SCIENTIFIC ABSTRACT ROZENGART, M. I. - ROZENGAUZ, D. V.

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SCIENTIFIC ABSTRACT
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S/020/60/134/006/017/031 B016/BO67 AUTHORSs Kazanskiy,, B. _A.. Academician., Rozengarto No, I and a~ Freybergq L. Ao Effect of Potash and Phosphoric Acid Additions on the Aromatizing AC4.:tVity of Chromium Oride PERIODICAL3 Doklady Akademli nauk SSSR, 1960, Vol. 1349 No. 6~ PP- 1360-1362 TEXTs The aromatizing activity of the Al-.Cr catalyst.in the reactions of dehydrocyclization.of-n-hei~ane"land the dehydrogenation of cyclo- hexanJjis favored by the alkali ana alkaline-earth elements (Ref. 1). The authors wanted to study the effectof addit-:ions on the catalytic activity of.pure chromium oxide in the conversion reactions of hydro-, carbons, since in the Al-Cr catalyst chromium is the effective agent. The experiments which were conducted at 45001C and a volumerate.of 0.8 h proved that an addition of 0.25 wt% or K 0 in the form of potash com-, 2 pletely inhibits the reactions of dehydrocyclization of n-heptane. Card 1/3 Effe,,,'I of Potash and Phosphoric Acid S/020/60/134/006/017/031 Additions on the Aroma~tizing A;,-t:-Ivity of B016/BO67 Chromium Oxide Furthermore, the formation of unsaturated compounds is reduced to 1/7, and the cracking and isomerizing secondary effect of the catalyst is almost completely eliminated. This addItion produced the same effect on the dehydrogenation of cyclohexane to benzene. Howeverv toluene was formed from an n-heptane 4- n-heptene-1-mixture if,potash was added to the catalyst. The yield of toluene In this case was by, 60C14 1 lower than that without addition of potash. The authors wanted to clarify whether the inhibiting effect of potash is a speci-fic result of its alkalinme nature. For this purpose they-.studied~"hs affect of additions of 0.14 wt%o of phosphoric acid on chromium oxidz. The effect was the same as that of potash. Additions of both types also reduced the hydrogenating effect of the catalyst. Thesp experiments show that the promoting effect of potassium on the A-'!-Cr catalyst- is nol~ dus to ths interaction of the alkaline addition with chrc!mium oxids. This effect has a more comDli~'.%ated nature and appar-antly is the ~z-onsequenr,=- 3f the .-nt=raction of all. th:ree components-a of chromium oxide, of aluminlim orideq and of the alkaline addit.-L'on. One of the forms of this interaction was: described earlier (Ref.12). The fact that the aromatization of heptane and cyclohexane Card 2/3 Effect of Potash and Phosphoric Acid S102 6o/i54/006/017/031 Additions on the Aromatizing Activity OIL' B016%067 Chromium Oxide ceases after the introduction of K?CO 3 or H3PO4 on pure chromium oxide, whereas the aromatization of heptane continues, i~an be explained by the fact that -the two additions influence the first stage of catalysis, i.e.9 activated adsorption. The authors assume that these additions prevent the adsorption of the saturated hydrocarbons at the active centers of ,the Cr catalyst. The adsorption of the much more active olefin, molecules s of-this ph,~n:)menon., is inhibited mu ch less. To explain the detail further studies are necessary. The authors menti,).u papers b,-.r A. M. Rubin" shteyn, N. A. Prilbytkova, and A. A. Slinkin (Ref. 2). Table 1 gives the results of the above aromatization experiments. There are -1 table and 2 Soviet references. ASSOCIATION3 Institut organicheskoy khimi-I Im. N. D. Zel�nskogo Akademil nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of the Academy of Sciences USSR) SUBMITTEDa