SCIENTIFIC ABSTRACT PANCHENKO, G. A. - PANCHENKO, K. P.
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CIA-RDP86-00513R001238920020-4
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S
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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C. E.
"Some Hesults of the Use of S-,ectrosccpy in the
Analysis of Erass,~s and -;bronzes al the Lenin i-lant,"
1z. 'Nauk SSSR, 3er. Fiz. 4, No. 1, 20,10.
SINIOV, V.M., kand.tekl-n.nauk., OhSA~13F, M.A., inzh.; PANCHENhO, G.F., inzh
Yeasurinp relative increases of fuel c)nsumption and efficiency of
boilpr units. Avtom.i prib. no.2:113-3W '61. (YURA ]":22)
(Boilers)
PAJIGHENKOP G.F*
Introducing a valveless proportioning pump. - ~ -0
Gos.nauch.-issl.inst,nauch.i tekhinformo 18 no.5-117-18 "'I '"
1-1
PAW,HENKO, G.F.
Unit for automatic control of automotive tranBpartation in oF&n
pi's. Biul.tekh.-skon.inform.GoB.nauch.-issl.intit.nauch.1 tekh.
inform. 18 no.1:65-66 Ja 165. (MIRA 18t4)
PANCHENKO, G.M., elektromekhexiik; DMTENKO, Yu.K., elektromekhanik
A protective are for tolegrapb apparatue. Avtom., telem.1
sviaz' 6 no.8:39 Ag 162. (AURA 15:1)
1. Kharlkovskaya distantsiya signalizataii i avyazi Yuzhnoy dorogi.
(Telegraph-Equipment and supplies)
Ir
GUTNIKOV, B.Z., prof.; RUSAKOV, V.I., kand.med.nauk; PANCHENKO, G.S.,
kand.med.nauk; KOVAIZV, G.G.; AKMOV, A.I.; Imuchr'U7, li.v.;
KOMBACIMOV., A. Sh.
Iate results of treating patients with urethral strictures.
Urologiia no.6:45-51 160. (MTRA 15:5)
1. Iz fakulltetskoy khirurgicheskO7 kliniki (zav. - prof. B.Z.
Gutnikov) Rostovskogo maditsinolcogo instituta.
(URETMA--STRICTURE)
CIIATSKIY, Ya.A.; POCIMKO G.T.
-z
surp,ic.-l tres'--,ent cr 1-:r-,r tmorrha~-e ~n pi-ba.:Inary tubeculos-
Probl.tub.
1. Iz legoclwogo otdeleniya (zaveduyusiv-,ldy Ya.A. Chatskiy)
y -v-r n ~~r
Vlmitsl~ogo Dbl,-.s+-no,7o -'%uberkuleznogo dispansers (glaviy-
O.Z. Toretskayn).
(TI,BMCULOSIS) (HEVCMUIAOJE) (U-rf"S. -SuRGlay)
PANCHENKO. I
COMUnity, workers check up. Okl2ro truda i sots, Btrakh* 4 no.6:7-8
Je 161. (MIRA 14:7)
1. Predsedatel' zavkoma LipetSkogo traktOrnOgO ZaVOdas go
Lipetak. (Lipetak-Insurance, Social)
(Lipetsk-Tractor industry--Eygimdc aspects)
PANCHMOj IJA.
Sensitivity of the respiratory center to carbon dioxide in the
state of chronic hypercapnia. Biul. eksp. biol. i mod. 49
no. 5:25-28 My 160. (MIRA 13:12)
1, Iz fisiologicheskoy laboratoril (zav. - prof. L.L. Shik)
TSentrallnogo nauchno-isoledovateliskogo instituta eksperitizy
trudosposobnosti i organizataii truda invilidov (dir. - prof.
D.I. Gritakevich)g Moskva. Predstavlena deyatvitellnym
chlenom ANN SSSR V.N. Chernigovekiz6
KRESPIRATION) (CARBON DIOXIDE-PHYSIOLOGICAL EMQT)
PANCHERO, I.A.
Characteristics of respiration regulation after some surgical
interventions on th ches;~,Onectramyographic study). Biu.1.
eksp. biol. i mod. ~ no.11:27-30 11 'U. (I[Ilk 15:3)
1. Iz fiziologichookoy laboratorii (zav. - doktor meditainskikh
nauk Ye.N. Domontovich) TSentrallnogo nauchno-isaledovatellskogo
instituta ekspertizy trudosposobnosti i organizatsii truda
inva+av (dir. - Prof. D.1. Gritakevich), Moskva. Predstavlena
deystvitellnym chlenom APT SSSR V.V. Parinym.
(RESPIRATIOR) (CIEST-SURGERY)
(EIZCTRO14YOGRAPHY)
I. D.
PA 64A9T8
Ouse of ura mictradi" Pciwwsoypo
I=t
c:r am anci Inarg Ohm, Acai Sol Swalnlm =O 6 pp
gZavoiL I&'bP Vol ZITO So 11
Describes conatcWtIcu 8Ar&l&t wv&blO bwd
mnufaotwma eltbw ft%u 411TW or
tut ap"Wame of
mztm an *0 voltap CWTO vuoh In
chusaterlstic for US' an ury 01"tr4ide in nots"IL
Gnu to a f0v C"es with r"Pect to the hwa
PANCINNKO. I.D.
Use of solid electrodes for polarographic study of complex ions. Ukrain.
Khim. Zhur. 17, 872-6 151. (MLRA 6:4)
(CA 47 no.22:12039 153)
1. Inst. Gen. Inorg. Chem., Acad. Sci. Ukr. S.S.R., Kiev.
11. D.
.I~SSR/Chemietry - Folarography I Jul 53
'The Applicability of the Heyrovsky-lllkov~-cb
Equation to Polarographic Waves Taken :,t Solid
Electrodes In Fused Salts," Yu. K. De'-`jiarskiy,
D. Panchenko,- Inst o-P Gen and Inorg C' -i , Acad
sci USSR
DAN SSSR, Vol 91, No 1, PP 115-118
Wsults obtained with the use of Pt electrodes on
AgNO3, Cd(NO 3)2J Mg(NO,)2p Zn(NO3)2' AgC1. CaCi 2)
1
TIC1, FbC12, ZnC12, NiC12, COC12, and ~UC12
266T5
dissolved in molten N&M)~ shmed that the Heyrov-
skiy-Illkovich is valid for fused salts at solid
electrodes. This opens up nev possibilities for
the polarographic investigation of salt melts.
Presented by Acad A. 5. Fh=kin 24 Apr 53.
FXTICHT-OaD, 1. D.
Dissertation: 'Polarographic Investigation of Molten Salts
Cand Oien Sci., Inst. of General and Inorganic Cherdstry, Acad
1953. (Referatimm zhmmal-mAmiya. moscow, No 9, F-v 54)
t7 Using Solid -Elactmies."
Sci Ukrainian SSR. Kiev,
SD: S111 318p 23 Doc 1954
MA M T, B.F.; PANCHE M , I.D.
Equilibrium diagrams of binar7 systems: magnesium chloride --
alkall metal chlorides. Zhur. ob. khim. 25 no.11:2038-2043 0
155. (KM 9:4)
1. Ins ti tut obehch*y I iaorgani cheskoy khl ml I Akademi t nauk Ukrai n-
Bk07 SSR.
(Chlorld6i)
USSR/Physical Chemistry Electrochemistry, B-12
Abst Journal: Referat Zhur - M3Jziya., No 1., 1957, 536
Author: Panchenko, I. D.
Institutioni None
Title: On the Equation of the Polarographic Wave Obtained with a Hard E.Lec-
trode in Fused Salts
Original
Periodical: Ukr. khim. zh.j, 1956, Vol 22, No 2, 153-155
Abstract: On the basis of the picture of the deposition of metals from fused
salts during polarographic recording with a hard electrode presented
earlier (Referat Zhur - Khimiya, 1953, 288lj 19540 21433; 1955, 5357),
a more exact equation for the polarographic wave under these condi-
tions is given. The equation is based on the assumption that the
activity of the deposited metal is a function of the current, due to
the diffusion of the metal in the hard electrode. The equation thus
obtained is identical with the Geyrov-IlIkovich equatioon.
,)AIJ 7-. c:~,b_V?ey
Card 1/1
MICHUMO I D. I 1-V:U,-C)V, B. F., an3 DELDMSKIY, Y. K., Institute of General
and Inorganic Chemistry, AS U561R, Kiev.
"Thermodynamic ?-,~-perties of C-rtbi:. i-.
D pnpel. !31;1)Mitt(,(1 M. t'-,e lnternn,,~Onvl .~:!-rposium ~-T:
Chemistry, (4-15 ~3 1, Progue.
/ 1, . I
MARYMV, R. G. , DELIHOLMIM, U, K. , and FikNCHL14K~.7, I.-D.
(InstAtute -)f General and Inorganic Chemistry, Acad. Sci. Ukr. SSr, Kiev,
- 11
"T"F-'rmodYnamic P"DP-ties Of Some Fused Chlorides,
PaPer suhmitted at S~viet ;!Igh-Polyii~erg, intl. C,xL7er-:!n-e, Tir ttin6ha,,i,
21-211 July 11:45P.
