SCIENTIFIC ABSTRACT RYZHKOV, V.M. - RYZHKOV, YU.A.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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S/058/62/000/002/005/053 A0581A.101 U"M A ORS: Ryzhkov, V. M., Skrotskiy, G. V. A TITLZ-: Some special features or.the free precession.'of atomic nuclei PERIODICAL: Referativnyy zhurnal, Fizika, no. 2, 1962. 37, abstract 2V284 ("Tr. Uraltskogo politekhn. in-ta", 1961, v. 111, 45-62) The cutoff process of polarizing magnetic fields in experiments.on the free precession of nuclear magnetic momentsis examined. It isishoem that 'if the time in which the magnetic field changesdirection is shorter than half.the~ Period of the Larmer precession of the nuclear magnetic moments, the nualea-- magnetization vector does not manage to keep up with the field (anadiabatic case). the field,:the nuclearmagne tizati on vecto In the case of slower rotations of r doeskeep up with the field and free precession is not observed(adiabatic case)'.''-"~. The effect of magnetic-field%inhomogeneities on the amplitude of free precession, is examined. It is-sho,,,m that in the case of a constant gradient and a cylindri-,~'.''. cal.specimen, the envelope of the oscillations of the free-precession signal can,, .,,be expressed by a Bessel function of the first order, which corresponds to,the .Card 1/2 .620 C 3 5/08 62/00b/009/002/975 Y /30 B138 B,177 AUTRORS:, . ~yzhkov, V. M. Chirkov, A.K. TITLE: The measurement of-weak magnetic~fields by the elect on r n tic resonance method. paramag e FERIODICAL: .. Referativnyy zhurnal. Khimiya Ij no. 0 1062 21 abstract.qB114 (Tr. Ural' khn 4, %. skogo polite ta.,,sb. III 1961, 89-107) TEEY M A:the6retical analysis is,given of methods'for meapring weak Magnetic: f i'eld s~ (of :tlqe:terrestrial type)~by,e.p.r. it foklows from this n that a alysis , te. m-e f the maximum attainable accuracy of absoly -asurements o weak magnetic fields, usingAhe 'radica~l ma -diphenyl--G-picrylhydrazyl, is 5 - I 0-~%. 1. This by the accuracy, with which the gyromagnetic is g9verned ratio for:an e , lec:tron is measured. The maximum accuracy is.attainable 'When e.p.r. is ,detected.by,the oscillator method for a magnetic field of, not less~.Ithan 4 oersteds. If. other specimens,are used, the accuracy of absolute measu 2 rements does'not'.exceed 6-10- The accuracy of relative Card 1/2 een a,-ma. lean xie~'. ~6 I ix16-A A; iain aIti ASD,(a)-5/ATETR APA( pj!! NR': -.ACCESSION -AP4 j~g4~~ enei inddlat, pen ipg-'7 be-~ woiicihg,--S,iwf 'acift- 10 Gard V 3 c-f W)scow Math~ma;',ical (cont. 1087 TABIE' OF COEMITTS: Bereza.,2~skiy, Yt..M. (Klyelr). On tb., in the Inverse Problemof -si -z for + "Id ge -p peec ra-1 A.-aly b-- Ini., r Bqz~e-.Lia The, !,.asic xesatsgive~--- iL~ ax-tic-le were presented at the, November 9. 1959 sessioz of tbe Wacnw I~W.-,.hematical Socle-%Y. The article contains the 1.)L Carl;s1z, res:zlt4s coicermteg hyperbolic eqrotions., P-) Proof of the 1r, ~3'3 21~ of ezm izxersp Timblem. caimiected Ra f -zh) K.-aa-uosells'Uty, M.A. az~--A R., ..--kjy~ Ya. B. (Vorone Orlich Spa.-s amd Norairear Jzj:~P-gral ETaations 6-3 s give a., Jn +.!,ds.ar?,ic1e were, presented at the March 2~ 1954 The basic reelzi- -ticle contains the fol- session of the Moscow Malhhemtical Society. . The az 2) Splitting of linear. lo-Winq sections: 1) Basic definitionB; CE.