J,11Y 159 1960 Card 3/3 S102016011321021341067 B0111BOO2 AUTHORS: Rozengart, M. I., Slinkin, A. A., Rubinshteyn, A. M. TITLE; structure and Catalytic Properties of Chromium-silica Gel catalyatsk PERIODICAL: Doklady Akademii nauk SSSR, ig6o, vol. 132, No. 2, PP. 367-370 TEXT: The authors found out that the chro'mium-silica gel catalyst first treated with ethyl alcohol and then heated ir the air current, soon is poisoned during, the aromatization (dehydrocyclization) of n-heptane by coke deposition. This: catalyst had antiferromagnetic properties and its radiograph clearly showed lines of Cr20~. The same catalyst but heated in the hydrogen current (instead of air), remained unpoisoned during 2 hours of the experiment, and proved to be, paramagnetical, and radiographically amorphous. Fig. 1 gives an adsorption scheme of a paraffin hydrocarbon.on crystalline Cr203; A new molecular C-C bond.develops besides,the aromatization. This causes. he development.of molecule. chains and networks of the polymer on the surface.of the catalyst. They are trans- formed into coke. The catalytic experiments were conducted according to.the methods of Ref. 7. Fig. 2 shows the changes of the refractive index of the Card 1/3 Structure and.Catalytic Properties of Chromium- S/020/60/132/92/34/06,7: silica Gel Catalysts B011/3002 catalysates during the experiment,. Tabl.e.1 illustrates the aromatization of:, n-heptaneland cyclohexane under atmospheric pressure. Hence it is clear that the above-mentioned,differbnces in the behavior of catalysts,are not due to admixtures of other metal oxides in silica gel. Table 2 gives data on the phase composition and magnetic properties of the catalysts I-IX investigated by the authors. Hence, these catalysts can be classified into two groups: 1) radio- graphically amorphous, paramagnetic - samples II. and III. The temperature dependence of their susceptibility follows the law of Curie-Weiss - This allowed the calculation of the magnetic moment (3.2~L B). 2) Samples IV_IX are ,antiferromagnetic. k1l. their radiographic lines were identified as lines of Cr203' Sample VIII produced from sampleI by heating in the hydrogen current without alcohol treatment, thus contained crystalline Cr2031 like samples V. and VI. Sample III however, which was produced by heating sampleJI in the H2 current, proved to be radiographically a morphous, and paramagnetic. The authors assume that Cro in.the first case is immediately reduced into Cr2O 3Y and by alcohol treatment in the second case develops some intermediate compound of chromium not affected by air.. This intermediate compound however, produces the crystalline Cr203 when heated in the air.current. This inter- mediate compound possibly is a chromium silicate developing during the alcohol Card 2/3 Structure and Catalytic Properties of Chromium- S1020V6011321021341067 silica Gel Catalysts B011/ .002 treatment of the catalyst. It may consist of non-stoichiometric chromium oxides, developing during the re(ikicti~ar, Qf Q-_Q~."aj Vv% othq~r- mineral acids,. There are 2 figures, 2 bles, and 7 references, 4 of which :are Soviet. ,ASSOCIATION: Institut organicheskoy khimii im. W. D. Zelinskogo Akademii nauk Acade Y of Sciences. USSR) PHSENTED.