SCIENTIFIC ABSTRACT RUDENKO, N.S. - RUDENKO, P.

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SCIENTIFIC ABSTRACT
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'WV/1 '59-58 ... C-23/29 DensiLy of the Liquefied Gas aiany timr, o in the py,:,-nome ter. III) e Mj_x4-Ure ondensed unt-il a certain, level was rea,~hed in t-h-It- pymmneter tube, The condensed, mass of the &alution was determized from the difference of pre-Ssuxes be-fore, and after c;ondensatlon from the volumee oocupiedl by the gas and its temperature,, 17-Iie liquid le--rel in the py,:,,-.j.o,,neter and the merz~u_ry level Ln the manometer wers, measur-ed by means of a cathetometer to within 0,1 -rnm,, OxZ~&_--,r. was ob-15-ained by decomposition of pnta.=,_qDjn pezmang-anate-, pure nitrogen was produced by rsmc,-~~al of oxygen over hot ccpper filirnez,; arger, had ~~zf r~.Yygen. 'Phe sclut-ioLL compositions were determined to vri'-hin 0.05,17f-., The 1,yenometer wa~~ by weaå the. density of pure fgen: nirrogen 3rd ari;~ n. Th;E~ largest d- -7- nc-e between t~ae results obtairLr--d a-r- th~--, authc)r-'s pyzricm-~-zer and 4ihose x--ported. earlier (Ref 1, 2,) did no~, excleea 0.25. DensJl-ies of nil;rogeL~ -- -.~xjgen ~zcjutic.ns witil ,3,~851. &3.~F7,. 81,3c: 20.4, 315, and 89 of oxygen, were measured betw,~~A,7.1 ;;5 and 80'7'K-. resui-,73 are shown. -in Table 1. Stmilar measurennn~_,s wsre carrip-a ol it, Card 2/4 for 87.*, 78-5: '---3,2 -SOV/1 Density cf the Li--Uefied Gas Sol- 4.9.1, 3-2-7., 19.,4 anal of the res7i!-, 1 ..., .. s ar~ gi-Ten in Tab le 2, In sOlu--ic'ns f-he -.-OlumaZ are," C, not additive, or, 'he sc-~!.uticv- is no-1: the SUM of t~ie vollumes of The expi-Lrinental (If the A..O~) " 1, -,-. 4-~- 'llose wll-ll:~ll ,an be. exp-,, a cl 1"i-lit' "I~- C'm ,y se ou~,- !'Ale exrps;~ T Measured dsnsit,'es I E ic-nis -a re 1", 1 `:PD r t, han ---,le -u-a !.ue F, C ~2 1 4-.,3 d b::~ 2 i - s c.. dd J t- aai ccUst~'!Tlenl;ly de-p-ar-6ilre froa I-S If 1- E~ c i - r2.,- h,,,,e e r1aa. s n z (a d. !. f IL e n e C', I , ~le; es .1 ame f the L.- u 0' the ib- e t o -c, a!k ~~hem p c ul-Qre abso Df d-' e L S Y L,7Y - the speci-fi.c, t.jnrjir,7 ere.rgd.e3 and tileir s h c J.- la in Caiyl ~51L~ 11-he case and SOM I 30--r-&-.6-23/29 Diansity, of the Llq~uefted Gas SOi`ut'Cn-z- -02~, A-02 the departures from additivit-,, are due t-o -lb-he last ii-wo reasons. There are 2 figures, 5 tables and 13 references of which 5 are ~c-qiet., 6 English and 2 Dutch. ASW(JIATIO1,T:Iqiar'kovskiy Gosuniversitet -Uien.i A . MI. Go r *1 ko g,-, Miarlkov State Universi-ty imeni A.M.Gor"kiy) SfjBi~-IITTED: llth April 1958 Ca v(I 4 /4 65704 10'4000 S(JV/139-59-2-3/30 'AUTHORS. Blagoy, Yu,P., and Rudenko,, N,S, TITLE, Stirface 'Pension Of Solutions of Liquefied Gases N2-021 A-0 2 l'BRIODICAL., lzvestiya vysshikh uchebnykh zavedeniyj Fizika~ 1959, Nr 2, pp 22-26 WSSR) ABSTRACT4 Surface tension of a solution depends, inter alia, on,- the difference between surface tensiojis of the raire components, energy Of MiXing Of the solution, orientation of molecules in the surface layer and forces between these mulf-cules and on association. oz- dissociation of the GOIIS4tituent incilecule, B.Ya.Pine~~: (Ref 1) calculated adsorpt.ion and surface tension of solutions of simple liqui.d.~, and related these quantities to the energy of mixing of solutions., R,,V~Bakradze arid B.Ya,,Pines (Ref 2) show-ed that the formulae ootained describe correctly behaviour of surface tension, of liquid aLloys. The present paper reports initial results of a verification of the applicability of the lines -Lheo.ry to sur-face ten_~-:L.,.)n of N2-0 and A-02 solutions,, These studies covered the Card 1/3 temper,~.ilure range from the boiling point of Ithe I-ilre 6570h SUV/139-59-2-3/30 Surface Terl_,4 jon Of Solutions of Li(JUef ied Gases N'2-02, A-02 con'Ponerits to the temperature of their solidification~ Two methods were used to determine surface tension: capillary rise method (used for' N2-02 solutions, cf Fig 1) -A n d m, -ixiinum pressure of gas in a bubble method (used for A-02 solutions, cf Fig 2). Surface, tension and its temperature dependence were determined on N2-02 solutions with 10, 26, 54~5, 70, 80 and 90% of oxygen, and A-02 solutions -ith 19.5, 31s 47~51 67, 81 and 90% of oxygen. The results are shown in Tables I and 2 respectively. Surface tensions were found to rise linearly with temperature, except in dilute solutions of argon in oxygen (in.these solutions adsorption caused departures from linearity at low temperatures). In N2-02 And A-02 solutions surface tensions were smaller than the sums of surface tensions of the pure components, In N2-02 solutions, this non-additivity was due to noti-additivity of the interaction energy between molecules (the energy of mixing was not equal to -zero) and due to adsorption. ln A-02 solutions) the non-additivity was due to only the non-addiiivity of the energy of interaction of molecules Card 2/3 (the energy of mixing was positive). The results obtained 65704 SOV/139-59-2-3/30 Surface Tension of Solutions of Liquefied Gases N2-02, A-02 confirmed the Pines theory, There are 4 figures, 3 tables and 8 references, 5 of which are Soviet, I German, I Dutch and I English. ASSOCIATION,KharIkevski-I gosuniversitet imeni A,M,GorIkogo (Kharllcov State Uni-versity imeni A.M.Gorkiy) SUBMITTED. Julie J-7. 1958 Card 3/3 22 S/056 61/040/003/008/031 B102 B2092 AUT-HORSt Grigorlyev, V.N.9 Rudenkov N.S, TITLE: Density of H 2-D2 solutions PERIODICALs Zhurnal eksperimentallnoy i teoreticheskoy fiziki, v. 40, no. 3, 1961, 757 - 761 TEXTs The influence exercised by quantum effects on the microscopic pro- perties of the substances can be inferred from the physical properites of isctopic solutions. This influence becomes manifest in a deviation from the ideal behavioz, especially in light substances and at low temperatures. From the system D 2-H2 hitherto only .the liquid-vapor and the vapor-solid, diagrara has been studied. The results obtained, however, indicate that the behavior of this Sy%teM essentially differs from that of ideal solutions. B.G. Lazarev, V.S. Kogan, and R.F. Bulatova (ZhETF, 34, 238, 1958) die- V\ covered a stratification of the D 2-H2 isotopic mixture into two phases at, temueratures below the melting point. In this paperg the results of fur-, C,.-jrd 1/5 S/056J61/040/003/008/031 Den:iit-v of H2-D23 C) 1 U t i 0 M3 . . . B102/B202 ther -,tudies of the deviation from the ideal behavior of this isotopic mix- ture between melting point and 20-4 0K are presented. The authors attempted to determine the excess volume of the mixturet 4V - T - (OHTH +- cD VD) where V are the molecular volumes of the solution, of hydrogen and of deu- terium, c the molar concentrations. The measurements were made by the me- thod of hydrostatic weighing by means of spring balancesl the device per- mitted a density measurement with a summational error of (0.1-0.2)%. The measurements were made with temperature increase as well as with temperature reduction in the range studied. The ortho-para concentration of H 2 and D2 corresponded to that at room temperature; no considerable change in the density, as a result of ortho-para transformation, could be observed. Also the HD formation was inconsiderable as was confirmed by studies of the same mixture on various days. The densities 9 of eight mixtures with D 2 concentrations of from 10 to 90% were measured and the molar volumes (V=MIR,ju molar weight) were calculated. The correction for the produc- tion of vapor was 0-15%. The temperatures below the melting point were calculated by means of aft extrapolation formula. The numerical results Card 21-5-.,,ii 2 211 0 31056'16-11040100310,08.1 .31 Durl.