SCIENTIFIC ABSTRACT PETROV, YU.G. - PETROV, YU.L.

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SCIENTIFIC ABSTRACT
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J, 8 1 L.4 r 7 k. ak K A 1, 'It k-V M a sk. I Iturorkov , , !.: o, Ei k 11 j v ti , v . -,i n n b v f .9 e r I i in the flqaion of i by lioqin S: ;:R,^ F: Vri;;,crii ttj,~ i A ed Neytronnava fzikr., CC'. rb t:.P I, of Sr Zr' yv' n fisai,,n of U d i y f i ET, or, ni-ty t ~rri u r.r, i I,- p" a te arrar,.-,ed In the therL-l -:olumn --,f 4 re&,-Lr~r of tr.o AS USS-'-( Berved as n(--utrin Bour~-e . 500-rw tarceti were produced from each oubst~nce to be flssiaw~ Tho I evet-A6 zerc recorded In a flosic-ri chamber during the entire krrni.a*.ic:-. puriod (Fit;. 1) The fission fraFment yields were determinei fr--- ~:,-ir Card 1/f 0 7 n t V Vol A A N Id Y --urd . ;i Eq u lim P, ni- e Ivanovalkly ~m-, ;rjst,4t~.- r, a rga n, k i k i 5(2,3) AUTHORS: Balandin, A.A., Academician, SOV/20-1 27- 3- 21 /71 Klabunovskiy, Ye.I., 2a-txov-,-7u.1. TITLi~. Confiburation Interrelations in Stereospecific Catalysis P&iIUDICAL: Doklady Akademii nauk SSSR, 1959, Vol 127,Nr 3, Pp 557 - 560 (USSR) ABS'THACT; The multiplet theory of catalysis shows the existence of a certain structural homology between the reacting molecule and the fine structure of the c&talyst surface. These relations were investigat&d by several examples of the heterogeneous catalysis (,Ref3 Henceforth they have to be investigated in the field of asymmetric micro- heterogeneous catalysis, sincP tn~! principles o -" 'n e structural and energy correbpcndt~nce oi the uuil-ip~"'t theory was also applie,i to foi-- ~-., ta f i'~, Ile efTectivity of' the stereospecil'ic c,~talysis dapen,s in the degree of the structural no7-res,;ondenc-1. Therefure it is of interest to enlarge the know'-edge about reaction!i Card 113 catalyzed by micro-b;terogeneous asymmetric ratalysts Configuration Interrelations in Stereospecific Catalysis (ferment samples). Skita catEdyst (colloilal palladium vith gum arabic as protective colloiC.) as such kHef 7). These catalysts were produced accorzin,~ to referenceg which was altered according to referenc& 1 Phenyl- and dkfrnaphthyl- glyoxylic acids were chc,,--r~ initial compounds which develop oxy-acids with a able optic activity namely: mandelic acid and " -n~nht glycollic acid. These turn in opposite direction, bt-1 to the s,ime configuration series. Figure 1 3hows ki.-.- curves of the hydrogenation phenyl-,Iyoxyli- ~ic-'-J n, the dioxime in coordinates: rc-action rate versu and rate versus - degree of tranrfo:-:--tion. ~abij results of characteristic Px7eriment, with rej-r.1 optical activity. The comparativ-e-ly hi.-.-, va'Lu,-. )f 0-.e optic activity of the develo2ed din-mine is ntrikinj~. T1-- results obtained show certain configuration interrelations between the catalyst and the reacting molecules. In the cases investigated the protective colloid (gum arabi2) does not seem to act as asymmetric carrier, nor as optically active solvent. The asymmetric carrier chosen by the aut'jors Card 2/3 has a selective effect during catalysis, since it favors the Config-uration Interrelations in Stereospecific Catalysis SOV/20-127-3-21/71 development of an acid with a D-configuration. The above results prove a great configuration correspondence between the asymmetric catalyst (rather the asymmetric carrier) and the spatial structure of the reacting molecule (Ref 13). Special experiments proved that the protective colloid also acts as asymmetric carrier (also Ref 2). The results obtained finally prove that the metal particle is not in the solvate cover of the micelle, but immediately contacts the asymmetric molecule of the protective colloid. The course of an asymnetric adsorption and of such a catalysis thus become possible.Tbere are 1 figure, 1 table, and 13 references, 11 of which are 3oviet. ASSOCIATIOP: Institut organicheskoy khimii im. N.D. Zelinskogo Akademii nauk SSSR (Institute for Organic Chemistry imeni N.D. Zelinskiy of the Aoademy of Sciences, USSR SUBMITTED. May 18, 1959 Card 3/3 FITRDV, MROV, Ye.I. Bffect of shock waves on the wear and tear of kzxittiAg needle hooks. Tekst.proza. 20 no-5:39-43 MV 160. (MIRA 13:8) (Knitting machines) (Strains and stresses) KIADUNOV,KIY, Ye.I.; :.A.LAMIN, A.A., akademil, PET-IWV,-Yll 1- Hydrogenation ofco.-keto Lcids over a cclloidal ;,allac-u~. yz--. Dok-1. AN ~-'Sft 13~ no.2:377-36.0 JI 161. i'M T ;~; 14 1. In6titut organicheskoy khimii im N.D. Zelinskogo AN (Acids, Organic) (Byurogenation) .21 ( 8) ' AUTHOR: Petrov. Yu. I. ' TITLE: nd Pu ma R eiation From U T1. e an - 2~5 2 (Gammia-izlucheniye oskolkov U :R, C L , V9 a ener6i, 3L. 1 ~)5? _ , A-L T of flssi~,l fr_~ iv_~lent ioniz,_* ,i 'in l.: _zl e -n examine- .,:th LL-1 air.e:lu~ I,e C~Lrl-ied --it u, i:4 t v counter. The exw..-ri _t i ,ilc . 