SCIENTIFIC ABSTRACT PAUSHKIN, YA. M. - PAUSHKIN, YA. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001239510019-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ACCFMION NR: AT4008607 8/2082/63/ODD/044/0033/003t)
AUTHOM Pevushkin, Yet-Mi-Panidi, 1. S.
................
77TLE: Syntheeis of borori-nitrogen-containing compounds from borig) acid
SOURCE.- Moscow. Institut neftekhimicheekoy I gazovoy promy0shleimosti. Trudy*.
no. 44, 1.963. Neftekhimiya, pererabotka nefti I gaza, 303-38
TOPIC TAGS: nitrogen containing organoboron compound, boric acid, boric acid.
nitrogen derivative, boric acid derivative, boric acid.'arylamino derivative, boric acid.
alkylamino derivative, boronic acid.anilino-. polymer with urea
ABSTRACT: A new class of compounds containing V.,ie boron-nitrogert bond, the arylamino-
boric acids,has been synthesized by direct condensation of boric aciel with arylainines.
7be cou:rse of this reaction was found to depend primarily on the temperature at which zinc
chloride Is added to the mixture of boric acid and wnine, as well as on the quantity of the
condensation agent (aniline, p-toluldine, o-toluidine, or p-anisidino). Temperatures
ranging from 130-170C were tested to determine which particular ax-flarnino-boric acid
would result and whether the end-product would be an adhesive resin, Aliphatic amines
did notrenct, but alkylamino-borio *acids could be obtained by an exchange reaction with
an arylianino-borio acid. This reaction Is very exothermic and, with mothylamino, takes
Card 1/2

ACCESSION NR: AT4008698 8/2982/62./000/044/0043/1)047
AUTHOR: Paushkin, Ya. M.; Nizova, S. A.; Gayevaya, V. S.
TITLE: Synthesis of high molecular hydrocarbons with conjugated double bonds by do-
hydrohalogenation polymerization
SOURCE: Moscow. Institut neftekhImicheskoy i gazovoy promy*shlentiosti. Trudy*,
no. 44,1963. Neftekhimiya, pererabotka neftl i gaza, 43-47
TOPIC TAGS-: conjugated polymer, conjugated system containing polymer, poly-rinyleno
hydrocarLmns, polyacetylenic hydrocarbons, polymer, poly(phonylaccV leno), heat
resistant jolymer, EPR signal, paxamagnotic polymer, vinyl compound polymer, poly-
merizatiork, dehydrohalogenation, dehydrohalogenation polymerization, vinyis
ABSTRAcr: In view of the intereEting specific magnetic and electrophysic-Al properties
of polymeric hydrocarbons containing conjugated double bonds, the aut]:iom studied the
formation of polyvinylones by dehydrohalogenation polymerization at 200C in the presence
of excess 11"MO: Ar Ar
CH-CH, "40
"A6C11+2n11X~+ftCa0-r*
1/2
i Card

ACCESSION N11: AT4008698
The starting compounds were .(, b-dibromoothylbcnzeno, 1, 2-dibromoh aptanc and
1, 2-dibromonc-nano. After isolation of the yellow to red to brown polynicrs, they were
subjected to infra-red and electron paramagnetic resonance spectroscol:y, as well as
determinations of the chemical composition, melting point and molecular weight. 71le
polymers wl-iich were soluble in benzene had an average molecular woight of about 1000
and a melting point of 260-290C, while the insoluble polymers did not rnelt even at 400C.
The Parrow EPR band indicated the presence of paramagnetic particles in the macro-
molecule. Drkg. art. has: 1 figure, 3 tables and I structural formula.
ASSOCIATION: Institut neftekhimichoskoy i gazovoy promy*ahlennosti. Moscow
(Institute of Potroleum Chemistry &nd the Gas Industry)
SUBIWITTED: 00 DATE ACQ: Wan64 ENCL- 00
SUB CODE: C-C, MT NO REF SOV: 007 OTHER: 002
2/2
Card

PAWHKINp Ya.M.; POLAK, L.S.; VISIINYAKOVA, T.P.; PATALAKII, I.I.;
M&CHUS, F.F.; SOKOLIUSKAYA, T.A.
New iron-containing polymers on the oasis of ferrocene
and their electrophysical properties. Vysokom. s.)&J.
6 no.3:545-550 Mr'64. (MIRA 17:5)
1. Moskovskiy institut neftekhimicheakoy i gazovo,y
promyshlennosti imeni Gubkina.

PAUSHKIN,, Ya.M.; VISHNYAKOVAJ. T.P.; SMIRNUV, A.P.
Exothermic catalytic F/rolyais of unaaturat6d and aromti~!
hydrocarbons. Neftekhimlia 1 no-4:514-520 JI-Ag 161.
(MIIA 16z11)
1. Institut neftekhimiohaskoy i gazovoy promyshlennostl
imeni I.M. Gubkina.

