kemitrw ugoll. shakht no.505-29 162. (mm 17:8)
1. Karagandinskiy gosudarstwoMy inzbenerno-proyekUyy institut
po proyaktirovaniyu sbakhtnogp~Btroitellstva Nara&ndiuskogo
ugolinago basselm.

NUDELIMAN, S.L.; SIDOVNKO, G.A.
Structural parameters of samarskite. Rent.min.sy-r. no.3:66.-70 '63.
(I-ffRA 17:4)
1. "sesoyuznvy nauchno-issledovatellskiy institut minerallnogo
s3n ya.

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UNRfthysics - "tallocraphy May 52
"ftaihical Method of Determination cif a System of
Paramters amd Indices or Mbiof TatMonal, Hexa-
goml &A Hhoubic Crysta.Uine Systems,," S. L. Nudel-
"Zhur Tekh Fiz" Vol xMj, No 5P PP 773-783
Described metb[od Improves previous deficiencies in
allowing one to det rhcobic systems. It also en-
a~-ales construction or equipwnt uhich may be oper-
ated by an inexperiewed laboratory assistant. In-
debted to A. 1. Kitaygorodskiy. Received U Fab 52.

AUTHOR: Nudellman, S. L. 120-2-24/37
TITIE: st ent for X-ray "Iftttern Analysis. (Pribor dlya
Rasshifrovki Rentgenogramm).
PERIODICAL: Pribory i Tekhnika -.Bksperimenta, 195?, No.2,
PP- 83 - 88 (USSR).
ABSTRACT: It was shown by the author (Ref. 1) that it is possible
to design an instrument for the analysis of X-ray pattern..
In the present article the author describes the mechanical
construction and the use of such an instrument. Figure 1
gives a detailed drawing of the apparatus. The principle
of its use is restricted to the analysis of -(,'-ray patterns.
of simple rhombic systems, since tlie X-ray patterns of
tetrahedral, hexagonal and zymmetrical lattices of rhombic
systems may be considered as particular cases of -the above.
In order to explain the sequence of determining the line
11~2 sin 2 01W2 from all possible indices HKL, five main
1-
g1r9ups of operations are established and the sequence of
operations of the instrument are discussed. It is shown
that using this instrument it is possible to determine
from the powder method, the type, parameters and indices
of crystal lattices of cubical tetrahedral, hexagonal
Card 1/2 and rhombic systems. It is also possible tc determine

Instrument for X-ray Pattern Analysis. 120-2-24/3?
the type, the system and parameters of subsuances from
which drystals cannot be grown, zhich means that
patterns may be analysed of substances which, up to now,
have not been determined in such a manner. A mechanical
drawing of the instrument, 1? diagrams representing the
consecutive steps in determining the intercepts of various
lines and one table summarising results of analysis as
obtained by manipulations in any one of the five above
mentioned groups are given. A. I. Kitaygorodskiy has been
interested in the above described work. There are 2
Slavic references.
SUBMITTED: June, 14, 1956.
AVAIIABLE: Library of Congress.
Card 2/2

05458
SOV/120-59-3-29/46
AUTHOR: Nudellman,_q, L.
TITLE- An Instrument for the Interpretation of X-ray
Photographs of Polyarystalline Substances Belonging
to the Monoclinic System (Pribor dlya rasshifrovki
rentgenogramm polikristallicheskikh veshchestv
monoklinnoy sistemy)
PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 3,
pp 125-127 (USSR)
ABSTRACT: In a previous paper (Ref 1) the present author described
an instrument which can be used to interpret X-ray
photographs of polycrystalline substances belonging
to the orthorhombic system. The present paper describes
an application of the above instrument to the interDre-
tation of X-ray photographs of monoclinic crystals,
To begin with Eq (1) is re-written in the form of Eq (2).
where a1 = a sin 0, c 1 = c sin 0. Eq (2) is then split
into Eqs (3), (4), (5), (6) and (7) which correspond to
the indices hOO, OkO, OOCq hkO and Okt of the monoclinic
system respectively. It is argued that these indices
may be interpreted using this instrument similarly to
r'ard 1/3 the same indices for the orthorhombic system whose

05458
SOV/120-59-3-29/46
An Instrument for the Interpretation of X-ray Photographs of
Polyerystalline Substances Belonging to the Monoclinic System
parameters are a , bi c11 Eqs (8) and(g), which
correspond to h0i and hkt of the monoclinic system,
differ from the analogous equations of t1ae orthorhombic
system by the quantity -2h Cos P/a 1c ill Since in the
instrument describ9d in Ref 1 the parameters a, b and c
change their values depending on the displacement of
the indices hke,, which are represented on the instrument
in Pe form of moveable wires,relative to the lines
1/d , which are also represented in the instrument by
straight lines intersecting the coordinate axes at
equal distances, it follows that the quantity -2hF_ cos 0/
a1C1 is transformed into 2h~ cos P. The latter quantity
may be found on the instrument as the difference between
the ordinate of the h06 wire and the o5dinate of the
intersection of the y-axis with the I/d line correspond-
ing to these indices. The indices hk& may be found
in a similar way. Thus, the instrument may be used to
Card 2/3 determine not only al b and c but also 0, i,e, it may be