-~ity of' H-D -'_101 U!, i C113 ... 31021B202 2 2 are listed in a table. ~The results prove-,the considerable deviation from the ideal behaviorl at all. temperatures studied and all concentrations 3tudied, the mixing volume was negative and of the same order of magnitude as that of the liquefied gases,(e.K., 0 2- Ar or .0 2-N2). The results ob- tained are compared wi 'th the theoretical results by other authors. Good agreement was obtained with dV= AV + 6V and j6VI_PAE t AE ~-AH-ToLAV/P V v W compresgibility of the solutionp 4E excess mixing energy,at constant V Volume) J11 excess mixing enthalpyg o~ thermal expansion coefficient) as wc-ll aa 8V 11 _Fe102(NV1"P2V2)(p1,: WP2) a vinue, close to 1 iSLO1103011-for T instead ')f 0-4 (as given by'Mear3), which, ho'wever, cannot be substanti- . ted. It wa3 fo,ind that the e xpe rimen. tally obi5ervad contraction in the formation of the H -D^ solution cannot be -explained by the present theory. 2 Thera are 2 figures, I table and 1.5 referenabag' 6'-Soviet7bloo and 9 rion7 Card 3/;-,i(/ 221,18 S/05~1-61'/040/003/008/031. Density 6f R 2-D 2solut--ons BII-02B702, kSSOCIATION! Fiziko-tekhaicheskiy institut Akademii nauk TYkrainskoy SSR. (Institute of.Physio3 and Technology of the Academy of Sciences, Ukr,-,inalaya SSR S li-FINITTED Oct-lber 13, 1960 Card 4/5 r k r f V "V STMCTURE AND PHrS[CAL P-RCPERTIES OF MATTER IN A LIQUID STATE renorts read at the 4th Conference convened -in KIYEV from 1 to 5 June 1959 bli h d b s e , pu y the ryublisheir, House of KrZEV University, y-r _yKV~ ussR, 1962 G.S. DEN13C.V and V.Y. ',Hu,,A.-,,ov~q(jY, Spectral Inves- the C)I,rtonyl Group of Ketoncs :-.rd Protot~-donor Mcl,~~Cule3 144 I.Y. 7CLCKH(7VA Arld V.A. GORBUS1!K::KGV"' k"Ifect of tf;,, 'hL tj Deut-rillm on the Cr1t1c;tl Temper,Lture &:,.I Polarization of Y~,lacul,us 14.1 BLA~OY lavi N.S. hZ1F_',X0, Tho Surf-ice Tnnalon -And YLI P . . -ri --- - 1414 ATY 07 i~ljujti_cl Gau _;olutione ~rticl--!3 (if Qp~cial Interent (Lr--t thoac ti~,*I;.nlng on PF 57, 65, 115 rr.1 144 (2) rk::1!'ect'.VC1y. -ACCESSION NR! AP4006SZ4 s/oizo/63/000/006/0093/0094 AUTHOR: Voroblyev. 0. A.; Mesyats, G. A.; Rudenko, N. S.; Smirnove V. A* TITLE: Pulse generator of steep 150 kv pulses SOURCE: Pribory* i tekhnik& eksperimenta, no. 6, 1963, 93-94 TOPIC TAGS: pulse generator,, hv pulse generator, steep pulse generator, pulse structure ABSTRACT: An improvement in the Arkad'yev-Xarks. surge generator circuit is described which permits shortening the impulse front from the ordinary 10-7 to 10-9 sec. Parasitic inductance of the surge generator is compensated by a non- inductive (type KOB-3) capacitor in each stage and by a special 150-pf noninduc- tive capacitor conne cted across the test piece. The latter capacitor is briefly described and its design sketch is given. The conventional output sphere gap is replaced by a needle gap to suppress'oscillations. the most stable switching is Card Card 1/2 RLAGOY, Yu.P.; RUDENKO, N.S. Density of solutions of liquid gases N2702i Ar-02- Izv.vys.ucheb.zav.; fiz. no.6:145-151 159- (MIRA 12:4) 1. Eharlkovskiy goouniversitet im. A.M. Gorikogo. (Gases--Liquifaction) (Specific gravity) AP6000190 SOURCE CODE: UR/0056/65/049/005/1394/1.398 AUTHOR:. Rudenko, N. S. 30 ORG: Tomsk Pojytechn1c Institute im. S. M. Kirov (Tomskiy-'pdAitekh- nicheskiy institut) TITLE: A new method of high voltage supply to streamer chambers SOURCE: Zhurnal eksperimentallnoy,i teoreticheskoy fiziki, v. 49, no. 5, 1965, 1394-1398 TOPIC TAGS: particle tra ck, particle detec.tor, power supply, spark. chamber ABSTRACT: To increase the brightness of streamer chambers and facili- tate the photography of the tracks, the.author developed and verified. experimentally a.higb voltage supply for a streamer chamber, making possible production of narrow bright tracks with good stability. The tests of the power supply are described elsewhere (Izvestiya VUZov, Fizika v. 4, 178, 1965). The present article consists of theoretical calculations and an analysis of the experimental results. The brightness (the number of ionizations in each Individual streamer) is increased without a substantial increase of the dimensions of the ionized region by applying a series of alternating-sign pulses after the main pulse on Card 1/2 __XCC NR: AP6000190 the chamber (this procedurevaB suggested by G. A. Voroblyev in a ori- vate communication). The test procedure and apparatus are described in detail. Particular attention is paid to the gradual transition from the tracking mode tothe projection mode, when high-quality tracks can be obtained with almost the same size and brightness of the luminous centers (6 = 1-2 mm) in the directions along and perpendicular to the electric field. The experimental results are in satisfactory agreement with the calculations and.it is concluded.tbat the new.power supply., yields good tracks more consistently than when single high voltage. 'pulses are applied 'to the cha mber plates. Author.thanks G. A.Voroblyev 'for continuous interest-in this work and for a discussiori of the re- Orig. art. bas:'2 figures and 1 table. SUB CODE: 20/ SUBM DATE: 26may65/ ORIG REF: 004/ OTH REF: 003 d .2Z2 7 ACC NRI AP70076t7 SOURCE CODE; UR/O386/&6/oo3/OO2/OO6l/OO63 AUTHOR: Vorob y vo G. A.; Rudenko,, N. S. hni al Institute im. S. M. Kirov,.Tomsk (Politekhnicheskiy institut) ORG: Polytechni TITLE: Isotropi~ spare chamber ~SOURCE: hurnall Z eksperimentallnoy i teoreticheskoy'fiziki. Pialma v redaktsiyup v. 3. j!4o. 2, 1966, 61-63 TOPIC TAGS: spark chamber, charged particle, particle track, particle trajectory i4 ABSTRACT: The authors propose a spark chamber with:three mutually perpendicular'pairs 1:6~ electrode places in order to register in spark form the track of a particle moving ":i~i,,in arbitrary irection in space. A pulsed voltage of fixed duration and amplitude 'i lied to ea4h pair of plates and a time interval is established between the' As -.,app -izigvint of termilation of the voltage pulse on the first pair of plates and the fz~if-int of applic~ation of the pulse to the second (with a similar time lag betwedn fig iiicond and t" pulses). In this way theelectric field in the chamber revdrses .:Its direction spaice three times. To explain the operating principle of the chamber,. three possible'drections of the particle track are distinguished: 1) The parti6le-. track is incline4 0* - 45* to the direction of the electric field of the first plate. pair. In-this arigle range., a pulse appliea to the first pair of plates'produces a spark that follc~s the inclined particle