SCIENTIFIC ABSTRACT OKHREMENKO, N.M. - OKHRIMENKO, I.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001237910009-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ViG
/r-T A )-2/1r, FF (n )-2/E (v)/'E M/I
L 6&U2:;:0 ENT (I;,/ Dv~ M.;
lip(c jf)/'i;~'.
4,
AUTRORt Okhremenkv, N. M.
TITLL - raf agnet I c fields and e I.-
Tnve9iigatIcq, of Apatial
nduct or, p-a-f-,pa
rittic aff*cta in L
SOURCE Kagnitnaya ~i !-,c
P=4
ABSTRACT, The extenAior, ar--~Ivticdl t'T-'~di~es of spatial distributim -'f -
magnetic fieldz in a flat ir;-- i-iuc-tiov I~h liquid metal rp--
Finite widths ~dnd --,f tt,~~ ~nductur coilz and the chrin-;~,
presence of metallic W'A~!S ar'- ta)(en *-"nto accoilm,
of MaxweLl's equationq ~s 5(,1v-,! f~lr thr-p r-Fjons ihown in fig. I :if ~'i-
The system 4fticlenry !~i Riv~'r; ~n lerv-'I~A of thf' coefficiert of demagne"
(ratio of inductor co., I cjrr(int s wl th ILc-3j riO withmut load, or r5tir
ing ffiftnet ic fields). c-oefficierpr valtieb for a oet of pole separatic.,'
j
presented graphically. The wialytic rel.ation% penrit accurAte calcu,at'*;:-.
I Card

7
ACCESSION NR.- AP'~011!107
parforemce of 0e device confidering transverse and thickness frinrre
and accounting for maction of 5econdar-v cvr:vntn. These calculations
firead by the Pxperimertal rpsu-n whi--;. 11 be pub1fahed. Orig. a;-t-
fomulas, 6 figures,
ASSOCIATION - none
SUO 20M,
40VI 004E 0 Me. R otr,
i C4rd,

EXCLOME: 01
rig. 1. Diagran of the
!Lnear induction pump,
I --thermal insu lat i or, ( C
g&P)l 11---ChanrOl W1311-~
liquid metal
Card 3/3

OWC.-I-n-sno. :N.14.
Transverse adRe affect in flat Rnear induntim ;n=a. -"+H. rldr~
no-3287-95 163. 'Y7 -, C. I
. RA :La; _ j

L 848(-66 EWT(l)/EPF(n)-2/T-2/ETC(m) WH/DJ
717'
LAVel ter. lag Td&; 0khremenkof No me
y Y,
ORG s none
t,ji
TITLEt A cyllndri Class 59, No- 175824
~SOMCEt Wleten' izobroteniy i tovarnvkh znakovq no. 20t 19659 124-125
TOPIC TAGSs pump, induction pumpt mechanical engineering
ThisAuthor Certificate presento a cylindrical induction Vamp ..-onsisting
jof an anrmlar duet# a magnatio circuit, and a magneto with a three-phase vinding
i
"(see Pig. 1). To increase the pressure efficiencyt the duet of the yump oarrie3
Jozgitudlml baffles made of an electrically conductiTe material.
iCard UDCi 621.669

:Orig* art. bass I figure.
SO COM 14t 113/ SUBM DATEt 2689P64
Fig. 1. Ptmp duot; 2-- longitudinal bmff'~e3.

907 EWA(h)/ETC(x)-6 JD/Wvi/JG/EMUV0382/65/OW/66j/0087/0095
AUTHOR: Okhremenko N M
ORO:- None
,TITLE: Transverse edge effect in flat linear induction pumps
SOURCE: Magnitnaya gidrodinamika, no. 3, 1965, 87-95
TOPIC TAG$t magnetohydrodynamic theory, magnetohydrodynamic pump, liquid metal purp
ABS11tACT: This work eals with a refinement of design theory for liquid met I t~a
q. nEne-L
tohydrodynamic pumpsl mo're specifically, with the, development of coefficientt,-, asses-1
=--Ing, the pressure attenuation of transverse electrodynamic edge effect in f:.at, 1--ne I
ar induction pumps (PLIN). Fig.l. The analysis utilizes spacial -patterns of the elec'
.tromagnetic field and express' el
ions for the reaction coefficient of induced currents d -~
Yeloped before (N.M. Okhremenko, Magnitnaya gidrodinamika, no. 1, 1965, 97). The ana-'
ly.xis was'based upon constant magnetic flow or constant average magnitude of the re-
sult-rit magnetic induction. This approach was considered to correspond best to the phy-
sical meaning and to the concepts of contemporary theory of electric machinery. Die
analvais was made for pump configurations where the magnetic field of the pump could
be C~nsidered plane-~,parallel. Exact and approximate expressions for the ele;tonagnetic
pressure were obtained for the case of sinultaneous transverae and vertical flurface
effects. Three cases itere investigatedt 1)7for the case of an infinitely w1je channel
Card j12~_ - - - UDC 538.4021.(89

L -14232-66
ACC NR, APS024907
z I - 11 - heat insulation or air gap
II - III - metallic walls of the citannel
III liquid metal
Flow along axis x; pressures
:-1:7 a function of y and z.
Fig. 1. Schematic of a PLIN pump.
.2) for a-limited width channel, with arelatively thin metal layerl 3) fc.r a E.Mited
.width channel with a relatively large thic'Kne3s (height) of the metal tayer o:! strem'.
The results are considered necessary for the, treatment of pump designs. Ortir. ftrtJ
has 3 figures, 25 formulas.
SUB OODEi /3,.20/SUBM DATB: 22jun64/ ORIG REFt 010 0711 RM )01

L 16931-66 ENVI)/7FWrI%m )AW (n)-2/t/KC(m)-6 IiII(c) VIlaj
SOURCE CODE: UR/0382/65/000/00JAY0003/0023
_A^C NR AP6003196
:AUTHOR: Qkhremanko N. M.
IORG: none
.,,IiI'TIX? InductionZLmps with traveling magnetic fields
ImSOURCE; Magnitnaya gidrodinamika, no. 4, It'65, 3-23
:TOPIC TAGS: induction pump, MED generatcr, electromagnetic field
--Anduction p=p3 is siTr-
ASTRAM Thaoretical~zad experimental -esearch ow-Ainear
iveyed_ Both published and unpublished data are included in the survey. Tho main
~prr%blem in the theory of induction pumps is the mapping of electromagnetic fie'dr
'in -.,he various parts of the pump. The usual approach to this problen consists of
;solving idealized c"es without edge effects (and hydraulic effects), edge effects
Ibeing invostigated separately. Problems which have been solved in this area are
idiscussed and analyzed. The solution of the edge effects is facilitated by the con-
1 siderable similarity of this problem to that of asynchronous machines. Anot hez, in. -
i1portant set of problems I's associated with the secondary effects. The importance
UDC! 538.4:621.689
Card 112

!ACC MR: AP6003196
:of experimentally checking the theoretical computation of secondary cur-ents and
i
;fieIds is pointed out. Teo little work has been done on hydraulic prootsses under
.,Pagnej:1c,fields. In most cases turbulent flow of liquid
Ithe action of traveling i
ffietals constitiii-es"the operating node; e. however even the solution of lamLnar prob-
lems is very difficult. Snme computation -tzsults are presented- and an approach to
this-so-1-u-tion-0-f ---more- important aspects of - this. DO.-oblem is suggestcd. P: in also
limp6rtant to crosscheck theoretical a-imputevibno and experimental measuivmcnts deal--',
Ung vith efficiency of pumps at Yar!(,)u4, operating regimes, where mutual inductances
--part- Th ell ental work in th s area, whic)i has pro-
tween stare portant. e
.7 -6f -in-&-ft-1-on
.1tion _pumpifTs also reviv.4ed and gaps- -in experimental- data are- indicat-
-.7
- ed. Orig. art. has: 6 figures.
~SUB CODEi 13,20/ SUBM DATE: OIJul64/ ORIG REF: 060/ OTH PIF: 007
'Card 2/2

";at; UUMN Mir a)
tL~~ -,--AI - 1 A _4 A
f44s-Oul, ~L
PmWoma for *dead& InTsougatkft, in th, glow of Win*
Production. Nt., -1; Okhmmolm. rl"filf &
dram S.-S.S.R- 9. No. S. 4."(194Q).--ntW ntentkm i.
-awk of nta)or pn-"enjs,e+. hellw"Tment in JUkC
(tchnQ1097 Ili Prtpn., &p1sliculina. of r~,W to the pr~,,
improvement in mntrol mfIh0,I%, detri. of optittul rate 4
a in diffllrUl OIA-Krb Of )W%UflP'jlmWj 400
I
diffrrTnt "illVI, &Ikl .111V lyl..
got
369
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ji LLIC
thL loweputive sctitm 'd
iv h-iy
:~y cill it v