-rd 2/8 Transactions of the Moscow Mat Ihematical (Cant.) loat the following-pections:. Introduction; Ch. I. Cohju~pte Systemi; 1) De Sig-' ,nations and basic definitions; 2) Differential 'equation "'Ining conjugate V.Stems; 3) Condition for complete stmatification of a cmjuaLti s-ystem~ Ch.,II. Completely-Stratifiable Conjugate Systems; 4) n7 lonjusate fystems; 5) Conjugate Systems,with one multidimensional component; 6) Completely stratifiable conjugate systems with several, multidimensional 'Components; 7) General remarks oncomplete stratifiable conjugate systems; References. Fage, M.K. (chernovitsy). Operationally Analytic Functions of one Indepence-at Variable [171=ctions Defined by an Ordinary Linear Differential Operator, L of an Arbitrary Order With Continuous Coefficients] 2?7 The basic results given in this article were presented at the October 30,.' 1956 session of the'Moscow Mathematical Society. The articlecontiins the following sections: Introduction; .1) L-bases; 2) L-analytic polynomials; 3) Taylor.'s L-formula; 4) T&ylorls L-ilaries; 5) L-holomorphic functions., 6) L-analytia functions. - Uniqueness theorem; 7) Regularly convergent sequences of L-analytic functions; 8) Operator with analytic coefficients. 9) Local equivalency of operators,of anequal order; 10) Cauchy problem in the region of double operationally holomorphic functions; References Card 5/8 Transactions of the Moscow MeLthemtical (Cont.) 1087 Levitan, B.M. Differentiation of Eigenfunction Expansion of the Schr&inger Equation., ~269 The basic.results,givenin this article were,presented at the October 4, 1955 session of the Moscow Matbe Imatical. Society The article'contains the, following sections: 'Introduction; 1) Solution of CawJ2y problem; 2) Nvaluation. for arbitrary'pigenfunctlons; 3) Evaluation of derivatives of eigenfunctions. it_ gion; nt function in the case of an infin re 4) Differe iation OfLeigen expansion; 5) The case of f'x)_4+LCD' at 1xi-ow; Fleferences. Men'shov, D.Ye. IAmit Ametions of a Trigonometric Series 291 The basic results given in.this article,were presented atL t he April 16 Li957 session -of the L Moscow MathematicalL Society. :: The article contaids th .e following Lsections: 1) IntrodUCtion.,[Basi Ladefinitions and L formulation of threetheorems]; 2)'[Preliminary remrks, &-finitioxis and L jivaxiliaiy theorems needed to prove theorem 11. Proof of theorem II(.L L 3) [Definitions and lemn-s needed~to prove.theorem 13:1];,4) (Proof of AVatioj2 L III T11--orem 111; 5).'De of tbiinvm I from tbeorems II and References. Grayev, M.I.. Unitary Representations of Real Simple 1,1e Groups L 335 This article-was presented at the Jan~ary 20, 1956 Session of the A1.1-Union Conference on Functional Analysis and its Applications. The article contains the..fol.loving seetionS:Llntroduction; 1 group; PIra- card 6/8 meters and an invariant measure C, r i group; Transactions of the Moscav Mathetmitical (Cont.) 1067 2) Generalized lin6ar elements and transitivemimifolds; 3) Discrete: series of repi-esentations of Itype, 1; 4) Irreducibility of representations of a discrete-series;~5) Traces of representations of a discrete series; 6) indiscrete basic series of unitary representations of group; References. Machnik,,L Solution of Post, SReducibility Problem and of Certain Otber L' Problems of, the, Mwdryj%.5f --Algorith=. I. L B&sic results of the 350 article were presented'at the October,162 1956 session of Va Moscov Mthe-motical Society. The article contains the folloving sections: Introduction; Ch-'I. :F=ctional Representation of Phrtially Facursive Operators; 1) Cortege and qmsi'-cortege;LL2) Ft3nctio m-1 r*epresentations L of operators; 3) Universal partially recursive operator; 4) calculation [solution] of .14,- (Medevedev] problems; Ch-II. Decision Problems of Enuwrable Seti; 1) Semilattices 0&-(p); 2) Post's iedUalbility_ problem References. -Mcbmik, A.A. Isomorphism OfLSystems of Recursively Enumerable'Sets With Effective Properties