SCIENTIFIC ABSTRACT SAMOYLOV, M.A. - SAMOYLOV, O.YA.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001447010005-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 22, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SAMOTLOV, M.A.
Machine planting of sugar-beet transplants. Sakh.prom- 33 no-3:
48-50 Mr '59. (MIR& 12:4)
1. Voesoy-uzr;7 nauchno-isaledovatel'skiy institut sakharnoy
avekly. (sugar beets)

. SAVIOYLOV,.J._',,~~,_kand. Lekhn. naukj VC)L'FMA!,I, T.D., inzh.
Self-a-diusting reducing gear. Mash-inostroenie no.5.-r-2-5"
- I
5-0 10/5. (P.TIRA 18:9)

'18267
S/135/6P_/0r,o/oo6/oi4/o14
AOO61Aic6
AUTHOkS - Sauioylov, M. I., zarvatin, I. P., Engineers
TITLE: A device for spot-welding box-shaped structures.
PERIODICAL: Svarochnoye proizvodstvo, no. 6, 1962, 38 - 39
TSYT- The authors developed and brought into use a special device for
welding box-shaped structures, at two spots simultaneously (Fig. 3). The device
is mounted with the aid of collar I and lever 2 onto the lower fixed cantilever
oil a spot weld-in-- machine. The electrodes 3 of the device are coaxial with the
electrodes. Vhen handle 4 is rotated, rod 5 Pulls or,pushes wedge 6;
as a result the distance B increases or decreases. By loosening bolts 7, the,
device can be turned or displaced so that the access through the operating holes-
into -~he box is possible. industrial tests of the device showed its
advantage over mandrelz. Box-shaped structures of a wide range of dimensions--
can be welded with the aid of this 1nstrument. The use of mandrels is eliminated.
labor efficiency is raised and stable welding conditions are ensured. Tlie
quality of the weld Joint is satisfactory.
Card 1/2

s/i 1,5/6P/boo/Qo6/b 14/0 14
A device "or spot-welding box-shaped structures A00o/Al06
Figure 3: A device for spot-welding box-shaped structures
6 J 4 There are 3 figurPs.',
7
j
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Pim. 3. nPIICnOC06.IeHHe A.19 TOqeqHjn
caapmt xavo6qaTOA KO JICTPYXttFIH.
Card 2/2

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card.

BROUDIN IL.M.; PI-MITEREVA, $.I.; Prinimali uchastiye; $AMOYLOV~ M.I.;
GOLUBOVICH) X.~
Effect of cortisone and testosterone on the eQntent of asparagine,
car*nosine and anser4ne in skeletaland heart muscles. Biokhiriiiia
27 no.1:42-47 Ja-F 62. (MIRA 15:5)
1. Department of Biological Chemistrnf, Ist Medical Institute, Moscollf.
(STEROID HORMOITi-3,S) (WSCLES-)
(HEART--MUSCL)-,;) (ASPARAGINE) (PEPTIDES)

SAMOYLOV, M. I.

SAIVOYLOV. M.I.
Disturbance in the functional activity of the brain in dase of
hemorrhage.: Biol. v shkole no.2:95 Yx-Ap '62. (MIRA 15:2)
1. Institut vysEhey nervnoy deyatel'nosti AN SSSR.
(BRAIN--IiEMORMGE)

"YA

VCLKOV, Mikhail Iyanovicho' prof.; GELIKER, Vladimir Oakarovich, kand.
takhn.na*; ZASHCIWIN, Alekasy Nikitich, kand.takhn.nan
LYSIKHINA, Aleksandra Ivanovna, kaid.tekhn.niauk; KIKHATLOV,
Valentin VasillyAvich, kand.tekhn.nauk; PANTETAYMY, Fedor
Nikolayevich, kand.tqkhn.nauk;-SAKOXWV, Kikhail Pavlovich,
iuzh.; ORRATSKIY. N.V.,- prof..
KOROZOV. V.I., red.; KALIXOVA, N.V., tekhn.red.
[Handbook for road engineers; road materials) Spravo 'chnik
inzhonera-dorozhnika; dorozhno-stroitellnya materialy. Moskva.
Nauchno-tekhn.izd-vo H-va avtomobillnogo tranap. i ahossainykh
dorog RSFSR. 1959. 308 p. (MIRA 12:8)
(Road materials)

VASILENKO, Aleksey Nikolaye-vich: kand. tekhn. nauk; DRYZHAKOV,
Yevgeniy Vasillyevich, dots.; ISAYEV, Sergey Ivanovich,
kand. tekhn. nauk; KORNEYGHUK, Nikolay Karpovich,
kand. tekhn. nauk, dots.; KOFANOV, Dranovich;
assistent; RRUTOV, Vitaliy Ivanovich, doktor tekhn. nauk,
prof.; MIRONOV, Boris Mikhaylovich, kand. tekhn. nauk;
IlIaIATULIN, Iskander Nigmatulevich, doktor tekhn. nauk, prof.;
NOSOV, Mikhail Vasillyevich, prof.; SAMOYLOV, Mikhail
Sergeyevich, assistant; SPORYSH, Ij-orTra=vMrc5,'5'7d. tekhn.
Viktor Ivanovich, kand. tekhn. nauk;
SHISHOVI Yevgeniy Viktorovich, kand. tekhn. nauk; YUDAMf,
Boris Nikolayevich, kand. tekhn. nauk, dots.; KUTYRIN, I.N.,
dot--., kand. r4tzerz:';ttII-SHUMOV, A.M.. dots.,
retsenzent; -'TUFITVii,"- L.A., red.;--FftFIC G.I., red.
[Problems in technical thermodynamics and heat transfer]
Sbornik zadach po tekhnicheskoi termodinamike i teplopere-
dache. [By] A.N.Vasilenko i dr. Moskva, Vysshaia shkola,
1964. 369 P. (MIRA 17:4)
1. Prepodavateliskiy kollektiv kafedry termodinamiki i teplo-
peredachi Fio:3kovskogo vysshego takhnicheskogo -uchilishcha
(for all except Kutyrin, Shvedov, Tupitsyna, Fufayeva). 2. Mo-
skovskiy aviatsionnyy institut (for Kutyrin., Shvedov).