POPOVj X.,S., -kand. tekhn. nauk; GAY'VOFCNSKAYA, 2.1.1 URANETS, V.P.;
NILOV)- V.1.3 VALUYKO, G.G.; OKHP0&HKO1 N.S.1 ZHDANOVICH.,
G.A.; DATUNASHVILI, G.S,;
KURAKSINA, -N.K.; TYURiN,--5,T.,- TYURIXA, LA; KRI-MHAR, M.S.;
RAZU"VAYEV, W.I.; S.T.; MIRRAYIDV, S.M.;
ZH.TLYUOVAJI O.P red.; GLIXI-19i'y N., red.; FISENKO, A., tekhn.
red.
JWine making) manual for the vorkers of vinerles on state and
collective farma in the Crimea3 Vinodelie) rukovodst-yo Blia rx-
botnikov -vinodellaheakikb zavodov sovkbozov i kolkhozoy Iryma.
Simferopol', Xrymizdat, 1960. 415 p. (MIRA, 160)
(Crtmea-Vine and wine making)

OMXMF,WKO, N.S.
3~qthoas of reducing BDCar losses during the vilting DfMaPes-
:81okb1m, -71m. no.4:223-234 '60. (Am 13: 10)
i, YeeBoyust7y taimebto-issiaovatevskiy ibstitut vimoasnyx i
vlnogradarmt7A 'Magaracbm,
(wine and vine making) (Grapes) (sugars)

WJMJKXMMQ# JX,, dots*nt, kmrA.,t#khn.n&uk (1sAingrad)
Rectroxagutio pbenomena In flat induction props for liquid
zwt&3,sa 31ektrichestva, mo.:)j48-34 Mr 1,60. (XnA !.): 6)
(Pumpims Imehinery, 3100tric)

RENGEVICH, A.A.., kand.tekhn.nauk; SHAUTARI, F.S., Inzh.; VOLODIKO, X.F.,
Inzh.; IYUSHMERKO, A.I., inzh.; GALUSHNO, M.K., kand.tekhn.nauk;
YUZNETSOV, B.A., kand.tekhn.nauk; XUDELYA, 111.7a., inzh.;
MHEDA) 2U., lnzb.; OKHRIMHUX., O.Xh., tekhnik
Causes of the breaking of axleB-of electric mine locomotivas.
Yop. rud, transp, no.6:192-203 162. M U 15:8)
L DnePropetrovakiy gorWy institut (for Rengevicb., Kuznetzov,
Kudelyn, Mokheda, Okhrimchuk). 2. Donetakiv mauchno-isBledavatellskiy
ugolliVy inatitut (for Shakhtar', Galushko). 3. Alek3and:rovskiy
mashinostroltel'W zavod (for VolodIko, Yushchenko).
(Mine railroads) (Axles-Testing)

RENGEVICH, I.I., kand.tekbn.naukj MRDA, M.K., inzb.-) DASUEVSKAYA, YO.A.V
inzb.; MCHIMNA, ROL, inzh.; OWIL-E-HUX O.M., tekhrAk
Basic resistance to movement of mire cars Im a train. Vop. rud.
transp. mo.602B-334 162. MILA 15: 1)
I. Dnepropetrovskil go-.nyj inatitut,
(Mine railxoada)

OMIMENKOP A.A., Inih.
Ile ".-110 borAns and loonent-op mchine. Energ. I elektrotoYh.
rr-,)Yj. no.3:57 JI-S 165. (-MIPL 1889)

"!rf1,.,-nr-e of rf, of t~ir rc(llict'or~ r-dil o-
t'~;e `l"rr:arisr-s of ?A-c'v Orcn'7 of "-.-d "anner
Hov, 19~5 OF ~l for tJ~-n T'P-r.-- cif
Of 'Jetv'rin-17-~r icirniccs)
-50: Yni-.hnaya L-tonis', No. 2)~, Yos=,, -lun np

nyzH"Ovsxly, V.0.3 OLMIMMOO 4!~,j 0ONCIMUX, G.A.
organization of Whor In mannal Cultivation of sugar "beet
croys and Ito Inprovement. Gig.trnd'a I yrof.z". ' 3 no.2:51
14r-Ap 339', (MM 12 16)
lo Inatitut gigl7eny traaa I -prDfiabolevaniy.
(SUGAR RYMS) (AGRICUIMM-HTGUMC ASMTS)

SHLYInWIJ 7.H.; D)UMDENKO, A.?.; BORMIAMMY, N.A. (Xiyev)
Sme imdustrial hygiene problems in the operation of electric
steel-furnam, Gig. truas. i prof. zab. 4 no.12,.U-15 D 160.
(',IIIR,l 15:3)
1. Xiyuvskly nauchno-issledovatel3s)dy institut giglyany
truda i proftabolevanly,
(S7-ZTEL IMI)STRY-HyGrnic ASPECTS)

ZHIRI.OVAJ G.Te.j OKM~WXO, I.F.
Some problems of work kygi,,~ne in the loading and unloading
of porcela2m 3dIna, Trudy 1r,,-. med. In5t. 1,72100-101 162
(MIM !6%3,2)
1. Yd~m7skly institut glgiyany truda I profaBslcnalln7~cl =a-
bol.evaniyb

MUSIMM, O.F; OIMDIENXOj A.F.; XUBYAX, O.D.
lWrovement of vork processes In modern eteel smel,ting
estatlisbment, Vrach.delo no.31!10-112 Mr 163.,,. (XM ih4)
2. Xiyevskiy Inatitut gigiyeny truda I professionallnykb
zabolevaniy. (SWLTING-HYGIENIG ASFECM)

22 (1) S07127-59-2-12130
AU-111OR3 Okhrinenko, 3.1 School Director
TITLE: Imporiant Tasks (Va2hnyye zadachi)
PERIODICAL: Professionallno-tekhnichenkoye obra2ovaniye, IS~59, Nir 2,
p 20 (USSR)
ABSTRACT: Realization of the program adopted at the 21st Party Congress
-will require fir3t-class engineers. The Dymer School of Agri-
culture Yechanization has already trained over 7,000 machine-
operators for the Kiyev Oblast' and the virgin lands of
Kazakhstan, but the demand is constantly increasing. The
skilled tractor-operator is the =oat sought-after person in
the kolkho%. The kolkho2es try to make the utmost use of
mechanical equipment now at their disposal, providing, con-
currently the be3t possible naintenance and repair. However
the great demand for nil kinds of agricultural equipment
does not abate. The Minskiy traktornyy zavod (Minsk Tractor
Plant) alone is now developing and will produce within the
next few years 28 differently designed tractors. The author
defines more precisely the new and additional duties requir-
Card 112 ed of tractor operators, and lists other specialists required

Important Tasks
SO7127-`,19-2-2 2/30
W
by the kolkhozes. He believes that a need exists for re-
organization of schools of agricultural nechnnization into
vocational-technical schools. A skilled tractor operator
should have at least 2 years of training. The need to develop
training farms is also empbasized. The Author believes they
should become a st.bsidiary enterprise of the school.
ASSOCIATION: Dy:r;erskoye uchilishche mekhanizatsil sellskogo
NY 1, Kiyevskaya Oblast' (Dymer School of Agri3ultural Nlecha-
nization NY 1, Kiyev Oblast').
Card 212

ACCE N R -11 ~, 1-1 ~ I I .I- -
!4 J S S Yf; 40 0
ALTT110fl, B M ~Se' tic) B
TITLE
he 4- metal
SOURCE
te ~A v t
of e xw_~ I j! nkI
11 In ino'. ~l c 4" 1,
Ph
IL~O;l ;'Ii~
A0 I

L 16
ACCESSIC)N Nk '0
Concluded thtl tlk, f,, ~;r 7--. 1- .! 2 2
trEoisitions
beCaLlSe Of I "It. i~6,,
acence gpectra of T,l we r,-. u-j t rt? t e d
maxima it) ihe 1111TII!l t 171 ~ht,
635 rim- - we rf~ A IR r( r" __4~

respecti-,ely. in !hf..
k)f the T-e. d t-_1 ,,kl~-_ f-.r a f-s t 1T I s A-q
t h? b an d I& Ih 1 Y, e 0
11,ze ii M,- tj r:?
~4 k 1 Fn W
cormsponds to a t i i r t-) r :)f zhr- kn, ]),-,2 (n4
the free Sn tom, i v~-,xt oafvm fort"hon maximurr of he j,vro
band 1440 nn)) revc rse ir- ins~tir)r,~ I-
4 equalli!)ns
ASSOCIA Tlycl-N. 1%
Y m
.
SUB INIFF'T E D .3 uSc - F,

