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SCIENTIFIC ABSTRACT PAVLOV, S. A. - PAVLOV, S. A.

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CIA-RDP86-00513R001239620009-9
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December 31, 1967
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SCIENTIFIC ABSTRACT
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7-7- W/WAW: IMIC) L 23228 ACC M11i AMC03597 SMCE CODE: UR/0191/65/00DADMOD32/0D34 AIYM: ANnas Iyev.,. _110y S. A.; Kaz A* Mq Ph poyt* V. L&; ZLe~B~.I ORG: none.,,, tic, T-ITIE..' RoeIntgenographic investigation of modified polyamideaC SOMCE: Plasticbeakiye massy, no. 2, 196% 32-34 TAG po lyaddip polywr~ irradiation resistance, radiation shieldings nuclear Isid p ePoxidep polyurethanep chromium cospound ABSTRACT: ~ftw,.Wcwication of,,polymerstriih mineral substances han er '~:impwtanci t6- the prop .&ration of bhterials reatsUmt to naclemiradiation.1 Nater- 11di Are )MwP'wbicb-Are di pernions of c=pDw9s of boron.and learrift em-wel -rbr polymistbanerand allicon=2 which are not inferior to boron and lead in ability to - deflect slow neutrons and gamw rayso . CoveriTNIS I based on these din- -persions are sure effective than coverbW made frog othernatirials for protect- ion frica mmlear radiation. These materials can be used for.mWdn special.pro- tective clothing, for enclosing x-ray Installation, etc* Upon considering the .-value of the effect caused in mixed plyaiiide compounds of trivalent chroniums, the authors studied the effect of various don&n of ionizing radiation an the structure of polyaidde AX 50150j (obtained by the polydenation of Arsalt and S-caprolutum in a Is 11-r-at-Loyi%dified with dirmium chloride.' Radiation was Condueted at 2DO C in the presence op fair on the "K-20ODD*p an.installation for radiation-chudcal inwastigations, which has a source of Same radiation from Co-60 with an activity of 20OW gno-equivalents of Ra. Pblyamide " obtained 4~nd JA UDO: 678-675.01:543-422.8 1. 23228-66 '7-Abc HR, AMM597 an.the basis of AG-aalt-SG-salt and epsilon-caprolactum in a 1:1:1 ratio, was also used, in the study. It was conciuded that the introduction of considerable quantities oUtrivalent chromIum salts into a solution of mixed polyamides, results in the lose Obf -crystallinity of the film material obtained. The action of gama radiation up to vai'114 ntgen-doses does not cause substantial changes in structure. Furtherp 20D -when the content of the chromium chloride in the polyaside in insignificant its action'is expromed in the fixation of the structure forned- when the content 'is high, it is expressed in the opening of the chains and bl;;); of sacrosolecules :and in -the disturbance of their ordering. Finally, the introduction. of glycerine .,Acceleratss the lost of erptallinity of the polyaside S-6 during radiation buV at a lower rate than the radiation-caused changes of the mechanical MA other parties of this polysside. The structure of polyasides AX MD wA VO I even after &MtIon of a pliwticizer, exhibits considerable stability in the ~. action of radiation in the dos'e range up td 500 milliroentgen dose. Orig. art. has: 211gures and 3 tables. [JERS] SUB COM 11j,- 3.8 SUBM DATE: ~none CRIG REF: OD9 L_C_Wd: 2/2~-S& NR1 AP6023405 (N) SOURCE CODE: UR/0323/66/000/002/007810034 AUTHOR: Belokopytova, V. S. (Engineer); Kalinina, L. Ye. (Can"te