05458
SOV/120-59-3-29/46
An Instrument for the Interpretation of X-ray Photographs of
Polycrystalline Substances Belonging to the Monoclinic System
used to interpret X-ray photographs of substances
belonging to the monoclinic system.
There are 3 figures and 4 Soviet references,
SUBMITTED: February 12, 1958
Card 3/3

AUTHOR:' Nudellman, S.L. SOV/70-4-4-28/34
TITLE: On the Lattice Parameters of Chrysotile
PERIODICAL: Kristallografiya, 1959, Vol 4, Nr 4, pp 621-623 (USSR)
ABSTRACT: Preceding communications (Refs 112) have shown how to
index X-ray powder photographs of orthorhombic and mono-
clinic crystals. Chrysotile is here used as an example,
although the parameters were known. Pata from J.W.Gruner
(Ref 3) were used for which Gruner hiiziself had found
a = 5.33, b ;= 9.24, c = 7.33 1, 0 = 13 0161 The metho
described earlier gave a = 9.06�, b = 6.715, c ~ 8.089
P =_6202. The 2space group is C 2h - ~iae rem.s. value
of W s - d- ) is 0.0008 with this cell and 0.0019
ob Cale
with Gruner's, the greatest difference being 0.0025
compared with 0.0657 with Gruner's Qell. A tab-'e of the
indexing is given. There are 1 figure, I table and
7 references, of which 4 are Soviet and 3 English.
SUBMITTED: October 25, 1958
Card 1/1

S/I 81J60/002/010/046/051
B01 91BO56
AUTHOR: Nudellman, S. L.
TITLE: Letter Addressed to the Periodical "Fizika tverdogo tela"
PERIODICAL: Fizika tverdogo tela, 1960, Vol. 2, No. 10, pp. 2637- 2638
TEET: In this "Letter to the Editor" the author corrects an error in
his earlier paper (Ref-1)- In this paper the quadratic form of the tri-
clinic syngony was erroneously represenicii by equation (27). Thereby,
wrong values were obtained for the parameters a, b, ci ap O,of caolinite.
The author gives the corroot representation of this quadratic form and
obtains for these parameters: a - 5-17 A, b - 8-93 Ap 0 - 7.37 A,
a - 910 46'R P a 1050, and Y - 890321. Also some other changes in the
text are dia6ussed. There are 3 Soviet references.
SUBMITTED: March 16, 196o
Card 1/1

NUDEL I MAN, S. L.
Instrument for solving X-ray patterns of
of the Iriclinic system. Kristallograflia
polycrystalline a,-')stances
5 no.5:819-823 S-0 160.
(KIRA 13:10)
(X-ray crystallography)

NUDELTAIT, S.L.
New graphic method for deciphering debyoograms of subotancee of
cubic, tetragonal, and boxagonal oystems. Min. sbor. nc.15:10c~-119,
161. (MA 15:6)
1. GosudELrstvennyy univer3 itet, Chernovtsy.
(X--ray crystallography)

NUDELIMM, Samuil LIvo Ch; I-1AKEYEV, V.!,,; red. izd-va; GUROVA, C-A,,
% -- - - - - t i~M-. -r e -d. ~yi
(Use of the varinble scale method for deciphering powder
rentgenogram,s]Raehifrovka poroshkovykh rentgenogramm metodom
perememogo Diasshtaba. Y;oskva, Gosgcoltelchizdat., 1962. 83 p.
NXIA 15 -.9)
(X-ray crystallography)

NUDELIMANO S.L.1 FRANK-KAMENEI-SKIYp V.A.
Size of the unit call of cooperite. Rent. min. syr. no.2t
105-107 16?. (14IRA 16: 11)
1. Mningradskly gosudarstvennyy universitet.

NUDELIMAN,
---
Determination of the coordinates of atme (ions) based on
the X-ray p"r data.,Rant. min. syr. no.2:108-114 162.
(19RA 16111)
I. LeningradskLy gosudarstvaniqy universitat.

BOMIAROV, Ya., arkh-'*.;~k,,-,i , V., ar~,.,-, "EZA ~YA, 'I.,
arkh'tektor - U. .
D e v e 1 opine n t , ~ I I, , ~-., ly " r, r ;~. ~ ~!~ f f, ~ -I I r.,~, t: r , :?- !, '' - !-~ o: L, ~ - .,. , ~~, r.11 I " r 1~ .
1, ,
Ek3per. -, . N -.1 .

