SCIENTIFIC ABSTRACT PUDOVIK, A. N. - PUDOVKIN, M. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001343530002-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

FUICNLK, A.N.; GGLITSYNA, G.A.
Reactions of aadirion cf- and
phosi:h.c.rothi-oic. acids. Zhur. ob. khlm. 3-' nr~. 3:?,7E-;,;*g-',
L. ns~.Jltut o-rucanicheskoy khimid Kazan'.

I
"UDOVIK, PI.N.; Fpiyz,61,7~!N, 1".M.
r
Mechanism of rea,,-tions of phosphorus ac-d chlo --des -with ovi s
of alkenes and d-ienes. Zhur. ob. khim. 34 no. 3:882-SS9 Mr 164.
(IMIRA 17:6)
1. i;azanskiy g03udarstvennyy universitet im. V.-I.`.'11-,,,anova-
La n i na .

PUEOVIK, A.N.; YCVSI'AFtYl-.V, G.I.
Diphosphonic glycols alp:~Osp!7,on-c d-*--~--s and some cr theJr
I - -- - -
reactions. Zhur. ob. khim. 34 no. 3:FqG-E-92 'Mr 164,
(M!I,Rj't 117:6)
1. Kazzinskiy guoudaroLvomiyy universitet.

il]DOVIK, A.N.; UZOVII'VA, FL.G.
Reactions of diene s-nthesis involving esters ofCC- andg-
carbethoxyvinylphosp~inic acid. Zhur. ob. khim. 34 no. 3:
1031-1032 Mr 164. WIRA 17:6)
1. Kazanskiy gosudarstvennyy univc-rsitet.

Card 1/2

Ail

-65 EWT(M)/EPF(c)/EO(j):.
L 17954
4/034/067/2471/2472:
S/0070
6
02
MTW NR: AP50
9
5
AUTHOR: Pudovik A N.- FiLyzullin, E. 14- Mukbametzyanovij Kh;
n.-
TITLE: Reactions of diglycide-etherVth. h1orides
1964 2471~2472
SOURCE: Zhurnal obshchey khimiii.,v. 341 n6.
TOPIC TAGS: ether, phosphorus-acid, chloride, ester,, 'sulfur.
the reaction of dig ycide- thiir with~ -chlor dies horus:.
Abstiact: In e i Of ij~b_s~
pe s n~th
acids, the oxide ring o n o ~e side . of the-'Primary carbon atom*, f orMng
*
phosphorous-'aci
beta-chloro-betal-glycidlisopr6p~ldialkyl--etter Is'6f
Sulfur was added to one of the:.Okbdiicts.:-;-:beta-chloro.~be'ta'-glyIcidyliso-,
propylidiethyl ester of phosphorous acid,,,producing thebita'-chlotowbeta,'
-glycidylsopropyldiethyl ester-of thipphouphoric acid. 'In the reaction of-
diglycide ether with two males (if -the chloride:of diethylphosphorpua.acid,
addition occurred at both .oxide rings, forming tetraethyl_ialpha,_:alpha1_
u ak; an
dichloromettiyldiethylene glycol diphosphate Orig. art, has 2 forin1 d
1 table.
Card 1/2

PcJ Pr~ RM
L 17959-65 EWT(m)/EPF(c)/EWP V-
58-5
-ACCESSION NR: AP5002618
AUTHOR: Pudcivik, A. N.; Muratova A., A Silvel!yeva, V. 'A..
Card 1/2

L 18279-w65
ACCWv9SION NR: P.P5002985
are rearranged during the reaction to dialkyl(dlpha-'- h 1).
carbethoxyet.y
thiosphosphates, diethyl(alpha~,dieihSlthioohospho6e)ethyi~~ho-sph~ite~, 'a nd-
diethyl-alpha-acetoethyl thiophospliate.:. in the . reaction of dief.,hylthio-
~ esitei of alpha-h~drbxy-~.
phosphorousacid with acetophenone, the d.iethyl.-
.
alpha-phenylethylphosphifiic acid*aa formed.ih-onlta smalt-y'leld' izoat
of-it decomposing to the.stirting miterialo:,Uppn.dibtillation.-,It:was
concluded 'that replacement of ~ the jhosphinic~. gro4p ~by the thioph6iphinic.~'.
Xroup, exhibiting a*sMaller induction effect.aa.'a-reault-of thelower.