E-_~jo~,661
PANCHENKO, I.D.
Investigating the performance of lubrication system valves In
D-54 engines. Makh. sill. hos. 9 no.4:26-27 Ap 158. (MM 11:5)
l0krainalks akademiya sillskogospodarskikh nauk
(Tractors --Zng4 nee )
I. D.NJICHENKC, GT"lAAT,I, Ye. B., A. A. KOLOTIY, Yu. 'K. DE1.31ARSIKIY
,.y r", , Sri' - "
"Electrr~lytllc Pr,,(j_jt- 1,,~. ,)f T az~ ,
- I -C, - - -
10,'U~h Ac. Sc. Ukr SSR.
report inxb-Itted at a conference on rwv methods of lead production concentrates,
Gintovetmet (State Inst. Ron-Ferrous NetvaluzW), Moscow 22-25 June 1956.
(for entire conf. see card for IMM, V. P.)
.4 50) PHASZ I BOOK XXPWITATIOW SOV/2216
Sovoshchaniye po lektrobchlmll. 4th, Moscow. 1956.
Trud),. . . ; I 8born%kI (Transaction. of the Pourth Conrorince on Sleet
rodh*mIstry; collection of article.) Moscow, I'd-vo AM S=,'
1959. 868 P. Errata slip Inserted. 2,500 copies printed
3ponvoring Agencys Alcademly. n..k SSSR. Otdoleniyt WhImichokIllh ri
nauk.
Editorial Boardt A.%. Fr~klh (Reap. Ed.) Acedemlelan, 0.1 @.In
,,,Y:Iln
Profeagorl S.I. Zhdanov (Reap, Secretary), R.N. Kabanov. ir,~.
feasor, S.I. Zhdanov (R. up. See rutAry)) B.N. Kabanov, Pro .r,
Ya. M. Kolotyrkin, Doctor or Chemical 3clancea; V.V. Lose: F D.
Lukoytoov, Professor; Z.A. Solovlyeval V.V. Stander, Prof ;.or:
and 0.14. Florianovich; Ed. of Publishing Rougoi N.G. Y.Cr.,:
Tocn. Ed. : T.A. Prusakova.
PURPOSEz ?his boo' ':e!~tnd.da'ar.nc'enn atrical *ngl-
and all
lurC:lr-c err I
are, phyalclst~, Irgi td !. a h~t-"-t`d
-1oua as-eta of I.ctrocne.latry.
OVERAGEt The book Contains 127 Or the 1,18 reports present.,! a,
the
rou rth Conr.renc. on Electrochemistry sponsored by the r4part-
sent of Chemical Sciencjs and the Institute of Phy.1c,' Cz%&m,5try
Academy or Scl %.USSR., Tn.
on..
gr&n 0Ct ro e.1.ki_tic , doub lay r he r1. , and
alvanic processes In metal -1-etrodepositon and lnduntr-:., lct-
rolyalaih Abridged dl-eufl5iona are given at the end or va ij "I' I-
b not Included here nave b-
810ni.h.d*,131orit, 01 report.
PU I r.er.od1c:t ll!er' t.m...:c 0p;rao-.1It,,,.._
Reforences 1h and ofthercl.: _rt,.~.d.
Transactions olf'the Fourth Conference (CorT.1 -/r.-
Jxl-rnov, PI.V., and L.D. Yushtna (Uralakly filial SSSR-_v~
AN . I
Brand cACSdemy dr SCIOncca. USS 0).C, thodle Processes During
the Phr; I pl t.tl0, of Thorium From Fused Electrolytes
I.T. . and A-B1Zb_'n-.y4 (Oo..dars!--,yy --h-
Imaledovatel'skly-vinst1t,t tavetryK I ~t-llrlc
N , . r_A
11:,nea,c hInstitute of o r ra Meht I:t), M-n~ r the
. '. ctlon ofGale ra From Suspensions in Flu.,,5 v--t-- Or
Nagne 51.. and Sd'.u. Chl-rid- at . Llq.ld-L-! 352
Fanchanko, I.D.(I~stltut obahchy I
te or GeneraId Ino rganct ry , A~ao,..y
,q.~:nfFO
U~, 5F
of Sciences, rs H). tion or aiaro,r ph:C We,. at
Solid Electrodes In Fused Salta 355
C4QMWk. 3.0 (Avlot-lonnyy InatItut Kuybyah.-Avlation Ingri-
t
ei rXuyb,-Scuae Problems or the Polarograpny Of Pw8ed
utc Y:hev) 358
1.y1.b':rd.O'Y'1.. and V.L. "Wets (Onsudbrat-nnyy In.% Itut
Card 15/34
11 "a' lnd~,try). D.,-pns!! !nr. ftlt.ge and P,~p.rt Is.
aUs,,r. us ". u,
1 .11 d n Non rro ~t- gy 362
Dl&cu.~j on IV.?. M-h.-to nd --,,l..t%ng -th.-I j65
PART V. THE ELECTROWEPOSITION OF KETAL.S ~69
g-nov, j
(F yslc:, 1-titut" o: .th~ El,~garla, A-Ademy or 3c!--_-,'
Spiral arowtn and 0_v-1t,ge D.rMS t . E.,,.
hItcryntn.!jzatl-
of S IIv., 371
lo,,rl,. I- I'l .D.E. Con.0.7 (U.S.A.). D,t-t-
,..n or
Pyr
.111~h Dail Ine h- I Itn. E;-td~) .
R
V~grmmy-, A. r. Nonn-s;--1ty of an E~-trodr Surf-,
Card it,/ 34
tn. M-,, !.- r ',- E-t or
POI-ArOV, YL., P, , a1.11 ......... .lnntlt,t~ ~1
t
0 5(4) PHASE I BOOK EXPLOIrArlON 50V/e.
3oveshemanlye po olektrokhtsil, 4th, Moscow, 1956.
Trudy_; Isbornils) (Transactions of the Fourth Confe"n". on liect-
roch"Istry; Callectlonor Article.) Mosco:,,Izd-va AN SSSF.,*
1959. 868 P. Zrrat& $I p Insertsd.21500 1.8 printed.
Spon *ring Agoncys Akadomiya nauk SSSR. Otdolshiye xhImicheakikh
Zdttorlal Boards A.P. Frumkin (Romp. 9d.) Academician. O.A, Tooln,
Proftemors 3.1. Zhdknov (Reap Secretary), B.N. LAbanov. Pro-
f sm;r.
TV
Lukowtmov,,Prorassor, z.A. Solov-yeval V.V. Stonder, ProfIssor,
" 0. N orianovich; L . of Publishing House, N.G. Yegorov;
Toc.h IT. A. Prusa ". vd
4*
KMP=t This book 1:,Lnt*hdod for chemical and electrical ongi-
83,00", physic I:to,to It r6 .1.0t:tand re.archora Interested In
various aspect of .1 Oct rochI Y.
The boo It contain. 127 of the 138 reports presented at
rt h ConC*r!nce On 81-111-11sam"try sp,,slored., y
~ Inc to Depart
t C ..1 .1 P Y I
Mh`h% of hcce,,. &;d.tho,InatItu 0 Che. -try,
&Cadv.y of Sciences . USShc. Is, it on pertains to dIrr ,ant
bra,., a of eloctrocheol CA I llntl,,, double I,,vr t1-rl and
he I ,..t_
do,. on . n at :,
gal" 1e processes in me ro adsIdo, r
rol""s. Abridged dlecut:lona-mr. giveonitt thd :ach divi-
sion. The ssajorlty of r:plrts not includad her. %v, b In
0
published In periodical It tOrAturs. No p roon,allttoo r me.t1-d.
_2!rnr~hc.a are g1," at the and of most 0; the articles.'
(Institut gookbiall I snalltlohegkoy chimit
As &,:~ 1-7 1V.1. Vrhad.kogo - institute or Goothesslatry
assud A al chemistry 1,,"l VI. Vr,ad ly~ A~:d;~Ya.l
3.l..':!y' U'SCSR). Diffusiono, gj.~, r. ly .:k. hth ~0-
graphic i.thod 6,11
1~~;--*nd E_A_ Zhlg~lcva (Institute of Physical
A-d-y Of Sci-s., USSR), Dirr-i-n r 0AY';-
Through Thin Films of Electrolyte- 684
isio~*.Ion 10 S. Kaenthek, Yu. A. Chistand2h.l. Y,. A. Vdovin,
O,B. Khachiuryan and contributing authoral 68q
pART Vill. gl.E,~rRos:HEP41CAL PROCESSES IN NONFERROUS 695
XYrrAl.L',,(QY
3t_andar._Y.X. (Dnepropetrovsk 1,otitut.oof Ch le.1 T.Ch- "!y
L~mwssl P.E. Uzerzhissakly, Institute f Ch.:j. t'y. Acd..y
of Sciences, XazSSR). Electrolysis as a mean* Of' Combining
Card 27/ 34
3*vvral Notallurgical end Ch--lc-l Produltl-I Pro~.o...