trajectory. The second and third pulses Card 113- UDC: none ACC NRt AP70076t willexert no greiat influence on the already-produced high-density plasma, becciuow of their short d ation and the short time delay relative.to the first pulse, so, that'the par~ticl density in the plasma will not drop noticeably during the time-of ac-Cf8n of these lses; 2) The particle track is inclined 0" - 45* to the electric fi6k'of the see plate pair. Application of the first pulse produces a.colUM4 I0?,Wya,lanches (a in a streamer Lchamber) along the particle track. At the same tLime, a ditage pulse this duration and wnplitude is perfectly adequate for production of".a~spark If th particle track~coincides with the direction of the electric fiqld. When the second pulse is applied, a spark is produced along the particle track. jn 14'b:~s case the co~lditions for spark, production are better than in the firstP since the interaction b~etween neighboring avalanches is made much stronger by the larger n~hber of charged particles in each avalanche than in the.first case; 3) The particle track is inclined,O* - 45* to the electriclield of the third set of plates. The first voltage pulse acts as in the second case. The second pulse develops the already~produced avalances in a direction perpendicular to the first. The third voltage pulse produces the spark along the particle track. The experimental setup is shown in Fig. 1. A voltage pulse with rise time 2 x 10-9 see, obtained with the aid of a special generator,:is applied to each pair of electrode pairs a separate by cable. The cable lengths were chosen such that the delay between pulses was 50 nsec- The dura+ion of each pulse was regulated independently by means *of itbree discharge, gaps (nitrogen, 10 atm. pressure) placed at the ends of the lines ahead of the eldetrode~.'L plates. The electrode plates were insiilated from each other by inmersion In trarieformer oil in a Plexigla~ chamber with double-walls. -An external air-filled chanber cmitaine Cr2rd, 2 /1 'ACC NRt AP7007 7 L D t7 LI c ~3 Gen. start. Fig. 1. High-voltage-supply Ao spark chamber. 0 f- cutoff discharge gap, CC - coinci- dence circuitv OC - spark chamber. a glass chamber f~lled'with neon at 760 mm Hg. The dimension of the glass chamber was 10 x 10 x 10 cm. The field intensity was -15 kV/cm. The authors thank Corresponding member,A. I. Alikhanyan and Professor A. A. Vorobtyev for interests and collaboration.on thisIvork and Engineer M. I. Kozlov for assistance in carrying out the experiment. Orig. art. has: 4 figures. SUB CODE: 20 SUBM UTE: 150at65 CRIG REF: 002 OTH REFs 001 -Card- 313 IF ACC NR CA (;ODgj--UR/6o~6/66/040/008/1969/j969-1 Af>7oo4667 AUTHORt Rudonko, N. S.; Konareva, V. G. ~ORGt Physicotechnical Institute, Academy of Science6p ElkrSSR (Finiko-takhnichookiy iinstitut,Akademii nauk UkrSSR) :TITIZI Viscosity of liquid deuterohydrogen .SOURCEI Zhurnal fizichaskoy khimlip v. 40p nos-8# 1966# 1969 iTOPIC TAGSt liquid hydrogen, deuteriwn, fluid viscosity, deuterium compound !ABSTRACT: The viscostiy of liquid deuterohydrogen RD was measured in the 16.7-20.40K I Irangs. Fig I shows the dependence of the viscostiy cooffioient of RD (and also D~ land H? for ;omparison) on the reduced temperature. Values of the viscosity ooeffi- cients at several temperatures are given belowl I t' -K 16.0- 17,0 IS10 19,0 '200 I 1",C08 338 321 284 255 23 11t in apparent that the viscosity of liquid HD lies between that of liquid H2 and 1!L- quid D~. Although the viscosity of the liquid isotopes Increases with their mas5s no isimple relationship was found between mass and viscosity. Orig. art* hast I figure. Card UDGs 541oll ~ 77 --- ~11--. RUDRIKOY N.S. Method for obtaining a bright and well localized particle track in a streamer chamber. Izv. vys. uclieb. zav.; fiz. 8 no.4:178-179 165. (MIFA 18:12) 1. Tomskiy politekhnicheskiy institut imeni S.M. Kirova. Submitt,ed March 13, 1964. L 328-66 EVIT(M')/-PF(c)/E'dP(t)/EWP(b).-~-.-DZAAP-/-IJIP( ACCESSION NR: Apwnio6 iiV665 /6~/CWOO/047/ AUTHOR: Rudenko, N. S.; Konareva, V. G. TITLE: hydrogen isabope solutions :SOURCE: Zhurnal eksperimentaigno3r7teoreticheskny fiziki, v, 49,:no. 2, 1965, 44T-448 gas viscosity, viscosimeter.,.bydrogen deuterium TOPIC TAGS re 1ABSTPACT: This is a continuation of earlier woroeZbM v .38, 2700, 1964), whe measurements of the viscosity,of H2-D,2 solutionswere reported. In the present ~investigation the authors used a capiLW7 viscosity meter, described by,them. else.. ~where (ZhFKh v. 3T, 2T61, 1963) to measure the viscosity of H2-1iD and E)-D2 solu-'. 7i tions in the entire range of concentrations: it, t~mpeiatures, 15--20K. In all the' investigated solutions, the dependence of the viscosity coefficients on the cdhn- ~L .centration had the same character and the summary viscosity coefficients.were, rsmaller than the sums of the viscosity coefficients of the~individual compone~ :The deviation of the viscosity coefficients from additivity is found to be related with the mmss differen e of the components.of the solution. Ox-U. art. has: 2 !~figures and 1 table. Card 1/2 0, 901 r ?S- ------------- Card 1/3. fp - ; i- V PUDENKO, N.E.; puic,.= c-l ,trey, gt (YT Z~.ur. tek'-4 f'jz. 134 IRA Y"i ro',ra, ornsk. :ACCESSION KR: AP4040312 8/0057/64/034/006/1079/1082 ;AUTHOR: Rudenko, N.S.; Tavetkov, V.I. ,TITLE: Investigation of the impulse dielectric strength of several liquids ISOURCE: Zhurnal tekhnicheskoy fiziki, v.34,,no'.6, 1964, 1079-1082 ITOPIC TAGS: dielectric strength, dielectric property, liquid dielectric, capacitor ~ABSTRACT: The impulse dielectric strength of tap water, doubly distilled water, ~glycerino, and ethyl alcohol was measured at gap lengths of 5, 10, 25, 50, 100 and i500 microns and pulse durations trom 0.1 to 10 microsec. The measurements were undel- ~taken primarily to evdluate the liquids for use as dielectrics in high voltage 'pulsed'capacitors. A single stage pulse generator producing rectangular pulses with! ~amplitude up to 20 W and,a rise time of 0.01 microsee was employed for the measure- :ments at gap lengths up to 100 microns. For the 500 micron measurements a five stage ;pulse generator was used which produced up to 100 W pulses with a rise time of 0.1!