SCIENTIFIC ABSTRACT PRIKHODTSEVA, V.P. - PRIKHOTKO, A.F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001343020009-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

24(5),24(7)
AUTHORS: Dzhelepov, B. S., Prikhodtseva, V. P., SOV/48-23-7-7/31
Khollnov, Yu. V.
TITLE: The y-Emission of Cs134 (1-izluoheniye C0134)
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1959,
Vol 23, Nr 7, pp 826-827 (USSR)
ABSTRACT: The object of the measurements carried out by a magnetic
spectrometer was the determination of the relative 14tensity
of the y-lines. The measurement results are shown in two dia-
grams, the half-width of the lines in the range of 1 Mev is
indicated with 3.3 %, and the intensities of the lines are
compared. The half-width of the lipos could be reduced by a
better focusing to 1.6 %. The resuits o'f1iiis investigation,
the energy andihe relative intensity of the y-lines of Cs134
are finally compiled. The authors thank V. A. Yeliseyev and
A. Ushakovalbr the execution of the measurements, and
N. N. Zhukovskiy for making possible the measurements by the
elotron. There are I figure, 1 table, and 11 references, 4 of
which are Soviet.
Card 1/2

The y-Emission of Cs134
SOV/48-23-7-7/31
ASSOCIATION: Radiyevyy itatitut imeni V. 0. Xhlopina Akademii nauk 83SR
(Radium Institute imeni V. G. Khlopin of the Academy of
Sciences, USSR)
Card 2/2

,Won g GrLg= -yw. To. P.. Dshgl.po,. 3. S.. Z.Iotev,jo. A. V.,
liable, T. To., Prikhodlwvx, V. P.. thol-nov. To. V.,
shchaki., G. To.
IMSt Radiation ?"a AsT4 (Islu.h.nire A.74)
MlaDIcALg Is ... %tya A"4..ii -k 555R, 5.riy. ftsichoskaye, 1956.
Tol. 22. Ir T, pp. 831-8 3a (USSR)
ABSTRACT: In December 1957 t4 authors obtained a radlochealcaIly pura
P"Watim Or As ~-4 C.) with a t.04 specific
Th. characteristic features of this docay were examined and
prolls*ly do trot the prod"tion of the rrvparstto~
'
ta
h
d
I
"a produced 707 a bombsrdwaat of car-
;7
blu
A
is doo.ribed
T
vantum with deuterons wit4 " vc.Egr of 10,8 N.V. --- re.ult.
of the investigation of A - and 0 -a; !ctra are sz7%ia*4. It
1
4 1. of an 2 -%Irq.
is Proved that the ground state of &.

After the C.,C -,', ~' Qtra nad been xubt,racted the
-bypss.- .- ' 0
b:th spectra ~ovod
a
Curie diagrasim far thC"n"t0 ;f
,
so iac*
to be rac tilt In the ck-ground ah
.
at.
K- and (L-U) . ver.ion-lines of the i-ren Pitions of 596 and
:
Cart 1/4 635 bet -w clearly worked. Th, X-635 Lin. is. wittaut doubt,

treAdItim- 2*
of the 0". with Ihs
_6 k.v

Munitions which 1,7 cOfto
acted with too positron brwach. cor-
d
Ilion* Oro nor- cOmplic.t.d, as the Froportion of in% K_csp_
'
at be known In order to be able to d.l.raiz. 'I; Iso
' 'he d
t
i
T

.
.rm
he a
rum
n.jjon :fim,.~. given.
of Sh~;
rodlalloa of #8 we stl
at.d b
sense of th
g
y
o
el
recall *Otr0n#. Tha rl='. intensity of Shro.
"a Iti led with.quipa.nt' Of . better rv..tut-oa:
Theh11. ILA., hO - 566- old the 635 key its..
with the,of Ma 4Q-APMoaftt of a lower resolution. but
of a I=ImOQ- Intensity seeplIfied by Szo hundredfoll , it v~x
mAten t"d to find harder V-Iin.o in the radiallo. of 42
:
The d
cay energy In the transautation from As.- Z.
T
4
gives rt Ito the as suap%ioa that %he levels of I-
cited 09 to those of 2500 k.T. AotmutIly in the -Pwalx~l race.
of 1200 MV a pron~ncod ..pszol"atma of the couz%xing mt.
above the q.iot background Ouno~t*d with %be softer Ila..
me observol. Th. intensity of this lima to smaller *y a
fact dr, of flO
than that or %be to sh.-
t
thetin Go he second 1".X or zol"llon probabIX be& an
energy of 1200 k.T. If Shim 1. true. is should be
Cart 2/4 that a transition from ths, second level to the fL,,% Lmo ~f
!.410lon Frow Am74 SOY/48-22-7.1%/26
.bout 600 W estate and that this level form. - dou*'.t tth
th
n 596 keY Lin*. Th*.r"1fltmtI:a1A two decay schme at
As 4 mre~ investigated In the Istch.;t.r am* remarks -.-
coming theti Ividual levols am given. &A regarAl t~. 4o.
wwgl.m of h:4 transition at As - 5960 key of Go? I% to
shown that Ln this transition the ratta to qt - a
to the Leve tlgattoni of the ratjo K/A im, the A-3161o,"
to jh~ level at 5~6#3 key of CA 4 is to shown that -no ratlo
Jr/O for this transitio 'us 1:'
" " a*-'; :I .% 12W. key
:.f,r_,4 j: ptobably a ..... .Met . I., yjth the ~s,-
or'1 2. Th. do-;nd :..it:42j-:-I of 31. Y"b.%Iy
ceiar 1300 k.1 and Is .th '" .
s. x .r..y.., 1. p. 3.11nov, Va. To. To. N. xb.,,a, wed
Wheir Imems lollaborated In the work. 7h*" are 5 fir-,
5 tables. end 15 refer .... a. 5 of which are Soviet.
card 5/4

21(7) SOV/48-23-2-7/2o
AUTHORS: Dzhelepov, B. S., Prikhodtseva, V. P., Khollnov,.Yu. V.
TITLE: y-Spectrum of J131 (y-Spektr J 131)
PERXODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1959,
Vol 23, Hr-2, p 206 (ussr-,)
ABSTRACT: The authors investigated the y-spectrum of J131 within the
range of 200-800 kev, determined the intensities of well known
y-lines and the y-line with 514 kev, of which mention is made
in paper (Ref 2). The results of these investigations are con-
tained in a figure. For the intensities of y-lines the follow-
ing values were obtained:
E kev; 278 362 514 633-5 722
I % 5-7 100 < 0-4 8.9 1.9
In addition, a special investigation has shown that the intensi-
ty of the y-line with 514 kev never exceeds 0.4% of the intensi-
ty of the I-line with 362 kev. The atf-thors thank V. A. Yeliseyev
for help in the measurements. There are 11 fiVres and 2
references, 1 of which is Soviet.
Card 1/2

y-Spectrum of J131
SOV/48-23-2-7/2o
ASSOCIATION: Radiyevyy institut im. V. G. Khlopina. Akademii nauk SSSR
(Radium Institute imeni V. G. Khlopin of the Academy of
Sciences, USSR)
Card 2/2

21M SOV/48-23-2-8/20
AUTHORS: Dzhelepov, B. S., Yeliseyev, V. A., Prikhodtseva, V. F.,
Khollnov, Yu. V.
TITLE: y-Radiation of Br 82 (y-Izlucheniye Br 82
PERIODICAL; Izvestiya Akademii nauk SSSR. Seriya fizicheakaya, 1959,
Vol 23, Nr 2, pp 207-210 (USSR)
ABSTRACT: The 7-spectrum was stu"d by means of the "Rytron" spectrometer.
It is given in figure 1. 10 lines were detected. The energies
and relative intensities obtained in this and another paper
are listed in a table for comparison. The best accordance re-
sulted from reference 8, bothfor energies and intensities.
Within the range 1700-2000kev aweskline at 1780 kev and only
one elevation of a point above the background at 1910 kev
were found. Within the range 2000-2700 kev no lines with an
intensity above 0.2% were fouUd. The conversion coefficient
of the main transitions in Br t$Z was determined by means of the
intensities obtained. The initial value of a for the transi-
82 K
tion type E2 of trannition 777 kev in JKr was adopted from
tables published by Sliv and Band Ref 13) with an amount
of 8.22.lo-4. A decay scheme of Br8 b Kr82 is given in
Card 1/2 figure 2. The transition types of the individual transitions

y-Radiation of Br 82
SOV48-23-2-8/2o
of Kr 82 were determined according to a comparison of the
theoretical 0k values with,the experimental ones (Table 2).
The lines 1648 and 1780 kev detected for the first time as
levels are not given in the decay scheme. There are 2 figures,
2 tables, and 13 references, 3 of which are Soviet.
ASSOCIATION: Radiyevyy institut im. V. G. Xhlopina Akademii nauk SSSR
(Radium Institute imeni V. G. Khlopin of the Academy of
Sciences, USSR)
Card 2/2

GRIGORIYEV, Ye.P.; DZRELEPOV, B.S.; ZOLOTAVIN, A.V.; MISHIN, V.Ya.;
-PRIKMDTSEVA, V.P.; KHOL1110Y, Yu.V.; SHCHUXIN, G.Ye.
................................................ :_
Study of As74. Izv. All S.S.S.R. Ser. fiz. 22 no-7:831-838 JI 158-
(MIRA 11:9)
(Arsenic--Decay)

11 f ,
21 ~7) QV/ ro- 121 - '-!1 /4
AUTHORS: DzheleDov, 33. S. , Corresponding Member, Acade.--y of Scie-
USSR, Prikhodtaeva$ V.._P., Khollnov, Yu. V.
140 (0+ + 0+-perekhod v C014o)
TITLE; The 0+ + 0 -Transition in Ce
PERIODICAL: Dolclady A),.-atlomii ninik SOSR, 19511, Vol 121, Nr pp 9 9 5- 9 ') 7
(USSR)
ABSTRACT: By some authors the following problem was raised: Do the
conversion electrons X-1909 (- 1909 keV) correspond to the
transition betweer~ the excited state (1909 keV, quantum
characteristics 0 ) and the ground state (also 0 ) ? In
order to solve this proble T~' the authors carefully investi-
gated the y-spectrum. of La in the energy region of
-1900 keV. Lanthanum oxide irradiated by thermal neutrons
was used as a source. The original activity of the preparation
was 2,6 Cu. The results of' the measurements are given in a
diagram. No 7-line is observed in the energy region 1H0-2000
keV. The intenaity of the- ~_rays -1900 keV (if t'hey exist
at all) is less than 4.10 quanta per disintegration. These
Card 1/3 data (together with the data of two previous papers (Refs 1, 2)

The 0 + 4 0 +-Transition in Ce140 SOV/2o-121-6--ii/45
concerning the intensity of the con~version 1* 1r,09 kev"
~ne , j
anable us to conclude that there is a 0 *r + 0,r -tran-ai 4" ion.
In order to confirm the eXi3tence of the line K-1909, arid
for a more accurate determination of ita in~enaity, the
authors investigated the h~~d part of the spectrum of the
conversion electrons of La 0 by means of 2 sliectrometers
of the ketron type. These spectrometers were placed at the
authors' disposal by A. A. Bashilov, Leningradskiy univer-
sitet(Leningrad University) and K. Ya. Gromov ' 0iyevfy
institut AH SSSR (Radium Institute AS USSR). La"d was tined
as a source in both of these cases. Accordine to tiie results
given in a diaerara, the existence of the lines K- and L--.I',)09
is beyond any doubt. The transition has the average ener~ry
1902 keV, arid the ratio of the intensities K 1902 /K 1596 ~_2
equal to 0,220,(i.e. the averaCe value of all the v.,eaaux,.ien%
series). Por the lower limit of the conversion coefficient
of the transition 1902 keV the value 'K-1902 ~' 0)38 was
found.
This leads to the conclusion that the transition wizh the
ejerf n " 140 is the hither'.o unknown trani_iDion
,7,,1902 keV i Ce
0 - 0 . Besides, the authors sought antl found t1he K- and
Card 2112, L-conversion lines which correspond to the 7-lineo 2.-1"43 ~Jrd