DETBAREIII~ER, M.I., 6EREPHPINNIKOVA, K.L.j 'IEHIOVSKIY, V.A.; I-rii-mail
F,M., NOVIKOV, L.Z.,, LURIY--', F:-"~EN,
Yj'.~ KARAKN'i A,~. fdt~:~eizaedl, KUiTR, L~I.-, --~KLC7, ~-,z
KJArEDEV, F.V.- "FltTI/XH;f~OV S.C.; BONIDAR', V.G.w
I
P~T.; ~UNINA, 4-,V.,; OBEKOV, F.F.; NIKOI,AYFV, N.I.; yjk?,clk)LAVY
T.Ye.; NUDYL'_MAN
Gasificatior of mazut under pressure In a steam-axygen th13t,
Gaz. pron. 9 no.11,49-5.0 164. (r-R.A 17~12)

GRINSHTEY,U, V.I., inzh.; MDELIMM, V.N., inzh.,* RAKRI-Mov, I.A., inzh.
YegatiVe sequence power relay. Vest. elektroprom. 34 no.8:74-75
Ag, 163* 04IRA 16: 0)
(Electric relays)

EWW
NRi
AP6030580 SOURCE CODE- UR/0413/66/000/016/0062/0062
INVENTOR: Grinshteyn, V. 1,; Nudel'man, V. N.; Ollnov, V. M.
ORG: none
TITLE: Contactles s overload relay Class 21, No. 184957 [announced by
Chuvash Scientific Research Institute of Electrical Engineering (Chuvashakiy
elektrotekhnicheskiy nauchno-issledovatellskiy institut))
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 16,
1966, 62
TOPIC TAGS: contactless relay, overload, RC circuit, transistorized balanced
amplifier
ABSTRACT: The proposed contactless overload relay utilizes semiconductors
and contains an input relay unit, R-C circuits with an adjustable delay, and an
output unit using electromagnetic slave mechanisms. To divide the controlled
heteropolar lines galvanically and thus insure relay sensitivity to the overloads
of both polarities, the relay contains two transistorized balanced amplifiers
Card 1/2 UDC: 621. 316. 925. 43:621. 315. 592

45832-66
AP6030580
whose outputs are connected with the relay unit input, and the inputs are
connected with the shunts set up in the lines to be controlled. Orig. art. has:
1 figure. [DW]
Fig. 1. Contactless overload relay.
I-Two transistorized balanced
amplifiers; 2-relay unit;
3-shunts; 4 and 5-controlled
lines; 6-H-C circuits; 7-out-
put unit with electtomagnetic
slave mechanisms
SUB CODE: 09/ SUBM DATE: 21Jun65/
Card 2
124

NUDELIMAN., Ya.I.,, inzh.
------ -
Stock metal trestles for the assembly of the precast reinforced
concrete elements of one-story industrial buildings. Mont. i
spats. rab. v stroi. 25 no,5:21-22 My 163. WIRA 16:7)
1. Trest Stallmontazh.
(Scaffolding)

'IUVC-L'7AA. '- , 1-
- , LL
42224. NUDELIMAN, YA. L. Integrlllyye uranuneniya ustoychivostl sterzhney, sterzhnevykh
sistem i plastin. Nauch. trudy (Odes. In-t inzh. mor. flota). VTP- 7. 1945,
c179-93- - bibliogr: 7 nazv.
So: letopis' Zhumallijykh Statey, Vol.47, 1948.

KMv IlLe L*
do of ealaulatiag proper frequesoles and arLtical force to bar fromwork syetsise Lold red
W-vo t*Wm*-tearet. lit-ryp 19V. 175 p. (Soirammays problemy mokboidid) (50-207731
1w".58

;-: , 1; - Y.- ;
30803. NUDELIKAN., Ya. L. 2nd ~qO'NSHTEYN, N. 1.
Novyy metod opredeleniya chastot mnogoprolatnykh balok na uprugikh oporakh,
nagruzhenr,ykh sosredotor7hennymi massami. Nauk. trudy (Odes. in-t inzhenerov mor.
flota), vy-p. 8, 1949. S. 38-49.

1. -, YA*- L-.--. ERLIKHP' L.- B.
2. USSR (600)
4. Elasticity
7. Elastic stability of the surface layer of some machine parts. Vest.mash., 32,
no. 12, 1952*
9. Monthl List of Russian Accessions, Library of Congress, April - 1953, Uncl.

to."/Yatals xlastlcity$~Plasticity 3.1 Aug 52
"1w*e Formations on the Surface of Certain Pkchlaq
Parts," Ya. L. Nudel"man and L. B. Erlikh
IOU SSSR" Vol 85, No 5) PP 970-974
.In the thin surface layer of many machine parts
occur -compressional stresses during their prepn
'or employment. Establishes that under definite
*oaditiona elaistic. or elastic -plast ic state of
,""l in the compressed layer become unstable, as
result of vhich regular vaves form on the sur-
face,of metal objects. States that the phenomenon
239T66
vf itability loss in the form of waves on the
surface of real objects is rarely observed in pure
tars, but is more often in the-form of specific
,ruptures in the surface layer. Submitted by. Aced
B. L. Sobolev 12 Jun 52.
239T66

"A I'letaod of a,ua:1_i.-_n~: of For_-es '.L~C 5,~t Up
t'~Ie 01" TFOrceS 11 Tr. 0 *(;z 3idr,_ Ili-
raetii-_C of solving- fret luency e uati.-)ns md cc un tior - o P st- I i t ' :-I(-;' -~O ; .)f
p
I I - -11 - ; , " .- U
successive iiano:-Ation of It is ot- te(1 tii~:t for r-,
this met.~iod, -Irldc'.-, i~ ba.,~ed on findi-i,- a in,erv--.l fc,, ung-nowi ro~,-t o an
tiori, is ralativel~,- simple. of Lr!~_'Iic to:.. '..-c
1',.55) SO: Sun.,"o. 713, 9 liov 55