MAZI'TVA, F.N,~ PAUSHKIN, Ya.M.
Synthesis of n1tro derivatives of a-kylated phenolm. Izv.AU
SSSR Otd.khim.nauk: no.5,943-945 N, 163. (AURA 16:8)
1. Institut organicheskoy khlaii AN SSSR, Kazaml.
(Phfinol) (Nitro compound,5)

ZhORU", Yu.M.; 1-Urgaleyev, I.G.; PAUShIll, Ya.M.
ldnetici3 of cat&lytic hydrochiorination of styrene. Nefteki,imiia
I no.3:399-4C,4 My-Je 163.
I.. Moskovskiy institut nafteLldmicliesko7 i gazovoy promyshlei.riosti
I.M. Gubkina.
(Styrene) (11),drochloric acid)

TUSRI ZIJCHRA; PAUSHIaN, U.M.
Using cobalt an alumtmm oxide as a ca-~alyst for the vynthesia
of aromatic hydrocarbrna oJ' crude oil. Izv. V" 0 ucheb. zav.;
rieftl i gaz 5 no.7t57-63 IQ. (MIFLA 10t 7)
:L. Moskovskiy institut neftekhimicheek-ey i gazovoy prroWBh-
lennestl imeni akademika Cr-jbkina.
(Gatalysts) (Hydrocarbons)

PAUSHKIN, la.M. ; NIAZITOVA, F.N.
Synthesis r~f 2-aminc-4-tert-alkylphenols. Izv. Ali :USSR. Otd.khim.notuk
:io.6:1127-1128 Je 163. (MIRA 16:7~
1. Institut organichoskoy khimii AN SSSR, Kazan'.
(Phenol)

vith qale
,IMA. oxide
SOURCE: NegelOajmiy~a,,,~. 30 no. 4. 1963P 515-517
L 18376-63 EW(J)/EFF(c)/EWT(m)/EW(q)/BDS ASD,/=-3 Pc-4/Pr-4
ACCFZSIOX MI: AP3005447 &M/WW/JD S/0204/63/003/0M/0515/0517
AUTHOR: Paushkin, Ya. M.; Akutin, M. S.; Nizova, _S. A.
75
TITLE: ].>re-
.paration of pplycon u ted systems by *the reeztion of a.. j3-dibromides
TOPIC TWIS; con~ugatad yoly=ro polyvinylenco conjugationo semiconductor,
organic semiconductor, dehydrolalogenation, polyphenyLuvtylene, (1,2-dibromo-
ethyl)benzene,, 2,3-dibromopropionitrile, (1..2-dibro=etlkyl)benzi-.ne-2,3-dibromo-
propionitrile copolymer, copollmer, calcium oxide, EPR., IR, eleetron parwaagnetic
resonance., infrared spectrum, a, f~-dibrmide I
ABSTRACT: A method has been proposed for preparing conjugated polymers (poly-
vinylenes) by dehydrohalogenation of a.. 0-dib ) 0 C cogp2unds7~dth metal
oxideLcr ):,y&-oxides. The method has been used to eynthesize 1T_poiypbenyl-
acety Mej(PPA) from (1,2-dibromoethyl)benzene (1) and. 2) evidently for tS6
first t1m4) a copolymer of I and 2,,3_dibr0MoPX2k.Lonitri); 11). Reaction 1 vas
carriecl out, in the presence of CaO (I/CaO at 180,, 200.. 250..
Card 1/4

L 18376-63
ACCESSIO11 NR: AP3005447
or 300C for 2, 4. or 6 hr; the PPA was purified b) multiple reprecipitation.
The PPA y leld was 66-6%. Polydispe- rsity of the PPA prepared at 2000 for
6 hr was determined by fractional precipitation. Four fractions were obtained
which were yellow to black in color, softened at 3.75-182 to 250C, and had
molecular weights of 600-1600. The average molecular weight vas 1000-1100.
Reaction 2 vas carried out at 200C for 6 hr. with a I/Ii Wiar ratio Of :L/l.
The copolymer was dark brown,, slightly soluble in formamide,, and highly soluble
in concentrated sulfuric,, hydrochloric, or phosphoric aeld; its softening point
was belov 4,150C. The thermo=chanical curve for PPA of molecular Veight 1600
shoved that it can exist in the glassy or liquid atate, 'Cut not in the high-
elastic s'%,W.;e. EPR and IR spectra for PPA and tlu- copolymer confirmed their
polyconjt.ga,:ed structure. All the PPA fractions (=ept that having the lovest,
molecu-Im- v(-i-ht shoved a narrow EPR signal with im unpaIxed-electron coneen-
LO
tration of " V/g; in the copolymer this concentration ves 2.7 z 10-118/g. The
IR spectrum of PPA was identical with those obtained by Yu. Sh. Moshkovskiy
N. D. KoEitr,:iva, and A. A. Berlta. (Vy*sokozol. soyedinartlya, 3., 1669,, 1961~.
Card 2/4

L 18376-63
ACCESSION XR: AP3005447
IR spectra. suggest the following course for the c2polymBrizati, LU -A
C= CIL -C -Cff -C-CU -C-CH-
Br Dr Br Dr
i I C, N C 11,
it CIL - CH3 + rANI - (-'I I,
cd,is CON
4111 C411b
C CH - C CH - G = CIL - C = CH
It Is assm3ed that by varying the
vith various aryl, and &13Vl side
for=x1as., 1 table,, and 1 figuxe.
initial dibrow comp=dj conjugated
polymer$
groups can be obtaimd. Orig. art. b&3-. 2
Card 3/4

1 183716-53
ACCEMON M. AP300544T
,y
ASSOCIMMOR: Moskavskiy instttut nefteldiimicheslcoy i gEaovoy promy*shlermosti
in. 1. it. Clubkina, (Moscov Institute of the Petrochemical and Gas Inilustr-v);
Nauchno-is:31efLovatel'skiy institut plastmax (Scif.;ntific Research Institute of
Plastica)
SUB='.D: 2cNov62 DATE =: 06sepl:"3 ENCL: 00
SUB COM: CH, MA. NO REP SOV: 001 OTHM: 002
C.rd 4/4