CC0E-GP, GC ~40 -REF SC)V-- 014 7~ OTHER. u i ?,
2 112

34425
S/185/61/006/006/002/030
3S74 0 7, 1 /3 11) D299/D304
AUTHORS: MilYYP M.U., and 'Okhrimenko, B.A.
TIME#- Absorption and luminescence of halide solutions of
thallium and tin ions of different valence
PERIODICA11 Ukra,;inslkyy fizychnyy zhurnall v. 6. no. 6, 1961t
730 - 733
TEXT: Experimental datay relating to the spectral characteristics
of.Bn2+ ~ Tl+ and ?b2+-ions in crystals and solutions, are analyzed
to ascertain the electron-transfer mechanism. Although the spectral
characteriBtics of these ions exhibit many similarities in the cry-
stals and in the solutions (such as similar structure of absorption
bands, same position of maximum), there are other experimental
facts which cannot be explained by one and the same mechanism of
electron transfer. The maxima of the absorption spectra of Tl+ and
T13+-ions in solutions Nvith residual C37 ions, practically coincide;
luminescence of T13+ could not be observed. 7"he absorption spectra
Caxd 1/3

S/185/61/006/006/00.?/0,30
Absorption and luminescence of D299/1)304
of Sn 2+ ions are more complex than those of Tl-ions, being composed
of 3 smaller maxima (227, 262 and 284 mp) and one "principal" maxi-
mum (220 mp); on loosing 2 s-electrons, the Sn2+_jon is transformed
into a Sn4+_jon, giving rise to luminescence (at roon temp,~rature).
It is noted that in all the cases, the concentration of Sn2-t, Sn4-,
T1+ and T13+_'ons was 10-4 _ 10-3 nol/l, and that of the halide
ions -- 7.5 Mol/l. Further, the similarities and differencefj in the
behavior of Sn2+ and Tl+-ions are analyzed.. The formation of T1C1
and :PbCl-complexes was observed. In the case of Tl+ and Pb2* ch1orL-
solutions, it -was found that a change in temperatures leads to a
shift in luminBscence spect.ra without a shift in the nbsorption
spectra, whereas a change in Cl+-ion concentration at constani tem-
perature, leads to a considerable shift in the absorption spectra
without affecting the luminescence spectra. The described experimen-
tal facts lead to the conclusion that difl'erent electrons take part
in the absorption- and luminescence processes. 1-t can be assumed
-that the absorption of T13+ and Sn4+ ions is due to transfer of d-
electrons. The fact that the red luminescence-band of Sn4, Ions ha2
Card 2/3

S/185/61/006/006/002/030
Absorption and luminescence of ... 3)299/D304
the samo wavelength as that of the Sn 2+_ ions, shows that tLe "prin-
cipal" absorption-maximum of the Sn2+-ion, as viell as the
Dorption-band, are due to excitation by d-electrons. The same consi-
deratdonB apply to Tl+ and T134 ions. With such an interpretation,
the luminescence of the Tl+ ion and the green band of the On ' ion
can be considered as migration of 9-clectrons to the sites vacated
by d-electrons, which became excited by absorrtio:,. o'. rl.otons. The
absorption maxima which appear as a result of the traiisformation of
Sn 2+ ions into Sn4+ ions) arl probably due to the transfer of s-e3e---
trons, from the fundamental S 0 level to excited 3P00102- leiels.
The inverse transition 3:P0,,1,2 ---> 1 S0is responsible for tho red lu-
minescence-band of the Sn2+ ion. There are 3 figures and 14 referen-
ceB: 11 Soviet-bloc and 3 non-Soviet-bloc. The reference to the Eng-
lish-language publication reads as follows: P.E. Williams, 11hys.
Rev., 30, 306, 1950.
ASSOCIATION: Xyyivsk~-y derzhuriversytet in. T.H. Shevchenka (Kyyiv
State University in. T.H. Shevchenko)
Ca-rd 3/3

S/04 8/61/025/`~O 7
B104/B203
AUMOP'S. :Belyy, .2. U., 0khrimenko, B. A., and Rud1ko, B. F.
- ___. --- - ------ - - - ~ -,.- -.- -
TITLE: Recombination luminescence of Sr14+ In aqueOUS 301Uti:)11 Of
LiCl and HC1 at lo's temper?Aures
PERIODICAL: Izvoutiya Akadenii. nauk SSSR. Seriya fl2icheDkaya, r. 25,
no. 3, 1961, 426-428
TEM This paper was read at the 9th Conference on Luminescence (Crys"91
Phosphors) in Kiyev, June 20-25, 1960. Tt is known that the optical
characteristics of alkali-halide crystal phosphors and certain concen-
trated solutions have much in common: the absorption spectra are in
practical agreement, and the luminescence spectra have aloo rortaiii
correspondences. Bence, the authors conclude thni a study of conc:~nlr&ted
halide solutions containing hanvy motal ions night help to clarify absorp-
tion and luminescence mechanisis. It has been found earlier that a red
luminescent band could be observed in a solution of Sn" In LICI(Ii(11) oil
reduction of tamporatiire. The lumineseence spectrum of this solution at
'the tomporature of liquid oxygen consists of a blup band VIC, Mp
Card 114

S1048 61/0 '25/001;(/0.', 310 -1
Racombination luminescence of... B104 B203
and a red band (Curve 3 of the figure). The present paper deals with 'he
origir. of this band. It was found to have three maxina: 585 A, ~,05 mp,
and 635 m~L Further, It was stated that these two bands werc oxcl4ted in
different parts of *the absorption npectr= the blue orie at *L~e
ticn maximum of 226 rri)b and the red one in the regior, of two distinct
maxima at 262 m)k and 276 irg. Fig. I shows the absorption and lumine.,:cence
sl)ectra of t-wo solutions. It was found that the absorption spectra cf
these solutions did not sldft on reduction of tenqerature, only unierg,~InF
a slight contraction and elevation of the band3. It was further si;owr
'that the absorption spectra of the t*wo solutions had a distinct maxir.,.1m
at 226 m)L, and two less distinct maxima qt 260 m~x and 276 mA. The
luminescence spectrum of the solution Sn 14+ * LiCI(ECI) had only a red
'band. It is asaumed that the long-wave absorption maximum of the ,joliltion
Sn i+ + LiCl(HC1) is cnutied by tho trnnaitionn Iso ) 3P0,1,?* Thi::v
however, alvo clarifies the triplet structure of the red lurninescert band
of Sn". The si.-Alar structure of the red luminescept band f)f s,4~
.1~
tions is explained by the same transitions in the Sn' ion as above,
Card 214

3/048 61/L)"5/'03/"43/C)47
Recombination luminescence of... B104/3203
since they also give a red luminescent "band of the Sn lon. T~i3 in'er-
1D.Tetation Is confirmed 'by the agreement of maxim-a of the excitation
spectrum calculated from formula . ACOC X. -qxv C 1+X C.)d
LIM ~Mjfxx 247D
-witb the ones found exp eximent ally. Bore, I and I are the intens-4.
JI)OM -- 0 VY
of luminescence and the intonsity of the exciting light, ck is the
4+ -
probability of a recombination of'an electron and of an Sn ion, K., '40?
Cx, and Co are "bsorption coefficients and concentrations of the Cl- and
4+
Sn ons, and d is the thickness of the absorbing layer. It 7aii shoin
that reached a maximum at XAX w C 2/C2. In a sulsequent d:.3ciac3ion,
Ch. 3. 1-ushchik dealt with electron transition-z: causing atsorptior in
activated crystals. .'here -are 1 figure ard 2 Soviet-bloc referer.ces.
ASSOCIATION: Xaf edra optiki Xiyevskogo Gos. universiteta im. T. G.
(Department of Oplk-.ics of the Xiyev State Univcrsit~ imeni
T. G. Shevchenko)
Card 3/4

I- L 16861-63 FW k"7 I Sv JB/jG
ACCESSION NR~ A", ~~ -*: -I S,-`-~358/6311/3-1- '- - I - .-
SOURCF: 1, z
AU7HOR-
TITLE: Photochemical\ trans forynations i.n halide acilutions o~ i
valent thallium
1611
CITED SOURCE2 Visny*k Ky*yivs'k. un-tu, no. 5. 1962, ser. aBt:r-.)T
fiz. ta khimiyl, vy*p. 1, 115-21
7TOPIC TAGS: photochemistry, thallium, photochemical transforn;
halide solution , lum-inescence loss
TRMSLATIONi It is shown that halide solutions of TI qradua!]-~
. I
their 1vininescence a-bility under the influence of ultraviniet
It is established by chemical &nal~-sia that as a result of irr;
Card 1/3