-- i I .microsec. Molybdenum electrodes 0.45 mm in diameter were used for the measurements ;at 100,microns or less and L5 mm diameter steel electrodes were used for the 500 ,micron measurements* The gap lengths were measured to 0.5 micron with a 120 power Card 1/3 am A-1-cx5sli.W lip; AFlulVJL4 ;ACCESSION KR: AP4040312 S/0057/64/034/006/1079/1082 ;AUTHOR: Rudenko. N.S.: Tsvetkov, V.I. ;TITLE: Investigation of the impulse dielectric strength of several liquids ;SOURCE: Zhurnal tekhnicheskoy fiziki, v.34, no~.6, 1964, 1079-1082 itor ,TOPIC TAGS: dielectric strength, dielectric property, liquid dielectric, capac ~ABSTRACT: The impulse dielectric strength of tap water, doubly distilled water, iglycerine, and ethyl alcohol was measured at gap lengths of 5, 10, 25, 50, 100 and j500 microns and pulse durations from 0.1 to 10 microsec. The measurements were under- ;taken primarily to ev4luate the liquids for use as dielectrics in high voltage ;pulsed capacitors. A single stage pulse generator producing rectangular pulses withl ;amplitude up to 20 W and a rise time of 0.01 microsec was employed for the measure- ments at g"p lengths up to 100 microns. For the 500 micron measurements a fire stage !pulse generator was used.which produced up to 100 W pulsea with a rise time of 0*11- :microsec. Molybdenum electrodes 0.46 mm in diameter were used for the measurements ;at 100 microns or leas and 1.5 ma diameter steel electrodes were used for the 500 micron measurements. The gap lengths were measured to 0.5 micron with a 120 power Card ACCESSION NR: AP4040312 Imicroscope, and the electrodes were reconditioned after every 10 to 21) discharges. For each overvoltage the probable breakdown time was obtained by averaging 10 to 20 ,breakdown.times by means of a Laue curve (M.Laue, Ann.Phys.76,261,1925). The diaper.-:, sion of the breakdown times *decreased with increasing overvoltage. The dielectric strengths increased with decreasing gap length as well as with decreasing pulse'du- -ration. The curves of dielectric strength versus pulse duration were all convex to both axes, and their bonds were rather sharply marked for the longer gap lengths. For ~ given gap length the bend occurred at about the same pulse duration (1.5 micro see for the 500 micron gap) for all four liquids, and at shorter pulse durations for., Ahe shorter gaps. This suggests that the breakdown at high overvoltage involves i spanning of the gap by a charge avalanche. The dielectric strength continued to de: :crease with increasing pulse'duration over the full range (to 10 microsec) investi gated. The authors suggest that the breakdown at long pulse duration is due to a .thermal effect arising from the high conductivity of the liquids. The most suitable! .of the liquids for use as pulsed capacitor dielectrics are doubly distilled water and glycerine. Such capacitors should be pulsed for one microsecond or less.* " In ,conclusion the authors express their gratitude to O.A.Voroblyev, candidate In tech- nical sciences, for.suggesting the topic, for his Interest in the work and for dim- ,cussing the results." Orig.art.has: 2 figures and ltable. Card 2/3 "'R ACCESSION AP4042374 S/0056/64/047/001/0092/0096 AUTHORS: Grigor'yev, V. N.; Rudenko, N. S. TITLE: Surface tension of liquid isotopes of hydrogen and of H 2 D solutions 2 SOURCE: Zh. eksper. i teor. fiz., v. 47, no. 1, 1964, 92-96 TOPIC TAGS: hydrogen, deuterium, surface tension, deuterated com- pound t%BSTRACT: The. authors hope to resolve the discrepancy between the theoretically calculated and experimentally c~bserved relatively large decrease in volume (-I%) upon formation of solutions of hydro- gen and deuterium, which cannot be explained .,.,ithin the framework of the simplest theory, by obtaining information on other properties f 0 'L solultions of hydrogen isotapes- :ExpenrL-Liental data are presented on tha temperature dependence of the surface tension of hydrogen, 1/6 ACCESSION NR: AP4042374 deutorium, anj doi-iterohydrogen, and solutions of hydrogen and deu- terium. To permit coMpaZ-1so-11 With calculations base-4 on the quantuxa theorem of corresponding states, the authors first determine the Sur-, face tension5 of the pure isotopes. These measurements are of in- c-,ependent interest since the published data on the surface tension of hydrogen are contradictory, thus cast'ing doubt oft the data on R11-lich were measured with similar install~_tions. The pro- cu-dure and equipment used to measure the surface tension of the pure isotopes of hydrogen were described elsewhere (V. N. Grigor'yev, Z'hETF, v. 45, 98, 1963). The same equipment was used for the solu- tions of hydrogen and deuterium. The method of preparing the solu- tions and of measuring their concentrations was the same as described~ bv the authors elsewhere (ZhETF, v. 40, 757, 1961). The data on the surface tension of hydrogen agree well with the results obtained by Kamerlingh-Onnes (Comm. Leiden v. 13, 142d, 1914) while the data previously obtainod gor doutorium by Van Ittarbook and VAn PAOM01 (Physica, v. 7, 325, 1940) are approximately 5% too high. The Sur- 2/ 6 ACCESSION NR: AP4042374 face tension of the solutions was found to be several per cent loweri ~than the additive values, in qualitative agreement with the theoreti-;~ cal calculations of I. Pirgogine (Molecular Theory of Solutions, Amsterdam, 1958). "The authors are grateful to 0. N. Grigorlyeva for belp with the measurements." Orig. art. has: 3'figures, 1 formula,., ~nd 2 tables. ASSOCIATION: None SUBMITTED: l8Feb64 ENCL: O~3 SUB CODE: NP UR REP SOV: 004 OTHER: 009 ACCESSIGN NR: AP4042374 ENCLOSURE:02 Surface tensions of hydrogen and deuteriun solutions Ad T, 'K Ou"/" Ad % T. 'K Ad' % CD.- 7,2% 32.8% CD . 19'Or" 2,72, 2,5 J 20.44 1,q8, 1,4 20.42 2,31, 2,9 19,39, 2,82, 2 7 i9'98 2,044 1,9 20,4t 2,31, 2.9 18,94 2,91, 3:2 19.66 2,11, 1,0 20,4t 2,31, 2,7 18,40~ 19,28 2,193 1,2 19,27 2,53: 2,4 18.93 2,91, 2.8 18 82 2,25., 1,0 18,86 603 2 .2,4 17,93 - 18:48 2,3 16 18.25 2,70 _ 17,34 1823 2,35, 1 .18,48 2X4 - N 77 17: D4 2,40, 17,92 2,76, 0:69 (continued! on enc'lo sure #3;) Card 5/6 ACCFZSICN NR: APh042374 ENCLOSURE t Oy, CD.= 15,2% CD.=38,6%. CD,= 74, 1 % 20,44 2,09, 1,2 20,45 ~2,34, 3,2 .20,44 2,8%. 3,2 20.43 2,IN 1,0 20,44 2 373 2.6 20,44 2,89, 3,1 19,61 2,24j, 1,1 20,46 2:37o 2:t 20,43 2 90a 2,9 19,17 2,31, 1.3- 20,41, 2,364 2,5: t9,99 2:97, 3 1 18.80 2,38, 0.8 20.43 2,35, 3,2 19,91, 2, q8s 3:3 18 35 2t453 20,39 2,39, 2,1 19,39 3,10 3,0 17 2,577 20,32, 2 393 2,6 ' 18.96 3,18, 19,46 2:3.1, 3,2 18,56 31243 CD. = 23,6,% is, 8j- 2,63, 3,6 18,42 3,29, 1 43 W 2 19 2 3 18.40 2,761 - 18.14 3.30 , It 1 20 a , 2 20a , 2 0 17,21 2,921 17,8i 3,37, , 20,08 , 2,26, 1:8 17,14 2,95& CD.= 82.3% 19,/,S 2,37, . 1,8 = 49,90% CD 20.38 3 ON - 3.3 19,43 2,38, 1,8 . .20,36 3:01, 3,2 .18,69 2,594 1,4 20,46 2 62 6 7 19,48 * 3,173 4,2 1808 2,624 - 20 4/is 2:62. 3:2 19. 17 3 241 4,2 17:47 2,71 - 20:44 2,63 3,8 IS 27 3:40t 16,44 2,86, 20,43 2,C>4--. 4,0-. 17:9 .3,47, (continuation of enclosure Card 6/6 ~YPENKO) U.S.; KOUAREVA~ V.G. Viscosity of liquid hydrogen and deuterium. Zhur. fiz. khim. 37 no.12:2761-2163 D 163. (MIRA 17:1) 1. Fiziko-tekhnicheskiy institut AN UkrSSR. GRIGORIYEV, V.N.; RUDENKO, N.S., Density of H, - D2 liquid solutions. Ukr.fiz.zhur. 7 no.7: 737-739 Jl 192. (MIRA 15:12) 1e Fiziko-teknicheskiy institut AN M-.rSSR, Kharlkov. (Hydrogen-Isotopes) (Solution (Chemistry)) (Densitometers) RUDENKOj N. V. Cand Chem Sci -- (diss) "Alkylation of benzene and Its substitutes lrj alcohols in the presence ofi,alumosilicate catalyzer#-Mn r atmospheric pressure." Mos, 1959. 