SCIENTIFIC ABSTRACT PROTIVA, M. - PROTIVA, K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001343320013-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

COUNTRY Czechoslovakia
CA~EGORY
AS3. JOUR. iZ:~h i-:,i.
AUTHOR
NIT.
TITLE
ORIG. PUB.
ABSTRACT
G-2
57137,1
is allowed to stand 12 hrs at the end of which
period 4 gms of 211-Ft2S(:k-H20 are obtained,
mp 128-132* (corr; from water). For Communica-
tion YL11I see RZhKhim, No 14, 1959, 49433.
P. Sokov
CARD: 4/4

PROTIVA, M.
"Winter meeting of the Swiss Chemical Society in Zurich."
P. 522 (Chemie, Vol. 10, no. 6, June 1958, Praha, Czechoslovakia)
Monthly Index of East -'?UrOPean Accessions (EFAI) W, Vol. 7, noe 92
September 1958

CZECKOSLOVAKIA Organic Chemistry. Synthetic Organic G-2
Chemistry.
Abs Jour: Ref Zhur-Khimiya, No 23, 1958, 77579.
Author : Novak, L. and Protiva, M.
Inst : Not given. I---------
Title : Syntheses of Estrogens. XI. On the Chemistry
of Derivatives of 5-methoxyindianone and 4-meth-
oxyindianone. M. !'-phenyl- 'r-methoxybutyric
Acid.
Orig Pub: Collect Czechoslov Chem Commun, 23, No 4, 663-672
(1958), 673-680 (In German with a Russian summary).
Abstract: See RZhKhim, 1957, 71596 and 71597.
Card 1/1
5

CZECHOSLOVAKIA/Organic Cherlstry. Natural Products and Their
Synthetic Analogues.
f,bs Jour; Ref Zhur-Khim., No 24; 1958, 8i76o.
Author Adlerova E., Novak L., Protiva M., Jilek J., Protiva M.
Inst
Title The Synthesis in the Group of Estrogenic Hormones. XrV.
2-Substituted Derivatives of 3-Methyl Cyclohexanone
Carbonic Acid . XV. The Reaction of Phenylacetylenes with
Substituted Cyclohexanones. A New Complete Synthesis of
One of the Racemic Doisynolic Acids.
Orig Pub: Collect, czechosl. chem. conmun., 1958, 23, No 4, 681-
691; 692-703-
Abstract: See R.Zh. Rhim., 1958, 11219, 54013.
Card - 1/1

CZECHOSLOVAKIA / Organic Chemistry. Natural Compounds G-3
and Their Synthetic Analogs.
Abs Jour: Ref Zhur-Yhimiya, No 23, 1958, 77835.
Author : Pliml, J., Borovicka, HT., and Protiva, M.I. and
Protiva, 14., Botovicka, B. , CiMT-er-, T-- , and Sedivy, Z.
Inst : Not given.
Title : Synthetic Analogs of the Curare Alkaloid. VI.
Some Notes on the Preparation of Tris-2-diethyl-
aminoothyl) Ether of Pyrogallol. VII. Two New
Models for Tubocurare and Two Bis-quatornary
Ammonium Salts.
Orig Pub: Soll Czech Chem Commun, 23, No 4, 704-711, 712-719
(1958) (in Garman with a Russian summary).
Abstract: See RZhKhia, 1-4'57, 51216; 1958, 4777.
Card 1/1
46

CZECHOSLOVAKIS / Organic Chemistry. Synthesis. G
Abs Jour: Ref Zhur-Khimiya, No 7, 1959, 23411
Author : Borovicka, M.; Rrotiva, M.
Inst :Not given
Title :Antihistaminic Substances. XLI. Derivatives of
1-Aza-2,3-5,6-Dibenzoeycloheptadiene (Homoacridan).
Orig Pub: Collect. czechosl. chem. commun., 1958, 23, No 7,
1330-1335.
Abstract: See RZhKhim,, 1958, 43415.
Card 1/1

