SCIENTIFIC ABSTRACT PERSHITS, YA.N. - PERSHMIOT, YA.A.

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CIA-RDP86-00513R001240120010-0
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December 31, 1967
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SCIENTIFIC ABSTRACT
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ACCESSICN NRt AP4036566 S/0139/64/000/002/0131/0135 I AUTHOR: Pershits, Ya. N. TITLE: On high temperature electrical conductivity in alkali-halido crystals with impurities SOURCE: IVUZ. Fizika, no. 2, 1964., 131-135 TOPIC TAGS: electric conductivity, alkali halide, vacant point, lattice, absolute zero, potential balTier, activation energy, ion capture, potassium chloride, potassium bromide ABSTRACT:: Electric conductivity expressed as a function of temperature in Olkali- halide crystals KCI and KBr with electrolytically added Cu* ions was determined, Analytically, this is expressed by q Ae xr - Be ,r where F, - work necessary to create a pair of vacant points in a lattice at absolute zero temperature, c..;,, - height of potential barrier for lattice ions at C.T ACCESSION NR: AP4036568 abscluto zero. &-perimental graphs were plottod for or- (11f ), and the activation energy E of both KC1 and KBr was determinod from these graphs. In electron-volt units, E is 2.06 for KC1 and B is 1.97 for KBr (B a E/2 + 4)1). it is sho--m that the increase in electric conductivity of the alkali-halide crystals is caused by Cu* ion capture in free lattice points. Orig. art. hast 6 forimLlao, 4 figures, and 1 tablee ASSOCIATICK: Pskovskiy gospedinstitut imeni S. M. Kirova (Pskov State Teachers College) suBmiTTED,,,. 17mar62 DATE ACQ: 05Jun,64 INCLt 00 SUB CODE: SS 4crrd- 2/2 NO REF SOVs- 001 mm oo6' s/oic)6/64/ooo/oo3/r,005/DC 5 CLs Llef. ilb. glektro'.Alm. I. encr(;., Aba. P20 OCT, A'J' 7 i.. its PerchAu. Ya. 14 T!"'i-l't Effoat of foreign Ions on tho alectria conductiv-Ity of allealk-ha crm,tala. Abstract C*T--*t SLWICEs Izv. Loningr. oloktrabEkbn. in-ta, vy*p. 51, 1963, lob TC:~`C TAGjs Icnic crjatal. orystal conduettvity, forol-n iow in c;y3tal, C~~Jll llal-)Ceno cinjatal (m cloctrolirtic introd-,iotlon of Cu-Iona Into alkali-halor:one crystals (',r,], X-tw), a parallollan can bo soon beWoon t~e lo-arithnic linea of te...-poraturo vs. conductivity for pura cryztals and thoso for the orfatals ult'.~ imnurlty Intreduced un te the saturation point at Cho measurem-iont tor'.Peraturo. Thma, for tho, It! bipurity- conductivity, Ue ae'llvatle,n ener,-7 coincides with ttat rx1orlty carriora. Tho position of the front of tho ion cload leaving the Cr/Slal and tho curront zoazurad In the ci-jotal remit doteminlai; tho axbility and ecneontration of forolm lons, The activatlon-enorf-j componants are determined r % he tw f z te iporaturo-condactivity curve and tho =bIlity [Fskovskiy gos. pcrd.,.-ogIcb. In-4 Ime S. H. Uroval 1/1 DA73 ACQs IOAPr64 SUB COMs 9V,' SS =1 00 3J 17 PERSHITS., Ya-.K.; GUTMO, V.I.; ANGSOVA, A.I. Effect of foreign ions on the electroconductivity of irradiated alkali halide crystals. Izv. vys. ucheb. zav.; fiz. no.1:3-7 164. (M] RA 17 -.3) 1. Pskovskiy gosudartAvennyy pedugogicheskiy institut imeni Kirova. PERsHrTs, U.N. Motion Df metal ions in alkali halide crystals. no.207t*L32-148 161. (MIRA 16g5) 1. Pako-eskiy gosudarstvanny-y podagcgicheskiy Institut imeni S.M. Kirova. (Alkali