SCIENTIFIC ABSTRACT OBOLENSKIY, V.N. - OBOLENTSEV, R.D.
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Collection:
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CIA-RDP86-00513R001237710014-5
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Sequence Number:
14
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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L 37660-66 9WP(k)/EW(d)/F4P(h) 'a&(1 .,'FWP(V) BC/GD
ACC NR3 AT6012354 SOtrRCE CODE: UR/0000/66/0001/
,AUTHOR: Gurevich, 1. M.; Obolenskiy, V. N.,; Portnov, M. L.; -7(,
IPshenichnikov, A. M.; Khvoles, V. -A.
ORG- none
TITLE: Complex tele -information system for industrial plant
SOURCE: Nauchno-tekL--dcheakaya konferentsiya po sredstvam promyshlennoy
telemekhaniki. Moscow, 1963. Promyshlennaya telemekhanika (Industrial
telemechanics). materialy konferentsii. Moscow, Izd-vo Energiya. 1966, 190-201
TOPIC TAGS: remote control system, supervisory control system, industrial
automation
ABSTRACT: Developed by the Central Scientific Research Institute of Complex
lAutomation (TaNUKA , a system for transmission of discrete aid conti, us informa-
ition over a distance up to 20 km is briefly described. The system is intended for
iconnecting individual automatic machines and plants with their control computers and
ialso with the dispatcher's desk; it is designed for a chemical combine whose
Ord 1/2
L 37660-
ACC NRs
0 ;
individual parts are scattered over an area. The system includes the equipment for
transmission and reception of information, for data processing, insertion into and
withdrawal from the computers; the central dispatcher's station equipment includes
digital display panels, scaling devices. parameter -deviation signaling devices and
recorders. and integral-parameter and statistical -data recorders. Block diagrams
of principal parts of the system are explained. Orig. art. has: 6 figures.
SUB CODE: . 09,13/SUBM DATE- O8Jan66
OSOMMM Te.L., starchly master.
1", "7
Hand press for mkW washers and nuts. loorgetik 2 no.9:22 5 154.
(Ptmahing mwhinory) (MU 7:9)
OBOIZNSKIYO Ye. P. : Master Tach Sol (diss) -- "InveatiMtIon of tho otressr-d
%iik
state of grooved rolls. in twisting". Mosemr, 1958. 15 pp (Min Higher Educ LISSER,
Moscow Automotive Mechanics Inst), 200 copies (XL, NO ~, 1959, 110)
AgTHOR: Obolenskiy, Ye.P. 113-58-7-7/25
TITLE: ~Ex 1~~
~mination of the Torsional Rigidity
of Splined Shafts (Eksperimentallnoye opredeleniye krutil noy
zhestkosti shlitsevykh valov)
PERIODICAL: Avtomobillnaya promyshlennost', 1958, Nr 7, pp 16-17 (USSR)
ABSTRACT: The analytical determination of the torsional rigidity for
profiles with a complicated cross section is very difficult.
A method of experimental determination is suggested by the
author. It also permits the determination of the magnitude of
the moment of inertia of variouf sections under torsion. A
total of 17 splined shafts of diverse brands of steel with
diverse section profiles (Nr 1 and 2 splined shafts with 4
teeth, Nr 3 to 6 shafts of the transmission of the "Universal"
Tractor of the Vladimirskiy traktornyy zavod (Vladimir Tractor
Plant ), Nr 7 to 17 the secondary shafts of the transmission of
the ZIL-150 car) were placed under torsional stresses. Ur 12
to 17 were subjected to hi6h-frequency hardening. The ob-
tained results are represented in tables arranged by the
serial shaft numbers of the experiment. Such experiments
can be carried out in the usual plsnt laboratories where
Card 1/2 there is a torsion test machine.
113-58-'7-7 '25
.. Experimental Determination of the Torsional Rigidity of 3plined 7hafts
There is 1 diagram, 1 graph, 5 tables and 5 Soviet references.
ASSOCIATION: Moskovskiy avtomekhanicheskiy institut (The Moscow Auto-
mechanical Institute)
1. Shafts--Stresses 2. Shafts--Test results
Card 212
A d iz
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5.13
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3-313
fill
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S/044/62/000/006/082/127
B166/B112
AUTHOR: Obolenskiy, Ye. P.
TITLE: Uee of the method of finite differences for an investigation
of the stresses to which splined shafts are subje~ct during
rotation
PERIODi.CAL: Referativnyy zhurnal. Matematika, no. 6, 1962, 30-31,
abstract 6VI47 (Sb. "Raschety na prochnost", M., Mashgiz,
no. 4, 1959, 205-223)
TEXT: The author gives results of a calculation, by the method of finite
differences, of the stresses to which a splined shaft Is subject during
rotation, the shaft in question having four teeth of varying heights and
different sections. The familiar 5-point and 9-point difference equations
were used for the calculation in the case of a square grid. The boundary
values at those points of the grid range not coinciding with the contour
of the given cross-section were corrected by Shaw I a'-formulas whose order
of error is a 3(a - grid step). The stress function, which eatisfies
Card 1/2
S/044/62/000/606/062/127
Use of the method of finite... B168/B112
Poisson's equation
a 2F a2F 2
2 + -a2
ax y
when F = 0 on the contour, was determined for different grid step3. As a
result of the calculation, the value of the stress in the center of the
grooves of a splined shaft was determined with greater accuracy and was
shown to depend on the height of the toothi the coefficient of stress
concentration was shown to depend on the section of the splined shaft. A
formula for calculating this value is given. The torsional rigidity of the
splined shaft was also shown to depend on the tooth height. [Abstracter's
note: Complete translation.]
Card 2/2
GOLID# B*V.q doktor tekhn.nauk;--UUQLENSKIYP Ye.P., kand.tekhn.nauk;
YEGOROVq L*A*9 kandetekhnortaa' -
Strength of motor-vehicle shaftso Vestemasho 41 nool:22-27
ja 161. (MIRA 14:3)
(Yotor vehicles-Transmissiod devices)
GOLIDs B.V,, doktor tekhn.nauk; OBOLENSKIY, Ye.P., kand.tekhn.nauA
Strength analysis of semiaxles of motor vehicles. Avt.prom. 28
no.2:23-26 F 162. (MIRA 15:2)
1. Hoskovskiy avtomekhanicheskiy institut.
(Motor vehicles--Axles)
oo M'47,M'
,y ye.
AID F - 724
Subject USSR/Engineering
Card 1/1 Pub. 29 - 17/26
Author Obolenskiy, Ye. S., Foreman
Title : ifafid:pres-s -f-o-r--wa's'h'*e-rs and nuts
Periodical : Energetik, 9, 22, S 1954
Abstract ; The author briefly describes the press of his own design.
One drawing.
Institution : None
Submitted No date
OBOLPUH, Tu. A. (Obolonalkyi, IU. A.), iuzh.
Cemented gravel filter. Kekh. sill hoop. 9 no. 7:24-25 J1 '56.
(Mi&~ 11,-8)
(Yilters and filtration)
OBOLMKIY . YU A. (KIYOV)
-- --l
Automatization of water works. Vod.1 san.tekh. no.9:19
S '59. (14IRA 12:12 )
(Water-supply-Automation)
OBOLMKIY, YUOA. (Llbolenslkyi. IU-A-I, dotes'
Pump without packing Cups. Hekh,sill.hosp. 11 ao-2:24-25
7 ,6o. (MIRA 13:6)
(Pumping machinery)
OBOIZIISKIYI YU.A. (Ki.yov)
Laying an underwater pipeline vith a diameter of 1400 =.
by dragging it across the river bed. Stroi. truboprov. 7
noo7:21-22 n 162. (IIJU 15:7)
(Pipelines)
"Obtainin Smmd. Thermal Joints In Steel Vast-
Dr Tech.Sci, lAureate of Stalin.Prizes,
Tu. A. Nekhandsip F. D. Obolentsev Cand Teeh Nit
leningmd rolytech Ust Iumni M. 1. ftllniv~
...~,Litey Proizvod" No ~5-19
londucted expts to establish. conditions for.*
Otalaing sound: vatal in X, TO Lj, Y and,
matjLl
"p94 Joints of steftl castiogs, using.
1'abills, Also studied influence of diviensions.
vmd material of chills on their effectivenessi,
19*0
W ctl-d gas *we of 16IMS on thi'~4uiiliv 41
Xh.-Ttkh; Ildn'tell. :14ashinoattrAtet. UQ aornik
6~
, 201-14,. Effea). 2hur., Mdr. 1956 131~ 14n. 1-0M,
Loughne!A; of tile, rurfard a ca*.,t'-i WIP-.
cuts btu~,Uisc of
tuation Intel tLQ Porebi of 1911-41 5Fb4Y mull (Mew-
ttration roulluana (1)) ovbyfiav~sfmu without wgnet-
I from the ma-tAl (juetwit r"'ghn-ns
6 Ansly~ud for the lovandon E-1 eab a thete r1joilimm-s
es. I was fornitd =dtr the action of tbe hydrostatic
Isura of the metal. Capillary forces, depeudiag on
.ther or not the metal fortli is vvet. can increase or deAcreaw
I b directly dependent upun tl,c coampum C4 the M01-
wedWm, i~e temp. of the- metal, shd Its coatut time
77
080LF_NT_5F-v, FJ)
25(l) P 3 PHASE I BOOK EXPLOITATION SOV/1440
Nauchno-tekhnicheakoye obshchestvo mashinostroitellnoy
promyshlennosti. Leningradskoye oblasibnoye pravleniye
Litlye povyshennoy tochnosti (High-precision Casting) Moscow,
Mashgiz.. 1958- 196 p. (Series: Its: Sbornik, kn.45)
7,000 copies printed.
Ed.: A*No Sokolov; Tech* Ed.: L.V. Sokolova; Managing Ed. for
Literature on Machine-building Technology (Leningrad Division,,
Mashgiz): Ye. P, Naumov, Engineer.
PURPOSE: This book is intended for engineers and technicians at
foundries and planning and research institutes.
COVERAGEi The book contains the transactions of a special
conference called in November, 1956., by the Leningrad Oblast
Administration of the Nauchno-tekhnicheakoye obahchestvo NTO
,(Scientific and Technical Society of the Machine-building
Industry). The articles describe advanced techniques used in
Card 1/5
High-precision Casting
SOV/-1440
precision-casting processes such as shell molding Investment
caating,,"pressure die casting, press die casting toalled in
Russian forging of liquid metal"), and auction casting.