- January 23, 196D, by B. A. Razanskiy, kcademician SUBMITTED; Janua,r.Y 15, 1960 Card 3/3 5M SOV/20-126-4-27/62 AUTHORS: Kazanskiy, B. A.; Academician, Rozengert, Kuznetsova, Z. F. TITLE: The Effect of Some Admixtures of Alkali Elements on the Properties of Aluminum-chromium Catalysts (Vliyaniye dobavok shchelochnykh elementov na kataliticheskiye svoystva alyumo-. khromovykh katalizatorov) PERIODICAL: Doklady Akadomii nauk 83S11, 1959, Vol 126, Nr J, pp 787-790~ 1 (USSR) ABSTRACT: As is known, the admixture of small amounts of -potassium and cesium to.the catalysts mentioned in the title, increases.. r the output of final p oducts in the reaction of,.aromatizing paraffin hydrocarbons,,(Ref 1). In publications,however, there are no reliable statements on a similar effect of other , alkaline elements. The present article is dedicated to.the latter problem. A description follows of the effects of equivalent amounts of Li, Na, K, Rb and Cs onthe activity of two preparations A and B of the mentioned catalyst, in 0 ~ the reaction of dehydrogenation of n-heptane at 520 . Lithium is ineffective for the increase of the output of aromatic Card 1/3 products of heptane. The introduction of sodium however, raise's SOV/20-126-4-27/62 The Effect of Some Admixtures of Alkali Elements on the Properties of Aluminum-chromium Catalysts 3y 81/4. This promoting effect still the output in both catalysts I increased with potassium (13 and and reached its maximum with rubidium (21 and 1,5%), for cesium it was 9 and 13~fo. The same was observed in the dehydrogenation,of cyclohexane with A and B. There is a great similarity between the effect men- tioned above and that of the same admixtures to catalysts of iron magnesium (Ref 3). If alkali elements are added to the catalysts mentioned in the title, the output of the catalyst increases, i.e. the cracking of hydrocarbons decreases,. This ,-ives reason to the opinion that.there are activecentres in the catalyst concerned which catalyze reactions of crac.k-,. ing and of the polymerization of unsaturated hydrocarbons. In their course they develop carbonium ion, similar to.the clas- sical case of the catalyst aluminum silicate. Such an ad- mixture of alkali elements apparently reduces the "coke," sediment on the catalyst and thus increases..the stability,pf the latter (Ref 4). It is to beexpected that the application of alkali elements will reduce the temperature.o.f regeneration in the catalyst. This would increasb the s tability of the Card 2/3 latter, and extend the duration of their application. On the 3OV/20-126-4-27/62 The Effect of Some Admixtures of Alkali Elements on the Properties of Aluminum-chromium Catalysts other hand, the thermal stability of the catalyst is reduced by alkali (Ref 4). The role of this one part of the effect of alkali'cannot be explained sufficiently. There are 2 fig- ures, 2 tables, and 6 references, 3 of which are Soviet. ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (Inatituteof Organic Chemistry imeni N. D. Zelinskiy of the Academy of Sciences, USSR) 50) SOV/2o-126-3-31/69 AUTHORS: Kazanskiy, B. A., Academician, RoLen6art, W. I., Kuznetaova, Z. F. TITLE: Destructive Alkylation of Benzene by Propane (Destruktivnoye al-. kilirovaniye benzola propanom) PERIODICLL: Doklady Akademii nauk SSSR, 1959, Vol 126, Nr 3, PP 571 - 574 (USSR) ABSTRACT: The reaction of paraffin hydrocarbons with aromatic hydrocarbons , - can open new ways to the production of various aromatic sub- stances, and contribute to clarify the nature of catalytic trans- formations. But it belongs to the most poorly investigated branches of hydrocarbon chemistry. Patents (Refs 1,2) show that_ benzene is alkylated by paraffin-hydrocarbons in the presence of hydrogen fluoride, boron fluoride, as well.as t heir mixtures. The patents state that only such paraffins are'.sluitable which possess no less than 5.carbon atoms in the chain. On the basis of.references 4-9, it was to be expected that toluene