SCIENTIFIC ABSTRACT KOPTYUG, V.A. - KOPYLOVA, V.D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001401430008-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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-Acc. Nr*-. Abstracting Service,( e f Cod a
3
C11E.NMICAL kBS.T. 47
lber
819 94d Isomeric phenythexameth% tz~nonimn ions and
r
tbeir interniediates Rn Avlli:
it~

7 L
ITrt e~.inlj of
771
Org. M~4nz. 1970, 60), 102-7 (Russ l ~rjt~ ~
with

' vyeto-'
*

,5,(3-
Ielle 3-phvl)V1j,J,2
5-rfiene il'. Similarly 4-we0i
hexa-2
pentanictliylcvctt:)IiQ-~a-2,.!').cliei,e (11) WaS PrePd. ~ X'MR SPec-
'IF n
troscopy showed that in BFi-I iixi.' 6t: 90 to -80' 1, 11,

wns.
give, resp., 1-, 3-, or 4-phcwjhe\
irl BF3.HF: mixt, to
The tuillp. of I sof from
-10' Cause-, tile f"Irillatioll of

M~,

beiizerionium ion (Ila) besidc.;
ben coutwlj~
zequ., ioui ;on fla At 0' the ini lluxt.
Hviznig 1-11'. an HC1 gayt

E F L F E

Ace. Nr -
J~0053767-
Abstrac ing Service:
cmicALt ABST. -,A10
Ref. Code:
URO,? 64
?b 5tu a i
110864d Isomeric transformations of substitu d methylene-
cyclohexadienes. .1%tozu1enko,L.. M;; Koptyujq-1Lid6. (Novosi-
bi~~k. jp t. Q&g. Kbgn, '~MvoQi~gx, msz:,n). 4h, (irk. jimm-
1970, ti(12). J16-10 Muss).1 Ln CQ14 soln. 4-hydr6sy-4-phenyl-
1,1,2,3,5,6-hexanieth,.,Icvclohexa-2i5-dietie (1*. A., Koptyug, e1
al., 19701 loses H:O ana.in 2 hiat room temp. 'it, is cojl~erted
into 6-methylene-4-lphen~1-1,1,*1,3,5-ir-ntat~ethyic~-clohexa-0~.4-
diene(l). Addn.ofO.66%CFICOII+totitesolti.~causc:sisom-
erization of I to 6:'):2,4-methv)eni-3-phenyl-1.1,2.5.6-I)enta-
methyleyclohexa-2,,r;-dien"-Tneth Ilene-2-pKenyl-111,3115,6-
y
pentatnethylcyclohexa-2,5-d iene-;-4- methylene - I ~ phenyl - 1,2,3,-
5,6-petitamethyleyelohexa-2,5-die6e,.mixt. 1-be isomerization
proceeds through "pheny1hexamethylbenzenonium ion.'
REEL/nWE
19830830

!7'
.112 022 UNCL ASS IF I ED PROttSSING DATE--230CT70
-T,ITLE--STRUCTURAL FEATURES OF SOME DIPHENYL OXIDE DERIVATIYES -U-
-_'AUTHQR-(02)-BAKHVALOVj O.V.1 KOPTYUGI V*Ao:
~:OUNTRY OF INFO--USSR
~!~OURCE-IZV. AKAD, NAUK SSSRw SER. KHIM. 1970, (1), 143-5
E_ PUBLISHED ------- 70
,:'SUBJECT AREAS--CHE-41STRY
joPIC. TAGS--ORGANIC OXIDE, BENZENE DERIVATIVEr 8ROMINATED ORGANIC
~~'-~~'COMPOUNOI PHENOL? POTASSIUM HYDROXI'DE, C:OPPER, IR SPECTRUM, MOLECULAR
:COUTROL MARKING--NO PESTRICTIONS
oblCUMENT CLASS--UNCLASSIFIED
REEL/FRAME--1984/1669 STEP NO--UR/OOS2/7i.)/000/t)01/OL~t3/01't~
_CIRC ACCESSION NO-AP0100273

.212 022 UNCLASSIFIED, PROCESSING DATE--230CT70
i;IRC ACCESSION NO-AP0100273
:_,A8STRACT/EXTRACT--(U) GP-0- ABSTRACT. HEATING 82 G P-C SUB6 H SUB4 BR
WITH 41 G PHOH AND 19 G KOH IN T14E PRESENCE OF0.36 G FRESHLY PPY.
6 Hii AT 180OEGREIES WITH REMOVAL OF H SUB2 0 CONTINUOUSLY GAVE
27PERCEAIT (P-8RC SUB6 H SU34) SU82 0 (I)t D SU80.3 92-50EGREES: AT
-220DEGREES THE YIELD OF I WAS 35PERCENT'. SIMILAR REACTION OF P-BRC
AlNo cu:
H SUB4 GH AND PHOR WITH KOH GAVE BUT 7PERCENT I . ik spEcrRA
-OF~THE PRODUCTS WERE EXAMD. AND IT WAS IND[CATED THAT THE CLAIM OF
f 2 CONFORMERS OF I IS DUBIOUS CRUDENKOu ET AL-1
EXISTENCE 0 19691, rHE
R_ESULT~ REPORTED-HY R. ARE PROBABLY CAU,SED BY IMPUR11TIES,

1/Z 012~ UPICLASSI F I ED PROCESSTPIG jATE--13,NI0V7Q
PUSIT10" uF THE LABEL
..TITLE--USE OF MASS SPECTRUMETRY FOR DETERMINING THE 14
_..lN CAR613ili 13 LA6ELE0 NAPYTHALENES -U-
V.A.# ISAYEVp I.S.p GORPINKEL, 41
OUNTRY OF INFO--USSR
C
AKA0. NAUK SSSR, SER. KH I IA. !1970, (4),a5-9
------- 70
DATE PUiiL ISHED
ISUBJECT Ak-EAS--lNUCLEAR SCIENCE AND TECHNOLOGYP CHEMISTRY
TOPIC TAGS--MASS SPECTRUMs CARBON ISOTOPE, CHEMI CAL I.ABELL I ING ,
NAPH THAL ENE tGRIGNARD REACTIONt KETONE.
c eriTRGL'j'-lARf%lNG--;%0 REST~-~ICTIONS
DOCUMENT C LA 5--U-NGLA 5