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Country Czechonlovakia
Catcrzory
liba. Jour to
Author :
In.,) t, itut.:
T i t 1,,-
Crir~ Pub.
A'an-G-ract
5-2
Hach, V. and PrgjjaL&,--M,
NoL given
Antihistamine Compounds. XLl 1. Der;.votives of
1-Aza-li-th"a-2,'-5,6-,iibeiizocyclo)Lep~~,-tdierie
Olorr.ophenothiazine)
Collection Czechorlov Ch.-,.-r. Commun, 2j, Diu I.J.
1941 134' (19~:8); Chei.-i List~v, 51, 1909 (195/
See RZhKbim, No 2-~, 1956, 7??02.
Ceard

6R f
P,T
1/10
i czecho&" ovak--La
t
t 140, 5 1960; NO*
I Ve~delek, Z. J~ and Protiva, M.
I Not (,given
1 Corrno;irds Which Block the Sympathetic Ganglia. VII
Deriv-3tive-a of 2-AmirioiFocampnane.
I Ciiem U,5tj, 52, No 12, 23703-2377 (1958),
The preparatiot of analdes of 2-aminolsocamphine
(1), 2-meLiqlaminoisocamaphane (II), and 2-dimethyl-
aminoisocamphane (111) and of their reduction prod-
ucts, V,3ubstituted 2-methylamA-no-;-Fo~-air-phane,-;, i6
di,scribed. A mixture of 1.4 gm ! and 1 gm FIC01,11i,
is heated for 4 hrs at 130* followed by heatin!7 for
io udn at 145-15C,* to give 2-formylaminoiso-camphane
IV), Yield 0.75 gm. To a noluzion of 2128 gms D-
camphene (V) in 4015 m! CHICOOH, 84 ml. of conc
L J4 followed by the
.~S' are added with coolingr,
186

o.
IT!5~
Jon.
Ila. 5 196'js
Owdered IvaCli a r, af
of P
6-1 - r.
of 252
i so. and 30"
-2
a n:. - j L" '
.~turel,f 50r c-;o. ul~ ir, F.
Whig h a Z; ti-p- res
is added 0"~e, I - rz at 20G and Poure,
48 n
S110.3ed to ',h
f;.jjj.--,ed 71'L,-
vg- of i---- reut
e extrac t is
t IV~ r -Th
z 61 Wl -t0% NO-2 r-(:~
vf:~t, .,es r, TV
rle
t
"h',ut of t I cat 0
fj.CZL-jC)n- APP-
_,,cjj cord 1"r,
..i furt"er

960.. No
RM"im', n

:%
S
%
PUB, I
!::t, GT FiveG 143 gms of crude IV from
1.,,-S gmr, L-V. The reduztiGr, of 2-nitraiiacerphane
w-1. th Ila -LP alcohol gives I, mp 182-1841 (distilia-
E 3~ 120D + 211 flalc) , picrate mp 222* ( I
tion)
,
alcl; the hydy-och-loride derivatives Eaelts above
3"L" , A mixture of ".1 gms crude !V, 25 L-,L 10",
"aOF., and 25 ml aco,~;ol is heated for 40 j,rc-:
vield of 5.2 gm~ I is obtained. The red-w. ti~;nf
gm TV with 0.5 gz M A H, in ether gives~
hydroc~--Lcvid~- :.!c
;`~D 3AO 13 -7

C Er R, I ff -I I CzechoslovakAa G-3
CA r-MMY I
ABS. JMR* 112MMoo., Mo 5 1960jp ITO& 17 9.5
ITITFOR
POT,
CRIG. PUB*
1LB5'MCT 1 25-16 (from isopropyl alcohol-ether). The reaction
of DL-VI with Bt(Cf4 )5 Br instead of the corre-
sponding diamine gives only tha hydrobromide of
DL-VI, mp 24?* (from alc-ether). The analogous
f
reduction of IV (obtained from D-V) gives D-VT,
up 70-720/1-1.5 =, a2OD 1.4835, [a POD +31, (c
I ; a1c), hytirochloriLie ,~ 294-295' (deconp; from
iso-C-3 H7 OH-ether),' picrate mp 1670 (from 60% ale).
L-VI is similarly prepared from IV (outained from
L-V), yield 40,%, bP 78"/5 mm, n'ODI,4868, -[c