Special attention is given to the production of large pre-
cision castings, one of the principal problems in the industry,
At the same time., methods of improving the precision of
sand-mold castings are examined. Experience gained in the
mechanization of precision-casting and shall-molding processes
is reported. Information is given on the present state of
precision casting, both in the USSR and elsewhere. No
personalities are mentioned.
TABLE OF CONTENTS:
Preface
Gulyayev,, B*B. Production of Precision Castings Outside
the Soviet Union
Shub, I. Ye. (Chairman, Committee on Special Methods of
Casting,, Leningrad Oblast Administration of the Scientific
Card 2/5
High-precision Casting
SOV/1440
and Technical Society of the Machlne-building Industry.
Equipment for Producing Castings in Shell Molds 18
Kolacheva, O.V, Heat Conditions and Thermal Stability
of Shell Molds 36
Obolentsev, F,D. One-piece Sinterable Molds as a Means
the Precision of Castings 43
Dobrozrakov,, 0.1. Production of Iron Castings in
Shell Molds 55
Belogay,, V*M, Experience Gained at a Plant in Shell
Molding 61
Goryunov, I,I. Increasing the Precision of Investment
Castings 64
Card 3/ 5
High-precision Casting
SOV/1440
Golovanov, N*N* New Equipment for Investment Casting
L'vov, A,A* Experience Gained at a Plant in the
Production of Large Steel Investment Castings
Lyashchenko, N.N. Gating Systems for Investment
Casting
Obolentsev, F.D., and V.P. Kalenov. Effect of Various
Factors on the Formation of Cracks in Molds During
the Melting-out of Patterns
Plyatakiy, V*M., and N,N. Belousov. Recent Achievements
in Producing Cast Blanks With the Use of Pressure
Goryunov, I.I., M.F. Makellskiy and A.A. Demidova.
Pressure Casting
Shohegolev, A.A. New Development in the Pressure Casting
of Brass
76
94
99
107
112
127
138
Card 4/5
High-precision Casting
SOV/1440
Sobolev, A.D, Experience Gained in the Production of
Large Pressure Castings
Krasil'shchik, N*L. Experience Gained in Press Die
Casting
Mednikov, Z.G., and R.N. Trofimov. Press Die CastIng
Belousov, N.N., and A.A. Dodonov. Production of Castings
With the Aid of Suction
Shornikov P.N. Production of Casting Molds by Pressing
in 11~ydrpaullc Presses
Vishnyakov., N*V* Increasing the Precision of Castings
Made in Sand Molds
150
156
168
176
185
190
AVAILABLE: Library of Congress GO/ri
Card 5/5 5-5-59
S1 123/59/000/0 10/064/3--,
AG04/A00 1
Translation from; Referativnyy zhurnal, Mashiriostroyeniye, 191-~9, No, 16, 1),
# 38750
AUTHOR., Obolentsev, F. D.
TITLE: One-Piece Clink ng Molds as Mee-ns of increasing the 1~astirg
Precision
PMUODICAL.- V sb.. LiVye povyshemoy toahnosti. Moscow-Leuningrad, Masngiz,
i,,158, pp. 43-54
TEXT: The author reports on the effects of or-pi-?c- -1inkering mc',Js and
precision of models and molds on the linear dimenslons of castings By te'-T~S 11
was established that the precision of linear castirig dimensions deperds rn ',r-
following factors: 1) The model should be made with the prescrited "~~,'-ranx-~:s
of materials making it possible to preserve this REfecisio%during the me.,Id-mar.,-,
facturing process; the best models are of metal or d1spexigable patt'~rnz on a
polystyrene base. 2) Mold materials should possess a good cc_nsistazicy, th6rv_-_f0T-.
dry materials and suspensions are used. 3) it must be possible to rEmovq the
Card 1/2
S/123/59/000/01o/o64/o68
A004/AO01
One-Piece Clinkering Molds as Means of Increasing the CastirA PrA,:Jslon
model from the mold without deforming the latter. 4) Affter the model being
removed, the mold should not be subjected to tempera-var~l effects. 5) The mold
should be of the one-piece type, since assembly ope-ratiouns cause the greater
part of inaccuracies (50 - 70%). 'Their absen2e renders it possible to reprodice
the model configuration with a high degree of precision, and warrants small
tolerances in the dimensions of the mold as a whole. There are 11 figures,
Ya. N P.
Translator's note: This Is the full translation of thF~ orig1nal Russlar, ab.~~ra~-f
Card 2/2
OBOLMTSV, P.Dt
or salt patterns and their effect on surface quality
of one-piece molds. Lit. proizv. no.1:16-19 Ja '58. (NM 11:2)
(Patternmkiag)
AUTHOR: Obolentaai;,- SOV/-63--58-2-10/46
TITLE: The Formation of Sand Crust in Casts Prod,,.~zed :f Different
Alloys (Obrazovanlye prigara na otllvkakh !zgctcv1yayemykh iz
razlichnykh splavov)
PERIODICAL: Naurilinyy" doklady vyashey shkoly. Meta',',,urglya, 1958, Nr 2p
pp. 66-71 (USSR)
ABSTRACT: In cast'-ng iron-.carbon alloys in sand mcld5 silt,~ates are
formed due to the interaution between the cxides and
the material of the molds. The formation of silicates does not
only ociur during the metallic mel'." but aleo du_-ing its sollldi-
fication. Also in the cooled metallic melt ox-4dation phenomena
occur. The oxygen necessary for the oxidation 413 obtained mainly
from the pores of the mclds. To remove -this anfa-icratle effect
of the molds it ~s recommended to use mclds that are as far as
possible free of pores and gases. The oxidation proda,:;ts formed
are equa2ly distributed in the metallic melt. In *..-zk-~ng with
alloys -.ontain~ng 'Iron and chromium Al 203:,T C:: 203are formed
in the casting process at the su--far;e of the m8ta~_lio mel'.0
Card 1/2 These oxides do not react. with the sil!.~,cn d_'cz-_'dP -,ontent of
SOV-63-.58-2-10/46
The Formatior. .-)f Sar-i Cp.;st Cas's Produced of Diffprp-n4 A-- ~Yq
the moldsl th-.is -I.t may be explained that. al--y3 wi th a',,.Imln,.LM
and ~;ntent 4-. pra.-Al -:ally nnt show t3,.1-h i3and -rust-3
when ~~aet ~frj mr.2da ~7tontairilng A' sr- -,he all,--ys
.)ntairiing chrom'~um have the Q-ane pxopert~~!?S. Th are 4
figares and I table.
ASSOCIATION: Leningradskly politekhnirheskiy Lnstltut (LPningrad Pc '~, y -
te~hn' 'a"
SUBMITTED: Octobq37 19
Carl 212
OBOISUMV, F.D.
--- - ---'o Tne-plece baked molds increase the precision of casting. C lzd. I
WNITOKASH 45:43-54 '58. (KIRA 11:6)
(Irounding)
OBOLSHTSM, F.D.; KALEROV, T.P.
.
Effect of various factors on crack formation In molds during
melting out of patterns. C Izd. j IONITORASH 45:107-111 158.
(Founding) NiRA i1:6)
lot
mh
op -
At
vil.i
ate
in
to
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Ma
ala
,--OBOLENTSEV, Fedor DmitrIyevIchi_GULYAYZV, B.B., doktor tekhn. nauko,
pror,, r6t-se-n-ze-nf; -SOKOLOV, A.N.0 kand. tekhn. nauk, dots., red.;
VAROVETSKAYA, A.I., red. izd-vaj BARDINA, A.A., tekbn. red.
[Quality of cast surfaces] Kaohestvo Utykh pavarkbnostei. Moskva,
Goa. naucbno-tekbn. izd-vo mashinostroit. 3.it-ry,, 1961 181 P:q)
WRA 14.
(Surfaces (Technology)) (Fourding)
I
PHASE I BOOK EXPLOITATION SOV/5458
Girshovich, Naum Grigorlyevich, Doctor of Technical Sciences, Pro-
fessor, ed.
Spravochnik po chugunnomu litlyu (Handbook on Iron Castings) 2d ed.,
rev. and enl. Moscow, Mashgiz, 1961. 800 p. Errata slip Inserted.
16,000 copies printed.
Reviewer: P. P. Berg, Doctor of Technical Sciences, Professor; Ed.:
I. A. Baranov, Engineer; Ed. of Publishing House: T. L. Leykina;
Tech. Ede.: 0. V. Speranskaya and P. S. Frumkin; Managing Ed. for
Literature on Machine-Building Technology (Leningrad Department,
MashgIz); Ye, P. Naturov, Engineer.
PURPOSE: This handbook is Intended for technical personnel at
cast-iron foundries. It may also be of use to skilled workmen
in foundries and students specializing in founding.
COVERAGE: The handbook contains information on basic problems in
the modern manufacture of iron castings. The following are dis-
cussed: the composition and properties of the metal; the making
of molds; special casting methods; the charge preparation; melting
Card-0~1
Handbook on Iron Castings
sov/5458
and modifying the cast iron; pouring, shaking out, and cleaning
of castings; heat-treatment methods; and the inspection and re-
jection of castings. Information on foundry equipment and on
the mechanization of castings production is also presented. The
authors thank Professor P. P. Berg, Doctor of Technical Sciences,
and staff members of the Moostankolit Plant, headed by the chle-t
metallurgist 0. 1. Kletakin, CAndidate of Technical Sciences, for
their assistance. References follow each chapter. There are 287
referenceso mostly Soviet.
TABLE OF CONTENTS:
Foreword [N. G. Girshovich) 3
Ch. I. Composition and Properties of Cast Iron (N. G. Girshovich) 5
1. Equilibrium diagramfolassification, and tne structure
of cast iron 5
2. Effect of various factors on the structure of cast
iron 15
Card -2-/-a1
Handbook on Iron Castings
SOV/5458
3. Casting properties of cast iron and phenomena related
to them 16
4. Mechanical properties of cast iron 24
5. The process, chemical, and physical properties of cast
iron 33
Process properties 33
Chemical properties 33
Physical properties 37
6. Selecting the composition of iron for casting 40
Bibliography
66
Ch. II. Planning the Mold-Production Process 67
1. Principles for selecting the mold-production method (I. A.
Baranov) 67
2. Geometric accuracy of castings and methods of improving
it CF. D. Obolentsev) 70
3. Easj_-mdn--uf4i6turatLl_ity of castings (N. V. Vishnyakov) 75
4. Selecting the position of a casting in the mold (M. M.
Vyshemirokly) 87
Card-a/11,
e "I
-)!~16
report : re3entpd Eit 1.1,e 'c :~e cr.
a t I . e'I sti., s! cr j--ed I r~
ow r-,
KHACHATUROV, S.S.? OBOtITITSOV, F.D.