The 0+ -* 0+_ Transition in Ce 140 SOV/'2o-121-6-11/145
2390 keV and to the y-line 2515 keV. A table --_-',ves the ex-
perimental and the theoretical conversion coeificients on the
X-shell for the transitions discussed in this paper. The
authors thank A. A. Bashilov and K. Ya. Gromov (who made
it possible to carry out the control experiments by means
of their spectrometers), 11. 'D. !Tovosilltseva for the chemi-
cal separation of La140 from a barium solution, and also A. G.
Dmitriyev and Yu. A. Gurlyan for their help in carrying out
measurements. There are 3 figures, I table,and 6 references,
5 of which are Soviet.
ASSOCIATION: Radiyevyy institut im. V. G. Khlopina Akademii nauk SSSR
(Radium Institute imeni V. G. Khlopin)AS USSR)
SUBMITTED: June 30, 1958
Card 3/3

Y11. V.1
o~ 0 4- Transition in CeL4.0.1. 'iuclear Physics, vol. nP." '49
(."4'0. Pollani P,,ful. Co., --"---.sterJan)
Radilmn Inst, i,,Yi V.G. Flilopin, Acad. "'Ici. U33R, Leningrad.
A search has been made for garuna-gitanta of enerEy.--IO(DO kel in t'Le spectriurt
of La'" by ne--n3 of a rarima-spec trome ter by analysis of recoil electrons. it is
shown that is such exist, their intensity is < 0.1~y 10--3 (Tuantum per dis.-LnteEra~ion.
It is simultaneously confirmed that the spectrum of conversion electrons contains
intense conversion lines correapondi-ing, to a transition energy of 1902 keV.
The lower limit of the conversion coefficient of this transition proved equal
to 0.38. Such a large valne olF* t~,is li~7-it indicated that it is either a transition of
high multipole order (7- 7 l0),or.aOr--'-P- O~transition in vkdich gamma quanta of the
,iven energy are entirel~v absent. The first assiL-Ttion may bo discar,lcd S4nce in this
case the lifetime of the 1900 keV state shoiild be very great ( :;;,101" years), """'ereas
the intensity of the corresponding conversion line falls off Aith a ~Iajf I ife of 5.-M~ 140
ho-ars. ',-Ie are thus dealinr here idtli a new G+ -" 0-- transition.
The paper also disrlisses, Ithe characteristics of soveral. othpr transitions io Ce

'PRIKEODIKO), V.S., kand.med.nauk
Clinical and biochemical changes in chronic tonsillitis in children.
Sov.med. 25 no.5:99-104 W 162. (MIRA 15:8)
1. Iz kafedry detskikh boleznvy lechebnogo i sanitarno-gigiyeni-
cheskogo fakulltetov (zav. - prof. G.I.Tets) Kharlkovskpgo
meditsinskogo instituta (dir. - dotsent B.A.Zadorozbnyy) na baze
detskoy dorozhnoy bollnitys (nachallnik A.G.Kovalenko).
(TONSILS-DISEASES)

18-7400 65695
SOV/136-j9-10-12/18
AUTHORS: Karasevich, V.I. and Prikhod'ko, V.Ye.
TITLE: New Developments in the Production of Aluminized Iron
PERIODICAL: Tsvetnyye metally, 1959, Nr 10, pp 68-75 (USSR)
ABSTRACT: A method of producing Al-Fe-Al bimetal sheet, suitable
for the manufacture of kitchen utensils, was developed by
the staff of VAMI about 25 years ago (Ref 1 to 4).
Following the development of other, easier to produce,
bimetal materials and owing to the continued increase in
the output of alum�nium sheett the Al-Fe-Al bimetal found
little application. Interest in this material has been
revived recently in connection with the possibility of
using it as a substitute for nickel in the manufacture
of some components of electron tubes used in the wireless
industry. At temperatures above 6000C, the surface of
the anode made of aluminized iron, darkens as a result of
the formation of the intermetallic compound FeA13; this
makes it possible to eliminate the cumbersome operation
of blackening (carbonizing) the bright nickel surface,
which at present has to be carried out at all the plants
Card 1/10 manufacturing electron tubes. By replacing nickel with

65695
sov/136-59-IC-12/18
New Developments in the Production of Aluminized Iron
aluminized steel, a large quantity of nickel strip would
become available-for other applications, the performance
of the electron tubes would be improved and their
manufacture simplified. It was for this reason that work
on the production of aluminized steel by the method
developed by the Giprtsvetmetobrabotka lnstitute, was
resumed about ten ),ears ago. Armco- A iron (< O.u25'/Q' C)
sheet, 6 mm thick, was used as the starting material,
with aluminium AO (GOST 3549-57), 0.5 min thick, used for
cladding. The process employed was quite complex,
required a large proportion of manual labour and
comprised the following operations: cutting the iron
sheet into.strips 120 mm wide; normalizing the strips at
850 to 900 C; pickling in a solution containing
10% H2SO4 and 3% HN03; cleaning the strip with steel wire
brushing; rolling the strip to 5 mm; degreasing it with
aviation benzene; cleaning the iron strips (5 x 120 mm)
and aluminium strips (0-5 X 130 mm) with steel wire brushes;
cladding both sides of the iron strip with aluminium;
heating the clad material at 450 to 500*C for 1.5 hr;
Card 2/10 hot-rolling the bimetal strip 6 mm thick to 1.5 nun,

65695
sov/1-16-5 9- 1j- 12/18
New Developments in the Production of Aluminized Iron
according to the following rolling schedule:
6---.~,4.8--+3.8--+3.0-+2.5--7#2.1-+1.7--01.5 mm (kerosene being
used as the lubricant); cutting the strip in 3G0 nuT,
lengths; annealing at 45Q*C for 2 hr; cold-rolling from
1.5 to 0.8 mm, using two passes with 15% reduction and
two passes with 10% redttction; annealing for 2 hr at
450 C; cold-rolling from 0.8 to 0.4 mm in two passes
(15 and 101' reduction); annealing for 2 hr at 450*C;
10
rolling from 0.4 to 0.2 mm; annealing at 450*C for 2 hr;
rolling from 0.2 to 0.1 mm; slitting the sheets to the
required width. The finished product, constituting a
bimetal strip 90 to 100 mm wide and 0.1 mm thick, was
comparatively hard and the attempts to soften it by
subsequent heat treatment were not successful. Various
annealing temperatures and times were tried in order to
produce soft material free from dark stains (indicating
the formation of the intermetallic compound FeA13) but to
no avail. In order to simplify the manufacturing technique
and to minimize the harmful effects of diffusion of iron
into aluminium during annealing, the process outlined above
Card 3/10 was modified in the following manner: the steel slieet was

6569"
SOV/136-59-101-12/18
New Developments in the Production uf Aluminized Iron
first rolled to 1.8 rwri thickness, i1ormaiized, 17ickled,
brush-cleaned and then clad on both sides with aluminium
strip 0.2 min thick. The subsequent hot-rolling
operation was carried out at 180 to 2000C since, at this
temperature, no diffusion could take place. However,
the product obtained by this modified method (whose
complete schedule is reproduced in Fig 1) was still
unsatisfactory, so to slow down the rate of diffusion of
iron and to prevent the formation of the intermetallic
alloy FeAl an aluminium-base alloy containing 1.0 to
1.3% Si anl'0-5% Fe (Ref 5), was used for cladding instead
of pure aluminium. With this cladding material, dark
stains appeared on the finished product only if the
intermediate annealing operations were carried out above
540*C; bimetal that had not been heated above this
temperature was stain-free and characterized by
comparatively high ductility, the depth of the cup formed
on the Erichsen test piece being 4 to 5 mm, ie within the
specification limits set by the users. These firidings
were substantiated by the results of an investigation
Card 4/10 carried out by A.P.Smiryagin and O.S.Kvurt (Ref 9)

65695
SOV/136-5 9-1()-12/18
New Developments in the Production of Aluminized Iron
reproduced in Fig 2, where the thickness (mill) of the
intermetallic alloy layer formed at the Fe-Al interface
during annealing at 5500C for 1. 3, 6, 12 and 24 hr is
plotted against the silicon content (wt-~4) in the
aluminium alloy. It will be seen that even after 24 hr
anneal at 550*C, no intermetallic alloy layer was formed
when the silicon content in aluminium was within the
0.5 to 1.0% range; the intermetallic layer was formed
when the silicon content was less than 0.5 or more than
1.0%. When the annealing temperature was raised to 6oooc,
the formation of the intermetallic layer took place
irrespective of the silicon content; at this temperature
the diffusion rate rapidly increased, owing to the
presence of the a + P eutectic (melting point - 5770C).
Originally, the improved bimetal strip was produced in
lengths not excrieding 2 m, which were not convenient for
use on automatic presses or punching machines. This
necessitated further development work, as a result of which
the following technique was found to be most suitable for
production of the bimetal strip of the required lengths:
Card 5/10 cladding the iron sheet (6 x 1300 x 1300 nun) with silicon--

65695
SOV/136-59-lC-12/18
New Developments in the Production of Aluminized Iron
bearing aluminium 0.7 Mm thick; hot-rolling (2000C)
the clad strip according to the following schedule:
7.4-Y5.3-04.4-*3.0 mm; cold-rolling: 3--V2.6-42-3-Vl-8->
1.5-01. 1-*o. 85-?0.72-,00.7--0,0.35--v-0.2--70-17-*J- 15 ---0'0. 12 -;P
0.10 mm, with intermediate annealings (2 hr at 400 to
4500C) at the 0.7, 0.2 and 0.15 mm stages. Although
strip in coils 20 to 70 m long could be produced in this
manner, the process was still uneconomic, mainly owing to
the low output of the rolling mills. Application of
heavier rolls made it possible to reduce the number of
passes and to increase the productivity to 12 machine-
hours per 1 t of the finished product. Mlarked improvemen
was achieved only after the problem of cold welding of
aluminium to steel had been solved and when steel and
aluminium strip was used as the starting material instead
of single sheets. Before the introduction of cold welding
sticking of aluminium to the rolls occurred frequently
when insufficient quantity of lubricant was used or when
it was attempted to use heavier drafts; when cold welding
(carried out by deformation of 450/6 or more) was embodied
Card 6/10 in the process, this effect was eliminated. In its final

65695
SOV/136-59-lo-12/18
New Developments In the Production of Aluminized Iron
form, the process comprised the following operations:
(1) slitting the steel (armco-OM containing less than
0.05% C or steel 08KPOM with 0.05 to 0.12% C) strip
(2 mm thick, 220 nun wide, 500 kg coil) into two parts
(110 + 110 mm, 110 + 90 mm, 100 + 100 mm); (2) cleaning
the strip surface with steel wire brushes; (3) cladding
with 0.2 mm thick, Si-bearing aluminium strip (20 mm wider
than the steel strip) and rolling (in one pass) from
2.4 to 1.1 mm; (4) cold-rolling according to the
schedule reproduced in Table 1 under the following heading
thickness (mm), initial and final; reduction (absolutelmm
reduction (relative %) per pass and total; (spindle oil
mark f'211 or 11311 was used as the lubricant); (5) slitting
the strip into the required width; (6) annealing the
strip in a continuous annealing furnace (dimensions of the
muffle: 3300 mm long, 440 mm wide, 180 mm high); the
annealing conditions are given in Table 2 under the
following headings: thickness (mm) of the strip; rate of
passing through the furnace (m/min); muffle temperature,",
Although the material obtained by this method was quite
Card 7/10 satistactory (the depth of impression formed in the