P L I b t ' 144 if - jj) M , L , Call Hr: AF 1108825
Transactions of the Third All-union Mathematical Congress, Moscow, Jun-Jul '56,
Trudy '56, V. 1, Sect. Rpts., Izdatel'stvo AN SSSR, Moscow, 1956, 237 pp.
Nudellman Ya L. (Odessa). Some Problmems in the
:~Aoo' Elastic Stability.
General 208

SO'Y/124-57-4 -4811
Translation from: Referativnyy zhurnal. Mekhanika, 1957, Nr 4, p 134 (USSR)
AUTHOR: Nudellman, Ya. L.
TIT LE: On a Method for the Solution of the Stability Equation (0b odnom
sposobe resheniya uravrieniv ut;~Oyj;h~Xpst~,Y-,
PERIODICAL: V sb.: Issledovaniya po vopr. ustoychivosti i prochnosti, Kiye
AN UkrSSR, 1956, pp 102-IIZ
ABSTRACT: The problem as to whether a frame is stable wi'th a prescribed value
of the load Pis solved by the analysis of a sequence of systems
derived from the basic system of the slope-deforma-. _n method by
step-by-step elimination of connections. Let 11 a I (P,' J! he the
matrix of the n2 coefficients of the canoni~R) equat%ons of the slope-
deformation method. The coefficients aij (P) are determ*1ned in
accordance with the recurrent formula
( P) CL P)
(k)(p) a (k - 1) (P) _ c' k jik
ij ij a(k - 1) (P)
kk
Card 112 (i. k+1 . ..... n; k = 1, 2, n- 1)

On a Method for the Solution of the Stability Equation
SOV/124-57-4 4821
In order that a frame loaded with forces consistent with the parameter P mav be
stable, it is necessary and sufficient that the basic system of the s lope -deformation
method be stable and that
CL (k- 1) (p) > 0(k = 1, n) N
kk
For a practical computation of the critical parameter, the range of its variation
must be given from the outset; this range is later narrowed by means of successive
approximations with the application of criterion (*). This process of computation
coincides in each step with the evaluation of the determinant of the canonical cqua-
ti~ons of the s lope -deformation method with the aid of Gauss' algorithm. The
arti.cle is in line with the author's other works on the same subject [e.g., "Metody
opredeleniya sobstvennykh chastot i kriticheskikh sit dlya sterzhnevykh sistem"
(Methods for the Determinations of the Natural Frequencies and Critical Forces
for Rod Systems). Gostekhizdat, 1949].
V. V. Bolotin
Card 212

SOV/1 24- 57- 5-6046
Translation from; Referativnyy zhurral. Mekhanika, 1957, Nr 5, p 146 (USSR)
AUTHOR: Nude-I'man, Ya. L.
TITLE: Some Problems of the General Theory of Elastic Stability (Neko-
toryye voprosy obshchey teorii uprugoy ustoychivosti)
PERIODICAL: Tr. 3-go Vses. matem. s"yezda. Vol 1, Moscow. AN SSSR, 1956,
pp 208
ABSTRACT: Bibliographic entry
Card 1/1

HUDELIMAN, Ya.L.; OVCHIMMMV, P.P.
.4
, - I
Handing of beams with variable cross section accounting for
shear deformations. Prykl. mekh. 2 no.1:40-50 '56. (WRA 10:2)
1. Odealkiy gidrotekhnichniy institut,
(Girders) (Flexure)

IMI I doktor fiziko-matem. nauk, prof. (Odessa);
igii~QZAAA
kand. tekhn. nauk (Odessa)
Method of superpoeftion in problems on the stability of
elastic systems. Isal. po teor. sooruzh. no.12:89-100 163.
(MIRA .16:6)
(191astic rods and wires)
(Stability)

VILIGA, M.A., inzh. (Odessa);.. NUDIE4LIMAN,10,1,1. , doktor fiz.-matem. nauk,
prof. (Odessa)
Stability of rectilinear rods with elastic longitud;ml connections.
Isol. po teor. sooruzh. no.13:183-187 164.
04IRA 18:2)

WMELIMAH, TO.S.
Cost keel-blocks to be used in shipyards. Sudoetroenis 24 no. 6:56-
57 A '58. ( 14IRA I I . 8)
(Shinbuilding--EquiDMOnt and supplies)

SUIRLIMAN, U.S., inzh.
.-
Repair of the ferr7 4Zapoliarn7l.11 Sudestroenle 25 no-3:
47-48 Mr 159. (KIRA 12:5)
(Ferries--Maintenance and repair)

~,-: ~Pu ~~ "I ;:!a~ Wt

MMILIKANj.H. (Moscow)
Repellents. Priroda 44 no.10:86-88 0155. (MMA 8:12)
(Insect baits and repellents)