L 18954-63 EWP(J)/EPF(c)/EWT(M)/BDS ASD PC-4/1r-4 1411WWIMA Y
ACCESSION IM: AP3006530 S1019115VOO010091000,010010
16?
AUTHORS: Faushkin, Ia. M.~ Nizova, S. A.; G4yevaya, V. S.
TITLE: The synthesis of polyViDyl dradwrbons by means; of def7drohaloid
polymerization
SOURCE: Plasticheskiye massy*, no. 9. 1963,9 9-10
TOPIC TAGS: polymerization., polyvinyl., dohydrohaloi,j polymerization, dibromoetlWl-
be=ol, alchlorcethylbenzol, polyphenylacetylene
ABSTRLCT: Aut3ors studied the preparation of po?,,vinyl compounds by means of
dehydrohalof.d. polymerization of Alpha, !3eta-dibrc..moe-~,lz,-lbem2lland Alpha, Beta-
dich1oroet,1z,l~,.',-nzolj1n the presence of crcLde saltz; of metal by'droxides. A neng
method for the preparation of pol~rrinyl lVdrocarbons by means of interlinking
reaction of del-qdrohaloid polymerizatign of the dehalogenized monomeric derivatives
has been proposed. Zoly
, phervlacety Lene Pas obtained by the proposed method. App-
arently, it is possible to obtain polylWdrocaarbons from other haloid and
dehalogenized derivatives by the same method.
Card 1/*/

PAUSHKIN, la.M.; LUNIN, A.F.
mars with
37nthODiB of new nigrogen and hydroxy :ontalnlyig pole
conjugate bonds from sodium carbonate and ammonium chloride.
Dokl. AN SSSR 150 no.41823--825 Je 163. (MIRA 106)
1. Moskovskiy institut nef tekhimi, che okay i gazovoy pran7sh-
lennosti imeni I.M. Gubkina. Predstavlano akadomikon A.V.
Topchiyevym.
kPolymers) (Sodiun carbonate)
(kaorilum chloride)

PAUSHKIN,_IA.M -YAKOVA, T.P., PATALAYX, I.I-,
.r, POIAK, L.S., VISM
MACHUS, F.F., SGXOLINSYA.YA, T.A.
New ferrwi-containing polymers on the basin of ferrocene and their electrophysical
properties.
Report submitted for the International Symposiuri of Macromolecular chemistry
Paris, 1-5 July 63

lion, to ia lria ationo

fteT:thol bove
of 60
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DATE AM'i: 24JU163
SUBMn

no iw. Sov: Oo

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7:7

PAUSHMj Yk, ~!j. GMAL, Ibmgim
A3kenylation and haloall7lation of benzene by baloa-Uyl
compounds in the presence of a boron I'luoride-based catalyst.
Doki. AN SSSR 147 no.4:953-856 D 162., (MIRA 1611)
1. Predetavleno akademikom A. V. Topchiyevyu.
(Benzene) (Allyl compimnds)

ICN XR.~
-,AC(~ AP3009M
.4
SUBVX=00 26D0062
INCLs OD
So CoDst
olm
i-, 4
qt
ji

PLAU~SHM. ~Tka ~ TOPCHIIEV, A.V., NUHTIM, S.D.
Methods of synthesis of vbyl-eyelo-hexans
Report presented at the 12th Conference on hijgh molecular weight
sompounds, devoted to mononera., Baku, 3-7 April 62

,YAUSHK.Ul-, YaM,, VISHNYAYOVA, T,P, - PATALAKH', Ll, i SOKOLIMAYA, T.A, -
MACHUS, F,F.
Ferrocene-based symthesis of polymeri3 and some of their !,lectro-
physioal-properties,, Dokl,. AN SSSR 149 no.4A56-859 Ap '63.
(MIRA 16-.3)
1. Institut neftekhimicheskoy i gazojoy promyBhlennosti im. LM~
Gubkina. Predstavlano akademikom A,V,Topchiyevym,
(Polynigrg) (Ferrocona)

__PAVWlp,_ Ya.M.; MRGALEYEV, I.G.
Alkylation of o( - chloroothylbenzone with propylena. Reftekhimiia
2 no.5:784-4787 3-0 162. (IURA 16: 1)
1. Moskovskiy inistitut neftekhimichaskoy i gazovoy promyshlennosti
imeni I.M.Gubkina.
(Benzene) (Propene)

PAUSUD, Ya.M.; VISENYAKOVA, r.p.; CHERNUKHINA, V.G.
Catalytic reforraing of naphthenic hydrocarbons of gasoline fractiins
into aromatic hydrocarbons on a catalyst with 0.1-0- 3~6 of nickel.
Izv. vys. ucheb.. zav.; neft' i gal 4 no.5:69-73 '61. (MIRA 15:2)
1. Moskovskiy institut neftekhimic:heskay i gazovc)y prorrvshlennosti
Imeni akad.I.M.Oubkina.
(Hydrocarbons) (Cracking process) (Catalysts, Nickel)

PAUSHKIN, Ya-M.-,; HUMAYEV, I.G.
Kinetics of the ab.-ylatioli of benzene, by propylene and the effect
of certain physical factors. Izv.vyv.ucheb.zav.; neft' i gaz
5 no.2:77-80 162. OEM 15:7)
1. Moskovskiy institut neftekhimichoskoy
imeni akademika I.M. Gubkina.
(Benzene) (Propene)
gazovoy promyslilemnosti
(Alkylation)

PAUSIM11. ip Ya.M.; LU', I I;, A. ~.,, MUT I UHAI~ , Lh .
Difluence of ultra-riolel~ ---ays cri the lsomerizatlari cf cyr-Ic-
hexane to methylA-y,-,Iopextwie. Izv. v-r-l. uahab. zav.; neflol i
gazo 6 no.fCF7--~,2 163 (1-11 RA -' 7 V )
1. Moskavskiy lnstltut n o-'LIkYiJ nitc Imakoy i gazovoy promyt3l.-
lennosti imeril ukademiXa I.M. GubkIna.