(3,csao Nov Processes or Rydr..lIctric M.tall-KY) tg-.
Aaz.~
L~kl , M T. ("zakh Stftto Univeralty. Ac.,Jo,.y or~Sci
2 Pr.ble- or AMaIg.. %.t4j-gj -t
Of Metals With A-11ga.. 1,04
Y1-_X , D-J!-
":l:-- nd A,_A._Kqj_o,:jj rIn
Ukr!;rR). EI-1-
M 1 ,t c N rlfIcAt h Or ~ dr- d S,:t. ~10
1~h~1;11; (,_t :t.t. r
d.c 0. SR' Tnv-"t 1K,, ,,, , r
and Anodic P0lftr-t11n or 11,c srd,~ T
alloy' t. S. ;15
A!; Ur
R16-rch
Card
41,111, Proc~?'
u,
p _d~ in r t -Chl 14, E.-I _)t.
Zar*:IKJY, S.A. , I.G. Zh-l"ItIkly -1 A
A-011 BI)s-!~r or A-g--c .11,1 It, All~y,
0 5(4) PHASE I 500X FXPLOITArION SGV
SoVaShCharlye Do olektrokhImll. 4th, Moscow. 1956.
Trudy... ; lobor~lkl (Transactions of the Fourth Conforeno. on Elect-
rothemistry; Collect lontofhr-tic Ids ) 214oscow, 12d-vo AN Sssr, :0.
1959, $68 p. Errata @I psert.500 copies print-,!
,Iponoorlna Ag-cy, Ak4d,.1y. n4w, SS.SR, Otd*10~11* khl"lon-11h
IdItorl:.1.90 rdt d))Acad*;Ic1an Y.Min,
Profe, ri:3-a.$- Pru'"kin (Rvsp. Iry ,B. . ltao~.Ov`,'i
Zhdanav 'Reop;c'ecroy'a,
a. Zh.dAnov(Ron P. 3re &r )-, B.N. Kabanov. Professor,
Ta. DR. KO
f 7ar' Siolty~rktn, Doctor of Chemical Sc,lw~ost V.V. Losev.PD.
Lukovtoov, P,"ressorl Z.A. Solov'yoval V.Y. Stender, P-rejaor~
and O.R. PlorL&novlch; Ed. of Publishing House, X.G, YoKorov;
Tech . Rd ., T.A. ?ruan kova.
'UR POSEj This book is Intended for chemical and *Ioctrlcal ongl-
phlo Icleta, metallurgists and revearehors Interested in
ri. Abpocts of electrochemistry.
OVERAGEt The book contains 127 of the 138 reports PmN*nt:d.:t 't
the Fourth Conference on Elect ruCheMiStrY 1tPpOn11arod.b~ya!hCn.mp1
sent at Crwml&:,1,5cl&nces and the Inatit..Phy I IIstry
Academy 0f3el.a. USS R. The collection pertains to different
branches of *Iectroctlemic at kinetics, doubt* layer theories -1
,!c pr,acod.8:d, do post ad i du tr I
to.hbri dl c.n are given at the end of esch d1vI
sion,,hTh.,zaJorlty,Oflr1 DO Pt a :.at Included he" have been
pub!,,.,d. n,rrlld on literature. No persOnAlit-05 art m-tioned.
..fgiven at the end of most or the articles.
Oak (Institut geokmoll I analitichookoy kh1mil
AM S: Iment V.I. Vernadskogo - Instl tu to OrI try
and Aly-tlc.l Chemistry L.onl V.I. Vor-d
'an t P,.,."
Sclan`a9,,.USSR). Diffusion of glectrolyto,
cthod
graph. brr
"a B-S.t-tt; E.A- Zhlo.-Lova (Institute of Phyi1c:1
Ch..IBtr7. academy or USSR). Diffu-1- yg-
Through 71r, In rllvz or Eirctroiyter Ct34
Discuss I an ( a-Katnthok, Yu. A. Chltmd2h*v, ru. A. Vdovin,
01a, Khachi!ryan and contributing authors] 689
PART 7111. 9LXCTRXHEPqZc AL PROCESSES ZM NONFERROUS 695
METALLURGY
St*nder .-T 7. (Dnepropetrovsk InstitutooorcChomical Technology
Town-, V-9 Dz.r.hinakly; lr~lttutrhemifttry
as: so a " n d-
of Scl..c; X&ZSSR). zlo,ctroly to I -; C-Abinin.
Card 27/ 34
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ACL"Yg-kly. P.T. (X---kh StIt, Ulil-11t,. Acade-y of Scomnc,m,
Ant -FrT:-- Some Proble- or A-alrhm Ketajurgy iun
or Metals with Amajg_3
(04
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A11aY.
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P5662
5/075/60/015/004/002/030/XX
B020/BO64
AUTHORt Panchenko, I D~
TITLEs Derivative Polarography on Solid, Rotating Electrod,-s in
Molten Salts
PERIODICAL: Zhurnal analitichaskoy khimii, 1960, Vol '5. No 4..
Pp~ 388 - 390
TEXTs Since a number of metals is obtained by electrolysis of molten
salts, the investigation of the electrochemical properties of the
accompanying substances is of interest, which is possible in each case by
means of derivative polarography Ye, M Skobets (Ref, 1) obtained the
derivation peaks for a number of compounds on solid electrodes and in
aqueous solutions, and N. G, Chovnyk (Ref 2) in molten salts The author
aimed at determining the decompos4tion voltage of some metal chlorides,
studying the change of the diffusion current as dependent on the speed of
rotation of the electrodes, and the change of the polarization curves as
dependent on the rate of polarization, Silver, lead, and cadmi-in
chlorides were investigatedi a eutectic LiCl-KCI m,.xture was used as
Card 1/4
85662
Derivative Polarography on Solid, Rotating S/075/60/015/004/002/0~0/XX
Electrodes in Molten Salts B020/BO64
supporting electrolyte, and the polarograms recorded with a HeyrDvsk~
polarograph.. The sensitivity of the galvanometer was 1 6 10'9 a/ra T~e
investigations were conducted at 400 C, and the temperature was kept :rn
stant to within +20C by means of a thermostat Porcelain crucibles W'.tr'
a platinum mire cathode and a platinum plate anode served as electroly?-75
The electrodes had a speed of 100, 500, 750, and 1500 rpm Fig 1 gives
the scheme of the polarographing cell The authors first recorded the
usual polarograms with separate and joint precipitation of the metals on
an LiCl-KC1 background. With separate precipitation of the metals.
reproducible polarograms were obtained, whereas with joint precipitation
no positive results were obtained The decomposition voltage of the
supporting electrolyte equals -2 3 v The half-wave potential for silver
is 0.9 v, and for lead, 0 95 v In the reduction of cadmium chlorido, twc
waves were obtained; the potential of the first half-wave was ' 1 v and
that of the seoond one, 1 3 v In the authors opinion, the first wave
corresponds to the reduction of cadmium chloride to the subahlorldo. avd
the second to the reduction of the subehloride to metallic cadmium At a
concentration of 0.001 molar parts, the diffusion current limits were
Card 2/4
P5662
Derivat',ve Polarography on Solid, Rotating 3/075/60/015/004/002/030/XX
Electrodes in Molten Salts B020/BO64
0.24 ma for silver, 0.32 ma for lead, and 0 16 and Q~06 me, respectively,
for cadmium. The derivative polarograms we:-e recorded at a sensitivity of
S-1/200. The derivation polarograme of ailver precipitated from an
LiCl-KC1 supporting electrolyte at an AgCl concentration of 0.001 molar
parts (Fig. 2) and of cadmium precipitated from an LiCl-KC1 supporting
electrolyte at a CdC12 concentration of U007 molar parts (Fig 5) are
given. The derivative peak potentials of the chlorides investigated
correspond to those of the half-waves with insignificant deviations The
derivative peaks (Fig. 4) resulting from coprecipitation of silver and
cadmium are similar to those found in coprecipitation of lead and cadmium
With a rotating cathode, the height of the derivative peak as compared to
the stationary electrode is twice as much at 100 rpm, at 500-750 rpm, three
times as much, and at 1500 rpm, four times as much The respective
derivative polarograms are shown in Fig. 5 An exact mathematical relation
between the speed of the electrode and the height of the derivative
polarogram peak cannot be established The diffusion currents on rotating
electrodes in aqueous solutions increase 15-20 times at 700-800 rpm;
diffusion currents in melts are, therefore. 9 7 times smaller than in
Card 3/4
Bq66',~
Derivative Polarography on Solid, Rotating 3/07 60/0151/004/0021/030/XX
Electrodes in Molten Salts B020YB064
aqueous solutions, which is due to the temperature of the former sin-e th~-
diffusion coefficient is an exponential function of temperature Sin':9 the
coprecipitation of the metal ions examined showed no positive results :,Y:
ordinary polarograms' the polarograms were recorded for low rates of
polarization (10-20 mv/min), and it was found that, at low rates, the,
limiting currents are recorded in the coprecipitation of metals (Fig.
and the stepwise reduction of cadmium chloride is confirmed, This paper
was read in the Analytical Section of the VIII Mendeleyevskly sl'yezd
(VIII Mendeleyev Congress) on March 21, 1959 There are 6 figures and
8 references: 6 Soviet, T-US, and 1 German
ASSOCIATIONs Institut obahchey i neorganicheskoy khimii AN USSR, Kiyev
(Institute of General and Inorganic Chemistry of the
AS UkrSSR, Kiyev)
SUBMITTED: June 15, 1959
Card 4/4
1310
AUTHORS: Panchenko, 1. D., K.