metal halide zrystals) (Metal ions) PERSIIITS,,..Y GUTMAN, V.I. Effect of capture centers on the electric properties of alkali halide crystals. Uch.zap.Pbd.inst.Gerts.no.2G7sl49-162 161. (MIRA 16 1. Pskovskiy gosudarstvennyy ped~glcheskiy institut imeni SiM. Kirova. (Electrons-Capture) (Alkali metal halide climItpes--Electric properties) MSHITSP Ya" No Effect of strange ions on Um electroconduokvity of alkaU netal haUde crystals. Izv. vye. uch. Sav.1 fiz. 323-8 162. (MIRA .15:10) 1. Pokovskly pedagoeicheakiy institut imni S. M. Kiffta. (AJM3.i ustal halide crystals-2ibetric propolfties) (Ions) 2/XWP(q)/EWT(m)/BDS/T-~ AITTC/"D/SPD- PU-4 i 1304.~' 4 PAM - ACCESS1011 NR;- AP3DO0613 toy AUTHOR. low TI= rhe mechantsm of changina conductivity during aging of YnAIIS ceranLes -be keetrolyj,13 of alka.111-halide crystals and + W=,, ;~Fizilm tv~rdogo tela., V, 5. no* 5v 1963.,11348-1357 % ~tdntalum, alkali halide, ceramic aging, resenera- 1-71OPIC TMIS: rutil titanium~ .1 tloni F--,,,'enter., C%'Mr, dislocation.,conductivity,, rutile cermdc, rut.ile. cerar:&c iN;Ing 41 AWMACti' The aut4or'n purpose In to show experimentally that not only regenerwtjon but atso succeeding aging of 'An-bearing ceramics con:for= to the same.pa*~erzi ibatjs observed in alk-I *1 -halide 'crystals' during compiwaie rciethods of Investigatich. In his experiment be used the staining Method with S flat tantalum: electrode' and found Weat: similarity between the .Ti-bearing cermles J'and the i0knI-1-hallde3. His'results show that at relatively.low temperatures (10D-3001~.-) the move.t~,t of added current carriers tokes plsce within the: crystal 4 grains g dislocations that remain in Car, ratile Or within wssic blocks, forrAn Ithe c ers could be F-centers,but since such rystal after annealingo These carri 4card 7/2. A-487= M; "3000613 xi~~Ji -Mv~* b,e ~divplaced only vhen Ionic conductivity In yrezent.,* aging' early t tratures giving Mte to marked displacement of Ions Inthe.elee begiz~ a teMe Icia field. 1he Identical haractdr of -'them tim relationship of curr=t at all texNkratvres, tring which aging vas observed clearly yoints to electrolytAc oo, opses In satociation v1th obange f= rapneration to ronewed aging even at w 'low leveraturas, Considerable doat Is cast on data suggesting the electrolytic condiictivity Is absent in titardum o~dde, it Is more I:Lkelv that the e2ectrolytic prodt, ts gathers at the boundaries of wassic blocks or crystal'grains. ne aging of T16-bearing cerandes at high terVaratures is associated with the spread of Current carriers, from both electrodes, but regeneration is associated vith the izwmnt 6etrcn cipids. Orls. art. hast. 8 figares, 2 tables,, and I I formulas. of el hS=,MTj PSkj:~VS]M, -S. H. Kirova, V gosudarstvenrW*y pedagogicheskiy institut in. State Pedagogical ImUtute) P-skoy SUMMr4MM: OSNcw62 DAIE ACQ: 11 JUa63 MM: 00 SUB 0#,; 00 IND W SDV: 012 OnW: ODA Ca 2#1~ -- - ------- PERSHITS. Ya.N Mechanism underlying conductivity variations in the aging of rutile ceramics and the electrolysis of alkali halide crystals. Fiz.tver.tela 5 no.5tl348-1357 My 163. (NIRA 16s6) 1. Pakovskiy gosudarstvennyy pedagogiche8kiy institiit imeni Kirova. (Ruttle--Electric properties) (Alkali metal halide crystals) PFMHITSP YEL.R.; GUNAZI, V.I. Effect of foreign ions on electron processei3 in ionic