electronegativeity ofaulfur in-co6parigon-At4
'oxygen,-exertw~a substan-
-tial Of luence on the -ability:
cearrangement~ Orig. Art. has Tfdrmulss and I. Ubles' -5

T
'..unv Atei--Viii-Verai y.
era
ASSOCIATIONs Kaimsk*- 4,
;g0sudarstve

63:
SUBMITTO.- OIJU1

OCIFIf OTHMi
.No SOV
vi

CaM 212

C_
7-65 -EWT-( )/EPF( E PR/*WP4# -
1 4130'

AC TION NR
AP5OM35.
Q.
L4
GoloveA
E
1
shevar~va
k
i k A
N
P
d
,
.
.
s,
a
ov
*
u
AUTHORI
. I
id chlorides W:
dialkv1phosphorous ac wi
horic ;and
rl de
3j
f di
i _:_:; 7.*:-;,~-
.
a
cj
MTM R
actionv
p ".
d
d,me h
,ethylene Slyco~ Gate acrylic

34, no. lo,- .1 4i
SOURCEt- Zhurma..obshcheyl-khi

rou-S acid, he
TOPIC TAGS: ;phosphoric-'aciA chloride'- ethy 4
roy'li
'Abstract':,Dialkyl (ac' 1(methacroylLith~leneglyqol)
hospmtes were prepared ~by react ion of.dialkytphosphorlc adid: chl6d ires' with

tion In
n
.ethyle,e.glycoll-esters of acryl ic, -a nd tae'thacryl Lc: acids: in. ether.~ 96 4
~the presence of -triethylamine:. ]Dial kyl (m~thacr6y_ lethylefieg lyciofi --- phoa~hite_q
yere prepared by reactidwof dial kylphosphorous- acid'-chloridiii, -with the eth

ileneglycol ester, of . meth- Th nee ~ of,: trivalent p as 'h ius
acrylic acid. le, prese h p 9 n
4the raction product. was-'confirimed. by~.infrared spectra and thi6 ugh ihe ~_'_add it ion
6sphi somer z
,of sulfur, to give diethy~'(metharroylethyleheg~yco.l)-thidph ' ate.-I

h I
tion.with ethyl iodide produced th~_Fthyl(methacroylet y. eneg ycolYebter of
'
-t
dthylph6sphinic acid.. SMe of- triethyl;:*Ph,',~phite:anA-4~~hildi(metha
'
~
*of,di th 1
i
craylethyleneglyeal) phosphite were .-produced in the - f orutatidn
,(met
-diapdrp rtionatiort
hacroylethyleneglyeal) ph6iphite 9mgk.1nte'rMoliculst 0
LCard_3./Z___

_1 65
'ACCESSION.NRl' AP4045101
_W$
6
studied # -0 -diphehyl--~~OhosphorochlA
h reac
was t a. tion, oi ,0 '14
_he::_ML_X_GV anhydrLd6jW"
with. PotafsLum, acry ate or--in I-V
-2i",
58-59, and 7445C)
Lh 5OZ yielde i
So se
~7
H 0) PCI + KOOC" -~:OR is 011,3. (C CIL' 66-1.~ CH
M,
_44he reR -i-h*'. CH
W11"
c:tn''' i It f ir'- e-16. seh c e
van t s& niA - P-0 I ymat to
its 2 ~-l 6-tmu as'
-ASSOCIATION. s. KaxanskLy" ft'
&nova-Ledina. (Ka*zall_!:Statd-,
UnLveraLty
_5
A ~W I-jz '3169
811c]
SUBMITTID 29Fsb64 I
REF~ 0
V 118RS
SUB: COD]
06
~3/3