TITLE: Electroly~ic RecDveri' :f J_eaj Fr:.m --.e Fac-:-1,-
Mel-ed
Lead and Bismull', Dr.Dss
PERIODICAL; Zhurnal prik I a d n - y kh i I , 196 ~, '1:; 1 3 3 , NP P
156 (USSR)
ABSTRACT: Large-scale labora*.~_,ry experiment.s
lead refining were :.-~~nduc!..ed in _;rder lu f*i)%.J 1-e te2,
conditions and materials for removing Impuri',Ies
lead and for producing different grades ~;f lead. Crude
fact3ry lead and bismuth drDss were ~;sed. T-e
c-lncl-_~sions were made fr~~zT. ~_'.ne da'-a ~)t,.aine~l. T 'I, e s e
eW-ec'ic eleclr-~'yles may Itle used in e.!ec'r-'.-.Y' lc -'ea",
refining: PbC1 -KCI-NaC1, FbC1_-NaC,, and
2 e
It was found thal by refining -he cr-.~ije lea--3
recc)very of the ca!~~'..ode lead, grade leal "Is
wil-n _D096 rec-overy, graie C_ lead is _-1;1a;nej;
If
Card 1/2 rec3very in a 1~riple and. doublme e,~-_ec7ic :f '.eaj,
-7 C::
Electrolytic Recovery of Lead Frzm e
Factory Crude Lead and Eismut '- Dr.-Ss
Using Melted Electrolytes
SUBMITTED:
C
pz:-ass ~.m, an' !~,-ade
.:-. e e I e c re-
ob~ailned. 1* ,,;as
fining of bismuth. qross containing ~% _-A- Bi-, I-ade
CI lead car. be ch'alned (~,ne 1.h~u3andt_~~ Df a oercen'
-f Fi); dr':~ss C-n-aining 13% of B4
L yields grade 4~
c a d e lead ~)!-.e ~.f a -,.ercen'~
of Bi I- was
con3i 4Dns are ~-p'im a ar.-',_~e
curren.- iensity (D a), 11
amp,,cm
density (Dc amp,.-,r-.,:'. Yield based :,n c-,r:-e,,-.'-,
Elec-r.**2 erle--
There are :a'1-:es; and referer~ces.
Novemter
Card 2/2
17
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.ZTxu TV21 -M-21.0m
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2- TT Z-a "ll-S) (-1-W 'n M-44
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T_.j
jidw
S/0%61/000/00~~ -z
D210 D303
AUTHORSt Delimars'kyyl; Yu.K., Member of AS UkrSSF, Par..-n-nki
I.D., and Shylina, H,V.
TITLE: Rotating disc eie,~trode in the polarography of
fused salts
PERIODICAL: Akademiya nauk Ukrayins,koyi RSR~ Dopovidi, n2.
1961, 205 - 208
TEXT: The authors state that the ql)est--on of theore*:--al-y -.n--.:-
preting polarographical curves obtalned for fusea
with the use of stationary or revo-ving cyiindrica- e-e-tr-.r,~s -an-
not be regarded as solved, because di-~'ferent investigators r-rose
different equations for their interpretation. Oniy V.G- Lev-~.'-L
Ref. 3: Fiziko-khImicheskaya gidrod-~namika, FizmaLgiz, M.,
Physico-Chemlcal Hydrodynamics)) worxed ou-, a theory 0:-
~
tive diffusion of a -otating nisc elec-rode, i-.s equizy natl-g t-e'~In
proved for aqueous eie---,ro1y--e sou!-on3, The tni-.kness
Card 1/6
Rotating disc ele--,rode -.n D_' 0/ D5C"
diffusion layer is g:ven by '~ne eqa'.-1on
z ~ 1~6 * ID Y-~ ,
where 5 is the layer thickness,
kinematic viscosity. w - angula.
electrode. The ultimate -urreni
nFDC
-d 5
Y1/6 - WY -,
D - -oeffi,~ien'~ of J,-ff_is:_,;
velo-~_Ty of tne ro,,a-ing is-
valae :s gLven by -he
which, taking in--o accc-.in-, Eq., (41 ma oe expressed as
2,1 3
1d = 0.62 nFD
The authors decided to apply Lev.-,,h 9 'iecry to fused saits.
obtained polarograms of a series of e ~Lroiyie8, using a
disc electrode. They investigated Ag: Pb7,1 CdC:, and T.,"_ on
21 6
the background of a fused mixture o- C1 - KC-*. PD!arograms were
Card 2/6
S~'-0211'611000.- O,Dl-f
Rotating disc electrode in ... D210/D303
obtained by means of a check polarograph LP55A, Experimer.~s
carried out at 4200C in a china crucIble, cap.- 100 ml, sn- ~-r
was a platinum plate of 4 cm2, the cathode a platinum miz:r:a
set in a molybdenum tube, discis angular velocity 100, 500 ar-
rev/min. Apart from normal polarograms they obtained der:vat~.t.L2
ones, by using an electrolytic condenser, consecut-,ve-y
with the galvanometer. The depolarizer concentrations weTa n 7.-
range of 0.0005 to 0,003 mol fractionsz Their f--'-rst obje--'.' Na:-
investigate the dependence of the limit-current on the -a-.-?
electrode revolutions. Polarograms obtained with diffteren,
trode angular velocities are shown in Fig. i. On the basis - .--e-
se, the authors found that the above dependence can be
by the equation: 0.58
id - K - w
This is in agreement with Eq, (6), which follows from Le-;- h
connective diffusion theory. They thus proved the adequaccy of' thIs
theory for fused electrolytes. ir which It is possible t:, .a,3e a r--
Card 3/6
Si 02- / 6 1 /000
Rotating disc elecirode in D213/D303
tating disc electrodez Their experimental resuits are g:v~_-n,
bulated form. Two waves were observed for cadmIlum an~
des which is obviously cue to the formation of univa.er.'.
The authors express the opinion that the use of tne rotat:n,-
electrode allows polarographic curves to be obtained wIth
concentrations than with the stationary ones which is a
its higher susceptibility and permits a more precise
interpretation. Kinematic vis2osity values being known, P'S-
sible to calculate from Eq. (6) the diffusion coeffic_er_-.S -!. -- V_~
sed electrolytes; the authurs found that this c-oeff.J*:-_e.--. --jr
ver ions equals 0.9 ~ 10-5:m2/sec, which is in good ag7c7me'~' W-il
data obtained for determining it by different methcJs. iArs-_-,
tor's note: Methods not giveril. There are 3 figures, 1
8 references: 6 Soviet-bloc and 2 non-Soviet-blo2, The ref,~ren.es
to the English-language publications read as foilows. E..D-
T. De-Vries, knalyt. Chem,. ~7, go6, 1955; J_ C--,rber,,, S. VLnt.~P~,
F. Alberts, Jz Am- -ahem. Soc., 79, 3020, 19`57,
Card 4/6
S/021/61/000/002/01-1/0-13
Rotating disc electrode in ... D210/D303
ASSOCIATION: Institut zagallnoyi ta neorganichnoyi khimiyi AN URSH
(Institute of General and Anorganic Chemistry, AS
UkrSSH)
SUBMITTED: 6eptember 3. 1960
Card 5/6
PANICHENKO, I.D., kand. tekhn. nauk; VEDMIDI, M.P., kand. tekhn. nauk;
NATANZON, I.I., kand. tekhn. nauk, red.; KOSOVSKIY, V.A.
[Kosovslkyi, V.A.], red.; KVITKA, S.P., tekhn. red.
[Temperature conditions of a lubrication system and their
reguUtion] Temperaturnyi rezhym syete?W mashchennia ta iolio
reguliuvannia. Kyiv, Vyd-vo Ukr. Akad. sillolkohospodarslkykh
nauk,, 1961. 146 p. (M3RA 15:4)
(Tractors-Lubrication)
PANCHENKOP I.D.; SHILINA, G.V.
Rotating disk 6lectrode in the polarography of fused salts.
Zhur.anal.khim. 18 no.8.-920-923- Ag 163. (MIRA lb:12)
1. Institute of General and Inorganic Chemistry, Academy of
Sciences, Ukrainian S.S.R., Kiev.
PANCHENKO, I.D.; SHILINA, G.V.