9 pp with graphs (Mos State Univ im. M. V. Lomonosov), 150 copies (KL, 48-59, 113) -12- 5 (3) AUTHORS: Turova-Polyak, M. B.; Rudenko, 5. V. SOV/20-126-6-40/67 TITLE: Alkylation of Benzene and Some Substituents by Isopropyl Alcohol Ci,er e.:-. A:_umin~ -silicate Catalyst at Atmospheric Pressure (Alkilirovaniye benzola i yego zameshchennykh izopropilovym spirtom nad alyumosilikatnym katalizatorom pri atmosfernom davlenii) PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 126, Nr 6, pp 1269 1292 (USSR) ABSTRACT: With the increasing importance of the alkyl products the sub- ject mentioned in the title becomes more and more interesting. The catalysts mentioned in the title are widely used, the al- kylation in the vapor phase in their presence, however, is still insufficiently investigated. The authors investigated the al- kylation of the following: benzene, toluene, phenol, chlorobro- mo- and nitrobenzene by isopropyl alcohol. They obtained A) Cumene (yield 79%) (source for the production of phenol and ace- tone, Ref 1)IB) zymol from which also styrene homologues (mono- mers for the production of artificial rubber) (Ref 2) may be produced; C) alkyl phenols (washing agent), phenol formaldehyde- Card IA -resins, initial.substances for frostproof rubbers, Ref 3); D) ~,i srd Som-3 Subst-ituents by SOV/20-126-6-40/67 llc~)Ihrl Over c~!. Catalyst _ao -P ~i c- c' r e a a i. r L! iiatogen aubotituants of benzene (aemiproducts for various syn- ~h,t,aaa. eapecially production of halogen-aty renes? Ref 4) etc. The yields of the latter were: isopropyl-bromine-benzene 69%, ufflol 79%, ieopropyl-phenol - 81% and isopropyl-chlorine-ban- _'Onq 611% of the amount of alcohol used for the reaction. Nitro- ben,!ene could not be alkylated. The activity of the catalyst A roximately i nimains eu"fickently high for app 9 hours (Fig 1). Thereftre ,he oatplysts mentioned in the title are suitecl for &Ikylatioa be-iauae of the simple regeneration and their anti- eox-.ro&ion pri--per-ties. The results obtained by the authors con- -ern4n.g the thaxacter of the functional groups in the benzene Cycle, th'e temDerature at which the reaction is carried out, th'_: of the supply of the reacting componentesand their xatlo agre,~, trell with the theoretical principles. The prvat-n~e of toluent, in alkylation products besides p-zymol and ia in oontradiction with the data on the mainly orient- the methyl group in an o- and p-position-The in- ~,L-rre-',.j,ti~or~ of the products of normal and anormal orientation Re ti) on the alkylation conditions. The higher the A;~'!l'triin of eo-v! Soxe Stibitituent8 by BOV120-126-6-4016( Catalyst of thc- 'italyet, the duration and the temperature of t"i-Le stronger is the tendency towards a formation m-derivative. The mechanism of the catalytic of thc, a~-omatia compounds by alcohols has not yet It~flaitely di."Iermined. Various considerations on a possible 6 12 anat..t,.~;n -)f thk.L3 mechanism are given (Refs 7, ;log 04,15). (1), and (3) describe the general mechanism of The authors carried out the alkyla- in Iti(i prpaince of 100 ml globular alumo ailioate for I - a", 200 - 3500. Figure 3 shows the optimum yields of i'.jxo1q .propyl-ahlorobenzene, isopropyl-bromobenzone; end Figure 4 shows the dependence of the L tbe r:OotAty ofthe supply. In all eases the redue- t"~n 'tf Thl -z,,>ncantration favored the increase of the y1all cf aon-~61kyl produ--is. The structure of the alkylation pr~A;2-'ta Nara !I-nfirmed by the production of derivatives in SOMA. U$1~5 aleD apo;~IrosuopP:ally. There are 4 figures, I table,.and *:6 1.0 of which are Soviet. Alkylation of Benzene and Some Substituents by SOV/20-126-6-4o/67 Isopropyl Alcohol Over an A!-,in.lno-jilicate Catalyst at Atmospheric Pressure ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova (Moscow State University imeni M. V. Lomonosor) PRESENTED: March 4, 1959, by A. A. Balandin, Academician SUBMITTED: March 4, 1959 Card 4/4 5.3400 77357 sov/79-3o-1-18/78 AUTHORS: TLIrova-Polyak, M. B., Rudenko, N. V., Ling Li-tang TITLE: Catalytic Alkylafton of Phenol With Isopropyl. Alcohol PERIODICAL: Zhurnal obshchey Ichimil, 1960, Vol 30, Nr 1, pp 94-98 (USSR) ABSTRAM The effect of the hydroxyl group on alkylation of phenol was studied. The optimum conditions of the reaction over altunino-silicate catalyst are: temperature; 210-2300, and space velocity of reagents, 0.2 hr-l. Increasing the concentration of phenol tip to 20 moles per 1 mole ot' alcohol decreases the yield of diisopropylphenols and increases the yield of mono- Isopropylphenols up to 81%. Recycling the unreacted phenol raises the yield of monoisopropylphenol to 95%. Increasing the concentration of alcohol in the reaction mixture facilitates the formation of dialkylated prodLICt3. The obtained monoloopropylphenol consists primarily or the.para lsomer with can admixture of the Card 1/4 ortho isomer. The act1v1ty of catalyst decreases Catalytic Alkylation of Phenol With 77357 Isopropyl Alcohol SOV/79-30-1-18/78 Card 2/1~ sharply after 19 hr of use, but it can be fully regene- rated b~ treatment with a strong stream of dry air at 500-550 . The mechanism of the~alkylation is explained by the formation of carbonium ions, which alkylate phenoL '112~(' _C113 + 11+ (CCIt) ~ G113- Off C11/113- _CII/CH3 -\CIJ3 '\CI13 + W 10 Ho/C The fractional distillation of the obItained product produced se~6ral fractions. One of them, bp 124-124.30.V mp 15.50, n D 1.5282, was o-isopropylphenol. Reaction of o-isopropylphenol with manochloroacetic aced yielded 0-isopropylphenoxyacetic acid, mP.131.5-132.5 Reaction of o-isopropylphenol with potassium persulfate produces a blue solution, which is characteristic of Catalytic Alky-lation of Phenol With 77357 Isopropyl Alcohol SOV/79-30-1-18/78 20 o- 1,9opropy I phe nol. The frL otIon 1211.3-136.80D 110 I" 1.52'(.1. yielded o-Isopt,opylphenol, 'ID 1.5280, by 1'reez- I% ouL, and a ~jmall arnotitiL ot' p-loopropylphenol, mp 6o . The fraction 13668-137-30 yielded crystals of p- isopropylphenol, mp 60 (after recrystallization from alcohol) on cooling. Reaction of p-isopropylphenol with monochloroacetic acid yielded p-isopropylphenoxy- acetic acid, mp 81.5-82-30, and with benzoyl chloride, its benzoate, mP 71.2-72.20. When an alkaline solution of p-laopropylphenol was treated with potassium persul- fate, an orange solution was obtained, which is charac- teristic of p-loopropylphenol. From the fraction with bp above 2 0, a 2,4-diisopropylphenol, bp 144.5-145.60 (20 mm), n~oi 1.5120,was obtained. There are 7 figures; D 33 references, 9 Soviet, 18 U.S., 3 U.K., 2 Japanese, 1 German. The 5 most recent U.S. references are: Jordan, T., Vapor PressLLre of Organic Compounds, N.Y. (1954); Sowa, F., Hinton, H.,J. Am. Chem. Soc., Card 3/4 Catalytic Alkylatlon of Phenol With 77357 Isopropyl Alcohol SO-09-39-1-18/78 54, 3694 (1932) f1an3ch, C., Robertson, D., J. Am. Chem. Soc., 72, 481o 4950); sowa, F. c . Hennion, 11. F., tlicuvd,-nc~ J., J. Am. Chem. Soc., ~7.0 7Q9 (1935); Garponter, M., Wood, T., Easter, W., J. Org. Ch., 615 (19511). ASSOCIATIONs Moscow State University (Moskovskiy gosudarstvennyy universitet) SUBMITTED: January 12, 1959 Card 4/4 TUROVA-POLYAK) M.B.; RUDENKO, N.V. Catalytic allcylation of bromobenzene with propyl alcohols. Zhur.ob. khim. 31 no.6:1982-1985 Je 961. (KM 14:6) 1. Mbskovskiy gosudarstvennyy universitet imeni M.V.Lomonosovae (Benzeni) (Propyl alcohol) 37636 S/07 62/036/005/011/013 Bi 01 Y-11 10 ,.U 1, E CS Oreshko, V. F. (Deceased), Gorin, L. F., and Radenko, N. V. 7 Composition of the products of starch radiolysis 17 