wouldi,~,,. originate by the interaction of benzene with differentparaffin, hydrocarbons under pressure and in the presence of nickel.cata-. lysts. Preliminary experiments by the authors have.confirmed this expectation, for it came true with normal paraffin hydro-, carbons (heptane, hexane, butane, propane) at a much lower Card 1/2 pressure (60 atmospheres overpressure) than indicated in' refer- Destructive Alkylation of Benzene by Propane SOV/2o-126-3-31/69 ence 6. The said reaction of benzene with propane was closely investigated by the authors on nicicel deposited on 3iliceous earth. Table 1 shows the yields of "alkyl benzenes", table 2 the influence of temperature on this yield. Table 3 indicates the influence of the duration of test on the activity of the catalyst. Figures 1 and 2 show the fractionation curves o.f.th.e. catalyzates. There are 2 figures, 3 tables, and 11 references, 2 of which are Soviet. SSOCIATION: Institut organicheskoy'khimii im. N. D. Zelinsko.-O Akademii A nauk 55SR (Institute of Organic Chemistry imeni N. D. Zelinskiy. of the Academy of Sciences'USSR) SUBMITTED: March 11 , 1959 Card 2/2 8(2) SOV/32-25-4-54/71 AUTHORS: Buslayev, R. V~~ Lavrov., I. A., Lutsek, V. P., Rozengart, Y. I. TITLE: Impulse Timing Relay for Rectifying Columns (Impul'snoye rele vremeni dlya rektifikatsionnykh kolonok) PERIODICAL: Zavodskaya Laboratoriya~ 1959, Vol 25, Nr 4, PP 493 - 494 (USSR) ABSTRACT: An impulse timing relay was designed for the purpose of auto- mating the removal of distillates from laboratory rectifying:. columns. Impulses may be altered over a wide range, from 40, Lmpulses per minute to one impulse every three minutes, the impulse duration ranging up to 38 seconds. The apparatus is,-, fed with 127 v alternating current. It is 24 cm long,,,15,,cm, wide, and 16 cm high. The relay is actuated through mechanical switches operated by a reversible electric motor which perio- en from~the di--,'it~ ch-angas the sense of rotation. It. can be se schematic -illustration of the rel4.s (Fig), and the descrip- tion that the electric motor is of the.type RD-09, and that an intermediate relay of the type RPT-100 is.used., ThereAs Card 1/2 1 figure. AUTHOR: Rozeng4rt, R. I razanskiy, B-19 A., 20-119-4-24/60 Member., Academy of Sciences, USSR TITLE: Dehydrocyclization of'n-Hbptane on Aluminum-Chromium Catalysts (Degidrotsiklizatsiya m-geptana na .alyumokhromovykh,.katalizatorakh) PERIODICAL: IToklady Akadbmif Nauk SSSR', 1958, Vole 119, ITr 4, 716-719 (USSR) ABSTRACT: The short time of act-ion is one of the peculiarities :of the catalysts in question in the aromatization of' paraffinic hydrocarbons. They must be regenerated: after- several hours since they are deactivated by coaly deposits ("coke"). The authors'6xperimen-ts concernin6 the process.mentioned in the title showed that continuously acting catalysts can be produced which remain active up to 27 hours and have a yield of 67 percentage by weight of aromatic compounds during this period. After,100 hours of action with periodic regenerations the duration C-ard 1/3 of the working period of the catalysts was reduced'to 10 12 hours and did not change during the following Dehydrocyclization of n-Hbptane om Aluminum-Chromium 20-119-4-24/6o Catalysts 115 - 117 hours of action. After 215 - 217 hourr of action the surface of the catalysts was reduced to one third, the volume.of the pores 1 : 1-5. The total yield of the reaction products and the toluene yield computed with respect to the heptane which p9ssed through the catalyst i-s not changed considerably. The experiments with catalysts of different