Theor7 of convective diffusion in the polarography of fustA
salts. Ukr. khim. zhur. 29 no.Ilt1164-1169 163. (MRA 16:12)
1. Institut obshchey i neorganicheskoy khimil AN UkrSSR.
J .1-.h F4T (rn)/ETC ( f VETi 1J Pc DS/,-ID/.TG
ACC NRi AP6013084 SOURCE CODE: UR/0073/65/031/011/1203/1206.
AUTHOR: Panchenko, I. D., Penkal I. I.
Lo
ORG: Institute of General and Inorganic Chemistry, AN UkrSSR (Institut obshchey i
neorganicheskoy khimii AN UkrSSR)
TITLE: Polarographic study of rare earth elements in fused potassium bisulfate as the
supporting electrolyte
SOURCE: Ukrainskiy khimicheskly zhurnal, v. 31, no. 11, 1965, 1203-1206
TOPIC TAGS: polarography, lanthanum oxide, gadolinium compound, yttrium compound,
cerium compound, europium compound, potassium compound / LP-55A polaro raph
ABSTRACT: A polarographic study of oxides of lanthanum, gadolinim, yttrium, cerium,
and europium was carried out in potassium bisulfate as the supporting electrolyte by
I'sing a rotating disc electrode. The reduction polarograms were recorded on an LP-55A
polarograph at 2400C, and the half-wave potentials of the reduction of the oxides were
determined: Ei/2 was 1.1 V for La203, 1-08 V for Gd203, 1.03 V for Y203, 0-9 V for
Ce02, and 0.4 V for EU203. Thus, the deposition notentials differed appreciably in
this fused electrolyte.~ The limiting diffusion current was found to be directly pro-
portional to the concWn-tration of the oxides studied. The diffusion coefficients of
UDC: 543.253+546.6+541.133
1/2
L 30243-66
ACC We AP6013884
the ions were found to be 2.6-10-5 for La, 0.31-10-5 for Gd, 0.33-10-5 for Y, 1.11-10-5
for Ce, and 1.34-10-5 for Eu. The thickness of the diffusion layer in fused potassim
bisulfate was calculated to be %2.10-3 cm. Orig. art. has: 5 figures, 1 table.
SUB CODE: 07/ SUBM DATE: 260ct64/ ORIG RM 006/ OTH REF: 002
Card 2/2
FA NC F-ENT 5: 1 . D. ; B7 Y F M
Un,~ of var '.Le ~ra: ny
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Jnstitut 'A-I~irul~ AN llkr~~"R.
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I
'-'s e f an a -_i t -:ma '- - c -me- ~ 8 ~ i r,, ~,: 1, ng a lac trr,,-,e 1, n *~he :,~ 1 ar-F-Y
L Ir
-, I:I'a F;- salts. "hur. flz. xt~im. ~', no.21514-51~ .
, M., .? A IF ; d. '.
- Tns'.i, ;I hr-Y ' n- "imai "I"
L ~0215-66 EV1T(m)/E_rC(f )/T,/E*.NP(-,)/r--Tl IJP((,, )DLS/JD/JG
ACC NRz AP6015011 SOURCE CODE: UR/0364/66/002/005/0529/0535
AUTHOR: P chenko, 1. D.; Penkalo, 1. 1.; Delimarskiy, Yu. X.
ORG: Institute of General and Inorganic Chemistry, M MrSSR, Kiev (Institut obshchey.
i neorganicheskoy khimii X9 UkrSSR)
TITLE: Polarographic study of the cerium gr~)up of rare earth elements in the fused
LiCl-KCI eutectic as supporting electrolyte
SOURCE: Elektrokhimiya, v. 2, no. 5, 1966, 529-535
TOPIC TAGS: polarographic analysis, lanthanum compound, praseodymium compound, sama-
rium compound, europium compound, cerium compound, neodymium compound, lithium chlo-
ride, potassium chloride
ABSTRACT: In order to determine its usefulness for analytical purposes, the authors
investigated the polarographic behavior of lanthanum, cerium, praseodymium, neodymium,'
samarium, and eu in the fused LiCl-KC1 eutectic at 4000C, using a rotating plati.;
num disc electrode.j Polarograms of the reduction of the rare earth chlorides were re-'.
corded at various concentrations of the chlorides. A direct proportion was establish-
ed between the wave height and the concentration of the depolarizer. The half-wave
potentials were determined and differences between some of then were found to exceed
UDC: 541.135.3
SOV/149-58-5-14/18
AUTHORS: Layner, V.I., Panchenko, I.I.
TITLE: Blectrode Processes in Blectro-deposition of Nickel frc-,.,-
Fluoborate Electrolytes (Zlektrodnyye protsessy Dri
osazhdenii nikelya iz ftorboratnykh elektrolitov)
PERIODICAL: Izvedlya Vysshikh Uchebnykh Zavedeniy, Tsvetnaya
Metallurgiya, 1958, Nr 5, pp 124 - 130 (USSR)
ABSTRACT: The object of the investigation described in this paper
was to study the effect of various factors on electrode-
position of nickel from fluoborate solutions and on the
quality of the deposits obtained by this method. For
the preparation of the HBY 4 solution, chemically pure
H3BO3 and an HF solution (whose concentration was deter-
mined from its density) were used in the stoichiometric
ratio, R 3BO3 being added (a small quantity at a time'.
to the continuously stirred and ice-cooled BF solution.
To the obtained HBF4 solution, also continuously cooled,
nickel carbonate (a small quantity at a time) was a4ded
and in this manmer it was possible to-obtain solutions
Cardl/8 containing up to 180 g/litre nickel in the form of
SOV/149-58-5-14/18
Electrode Processes in Blectro-deposition of Nickel from Fluoborate
Electrolytes
fluo'borate (density approx. 1-5), which could then be
diluted to any required concentration. The characteristics
of the experimental electrolytes (pH . 3 in all cases)
are given in Table I which shows the nickel concentration
(N . 1 to 4), the content (in g/litre) of fluorine, Fl,
present in the form of BY303, the content of fluorine, F21
present in the form of BF,-, the total fluorine content
F - 71 + F2 , the B content, the F/B and 7INi ratios,
the NiC12*6H20 content, and the density at 20 OC. Nickel
anodes and steel, copper or brass cathodes were used in
the experiments, the results of which are reproduced
graphically. The effect of the current density
(A/dm2) on the cathode potential is illustrated in Figure 1,
where graphs 1, 2,.3 and 4 correspond to the nickel
concentrations of 1N, 2N, 3N and 4N, respectively.
Figure 2 illustrates the current-donsity/cathode-potentiaI
Card2/8 relationship for electrolytes with no excess of H 3 BO3
SOV/ 149-58-5-14/18
Electrode Processes in Electro-deposition of Nickel From Fluoborate
Electrolytes
i
(graph 1) and with 5, 10 and 159/litre R BO -n excess
3 3
of the stoichiometric ratio (graphs 2,3 and 4). The
results of the tests in which the current-density/cathcae-
potential relationship was s8udied for 3N electrolytes
containing no C1 ions at 20 C agd those containing 1~5,
and 50 g/litre NiC12'6H20 at 50 C are reproduced in
Figure 3 (graphs 1, 2, 3 and 4, respectively). The sa-me
relationship for a 3N electrSlyte with no excess of
A0 40 and 50 C is shown in Figure 4
H3BO3 at 20, ~ I -
1 to 4). A 3N electrolyte was also used for investigat----
the effect of the pH number which was varied between 1
5 by mean of HBF4 or sodium iodide additions. It was
found that at pH = 5 , the electrolyte is unstable and
contains black, insoluble particles (most likely Ni(OH) 2 wit
basic salts) held in suspension. Pitting occurs and a
dendritic deposit is obtained which at low current densities
Card3/8 (1 to 5 A/dz2) becomes dark. At pH = 4 , low current
SOV/149-58-5-14/18
Electrode Processes in Electro-deposition of Nickel From Kuoborate
Electrolytes
densities result in a dark deposit, while dendrites
formed at high current densities. At pE = 1 or 2
intensive evolution of hydrogen takes place on the cath--.-Je
surface, the evolved gas forming bubbles which adheTe t-
the cathode and cause pitting. Best qualty deposir~s a.-,e
obtained at pH = 3 . Yield per unit current varies in
all cases between 89.6 and 99 '/%, increasing with -Jncrea-~.-~ng
current density and at high pi (3 to 4) values, and fai'Ling
sharply at low current densities and at pH = 1 or 2 .
