SCIENTIFIC ABSTRACT RUTOVSKIY, F.K. - RUTKOVSKIY, V.YU.
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Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001446210005-8
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RIF
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S
Document Page Count:
100
Document Creation Date:
January 3, 2017
Document Release Date:
June 21, 2000
Sequence Number:
5
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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CIA-RDP86-00513R001446210005-8.pdf | 4.18 MB |
Body:
RUTKOVSKIY, F.K.; GRIBK5V,SKIY, V*P.
Density distrIlluation of intense radiaticn I n an a!Lzrrb-;ng speci-
Men. Zhin'. prikil . spek-L. 3 no. 1:32-37 i1 165. 18
RUTKOVSK F.K.; GURIYARCRIA T.K.
Yj,
Density distritrution of pimping radiation in a. trigonal rod.
Dokl. AN BSSR 9 no.6:364-366 ja 165. (MIRA 18:9)
1. Instill,ut f-Lziki All BSSR.
5~--Wk(lk
m
fktc~k~ 2/VkEr.-O~)-~2 i h G
AP510 .0037
ACCESSION NR:
M/00-1190
53
K-~TSGR.' Rutkoviktrij. Kof-Grib
are=
TITLE: Distribution of density of intense ta&ation in an absoibing sampl
SOURCE: Zhurn&l prikladnoy spektroskapiij Yo 3# no* 1p 105P 32-37
25 on intensity distribution;,.
TOPIC TAGS: laser MW, laser UaViati
light energy density
ABSORPTION: The authors derive an integral equation for the density of 11
ght emn
gy in a laser rod of arbitrary geometrical form vith an absorption coefficient
depends on the irtennity of the exciting light., and give numerical results for a
cy1-'ndri,&,l roe. The calculations are carried out for tvo extreme casen, when the
exciting lig1r, outside the diffuse,, or- when, al-I the rays.
opagatc perptni"LexClar-1- -th e.s'- w-kice':
r 9 e-~sid s.-~--..The bleaching of 1 6 substa66
p
the ac'-f i
.-(sn- of Wenwi,~ i4diAt Ault p e-d e
tak- - -----
_U
tioLs cf the liert penetrating, into. t e r -~Lre en ntoacco=. -Zie--'rez its-
are used -:;o feymaate a simple method for determining the parameters of
such aL a ensure uniform excitation of the meftum with ininirnm therma,! stresses
and rv,!r-:-unn temperature gradients. "The authors thank S. T. lqsak T,?r performing
the computer CLIMAIStlions# Orig. art. has: 2 figures and 11 formiUas. j02]
rd
a T
7 F71
I W-F.
t" "L 62252-6
ACCESSIMF
nonig:
&SOCIATIOM.-
-Ounc= Lf
I= 00
'REP "Sov:i
moi 0o6 40
ATD
_3
-'A
itrn
i-card 2
PC
P
P(e 1 E. YOMM-1/9W,
818 rr (m
ACCESSION NR: AP5037694 6 0061036
AUTHOR* Rtrtkovskiyv F.,,~ K. Gury6Kdvjji - -----
7
TITLE: Distribution of: ump r ation dens-Y n a trihe'dral r-od'.-.--.
p
SOURCE AN BS-SR. ~Daklacl1y,
ser*- serlr6d-
TOPIC- 1aseri---ve6dymium 1i I' er-model
aser- q I
_,oi
N , ---* - ,- ti---
-can f.arbit the-~ r a
ABSTRACT: Although laser -rods bA. 47!
tribution was hitherto investigated only in iism int-41indiic -"'r a
The present study is devoted to a tribedral prism, a shape proposed occasionall~y to
A. --;M- 4:1k ~A--- 4-u,.a-
c
its faces and intlitmirif; the corre di ~~--In e.
cal computations were with the d of an electronic computer. P17ots are
presented of the distribution of the relative pump rad&atlon density In one-sixth
Iof the normal cross nection through a neocbmiium glaps*riw& The results show that
in the absence of absorption the radiation denalf-y-To evenly distributedp and in
the presence of absorption it decreanes towards the center of the rod. Mkximum
density is observed tit the corner of the prismj, owing to the decrease in the op-
-COAL
~ -
, - --- -, ., . . . , ., -
-THO- mr.sov:~!,
-,,W2.-,
Ri-11KOVSKEY, P.K.