of techniral Psylor,, S. A. (Doctor of technical sciences, Professor) ORG: I Belokopytova; Kalinina I All -Union Research Institute of F11M bbterials and A rtWcl, Leather (Vsesqyuznyy nauohno4seledovatellaidy inatitat plenochafth materialoy I Iskusstvem kozM); I Parlov IMoscow Technical Institute of Lfg~t Industry (Movskovfy tekhnologicheakly Jinstitut legkoy promynblennosti) TITLE: Vulcanization of latex films for the production of polymer film materials by the ionic deposition method SOURCE: rVUZ. Tekhnologlya legkoy promyshiennosti, no. 2, 1966, 78-84 TOPIC TAGS: synthetic material, vulcanization, gel ABSMACT6. The preBe.Ut inVOB 9gation is devoted to vulcanization of latex gels relative to the production of artificial leather.N Ionic deposition was used to obtab latex gels. The carboxyl- containing latex SKN40-lGP vilth 3% methaerylic acid' ~Rs used as the main film-forming latex. Even though with ion0deposition the gels have on open structure, upon drying there is a tendency toward consolidation and formation of monoUthio films. Therefore, the main task 1/2 1; 9346-67 ACIC NRs -AR AUTHORS Afanastreve Pavlov, '3_ G ORGS Department of Technology of Artificial Ioather and Film Materials, Moscow Tech- nologLeal Institute of Light Industry (Kafedra tekhnologii iskusstvennoy kozhi i~ pTe-nOchy~ma Xer lov, ~~~rvs :Ly ~ekhnologicheek~y institut legkoy promyshlennosti) :1 TITLE: Prrmomechanical vK2Partlei of irradiated pply idea croas-linked with chromi- uz chloride SOURCES IVUZ- Khimiya i khimichoskaya tekhnologiya, v. 9, no. 3, 1966, 48o-485 TOPIC TAGSt chromium compound, chloride, polyamide, irradiation effect, gammA radia- tion, thermomechanical property ABSTRACTS An attempt was made to determine the extent to which the addition of a cross-linking chromium complex (chromium chloride) followed by irradiation with co6o Y rays affects ther thermomochanical prOD!Fties of-films of mixed-typo polyamidos. Die film-forming polyamides were AX 14L~_4 an-1 S-6. '~ "ine results of thormomechanical tests confirmed x-ray diffractioy; -data obtaine-a -earlier to the effect that the intro- duction of increased amounts of chromium chloride causes the structure of the film material to change from an amorphous-crystalline state to an amorphous one. At the same time, the thermal stability of the films increases, and the flowability disap- pears in the temperature range under consideration (25-3000). Under the influonce of Card 1 2 UDCi 678.O1t534678.o2R+rA'-'c L 06346-67 AC C- -N R, AP6030324 xrad, the cold flow of polyamide films with a integral doses of y radiation up to 500 and at ter..peratures close to the fusion tem-' high chromium chloride content increasess peraturos of the initial compon-nts. those polyamides chanze into a vigcofluid stat,6- It was found that even the formation of a weak radiation network of gel between the maromoleculeS in polyamide films which were first cross-linked with a salt of chrom'- are at least one order of magnitude um (III) requires integral radiation doses that j,dtial polyamides. Orig-~ higher than the doses corresponding to gel fomation ill the .A. has, 3 figures and I table- oRiG REF: 007/ On REF1 001 SUB CODE: I,/ SUB11 D&TEs 06Jun64/ Card 2/! Ot"E L 0754~~7 E'-'PW/_WrAm)_ ii c) RM XCE. Nxi IT6014711 AT ---SOURCE-COD9-.