0 i, 1 lti from 3 0 sec to hours aft.:r the irr: I .f the tar.,et~: rare t:.e e v, ,-)f the U~, e L., ~,:. 11 - 41 1!,e (, scc, _-_- ""Ke inniz .::ion :::e:_,-.ure..e:.. .-,-ere cor..3u.-ted ~,ith d5ffere..,+ th.2 detector -th i- in -nen thil.- 11 G. d f~ w I q 1j _~ C G 11 r e elect.r,~deaq con_i.,~ted -)f ~n t_ AA .1.0 t 1. stfewns viere inten_,ified ~Lndl -ec ..-,h; use of a -feedback (..ef 2 _Lnd ~i:e ",u- i:~~ of the ai;q.llifier redured 0~0, 1 Card '/4 the t...rL;el,. me-,~3ured lb, tl:e 6- _L, I i v f :. - C, i ~ 4~ ! " , - The ;Gnintra Radiatlon From U23r and Pu 239 Fijsio~i Fi-LL~ents 7-OV/9-1..7 ~uhich -.-irLs si.--.,u- eour, - -Irw ~vith the use of a xt-h 275 navrn cl,aarge :)f U -- (Ti-,is metll.ord e by 0. 1. Le- --an,:kiy. V. e t 0 f e 17 t he i: I I h- 2 th e expe r i i;,e nt 1 :7i e i% Q '.he 2-~ -L h e L, ej.- ,,or e f a,., e, 1 later :..e:-,ti~:-ed re-ults ^cLr'.. the n Ld work cf T. T. Le-.,.int,-v V. V, a:id + 0 can be estiLlished that ti.e thermal neutronn md flle Dr Of :Iator~! 1 nard 2/4 2 x r, 219 , .-, ~, 8,.- -- -- I c .1, , The Gamma Radiation U -nd Pu i s ~- 1, 3 --1 7 Iragments neutrori3 are Identic,il. 1'1;e in-space I-'r-idi,itinn in riater v,,a,,3 also i.-iearured. ;;ero .:,)o,'. inoc found when compared with former tudie7,. '!!.e -,ield cf the T-radiation energ-j- in one second per N-.-a2 'et-Tinined, i", three methods, each indai,eridont from the ntl,crn: I ) Uie in-:-,~, , c distribution of the ?-(Jocin in water -,--ran inLeLratccl, 2) tl:e d ztx of the ionization measurements in open ~ir .,,-are evaluate,'; ~--S mean ?--ener,-~, 1.5 Iflev was assumed, ~) the F--;cLivities of U2 2-9 2 3 ;ruuFe t -,r.--e t and Pu tur,-,ets were compared with ~- Nu Was simultaneously irr:,diated ril'th thermal neutrons. T:.e measuring results from 1) and 2) are identical up to In the ran-e (25-60 sec) the results of 2 --.-.d eet overlappini- 11 - up to -4 10 For the values Er(t) in the different time interv:lls the meiisured c-.,.--ves car, be approximateal i:. '.-e following expressions: 0.05 to 1.' sec: 11-78 exp (-7.14t) + 1.'3~1 t 2 + exp (-0.C51 )I 10 to 60 sec: 6.26-10- [2.1B exp t) + e-71; Card 3/4 1 . .1 j] 2-1,5 2 7~ -I The ;wwna !iadiation Prom 11 and Pu Frai:L-ents 60 to 72-00 sec : I - 1 15 05 1.5 to " h: 2-97-10- t", ,4 The thei.-e of thiz stud- w-~s -roposed 0. 1. Le~,pw~skiy. There axe 5 10 references, 4 Df Lre su,~crvised lb, fi,-,ureq. -1-d joviet. U B V. ITT l'arch 27, 1959 Card 4/4 PFTROV, Yii.l. li. 1-11 l--. Mall.ing of amall Pb cryist.rils. Fiz. *.vear. to!'h ' , 1, -1 - ) ) i, (ICRA 1. Institi.* kh--'m-I*che.-,koy l'iziki AN SSSR, Moskva. ZUBAREVA, N.D.; OBEREMOK-YANUBOVAt A.P.; PETROV, Yu.I.; KLABTJNOVSKI-Y. Ye.l.; BALANDIN, A.A. Determination of the heats of combustion of DL- and L-mandelic acids. Izv. AN SSSR. Ser. khim. no.1212207 D '63. (MIRA 17:1) 1. Institut organicheskoy khimii im. N.D. Zelinskogo AN SSSR. ,-E I r~(!, 9 lu. 1. Anomalies of the ~rie-.,Ttal expaviic,ri an(I ;i3i-r. c. saariIl a1tuni'rit-L-n crystals. Fiz. twer tela 5 no.9:2461-2-/.76 3 163. (KIRA Ir : - ', 1. Institut k-d-,,-i,,!he.3kny fiziki AN SS.~R. PETROV) YU.I, High-temperature X-ray camera ':~- analyzing powders. Frit. _' tekh. ekap. 8 no.41162-164 JJ_Ag 16" (MIRA 16:`~ L~ 1. Institut khimicheakoy fizlkl AN SSSR. REZANOV, I.A.; NGO TKHYONG SHAN; SHFYNKANN, Yu.M.; RATS, M.V.; KFUG, O.Yu., ZYRYANOV, V.N.; RAKCH-;;TFV, A.D.; YAKOVLFVA, Ye.B.; PET~CVA, Y.A.; KUZNFTSOV, Ye.A.; YUUINA, V.7.; BA.P.DINA, !f.Yu.; SI~6~ICH, I.M.; ATANSYAN, S.V.; SERGEYEVA, A.M.; PARFFNGV, S.I.; RUTKOVSKI, Yatsek [Rutkowski, Jacek]; MAKELINA, M.Kh.; ZVEPYV, V.P.; TERNOVSKAYA, V.T.; SAMOYLOVA, R.B.; YF.HMAKOVA, K.A.; BYKOVA, N.K.; MEYYEN, S.V.; BARSKOV, I.S.; ILIINA, L.B.; BABANOVA, L.I.; DOLITSKAYA, I.V.; GORBACH, L.P.; BUTS'KO, S.S.; 'hFSKIR',KjY, JI.A.; SVOZDFTSKIY, N.A.; PRYALVKHINA, A.F.; GROSVAL'f.,, M.G.; MODFL', 'lu.m..: GORYAINOVA, I.N.; MEDVFDFVA, N.K.; MYALO, Ye.G.; DOBROVOL""KIY, V.7.; KHOROSHILOV, P.I.; CHIKISHEV, A.G. Brief news. Blul. MOIP. Otd. geol. 40 no.3.-122-154 My-Je NPI IP:P/I ACCESMU NRI API-OW-861 S/0181/63/ODS/M2/3533/35W AUMR& Petrays _INLXO, TMA# Men little Pb crystals w1t SWECRe Fialks. tvardogo tela, v, 5,9 no, 121, 1963m 3533-35W TOPIC TAGSs lead crystal,, lead "ptal meltin& thermal expansionj, melting point,, lead crystallites aerosol particle, load, malting ARSTR=s X-ray studies U re made of the ther=Ll eqpansion and melting of aerosol particles of lead - 2o10 on in diameter, The author discovered a small over- heating of particles to -18G above the melting point,. which is wcp1ained by the difficulties of foraing nuclei of liquid with4a the sm;LU volume or the substance. He has shown that the cours* of thermial expansion and the lattice parameters of the particles agree with data for massive astal. In contrast to Mmile experiment* with eero al Particles of aluninia no effects of oxide coatings were detaoted, The author measured the temperature factor of x-ray s"ttering up to the melting point of the a7stAlUtese Obserwed dowUtion from, the Debye4sllsr them7 is Cwd 1/2 ACCEMON MR: API"861 wVlained by the developeaft of structural lattice defects, On the basis of studies on the function of r&dI&W distributed atom of liquid lead and by coVar- ison of the laensity of radiation scattered by crystallites and the mit, the author concludes that advantages my be gained by employing a polyarystallins model of a liwid, wZhe author c;~rsxses Us tha*s to Tue I* Pedorvr for Us aid In the work.