D.L.3trIlbution of dlffu~e drm~it.y j.n a homogei-eous isotropic
absorbine medium.. Zhlxr.rrl~kl. SP;~3k,. 2 no.~',:30',7314 Al) 165-~
. . . . . . . . . .1,
L -iL I
-a t"LLE
IM,
.6�0-6
5
ACCESSICK Nit. APS020801-1
111VO048/66/029/0W/13G9/ 373
--9ribkc tz
AUMOR:' Am~~skl~ vskIyjVaiW;-1Mrsv
Trm.- Density distribution of diffuse exciting light in a luminescing specimen
IRep2rt, Thirteenthl'.oaference'on Luminescence held at Khar'kov, 25 Jim to I July,
196Y
SOUHM:-: AN 8SSR.-Isivestlyao'S,firly'a fizichaskaya-i -'ve' 29
rpti6h
TOPIC TAGS I laser light::-.absp iub~
WF
ABSTRACT t=-The-authc rs -have- d -a ou ated~-t e-.--'lntens ty'p- a
rom the ixid- of. an", Ti~~ R i:. wit
distance r-. f nf "Itely &r-. cy. "er,
-'iefracti.v6 on-coeffi ,
c nt. -~k~j.,. ated' n- A:-, ield diii e'
have -dhecked-~.thed
jL-resu ta7b ex erlmentd nds
M-H-ri-P
4! ;- ---amouiRtiv- b'
different sizes contaird ng d f erient
L ofi-a sorbent-dye* e investigatiowL-~`4
was undertaken because of its technical interest In connection with laser do
Calculatioms were performed numerically for several values of n and kk both for
cylinders with polished walls and with diff usirk-, walls , and the results are
,Pre-
sented. graphically. For cylinders with polished walls the intensity is almAst
Independent of r- fox, it certdi:~ -94r-4a ued-,.
7-7 7 `7
n;
0~~' 4:4 1- 7~-LZ.71~ =77L v- -
Nlio W.
MR
-7,
ARS020801,
L3ai~ ka -the i~~ Idcwaal
Ott
h i-it i~
For cylinders with diffusing walls t i ecrqases..wi~th ecreas UU
CalCUILtiOng were also performed In which the variation Of k and n with frequency
was taKen Into account. Resiults are presented for a material with a single
:Lorenttian bbsorption line in a radiation field Of which the Intett9ity is Inde-
3~;
!pendent of frequency.- and for a ruby cylinder in 8000K black-body radiation. The
experiments were performed on cylind r9 with radii from 0.75 to 1.25 ca and absor
P
tion coefficients from 0.02 to 3 cm-,, using monochromatic light from a mercury arc*
The means used for measuring the luminous intensity within the.cylinders are,,not
an ;-ylt
described. r/R les's th
The experimental results agreed with the calculations for
0.6. For larger vaLues of r/R the measured Intensities were up to 25% higher than
the calculated. This in ascribed to total reflection from the wall of the cylindere,
Or1g. art. has: 8 formulas and 3 figures. 15
ASSOCIAMM instii;.ut ffAki-_. AkAdemii nauk BSSR
Sciences, BSSR)
SUMUTTED 1 00 SHM: 00
aNO REP SOVt 003 Rot 006
Cord 2/2
(Institute of Physics AcrxdeW-l
7,
P(
6-39554-5 M/ ~X?
2ML
/65/920/008/1~69/13173"4 2
ACCMSICK MR: AP500,10801 VE00
AUTHORS QrIbk0vskIg#V#PoQ[tsVtsovj .4,~
T ITLE Density distribution of diffuse-e iting'.light In a juminescigg sjj4etmsjj:~~
xc
/Report, Thirteenth Conference-on-Luminescence hold at KharOkov, 25 June to- 1. Juily-~-.
T96g
F,
7- 7 4-,7-1 7,-j
M
IL
__965 1369- 373-ra~f
SOUWEt AN SSSRa I:rvestiya*'. Seriyst- fix ~c eskays i'~v 29 no*' 6'
ffus
-TAOS* -laser '1i
ght 6b s or
TOPIC V., - 1 9: ,
~7-
-T -h e cula`"~~_l
THICT: he-'authOrs cid~' :t 6-- ntens ty-of-th adiAi at~Lth
-ABS on.