:r- o),
-r~ on.'s
"10 1120t'1-2 .2 '9 It-,'
1. Kazans' i-. sud a r i tve nny,
y

f~.n!
ennyy universizetu-

ACC INR: AP6028903 SOURCE CODE: UR/0079/66/036/008/1467/1472
AUTHOR: Pudovik, A. N.; Pudovik, M. A.
ORGI Institute of Organic Chemistry, Kazan' (Institut organichookoy khimii)
TITLE: Atomic refraction of phosphorus in asters of alkylarylphosphinic acids, in
aa7lphosphinic acids, and reactions of addition to unsaturated compounds
SOURCE3 Zhurnal obshchey khimii, v. 36, no. 8, 1966, 1467-1472
TOPIC TAGS: organic phosphorus compound, light refraction, phosphinic acid
ABSTRACT: A series of asters of phenyl- and p-tolylphosphinic acids have boon synthe,
sized. It was found that the atomic refraction of the pontavalont phosphorus atom in
esters of phenylphosphinic acid is equal to 5.60, in esters of p-tolylphosphinic acid
to, 6.10, and in esters alkylphonylphosphinic acids to 5.34. Replacement of the alk-
o.Nyl group in dialkylphosphorous acids and esters of alkylphosphinic acids by the
phenyl group causes the atomic refraction of pentavalent phosphorus to increase by
1.08. The addition of monoesters of p-tolylphosphinic acid to acrylates, mothacryl-.
atps, and acrylonitrile, and the addition of monoesters of p-tolylphosphinic acid and
di~lkylphosphorous acids to Schiff bases having two carbon-nitrogen bonds In the mole-
cule were carried out. Crig. art. has: 5 tables.
SUB CODEs 07/ SUBM DAM i2Ju165/ ORIG REF: 004/ OTH RMS 001
ill - - - __ obc. s7AI .

A C C N R t -AP 6 0 -2 5 9 1~7 -S O-URC' E- -60- D-E -:u Q-60-7-9 /-6-6-/U3--6-/.O--07/.-l 2--3-2/-12--3-6'
AUTHOR: Pudovik, A. N.; Yaj3trebova, G. Ye.; Nikitina, V. 1.
----------
ORG: Kazan State Unviersity (Kazanskiy gosudaretyennyy universitet)
TITLE. Esters of d-cyanovinylphosphonic acid
SOURCE: Zhurnal obshchey khimii, v. 36, no. 7, 1966, 1232-1236
TOPIC TAGS: alkyl cyanovinylphosphonate, diethyl cyanovinylphosphonate, dibutyl
cyanovinylphosphonate, ;4,f
ABSTRACT:
.Diethyl a-cyanovinylphosphonate (I) and di-n-butyl a-cyanovinylphosphonate
(II) were obtained by the condensation of formaldehyde yith diethyl and
di-n-butyl phosphonoacetonitriles in-the presence of piperidine in methanol:
(R0),P(0)C11,CN+C11,0, C11g=.C-P(0)(0H)&+Hj0
Card 1/-j um 54T.313.2 546.185

ACC NR: AP6025987
Table 1.

Wtklc COMPOUILd- CIM 3) -bpl 20
d 20
n
~,
al D Foulke F06.6 ca.
-
2P zp
I CIIe-C4CM)P1OXOCtH,), 21 82--M' 1.1040 1.440 43.31 46.76 10.85 C'11111110'r Iiw
It C"e-C(CKJ 1`10)(0c,"rit), 25 96-98 1.0176 1.4150 63,72 63.22 13.20 CRIHW"OP. f2.05
Most.

III (CIH,O)lp(o)cm(CN)CIIIP(O)(O(~"&)s 79.2 173-174 1.1706 1.45M 75.06 74.55 16.1 1 -C,IH,NOP, mso
(2)
IV (C,ii,O),P(O)cu(cm)clf,F(O)(OCIarN)I 50.5 175-176 IA328 1.4503 84.05 93.78 17.81 e'lln"Osps ' .7.45
t0-97)
V (C.H.0).P(O)cu(rN)CH,SCOCH, 54 133-135 1.181f 1.4725 62.54 U.33 11.82 C~11161104ps I Me
(0-04)
TI (C&tI&O)1P(O)Cn(C..qCIIsC,H, 49.3 Ila-fig '1. 1258 IAM d2.53 42.52 12.57 r'HISMOSPS 13.M
.
.VIJ (NC#HIO)sP(O)CH(CN)CHIP(O)IOC,Hh 75 iSS-168 1.1060 LOW 93.07 03.03 MAX co"'Nops 111.18
.
54 ISS-155 1.0350 I.4M 39.24 59.04 11.18 CnwmmO,,P 13.30

Ix (CtI8Ohr(oj1cHJc(1)cff,,pio
4 St.# fa-tic 1 15M I 4m cn WRO'p, fv.23
cons P-04