65695
SOV/136-59-10-12/18
New Developments in the Production of Aluminized Iron
Erichsen test being 5 to 7 mm) and although no dark
stains were formed, the formation of a thin FeAl 3 layer
at the iron-aluminium interface during annealing was
unavoidable. -metallographic examination revealed good
quality of the bond between iron and aluminium alloy
but the clad aluminium layer sometimes showed a tendency
to break away from the iron base during the deep drawing
operations. This effect was obviously caused by the
presence of a brittle FeAl layer; the relationship
between the thickness of tLs layer (mm) and the
annealing time (min) at 600*C, for iron clad with 0.5 and
1.0% Si-Al alloys, is illustrated in Fig 3; (Abstractor's
note:- the units of time used in Fig 3 and Table 3 for the
batch annealing are obviously wrong: the former should be
see and the latter hr) photographs, reproduced in Fig 4,
show the microstructure of the aluminium clad iron strip
(a) 0.10 mm and (b) 0.15 mm thick, annealed by passing
through the furnace at 600 and 650*C respectively. To
avoid the formation of the brittle FeAl layer, continuous
annealing was replaced by annealing at lower temperatures
Card 8/10 and for longer times in a batch furnace with forced air

65695
sov/136-59-10-12/18
New Developments in the Production of Aluminized Iron
circulation. The comparative results obtained by the
two annealing methods are given in Table 3 (continuous
annealing - top, batch annealing - bottom) under the'
following headings: nominal thickness of the strip, mm;
thickness of the clad layer before annealing (mm and %);
annealing temperature (OC) and -time (sec); (see Abstractor's
note above) the thickness (mm) of (a) chemical compound,
(b) silicon-aluminium compound and (c) average total
thickness (mm and It will be seen that no FeA13 layer
was formed in the batch-annealed material. The improvement
of ductility attained by changing over to batch annealing
is illustrated by data given in Table 4 under the following
headings: thickness of the bimetal strip, mm; depth (mm)
of the depression on the Erichsen test piece (a) specified
in TU 1053-54 (not less than), (b) actual, after
continuous annealing and (c) actual, after batch annealing.
(A satisfactory way of batch annealing the 0.10 mm thick
bimetal strip has riot yet been found.) Several
conclusions were reached: (1) 20-Fold increase of the
Card 9/10 treated material has been attained by the introduction of

New Developments in the It"'r(Am t, j ot, ,1
tile
brittle FeA13 laycr i-s CrYi-114"~1 il,
content in steel , i ts fornv-O- i~--v iio,
both low (O.fj35o) anil hi di :~o,
3 ) Th e f 0 Z- IT! -1 1. ()11 0t Ile I,* A i
by t h e a pp-L i ca t t on f "i! i S
claddi.ng atict by bLit cn irmv~x I
There az it f 3 --ti r-
ASSOCIATION:Leningradskiv za ,- a tpo r
(Leningrad I la-lt- fr
Ti
Card 1C.110

LEVIN, Mark Mironovich, prof.; Z&DOROZIINYY., B.Ae. dotsent, red.;
BELOUSOVI V.A., prof., red.; BONARIUS, N.N... prof-., red.;
VOROBIYEV, F.P.P assistentY red.; GRISHCHENKO, I.I., prof.,, red.;
DERKACH, V.S., prof., red.; KORSUNI, A.Ya., dotsent, red.;
KOSHKIN, M.L.9 prof,, red,; KUDINTSEV, V.I., dotsent, red.;
PIKIN, K.I., prof.', red.; PRIKHODIXOVA, Ye.l., prof., red.;
POPOV$ I.D., dotsent, red.; SOLOVIYFV,,M.N., prof., red.;
SHTEYNBERG., S.Ya., prof., red.; KHARCHENKO, N.S., prof., red.
(Repeated swgery in stomach diseases following operations]
Fovtornye operatsii pri zabolevaniiakh operirovannogo zheludka.
Khartkov, Izd-vo Kharikovskogo gos.unir., 1961. 177 P.
(Kharkov. Madychayi institut. Trudy, vol.58). (MIRA 16:2)
(STOMACB--S URGERY)

PUTILIN, N.I., prof.,vtv-red.; ALEKSENTSEVA, E.S., prof., red.;
MAKARCHENKO, A.F.J, akademikf red.; prof.,
red.; SKLYAROV, Ya.P., prof., red.; TORSKAYA, I.V0, kand. biol.
nauk, red.; FELIDMAN, A.B., prof., red.; FILIPPOVt,.A.G., kand.
bkl. nauk, red.; FUGOLI, O.M., prof., red.; YANKOVSKIYA, Z.B.,
red. izd-ia; MATVEYCHUK, A.A., tekhn. red.
(Selected works]Izbrannye trudy. Kiev, Izd-vo Akad. nauk USSR,
1962. 454 p. (MIRA 16:3)
1. Akademiya nauk Ukr. SSSR (for Makarchenko).
(PHYSIOLOGY)

TOUIACREVI V.N.; PRIKHOLIKO, L.S.
Spectrophotometric determination of chromiu2 in the form of chrcedc
ions in high-chromium steels. Izv.vys.ucheb.zav.; khim.i khim.tekh.
3 no.6:985-98? 160. (MBIA 14:4)
1. KharIkovskiy gosudarstvennyy gosudarstvennyy universitet imeni
A.M.Gortkogo., kafedra tekhnicheskoy khi7nii.
(Chromium-Analysis) (Chromium steel)

USSR/Cu_Ltivated Plants - Co=ercial. 0ii-Bearing. Sugar-Bearing. M
Abs Jour Ref Zhur Biol., No '_% 1958, 02464
Author PrikholIko, M.
Inst All-Union Scientific Research Institute of Tobacco
Title Effect of Bacterial Fertilizers on the Yield of Tobacco
Seedlings.
Orig Pub '193rul. nauchno-teklin. inform. Vses. n.--i. in-t tabaka i
maldiorki, 1957, 3, 39-42
Abstract The effect of azotobacterin and phosphorobacterin on the
acceleration of the forced MtOring of tobacco seedlings
was studied. F'-periments, repeated twice, were cond-.cted
at the All-Union Sciosi-~ific Research Irstit-ote of Tobacco
and Rcstic To-oscco M-Akhorka (Nicotiana rl'.stica) in the
city of Krasnodar in 1955-1956 on the tobacco variety
Ostrolist 2747 on the hothouse plots of 2 square meters.
Card 1/3
- 102 -

USSR/C-Itivated Plants - Commercial. 0-41-Bearing. Sugar -Beariar:,-. M
Abs Jour Ref 711-ur Biol,, No _;.8, 1958, 32464
Ba!~te-_-.!-.* fe;.tilizeis were applied d-ring the crosslet
stable of the seedlings (azotobactei-in was applied at
the rate of one hechai-e 'Lot to 60 uqi,,nre meters of the
hotho.se area, and phoaphorobacteriti la the amoont of
50 cubic centimeters of liquid or 5 grams of dry prepa-
ration on the same area). According to the data of mi-
croscopic analyses, the mediom of the tobacco seedbed
was favorable for the developmeat of azo-tobacter. This
was confix-inecl by Uie appoarance of an cnC;roken film of
azotobacter on p1ot3 which received azotobacterin. In
addition to the local or apontaneous azotobacter, the
applied azotobacter also developed weli in them and its
amo.nt increased rpon application of phosphorabacterin,
Mineral fertilizers inteasified the development of azo-
tobacter. Bacteria.~ fertilizers did not increase the
ag3re-Sate crop of the seedlings fit for t.-aasplanting,,
b,A t"Ley accelerated their matitring (especially
Card 2/3

USSR/Cultivated Plants - Commercial.. Oil-Bearing. Sjuaar-Bearing. M
Abs Joar Ref Zhur Biol., N 13, 1958, 82464
phosphorobacterin) which is important in carryinC~. out
tobacco planting d,~rin.- earlier periods. Bacteria!
fertil*_47.#,rs died, nc.' show any s~l.bstantial effect on the
hF-dgit of the b,.t -they increased their weight
some~,~~itt. Therr; ve.-, a larvae a,,noiint of smal). 1,,mps of
soil o:i the roots of the seedlings which increases their
ability to take root LIPOn transplanting. -- L.A. Lomaki-
na
Card 3/3
- 103 -

PRIKHONIKOV, 0. F.
PA 245T88
USSR/Ibteorology - Fog Nov 52-
"Causes of the Formation of Advective and Frontal.
Fogs," G. F. Prikhonikov, Cand Of Geog Sci, Kiev
State U
'14eteorol i Gidrol" No 11, pp 40, 41
Radiational cooling in the process of lowering air
temperature is important in fog formation. Concludes
that advection fog is formed between 2200 and 0900
hrs in 45% of the cases. 85% of the time frontal fogs
are formed in the evening, night, and early morning
hrs.
245T88

PRjY..j4C).ijOV, E.
Relonder for the ~dnking cutter-loader, Sov.sha.~ht. A. rio.4:29
Ap '62. (MIRA 1-5:3)
(Coal mining machinery)

.PlIKHOROVICH, Ye.F., BOGDANOVICHI N.A., KOGAN, M.S., BLOKII, G.A. and ZHITIWA, Z.N.
"USSR work on formulation ~f rubber for protection against x-rays," Khimicheskava
Fromyshle~--.nostl, No 2, pp 10,'-101, (36, 37). 0
SO: Translatinn -W-30667, 12 Jul 1954.

PE I E'i it f ~ 11 ! V , f, . ; ~JJ(W ',.A' ~ J,( I, I'- .
I , ).I I
SpecLral studies of azulpr.,e. Part. 1. (~pt. i spcktr. lp-
390,14,02 Mr 165. ('~T.,'~A i8: 5'

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lr-,,i.,;4,Allov antr:~~.-.-,cna 1 f,=,in"r.-irm.
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PAOUIS46 doe NeOPINIFIES woo 1

2106. Abawptke SpOeMm ai Pbeasoathrafte sad Spectrun 4d
AlRdW600100012VA108. 1-W.ObMN"T~oadA.FrM&oQko. Pkyx.

0o f ZWO. d.AWJWMs&,%, 1. 1. pp. 84-ft ISSL [is Esq?W
M old phomax-throne in polariged W consists of three rrgimn . the
S&SIM&M cav-t.; Consists of a few tin" cc narrow
weak is the main Spectrum: the
third. beyond UOW coto-k. consists of broad diffum bands. The sPectMM
for the light vector parallel to the (010) piano consists of bands which we

:411 a little narrower than in the ""bu of the other component. Tbew
to an narrow MW broad spech Photographs, meagurements.
intenaffia OW daft Jor these two -1 P1 in each of the three regions, with
thick and Oft crystals, arvo given mg dhomined. The spectrum ot an-
thrmemisolomMulydooKfAukdotwooq ph in poladoed light showing a
roon" rMutbilaws, The absorption bamole we so broad and num
thmSdISYSMOVINIP-111 Ovetbe impreockoos oftve very broad bands. With
PDbH=d UgK those bamda slow a diftent wWb according to the arienta-
thn of the podarisatim. The spectrum ol gameous anthracene is very
sindar to that of tow-Cryoul, being a Supoorpodtion of both cryvbvinc
spectou the bNed good the marrow. Results am discu3ned in reUtion to
crystalline Structure. M. B.
A I L A ORTALLOSISICAL L"11*101 CLASUPKAIMS
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. Thevril. Phys. (U. S. S. 671-81(IM).-Trans.
00 it. Parent Crystals of O-N and O-A mists. wete used; -00
their abomptiott spectra were photographed at liquid-14
W
h -00