SAMOYN-J, V.S., otarsf;iy prapoduvaLell
~Iea+l aaxc~ang.~ at. tvl-e p-r-cpaga ticr, of a twisted rcn~
ftl~zfd jet. ri & fioodid lVIr.vys.-ulci-eb zvi mas
hino~tr.
r. c,5103 -'1 C, h 4. (MIRA JS..I)
vy~2-'h,~yG '-~khrvl,,,Yesk,~ye uchillahchp im.prJ ll.EoBauvianaa

ACC NRt AP70066T5 SOURCE.CODE: UR/0145/66/000/010/0062/0070
AUTHOR: Samoylov, M. S. (Senior instructor)
ORG: None
TUM On calculating a laminar twisted jet of ccmpressibla fluid
SOURCE: IVUZ. Mashinostroyeniye, no. 10, 1966, 62-70
TOPIC TAGS: Jet flow, laminar flow, flow analysis,lcompressible fluid
ABSTRACT: A computational method is proposed for studying mixing of a laminar twisted
jet of compressible fluid with a homogeneous motionless medium. The analysis in based
on application of the mqtpod of defomation of independent variables to equations for
free flows. The articlqlvas presented for publication by Doctor. df tecbnical.sciencea
V. I. Krutov, Professor~*t the Moscov:Technical
SUB CODE: 2o/ Bm~ DA 93kay66/ 00
M
621.001':'~
Card
2

----------
3
ACCESSION NR: AP4043311 S/0145/64/000/006/0127/013
AUTHOR: Samoylov, M. S.
i -TITLE: Free deflected flow of a compressible fluid in'a stationary environment
SOURCE: IVUZ.' Mashinostroyeniye, no. 6 1964' 127-133
TOPIC TAGS: free flow, compressible flow, larninar flow, deflected laminar now,
stationary flow environment, flow analysis, Iongitudinal veilocity component, radial
velocity component, excess stagnation temperature, indeipendent variable transformationj
I hydrodynamics
ABSTRACT: A primary sector of laminar deflected flow is analyzed by applying the
known transformation of independent variables to differential equations of motion and
energy in free flows. An approximated solution is obtained for motion andbeat exchange
e s Pen in the
equations of such a flow in a flooded space filled with th ame liquid. It is giy
form of a function allowing one to determine longitudinal and radial components of stream
CO-
travel velocity and the excess fluid stagnation temperature in a deformed system of
ordinates. Another relationship is given for conversion from E, rkcoordina-tes to the normal
x, r syst43m. Orig. art. has: 21 equations.
1/2

180-w 65'
myr( WP
3
4
ACCESSION JR: AP50097707-
j;h
P11wq
Pin- 8Y
axial and tangential vel-do, ti,;:`~com=enta- v -,Llf, -cylizift -A6&Mifia1qeq~--:an
1-
6o compbnenta* t6
olosed form solution is obtaimed-16r-lidth vel A assumpi,
that the Wrbulent visoosity coe'dioient is constbnt. It is theii abstmed tMt,
~visc(ms shear stresses can be represented more generally by P 12r 84 at,-,.
ar Wr
.and the expr9asions for u and. 4: i~M/r become
-77
1/2
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7 7-

27Feb 4
wl.
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SAMOM
Work practice in silo construction in Oral Province. Sell,stroi.11
so.7.*.2 J1 156a Ona 9 9)
1,Glavnyy inzhener Orlovskogo oblastsogo upravlaniya p* stroitell-
stvu v kalkhazakh.
(.Ovel Frovince--Silos)
IL

~7 77-'
ACCESSION ]HR; APS006921
SA06
777-
-AUTHOM: l6v 9;,~ A.
Tj __I; P. Saiacm
r. S
ABSTEAM Fetrolel
-6nes-,,--are -Iggr o
,x~ealsoh,, -f orth
e -Pl7p,
of ih67466ib~iiti~
of
A-06- at a mpe
an --:i4--pvessv~4f-
Goo

L 65

BUCIRIEV, K.U., prof.; UVALIYEV, I., starshiy prepodavatell; OMAROV, K.S.,
Catsent; GLEBOVA, V.N., dotsent; LOPATNIKOV, G.I., assistent;
-,~~I-.IPYLOV; N.G., assistent
Besnoitioais of cattle in the Lake Balkhash region. Veterinariia
41 no.5:59-63 MY 164. (MIRA 18:3)
1. Alma-Atinskiy zooveterinarnyy institut.

SA-MOYLOV, N. N.

SAMOYLOV, N.N. (Leningrad)
Pa4~tors..,of-ext'errial-'environment and processes of restorative
regeneration in the rabbit comea. Pat. fiziol. i ekspo terap6
6 no.6t 73-74 N-D'62 (MIRA 17:3)
1. Iz laboratorii eksperimentallnoy onkologii ( zav. za-
sluzbennyy deyatell-nauki prof. N.V.Lazarev) Instituta onkologil
(dir. - deystvitelthyy chlen AMN SSSR.prof. A.1. Serebrov) AIT
SSSR.

KALPIN:, G.Z.; RUBLEVA, K.I.; SAMCYLOV N P - REBROVA, G.I.;
ROMANCRUIL, Z.A.; KWUSHNIKOVA, V. .,.red.; TIKHONOVA, Ye.Mo,
red.; BALLOD, A.I., tekbn. red.; PROKOFIYEVA, L.N.., tekhn.
red.
[Manual on state farm Wates and other state agricultural
enterprises) Spravochnik po oplate truda v sovkhozakh i
drugikh gosudarstvennykh sellskokhoziaistvennykh pred-
priiatiiakh. Mosk7a, Izd-vo sellkhoz. lit- zhurnalov il
plakatov, 1962., 550 P. 15; 3)
1. Ninisterstvo sellskogo khozyaystva SSSR (for Wpin,
Rubleva, Samoylov, Rebrova, Romanchuk).
(Agricultural wages-Handbooks,, manuals, etc.)

KALPIII, G.Z.; RUBLEVA, K.I.; SAMOYLOV, N.P.- REBROVA, G.I.;
SAGAFO)A, Ye.A.; S red.; TIKHONOVA, Ye.M.,
red.; VIAKHOVA, N.N., tekhn. red.; OKOLELOVA, Z.P., tekhn.
red.
[manual on wages on state farms and other state agri-
cultural enterprises] Spravochnik po oplate truda v
sovkhozakh i drugikh gosudarstvennykh sellskokhozyay-
stvennykh predpriiatiiakh. Izd.2., perer. i dop. Moskva,
Sellkhozizdat, 1963. 638 p. (MIRA 16:12)
(Agricultural wages--Handbooks, manuals, etc.)