grain size confirmed this assumption. An experimental part follows. From the obtained results follows-,that the-grain size of the catalyst influences the amount of the yield of aromatic compounds. The reaction velocity is influenced by the diffusion of the components of the reaction mixture. Hbnce follows that the heptane aromatization takes place om a promoted aluminum-chromium catalyst in the diffuaianLrange. The influence of the grain size is a general phenomenon (references 8, 9) for several reactions of saturated lirjdrocarbons at the catalystsin question. This is apparently explained by the fact that at comparatively high temperatures Card 2/3 (450 5000) the reaction velocities become.equal or Dehydrocyclization of n-Heptane on Aluminum-Chromium. 20-119-4-24/60 Catalysts surpass the diffusion velocity of the hydrocarbons in the catalyst. There are 1 figure, 2 tables,,, and 9 references,, 7 of which are Soviet. ASSOCIATION- Iftstitut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy AS USSR) SUBMITTED: December 269 1957 Card 3/3 4.7 9 6 9 9 0 9 a a 6 a a 0 9 0 a 0 0 a 9 was fit 40 0 4 0 0 * 0 * a 0 a 0 0 0 074PITi4m .4 1 a I I # is it 11 It w is m it m Is v E F C H I a L a 9 9 9 4 9 9 IF IF a IF a 0 9 9 9 C -4 4 0 0 0 0 a 0-0 ~00' it a u to -1-,v is 0 a 41 a u 1, 4 f It I It 00 ~ . ,ST -- plIOCISS11 W psoprol.1% 00 most of training an the anjount of adenosirmtriphos, clog of rabbits, pil4wous and chickens. lc acid lit the nine - w ill tile all A k 0 . iva ~ C, PhIltic Acid Couttilt of tubbil, pix"'ll and Chickult lullCle Th Ii 0 - e I .1-tvetl Ilmirr the iolluelltv fit truilling. M. outclat i~ Main. id c lulloAmd lac 0 ill TA1.1,11, -IS 1110 721 lit.. uIlve tile "'Illph-liml of "' i d or eu- tile tl,.-wed- its thr u fIlMill, l Iv jaliplr~ Itro 90 90 411 :01- 2 coo - zoo , l e WA 4tTAttURUpC4L UlF..V"9 CL.S%lPlC.TlC- too 0 F t 0.1 -7- itiv V-11 It . I 0 u "A""!; P, (v trip ONK wet ors[ ptult ItK Ar N 9 a a I I v A 0 0 0 010 D 0 0 0 0 0 0 9 0 0 0 0 0 0 0 0 0 G a : 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Gi* 0 * 0 o 10 0 0 0 0 0 a 0 0 0 0 0 0 0 O 0 0 0 * 0 0 0 0 * 0 0 0 0 ' G f I to *all I I 11 it is 14 is It it is 1"I alt nn So IS v a M v it v to " 410 41 a 13 1. ' a U a O~Co -A A I-V v v 7 A -0 L-t-j --Jk 4 M I I Aqjj~$-- T .-!~Al- A"t, 060FINIO(I 1.001 4 .1 -00 Formadon f CtedWoLde from 91 ' '*tnitary Chent-til ,t., to an . t . III-Okho-M-ya I3,3&,,4(l94X).-Thc (OfInAtiOn of creatinine front phosphoctratinc is a spontaneous proc- r5s. an4l is not dependent on any enzynatc system I'M- rut in muscle. In fact. muscle tissue may be absent. The pit can be varied from 5 to 0 without affecting the too 0 0 j rate of cre-Atinine formation in pure soln. XaF increases = Ihe 4!rcompn. of phosphoerratinc in nimscle prepus., thus 0 0 00 forming more creatit4ne. In the absence fit muscle (issue NaF is without effect on the prucess. It. P. I to 0 -a go =0 00 f; -I-WC I'lu b CV au J ~ ~ 0 ', z L , too A S OS L A METALLtWG KAL LITERATtXf CLASSIFKLTICM tso ,VG- 411-ill. 00 SdI441) L. 13- Cat 1 g U a AT -0 It IT it a . a I . A 1 KID n a OT 0 0 00 0000 :4 : : : 00,00 0 0 0 OL9 0 go 1 0 d-GlucosidAse he brain- N. V. K=rashmm bind V., I - Rmcuttatt (%'. M. fickhtcrvv I" vch"t%climl. llt,t,. 