0-T
distance r from'the axis-_of-.'&W infinitiily.-Iong7.-bijrcular.Icylinder,,.'Of.,-rtidius,:R,-, with-
t q;
n-' diff
r4f'ractfve.4ndwe~n, am abs-orption-coeffic but k,. ocated I' of
esu 8~
o and av -~ehecked-thelr,-r_ A th~p
-radi i -.h e t I i ciiinde
Jast c-
-dye*' The-inve
different sizes containing different-am- I absorbent
was undertaken because of its technical interest-in connection with laser designe,
L
Calculations were performed numerically for several values of n and kR both for
cylinders with polished walls end with diffusing walls, and the results are pro"
_1?~ -
sented graphically. For cylinders with polished.walls the intensity-is almost
depend ng on-n.;-.foro all-i --vilues
independent of r for a cortaiii.-vilue '02,k]WI I-
--~~77F-7777-. j
67
-xit1liLde i bec iu ai_:i
_kR-the Antensity.- norea, cress rwzr__ se-of-r6 ract heS
rs with diff using--viAll I ecreases with decreasikn
s_tbe.Jnten9ity~La,_vays
For-cylinde
'
_
. it: with frequency -
Lso performed.in w ch-t
calculations were v~ hi he variation- of-k and
as taken into accolint. RAults are pre'sentied for - a- materi al wlth:.a single-_
w
Lorentiian -hbsorption line. in a radiation field of which the intensity to Inde-
pendent of frequencir,* ahd for a-ruby cylinder in 8000K black-body radiation.
on cylind rs with radii from 0.75 to 1.25 cm and abs
experiments were performed
tion coefficients from 0.02 to 3 ci using monochromatic. light -from a mercury -,ar6
The means used for imeasuring-the luminous-. intensity within *the cylinders am, not.
described. The exlxirimental results, agreed with the calculations for r/a less than
O.G. For larger valLues of r/A the measured intensities were up to 25% higher than
the calculated. Thl.s is ascribed to total, reflection from the wall of the cylinderi. -
[15 1
Orig, art. has: 8 J~Ormulaa andi-figur Be--
Jnstittlt-f nauk--BSSR-(Institui~_._ oiiii .ca
-ASSOCIArION:
Sciences, BSSR)
SUBMITTED: 00 ENCL: 00 SUB CCDH.::CC_
.,ATD
NO REP SOV 1 003 OrH$Rs 000 PRE38:49W
6rd
A/2
ACC NRi 06024337 SOURCE COM"; UR/0428/66/000/001/0131/0133,
A.UTHOR.: Stepanov, B. I.; Cribkovskiy, V. P.; Rutkovskiy, P. K.
01~iG: none
TITLE: The effect of the Q factor of a resonator on the power of the radiation
generated
SOIPC-7: AN BSSR. Vestai. Serjya fizika-matematychnykh navuk,.no. 1, 1966, 131-133
TOPTC TAGS: resonator q factor, resonator, generator, stimillated emission, excited
particle
ABSTFaCT: The dependence of the power generated by a resonator u'pon the reflection
coefficient of the mirrors r is examined. The effect of r upon the pumping efficiency
is taken into account. The radiation flux through an element of the end surface ds is
determined by the expression
In
-dS. IV
gen g ea
r
P + In
where W is the power of the stimulated emission per unit volume of the working
gen
material; e the length of the rod; and r and r' the reflection coefficients of the
ends; the denominator is equal to the loss factor. it is found that, when the rod is
short, an increase in the reflection coefficient from 0 to 1 can lead to great change
Card 1/2
L 09976-67
A&_
AP6024337 0
in the absorption coefficient of the pumping radiation under generation conditions
and, therefore, to a change in the pumping-radiation density in the specimen. The
considerations are valid for three-level generators and those four-level generators
in which there is appreciable depletion of ground-state partiolea. Orig. art. has:
3-formulas and I graph.
SUB CODE. 09/ SUBM DAM 3WuI65/ ORIG REFt 004
WH
;ACCMSIQN NRs AM,,013856
MMOM Rutkovskii
TITIXj Distribution of density of diffuse;_rimation in a ho~wgineoux inotl4mi(j.