In the next stage of the investigation the anodic procesc.es
were studied. Four types of electrolytes were used
containing (in &/litre): (A) 25 Ni(BF 4)21 68.5 Fl,
138.7 F2 and 34.4 B; (B) same as (A) plus 15 NiCl 2' 6E20;
(C) 240 NiSO 4'7H20, 30 H3BO 3; (D) same as (C) plus
20 NaCl. Cathodes were made of electrolytic nickel or of
non-passivating nickel containing C 0.2%, Si 0.2% anrl S G~00
(Ref 12). To reduce to minimum the difference between their
Card4/8 true and the geometric surface areas, the cathodes were
SOV/149-58-5-14/18
Electrode Processes in Electro-deposition of Nickel From Fluoborate
Electrolytes
olished first mechanically and then electrolyticall-'y
to remove the plastically deformed layer). The results,
f
in the form of graphs showing the relationship between
the anodic current density and the anode potential, are
reproduced in Figure 5: graph (1 n -passivating nickel
anode in electrol7te C; graph (B _- a0sn(l) but electrolyte
D used; graph (3) - non-passivating nickel anode in
electrolyte A; graph (4) - as (3) but in electrolyte B;
graphs (5) and (6) - electrolytic nickel anode in electro-
lytes C and D, respectively. When the ratio of the anode
and cathode surface areas was S a/Sk = 2:1, the yield of
the dissolved metal per unit current was high even in the
absence of chlorides in the electrolyte but for
F)s/Sk =1:1, a slightly lower yield was obtained. After
the bath was operated for the equivalent of 800 A.hour
per 1 1tre of electrolyte the concentration of the nickel-
bearing salt in the solution was unchanged and only a
slight rise in the pH number was observed. In their
Card5/8 conclusions the authors state that: i) the main advantage
SOV/149-58-5-14/18
Electrode Processes in Electro-deposition of Nickel From Fluoborate
Electrolyte
to be gained by using the fluoborate electrolyte instead
of a sulphate solution for nickel plating is that the :rDcess
can be intensi-fied, i.e. Ugher current densities can t;e
employed without affecting the quality of the deposit
and yet without reducing the yield per unit current. Tlie
maximum permissible current density can be increased by
increasing the Ni concentration in the electrolyte (up to
3N) and by using higher temperatuxesi a when the
concentration of H 3BO3 in the electrolyte is increased,
the cathode potential is reduced and so is the maximum
permissible current density. In spite of this effect,
which is probably due to partial dissociation of
Ni(BF 30H)2
Ni(BF 4)2
to
and to a decrease in the activity
of the nickel ions in
to maintain the H 3BO3
15 g/litre) above the
stoichiometric ratio,
Card6/8 stability of the electrolyte
the electrolyte, it is recommended
concentration slightly (approx.
value corresponding to the
since free H 3B03 improves the
and makes it less reactive;
SOV/149-58-5-14/18
Blectrode Processes in Blectro-deposition of Nickel from Fluoborate
Blectrolyte
iii) the effect of chlorides introduced in the electrolyte
in the form of NiGl2.6H20 in amounts up to 15 g/litre is
beneficial, since they reduce polarisation. However, at
high (more than 30 g/litre) chlorides concentrations, the
maxI-1- permissible current density is lower and the 0
quality of the deposit is adversely affected. At 50 C,
the effect of the chlorine ions becomes insignificant,
most likely owing to the reduced adsorption of these ions
on the cathode surface and to sufficiently high activity
of the sAode, particularly when made of non-passivating
material. Owing to the latter factor, the fluoborate
electrolytes are quite stable, so that in operation it is
only necessary to replenish the fluoboric acid in order to
maintain constant pE, since the anodic yield per unit
current is slightly higher than the cathodic;
(iv) the optimum value of the pH number of a fluoborate
solution for nickel plating is between 3 and 3.5. At
pH - 1 . the yield per unit current is too much affected
Card?/8 by the variation of the current density, while at
PANCHENK09 I. Lp Gand of Tech Sci - (diss) "Electrolytio NicM1 Plating by Cobalt
and an Alloy of Nickel and Cobalat From Fluorinated E2actrolytes," Moscow, 1959,
22 pp (Institute of Non-Ferrous Metallurgy im M. 1. Kalirdn) (KL, 4-&, 120)
0v, -
AUTHORS: Layner, V.I., Doctor of Technical Sciences, Irofessor,
and Panchenko, I.I., Engineer
TITLE: Nickel Plating in Fluoroborate Electrolyte
(Nikelirovaniye vo ftorboratnom elektrolite)
PERIODICAL;Vestnik mashinostroyeniya, 1959, Nr 5, pp 65-66 ~USSR)
ABSTRACT: An experimental study is reported concerned with the
effect of each of the main factors on the nickel
plating process in fluoroborate electrolytes. The
solution of hydrofluoboric acid was prepared from
hydrofluoric and boric acids by mixing the latter
into the former in small doses accompanied by stirring
and external cooling. Small doses of nxckel carbonate
were added accompanied by cooling. Concentrates with
a specific gravity Of 1.5 containing 180 g/litre of
nickel can be obtained an fluoroborate of nickel.
The fluoroborate of nickel has the formula
Ni(BF4) .6H20 A method of analysis was used
'
i
sa, I.G. ("The Chemistry of Fluorine
propose
by Ry
and its Anorganic Compounds" Monograph. Goskhimizdat,
1956). Nickel was determined by the alkaline solutlion
Card 1/5 of di-methylglyoxime. 500 milli--litres of diluted
SOV/122-59-5-22/32
Nickel Plating in Fluoroborate Electrolyte
concentrate were used in each test with a nickel
anode and a cathode of copper, iron or brass foil.
The current efficiency was measured with a copper
coulometer. The specimens were electro chemically
degreased, pickled in nitric acid (copper, brass)
or hydrochloric acid (iron), washed in water then
in alcohol, dried, cooled and weighed, Befare j=iers2ng
in the plating bath, the specimens were pickled in a
10% solution of sulphuric acid, washed in mains water
and finally in distilled water. After plating, the
specimens were washed in cold and hot water and in
alcohol, dried, cooled and weighed. The curves of
voltage against current density were plotted from
measurements by the compensation method using a
platinum disc cathode soldered into molybdenum vlass.
Before taking the readings, the cathode was zovered by
a 5 micron coat of copper from a sulphuric acid
electrolyte. The deposited nickel was removed in hot
Card 2/5 50% HNO3 or- by anodic dissolution in io~u H2S041
Nickel Plating in P'luoroborate Electrolyte
..)OV/122-59~5-22/32
The anode was a disc of non-passivated nickel,
Examining the effect of nickel salt concentration an
increase from I N to 3 N solutions at a pH of 3.0
and 500C increases the permissible current density.
Deposits of 25 microns are obtained without burns and
dendrite formation at the corners. Further increase
of concentration is not profitable. The concentration
of boric acid has no effect on the current efficiency
and the quality of the deposit. Solutions with a
small excess of boric acid (10 g/litre) are more stable.
The effect of chlorine ion concentration was studied
by using electrolytes without chlorine ions and those
with 15, 30 and 50 g/litre NiC12.6H20- Without chlorine
ions, the quality of the deposit deteriorates., pitting
increases, the current efficiency diminishes and the
permissible current density drops. 15 9/litre is the
beat concentration. A temperature increase i3
beneficial by reducing polarization. The permissible
current density increases and the quality of the deposit
Card 3/5 improves up to a tsmperature of 60"C. The pH value was
Nickel Plating in Fluoroborate Electrolyte
.-~OV/l 22 59-'-, -22/ J,e'.
studied In the range between I and 5~ At a value of 4
and above the solution becomes unstable. At values of
1 and 2 the deposit contains much small pitting. The
optimum value Is 3. The buffer propertipq were studied
at a temperature of 20'C by adding to fresh samples of
50 millilitre of electrolyte quantitlea of 10; 20 and
30 millilitre of 0.2N solution of NaO11 and 0.2N solution
of HC1 and the measurt~ment of the pH value of the
solution by the quinhydron method, The electrolytes
differed in the nickel, boric acid and chloride content.
Sulphuric acid electrolytes were examined alongside
the fluaroborate eleztrolytes. It was shown that
fluoroborate electrolytes have a substantially greater
buffer prcperty than sulphuric acid electrolytes with
buffer admixtures. The stability of the electrolyte
of the optimum composition,. after plating under optimum
conditions.was judged by analysis for nickel fluorine.
boron and the pH value after 100 ampere~hours A very
good stability was observed. The anode to cathode
Card 4/5 surface ra-.io was -,aried between 6.1 and 1~1
Nickel Plating in Fluoroborate Electrolyte
SOV/122-59-5-22/32
After 300 ampere.-hours per litre of electrolyte, the
nickel, both forms of fluorine and boron contents did
not change. The pH value rose from 3 to 3.4, The
anode and cathode polarizations were plotted (Fig 6).
The adhesion of deposits on iron, brass and copper
specimens was judged by bending over 180* until fracture
and by heating to 150*C. Deposits of 10, 30, 6o, wo
and 500 microns were tested. Except in the thickest
deposit, no delamination was found. 1n deposits
beyond 30 microns, porosity was not observed. There
are 6 figures, 1 table and 11 references, 8 of which
are English, 2 Soviet and I French.
Card 5/5
PANCHRIZO. Ivan Ivanovich; PROKOPYRY, K.A., kand.tekhn.nauk. retsenzent;
9~ 1- h -ad - VASILOYEVA, V.P.. red.izd-va;
nz ., i .,
SHCMININA, L.V.. tekhn.red.