15, 1.1;1- is oil"clit III tile fmaill rahloit. .111.1 vAt. It 'tclih, "mWilit'll,o ate Imt timilluillvd. lite illcut"li"ll 4o( lorailt ti-uc with ".11cilk ch" leml to tile t.1 . I lite 11.1ving 1~11 sl3pplictl toy eml. t.katlivultitli; tilimocnimlislus (strclittoemvi allit suphylt,o- Preparation of highly purified liver esteritse. VARozen-, AArl. C. A, Kibarifits. E. I Iteriiardelli. anti P., A~ Finognov. j),.k4jjj acetone J~Iwtfer (.5,41 g'), wlto4r activity %%" 0.7 (units (it rclative activity jWr Ing, of protein). was obtained froin pig liver placed in 400 ml. of 0,0213 N NH.Oll, incubated 0.5 hr. at 35,7'. and filtered through cheesecloth. . This was re- IWAted 2-3 times with fresh N11#01f. The combined cits, 1 :1 L, pit 7.5-8,0. activity 14, were acidified with 0.5 1~ AcOlf to pit 3.5-5.8. lot stand overnight at 3', and filtered. rhe filtrate was neutralized to pit 7 by Nlls()H followed by :91 9. (N'114W. per I(*) ml, soln. anit let stand ovemight. The ppt. was diwarded. and the filtrate. activity 30,'w25 treated with 7.5 g per too nil. and let stand twerstight to give a crunitily ppt. of protein that contain% the bulk of the enzymr, The ppt. W43 C.Itd. rrpratrdly with 45%(Nll.)-.SC). at 1.117.0-7.3. the lantextit. being runover- night near U'. The residua I ppt. was taken up in 10-12 ml. of cold 11:0 (activity 00)a nil dialyzed against cold I fj0 for 48 hrs. The resulting plit., filtered off. yieldsa yellowish soln. o('the enzyme with activity 210-9-10. The,product was tested by elect roplusr";,; . which showed the presence of,:.' components.,one 6-ing present in %mail amt. and nhowing treater mobility. Sample,; taken from electroplioresisexpt. -at varion4 IfIratkin,, showed that the more mobile comp- tient has relatively low protein content (n.21 mg. per Ing,) and ban no enzymic activity. Other fractions Aimed ac- tivity but thin was well below that ofinitial firelm. fion,,ibly 'his wa.%caused bya iossor the prosthetic group tinder the mi. tioncifelce.field. 'rhisiictitifirmmlbytietectionofaininor, vM rapidly rnovifiK cottirtonent ift early stages of clcrtrc~ phore4%. The rui)-tur prepti. showmi max. activity at pil .14-8.5 and purification di~-% not affect thin otitimunt. 0, Xf, Koolal-IT as 'I phos ~h-t .:reference ROZRNGART. V.I.; MASIOVA, M.N. Rate of incorporation of labeled melthioniae in, rabbit. tissue in convulsions induced by 6etrazole and electric. current [With summary- in Inglish]. Diokhtmi is 22 no.'6:947-953 N-D 157- MIRk 11:2) 1. leboratoriya, blok-himii Vses.oyuzno_po nauchno-iss ladova tell skogo sanitarno-khimicheakogo institute Akad,emii meditsinskikh nauk SSSR, leningrad. (CONWISIONS, experimental, off. on methionine incorporation in various organs in rabbits. labeled prop. (Rua)) (MWHION1114B,. 'metabolism, incorporation in various organs in exper. convalsioni in rabbits, labeled prep. (Rua)) fifiaigmimi6" SUB CoDE.-. o6, 07/ SUBM DATE -.,,lID666k/-`-.SOV REF:,..% 03 ,,OTH,REF: 012 Card 2/2 ACC NR: AR6033651 SOURCE CODE: UR/0417/66/000/009/0024/0024 AUTHOR: Rozengart, V. 1. TITLC: Biochemical aspects in the classification of anticholinesterase substances SOURCE: Ref. zh. Farmalcologiya, khimloterapevtichoskiye aredstva, tolsikologlya, Abs. 9.54.149 REF'SOURCE: Tr. Leningr. pediatr. med. in-ta, vyp. 32, 1965, 140-151 TOPIC TAGS: anticholinesterase, biochemistry, neurophysiology, enzyme ABSTRACT: Anticholinesteraaes were classed as "reversible" or "irre versible" cholinesterase inhibitors on the basis of their. -.biochemical mechanisma. Group I compounds form covalent 'bonda between the acyl group of the inhibitor and the nu-1- cleophilic group of the covalent center Corganophosphorual compounds, carbanates) while the nitrogen atoms of group Il coupounds react with the anionic centiars of the sub- strata (quaternary ammonium compounds). [LP) SUB CODE: 06 /WA-50; CBE V0- Q4 Card UDCs .615.785.4 Prote, -act ngtw Lc'surface'-pVt i, ok `~,"41iii-46 ts reaction. w th Tm i~biirate forms 'with-f-the en react with-:OPI This 7,also -~ idadi'~.