Card 2 1- 3

ACC NRt AP6025987
The addition of dialkylphosphoroiis acids, ethyl- ethylphosphIAateu-#idAmmraks,
and ethyl mercaptan to I and II gave.the.corresponding eaters shown in the
table. Orig. art. has: 1 table.
(W.A.. - 50; - CBE No. 10
UB CODE: OV SUBM DATE: 10may65/ ORIG
S rW: 004/ OM MF:O0
Card 3/:3

ACC NRi kv6025995 SOURCE CODE: UR/0079/66/036/00t/1345/1345
AUTHOR: Pudovik A. N.; Khusainova, N. G.
ORG: Kazan State University (Kazanskiy gosudarst-iennyy universiteo
TITLE: Addition of 0,0-diethyl dithiophosphonate to esters of unsaturaLW phospbonic
acids
SOURCE: Zhurnal obstichey khimii, v. 36, no. 7, 1966, 13115
TOPIC TAGS: alkyl d ith iophos phonate, unsaturated alkylphosphonic acid/ AAfd-~j
ABSTRACT:
O,O-Diethyl dithiophosphonate (I) adds to.6,0-diethylvinylpilosplionate
(II) to form adduct III, bp 164-165*C, n20 1.1776:
D
(C'H!j0)tP5Sll + C"1=514P(oc H) 5 0
I . I- :A
(0" 11 - (C2115 0), P -sGfl ~Cllj P Wc'fl')l
(Ql,0),PSSK + 8rCHz(:HjP(()Cl"3)&j III

ACC NR:
addition apparently
The
proceeds by an ionic mechanism and is contrarv
to Markownikoff's rule. The addition of I to dialkyl esters of I-prop'ynyl-
i :phosphonic acid (where R- is a-butyl or -ethyl)
c11,
(C11150)"'S" + C1f37G=C-1'(011)2 (C211r-O)t1'
I If If
8 ~s 1)
yielded 0,0-diethyl S-1-methyl-2-diethylphosphonoethenyl dithiophosphate,
bp 171-172*C (2 mm), n2o 1 5074 and 0,0-diethyl S-1-methyl-2-dibutylphos-
D 20 1.4995.
phonoethenyl dithiophosphate,__bp 168-169% (5 x 10-2 mm), n
D
art_.-4a'_s-:' 2 tormulas. -7-
9 ----- 50;--CBF,-*No 1b]-
SUB CODE: OT/ SUBM DATE: -16Dec65/..
2/2

ACC NR: AF05028903 SOURCE CODE: UR/0079/66/036/008/1467/1472
AUTHOI: Pudovik, A. N.; Pudovik, I'l. A.
OiG: Institute of Organic Chemistry, Kazan' (Institut organicheskoy khimii)
TITLE: k..o-,,ac refraction of phosphorus in esters of alkylarylphosphinic acids, in
az7lphosphinic acids, and reactions of addition to unsaturated compounds
SOURCE; Zhurnal obshchey khimii, v.-36, no. 8, 1966, 1467-1472
TO?IC TAGS: organic phosphorus compound, light refraction, pbosphinic acid
k
.11C L LI
'35T" T: A seriGS of esters of phanyl- and p-tolylphosphinic acids have boon syntha-'
sized. It -was i~ound that the atomic refraction of the pentavalent phosphor-as ato= in
estarz of phenylphospl.inic acid is oqual to 5.60, in esters of p tolylphosphinic acid
k1o 0.10, and in esters alkylphenylphosphinic acids to 5.34. F.3plac=ent of the alk-
cxyl group in dialkylphosphorous acids and ostors of aBsylphosphinic acids by the
-p.-or,yl group causes the etomic refraction of pentavalent phosphorus to increase by
A.08. 7he addition of monoesters of p-IColylphosphinic acid to acrylates, mathacryl-.
--tes, and acryloniE'ri-le, and the addition of raonoesters of p 'olylphosphinic acid and
y1phosphorous acids to Schiff bases having two carbon-nitrogen bonds in the mole-
cule wore carried out. Orig. art. has; 5 tables.
SUB CODE: 07/ SUBIX DATE: 12Jul65/ ORIG REP: 004/ 0-TH 10IFF: 001