C D I C;11:, 1hurnal -t*izicheskoy khimii, v. 36, no- 5, ,962, 10C34-10 5 starch --'h t~ co.,:%,cosizion of obtained by irradiating potato 00 Mlois:;Ure) Co (doses, 12-100 and 20-106 r; dose rate, _i:,) in sealed 6lass ampoules was investigated by chromatography. /Z-- r Hasu_ts: (1) 'I'he gaseous products of radiolysis contained neither CHr'. nor Co. (2) 1! and CO viere formed in a ratio of 1:1, which indicates 1 2 2 t'-e "-estruc:ive cleava6,e of the glucopyranose rings, resulting in the ~3i-_ation o-f Penioses and formaldehyde. (3) The following mechanism is 51;1-c,~Zzed --5*or the cleavage: (a) The terminal glucose rings are split off Uo fo= rentoses and formaldehyde; (b) the for-maldehyde is oxidized to fox,mic acJ d by the oxygen in the ampoulei (c) the formic acid decomposes under the e:['fect of gamma radiation in H2 + CO 2' There is I table. Card 112 sj/076/62/036/005/011/013 C o S -Z or o f e products B-101/B110 T S'S' 0 C 1 AT i ON tekhnoicgicheskiy institut pishchevoy pronyshlannosti (Moscow Technological Institute of the Food Industry) SU ~:.i -7'TT-',-'D: Aucus t 11 go, 1 Card 2/2 777. BABIN, Ye.P.; RUDENKO, N.V.; .1 IDORENKO, L.M.; BORODINA, Z.S. Effect of the temperature on the composition of cymene 'fractions during the alkylation of toluene by catalysts based on aluminum chloride. Zhur. prik:L. khim. 38 no.5:1185-1188 My 165. (MIRA 18:11) RA 171. 91 i~ V3K ORESHKO, V.F. (deceased); GORIN, L.F.; RUDENK0, N.V. COMPOBitlOn Of the gaseous products of a starch radiolysis. 2hur.fiz.khim. 36 no.5ilO34-1085 Yv 162. (MJRA 15:8) 1. Moskovskiy tekhnologicheskiy Institut pishchevoy promyshlennosti., ~(Starch) (Radiation) (Gases--Analysis) 19 Phyalcocham kml s~rv and N Z R Lin t, I z.. Ostov on );;) t:~ . C CO on). bly a. 17164g =I)d~U l .W1 teal L: t 4 yst"n (il 47 the sansexnG lhlhe I Pd -W- % Coomfw has * Th -P- COIN has At abou 4 twx at 43 ' . are 214hti ~ 4 at". lkt 50 it 133 . e 120 and 1,M-,rv slightly v botherms at co"vex to the COHIPO. axis is Indica6v, o( th which b , ,C 120-110 vex to the campa 1 an 10fiection 1 d Wicalk Th 6 . e a en C* of a Chem. compd. at these or does the tLmp . coca. of q In this ran =e 2 COMM temp Th e I , of 0 mol. : ~= COMM. The ~t 136 than h Curve of t* " arw Similar I-P qt . . & ed. IS the 11 Curves, a ad the ejec. 30the-s have the same shoj* cond- W faml " to the ,~. And . cuely 0( g curves besides, 2 'Mini, has a ruts. at 63 mm . n1 imns am . t he ,jnmefi'y MI.- Curves -1 -v and o( the tem& coeff. of . show n f rn1s. (2) 1. tile system O(N (01,Z~ul , Ijo s. (2) 1 , a in" The At &) % cu torn IT., ha --I. % at A CO(sif rv" of Coe a "1" 136% but h II. c 1, forrm a 1:1 comp'l and 133* have wAx , the R isotherm at 120 at 62.6 and &s in 0l Th of g has 2, it Vt-11101, no -'W %- T-b, 2 tninju,. n4 he 7'be t11 ilish" -( 'h e curve of the temp c0eff, of , has a-U%mZCOa(t'r)O l p The Plots 0( the d - * am str h e P- caeg is it" ,, "0 mw- evidently, A 1. OMZPd a g t lines. The g ij;tj 120* has a Min " At About 62 at it" branches iz; It nmx. a t 33 CO(NH. ~. And on, .1 . - but the Max. dim At 135 1. UW nd, I, flection pain Ppears. The 49 curves have' t b at a out 60 ,W. an bil and the LM . coff. has a m&x- at th& Point- U. bid. If t g 39-05-0 In the famed by wfth and D. B. Nor. obskcjw 2- =!"a S l ww h lab o e -C t r y The viscmity, d.. and cle tcmwemstudkd*tJ2O.I35,sndlW*: urea-benswcAdd Cb~aU&l Abst. '(I), urea-Sallcyclic acidy). The dw. cond. of the systems. ures-,anthmallicaM( ).wssaIwstmd&datllA.l3D.awd 1101. 48 145*a to 1. the vfxxxdty sbowed a single am. at 00 Md. 120* the smom l e U d 70 (JAW) Apr. 101 1954 i % on& . % urea ( ) an , mounced Ybeosity max. occurred at approx. 0%. I n Ge"rel MW nw 0&1 mistry,, I end U. the temp of wwo P The the 50% region. callrecomen.range. 1"I. fww" z (W..ky Itimmes 1". 84 50% with me elec. cond.) had a to a. sm ekber Wde.: i : yb l w " me We %wn. o lusymmul VX was &am. at ' -- -- - ~ - I ke , ,, n - - lion of the empd. CO(NHOrQH&~Wis Qb;zwim Two compds. evidently fwm in system ff: CO(KNO)r- ' COOH I (OH n . C~HAOMCOOH mad 2MNHsVrC4H4 ) , M, an acid-base reaction Is Indicated. Frek"VA besting of equimalar mixts. above 150* Rif.. am al difficultly W. subsIante. D. misch RUDLPITKO, N.Z.; DIONISIYEV, D.Ye. Physi6oche~ical an&lysis of binary systems formed by urea and aliph.,.,tic acids. Zhur. Iob.khim. 23 no-5:721-725 My '53. (IMI-RA 6:5) 1. Rostovskiy Gosudarstvenniy universitet imeni Y.M. Molotova, Laborat 0- r*a organicheskoy khimii. (Systems (Chemistry)) (CA 47 no.17:8494 '53) l.; T RUDMIKO) N. Z. ussRI Chemistry Reaction processes Card 1/1 Pub. 151 10133 Authors Rudenko, N. Z,., and Diomayev., D. E.. Title Reaction of urea with phenols investigated by~the physico-chemical analysis methods. Part 4. Periodical Zhur. ob. khim, 24/8., 1327 1332,p August 1954 'Abstract Systems formed by urea and p-nitrophenol., o-nitrophenol, 2.4-dinitrophenol 2.,4,6-trinitrophenol were investigated to determine theeffect'of position and number of nitro groups in the phenol molecule on the nature of its reactions with urea_ The viscosity., density, electrical conductivity and fusibility of the investigated systems, were,determin'ed, Cleavage was established in two of the experimental systems. Ten references: 7 USSR and 3 German (1906 1953). Graphs. Institution State University, Rostov/Don Submitted February 17., 1954 lInteractiou of acetamide with soin Ali hatic dils its studied by the mZ~to ph emic in XqS. kudeako. Z. K. L)zhclom 2 D. E. Dionts'er zhur. Ur')~R"'i In, K 1; Z'-" vab I ri,,,ri propertv fiagrani5 i,ere detil at -,0*, W!'. and IXY f- hmar' ,stems kith -X,011. F'rCCI,14. Ar-.Co..H. 1 -1 41.0 01, in rIpLci 1.) in p . d i,casitv. and cond -,;III , 0. ..,It gTapilicalhr. Indicate r1w --xi,renc-f,-fu- .', I, hr liqlml Slate it. r '-frifin aKr'~e. with A- 11, .,)H kcNH-PrCO~I.Ii, AcNll, \,I,(-'O,H. and -\c- ".J C.1 47.9494d- t, NI K 01\,00 am yffft of wtems~ formed -by Z ObskAd KAim, 25,' g 7 . R. 25, 24P H C .4 . 415, 601$g 47, PAN& -M-p 6 NHth--QHr()Il. - r: I 'If 4ygtCMS M 11.4 MINH, 1,-_kfcC,H,OlI grapt ...... fly COCNI'l- it, fiagram which ag"es with rv~silti F P,1-11in ;.nrl V -sig (CA. 22, 4336); viscosity ccurvr_n pa~ r igh max. at 715 mote-% CO(NI40i; n,, sirig.larit,. In this gystem, t: -incd t 2 C0(NH,,)--C"`HjOH coinjid. The ,w ,s ,,f ; ,, " r CO(,'*b)-2_C..1IOH shows mtnplrx compd. , fl !,.Itt.~" ., ,Vitli eut'~ctics at 105* and 104*, composed of, ; In ind 42.5 mole-% CO(Mlli)j; the compound , " ; 2(2-C,,Jl,(:)II) has m.p. niax. at 108*; viscosity ---45') pav; through a max. at 75 mole-O' CO- O ,-inrtng the rN,,mble existence also of " . CO( NT)7- j .1fr(M. "nd. Ur~ shiww, ii. slntguk~ity, the -&me 1 Th Nll f CO ,)r-- 111114r, trite kt d. curves. e Srstem o ( k I 'j--, ., -.1, . diagram w iich agrees with thl of Puschin el ai. (ti. above). but a conclusion as to Immibic ,-r,tLwf fwmation cannot be made. Curves of d., cond., m'! i-t,,wv do not indicate clearly any compd. formatiou; w) i h 1l h l S , curve s in-i o t a s tape (very s -nd, i it -it ti-ir .10%; at Inwer temp the curvature is I rd, III,, (I,-" in y be caused by a~sociatinn of cres,4. G. M. Kosotapoff__ DZHRMf,WOVA~ Z.K.: RUDENKO, ll.Z.; DIONTS7YEV, D.Ys. PlWaic*chemical ntudy of the interaction of aretmide with certain sromAtic acida. Zhur.ob.khim.26 ne.5:1322-1326 my 156. (MLRA 9:9) I.Restovskly-nA-Denu goxudnratvennyy universit,-t. (Acetmide) (Acida. Organic) I-OT D-j Interaction of 'Redtamitio ~ith.