PAUSHKIN, Ya.M.- LUNIN, A.F.; OW,'01', O.Yu.
Polymers wltr~ conjugated bonda fr6r, ammoniam carlwnsite an-`
bicarbonate. Vysokora. soed. b na.4:734-736 Ap 'O4..
(MIRA 17.~()'
1. Institut neftekhimlchesk,~y i gazovov promyshioniostl Imeni
I.P. GubkAna.

PAUSHKINI, Ya.M.; YUZVYAK, A.G.1 HUBINSKEYN, A.I.
Synthevis of dimethylcyclohexadiene and vinyleyclohexens by the
(Limerization of butadiene. Dokl.AN SSSR 144 ro.38581-584 IV
162. (IOU l510
.1. Inotitut neftelEhimichookoy i gazovoy prouqolalennosti im.
I.M.Gubkina. PredstmvIeno akademikcim A.V.Tope!aiyevym.
(Butadiene) (Cycloboxadions) (Cyclohexons)

S/023/62/147/004/019/027
B101/B186
AUTHORS: Paushkin, Ya. M-.-, Galal, lbragim
TITLE: Study of the alkenylation and halogen alkenylation of
benzene with allyl halides and a catalyst based on boron
fluoride
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 147, no. 4, 1962, 853-856
TEXT: This is a study on the reaction of benzene irith allyl chloride or
bromide with a complex compound of BF 3 and ortho-phosphoric acid as
catalyst at atmospheric pressure and 25 - 73 0C. The catalyst addition
was 20 40%, the benzene : allyl halide ratio was varied between 0.5 : 1
and 3 1. The optimum temperature was 50 0C; at 70 0C, the amount of
resin-like by-products increased. The reaction product was extracted
with ether and fractionated in vacuo. (A) With allyl chloride the
following fractions were obtainei: (1) b.p. 86-810C/3 mm Hg, corresponding
to P-chloro-isopropyl benzene. The optimum yield of 32.9yo was reached at
500C, a catalyst addition of.20%, and a ratic, of C 6H6 : C3 115C1 - 2 : 1;
Card 1/4

S/020/62/147/004/019/027
Study of the alkenylation a.nd ... B101/B186
(2) b.p. 117-1190C/3 mm Hg .corresponding to 'i,2-d'iphenyl propane;
20 q e 20 1.
(3) b.p'. 145-1750C, d4 - V-0509, nD 5627, mean molecular weight
233, content of unsaturated compounds 4.3% and of! C1 20.44%. Thin
fraction is,an inseparable'riiixture of secondary.i~eaotion products.
3 f
1,2-dichloro propane was alao found in amounts *Iiich increased vwhen the
reaction mixture contained"fin insufficient amount of C H (B) With allyl
6 6-
bromide, the following frac-tions were obtained: (1) b.p. 41-45'C/3 mm H9,
corresponding to 1,2-dibromi) propane; (2) b.p. 95-9700 mm Hg corresponding
to0P-bromo-isopropyl benzene. An optimum yield of 56.2% was reached at
50 C, 20% catalyst, and a ratio of C 6 96 : C3H5Br - 2 : 1; (3) b.p.
110-14000 mm Hg, a mixture of P-bromo-iso;ropyl benzene and 1,2-diDhenyl
20 20
propane; (4) b.p. 170-195OC/3 mm Hg, d 1.2141, n 1.5743, mean
4 D
molecular weight 280, content of unsaturated compounds 36%, Br 27.4%.
The yield of this fraction increases when there is no benzene excess.
P-ohloro-isopropyl and P-bromo-icopropyl benzenes were identified by
dehydrohalogenation yielding a-methyl styrene. Oxidation with KMnO 4
Card 2/4

S/02 6211 47/r- -I 4/:~ I -,- ' -- 2 7
Study of the alkenylation and ... B I rjly:31 86
1,2-dibromo propane yield of 12.6-22-7% obtained by reaction with allj"
bromide, is explained by the readiness of FlBr to separate. There ,iro ~
figures and 5 tables.
PRESENTED: April 28, 1962, by A.V. Topchi.Yev, Academician
SUBMITTED: April 28, 1962
1
Card 4/4

FRENKIN, E.I.; PRLKHOROVAp A.A.; PAUSILKIN, Ya.M.,- TOPCILIM, A.V.
freparation of phenylboron dibromide by &Lrect synthesis. 1xv.
AN SSSR OW.khim.nauk no.8:1507-1508 Ag 160.. (MLU 15:5)
1. Institut neftekhimicheakago sinteza AN SSSR.
(Boron organic conpounds)

PAUSHM, Ya.M.; PAVIDI, I.S.; H-,~',"017()VA, L.A.
Synthesis of semisymetrizr,-I tris.-atraldes r)f borl-. ac,d.
Dokl. All SSSR 15'~ no.3.-612-614 N 164 (MIRA 18.1)
1. Institut neftekbimichoakoy i gazavc,'1 promyohlerrinst! imenj
I.M. (kibkIna. h-odit-ivlen~ akladomlkom k.P. Ncsmeyano"n .