NUIMLIK&N. E.N. (Maskya)
Herbicides. Prlroda 45 no.3:80-83 Kr 156. WRA 9:7)
(Herbicides)

-410 gotteldal BS1t*#0 by Z. N. WelINKUP V44cov prircftm Nw-
cow, Vol 4~, No 8, ~ug 56, pp 88-91
Considerable success has beet achieved with insecticidal baits as a
mesas of controlling harmful insects. The usual methods of applying in-
secticides, i.e., dusting, spraying, aerosols, and insecticidal smokes,
,are not always fully effective, and in many cases their use is inconven-
A~nt since they require the removal of foods or other objects with which
bwans may come in contact from the area to be treated. Insecticidal baits
fisve two advantages: first, they bring the insects into close contact with
.the poisons, and second, if the bait is a food, the poisonr kill the in-
,sects through intestinal absorption. The use of insecticidal baits became
#wsible with the development of organophosphorus compounds -- parathion
Ithicf0s], diazinon, dipterex, malathion (karbofos], and others -- which
.iie used with sugar water, powdered sugar, and other sugar preparations
f6t the destruction of flies, and with food products for the destruction
.of-roaches. One of the more effective organophosphorus compounds is the
.tw.wly developed insecticide DDVF, which has the following structural for-
irdla: H3CO
0 P 0 CH CC12
"f0,

-:DM U
isno less toxic to flies than parathlon, b t in considerably less
q6to'C-16us to warm-blooded animals and humans.
Sugar-baited insecticides, however, fail to attract fruit flies. In
1952, it was found that certain protein hydrolysates had the capacity to
attract insects, and when used in combination with parathion, malathion,
~aad DDVF formed insecticides which were effective against fruit flies.
Ode of the more effective lures, whose action has not yet been clarified,
is methyl eugenol which has the following structural formula,
OCH
3
OCH3
CH2_C11 - CH2
Methyl eugenol is marked by high selectivity, and attracts only male
friAt flies. The great power uf its attraction makes possible its applica-
tion in small quantities and over small areas.
Insecticidal baits form a simple and effective means of control of
fliesAn cases where other methods of applying iasecticidzs are not prac-
SLAyn ~ ;L3

36564
3/081162/000/006/110/IIT
B168/B101
AUTHORS: Devirts, E. Ya., Kaplun, M. G., Nudellman, Z. N., Novikov, A.S.
TITLE: Chemical mastication of natural and butadiene-styrene rubbers
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 6, 1962, 692, abstract
6P560 (Tr. N.-i. in-ta rezin. prom-sti, sb- 7, 1960, 3 - 16)
TEXT: Methods of producing the chemical plasticizers peptone 22 (1) and
rhenacits V (II) have been worked out and these substances have been
synthesized under laboratory conditions. I, II.and imported rhenacits
IV (III) were tested as accelerators for the mastication of natural
rubber and NC-30A(SKS-30A). 1, 11 and III are effective chemical
plasticizsre for mastication of natural rubber in the rubber mixer at
120 - 130 C. II and III accelerate mastication of natural rubber on
rollers at 70 - 80 00. It II and III do not affect the physioo-meahanioal
properties, the resistance to heat &going or the swelling of rubbers* II
is an effective plasticizer for SKS-30A when the rubber Is being
processed in the rubber mixer and on rollers. (Abstracter's notot
Complete-translation.
Card 1/1

szoc'
ZZ Q S Z I U'~
AUTHORSt Nudellman, Z.N.. Novikov, A.S.
34293
_A~
S/138/60/000/005/005/01~'
A051/AO29
TITLE: The Structuralizing Reaction of Polydimethylsiloxanes in the
Cold Vulcanization of Polysiloxane Rubbers
6
PERIODICAL: Kauchuk i Rezina, 1960,A
I\No- 5, PP. 17 - 20.
TEXT: The present article is dedicated to the experimental confirma-
tion of the condensation of alkoxy-derivative metals, metal-organic groups
and silicon of the general farmula M(OR)n, (where M is a metal, Bilicon,
etc., R an alkyl or aryl group, n the valency of M), at the hydroxyl groups
of the polysiloxanes and also to the study of the mechanism of this conden-
sation. It is proven that the condensation of the polyalkoxyailanes with
polydimethylsiloxanes takes place only at the hydroxyl gromps of the latter.
The complex-catalytic nature of the solidification of the polysiloxanes at
room temperature is also shown. In order to clarify the mechanism of con-
densation at the free hydroxyl groups, the effect of certain admixtures on
this reaction was investigated. For example, by adding aluminum pyriaine
Card 1/4