V imp. w
t
e results limi in 12 tablet and graphs. The

0 iqwctm of the riliml, coux-idir with %how CJ %Aid 4) -0*
00 A~* unit toughl with thow tit gametRis 0 under high pressure.
Wmwn. 70 takes placr in the cryst. as well as in the gas 0
state. and the vultm; twind from spectral data agree with -00
show obtained by extralvlaticin from the gas stair. ~4 so
1.0

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it I iiiiii wvr~- ts-d III,
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.49

Ala It A t?AttV*GK&t MI.Al"I CLAVIIFKAfIC" rA
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I T .1 1 t Ov (w a ON a. I w 41 a 3
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A- -a A- A I." -J~-
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1-00
MOM) (in English).-Ov and No 1-m solid
Osolus.listberenget)-15.7% No and G-M% 01 with atutce-
tic point at 22.6% No at 60.1'K. WhM Oj-Nj CrYstsh
fortned by very rapid cooling, and of varicols compo. . are
heated front :Y?A'K. up to the Ill. P. ($two" < 6P K.),
ad 'I"r,
nd A. Yoovnel. Ado yikochim. 1. A.
A S M - I L A WITALLUNKAL LITERATME CLASSOPKAYMp
am
qb fA 0 AV 10 11
0 0 0 0 0
v,
099400040606
0 0 0 0 0 0 0 1
'-so
the crystods fir%t txvome tufbkl. then spin alm dear and -00
fitudly mett. Below 10% (h. tile C Y" Is r-main clear
I
a .00
1h. front 15 In
,-,.
and melt at 62.5' for 0%, W.4 for I
they are clear at 20.4', berow turbid at alkx t
50~ ()g
"'
*
K. befoir writin
27 , hu spin clarify itt :11141
.
t
;.0
W for 30%. M.2' it* rj0%l-. from W to fPJ% the crystals
'
.
. but become dear at about 44
am turbid already at 20,4
,
-
*
'
for &5%. 50. 1
for
,..S% 0'. frooll OW
AM melt at 51.5 CIO 0
to 84.3% the mists. am turbid throughout the range
studied, wool It= 94.3 to woorty 100% Os the turbid inixti.
clarify at about 42* before melting at 81.3' tar M. LO 0
for 100% 0,. The absorption spectra of the turbid phaw
00
show more intense bands. spread out mom toward the .
violiet. The two transparent phases abow situilar spectra 2so*
" t that at the higher temp. the bonds are wider and
h
h
d
4
6
r
v
t
mt t
e ~Ym&
low leff atructurc. It in cowlu
I
obtained were unsiable undercoulcoill crystiobt of mqgvu
iu $-nitrogen. which disintegrate on warming abuiv;~'K.
i
f L
i
l
i
f
00
s o
n
urm crysta
n
and then on further warm
h
ng &p
0-altrullen (about 41P). The 0, Worts are shifted by 4
600
100 A. and 16 A. for the lit and 2nd series with reop-t
to those for -oxygen, atul must of them a PC%( as doull. '00
Iva. Rathingrin
boo
MCI
Is
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a
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6
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A
AL
A 0 di W d'_P 0
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-
-
-
.- L-T- 0 #
AD*-
0 0 J
uld ammonia, 1
sefid and Us
Of li
ht b
Ab
ti -00
-00
.
on
sorp
l
g
y :
00

oer M ts in the LsIble and ultrairtalst calling.
r',SWLWL"-!!, J. ExW. liseare. Phyt. (U. S. S. R.)

3"10940).-From W)O to 29W) A.. the abttwp- _00

1 -014,
ion spectrum of liquid and cryst. XH. ts~ the
'of
point is continuous. and is sirmigly shifted into the ultra.
Wit) cm
fur the
uid
1600
th
li
i
f
l _
cut.
or
e
v
.
o
ict (
,
q 106
itistive to that Ad iuitW absorption of the pa. The ab-
-90
ItArption limits for MW Now are, few.; 24W.
"V
"all
."evessaaaft Is So Whared
2W and 2316 A.
. -00
Ago*
U1
region. /Nd. 4(".-Tbe abomption spectra of liquid
Zoo
aq soLW NHe frogn YM to 10.00U A. contain coa-
are the same
0
between the
zoo
sulid pha~.
!lan 'Pectra
The doublets are ovrrtone doublets with A, TAXY1 Cln. -I ~
the ablOrPtim spectrum of the solid Is blAifird by 300
79
go o
cm.
with respect to tIuAt of the As... F. It. R.
goo
;too

I L A
ITAUU
114KAL LITINA11041 CLAIINACAIMN tie 0
-
S Ago 0
A
I
Islas,) At QMI Ogg
-
V -
-r
4JLMQMt
t
_
41till OVE QkV &it
-
U 6 AT 40
" "
T
- I F 1 5 4
; ~ ; ; j, it a it K 7
1 1. 1
i I W a a 4 3
N An I -
4
ev
,
1 101
I 0 0 6 0 0 *1
to 0 0 0 0 a 0 0 0 0 0 0 0

0 a 0 0 0 0 0 0 0 0 a 0 a 0 0 e v

10 Is Is ill 11 1, 13 1. is 11 v is is 40 41 u 43 at axe
A A -C.- IL
00 ILL' A L-L-144

-
-
-
-
-
-
-00
-
-
-
-
-
tion
i
WLd and liquid smino~l~. 1.
A
o
b
t
to
s
boap
tia
The

TO'abucoon Wctrum from UM to ZOW A. 11.
00
Absorption spectim from 10140 to 5000 A.,.A..I'tik.-
but,ko. - Aeld'elipikakin. U. R. S. S. 12. 669-64. 5(~5-
00 L(ivlo) Oll Evg1iA).-.1kc C. A. 33. 1&0. E. 1. C. of
00
00
00
00

oew 00
0011

zoo

00
1L A M.$LA OCIALLURrICAL. LITERATLARI CLASSIVICAUCIN u
30Z Ir

WN)~*
-7
IN "Is') 41t a., 'It, 4141110.1. ca a.. ill
0

U It AT NO IS

it it IN two Pi DIN INS

"

in
it it K Kw n s
ic a It It a It tr
I
:

0 0 0 g : 0 0
0 0 'O1
0
0
:
0 0 it 0 0 a 0 0 0 0 0 010 0 0 0 0 0 0 0 0 0 0 0 0 0 0

1000
our U 45
'JUL AL v IF G so At 1 0 fu 4 Tz.
It CN AT is T1
.111(t
.01I.Ndlif.13 vanil.jill 113104111, a 1. 1 f s v
0 rIW3'
&3
for
O'er
111M) 1"111121%
is
11'.1131 1 l;.-Amlailikil)
o INV I Xf 19 , wr * V'd
lj.vy!~vp
0 W. jjj"jrjjIjA Isur iiinirmilA 141111nJIM 11P
.111 **mm, mlmij~ja .11
.61111pi vil %.Hl~ will(IMMAIP .1111 - C.
mll , .111: , I 1~. Ill stills) -I, jr
llr)%A I vati I ill still jj.kii6 Ism lit li - Ist.lil I Xill 111dilifl., Ail 'Jill
I l 'A liow-to wp-I .,,Is Ill t mll Suillintp All AIP111111- t17
l~lj" -.1 " Ill % .,I.t -ml I fa 00
00- 1:; A q'immi aili J-0imp All litly %.1.11 all) 1110 Ill
I!,11. ill .,ill %,I J.,I)II. 1111111 ill :: 1 1go
-idut"A afI.L JPIA F311!1 Jilin 51111011 limpli-jr,
rjulvii ill p-,qdr* -1 1 r00
of- 00
AINITS,
2 U0q&O11qV 'At
0,, in au pMqa-
.,r4J;;.dtujj All, is stirisin )is expads 'troTAjovity ir 00
00- 00
r
-U-W XF-M -W-T-T 00
0;0 K a w Is or it K a "(Siri 11 DI A 1 7- v
0 0- o :0,0 k-
op I'm

a is 0 U a 16 is U a a a
00 A
90 0
A
00
go
00
0
*:
so
'33
'41
P1141:111,11APS AND 06tw9froff mmp
w it a 0 41 a Q 4 41
Nor, A- I,-" cf!_OFML__
Abst"CiPt" afircull'of ainaff Crystals of naph"Woras at
WK. A. Pri Wicks, /full. wad. ,,, V R..%S. .%i,.
pby,.. 9, L'I I 17l 191,N)i1j) HII-Lifs). %I F-im 1, still, lit"
i,twetnifil ..I 11414111141clic ix"llb6t, .4
tlllfttw W1111%. Ill the irgioll 110111 X1441 I.,
A. On C-4ing 1,)Wll W the ti-sill). i)1 bri'l hythogro).
the are re-1vol ifil.0 & 111111tituds: i line.. 11AMM
'I'lil Wtul, ,ilh A "trucluse. "im- .,(
Ihi-tti'"Ify 11"furahl" its roun. IMA,
Ml, It- 11141 driAll'i it( 41111% title ClIn lie 449W1`41-11 -IV 1.,
," i I.... kyrs. Ill.. ..... 13.14
sit ~111111) A. mosd toundwr almna :11 ). At W ),,, 1-ilt tit,
Ib ptiou arid the flimfe-ortice spirdrum wi,w -w-N-4 ill
114111. Mil.., tvirroilloolditle tit d....
f!'"fic frall'itioni 4-wilchir in 11"Avvioceme Awl ill Al-11,
Win; the wave numbers (in shumptiorn) of the coinciding
IMC, Are. '."5, 310M.'s, 31WI0.1. anti 3100; cm. 1.
vrolin thew liwis. the following IS pwriods td vibrAti-wal
prolucoissione comM In dot : At - IN, 210, NX), 415,
N211,71b.M.M. NO, 100). 1135, IM W5,1310. IMA),
144-:1. ISMI, .3(M em."$, )Umkg-s prWrist,hill's vigil 41.1
'"' 11crivett -6tarting from the Unit 31730 cm. -1, which there.
,,at Carl id- be cunwiticted as c4scre"ttli-tit tit a purely
clectrottic(riArmition. The corresporaidegicc o( th- Wfp^i%
to intrattiol. vibmtions is proved by their identity with
RainAtt (trquencit3 and witb istirsured frequenci" isf Bins.
..f The low wave numbers r - 2,1. 13, 67.
,%list till vm. 1, iloubth-~ prewnt in Al-isfilpsts, awl ill,
101,11V Viol& Ill P"bably lk-1.41s: I., illicifil'.1
Vib V( -WO tLtOlt N I
A Is 4 - I L A ENTALLMMAL LffgRAIWW CLAUPWAIW,
&d-
14166110 NAP 'iiv gag .11181 ~_ isg-
- 0 1 4 6 A
U I w 0 4; -ML I a ad 0 a w -I w #A 0 A
.00
"09
-00
so
go*
00*
see
400
Mae,
41010
fee
590
to 0
lee
too
Ja*

PniKH0TtX0, A. F. A 19/49T89
um/ftyslos sep/oat 48
Crystals, Organic
Crystals - Oscillations
"Blectronic and Oscillatory Ievele of Raph-
thalene Crystals and Molecules," A. F.
Prikhottko, Phys Inst, Acad Sci Ukrainian SSR..
4 3A PP
"Iz Ak Nauk RASR, Ser Piz" Vol Wo
Treat subject under vapor spectrum, oI"eifica-
tion of spectrum lines of a crysU~L, *and A-
lines and B-zones. Special diagram shows re-
sults.
4&'
7xqAqr8q