Card V8 On the Characteristics of.the,Isotherms of S/011 0/034/04/10/042 0/1/301 Electrical Conductivity of 1-1-valency- Salts B01 09, in Solutions With Low Dielectric Constants standard capacitor oftype ME ~-4 (Fig. 1, Scheme of the Arrangement). Table .1 containsthe values measured for the dielectric constants, densities, and electrical conductivities of,~,butanol-hexanemixtures, Table 2 the values of the dielectric constants and viscosities'of several solutions, Table 3 the values ofthe electrical conductivities of the-501UtiOnB at 250C. The maximum observedin the conductivityisothermal lines is determined by the increase !n viscosity. The sharp rise.of. the isotherm after the minimum is believed to b due to.the lower activity coefficients of the:ions as well.as to the.increase in the dielectric constants of the solutions on account.'of the-higher salt concentrations-* The dissociation constants of the ion pairswere calculated (Table 4), and1t was shown that the.theoretical:equation by Bjerrum (Ref. 6) and A. M.'Sukhotin (Ref. 7).:satisfactorily represents the dependence of the. dissociation constant upon the dielectric constant of the~solvent. There are 2 figures, 4 tables, and 9 referencesp.6 of which a Ire Soviet SUBMITTED:, June 1.4, 1958 Card,2/2 5(2) PHASE I BOOK EXPLOITITION SOV/2946 Leningrad. Univers Itat Voprooy knimil (Problems in Chemistry) Lengingrad) 1=4-vo I Serivai Ital Uchanyye Lenin gradekogo. uni v. , 1959. 160 P- zapiokl, no. 272) (Series: Leningrad. Universitot. KhAmichookly rakultet., Uchenyye zaplaki. Seriya khW chesk1kh nauk, vyp. 18) 2,60O.coples printed. Resp. Ed.: A. 0. Morachevskiyj Ed.% Ye. V. Shchemeloval Tech. C41 Ed.s S. D. VodolagIna. 1n r*s*&rob :nd t s v PURPOSE: -This book In Intended for chem.: , ; . , d duatry an well an for teachers and u nt In chemi &I vuzoa. A6E This collection of eighteen articles on varlous branches C.V: I NN of chemistry, mainly physical and an lyticalo was compiled on the : Chemistry Department of basis of experimental renearch.by th Leningrad University. The articles d al chi*flr VI" method& of :Isolatino, rare earths in pure form and Ident, rylng,.them.. No 0oalirien are mentioned. References accompany Individ a 8 :per art cles. , . TABLE OF CONTENTS t 'kLk"-Th fluence or Surface- e fet a e in .nd B. S. Kra V , L 3'' __ih`e-Drz-cF&rje Xinet X_~fv. c on I . of Some Cations .is ~ .. 3 u b % ~~ ulamry -7- atudy of t.116 Rex Xraaikov, B. S., and e M ~ W se In the 31 orCopper Ion Dloch&T~gea re nee of Tribenzylaosin a I and L-3._Ec3UhAMrit. Regularities of Dayfets. I Tollnt NI an I Copper,jon Discharges. 11. The Inr2u&noo of Temperature, Cathode Potentials and the Presence or Surface- Active Anlons on the Distribution of Current between Nickel and Hydrogen 40. Zakhar!7-t~1 and X M _YAAII"ko- The. ApplLo ability _ - 48 R ~ e the Study or dox Systma f -Layered Elect odes Yo o TnIn .1 Zakhar-yevakly, X. S.'.&ndM_A-Kro.1'kav Study of 3*41~~-' and Potassium- Nitrate Melts by the Electromotive Parse Nothod 57 1n Shkol 1kova, R, 1. The Solubility of Gases In Colloidal , . . yo. 64 Xozhevnikov 3 P. The Method or a 'Triple Contact 87 Yef"mccY.Q ~s and A. V. Ooncharov. CopreaLpitation of ThallIum WI on Hjdrdxr4i- 94 ,, Yerramov. 