ACC _NRi AF6Q1705 SOURCE CODE; UR/O 1316 /Q00/QiQ/0l6V0'l0l_
TIMENTORi ~Samoylovl 11. S.; Ronzhin, 0. Vo; Bogoslovskikh, D. 1.
.ORG: None
TITLE: H~ydkomechanical throttling device with programmed control. Class 42, No.
181891
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. lo. 1966, 101
TOPIGTAGS; flov control, gas flow, valve
ABSTRACT., This Author's Certificate introduces a hydromechanical throttling device
with programmed control, The unit contains a needle for regulating the rate of gas
flow, an indicator for cheekiiig-the actual gas parameter, and a choke with a regu-
lator connected to an electromechanical transducer which operates an a signal from a
program unit which compares the actual gas parameter with the programmed parameter..
The installation is designed to maintain a given programmed gas parameter at the
output 1~y controlling the rate of motion of.the needle valve. A Piston is rigidly
connected to the needle valve with pressure fed to the rod cavity from the ouput of
the installation. The piston cavity ia.filled with fluid and connected through the.
choke to the regulator with simultaneous connection through a bypaSB tube to a check.
valve and a tank.
Card 1/2 uDc: 621.646-503-55-543.2

S/853/62/000/000/005/oo8
A006IA101
AUTHORS: Stroyev, S. S., Samoylov. N
-a-
TITLE: Investigating the scale resistance of some heat-resistant alloys
SOURCE: Termostoykost' zharoprochnykh splavov, sbornik statey, Ed. by
N. M. Sklyarov Moscow, Oborongiz, 1.962, 1o4 - 123
TEXT: The scale resistance of the foll6wing materials was tested: Ni-base.
type XC 3 (ZhS3) and "Nimokast" cast alloys.: Ni-base alloys 314,437 B (E1437B)
314 617 (E1617), E16l7 and "Nimonik" type alloys, 3H 787 (E1787) steel,
1 X Me (1Kh18NqT) steel and X2OH8OT (Kh2ON80T) alloy. A machine was
.)T used
performing 3 types of cycle; a) symmetrical heating and cooling and alternating
tensile and compressive deformation; b) accumulation of compressive deformation,
end c) accumulation of tensile deformation. The operational section of the spec-
imens investigated was 3 mm in diameter. The maximum cycle temperatures were
1,2000C. The scale resistance of all the materials investigated decreased.
with higher maximum temperatures of the thermal cycle. The scale resistance as
a.function of the maximum cycle temperature isexpressed by a hyperbolic curve.
Gard 1/3

3/853/62/000/000/005/008
Investigating the scale resistance of some.o. A006/A101
for Kh20N80T alloys, 1 Khl8rlVr steels, and EI437B alloys, and by a straight line
for Zh33 type, Nimocast, EI473B, type E1617, type Nimonik alloys and E1787 steel
subjected to dispersion strengtHening. When the maximum temperature changes,
best scale-resistance properties are shown by nickel-base cast alloys at the
lower level, and by E1437B and E1617 alloys at the upper level of maximum tem-
peraiures. Fractures and cracking occur perpendicularly to the longitudinal spec-,
Imen axis and are accompanied by changes in the surface and the operational sec-
tion shape. At lower elastic-plastic deformations the scale resistance of the
materials increases consiaerably, but the course of its changes remains the same.
with var~Ving maximum temperature. Larger diameters of the operational sections
raise the scale resistance of all the materials within the whole maximum tempera-
ture range. Thermal fatigue failure is accompanied by considerable stresses,
attaining and exceeding the yield and proportionality limits. The dependence of
maximum -thermal stresses on the number of heat altermations is of a complex na-
ture. The dependence of tensile stresses upon the number of thermal cycles re-
produces qualitatively tension diagrams obtained during short-time rupture. A
reduction in the diameter of the operational section of specimens increases the
maximum -thermal stresses. The thermal fatigue failure of some materials occurs
Card 2/3

L-0181.1-67 EWT(m)/EWP(t)/ETI JJP(C) 'jD/JG
Alff'NAI Al*:16035636 SOURCE CODE: UR/0089/66/020/005/0438/0439
AUTHOR: Garbunovq L._M.; MItenkovL F* It.; Samoylov2'O. B.t. Farmakovskly, Ve V.
ORG: none
TI11X : CroEld-section averaging In thermal-mgion for media containing ~Irconlum
hydride
SOURCE: Atomnaya energlyn, v. 20# no. 5, 1966, 438-439
A
TorIC TAGSt zirconium compound, hydrida
ABSTRACT: The average values In the thermal region T,ere calculated as a function
of temperature and -of absorption per single H nucleus, using the results obtained by
averaging the spectra for Infinite homogeous media poisoned by the absorber. It
was found that the averaged absorption ctoss sections follow a.W-1law and do not
exceed 20 barns in%the Interval from 293 to 7730K. Orig. art. hass 4 figures.
SUB COM 07 SURM nATEs 14 Aug 65 ORIC REF: 003
UDC: 539.125.52:539.17.02~
Card

I ACC NR: API'000803 (A IR SOURCE CODE: UR/0089/66/021/005/0
AUTHOR: Mit-enkov, F. M.; Averbakh, B. A.; Gorbunov, L. M.; Samoylov, 0. B.
ORG: none
TITLE: Contribution to the calculation of the Do
ppler temperature coefficient of
reactivity of homogeneous reactors
SOURCE: Atomnaya energiya, v. 21, no. 5, 1966, 4o8-41o
TOPIC TAGS: iraclear reactor characteristic, homogeneous nuclear reactor, temperature
coefficient, nuclear resonance, approximate solution, computer calculation
,ABSTRACT: The authors present a procedure for calculating the derivative of the res-
onance escaDe Drobability with respect to the temperature, or the derivative of the
effective resonance integral with respect to temperature, for the case of a homo-
geneous reactor. The calculation is similar to that given by G. L Marchuk (ChiL-llen-
nyye metody rascheta yadernykh reaktorov [Numerical Methods in the Design of Nuclear'.
Reactors], it., Atomizdat, 1961) for a heterogeneous medium. A set of plots of the
derivative of the self-screening factor with respect to temperature, which is evolved-
in these calculations, is included in the article. This set was obtained by,solving
the appropriate differential equation with an Ural-2 electronic computer. Orig. art.
has: . M formulas and 1 figure.
SUB CODE: 18/ SUBM DATE: 2lDec65/ oRiG REF: oo5/ oTH REF: 001
Ca-rd UDC: 261.039-512.26

i.G.; SAFICYLOV. 0 T
Exnarlance in the reinforcement of mine shAfte. Gor.7hur.
5 '57. (NITERA 1,,)9
I. Glarvi,;-.v inzhener Al ahnkhtoatroitellnogo unr,-vleni7a
(f or Orlov 2. Zame a i t e Inachr, 11 rika proll zvodst vennogo o t d, el a
Alt.yn-To,,)kanakogo mrnvleniya (fer Samoylov).
(Siisft sinking)
f

PODBOIISKIY, L.Ire.; SA~2~.O P. inzhener; SMMNDT, G.M., inzhener.
Set of devices for transporting concrete mortar with the-use of
concrete pumps. Gidr.stroi. 25 no-3:22-25 AP 156. (NMA 9:9)
(Concrete conatruction) (Pumping machinery)