L IW-14- f-,.i
ACCESS ION NR: AJ-
tion the 'n+ is tran~iformed intc T!, 3+ ,.he solutionF, of w
luminesce, tile maxima of -he absorption E;pc-t r~i
3 +, .- " .1.
TI whi ~e
It _S 8
the ions Hal- and H-t a re a.",
the al)ser.k-e ~_f _;:7~
solution, no .~-rr_ca_ iea~:tion a observed. Wt~'
conccntration of Hal- or R+ (or both simultaneously), the -a-
photo-oxidation decreaseb. Such a hehavi,or 'has made
interpret the .-eac-1-on
+ 0 2+
manner: Hai H + h v __P Ha- 14- HT1 + Hal
p TI + Hal i T1
+ 3+ 0
+ H ,*,Tl + H On the basis of the proposet mechanism,
tion is carried out for the course of the photochem.Lcal react.;UV-
Card 2/3

L 16961-63
ACCESSTON NR: XR30106313
A comparison of the calculated curves with experiment hats
given a satisfactory result, A comparison of the conr~entra*--
pendences of~ r~,,e pl-.r%- --~ 'r.e-- -al
A;,F~v~~ar-ed process for T1 shows that the processni; afn.
--perfectly analogous. This makes it possible to extend the
2+ 3+
mechanism to the ions Sn and Sb
DATE ACQ: 15Aug63 SUB CODE: PH [~N-:-:
Card 3/3

SEMP NO U* Oil B*A*
M""Mmo-ft
Structural ehn cteristias of the spectra -of lumixeseent
electrolyte solutions. Isv. AN S&SR Ser. fix. 27 no.3j666-669
Yj 163. (MIRA 26s6)
1. Xafedra optild Xi7evokogo gonAantvennogo uni-verelteta
imemi 'T.G. Sbeyebenko,
(Ileotrolyte aolutiona-Spectra)

L 41,498-65 LAPTD1 M aley C Ep F 2 t V~~Ipb Pr- V-Di
IWO k ___JD
ACCESSION TIM: AP404886:
AUTBOR: Bfly4ly, M, U 0ioli-irnenko, B. A.
AATLC-. Effect of ternper,tkirt., or -,hii alld absorptio-1 SP('(
heavy metal salt polu-I.ons 11 investigaton. nf tin salt solutions
SOURCE, Ukrayiris'ky4y 1'k:~v-*cn-ny'-1,y zhvrni%, v. 9, no. 10, 1964. 105'!
TOPIC TAGS hea-, A,.inmaus lhialide,
lead halide, lijrnine~'C(~TWV 'urnne,~;cer..
tion. function
pf
ABSTRAM', 7he s p~'~ e 1' 1 ~,S (j 1 .1 Hai- Ime
Mal -C1
HCI-TI XBr-71 H it I' B rPI) - 14 .4 C re !r. v e.3 t iad
tation q*ctrcA of Lhe : at lic" ut on 1~ ha ve [A J Z'st I nc I pt ructu t e , (III' f E
the sho rt- wa vfj ?,n d , h v IA V CI ri or i eu, n i n e s c e n c e s pec t r~i rrir
tLin. It was concliidod .tuniinc-scence baricjs rj.'
C111d I/
7.

L 4'1498-65
J~P-~:- AP40 "05-2
~ m A- - 50 C;
tione consist of Severa- over~;.-ippirq,, bands, mnith the overlappir,!,
lhat it3 ovcurrencT., could not he er,";ablifitit-id by &F*ctr-a! measurementii
greater overla pping -i ppa re i oc c u r re (I i n 14 -T' ' and H Br - TI' ro i LJ,
but the cnmplexi(V Of t~;t?-As c,,,)uIo nut determined expirimentill
absorption and lumane sc tnce s;*R1, ~-I ra and c x(-. ital ion functions of HC*I - S
Z6. 2+ -e
Sn and If -Sn r~ W P I ioun(. ,o fol'o-w the s a m e :- ul e s t; i
2S04
containing solutions. The c ha rG (J e ristics of the ban dr, we r( 1
distinct in the Fif I-Sn' 'tie 'Iuminescence upec,,run.
gree 1) 4 ~ On r,-, an (I r d o~~(;O^ n ni), the latte r con s~ st i
of 2 bands
overlapping bands with the rnaxima ~,,, 58,,), 605 and 625 nm, The spec,r
excitation flanctions of -,nd Ii B r - Sn 4 ~- solutions werc- allso
A number of Coe FweuIi.Ar,,T,,c-3 in lhet;n spectral characteristics were exf
the assumption that the lwn~nwscenc~e of these solutions it, of it recombY
t!wre: Hal- - hv S r; i ~- L_ '3+*
Hal . + , Sn ; Sn3r* - Sn
Sn3+ + Halo - Sn4 . Ha, _. The --xc itralon functions w?pre calcul atf~t i
basis of this proposed irip chaqism an-~ wero in satisfac-tory agreerneii,
experimerital excitathon funcl-*ons, corrot>orating Lhe proposed mechar..S 7
-Card 2/3
RAMPERI-W!

L 41496-65
ACCESSION NR: AP4048862
Orig, art. has: 5 equations and 11 figures-
ASSOClATlbW:---Ky6yivsl-'k ve-neftk;~ Ki-ov
a,
te Unky~ersit
'Y
SUBMITTED: 30.Sep63 ENCL: 00
SUE WDE: C;P, ic NO REF SOV: 003 OTH ER 0 () B
cor,d 3/ 3

"-07 W-7- W. -A4
ItIMI Dom*rntng the luminescance of triply charged autimmmy iom LID f1,093011
01010M 416port, 12th couforeace on Lumimmecence bAld in Llvoi,
'40CU-01yo a
30 jask.-O rob ILOGg
SOLV=t AN $561. Isvestlys gerl" fiziohemkoys, v. 29, no. 3, 1965, 391-31,4
9A ,I
qWX -most P"Mmrscef balidel antimmy, Imineseence center
AVWTNW% The autt-oirs have InventIpted the lu-sineecance of froxan squeotle PA--
Uo" CS MI NW Har containing Sb*3+ iow. Both untarials werv teumd to eu&- I n
"D lumdumacence, bands with difforent excitation functimm; me in the greer nod
Ln 09 iod. The red tundnamcmace band of IM-Bb"14 Vas found to Consial D~,
thme auto. lbeso are asmo-cialted vith the three 3P otateo of the fr," ~~b
'4 app*sred to be aUiple &md tb* autham. conaijeer
&am* Tim~ ved baxd of Mr-Sb, -
Sat PrAeble that MIA bmid Is ameociated with ths 40 etatAp-, Objeottona
relaW apimt the mtural aazmrtian that tb.* different excitation fmoticnii n'
L EK~
Me 1--S
- NOR

v- Acowsw mm Apamon
tbo* toft bamm are due to the existeow ci two different kim" of ImIzescocoo
0"4*0 0 aW it in pmpoo*d that the twe bands are rather " to two d Iffor t-r- t
elftt"m %~itiowl the rw haw UA !-"ru" to A=awua 4d the owtor * oaju.. 1
to swig iS4 a a- iomr 6 elsow", to the next hism r 'p
staft. GaU. art. b"1 a f2curso.
Bond 00 M owl at, K-6
a ow 4wws #W 1 001
cood,

z) arl, I'mi.
:Tfecz of on thr: lumLnescencp
speotra of of heavy notal wiltn. PtArt ". Stufly
oil tin salt solutions. 1PAr. fiz. zhur. 9
0 1 ~, ,, (".!lu 1~,:I)
Ef,fe-Qtw of temperature on the ILmInOBCenC9 and aborxptim
spectra of moluti,:,,nn of heavy notni -rltn. Part 3,., Intez-
pretatior. of 41hp. cptctrn )f rolutions ccintralnlng n jb
4-*
--n ions. M:r. fIz. zhur. 9 no.104.106~8-~10?3 0164
('-'.T-.bl 18:1)
1. Kiyevskiy gosudaratvmnyy uni,.ersitet im. Shevc~erk,,.