~ no as wdih b, - I , 'TI~1-1- oc XMM cal methods of PhYsTc yats. -.1nuft- M. P -tikF and D- '14" 1 n U, Pr!~ ii~~V A k-'1'qzr , I ----D .on). Zhur Oh~hrlm 1866-7 cf C.A. 50, 143:37a.-The thermal curve of the sy%tern 0 ' AcNHrPhOH showed a compd. AcNH2.2PhOH, in. 42.5 , and entectics, tn. 29' with 55 mole % amide and m. 30.2* with 10 mole % amide-, vigcosity-telmp. curves of the sys- tem are convex toward the compri. axis and the d. curves are concave; Loud. reaches a tnau. at DO mote 0/0 amide at 8,55*. I'lie therinal curve of the syswn AcNIfrpyrocatechol has a eu tectic at -10 [note % amide, tn. 26% and transition point at 37.6% at 74 mole % amide; viwosity and d. curves are concave to the compni axis; cond.shows a max. at 80 mote % arnide. The therinal curve of the AcNfT.-r-.*orcinol system shows twerystallizable.inelts in mid reghm and glass ,formation; viscosity curves are. convexto the compu. axis, and the cond. curves'are;sligfit[3~. convex. The thermal curve of the AcNHvhydroquinoneqystem has a eutectic at -J.- 65* and 83 mole % amide, transition point at 100* and 60 niole % amide; the vi%cotsity =ves are convex to the compti. axis, whereasA. curves arc-, concave to this axis; cond. curves are convex to the axis. Thermal curves of s~-dtcms of AcNHI~%kith-.3--isoinctic.,nitr -ophenols raVC:L ' cutectie with ortho isomer at'ZO.5* and 15 mold % amide, 1. 1 4-vin pd. with - the- meta isodier, m.- 43.1 d an cutectics at 47' and 69 mole % timide, aAd 47.8'and 38.5 mole amide; - with the pa~ isomer' there forms a 1: d., M, 05', and cuiectics at 65* arid 67. mole antide.:atict 78*. and 29 mole- % amide. ~.The-SyAem AcNIII-2,4-dinitro- phenol has a eutectic-at 76 mole % amid---, tn. 60% with: AcNff-2,4,6-triaitrophcnul thm is a e tectic at 70 mole arnitlei m. 30', anda transidon. point. in. MUS*,at ;) mole - Idic4tiall of an: incongnientl, nelthig % amide.: with h y I In- !A 4 ~- i 1E, I f V, 1'. 1ITl,.ZK. ;2-UD Y __ F! -U TOPAL, N.Y Pli,;,,--,'cochemical analysis of the ternary system urea naphthol - acetainide. Zhur. ob. k~im. 34 no. 3:?31-734 Mr 164. (MIPk 17:6) 1. Donetskiy reditsinski-y instititt i Dtnetsko, otdeleniye ~L ye lps'ituta organicheskoy khimli AIT UkrSSR. BABILM, Ye..P.; MARSH'rIJPA, V.P.; RUDENKO, ?I.Z.; BORODINA, Z.S.; SIDORENKO, L.M. Kine~lcs of the formation of isomrs of isopropyltoluenes in toluene alkylation by propylene. Izv.vjs.wheb.zav.;khim.i lrjiim.t--kkt. 6 no.5:787-794 163. (,MIRA 18:142) 1. Donetskiy meditsinskiy institut i Donetskoye otudeleniye instituta orgariicheskoy khi-nLLI AN UkrSSR. SHEYNKMAN, A.K.; RUDENKO, N.Z.; KAZARINOVA, N.F.; LYSENKO, V.B. Structure of quaternary salts of 4-(p-dimethylamInophenyI)- and 4-(p-dimethylaminostyryl)pyridines. Mur.ob.khim. 33 no.6-1964- 1969 Je 163. (MM 16:7) 1. Donetskoye otdelenlye Institute, organicheskoy khimii AA UIcrSSR i Donotskiy gosudarstvennvy meditsinskiy institut. (Pyridiniurs compounds) 5W SOV/79-29-5-66/75 AUTHOR: Rudenko, N. Z. TITLE: Reflection of Picrate Formation in the Curves of the Ultraviolet Absorption Spectra (Ob otrazhenii obrazovaniya pikratov na krivykh ulttrafioletovykh spektrov pogloshcheniya) PERIODICAL: Zhurnal obshchey khimii, 19591 Vol 29, Nr 5, PP 1716-1724 (USSR) ABSTRACT: Under investigation werethe UV-absorption spectra of picric. acid, pyridine, p-toluidine, urea;.-furthermore picrates.of pyridine, p-toluidine, urea, at different concentrations in, three solvents: water, ethyl alcohol and carbon tetrachloride. The spectrophotometer SF-4 served for-the investigation. The picrate formation is such that the absorption curves found do not coincide with the curves according to Beer's law. Number and position of the points of importance do not change. The st.i-,.agest deviations occur in the shortwave range of the spectrum;they are the larger, the smaller the polarity of the solvent is. There are 9 figures and 12 references, Card 1/2 7 of which are Soviets SOY/79-29-5-66/75 Reflection of Picrate Formation in the Curves of the Ultraviolet Absorption Spectra ASSOCIATION: Stalinskiy gosudarstvennyy meditsinskiy institut (Stalino State Medical Institute) SUBMITTED: February 11, 1958 ;L U D E -SMA/vith, Addo/by-matb 6 of c HaRk 'k State unly., 5W5d*- R rA~M,-Thecompn.-pmpertvdkgmmswere- aced lor the'tMems fwmed by bimry mbrts. of Ph- WICOXH# *oit (ftN-H)*CO on one hand and AcOH, Pr- COO, AWCOIH, CIMMIL CCIsCAH, BzOHr an& PHOUC"Wouthedther. 7ueWopertksxtwUcdtndudc4 *t .,-And awr m o4 "toto ri M of 4q, ty DO* Xov _ t - thosik PrCalmd m- contc. C19W I lodk4to the "Wence of futovxtion between the com- W IF its.- *s'vho*oLby.slhjWv joints oq_thC~mves. Ph- OH__ 12- t VO-M h t rMCOKH A ic % c r ". em p , as A eutect a AeOK M 80, the P l " t W% A60 hNHCO1MrFrCO&H- system has a 74, PhNHCONH nd a m. - a ep ec r i AmCOJI system hu a etttectle at 00 i6ir % RCOX, m. 49 Cl N l 9D CO H h - CHjCQjK-Ph N H ; mote % RCCW m. 41.5*. and and 50 mote KC0,H; PhNH as a eutect e tit j a trandtfou point ot 701 CONHrCCLCOIH eutwtk Is at 80 mole RCOA in. 34'i and the tnmsitfou- voitit Is p~j P. 71.51. 0. M. Km*poL at 50 tnqj~yq (YI _~!77 USSR/Thermodynamics. Thermochemistry. Equilibria. Physico-Chemical B-8 Analysis. Phase Transitions. Abs Jour : Ref Lhur - Khimiya, No 8, 1957, 26176 Author :Z-K. Dzhelomanova, U. Z. Rudenko, D.B. Dionis'yev Title - :Study of Interactiorf'617KE-655iEde with Some Aromatic Acide by Method of Physico-Chemical Analysis. Orig Pub :Zh. obshch. khimii, 1956, 26, No 5, 1322-1326 Abstract :The fusibility, viscosity, density and electrical conduc- tivity of the systems of acetamine (I) with benzoic (H), cinnamonic (III), salycilic (IV) and anthranilic (V) acids were studied. A compound of the composition 1 : I forms in the system I - II. The composition of the incongruently melting compourd in the system I - III is 1 : 2; the eutectic point corresponds to 67 mOl-% of I and 560; the transition point is at 56 mol.% and 700. The fusibility the system I - V consists of two branches cros- curve o~ sing at the eutectic point (68 mol.% of i and 480). The presence of chemical interaction is assumed on the basis of the curves of electrical conductivity. Card 1/1 XMIX0, 0.; CHAUV%ZATA, K. [Chaievallca, U.], red.; LEPCHMO. K., tekhn.red. [In the Dnieper reaches] Na plesakh dniprovykh. lyiv, Derzh. vyd-vo polit.lit-ry UM, 1960. 