[Vibration resistance of turbine blades] Vibratsionnnia prochnost'
lopatok turbin. Moskva, Gos.nauchno-tekhn.izd-yo mashinostroit.
lit-ry, 1959. 25) P. (MIRA 12:9)
(Blades--Vibration)
M dj~
Vl-)~LWfFll, i,', , -~.
*:-: but ',.n
.-. I I~cv and K-,:~ v
F , ". v I -., - ( - . z i " ; . ~ ! ,T ,49,--, '. - ;l .,. . 11 ', . " 3 no. 5 ~ 62 5
.1
C 1) t " (MIRA 18,4)
- k -4-
Alloys of Titanium With Tungsten and Aluminum," by N. T.
Gudotsov and I. P. Panchenko, Izvestiya Akademii Nauk
SSSR, Otdeleniye Tekhaicheskikh Nauk, No 2, Feb 57, PP
135-143
An investigation of the hardness, endurance, and heat-resistence
of alloys of titanium with 3 percent aluminum and 5, 10, and 15 per-
cent tungsten revealed the expedien-y of alloying titanium with both
aluminum and tungsten; these alloys are strengthened at 400-600 de-
grees (centigrade], as a result of which the hardness at room temper-
ature is increased to 44, 82, and 85-1-17 Vickers units for the corre-
sponding percentages; hardness and endurance increase with increased
tvagoten content. (U)
USM/Microbiology Antibiosis and Symbiosis, Antibiotics. F-2
Abs Jour : Ref Zhur - Biol.: No 4, 1958, 14736
'tuthor : Gromashevskaya, L.L.. Golub, W.F., Panchenko, I.F.
Inst
Title Sensitivity of Dnrseatery Bacteria to Biowjcin.
Orig Pub V sb.: Disenteriya, Kiev, Gosmedizdat USSR, 1956, 62-69
IbStract Studies of the sensitivity of 120 strains of Flexner bacte-
ria of various serotypes and 80 strains of Sonne bacteria
to bionycin M, levonw~;etin and norsulfazole shoved that
the most active I depressed the growth of the msin mass of
bacteria (91-5% of strains studied) at a concentration of
0.1-6.0'r/al. Sonne bacteria are more resistant to acti-
vity of I than Flexner bacteria, the sensitivity or which
did not depend upon belonging to a definite serotype. 7he
microorganisms are more sensitive to I on a MDore than on
a Drobetko medium. I decreases oxygen eonsuwtion on a
propiferating as well as on a non-proliferating culture
Card 1/2
Card 2/2
137-58-~-4253
Translation from~ Referativnyy zhurnal, Metallurglya, 1958, Nr 2, p ?_81 (USSR)
AUTHORS: Gudtsov, N. T. , P.an.chen_kp_,__I,P.
TITLED Titanium- tungsten Alloys (Titanovol'framovyye splavy)
PERIODICAL: Sb. Mosk. in-t stali, 1957, Vol 36, pp 5-12
ABSTRACT: A study was made of the effect of W on the microstructure,
hardness, and long-term strength of magne sium -fusion -process
Ti alloys (with 5, 10, and 15% W contents) smelted in graphite
crucibles under a residual pressure of 10-2 mm Hg and contain-
ing 0.7- 1.0% C. The alloys, quenched in water after being main-
tained 1-2 hours at a temperature of I I OOOC, had the micro-
structure of a transformed A and molecular phase containing
r%.* 10.50/. C. As an alloy's W content was increased, the micro-
hardness of the molecular phase increased also, as a result of
its enrichment with W. Quenching reduced the hardness of Ti-W
alloys and increased their ~ . After being annealed at r-4 8000
they had a three-phase structure. a molecular phase and two
solid solutions based on 0(-Ti and W. The microstructure of
alloys which had been aged at 200-5000 for 10-24 hours retained
Card l/?_ the acicular form it had acquired as a result of the quenching.
137-58-2-4253
Titanium- tungsten Alloys
As the W content was increased. the formation temperature of the high-
strength phase rose from 2000 (in the case of the Ti) to 400-5000 (in the case
of the Ti/15%-W alloy). Gradual heating both intensified and raised the t.emp-
erature of the dispersion -hardening process in the W-enriched alloys. Heat-
ing to 6000 caused coagulation of the high-strength phase and a decline in
hardness. At 650-7000, under a stress of 10-20 kg/mm2, the investigated al-
loys exhibited a relatively low long-term strength, which increased, however,,
concurrently with their W content.
G.T.
1. Titanium allays-Microstructure 29 Titanium alloys-Produotiou
3. Titanium alloys-Test methcda Titanium alloys-Test results
Ca rd Z1Z
--- PANCHENO., I.P.
Modernizing crank presses. Yashlnestreitel' ne.11:1-8 N '58.
(MIRA 11: 12)
(P*wer presses)
PANCHENKOLI.P.; GUDTSOV, N.T. [deceased)
Investigation of titanium allus with tungsten, aluminum,
beryllium and boron. Titan i ege splavy no. 1:134oa23
158. (MIRA 14:5)
1. Institut metallurgii AN SSSR.
(Titanium &Uoys-Metallography) (Creep of titanium-Testing)
iota) 11 - APS?RWIS
Ak"Odys,
?atom I rego splavyi astalluralys I motellevedontle (Titanium W4 Its
Allorej mtsilur4w ww mysteal motallwa) assom, lad-im
1958. 1" 0. 4,000 **pies printed.
Amer. Carroppermilng Nowbor. um Assammy of bolonevej
sm"s mal"09 V.s. ash*MLkovj To". a&.$ &.A. luselews.
ZYMOVOMONs VMS be". at vhleh a rhamm, I 30191tation (30/1200)
has be" Prepared. to a sollootion of "Lentifle papers devoted to
the study of titanium and its alloys rova three issim points of viewl
phyfleal, metallurgy, taming 04 Welding. Special Problems in-
laolude struo;:M shanges, seemn4ag daring w*141RS, de-
or me Detest of hosum fasam, Ow"Impmems at tr,&Ab-
411151 memo" or we= See oxidation as Mariana tomperabar".
Far 1. MMICAL UWALUVAI
can 3A)
Titanium and Its Alloys (Cont.) AB-1
Qudtsov, N.T. and I.P. Panchenko (Institute of Metallurgy, USSR
Academy of ScienceWY-q-n_ve_sf1_g_a__f_1on of Titanium Alloys Containing
Tungsten, Aluminum, Beryllium, and Boron 114
The aim of this investigation was to study the microstructure,
hardness, and creep of the following alloys: 5 percent W + Ti;
5 percent W + 3 percent Al + TI; 5 percent W + 3 percent Al +
0.1 percent Be + Ti; and 5 percent W + 3 percent Al + 0.1 per-
cent B + Ti. The following materials were used for making the
alloys: Mg-reduced titanium (99-93 percent), aluminum (99.99 per-
cent), beryllium (99.3 percent), and ferroboron (20.45 percent B).
The alloys were vacuum-melted In graphite crucibles. The Ingots
were forged at 800-11000 C into small rods, from which the test
specimens were made. Quenching was carried out at 1100*. The
specimens were heated in evacuated quartz tubes for 2 hours, af-
ter which the tubes were broken in water. Conclusions. 1) Al-
loying of t1tanium with W, Al, Be, and B reduced Ehe creep rate
26-40 times at 5000 C and under a tension of 5 kgp/mm~ during a
528-hour test period. 2) The alloys tested should be used at
temperatures below 5000. 3) Measurement of hardness In a vacuum
installation in the process of heating at progressively higher
temperatures permite the deterraination of the hardening range,
Card 25/ 43
Titanium and Its Alloys (Cont.) AB-1
and measurement of hardness during Isothermal holding at heat
makes it possible to trace the rate and duration of the harden-
Ing process and tu make a proper choice of aging conditions for
the alloys. There are 5 figures, 7 tables, and 3 references
(2 Soviet and 1 English).
PART II. FORMING OF TITANIUM AND TITANIUM-BASE ALLOYS
Favlov, I.M. (Institute of Metallurgy, USSR Academy of Sciences)
General Conditions for Forming Titanium and Its Alloys 124
Titanium and its alloys require special conditions for hot and
cold forming. Cold deformation of TI (alpha phase), as In other
metals with a hexagonal structure (Mg, Zn, etc.), is accompanied
by marked twinning. Cold ductility of Ti is greater than that
of''theBe other metals because of the greater number of possible
slip and twinning planes. In a single cold-forming operation,
Ti and its aommoner alloys can be deformed by not more than 30
percent. With fractional (or repeated) deformation the figure
can be brought up to 80 percent. Cold working in a particular
direction causes anisotropy to develop. The crystal anisotropy
is weak, but the mechanical anisotropy rises sharply when car-
Card 26/43
A UTHOR: -Panchenko, I.r. SC)7/1 I 7-5'~- - 11 -5/,76
TITLE: The Modernization of Crank Presses (Modernizatsiya krivoship-
nykh pressov)
PFRIODTCALt Maahinostroitell, 1956, Nr 11, pp 7 - 9 (v'-)1i)
ABSTRACT: Crank presses of the firm "BernlhgELUZ", with a pressure of
180 tons and more, are used for cold drop fortring, The fric-
tion clutch of these presses has been modernized by engineers
of KhTZ. There is 1 diagram.