--to'f' eet-~cara bi i I I id" -~~_t be - hils'-1, fi TIONS A r nauk'SWR~ 0_0 Ye.j.; KttatClj~7-. -ademik; ".P.; GOVOVIKOV, U.N.; GODYNA$ ak ~P,"L'SON, M. Ya. R07ENGART Ye.V. YA KOM1:V , V. Anticholinesterase properties of o-uthyl-S-alk-l ~ y1methyl-thiophospKi- Plates. Inhibition kinetics and structure ol' the active surface of cholinesterases. Dokl. All SSSR 158 no-4:880-883 0- f64- 1. Institut evolyutsionnoy fiziologii im. 1.1-1. Sechenova AN S.")EIR 'i lrstitut eleme-ntoorganicheskikh soyedineniy All SSSR. '.ROZENGART, Ye.V..; GODYNA, Ye.I.,.GODOVIKOIT., N.N.. bss~: (I~itit~A6 of E~6i t;~o6oi?ri;Emic!hebkilch.-'a6y6dinia-i ,of oun 4e cesi,. ompl. . ds,~ 1-80) AUTHORS; ja3~~~~Tayts, N. Yu., SOV/163-59-1-17/50 Sorokin, A. A., Poletayev, B. L. TITLE: Investigation of the Performance.of a Slit Radiation Regenerator (Issied6vaniye raboty shchelevogo radiatsionnogo rekuperatora), PERIODICAL: Nauchnyye doklady vysshey shkoly. Metallurgiya, 1959, Nr 1, pp 80-84 (USSR) ABSTRACT,. At present.slit radiation regenerators are used to, a large extent. They.'are composed of two cylinders. The combustion gases pass through the inside cylinder, the air streams ,through the annular duct between the cylinders. The Dnepropetrovskiy metallurgicheskiy institut .(Dnepropetrovsk Institute of Metallurgy) in collaboration with the metallurgicheskiy zavod im. Dzerzhinskogo (Uetallurgical Plant., imeni Dzerzhinskiy) designed a slit radiation regenerator.for soaking pits. This type of regenerator differs from others described in publications by the feature of being provided with a bilateral heating of the walls. This is accomplished by a'flue gas duct in the inside tube of the regenerator and between the outside tube and the re-eneration chamber. The Card 1/3 theoretical investigation (Ref 1) showed that by this method Investigation of the Performance of a Slit Radiation SOV/163-59-1-17/50 Regenerator of heating the efficiency 6f the regenerator is considerably increased. A test unit vas erected in the above-mentioned. works for the purpose of studying the regenerator in question. It was composed of a furnace with two interconnected chambers, a combustion chamber, and a regeneration chamber. The air supply of the test unit was provided by two VVD-G high-pressure fans with 20 kw electric motors. The slit radiation regenerator 2 with a heating surface of 21.6 m , intended for use with soaking pits and with a rated capa city.of 250o m3/hour of air heated to a temperature of up to 700 0 was constructed of 5.5 mm B1417 steel sheet. The investigations were carried out at different temperatures of the flue gases enterin, the 0 regenerator (varying between 800 and 1300,) with unilateral and bilateral heating and an uniflow direction of the flue gases and of the air. A counterflow arrangement of air and the.. flue gases at gas temperatures of 800, 900, and 1000 0 with bilateral heating was also investigated. V. A. Epshteyn, Engineer, and I. I. Kharybin assisted in the experiments.-It was found that the regenerator tested operates with a high Card 2/3 thermal efficiency within a wide range of gas temperature. Investigation of the Performance of a Slit Radiation SOV/163-59-1-17/50 Regenerator The investigations substantiated the conclusions drawn from theoretical considerations concerning the high efficiency of such a regenerator with bilateral heating. The engineering data obtained for a wide range of flue gas temperature (f rom 800 to 13000) indicate the-advantages of using such regene Irators in this range of flue gas temperatures. The