30 P. (MIELA 13:5) (Dnieper River--Navigation) RUDENK0, O.A.; IZRAYETSKAYA, N.N. Orbit slements nf 16 r3steore. Astron.tsir. no.202:19 Je '59- (IffRA 13:4) 1. Odnnskaya astronamicbeekaya observatoriya. (14ateors) S/169/62/000/002/0r-.1-4/072 D228/D302 kUTHORS: Kramer, Ye. N.t 4UjgLhg_ ~~. and Teplitskaya~ R. B, TITLE: Calculating the elements of the geocentric orbit 0 .'I meteors PERIODICAL: Referativnyy zhurnal, Geofizika, no. 2, 19612, 3~ at-. stract 2G16 (Mezhdunar. geofiz. god. Inform. byu.1.,- no. 3, 1961, 71-78) TEXT; The method used at the Odesskaya astronomicheskaya observa-- toriya (Odessa Astronomic Observatory) for measuring meteor pho-, tographs is stated. Schemes are given for calculating the radiant cocrdinates, heights, speeds, arid braking of meteors at different po-ints on their trajectories. These magnitudes are used as origina-11 quantities for calculating the atmosphere's density and temperatur-, i,n the meteor zone (a height of 70 120 km). /'-Abstracter's noten~ Complete translation.-7 Oard 5; SIO 35/50/000/00 6/0 2 -P/0 3 8- AOO 1/A00 I Translation from: Referativryy zhurnal, Astronomiya i Geodeziya, 1960, No~ 1"), P. 66, 5319 AUTHORS F!ad-~~ ~~ka, C. A , 7 lzrayetskaya, N. N. TTILE~ Orbital Elements of 16 Mrs-talors FERIODICAL-.~ Astr-~n. tal:7kullyar, 1959, lyunya 5, No. 202, p. 19 Rad'szntz and elemen's of the or-bits of 16 meteo-rs are presented Tm. which were photographed at the Odaesa Obsematory in 1957. Translator's This lz the ftill tz~anslatior. of 4-he original Rus-zi-mn ""ard !,/I BA-BLNEO , P. ; FISIr-R, L. A. ; RUDIE'r.-O , P. This is most important in educational work. Sov. profsoiuzy 17 no.18:21,S 161. (MIRA 14:8) (Community ccntcrs) Orade unions) RUDENKO, P.; Cl1WOV. A.Ye.; SACIEKOV, S.T.; MARDYYEV, M.M.; SOKOLISKIY, I.Ye. Throughout the Soviet Union. Veterinariia 36 no.9:92-95 S '59. (MIRA 12:12) (Veterinary medicine) ZABROT)SKIY, A.G.; SMIRNOV, N.K.; Prinimali uchastiye:,-RUDP~~Q,.,,,R4.; FILIPENKO, I.S.; SEMENCHENKO, A.D.; KORCHEVSKIY, M.I.; TEMASHIrM, D.S.; MARTS, S.F.; BRITSKAYA, Z.A.; RESHETOVA, L.N.; SHAKHOVA, V.A.; DANILENKO, P.L. More about the effect of the amount of water and of its automatic proportioning in the boiling to pulp of raw materials. Trudy UkrNIISP no.5:13-20 159. (MIRA 16:11) 1. Vashkovskiy zavod (for Rudenko, Fillpenko, Semenchenko, Korchevskiy' Temashnyuk, 9hvarts, Britskaya). 2. Chernovitskiy spirtovyy trest (for Reshetova.. Shakhova). 3, Ukrainskiy nauchno-issledovatellskiy institut spirtovoy i likero-vodochnoy promyshlennosti (for Danilenko). M&T S/831/62/000/008/012/016 Z/ E032/E114 AUTIIURS: Kramer, Ye.N., Teplitskaya, R.B., Rudenko, O.A., I zraye t skaya, N. N. , and Vorob I ~ TITLL: Photographic observations of meteors of Odessa SOURCE: lonoafernyye issiedovaniya (meteory). Sbornik statey, no.b. V razdel programmy MGG (ionosfera). I~Jezhduved. geofiz. kom. AN SSSR. Moscow, lzd-vo AN SSSR,-1962, 75-96 TEXT: The odesskaya astronomicheskaya observatoriya (Odessa Astronomi.cal ()bservatory) has been carrying out photographic observations of meteors from three points,.namely, Mayaki (A), Kryzhanovka (B), and the Botanical Gardens.(C). The base-line lengths are AB = 44696 m, AC = 38622 m, and BC = 1302 m. Each photographic installation consists of four "A109 -3C/25 (NAFA-35/25) cameras (F = 25 cm, D:F = 1:2.5, field of view 39* x 530). At the 14 point A on e of the cameras is pointed towards the zenith and the remaining ca meras point East. South and West at angles of 35*~ to the ,vertical. T he photographic cameras at points B,and C are set up so that the common region for all the stations is at a height of Card 1/3 SA31/62/000/008/012/016 Photographic observations of ... &03Z/EI14 ~ el 60-100 kiii. All the cameras are fixed. Time markers are produced by a variable shutter. Observations carried out during 1957-1958 ~show that the NAFA-3s/2j cameras are riot sufficiently effective for V meteor astronomy. They have inadequate objective resolution and are subject to mechanical vibrations which give rise to defocussing. The vibrational effects were later localised and isolated. The photography was carried out -on type AK (DK) films (sensitivity 300-350 GUST units). The development was carried out automatically.. A calendar of the observations is reproduced covering the period July 1957 to December 1958. A detailed algebraic scheme is out- lined for the determination of the coordinates, heights* velocities and decelerations. Estimates are also given of experimental errors in these quantities. In a typical case the errors in the height, velocity (at 54.15 km/sec) and deceleration (at 15.2 km/sec2) were found to be 1 0.09 km, 1 0.42 km/sec and 1 2.6 km/sec2 respectively. The magnitude of the meteors was determined with the aid of a special apparatus producing an 'fartificial meteorlt. In addition comparisons were made with the diurnal motion of stars (cf. preceding abstract). The atmospheric density was calculated Card 2/3 5/831/62/000/008/012/016 Photographic observations of ... E032/EI14 from formulae r-eported by L.G. Jacchia [Technical reports nos. 2, 3 atid lo (Ijnrvard reprints meries 11, nos. 26,: 31 and 44 res pect-lvely) Detaiiaa -nu-mertcal resijILAs ail're reprodticed. Altogether 106 baeAs 1kne phatagret-phs were obt&jnoid, 23 of' which word recorded at all three points. A detai-.Led catalogue in reproduced showing the geocentric and heliocentric elements and other information for Ib meteors recorded in 1958- There are figures and 5 tables. Card 3/3 KRAMER, Ye.N.; #UDENK0, O.A~; TEPLITSKAYA, R.B. Calculating elements.of the geocentric orbit of meteors. 14--zhdunar.geofiz.god no.3:71-78 161. (MML .1/,: 10) 1. Astronomical Observatory of Odessa University. (Meteors) RMS-1,MN S/035/62/000/004/024/056 AOOI/A101 AUTHORS: Kramer, Ye. N., -f-u~~~ eplitsk4a, R. B. TITLE: Calculation of geocentric orbital elements of meteors PERIODICAL: Referativnyy zhurnal, Astronomiya i Geodeziya, no. 4, 1962, 66, abstract 4A552 ("Mezhdunar. ge'ofiz. god. Inform. byul.", 1961, no. 3, 71-78, English summar-jj TEYT.- The authors describe the methods of measuring meteor photographs,. employed at the Odessa Astronomical Observatory. They present schemes for calcu- lating radiant coordinates, altitudes, velocities and dragging of meteors at various points of their paths. These quantities are adopted as initial data for determining density and temperature of the atmosphere in the meteor zone (70 to 120 km altitude). AuthorV summary [Abstracter's note: Complete translation] Card 1/1 -19~ M s/16q/60/ooo/oo6/ol6/021 A GO 5/A 0 0 11 Translation from. Referativpyy zhurnal, Geofizlka, 1960, Mo. 6, P~ 182, 6770 f~-,denlkc, 01, A., lzrayetskan, N. N- T-ITU: Elemezt.2 of the Orbits of L6 Meteors PFRIODIrAL, As-!~-c-n. t-=Irkulya:c, 1959, 5 Irmya, Nlo. 20.2, p. 19 lhE radiants and elements olf the orbits of !6 me"4-or-- azs pn~zent~-d, whl,~h were photographed by tllar- azt:ronoml.:2a.1 obse-xrvatary at Odessa in 1957. The ba2is isnigth was 38 Ion, 'The photographs were takm during the ~il,3ndar-d msteor Patrols wlt~lh an obturator of variable aestlcn~ ans.ato-'.~ Th.'-s 4 'r ths f~ull translation of the orllginal Fu-slan a'~:S trac-t. Oar-d !/I ~7 1 U-65. R 4 1 A CC S 10 N NR: AR4o 9322 meteor. observations bare presented in-,the form of ta6les and graphs;-,~hese resu I ts:. colncide~wlth data from rocket measurementsj~r heights of:8 c e~ 5-95 kn.,'-- The iietl I escription 9 ves a d of amethod for determining thip,:Olfgh 'e of:a: 'dteor:.us In t~tlm m an obtu rator with a bi Blbll A t: varla e,cross'sectlen ogiaiphy,of-31 ems Babadzhanov. SUB.CODE'. AA 00 , , ~;- --," : -7