Producing the bushings of tw-bodri,11 blade rows by casting in
ceramic molds obtained by hot pressin.g. Trudy VIIIIBT no.lit
151-155 165. (KIRA 18*5)
OJ3OlM5FV* N--l- (lbarlkov, Fushkinskiy vllyezd, d.6,kv.6)
Potentiated carebrospiml enesthesia. llov. khir. arkh. no.1:87-95
Ja-F 160. (HIRA 15.-2)
1. Khiruri'aheskoys otdoleniye Kharlkovskoy oblastnoy klinicheskoy
bollnitsy -!~Vtetskaya khirargichaskaya klinbca (zav. - prof.
A.Z.Meyt-~ ) Khartkovskogo m6ditainskogo instituta.
(UINAL VILSTRESU)
OMMMET, N.I.
Significance of autoncmic-rerve block and continuous saturation
of the patient with a mixture of air and ox4ge in spinal aneetheoU.
Xhirurgiia 37 no.076-81 161. (NDA 2414)
1. Is fakulltetakoy khirurgicheskoy kliviki (sav. - profo A*Zo
TseTtlin) Miarlkovskogo meditainakogo instituta. i kkirurgi-
oheakogo otdeleniya lharlkovakoy oblaotnoy klinicheskoy boll-
WAsy kglavMy vrach V.A* Pizhankova)e
(SPINAL ANESTMIA) (MCAL ANESTHMIA)
11 11 41 Is M it a 11 a a 14 b v a " a It tj u 14 IS 66 u ill a 4) 41 a 0 it 0
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ffWj(,ln Wa% tiMd (flifil UtIVAIII. Clltllfiil-~ With 92"; INN),,
washcd with NaOlf, strain-dwil. anti ditiif with C&Clj-
The i*mucric xYlvin-li in the fraction- wvrv dvid. by the
itivituKI tit Titum (C. .4. 14, 2-2,A) fly oxidAticin with alk.
KNIVLO. And ppta. of lizoll slid ,.. ov- And P-11hiltalti.
achiti with H&Clj. Thc ttittative ftult4 ,how that with
increasistig temp. of the pynigenic dirctinigiti. ihealis. anti
-ClAtive percent of m.%ylrnc kicres-e% f idl ill& f
4
filim hicimer lint Stilly, while the contritt-7-11-ilyVicur 10
Phh't (1vcrc*w. The iviont-ritAtion of ".xvient into thi-
toc(is twittict will be 46%.1144t.41 in a tAter paper. C Is
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11-TIM d bK4k.
WMtMWd by 41 dm dool of
d fbe Ortntttd pWj" b. S& -09
sea 123' (w%. trkw). Un 60dowim COMPAL WM
in switc: 2 114fiendbit4l4city":
'
09's Z4mt*jf44qpQff94WMc
M
008 cibirt4-pudeme. Tbassi.aldwadw
008 %V . A. A. PbftwvV
's
doe
004 4*0
sell
8
coo
4100
800
so*
E400
I k A GUALLOWAL LITUATNIff CLASWICATM so*
a.. gag gosiol GO a" all
04 41"noil]
;6
;&;;j a 2
Val ;,l oglin inial Ills-I If" 0 a 9 1 w a 0 a
090
: 0,0000 e0 0
eoo:
to 0 wo 0 0 0 w W, w w- - . b
0 0
?TON-olt 108 101 6e4 !v*411 in a316
a A-f- -A-1-L-WJpL~L9u
60,4
.0490
100.0
sea UA b"111061114610 ld
2 _L I-_I_, i; . - . - -
o4 f 6 6, v-0-m-w w " 0, A- *
NO 911 SAN NO 16041 d 64464
row
MI
I
A
.
.
f
.
004 i A -4
(Mtlkw, " T-A. but*- akai-d by
0*4 '4bysmacts nunif d 4be W40490044 fe"l-Ovatim
098
of 41W OtIdd 0" to oi. at MCCIS ~Clfs 0.5
0r CO, wwiykaa
4 . Tu4seded tin bwp.o got, a# late
saimpk lab.
*A aw um stodw. [Vo.
'040" mw kkwIWAAw we* %ad go ejImI&VA. TWe Uto at liks
00 feldlya moo Swim, 4w q",-- 30
Im'
vvbm
Ow
s.
.
All 01W lowlt Ot"I
~
Utba cauftd). MO. a# wu- I.A.). Th*
M
f~
n
"
a
wq
thwe a"
ow4mqcd
4
W. It""
-0d
-04
"00
goo
Coo
of
WOO
moo
6*0
woo
of) iso
00 0:044:0 0 40 0 9 0 0 40
, 1 -8-4
0 0
do
lei
04
ION
&"New -dwomm
MW IRT IN W raw 4"Jaw
RM an Aeg
AG
9
ODOWITSM', ~R. - D.
"Physical Constants of Components Contaired in the Light Motor Fuel," Gostoptekh-
izdat, Moscow, 1943
*- i ; i ;-i7;-* 4-11 0
t , , I " , t. It -
0 i-C-2
a I . I
mom . I
" tp
M 0 k
'a
a Ill. 1,
I,v s 0 v a I v
Tf a A
I a
a a
P*DC"Sts Age foorgWriss etc
-we
et
m am A eon= CiTALTilf.
Okmos -veSA*& -0" Imp 180,
,
:
on-of MO.& tliw& TW-11"Vol. Ut., 9 boi.~ Iffits WO&PO W.
&dl* Abstres, 40 Apr..lqiy~v. TO*` Dg Orl~wta lav"UsRiko file
pasibility it bydr~b~ hnfift a* 6-amabered
00's Sub= atm,shfifi MW ~dwada-iamjm saulva# a swim or,
as #t
GOVW M~t Wobe at ddqdruplbatt
00-
-_
- - : ~ -:
-
~: ~ ".A6 sp"al,flm IW =it vu made ~:fta
~ -ru-1 Igoe
,
,
_ saktat'st 486mmm" by Qw. 41POSSAU
-
a
i
i
a
Mae
sawt at
11
tilraud ft aw m"m de
w
m
0 b m I" miotsaw- ementm- to armti" W"'
at. Outim &*""Rated ~tl"tl
Ud.b*UW'- ip si'.ddl* C
mpestrw awlys's at' a DMW dMO
saftbuew 0* IN m vat
see
-__M
, jw. lb -F 51-4
.. sp dc At K W At
rqw .4
1
'10 Q ~ we
09-A
At
000
004
oed
I . I
0.0's,
'00.2
60's
04111W
- ~ I - ~ . . & . 4 "2, - - - - 4~-
toooo. 0 vw-w-w-w-w-*-w *-* 4-
11, 1 Is 14 Of a m a to I, POP f : 0 to
4-41
_J",~UAJLAA. YJ ~, "-fFal.U.'t
A,!!! ~04-46_
R. D.. 2.419.0, 0. 10.0, 0-9. all 0.9. 0. 04, sik 0. (k 0A I ik
ch"f Whit 'ILK ll~
(tys, J 146 14.WU 4.7.0.0.2.1,
V.4f,
5
0=38mmmses
1.
1.4. 00 fhV &MdW
dw " -m
Clow.."-A Kmw4*tc &"y4s was canied am of the
much"imm (d.
eo.=I~z 04 Ike pyltdyvk 4 (1) pbome Mv. 11116 1815(IM)) d dKom". We IMIKM md C,,H, is
1,1010 luoppoftfAv. The aktmtdvw wbmw tqvwMN4 (""o"
i (111 Pm IVI 04 tdkl*, f U. 141. w *114.4,141 (111) It4 PRO to lum"1104110" 1#441 liau"Wic am aw
101* f 0 N. 4 137 Ift pWV9W0 fUt-to 3 3 IMU, 14A t(Wit, 1K0 rl"ll 14 th" (411twd (to 2 ways, (1) 1 "Kim* - a
111A, ".' TbV tg*to4 bekwv 0,% con"cakam. % Opouewn. MILIWIl - R%0 + KCI#t*Cllj% - IkH + pbme
r19, U404 pmduc 0) wm-. 1 39.9. MOP. W.1; U tal, (shnibidy game + P%CHIM* firmus rwat)P "a (2) a
111490 70-0. US 14P, 972, W.7. The UqWd products vou. PUOH - H&O + ftCIWPb Sam + c6m (allwasto
4"obved by a wift al ftwic"dow 04 tons. ( -- lume+C0411mempkelf(ORWO). rudwifewom
a Ole w*P elkine toy of iv" c4if's + Co. Tw I" C094 mid POP.
cImc
; 4 ; I 1 411 Ow 404 cm%"Qtm VOIJ46, PiTtAllk R*ft an to %*KOM
I 1 44% ..4 "amt of cjft. Mmv. Impfule *I Ike 441wr t%ftl at =Ib* the IAII or 160 MV4
1 1 R , mae-ciii at el. CON W. Mill, a- IM4 (0911141140 of (Ift fdx*llbl~ PWUS ah Ph + MA)
x4callApill. I-xykttA, JIM. MCOMc, c(ra- and Iftome - Pho + Ice; fimther . ,
ad the Mdi-
Mom. I J. OA. 0. 10-6. cob W=4 Rkle's Kficibe kod to the podsc s wt
i 0,1116 0, 0. 0, 0. 114,41. 0. ZA, 0, &1. 0, 0, 0. 23.0. 11.4; fated. 0- M. KWOPA:r
0 0-114 0. 02.3.1,41.0.7. 40, 0. tfacc-, 31.6,4.1. 1). 0, 8.1.
p lip ir li IV 4i 4 di Im d OR
do ale 0 0 0 a 0000000000,111
A;A a so 0 0 0 0-0 111, 0 0 C&A
00
goo
00
Q10410
a
too
9 of
6o'4
goo
use
0 3 0
0'* 0 p
0000000000*00t: *
0010900000000 ::0
a a c
r*:-'
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F
0
910
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At 1
009
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0 6111;
00.
so
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0 * ,0*00000000000000 0.-0-0 p 0
000900090969996996 000:
f ; 0
a a a 0
!, - - Iff 01 by u
A-A
-
0 I VIA)WItisa".4 '11 '.JMU%A! )to -%)%!Ul AJIftJ!1I
I" off AtIR 9142flut" k! "I J`f-IJ aPsh AH Q& Imn(ij ~4-
'
*
"
-
: .,utldj4
-)qjL '4uTIujdjAq1juqjj-f
, 1mv
;.