-UR/0323/65/000/006/0028/0031-7~ Korol'kov, N. V. (Engineer);,._Pavlo%!,__S. A. (Dr. of technical sciences; Prof.), ORG: Moscow Technological Institute of Light Industry (Moskovskiy tekhnologicheakiy institut legkoy promyshlennos-L7i)- TITLE: Synthesis of hexamethylene-bis-iminoac tic acid for preparation of polyatnides used in the production of artificial lea ther. 1. Study of condensation of methy monochloroacetate with disodium hexamethylenediamine SOURCE: IVUZ. Tekhnologiya legkoy promyshlennosti, no. 6, 1965, 28-31 TOPIC TAGS: synthetic material, leather, chemical synthesis, hexamethylenediamine, condensation reaction, nethyl acetate ABSTRACT: A reaction proposed for preparing alkyl eaters of hexamethylene-bis-imino- acetic acid and the latter by hydrolysis did not give the expected results. The syn- thesis was studied to find routes more convenient than the hydrolysis of nitriles, obtained by condensation of diamines, ketones, or aldehydes and hydrocyanic acid. The solution of 23 g Na in 350 ml methanol reacted under reflux with 58 g hexamethylene- diamine to give disodium hexamethylenediamine (NaHN (CH2)6NI[Na). After washing and drying, 165 g of the precipitate was added to a stirred and ice-cooled vessel contain- ing 210 g methyl sonothloroacetate and reacted 1.5 hr at room temperature. Mixing Card L o7544-67 Att NR, Ap6014711 with chloroform and water, extraction with chloroform and crystallization gave a prod-: uct of 101-103C mp, and after hydrolysis with acid or basic agents a compound tenta-' tively identified by elemental analysis as CICH2CONH(CH2)6NIICOCII2Cl. Thus. the re- action with methyl monochloroncetate proceeds via cleavage of eater and formation of amide bonds and cannot be used for the synthesis of hexamethylene-bia-iminoacetic a!id.~ Drig. art. has: 3 formulas. BUD CODE: 07/ SUBM DAM 27Feb6S/ ORIC RM 002/ OTH REFt 004 Iq ACC NRs AP7002538 (A) -"'souRag cDDE:'*-UR/0413/66/000/023/0012/0012 INVENTOR: Knyazev, N. N.; Bokov, Yu. S.; Lavrishev, V. P.; Pavlov, S. A. ORG: none TITLE: Preparative method for crosslinked polymer coatings. Class 8, No. 188942 :'SOURCE: Izobreteniya, promyshlennyye obraztey, tovarnyye znaki, no. 23, 1966, 12 TOPIC TAGS! polymer coating, chlorosulfonated polyethylene, polymer crosslinking. ,UV irradiation ABSTRACT: An Author Certificate has been issued for a method of preparing crosslinked chlorosulfonated polyethylene-based polymer coatings with improved mechanical properties. The method involved application on the substrate of a chlorosulfonated polyethylene solution containing added triethylene glyool dimethacrylate and a sensitizer junspecifiedl,remDval of the solvent by drying, and UV irradiation.* SUB CODE: 11, 07/ SUBM DATE: 17Dec64/ ATD PRESS: 5112 Cod UDC: 678.741-416-9:547.391.3'422.2 ACC NRv AP6033910 '4 SOMCE GODE: UR/0323/66/OW/004/0050/OD56 AUTHORS: Prokhorov, L. I. (Engineer); KhromDvs, N, d, (Candidate of technical sciences, Docent); Pavlov, S. A. (Doctor of technical sciences, Professor) ORG: Moscow Technological Institute of Light Industry (Hoskovskly takhnologicheakiy institut legkoy proWshlennosti) TIM: The influence of the type of diisocyaaate and of blocking substances on the properties of porous materials manufactured from earboxyl-containing rubbers SOURCE: IVUZ. Tekhnologlys legkoy prorphlennosti, no. 4, 1966, 50-56 TOPIC TAM : polymer, rubber, toluene diisocyanate, mothylmethacrylato / SKS-30-1 rubber ABSTRACT: The properties of porouA