0090000*0*0 see
7.0 T - em- ~ "-~n -.1
I A I 1 9 to It 11 1) u Is 96 It
14-1111-k-I-IJAJ
I'll -A"t, rqj~!".vw
go.
Ar
it
u
111 Is All P J) it a it x is m A. Q u zJR
OKI 00
-00
Dispersion a( Anthiacene crystals in the visitile page at
the SPOWUM- 1, V. (Havilituv, A. F. and
Aw. 141P11. Fit. I@, IIAI 1~,
0IM-41, 1-*of ivv%til, I'Malurd I)y mil,11111iti-I, .,I it,-
wAv, Icultih, A WPOI, SIM. -Ilklil. IfXW). 4:111611.
114111, IIVAI A., - 2 111. 2.22. '21 'N. 1.1.31, '~' 3.5. *.'~ 11
`
'
1
-411
114. 2
..M; Poo 1,
611, 1.1417, INI, IAX1, H17. 2 117,
...4, .-42; 1.67, LIA), 1.131), 1.6ih, 1xvi,
1,117s. 1.7115; anitle betwern the optival uxi% anal liar pi r-
Imudictil.ir III Or (IX)D Farr, 15.0, 14-3. 1-,,X, IWIV, 22 2.
,
IIA'
-Iw
0
911
3
35
0
1
ill
m
l
111
il
l fee
.
-
-
.
I%,
e
"
rrtt
,
c np
vo
,
;
,
,
li
S5, K1, 711, 117, 51. ;W". Valn.* .4 thr tvil't, lit OW .11,
I
ilia ".. Arc, j-p., 311311, 3731), ind 37M) A.; CIO 0
3.f#;, 2.910, 2.V, and 2.W; /I - 0.512. 0-17).
0,087
and 1).f)91,. The -e 4,,cilliutr
.
-Imigill. calvd. lty.j arc - 1,01.
IW;I. 1). 17, and 0.17.. N. Thmi
_!SO-ILA "TALLUSCICAL LITIMATIM CLASSWOCJITIOM
111* 0
=0 41
AV to As to i 1-9 li of ig a Ii dt 411114
r-O
MIG 0 0 0 0 0 0 0 0 0 0 0 0 a
10011,11, 0100000000 0 000 0 oso a 4 0 0 C 9

CO
lKlectionic and vibratictisal favele of the crystal and the
molecule W naphthalene. A. It. PrikhoCko. Zhur.
Fk,141, Fewtl. Pis. 10. 44,
433lb. -The newly det-1. sitectruin of the vapor coincides
with thAt Of ltellfi Anil Uutilb (C.A. 18, 24M) only in the
fri,quencyal the Ist electronic transition P; m :12155 cm.-I
but differs in the vilw.stional struclure. The vibrational
frequencies astricil. with a,,' are 473, 7M. IM11, 1181,
1414, 1"O. and P1,11:1 rin. 1. without distinct combina-
tintsti. The 2nd rimiti-sir transition P;I - Will Is
attiord. with the vibralloni IM and 1379 withl
Intense combination frequPitcIrt. The rutatlotial branches,
dispo,ed on the long-wave side of the hand heads, are
unresolved but (to show altrru.stitme of intensity. A
few weak hands are due to transitions from excited vibra.
tional states of the ground level. The spectrum of the
crystal consists of b 1*9 - ~p g in light polarized
prArAllel to the mix oclinic axis lying in the plane of the
11take, and a lines, parAllcl to the a axis perpendicular to
b; as a rule, b lines are more intense than a. RistAtional
structure and shading are completely abient. Part of
the lines. or bands. can fie groupeil into series. Othet
lines from satellites of Ic,wr intensity around the serial
lines. All lines become increasingly diffuse tovinArd the
ultraviolet end. The spectrum has a continuous back.
ground. more intense ArFAInd the scridl lines. All series
of the crystal can lie divided into 2 cateffnrics. The Ist
rategoty conitiriu-4 writ-i %hownic it 111%tiliCt JUAlOgy with
the spectrum tit the v-.klxw: the lines are only weakly
tiolarized. i.e. they jppeAr in hinh the 6 and the a coin-
ponent. One such series begiim with P; - 31965, corst-
bining with 4M, 718. IM.M. 1113, 1191, IM, 1431, and
1577 cm.-I, of which only 71H 1wrisibly Appears as the
hArnumic 14:11; t, - 3:17.311 onnbi"~s with the mail.
VIIJI'Ati(XIIII 518 Anil 13AR. blCtIlk-Al With the 14AMAII ftV-
urucies I$IX and 1:194, Anil with Intense COM11111AIIAMI lines.
1. compared with the vAltor. P; lit the crytt4l Is shifted
to the red by W), Pit by 211PJ cm. 1. The 3 wries of the
2nd category have noanalogy lit th,- slk-ctrum of the vapor.
and in SpeLitic for the crystal. The Ist series of this
category begins with the pure electronic -transition line
r, ~ *U41, and combines with 212. 4418, 518, WA, 9W,
Anil 13.93 cm.-I. A 2nd wrici is built on P; - "I.
appearing in fluorescence As A weak double line 21P341
And V.Kifl. Anil in almyristims as a double line 29914 and
21UJI. of which the lit 1, 6. the 2nd a; tinly the former
-rJ'A7-

combine% with mat. vibration frequencies. 4M, 724, I=,
and 1.191. The 3rd series, based on the electronic transi-
tion P; - 31062, is the main scrics in the fluoreicence
tpectrum, where it combines with several mol. and lattice
vibration fivquencies. In absorption, the corresponding
Pines are 31063 (b) and 31050 (a). In thicker crystals
0.0-1.5 mm.) these lines are split into doublets of Ap -
22 cm.-I. Two weaker lines. 31WA and 31MO, appear
in duortacence only. All lines of this category are. in
contrast to the let category, strongly poLLrized. i.e. they'
appear prefertntially as either a or 6 components. The
some character of very strong polarization is proper to
two fit"her groups. which. however. are uncormccl"t
with any known vibrational frequencies, and must be
attributed to elecuortic states of the crystal. One such
ists of two A Unes 31474 and 32227; another 6
Fo ramu U 'by two B bands. 316W-3108 and 32241-321270
cm. 1. The polarization of the series of the Ist category
14 evitivritly dctd. by the symmetry of the mol.p that of
the 2nd category by the symmetry of the crystal. Almmt.
all fluorescence of the crystal corres as to transitions
from st,itrs proper to the crystal and ruilt On " - 31M-21.
The only transition from a state characteristic of the rne).,
319M. gives rise only to very weak fluorescence.
.N. Thou

aphthalene vapor. A. F
kh.t !emo, zpactrum, of,,n R .
AVA. ',, ,' K""' ;'"'
Ekipil. Teo'el Fit, 19, is-, 9-N 1919). - I'lu 'j-1rinn
redet.l. at lc 'Ps. varying by W* 1~t,mr"n 1.1 :.11.1
with 3 thickn"*," of the abitx1tint 6"t ~ 11. 17. t tilli
'n
It consists of 3 series. cormspolli(illir to :1 differtot
to the
electronic transitions. The 3rd %Lrics rc.tcli,- 'it otti-
Schumann region. and only its tat members we"r Ph
graphed; it appeAr-� to be a series of %trong alwvptlo -
Bands of the 2nd en'"
beginning at about 44tXX) cm.
or'
sire mom Intense than thooe of the tit- Rwational sir her
jute is too fine (0.1-0-3 cm.-I) to be resoly.ible in cit
writes. All bands are degraded to the ml. 4nd the extcn-
,,ion to the red increases with the temp. owing t0 the All.
porance of new lines. All bands have 2 rotational struc-
ture branches. The hand edges are sharper in the Ist.
more diffw in the 2nd series- In the tat wries, electron
tmnsition rz - 32455 Cm. -', the Positions Of the blue edges
of the abort or long branch tit the bands. vibration fre.
quencitell (and int-sititts) are: 31511 (short), -L44;
319C (short). -41161: ;rZ196 (long), -. DO: 32455
,hort), ". Iffl; XN72 (long), -, 4.5; 3-1928 (shart),
(4
+ 473, 85'. 33104 (long) - -', 't3158 (,hnrt). + 703. 70;
-LrM8 (long), -, 50; 13457 (short). + JIM, 75; 335; .9
(long), -; .33&36 (short), + I 191, M; XV414 (long) - -
34NNS
xWo (short). + 1415. 60; 34010 (long),
much weaker lutnd:.
(,.hort), + IrAM, 100. Two very
31511 and 31902 (%hurt) - aPPC*r in 2 1110-cm. layer at 50 -
und dlsaiiti~mr rapidly with rising temp. The vihmlion
frequcticiri, 47:1. 7M. IINC. I litil. I ti.% 19411. -1 11"Ll.
fit. I03dAbt'irr.%II'.J ... Il'I In I 1.."'Inpaft, with lh,,
frequencies, 41M. 7LI. 121h. 1442. mad 16LI4. and "tit$ III,-
frequencies Of the er"t.l. The 2nd -i- i. 1-ilt
the electronic tran4ition 11
-35W5cIn.--. Th,fulW-iixK
are the positions tit both edges anti tnaxiin.! of Wild. (In -
tensities estd. visually). and vibratinn freqnenric4 Ar.
35724 (beginning of lbt hand) , 0; 357,61 (11); 3579A (Iii.
X%RZ3 (6); 33K% (blue edge. tons branch) (it);
hort) (10); MS J10). a# - fH); 3&Y-15) (3); X041
(3); -Iftril'i (4); 35ftl Mine rilgr of wrik Nind) (I I;
'M;7 (0); M~%" (1); :162611 (;1); 3OLV9 (3), 3#~Jlq
(blue edge. long) (4); M343 (4); 3t):157 (s); 36176
(8); 36398 (blue, s1wrt) (8), A, - +4191; 36417,
(0); 36435 (01; 3t"57 (1); WOM (1); 364.~i 10); 3(%L1J
(5); 36fti (blue. bhort) (5), A- - + VAP), interpreted as
2 X 493; 30210 (1); *Jl;9NJ (bitic c,lgc of Weak 6-ind); r,
37048 (1]); 371M (1); 37179 lh~; 37LI91 (8), :17~.'::fll (X);
37243 (blue, long) (8); 372:37 J.14); 37273 (11i); f%.NKS
(blue, shoro (10), Ar - 1397; 374 12 (blue cdKc of'wvak
band) (3); 37,4111 (1); :17,559 (1); 37(447, (h); 3,-, 13 1A);_
37723 (8~; :177,17 (blue. long) (9): 377US (blue, hurt)
ap - +IbW, interpreted a, 1397 + 493; 37813 (bluc
edrc of wcuk band) (3); 3N)U5 (2); .18195 (4); 18232
(4); 3N294 (blue, short) (5), A, interpreted at
1397 +
X 493); XS~l (51; .1 'VJ I V 311012's (5)
11014W
. 1 (01; 3NG87, (tell edge of br,ud li.4nd) '(6), . 36
(blue edge of broad Wild) (6). .10 - _" X 130". The 21
vibrAtion frcquencit=i, 493 anti 1397, ".tnjJ4J`C With the
l,tarnAn 512 And IMA. antl the tluor~s~cncc fruiluctici- 52t)
and 1370 cm. -1. and with the spectrum of the cryst.d.
N. Thon

PRIMODIKO, A.
Broude, V. A., Medvedev, V. S., Nechaeva, N. E., Prikhodlko,, A.A., and Kharitonova, 0.
P. Faperience during a wide investigat--'on of spectra of crystals or orWanic
substances at low temperatures. Pages 488 - h92.
Inst. of Physics
Acad. ~X Sci. Ukr. SSR.
SO: Bulletin of the Academy of Sciences, I7vestia, (USSR) Vol. 1h, 11o. h.
(1950) Series on Physics.

bbdwem6 Ow wwk. 1. V. oh"l
mvw wW A. P. Pt hod. Nsak.Y.S.S.M.:,
.W. Pis.-Te.-504(i )-A wkrmb*w4rw~ .6 time
)&ado type was constructsd and the so of &nthrwene was
massawnd ballt IN the diremim of the b and the a axis at
MWAid-N UMV. T%~ o ewvo dwm A abomptim
betweam =Fbak"4110 A. Press i1w cwv" the
tear fam is embd .Ow The chetrunk iremaltia" 4t,%
=
UOU A. mM h MW A. 7U moread tnuokim is to timan
aw"W thme dw km OW histil we I I I almm Ow.
Matnd "is ed on ad. It Is PIMM4 tkat Ow CK sham
611mr, electrook Vallaillism dmId gmiml, 8, Pak="
u IS
5
p

1. PRIRTDT"KO, A. F.
2. USSR (600)
4. Luminescence
7. Luminescence and light absorption in crystals of organic compounds. Izv IN SSSR
Ser fiz.1f, No. 5 1951.
9. Monthl List of Russian Accessions, Library of Congress, April - 11953, Uncl.