% orig. aft. has 1 4 ngorem. MWUTMNI Inatitut Idd-Icheekar fisiki AN SSSRv NDsom (Institubs of Chemical Pbyvios AN SM) SULKMMI OSJHW DA22 ACQs War& ENCLs OD BUD COBB$ PH NO RIW BOYs MS ordERS 010 !Cwd me KLI-SiPt' '111A 'Y , Y , . : . ; 1; '.' 11, ' M,, '~' , Y , , , . 'r -,, -~ -,- , y ~; . z . Ap~ -I ' -a '- : ~, ' . : * p - -, ..~ *, :-.1 ''. , -. i7 :- _, C-F, '- '. , .-~ 2 *, -,:'7 -, " --- - v- -.- - I I~Urp- of ;2*,~ .-I --Ivne.- . r - '64. k.~11*11". "-: --~ I. Tiis, it t, 11 c:ym.,-.' ~ -, , mon! I'e I lrns~uvo. PEnOV, Yu.I.; PUS TN, B.A. Dispersed condensates of al--;minum vapur on glass. bok--. 1~?" 7C~:rl 160 no. 5: 1133-1135 F 165. J. Institut khIm-icheskoy fIzIkI AN ~S)~;R. Submitted AupBt -u, 19t.,4. ACCESSION NR: AP4041722 S/0181/64/006/007/2155/2159 AUTHOR: Petrov, Yu. I. TITLE: Anomalies of thermal expansion and scattering of X-rays for small nickel particles near the Curie point SOURCE: Fizika tverdogo tela, v. 6, no- 7, 1964, 2155-2159 TOPIC TAGS: x ray diffraction study, nickel, x ray scattering, nickel, ferromagnet, thermal expansion, magnetic structure ABSTRACT: To ascertain whether crumbling of nickel leads to effects other than loss of ferromagneLlsm, and to investigate the physical properties of small ferromagnetic crystals, the author studied by X-ray diffraction the thermal expansion of single-domain nickel particles with average diameter -5 x 10-6 cm. The nickel powder was prepared by an aerosol method, with metal vapor condensed in a rarefied argon atmosphere. Most particles were oblate spheres and Card 1/5 ACCESSION NR: AP4041722 had a narrow (2:1) range of particle size. Volume anomalies, ex- ceeding by two orders of magnitude the corresponding effect in bulk metal, were observed near the Curie point. The temperature factor of X-ray scattering obeys in the main the predictions of the Debye-Waller theory, exceptu" the temperature region near the Curie point, where the heating of the particles is accompanied by a re- duction in intensity and a smearing of the lines. After a repeated heating of the particles, following annealing from temperatures above the Curie point, these anomalies were eliminated. The ob- served phenomena are explained under the assumption that the parti- cles are made up of a large number of initially oriented magnetic- dipole "subcrystallites," whic-h execute under the influence of the thermal motion small rotational oscillations about the equilibrium position. Orig. art. has: 3 figures. ASSOCIATION: Institut khimicheskoy fiziki AN SSSR, Moscow (Insti- tute of Chemical Physics, AN SSSR) Card 2/5 ACCESSION NR: AP4041723 S/0181/64/006/007/2160/2167 AUTHDR: Petrov, Yu. 1. TITLE: M~!I'~!.Lrj and crystallization of small particles of Bi, Sb, and Pb. muchanism of phase transformations of metals SOURCE: FiziKa tverdogo tela, v. 6, no. 7, 1964, 2160-2167 TOPIC TA~;S7 ',,-Lsmuth, antimony, lead, x-ray diffraction study, phase transEt-)imation, melting, crystallization ABSTRAC'I': A(ii~)sol particles of Bi, Sb, and Pb with diameter -2.5 x x 10 m wete- investigated by X-ray diffraction. Such a study is Of illt :, !'.-L :11 -in view of the absence of complete theory of phase L.,1116f(11;11dLions of condensed systems, knowledge of the melting and cry.,:~-'-'I-lization of minute metal particles can explain the role of the scale factor and disclose peculiarities not observed in bulk metal. The 1,fghly dispersed particles were prepared by drawing Card 1/3 ACCESSION NR: AP4041723 metal vapor through a rarefied argon atmosphere (0.1 mm Hg) and con- densation. Copper X-radiation was used,at Z 33 kV and 20 mA. A lowering of the melting point was observed in the case of Bi and Sb, and superheating in the case of the Pb particles. It id shown that near the melting point the Bi and Sb lattices contract and tend to a closer packing. Freshly prepared Bi powder contained an amorphous fraction which had a long life at room temperature and was stable against heating up to the particle melting point. The results are explained by assuming minute single crystals to consist of many subcrystallites, each with several face-centered cubic unit cells on edge. This holds true even at room temperature. The na- ture of the subcrystallite boundaries is still unclear. Unlike mosaics, the subcrystallites are not affected by preceding heat