materials obtained by the action of 2,4-toluYlone diisocyanate and of hexamethylonediisocyanate respectively, blocked with either acetoacetic ester or with tertiary butyl alcohol, on the carboVl-containing rubber SKS-30-1, vere investigated. The investigation supplements the results of L. 1. Prokhorov, N. S. 111hromova, and S. A. Pavlov (Poluchenlye poristykh struktur s ispollzavanlyom blokirovannogo toluilendiizotsianatap Izventiya vysrhikh uchobnykh zavedeniyp TekhnologLy legkoy pronyahlennosti No. 3, 1966). The rate of gas evolu- tion during heating and the pechanic.0 properties of the produots'.*,were, determined. -AP6Q33910 Plg~ 1, Dependence of the amou t of gaseous products 3 formed during the interaction of free and av blocked toluylendilsocyanate respectively with metbylmethacrylate the period of look on heating at 1500. 1 - blocked diisocyanate- 4-' 2 - free disocYanate; 3 free diisocyanate in the presence of triethylamine .4 0 40 X Rea-king time, min The experimental results are smarized in graphs and tables (see Fig. 1). It was found that the introduction of 2,.4 toluylonediisocyarukto blocked with acetoacetio ester into rubber SKS-30-1 yields a better product thah does the introduction of hexamethylonediisocyanate., simila ly blocked, into the same substrate, Orig, art. has, 3 tables and 3 graphs. SUB COIE: ll/ SUBM D= s MoV65/ ORIG REF 3 062/ OM RV i OM card L 98-165-66 94TWIEWP(J) RM ACC NRs AP6019943 SOURC-ECOD-E-i- U-RfO323-/661(-)k/o-,~l-/6033/0036 AUTHORS Korollkov, N. V. (Engr.); Pavlov, S. A. (Prof.; Dr. of Telical Sciences) ORG: DODartment, of Technology of Polymer Film Materials and Artificial Leatherp -Moscow Technological Institute of the Light Industry (Kafedra tokhnologii polimernykh. plenochny h materialov i iskusalvennoy kozhT Moskovskogo tokhnologichoBkogo instituta legkoy-promyshlennosti) TITIZI Synthesis of hexamettk-lene-bia-iminoacetio actdNor the purpose of obtaining polyamidea for artificial leataer production. Report No. 21 Study of the reaction between the disodium derivative of hexamethylenediamine and monochloroacetam!Lde SOURCES IVUZ. Tekhnologiya legkoy provWshlonnosti, no. 1, 1966, 33-36 TOPIC TAGS$ organic amide, hexamethylenediamine, hydrolysis, organic inine compound ABSTRACT: The reaction of the disodium derivative of hexamethylenediamine with chloroacetamide was carried out by preheating the two reactants in solution, then cooling the reaction vessel once the reaction had started. The reaction is 2H,NOC - CH, - C1 + NaHN - (CH,), -'NHNirl- H2NOC - CH, I- NH - (0%), - NH - CHj - COWS'+ VaCl. Miltiple reezIrstallizat1on from hot CM4 produced hexamethylens-bis-iminoacetio acid 12 L NRt "019943 in 4bout 65% yield. In order to Identify the amide obtainedp the content of total nitrogen was determined by Kjeldahl*a nothodp and the amide nitrogen was determined while also studying the conditions of hydrolysis of the amides H3NOC - CH2 - HN - (CH,), - NH - CH, - CONH, 4- 2H,0 - -,, HOOC - CH, - HN - (CHI)g - NH - CH, - COOH + 2NH,. The optimm time Of hydrolysis and Its extent were determined from the amount of amonia evolved. Orig. art. has$ I table. SUB COMI 07 / SUEN DATEI 27Feb65 / ORIG REF# 001 / OTH RW# o03 CWd GOLUTVINA, L.F., kwW. tekhn. naukj L6W-,."A" doktor tekhn. nauk; IVASDVAV YC.I.? nallchnyy Botrainik; POPOVA, P.A., nauchnyy sotrudnik; ZADVWJOV, II.P., nauchmyy sotrudnik Operational properties of fireproof coated materials. Nauch.