Absorbing sample
_k
-SOURCEr - -Zhurnal -1yrikladnoy- iqa;oB opi
& Aistilbutio rAdiati i-cil
TOPIC TAGS i radi tici density isdiatiow. hJ'Airfuse,'
neodymium glassiro4, density di-stribution, i s:ot r-, 6 p-. A- a-, m-La- tr!
absorption,
V
f
IIABSTRAM A general 'equation Is dwived for the calculation of -the. intensity- a
light in a sample of arbitrary shape, and the distrib Van of -e-light-is fixwest,4_
gated in a rod vith a rectangular cross section. It is assumed in the caleWation
that the excitation is produced by fully diffuse,, monachromatiep and incoherent
radiationg and thst the absorption coefficient in constant over the entire-volume
and is independent. of the intensity of the light, This makes it possible to employ
the lavs of photastetric optioso The expressiong derived for a bwTy of arbitrary
shape, gives the relative spatial density of the light evergy In the body with &1-
lowance for smItiple interml refleations. The remilt In in series form and car.AIi-
L
.0148
-the' A-er- Uftb6l~-*d: terms- corrts
Ini-under-which lai-eWil sqp'r ted-bya,-Un te~-.
--pondivg~to a finite, mumber'of 'i6flictiont) -ar4- discussed.
i47 V
ie_ e
_r__MAda an ele trgnio'Com-;
Retval -nead7niva-glamo--ro&vi&:a'--i~-iL--raU-
puter. 7he fraction of the light absorbed is given fordifferent rod parameters,
"The author thanks -Ve P. GrIbkovskly ford-& disensviom of the nauttgraript and for
figv&es -and 28 foroulas
ce*" ORge art. had
useful afti
7r
ABBOGIA=QN:,. none
On, C=::
SUMTMv.
ATIK
MW sovt~" PIMM 8
arii .
J1
RUTKOVSKIY, F.K.
Use of a point diagram for computing the frequency contrast
characi cristics of,an objective. Doki. All BSSR 5 no. 2:61-64
F 161. (MIRA 14:2)
1. Institut fiziki AN BSSR. Predstavleno akademikom AN BSSR
B.I. Stepanovym. (Lenses)
SALIM, N.I., muter gazovogo khozMstva,--WTKOY_4IYq G.G.,
gazovshchik
Improving the hot blasting valve in. air preheaters. Metallurg
5 no-9:9-10 S 160. (KIRL 13:8)
1. Nizhna-Tagil'mk:ijv metallurgichaskiy kombinat.
(Air preheaters) (Valves)
RUTKOVSKIY, G,,Ya,
increas=g the blast furrace process 4n the Ukrainian S.S.R.
Met. i gornor-ad. prom, -s.1-.10-12 TS_F 164. (M:RA 17 10'
DUBOVIK, V,.Nl.,, St.. Prepodav.; MAIMIN, A.U.- kand. geol.-rdner.
NTSEVA, A.Ya., kand.-geogr.
nauk. d.-ts.; OTTO, P,I.;RUMYX
nauk. ispolMayushchiy obya~bawiuou-L uu,,u.; Shtt&GIN) I*A*.q
St. inzh.; MOSKALEV, A.F.; KOLESNIKOV, B.P., prof., doktor
biol. nau~p rektor; OKOROKOV, V,I.:,kand. biol. nank, dots.;
KLIMENKC, h.A.~ STARIKOVA, L.A., assistent! SHUHILOVA,
V.Ya., assistlent~, MAKSD-!0VA, Ye.A., dots.; KIRIN, F.vp-,.
kand. geogr. rvAak, dots., KUWETSOVA~ A.V.9 red.;MATVSM,
rad,.; 1-11W,0ZOV, V.K., red.~ RUTKOVSKIY, I.M.,, red.;
TYAZIMPLINIKOVI ye.V., red.
Illature of Uel~~%binsk'Province] Prirodl Cheliabin'skai ob-
lasti. Chellabinrkr T~jzllnc--Urallskoe knizhnoe izd-vo 19
64
?J+1 P. (MIRA 18:7)
1. Kafedra geografli Che-lyabinskogo pedagogichaskogo in-
stituta (for Daba-iik, Mamin, Runyantse-va, Kirin). 2. Nachall-
nik geologicheskogo ot-dela Chelyabinskogo geologorazvedoch-
nogo tresta (for Ot-.-~). 3. Chelyabiwkaya gidrologicheskaya
star
, tsiya (for SeregLn), 4. Nachallnik pochvennoy partii
Chelyabinsk(rj zen-LIeuotroitallnoy elkspeditsii (for Yoskalev).
5. Institut bi-ol,-.gi--^ Urallskogo fillala AN SSSR (for Kolesnikov).
t. Kafe6ra zooa-)gii Chel.yabinskogo pedagogicheskoga J-stituta
(for Okorokov, Starikova, Shumilova). 7. Chelyabinskiy rybW
trest (for Klimenkc,,'.