treatment. or origin. This hypothesis is confirmed by experimental and theoretical results of other authors. "The author is grateful to Yu. 1. Fedorov for help with the experiments." Orig. art. haal 6 ficjures, 2 formulas, and 4 tables. Card 2/3 ACCESSION NR: AP4041723 SOCIATION: Institut khimicheskoy fiziki AN SSSR, Moscow (Institute Chemical Physics, AN SSSR) 7TED: 24Dec63 CODE: MM, SS NR REP SOV: 015 ENCL: 00 OTHERs 024 3/3 800b 31020160/1 PM4 /'B-j64 AUTFORS: Gen, Yl~ Ya. and Petrov, Yu.. I. TITLE: Emission of Cher.ically Active Particles in Aluminum Oxidation PE,R 10 DI7A L Doklady kkademii nauk ISSSR, 1560, Vc! 157, No PP, 1361_1~76~ TEXT: The authors state that. aluminum. qurf~ir,~s freshly prepared in "uminum -bas sprayed vacuum blacken X-ray films in the presence of air. A. onto glass plates from glowing tungsten wire at ap.-roximatelY 5 10 torr, or as aerosol in argon at G.1-1.0 torr. Ordinary photographic films were not sensitive, 11X11 or "XX" X-ray films were blackened or, ap-,lying the glass plate. The effect is prevented by luminescent crystals of Cs1, Nal, KI, anthraceno or naphthal tine, I;y a;ply1nF an oil film, insertinn of black paper, mica, slides or quartz, as well as blowing air between glass plate c~nd film. Fig. 1 shows a diagTam of the blackening measured With the AO-10 (DFE-10) densitometer as a function of the time elapsedg,71n ~e~e production of the aluminum layer. The aluminum particles Card 1/3 8004 Emission of Chemically Active Particles 'n S K Aluminum Oxidation BV-'Q4j'B064 had a diameter of approximately 10-5 cm, measured with the ~M,3(zl.Z' electron microscope. Fresh aluminum layers caused more intensive 'blackening than older ones at the same t'.me of exposure lasting one hour. Fig. 2 shows the diagram of a glass plate sprayed with aluminu,,.-.- aerosol on an X-ray film. The more intensive hlackening found at the edges is explained by the differences in dispersity and temperature of the particles on the surface and edges of the glass plate. Fig.. 3 sY;ovs the shadows of slide and quartz, as well as of a two mm Eif-h brass ring The dependence of the blackeniri~- )n the height of the air layer (ur to three cm) in pipes of aluminum, copper, or brass can be Feen in Fir. 4. The authors assume that the blackening of the film is caused by an ai-enT formed in aluminum oxidation, presumably ozone They thank I.V Yererrin~, and Yu. I. Fedorov for collaborating There art- 4 fi:~ures coviot references. ASSOCIATIOV: Institut kbimichoskoy fiziki Akademii nauk S7311:R (Institute of Chemical Physics of the AcE~demy of 7ciences 7--SR) PR_-'S_--NTz._T-. March 31, by V. N., Kondyat'yev. Acu.emician Card 211, 84706 Em " s u i C. !, Active purt; -- .-~s in Alumiru,r ation 3. -~ BY I". ,-' : ~,'.a r c 1. 11 C , 1 ~.) ' 0 7 - li ~2'--,:',-'.--,'l -I'--,., . '-- - A I Card 3/',~ 4953-66- EWT I J)AWA.(~)T-IZ JK SOME CODE, ;r86/65/OOQft --AUTHDRS8 -Xitinv 1~- Petron Tue 1. 3yurins, Ve-L.; Wtnlk,, V& 11!5 C~ ;4~ --.ORGI none ~TITLW Strain W of oi cattle. Clans 30p .a~e Byulleten' isebrateniy i tovarnykh anakov,, no. 16, 1965s.67 virus Wj cattlep lamnity ABSTRACT: This Author Certificate describes the strain U of the plague of cattle, 1964. Culture properties: grown on a culture of cittle kidney cons. Causes - cytopathogenic action with formation of aMlasts,, internuclear at~d cytoplasmatic inclusions on ths 4th to 9th day. after virus injections Titer 10~1'p TaPD 5014* -Reactogenic proportions causes a light toWerature reaction in affected cattle. Antigenic proportions causes the formation of virun-noutralizing and complement- Axing antibodies* lumnogesdo proportions causes in animals a sustained. immunit: ..to epizootic virus according to the type of interference* Nonroversiblej non- Card -"76.Q5�jj6:Lq 6.990.27 5W SOV120-127-2-361'70 AUTHORSs Gen, M. Ya., Ziskin, M. S., Petrov,-ju. I. TITLE: PERIODICAL% Investigation of the Dispersion Degree of Aluminum Aerosols in Dependence of the Conditions of Their Formation Doklady Akademii nauk SSSR, 1959, Vol 127, Nr 2, PP 366-368 (USSR) ABSTRACTt Fine-disperse metals stand out because of their high adsorDtive and chemical activity. Therefore, the importance was felt of investigating the relationship existing between dispersion degree and activity for particles smaller than 10-5cm. Owing to the difficulty met in preparing particles of sufficiently similar size in the mechanical way, the method by Gen, Zellmanov and Shallnikov (Ref 1) was applied. Aluminum was evaporated on a tungsten spiral in a glass flask filled with inert gas (Ar, Fie, H). The loose precipitates forming on the cooled flask wall exhibited a different coloring depending on pressure and kind of gas. The black (finer) precipitates tended to self- ignition in the air. The dispersion of the aerosols was investigated by means of the EMZ electron microscope. The degree of dispersion was determined