BELTYJP ']A'.0.5
Lue-rescence of Sb~3 Ions in frozen electra3yta soluticnz- !:,i*
Ali sssR. sar.fiz. 29 no.32391-39.4 Mr 165. (MIRA 18-4)

OMMIMMOS Go
Repairing the min jot tube of -the X~80 carbnrator. Avt. tralIND.
36 no.21.33 JA 158. (Milu ha)
(Automo'biles-7-Agines--Carburstors)

V.124. - SM-NTING'47 A. j, N.I B" ^ye.1 . 9 1MERCO, G. T.
k .! j !, -
YInw b:L-na'frjrgt!r.-a axA- cpticani arJoctIrr-p7 of > I-I*nz)r-L 7-
J 4. 110
glutamate molecules im 3olutten, Vy3c1cm. act:J. 7 nv.6:ijC I
jo 165. (MIRA 18,C?)
1. Inntitut v7zokcmnIekuIyLrt7kh soyadinanly AN SSSR

0 0
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of lb;~ cjv M&-jfr.,At-V JOAd Okhri" -tio
.4th th. dit
4clAllott lwad P. alld-crk P, uk-ra
mammuy otAnd in~
trmli-tiv dnrl nr-o-,

OMIMSNIO. I.?.
3loebomistry of the sumery glarvi. ?Art 2, ActlTity of zammary gland
atzymes In blood. Ukr.biokhix.'zhur. 22 no.2:205-214 150. (MMU 9:9)
1. Xafedra tvarinni-te-tva Zhitomirs)kogo aell skogospodars)kogo
inntitutu,
tINZYM) t)(AMMANT )HANDS)

09HRIMMO I.P,
Xff act of fodder alkalinity on t'he calcium and phosphorus content
of milch cow 'blood. Ukr.7)idkbim.sbur- 31 m0-63889-897 359.
(MM 33:5)
1. Zhitomir Agricultural Institute.
(COWS) (IBLOOD-AUMIS JM CMIST-RT) (CAJZM IN THR maDT)
(PEOSPMUS IN TH3 11ODT)

*141 0 0 00 0 000 1111 0 0 - -
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s * 0 6 0 6 0 0 0 0 *#)-a - -V-* -
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Of ~ Am Uff lad. I j?, S. q. )t,) 11. 121, p
ji'spho air 'givro a
l
'
0 vinyr-as "OM Imp., -.V
and -M
,Aywiotn milm $J
if) and ail I)ufwtnf 411) trIth nalt'rMl j,"h1wr.
11W 1111%K W j vith 11 air I-d jwv%q V It 0d 2r0)
"
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the anfl. of
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1. Mills. of I th ~Mjufjj TUMmj
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The nworchv on*ck vi "White A"t IDIPILbe to u4tir*
materal and synthetk rablberip. 1. .4. OthmetrA,. aml
A. A A-1.0-MA 4 1-ttlillSt'.1-1 Tn b 71"t IV- -'J"IVJT 1-fl-IM
trad, J'.444-4- J0.1 am I~J'lmsp4j A-I) 1"o. DO IA,
I'll, ..4 tat%b V-1 1).
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solki I'Q opitoom" .4 3 ..- I ,P "
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V.IVcll I J- ll.-A a, a IkIW lh~kn %)Wn tivwq,M~. 1 0, ti-I
Jlw W)WI31V J~ Om om W~lh willwl WI,l b. 11, Ill... $.A
if" Y. I'M ~WAIIW% 14-4-317f"l -11? .0111 14) 314 31. 111. 14
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111h)WIS n. .1. 1)%- A~.
Wor.) WO 3ampmarl, .10 %$)1)) IV. evs,P) 1~ Is'l
13 IV, 1 )V)aplo.~

OMMIMMO, 1. S. ; 0740
_ - 73 Y. A.?.
OA*ww 4maus.
)(,s,iio,d,, f 'or delarmining 'tbe dbCDMPOVA'%lDn temparsturs of bigb polymrs.
Zan i"'. -23 mD.3:333-335 '57- (XILU 10:6)
(Polyzers) (RubleT) (3~,rvlyvix)

USSR / Chemistry of High Holecukar Compounds, L
AbB Jour i Ref. Zhur. - Khimiya, No.2, 1058, 6782.
Author : Setkina, O.N., Okh.Timenkg___TS.
Inst 3 Lensovist Lrsningrad Technological Institute.
Title : Determination of Unsataration in Three-dimensional Polymers
of Caoutohouo by means of the Infra-Red Spectrum.
Orig Pub : Leningrad tekhnol. in-ta im. LenBoviet 1957, Vol~37,
91-97.
Abstract i The relationship of double bond content in positions 1,2
and IA in caoutchouc (SKB) subjected to thermal treatment
was invostiga,ted, by means of absorption bands at 910 and 970
cm-1. During the treatment of SKB at 10,000 k#/cm pressure
and 1600C. the relative concentration of -CH-C11- groups
gradually drerea3ed from 100 to 28,1 within a period of 8
Card 3 1/2

OMIMEILXO, I.S.
H-Agh-pressure Tulcanization of rulber. Xauch, I res. 17 mcl.3:5-11
Xr " 5 8. (YM 11:6)
1.Le7Angraa8k17 t8khnOlv9lthGBki7 institut imOni L8tBDV9t4-
(Vulcamisation) (Rubber, Synthetic)

XO]3:RTSKATA, T.M.; USTINOV.A. 0.N.; BMIZHNMR T.A.
Changes of st7rste-butadiene latexes in lacquer coatings. W~WkreB.iwt.
I Ikh prim. to.-4:26-30 160. O(DU 13: 10)
1. Uningndskiy teklhnologlobooldy inetitut in. lonsoveta.
(Paint vaterials) (Butadiene) (latex)

Study of the styreae-butadiene-methylvinylpyridine copolymer a9a
film-forrAing material in vxter-omulsion paints* Iakokras.mat.i Jkb
prim. no*5:8-11 160* (KIRA 13:11)
1. Isaingradekly tekbaologicheukly institut Imerd leneoveta.
(Pai at) (Polywre)

S/138/6Q/OD0/C-07/%','D8/O1 0
AO51/A029
AUTHORS: Okhrimenko, I.S.; Belenlkiy, I.A.; Potapenko, M.N.; Veyrberg, 1.4.
'TITIEI A Study of the Internal Pressures Daring the Molding and Vulcaniza-
Irocesses of Rubber
tion P
PMUODICALi Kauchuk I Rezina, 1960, No. 7, pp. 39 - 44
MMS A study of the"internal, pressure" produced within the mold during
the heating and vulcanization of rubber in of the greatest interest, since it 13
one of the main factors In securing monolithic produota in the manufacturing o~,,
molded rubber articles. It is also Important for determining the rigbt am.0,jr.-, -- -
rubber mixture consumed In the process and for the rational r4,' ter.,3riy
in the plants. The range of pressures used In rubber manufa^,turlng 1-,3 f:%~n I:-'-
cm2 to 600 kg,/cm2. In the 'thermal processing cf rubber and rubber mixturas volu
metric changes -take place at a constant external pressure and a change take--= plae:~
in the minternal "pressures at a constant volume of the polymer. The 1--ningrad
,"Skorokhod" Plant was first to use the instrument shown diagrammatically in Fllgure
I for the determination of volumetrio change in rubber during vulcanizatIcn, Ar-
Card 1/4

A051/AO29
A Study of the Internal Pressures During the MoldJqg and Vulcanizaticn Prccesses
of Rubbe,-.
other instrument -of the ?oisson type was developed for the measurements cf *rItE-r-
nal pressures (Fig. 3). A further description of the instrument and -...9 net~cd
used for the experiments is given. The Internal pressure was calcultted by t'~e
formulai Xcon. - (Pstart. "~ AP)
-Pint. - Sr . 3p,
since the principle of the instrument is based on the ccmpensatlon of ttte inte=a_
pressure of the rubber by means of a pressing unit. Xcon. is Lts prjl-,ssur? after
the heating cf the rubber, PBtart. is the starting prezirare 5 Wcm2, LP the -:c:--
rection of the thermal expansion of the Instrument parts and the pr.-N!3s, S, - the
area of the tross-section of tbe rubber sample (usually 4.~;2 cm2)' 31, - tte wea L/
of the cross-section of the press plunger (254.34 cm2). Ube change in the vclum-?
of the rubber mixtures during the heating and -vulcanizing process, a3 wall as the
change in -the internal pressure during those processes a-re further discussed. Tr?
conditions for reducing the amount of -v-ulcan'Azed rubber waste were 3~,ught and
is stated that these might be accomplisbed by the use of a sealed mold cf -zhe
Card 2/4

S113816O1OC*A---,-7/0~- 3/1. 1
A051/AO29
A Study of Uhe Internal PreBsureB During the Molding and Mulcanizatien Frccessee
of Rubber
Poisson type in the rolling process. It was found that the amoun 4. of
depended on the type of mold 'used, the weigh'. of the raw material, call'tre, e---.
The internal pressure of rubbers, vulcanized in the hermeti caj..' ;, 7- Beal ed Pcizz:r,-
type molds reaches high values and exceeds the extemal pressures used _n
by 10 to 20 'times. Due to the fact that -the internal pressure in thw)se molds 12
always greater than the external pressure, a qualitative molding and -,rj1can1za-~.'_1cn
of the rubbers can be accomplished, the excess usage of rubber frcr :raw zeml-f-J,
ished articles can be brniight to a minimum, as well as -that of the -.raloanized waz~i L/
products, and It can also eliminate certain types of waste products. In thia Cas=
light-weight and low-energy equipment can be utilized. An external p.raBBure cf 1("
- 12 k&/cm2. is suffici ent f or the initi al molding of the rubber art! whit c.1. "14 e -
termines -the necessary power of the equipment. The subsequent mcid-Ing wn-uld "te
sured by the constant presence of the Internal pressure, which 13 3reat-:?r th13:-.
external one during -the vulcanization of the rubber. The amcunt of the r.;tter
the hermetIcally-sealed mold remains constant, and the volume change3 sligntly a-%-.
cording to the tenerature and pressure. It Is emphasized that tne 'Apin-11~1n;:!~ of
Card 3/4