PRMOTIKOP A* Fo
Broude, V. L,,, Medvedev,, V, 3,9 Prikhotlko A. F, Electronic and vibrating levels
of the molecule and of the benzore -crysd~ P. 665,
Institute of PlWaica
AcadwW of Sciences,, Ukrainian SSR
July 20, 1950
Sot Journal of Experimental and Theoretic Physics, Vol, 21, No, 6,, June 1951

7300 TT-541
AND ADSORP=4
OF CRIMTALS OF
CH
POLYCYCLIC HYDROCARBONS. (5yeahanie I Tavat
Metallov Politsikilchesk1kh Uglevoftrodov). L,V.
Obrdmov and A. F. PrikhoVko. Translated by WknV
from Akad. Ndumm:Wm:m-., MW-atl S. L Vavilov 197-
209(
The spectra In luminescence and absorption and the
rtfrActive Irdices were Investigated (or it series of Linear
condensed hydroaarbons (benzene,. napbtbaltue, mathracene,
w d napMbaceae).at I-, tg-pgrafurgg 'Me results of this
Investigation are discussed in detail. From a comparison
of the arectra of vapors and crystals, . Me AqjGjKALh&WkLqf
a crystal caa be classilled ALL the crystals observed were
brightlyluralnescent. (B.J.H.)
Z'

USSR/Physics - Spectrography, Crystals May 52
"AI)sorption Spectra of Benzene Monocrystals in
Polarized Light," V. L. Broude, A. F. Prikhot1ko,
Phys 'Inst, Sci Ukrainian SSR
"Zhur Eksper i Teoret Piz" Vol XXII, No 5, pp 605-
6o9
Investigates light absorption spectra in benzene
crystals in the case of oscillation of. the vector
Of light parallel to 3 symnetry axes of the crystal.
Observes series of veakly polarized abaorptlon bamu
in all cases. Series of sharply polarized bands are
215119k
seen only in. spectra.in a and'c directions and axe
absent in b direction. From comparison of ob-
t&ined resats with theoretical computation, deter-
mines-'the sy=etry of forbidden transit-ion in
benzene as Alg-j> B2u. Indebted to A. S. Davydov.
Receivedl 14 Jun 51.
211.51T-94

PP IFH CUP f V

Structure of the molecule of digier! oaa%racene I its
-
'
-
Me ev. R. III
homologous 5pbstances. - R
)d
1111"'y'
"
q
. sr. 15-1 1 ).-Pure
-A k a7.
ki 1.
s I
9-methylanthracerie (in. 79.5-80.5*) was transtonned Into
its dimer (m. 22128-228.V) by irradiation of its ace-
toile soln. by a I-Ig are-lailp and recrystn. Absorption
spectra of the crystals sly)w 2 electronic transitions.
The fin, serie3 nf [)road aln)rptiou bands begins with a
strongly polarized triplet X - 3000.1; 4004.5; 4030.6
A.; tile second scrk-3 hai a long-wave limit of ubsorp-
tiou at X - 2560 A. for ow, I.claritatiou and 2000 A. for'
the other. This spectraill I!; entirely different from the
monoiner spectrum, The photochem. reaction takes place
not only in soln. but also by irradiation of monomer crystals;
it can be detd. by the loss of birefriiigLnce. The trans-
formation is effected by a change in t4e valence bond which
leads to a configuration similar to that of hydrated anthra-
cene derivs. Tim aromatic structure is lost in the central
ring. Pakswer

of the
4~
=

1
44. 2
by tte
Choaxical Abet. ~Me**C V. ~._ MIXMEFI_F5~T_rl anA A. F: Pn_-k
-
- - V"~"
7 JV4
ftGURG
A
"
69
476
kLD
~aL
# R
Vol. 48 Kai 6 - .
z
.
.
.
A
,
.,
m*,~W
,
7
Nhr d r
ectr"co
fcall
alk
thted benttaes
Caa be (dentire
.

OrganM OhsmIGU7 e
y.
~
p
p
y
The spectra of some -of (he ptoducts are repr(Auc-d
TEve folfw%vior chazaerristic pumfy~
-ketrwic ficquetteles were observM at - 100* (the state.
of the Smimim %Mn): Reph, Cry-4t, tow-temp, form,
37.M7 cm.-t-, - HtPh, crrt. high-terap, jorm, 37,2a3;,
'
PrPk 4uncirphous, 37,231; cumene, amorphous, 77,340;
m-CAtM, , etyst, high temp. form, 37,225; p-xyfene,
vryst.. 30,10. P-EtC41f4Me, cryst, high-temp. wnn.
MMO: t-eymette. cryit. V1,667; a-xylerxe, cryst. Itich-
temp. foim. SOXH; e-FACIMMe. cryd., 37,060; fetra-
cr"t,, 30,370; m-xykne, cryit. high
t-emp. forrq, Z6,778. In a Ifyca series of a type the 6peetra
me dm9ar sad chalu-bmn~hfnx does not alter the central
type af t1w. ap"tMat. 0. U. K"12DO -

The Committee on Stalin Prizes (of the Councii. of Ministers TZSR) In the fielda or
sclence and inventimw announces that the folloving ocientific worre, popj-lar acl.g-n-
tific books, and textbooks have been zrabaitt-ed for competition for Stalin Prizes for
the years 1952 and 1953. (SovetakaZa Kultum cyw go. ?2-4o, ?') Feb - 3 Apr 1954)
, Most!
Title of Work
Davydov, A. S.
Prikhot1ko, A. F.
Obreimov, I. V.
Research in the 1'ield of
the spectrosco:ly of
molecular crysta-Is
NuainaZed b~
Academy of Science5,
Ukrainian SSR
SO: W-3o6o4, '17 juiy 1954

USSR/Physical Chemistry Molecule., Chemical Bond, B-4
Abst Journal: Referat Zhur - Khllmlya., No 1., 1957, 91
Author: Broude, V. L., and Prikhotlko,
Institution: None
Title: On the Paper-by McLure and Schnepp
Original
Periodical: Optika i spektroskopiya, 1956., Vol 1, No 1, 102-103
Abstract: The causes for the divergences between the data of McLure and Scbnepp
(Referat Zhur - Khimiya, 1956, 60739) and A. F. Prikhotko i 'Zh. eks-
perim. i teor. fiziki., 1949, Vol 19, 383) concerning the location of
the absorption bands for a monocrystal of naphthalene. The authors
have conducted analogous investigations on crystals of naphtha!,--ne
and its deuterium-substituted derivatives and have found a substantial
difference in the spectra of freely suspended crystals similar to
those used by Prikhotlko from the spectra of crystals obtained by
melting 2 quartz plates. The latter-spectra show considerably larger
bands with a certain shift relative t6 the spectrum of free crystals
Card ~/2

USSR/Physical Chemistry - Molecule, Chemical Bond, B-4
Abdt Journal: Referat Zhur - Khimiya, No 1, 1957, A
6
Abstract: in the IR region. Microphotographs of the spectrum of such a crystal
are in full agreement with those published in the paper by McLure.
The authors ascribe the changes in the spectrum to the great stresses
produced during the cooling of the crystals by the ifference in the
coefficients of expansion of the naphthalene (2-101 deg-1) and quartz
(2-1o-7 deg-1). The interpretation of the electronic spectra of
naphthalene must be carried out according to the spectrum of a free
crystal or by making allowances for the distbrtions in the spectrum
due to the action of exterior forces described above.
Card 2/2

Category: USSR Physical Chemistry - Crystals
Abs Jour: Referat Zhur-nimiya, No 9) 1957) 29723
Author : Broude V. L., Prikhot'ko A.F.
Inst : not given
Title : Investigation of Structural Changes in Crystals on the Basis of Their
Spectra at Low Temperatures
Orig Pub: Kristallografiya, 1956, 1, No 3, 334-341
Abstract: A study was made, in polarized light and at temperatures of 77 0 and
200K, of the absorption spectra of a number of molecular crystals of
aromatic compounds (essentially hydrocarbons of benzene and naphtha-
lene series). It is shown that the absorption spectra, the same as
many other properties of the crystal (refraction index, coefficient
of expansion, etc) fully depict lattice anisotropy. The changes ob-
served in exiton bands of the crystal spectrum make it possible to
identify crystalline modifications, and in some instances permit to
evaluate lattice sy=ietry. In the spectra are also reflected the in-
Card 1/2 -24-

Category: USSR / Physical Chemistry - Crystals B-5
Abs Jour: Referat Zhur-Khimiya, No 9., 1957, 29723
clination of the molecule in relation to the crystallographical axes,
the form of distribution of admixture within the crystal, photochemi-
cal transformations which take place in the specimen, etc. Investiga-
tion of crystals of different thiclmess, on a quartz base layer, has
shown that the spectra are also affected by the effects of external
influences. The paper demonstrates that low-temperature spectral inves-
tigation of crystals can provide a valuable addition to roentgenographic
nalyses. It is noted that correct evalu tion of the effect of crystal-
line structure upon the spectrum can be had only in those instances
when the investigations are carried Out in polarized light, with polari-
zation along the axes of cauchy ellipsoid.
Card 2/2 -25-

BRODIM. M. S. JQWVRDW, V.
CrYostats used
tures- PrIb.i 'A Jamin interforomtry at liquid hvdrogen te era-
ekh-OkSP-no.3: 96-98 N-D 156. '7
Is Ins"tut fizlki AN UISSR. (KLRA lo: 2
(Ilt,rfercq~try) (Cr.