,
46 'mtwl-v) %ouri
'
60= zifitoijuMp
'~Iwtuadjo(qlmu-j:
4~1 v-k.j fit -Ajt~ ImnJAJL -1m,1 urn Sm, .-III
00. 1 'Iml r J.-Jr. too 1411. or % 'plmv.
141 U~1~1 -JJJJPI' I`o' 1'-"1 4 '%I%!uJ
to-IjujuipAq ~!Amu(n! Airsims V)Swa$VA* Iu4uDdux),-aAM
00.1 axAivtjv us j?p'%w1 if sallew 1914pus lI3"j)lq A(I -011 31119
-iijili 1"m -Iwm 4ija q*qtA -pahwjax
-m"1 I"'J'As' "i"'s V
0. ! 1
) pololdo. y 'Aam"14410 'it poly
W#V
.
trio, GossAm-
ov F If
a Q a a 4 a
too a a
0 0 0 0 0 0 0 0000
lot 90
00
p 00
0 00
J, 00
Do
00
00
001
A!
&i
~
00 a
00
00-9
a
,0,e
pit
wo 'Vito%_
J-At,
-P
I
lowflikowlian of oulfull -centakung; Sato,
064c"t,cwt. J.
t9,SJ14l`ptT1$("7f""ft-ftww)-
In high (0.441%) $. law-lawrifone ccwlc rponlitle, sulfunic
A" wad Vulfilew, Inurtmord toy forAtillrut with catied. fit-
SO,, MCI! 446 IWAting 11,011 litS, 1140('411fill", Lml (org.
.441114114`%. dkMfl - Coll. f- Mk, Alki " + 3
C110-ell.101 3 Cllt.Cll. 4 ;1 11,40 1 1%; lht uilk(A-
linunditwolm It lit ttv"ifirflut v III, I licit Ninalml Ily It%
wollmiliin 1., 11.4. In dw 1"Invinit in-Imin lViv%eltitlit Alu'vt
;M%)*. JIW jrlin-6.111 I, CAttilliff-I by FC. Ailing I'll 4 .1;
f t, Fo's PC + HA - UO-S + 11, afkl FO; + RCII#-Cll.R
11tW+ kCti:Clik I- Fe. The o"fivrins ructiturn avul
the lxeicuct tol HA. lit thr high tt;np,, lorated Fe ag.tinst
4
1 wortAUCK CAIWAille COfItg. W.74~~ P21AMMI, 29.1% CYCIG
Ifi.27t. artlinfiffic cowingids.p 0.414i]~c S (of whkh
INS 1140'
mirin-alit.4tis 13.7, disnifitle, 15.9. &ulfides 6.73,
elesnoulAry 31.9). sulfanAt"I with
I.,5r; ,I ill 4m vin'. untlegZA) atin..
Ito, 3 hr%., at A Fair til Coo) twit.. hr., re-ultrii. drioemlins on
Will,
-- ;
0 0 0 0
.00
1011111
'00
109
4-0,111v in, I'leill flu." -00
It". living nult-filirl" if V,iff I"'lly lic (Illitice F
"Alk-i 1-1 OAVIW; wY W; USAI. .11111 11 11 1111115'
.1th
' 0e
,
"
, )VA), Cir-icking 04 life wall'"tifed. fitati-trillp
dir
.
g4millne yidded 114)"l :.,I fl I
4
44
. 49
against HAAr-, in st-ladifil ligh -4cking. tfic,try
i
Winctl CII.Cli:Clfv 13.4. Clljf
ClIXILCI1,43, (Clj
C:.
)
&
,
CH, 1A 1111, 111, W1, 20.0. CH.Cilicil, 19
2
lut
""
.
,
e
13-M. Cello 4.8, Clit;CH-01:01, 0.4. IWS #).:I, l1,
tnd thwas cialwaituir-o d vainAlik clicno raw 1111ACCIli4f, Ti
rtCVAtiOn 44 thV t
t
W
A[W no. I% title (lowly lit Vinnin~1,4-111 of
nA W an in 41
co-ir An U11-1,11. ,vmq.j..
I ZOO
MOO
WOO
it
of COR
Oo 0 0 0 0
A
oo 4
00 a
a
v wAr "OUP441 ISIS*
0 L, , 1,
e v 09 IL- I
Isis
W"
Me
t
INK
00
*at"
I it
o0 v
fro," t A
l,
00 Isla. colmO
%p4- Nam, cmttkt.
1
col
" q., h,
isith With t A 111'"t
ti
00' ati,j %,. A
it till%
-"
ct
d
Ttm
'a WWI
act
-A
it C
Wait
j till
.
;
jJK
w
A
jag a
090 000
-00
zoo
zoo
see
40 0
use
wee
see
0 a
Ir S
0 49 0
1*** 60666060 -
0. 0 * 0 see*-* 000.
A r A 0 R M I
of r
00-4
00
2
v
:: :11
00 a
00
00
00
00
00 11
-s,
o
FIV43 M
rt -I~W
I 0;d_m_x_Qe L.
4.9 f,#~Jsj -04
*0 0
'00
ve
=00
r* 0
re 0
rip 0
" an umAid. hydratarbon, the Yielil i", M-11
the AMI, of [be JAJJCf, rfUjItAllaCtiflot the t%ma- lu.ma A
with
f
Aft'.
(;M, (C.A. ST. M7-) ofm lowerittigJ thedexr- -o
ontjUtiM of glipl-tiC hydg__jxXL1j With JIUIVA,11149 ""I-
t4mt of oututd. CGMP&. Qbkgful Alld MitlifirMOVi It ""
.
I
t
l.
NC
M
the wboje tome abundant with uflAtd. t
chain and the bighrr t1wat-4- wt .;
h
I Z
e
t
a W"
trom 1,114. C4
1
; OO
1 11411 s
xts,
los
to-
-16
e
io
h
fi
t
.,
e puir
ut
x t
cootal)Ns,
1'
V ON)% I" t1m tstlary
12'
IV 70
.
,
,
Inixts., I was appt"s- midwky fjOwmis the mupekselsts.
'
N
Mat
__ one
r
a guy 4d a* at bkwy Oww" of
hTobv%Nboomos to womadmNost am a dw
:=ie U. R. D. (11POICOAminrand Von. N. Umv ($us-
CAM. (USS.R.) IT. M7-
ON0947)(im Rtmism) : d. C.A. 41. law-Time ykl&
at siommmic campdot. othtalmed evotor a Cr catallost at 4110',
val. rate 04. duration, of rums " molim.. wee detd. (a
a-beqUite ( 60actsm (a). 1-beptem M.
711.V), (Y). and Im
bimmy mdft. thwed. To emwo do comowdgkT.
the Cabapt WAS 4tCtjVAtcfI [it an air struns 4-5 hors,
tamforte OKk Wf" Alid 1-1.3 bg*. After each Full and JeSted
ve-th 0-horptatte under the standArd coatlition,4 adopted;
irre, to poietanius hAvius tkcn tAmemed in reutioutto
with amatol. b1drocarbmas (not with "td.
Ch"ged when necessary.
to proomd U-12 tain. (14-2.0 cc. by&(),-
bprfQn the products were collected. With
the Me comlods.. the bdam. (wi, %, mp.. of liquid-
cme acid "a, and of arismAtics. uwfisi%A. atul ptraf.
tom livid) .: 184.2. 7,0. 8J, 12-4). 11.7. 4-0.2;
".2. 10.4; IV 69-8. 9.11. M.S. 30J, 64.6. 3.1; V 08.5
10.3. 21.0. 32.3. N.0. 8.5. UMSAtd. hydfOCACIMM giT4'C'
!~Ioer ywMs uf Arommilics In the binary
oo". 170 + IV M. I &I + IV M 170 F IU if), I fit) +
m W. 1 70 + V ti, I so + V w, h 70 + IV &1. 11.01 +
IV su A 70 + U; U m + 11161). U 70 + V a), 11 'A) +
V50. 710 + 130. U25 + 1 15, the yieksol aromatics
_,,!!~ftj1r1C,_VAdditiVC:
I - - - . ~ - I- __ - .I - -
ETALLURIGILAL LITINAtOf CLOSIFICAT"
4o~
0,
ow
01, U it I
0 0
41 e1i 0 0 0
... dad..
L I a 0
It as I a a 3,
0 om 0 0 0 0 0 0 40 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 IS 0 0 0 0
?2m#Lu sap ffffm
-
-
hd-
d
6 apood"m ~ w , SO 10
tj
j
=
iwd A. V. Nioll.
A
A &musk k
t!Vil VW T MOM -
dand" od~mw left q
ik am. 4t
w6w sow.
f%.m
sip) -s
saw = is do
in the
?be fatle mav~w)~= A@
W &W mce but
vow-A as the
6i6*-* bit cc a._
Awn In comfookm
ow dm cwkv. Cie W.
-3mw ado-. PX
-00
.00
as
go
NO
O;i~NTM, R. D.
pro"Cdeit of chroml
^oatedyng. 061111
entsev Pr rm
KixeUk
A
W
ii
a
:z5.Ax=.1VmuX
y
lmm.-w-oa CrIor. at 4w*, under 10 atm. of 11L fit
elocity of 0.2 L/I. cawyst/hr.. the carnim of the
tion of a cmkittg amlitte. originally 54 unatd..
ms
4
23
2S
attd45 the o
t
ne
l
f
S c
a
p.,
no. arapped on
,
rom
,
.
y
72 to 70. !Tlwltb HtSO4) of the uum(d. cmpdm.