FOIMORSKIY. L.Ye.. inzbener- SAMOYLOV, O.F. i=hSner.
Increa9ing the performance of S-230A concrete mixers. Stroi. i doro
masbin,ostr. 2 no.5:12-15 My '570 (MLRA 10:6)
(Kixing machinery)

(Pneilmatic-tube transportation)
(Goncrete--Transportation)

(concrete mixers)

PODBORSKIY, L.Ta.. inzh.; SAMOYLOV, O.P., insh.
Investigating the performance of an automatic concrete
placer. Stroi.i dor.mahinastr. 4 no-8:27-29 Ag '59.
(MIRA 12:12)
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el'S

heroftliamistry and mosis Strutsm. M: Red@ 4d
will Ills
Sr
slltis a( M
Co
" *ad
f
ti
1
h
i
2
.
air
i
s
ft 6
"
m
.
.
yt
g.
A. Of. Kaltuxtin-4kif inul 0. YiQ'i-implWY M S. Xur"llo'
Inst. Cwn- Ituirs. Clu-na.. ArailAri. Moscow).
I=h-st. Akad. Nank S.S.S.R., 0(del. KUM. XONA 1990.
2RZ7f.-Tbe following bests of sofa..
337-43; cf. C. A. 43 and Romini..'333.1. is tit error owing to their use of d&tA Ld
.
q. in kc-Al./mole, in IIC1 (molall concti. in parentheses)
01"
25 A 0 Berthelot actually rrtaininir to the hydrated adt; the
a
beat of hydration aelo, + lip - Cacto'.1110 (from
-
.
were dctd. in an Isothermal calorimeter at
M&C.0, MM) + 2-03; cacto, (3-8) -0,02; CaCVN.Hvo the heats Of 501n- In IIC0 IS 6.9. which gives for the heat
of formation of C&CtO4 332
0
clow to the vulue errone
(3.6) -OX); .1wC,0, (3.8) -2.45; BaC^ (3.9) -3.71:
16.714; SrCls
MgC1,611,0 (3-8) + 0.45; CaCl, (3-8) + .
.
,
owly uttributed by B. and R, to the anhyd. malt. A plot
of the beats of formation of the anhyd. oxalates pif
-
(3 .11) +QAV; BaCl. (1-9) +1-71. II.C,0. (3-8) -2-34;
The solids Avre in amul. livinq I
9) -2
57
0
IIX
(1 g.
equiv.. against the log of at. no. of the cation, gives the
-
.
.
2
1
to DJXJ M An. The best of funnatiOn Q Of
1*
P expected straight fine, above and practicallutt
trallel to
the correspondin
strai
ht line for th
i
i

:.
C1C,0' Is Q - Q1 + 0 - 2Q1 + q1 +
Kyd
1,
;
t e car
ts,
n
g
g
both m" Ca ties a little above the line
Be (carbonat
)

.
where Q, juji (), are the brilt.% of formation of
Y
CaCl, and 111C,04, tvsp., 0 is I hut of IIC1 in 3.8 M soln.. e
,
I
he ow it. The ifilkrence of the beau of formation per C.
equiv. of the oxalate and the carbonate of the sum .1k

and q3 anti V, aw I he hcuts of %otn. of solid CaCl, and
The%ameprocedure tic, .
earth tuctal is comt.. 17 ~ I kcal. U111% this value. the
i

to Q for Rnhyd. NtzC,O.. SrC 10.. and BaCtO.. Tar., ii-equ
v. beat of formation of HeCA Is found - 134a
kcal. close to the graphically esM 136
or 272 liral
/mok

of Saln. of anhyd. NIsCls in 3.8 Af IICI Is detd- by adding
the heat of hydration of ?-lgClj to the lwxahydrate, 32.19111 .
.
,
The &:~rrect value should be around 7A) Irul./traile.
kraLimole, to the Wat ofsoln. of N19CIt-AH&Q. Wlththt N. Thon
bral" of flifutatioll of anhyd, 1611cly. caell. firch. B&CIS,
Aild IIgA:t0,, rilmi!, rr,p., to 1&1.3, 190.0. 197.97 MA in
and 197.6. and the Irsts of faftnatio. of IM in 3.WAI It

/Wok' the
1.9 Af soln., resp.. to 38.71 and 39.07 kcal.
hests of fornuition of the anhyd. oxalstes am: USCA
:iws. CaCA 3W.2. SrCA 327.7. BACA 327.6 kW,/
ionle. Fix CaCvLN. thif value tabulated by Hicitowsky

Hydratilin of INK11111YIN IM 18 0498~w 0- ye-
Rlmollov (Acad. Scl. U.S.S.R., Nfowow). D414dy Aked.
77. (MIA1951).-11irtook' (CA. 37,
.14101; 40, 6%121) interpretation at the expri. fact that the
WITIP. CIDI!ff. of tLe mobility V of hydrated ions is greater
sem
than the temp. cceff. of the %ri ity q of 1110. by prog"s-
sive dehydratkni nith incrtraiing temp, and cormponding
titcrea4e of the Stoktz,; radii r of the ions, fAils to account for
[lie fact that for nonhydrated ions dUltdT < dq/qdr.
whemiq Stoke.-V tilmition Vill, - cunst. Sly" dtflUdT -
--JI/qdl*. Actutilly, tile very colierpt of it fixed no. of
11,0 mol%. bound toun 4m.,,and Of A definiteNtoket rad1ka,
it at fikult. The lutal hydi nm energy of an Ion consists
IV[ ;I 10;Irt title In the lit-arest surrounding IFO mols.. which
Illay cith .c.r incrt-aI%c-or dectria-sc the entra of the s Iyste.m
Iml-140, and a part due to the =in of the scdr I of the
InDre reluote 1110 mols.. and which always reVAIL A is 41111-
CTCAM of that energy. The activatiolt "Iterly A Go Ill ad the
11,0 tools. ne-arest to the [on is Increased by hydrated Jews.
but 11"Ireased by nonhydrated ions. Consequently. In the I
'tillice. tile lutrall little 131 stay Or 1110 around the Ion
("mig. hydtatlems"). .18,1 1. incleAsed In the
A-igunieut of it fixed hythathut no. to an Ion
And introductiou Of a definite Stokes I, would be Jumuled
OWY if tbAt time Of Slay Were V
cry markensy JoISM than am.
COrl'"Posdingtimeln pure 11,0, Tbatthigignagollims
CO=t-- With 1h - Viscosity of JJg0 In the nearest helghbW
hood of t-he ine. r. - crystalloche,
n. radisis of the i..)_
With E + AE of the triewes; glow as
modified by the Ion one has ldqlpd7l ~Aftlftdlze;
AEIRP and P
WIFIM + Idgled7l - IXZ-..
ftq-tlY, if A > 0 (hydrated ions). WlVdr > - dqlvdr
WW it AN < 0 (neg. hydrztion).-4IU/VdF < _Jq1,dF:
f`- &YOU" data to' for 160 and dL,111,W T kw Ll
and CJ-. one finds for LI Ag . 0~4.
-0.4 kcal./mole 1lo; these figw,, and for CI AE
are lowell, th,, d,
definitely too high estus. of Eucken (C-4.4;, 64Ws). The
value of 4E for Lf " Shows that eveit in this Instance of a
Iat-sly hydrated univalent Ion. there can bit so question
of any Pertnaneint bindin Of HoO mols. by tile loo; dm
tisse of may r at 110f) =. Around Li 0 is wely twim tha
(n) in a pure HoO =Wfum (by I - W&x jar), .1 At Sense tger-
else "J"Y"a of 4 ""In "ItIldinatmin no. of HeO Sovie. sg;~_W
an Im; thle a*' 'a locee""d in mmPui" with pure H00
If I > to. anti isderreaxed 11 1, < '. The minond. of itt'
Around a lIpfratmi Jou is higher. and around a -hydraw
lon lower IIIAII thAt Of pille ]JAY. Ktotrolytie IftUble"MCM
Of 11110 COUSISts in transference of voh. of great" or lusafier
d. Motion of hydrated callous to the cathode 1# accost.
P-iOd by effective transference o(ff,0 in themmedirection-
"do"I Of nwhYdrated unions to I be zMde is gft=.W
effective transference of Iflo in the te directloslN.
N. Tbm