PAUSITIN Ya.M.; *rJZVYAK, A.G.
Production of vinirleyelohexone by ej-clopolymnrization of blitadip-ne.
Izv. vfs. uci~eb. zav.; neft' i gaz 4 nc).2:6-74 161.
(MA 15:5)
1. Moskovskly Institut neftekhimicheiskoy J. gazovoy promysheInnosti
Imeni akademika Gubkina.
(Butadiene) (Gyclohexene)

J
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FAT5006932- S/29 006/05116054/0059'
82/64/1
Rl",:Ni
zovIdt. S'aA-,'; G4184 3, -Kh. Pauahkin, Ta.M
t~a"' ives
-T1TL1K-_: -11eudwobalou f the dibromo. t ..of ally-1- ar )matic
.~Compoundv
M&qcC;w.,: ihatitut neftlakhimicheako I '~oiroy Trudy, -no.
y 9a
51 1964.- -Vef tekbimiyat, nef 6ikhimicbeskiye pirots~~ssy i-6eftepiererabotka lPetroleumi
proce4ses jin& oil refinin -59-
g), 5.4
ow:Ip'O'U 9
31C TAGS -akoitatfc- d n dehydrohal6oolymer.~zation-, polyconju ated
, i-f 0 -poi
system, n raf. spectrum$. -~dimethylbenzylace!tylenej
.4
ABSTRACT:' OMO U
ropy~' aromatics c o 6da werer used,,to. prepare-a series
of --#olyC*2L d dins f high thermal) stabifity b eans of the dehydrohalo-
UE
-react opyl monoxn rs
l ;en, t on n. e:dibro~lopr Were obtained by brominating. i
po ymer sa e
phir4~ icochemicat properties: of. these monomers and
P~'_`i6du*cjva_-6f_ -thAr bromfiatioiji are- tabulated, -as Jim the cand ition~. of tbd
hal it n'and.4he propertles'of',the pol*,iers obtained. 'Infrared
tklikd ro opolymerlu io
-7spe6ftA::*f-sojhe-of thf!se~pol were taken, abld the '~ftber' of. paramagr
yners Ti ietic parts
stance.and. fundamental absorpt
per gram. of- s;A iov bands ~in these spectra.~are
rd

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A-
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-ACC99SlOW-NI,- 006934
4
v2981A4 i6/0069
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_IZ
--4'-usllkiu' To. I :so
Kokos leva,
t
r, -j r boric- --ac
l"I TL9 z
ai eactio -,of C ii~ tr ~sami es _6
77-
90M_ nS itut nef tekhiluitheskoy: i g4izovoyj~iomy ennosti. Trudy,
C
ndftekill. icheokiy
A nef t6pererabotka
M e 0!roesess!"
n -"trochenical, processes ai 'd 0ii 'T4 ining) 66-69
:04itroleiii cbem
TOPIC-TAGS h _6 ic w4diln i -organo broll to 'pb(did boric_acjd~aAid
6 eroonairw
e$
116in~i~6AUO exchang'e. r0act
4BST IT:' Tki sy0then tAcal tiiik6ides, 6f l6ric acid is based on &I;
RAC ivof Sim ffy6w
bettleatn- f
cal' trIsamidep q - orAc acidland primary and s,.
ethylamivo)borine an
Th d
johjit q_--AMin.u* -0--tri amios used I
ibylamitio b6rine-,~ and, tfi axinafv._wcre.Ja i at loobutylamine,:
09
1 amine, ji h d, d _j o --- b u t y I am -W,
ft-hexy The Pyoic heiaLcal ropertles
r somWes"obtained ar-_-"Iiabulitii~ The, boron content of
t i
A h ~neutron i6b
sorptiome
;ked prod m4 to was deteruan d: by t 4 tric viethod
e
A0 mlop6d';-bi,~"the AuifiorB in 6DOpevition -wit
h ths
_And-
'~-bided dn Ith-a"'tj 'd u f f the t10 i '~ture neutrons iuid thus
ev. 4 cy o atomq. 0 got6'Oe to cl
_Ctiid A/1"

Tj
81011' -AT5006934
3,
ux: o 1: erm .al 'isissins. Oro
the pr -neutrons ugh: the sampl, A-
--attenuate -
ift fl f h
ry
-th' terminatio'-~of borbi is given. tris- .
ast an, lfii~- A .: de Six,
.-.de-ice use for;i i
o- A,-rew d
~ClaGfl ~V SeMiSYUMAGtric4l, Ides of-boric. ac-i --- vere
--tri I I I , - Ij~
Ot 't -2- 1 igures" i- d,~ I ,t
an a4li"
~go
T-
msoWrlomv- 11tiatititC`6~fteWmI64; k6t-Ar Monvoiti Moscow
p9ov
cal, ~g:&Jff:-: dust initltute):~
tip
CLI BUB' CM I
-0(0
MAX
Rt 2
z
Co.