8 NO- -6r (Itte and the
and the a natics from both the odginal gaso
'
Feb4. 45 :1954 catalytmte, the aniline paints of the remidulug pacatlins
wire, resp.. 67.8 and 69.7% and the.% paints, resp., 141A
Organic Chadatry; and 152.0'. These chanavs lead to the conclusion thett the
hydrugenaflati has-resulted In an IsontedrAtion of aliphatic
hydrocarbons to Zinethylpentane (a the amt. of
However. a sise of the anillne point of the hydrogealrAte
is not always due to an Isomerization of ituaffins. A (mc-
01'
b
6
d
fl
h
-1
on
an a c
. 9
. passe
romailuminasilicate cat&-
lyst at 4601 at a sp=e veloc(ty of 1. utider 40 atm, 1(g,
ham the cctupn. methy1cyclah"Ane 63, methyl-
hexanes 15, and heptine 22%. aniline point 61.4'. to a
compfi* 13 aminatics. 52 methy1cyclahenne, he tan" 35%.
I'
anil paraffinic residue 52A*; In
ls Instance.
the t. far" 1. Consisted essentially of an Umatizatio";
of na
llleg,
td, "' ""ho"t Sir
Thi
t th
oil It
s t
e
y
,
~
tin, t will (th F~dt
re 1. P~' 'Ith out
e~
e,
that a cousIderahte degree of can be it6W
at low-teurps., LCMtrary. (it widW-%nd-
cow am
Aug. The product COMVU, M
ive to veto
aromatics relat
a-6: I a 1.81
testalyzate) was. at 4SU*. o4lam "tocit
2.0; at 5100, spowe velodty 0.6:7 0.1
0.6:7 4.0 Igo
On the ione catalot. 2,3k-trinteth
Id iise
be aromatized with rdatively little ormatim rof colz and
-73. 15. 12. 4.0. 5.0; at 5WO, 1 -5:
gas; at 610'. 0A. 74,21,
7.0, tO.C. In the dehydrogenatlon of butanes wM CrA
on altualtia, a significant amt, of lsomcrizatton (16-23A)
accumpanies the main rWtWQ' EXAM I I a
cuours(cul, - fo'C41fm Ut ti Cit
leact.
'Itat PASSM, 'Q Q11% 6C t. e4ift. Ift-WhIfe, reactant
83.5.0.7;
13.~. 77.2. At hIgtmr temps. the Isamerization mctloiss
QLPpear to Wroc'the formation of fittle-brarwhed cc stoaght-
chain alkanes. sit kt rate comparable to that of the- main
aromatization. at dehydrogenation reactiom. The Imu-
crization can he coucelved its the tviult of deby Mt..
don with cyclitattott. fall4u:ed by ~",r
h,,tr,,&aJ(on t(je
Cy'do to it FAVAlt. ~ It I's tltj(~Wwthy that Its 6e aromatiza-
'dact of t. om could find In the Products fliplawt Amts. 61
2,3,4-trfiuethytXpentene~ hat no 2.2,4-trintethyl-4-pentede.
Omsequently. CH, and CIT groups ace (lehydrogented
more easily than ClIt. There 14 an, aamlstaWle analogy
between the catalytic actions ol Cr,04 3ad AM#.
J.
clentsev) 1). "'2he Irn ~n.
7cs.
91 9 L, c ~1'3 !,c n '--i~~Lrnal In 1:1.
OBOT '-",'TTSFV. R. D.
~bolgntgev, R, Di, "'-he pyrolyn' -s rif 3-methyl pentane at EltmOf,.TlhcriC iresr-ure," Uchen.
- ~f -1 - ,,
zapiski (SnT',It. ;;'OR. un-t irs. Chprnyrhevs,-7o~O)', Vol. Y-TI, ,ryT-. vhlm- 7.. - -
- Bibl i,)P: P. ir)6
SO: U-11031", 2) 00t 5", UetoT,-is lZhurnil 'nykh Otntey, I-To. 16, 19,9;.
OB C71i rT F.3217 R. 1).
Obolentsev, R, "On thr, studv of th compositi n of1centers of etor,~ti-nl of low-or-truze
gp-Aoline, as applied in th~, icomr-rizi,tion of j! rrffin-rip.'r h then r- 1; i *,, t7lrl-s , " U-:, f-- a .
zapisl~-i (S.,,rat. gop un-t im. Cheryshevs~ozo) Vol. JX, vy;. kh-7.., p. 1~77-1-, -
Eibliog: 14 items
SO: U-IjQII. 29 Oct :~q, ~jetoiis 'Lhurn.-,l I.-. k1i -t -,ey, No. 1c, IgLq),
(')B0IF,-?TSFV, P. D.
Obolentogy, R. D.- 110n #.hn, ,f 'xyIene' concentr!:i-ioa in rurifled
oil' resultinF from T-yrolysis, " Uchen. 7.~ F isi-i (S~ reLt. i:-P. an-t lm- ~h~ rnyshpvp:-o,-c,,
Vol. XXI, vyp. IChim. , 1919, - . 119-27, - BibI iog: 7 items
SO: U-Lqqb, 21, C,ct --j, (Leto-pis 'ZhurrvLl 'nilch ~'t- t-y, No. 1 -, 19;.9).
(-,BOLF,ITTS7V, R. D.
Obolentsev, R, D.- "The stal-ilization of only I,nrtially ?:ydrvtec c,..r-.uretc;T motor fuels,"
Uchen. 7-)riski (S-t. iron. ur.-t i:;. Ch-r-nyshevs~-o.1,o), T,'. X71, vyp. 1~ ~, .: .-~ -, 1.
- Biblinp:: 7 items
SO: U- Q'II;, -Q Oct ~!, (LetOT)iS '~-hurn-l 'ny~-h "L-Lfly. NO. L~, 1'--49).
OBOL7'TTc)SV, R. D.
Obolent-tev, R. D,and KuvahinovR, 'T. 11. "The catalytic -~~racldn - of h,,,r-racr rltonc.
Cracking, in th- presence oil ~alumlnoeilivlte -r!tP1,7zer, or polymers. ;-rocucec by
phosphoric acid polyn-ri-ti n of butr~ne-butylene and penta-i-mylene fractions," Uchei~.
zapisn (Sarat. eor. un-t Im. Chernyshevsko,~o), Vol. XX:, vYP. khim., lc)4q. -, , i. L-~ .-
Biblio!~: p. 153
SO: 2n Oct 5-1, (Letoris ',--urn- 1 1 rvkh Sv tey, . 191 Co .
so
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71nia): cf
Vf"Y* Z,$Okq of
".1ralop
.
.
.
"KMONON" M. u6tAttrif for
$*I lit" " on Wt ACIV- 44419M f.Wt6LMJ
vroge lltd AWS.41"I lii-lit. 14 fill' fFAVtkIl6 11. 173 40%
11
ckatA"Ctileqt by 4
O.W13, qW, I.M44. flow. wt. Ill.".
mt no. M, Solid con.ist Ing 4 it mixt, of (.) 22.4.6.6-pentA.
wul I&), 14MIM pcmtfwf- 1 .16 mid itt'.1 4 g,a-m) ol..A, So--- ..0o
Its file rAtito h"'Ir.4.1404 tol-1.1 - . . f.
-Aiv
~0 44A. %.kvtt~j tilitel A wttlu .41 fit"
tit Itle .Jl~ Ill. -, fill' fh Ill. L.'I J411HIl.
"
UJUCHIMKIWAIC vow-loind "1.41ySt. no 411frooryfil SI&SAV vehod.- I'lle
IkKkAl Ill it. Allil 1"111114- kl.AlhNL&fV 49 w
L'L CAtAlywhir.. gr 0" lattalks/l. catAlyst/lor. curve. age well f,fullred I'v tht- i,,pI_14xI jor 'j,
11---pitil Of I'MIAlkVS. hS OCItIl. Of 41 -f1CtiI4X4%" tittle lit jjz% Wills h - 1 11-4. ..11,1 1 AN it ;1M%7 . AM
custact. Ile. titelf 10,I14NO .4 five 411tv tittle 4.6 C'MI.V1 '.logo 6, 1 1 '1, .4".1 -11 .1. 1-1, , .11.1 0 - 2 As
,
T To 0": no its ituile.. tell I 1W iNNI'l A, 6.11tow. Aftliefflits
VIJIIAI~otl
or
/Cattle I ju*~Ilo 41-73. .4 [Ali pto- . A Iiiii-r t.1w loam 4 1 1. givi.od An ArtIV416.1
With Wig
pyletw t 1.44tylvow.. ethylefle. It,, suite (4 SAM. hytt"o. ftud,- l1loglWO V.111se. soft arceAttAtittif
i
C&$bUus) ir.1111. J. 4. MO. to.to. 4 - 4; wt. ,at, Of 114ttiM 114`41lftlet., at 307', At oxthwh temlo.. 37. 1 AM lower, the yirll
6
d hwo, nAe and tat. kaws. Sts.$, 1_14I.ji.
f 'tit iiSSIMOVIelle IMIS.4, .4 file I
(
J7
jAme antler. at
to is. 1.
At "Id&-, itichigott-i
ctuilor 1 6.4~1. 04. .1faiffeil At . - 41 If 40.11, ie I.MCt thdol
W - V, M.4. x - JI.toot (W8.4. 0.6. 41.fo. 41 (1
4.111, of 1. - 4121 1 lw,lomlotl .4 the e.g. V-Aiw% Not 11111,
,
43.1. ItS.A. At NO% 41,11, r, - 81 d. T With site ietitlo. Ait.1 fill .; wills rt-itt6 lemp.. the amt. on
-
O.W., (94.9, 5.1. t0.11, 41.41. 11.1)), 3.,1. tjutykrttif~.. tiwtrac, ."nentut. Still. hyde,wArlitict. Ifl,
a 0
18. V, - 26.9. x - 1.441 045.7. 1.3, 0.11. om. 0m), X1.0, did! &fill. (11 4-5',it Wt-CC ittlCrt"I Mily In "InA At ;.Nkb',
33.6, 4.43. 7-0. w - MNI. r' - r - it #I
t with CH. its Ow Aml. 2.5-3.A, ~. the ICA C.11. .,.I C.M.
0,0. 0.0, ioAl) .
111,2, 3-8. 141.10. At .107'. w - 'the 144714 Of 10141fif tti'llollit'll IS I1ldhV%I At 1%11'. 146"exi do
0. 9, :6 37.4. N
T tit jocti. Iva, it it. to 1). if Ili. u4$. 4, .ds 4.