he"Mco of hydr" Ionst on tim hentsersafultifin of"",
o. ya. sanionny (N.H. Kurnakov Insi. ren. Innre. Chem.
INT Y.'- Po4kily Abad, Nask S.S.S.R. St. 641-4
(1931),-Integi-al beat$ of soln. L of 11CI, KCI, 119CII.StIr.
0. CaCh. V,%f-p4Br (0.05 moles/60 mows MO), mud N&CI
MA7 moles/M moles 11,0), in sq. IICI joint. of in (moll"
I let "An ifloles 111.0) lip 11) 3.A. liv Isitibermat rularimetry at
211'. Por.111 Ill*%* 46116, Willi 1110 elimption fit NN4414r. Immi,
1. derfr~, and nrit, L Inefraw, linearly Willi Itiffoanillm me.
The tirg. Aopi,i hirrease from LICI to NaCt to KCI; "Mall.
quently. the effrct in linked Willi hydration of the diesolvin
rations. The heat of win. of N'sCI In sq. soins. of HCI
I'190t. and IA0 times" linimfly with IHCrM%Iflg LOOC.
If of the clrrmixtialling clertrolyle. the slope decrefting it,
d~. but L of V&Cj it, 1q. wins. of KCA increases
Imenly with irnreasing NJ Of K('I. Them effects can t he
interPfTted On I he basis Of the beat of hydration It audo the
mkd'O"`(thelf1-0+im-
cut.. as against I-M ". fcw.LI4; however. 11C1 depresses
L of XaCl mom -strongly than dces LiCl. Therafflusofthe
140*1011 should beclosetothat Dfthe1l,0mo1..I.-78A..i
Close to the radius of K* - 1.33 A.; nonetheless, the effee*73
of HCJ and KC1 on L of NaCl are te. A possible in-
t"Welfilion MIS on The conmyt =t proton waliffering
Irnm me IGO tool. to anoth". and staying: Only a short
wmit with any definite IIA
a ments Pos, ejec. charge ~ (smaller than the elementary
char 0) beinit imparted to each 11#0 mol.. mind can be rell,
Jeanted formally bT a "Inean" Ion Ill. WoUfM*. such
; pratint Y.
an Ion Can be CMCV ved **fill to the fact that I it
the "well llast of stay Of a proton with a firtillit Ilil limit,
is much "t~t thiin Off m"n lInw Of stay Of that 1114)1- In
its temporary equIl. t1w. The exhilrove fit lite mrisis
r 71. uls"i between the
cb&rp # rejWts a fame Rddni. ffif
ydr%ting 111*0 mots. and the hydrat"ble cutIOU Of the salt
gains into soln. The energy of that rePulliOn lower$ It "I
thq cation, and.con'tcrientiv. lowers L. Althesametime.1
the mean pas. charge of the it.0 mots. riniulti, in -cute addift.
attraction to the anion of the sail. Gettemily, the repul-
sion effect on the cation predominates. but the attraction
effect . th. aid. can become predominating if the anka
is much windier than the cation. as In NifeAfIr. In this
caft, L increases with IncreaAme Sit, of 110. as of-1.
The effect at HCI on L of salts permits an ntn. of the cts,-
ordination no-otimin 211- 201-- Ittur"soutth"indil.
wins. each Cation is surrounded, on the av.. by 4 HO mals.
N. Than

fop T 7
byL
Ye~]
T

-,-LLU lumon].", IL I -the
'it for
J-
to-ordina
0= for m4tdnl~).'

- h
C'f "Gmii in 06 co-
Hall
th
so coffeB
S
I-4i 4 $
otul
l
.
a
"
m
P
p
O
ing to tba Ilist mawin thim~cu;" of ridiA -awAu
tion), and
IAT
t th tal 4113 the.
tem
or wh
lek th
e
p.
161 IiQmo~ cases: (e.g. v
Athough 62, is larje
at appian that,
.
112 < Ith, "and the diflimaw increaecs witivincreasing atomic.
'
otaultber.-I omp!
t1i to of Uni:
d
or an
x 'n
w
iiii it
*ini
tbat
hid
n
4b

1
d
~'a=W~Uqwla
-
, e
ovi
y
g
g
. p
iitlemp. h
~'re
Y-z"-bt6cks",-i)f-itoms--(cf.~- I
At,
It
X
1
Kinetic - ]VO
r ......-
conto

de to w
61
be
in orddir to c:4160106 ilia mean numlier

i
'n
f o ~iiridtli itrai. crik~-.kp

a bos -m~ I).