RUTKOVSKIYP L.A. (Ordzhonikidze)
Influenza and acute catarrh of the upper respiratory tract as a
cause of a temporary disability. Sov. zdrav. 19 no.11:40-44 160.
(MIRA 13--11)
1. Iz dorozhnoy bollnitsy No 2 Severokavkazskoy zheleznoy dorogi.
~-(INFLUENZA) iCATAFMI) (DISABILITY EVALUATION)
RUTKOVSKIY,.M.L.,.kandidat khimicheakikh naiik.
Corrosion of ch"ical apparatus by an aqueous volution of
monoethanolamina. Khim. prom. no-3:153-156 Ap-My 156.
04LRA 9:10)
1. Gosudar9tvennyy institut azotnoy promyshlennosti.
(Corroalon and anticorrosives) (Chemical apparatus)
(Ethanol)
RUTKOVSKIY, M.L.; MESHCHERYAKOVA, I.D.
Search for the material of a reactor for the preparation
of a polyorgranosiloxane liquid. Zaj3hch. me'.. 2 no.1:104-
106 Ja-F 166. (MIRA 19:1)
1. Submitted April 8, 1965.
_L 01286-67 _Z1
~,.,VEWPCWT DWP(t),~ETIZN~PJKI
ACC NR. AP6003328 SOURCE CODE:
JAUTHOR; RutkovBkiy~ M, L.; Meshcheryakovaj I* Do
iORG: none-
UR/0365A6/002/001/0104/0106
TITLE: Search for material for a reactor used in the production of polyorganosilOxanO
liquid
SOURCE: Zashchita metallov, v. 2, no. lo 1966p 104-106
TOPIC =S: corrosion resistance, monomer.,: siloxane, molYbdenUM containinQg alloy,
titanium base alloy oz~mA6LO-' a~uzj) OA-tl
ICY,
ABSTRACT: 1yorganosiloxane liquiAv,1322 30C0 is prepared now in an enameled
reactor by the reaction at 95C of a mixture of organic silicon monomer with 25% solu-
tion of NaOH. A number of corrosion-resistant alloys was tested for-behavior under
reactor conditions because Soviet industry does not now produce apparatuses that are
protected by acid-resistant enamel& Samples 40 X 15 x 2 mm large) after the required
treatment, were suspended on teflon ribbons in the working reactor into gas and into
liquid phases. The.suspension was devised so that the samples neither touched each
other nob the walls of the reactor. For the alloys investigated, the corrosion ra s
at 95C in the gas and liquid phases were determined (in mm/yr) to be as follows:1
Card 1/2 UDC: 620.193.4
L 01286-67
ACC NRs AP6003328
Gas phase, Li Uld phase,
mz/yr lryr
lKhl8N95 44 51,8
El 4.25 5,28
-T--l 78 88
T I 4~'
58.8 89-5
I 'Ti-; 0.2% ]~!_jj 21 50.3
O-H + 30% YD 0111 005
F-P-495 (Ni 4 11% ~b 1*05 0.54
P M-YF5 ANi t 16% ~b 4,5 not tested
The alloys Ti + 30% ~b and EP-495 were the most resistant to i n. However, the
technology for producing Ti-Yb alloys is not yet developed arp 5 can be used only
, s9o
if the production of the apparatuses does not require welding because its welding
seam has a tendency to intergranular corrosion. TIhere7Ts-,-E=-ver, the alloy EP-496, th-31
welded seams of which have no tendency toward intergranular corrosion, Alloy EP-496
(.Ni t 28% ~b f 2% V) was thus recommended as the material for the reactor..Orig. art.
has: 3 tables and 1 fig.
SUB CODE:11,lYIjSUBM DATE; 08Apr65/ ORIG RU: 0031.. 0TH RM: 001
Card 2/2 Mjs
(ChemiczJ equipment cogusiun with xque;;i-zVmetfuw~l--
In 50"Utions M
k4
drg~rwncv in tne ian and pl3nt tests
i4 cwtied by the motion 4 tht liqt4d--jteam emulsion anJ the
13 14" steaM superheating. The addn. of () 1% K,CrA
lcgwt:fed the 5?M corrosion R-60 tinics, but the dichromate
is quickJy uged up by the HS, A periodic vacuum dista.
of the antine is recommended to rrmove the corrosion-active
components in the soln. W~.M. S
'x
RUTKDVSK7j M,,L.-;-.ANTJFRIYZVA) N.A.; KOPIYEVA, O.M.; POTAPOVA, N.V.1
---7--kkii-kv, i.v.