: - ;%;'; IIWV Atv V19V vi- at *it ~ %I( AIIJ1911% to 1, 41 1---
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htdkvr. Will. rwt, I-e- 44 cy. Cie. lots,
of If 9 tvftlp~ Al"I w I I
I h '""ftsind op. I he V"l
,IIVAG ACUI 141 Ittv %411tr liffto that Is# 'W's,
k ft, "he M'ce- gwmlgkftl is acs 'k.
at lwl-ajo- ORIAlLst MAUlly tj Irm"IsAlks" (it
the mten" pnkjuc,,I at M.,
fail in t1w r
Ir- buAtis-l"No. I lie vk 4act IjIM-1,V
Val lillk *Jill . 1, lif of brojeft
307 % dial. . if.-q-fraw - I. at akl~.Vqr,
at Ih4l tettip. ,kJ "ilk Ow W
_ 4, it Its
I'll-tug fist "r t W 11.7411%.
is"It"ller And tof Iitwr,
"'e'llfust'rAt"I ily Jim
O&W. cif'. O"k"tI7 ciffs C.11-- it --r.1 C
ill Amu.. . - , . . - .1X -- .
41-11. 41wil I - . -Mj.i-A*wf;
41111A. '. tam 1,26.
Its
Ui3kA. IAI Ji.
Its Alkl.
MAWL491Y. Now 4.
amirl"te which. its vww 4 the pirewtur ut belstrues. t-
Ilk-AL"t UI-%O -- .4 11--1411-11 141-11114 -4 1, fttAf it 1. 11114
Imm-111'al.:wl .111cif,
11W Mot( 1-1- i.htwe fe-11-1 ..Iwtte
I into 11 111, d ... 1- uts'Wig.a.111 furtherds-i-Isr.
l1wfistAli-141 till'. It I'lle 1.11..$ .1q, 1. fiN lite du.
m4m~lk~w -141srm. ..% 041,4r.f
11,W4,1116 1.1(w) lcaw,
"ollifectiql, Alm., of dalm-1 wltwls I. tMOV
ACT WTV11111g. EVU144111st. Imeth thC 01) MUI 0110
(01) WMICIM C4t1 11114kCIC11 &JUJI VIISC91SAI NMI. H. ill Act"-
f1wil with list I list, &.1 #,1 1-m-1114tims
(..I Jill.. till. IIW I,.) jfjrtj~f 0.9
a IN,
twp(rsw. wilh mfl~jtsvlst I,v the 'hisslac
igwul. uc lms,r arlitch .11~13-
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Cf69WA eta tt
d9shak "14 7 -.1 hmdca~ add tme 4
'Jumim= 61tior X..v L)bqkWmv-, J. Ap
Chm. U.S.S.R. U. 120-1332(i95OXEw. USUSJMW614~!
U%e C.A. 0. 44&b. 5, R.
Cteddft of ethyl AC4114te ea 1114 d=id~WWA(*~~re.
,, (
It. I). 4*K4vttt*rv Aful Via, N V.8le C ev
S. ft.
114W A k44. Vdalk S.S *
11. 4M VVIOS(l) I cf. C.A. 4J. I-Voth. - Clitadittattes of 4
tillefs. coal") -self 41 Poo" ilh A mil, of 1 1, Artlipt 11.
raffalywhr . Im ."'in . 4 C". C'. 0). will V- into.. I"J. , -
as a she folloonix 1,1101111.1, 1 "1 fliv~Itimalmill: frortion oil
tqa~,-O% sileCto (itictatirml f.v Ciff. t-t wmi mam the 2.4-
diU"hmYlhY,lr4--(#C)' 711 JCI*, us"I"'Anvil. Acopt;
.._ , too allitall Im atialy,i.; 1117, - I IS% utandy AOII a
M- IfIT.
6dentifittl as Ac('Ax) No &Wthyttm acre foutt4l. At
AcOlit Willy usuiergoes caltmalytic 41ccompa. The
CCh wkkh adtar IAross i~ prolmatly a lwodurt of "Iadej'y
,arjoin, if. lFfstal A, 4 M undr, file effect of Alumi-ilk'ate-
,rbe Kbeffm 2CI1,C(.&,['.t - 2C16:011 a- 2CH-CO'll -_
C(h + Ill() + (CI(O'CO i% potulated. it 'lifflers (Tom (tit
whegue Us set"Iervu. 1C.A. 2. for .11^ ratialyst.
Whm AMY vtaa~ t-witird ul"IM thc' stunt cor"litio"s- the
WUMIUCt (by v(4.1 WIL4 CO. 73.5-
C 114 (1 fl, iL.(, C It. it); Cilia And X.C.U.. I
H, 114111M much Melco
Via- liquoll tn"ith" I Vm
("'"I ahkIl -olit 14 119, KAW.M1, 14,0111, f~. msch A.
age likely forl"cel to, and I . olitaincwt flit ~Atflv 14(01184 f -
(rotot AcOll a- dW it ith AIP, AM
lKit lite fulmiglaNI .1.14. Inosill". Olifferetf; % 'altAin"I ('0
411.1 lilt ow-C'll., ohil" (I. Allis V. foutill i-f-C411. llowl o'.
It noill be &MU911"t (ItAt flit dminlini. 4 AtfiCt ni-to At (a
Io'11-41% fly 111C . lojfj~ t,141)11~folj bw 10,01
AtOll (over Ali(). ft, C(1,. 4,01 11,41
H*et%%St Was alml Crafritt'! tot dIomljn~iliLA#*. do's in) 041
fVQM IlAik take. Witjj.W~_ (fly at ,,ni
durstiam of 5 jars. st 1gj '
_2101), And #; hr.. At !M01" thr .'1h1
products were cluarvacterized maw, falln- frnoi alurim-
Silicate. sallow. no. 98.9, acid tin. 412. 1. ~frr Im 21I.S. lit n..
M. m. .37-4 V; (fain clay. the iwrestomidiiiag run. are :41, 4,
:0.5. 12.9, 12. 47-324% thaw 'd low 'Wiclivaj titermrat. 104 1.
inl. 84.0. 1. 63 49'. Va gas 'Ittring the fraclioll,
halt in the atm. of the app. aA, fotsotl 09". C(h finvass
aftiminalitilicaste floss t.6r; CO. (rtwn Oay. (if the esters in a
the arax tlot-M,-' driven[.]., prolWily it, (-oo.
vittsilm to acidt aM uii--.tttl. hydrovarlion. and (2) tit-
mboxytiation at the swil .=4 livilrncrttalumi 4 the uniatil
hydrucalma. Matly Of Ot All-, of the A A% ~Vvl to he !c-.
hy,frated in the proces,. Kifty [.If,
CA
ummmy.diled. Vm* S.S.S.R. 73. 1211-40941111).-fe'l
sm"Glom at mw (nom welocitim04-41A I./I. catelywoU
l1r) do* No 4w, (10-11100 100-ftft (11
fec" commietiag maidy d C^ wid
man mizi.: at SWO. there in am somme meet. W
cu" - wills clim comenct tim v (we w 44 Vol,
% . at 400-W* the so bk6wm a= arm
&,csfu U. md cju or
, , comesis own"V C614. md
k0. unaided (by addatiet " maimir a
L . ",go -
of 1j4im-Ffw4% ad 114 (ho.429" IS the
"an 1:2. comm"motty, the main comain (a) 1
Cjfo + C~% a somimpoded by a dimmobstims t"c"
(b) 2 1 ~ C41f. + The now of W do,
t1wom" Milk Ow temp- amt "(sh r, T1w Mabot amt.
of
V41 IOMI tAV NVACOM ~0 WrOld SLI% 40 4110 tOW C6114
tie km"t to 2% (at W). TIN Can Q1 do
4_6=1_ Is scot 4mmilmilik by amy chalk Umak
On, bwawt*dmmdmdbvlmlD/(D -all -*0,
u4me --"A. *.ee al! dmiurywims, in %. at the
Glen, Coup.. it - oboaTC41 dcom 41 dralkywim; r -
comfort time in me. The PW~CM 4 md & Me Mated
ft tOW faft or by v - (100 - JjoW -8. ~
dwilmletim as tin amw r owemod in % the eMs.
D at ow shom later. KEP&L somorim
at 390% So. 0.483. OW 0.7n;
at 4320. W. 40.4. "A tie.
as a tviedickm of r at 4w sad me ham a
-y shorp at 460* At 360' tlim
mdur at am M,wU= b dow to 6iZi- (b -~, U&
t-D. d medesce of a and 6 is an omM 374 X
.4L r , Ig kbv4
10184 bm3ft6e-MAw1 Islawastfoccom-
cqm d 4's , -c . Is WkfW
coodkiwastd vols. lbe .1
lw~ceropwmmmw cata
llw wave iatmovesiflago 604M tw 0 let -.04" at
00% soralially at The 12m1 mter at 49NO-4 **I'd t1w ZM4
or at k4w mxdy of lbe 3rd onlor at SW . N. Tbm
.11MOV
% - %
At". Nss* X-S-S~R- 73.3110-=
(11"0. -The (alto-sing A" the material botAncrit (temp..
Wt. ';' g-. catalyrAte, coke) alwained in dew runs at I
I. CAIAIY%t (%Y1jjjWtt~ At qili4rMte) ht. lQhyjr~ Xjy_j
44M..
A; 340W. 3.1~1'
14, tal 7. AS, 11111'. 11:4. ".It, A.7; dimAttv 4 111) mu -'
44k"*J(IA,5I,X, 121,11; c1hyfrmaivul 4v~
'00". 16 2, A4.0. 29 S. Vicht- 4 th~ pirmfuct. , I,, ttk-
or-ler 11, 11,411, 111, IV, C.11,. AcOll. AM, If,, Co. Cit
c4h) in malvit/1101 nio" Initial rat"P.L. wt-tv: I (:I1'1W*1'
2 5, 70.0, 411-11. 4.5. 23, 0.2'. 2.0, 0.3. 112, 1
I
14-101 -A, A1.3, :11 7. 14A. O.S. 0.9, 14 4. 1 .,'1, 1.2. 1) X.
W7: (215AV) -, :00M). 0.7. 13.3. 0J. 0.1. 12.0, 2.1-1. --,
M(N)") ---, CIA. 11.9. 11.9. 4.5. 2.o. T7.7, 11.3,
1.4; MUD') -. K4.2. ;W-2. 0.3. 111.11. 1.3, 33.0.
10.2. 0A, 41.4. 0.4; (41W) --, 714.14 Is.S. 10.2, 13.5. 4.1.