by counting and measuring Card 1/3 the particles on photographs (Fig 1). The differential and Investigation of the Dispersion Degree of Aluminum SOV/20_1 27-2-36/70 Aerosols in Dependence of the Conditions of Their Formation integral distribution curves were in all cases similar to those shown in figure 2 for an argon pressure of 27 mm. The dependence of the weight average of the particle diameters on pressure and kind of gas is illustrated in figure 3. In each gas a maximum diameter characteristic of the respective gas is attained, which does no more change with further pressure increase. In the case of gas pressure below 1 mm the particle diameter was smaller than the resolving power of the electron microscope (,....10-7 cm). Table 1 specifies the oxidating properties and the analysis of the aerosols oxidated in the air. Figure 4 shows the dependence of the metal content in the oxidation product on the diameter of the particles. The oxide layer thickness waB determined therefrom as amounting to about 10 molecular layers. The spherical form of the part4-cles is a Card 2/3 Investigation of the Dispersion Degree of Aluminum SOV/20-127-2-36/70 Aerosols in Dependence of the Conditions of Their Formation characteristic feature. Attempts are being made to clarify the structure and the processes in the formation of the solid phase. The authors express their gratitude to A.I. Shallnikov, Corresponding Member, AS USSR, for valuable advice. There are 4 figures, 1 table, and 1 reference. ASSOCIATION: Institut khimicheskoy fiziki Akademii nauk SSSR (institute of Chemical Physics of the Academy of Sciences, USSR) PRESENTED: March 13, 1959, by V. N. Kondratlyev, Academician SUBMITTED: March 3, 1959 Card 3/3 PMOV, Yu. I.; KARAVAYAV. M.R. Rquilibrium in the vapor-phase sy-nthesis of nitric acid. Izv. v79. ucheb. zav.; khim. i khtm. takh. no.1:119-lZ2 158. (MIRA 11:6) 1. Ivanovskiy khimiko-tokhnologicheekly lustitut, Kafedra, tekhnolo- gii neorganicheakikh veshchestv. (Nitric acid) ACCESSM NRs AP4011778 3/0192/64/006/001/0315/0316 AIMFOR: Petrov, Yu. 1. TITLFs Tomparpture factor in the dispersal of x rays during anomplous heat expan- sion of small aluminum crystals SCIIRCE: Fizika tverdogo tela, v. 6, no. 1, 1964, 315-316 TOM TAGS: x ray, x ray disperiall, temperature factor, anomalous heat expansion, aluminum, small aluminum crystal,serosol particle, oxide film, heat treatment ABSTRAM The temperature factor related to the dispersal of x-rays in aerosol aluminum dust with a mean particle diameter Of , 3.5 x 10-5 cm has been investigated. The powder had been held in dry air for a long time. Apparptus and method used in this work were the same as those previously described by the author (FTT, 5, 2461, 1063; PTE, Wo. 4, 162, 1963). Experiments were conducted in argon under the pres- sure of 25 nn 11g. Lines (111), (113), (233), and (315) were messured photometrical- ly on roentgenogroms (the intensity of lines at 23C was taken as a unit) . Up to the temperature of - 9DOC theoretical results and those obtained in the present experi- ments showed good coincidence. At thi s temperature the anomalous parameter of the metal IRttice is Fpproximstely the same as thnt near the melting point (6WC) of Card 1/2 ACCESSI CN N R: 04011778 massive retal Pnd of the sare particles covered with arorphoua o3dde. Thus, at high pressure, the Dobye-Valler theory proven correct forQ - const. across the entiro temperaturo renge of this investigation. Experiments at atmospheric pressure produce 9 as a function of the crystal's temperature. Orig. art. bass I figure and 2 forLralas. ASSOCIATICV: Institut kbimicheakoy fiziki AN SSSR, Moscow (Institute of Physical Chevdstry AN SSSR) SUBLITTED: 05Jur.63 DATE ACQs 106b64 ENCLt 00 SUB COD-rt PH NO FdF SOVs OD2 OMRs 002 Card V2 S/120/61/000/002/042/042 E210/E594 AUTHOR: Petray,__Yu. I. I--- -- - TITLE% A New Method of Evaporation (Vacuum Deposition) of Aluminium from a Tungsten Wire PERIODICALt Pribory i tekhnika eksperimehta, 1961, No.2,pp.196-197 TEXTt A new method is described of evaporating aluminium, a method of sliding the drop along the vertical. The instrument consists of a 12 cm long evaporator a which is twined from four 0.5 mm dia. W wires and fixed vacuum tight on current supply leadeg which are cooled by running water and arE insulated from the body. A bent nickel-plated copper tube 6 is introduced through the lid, using a rubber seal; this tube can be moved vertically and rotated about its axis by means of the handle A , With the help of gearing 2. inside the tube, aluminium wire of 1.5 mm diameter is fed through the rubber seal e. The tube is adjusted to the desired height and is turned to the side away from the hot evaporator, which allows the passage of about 50 to 60 A. Then, a second of 2 to 3 cm of aluminium wire is pushed out, which is fed into the .,raporator by turning the tube. A bit