ilia the rat IQ
60

uid and 361id, at
th
O'ni-1P. 0% i
~~
midthi cAculated b 0-10, 0-14~wsd 0 07- 1
in formula

and,
Air Na,,
6br
wrved c1 ango. I
n
I ) , , - t L: ~,~l
are ins fficiont*,Io~caust,
-Wi4tativo -exp na tjorv,uls-ia
a
" '
"
to
mexis nexio iii
?
histi U). V eriich,
4o investi
*
-
the dcpcn& co-afti: -nIjIwf6
a it fBbp4-ru
I
to oem japi ut i~

liquid, S. ca o6

'
t
d
s 6 r
i
b
cxp~rfinhnti.
All n ddds'~ t.
Owel Ing oi-
'
d'wtiu
f
h
k
r
.1 or
i lo
i
~
t
en mit
o
es
to

a I random tiael

,
' -Tl -ardi

layer. ~ to mean 66 nation num r
le

6r ilia rem
r4d .2-110'eretisqd~ Linearly "writh
6 inteiiial 6yet
-tile numbili: orvoitt ~~- The gnspli- obtained'eauld be used. in

Cimiunction with t1v
*
'
i knovvii if -'ea at
vit1luts orn., wid. L116 Icr%2
v
,
~
_,viM, Pii- Incl
to
hig, tculawil
and Roar( iniousinw-.
a vol.
'

(d!) of ilia holes." '
Min, t144nolizzi 1j. Nii; K.
In"
llg, mitt

S, 4 Mimi

SAflOYLOV, 0. Ya.
USSR/Physics - Solid 5tatc Phyalue Nov 53
.*Conference on the Liquid State of Yatter, Hold 2Z-30 Pay 1953 at Niev bv, the AcadwW
of Sciencess Ukrainian ZSR., and Kiev State University im T. G. Shevchenko," S. D.
PAvikovich
G. T. Podbehina and F. 3kryshevskiy
Usp Fiz flauk, Vol 51, No 3# 393-405
Summarize retporta by the following; V. i.-Danilovi on scattering of x-rays in liquids;
A. F. Skryshevskly, on x-ray study of nolno of K011, MON.. LIM, LIM#, and H S041 U.
A. Foray-Koshita, on integral analymia of Intenoity cvrves; r.,V. Uragin, is, 00
r,hvidkovskiy, C, Ya. Saroylov et al. cn x-ray studies of liquid structtre; A. Z. GolikV
on. cberacteriatics-,-oT7r-oTe-c-07ar structure of liquids; 1. V- Fadchenko, an modeling of
liquids; F. X. ShesUkovich, on now liquid rodels end influence of central and dipole
forces on close ordering; A. Z. GoM and his associates S. D. Pavikovich, A. V. Orish-
chenko., v. % solcrao, and 'N. A. rvndich, on viscosity aM density of matter In the
liquid str4te; V. V. Chulmovskiy and D. S. Karenetskays, on the influence of tolecules,
size and the intermolecular Intensity on viscosity coeff; A. F. rrynza, on tharwo-diffu-
sion in binary systems; S. S. Urazowkiy, rresenre of grouping of identical atcmo; A.R.
T'egel I,, on relation between electrical properties end structure of, liquids; ~,. F. Wks,
on light-dispersion ir;ethod for studying liquids' structure.

'7
%
Akad. Na
Uk' S.S. he
fons on translational tnotion-:of the n' water mol. is
by magnitudes'of AE, the chafi In ionic po-
ge
tentfid barrier. The. magnitude depends on. the, crys
ulius of tim lons, and . when,&E > 6, th -andwh
ey hydrate, en
;'AE ~C 0, they do not. - Ile boundary condition carrel",
r.-si.1.27A.-This:coriespon
nds to ds toa hypothetical
In nd which thvr~ean
surfike d. of nedreit water mols..
6orresp6nd3 to
-the mean 3urface d. of wat ols In ter.
er
wa
'Inthe eiluatibn p' "14w(r on:
inad
n
TI dius of 16'and mol. teis'4W +
1.38 is them
Surface of l5i,coami
Ination SR of. Ion add:
repcesents the q0au.surfam &of.watrx 14q nearest the -
At 25* plmt,~ - .0.044 A;;: from thb 1.24 A.
hkh respondd cloiely, to "the value obtained b
Im cor Y'
alls X -and N&'~
thermochim. methads. Mlsialtie falls be
forallrall -metals. V. N.'Xednarskl
7
T . . . . . . . . . .
4.

tdt?o Wlatims'
of
)w proce".

54MOY40

dmibtry,
SiOU cheld t~17
Nr

.-Caxd 1/l Pub-':, 22 -

ore
uth
A
L
13n

litle , 1. The~:mo 6m ~the-,b,ti~Udture.6-f-diliit6d.~6Que 'Jul-

ch, ical st~i*'of OUS Urp
- ''. , _ - 1.

chloride And uii*l. itr e--solutions-'.,":
_n

p6riodital
1~- 99-102-;, 1 1954.-~
Dok. MSSSR 58/

Astract . ~ ~

f -;Oolution~'of UO~01~', :3%0 `band' (No
he inte&al hed 6-p '-UO
_- ~- , --3- Z

ere a H,
in- ad in aqueous, Acid - 6 u ions b~,:, th
me sur_ 0
2 A
e U ti" f
emi,6~1, m th6d or a--
th6amoch din ril~,:us d
or the de
a on o
- e
~
.
.
,
`
coo .rdinatimi m~bero of.,lons": -in 'aque .ous solutI ion,si` -The ieiAfo~
between the he`iCts- of.~ soluiioii~ of: -the s s. ~snd - the acid, ponde'n-

so. established'4-.
triition: in th6 - solvont w6s -established. Weis al
thtit the ~'structiire of -diluted' S'olution~o* 'corresponds --.~to- th Abb,

poosible 6hafige h structure H 0 '.,i fo
in t e of i, q, rmat;L
-I
_
_.I__
H (Y.
_:in-
~of, diluted solution's.the structureof rema sl~
2
-teen re erences:- 7- R Orman~

unt,
6ur
(19~i�53) iLble;, graph;' draw
Institution I cad. df.Scs~'USSR~r'Th~%N S ~X akov Institute of denw~31 .'and, -
urn
Inorganic,Chemistry
Presentee
Iby z_ A emIcian erp" 9
cad April 10 1 54:1,'I~

SkMOrUff, O.Ya.
Relation betveen the nobility and self-diffusion coefficients of
ions in solutions. Izv.Alff SSSR. Otd.khim.nank zo-3:572-5?3 My-
Je 155. 8:9)
1. Institut o1shchey i neorg anicheskoy khimii im. N.S.Iurnakova
Akademiimuk ISSSR.
(Ions) (Solution (Chemistry))

73 - ~-f /I ~,-
SAMOYLOV,O.Ya.
Negative ion hydration in aqueous solutions. Dokl. AN SSSR 102
no.6;1173-1176 Je'55- (MIRA B-10)
1. Inatitut obahchey i neorgaLnicheekoy khimii imeni N.S.Kurnakoya
Akademii nauk SSSR. Predstavleno akademikom I.I.Chernyayevym
(11~rdration) (Ions)