ACC NRa-'AP602'59'88
06166fM36Vf2hO
SOURCE CODE: UR/0079[66-/
AUVOR: Pudovik, A. N. ; Khusainova, N - G.
---------------
ORG: Kazan State University (Kazanskiy gosudarstvennyy universitet)
TITLE: Addition of alcohols, amines, and dialkyl phosphitee to eaters of
y, y-direthylallenylphosphonic acid
SOURCE: Zhurnal obshchey khimii, v. 36, no. 7. 1966, 1236-124o
TOPIC TAGS: dimetbyl3ilyi-phosphonic acid ester, alkylamino dimethylallylphosphonate
d,-0 AOQ-) 0-1 -r-4-1 pJ-ojL.A.,L,- AAfQ1-
ABSTRACT:
Alcohols', amines, and dialkyl phosphites add to alkyl y, rdimethyl-
allenylphosphenir- acid (I) to form the following four types of compounds:
(C113)AC-CX-C11,-P(0fl)% (C.,1108011-CK-CH.- P(OR)lk
(Cj1j)jCX-Cjj.Cjj-P(011)2 (C113)1C-C11-CHX-P(011)2
(4)
Card 1/3 UDC: 547.315.1

NR, AP6025988
(R and X are given in the table):
Table 1. Adducts of alcohoisq amines, and dialkyl phosphites to
eaters of y Y--dimethyl'allenylphosph.onic acid
(RO)2p-CIIj-CX=C(CH3)2
Co fiel b
i
( 2 D
d 20 MRD Found Formula MI
"

P
P
P R x
in n
p
p
mm) 4, nD
~
% R
t
.
.
. round Calculat
d
I Cfls OC,H:- N 79 145- rJ) 0.99-In 1.4444 -
0.04
MG4
11.77
nosp 11.74
,I N-CI OCII 7G 120-122 (1.51 1.0140 '-"9' 19-AS 69.66 11.113 11011' 11.74'
It r?(j' OCAI. IA (5) 0.9962 1.4413 14.15 74.~a 11.73 C, Voir I,- is
: A...,
OCII .5
72 32 - x, (I 1
1 (1.9894 1.4516
79.,4
78.69
10.60 Cis n.041'
.60
.0
-C'11, (jr.14
' 57 "'i-On ('j.8) 0.9755 f,45441 IS4. Z9 W.51
4
7 9.90
19
63 cis 310.p
C
11
0
p 10.10
74
19
11
,
:, 1
(0)(UCII?), 82 147 (1) IAT27 1.4674 74.33 7
.2 . 1,
:4
'
, .
(
I[ P(OI(UC'I rN)j 65 156 (1.5) 4595
1 92.% 92.74 W&I q3ilnolpl 16.75

C'ffs
-
11101(0c it.
T.1 57 (".$1
I
I 067S
1 4590
: t0f.9 101.97 ts. to C"II"O'P' 15.51
N-(:~-If, POMOCIIih 74 . 154-155 11.5) 1.11511 1. 45FO 0;1. IiR 83.5 16.16 C1311200411t 18.12
x N--C~11-. NOHOG,11, 63 157-ISS (t.5) I.("- - t.KM 92.55 92.74 16.93 ClIH310IP2 19.75
x I N -C,ft, NOROC,101h 57 165(t.51 L(KII t.4.W 102 f0I.q7 0.311 CI-OfJ60IF2 Me
I
.1
~ N-c'II' P(oX0C It
51 61.5 203 14
3
1
1
5 LOW
1049
1 1.4583
1 M.]
74
92 t1l.22
92
74 M32
16
75 ~"H'O'P'
O
p
C
11 14.55
91)
5
1
X
.
XIV N -C,119
N-C4116 P10)(0
NOHOC'H
~ 79
81 -
6
6
1
. 9).
197P .
LOL64 4648
1:4601 .
102.3 .
101.9T .
16.10 l
14
"
t
Cn H,O,P, .
15.57