84293
S/138/60/000/005/005/012
A051/AO29
The Structuralizing Reaction of Polydimethylsiloxanes in the Cold Vulcani-
zation of Polysiloxane Rubbers
with butylate to polysiloxane or triethylamine (molar ratio of the amine
to the butylate of aluminum, 1:1), the reaction was considerably slowed
up and the nature of the formed products changed. If amine in "he ratio
of 2:1 or 3:1 is added, no structuralizing takes place at all. The authors
(Ref. 6) had already shown that when mixing polysiloxane rubber with alkoxy-
-derivatives of many metals and metal-organic groups, rapid gelatination
of the rubber takes place with the formation of high-molecular and in some
cases nonfusible products and products insoluble in benzene. In that case
it can be assumed that the reaction takes place at the outer hydroxyl
groups of the polysiloxane rubber. The condensation arrangement 6f the
hydroxyl groups requires confirmation since there are several variations
of the reaction, e.g., the break in the large polyBiloxane rings or chain's
with simultaneous bonding of the liberated ends with the structuralizing
agent. The interaction of metal alcoholates with two types of polysiloxan-
es was investigated. Table 1 shows the relationship of the aluminum buty-
late quantity needed for the complete structuralizing of the polysiloxane
Card 2/ 4

o4eyj
S/138/60/000/005/005,/012
A,051/AO29
The Structuralizing Reaction of Polydimethylailaxanas in the Cold Vulcani-
zation of Polysiloxane Rubbers
and the molecular weight of the polysiloxane. The experimental procedure
is outlined and the structural formulae of the reacting compounds are
presented. The results of the indicated experiments point in favour of
the reaction scheme of the polysiloxanes and the alkoxy-derivatives of me-
tals at the hydroxyl. groups. It is stated that the reaction of polysiloxane
with butylorthotitaniumlis a hydrolysis of the latter by the moisture of
air to orthotitanic acid and subsequent condensation of this acid with
hydroxyl groups. Another possible mechanism is the formation of an inter-
mediate complex compound, metal alcoholate with the polysiloxane, as a re-
sult of the donor-accepting bond of the metal atom with the oxygen atom of
the hydroxyl group with subsequent detachment of the alcohol. As a result
of the experimental facts, the authors claim that it is easy to explain
the difference in the nature of the gels obtained from polydimethylsiloxane,
aluminum butylateland butylorthotitanium. The accepted assumptions on the
mechanism of the condensation reaction made it possible to use tetraethoxy-
silane as the structuralizing agent in this reaction or other polyalkoxy-
Card 3/4

20251
q 10 N"-
3/138/60/000/012/002/009
A05l/A027
AUTHORSt Novikov, A.S., Nudellman
TITLE: The Kinetics and Mechanism of the Catalytic Reaction Between Poly-
dimethylailoxanes and Polyalkoxysilanee
PERIODICAL: Kauchuk i rezina, 19600 1, No~12, PP~ 3-7
TEXT: In a previous work (Ref.D the authors dealt with the catalytic
reaction of structuralizing of polydimethylsiloxane rubber with alkoxysilaneq,
which takes place by condensation of the latter with the hydroxyl groups of
polydimethylsiloxane and separation of alcohol. In this acticle it is point-
ed out that the mechanism of the reaction has been only slightly investigated
and it is further suggested that the kinetic3 of the reaction be studied
during the period from its start until the moment of the spatial lattice
formation. Such an investigation was carried out by measuring the elasticity
growth of the benzene solution of the CKT (SKT) rubber after it had been
mixed with the catalyst and the structuralizing agent in a spherical Hepler
viscosimeter. It was shown that the elasticity growth was determined-only by
the growth of the molecule. Fig.1 shows that the growth process of the
Card 1/8

20251
8/138/60/000/012/002/009
A05l/A027
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimethy1ril-
oxanes and Polyalkoxysilanes
elasticity for the system 15% solution of SKT in benzene-tetraethoxysilane-
catalyst (0-5 9) is not uniform. The shape of this curve is explained by
the many-stage type of reaction of structuralizing (Ref. 5). It is suggest-
ed that the initial part of the curve is determined by the first stage of the
reaction which consists in the formation of the intermediary complex compound
of one molecule of the catalyst with one moleculu of the hydroxyl group of tYe
polydimethylsiloxane and one molecule of oxygen of the tetraethoxysilane
molecule:
CH H H
0- 51 0-- Si
U113 U113
R OR
Sn'..O- Si - 0
Ult
(2)
This complex is then regrouped and E, new siloxane bond is formed, a catalyst
molecule is separated off, probably in the form of a complex with the separa-
ted alcohol molecule:
Card 2/8

20251
S/138/60/000/012/002/009
A051/A027
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimethylail-
oxanes and Polyalkoxysilanes
ME
CHA OR R
- 0 - Si 0 - Si 0 - Si - 0 + Sn + ROH (3)
CH., OR
3
The latter stage of the reaction correspondo to the part of the curve paral-
lel to the abscissa axis, It ia not the induction period, since the reaction
i3 taking place although not causing an increase in the molecular weight of
the system. Other confirmations ~f the intbraction with initial formation
of a transfer complex were obtained from infrared spectra of the system
(Figs.2,3). These graphs prove that thern i,s no induction period necessary
in the formaticn of the c_omplex in the given syst(am, The second stage of the
reaction increases the molecular weight to twice the amount of polysiloxane;
~fl (') R R H CH
3 \11, I . 3
- 0 - Si - 0 - 31 - 0 t S11 + 0 - 3 i - 0 (7)
1 A I
Card 3/8 al 3 OR CH 3