1. Forge presses--Performance 2. Ciutches--Design
Card 1/1
PANCHMMO, I- F-
Mechanized conveying of carts. Mashinostroitell no.11:23 5 160.
(MIRA 13:10)
(Conveying machinery)
.-N-V, Than Mikh,-yiovich, xapltan-nactavnik;
iV44
afi* vr, t k
te-eyev-i c r. Kaj~~ ar.-nast
!Y t av-':ift tanKurui
,!)alainp tankers to ,.h.-,
v AntarktJk-u. !.'cr4va,
Yri
"The Cllndc&-' buloriancE: .1 ~Ieclruc~~r- in the
Con ition cf the -yF;t- -r~ 41!e : 4"g
1 isturb&nces. " Canc Vet -)c-J oscow ' echno-I oEi--~--I '-nst Z)! 'he 1' e,,, t &nar-f
In6ustry, 6 jan 55. (VI. , 27 ec 54'
Survey of ScientifiC ap TecNii c!~ 1. is.-~-rtqtions e,er~e( al '.it her
Educational Inst"tutions (2,-'
SG: Sum. ',o. 556, 24 Juz-65
PANCHENKO, I.Ya., PUCHKOVA, S.M.
Condition of the organism of lambs poisoned with strontium-90.
Veter-inarila 42 no.5t77-80 My 165. (MJRA 18t6)
1, n9hI)j-67
ACC-,N-R~.=, 602-Y427
SOURCE CODE: Uu/0205/66/006/004/0625/06-7
Dobryakova, G. V.; Fanch!~nko,_ 1. Ya.; ?ovalyayov, A. P.
ORG: none
TITLIZ: Ratio of strontium to calcium upon passage from rations into dog skeletons
SOURCE; Radiobiologiya, v. 6. no. 4, 1966, 625-62?
TOPIC TAGS: dog, isotope, calcium, strontium, biologic metabolism, food ration, bone
ABSTRACT; -losts were conducted for 180 day5 on 2 groups of dogs whoso ovorall and
minoral mot--boli:.ri had boon raised to a slightly ponitivo �31cium balanco. 7,10 do'G
were fed bone meal from animals v?~jo had received strontium for a long tine. Loses.
for groups 1 and 2 were 4.4 x 10-Y and 4.4 x 1OZ8 curio and 1 and 10 g calcium
:respoctively. The animals wero sacrificed after 30, 90 and 180 days and samples of
:rations. bone, blood, soft tissuo5. urine and feces were studied radiometrically and
chemically. In group 2, the absolute strontium90 accumulation in bone was only 2 fold
;that of group 1 although its content in the ration was 10 fold. Calcium and strontium
,absorption in group 2 uras 1.5-2 fold that of group 1. No statistically valid
~differenco was found for the calcium content of bones from the animals of groups I and
:2. The same applied to soft tissues and blood. Results show that the uptake of
icalcium and strontium from the gastrointestinal tract and their accumulation in the
I
j Cord 1/2 U 088.91p612,014.48Z
L 09hl4-67
i ACC NR: AP6029427
body occurs in a certain ratio; thus their metabolism in the body is apparently subject
Ito the same rules. The uptake depends on the Ca/Sr ratio with a discriminatory
,correction for Sr. Q7ig. art. has& 2 tables.
14-0 CODE: 06. 07/ SM DATgs 4Feb65/ WZ REFs 002/ OM RUs 004
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t6 bit to bandle reaults taw vntbio
04m!!,= unit H CLARKS
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T-
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463. C&PI LARY PYCNOUSTUR FOR DEMMINING SK-CIFIC GRkVJTY OF
go %I GASOLIAW. PlOtnOvs, 0- V and PaMbSui~q#_ A. N. 60
000 (wertyanoe Khos., 1947. 2b: (2), 50-60; Chem. Abstr., .00
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PANCINNE, Kh. N.
'apilla.-y .3ycnonf- er tz:, )eternine '-he pecific 'rawit of
i. illetneva, Kh. N. eanchenko, 2 pp
"';eft---ano-,- Vol 2
Tche:-.ati:~ da.~m: a qraph. Jisc--sses :iea~; ren,&its isope:itwi,-,
benzol, isoorc-~-.-l-bEmzol, unl. avia-don ~as, a ta'jle.
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GIADILIN, A. N.; DUBININ, N. P.; ZHVETLJ140V, P.P.; NAZAROV, S.T.; PANCHERIKO, K.F.;
POPOV, V.A.; POPOV, L.A.; and STORDZHEV, M.V.
Tekhnilogiya Metallov, published by Mashgiz, Moscow, 1952
+Yffx sum #148
. r
PANCHE*,":C1, F. P., e,!.
- 0 i,x. -,~S'KVI , '.,'
P
,ussir,n scientism - s - fourl~ers ('f the A riimti
I t . , 7 ;,. .f
tekh: - . i zd-vo W 5~. - 7-0 ~ i, . 1. it -r.- , ! 3-,.-,' R )
T, ~.- I -!. RY5
Translation from: Referativnyy Zhurnal, I-lashinostroyeniye, 191-7,
Nr 1, p. 101 (USSR)
AUTHOR: Panchenko, K. P.
TITLE: Screw Profiled Form Cutters (vintovyye fasonnyye
PERIODICAL: Rezaniye metallov I instrument. Sbornik (14VTU, 1)4),
Moscow, 14ashgiz, 1955, pp. 111-135
ABSTRACT: The author presents a mathematical analysis of the dewr,--e
Of Drecision of a screw type thread form cutter and a
method of calculating design data. It was establish,,~-i
that the most important factors affecting the cutting
precision are the taper ofC)o , the relief nd rake
angles,and the angle of rofile diStortion~- . maxillium"
error with,~'/, = 60 and is 1.4 mm. The longer tht-
tapered part of the cutler=jeoc) and the shorter the C1
of the wider bas h
e (f), the greater the error. Wit
and-t = 30 mm, the error reaches I to 1.2 mm. The effect
of other factors Is practically nil. On comparing the
obtained data, the author concludes that screw profiled
Card 1/1 form cutters are as accurate as disc form cutters. B.L.Ya.
AIR JPOV. If F. , invthenar, B: dnkt or tskhni -ter ktk~ n-,
prof eamor-, BARYLOV. G I - - in-liener,- BXY~SPKA It Y D. , tn7.~ -na r:
BIMDICHAVSXIY. YS.G.. tr,-,)-7AA-: DOBKOV, A.A., inrhener.
M.A., kendidat tekhntrhevl-1~0, nauk; KOV.&H. V.14., drietcr feirl-ii-tp-
skikh nvuY, profeesor; V.S, doktor teklznl-hep~kri'4~', nauk:
tOlNilOVA. A.G.. karlidFit 'pl-~,ntrhesklkh rAuk,, JKUJRYj,,VTz:;m:V. L.T..
doktor kbialcheskikh nauk, orofeagor; KMYoHZVli. Ye.'~_ in?~,erer:
IAKdTTli. Yu.M., dektclr tOnnieheakikh neuk, ornfavsor; XATIR~U.11.
M.S.. twhever; SUVIYOV, kardidat tekhniche:-,klkh nsO,
SKIY, H.S., Inshener; 11 14. N. , inzherer: Y&
inzbener: PWOV. V P, ksrr, n! tekhni~,he,~klkv3 nalik:
loktor takhn t cheek t1rh nauk, o--f-essor: SA-~uV. V.V.,
cheskikh aeuk; asTAL I ~, r , teLrhnicheskilch nauk,
I,CKOLOV~'~K!Y, A.P.. dr,~-Lcr -P:~nicheskikh nauk, Drc)fesr-^r ap-eo d
sb%N"VICE, V.G., Ja7hener, Yu.--., in?v)*_r,,Fj-; ',v. I
irahener: TSAYTLIN, '_ !i., ~!.--ener; SHUKHOV, Yu.V.,
tekhnichaskikh n&O-; z5A,~tl L . , I. , kandidgt tekhnl-!hF-vtri-- i??!.
V(,Lk(!V, kandist talit.-iirhaskikh npuk: GORL
doirtor tekhnicheskt~rt nfjO-, rr,-fessor; GORCSff~IN. A.F..
90,-CHATOV. V.V., karclidall tothntcheslrik~-- neuk:
L~AYAV. 1.I.. doirt-tr fpLtn`-~Askikh nmuk, nrnfpF-~rr;
Imrididet tekhnicheskl~-,t r,,.~- MALOV. A.N., kandidp-
neuk; WWWAh, M. Yf-., in7,~erer.__UAGW~~~, v, .,dF
sirikh sauk; SkiDtATz;i. ,nzhener; STAYY.V. h.?., ~qql I. ~-A-
cheskilrh nauk; V. , i arhecer; TxUR -r fir;
,&L"f.Az4WVA, M.A. , kar ) lln + -~-hn tchaskikh nsnk;
(Continued on nert