0. V., and 1C. P. Sto;yLrov. Photometric Det*mL. nation or ThallIumIn =47-171ffs~ToTat_Spec tram Range 99 M0rACjjS"k1y Yu V , and 0. V. YrremoV. The Problem or. Arrayitloal2y Deterzining Thallium in ores And zoduzzrial Waste Products 105 Morachevokly, Yu. V.. and A. 1. Noviipx~ Coprecip.1tation - of Small Amounts of S~verftr-M emtnts With Metal Hydrox1doo... 1. Coprecipitation or Strontium With Iron, Titanium, Aluminum and Beryllium Hydroxides 112 I,. Coprocipitation of Small Am 0unto or Rare Earth Element& With Iron, Titanium, Aluminum and Beryllium Hydroxide& 123 111. L Coprocipitation or cplum, Rhonium and Ziroonjum With Iron Oxide 12Q norachavokly, Yu. V., and L Copr*olpltatim *v N' 11 _A of Small Amounts or Hart 14. ~ ~. n . With Natal Hydroxides. IV. Coproolpitatjon of Zucwjum ,in zrm. and. Aluminum-Ny4roxidoz 134 L S/0?6/60/034/007/011/042/XX, BO04/3069 AUTHORS: Ryzhkov, Ye. M. and Sukhotin, A. M. TITLE: Electrochemical Study of HCl Solutions in Solvents With Low Dielectric Constants. II 0 PERIODICAL: Zhurnal fizicheskoy khimii, 196o, Vol. 34, N -.7v PP- 1.402-106 TEXT: In Ref. 1, the authors studied the electrical conductivity of HCI solutions in butanol and butanol-hexane mixtures, and calculated the diS sociation const ant K of HC1 in the mixtures.. For solutions in pure but ano 1, itis impossible to perform this calculation. Therefore, K is determined d in this paper, by measuring the em,.f. of the cell Pt(H JHCl utanoijA-Cl-Ag 2) :tb at 25 0C. A compensation method was used in the measu rements. A flnT3-1 (PPTV-1) potentiometer equipped with an JZY-2 (LU-2) tube amplifier was used', the pointer galvanometer of which had been replaced.by an M -21 (11-21) stable and~a figure Acorrection .,.mirror galvanometer. Results are given in a for;atmospheric pressure and vapor pressure of H01 in,butanol was intro-.~ Card 1/5 Electrochemical Study of HC1 Solutions in 5/076/60/034/007/0.11/042/xx, .Solvents With Low Dielectric Constants. II BO04/Bo68 duced;,with the HC1 vapor pressure being measured by a method suggested by 0 N. A. Kupina and A. A. Ravdell. The relation E =.E - (2RT/F)ln C (2RT/P)ln af (1)'is derived for the e.m.f. of the cell, where f is the mean .ion activity coefficient. Applying the equation for the thermodynamic dissociation constant: K a2 cf2/0 a)f (2) d + HCl (f activity coefficient of the non-dissociated portion.of the electro- HCl lyte) one.obtains: E Eo (RT/F)ln c (RT/F)ln(l. a)f HC The 01 0 difference between the standard potentials E and E is given by.the equ . ation E0 E01 + (RT/F) ln K d .4). According to equa .tion,.(-1), a straight line with a slope equal to -0.118 is to be expected for the function E f(log c) for low concentrations (aFJ 1 f This, actually occurred when c < 3-10-'it M. By extrap'Olatio n to log c 0, it was found that 0 E -0-1430 v. The deviation from the value given, by N. A.- Izmaylov and Card 2/5~ Electrochemical Study of HCI Solutions n /034/007/0,11/042/XX s1076160 Solvents With Low Dielectric Constants.' !I V. V. Aleksandrov. (-0.132 v). is due to the fact that 't'-I e s eresearchers workedwith excessively concentrat ed solutions. For systems vith low di-I electric constants, only dilute solutions, are admissible., The second linear, 0 =_I-and a c nstant section with a slope equal to.~-.0-059 c rresponds to f 0 ~Hcl dissociation degree calculated_-.according to T.LShedlovsky (Ref.- 15) from the -conductivity of HCl in,butanol..It.vias'found from equation'(3) that Of E =~-0-085 v and from equation (4Y that K' 5-10, f mscalc'ulated from, d + representation of log equations (1) and .(2). The graphical Klvfac) in ' 3 shows tha values found deviate both from the.first and the-see t the Pig. ~ ond approximation of, the Debye*-~-: Hilckel theory.:This is explained by the low dielectric constant-The deviation of the function E = f(log~c) from linearity,for concentrations above 0-5 1-1 is,due' to chan es of f For HCl 1.15.M, f wasestimated :to.be'equal to 6~ There are, figures,..2 tables, n se. ish 1 Finnish,' a d I Japane and 15 references: 4 Soviet, 6 US, 3 Brit Card 3/5 (VITkIINS-B)