SAMOYYJM, O.YA.
Structure of diluted Aqueous electrolyte solutions and the hydratiom
Of ions. Shur.noorg. khim. I ne.6:1202-1209 Jo '56. (KIaA 9--10).
I.Institut obahchey i, neorganicheskey khimii imeni N93.1turnakeva Akade-
mii nauk 355R.
(Blectrolytes) (Hydration)

SAMOTIAN, O.Ta.
Coordina-tion numbers of Rb* and Cs+ ions In aqyeiys nikytuibs, IST.
AN SSSR.Otd.k,him..aauk nooll:1415-1416 N 056. .(MLRA 10:3)
1 Inatitat obahchey I xearg&nIch*ako7 khimii im. N.S.Kurnakova
;;,&~smii nauk SSSR.
(Rubidium) (Cesium) (Ions)

5 - ; , 0 '1- -
".. i ~ -. . - ~l ~ - 1~ -_,- 2"z * ,
- - . L " - -1 -- - - --,- . -,
- ~~i I , .. ,-.l,---,, ~, 1,
~ - 1 ~'. ~'. -, 4 " ." , I
1~1 - :% " -,": ". -, ":1- 1- ~

KAPUSTINSKIY, A.F.; LIPILINA, I.I.; SA-MOYLOV, O.Ya.
Gold calorimeter with sensitivity of 0,000050 for studying the
thermochemistry of solutions. Investigation of the heat capacity
of cesium iodide solutions with a tolerance of 0. 03 la (with
English summary in insert). Zhur.fiz.khim. 30 no.4-896-900
Apr. '56. (MIRA 9:9)
1. Akademiya nauk SSSR. Institut obahchey i neorganicheakoy,
kbimii iment. N.S. Kurnakova, Moskva.
(Calorimeters) (Solution (Chemistry))

SkNIAOYLOV, Oleg Yakovievich -- awarded sci degree of Doe Chem Sci for
the 8 Oct 57 defense of dissertation: "Structure of water solutions
of electrolytes and the hydration of Ions" at the Council, Inst of.Genl
and Inorganic Chem imeni Kurnakov, AS, USSR; Prot No 159 7 Jun 58.
(B2001 1.1-58127)

5(2) P HAS E I BOOK EXPLOITATION SOV/2735
Samoylov, Oleg Yakovlevich
StrukturEL vodnykh rastvorov el6ktrolitov i gidratatsiya ionov (Structure of
Aqueous Solutions of Electrolytes and Hydration of Ions) Mnscov,.Izd-vo
AN SSSR, 1957. 179 P. 4,500 copies printed.
Sponsoring Agency: Akademiya nauk SSSR. Institutu obshchey i neorganicheskoy khimii,
Resp. Ed.: A.F. Kapustinskiy, Corresponding Member, USSR Academy of Sciences; Ed.
of Pdblishing House: N.G. Yegorov; Tech. Ed.- P.S. Kashina.
PMIPOSE: The book is intended, for physicists, chemists, and chemical- engineers.
COVEP,kGE-: The book discusses the structure of aqueous solutions of electrolytes',
the thermal motion of atoms,,and a new approach to studying hydration of ions
in solutions. Problems considered in the 'book were studied'at the Institut
obshchey VneGrganichesko 'k'
.y him'i imeni.1.8-. Mxrnakova Akadem'i nauk SSSR
(Institute of General andinorganic Chemistry imeni. N.S. Kurnakov, Academy of
Sciences, USSR). The authar thanks A.F. Kapustinskiy, Corresponding Member
of the Academy'of Sciences, Professors:V.Ya. Anoso.v and-M.A., Klochko.:and
Acadjamician A,N. F~nxnkin. , He also I thaas * A.-ra. Samoylova.- There are, 229
reierences: !)0 Enei~b~, 89'SovietS 25 German, 18 French... 5 E- niglish, Italiazi,
and 1 Jai3anese.-'-

4 f e V U
AUTHORt Samoylov, O.Ya. and Sokolov, D.S. 11-9-7/14
TITLE: Conn*ction of Vertical Hydrochemical Zonatio n of Artesian
Waters with Peculiarities of Thermal Motion of Water Yole-
cules and Ions.,_ in Solutions (Svyaz' vertikallnoy gidro-
osobennostyami
khimicheskoy zonallnosti artezianskikh vod e
.
teplovogo dvizheniya molekul vody i ionov v rastvorakh)
PERIODICAL: IzXestiya Akademii Nauk SSSR, Seriya Geologicheskaya, 1957,
9, P 72-80 (USSR)
ABSTRACTz The author eXplains the general features of vertical hydro -
chemical zonation o~ artesian waters by processes proceeding
in solutions under conditions of slow descen -ding motion of
water molecules and ionst arise additional flows of particles
-
ihe.general motion of artesian waters. The
superimposed upon
author puts the following conception into the basis of hi.s
research: the ~herpal motion of particles in a liquid con-
siste in the fluctuations of particles around some temporary.
equilibrium states on the one hand, and jump-like transitions
from one equilibrium state -to another on the other hand,,, The
i
translational motiorsof particlesacre ac-tivaied Jum
p~ accord-
ing,to Polissar (Raf.'17) and Wirtz (Ref. 18). The author
Card 1/.$ summarizes the results of his research as follows-

11-9-7/14
Connection of Vertical Hydrochemical Zonation of Artesian W aters with
Peculiarities-of Thermal Motion of '#star Moled6le-s and Ions in Solutions
1. The average Qpquency,of.activated Jumps of sulution
particles (water molecules and ions) changes with depth.
This gives rise to additional flews of particle's of ions
downwards and-of water molecules - upwards. The observed
IncreaBe in mineralization of artesian waters with depth is
connected with this phenomenon.
2. Additional flows and correspondingly additional velocit-
ies of different ions are.unpual. Hydrated ions (most of
cations and also HCO_ and Ca ~) have considerably lesser
3 than
additional velocities no characterized by negative
hydrat-ion (most of-anions).
According to-the magnitude of additional velocities
4owgwards the anions can be arranged in the following series:
HCO- 2 P Cl-< Br < J. The observed vertical hydro-
I < so <
chatical lonation of artesian waters depends upon this differ-
ence of-velocities. In case of cations, the connection of
zonation with hydration is manifested less distinctly.
The article contains 1 graph and 18 references, 13 of which
Card 2/1, are Slavic.