S/138/60/000/012/002/009
A051/AO27
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimethylsil-
oxanes and Polyalkoxysilanes
possible,i..e., molecules where the donor-ac"ptor bond with one atom ef
silicon w 'ould not. significantly change the d*ensity of the electrons in the
other oxygen atoms. The reaction mechanism of catalytic condensation of
polydimethylsiloxane with tetraethoxysilane and other polyalkoxysiloxanes is
confirmed on an example of the gelatination of a benzene solution of SKT in
the presence of a polyethoxysiloxane-type structuralizing agent, where
n 10:
OR OR OR
RO - Si 0 - Si 0 - Si - OR (9) (Fig-5)
I I i
OR OR /n Un
There are 5 graphs and 5 Soviet references.
ASSOCIATI.011: Nauchno-issledovatellskiy institut rezinovoy promyshlennosti
(Scientific Research Institute of the Rubber Industry)
Card 5/8

20251
S/138/60/000/012/002/009
A051/AO27
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimethylsil-
oxanes and Polyalkoxy3ilanes
Fig. 1 Viscosity increase in a 15 lj~'j
9 4 solution of SKT in beftzene with te-
traethoxysilane and catalysts: 1 -
dicaprinate of dibutyl tin, 2 - dis-
0
tearate of dibutyl tin.
>
>
43
W (D
14

time, hours
C ard 6/8

n0251
r
S113 60/000/012/002/009.
A051X027
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimethylsil'-
oxanes and Polyalkoxysilanes
0
0
,a
r
+in]H INI
JIM WiHid I I II
100
80
60
46
V
0
c, r" ~- C. '.S
-o -0 0) tn cz) c3 c);;
ell cl~
c') Nc" N ~) ~)"f
V CAr
Fig.2 Infrared spectrum of polydi-
inethylsiloxane with molecular
weight of about 4,000.
0

F_

C.3 ~3
Ln
5 ci F-Sm 11) 41~ -1" f17
Fig-3 Infrared spectrum of a poly-
dimethylsiloxane mixture with an
8% tetraethoxysilane and 2% di- J
caprinate of dibutyl tin immediate-
ly after preparation.
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20251
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A051/AO27
The Kinetics and Mechanism of the Catalytic Reaction Between Polydimeth:rlsil-
oxanes and Polyalkoxysilanes
0
0 43
>
Cd $4
ZJ
14
5

-
g
40
0
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Fig. 5 Viscosity increase inal%4 solution
in benzene with polypthoxysiloxane and
catalysts: I- dicaprinate of dibutyl.tin,
2- distearate of dibutyl tin.
time, hours

S/6' 1/6
D244/:)302
OH .--Nudel'Man, 7.. 1,1.
TITLE: On the mechanism of cold vulcanization of poly t; ~11 oxaie
rubbor
SOURCE: Khimiya i prakticheskoye prime-en-1-ye
kikh soyedineriiy; trudy konferentsi-i, no. 6:
diskussii, resheniye. II Voes. konfer. p0
prim. krei-.moorj,!-. soyed., Lon. 1958.
AN SSSR, 1961, 210-213
TEXT: The author studied the kinetics of 'gelation. of
rubber-ber,zene solutions to obtain a scheme ~'or t'..e of
catalytic formation of structure in pol.,,dime-uhyl
The structure formation is promoted by tet.raethoxy8iiane 1;-4mi-
-Lar compounds. The process was studied by determi-in', viscoji-.--us
of the solution. It was established that organo-tin LLC;-~
on the hydroxyl group of polysiloxane rubber in such a .L; o
cause a shift of the electron pair from The 0 atoz: ~o -u-c: -,n LI-60M,
Card 1/2

"`/6 6 1/6 G/Jot,
On the mechanism of ... D244/D502
followed by transfer of an electron from the H to 0
When a donor-acce,)tor coordinaton bond is for::,.ed 4
Q
of tetraethoxysilane, a redistribution of electro!-.
4n -le latter, leadin6 to transfer of the reac~.Jvu c e,
molecule. Thi6 prevents the reaction of tetraothoxy!3J.*.'L~11U :.'1:) 1C;-~
with r,,ioro than ono moloculo of thu oatulyot. It L~I-Lt t)x
polymerization begins immediately after mixinE; t1,Q vi"'ich
n 4
would not be the case if the multi-step reaction mecha
-.)licable. 2hus the mechanism pro
posed by N. IJ
cov' ) is not correct. To obtain formation of a str-_cture, t.".e r u b b e r
was heated with 1.5c;~ of benzoyl peroxide. In the diL;cL*._--s4_Q.)~-. w'-Ich
followed Baranovskaya pointed out that her mechanism wa2 --ropo-ed
.Lor bulk vulcanization, whereas the author's mechanism u1j.;1it~d :)-,-,D-
bably only to the polymerization in solution. "-'here a-re 2 fi6-~r-es.
_133JCL,';I0Y,: .".auclino-issledovateilskilr instit,t rezJnovoy ~)romyoh~
~ P.,
lennosti, Eosk-va (Scientlllc Re---earcl- L.--.1,tate Of
the Rubber'Industry, Moscow)
~Iard 2/2