--7
aTLE*:,
;OUR Me
.CFA
iV64
4
4!6'sitai4n-i de't,
ectOrs, of themal,neul'rona-
'._--.1nStitut ne tiftimithesko I ri
0 p Pyshlermosti _Tkudy
eftekhimiya, neftekhi~ichiskiye pl~~tsesiy J; - nef tepererabotka
stryi -piltrochemi, V ot-1 reflning) 84-87,
cal.processes aw
boron-i a
ution-'_d'~L-ectij)i _`nautr6n absorption qn lysis, thermal
ter- res 111 10 orort c2m0und'
r apo
-the-vor watt
~4j ec tct'E k- to s tu y
PAT 1191
6 llity Upre
ficient Jefpctor,%Jor!~use~7' in Pe t;6n-sbseo~~tiometric-arialysls
U Z
The preliiaration-of a polyester
,reference to.,
m ng coutponen glyc6l: and-boric -acid is de
-oceintaftt
viP`h6r.-,'is_. pre 4.by-.mixing zincijoulfide. iwith themelt of this
is lowered
ic-tfo_n6f,__zi&1si'jlfide~-is facilitailed. , The*,! method, should riot e
-eparatiori-of colitimuous~ detec ors A. tabulation. of, the. character--* i
t
I- contiiiiing. det4'ctois': i16- gi-F.en*-e aiii._hIa19:':' 2 figuros 2
go i0,
in
roni-:p ~ip
--ABSTPACT'. The
8u fic
A Ajelltlyi~e

L 560j4i
AT5006935

istit"U~i ',nilf t-0040~cheskov: i
I
iblpritiosti
Moo
cow
prMy
i Ah f g48 It Ti Atliti6te) ,
7777-77777,
77777
777 777
j6.;, -- -- v
-0

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CODE

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Jt
:?
Qj�5 F
L424 VK&
WWAP Y FQi)~2AIVPM
U,6 At500693 - 'PINO 9V0
1,1/298 /3
0
-14.
Kuin itso4a L' ~I?
Paushkin, -~Xa.
13-11
1"' 1 b
._a CIO
o f -aromatic 1!comp6finds 'With- 'a 1* 1" in the presence
f
k6iCOW41 stittle neftekhint-cheskoy gAzovoY PrclrYshlennostl. Trudy, no. It
Sis 1964,."Iie"itekhi~tiya,~Iiieftekiiiinicht!skiye protsi.~ssy I nJiftepererabotka
(Petraleu'm,chemis try, pe-trachetaical processes an(I oil refining), 88-95
~70PIC, GS: all I llyl"alcohol,* zinc chli'sride cati~lyst infrared absorp-
-lation,: a
y
i ~um, tciluene,, xylenle' .-allylaromatic c6mpound
ATIMAM'_ Me' authors the-res n n
give utts of allyi4tio 'of i,olue e, M-xylene, iso-
pr,o'p.ylbi~;iet,ie_iand chloro.benzen,d with, Allyl alcohol in the'-presence of fused zinc
In th* Ation Of M-Xylene, the ei~fect of' el~le amount and activity
tfiloride:_ e~allyl
I he- : old ' d ositi-
01 thi 2I.Tic chloride c t yi an cbmp On of the reactLen
at Lyst on
produ,c.to a I 1-m-xvlene' and diallyl-m-xylene) u4s studied. Infrared absorption
allylchlaroberzene-are
spectra ese product and:of allylisopropylb.~enzene an
roperties of the allyl ~eriva-
luatrai:ed_:~.'an'd. discussed. Th physl~ochemical.!P
e
iiii dibromo derivitives are tabulated. Zihc_~hlorlde was found to
_.tiveB ani 't
1/2
ard
C

icp

-AT
-ACC9S9IOWA#, -~
~66606:
-
-
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---retailli" ith, f ev'repeate use,Tan uo-' be" allyl and" P.
-C
At-A yt 0 -at
-ioiAi, `- I-, h(id
witirat ves reac 857;: bf ~tbe-.theoretlcmjl. Origc:arti has: 4,figurcs~
.44ables ;mdT2--'fdkmulas9:I

ftelthlituichoukoyi4'az i Ow
ASSOCUTIOIII.,-~i-- Inat tut, ne. ow, y promytafilennosti) Rose,

(pitroc emicil".
and.las- illclu
h
I
nstitute)

S TocT mv.

NCt; 0'
SUB:CODE: oc
0
,: - 001
fib R": sow: OTHKR* 004
,

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4z

PAUSHKIN, Ya.M.; I "LAK, L..;.; LUYIN, A.F.; i ATALAKII, IT. ".
flew method cX Eynthe~iizing n*',*~rc)p,,j,-i-,-',-).-.Ia'_ri".r~i: -: ,-.-.n
conjugate honcip and the'r Pleotrc)phy,-i~,al
A,N SSSR 164 no.5:10~5-1068 0 165. (MlEA 18-1C)
1. Moskovskiy institut neftekhImIcheskoy i i,-Uzc;vcv jr,-,.iry~h'erincEti
im. I.M.Gubkina i Lnstillut neftEkhl-'nL'-l-heskoj,?o s~nte-za im. A.V.
Topchiveva AN SSSR. Sub-nitted March 18, 1965.

; ~., :~,~ , ~' .:.I ~ . ,f .
; 1, ~ , i~ ; , '. ... :d .
ilr,.1, -I ~27-3` '': -1

ac a

I
PAUSILKINY Y~I-' .; , , ~ . : , ~1, . , , ". 1'. ; ;,- -
1 .1 1 1. .
(ft D ~,. In rf": - r. -;-~ I -j :,-- '. T ~-, f. ~f ., r~. 1.~
: r, -,Mp-.- ~ -.a 4 On C, ". clrf~ 1 )11," ,
rc.44: 'i ~. I "" F : :
...