7Yjr. Pis. Rhim. 31, 537
X-ray invcstiptian results and the diffusies study indicate
that tl:e mal. arrangement of tee is rcwinm in water. The
leads to a filling-in of
trapsiz tianal motion of water mots
-.mafies of w-atex
holes n the structure. The are act
4aked M.1h Oic mol, assocan., but -with i_-- sIxxti-I Pe-qu-
Harities. Thegiare (Q*the t
the cksest regularity in the arrangemem of water mots.
-tr,)nglv e,ident tham ir, ,rher liquizis. T-c lad
'A,

r.,Y

P= C4 &nd
wuh an oft thermal ;!uvtkv& for dc%,.Ih,
the scollm- Are Au Qr I'L I'lm t=p. 13 meas=tJ A
rtsimma" themme= With a VA*-Lvhv at 6 x IL C_
7'me Sp- hftlS of aQ. 80h.13. --Of CAE at 25*'for MCL~
h~ IM afid- G _93 weti deW. 6 W33 dezd. as U.02
cal.lmdlq d--,T!T for a so.la- at Birkite dun. IL _R_

-/, 5
1 -26
SOV/2o-12 -6 'J
4
,
U.", OR samoylov, 0. Ya.

TITLE: the Theory of the Temperature Dependence of the
Coordination Nu:,~bers of the Ions in Aqueous Solutions
(1r tacrii te;.raperaturnoy zavisimosti koordinatsionny'Kh
chicel ionov v vodnyklt rastvorakh)
PERIODICAL: Doklarly Akadenii nauk SSSR, 1958, Val 121, Nr 6, PI) 1043-1044
(TJSSR)
A3STRACT: This paper investigates the problem of the temperature de-
pandence of the coordination numbers of particles in liquid
solutions of electrolytes. The particles of the liquid and
especially the water molecules in the aqueous solutions of
electrolytes constantly have a translatory motion - they
constantly perform activated jumps and interchange their
next neighbors. The observed values of the coordination
numbers are connected with 2 contrary processes: 1) with
activated jumps of the particles which convey them away from
the immediate neighborhood of the chosen Particle and 2).wi-th
activated jumps of particles which make the particles enter
Card 1/4 the immediate neighborhood of the chosen particle. The first

SOT/20-121-6-26/45
~oncerninrr the Theory of the Tennerature Dependence of the Coordination
.1unbers of the Iona in Aqueous Solutions
process causes a decrease, the second - an increase of the.
coordination number. The coordination number of the selected
particle depends on the equilibrium of the exchange of the
particles placed in itsimmediate neig-liborhood.,There is an
equilibrium condition for an aqueous solution of an electro-.
lyte. The problem of the coordination rumbers is investigated
for the rerdon of diluted solutions, and it is assumed that
the immediate neighborhood of the select6d particle contains
only water molecules. The.equation niji,= nj may serve as
an equilibrium condition; n. denotes the coordination number
of the ion, ji the average (with respect to 1 see) number 'of
the activated jumps of the water mQlecules in the immediate
neighborhood of the ion, n and j - the coordination number,
and the average.(with respect to 1 see) number of the activat-
ed jumps of the water molecules in water. An equation is
.,iven for the temperature dependence of the r tio, n,/n. If
g a
the teuperature increases, the coordination numbers of the
CarA 2/4 ions of neeative hydration (A E 0) will increase, but the

SOV/20-121-6-26/45
Concerning the Theory of the Temperature Dependence of the Coordination
Numbers of the Ions in Aqueous Solutions
coordination numbers of the ions with positive hydration
will decrease (with respect to the coordination numbers of
the water molecules). If the temperature is increased, the
water will be displaced to or from the ions (according to
the sign of A E). The investigated dependence of the tempera-
ture variations on the values of the potential barriers
(which separate the neighboring positions of the equilibrium
of the particles) is a general property of many liquid solu-
t4 -ons. The dissociation of compounds in liquids at higher .
temperatures is a manifestation of this delm ndence. Accord-
ing to the results of this paper, the dissociation in many
cases can be reduced to the following: If the temperature
increases, the particles of the liquid are displaced within
a region with lower values of the potential barriers. The
coordination numbers of the ions depend only slightly on
temperature. It is necessary to endeavor to determine exper-
imentally the temperature dependence of the coordination I
Card 3/4 numbers of the ions in aqueous solutions. Thdre are 3 ref-

SOV2o-1 21-6-26/45
Concerning the Theory of the Temperature Dependence of the Coordination
Numbers of t1m Ions in Aqueous Solutions
ASSOCIATION:
PRESENTED:
SUBMITTED:
Card 4/4
erences, which are Soviet.
Institut obshchey i neorganicheskoy khimii.im. N. S. Xurnakova
Akademii nauk SSSR
(Institute of General and Inorganic Chemistry imeni N. S.
Kurnakov AS USSR)
April 21, 1958, by I. I. Chernyayev, Academician
April 3, 1958

SAMOTLOV,-O.Ta-,, '
StrILCture of aqueous solutions of electrolytes and the hv-
dration of ions. Itogi nauki: Khim.nauki 4:48-54 '59.
(Electrolytes) (Ions) (Hydration) (14IRA 13:4)

5(2,4) SOV/62-59-5-29/40
AUTHOR: Sarioylov, 0. Ya.,
TITLE: On the Problem of-the Adsorption of Diffenmt Ions From Aqueous
Solutions_(K voprosu ob adsorbtsii razlichnykh ionov iz vod-
ny1ch rastvorov)
PERIODICAL: Izvestiya Akademii nauk SSSR.'Otdeleniye khimicheskikh.11auk,
1959, Nr 5, pp 931-933 (USSR)
ABSTRACT: The translatory motion of the particles of the solution1s in-
vestigated according-*
.to reference 1 in such a manner ae if the
,
particles performed-activated jumps from one time-equilibrium,
to the adjacent one. This conception in the present paper forms-.
the basis for the investigation of the adsorption of,va.-ious.-
ions from aqueous-solutions on the surface of solids. The
solutions are diluted to.a. considerable extent, so that ions
interaction in them may be neglected. Besides, only the ase of:,-.:
c
a weak hydration is investigated. If a transition (an activated
jump) of ions from and to the surface of the solid takes place
(average num .ber of ions jis and j ii res-pectively),,the relation

Card 1/3 c is jil
-
t
exi
bet
en the
t
at
n
s
we
concen
r
io
s c 0
s
s is ii
Ti

SOV/62-59-5-29/40
On the P::-oblem of the Adsorpt-ion ofDif2i-ent Ions From Aqueous Solutions
of a type of ions i on the surface and in the remaining volume
of the solution.and the times T in which the particles
,is, 'ii
are in equilibrium. In the,cases of a transition into an other
ecuilibrium under investigat -ion the particles' must have the
energy B + 4E and near the surf ace E + AIE + (I -a)AF, (0