X V
N-C, ~
Is
76
72-1
4
11.6)
1.0440
1.45M
111.4
111.21
14.80.
C1211404PI
14 5",
XVI C'u, -MCIIII)s 74 .I 20
Ilp-I 2) 0.9251 1.4654 75'M 76.57 11.49 C U H ON OiP 11:12
xyll
XVIII c ti,
`tl"
P ?I(C "al
h
Cit 58
66
a 14o.-143 3.5)
128
130 0.9m
Low 1.4520
1
41KIS 85.10
78
63 85.8t
711
99 10.80
.0
90 CII"003-
C
111
MO
P WAS
10
70
XIX .
A. "' "
r (
'j.
NICH ) .
62 -
41
156(2 Ot43
1 .
4781
1 .
as 49 .
88 23 .
o
45 S
14
"
I40
C
"
P .
9.75

xx ,
-
N-
"
C N(C
111
63 .
135-IJI
1) :
09M
1 46:17
:
005
05 04 -
g
70 's
n
2
C
11
w0
p 9.31)
. I
. 2 . . 1,
0
m

ACC NRt AP6025988
The addition of alcohols and phosphite esters to I takes place in the
presence of sodium alkoxides at 70-160*C. Amines (diethylamine and
piperidine) add to I on a water bath without a catalyst. Physical
constants of the adducts are shown in the table. Orig. art. has:.l table.
(W A 50- CBE No. 101
SUB CODE: 07/ SUBM DATE: 1214%r65/ ORIG REF: 006/ OTH REF: 001~

ACC N7.: 1,26031387 -SOURCE -CODE:-
'IXT1101: Pudovik, A. N.; Pudovik, M. A.
02G: lziztituto of Organic Chomisti-j, AcadoW, of Sciencor., SSSR, Xazan' (Institut
O*r-laaichaskoy khinui Xcadomii nauk SSSR)
K'413: Transesterification of monoothyl esters of ethyl- and phonylphosphonous acids 11
u~ith - cols
.1y
SO-.'C-": Zhurnal obshchoy khirii, v- 36, no. 9, 1966, 1658-i6~2
TOPIC TkGS: estorification, phosphonous-acid, glycol
A33TR~'.CT: -In order to dot~ermino tho offec'%-. of the nature of glycols on 'he courso of 1
.'-:.-anscr,to;.-ificatJon reactions, tho k-inolics of roactions of rizonoot osters of ethyl-!
I thyl
and Doo.Viphosphonous acids with 1,2-p-rop Ono glycol, 1,3-propylone glycol, 1,3-,
Yl
1,4- az-.d 20--butYllano glycols, di-p-lopylone glycol, tri-, totra- and hoxaethylano
glycols, el-th-o-l"reol, 2-butyne-1,4-diol and hydroquinono wc;-_-a ztudiad. Tho reactions!
c--rAed out -' r 3 hr at 1700C. Tao reaction rates doc-.Oas-3 in the seiries othyl-
10
ene Cli ycol ), dipropylonG glycol >.triat' hylene glycol > itotraothylene glycol > hcoxact'hyl-
Ono glycol-7
and incroase in the series ethylene glycol < 1,2-propylono glycol< 2,3-
butylone glycol < 10-butylene glycol. A series of acid diy~hosphonites werz& thus ob-
tained. 7hoy are relatively vIscous liquids soluble in alcohlol, water, dioxane, tet-
rahydrofvran and chloroform, and insoluble in benzene, other, toluene and petroleum
Card 1/2 UDC: 547.26q!4�5~~22

ACC INR: APOS03138?
A.
o'ho:-. Diphosphonitos obtainad from glycols %fLth a long cha' n of carbon atg,-.Is aro
stable in storap, whereas product" obtainad fron glycols such as ethylene glycol, I
1,2-propylano glycol and 2,3-butylene glycol change their constants during storage.
Table 1 shows.the physical constants of the diphosphinites tained. Oril-. art. has:
5 figures and 1 table.
d.-
DiphosDhonitue of 1
Diethyl 1,2-propylene glycol 11 .42 116-119- (0.04) 1. B80 1.4612 54.08 :54.48
Diethyl 1,3-propylene glycoll 50.7
Diethyl 1,3-butflene p1 col 49'
Y
Table 1
-Diethyl 2,3-butylene :lye 01 40.2
DietVi pentamethylene glycol 411 - I
51.4
Diethyl diethylene glycol
IDiethyl propylene glycol 35.8
tiet-hyl tetraethylene glycol 46.2
128'-130 (0.04)
143-144 (0.08)
128-t 29 (0.04)
M-163 (0.08)
160-162 (0.06)
144-147 (0.04)
152-155 (0.03)
S
u
--B CODE: 07/ SUB-1-1 DATE; 12ju!65/ OnIG REF; 004
Card /2
1.1630
1.1335
1.1360
1,1162
1.1815
1. U19
1.1618
1.4663
1.4640
1.4626
1.4672
1.096
1.460
1.466t
51,.37
59.98
58.710
63.72
60 94
70.03
82.60
54.1.
59.10 1
59.10
63.72
GO.74
69.97
82.49