of aluminium fuses rapidly Card 1/3 A New Method of Evaporation S/120/61/000/002/o42/042 E210/E594 and contracts into a droplet. It wets the tungsten and slides downwards, evaporating almost instantaneously without reaching the bottom of the evaporator. By displacing the tube along the height of the tungsten rope, the service life can be considerably increasod thus reducing the tungsten consumption to about I g/1 g of evaporated aluminium. If the aluminium wire is well insulated from the current leads, the wire will not scatter during fusion. Other wise a shunting of the evaporator may occur which leads to throwing off sections of the wire and intensive scattering of fine droplets. The described method has the additional advantage of axial symmetry; no laborious oneration is necessary for producing the tungsten spirals. The-tungsten wire rope can be easily twinad by a hand brace. If necessary, the central tube feeding the aluminium wires can be surrounded by several evaporators which operate alternately. Acknowledgments are expressed to Yu.1. Fedorov for his assistance in the practical work. There are I figure and 3 references: 1 Soviet and 2 non-Soviet. ASSOCIATIONt Institut khimicheskoy fiziki AN SSSR (Institute of Chemical Physics AS USSR) Card 2/3 AUTHORS: Petrov, Yu. I., Karavayev, M. M. 155 ;)8-1 '8/29 TITLEs The Equilibrium in the Synthesis of Nitric Acid in the Vay::,r Phase (Ravnovesiye pri parofaznom sinteze azotnoy kisioly~ PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheskaya tekhnologiya, 1958, Nr 1 pp. 119-122 (USSR) ABSTRACTs The authors introductorily give a survey of pullicat;uns (references 1 to 5). Since there is always an equilibrated mixture of N02 and N 0 4' the authors wanted to investigate the equilibrium of Ne synthesis referred to in the tit"e, if and when 5 reactions take place at the same time; ---~ 4 HNO + 2H 0 + 0 4NG + 2H 0 + 0 (1), 2N 0 ---2 4-4110 2 2 2 *-- 3 2 4 2 2f 3 and N204 kt ) 2N0 2 (3), so more as this problem has never been dealt with in publications. The values of the e q u i 1r i um, constants of the individual reactions which were calculated by means of the isobar-isothermic potential (references 6 im to 9) are given in table 1. The equilibrated gas concen-.rati0rs for the initial relations can be found by various methods. C ard 1 A The authors found it convenient to find these concentra-.ioni The Equilibrium in the Synt~,esis of Nitric Acid in the Vapor Phase 1-53 58 -1 -18129 Card 2/4 first by separated 91103-synthesis by way of N02 and N204. In this case, multistage equations with one unknown are solved before by the method of selection. After the afoz-e- said concentrations were found with the synthesis according to (1) and (2), the shares of the participation of the partial processes in the total process are found by mearip. of the method of selection (taking account of the eqi,i.libr-ium according to the equation (3) ) and the real equilibrated concentratiors are consequently found, too. The calculated values of these concentrations of ENO and of the trans-- formation degrees of the nitrogen oxihs in ENO axe given in table 2 for the stoichiometric relation of th com~orients in the temperature series from 325 to 425 OK and with the pressure from 1 atmosphere absolute pressure, According to the increased temperature, the degree of transformation of NO into HNO decreases more rapidly than the degree of N 6 . AccordLg to equation (2), higher degrees of tranz- 2 4 0 formation are achieved than according to (1), but in the total process the synthesis by way of NO prevails. Sinc~- the degree of dissociation from N 20 to 102, increases with increasing temperature, the share o~ the synthesis bv way Df NO2 in the total process increases also. Table 3 shows the The Equilibrium in the Synthesis of Nitric Acid in the Vapor Phase 153 - ~8 8,'2~~ calculations concerning the influence cf the water- and oxygen-concentration on the equilibrated tranafcr:.aat1'.1' of the nitrogen oxides at 3750K. It hence results ti.at according to the increasing content of steam, the trans- formation degree of these oxides in HNO 3 increases continuously. The degree of transformation first increa4iei according to the increasing content of oxygen, with approximately 3 mol it exceeds the culminating point ar order to decrease subsequently. A satisfactory conformity of the calculated concentrations with those found by Dzhouns (Jones, ref. 2) indicates that the authors tackled the solutions of the set problems in the right way There are 4 tables and 9 references, 2 of which are So-,~iel. ASSOCIATION: Ivanovskiy khimiko-tekhnologicheskiy institut, Kafedra tekhnologii neortranicheakikh veshchestv (Ivanovo Chemica' Technological Institute, Chair for the Technology of Inorganic Substances) SUBMITTEDt September 7, 1957 Card 3/4 PETROV, Yu.I.. kanct.fiz.