24(7) ?) PHASE I BOOK EXPLOITATION SOV/1365
Lvov. Universytet
Materialy X Vsesoyuz*rogo soveshchaniya po spektroskopii. t. 1:
Molekulyarnaya (Papers of the 10th All-Union
Conference or. Spo-~tros,.;opy. Vol. 1: Molecular Spectroscopy)
[Llvov) Izd-vo Llvovskogo :Eaiv-ta, 1951'. 499 p. 4,000 copies
printed. (Series: its: Fizychn-yy zbir-:Lyk,. vyp-
g Agea,:;---: Akademiya nauk SSSR. Komissiya po
Additional Sponsorln!; P
spektroskopii. Ed.: aazer, S.L.: Ted'a. Ed.: Saranyuk, T.V.;
Editorial Board: Landst-erg, G.S., Academician (Resp. Ed., Deceased),
Neporent, B.S., Doctor of Physical and Mathematical Sciences,
Fabelinskiy, I.L., Doctor of Physical and Mathematical Sciences,
Yabylkamt-, V.A., Doctor of Physical and Mathematical Scli-ences,
KornitsU:tv, V.G., CKnd:!da-'U---_ of Tee_-riical Sciences, Rays1dy, S.M.,
Candidate of Ph-ysical and Mat,hematicall Sciences, Klimovskiy, L.K.,
Candidate of Fhysft~~al am-id MathematlcaZl Sciences, Mil1yanclijik, V.S.,
Candidate of Physi,,,al and Mat",!iematica.2. Sciences, and Glauberman,
A. Ye., Candidate of Phys:Laal and Mathematical Sciences.
Card 1/30
3

Papers of the 10th, . ) sov/1365
PURPOSE: This of art,_4,1,_~es Is i-n-tended for scientists
working in the field of spectroscopy and for engineers and
laboratory ana'.1yste who use spectroscopic methods in their
work.
COVERAGE: This c~311ectlo-n of articles is concerned with theoretical,
experimental, and tech:-Lical problems in molecular SDectroscopy.
The applicat-ion, of molp_,~~7;21.ar spect-roscopy to various fields of
theoretical researoh is described in articles covering chemical
structure, kinstics, cat-alysis, theory of the chemical bondirg,
properties of crys-.-als, effect cf radiation on substance, etc.
Good coverage is :06o giver. to the use of spectroscopy in
organic and ino--ganic te-11unology 'M-noluding the study of petro-
chemicals (0
,, polymers, glasa, phosphate. boron compounds, etc.
Each article is followed by references. The text includes tables
and figures.
Card 2/a0
3

Papers of the -10th (Cont. SOV/1365
TABLE OF CONTENTS-
Academician G.S. Ob.-Ituary 5
Academician G.S. Landsherg. Introdur;tory Speech
at the 10th AII-Urzaon Co-nference on, Spectroscopy 7
Zavoyskiy, Ye. K., S. A. A-311-sh-uler, B.M. Kozyrev.
Paramagnetic Resonanoe 13
Broude., V.L., V.S. Medvedev, and.A.F. PrIkhot1ko.
Spectrography of Benzene Crystals at 20.40K 14
Brodin' M.S., and A.F. Prikhotlko. Absorption and
Dispersion of fig-HE-E-i- Gerta:.Ln- mole ~=,I ar Crystals 16
Prikhotlko, A.F., and M.T. Shpak. Polarizat-ion of
Abi6rptio--n-Bands of rmpuritles -4n Crystals 21
Card 3/0

BRcDjN. H.S.; ~RIKROTIKOj A.F.
Absorption and scattering of light by various molecular crystals.
Fiz . abor. no.3:16-21 '57. (MIRA 11: 8)
1. Institnt fi.ziki AN USSR. -spectra)
(Anthracene

FRTHOTIM,.A-.F.; SHPAK, M.T.
Polarization of i ity absorption bands in crystals. Fiz. sbor.
no-3:21-24 157. (MIRA 11:8)
1. Institut fiziki AN USM
(lamineseence) (&sorption spectra)

AUTHORS: Broude, V.L., Medvedev, V.S. and Prik-hot1ko-, A.-F. 51-3-6/21~
TITLE: Spectral investigation of benzene c .rystals at 20.40 K. 0
(SpektralInye issledovaniya kristallov benzole pri 20.4 K).
PERIODICAL:110ptika i Spektrosko iya" (Optics and Spectroscopy),
1957, Vol.2, No.3, pp-317-322 (U.S.S.R.) -
ABSTRACT: The present authors studied earlier (Zh. Eksper.Teor.
Fiz., Vol.21, p.665, 1951 and Vol.22, p.605, 1952) benzene
monocrystals in polarized light at the liquid nitrogen
temperature. They found then that a purely electronic
transition forbidden in the benzene molecule occurred in
benzene crystals as a resolved doublet with its components
polarized along the a and c axes of -the crystals. This
doublet was shown by Davydov (Zh. Eksper. Teor. Fiz., Vol.21,
p.671, 1951) to be due to formation of free excitons in the
crystal. This paper deals with absorption spectra of benzene
monocrystals at the liquid hydrogen tempera ure. The
apparatus i luded a spectrograph with 2.9 i/mm dispersion at
about 2600 T. An Iceland spar polarizer was used with a
special diaphragm to make possible recording of two spectral
Cardl/3 components simultaneously. Liquid benzene was poured into a
special cell and held in a crycstat which permitted rotation
of the cell. New samples coul(. be introduced during work.

Spectral investigation of benzene crystals at 20.4 0K. Cont.)
51-3-6 2
Preliminary cooling was carried out wi h liquid nitro en
and in the final cooling only 30-40 cm~ of liquid hydrogen
were lost per hour. The absorption spectrum of benzene
monocrystals at 20.4 K consists of more 'than 100 na row
(2-4 cm7l) bands. The spectrum begins at 37800 cm-1 and the
plates in the paper show bands up to about 41000 cm-1. The
spectrum of the benzene crystal consists of two basic series:
the K series strongly polarized bands which are related to
the fully symmetric vibrations of the benezei~e molecule and
the M series, more intense, whose beginning occurs when a
purely electronic transition is combined with vibrations of
E symmetry (523 cm-1). The K series occurs in crystals
My and is called "crystalline", while the M series occurs
also in gases and hence is called "molecular". The K series
consists of six groups each of which contains 3 or more bands.
The M series consists of four groups each of which has 3 main
weakly polarized components and less intense satellites.
There are also further bands w4ich a~j,itrongly polarized but
Card 2/3 of low intensity, denoted by K-L whose components
1
are very close together (2 to 0 m Interpretation of
the origin of these bands requires further work.

Spectral investigation of benzene crystals at 20.4 K ~Y~c
,~nt. )
There are 2 line figures, 1 plate with spectra anli-ft 2
references, 6 of which are Slavic.
SUBMITTED: August 23, 1956.
ASSOCIATION: Institute of Physics, A.C. of Ukrainian SSR, Kiev.
(Institut Fiziki Akademii Nauk tSSR 6. Kiev).
AVAILABLE:
Card 3/3

AUTHORS: Broude, V.L., Pakhomova,
TITLE: Effect of deformations on
(Vliyaniye deformatsiy na
O.S. and Prikhotlrko, A.F.
the spectra of crystals.
spektry kristallov).
PMIODICAL:"O-Ptika i Spektroskopiya" (Orptics and Spectroscopy),
1957, Vol.2, No-3, pp-323-329 (U.S.S.R.)
ABSTRACT: Deals with the effect of planar tension on the absorption
spectra of benzene, naphthalene, anthracene and CdS at the
liquid hydrogen temperature (20.4 K). The sample were thin
films held in a crystal holder. The assembly had a quartz
lens for photographing spectra of various parts of the
sample. The whole assembly was rotatable and was placed in
a cryostat with quartz windows. The spectra. were obtained
with a quarAz spectrograph whose dispersion was 2.9 X/mm at
about 2600 A. To study the CdS spectra glass optical parts
were used. An Iceland spar polarizer made it possible to
obtain simultaneously spectra for two mutually. perpendicular
directions of the electric veator vibrations. A krypton
lamp was used as a source and the iron spectrum for cali-
bration. Naphthalene crystalline films rigidly fixed
Card 1/3 between two quartz plates behaved differently for differe'rat
thicknesses of the film. Above 2-3 ~L thickness these films
cracked on cooling to 20.4 K. Thinner films exhibited

Effect of deformations on the sDectra of crystals. (Copt.)
51-3;7&4
spectral displacement towards ulturaviolet when compa with
freely supported samples. This spectral displacement was
accompanied by widening and weakening of bands and strong
polarization of the originally weakly polarized "molecular"
M bands (see the preceding paper). If the films were very
thin (0.01 ~i) only the spectral displacement occurred.
Similar behaviour with strongly developed polarization
effects was observed for anthracene films. Benzene films
also behaved essentially in the same way as naphthalene
but both the spectral displacement and polarization effects
occurrbd only in thin (0.2 - 0.5 -~') films. In CdS displace-
ment and intensity redistribution of absorption lines
occ'urrea for crystals under tension. The exDlanation of
these effects lies in the large difference of linear herma
expansion coefficients of the quartz h Iders (2 x 10 deg-
and of the organic crystals (1-2 x 102~ deg-1). Cooling to
20.4 K from room temperature produced an extension of 5% in
the rigidly held crystal films. In thicker films the ex-
tension is non-uniform across the 5amDle thickness being
Card 2/3 largest at the planes of cont;-ct with the quartz plates.
This non-uniformity which pro,.uces lattice distortions,
accounts for the displacement, weakening and widening of

51-5-7/24
Effect of deformations on the spectra of crystals. (Cont-.)
spectra of the thicker films. The thinnest films are thir,
enough to be extended practically uniformly -throughout
their volume; in this case only the spectral displacement
occurs. Polarization of the "molecular" M bands (whose
excitation is normally localized in the molecules) is due to
formation of free excitons in non-uniformly stressed samples.,
The actual mechanism is not clear and needs further study.
The peculiarities of benzene are attributed to its
transitions to a doubly degenerate level (absorption bands).
There are 2 plates with spectra of naphthalene and
Card 3/3 anthracene, 2 line figures and 12 references, 11 of ahich
are Slavic.
SUBMITTED: August 23, 1956.
ASSOCIATION: Institute of Physics, Ac.Sc. of the Ukrainian SSR,Kiev.
(Institut Fiziki Akademii Nauk USSR g. Kiev).
AVAILABLE:

AUMORS: Brodin, M.S. and Prikhot,ko A.F. 51-4-7/25
TITLE: Dispersion and abso-ii~~_~oi_h_~~71-n anthracene crystals
at 20.40K. (Dispersiya i pogloshcheniye sveta v kristallakh
antratsena pri 20.40K).
PERIODICAL: "0;)tika i Spektroskopiyall (Optics and SDectroscopy)
1957, Vol.2, No.4, pp.448-453 (U-S-S-R-)
ABSTRACT: Colourless anthracene crystals s rongly absorb in the
near ultraviolet at 24500-29000 cm-i (first electron-
vibration transition in the crystal) and also at
37000-42500 cm-1 (second transition). This paper reports
on the refractive index dispersion and the absorption co-
efficients of anthracene crystals at 20.40K at 25000-37000
cm-1 for two directions of the light vector: parallel and
perpendicular to the monoclinic crystal axis. To study the
dispersion a small Jamin interferometer was crossed by a
spectrograph. The method is due to I.V.Obreimov (Jubilee
collection of papers on the 70th birthday of Acad. A.F.Ioffe,
p.523, 1950 - in Russian). Spectrograms were obtained with
and without a crystal in the light beam. The absorption was
measured with the cooperation of S.Z.Shullga (see also
Zavodskoya laboratoriya, current number in print). A photo-
multiplier FEY-18 was used. For the dispersion and absorp-
Card 1/3 tion. measurements a quartz spectrograph of medium dispersion

51-4-7/25
Dispersion and absorption of light in anthracene crystals
at 20.40K. (Cont.) '
was used' Low-pressure hydrogen lamps were used as light
sources. Glan-Thompson prisms viere used as polarizers. The
iron are spectrum was used as wavelength standard. The
acduracy of measurement of the refractive index was about
2% and of the absorption coefficient 8-10%. The results
are given in four graphs. The refractive index at 20 40K
oscillates strongly (from 1 to 6) at 25000-28000 cm-,; its
value outside this regon is 1.5-2. The absorption coeffici-
ents (values up to 0. 0) are shown for both 2940K and 20.40K;
oscillations here occur.at 25 000 - 29 000 cm- . From the
absorption coefficieats and the refractive index the reflec-
tivity curves (values up to 0.50) are constructed; again
oscillations occur at 25 000 - 29 000 cm-1. In all graphs the
largest maxima occur at about 25 000 cm-1. The oscillator
strengths of electron-vibration transitions were calculated
to be for the three directions:(a) parallel to the monoclinic
axis, (b) perpendicular to that axis and (c) at right angles
Card 2/3

51-4-7Z25
Dispersion and absorption of light in anthracene crystals
at 20.40K. (Cont.)
to (a) and (b). Th& values were found to be: (a) 0.12,
(b) 0.05 and (a) 0.13. There are six figures (including one
half-tone plate), and nine references, seven of which are
Slavic.
ASSOCIATION: Institute of Physics, Academy of Sciences of the
Ukrainian S.S.R., Kiev. (Institut Fiziki All USSR, Kiev).
SUBMITTED: August..18, 1956..
AVAILABLE; Library of Congress
Card 3/3

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SA
SA.