17.3, 41.411, 0-41,41.411, 0.2; 111 CON)'i -. -. -, 19.3.0.5.
P4.411. "If. 2 .1%. IIIJ4, '21.5. 4).7; IV AM)*) . -. IV.". - -.
:011-4. 12-4. ZIA. 4.1. 1 11. -, it. 4-9. The dAta suljmtmutijs~
the rraction wiltrute
4wil,
'Col:C11, 'q Wit. A-4111 I C-It-
~t'k r'-.4ctt0M
~WtWIIW ATC 11W
it if AvII Into Cit. A11-1 4:4).
' I- lion of it,, w. Ttw
Cull, 1 '4VOINK KIUA ."
111 mind I "MAt-1 fit I ."d It -1v -01, th~ t1nij,
In contrAlt 10 Vtil*evl N. OvitAll ,f1,1 Knkh.r,1u-&vn
C..I. 44. l(rjUA) no III W4* f0lill't '11 (hv iff"Attell 14 11
It LNwr only amts. A Acil. N Thm
OwIMITSEV, R. D.
nA
U
-4-
KhM&A of doolkylaum of worm" Wmvus on to 4dum.
CRWkQ:lV-,&VAl %' %* (-fyJkfev
1
L G'iro. t-4m, '11, 043 AOMMI~Vtldl
CA O.T." It 14
omatization
*try Ar~~
Convftsion of Hydrocarbons in the Presence of 0*ide
~
C~ata4it o". III - The Role of Separate Convexs ions'
in tho Aromatization of Paraffinic ard rolef inic R_vdro-
carbons over Chromium Catalysts," R. D. Obolenttiv,
,'IYu. 1~~Usov,S'Chaix of Chem Conversion of Fettoleu,m
ana ML~, saritov State U imeni 1. G. Chernyshevskly,
"Zh* Obahch Khim" Vol XXI, No 8, pp 1438-~L4*;-1-z*!
ArOfttized n-heptane (I) and 2-methylhexene-2 (11),
aver ar catalyst at 4&01C to form aronwtica, coke
it"i, with olefins (from I) and paraff irs. (from 11.)
oaucts. Only I has induction Deriod. .9 e-~~'
,of 11 is, close to, type.. -.7ound eq,
Deli' try - Arowtization (costa)
44Vftdei*ce of aromatic formation on contact time.
A*t Vt 92 evolved confirmed simi2arity between Cr
iiA,Alimilnosilicate catalysts. Showed dependence
of set reacti 6na of conversion of 2,2,k-trimet1,W1_
jj~e, hepten6-1, I., and n on temp in limits,
450-5100 and calcd corr activation energies and.
t4~*,toeffs of reaction rates.
E-
Synthetic Elastowers
leftversion of Olefinic Hydrocarbons in the PM-
aim,61 'of Metal silicate ~ Catalysts. 111. Convq*~;
iiai of Certain Unsaturated Hydrocarbons
4"iernary Carbon Atom'on an Aluminwilicate
Ci*tlyst," P. D. Obclentsev, N. N. Gry&2eV, Set
Inst Chem, Saratov State U Imeni N. G.
=
nyahevs.kiy
:.,%h4r Obshch ?3%ImP Vol XXI, Wo 9, pp 1588-1602.
J&istigated for the lot time conversion of 34~'
:Alii~uteue-l (I), 4,4-dimethylpettene-1
VW/Chemistry -'Liquid Fuels (Contd)
-2,3,o.3-trimethylbutene (T-11) over alumiadsilicat6-1
t at 300-4560C. Basic formm of ConversIOW
mproportionation of R,.poI$wrIz&iion,
~Iaboi~rization, coke-formtion. DecaTnof
*i4;,,Very probably 2,4,4-triwthyIp6ntene-2*dib;
of the tne (CE3)3C-CR%,CR2, vhere A
.6,r 013) is explained by ifitermediate rormation,.~,,,;
-'~fli.-iembered rings according to schemelproposl"`.'.~,
S. V. Lebedev for depolvoArization of dec6ne'O
try - Petroleum ftt 51
rsion of Rydrocartons in the Presence of
oxide Catalysts. IV. Dehydrogenation of Butanes
Ov*r Chromitm Cstal~mt.." R. D. Obolentsev; K. A.
yetolk inins, Ye. V. Skvortsovs, Students, Chair of
ChmTrocessing ~f Petroleum and, Cases.. Sarstov
State U Imeni. N. G. ChemshevskiY
,w.*A.mr mahch xhW Vol M, 19,: 10, pp 1800-,1806
;Dv*ft,ogen&tiOn of n-butane and, iodbutane at
t"p~ in 500-550o C temp, range over Cr catalyst
prepk by coppta of Al, Cr hydroxiden yielded
Petroleum (Coutd) O~t' 51
butenes, isobuterig, probed that Cr cat"t,
bas good isomerizing properties. Proposed eq*';0r'
dopaiAence of extent and rate of debydrogenatIca
'Of'0.1butane and isobutane on time of contact ak"
at vhich temp reaction has induction pe*1.09.
Iscomization capactity of Cr catalyst makes
I..' 110virington, R. Rideal, and S. Te. Raft's aro-
Mativation scheme doubtful.
21~ckt 51
"Transformation of Eaters Under the Influence or
Aluninosilicates," R. D. Obolentsev, Yu. N. Usovp
X. G. Voyakovskays, Saratov State U imeni 1. G.
MiernythevokLy
w
Dok Ak Nauk $=I' Vol 1=, No 6, pp 889-892
Natural clays act an catalysts in a vay sixi'lar,to
oluminosi3lcates on the following esters: ethyl
iormie, ethyl acetate, ethyl benzoate, methyl
benzoate, and isoaqrl acetate, transforming then In
Wt into wlmtd hydrocarbow. Traneformationi of'
this tnv under the catalytic action of clay and
the effect of high temps may bave played a role
,in the formation of natural petroleum occurrences.
Balanow al. the expts. am =Wyst A.. 580'. $p
dmom is add lite%
CILt&17*jrkr
I
A
.
.
..
312 = 37X d. Mg- *W d p,'16~
Mz fesdat- ZCX W.S. ica.
CH
57
1
IOTJ
0
6
ff
C
BE~ 15
M 183
CJ4 151
Chamicalw"Abst, .
.
.
.
.
.
.
,
.
'13A CtfXd 3.0. Cgth 4A, CJfa IOA. XCOo 2.8. Cjfs 4
L,% reacted to XC
3
W
W 216
11
t
MaH
At: NO
Vol* .
a
. nto
I
.
cm *
,
.
1914
rob 25 17. to ZCv + Cs 15. to amatko & (M A W, 1
23 111,13.5. U.3,14,
52 0, 10 7. 37.3; 1103. 23.9 1
orii"do cm
#417
67.0. a .5.5-0.4-8,281; 14.3%.G; OIEQ
ILIOO 3 116, 24A - 63.0 U.T. a5A. 112, 82, 10, ff
4.2.~53 2.0.2.4.6.4.114. 10.14,
59.5:1W.6.70A.Ek
.
(IV) S. MO 3 30- 21A. 743, 44.29S. 22.1. 10A,
22.0. - - 10.0 74- 8; (V)
34
11.7. IW; 19. 31.13.
2A - - 7 1 SO- - - W; (VM
'
i BA ~2 i4
'510 .90, Ii.g. h.f. 12
4 The
0.0,
t
&
I
h~ IG
m wt. age.
U vm
,c%
t
matics 20-0. satd. NVA 3.0; T y9
-4. 12.2-~ (W) 90A. 1046 AO
8". 15W."O.O; 03A. S.D. S.0.
up_ rA
cto Ps wo, ff# do CJ 1.41 C&I
ZC (U) 6
ON 3. Isi Is. 22~ Is. 1.7.
14. ".9 2AW. 2.1, U. 103. 9.S. 3.7.1.7;
I WT, 13.1.13.4. 13; (IV) 11, X
21A. 0 a
..CI"4 1j. CA
~ 14Ajbo-Cjtj14.Q.CH
+
s
+CgI.~
.9.
ff.
3.!
Work. Yd. a. L!
Tbue
41M
coanted fw-,by, g to tbove
ed (C-4. 41feaft) fw tile rewdoo am an
Wit* tblk
dtagev&MM
-f
is w br,
6 MCtCCwC:CI4 4 Clu +MiLCO
Ome
sc~
;
M,
M e9 C Me-M fS CHS + CKS.-Cute
C IHI%VC
F4
+CEfjCKeCjCH
,
CIL + CHICCICH -4 poijam,
M 1.01
Th~ test of tbeme; I Consirti in CMP=i%w of tift Qb-
butam Which Gir DeMW-Y~MV
Can 4~w_
slerveA yield of CH4 and the yields calcd; in pcovortion to the
- " e.
w of olive conespanding-to the schemes &-
d
te S ,
brou expanuou of
t gh -Ing kw&bwtyk7ck*CoP=%e, Ptoduced
.
.
_Y
Thie actijal ykld of C14 in V is intennediate between that,
ydrqpmatim Prizowt
by h of a Y, (OMMA krf-butylcycto-
CQ
w
C
"I 3 de
t
d
i
d indc, and 6 t. IT, LIT it Is hitermetliate be-
'called for b4
: a
ces
C Ys
pro
ew wou at
zation tM" A
P
P
In fouga tat Uffles in
Como short
contact time
iffer-
the d
-ka A fit
tvieca cn the amt.
l
Ihat evolved In
dromation 61 Aenes atW
i0ent on
b
.
ence disappears' The, yield of coke Ix aboat 3 tfines as
-
.
y
.
the Ut prodaced In seoxvla:7 ots A as an B. On A. sharp shattening of the CORtgKt
i
l
"
dehydraMadous. Wis. fit 1. ff. M. V. my.. 103 170.62.
rf
24 i~nks/JW rimoks ?WegCCMe;Ct(u 'it is A *kQy4ow me gesu
ts in mar
decreaw no tf- A~~--~
t
sion of secoadary dthydropnatiorm, an4 decrease of the
in V-which, j4dking hy thei ant; of Clig, shoold curre;r~ deVee of Lowering
t of the temp. acj~s lit
the same dirictimt a4 ashartmiag o( he contact vate.
toschmics d.4. and Mallimly hiah in-T. ff. which should
v. Than
"frespand.more. nearly to k ancl d. Tljh is taken to (ndi-
-
roe-
in intbitantous
ok
k Nmed wainl
h
t the
t
. c
e
A
In
eJ
y
p
mr-'
enmflon aF,gKAymm
m" of Vxmitka and dehydro
,
g
(rduly tiot of the ammatki. - Tho
hysclictife 4 Is (ts-.41imed to take pjace-
t# tA 2.2,Uvimctbykyc~
- - -- -
~0~ %'IEN7751=-, ft?,D.