PAUIRKIN, '!~i. P.; I'll 1, .. :,. . , . . .
AI kyl at I or, ', , ,; ~ f* 4 - -~ .',. , ( -' .1 -,- I ..'. :; . ~ '. -: ~ ~
'!'rudy MINKINCP -,,' It I. 1 .1, : . , ,

YUS!i.' /AKOA; Yzt.M,
Using new cataly:3 for L~.e ~E: 'alyl, , - rt:formilng f : ~ -
substances to ob,Uiir. arumatic hydrovarbons. Trudy
I , ,il Z" . r
no. 44: 14 8-1 r, 5 163. . .

VISHWAKOVA, T.P.; PAUSHKIN, Ya.M.; KLDIENKO, M.Ya.; MAR'YhSHKIN, N.Ya.
k,
Oxidation of n-butylenes to Methyl ethyl ketone in Wre5,nce cf
a palladium chloride catalyst. rzv.vyB.ucheb.zav.; khim.i khim.tekh.
7 no.6:989-992 164. (MIlu 18:5)
1. Moskovskiy institut neftekhimicheskoy i gazovoy promyshlan,.ustj
imeni Gubkinav kafedra neftekhimicheskogo sinteza.

I-AU6)IKIJ,J, 0,14AROV, (,.Yu.
Preparation cji' pz)".yphenylenes from ~,yscxci--,. .90ed. "
no.4:710-'/12 Ap 165. (MIRA 18:6')
1. MoskovskJy institut nfifte-khimicheskoy i gazovoy promyshlenr,,,~t~
imt-ni Gubki-na.

V S

KO U 1~ N I ~ ~)Ij ~', V., ~' J. I i ~ -, ~ : I 'V ,~ , k-, ,I-~ I %',H F i N ~. a. 'A.
. !VU I nrl .I es n: tnt ',.(I u,.d phroe 9 kyl at I on G! bel',Zeno~ w ' th
cy -- I o h vx ene , - n,-,.r , I ' 7, . k til m -~Q v. -) . ~, ; 14 58-1463 jo 't)'. .
(Y-'Rlt lp;li,
1. Mr) skov sx-'y 1, n e t i t~i T, nP f TFl C ~)WT K Oy i R11 ZOV Gy 1, rLITTis ~, I ennop, t!
~men,4 GubkiriL, -- u tri I '~ 1 id A p - ' ~ -'(; , 1) .

ACC NRI AP6N12841 OURCE COM: UR/0065/66/000/010/0001/0005
AUTHOR: Kolesnikov, 1. M.; Mirgaleyev, 1. G.; Paushkin, Ya. M.
ORG: MIYAh; GP
TITLEE: Alkylation of benzene with propylene by means of a silica-alunina catalyst
promoted with boron trifluoride
SOURCE: Khimlya i tekhnologiya topliv i masel, no. 10, 1966, 1-5
TOPIC TAGS: alkyl benzene, aromatic hydrocarbon, alkylation, petroleum product
.ABSTRACT-. Alkylation of benzene with propylene was studied by percolating gaseous pro-,
Ylene (0.5-1.5 mol/Al.) at 25-750C for 0-120 min throti~h a glass colwin (28 Trim in dia-
eter and 650 mm high) containing 226 g of catalyst (silica-alumina roromoted with 15.5-,
18-1 Wt % DF3) and 156 g of benzene. The object of the work was to define optimal al-
ikylation conditions. It was found that the yield of the alkylbenzenes was directly pro-
'portional to the BF3 content In the catalyst. It was concluded that the BF3 was Pxe-
sent in two forms: physically absorbed on the silica-alumina surface and as a strong
coordination compound with aluminum. Increase in the temperature was found to have a -
rather slight effect on the yields of both mono- and di-propylbenzenes. The content
of di- and poly-propylbenzenes in the reaction product was found to be proportional to
ithe molar ratic. of propylene to benzene used. The catalyst activity was found to de- -
Card 1/2 UDC.- 66.095.25:547.532

PHA3E I BOOK EXPLOITATION SOV/6088
Pxushl4n~ Yaroslav Mikhaylovich
Khimiya ranktivnykh topliv; topliva dlya vozdushno-r-eaktivnykh
I raketnykh dvigateley Chemistry of Jet Fuels; ftels for
Jet and Rocket Ergi ' s) Moscow, I 'AN 83" , 1962.
Tie 2d-vo BR
435 P. Errata slip intlerted. 4000 copies printed.
Sponsoring Agency: Akademiya nauk SSSR. Institut neftekhimicheskogo
sinteza.
Resp. Ed.: A. V. Topchiyevo Academician:; Ed.t E. .13. Dragunov;
Tech. Ed.: T. V. Polyakova.
MPOSE:' This book is intende4 for aeronautical enigineers,
rocket technicians, chemists, and other persons interested
In jet fuels and rocket propellants.
Card 1/0

ACCESSION M AP4043785 So'0190/64/0015/006/1467/1470
~AUTHOR: Lunin, A. F,; Paushkin, Ya, M,
MTLE1 ltomopcilycondensation of urea to polycyanamide,- a nitro8on-
:containing polymer with conjugated double bonds
SOURCEi Vy4sokomolekulyarny,bye soyedinaniya, v. 6. no. So 1964,
i1467-1470
TOPIC TAGSv polycyanamide, polycyanamide preparation, uree, zinc
chloride, organic semiconductor, semiconducting polymer
,ABSTRACTi A new preparative method for conjugated polymers contain-
ing heteroatoms in the backbone has been used to prepare polycyana-
mlde* The presence of nitrogen atoms both In the conjugated backbones
~
iand in the side chain was expected to have a desirable effect on the
:electrical properties of the polymer# The method involves the newly
discovered polycondensation of ureiwhich is assumed to proceed as
~followsl
Nils Nils Nils %,III
III"_IA-O_.AsN -1J.-N-t,.N
'Card