A051/AO29
A Study of the Internal Pressures During the Molding and Vulcanization Proces-3es
of Rubber
tbese tests 'render the use Df heavy equipment and high PTBBB=eB unnecaszar7, In
addition to serving as a basis for the vultanization of rubber producti In clCZ,-t:I
molds outside the vulcanization process. The use of hermetically-sealed Polzscn-
type molds for general use in the manufacturing of molded rubber articles Is re-
commended. There are 4 diagrams, 6 graphs, 2 tables and 5 Soviet references. tl
ABSOCIATIONj Leningradskiy Tekhnologicheskiy institut im. Lensoveta i Lenllngraa-
Bkay,a fabrika "Skorokhod" (LeninRrad Technolo&I Institute im,. J~sns)-
vet and the Leningrad Plant "Skorokhod)
Card 4/4

3/08V61/000/020/020/089
;V
M101/3147
AUTHOM Tafremov, 1. F', QkYar~m ko 1. S.$ ]3aBenkv7 X* A.
TITLEj Sedimentation of polymer suspensions
PERIODICAL: Referati-rnyy zburnal. Xhimiya, no. 20, 1961, 79, abstract
2013599 (Tr. leningr. takhnol. in-ta in. LenBoysts, no. 61,
1960~ 132 - 135)
ITEXT3 The c'suses of the different -volumes of sediments of polymer
suspensions in -various liquids vere examined. For this purpose, the
sedimentation i,olumes of spherical partioles of polifers (polychlorovinylt
fluoroplast-3, polyethylene, and a-polyoxymethylene which do not aggregate
au:ring Bedimentation, were measured in air (-volume weight), water$
toluenep xylene, and oellosolye. The differebt volumes of sediments were
found to "be due to the molecular component of the disjoining pressure of
the layers of the liquid between the polymer partiCIOBe Tbo disjoining
pressure Is directly dependent on the energy of interaotion between the
dispersing medium Land the suTfaces of particles of the disperse phase.
[AbBtracter)s notei Complete translatiDni
Card 1/1

qp~M~~, 33MIXIT, I.A., POTOSHKO, X.I., TITOUG, I.A.
Stady'of intenial pressureB in the process of molding and TuIcan-
Iza-tIon of rubberB. X&ucbi razo 19 xio,.7:39-44 JI 260,
(XIRL 13:7)
I,-UnInUaaskly tekboologlasekly hatitut in. I*nBovata i
lani-agradskVa fabrika *Skorokboa* - '
(7a~cani!4ati=)

TIMMOV, I.F.J OKHRIMKO,- I.-S.] BASENKO, M.A.
39dimentation of polymer suspensions. Trudy LTI Yto.UiI32-
1,33 )60. (Ymu 2535)
(Polymero) (Partials size deternination,

22565
iDoo 2~2'0s' 13,81. 3/190/61/003/005/003/014
.2.2 J-0 B110/2230
A'UT-HORBi Okhrimenko, 1. 5., Petrov, A. A., YerkbolantDov, V. V.
TIT1Ej Meohanisia ~of the formation and reverBibility of trimara con-
taining.. pyridine rings. 1. Mechanism of trimer con-Torsion
PERIO'DICALi TyBokomolekulyarnyye auyeaineniya, Y. 3, no. 5, iq6i, 724-72e
TEM Trizerization yields insoluble ana mon-melting products of high
strength. The present authors intended to examine the trimerization
mechanism of copolymers containing pyridine ring, as well an the
possibility of their reversible conversion to form linear polymers. A
reversibility has alrea-dy been observed in the acid treatment of tTimers
containing azomethime group in the side thain, obtainea by polymeTizati 8 n
of Schiff'B bases with vinyl group, as well as in KOE Tulcanination st organic solvents, except petroleam
other and gasoline, was obtained. Tho average molecular weight was found to be
2,4W corresponding to a condenselon degree of 9. The re-precipitated polyester
was investigated by apectrophotometry on an -14KC-12 (INS-12) apparatus. 7"he obtaln-
ad infrared absorption zpeo-'.,Jm proved the prtsence of double bon" In the tranB-
!card 2h

SAV611034100-VO071017
Unsaturated organosilicon polyesterB and the... -A 057/A 1,229
position (900 - 990 cm-1, 1,~R20 cm-1), siloxane bonds (1,020 - 1,091 cm-1),
(CHAD' groups (800 - 914 'cm-', and 1,P59 cm-1), ester groups characteristic for
fumarates (1,140 - 1,180 cm 1) and end-carboxylic groups (9W - 950 cm-'). Me
obtained polyester is miscible with styrene within a range from 3.5 : I to 0.3 - 1,
and transparent homogeneous solutions are obtained. Properties of four lacquers
(see table) based on this polyester were investigated and it was observed 'that in
comparison with maleic resins -the double bonds In siloxane-modified fumaric resin
show lower activity. Thus a lacquer based on -this resin required heating to 2,000C
to lldxV' within ~~O minutes, i.e., to produce a three-dimensional structuration to
7C% 0~19- 3). At 1200C the same degree of structuration requires 7 hrs (Fig. 2).
The drying Is the result of two Independ~nt processes- 1) a cavalytic polyneriza-
tion with an initiator (1% of cyclohexanon~ peroxide), and 2) sxi oxidative. struc-
turation produced by heating over IGODC. No Initiator seems to be necessary for
the latt:er process. Elasticity tests carried out by the MILK method and hardness
tests on a NnA-4 (GIFI-4) machine showed that films obtained from these lacquers
have high elasticity, but rather low hardness. M-ms lacquer no. ill showed after
70 minutes of drying at 20CPC a I mm flexibility on a rod and a 0.195 hardness.
Tl~ere are 3 figures, I table, and'2 Soviet-bloc references.
SUajITTE.6.-.. July 5, 2960
Card 3/5

- OKMWMQj~Lj_~AKOVLEV, A.D.
Economizing zolvents In the manufacture of paint materials.
Lakokras.mat.i ikh prim. n0-1133-36 162. MRA 15:4)
1. Leningradskiy takhnologicheskiy Institut im. Lensoveta.
(Paint materials) (Solvents)

-,- OmiWEIRO, I.S.; XOLIN., V.L.
'Use of the YNT-3 instrument Tor hardwas evaluation and atudy of
the bardening procoss in lacquer coating, LakokraBmat.1 ikb
prim. no,2:4&-52 362. (HIM 15:5)
2. Leningradskiy takhnologicheski institut imni LenDoveta.
(Protective ooatings"TeBti~~ (H6uurJx4 Instrumnts)

AUTIJORS:
"TITLE:
PERIODICAL:
2/011/62/019/010/001/009
E112JE435
Nlyshlennikova, V.A., Li-Iz*7-S7a, 0khrimenko, I.S.
Preparation of organo-disper3ed resin solutions,
based on high-molecular polyoxymethylene
Chemie a chemickS tethnolosia. Prabled technicke' a
bospoda'i~ske' literatury, v.19, no.10. 1962, 464,
abstract Ch 02-6268"(Lakokras. Mixterialy, no-3, 1962,
.12-14)
TEXT: Polyoxymethylene or polyformaldehyde is an excellent raw
material for the produttion of paints and lacquers. Its melting
point is 173 to 1750C and it is highly crystalline. The polymer
is, under normal conditions, insoluble in.the cotven~ional
solvents. It only swells slightly in-dibutylphthalate, pyridine
and chlorophenol. It shows good swelling in tyclic hydrocarblbn3
and an Leven better swelling in'phenols. In some solvents
formation of gels taken plate at elevated temperatures. In the
preparation of the dispersed organosolz, which are to be converted
later ohto films by means of heating, the 4isperaing agent is an
important romponent. Dibutyl-phthalate and pine oil proved to be
C&rd 1/2

Z/011/62/019/010/001/009
Preparation of organo-disporand ... E112/E435
beat; they are added in ihe proportion of 1:1. The dispersion
is carried out in a ball mill or comminutor. After application,
the surface coat must be heattd for 10 to 15 minutes at 2000C.
It is resistant to water, solventb banding and impact. Ageing for
.400 hours at 800C did not produce any change.
I a3setch, 2 diagrams, I table, 18 literature references.
[Abstracter's note: Complete translation.]
Card 2/2