- issl. trudy VNIIPIK no.14:83-92 163. (MIRA l8zl2) FIMOVAT K.A., kand, takhn, nauk; BADANIVA, A,I,, kand. tekhn. nauk; ZOLDMV, V.I., inzh.i ~'IXWV. S.A., doktor tekha. nollik Sow-characteris ties of leather fibers used for the manufacture of-Artififteal-leather. Report No.3g Effect of the relative moisture of Air on the str=ture formation of artificial leather. Nauch.-isel. trudy VNI1PIX no.14g 10-15 163. (MM 18s12) ABRANDVA,, V-V-, starsbiy- nauchn" .&otrudnik, PIDTNIKOV, I.V., kand. -Ai,-hn. nauki FIXYDGEIR, K.I., -badahiy mauchnyy sotr-adnik,- PISARENKO, A.P.,,doktor Aim. nauk, prof.; PAVLDY,_S.A., doktor tekhn, nauk, prof. Manufacture of artificial suede type leather without salt washout. Nauch.-issl. trudy VNIIPIK no.24tl56-163 163. (MIRA 18:12) SMY"'itylv2p Y.A., nmur.-hryy io-. 5,A,, d( I pr,)~, , : V. , kfAnii a t~ "TT., :",~Ur. Olipt, J on of but3d! one-nitr Ile ruhbcr '- KN-26! ---~ --I i I c.; hane lind iiial, tridy 0';' K -I ijL - . 1. 1v -.- , A. '. SHMELFVA, T.A.; C-FIGOR'YEVA, N.V.; FAVLOV, S.A.; LFVTNA, V.], Use of polyacrylAtes for the strengthening of the skin o! sheep pelts. Kozh.-obuv. prom. 7 no.9;33-35 S '65. (MLRA 1~ :9,~ J0 t "go-66 zw(S:)1EPF(q) WW/RH ACC NR: 'AF5024957 SOURCE UR/02110/65/ODD/016/0020 All, AUTHORSs, _Gplutyiria. L. F S A Avilov. Ai A,; Butuzkina Z.. A. D. S.;. Streff tai Taentaiper~ Z. BeliPlotn is r ORrj:. zona- TITIZ: Plethod for obtaining fireproof-coverings.. Class S. No. 173702 SOURGE:1, Byullstepl izobreteniy I t6varrorkh znakov, no. 160 1965, 20 TOPIC TAGS: fireproofin9v fir ~00f covering, sodium bicarbDTmte., potassium epro~( bicarbonate, aluminum sulfate., PAZ4CA.44- ft>.AZv~ , fz.. AL-A /u 4,.~ J6_441 ABSTRACT: Thif Author Certift ate presen s a method for obta W ng fireproof C coverings on the basis ofAigh polymeric nateria)a containing antipyrenes. To 'Oib6-forming coat1vgaL$oss9ssihg high tire repiptAnce obtain qelf-extinmishir and low beat conduction, a mixture of strong Ei an (for instance, sodium or po sium bicarbonste),, salts of strong acids (for Instance, aluminum sulfate), and containing vater of crystallization (vitrialm,, alum,, and others) are used an antivy"nes.., A SUB ODIM: SUBM DATES 29Doc62 SIM =m 678.049.91 card iAw DOBRYNINA, L.Ye., assistant; PAVIDV, S.A., dokt--r tErl.-)jr. nauk, 1- . - , ~ Properties of the solution and fiLm, for-matl(z r-f Bolvar and arrylic resins. Nauch. triidy KIILP no.30:96..101 164. (MIRA 18: 6.) 1. Kafedra teldmologii i skuss t-,,mr--c-jy kczhi " plei ochny'f-h materialov Mcikovskogo instltut-a legkoy promyshlennosti. KIPNISV Yu.B.; SHTERN, I.A.; PLOTNIKOV, I.V.; PAVLOV, N.N.; PAVLDV, S.A. Use of modified polyamides for the finishing of artificial leather based on rubber. Kozh.-obuv. prom. 6 no.5:31-34 PT '64. (KRA 17:12) .401: MS.'' AP5625022 SOURC6 A, tYJR/0266/65~p/016/0081/ODU 40 AJJTHORS3 Dobrpdna~, 1. Ye. Fill chikov, A. S.1 Xhromxmj No Be; Pavlovp S. Ao ORG: none TITLE2 A method for P ticiziny. po~yamide products* Class 39x No. 173932 SOURC& Byalleten' izq~reteniy i. tovarnykh anakov., noo 16, 19659 81 TOPIC TAG3z plasti polyamide, formaldeWe 1;AB5rRACTr This Author Certificate-presents-a method for plasticising-polyamide products -(such as films) with polyesters, To improve: their quality, the products ax*, troated with fornmadftde. SUB.00M.Mr.'" suBm DATEz o2jui64/ oRiG. REF s oDo/ OTH RUt 000 uDa-. 