-matom.nauk: PETROV. Ye.l., starfihiy nauchnyy sotrudnik Stress waves in rod-type machine parte caused by a longi- tudinal impact. Izv.vya.ucheb.zav.; mashinnstr. no-5:11-24 159. (MIRi-, 13:4) 1. Institut khimichookoy fixiki AN SSSR (for Petrov). 2. VsesoyuxzWy Hauchnn-issledovatel'sMy inntitut legkogo telcatil'nogn ma eh inns troyaniya. (Strains and stresses) FTTROV, Yu.1. Subthreshold ionization losses in fast-neutron ionization-pulse dosimeters. Atom.energ. 3 n0-10:326-327 0 '57. (MIRA 10:10) (Nuclear counters) (Ionization) (Radiation--Dosage) T il- c v \/ L T AUTHOR: Petrov, iu.1. ag-lo-11/36 TITLE: Su'~-threAcIZ-16nization Losses in -:'as,-','eutrcn 1~rization-lulsrz Dosimeters (PodporogovVe poter' ionizataii .~ ionizatsionno - imnuAnotri dozimetre b~,strykh neytronov) PERIODICAL: Atomnaya Energiya, 1957, Vol 3, Nr 10, np 326-327 ABSTRACT: By means of a proportional counting tube it is possible, ahen measuring neutron doses, to eliminate the 4' -sub-grc-und (arioording to Hurst). The most essential disadvantaEe of this method is caused by the uncontrolable ionization losses below the threshold value). These are measured accurately for the case that the recoil protons penetrate from a thick radiator into a small gaseous slit which always takes place on the occasion of the impinging of neutrons onto the surface of the radiator. It is shown that, if the threshold value is 0,1 KeV, the thickness of the ga-secus slit is I am and the ener&-y of the neutrcns to be rc- corded wnounts to 3 MeV, the ionization losses amount to 31,-, whilst Hurst estimates them only at -,, CO-1 . There are 3 tablc:i. SMOTTED: I-ay 24, 1957 AVAILA13LE: Library of Congress Card 1/1 TOLSTOPYATOVA, A.A.; BALMIN, A.A.; MATIUSHENKO, V.Kh.; PETROV, Yu.j. Kinetics of the dehydrogenation and dehydration of &lcohols, and of the dehydrogenation of hydrocarbons over WS2 and MOS2 catalysts. Izv. AN SSSR Otd.khim.nauk no.4:583-590 Ap 161. (MIRA 14-4) 1. Institut organicheskoy khimii im. N.D.Zolinskogo AN SSSR. (Dehydrogenation) (Dehydration (Chemistry)) (Molybdomim sulfide) (Tungsten sulfide) PETROVO YU-I,- I- khimicheskoy fizik (Aluminum) 1'-~ TT, YEPOBESHNIKOV, V.N.; KIRILLOV, V.P.; EJZIMIN, V.H.; PFMOV, YU.K. Dynamics of the effective angle of the sector in accelerators with rectangular sections. Izv. vys. ucheb. zav.; fiz. no. 1:139-1L4 ,6o. (MIRI 13:12) 1. Hauchno-issledovatellskiy institUt Dri Tomakom politekhnichE)skom inBtitute iment S.M. Kirova. (Partirle accelerators) A06 P/A I AUTHOR- Petrov, YU. X. TrN,Ei Effect of the sector angle dynamics on the oppratinn ~-,f' 9 w-r foousing accelerator having 4 rectilinear sections PERIODICALt Beferativnyy zhurnal, Fizika, no. 1, 1963, 43, abstrart. !1' (In collectiont "Elektron. uskaritell". Tomsk, TomskI5, iin-t., 1961, 149 - 151) TMz In a weak focusing acceleraior, having 4 rectilim--ar gaps, th- I-qp'! librium orbit distortion, due to the decrpa!-;e of the effective angles Of thl? netic sectors (quadrants) during the accelerntion process, was studied. 71- decreaae ds caused by eddy currents and rem-wwitL indUCtion (frr weaf. well as by magnet saturation. A. Fateyev (Abstracter's notet Complete tr~nslationj Card 1/1 PETROV-, Yu.K.; PESHWV, A.V.; KUZIKIN: V.N. Adjusting the radial topography df the magnetic field in cyclotrons. Izv.vys.uch,zav.; fizo no.4s2l-27 162. WIRA 15:9) Iv, 1. Nauchno-issledovatellskiy institut pri Tomskom politekhnicheskom Institute imeni S.M. Kirova. (Cyclotron) 69451 S/139/60/000/01/025/o4i E032/E414 AUTHORS. and Petrov, Yu.K, Kiri I I ov V..P., KuzImin, V.N. TITLED The Dynamics of the Effective Angle of a Sector in Accelerators with Straight Line Sections 77 PERIODICAL:Izvestiya vysshikh uchebnykh zavedeniy. Fizika. 1960, Nr 1, pp 139-144 (USSR) ABSTRACT: The design orbit in accelerators with straight line sections is usuallv in the form of a closed curve consisting of four straight line sections connerted by four circular arcs of radLUS To and subtending an angle of 90' at the centre one of the necessary conditions for the actual orbit to coincide with the design orbit is that the magnetic field should be zero over the straight line sections and uniform over the other sections, However. owing to leakage, the true magnetic field always differs from the design field so that it is always necessary to introduce the concept of Card 1/3 the effective angle of a sector and this is defined by V 69451 S/139/60/000/01/025/041 9032/E4 1.11 The Dynamics of the Effective Angle of a Sector in Accelerators with Straight Line Sections Eq (1), The actual distribution of the field is normally of the form indicated by Fig 1, The effective angles of sectors will decrease at low fields owing to eddy currents and residual induction. Thev will also decrease at high fields owing to saturation effects. This will lead to the appearance of a well-defined fourth harmonic of the distortion of the design orbit. and to a reduction