23764
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B110/13216
AUTHORS: -Nudellman, Z. N., Sviridova, A. V., Novikov, A. S.
TITLE: Synthesis of linear alumosiloxane polymers by silanol
condensation
PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 6, 1961, 641-645
TEXT: Since no method han been described for the preparation of linear
metallosiloxanes of preset struoture, the authors tried to synthesize
these polymers by appl ing silanol condensation (Ref. 1: Kauchuk i
rezina, 1960, 1 ~. This condensation takes place on mixing organo-
silicon compounds containing the silanol group Si -OH with alkoxy
derivatives of metals, organometallic groups or silicon (e.g. aluminum
alcoholates, dialkoxy derivatives of the monoacetylac,,etonate, other
aluminum complexes, alkoxy derivatives of titanium, tin and iron, etc
Separation of the alcohol and formation of the metallosiloxane bond tak;
place under very mild conditions according to the following scheme:
V OR H 7R
Si -0 .- M Si -6.. M ;P Si-O-M 4-ROH. For this reaction the authors
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Synthesis of linear alumosiloxane.,, B110/B216
used a bifunctional aluminum alcoholate with 2 reactive alkoxy groups,
i.e., an alumintim butylate-acetoacetic ester complex:
CH CH OR'
3 ~., , A# 1-1 /
C
0
Al
C4a90 Oc 4H9
Oving to its uniform electron density distribution over the ring, this
complex ifj more resistant to hydrolysis than the alkoxy groups. On treat-
ment with water, the alkoxy groups are hydrolyzed off, and condensation
yielding a linear alumoxane polymer takes place. A similar behavior was
to be expected in ailanol condensation. Polydimethylsiloxane (molecular
weight 3,000-50,000) having silanol groups at the ends of the chain was
used as reaction partner. The two components were mixed in benzene in the
required ratio and the polymer formed then precipitated with acetone. The
polysiloxane molecules of high molecular weight determined the basic
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Synthesis of linear alumosiloxene... BIIO/B216
properties of these modified alumosiloxane derivatives (RAS), which are
modified by aluminum links. The time required for the reaction is
directly proportional to the molecular weight of the polydimethylsiloxane
derivative used. A comparison of the viscosities of MAS (Table 1) in
toluene and solutions of the initial siloxane indicates the increased
molecular dimensions of MAS. Their greater hardness is due to the
formation of donor-acceptor bonds between the aluminum groups of different
polymer molecules and to multiple coordination of the aluminum atom. The
oxygen atcm in the alkoxy group of the acetoacetic ester has the greatest
electron density and is able to form complexes. For.this reason the
ethyl and octyl esters of acetoacetic acid , having different complexability
were used. Hardness was determined thermomechanically according to
Kargin in the temperature range -600C to 2000C (at a rate of-40C per
10 min). The extent of intermolecular interaction is mainly determined
by the relative number of aluminum links in the chain. The properties
due to the aluminum links are more marked if the initial oiloxane in
lower-moleoular. The Al content of MAS depends only on the molecular
weight of the initial siloxane and not on the ratio aluminum complex/ailoxane
(26,300 -1-99 % Al; 3160 -3.61 % Al). The greater hardness of the second
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Synthesis of linear alumosiloxane ... B11O/B216
polymer is due tn its higher Al content and the numerous Al links. The
above-stated comDositiori is confirmed by the findings that the polymers
are completely soluble in benzene and toluene, flow under pressure, melt
on heating and sinter at high temperatures. The residual compression is
also characteristic of structureless polymers. This is corroborated by
the viscosity (Table 1) and the presence of Al in these polymers.
Acetylacetone forms very stable acetylacetonates with the Al of many
aluminum compounds, splitting the Si -0 -Al bond, On treating MAS with
excess acetylacetone at room temperature (Table 2), the initial polydi-
methylsiloxanes were regenerated, which shows that condensation did not
take place: Si-OH +HO-Si Al 0 Si-O-Si + H 20. Heating of MAS to
> 2000C leads to reversible softening, which together with its resistanae
to pyridine, is not in agreement with the presence of a large number of
complex bonds H N/ V
SiA ...Al ... O-Si
This method can also be applied lit the u~rntheeie of linear polymers
modified by titanium, tin, Iron, etc., in the given order, their properties
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Synthesis of linear alumosiloxane... B110IB216
depending on the metal alkoxide used and its ratio to the polysiloxane.
There are 1 figure, 2 tables, and 3 references: 2 Soviet-bloc and
1 non-Soviet-bloc.
ASSOCIATION: Nauchno-issledovatellskiy institut rezinovoy.promyshlennosti
(Scientific Research Institute of Rubber Industry)
SUBMITTED: July 25, 1960
Table 1: 'Viscosity of toluene solutions of MAS in initial polydimethyl-
siloxane derivatives. a) Mol-wt. of initial polydimethyleiloxanes;
b) polydimethylsiloxane; c) concentration, g/100 ml; d) given rate;
e) KAS; 1) viscosity at 2000; 2) viscosity at 250C.
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