m7stals. Izv.vys.uch.mav.; fiz. no.4:123-129 162. (MIRA 111:9) 1. Pskovskiy gosudaretvennyy pedagogichesk:Ly institut. (Ionic crystals) (Electrons) s/139/62/ooo/oo4/010/018 E132/E435 AUTHORS: Pershits,.Ya.N., Gutman, V-1. TITLE: The influence of foreign ions on electronic processes in ionic crystals PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Fizika, no.4, 1962, 123-129 TEXT: It is established that the influence of added colouring on the electrical properties of alkali halide crystals is caused by the presence in them as impurities of heavy metals, the ions of which act as centres for trapping electrons. The trapping of electrons by foreign ions in crystals irradiated by X-rays has been studied experimentally. A means of colo 'uring crystaln from a plane metallic cathode is described. Trapping of electrons by ionic impurities leads to additive oir subtractive colouring of the crystal. As a result of additive colouring the neutralization of impurity ions takes place decreasing the number of trapping centres. The trapping of electrons leads to changes in the electrical properties of the crystals. There are 6 figures. ASSOCIATION: Pskovskiy gospedinstitut (Pskov State-Pedagogical ~UBJIUJD: May 3s 1961 Institute) ar 3 2 0311. S/139/62/000/003/001/021 Eo39/E420 AUTHOR: Porshits, Ya.N. TITLE: The influence of impurity ions o),,% the eloctriral conductivity of alkali-halide crystals PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Fizika, no.,3, 1962, 3-8 TEXT: Copper ions are introduced into KDr crystals by passing "J_ an electric current through the crystal using a copper anode. The temperature dependence of the electrical conductivity of' KBr is measured for different temperatures of introduction of copper and the activation energy is shown to be - 0.1 ev less than for the pure crystal. There is a significant increase in conductivity as the Cu* ions enter the crystals and a corresponding decrease when they are removed by reversing the direction of the electric field. Measurements are made of the mobility of copper ions in KBr, KC1 and NaCl. The temperature dependence of the concentration of copper ions coincides with the temperature dependence of ionic vacancies in the crystals (at bqP-~C the concentration of ions is - 5 x lol7cm-3). Cardli/v PERSHITS, Ya.N* Aging and regeneration of ceramics containing titanium. Fiz.tver. tela 3 no,n;*95-3502 11 161. OMA 1-4: 10) 1. Pskovskiy gosudarstvennyy pedagogicheskiy institut im. I&M.Kirova. (Ceramics) (Titanium) I.T.2 L40 AUTHOR: Persh its, Ya. N. TITLE: Ageing and reooveri of titar.. ir 30792 16,?/003/011/036/056 -%.ruing ceramics PERIODICAI: Fizika tverdogo tela, v. 5. r ~, 1, *961, 3495-3502 TEXT: The electrical 'conductivity of ceram, - -.-r.-.-_1ning titanium increases then a constant electric field L_iz for some time. Thia process is termed ageing. When the direct.,~T. 1_' -~,e field is reversed, electrical conductivity will rapidly drop aa,.. 4t.icn process is called recovery. The variation of current with t~a., *~,q mtasured in T-80 (T-60) tikond ceramics in the temperature range 16"_ -`-1 '' Disks with graphite Reeovsr~ .i. --iti)d theoretically as electrodes were used as samples. the migration of an additional-carrier c1C.'! grain boundaries. This was confirmed by experiments which :il' the mechanism holds good at lot, temperatures (i.e. t