in the maximum energy of the accelerated particles In the case of xnductive acceleration the betatron ratio is also affected All these effects have been investigated by the present authors using a plane model The effects have been found to be small towards the end of the acceleration cycle, They have the biggest effect at the b(~glnning of the cycle. In the latter case the amplitude of the fourth harmonic of the design orbit becomes comparable with the radial dimension of the working region and the Card 2/3 change in the betatron ratio may be of the order of a few 6~ 69451' S/139/60/000/01/025/o4i E032/E4i4 The Dynamics of the Effective Angle of a Sector in Accelerators with Straight Line Sections tenths of a percent- The reduction in the sector angle may be compensated at the beginning of the acceleration cycle by increasing the injection energy The field at sector edges may be corrected by d-c- current methods There are 5 figures and 2 references- I of which is Soviet and I English ASSOCIATIMN11 pri Tomskom politekhnicheskorn institute imeni S,M,Kirova fScientific Research Institute of the Tomsk Polvtechnical Institute imeni S.M.Kiro%,) SUBMITTED~l April 3., 1959 Card 3/3 o/62/oOo/ool/oli i E 19-2/ E3 8 2 luz'min, V.N. and Petrov. Yu.-' TITLE: Equipment for neasuring the meridian plane oi the magnetic field in an accelerator ~,-,IODICAL: Pribory -1 teklinika eksperimenta, no. 1, 17-, :-A. .1easuremien'L of the meridian pizine is base(! on thf, meLhod ot- a permalloy )robe kRef. 1 - J.';-;. KC11V instrum. , 1051, .2 5 6 G. Dianbrini-xlalzizzi ,~uovo cimento, 1956, .-)--)6 %..,here the signaL due to t he tr:~nsition of' the probe through the zero value of' the maglit--ic field is detected by an electronic circuit (!icf. -) - Yu.'N. ',iolLal'nikov, G.:-i. 5ozin and L.V. Yeremin - -'T7, 1,)5,'-,,, 111). -!1. The i-)robe is situated in the anerture of the tube of the equipment in such a way that tiie axis of t.i(- pert:ialloy core coincides with the axis of the tube. The tube can be rotaLed b", 1600 aroun(.~ its axis and can be fixed in to opposite poslt.1011~1-1. Tne axis of rotation of ti)e tube is made iiorizontal and the tube can be displaced vertically within the air gap of' the ellectro- m a gn e t .Tiie vertical position of the tube, i.e. the coordinate Card 1/3 Equipment for measuring .... L19'-'/E362 of' its meridi.An. T)lane, is determined by liydrof~',ZiLiC lovol-ijii,- with an acctiracy of ci-ii. The instrut-tiont can be c.-irr~(.,d one neisuring position to ;,noLher, togetner with its tl-LTIO'I. -ny i;ipasurement carried out by the instrument is a ros:lit 0' 3veragin,-- the readin'-s taken in two oppos-Lte o; tht, Li:he, ~-;o that Lh(- ea-or due to zhe presence of the vcrtic.~,I projection of' the angle between the axis of ttie c 0:, 0 and the axis of roL.-tLlol) ()f.t1lo tUhO _Ls elitilirinted. I,ho I11-~ ( 1"I: monL C,11) be 11S ed W11011 a--;S embling the ei cc troimign eL o I' im auC o I -I ator ani in t his cas e i t is nec essary to. produc c ) coiis L~;nt f i.c--~ III L,Ie gap of' the e1 cc tromavnet -Tne instrument was used to measure the i,-icridian v)lane in a field having a stronvLli (,i' 20o or and ti,.(, curvature of tiie field lines of' 1.2 x 10--) /cIll. IIlie mcas~,,rements were carrieu out while changing tlj(~ djr(ICti,-)II Ot' Lll,~ -,isured -'F'ield and four roadings were taken at each point. Card 2/3 S/1 20/62/000/001/ oil II /c,6i ~~,.iuipmcn-L l'or nicasuring . . . . E192/E382 The c-rror of' the measurement s was + 0. 5 mm. Tliere is 1 figure. ASSOCIATION: \',luciiiic)-issledov;itei'siiv in-stitut vaclernoy FiZiki,- elel,:Lronilizi i avtoriatiki pri Tomskolll politelrhnichesh.om institute' k':cientific itesearch Institute of Nuclear Pilv-sics, Electronics and Automatics of Tomsk Polytechnical Institute) a U 1j', :.,ay 6 , 1961 Card 5/3 S/139/62/00o/oo4/002/018 E 2/E 5 l4 03 ALIT11ORS Yit.K. , Pothov, A.V, tind Ktiv.'m1ii, V.N. TITLEt Correction of the radinl topegrnphy of the iiingitritit. field in cyclic accelerators PERIODICAL: Izve8tiya vysshikh uchebnykh zavedeniy, Fizilta, no.11, 1962, 21-27 TEXT: The aim of this wor1c was to investigate wheti-ier it would be possible to correct the radial variation in the na~,netac field by placing current-carrying conductors directly on the ;)oLe faces. Detailed experimental studies have shown that if the distance between the turns of the pole-face coils is made variable and the current through the coils is made'to increase linearly at given radial distances, then it is possible (a) to incren.--,V the intensity of the focusing magnetic field by about 20% (typically from 9-10 kOe to 12-13 kOe) and (b) to correct the nonlinear saturation effects. In the particular case investi,~,JT.ed it was desired to produce a design field of the form n r (x) 0 Card 1/2 [To + X1 Correction of the radinl ... S/139/62/ooo/oo4/002/011; E032/E5i4 with 0-57