51
AUTHOR: Prikhotko, A',"F',-
TITLE:A Study of Spectra of Molecular Crystals at Low Temperatures
(Issledovaniya spektrov molekalyarnykh kristallov pri
niakikh temperaturakh)
PERIODICAL: Opt'ka i Spektroskopiya, 1957, Vol.III, Nr 5, pp.434-
452 (USSR)
ABSTRACT: Systematic work on the spectuscopy of molecular crystals
was begun in the USSR by I.f.Obreimov in the late twenties.
He showed that at liquid helium temperat-1.,,res the absorption
spectrum of azobenzene is of the line type. It can be rep-
resented by a series of electron-vibrational transitions
from a normal state to an excited state. Results of studies
of spectra of molecular crystals, which. are a continuation
of the wo 'rk of Obreimov at the Physi co -Technical Institute
of the Ac.Sc, of the Ukrainian -S.SR are reported in this
paper.
1'. Experimental. Vie majority of organic compounds crysta-
114se into molectilar lattices and most of the work at the
above Institute was done on such crystals. The method of
obtaining such crystals has been described in Refs. (33),
(38) and (23)~. The crystals are often in the form of thin
Card 116,

51-5-3/11
Study of Spectra of Molecular Crystals at Low Temperatures.
plates (a few hundredths of a micron to a few microns thick).
Larger specimens are obtained by cleaving large monocrystals.
Substances which are liquid at room temperatures are crystall-
ised directly in a cryostat by slow cooling of the container
in which the substance is placed, by liquid nitrogen or its
vapour (Ref.21). Substances which are gaseous at room tem-
peratures are first compressed into quartz containers and
then crystalised by Slow cooling with liquid nitrogen or
hydrogen (Refs.41, 43-45 and 54~. In this way more or less
perfect monocrystals are obtained and their spectra are
studied at liquid helium and liquid hydro en temperatures.
Metallic cryostats are used (Aefs-130-1M, one of which is
shown in Fig.l. The c:r7ostat has three pairs of windows so
that it is possible to photograph absorption and luminescence
spectra of any given crystal without moving it. Full det-
ails of the various auxiliary apparata are given in Refs.(19)
and (130) to (136).
2. Absorption of light bv molecular ervstals. When the
temperat~dr~e of crystals is lowered various chan~;es in the
abs)rgt'Qn spqctra are,jb erved. Changeasbo V have
beeno ubject d to deta ea study t et ULnsst'i P
at h1d 0 Me.
Card ~/6 For example, E.I.Rashba has worked on the theory of strong

51-5-3/11
Study of Spectra of Molecular Crystals at Low Temperatures.
interactions between electron excitations and lattice
vibrations in molecular crystals (Refs'.1-5)t and the inter-
action of excitons with molecular lattices (Refs.127). Rad-
ical changes in absorption spectra in going from the gaseous
to the crystal phases have been observed by M.D,Borisov
(Ref"2), M-S.Brodin (Ref.5) and A.F.Prikhot,ko (Refs.1,4,5).
A coj;~ider~ble amount of other work has also been done in
this field and a complete list of references is given.
3. Luminescence of molecular crystals. Luminescence spectra
of napthalene, anthracene and other crystals have been in-
vestigated at liquid hydrogen temperatures (Refs.37, 39 and
40). Strong luminescence of these molecules is observed
when they are introduced as an impurity into other lattices.
They have a practically line luminescence spectrum (Refs.3,
56-58 and 128). The number of levels, their symmetry, pol-
arisation and the selection rules have been obtained using
group theory (Refs*.67, 77, 98, 101 and 103). "Energy mi
ration"-was studied by A'.N.Faydysh and others (Refs.63, gEf
92-100).
Card 3/6

51-5-3/11
ystals at Low Temperatures.
Study of Spectra of Molecular Cv
4'. DisZersion of li&ht in crystals. Determination of
cillator streng1lis. The optical behaviour or -crystals
is rmined by 3 quantities: coefficients of absorption,
reflection and refraction and their dependence on wave
length. Two of these are independent and if they are known
the third may be found from the well-known formulae of
crystal optics. The absorption and dispersion curves and
the crystal spectra change when the crystals are cooled.
Wide absorption maxima split into series of narrower maxima.
The rise of absorption curves towards the absorption bands
becomes much steeper and the coefficients of refraction in-
crease rapidly in this region. Small maxima in these curves
become more pronounced, as can be seen in Fig.121 where the
dispersion curves of diphenyl crystals are given at 200K
(Refs.1, 29 61 8, 9, 36-38, 61, 65 and 66). Fig'.13 shows
dispersion curves for anthrace'ne crystals at the same tem-
pqrature. The rapid rise in the dispersion curve of the
b-component is due to a strongly polarised band which begins
the absorption series (Refs.1, ?, 6, 8, 99 36-38, 61, 65 and
66). The theory of dispersion is developed in Refs.73-76,
819 86 and 1447. Integral formulae have been obtained for
Card 4/,the -calculation of dispersion curves of crystals which give

51-5-3/11
Study of Spectra of Molecular Crystals at Low Temperatures.
ood agreement with experimental data (Refs-.9 and 144).
ues for the oscillator strengths have been obtained for
M
a number of aromatic h drocarbons (Table 1; Refs.1, 2, 5-9,
61, 65~ 66, 138 and 14~. It was shown that the first trans-
itions in all condensed aromatic compounds are polarised
along the mean axis of molecules. Oscillator strengths in-
crease with the number ofrt-electrons. A similar situation
occurs in the case of crystals of other polycylic hydro-
carbons.
5. Conclusion. Studies of spectral and optical properties
of molecular crystals at low temperatures (both experimental
and theoretical) have led to information on the energy
levels, optical characteristics and the mechanism of the
various phenomena occurring at low temperatures. From a
knowledge of the main regularities in the spectra, it was
possible to establish a connection between structural changes
in crystals and their electron spectratand between changes
in these spectra and the elastic deformations of crystals.
The role of lattice defects,particularly important in lum-
Card 5/6 inescence spectra, has been elucidated. Studies of solid

51-5-3/11
Ptudy of Spectra of Molecular Crystals at Low Temperatures.
solutions of aromatic hydrocarbons h,&ve expanded the know-
ledge of spectra of complex molecules. There are 16 figures,
1 table and a comprehensive list of 147 Slavic references
(including full titles) is given under the title "Work on
the Spectroscopy and Crystal Optics carried out at the Ac-
ademy of Sciences of the Ukrainian SSR". The reference
list is subdivided into the following sections:
1. Experimental papers - Refs'.1 66..
2.. Theoretical papers - Refs.67 129.
3'. Apparatus - Refs.130 - 136-
4. Dissertations - Refs-137- 147.
ASSOCIATION: Pbysics Institute of the Ac'.3c. of t'-ie Ukrainian SSR,
Kiev (Institut Fiziki AN USSR, Kiyev)
SUBMITTED: June 289 1957'.
AVAILABLE: Library of Congress.
Card 6/6

BRODIN, M.d.; PRIKHOTIKO, A.F. [Prykhottko, A.F.]
'Vr
A
boorp O"n"%%*MV4rnion of light in certain crystals of tha
polycyclic series [In Ul=ainian with sumrwy in English]. Uvx.
fis. zhtL-. 3 no.1:79-87 JA-F 158. WRA 11:4)
1.Institut fizik-i URSR.
(Stilbene--Optical roperties)
(Acetylene--Opticai~

BROUDS, V.L.; YEREMENKO, V.V. [IEramenko, V.V.1; IIEDVEDKV, V.S.;
PAKHOMOVA, O.S.; PRIKHOTIKO, A.F.
4-z-.1-:7--- ~ 1: -'-
Effect of deformations on the electron spectra of crystals [in
Ukrainian with summary in English]. Ukr. fiz. zhur. 3 no.2:232-238
Mr-Ap 158. (MIRA 11:6)
I.Institut fiziki URSR.
(Crystals--Spectra) (High pressure research)

51- 4'
A.UTHORS: Prikhot I ko, A. and Shpak,

TITLE: S-i 1-3er~~
Absorption and Luainescence L ta- n
'
lyu-min-
Dibenzyl Crystals at 20.hrOK. (Pogloshc'qerjiye i
estsentsiya stillbena kak primesi v kristualla1d,
dibenzila pri 20.40K.)
PERIODICAL: Optika i Spektroskopiya, 1958, Vol.IV, Nr.l,
-
P.O.!?-29. (USSR)
ABSTIMT: The absorption bands of strongly absorbiriG cx-jstalf~
(e.g. stilbene and tolane) are still comparati-r-aly
wide at liquid-hydrogen temperatures. VFhen the absorb-
ing molecules are separated by molecules of a foreign
lattice (e.6. stilbene as an impurity in a dibenzy!
crystal) the absorption bands of the impurity are
sufficiently narrow to be called lines- Cr~ystals with
such impurities usually luminesce. The present paper
deals with absorption and luminescence of stilbene in
Card 1/? dibunzyl ci-j.-tals. The res,.ilts were ob. ned using a

51- ur --.1-3 r*26
Absorption and Luminescence of Stilbene In-ouritj 'n, Dibe!-.z-11
Crystals aju-- 20.4":K-
Hilger c.~iartz spect-roGraph of hiF~n dispersive power.
The absorption spez~t-ra were photoGrapned in Dolarizea
1 i ght- .The cell .,jith-the crystal 1.-ias conclied r,.-, the
hydrojn~n, A hyd-rc6en or a
temperature of lio
ki-jpton lamp was used as a sour,,7~e, and a-,--, a:r,:~ spectrum
between iron elef,,tiodes was used for calibration. The
L
crystal thicknesses in -absorption stadies- wer-e froii
several hundredths of a micron to 160 ~L. The s',--lbene
content was from about. 0.001I.-S t-o b-Y we---gh.-,.
S-D e C. ~L
To srudy luminescent I'm ci-jst-alline platc-s of I m-
1 -L
thickness were us(;-:cI- lphcse specUra we-re obtl-,~Llled 'rom
the same surface of the crystal onto wi-ii-Ch th-7 exr;i1tuin
liGht fell. Luminescence was excilu-ed b,", rrioans oif a,
Card 2/? mercury lamp. Crystals of dibenzyl p(~sses-s intrinsi3

51- L-3/26
Absorption and iki-ainescence ofIC In Dit,-enzyl
Crystals at 20.40K.
absorption in t'ho region of 3'1000 (,vi VIDich
of a larE;e number of narrow bands and lines, Oom,~ of
4ty
which are strangly polarized. The stilbene impur-L
i.
begins to absorb light frora about 29500 cm- FiF'. 1
shows t;fie absorption spectra of dibenzyl faoncci~~,rstals
160 ~t tLick with O.OLV; of st-ilbene (Fig.la), L
-thick vzi-th 5cl of L;Lilbene (Yig.11)) and 2 ~L -u-Iich
with 5cl,, stilbene, (FiF,._Iv). Ali regults i.-I this
fiSure and subsequentfie7ares and tables are quoted in
cl~-I. Table 1 shows the ruouli~-s of moasu.L-L~m,,~nt.~ or)
a 160 ~L thicIs- d2benzyl crystal with about O,OLV of
stilbene The -first column Sives relative
Card 3/? intensities obtualined visuall--. _"h_, ~,ecoEd colulam
d

53-- 4-1-3/26
Absor r i t 7 --, n L'i IJIL- e n 7, y 1
ption and Lur:inE;sce-,.~co Of Impu
I OK'
Crystals at 20.4
gives frequencies in cm- measi).rcd with 1-2 ca-
precision for narrow liae2, 3-5 cm-1 �'cr narrow
bands and 1.0-15