L 3179
EWT(m)/EWP(j W/RM-
---IX-P-6'0--Z 1-690 soutwo comt -uii/0079/66/03 /003/0565/05651
ACC NRx
AU."i 10 RR :Pudovik, A. N.; Pudovik, X. A.
Institute of Or;~anic and Maysical Chenistr7, Ali SSSR, Kazan' (Institut
1--anichoskay i fiZICHOSIMY K~03. Iff SS~~'~~~
0
Ij
TITL!,: Addition of acirl cyclic diothylene g3.ycol diphosphitellat multiple bonds
S011110i~: Zhurnal obshchoy le-aii-di, v. 36, no - 3. 1966, 565
'20-2ic reaction nochanisn. , caor-rIcal bonding, organic phosphorus compound,
I '
hctcroe~,clic base compound, chorieLcal reaction
AESTI~C'2: Acid cyclic diethylone glycol diphospUte is capable of underr.'Ping
ireactions of Tracleophilic addition to unsaturated electrophilic compo 41c0 in
C=C, C=C,, and C=~NT bonds. Phonjl and naphthyl isocyanates, ac nitriUle P-dimethyl-
ardnobyonzaidohydo, p-bromobenzaldohyde, and bonzalaniline urere us
unsaturatet
compoiuids. The reaction was carried out at 100' i-rith an excess of the unsaturated
cor.r.pound in the presenice of all,=li metal alcoholates. It am be carried out in the
absence of a solvent or in anby&--ous alcohol solution. Orig. art. has: 1 table.
SUB CODE: 07 / SUM DA7E: 010ct65 / ORIG RIEF: 001 / OTH RO-F: 001
03~d

L 25978-66 Lpw_v T
SOURCE CODE:
ACC NRa AP 15614 (A
AUTHOR: Pudovik, A. N.;
Pudovik.,_M. A.
UR/0020/66/168/002/0354/0356~
3,7
ORG: Institute of Organic and Physical Chemistry im. A. Ye. Arbuzov AS SSSR, Kazan
(Institut organicheskoy i fizicheskoy khimii Akademii nauk SSSR)
TITLE: Migration polymerizatiolf acid diphosphites, diphOBphinAes [sic] with
p-tolylene diisocyanate and some other compounds with two double bonds
SOURCE: AN SSSR. Doklady, v. 168, no. 2, 1966, 354-356
TOPIC TAGS: phosphorus containing polymers, fire resistant material, migration poly-
merization, para tolylene diisocyanate, acid phosphite
ol
ABSTRACT: Migration polymerization of acid diphosphites with p-tolylene diisocyanate
W or with some other compounds was studied. Cyclodiethylene glycol diphosphite
(II) or diethyl 1,3-propylene glycol diphosphite (III) [designated "diphosphinite"
in the original] were used as phosphorus-containing components. The effects of
temperature, polymerization time, ratio of components and the nature and amount of
solvents used in some experiments as polymerization media on the yields and properties f
of the polymers obtained were studied. Most of the experiments were conducted with
co-mponents in the equimolecular ratios, in the absence of solvent and in nitrogen.
atmosphere. In some cases, however, dimethylformamide, dioxane or etbyl acetate
J,
UDC'
Card 1/3 54 6.183:547-315.3 7-

L 2;`~978-66
ACC NR3 A~6ol%i.4
CIV,
CH CH 0, VC000
+ IS-OCN NCO
Y"Oclf, ff
30 3 -1
t
CI
();6 .act
F
r,--Nl ca
tic ONII-e
ff;P~OCHC If, _? '--~
CH3
O= (cif)).+0 + A-0C NCO-
If If
its c C fill eoNH -CHI
,F
_.triethylene glycol> totraol-1hylene gglycol> hoxaothfl-
ona ,lycol-;and increase in the series ethylene glycol < 1,2-propylono glycol< 2,3
b-etylone glycol