Kinetics of the gaseous boron saturation of nickel. Fiz. met.
i metalloved. 1-2 ub.2 17-222 Ag '61. (MIRA 14:9)
d
(Nickel-Hardening)
(Case hardening)
RUTKOVSKIY, M.L.; ANUFRIYEVA, N.A.; KOPIrr.VA, O.M.; POTAPOVA, N.V.
Causes of the linear relation between the thickness of a
layer and the length of time In the boron saturation of
nickel. Fiz. met. I metallovad. 12 no.2:292-294 Ag '61.
(MIRA 14:9)
(Nickel) (Case hardening)
0 )LIJI" Mz jos S/126/61/012/002/ 006/019
ElI.l/E435
Anufriyeva, N.A., Koplyeva, O.M.,
Rutic:)vskiy. M.L.3
'-p-6~*~~,7~~a _,N.V~.and Kazakov, I.V.
a
Kineti--s of gas boriding of nickel
kr,RIODICAL_~ Fiztka mc-allt-v i mealloveden 1961, Vol.12,
iye, NO,2,
PP-917-222
YEXI'; MaLer-ia15 su~:h as borides. silicides and carbides satisfy
~r-_ requirements of high chemical stability and resistance to
~:-si.on whic~h *e~' hni.:al der~ilopments are imposing. No
on the rate of boriding has yet been
is some dirergence of views on results
--'~Ported and there
ct,_-ainabla (e.g. Ref'.10; Zhigach A,F. and others, Metallovedeniye
I~ermj,ch&_~kaya obrab.,.>tka. __959, No.4, 45; and Ref . 11: Weintraub R.
..-d, a. Eng, Chem., 19-11", 3., 2991, rhe authors have studied the
P.,as boriding of ni_'-kt-I a-" 9()0'C uZing a 1.4-1-10 mixture of
The zas mixture was stored in a.
-on trichlrride and hydr.;gen,
-linder and ~,,dmitted,.. al: ~~ weaslir,&d ra;e. to a 30 mm diameter
ti_~r izontal quartz reaz;,.ion tube ~irL L' r,_Arnace) which could also be
with n-tro
I Gen. rhe fl.7,w of the gas,mixture was started-
the temperature rea~:Iied 500 cr, 000'C, Specimens were in the
1/3
S/,126/61/012/002/Oo6/019
h1netics of Sat, bori-ding EIII/E435
foi-m of re,~_tansular 25 x 10 x 2 mm nickel plates, cleaned with
and waihad uith a1,-_-ohrjAl~ Af*le: Ovickness measurement with a
Ol I d The thickness
-vitiater the spe-AlTle-n.3 WP I t, of
r e 1v v
~Kc ~ I Lonsutried in the formation or the boride film was taken to be
I,z;i( -ht, diffeyeii-.e between the and final thicknesses
!-_,~-iured at the centre of the specimen), A linear relation
0; !Ween At, (mm) nnd boriding time Mours) (from attainment of the
"~--rk-4ng temperature, 900'C) was found, At being 0.8 at the maximum
'40 hours, Gas flows of 6, 24 an-i 96 litres/hour were used,
e. weight,-gains in
sp:)nd:ng g"m2 hour being 26.6, 54.1 and 99.
,iz. f',,,,~w rate-6 were in the laminar range. From the results the
tri_rB -on-.lude that Lhe rate - ~ontrclling factor was boron
-31C~11 IrOM th,~: gas phase to the metal surface. 'In the range
the weigh~-galn rata (ie. boriding rate) was found to be
.,f~-viically independent of the boton trichloride to hydrogen ratios.
suggests that the tric-hloride does not participate directly in
1':i-_z A check on
a-ing but forms an aztive intermediate -ompound.
.'rt-ight of nickel losT during boridTng showed that it was under
indicating that nizkel dichl6ride is not formed: this is
2/ 3
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1- .8 a f iz a i b c~ rd Ang Ein/r,435
to the v-4"Iws of Pcwell. The boride film was found to
of thre,~ layers (prcbably N-,B outside, followed by Ni3B2
-Z~J Nf?B) sirith dlffcrent m;.-rohardness, The inner layer is
-.t-nnest- ThL- boundarles be-~wean the layers are probably non-
i.,a,-rided or weakly bcri,ded'components, -much as carbon, copper,
sulphur or sil!-~;on, All the boundaries are serrated.