678.67!i.674.oo2.2:547.281.i Card ;kA- i.htained Y,l, h. .4p 165. 1~ CV: V r-, j ns t 1 tu t AFANASIYEVP KARPOV, V'L'; ZVEREVI B-1- X-ray diffraction study of modified polyamides. Plast. masBy no.2l32- 34 165. (MIRA 18s7) ;~ i i'.; - " - A - ~ V, Ojvj, V , I . ; ZVET-',FV,. 13. 1 - AFAINASOYFV, A.M.- P ~f - . ~ - I Z,----ay I ;,"7-~jct , -n :f fEr-s cbs~ f7~m J- - Z. 1-r,adiatc,d Plnst- rtw3sy no.4:52-55 04JRA 18'-r) F I-,-- -:~ -, - , - . - , --, .. - - ~7~ - - -~z - A rt%V P-MAM *M. ATMAIRAQ0 '_--,jqtr4cWre -iDf_.0"qIymek_ and e-integr~ldos6i-Wt-.al66to-~-ddnbiderabI extent -_ft the -a formation of-016--films and character! 'tics off, the original structure. By -the-*finum formrti on, one can obtain the desired properties condition using a f R (e. g. I high thbrmal stability) in the irradiated materials or articles for a smaller ex- .,peadittwe of radiation energy. "We express our appreciation to Prof. V. L. Karpoy for --valuable suggestions daring the setting gp of the experimeuts and for his interest In this wrk.-I -Orig, 5 fi os and I table gur ,"I'ASSOMMOM.- None SUMUTED: OV ENCII.. 00 :SUB CODE s MT M, 002 NO AEF SOV., 008 OTHE SLAVNOVA, S.S., asoistent; IIAVWVk_.q!A,!_,_.doktor t9khn. nauk, prof.; SUSLOV, Yu.l., inzh., Use of Infrared spectrcscop7 in the Estudy of polymeric mater4als. Nauch. trudy RrILP no.30:102-10? 164. (141TA 18:6) 1. Kafedra fiziki i kafedra tukhziologii iskusstvannoy ko-zhi i plenochnykh materialov Moskovskago tekl-itiologicheskogo instituta legkoy promyahlennosti. KOLOSOVA, G.I., 14~dshiY nauchnyy Botrudnik; ~~T-OV, A. . , d o k L -., r tc- khn . na uk itudy-lng %~x structure of artificial sole leaUier manufacturtd on a base of leather fibers* Report No.3. Nauch,-'!.as1. trudy VNIIP1*K no.13%27-32 162. (MIRA 18~1) IVANOVA, L-I.A.- KAS'YANOVA, A.A.; PAVLOV, S.A. Studying the con~iitiorjrj of' thu ;i-cr1*ur-,,,irjn oi lf~ -!--: r: 0, complex dispersions, Of hYIIC)PhI 111C ~)(-.'IyTfiler.9 Eind 1,rIrI,---,it:I,,Ig, their water resistance. Kauch. i rez. 2.. nn.2212-11~ F 16~` W-Z4A 1. Moskovskiy tekhn, 'o~7 AFANA' IY~,V, ,,,j,,. ; : . ", k. :, ,. v 1.! f!': '~! 0 11 . j . ; I .'~ li J ~ 1 V , ~ * . j . - . - - i . - Y-ay ~-, "r,, ::1 .9 "u,'y (-; f -, a -,eci : , -, . ; --- . . , r, 0 - 'L : ; -3- 3 t, I ~-- 5. 1 ,- , . . \.~- -.! SLAVNOVA, 10 S- assistent-, PAVL(YV, S.A., doktor tekhn. naaR, prop, Physical methods of analysis of the supermolecular str,ict,-,res :' polymers. Rauch. trudy MTILP no.29tlO33-116 164, (MIRA 1~ 41' 1. Kafedry fiziki I tekhnologii iskusstiennoy kozhi I plenochnykh materialov Moskovskogo tekhnologicheskogo in!3tI*,iit& Ic-.gkr)-v prn1-nvf;h- lennosti. SHVETSOVA, T.P.1 SAFRAY, B~A.; PAVLOV, S.A. Ways to increase the strength of the cement fastening of mbber soles. Kozh.-obuv.pron. 6 no,lOt2l-23 0 164- (MIRA 18:1) UVOSTOV, V.A.; SIYIENOV, I.F,; PAVLOV, S.A. Mechanization of cLrroL harvesting. 4 no.llt25-26 IT '64. (141RA "B'3) AMMRSI Afanas'"v. A. M..- Favlov. S. A.-Z Zver TITMt X-ray studies of polyamide kilns cast from irradiated solutions Et PIsatieboaklo msayp no. 4, 1965) 52-55 POW TOPIC TAGS; polyamide, x ray study, irradiation! ordered structure UM 50 1 in trument, K 20000 irradiation device 60 .:-,ABSTRACTi-- The- results of invostigating,- the structures of film after Co gium a -6f zixe ~Iiradiatio 'of initial concentrated solutions d p