YAKCVIXVA, A.D.; ,U272TSOVA K.B.j Frinil-li
J JO
uohastlye.-IEMENKO, O.N,j GOnNOVICH, Z.F.; ZBORZHILj L.S.
Paint mixes and coatings based on Bqlfochlorinated polyethy-
leme, Lakokras.mat. i ikh prim. no.4t25-30 162. (MM 16311)

3',/276/63/COO/002//029 '052
A052/A 126
AUTHORS: Dlkhrimenko, i axov~ a v , A - and ku-fns tE,o vFt , r,
TITLE- or,
PERIAC,D)ICALI 'y vi. riirnh n io I oi a m a. sn o c, t rt? ri i
'K '14 t
Pr In, a tie I, 1ju I", -) - . ~
TEXT.- The regults ,)f 1,!vestigations of paint camposi-;.-,
ings o r, c o r -4 11i z e ,),?: containing 2 r,-27,,,
Da
7-2.
base pa* ~C. 1 B Pe 1-3j Y
duo ed;. ' t j a wi v I s e s ro u iiit t i ze' po I v.2 t ay r. c
positions i r, combin at, or, w, 1, n r~, a L n .4, whare by :1 -,,-c 1~111 it P!.I;
phony (it can bo %,Iced lo up wei,~Ilt
offect. 'n vi~tw of tho ac"dity of chloraouifuriLed
fying
~4
is recommendod t
dioxiae and ntae7s Lii~ IL~ L" nat) 'o t.~
Card 112

S 276
Paint compositions and 1,-)!)2/A 1 2~
nylguanidine and some mptal, oxid(jl 44 n t h e p re s e nc F) 0 f wh i c Y, tl i e '-L 1 L. -
passes into an insoluble .9 t. -tt t t, tn o u t t i ea t i n g . It if; pointed n~it
coatings or t)ase have a low
ty, corrcglon Is, " f-, c .9 u I ""; r I c al- 1-
mic &I subs -ancer 9 a e P JI S 1) t ; 1~ r f? W, 7
tions o' 11'a t6ural ar,.A ir i i a ;e r,~~ ~j n ac c 0 ti n t U f t i-, e L rp r
these caatir&,~a P;Npn t
and other industries.
le te t. I*,,:, Sf, t ,I
(Abu'racter's note:
Card 2/2

hulp
s/i 9oj62/()C)4/01 0/002/010
BIOI/B166
AUTHORS. Verkholantsev, V. V., Okhrimenko, 1. S.
.TITLE: )..*,ochanism oil the formation and reversion of three-
dimensional polymers containing pyridine rings. 11.
Conversion of the three-dimensional polymer into a linear
polymer
PERIODICAL: Vysokomoleku1yarnyyo soyedirieniya, v- 4, no. 10, 1962,
1463-1468
TEXT: Previous papers (Vysokomolek. soyed., 3, 724, 1961) show that the
action of an acid causes the formation of hydrogen bohds between the
molecules of CXMSIT-40 (S!:'JVP-40) copolymer, consisting of 40 parts by
wsight of 2-mothyl-5-vinyl yyridi 'no and 60 parts by weight of divinyl.
A three-dimensional polymer with the structure
_CH_
+ I -
E(CU3)C6H3 N:H:ZIC611 3(CH3)1 OH forms by cross linki6j. The conditiona
-CH-
Card 1/3

s/I 90/6 21004101 O/C C,210 I C'
.11echanism of the formation BIOIIB186
,causing revez~sion of the th.~ee-dimensional jjolymek pinto a linear polyi;ter
vere studied.( The internoi~cular bonds broke undeithe action of water,
'1k I
aqueous or a -oholic YOII OVSKMVP-40 films which had first been
ntructurized'by means of aA acid. The content of soluble linear polymer
was determined by extraction with benzene. At rood temperature, alkali
did no., aff " t the three-d-ijrensional polymer, at aC~1000C, the spatial
e,-c
structure was*partly destr~o~ed by 1120 and more int"sively by aqueoua
KOH, whereas alkaline KOH 'Drought about complete 6onversion into a linear
polymer. Solvents causinj; greater polymer swelling than 1120 accelevated
the nuclooDhilic cleavai;e. SM,WP-40 samples structurized by 0.1 IN HCII
were reversed more readily than those treated "ith 0.7 3 or 2.47 IN IICI-
H2so4 and H3PO4 had a simil ar effect. The density of cross links depended
on the acid concentration. Conclusions: Treatment of SK-,,IVF-40 with
acids causec cross linkage and also the formation,. dissolution, and
hydrolysis of salts. Besides 11-bond conplexoo, there also exist
pyridinium ions coordinated: with acid unions or OH groups, and free
pyridine rings. Weak acidA cause salt fo=ation:,,,>, 14-11... anion without
.structuratio~. Strong acid43 cause etructuration owing to R bondo:
Card 2/3

Mechanism of the formation
S/190162/004/010/r,02/010
Bioi/Bi86
> H... 11 anion. Strone, polybasic acids also form salt-bonds, weak
polybasic acids yield intermolecular salt bonds. Intermolecular E bonds
form at a certain critical acid concentration. Increasing acid concentra-
tion causes the formation of PyCl and finally also its hydrolysis.
Increased concentration of free pyridine rings, however, shifts the
equilibrium toward the formation of H cross links, E~nd swelling decreases
again. Rupture of H-bonds by KOH is due to the steric complex 1~ound to
Cl later becoming OR as a result of KCI fbrmation. With an
excess of OH, this complex decomposes into 2(CH 3)C6 H3N + H20. Besides an
_CH_
excess of OH groups, the nucleophilic agent has to reach the proton of the
H.bond, which is helped by swelling. Therb are 2 figures and 2 table's.
The EmElish-language reference is; D. 0. Jordan, T. Kurucsev, Polymer, 1,
202, 1960. P.
ASSCCIATIONI:'~ Loningradaki:r tekhnologicheakiy institut im. Lensoveta
(Leninerad Technological Institute ineni Lensovet)
SUBMITTED: May 29, 196~
Card 3/3

VJUHOLANTSEV, 7.7.; OMMMU) I.S.
Gbaracteristica cif the changes In the strength of pyridene-containing
copaymm, Xvmcb,l rez. 22 no.Ilil-3 N 162, (MM 15:12)
1. Leninpmds)dy tekhnologicbeakly inatitut JmAi
Unosovsta."
(Rubber) Synthetic)
(Tyridene)

I
1AXOM-W, A.D.; XCGU:ZU) 'I.V.; CK;E:E-L~,3110, I.S.
I
Obtair-J.-ig org.-inic di:ip,--r3iorz and coatlnZc on the lca.3t, of acrylonitrile-
butylacrylate copol,-)r.,r3. :rat, i ik,i prin. 110-3:3-5 163.
(Iff,%A 16:9)
1. Lanlngi%(Ijkly V~khnoluglclmjkly in3titut Im. Lensoveta.
OlrotccUv,~ cou!,im?o) (Acrylonitrile pclpv:-j)

TAXMIZV, A.D.) KOSHEIEVA,, N.V.; OMBIMMO, I.S.
Proteoti-ve coatingb vltb a baze of organlic dispersions of
pol-yacrylonitrile, lakokrazi. =t. i lkb prim. no 0:18-22 963.
imm 16-.10)
2. Leningradskly tekbnologicheakly Imatitut Ameni LanBovata.