experiments at: the test stand are at present continued. The problem of the optimum flue gas distribution between the inside and the outside duct is investigated. The Dnepropetrovbk Institute of Metallurgy and the Stallproyekt are at present en-aged in developing a multi-tube type of radiation regenerat ors. There are 5 figures, 1 table, and 2 Soviet references. ASSOCIATION: Dnepropetrovskiy metallurgicheskiy institut (Dnepropetrovsk Institute of Metallurgy) SUBMITTED: June 27, 1958 Card 3/3 LICIaINAMV,ju.I., dotsent, kand.tekhn.nauk; TAYTS, N.Yu., p',-if., dokto~ tbkhn. nauk; EPSHTEYN, V.A., .1 zh.- LITOVCHEIUO, Yu.K., i.nzh.,- KHUDIK, V.T., j n k inzh.; MININZON.7 R.D., inzh. Study o If noloxidizing hpating of alloy step-1s. Stall 25 n'o.5:469-- 473 My 165, (MIRA 113:6) 1. Diiepropptrovskiy metallurgicheskiy institut i zavod Dnepro spptss tal ROZENGART. a I., kandjekhn.nauk, dotsent; TAITS, N.Tu., doktor tekhn.nauk., Prof.; SPIVAY,,-E.I.: inzh.; SOROKIN A.A., inzh..: POLETAYEV B.L., kand.tekhn.nauk; KLIMENKO, G.P., i4-,; KOROTATE'VJ, M.H., inzh.; STRUCHMEVSKIYP B.B.Y inzh. Investigating the performance of holding furnaces for nonoxidizing heating. Stall 23 no.9:848-853 S 163. (MMA 16 t 10) 1. Dnepropetrovskiy metallurgiches7xiy institut, TSentroenergochermetl. zavod im. Dzerzhinskogo i Gosudarstvennyy soyuznyy institut p*o,, proyektirovaniyu agregatov staleliteynogo i prokatnogo proizvodstva dlya chernoy metallargii. AUTHORS: Tayts, N. Yu. Doctor of Technical Science, 133-58-5-30/31~ Rozengart Yu I Candidate of Technical- Science, orokin, A. A., ineer, and Poletayev, B. L., Candidate of Technical Science TITLE: High Temperature Preheating of Air in Radiation Recuperators ( VI T -_-okotemperalux odogrev vozdu~lia 1; G ~P~y P v radiaLsionixykh rehuperatorakh) PERIODICAL: Stall, 1958, Nr 57 pp 4/2-11-,-79 (USSR) ABSTRACT: The object of the paper is to olive a theoretical analysis of heat ezchange conditions in radiation - n' recuperators i order to develop a method for their design calculations and the choice of optimal schemes of radiation recuperators for soaking pits. Theoretical equations. forU 'he determination of heat exchange in recuperators are given. On the basis of the equations foLLr different schemes of radiation recuperators are compared: 1 direct current recuperator i,.rith heating from two sides; 2 counter-current recuperator with heating from t-uo sides; 3 direct current recu-Derator with heating on one side and 4 counter-current recuperator whituh hea-tin6 on one side. Card 1/2 It is concluded that for soaking pitus the first scheme 133-58-5-30/31 High Temperature Preheating of Air in Radiation Racuperators is the most advantageous. An experimental recuperator (Fig-7) was designed and its operation investigated. The results of one heati=-5 vrith cold charge 8-re shovin in Fig 8. The preheating of air reached 6~O C and the coefficient of heat transfer 45 K cal/m hi. C. The resistance of the whole air duct at 2r-00 m3/hr was about 450 mm H 0 Some deficiencies in the operation 7ere noted: 'UN.aestruction of welded joints and non-uniform heatin- of the surface of the tiibes due to a non-uniform distribution of air. A second recuperator. is beinG designed in which the above deficiencies will be ~removed. There are 2 tables and 0 figures. ASSOCIATIONS: Dnepropetrovskiy metallurgicheskiy institut (Dnepropetrovsk Lletallurgical Institute), Zavod im. Dzerzhinskogc (Plant imeni Dzerzhinsey) Card 2/2 S/709/60/025/001/002/006 D040/Di-13 Rozengqrt,. Yu.I., Docent TITLE: Uonox-,dizing metal heating in holding furnaces SOURCE: !"--:iuciiro-te!