1:
Ilgennostf, Moscow (Inautute
gnovo.
Liao Limstry)

aSO RIP" 0 --.-021

Elm
4
Pr
r6sApf: (~!)~WPO Wf: 4/0~4
V
7-1
CMSIW.NRI P5Q.1 1953
i'. _11iilL I ..Ocluoli0 YU.
............
ri
6m,-.. pb
121 A
'u-I r -0. -qui" v i:,
ri o-, synthesis 33,a sor* tion.-
0 eoqt~~j; UmWaturii dep~ence
P
the, ,
ie-"vutho"-jwepared -pDlypheTWIeneiAy-4~WdratUn
-The i ALI:): of- tdi catalyOt i9impirtant jield:
so monmer
-odiio-
61yMer-P. At ~heh:ol/ZnO: -ratios of I 13 ;"And 114i the yield, ie,.AearV-
e~that &i; -a.Lther higt or 0-9~
or b ie ratios (32~.a~!'against- 16~1~% for 6 hours of
readtion at Best, yield, yraP - obtaited at 350d'i half 'S~ ~Cain as as- at 300 or,L
-20Wie jolUb]- 1) -_7_Jn~L o=amide.
_M~Ime foxms a b.lao,k- powder# partialj~- dimet4ir
7h ~aiMou'melte 6t aboht -12VC; lho'.inuofiLble *~t, is infMille below 5=
'' - I;kI6. 1-1 .
h IR Peo 'UM 9, 1 wmb
b iovotipm s. "that the bahzene Angs ex i ined, ohief4 In. e
T a a 9 t2 show
bi~_ poktilmi~!'OTAY iTr small Im-b in the para posttiono'~ fItt'appesrb -that the po4-
throUgh- f
im reactior ormation j1hat imt ligroin fome aW
of i~rine.a
6n intermedUA a -of eriol* tablS
t I stage ilk -%a t=iafoXMti(m or. art* "S 1
7 T~_.
A/2
7ttrt 7t

skoy
IMUTHO 9
GubkLfis Woo,wir mutituto iii~ Petr6chemi-
pow (hie
, m Inaustry)
smuaTm I MM CODE OC
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24353
E1026161100010081002,1-)04
/00 D05l/Dll3
4FT~O~R- Paushkin, Ya,M., Professor
TITLE: Chemistry and space flights
PERIODICAL: Priroda,",no. 8, 1961, 16-20
TEXTg A survey of present trends in the selection of' suitable liquid and
solid rocket fuels is given. The article is interspiirsed with reintirks on
the history of rocket fuels and comparable materials. As a rule, rocket fuels
consist of a combustible material arid an oxidizer, and whereas many chemical
substances can be successfully used as combustible material, the variety of
substances used as oxidizers is mu,~h less conniderable. Liquid oxygen, which
is used for mid-range and long-range rocket fuels, iE; the most easily access-
ible oxidize~r. The combustible components of such fuels may be hydrof-Rrhons
alcohols or nitrogen-containing compounds such as amrionia, hvdrazine, and di-
methyl hydrazine. A fuel based on aircraft korosene has a hign aiorimetric
value. Individual hydrocarbons of the naphthenic type are uEed because of
their good cDking capacity. As compared to hydrocarbons, nitrogen-containing
compounds suzh as dimethyl hydrazine proved to be the best combustibles in
combination with oxygen. The fuel prepared on this basis, however, is more
Card 1/ 4

20 53
S102 611000100810021004
Chemistry anti space flights I)051YD11,z
expensive. The use of ozone in hydrocarbon fUels guarantees a calorimetric
value of 2B20 kcal/kg as compared to 2260 kcal.,/kg whon using oxygen. How-
ever, its endothermic properties, its instability and explosiveness do not
recommend it as an oxidizer. Fuels based on fluorine and some of its com-
pounds (irt particular CIF , F 0, and PCIO ) are characterized by a high spe-
~ty 2
cific thrust. The toxic and c,)rrosiv~ activity of fluorine speak in
disfavor of its use as an oxidizer, but these difficulties can be overcome
by collecting toxic HF durinkz tests and using fluorine-based fuels for the
second and subsequent stages of the rocket. En this way the atmosphere at
the laun,:hing site will not Is poisoned. Tog,ather with fluorine, combustibles
6uch as hydrazine, ammonia, and asymmetric dimethyl hydrazine are used. The
use of red fuming nitric acid containing 20-30% nitrogen oxides as an oxi-
dizing agent dispenses with the need to fuel the rocket immediately before
launching. During storage, concentrated HNO 3 liberates oxygen, which causes
int~reased pressure in the sealed containers. Tf 5ume HF or Ei 5PO4 is added
to mixturos of nitrogen oxidEs and HNOV then theop mixturOB will be chemi-
ra.1
ly sla,-,l,. an~ ali3u less ccrrosive. As e~ombuntiblcw componunts of IINO
Card 21 4

24353
3102 61,/000/008/002/004
Chemistry and space flights D051YD115
fuels, synthetic organic components reacting with END with self-ignition
or combustit-le organic substances are used. Self-igniting combustibles at
present employed are as follows:
/I- He
N C6115 CUS
I H HIN-N fill
\ He
C
V1, I~
O

Pffv=n- H3
/
BuR COUP7
Allue"arMAP&-
elan
,MIMIR Meznnjvz~
'L / b W FU
C
I'S
Nil,
C2H4N H,
Nil