601L V
~ .0
OBOMTSEVV P. D.
"The Physical Constants of Hydrocarbons in Liquid Fuels and DUB," Goa
dat; 1953.
VTMiK:iu&dojI' ratgr ~~S U1 tille pti~nne'!
-I
-
-UI
-
~~
Ea nd rnalybdan
'~
cRBE
.
0
TIff
MjT; cf. CA. - 48, 19,16i.-AroinaGiAVnit of
2,2,,vtzirnethyIpeatanc over Cr and Me )xjd,~ catalyxt at
atn. pressure wid 510' or BCO' with ~pacr: velocity 0.5 :La"'-
wa!i "difcf. Aronatizatior, lit this'case occan S&ILC--
tively: wer Cr catalyst p-xy1c:ve forms, while over UO
t'* -.L. f. -rylent frrtn,, ia 18% and resp.
8%,,YicIds-
The main reiction ii formation of butylenes and coke, which
tre-Ithes 13S-730% cf the reaar'd starting u-'actrial. Tim
-~'-MWI-zatc from Mi; catalm c;afzUair-cd some 70% aromaLk3
'
'
lon r,'
eH,,- vihicb form by aramaf irat
as IvIePh ard (
ni~~ylatir-u pz~uttn.. Th, ffi;641 prro6ueo ,,c 1~-I`-v-d 3
-cyzlic C -f, L~O-CHfj. U'l-CIFI., C.1-11t prd
b
~ 1; 6.
Ly':nz"' Ica
V-'UCe59 prC-:'x't- V-1 tc" dc'. -Au:
-YOG-'rop~me. intIcnI.-A-lat.-I i~ ilvdi-atcd.
G, hr'
USSR/aelrdVxy 0 &1 C0 FD - 1594
Card 1/1 pub. 41-15/18
Author :__MQjQajs4~v,, R. D.; Rozhdestvenskiy, V. P.; Yen1kov, Yu. V. and
usov. Yu'.-T.,,"ffzatov
Title : Obtaining hydrogen by the catalytic conversion of natural gas with
water vapor
Periodical : Izv. AN SSSR. Otd. tekh. nauk 8, 133-146, Aug 1954
Abstract : Investigates manufacture of hydrogen by meant; of catalytic con-
version of natural gas with water vapor. Studies kinetic laws of
methane (natural gas) conversion process realizable on laboratory
equipment of the flow type in the presence of typical industrial
nickel catalyst. Selects optimum procedure, on basis of laboratory
data, for industrial equipment. Diagram; tables; graphs. Thirty-
one references; 23 USSR.
Institution : Saratov State University imeni N. G. Chernyshevskiy, Bashkir
Branch, Academy of Sciences USSR
Submitted : August 7, 1954
AID 349 - i
Subject USSR/Engineering
Card 1/2
Author Tilicheyev, M. D.
Title Review 9k e 4andbook on hydrocarbons: "Physical
to
of Liqu ue s afid-M-d-,
Periodical : Neft. Khoz., v. 32p If5s 92-95. MY 1954
Abstract : The reviewer favorably comments on the increased data
for hydrocarbons (from 626 to 1323) in comparison with
the first edition and the greater number of references
(from 4T6--to 59T). The data given for most materials
were obtained from original sources. However, a few
references were presented from secondary sources, which
differ by decimal points from original values. A
number of data were obtained from the work of American
investigators like S. A. Board, F. L. Howard,
Fred V. Rossini and others.
Neft. Khoz., V. 32, #5, 92-95, MY 1954. (additional card)
Card : 2/2
Institution : None
Submitted : No date
AID 349 - I
xq
Of
--,Wtth'tbti Old
Ps".111irli.-I
v t.Tvvyfiv. all( , - 700,M)MI10,
owc1lilv.v
u At.
C., 71,
OBOLUTSBY, R.D.; MKM%fArA. S. T.; KASIMIMA. A. V.; GIADKOTA. L.J.
The.c'li~v"t4-6f organic sulfur compounds of the type ancountgr*d
in petroleums petroleum products. Izv. Yost. fil. AN SMLu*,,l0:
6"? 157. (MM 10111)
1. Bashkirskiy filial AN SSWL.
(Iklfur compounds) (Petroleum)
0 t-S61 I- F- IV T SE V, P) , D,
-2 "a-UMUZ "Ila- AYVAZOV. B.T.
Chemistr7 of sulfur organic compounds occurring in patrolsua and
petroleum products. Report No-.2.- Isotherms of the adsorption or
ow nercaptans, disulfiden and mar idea on silica gal. Isv. vost.
;
11. AX SSSR no.12:54-67 157. (MIRA llil)
1. Bashkirskly filial AN SSSR.
(ftlfur organic compounds) (Adsorption) (Silica)
ok
wl
-t- 7 :77777777777
6 0 L_ F-1V T.S r--' V, Af , L~
AUTHOR OBOLENTSEV R*D.p Ayvazov B.T. PA - 3159
TITLE Isolated froa Petrolaus ooourring in the
Tormay Goal-bearing Rod*.
(0- btitiltiofan# vydelpmnyy is nef ti uglenonnoy evity I vr-
nasinskogo sestoroshdonlya.- Russian)
PZRIODICAL~ Dokla4y Akadeali Sauk SSSR 19579 Vol 113# Nr 30 PP 614-615
Reasivedo. 6/1957 Reviewed: 8/1957
ABSTRACT Mineral oil was subjected to anisothernal rectification in'.
vacuun. On this occasion the temperature of the oube was
constant and equal to 135 * OP50 pressureg however, was re-
due*& from that of the atmosphere-to 0,5 torr. During the
ahromatographing pro"se three chromatographic filtrates were
colleated..The first filtrate was-& mixture of paraffin- and
naphtene-hydrecarbons which did not oontain sulphur-organic
o"younds. The-second riltrato-was am Intermediate product
with 1931 % totalialusio-of sulphur, The third filtrate was
a mixture of aroustic hydroo"bons and-sulphur-organia
compounds after ao*ton* had boom distilled off. The third
filtrate was subjected to a second chromatography under the
same conditions as the fraction at 196 - 214? The second
filtrate was solved in isoo~tan and subjected to further
CARD 1/2
AUTHORSt Obolentser, R. D., Ay-razov, B. V. 2o- 1.14-4-34/63
TITL3# On the Chromatographic Liberation of Aromatic Hydrocarbons
From Their Mixture With Organosulphur Compounds (K Yoprosu o
khromatograficheakom rydelenii aromaticheskikh leyodorodov
iz ikh amesi a seraorganichookimi aoyedineniyamli
PERIODICALt Doklady Akademii Nauk SS3R, 1957, Vol. 114, Ur 4, pp. 8o3-eo6
(USSR)
LBSTRACTs Numerous attempts to isolate aromatic hydrocarbons free of
organosulphur compounds from sulphurous petroleums and their
products by adsorbents such as silicagel and alumogel, were
frustrated. In order to determine the conditions of a chmmsto-
graphic liberation of aromatic hydrocarbons from their mixture
with organoeulphur compounds, which form part of the ligroin-
-kerosene distillates, the authors tried a number of adsorbents
of home producit (silioagel, aluminumoxide and activated char-
coal). The experiments were performed with artificial mixtures.
Technical isooctane was used as solvent. For measuring the ad-
sorption efficiency they chose the method of direct chromato-
graphy. The values of specific adsorption Yary widely and are de-
pendent on the quality of the adsorbents and also on that of
Card 1A the adsorbed substances. In a number of cases, the specific ad-
On the Chromatographic Liberation of Aromatic Hydrocarbons 2 o- 114-4- 34/63
From Their Mixture With Organosulphur Compounds
sorption of aromatic hydrocarbons differs from that of organo-
sulphur compounds. As an example there served the chromato-
graphic separation of a complex midure of aromatic hydrocarbons
and organosulphur compounds, for the case that the adsorption
isotherms do not overlap and the mutual influence of the mix-
ture components is lacking. By the use of different adsorbents
and by the repeated application of chromatography one can ob-
tain a complete separation of the chromatographed mixture. One
of these variants is illustrated by fig. 1. The artificial mix-
ture consisted oft butylbenzene, napht%alene,oL- metbylnaphtka-
lenet di-n-nonylaulfide, isohexylphenylaulfide, di-n-butyldi-
sulfide and benzy1mercaptan, which were dissolved in technical
isoootans. The results of chromatography are shown in tab. 2.
They indicate an incomplete chromatographic separation of the
sitd mixture. Comparatively small yields of liberated compon-
ents may be explained by the consumption of the substance in
analysis. Only some compounds were isolated in a pure state.The
failure of a clean isolation had been foreseen in the diagram
of fig. 1. The non-adequacy of the diagram with the final re-
sults may be explained by the overlapping of the adsorption iso-
Card 2/4 therms and perhaps by the autual influence of the components
On the Chromatographic Liberation of A-romatic Hydrocarbons 2o-114-4-34/63
Prom Their Mixture-With Organosulphur Compounds
to be separated. For that very reason those idotherms of the
greatest possible number of the above-mentioned compounds
should be studied. The liberation of n-butyl benzene from a
mixture of di-n-butylsulfide, di-n-butyl disulfide and ben-
zenameroaptan was obtained chromatographically under analogous
conditions over silicagel (trade-mark ACM) by a solution of
acetone in technical isooctane. The chromatogram in tab. 2
convincingly indicates the possibility of the above-mentioned
isolation and perhaps also of such an isolation from analogous
mixture of organosulphur compounds. Under analogous conditions
an experiment with the fraction 194-2140C of Tuymax-petroleum
was carried out. A considerable number of the aromatic hydro-
carbons may be liberated without admixture of organosulphur
compounds. The results prove that it is possible to separate
chromatographically mixtures of aromatic hydrocarbons from or-
ganosulphur compounds, in artificial mixtures as well as in a
small fraction of the sulphurous petroleum. Further systematic
investigations of this problem seem to be necessary. There are
Card 3/4 3 figures, 2 tables, and 3 references, I of which is Soviet..