XYSHLENNIKOVAJ, V.I.; SERGEIEVA, L.A.; CKHRIWMO, I.S.
Pmduction and sone propertieB of orgamodifiperBlomp of a fluorine-
contaiming,copo2yner. 1zv.-rys.ucbeb.zav.),khin.i kh1n.tekb. 6
no.1i:128-132 163. (MM 16:6)
L L-ani-ngradAiy takhnologicbeskiy inBtitut imeni LanaoveAt
kafedra takhnologii lakov, kraBok i nametallicbeskikh pokrytiy
i kafedra organichaBkoy khiaii.
(Polymers) (7luorine CDMpounds) (Dimpersign)

L I--
ACCESSION NR; Av,,~i4 6
AUMOR. Shioalovi--h V
TITLE. 4n t I c --:l r r i -r,
divinylstyrene S
SOURCX:
TOPIC TAC.S:
c h r -nne yi~', I o-,- 7,
AE-ST RACT;
prod UC L 5 0 f t h c ;r - f, rv
coacing are dis( t;s-e;~ I 'Ulf,
Tne c n ~t r :;-, E~
U&ed at the rL.L11, T T J!
r-h i c k) w*. r a
ft: A I V V.
pr,per t i ezi f
Lion of iron m- -.i-jrr k~
giveb the hi ple;l',
I I W) r1 V J
ity. Maicitann adr~e~~
Card 1 /2
Im Rp,6M
I'Ma - N'~
IN

L 1'1~'29?-61~
ACCESSION NR: A14041'h~'~
yellov improvi?d onliv
(in contrast LO c r) r, Bl( Vt, d T'V i I
go-ud clastici-v ll. C oi T C', 1
coatings madv W1 "I. -n -v~ .....
also pletted an6 prf, 'pci jz t i en g t ~i i rr 14
adbesion, vape t- p r, rrrw II I" V I ! PTIL V all,; Z e C, i Ti I TI
alkali L-,id ml ~, urv arc t,;-- E, 1~ s t t ei, well, ca- A s ne'! 1.
contaiair.5 15-20 1 f r. r- v o r.
11 c crnp -I r r 1~ oat It,F6
base coa ing Ai
GF-020 t~e new ~,Y-pc oi~ I c U I ~ I P.; -~ r.
cal process and, mA~.ei. s V V ~'h It -`1 - a i~IITI VL
-pzad"-L. Zto Pew o-Li-rree coati S~AA no WA
t
-And7 Ot ID r I pt- 0-1- art. Ikaf at,
figures.
AI;:SOCIATION:
SUM' .77ED ~ DO
r)T)F
NO REF sov:
Card V 2

ACCESSION 31M: AP-40-11456 S/0138AV000/006/0005/0009
AUTHOR; Verkholantsev, V. V.; okhri=enko, 1. S.
TITLE: Plasticizing of pyridine-containing copolymers by mineral acids
SOURCE: Kauchuk I razina, no. 6, 1964, 5-9.
TOPIC TAGS: pyridine, copolymers, mineral acids, plasticizer, SKS-701MVP-10
copolymer, butadiene. styreie, 2-me!hyl-5-vinyl-pyridine, elastomnr
.ABSTRACT: The authors investigated the physico-mochanical and thermomechanical
ch;vracteri sties (hardness, rupture strength, relative elongation, yield point), of films'
from mixtures of copolymer SKS-70MVP-10 (copolymer of butidiene, styrene and 2-
nothyl-5-vinyl-pyridine (20:70:10)) with hydrochloric acid, orthophosphoric acid and
polymethacrylic acid. Ile results show that mineral acids can act as elther hardening
or plasticizing aggents, depending on the amount in the polymer. Thus, for oxaxnple, 5-7%
Ml or 113P0 4 have a plasticizing effect, while 13-15% of the same acids cause hardening,
and evim groator concontrationa again docreaso the strength of the films - In contrast,
howover, polymothaorylic acid, whach forms an Irreversible space lattice with the copolymer
L;Ora-

ACCES'SION NR: AP4041456
Is a hardening agontat any concentration. In the presence of ippropriato concentrations
of the low-molocular-weight plasticizer dibutylphthalate, the hardened space lattice of
the copolymer and 13-15% mineral acid is destroyed. In this process, a ce-nLain stoichio-
metric relationship can be observed (maximal plasticity at 18% dibuty1p`.-,.7..a' 0, or I mol
per 4 mols HCl). By considering the ratio beUveen the polar and nonpolar portions of the
pyrldine-containing copolymer, as well as the amount of mineral acid added to the, polymer
mixture, it can be predicted whether the fiven mixture will be hardened or plasticized.
Orig. art. has: 5 figures and 2 structural ormulas.
ASSOCIATION: Leningradsldy tokhnologlebaskiy Institut im. Lensoveta (Leningrad
Engineering InstItuto)
SUBMITTED: OD
SUB CODE: CC, AM T
":3 ENCL: 00
NO REF SOV: 007 OTHER: 002

ISION M: AP4047209
5/0190164/0061010/1821/1,921',
AV
Bondwre-v G N Ch
TMB: Modification LA P01y'.Uride regir, vith Unasturatod; Aldehy'kep
SOW'E.- v vaokcm) lek u I viirr v vv 6-ovedtneniya, v. 6, no. 10, 196 t, 1.82 1 Ji~
TOffr,, T,4GS3 polyamide rt2sin, re.-tin mndificatlon, unnaturatod 41dehydr,
ficrolain, Qrotanaldehy'~v' po!-Pnei viscosiry, polyrier molecular weL~q
p
19TRACTi The audors -frwesrig~ited Uie act'Avit-, of arrolein, crtl-taqald-~.
awthylpropynal, and phinylpropynal in the mp.61 i~
polysmide resin. 54--". T'u a 1.07. rOlUtfOll of retin in 80% ethyl vAcc-I-
M tsolutioit of phosphortc; acid (21/. by weight- of tl~-e I-,
authors added a 6b
aldeh7des uare then added gradmilly OL-ring 30-40 win, at 50C, with cont ~i,
ittirring cantinm-d for ZO hr,~;. Thc poly-,wy- waa kinally priscipicated v!
water mLxture (1:2) ~fram t, aoluttoo neutral.1.4ed by dn0--IXL%' and tite "'ell t'
"turatLon in the mndUlad zleriifi ums datermined by t-he method or' Kattfmi:
results showed t -it the degree of iubetitutIc"n of the amide hyilriagen utT'K-
I covAjtjow~ ae detelanined by liodirm numbcr and Filemncal analyai.>', LA I V-14
of tho aldthyde structure and Uaia ulkthin the limits of O-IQ%. Frim 0. ,i
.A
112

Umnow NR4 AP"7209
4~
titfation eurves, car, be ee IuAl&v t~t imi bit 11&f ydqr
assoelAtod with dianges in molecular weight distributi&n, uhich Is in s
with the results obtairted by via,,:.,sity measurementas Origo art. haot I
2 figuiss and I table,,
-radaLiy tekhaologiaMskiy inatitut Lensaveta (),or Lrif~- ~i
45SOCUTM, Leming
t6eb=100cid institute)
EM 043 SUB ODR. )!f
0 RV MN 1 0104 MMs 004

4k--. L 3294711-65 i~ r; T j
..................
AZWGVW NR,. V4(1,47219
VT
AUTHOR; 0khrimeako. T. S.; DlywKonm-s, F.. B.
---- --- -- ---
TXTU, I 'Die proble"m of Lhe 111ttz,act-ion -f pol'~Twthacryli 'Lth
c acid
alcohol in cencentratwi aqut.-us i~ulutiort)
SOURCE: ~Vy aok-=olekuIyPrn,2 ye v, 6, no. 10, 1964, !P-,Il
TDPIG TAGS: polymthRr-(
-ylLc ac.40, poiyvirr.-I AlcahL-I, gel formtivn, 11,6
bonding, aster !ermation
ANTMAWT: The auch:)rr, studled Lhe effect of concentration, the rEitl-
timle and temperature on the I
t-,l Le rar. C I I n ~~e t~-%-e n pol vm- thacry c ac i iI'l. ~'i
4
polyvinyl Alcqh0l (ITA, LT, aqi'leous ~4olut~ic'Tz
PIIAA ;,as pr*-par~~r!'y IwI zr
of mthaqrylic acid in r---thyl fil-ohol at 65-70C Ln the
bermoyl peroxide. The ratio c-f the reactarrs by w-t. (PPAP.,-PVA) w--s ill
90:10 to 10:90 and the temperature waig vai -d betsween 0 and 150C,- IL
that at 16-18C Ln mLxturee c",tatning YM MAA and higher, A get-tike r-
formed. ',%e ariount nf geil viLh increas"ig ccmcentr-aFron of
CaMpoljndg, jner(!~gSed teMperjjt-,IrC~ p
.t~,4 rea~ction tij*e. The
soluble on lawiDrin.- the tem-pernture tt, 13-2C, and the nol-gel reversil-,41 i i
Card L/2
W'-
IIIIIIIIIM'I- NO

77T
tha
dependent an the degzee of hydration. It was also eatablished t t~, e j
0 mmr-Lnooluble producto of Ili." wibi FVA proceedo in two stages, 1-h (
Ltwolves the fountion of revenoible and irrevernible products as a rafitilt.
h&Men bondin betuven furctional. groups, and the second involves Cilitc!
fonationo Or art, hasi 4 tableA dnd 1 figure,
iV ASSOCXATUM j loeningradskiy tek-hnologicherkiy innt-itut La. Leas Yveta ?.--an

EW(tA)/EVF(c)/EVR I FWPk j P A./ps -4
AU7BOP.- Verkholnntftv,-V.--V,; Okbzlmenlm, I.S.; Yeframov, LF, 3
TITIZ: Viscogity of nemaquecria aoluftone of a jwr'j1irw,-