K,Kryukova and Z.A.Borisava and-M.L.Mironenko participated in
experiments. Therq are 5 figures and 17 references:
Soviet and 5 The twc, references to English language
--Abtngayer A.W_ Hurd D.T- Ne-wk-irk- A.E., Hoard'J.L.,
An., Chem, So 1943, Vo' . 63, 19"t,
'.I.. t-ntrijub E, Ind, a. Eng,, ChE~m_ 191.1- 3, 299.
S;U BINI rTTED,.0 b L 9 6 0
January 1.1, !96! ;'a I i-,-~ i an
3 / 3
E6565 S/126/61/012/002/ol6/ol9
IASGO E073/E335
AUTHORS: Rutkovskiy, M.L., Anufriyeva, N.A., Koplyeva, O.M.
and-P-of a-p-o-va-,-N-. V.
TITLE: On the Causes of a Linear Relation Between the
Thickness of the Layer and Duration of the Process
of Borating Nickel
PERIODICAL: Fizika metallov i metallovedeniye, 1961, Vol. 12,
No. 2, pp. 292 - 294
TEXT: In an earlier paper (Ref. i Fmm, 1961, 12, 217)
the authors and I.V. Kazakov have shown that in borating nickel
a linear dependeFice was observed between the thickness of the
metal layers At expended on forming the boron film and the
time of boron deposition /'I_- for /Ae 1~~ 0.8 mm. Usually,
the curve reflecting the speed of t~ e diffusion process is a
parabola, for which the equation y = f, ^r, is valid; linear
dependence between the thickness of the layer and the time is
possible only if the forming film has mechanical defects along
-hich the diffusing substance migrates to the surface of the
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On the Causes of .... 7 E073/E335
base material. A photograph of a polished microsection of
a boride layer is reproduced, from which it is concluded that
the linear dependence is not due to mechanical defects of the
film since defects at a direction normal to the surface of the
specimen were not detected in the film. Comparison of the
structune of boride films on nickel and cobalt has shown that
they are qualitatively equal in spite of the fact that the
increase in thickness of the boride film obeys the parabolic
law in the case of cobalt and the linear law in the case of
nickel; Figs. 3 and 4 show the dependence of the thickness
of the borated layer n~e, mm 0as a function of time, hrs, for
a borating temperature of 900 C for nickel and cobalt,
respectively. It was established that the temperature coefficient
of the speed of borating nickel at temperatures above 900 0
was considerably higher than was anticipated on the basis of
the exponential time dependence of the diffusion coefficient.
If borating was at 1 000 0C the eutectic NiB + N:L3B2 with
a fusion temperature of 990 0C formed and the specimens
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On the Causes of .... E073/E335
melted off. Formation of this eutectic led to thp idea that
in the case of the formation of borides being eicotIfdrmaI:-the linear
dependence between the thicXness or the borated layer and the
time at temperatures not differing greatly from the tempera-
ture of formation of the eutectic can be explained as follows.
At the surface of the nickel specimens which is subjected toborafing
there will be concentrational fluctuations; due to the exo-
thermal nature of the process this will lead to a local
increase in the temperature in the borated specimen and to
the formation of a low melting-point eutectic at these points.
The diffusion coefficient at these points will increase. . .
instantaneously and this will lead to an overall increase in
the diffusion coefficient and will result in a linear
dependence between the thickness of the layer and the borating
tim.p. Conservation of the parabolic dependence in the case of
'cobalt is obviously due to the fact that the temperature of
formation of the low melting-point eutectic Co-B, which is
1 105 OC, exceeds the borating temperature by 205 OC, whilst
in the case of nickel this temperature difference is only
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On the Causes of .... E073/E335
900C. Thus, the heat released during borating of cobalt is,
apparently inadequate for producing a low melting-point
eutectic at the spots.where concentration fluctuations occur
and, as a result of this, the parabolic dependence Ae = f(*t)
is maintained in the case of borating cobalt undw~ the given
temperature conditions. There are It figures and 4 references:
3 Soviet and I non-Soviet. The English-language'reference.
quoted is: Ref. 3 - Brewer, Dwight L. Sawyer et al
J. Amez. Ceramic Soc., 19151, 34, 173.
SUBMITTED: February 28, 1961
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